JAERI-Data/Code 2001-005 - OSTI.GOV

JAERI-Data/Code2001-005

B * Bi ? 13Japan Atomic Energy Research Institute

7\i- Y ! i ,

&fr ( T 3 1 9 - 1 1 9 5

9- (=r319-1195 'XW&fflWU&mttU^UTtlVltttffift) ^Ig'^C i i,

This report is issued irregularly.

Inquiries about availability of the reports should be addressed to Research Information

Division, Department of Intellectual Resources, Japan Atomic Energy Research Institute,

Tokai-mura, Naka-gun, Ibaraki-ken, 319-1195, Japan.

©Japan Atomic Energy Research Institute, 2001

JAERI-Data/Code 2001-005

( 2001 %• 1 n 300

319-1195 - 4


Development of Database on the Distribution Coefficient(1 )Collection of the Distribution Coefficient Data

Shinichi TAKEBE and Masayoshi ABE

Department of Decommissioning and Waste Management

Tokai Research Establishment

Japan Atomic Energy Research Institute

Tokai-mura, Naka-gun, Ibaraki-ken

( Received January 30, 2001 )

The distribution coefficient is very important parameter for environmental

impact assessment on the disposal of radioactive waste arising from research

institutes . The literature survey in the country was mainly carried out for the

purpose of selecting the reasonable distribution coefficient value on the utilization

of this value in the safety evaluation.

This report was arranged much informations on the distribution coefficient for

inputing to the database for each literature , and was summarized as a literature

information data on the distribution coefficient .

Keywords : Distribution Coefficient , Literature Survey , Database,

Literature Information Data , Institutes Waste , Disposal ,

Environmental Impact Assessment


s

2. JCffim&Jjtik 2

2. 1 M&tt&XM. 22. 2 I8S#& 2

3. Xlt t f lH&x-* 5

4. * tifit 330

Wl # 331##£SK 331

ft aft &-1 XlttUXh 332ft ft- 2 #gE&&©£« 344

Contents

1. Introduction 1

2. Investigation Method of Literature 2

2. 1 Literature as an Object of Investigation 2

2. 2 Investigation Method 2

3. Literature Information Data 5

4. Afterword 330

Acknowledgment 331

References 331

Appendix

Appendix-1 Literature List 332

Appendix-2 Definition of Distribution Coefficient 344


2

3

4

329

330

IV


1.

o o

H, Be, C, Al, Cl, K, Ca, Mn, Fe, Co, Ni, Se, Rb, Sr, Zr, Nb, Mo, Tc, Pd, Ag,

Cd, Sn, I, Cs, Ba, La, Nd, Pm, Sm, Eu, Ho, Hf, Re, Os, Pb, Bi, Ra, Ac, Th,

Pa, U, Np, Pu, Am, Cm, Bk, Cf

tLXMZi&Wt (Distribution Coefficient) WJA<

., &mm%.$kflr, m'jU


2.

2. 1

iL,

WHaift)|s|- (JAERI-M, Reserch, Tech, Review^)

2 . 2

o

JAERI-Data/Codc 2001-005

, ti 7 zRR ft

TiiLT<

A

B

cD

, IAEA Technical Reports

Series No. 247(1985) " 'Hk

S£*J t [nu/g].

3 -


- 1

mmmu

D-Aetc.),

it,

* y-mmmm

mt^mrn

MftMffl

mm

0. lN-KClSlffl, lN-CHsCOONHJbttJetc.

- 4 -


3.

assist.

- 5 -


BBi

D

A* U 7 1A*U7 2A* IJ73A* IJ74A* 'J7 5A* U76

, Eh,

A*U7 A*'J7 AU73 AU74 A* U 7 5 A*>J76

3 H1 A S~*

60 C o5 9 N i6 3 N i9 0 S r9 4 N b" T c

129 J

"'Cs

Am

0500100300300301000. 523

1000010000

04

70040040010

4000. 3030

1000010000

03

100808010800030

1000010000

01

300200200702000.80. 3

100020002000

01

5050502005000

100100010000

o2

6005005002004000. 50. 1

100020002000

t

- 6 -


:\ week, j i j i / O . 45£tm;membrane)

22-1

D

4 2 * y - > i 7 > ^ - ( 3 5 0 j i m ^ T , JIS Z 8801)

. Eh. ft-?r-r^

(3. OX)(0. 1%)

, Tc 10/3)

Desorption (M in, Max/Da ta&)

CCoN iS rTcIC sPuAm

535 ( 170,14500(14000,91100(83000,

45. 5 ( 45,0. 66 ( 0. 58,

125 < 120,82. 5 ( 80.

53000(53000,47300(43000,

2000/15)15000/ 2)1. 0E5/ 2)

46/ 2)0. 76/ 2)130/ 2)85/ 2)

53000/ 2)52000/ 2)

296 ( 250, 450/2)5840( 5500, 6200/2)

22000(22000, 22000/2)99. 5 ( 99, 100/2)

35. 9 ( 34, 38/2)46100(38000, 56000/2)44500(38000, 52000/2)

5370( 2700,250( 250,450 ( 450,1850 ( 1800,998( 830,

2. 72 C 2.7,5. 04 ( 4.8,53000(53000,42700(35000,

21000/7)250/2)450/2)1900/2)1200/2)2. 75/2)5. 3/2)

53000/2)52000/2)

160(440(855(

160,440,830,

4. 5( 4.5,43000(33000,49000(49000,

160/2)440/2)880/2)

4. 5/2)56000/2)49000/2)

- 7 -


:l week, l t i i / 0 . 45 ,tim; membrane)

22-2

D

illJ I S Z 8801)

(3. OK)(0. IX)

:> 0. 45 Aim©7

T c , I I 5/3)

. . . Adsorption (M in, Max/Da t age)

ccNsTICP

oirc

su

Am

16. 2(4950(3750(26. 7(

0. 311 (0. 375 (

114(

1.2,4800,3700,24.5,0. 22,0. 37,100,

58000(58000,52000(52000,

130/8)5100/2)3800/2)

29/2)0. 44/2)0. 38/2)130/2)

58000/2)52000/2)

9. 54 (770(1340(39. 0(

36. 0(

7,670,1200,38,--35,

53000(53000,61000(61000,

13/2)885/2)

1 500/2)40/2)

37/2)53000/2)61000/2)

—3690 ( 3400,1300 (19. 7 C 19,

--

60. 0( 59,48000(48000,56000(56000,

4000/2)/I)

20. 5/2)

61/2)48000/2)56000/2)

2. 89 (2470(440 (

72. 8 (0. 729(

0(877(

12000(1

2. 2,1700,380,

65. 5,0. 70,

0,770,

11000,52000(52000,

3. 8/2)3600/2)510/2)81/2)

0. 76/2)0/2)

1000/2)13000/2)52000/2)

- 8


22-3

D

ffl

%

ft

HUT••

•€•<£

CC oN iS rT cIC sP uAm

7tt<£

:S : 4

M * +

27. 7 (1840(2900 (18. 5 (1. 53(

0. 335 (65. 0(

£ (

U7,¥io

.(pH,

Na2B

jfgfg-1

04 (3.4O7 (0.

week, J l t . jM/0 . 4 5 / i m

*>«£. urn

m)IX) J

.= 10/1 (fc/fU Tc

0. 52,1700,2900,

18,1. 3,

0. 33,64,

61000(61000,72000(72000,

.. Adsorption t$

670/8)2000/2)2900/2)

19/2)1. 8/2)

0. 34/2)66/2)

61000/2)72000/2)

8. 09 ( 7.2,155 C 150,498( 420,

37. 2 ( 33,-—

33. 0( 32,54000(54000,58000(58000,

^ )C H OJl/ 7 —

£pH

SGe 4, I \Z1

;membrane)

IIS Z 8801)

H^Ttt 5/3)

%.¥•%](Min, Max/Datagc)

9. 1/2)160/2)590/2)42/2)

34/2)54000/2)58000/2)

—417 C 410, 425/2)

78. 7 ( 62, 100/2)9. 59 ( 4.6, 20/2)

--

45. 6 ( 40, 52/2)34900(33000, 37000/2)48000(48000, 48000/2)

tbtpm

\Z. 0 . 4

7D>S

4. 81 (6880(

844 (

1 1 5 C0(

0. 005 (967(

LL//

•5 MB

3.4,4300,

810,110,

0,0,

850,47000(46000,68400(65000,

t fc CO)

g^jo. 1

6. 8/2)11000/2)

880/2)120/2)

0/2)0. 01/2)1100/2)

48000/2)72000/2)

- 9 -


week, M'L . 45 M m:membrane)

22-4

D

15wt%, JIS Z 8801)

0. . \%\z

(fzfzL, T c , I f d O ^ T t e 5 / 3 )

... Adsorption in, Max/Data^:)

cCoN iS rTcIC sPuAm

1. 21(51. 0(56. 4(255 (

0(0(

174(1150 (

0. 36,49,54,

240,0,0,

145,1100,

6. 1/5)53/2)59/2)270/2)

0/2)0/2)

210/2)1200/2)

26100(20000, 34000/2)

- 10 -


(WM: 2 days, Decant at ion)

22-5

D

R T . JIS Z 8801)

Eh,0. . \%\z

i t=50 / l (fcfe'U T c , I C 5 /2~5 / l )

C oN iS rNbTcIC s

. Adsorption (M in, Max/Da taSc)

295 ( 27,240(6. 7,

75. 9 ( 7,214 ( 90,

0. 82 ( 0,0. 30 ( 0,

3300/82)1900/30)880/82)1600/10)10/12)14/12)

912 < 80,380(130,355( 21,355(230,

0. 21 ( 0,0. 05( 0,

4400/264)1900/152)9700/264)530/ 10)

0. 59/ 12)0.33/ 12)

631 ( 54,2600/141)525( 80, 2200/ 81)257 ( 53,1800/141)490(370, 650/ 5)0. 53( 0, 16/ 12)0. 17 ( 0, 3. 2/ 12)

1410(140,11000/82) 1860(300,13000/264) 1480(300,7300/141)

- 11 -


33- 1

B

, U87063,

No.I2345

- 2. 5

- 4

- 8

-13

n-AH -1—2

2. 67

2. 64

2. 57

2.55

2.71

7. 3/4. 8

7. 5/5. 3

9. 2/8. 2

7.8/6.9

5.5/4.4

6. 14. 28. 7

1428

(EXC:Na, K, Ca, Mg)( 0. 30. 0. 21, 1. 9, 1. 5 )( 0. 51, 0. 33, 1. 8, 1. 3 )( 0. 39. 0. 50, 29 . 1 . 8 )( 0. 42, 1. 4 , 16 , 8. 9 )( 0. 70, 0. 23, 8. 8, 6. 8 )

64 (%)94

360190

59

No.12345

Eh,pH EC(25 < C)[wS/cm]

2.548

-137 .47 .77. 1

105142123

(Na, K. Ca. Mg, SCU-S, CD( 1 1 , 0. 70, 4. 1, 1.9, 0.84, - )( 14 , 0.64, 4. !, 2. 9, 0. 74. - )( 9. 5, 1. 1 . 6. 4. 2. 7, 1. 0 , 11 )( 1 1 , 2. 2 , 9. 2, 4. 7. 3. 3 , 15 )( 9.6, 0 .25 , 6 .8 . 4. 1, 3. 1 , 19 )

253616

(ICP-AES)(ICP-MS)

NaCaC 1

KMg, SO4-S

-in


33- 2

U87063,

N aM gKC aS r

KA

7E3

BackgroundTONo. 2 . 3 TONo. 4 5

6. 3X10°9. 5X10 '1. 2X102

9.0X10 1

8. 6X10°5. 2 X 1 0 '2. 0 X 1 0 2

8 . 5 X 1 0 '6. 1 X 1 0 2

9. 5 X 1 0 "8. I X 10'1. 8 X 1 0 2

9. 2 X 1 0 2

7. 8 X 1 0 2

MNo. 2 fflfttio. 3

8. 8 X 1 0 "2. 3 X 1 0 2

2. 4 X 1 0 2

3. 5 X 1 0 2

2. 8 X 1 0 2

MNo. 2

3 X 1 0 °0 X 1 0 2

8 X 1 0 2

3 X 1 0 2

3. 0X10 '

NMKCS

ag

ar

6.5.2.8.5.

8X9XOX8X9X

10°10'102

10l

102

6. 4X8. 5X1. 6X7. 2X6. 3X

10°10'102

102

102

M

cs

gar

5.8.5.

2X5X6X

1 O i

10'102

6. 7 X 1 0 '2. 2 X 1 0 2

2. 5 X 1 0 2

NMAKCCMCNCZBSI

cBPTU

ag1

arnoiunrr

sabh

7. OX1. IX5. 4X5. 5X

8. 5X2. 4X1. 2X2. IX2. 2X3. 9X5. OX9. 4X6. 8X4. OX

—

8. 8X4. 2X8. OX

4. 6X

10°102

105

102

10'102

104

103

102

102

103

10'102

101

104

103

102

103

6. IX3. 7X6. 3X1.2X1. 6X2. OX9. 6X3. 2X8. 5X7. 5X4. 6X1. 7X

1. 5x1.9X

1. 8x4. 2X3. 3X

—

4. 2X

10°102

105

103

103

102

105

10 : i

102

103

10 : i

102

103

102

102

103

10"

103

13


weeks/i!fg:l hour, j^fr#fl£/3000G/30min)

44- 1

JAERI-M 9 1 - 1 1 8 ,

B

A'J• / \ '

No.

23 ®M±m

7664

« g [ g / c m 3 ] pHtthO/KCl) CEC[meq/100g] (EXC:K, Na, Mg, Ca)2. 81 9. 6/7. 3 24. 8 ( 12 , 209 , 1. 6, 4. 0 )2. 57 8. 5/5. 5 16. 5 ( 3. 8, 26 , 4. 9, 4. 4 )2. 65 8. 2/5. 8 1. 8 ( 0. 8, 9. 6, 1. 9, 2. 8 )

41.430. 023. 8

(PH, Eh,

No.

23 VPW

PH Eh[mV]9. 3 ~ 9 . 4 91 —1017.0-7.5 168-1956.3-6.9 196-230

K+, Na+, Mg2+, Ca2t, CP, HCO3", S042")

(0.84, 8.6, 1.9, 2.0, 15.2, 6.2, 6.2)

Am(in)

Mine ra l c o m p o s i t i o n

QuartzStilbiteSmect i teChloritePlagioclaseK-feldsparAmphiboparClinopyroxeneOrthopyroxeneCalciteAmorphous

Sand stoneMinor-

Minor-

Major-

TraceMediumMinorMinor-

Tuff rockMedium-

Medium-

MajorTraceTrace---

Major

Sandy soiMajor--

TraceMajorTrace-----

- 1 4 -


hour, &fr#«/3000G/30min)

44- 2

JAERI-M 91-118,

B

A d s o r p t i o nSo i l p H ( I n i t i a l ) Eh[mV] Kdl Kd2

P u Sand stoneSand stoneTuff rockTuff rockSandy soilSandy soil

9.49.47.07. 56. 36. 9

(5)(9)(5)(9)(5)(9)

101101195185230211

36163017

9202200

3J_030024020015004800

Am SandstoneSand stoneTuff rockTuff rockSandy soilSandy soil

9.39. 37. 57.46.56.9

(5)(9)(5)(9)(5)(9)

9291

182168206196

200 75040 170

530 2300170 1000

9500 >420003700 >29000

Kdl ... M>b

Kd2 y

Co - (Ce+Cw) 200[ml]Kdl = X

Ce 0[g]

* <D

Co - (C.+Cw) 200[ml]Kd2 = x

C5 10[g]

CoCwCoC5

4 j4

- 15


:24 hours, il^li/6000rpm/30niin)

55-1

U

JAERI-M 93-113, 1993^5/3

g[m] flg[H!, Mm] (-2000, 1100, 500, 355, 355-) Vg]7. 7-8.7. 3-7.7. 4-7.6. 7-8.

0670

(((((

0.--8._

19,

1 ,

11 ,0. 86,-

34 ,-

34.4.

27.

6,5,

3!

25.3.

13

7,3,

28.91.

10017.

100

53

6

)))))

1. 23.4

11.41.46. 9

H l E h .

pH EhCmV] ^ > S I S [ p p m ] (Ca, Mg, Na, K, S 0 4 2 \ H C 0 : r , C l " ) D0[mg0/ l ] ECL/zS/cm]7.1 498 ( 5 6 , 17, 19, 8 .2 , 78, 144, 3 9 ) 1.19 520

=6. 8~7. 5

Adsorption

36C 145C a60C o63N i8 iS r

I34C si a E u" ' A m

0. 36

21020016

340430680

0. 66.3

110300

14570

3193

1. 52870

16058

2200420360

0.64. 1

490240

11530810

3100

0 . 8310

43001500

56450

24002000

LSCLSCGe(Li )LSCGe(Li )Ge(Li)Ge(Li)LSC

Co - C VKd = x

C(l-W) M

w :

- 16 -


hours, JS'L^H/6000rpm/30min)

55-2 JAERI-M 9 3 - 1 1 3 ,

B

i S W fell ft, MDI] (-2000, noo, 500,355,355-) it^®ft[m7 . 7 - 8 . 0 ( 0 . 1 9 , 11 , 3 4 . 6 , 2 5 . 7 , 2 8 . 5 ) 1 .27 . 3 - 7 . 6 ( - , 0 . 8 6 , 4 . 5 , 3 . 3 , 9 1 . 3 ) 3 . 47 . 4 - 7 . 7 ( - , - , - , - , 100 ) 1 1 . 46 . 7 - 8 . 0 ( 8 . 1 , 34 , 2 7 . 3 , 13 , 1 7 . 6 ) 1 .4

( - , - , - , - , i o o ) 6 . 9

ffltiP ffifcM)

Eh,

PH10

Eh [mV]498 ( 56,

(Ca, Mg, Na, K, S O 42 , H C O . r , C l ) DOCmgO/1]

17, 19 , 8. 2, 7 8 , 1 4 4 , 39 ) 1. 19 520

, ^Htt=200cc/10g

=6. 8~7. 5

4 5 C 1"Ca

"Co6:1 N i85 S r

134 C si a E u241 A m

Adsorption

0. 211

2208145340260220

0.015

446833

20001000190

0.425

3720057

200048002700

0.06.6

63016028

4001500580

LSCLSCGe (Li)LSCGe(Li)Ge(Li)Ge(Li)LSC

- 17 -


66-

Kfl-B

m

/£

%.

ft

ANo

12345

1

£ (1-4 weeks,

JAERI-Research

i j 7

H€

P - -I\ 0

Gravel:

Chemi

ifeNo

12345

SiO2

AhOT i O 2

Fe20CaOMgOFeONa2OK2Op 2 0 sMnOH20

6.6.6.7.8.

cal c

3

3

PH3-7.4-8.5-7.6-8.4-8.

Mm

\frf(/V

vW)

t^

Jf)

J?)

>2000

omposi

77.11.0.0.2.0.0.1.0.0.0.2.

952321935576908350070339

pH. Eh,

1405I5

(((((

. *

f)

uii

96-004

2. 672. 672. 762. 582. 68

iI 'L^ii /3000rpni/20min

, 1996^2^

/cm

% Sand:c-JI

tion (Weigh

00000

76.11.0.2.1.0.0.1.0.0.0.3.

|g[mg/. 12, 0. 10, 0. 20, 2. 17, 0. 3 , 5

Uffl)

309230038064585453060362

3) I

1it

m

)

t l l ^ f l J t W (Gravel , Sand, S i l t , Clay)(((((

2000-74

1] (Mg2

. 23

. 17

. 13

.34

. 0

l/m

1.423.

n

0.0,6. 5,0.0,0.5,0.0,

urn, i^T\

Loam51.21.

0.6.0.1.1.0.1.0.0.

13.

:m), Ca32,15,97,78,9 ,

171697835227818845150853

2+, NaH

0. 25,0. 20,0. 26,0 .93 ,0 9

87 .575. 58.5

4 8 . 599. 5

J i l t :2 9 7 ;

7.5,13. 5,30.5,35.0,

(' 74-2//im

Clay55.23.0.4.2.1.0.1.0.0.0.

11.

¥M', K+,' 2 .5

1. 18. 12.91 6

297757626073516153060825

SO

J^±

€J

•MM4 2 ~ , F

2. 7,10. 9,

1. 6,6.8,

16 ,

5.0 )4. 5 )

61. 5 )16. 0 )

). 5 )m, Clay: <2^m

(A)~74MmJilT(C)cD3@

' (MM)78. 20

8. 310. 362. 461. 950. 98

—2. 552. 70

—0. 072.04

/A(^it#B#ttJ^-r *>zk)ICOs-.Cr)

0. 60 )0. 57 )3. 63 )2. 65 )1. 0 )

- 18


(1-4 weeks, Ji4>5>ft/3000rpm/20min)

JAERI-Research 96-004,6 - 2

B

. 5, 0.1. Ox

Adsorption

under 74/zm (pH) over

700-1000W 400- 500) 2 0 - 30

Kd =

Co

cVM

V Co— ( 1)M C

& c ^ 7 m <D

90 (6. 8-7. 3)60 (7. 2-8. 0)20 (6. 6-7. 5)3 (7. 6-8. 1)1 (8. 4-8. 5)

50-6040-5015-20

•4 c

•4 c

- 1 9 -

J AERI-Data/Ccxle 2001 -005

:2 weeks, il'L^il/3000G/30inin)

mmm±m£Gi&miJAERI-M 88-038, 1 9 8 8 ^ 2 ^

B

No. fif:1 n-A 500RT 1 -1.52 W 500^ F 2. 6-33 WBL%M,{t%f> 500UAT 3 -3 . 2

105-250

Eh,

( P u i l ^ 10 6mol/ml)

pH ^ ^ i i g [ u i g / l 3 ( N a 2 S 0 4 , NaHC0s,NaCl,KCl,CaCh-6H,0, MgCh-6H20)6. 52 ( 7.54, 19. 69, 8.56, 1. 52, 12.02, 17. 56 )

3CCGas Flow Counter (Aloka)

Adsorption

D —A 2400 5.0 4600 5.13600 6. 3 3700 6. 2

970 5.8 1900 5.739000 12.3 61000 12.3

Co-Cs-Cv MKd =

C, V

CoCsCv

concentration in initial solutionconcentration in solution (after 3 weeks)concentration on the vessel wall (after 3 weeks)

- 20 -


:24 hours, 4)

KURRI-TR—15K

2 + tUg2

1977^2^, 10, 79-86 & 203-210 (1975)

B

m No.

1 Amberlite IR-120B2 Green sand3 KUR sand

MCEC[meq/g]4.40. 150.031

:+-Mg2+)1. 92. 01. 7

feS [mm]1. 19-0. 3071. 19-0. 5900. 250-0. 125

1. 332.482.47

. Eh.

ftPH

Original water 5. 5~6. 5

) ^ S 20~25°C,

(Ca2 + , Mg2+)

T

0. O l j E i C i / m l C

TtBcw

W

Ca

4. 9X8. IX2. IX1. IX1. 6X4. 2X5. 2X8. 2X2. IX1. 2X1 C N/*

1, 0 A3. 8X5. 2X

gCLm

2 +

10" 2

10~2

10" 2

10" 2

10" 2

10" 3

10" 3

10" 3

10~3

10" 3

10" 3

10 " 4

10" 4

;meq/m

Mg

5. OX2. OX7. 9X1. OX4. IX1. 6X5. IX1. 9X8. OX1. IX4. 2X1. 7X5. 3X

. Adsorpt

SO /^

13

2 +•

i o - 2

10" 2

10" 2

10" 2

10" 3

1 0 2

10" 3

10" 3

10 3

i o - 3

10" 4

10" 3

10 "4

0

No. 1

24202971577095

110120300250340430

on

Kd

No. 2

272428404256574864

11092

110150

No. 3

4.4.6.

14111418163058487394

520

wCa

5. 2X8. 3X1. 6X1. OX1. 9X4. 2X5. IX8. 5X1. 6X1. IX1. 8X4. 5X5. IX

2 +

10"2

10~2

10"2

10 "2

10"2

10"3

1 0 3

10"3

10"3

10 3

10"3

10"4

10~4

8 S g

[meq/ml]

Mg

5. OX1. 8X8. 8X1.4X4. 8X1. 9X5. 3X1. 6X9. 2X1. 4X5. OX1. 9X5. OX

2 +

1 0 2

lO" 2

10" 2

10" 2

10" 3

1 0 2

10" 3

10" 3

1 0 3

10" 3

1 0 ' 4

10" 3

10" 4

r

No. 1

3936446568759879

120180160170250

Kd

No. 2

27242831283733334552556272

No. 3

5.5.6.

10101417131728283740

716

=50 (150ml/3g)

- 21 -


to:24 hours, >fr#Ri/3000rpin/20min)

99- 1 ¥£B, Vol.33, No. 4 (1991)

A

ABCDE

from Sea [in]170380220110430

( 2. 4-3. 2( 2. 8~2. 9( 2. 5~3. 1( 2. 0-2. 7(2.3-2.4

3. 5 )14. 2 )5. 3 )1. 9 )2.2)

(3. 9~4. 7( 4. 2~4. 4(3. 8~4. 8(4. 0~4. 6(3.5-3.7

7. 3 )19. 2 )17. 3 )16. 2 )14.1)

Eh,

pH ECUS/cm]A-upperB-upperC-upperD-upperE-upper

7.87.28.37.87.2

61052016001100500

Mg2+, Ca2+, K+, Na+, Cl(9. 6E-4, 1. 1E-3, 2. 6E-4, 1. 8E-3, 1. 6E-3, 4. 3E-3, 4. 9E-4)(6. 8E-4. 1. 4E-3. 2. 1E-4, 8. 3E-4. 1. 1E-3. 2. 7E-3. 8. 1E-4)(1. OE-3, 6. 3E-4, 6. 5E-4. 1. 2E-2, 6. 3E-3. 9. 9E-3. 4. 2E-4)(9. 4E-4. 1. 3E-3. 2. OE-4. 6. OE-3. 6. 9E-3, 3. 1E-3. 4. 5E-4)(5. 1E-4, 1. 4E-3, 1. 6E-4, 1. 1E-3, 1. 4E-3, 2. 4E-3. 7. 2E-4)

pH EA-lower 7.6 4000C-lower 8.1 1500D-lower 7.5 1600

Mg2+, Ca2+, K+, Na+, Cr, HCOs", S042")(5. 0E-3, 2. 2E-3, 1. 2E-3, 2. 4E-2, 3. 4E-2, 6. 0E-3. 1. 2E-3)(7. 7E-4. 2. 9E-4. 6. 6E-4. 1. 3E-2. 6. 8E-3. 1. 1E-2. 2. 5E-4)(1. 6E-2, 8. 8E-3, 1. 8E-3, 1. 2E-1, 1. 6E-1, 4. OE-3, 8. 2E-3)

370Bq/ml

Ge (L i) ^

- 22 -

JAERI-Data/Code 2001 -005

(Mto:24 hours, jI'L^i£/3000rpm/20min)

99- 2 ^ Vol.33, No. 4 (1991)

... Adsorption

'C o

upper lower

i 5S r

upper lower

C s

upper lower up lo

= 20(200m1/10g)

ABCDE

823006554320

66570440140310

46

17041

562206028

210

2. 23. 02. 71. 78.7

1. 8

2. 20. 8

110420180380540

17027015088

260

46

5222

9.69.89.69.39. 1

8.68.48.58. 1

8. 5

8.68. 2

- 23


:3 days, Decantation)

1 0

A

B, Vol.30, No. 10 (1988)

C E C [ m e q / 1 0 0 g ] ( E X C : N a + , K + , C a 2 + , M g 2 + , T o t a l )0 . 7 « 0 . 01. 0.02, 0.28, 0.07, 0 . 3 8 )0.7 ( 0 . 0 5 , 0.02, 0.30, 0.07, 0 . 4 4 )0.7 ( 0 . 0 4 , 0.02, 0.38, 0.10, 0 . 5 4 )1.0 « 0 . 01. 0.04, 0.44, 0.12, 0 . 6 1 )1.0 ( 0 . 1 6 , 0.07, 0.68, 0.15, 1 . 0 6 )1.2 ( 0 . 1 4 , 0.07, 0.68, 0.17, 1 . 0 6 )1.6 ( 0 . 1 7 , 0.15, 0.89, 0.18, 1 . 3 9 )9.0 ( 0 . 1 8 , 0.24, 5.70, 0.76, 6 . 8 8 )

16.6 ( 0 . 4 0 , 0.54, 8.63, 1 . 4 6 , 1 1 . 0 3 )

No.123456789

879(710-1000)600(420-710)388(350-420)308(250-350)220(177-250)164(149-177)1 2 3 ( 7 4 - 1 4 9 )6 1 ( 3 7 - 74)29 ( - 37)

0.00130.00190.00300.00370.00520.00700.00940.01890.0398

Eh.6" C o .mm, k*a.

S r . o

.. Adsorption

No. ' C o S r C s

123456789

5. 16. 28.713172331240410

6.6.7.7.9.1222240420

0 (lOOml/lOg)

24254

10121419242729180240

- 2 4 -


i - i

A

m

%.

ft

A*>J

ABCDEFGHIJKLMN0PQ

jt-i

IT.CaMgNaK+

TC

fill-!

±mSandSi l t -ClaySi l t -ClayGravel-SandSi l t -ClaySil t -SandGravelS i l t -ClaySi l t -ClaySi l t -ClayFine SandS i l tSandGravelFine SandFine SandSi l t -Clay

"zK#'ft(pH. Eh

i + 1.00-+ 0.53

0.900. 03

(2. 46)HCO3" 1.04ClF~NOCOSOTATH

0. 800. 01

r 0.03s

2 - 0, 2 " 0 .60

(2. 48)1.53

M-A 1. 04P-A 0

mm

®m2.1.2.2.2.2.2.2.2.2.2.2.2.2.2.2.2.

i

Vol. IS

- g / c m 3 ]

"6568465117525563261454284995496146

J, pH=4. 5~i

TFeTZnTMnTPb

mix. LPPI0. 10.900

pH(15t:) 7.

, No

0.—0.0.0.0.0.0.0.0.0.0.—0.0.0.0.

. ssI. 2 ,m l1J

1

. 8

[mn51

20264334381224242126

45222113

(1976)

l] CEC[/ieq/g]11.3

241. 755.669.5

167.947. 828.9

117.9140. 5246.0

60. 3149.024. 327. 1

122.838. 6

200. 1

Ca+MgCmeq/l] = 0 . 4 - 6 .

1

9 0 S r S r ( N 0 3 ) 23 7 C s CsCl" C o C0CI2r > 4 M n MnCh6 5 Z n ZnCl2S 9 F e FeCisO m A g AgNOs" M o (NH4)2Mo049 0 Y

1

— :Ml1.6.2.3.2.1.2.2.3.

£L LlllOl/ 15E-10~1E-10-4E-11-5E-14~5E-09-6E-09~2E-12~2E-08-0E-14-

J

5.1.9.4.3.2.4.2.4.

3E-104E-097E-116E-147E-093E-098E-127E-084E-14

- 25


Jem

11-2

A

±m

12BCDEFGHIJKLMN0PQ* Bfi

A-y-f/J

"Sr

500304065700454027010500106025151502570

MntdO

tt = 5/3~

/ J T" X? &C< > ' 0

] ... Adsorpt

m C s (i

> ITIFIS<_ VJ|H

1. 18,

ion

"C o

100 15028002500300050001200100013001000700020080001500300300015002000

-50/1

150250400350250200400201501010020018040010080

No. 8 (1976)

5 4 M n

902100250500010000

3050070070—5025014*800200070100

I

85 Z n

7510004000800018001200500800200

350020

2200—

19002000200200

1 1 0 m A p.

8100300100020035010170200—20100—3004006080

59 F e

1500100500120200560250—5

1000—40250515

"Mo A

140406

1606051340020020270—1.381.840

- 26 -

JAERI-Dala/Code 2001-005

1 11 -3

A

$!l

5£

^k

A*'JSoNo.

123456789

1011121314151617

miInNo.

123456789

101121314151617

mmB4^i

1-bed

±mM SandM SandM SandM SandM SandM SandM SandA SandA SandA SandA SandA SandA SandA SandA SandA SandA Sand

Height [mm]151618

13016752459.0

11596

15470201446.042.052. 5

pH. Eh. &#-r' l u e n t s o l u t i o n

mm9 0 S r6 0 C o

" 7 C s5 6 Mn6 5 Z n5 9 F e

1 O m A g9 0 S r9 0 S r9 0 S r9 0 S r6 0 C o

1 3 7 C s99 Mo9 ( 1 S r9 0 S r9 0 Sr

? Kd is not

—

1. 932.472. 331. 73

——

1.581. 501.341.681. 631.611. 361. 161. 161. 16

d e f i n e d .

i

Vol. \i

$$.(&¥

Weight22. 410.010.096. 310.050.015.050.075.057.084. 650.020. 080.023.422. 529. 2

} PH—

8. 107. 757. 727. 707.409. 507. 18

—6. 927. 307. 067. 206. 677. 067. 067. 06

, No. 8 (1976)

[g] P o r o s i t y M Sat37. 136. 343.444. 136. 332. 136. 333. 136.040. 745. 344. 932. 844. 547.444. 542. 5

A c t i v i t y [ t f C i / m l ]2. 9 X 1 0 " '3 . 0 X 1 0 " 2

6. 5 X 1 0 " '5. 3 X 1 0 " 3

1. 2 X 1 0 " 2

7. 9 X 1 0 " 4

4. 0 X 1 0 " 4

2. 7 X 1 0 " '2 . 4 X 1 0 " '3. 7 X 1 0 " '1. 2 X 1 0 " 3

2. 9 X 1 0 " '2. 5 X 1 0 " '4. 9 X 1 0 " '2 . 0 X 1 0 " 2

2. 0X10 2

2. 0 X 1 0 " 2

.degree100100100100100100100100.0100100100100100100

65. 371. 879.4

'%]

Dl/J

Flow rate[ml/cm2.

11.11.

7.12.

I.2.1.0.0.2.2.1.2.0.0.0.

9332521591097161563204886126472

!§M. &&. S*t

Adsorption

7min] Kd6.

18.409

5.148

??

4.13.6.3.

25.695

0.7.6.6.

78

0

96704

37384

- 27 -


:100rpmX60minutes, j t i i /O. i 11 ipore)

1 212-1Kfl-A

, 27, 123 —134 (1992)

AU

0.0.

I [mm]265265

2.2.

g/cnr6363

'] pH(H4.5.

2O/KCO6/4.03/4.6

CEC[mmol/100g]0. 821.00

o.0.

. Eh,

pH ^5 . 2 + 0 . 2 23

^>jSS[mmol/l]Zn(Cl", NOs", " , SO4+, K, Na, Mg, Ca, S i , F e )

0. 02—0. 15 (1. 673, 0. 197, 0. 231, 0. 514, 0. 833, 0. 833. 1. 019. 0. 243, 0. 455, 0. 409, 0. 129)Zn(0. 02, 0.08, 0. 15 [mmol/l])

0.

Adsorption

pH Kd(Zn)

H TO 4. 2~4. 4 1. 355. 1 — 5. 3 2.02

=2. 5 (50ml/20g)

- 28 -


^ t : 6 0 hours, j t i i /O . 45/im;Mi 11 ipore)

(I1 212-2

27, 123-134 (1992)

A*'J

H iCa?

&&[mm] ^ [ g / c n i 3 ] pH(H20/KCl) CEC[mmo 1/1 OOg]0. 265 2. 63 4. 6/4.0 0. 820. 265 2. 63 5. 3/4. 6 1. 00

. Eh.

Adsorption

fig PH

cr NO 3 SO42~ Si H

-f:t>zig[ininol/l]«U + K

Kd(Zn)Na Mg Ca Fe Zn

H 3. 53.

2222

33

3346

46

Ca 3.3.

22

22

33

33

46

46

45

55

.234.4.

4.

3.

3.3.

3.

5.

5.

4.

5.4.

4.

4.

4.

2602

01

94

9584

852631

95

0089

89

8684

1.3452.2.

2.

2.

2.

2.

2.2.

2.0

2.

2.

2.

2.2.

384349

320

353399

390

374354

361

388

355

332

395

305404

0.3100.3220. 313

0. 312

0. 3300. 333

0. 334

0.322

0.316

0.326

0. 273

0.326

0. 333

0. 323

0.331

0. 325

0.00

0

0

00

0

0

0

0

0

0

0

0

0

158 0. 148 0. 567 0. 385 0. 059 0. 707 0. 735 1

. 163 0. 152 0. 588 0. 386 0. 055 0. 714 0. 747

.164 0. 123 0. 580 0. 456 0. 095 0. 707 0. 721

. 157 0. 124 0. 551 0. 460 0. 098 0. 735 0. 719

168 0. 107 0.566 0.524 0. 115 0.707 0. 746

•. 168 0. 116 0.580 0.519 0. 112 0.707 0. 745

'. 161 0. 098 0. 567 0. 668 0. 145 0. 714 0. 764'. 165 0.093 0.584 0.677 0. 141 0.714 0. 754

'. 157 0. 181 0. 552 0. 388 0. 005 0. 664 0. 709

'. 160 0. 183 0. 567 0. 377 0. 005 0. 664 0. 701

'. 162 0. 167 0. 559 0. 453 0. 011 0. 664 0. 698

155 0. 168 0. 558 0. 459 0. 010 0. 678 0. 714

'. 162 0. 160 0. 559 0. 520 0. 013 0. 664 0. 725

164 0. 157 0.562 0.507 0.013 0.664 0. 722

i. 160 0. 132 0. 553 0. 725 0. 014 0. 671 0. 732

167 0. 143 0. 572 0. 724 0. 014 0. 671 0. 740

.378 0. 205 0.402 0. 119 (

1.424 0.209 0.403 0. 118

1. 387 0. 226 0. 388 0. 1161. 345 0. 226 0. 387 0. 117

1. 362 0. 209 0. 369 0. 117

.351 0.220 0.371 0. 119

.405 0.228 0. 354 0. 129

. 395 0. 237 0. 369 0. 133

. 395 0. 168 0.585 0. 117

. 340 0. 170 0.587 0. 114

. 346 0. 199 0.606 0. 115

.346 0. 191 0.605 0. 116

.379 0. 185 0. 593 0. 120

.404 0. 198 0.607 0. 120

.340 0.275 0.689 0. 153

. 394 0. 239 0. 646 0. 145

.0700.

0.0.

0.0.

0.

0.

0.

0.

0.

0.

0.

0.

0.0.

075

070072

062

065

069

069

056072

050

054

054

054

066066

1. (0.

1.1.

1.

1.

1.1.

1.

0.2.2.

2.1

1.

1.

32783727

68

5015

15

93

93

91

46

33

31

3535

= 2.5

- 2 9 -

JAERl-Data/Code 2001-005

( N $ E J g t - 9 : 1 0 0 r p r a X 6 0 n i i n i i t e s , S i f i / 0 . 45/zm;Mi 11 i p o r e )

1 212-3

27, 123 — 134 (1992)

0. 2650. 265

3 ] pH(H20/KCl) CEC[mmol/lOOg]2. 63 4. 6 /4 . 0 0. 822. 63 5. 3 /4 . 6 I. 00

pH

... Adsorption

Cai ion(H + .NH4 + .K.Na,Mg,Ca, Zn)

Kd(Zn)

AnionCCl . Br . NOs , PO4 3 . S 0 42 )

H 4.444.424.31

4. 31

4. 26•4. 24

4. 134. 11

3.91

2.93

Ca 5. 09

5. 13

5.09

5. 12

5.05

5. 02

5.04

5. 134.64

4.6

0. 301 (0.0.

0.

2.1.

4.

4.

8.

8.

0.

0.

0.

0.

2.2.

4.

4.

9.

8.

305753

726

004

999

515507

543

783

375

357

775700

155150

782

814

136

900

0.036 0. 018 0. 017 0.

( 0.038 0. 018 0. 019 0.

( 0. 049 0. 083 0. 082 0.

( 0. 049 0. 077 0. 081 0.

( 0. 055 0. 286 0. 314 0.

( 0.058 0. 280 0.315 0.

( 0.074 0. 714 0.801 1.

( 0.078 0. 714 0.800 1.

( 0. 123 1.310 1.535 2.

( 0. 117 1.488 1.550 2.

( 0.008 0.000 0.016 0

( 0. 007 0.006 0.015 0,

( 0.008 0.048 0.064 0

( 0.008 0.048 0.062 0.

( 0.009 0. 250 0.295 0.

( 0. 010 0. 256 0. 297 0.

( 0. 009 0. 774 0. 746 1

( 0.007 0.774 0.767 1

( 0.023 1.488 1.487 2

( 0. 025 1. 369 1. 487 2.

108 0. 013 0. 027 0. 021 )

107 0. 016 0. 030 0. 016

'. 227 0. 045 0. 070 0. 028

'. 208 0. 044 0. 069 0. 029

526 0. 117 0. 192 0.047

529 0. 113 0. 195 0.047

131 0. 248 0.444 0.067

117 0. 252 0.443 0.064

030 0. 529 0. 878 0. 076

.044 0. 531 0.892 0.076

124 0.011 0.091 0.012

105 0.011 0.089 0.012

. 2 0 8 0.029 0. 158 0.024

'. 175 0. 023 0. 139 0.030

•. 529 0. 086 0. 361 0. 034

•. 528 0. 085 0. 356 0. 033

133 0. 214 0. 659 0. 053

.122 0. 218 0.663 0.054

061 0.493 1. 193 0.067

061 0. 482 1. 149 0. 067

0. 383 () 0.) 0.

) 0.

) 2.

) 2.

) 4.

) 4.

) 9.

) 1C

) 0.

) 0.

) 0.

) 0.

) 2.) 2.

) 4.

) 4.

) 9.

) 9.

334

728701

106

078543

992

3521.50

359

366

838

721

045037

674

699

637

829

0. 194 0( 0.

( 0.( 0.

( 0.

( 0.

( 1.

( 2.

( 3.( 4.

( 0.

( 0.

( 0.( 0.

( 0.

( 0.

( 1.

( 1.( 3.

( 3.

140294

279

908

857788

082

564500

142

136

353

255

801

797

802

819

651

664

. 1430.

0.

0.0.

0.0.

0.

0.0.

0.

0.

0.

0.

0.

0.

0.

0.

0.

0.

150143

143146

148137

148

137137

160

156151

158

142

139137

136

129

141

0.016 00.

0.0.

0.

0.0.

0.

0.0.

0.

0.0.

0.

0.

0.

0.

0.

0.

0.

015039

034097

100209

232

415

440

020

018037

031

095

093

214

212

372

454

.0000.0.

0.

0.

0.

0.0.

0.0.

0.

0.

0.

0.

0.

0.

0.

0.

0.

0.

000000

000

052

054

158155

375

400000

000

onon063

066

203

195

450

476

0. 000 )0.0.

0.0.

0.

0.

0.1.

1.

0.

0.

0.

0.

0.

0.

0.

0.1.

1.

000 )069 )

066 )217 )

222 )

530 )591 )

143 )

194 )

000 )

013 )

069 )

062 )

224 )

220 )

524 )

539 )

156 )

162 )

7.5210. 575. 22

4.83

2.01

2.00

0. 97

1. 10

0. 48

0.4915. 28

15. 54

6. 56

4. 71

3. 77

4.06

1. 90

1. 76

0. 88

0. 89

=i. 5

- 3 0 -


t(l1 212-4

27, 123-134 (1992)

A

. -f:

H !!#>f£?$ [mm]0. 2650. 265

2. 632. 63

pH(H20/KCl) CEC[mmol/100g]4. 6/4. 0 0. 825. 3/4. 6 1. 00

I . Eh,

. . . Adsorption

Soil-bed Feed so lu t ion

Porors i ty "azKiiCcmVcn^]

H M ( l )H M(2)CaM(l)Ca?S(2)

0.3990.4180.3990.399

0.3360.3510.3690. 349

:[mmol/l] pH 8ft Ji*

0. 086 5. 10.147 5.50. 089 5. 20.145 5.4

Kd(Zn)

3.934. 163. 894. 20

1. 96(1.69)1. 58(1.40)2. 31(2.08)2. 06(1.83)

- 3 1 -


1

A

m

3

A*

No.12

No123

'IE

t

ij

RADIOISOTOPES

: C l a y ( l W + S i l t ( 9 W

T

i1

•

111122223333

*zK^tt(pH. Eh,

pH EC&^$§7K 8. 0v*)Wi7K 9. 7V W I T K 9. 7

fo. ttHJtOnl/

1000200

1000200200

20200

20200

20200

20

. 41

=r)3)

24 hours,

, 350-356

e ) 2. 802. 74 0.2. 69 0.

+Sand(90«

122211

RU

tm

* > * * . m

S/cm](( 1

Adsorpt ion

g) I

7977

88822813552424175245

MM/0. 45//m;membrane)

us , Pniisw.

(1992)

1 ^-^[111111] p H ( H z O / K C l )* 7. 4/5. 1

074-0. 42 9. 4/8. 1074-0. 42 9. 9/8. 8

a>»jK[mg/l](Ca,Mg,6. 3, 2. 4 , 12, 1. 1 ,5 , 0.01, 22, 0.35,

CEC[meq/100g]18 ( 7.9,

7. 2 ( 19 ,5. 0 ( 7. 4,

Na, K, Cl, HCOs17 , 32,

(EXC:3. 5 ,0 140. 18,

, S04,2. 1,

2. 3, 20, 64 ,

0234. 8Bq/mlK.£/0. 025-10mg/l Clf

fi£[/ig/g] K d ( S r

32003200

360033001300

610260011001100

78025002100

)

rmi

ACT:

14

Ca,2.10.

NO0.ND

>i

?$.

Mg0 ,856,

3 ,

9,

Na1.00.

Sr)0.0.

7Ktt

K)22015

025021

m

)))

))

- 3 2 -


(Jfc#:90 minutes, il>L>ft-lt/3000rpin/10inin)

1 4

Kfl-A

RADIOISOTOPES. 29 , 373-376 (1980)

AU

C E C [ m e q / 1 0 0 g ] ffifiXR] (S iO2 ,T iO2 , AI2O3, FeO, Fc2O3,MnO, MgO, CaO, Xa^O. K2O, H2O)3 5 0 0 . 6 0 ( 6 3 . 0 0 . 0 . 8 7 , 8 . 5 0 , 3 . 3 0 , 3 . 5 3 , 0 . 1 3 , 2 . 4 5 , 4 . 1 3 , 6 . 2 1 , 5 . 4 2 , 2 . 0 4 )

, Eh,

8 5 S r 5. 1 X 10 4

I 3 7 C s 1. 2 X 1 O - Z

5. 1 X 10 7

1. 2 X 1 0 " s

2 . 4 X 1 0 487

~ 9 ~ 1 0 " 1 21 0 ~ 9 ~ 1 0

, TDC-5)

PH

2

4

6

1012

... Adsorpt

Kd(8SSr)

1. 5

40

60

100

60

ion

Kd(I37Cs)

200

350

500

450

300

'M.M.> PH = 5. 0. 10~9 'K d ( 8 5 S r ) = ^ j 3 0 , K(

I 0 " 1 2 [ m o l / 1 ] T

= 20 (200ml/10g)

- 33 -


1 5

Kenichi AKIBA, Hiroyuki HASHIMOTO and Takuji KANNODistribution Coefficient of Cesium and Cation Exchange Capacity ofMinerals and RocksJ . N u c l . S c i . T e c h n o l . , 2 6 [ 1 2 ] , 1 1 3 0 - 1 1 3 5 ( 1 9 8 9 )

A

A'J, 32~6Omesh(5OO~25O/im)HtSVi

Eh,

Na, K^^^-^-tl-^'tlTppm, lppm0

level0

25"C> Polypropylene vial

Well-type Nal(Tl) Scintillation Counter

... Adsorption

C E C [ m e q / g ] K d ( I 3 7 C s )

Itado tuffOhya tuffSandstoneShaleAugi te andesi tePlagio rhyo l i t e01ivine basal tInada grani teRokko grani teLimestone

Bio t i t eChlori teHornblendeGrossularF o r s t e r i t eK-feldsparAlbiteQuartz

1.39. 7X10" 1

2.4X10 2

1. 9X10" 2

1. 9X10 2

1. 2X10"2

7. 5X10 3

5. 4X10" 3

3. 5X10-"3. 3X10~4

1. 2X10"2

9. 3X10" 3

3. 3X10 3

1. 1X10 3

6. 7X10"4

3. 4X10" 4

3. 2X10~4

9. 8X10" 5

110000100000

500020006000500

580090026080

22001800630420460

308931

- 34 -


1 6

Kfl-A

Kenichi AKIBA and Hiroyuki HASHIMOTODistribution Coefficient of Strontium on Variety of Minerals and RocksJ.Nucl. Sci.Technol., 27[3], 275-279 (1990)

Eh.

level

Polypropylene vialN a K T l ) Scintillation Counter

TTBCWSX Lml/gJ . .

I tado tuffOhya tuffPropyli teSandstoneShaleAugite andes i tePlagio r h y o l i t e01ivine basa l tVi t r i e massiveInada g r an i t eRokko g ran i t eLimestoneMuscoviteChlor i t eHedenbergiteHornblendeGrossularMicroclineF o r s t e r i t eK-feldsparAlbi teEpidoteQuartz

. AdsorptionCEC [meq/g]

1. 39. 7 X 1 0 " '3 . 4 X 1 0 " 2

2. 4 X 1 0 " 2

1. 9 X 1 0 " 2

1. 9 X 1 0 " 2

1. 2 X 1 0 " 2

7. 5X10 3

tuff 5. 7 X 1 0 " 3

5. 4 X 1 0 " 3

3. 5 X 1 0 " 3

3. 3 X 1 0 " 4

2 . 0 X 1 0 " 2

9. 3 X 1 0 " 3

3. 6X10 :i

3. 3 X 1 0 " 3

1. 1 X 10":1

7. 0 X 1 0 " 4

6. 7X 10 4

3 .4X10 '3. 2 X 1 0 " 4

2. 2 X 1 0 " 4

9. 8 X 1 0 " s

K d ( 8 5 S r )

550017000

150780

95440

39380

508222

1. 32000

140402071

1500. 92

1430

3.023

- 35 -


scm1 717- 1

A

ffl

/£

$k

It

HiroshiStat is tCoefficEnviron.

A*U7#©#JHIft;

No.(Upland) 1

23456789

101112131415161718

(Paddy) 123456789

101112131415161718

• (ftLfflfch? :150/minX7days, j i 'h f r t

Yasuda and Shigeo Uchidacal ApproachentSci. Technol.,

t CEC[miol/lOOg]

11.410.011.4

9. 313. 914.425.421. 611. 916.614.220. 8

1.41.4

10.46.0

14.423.910.610. 3

7. 316. 18.48.4

14.08.0

17. 815. 339.014.012. 233. 59.0

11.016.028.6

for the Estimation of

27, 2462-2465 (1993)

Ex-K[mmol/lOOg]

0.520. 330. 870.661. 330. 700. 390. 340. 850. 302.000. 820.070.071. 130.401. 750. 260. 320. 370. 260.410. 570. 540.430. 250. 290.461. 830. 730. 630. 330. 290. 510. 293. 27

Ex-Ca[mmol/lOOg]

2. 782.513.914. 32

11. 565. 747. 518. 632. 601. 213. 604. 710. 330. 362.961.413. 104. 872.482.462. 356. 673. 253. 256. 212. 645. 014. 19

19.445. 782. 507.032. 103. 144. 625. 14

s t r o n t i u m D i s

S#*. <*>£

t r i b u t i o n

t o t a l - A l t o t a l - C[mmol/lOOg]

334.3334.0255. 0266.9315. 8385. 5407. 7364.0304. 7426. 2356. 9285.0240. 5279.5283. 7278.0441. 8316. 2329.9295.4248.3349.9321.0316. 5333. 2300. 2372. 5348.4286.9322. 5319. 5364. 7293.4298.0285.4344.0

[g/lOOg]0. 730. 671. 681. 762. 501. 126.061. 911.034. 312. 544.460.070.071. 070. 901. 269. 660. 940. 741.452.451. 581.443. 010.484. 892.052.041. 721. 53

10. 212. 401. 462. 242. 00

- 36 -


(M£g£-5:150/minX7days,

1 717- 2

Hiroshi Yasuda and Shigeo UchidaStatistical Approach for the Estimation of Strontium DistributionCoefficientEnviron. Sci.Technol., 27, 2462-2465 (1993)

A

Eh,pH EC [mS/cm]4. 5 0. 0657. 2 0. 175

!<*>»{£[mmol/1] (Na+, N H 4 \ K+, Mg2f, Ca 2 +)

( 0. 327, 0. 096, 0. 013, 0. 041, 0. 044 )( 0. 810, 0. 006, 0. 076, 0. 271, 0. 640 )

50ml-Poleethylene bottle, 23°C150 reciprocation per minuteCentrifugat ion 4000rpm, Filtration 0. 45 /zm; membraneGe-detector(Ortec GEM-30185)+multichannel analyzer (Seiko EG&G 7800)

... Adsorption Kd(8r'Sr)=50~500o 3Jt=10 (30ml/3g)

fSODI

\ i r-O.1t 1-0.55

4

• J» ' * j

iO 30 «O 0etc

3 t V i 10 IS it 0 100 20EI 300 400 SOOK E«oh«rtgB«6l« C* Toll I iluminuir

600rh-O.CH

O0

< R«lnw«lef

o PuMyttf

* River waler

2 4 « « 10Tout car Bon

6 g 7 « 0 0.5 ! 1.4 2

p*t in *vp»fh»i»ni Ki ln BLipsrrtAiAn:

Fl«vr» 1. n (toWMhxn « , »ntf »0* or sotuSon proparUet.

- 37 -


:\ week, it<L^$t/3000rpm)

scm1 8

Takashi NISHI. Kenji NOSHITA, Masami MATSUDA and Makoto KIKUCHIEffects of Cellulosic Materials on Distribution Coefficients of 6 OCoand 2A 'Am in CementJ.Nucl. Sci.Technol., 31 [2], 169-170 (1994)

'Cellulosic materials' 'Mixing water'0 % 40 %

'KC-Floc' 4.2% 35.9%'Solka-Floc' 4.2% 35.9%'Tissue paper' 4. 2% 35. 9%

No. 'Slag-Cement'1 60 %2 59. 9%3 59. 9%4 59.9%

crushedunder 42mesh

Slag-Cement = Portland Cement(3)/Brust Furnace Slag(7)

H. E h ,

3. 7X!0 5Bq/?( 6 OCo or 'Am)

Well-type pure Ge-detector

No. Co

... Adsorption

IAm

1 20000 2500002 50000 2500003 50000 1200004 2500 7000

??ml/5g

- 38 -

JAERI-Duta/Code 2001-005

-5 : 1 0 0 r p m X 1 6 8 h o u r s , . . . 96, 216 h o u r s , i i ' L

1 91 9 - 1

H i r o s h i YASUDAE f f e c t i v e n e s s o f E l e c t r i c C o n d u c t i v i t y f o r E s t i m a t i n g D i s t r i b u t i o nC o e f f i c i e n t s o f S t r o n t i u m a n d C e s i u mJ . N u c l . S c i . T e c h n o l . , 3 3 [ 2 ] , 1 6 6 - 1 7 0 ( 1 9 9 6 )

A

A(Upland field soi" a / k ^ pH ^ S f i g ( 3 1 $ ) , Uniformity) CEC 7 C ^ J j J t 5 H m m o l / g ][ m l / g ] [ g / c m 3 ] [mm,-] [mmol / lOOg] Ex-K Ex-Ca t o t a l - A l t o t a l - C

0 . 0 8 2 5 . 3 2 . 0 6 0 . 0 1 4 , 18 1 6 . 6 0 . 0 0 3 0 . 0 1 2 4 . 3 3 . 6

diameter. Uniformi \y\t^$)$i\Zit't •560percenti Ie diameter ©it.

. Eh,pH EC[mS/cm] ^ > i g ^ [ m m o l / l ] (Na+, NH4

4, K+, Mg2+, Ca 2 + )4 . 5 0 .065 ( 0 . 3 2 7 , 0 .096, 0 .013 , 0 . 0 4 1 , 0 . 0 4 4 )4. 7 2. 4 ( 0. 07 , 1. 7 , 7. 8 , 1. 9 , 3. 6 )

I P ^ N K ( S t a n d a r d n u t r i e n t s o l u t i o n )

50ml-Polyethylene bottle$&M 0. 45Aim;membrane filterGe-detector (Ortec GEM-30185)+mult ichannel analyzer (Seiko EG&G 7800)

Run-1•SlK

Run-296 or 216 hours : 3*C, 13°C, 23°C

Run-3

(4. 2, 3. 3, 2. 7, 2. 1, 1. 7) K168 hours : lot:

, 1 /5,( p H = 4 . 5-4. 7)

168 h o u r s : 23T:

-39


1 919- 2

A

A

HiEf

roshi YASUDAfect iveness o

Coeff ic ients ofJ.

• ECtC

Nucl. Sc

[ml/g]Z°C, 13

Kd(Kd(

offinKd(Kd(

:100rpmX168 hours,

E l e c t r i c Conduct iv

. . . 96, 216 hours , £

t y f o r E s t i m a t i n gStrontium and Cesium

i . T e c h n o l . , 33 [2 ] , 166-170

.. A d s o r p t i o n°Q^ 23°

8 ; s r1 3 7 C s

(Run-3)8 5 S j .

1 3 ' C s

5si to*

10"

. .

•

10-

* 1 0 -

i

10'

C ©3M£, pH 3. 5~5) 8 ~ 800) 65 ~ 4500

: * © 0 {go

) = 17XEC"1 3

) = 220XEC"1 °

t v J -»

• D »

4 PI

i si

41 w

« 10 M » <Twnpmoira |*C]

Fi T 1 f*kK» of !b* «JO«itwm Mid

"Sr

1d

*•

° t • ' "

J M>1 3 4,0 *-5 $-D t . i

£up«m«tant pH

Pig. 3 Pwit «f liw stFOiUturo &nd «

*•* • * ;

c

... }& * •

•

EC { m ( CnT1*]

( 1 9 9 6 )

5 (D^k&i: (Run-

D i s t r i b u t ion

1,2)

?&HJ£=10 (30ml/3g)

*HJt=2.5

w l 1

•- 8 - ^ i*

16 » XT«nMnturt PC)

D

1

**

J i 4,0 «-S 5.0 6JSSitparrulant (iH

•iam AT 01 bbe uip«ni*UAt pK

• c **

' r . ° :

t ^

e

*

t

tut \JDEC |mS cm*}

(25ml/10g)

Ran I f ; 1 'a I

RvirZRun!

J ( B ' O> HUR2> Runs

Runi J*"C>

P3"C]RuntHunl :

- 40 -


2 C20-

B

m

Ik

ft

/

MNo

l1234456778

ft:

•

•

1

\*UVo.12345678

_

•"s_

--•V.

- - « .

' • s _

SLIB

In

Shinich

fe (8^-5:

i NAKAYAMADis t r ibu t ion CoefSelected RocksMem. Fac

Inada

Rokko

. Eng. , Kyo

g r a n i t e

grani teOhya tu f f

I t a d oMyoken

tMzk

PHi

71 1100

7 2700

77

11 50

7 200

77

117 4200

&t r i n s i c

tuffquartz

pH, Eh, Q.tf-1

ZK(2. 5L©s

1 week, 'MM and/or

Hirotake MORIYAMA, Haj ime

)

ARIMOTOf i c i e n t s of Americium, Neptunium

to Uni

2 5 0 -

2 5 0 -2 5 0 -

v. V o l . 4 8 , No.

Mm] lfc^tW\500T 0.500500 21.

250£4T 26.2 5 0 -2 5 0 -

500 43.500T 0.

:. mmm

zKHAm+Inada g ran i t e (o r Ohya

] . . . Adsorption2 4 1 A m

u m-

7700 7700

9000 17000

-

1700 3600

580 630

--

4200 4200

S

IV

220-

4302400

98-

1309300

22022

1300

Ge-detector50ml-Polypropylene

Centrofuge tube

2 3 7"

V I

13000 1.3

3. 3

43000

25000

1400 3. 5

13-

23000

1900 0.67

350 2. 2

18000

3 (1986)

AtmVg]ND51ND757500ND47

t u f f ) CDS

\f p

n m1.4 1.

3. 5 3.

--

3. 3 3.

12 13

-

0. 73 0.

2. 8 3.

-

*rs.

Eacr

A < t

77

5

923

I :itifi/0. 45/j.m;Mi 11 ipore

n:«ifl/0. 1 /zin: Mi 11 ipore

miriiS/O. O25/zm;MillIV:j!4>:fr&t /5000rpmX

V:ii-L^8t/5000rpmx

ipore

lOmin

lOmin

andand Kunio HIGASHIProtac

rocks

2 3 3

I

2.2.--

1.3.--

0.0.-

m

p j

54

54

6137

was

Ltzc

i

n3. 3

5. 6

--

4042

-

6.54.4-

+ !ii!/0. 1 n

inium for

crushed

). )

m6. 27. 3-

5265

-

1621-

Tt; M i 11 i p o r e

- 41 -


week, :MM and/or

2 020-2

Shinichi NAKAYAMA, Hirotake MORIYAMA, Hajime ARIMOTO and Kunio HIGASHIDistribution Coefficients of Americium, Neptunium and Protactinium forSelected RocksMem. Fac. Eng., Kyoto Univ. Vol.48, No. 3 (1986)

B

No.12345678

Inada granite

Rokko graniteOhya tuff

Itado tuffMyoken quartz

250-500

250-500250-5002 5 0 ^ f250-500250-500

ND0. 51

ND21. 7526. 7543. 00

ND0. 47

Each rocks was crushed

Inada granite (or Ohya tu

No.

11234456778

PH

~ 7~11

~ 7

-11

~ 7~ 7~ll~ 7

2

I

-210015000

--

440780---

17000

.. Desorption"Am

n_

1200074000

-

64002000

---

17000

m-

18000370000

-

64002200

---

130000

rv3000

-58003300600-

640440046092

12000

V

3700-

58000130001600

2300-

5700110043000

Intrinsic Ge-detector50ml-Polypropylene

Centrofuge tube

I :i!tifi/0. 45/zm;Mi 11 iporeII :i!tiS/0. 1 /.im;Mi 11 iporeni:&j8/0.025/zm;Mi 11 iporeIV: 3V + i i i i / 0 . l/tm;Mi 11 ipore

- 4 2 -


(J*#/24 hours or t£®/60 hours, itifi/0. 45Mm;membrane)

2 1

Shinich Nakayama & Donald M. NelsonComparison of Distribution Coefficients for Americium and Curium:Effects of pH and Naturally Occuring ColloidsJ. Environ. Radioactivity, 8, 173-181 (1988)

A

t±(Lake Michigan, pH7. 91)

Eh,

A:Lake MichiganB:Saganashkee SloughC:Argonne PondD:Volo Bog

Col loidal-OC[mg/l]11411

pH

7. 96. 6

ft-4Crn(10 l 6 m o l / l )243Am(10"'3mol/l) and

250ml-Glass FlaskSilicon surface-barrier detector

Adsorption

PH

A, B:magnetic s t i r r e r

K d ( 2 4 3 A m ) K d ( 2 4 4 C m )

AABCD

0. 350. 700.0875

4 ~ 74. 5 -8 . 53. 5~9. 5

7.96.6

4 X 1 0 4 ~ 3 X 1 0 6

l X 1 0 4 ~ 5 X 1 0 5

1 x 1 0 4 ~ l x io 5

8X10 5

1.5X105

7 X 1 0 4 ~ 3 X l 0 ( i

l X 1 0 4 ~ 5 X 1 0 5

1X1O 4 ~1X1O 5

1X106

- 4 3 -


(16 £ 5 :7days,

Ltti:2 2 , 224 (1987)

C

Eh,

C s ,Am

'/%& 5. 2X 10 3)S r : 0. 0 7 - 3 mmol/1)

: 0. O3X1O'3~O. 12X 10 3 mmol/1)

Cs, SrAm

±mBentoni teSandTatikawaMusashinoTamaHatinoheTakadateZeol i te

loamloamloamloamloam

. Adsorpti

pH(End)

7-9. 57-9. 57-9. 57-9. 57-9. 57-9. 57-9. 57-9.5

503505030170600

on

C s

- 2500- 10- 450- 450- 200- 100- 300-70000

S

200. 5

12070

r

-9000- 5

- 80- 600- 600

pH(End)

7-9. 5

2. 52. 5

4-74-7

1600

104

601400

A m

-35000

- 110- 20

-70000-70000

= 1.3-7.5 [g/1]

- 44 -


2 4 ' A m CDF>^CD Pl2 3 > 227 (1987)

C

P1tt(pH. Eh.

A d s o r p t i o n

pH Kd(24 'Am) pH Kd(24lAm)

4567810

2010080050015010

3.3567810

8901001007010

PH

4678910

Kd(M1Am)

5302515105

1=5 (5ml/lg)

- 45 -


2 424-1

* 30, 942-949 (1988)

A

ffififc (Gravel. Sand, Si l t&Clay)[volume-*] [weight-*] [g/cm3]5 8 / 9/33 ( 0. 5, 97. 5, 2. 0 ) 2. 69

D - A l 40/25/35 ( 0 . 0 , 58.0, 4 2 . 0 ) 2.68Undisturbed ae r a t ed s o i l

CEC Jt^ff lS ;[meq/lOOg] [mVg] [cm/sec]

1.9 1.8 1. 3X10 :

7. 6 22 2. 3 X 1 0 "

.-145cm), D-ABCtoSii.-517cm)

6 0 C 011 3.012 2.6

D - A d l f i O , 0.

s S r 1 3 7 C s2. 7 3. 23. 0 3. 09 . 1 1 1 . 0

[ppm]0. 140. 171. 3

[1/h]6. 33 5. 706. 08 1. 496. 35 1. 09

[i] ra660 20660 20

80 20

30cm4)Xl20cinH

O C o C l 2 , 8 5 S r C I 2 ,

i:i7

.. Adsorption

" C o ! iSr ! 7 C s

D —

6804002000

7203601700

660340

2300

0.750.550. 78

- 46 -


ti

2 424-2

, 30, 942-949 (1988)

A

A '

O —A

(Grave l , Sand, Si 1 t&Clay) ^ ^ CEC \ti[weight-*] [g/cm3] [meq/lOOg] [m7g]

( 0 . 5 , 9 7 . 5 , 2 .0 ) 2 .69 1. 9 1.8( 0. 0, 58. 0, 42. 0 ) 2. 68 7. 6 22

. Eh,

0CoCl2, 8SSrCl 2.

13 10

... Adsorption

" C o ! i S r

• - A51

3300no

2700

= 4 0 (800ml/20g)

Cs

4002500

- 47 -


mt o-.Uays, j&fr#Blt/3OOOG/2Oinin)

2 5 > 46 (1988)

C

Takadate loamCoastal SandToyoura SandBentnite 74ii!.T

H. E h .

0. QlU<DmiM.mB.i- h U

30°C

i. OX , Na0HX«HN03T

7 D —

Takadate loamPH

4. 14.95.77.07.89.010.0

Kd(Np)

111. 12355

Adsorpt ion

Coastal SandPH

3.55.467810

Kd(Np)

1. 53371012

Toyoura SandPH

4577. 5910

Kd(Np)

1515100450600600

BenPH

2379101112

tni teKd(Np)

2525305050100

1000

]J£=100 (5. 0ml/0. 05g)

- 48 -


U— i/ 3 X T h e o r e t i c a l S u r f a c e Complexat ion Mode l s )

2 626-1

I. Puigdomenech and U. BergstromCalculation of Distribution Coefficients for Radionuclides in Soils andSedimentsNuclear Safety, Vol.36, No. 1, 142-154 (1995)

A

The amount of ion exchange (clay) was set to lg/1, and CEC = 0. 2meq/g wasused.Precipitation of calcite and aragonite was suppressed.The sorbent was assumed to be lg/1 of clay and 0. 05g/l of goethite.

till H, Eh,Chemical Composition of the aqueous SolutionsAverage[mg/1] (Range)

Na K Ca Mg HCO* pH(soil) pH(sedin)ent)5(1-16) 2(0.5-5.0) 60(2-120) 2.4(2-7) 30(0-122) (4-5) (6-7)

The calculations carried out gave Kd values as functions of environmentalconditions, such as pH, Eh, alkalinity, and concentrations of cations.

ElementC sR aUNpP u

Kd[ml/g]1000500100100

50000

((((((1

Range )100- 10000)50- 5000)10- 1000)10- 1000)

000-100000)

**4^ (T.MHC^

- 49 -


(Theoretical Surface Complexat ion Models)

2 626- 2

I. Puigdoinenech and U. BergstromCalculation of Distribution Coefficients for Radionuclides in Soils andSedimentsNuclear Safety, Vol.36, No. 1, 142-154 (1995)

A

~, ••.« to-.

- 5 0 -


Xffi.

2 7

K. Bunzl and W. SchimmackDistribution Coefficients of Radionuclides in the Soithe Field Variabili tyRadiochimica Acta 44/45, 355-360 (1988)

Analysis of

A

Cultivated field (100X150m;diagonal- I :SW to NE;diagonal-II :SE to NW)The soil samples(Alfisol) were taken from the ploughed horizon(0-30cm)in intervals of 3. 6m.lOg of soil;25ml soil solution containing the 9 nuclides simultaneously

... Adsorption

JWK

* tx>i

B.t

3

a

A 1

Tc

1 /•W

1*

tM1»Vi . Jj

1

Hi'

"To" M •>: is ss D « Jt 30 to K)

DISTANCE IN LAOS

M of i CMXKltM Tw* T>>> a w i w •-' ih* unpllHf pm*i 9fiM i n i atlttx ^hM»«fw tey t

taeao

1C44D

0

50

10

£* MOC

•w

0

20

16

11

13?

xraCO i

• "" A

: :

SCOD

,030

2CSJQ

3

«00

0

10M3

C

3.1

0.1

SI

- ^

•

if i, '

l

i

1 t

13 3D 30 id SO 3 19 20 M :0 SO

DISTANCE IN LAQS

i uttnix r<ta. Tw lt>auwc< <« <«wll« runs n3t

- 51 -

JARRI-Data/Code 2001-005

Mfetik (Jt#:20days,

2 828- 1

H. Bachhuber, K. Bunzl, and W. SchimmackSpatial Variability of the Distribution Coefficients of 1 3 7 C s , 6 5Zn,8 5Sr, r'7Co, 1 0 9Cd, l 4'Ce, 1 0 3Ru, 9 5 m T c , and ' 3 1 1 in a Cul t ivated Soi:Nuc. Tech., 72, Mar. (1986)

A

A l f i s o L 0-30cnu moderately humified sandy loam (FRG)()pH(CaCb) 6.7

Carbonate (CaC0:O [%] 0. 2Total Carbon [%) 2.4Total Nitrogen [%} 0. 1

ClayS i l tFine SandCoarse Sand

ra[%][«

12.28.58.

1.

0434

CECCaKMnFe

[me/kg][me/kg][me/kg][mg/kg][mg/kg]

87814

180430

Eh,Soil solution very gently shaking lOg of soil with 25ml demineral-

ized water at intervals for 3 days, followed bycentrifugation at 4400g.

Cultivated field ( for wheat )situated on an almost plain plateau nearEschweiler-Lohn in the western part of the Federal Republic of Germany.Sampling Day November

Point 1 0 0 m X 1 5 0 m ; d i a g o n a l - I :SW to NE;diagonai-E :SE to NWinterval of the sampling point was 3. 6m(along diagonal)

7Co, and ':i' I ... AmerdhamSr, 1 0 9Cd, 1 4 1 C e , I 0 3Ru, a n d 9 5 m T c . . . New England Nuclear4^ and chlorides (others)

Soil sample ... air dried, seived to 2 X 2 m m ,Soil solution(24. 5ml) + Soil(lOg) I RI(0.5ml) ... agitated very gently

at 293K for 20 days at intervals in capped polyethylene cetrifugetubes

HP Ge-detector

1 3 7 C s6;'Zn,

[mo 1/1] r> 7

1 0 3

1 4 1

CoRuCe

4.1.5.

8E-101E-73E-6

6 "In1 0 9 Cd

1.3.

7E-62E-8

8 o S r1 3 1 j

3.5.

6E-82E-11

9

1

rimTc3 7 Cs

1.4.

OE-103E-6

- 52 -


2 828- 2

H. Bachhuber, K. Bunzl, and W. SchimmackSpatial Variability of the Distribution Coefficients of 1 3 7 C s , 6 5Zn,8 3Sr, 5 7Co, 1 0 9Cd, 1 4 l C c , I 0 3 R u , 9 5 m T c , and 1:!1I in a Cultivated SoilNuc. Tech. , 72, Mar. (1986)

.. AdsorptionNuclide Kd(Median) 95%Limit of Median Kd(Mean) Range

'Cs 8700 8300 - 9200 8900 5200 - 16500F r e q u e n c y D i s l r i b u t i o n

Lognormal

Zn 1800 1500 - 2000 1900 670 - 4300 Lognormal85Sr57 Co

109CdM 1 C e

1 3 1 T

PH

30230017003100

820. 337. 63. 28

29 - 312100 - 25001500 - 18002200 - 430076 - 88

0. 31 - 0. 387. 2 - 8. 67. 2 - 7. 3

29250017004700

930. 378. 87.26

20 - 35260 - 5800430 - 3000620 - 2540023 - 200

0. 15 - 0. 895. 2 - 186. 7 - 7. 7

LognormalLognormalLognormal

Normal

iue»|7

MMjCi46 ISO i«J

- 5 3 -


2 828-3

H. Bachhuber, K. Bunzl, and W. SchimmackSpatial Variability of the Distribution Coefficients of " 7 C s , li5Zn,8 5Sr, F'7Co, " ) 9Cd, 1 4 1 C e , "):iRu, 9 H m T c . and ':!' I in a Cultivated SoilNuc. Tech., 72, Mar. (1986)

... Adsorption

;l

T

1

J . .i fir

I U

-.

Vr

II11inTrk

0 5OCO iiOOO

'? i i

f!hi n

anrlkvnK «f tin

«oe toon i*ooo

*

£

"In

r

I —rtwo xxv MOO «ooe> woo

4

- 5 4 -


2 9

R. F. Pietrzak, G. Galdi, A.Weiss, P. ColomboShallow Land Disposal of Low-Level Radioactive Waste: RadionuclideSorpt ionTrans. Am. Nucl. Soc. CONF-790602—(Summ.). v. 32p. 114-115, Jun. (1979)

mUnweathered ti

. Eh.Trench-water

Ge(Li) detector

... A d s o r p t i o n

300

200

"? 100

* 0

J ffl

a 10

I 302Q

Cs-13»l

s - j ^ . 137

i VOTER |tti « 5.9, T - 20° C 1SOIL: IUIEAIKKED TIUL|

W-S2

; D DILUTIONCs-13t, 137

S 5 3 10S h

101

5 6 3 1

a?

- 1- K,jKHptiaicocfnc)CiKnwittr/)oiSnlio.

- 55 -


3 030-1

J.F. Pickens, R.E.Jackson, K. J. Inch, and W. F. Merri ttMeasurement of Distribution Coefficients Using a Radial InjectionDual-Tracer TestWater Resour. Res., vol.17, No. 3, 529-544, Jun. (1981)

-f• Fine sand (65-100w% < 0. 2mm & 0-10w% < 0. 06mm)

£ R g $ O . 38, i t S 2 . 7 ( A " ; i / ^ ^ 1 . 7g/cm3) , CEC 1 meq/lOOg

L_1

I 13*-

* t ±1.3jLj.,f,,,",,.!?., a t $ u

i l

ClkW-SIZS FHCTI0I" (1.I4* :<

: S

i l l -

F i

"[

J !I I . •

k 01 1

f 1 » « 0JUL

0 f S

Fij * Hmo|fln:! of nincutb;v of ><)iti[cf. Minertls ideniiAcd by optical jniarriU>§y. (Q, qufent; F., sttiatc M. mtc»: H, hemblcndc: »ai O, oihtf}.

Eh.

Fig i. X ray diftjac«>5rams (normli and huiut) TarKdimenil from 4-m depth. The nutnben t<lct 10 the measured unitctti spadcgi ia ftanomifrteR of ibe vahout mtAefiLs.

Temp. = 7 ~ 8 ° CPH Eh Alkalinity " f ^ ^ H E

[m] [V] [meq/1] 0, Ca 2 + Mg-TSr-+ Na+ K+ Fe Mn Si S0 42~ Cl"

2. 30 6. 7 0. 22 0. 97 - 12. 8 8. 0 0. 05 9. 1 3. 5 3. 9 0. 05 8. 2 18. 3 29. 02. 66 6. 8 0. 28 0. 96 - 12. 8 8. 0 0. 05 9. 1 3. 5 3. 8 0. 10 8. 0 18. 5 29. 64. 05 6. 5 0. 21 0. 92 - 12. 8 7. 5 0. 04 9. 1 3. 1 4. 0 0. 10 9. 0 18. 5 30. 0

- 5 6 -


7 4 — J I / K & ( R a d i a l In j ec t ion D u a l - T r a c e r T e s t )

3 030-2

J. F. Pickens, R. E. Jackson, K. J. Inch, and W. F. Merri ttMeasurement of Distribution Coefficients Using a Radial InjectionDual-Tracer TestWater Resour. Res., vol.17, No. 3. 529-544, Jun. (1981)

SpeciesTotal radioactivityInput concentrationHalf-life

Nonreactive tracer1 3 1182 mCi

1. 9 X 1 0 " 5 mg/18. 07 days

Reactive tracer8 5 S r

86 mCi1.4X10" 4 mg/1

64. 7 days

Radial position of multilevelsampling devices

Depths of multilevel samplingpoints

RateDuration (from start of addition)

(from end of addi tion)Total injected volume

withdrawal volumeAverage radial front position of

nonreactive tracer at end ofinject ion

0. 36, 0. 66, 2. 06 m

2. 29, 2. 67, 3. 05, 4. 57, 8. 08 m

Injection phase Withdrawal phase0. 719 1/s 0. 606 1/s3. 93 days

16. 9 days244 m3

886 m3

5. 0 in

PVC piezometer & peristaltic pump / Methyl methacrylate sampler / 0.45M m Mi 11 i pore HA / ^-filled polyethylene bottle / Nal (Tl)-r counter

Spike Injection S5 S r, =0. 36m r s p =0. 66m

K d = •

d tr— (—1)

2.302. 663. 05

p 1

tr,

2. 62. 64. 5

2. 73. 24. 2

P b t n

tn

porosi tybulk density of the porous m e d i atime at which C/C»=0. 5 for the r e a c t i v e / n o n r e a c t i v e tracers

- 57

J A ERI-Data/Code 2001-005

(Sediment Core)

3 030-3

A

J.F. Pickens, R. E. Jackson, K. J. Inch, and W. F. Merri 11Measurement of Distribution Coefficients Using a Radial InjectionDual-Tracer TestWater Resour. Res., vol.17, No. 3, 529-544, Jun. (1981)

Sediment Core<D+f->7°U|*l1I5cin©Alf?T3. 5m©g££ £ T ? © j & J I $ ; M o (Core-1, Core-2)'Dual-Tracer Tes t '0 8 5 Sr- In jec t ion*|7B^(4H) t c ^ ^ o

'Dual-Tracer Test'BH&&29-40B&K, illllg (Core)^ |®zK*^ Uj i ^ t ^ ( O . 45Mm?t^c, 8000G/20minX3,S e d i m e n t * f f i

Well-type Nal(TL) rcounter (Packard)

... Adsorption (& Desorpt ion)Core-1 Core-2

Sr

2.2.3.

306605

4.4.5.

837

4. 35. 17.9

Kd =Radioactivity of Sediment[dpm/g]

Radioactivity of Interstitial Water[dpm/ml]

- 58 -


: 3 - 4 r p m X 2 5 h o u r s , ^ f S 3 0 m i n / D e c a n t a t i o n )

3 030-4

J.F. Pickens, R. E.Jackson, K. J. Inch, and W. F. Merri 11Measurement of Distribution Coefficients Using a Radial InjectionDual-Tracer TestWater Resour. Res., vol.17, No. 3, 529-544, Jun. (1981)

4k

ft

fc, lg^Sediment i : 5ml

, 0. 45,uni-meinbrane f i 1 ter (Mi 11 i -poreWell-type Nal (TO r c o u n t e r (Beckman Gamma 8000)

. . . AdsorptionSediment (Core-1)

S r

2. 30 3. 02. 66 2. 83. 05 7. 8

d vKd = ( 1)

Cr w

Ci : initial concentration of the reactive tracer in solutionCr : final concentration of the reactive tracer in solution

59 -


3 131-1

m

A >

H. M.D i s t

?n

Johnsribut

s t o r a g eCan.

A'lJTtJ

tonion

areaGeotech

• E a s t e r nP h y s i c a l

O x i d i z e d

Kbshore

:5 :

R.WcoefforJ.,

ofcharacterist

ti

U n w e a t h e r e d

S a n d

C h e m i c a l

A4A8D8A12A23A32A38D14D23D28D33D38B 2 - 2 6C 2 - 2 2G8G10G12Ql 7W22

11

till

A4A8D8A12A23A32A38D14D23D28D33D38

1 6 - 1 8 h o u r s ,

Gifie

1 1 h a mi e n t s

andfor

il

l o w - l e v e ! r a dv o l . 2 2 , 6 - 1 6

tb'Amn 00

J . A . C h e r r ys t r o ni o a c t, F e b

t i u nive

Orp

andwaste

. ( 1 9 8 5 )

L a k e H u r o n n e a r P o r t E l g i n ,ics

B 2 - 2 6C 2 - 2 2G8G10G12Q17W22

c h a r a c t e r i s tCEC/

5.3.6.2.2.2.2.3.2.2.2.6.0.0.0.0.0.0.0.

3425802111038899789

EXCCa9.7.9.6.5.6.6.7.6.6.5.5.7.8.6.6.7.8.8.

2

5608907110873186522

ics

o f o v e r b u r d e nO r g a n i c

C a r b o n [ f t ]0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.

1722921201018272423161117231315191622

s a m p l e s «C a r b o n a t eCa

of overburden[ m e q / l O O g ]+ M g 2 +

1.2.2.2.2.1.1.2.1.2.1.1.0.0.0.0.0.0.0.

7121289190994733445

K+0. 20.40. 30. 50.40. 30.40.40. 30. 30.30. 3-------

SolCa230.28.32.24.20.21.21.27.22.21.21.20.71.76.47.57.63.85.

1 2 6 .

kit182014161620101312141515916232314237

e

m/ l O m i n )

c e s i u m i

* r * .

n overburden

O n t a r i o2mm

c o n t e n tDo

s a m p l e s «u b l e c a t i cf

6044726750560373705

M g 2 t

8.316. 213 . 32 0 . 01 9 . 01 8 . 31 9 . 32 1 . 720 . 82 0 . 51 9 . 01 7 . 514 . 628 . 31 2 . 41 2 . 51 7 . 815 . 82 9 . 0

K+2.11.3.19.10.12.15.13.11.13.12.19.4.6.1.2.2.3.5.

ns

5371753465351040888

mi

f r a c t i o n )[ft]

l o m i t e212329283025132632283336323642354238142 m m

[ m g / 1 , C sNa2.7.4.10.9.12.12.6.7.8.8.8.5.4.2.2.3.3.7.

+

9362489874106511195

Sr>o.0.0.0.1.0.0.0.1.2.2.3.0.0.0.0.0.0.0.

GraSand29.32.28.37.32.36.35.37.36.37.36.36.

764581786893

fract ion): u2 +

12019475592777588038058270114162640

g / 1 ]Cs +

0. 10.20. 20. 1

< 0 . 0 20. 13. 20. 10.60.60. 6--------

at a

i n s i z e [ f t ]S i l t4 0 . 23 4 . 23 8 . 23 5 . 83 2 . 03 5 . 83 1 . 236 . 941. 838. 737. 734. 5

C l a y171422111310911811114

S o i l - p a s t eCaCh7 . 8 17 . 9 97 . 8 98 . 0 88 . 0 88 . 1 48 . 2 08 . 1 08 . 1 88 . 3 08 . 3 08 . 3 17 . 7 57 . 9 28 . 2 38 . 2 88 . 0 58 . 1 48 . 1 5

H28.8.8.8.8.8.8.8.8.8.8.9.8.8.8.8.8.8.-

. 5

. 6

. 2

.9

. 3

. 6

. 1

. 1

. 7

. 4

. 1

. 8

PHO506045788290987092939502695482757072

- 6 0 -


3 131-2

m

#

H.M.Johnston, R.

: 16-1

W.Gil

8hours, &'b

lhamDistribution coefficientsstorage area forCan. Geotech. J.

~ZK#14(pH, Eh, rt#Chemical analysis offor

A8. 'A22.A28A44

Sand samplespH (Field/Lab)

1 6. 55/5 6. 99/

7.5 /7.92/

B2-26 7. 15/C2-22 7. 10/D23D28D34D39G10Q16W22for

A4A8.A12.A22.A28A39D8D13D23D28D34D39

7. 72/7. 55/7.45/7. 52/7.1 /6. 89/7. 03/

Till samplespH(Field/Lab)

8. 03/8. 051 7. 58/7. 601 7. 45/7. 585 7. 68/7. 68

7. 76/7. 787. 67/7. 707. 6 /7. 727. 49/7. 38. 02/7. 808. 32/7. 907. 92/7. 907. 56/7. 80

low-vol

level. 22,

and J. A

$Jffi/2000rpin/I0niin)

Cherryfor strontiumradioact ive

and cesiumwaste

6-16, Feb. (1985)

groundwater used

HCOs495324263136483419483357375378360448514

HC(h526459450313268223499489386270386376

Composi tion of synthetic

12345

M

Cation concentCa Mg30 1922 1930 832 1351 13

hbtiWik* 3. 0m 1C

" SO440210084483353. 63827639155019454924

8. 1

~ SO4

384766366

1049466450

49. 5441238291577270

2- ci10.110. 87. 35.02.96. 35.4

10. 63. 66. 315.05. 913. 8

2- ci8.6

13. 814. 517.017. 344. 910. 510. 88. 6

37. 95. 6

11. 8

groundwaterration[mg/l]Na710252

K1714342

PH7.7.8.7.7.

tmu.n>fflfe.

in Kd

Ca2 +

1238165641189459504844200110133

Ca2 +

6910714310069588011153475545

58068

2.0gt

determinat

Mg2 +

7566544923. 533.567746667671427. 5

Mg2 +

257693846050567263647256

forforforforfor

10.0

K+6. 75. 73. 5

16. 01. 13. 35. 26. 84. 64. 03. 20. 60. 9

K+2. 78.09.06. 74. 1

12. 12. 76.06. 89.67. 76. 3

in

ion

Na+

88330126373680106185773423

Naf18642126261861189. 3100404414243

A8 & D14A12-A38A4D8G10

&

»• i

-A

overburden

[mg/l.Cs

Sr2 +

1.913. 810. 25.3

.7 0. 8

.0 1.112.815.023

.5 20. 50.5

.4 0. 2

.8 0.4

Sr2 +

0.341.964. 2516.0-

3. 702. 126.44

10.59. 8

25. 817. 9

D23-D38

•In 7-.

Cs

Cs00

<o0

<o<c000000

- 1 0

at a

g/1]

-t-

+

.34

. 2

.03

. 1

.03

.03

.3

. 1

. 3

. 1

. 5

. 5

NcDSr

- 61 -


3 131-3

ffl

*

n

H.Di

v?m (JS£5:16-1

M. Johnston, R.W.Gilstribut ion coeffici

storage area for low-Can. Geotech. J., vol

• Wrist-action shaker

8hours,

lham andents for

J. A.

>$t/2000rpm/10min)

Cherrystront ium

level radioac.22, 6-1

•Automatic rcounter (Nuclear Ch

Oxidizec

[ml/g] ... Adsorpti on

andtive waste

6, Feb. (1985)

icago

Kd(S lGroundwater

till A4A8D8

Unweathered till A12

Sand

Kd =

CoCoVMf

A23A32A38D14D23D28D33D38B2-26C2-2G8G10G12Q17W22

Ce V 1(\ \

Co M f

: Concentration in

10. 66. 6--4. 14. 85. 8-4. 04. 53. 23. 62. 52. 92. 01. 32. 62. 11.9

the soi: Initial concentration in: Volume of equi 1 i: Mass of the soil: Ratio of counts

for a aliquot of

brat ingsample

Model

-)Synthet ic3413281218111399976

2

. 1 + 1.

. 2±0.

. 0±0.

. 9 ±4.

. 8 + 2.

. 2 + 1.

. 2±1.

.5 + 0.

. 7 + 0.

.5 + 0.

.7 + 0.

. 7+1.

. 5

1 solutionthe

solutused

cesium in overburden at a

1085)

S.248048486677

Kd(C s)Groundwater Synthetic S.3529±2176 4308 + 21531557=+= 371 733+171

17026 + 1390 7469±4288591±134611 =±= 148692+170751 =+=2221248±2361000 + 3631019=1= 1 98853±1651180 + 28328359437285166332303

at equilibriumequi1ibration added[g]

in the equi1ibratedthe ini tial soluti

soion

612 + 120833 + 208516 + 195607 + 56942+190654±135549 + 81709±50522±105

[mg/ml]ing solut ion [mg/ml]to the soil

1 solution

[ml]

to the counts

- 6 2 -


mum

3 232-1

m

?£

0k

ft-

Ay 5

L. L. AmesInvesYear

tigand

at ionJ. E. McGarrah

of B a s a l t - R a d i o n u c l i d e D i s t r i b u t1980 Annual Report

RHO-BWI-C-108

A'J7#<7

BasaltUmtanumPomonaFlow E

SecondaryMinerali

BasaltUmtanumPomonaFlow E

SecondaryMine ra l .Mine ra l .Mine ra l .Mine ra l .

S y n t h e t i c

GR-1

zatGr:Sm:

1234

fe(Pt

ion

, PNL—3462, 109, Dec. (1980)

Mine ra logy [v%] EG-SurfaceGr PI Py SM

38 26 21 823 34 31 614 46 32 5

- - - -

Sm Me Area [m 2 /g]

- 7 17.7 + 3 .8- 6 31 .2 + 1.4- 3 1 0 . 3 ± 1 . 0

98 2 646 ± 19Groundmass , P I : P l a g i o c l a s e , Py: P y r o x e n e s ,Smect

S iOa

55. 6451. 8754.47

43. 245. 544. 544. 3

{. E h .

i te / EG: Ethylene Glycol

AI2O3 Fe^Os

1 3 . 6 2 2 . 0 01 5 . 0 2 2 . 0 01 4 . 3 7 2 . 0 0

6. 5 9. 86. 6 9. 66. 6 9. 76. 5 9. 4

Groundwater Formulat

Na+

30.GR-2 225

K+

7 9.2.

Oxides [w%]

ion

-*.s

SM:

FeO MnO CaO MgO

10.68 0.20 7.17 38. 89 0. 19 10. 58 7

11.16 0.22 7.36 3

1.2 121.0 121.1 121.0 12

mmions

C o n c e n t r a t i o n [mg/1]Ca 2 + Mg2+

0 6. 5 1.05 1. 06 0. 07

Cl CO.,2- HC0.r14 .4 0 81 .5

131 59 75

33.08. 56

. 4

.8

.6

.7

F"0

29

Coeff i c i e n l

ize Range[mm]

0. 85-00. 85-00. 85-0

2

505050

s: F i s c a

as. sCEC

jneq/lOOg

1. 7 + 02-3

4. 7±0

60-70S e c o n d a r y M i n e r a l s

Na20

3. 302. 232. 79

---

SO42"11. 172

K20

1. 620. 391.58

0. 70. 70. 70. 7

SiO2

25108

TiO2

2.051.552. 11

---

PH8.0

10. 0

1

2

1

1430

]

P2O.5

0.0.0.

0.0.0.0.

391936

2222

- 63 -


3 232-2

L. L. Ames and J. E. McGarrahI n v e s t i g a tYear 1980RHO-BWI-C-

• Normal Oxygen

Kd obtcl i n e d a f t e rTemp C i

7 5 S e8 5 S r"Tc

1 2 5 J

I 3 7 C s2 3 7Np2 4 ' A m2 4 , p

7 5 S e8 5 S r"Tc

1 2 S J

1 3 7 C s2 3 7 N p2 4 l A m2 4 , p

*C] [mo 1/1]23 2. 63E-1323 5. 54E-1223 6. 55E-0823 4. 24E-1423 8. 76E-1023 6. 47E-0823 2. 09E-1023 1. 62E-1160 2. 63E-1360 5. 54E-1260 6. 55E-0860 4. 24E-1460 8. 76E-1060 6. 47E-0860 2. 09E-1060 1. 62E-11

ion of Basal t-Radionuclide DisAnnual Report108, PNL—3462, 109,

. AdsorptionEnvironment

t r i bu t ion

Dec. (1980)

50 days of solid/GR-1 synthetUmtanum Flow EBasalt Basalt5 . 4 + 1 . 3 1.2 + 0.3105 + 4 9 1 + 5

26. 8 ± 2 1 . 9 06. 8 ± 1 . 3 1.0 + 0.4705 ± 18 278 + 6

30. 0 ± 1 3 . 0 4. 1+0. 9277 + 103 622 + 180102 + 97 165 ± 16

0 1.0 + 0.1122 + 3 104± l

25.5 + 5.2 00 0

463 + 5 187±631.2 + 4.7 8. 3 ± 0 . 5

236 + 98 400 + 245353 + 224 300 + 26

PomonaBasalt2. 4 + 0. 712l±9

02 .0+1 .0

1685 + 2459. 8 + 0. 5696 + 93267+18

0130 + 4

00

747 + 3712. 1±3. 2717 + 3700+108

Ci: I n i t a i a l Radionuclide Concentrat ionpH: Average

Kd o b t a i n e d a f t e r

2 3 3 U2 3 3 U

Temp C

' pH for samples at lg/ml and 89 or

Coeffici e n t s : F i s c a l

ic groundwater contactSecondary

Mineral izat7. 6 ± 0 . 3274+16

014. O i l . 8

1000036. 9 + 7. 51355+1522572 ± 341

0339 + 5

00

1432 + 69553. 5±18.1489 + 3503328±609

ion8 408 ?07. 90,8 ?08. 25,7 508. 55,8 158. 75,8. 60,8. 35,8 758. 55,

8 7. 85,8. 20,8. 15,

93 days contact

PHIn i /F in

8. 35, 8. 40,8. 20, 8. 45,7. 90, 7. 95,8. 25, 8. 25,8. 20, 8. 30,7. 60, 7. 55,8. 45, 8. 40,8. 10, 8. 20,7. 70, 7. 80,8. 35, 8. 40,8. 40, 8. 40,8. 65, 8. 55,8. 70, 8. 95,7. 90, 7. 95,8. 15, 8. 20,8. 1 5, 8. 1 5,

8. 95/8.8. 90/8.8. 80/8.8. 92/8.8. 90/8.8. 70/8.8. 70/8.8. 50/8.8. 85/8.8. 40/8.8. 10/7.8. 70/8.7. 90/7.8. 40/8.8. 40/8.8. 15/8.

60 days of solid/GR-1 and GR-2 synthet ic groundwater contacti Umtanum Fl ow E

DC] [mo 1/1] B a s a l t B a s a l t60 8. 16E-09 5 6 + 1 1 160 8. 16E-09 2 . 8 + 0 . 9 1.

D i s s o l v e d oxygen

3+10 ± 0 . 2

in the so lu t ion contac t ing 20-C o n t a c t Temp S o l i d / S o l u t i o n[days"

1616313188888888

ro2323232323236060

[g/ml] Blank1/10 8.251/80 8. 251/10 8.251/80 8. 251/10 8.251/80 8. 251/10 5.101/80 5.10

DissolUmtanum

8.008. 258. 158. 35--

5. 305.00

PomonaBasalt

16 + 20. 9 + 0. 2

Secondary GroundMinerali

147 +72 +

to 50- mesh basalved Oxygen

Flow E8.308. 258.308. 20--

5. 505.05

[mg/1]Pomona8. 208. 308. 308. 20--

5. 505. 10

zation Water702

GR-1GR-2

t samples

Secondary----

5. 707. 103.904.95

90857590725065509040606570254545

- 64 -

J AERI-Data/Code 2001 -005

3 232-3

A* y -,

L. L. Ames andInvesYear

tigat ionJ. E. McGarrahof Basa

1980 Annual RepoiRHO-BWI-C-108

• Low Oxygen Envi

Kd at \

75Se75Se8SSr85Sr"Tc"Tc

2:!7Np2:i7Np24!pu24 'Pu75Se8"Sr"Tc

2:i7Np2 4 1 P u2 3 3 U

>3°C obtainedWater

GR-1GR-1GR-1GR-1GR-1GR-1GR-1GR-1GR-1GR-1GR-2GR-2GR-2GR-2GR-2GR-2

Contact[days]53535353535353535353616161616161

, PNL-

t-Radi-t

onuclide Di stribut ion

-3462, 109, Dec. (1980)

Adsorpt icronmen

afterSSR[g/ml]1/101/201/101/201/101/201/101/201/101/201/101/101/101/101/101/10

)nt (oxygen

53 or 61d

[mol/1]2.2.5.5.6.6.6.6.1.1.2.5.6.6.1.8.

63E-1363E-1354E-1254E-1255E-0855E-0847E-0847E-0862E-1162E-1163E-1354E-1255E-0847E-0862E-1116E-09

partial pressure ~ 7 .

days of solUmtanumBasalt16. 8±4. 0

-381 ±136-

4489±3165-

148 + 27-

5190±3290-

249 + 490. 6±0. 335 + 858±175. 6±0. 39.3+1.0

id/synthetFlow EBasalt1.0 + 0.60. 8±0. 7118 + 5139 + 12. 5±1. 70

11. 2±10.0

51. 6±14.48. 8 + 35.206 + 270. 4±0. 77. 4±3. 9

12. 2 + 1. 93. 1±1. 11. 6±0. 7

Coefficients:

87

ic

9

43

Fiscal

X10~?atm-02)

groundwaterPomona

contactSecondary

Basalt Mineralization00

157 + 4201 ± 400

11.9 + 2. 50

70. 8 + 51. 162. 9 + 0. 9298 + 931. 7 + 1. 63. 4±0. 45. 9 + 1. 75. 7 + 0. 62.0 + 0. 9

3. 3±0. 35. 5 + 1. 2--0079 + 1087±29

415 + 1781814±439278 + 742. 2±0. 83. 9 + 0. 2127 =t 30

8264± 12166108±23

- 65 -


3 3

N. Drndarski, D. GolobocaninRadionuclide Partitioning Coefficients in the Sava River EcosystemJ. Radioanal. Nucl. Chcra., Letters 199 (1) 21-26 (1995)

A USava Ri

H, Eh,Sava RiverCDzK

A d s o r p t ion

Kd

i 4Mn6(1CoMSr9 5 Z r9 i N b

IO3Ru,06R u

l 2 5 S b131 r

mCsi : i7Cs140Ba144Ce" 6 R a228Ac

262112223029402326434740273365

-l.S

Fig. 1. Distribution coefficient |K J vs. concentrationra t io {CR)

- 66


or 700hours, or itil or I)

3 434-1

J.F. Relyea, R. J. SerneWaste Isolation Safety Assessment Program - Controlled Sample ProgramPublication Number 2: Inter laboratory Comparison of Batch KD ValuesPNL-2872, 1979

B

CEC[meq/100g] Jt*ii»[inVg] ttttffi^[weight-*]

OoliticLimestone

Sentinal GapBasalt

B E T E - G l y C O l C a l c i l c C l a y s P l a g i o c l a s e P y r o x e n e s G r o u n d m a s s M e t a l l i c - O x i d e s

4 2 + 1 6 0 .75 5. 6 ± 1 . 7 99 1

4. 7±0. 2 2.5 10. 3± 1.0 44 32 13

. Eh.

S y n t h e t i c pH ^M-i ^ > i t f f i [ m g / l ] (Ca, Mg, Na, K, Sr, Cs, HCO3, S04, Cl, F, B03, Br)L i m e s t o n e Water 8. 0-8. 4 ( 5 0 , 3 .6 , 2 . 3 , 0 .4 , -, -, 153, 14 .4 , 3 .5 , - -, - )B a s a l t Water 7 . 7 - 8 . 2 ( 6 . 5 , 1.0, 3 0 . 0 , 9 .0 , -, -, 58, 23, 16, 0 . 7 , -, - )W1PP B r i n e 6 . 0 - 7 . 0 (900, 10, 115000, 15, 1.5, 1.0, 10, 4190, 175000, -, 10, 400)

( S a l t Water)

250ml, p o l y c a r b o n a t e , s c r e w c a p c e n t r i f u g e b o t t l e

L i m e s t o n e / L i m e s t o n e G r o u n d w a t e rL i m e s t o n e / B r i n e S o l u t i o nB a s a l t / B a s a l t G r o u n d w a t e rB a s a l t / B r i n e S o l u t i o n

ExplExp2Exp3Exp4

SeplSep2Sep3Sep4Sep5

is<k£r i i (16000rpmX60min . ) + Decanta t ion

Decanta t ion

= 15W (PNL fz tf it 2 7°C)(18-24hours)

- 67 -


wses

3 434-2

• C smm ?

ANLAECLLASLLBLLLLORNL-1ORNL-2PNLRHO

• S rmm ?

ANLAECLLASLLBLLLLORNL-1ORNL-2PNLRHO

• Pumm J

ANLANLAECLLASLLASLLASLLBLLBLLLLORNL-ORNL-2PNLPNLRHO

A* y f"

J .F . ReWaste

fit:7days or 700hours, is-i

lyea, R. J. SerneI s o l a t i o n S a f e t y Assessmen

P u b l i c a t i o n NumberPNL-2872, 1979

« » [ m l /

8 f t [mo 1,

6X10"'2X10"'2 X 1 0 ;

5X10"'1 X 10 7

1X10"6

3X10"'

Program -

^ P l t or 'MM o )

Control led Sample Program2: In te r l abora to ry Comparison of Batch KD Values

g] . . . A d s o r p t i o n

/I]Expl

65 + 2 ( - )1. 3 + 0.4(7. 8)88±1 ( - )4 9 ± 5 ( - )60±30 ( - )

227± 14 (8. 2)663 + 61 ( - )880±160( - )6. 8 + 0. 6( - )

• f t [mo 1/1]

3X10"'5X1O"S

2X10"'5X1O"S

1X10"1 X 10s

3X10"'

gfttmol

3 X 1 0 "3 X 1 0 "1 X 1 0 '2 X 1 0 "2 X 1 0 "2 X 1 0 "2 X 1 0 "2 X 1 0 "

X10""X10"'

3 X 1 0 "3 X 1 0 "

Expl5. 4±0 . 3(8.0)1. 8 + 0. 5(7. 6)1.4 + 0. 2( - )2. 4 + 0. 1( - )2. 7 + 0. 5( - )5. 9±0 . 2(8. 3)9. 3 + 2. 4( - )

14. 9 + 4. 6( - )13. 4 + 0. 6( - )

/I]Expl

1027±41 (7.2134 + 77 (7.

547 + 356 (7.4745 + 4931 (8.

32000+11000(8.3198 + 512 (8.

242 + 41 ( -1009+162 ( -770 + 36 ( -198 + 50 (8.

63000±19000( -690 + 320 (7.

1090+120 (7.2616 ±1135 ( -

Kd(End-pH))Exp2

0. 14 + 2 ( - )0. 2 + 0 . 4 (7.4)0 ±0 . 12( - )0. 16 + 0. 9 ( - )0. 5 + 0. 5 ( - )0. 6 ±0 . 3 (7. 2)0. 1 +0 . 3 ( - )3. 3 ±0 . 1 ( - )0. 04 + 0. 03( - )

Exp3401 + 2K - )

31 ± 2 (7.4)265±4 ( - )296±10( - )290±70( - )380 + 5 (8.3)453±12( - )380 + 70( - )255 + 7 ( - )

Kd(End-pH))Exp2

0. 18 + 0.01(6. 5)4. 2 ± 1 . 6 (7. 4)0. 1 ±0 . 2 ( - )0. 1 ± 0. 1 ( - )0. 9 ±0 . 4 ( - )1.0 ±0 . 1 (7. 2)0. 9 +0. 1 ( - )3. 4 + 0. 3 ( - )8. 0 + 1 . 2 ( - )

Exp368+17(8. 1)41+6 (7.4)81±1 ( - )55±2 ( - )45±1 ( - )89 + 5 (8.4)93 + 6 ( - )92 + 3 ( - )73 + 4 ( - )

Kd(End-pH)Exp2

6) 1283 + 89 (6.6) 1457 + 75 (6.5) 69±14 (7.1) 96 + 63 (6.1) 3709 + 2114(6.1) 139 + 31 (6.) 2. 6 + 2. 4 ( -) 130±16 ( -) 450 + 90 ( -

2) 280 + 21 (7.) 1146 + 137 ( -

9) 150 + 20 (7.9) 26O±2O (7.) 235 + 25 ( -

Exp36) 8.8 + 3.46) 6 7 ± 1 45) 1OOO±59O6) 1078 + 716

Exp41. 48±0 . 05( - )

1.4±0. 4 (7. 3)0. 6±0. 2 ( - )

1. 52 + 0. 04( - )1. 6±0. 1 ( - )2. 2 + 0. 2 (7. 2)

1. 79±0. OK - )4.6 + 0.3 ( - )

0.95 + 0. 13( - )

Exp40. 0 5 ± . 005(6. 7)

2. 9 + 0.4 (7. 3)0. 2 + 0. 2 ( - )0. 1 + 0. 1 ( - )0. 0 ( - )0.7 + 0.3 (7. 2)0. 4 ± 0 . 1 ( - )3. 6 + 0. 8 ( - )

0. 23 + 0. 02( - )

Exp4(7.5) 1304 + 222(7.5) 1280±188(7.5) 221 + 140(8.0) 294 + 80

6) 13000 + 8000(8.0) 12000 + 30006) 843 + 658

) 30±26) 221 + 147) 580+12

2) 592± 134) 312 + 66

2) 15±22) 200+170) 89+17

(8.0) 256±19( - ) 271 + 156( - ) 2473 + 1506( - ) 1260 + 504(8.2) 2056±1405

mmSeplSep4Sep2Sep4SeplSep4

Sep3Sep4

mmSeplSep4Sep2Sep4SeplSep4

Sep3Sep4

(6. 5)(6.5)(7.3)(6. 7)(6.7)(6.7)( - )( - )( - )(7. 2)

( - ) 37000±41000( - )(8.6) 22O±3O(8.6) 430±60( - ) 73 + 20

(7.2)(7. 2)( - )

7d7d7d7d7d7d

700hr7d7d

mmmm7d7d7d7d7d7d

700hr7d7d

ft-81/Sc

SeplSeplSep5Sep2Sep5Sep2Sep5Sep5SeplSepl

7d7d7d7d7d7d7d7d7d7d

Sepl 700hrSep5SeplSep5

7d7d7d

- 68 -


3 5

K * B

m

%.

A'U•

tfeT•

-to:••••

233

IT,

24

24

*(ftB : 6 days,

B. Al l a r d . U. O l o f s s o n , B.S o r p t i o n of A c t i n i d e s i nM e d i aS c i e n t i

7timWyoming

CEC ;

SynthetTotalTotal

S i x 25

fie Basis for Rad

Bentonite MX-80750-800meq/kg

3H, Eh, * # > r * > * s .ic GroundwaterSalt ; 306mg/l

TorsWei

ioac

^ ^ S / 2 7 0 0 0 G / 6 0 m i n )

t e n f e l t , R K i p a t s i and K. Ander s son1 -de f ined O x i d a t i o n S t a t e s on G e o l o g i c

t i v e Waste Management V, 775-782, 1982

mMm&r&. swiaaa*. -r^>^^§*, as . my^m)( m o n t m o r i 1 l o n i t e )

Carbonates ; 123mg/l

±1°C, pH 8. 5PolypropyleneMTtLtk 233U; LSC ^©f t t

Th, Pa, U, Am ;Np, Pu ;

] . . . Adsorption

Mit= 20m 1/0. 2g

T hT hP aUN pN pP uP uAmAm

* ) » ! « « [D.ol/1]

3. 0X10"7

2. 5 x 10"9

4 . 0 X 1 0 "2. 1X10"7

1. 9X10 7

1. 9X10"'6. 0X10"8

6. OX 10 l0

2 .9X10 7

2. 3X10"9

,; r ?Air

Kd

220022002000

360270390

1700170022002300

- 6 9 -


3 6

B

- ^ U - X N o . 13> NIRS-M-65, 61-68, 1987

H, Eh,

... Adsorption

Drop)

58034

21081

13020022

10

H . B e , C , N a , C l , A r , K , C r , M n , F e , C o , N i , Z nS e , K r . R b , S r , Y . Z r , N b , M o , T c , R u , P d, A g ,C d , S n , S b , I, C s , B a , C e , P r , S m , E u , H o , T l ,P b , B i , P o

"A gm B a141C e" C o51C r

134 C s5 9 F e54Mn

101R u113S n6 5 Z n

4000200

200050

100050070020

8001000300

2100420

1200360

—300

250060——27

- 70


»l£fc

3

B

ffl

fr

7

B. Tor;

•m(&w :

t e n f e l t,Transport of AcScien

/V)7tt<LS o i l - AS o i l - BS o i l - C

i f i c Bas i

WyomingWyomingWyoming

: ( P H . Eh. ft}

6 days, j |

H. Kipatsi ,

i>L^H/27000G/60min)

K. Andersson,t in ides through as for Radi

BentoniteBentoni teBentonite

• S y n t h e t i c G r o u n d w a t e r (pHSG-SG-SG-

rgE^Dnl,

1 ; T o t a lI ; T o t a li ; T o t a l

j 85Sr, 134Cs233U, " 7 N p ,

CarbonatesCarbonatesCarbonates

"4Th, MJPa"9Pu, Z4'Am ;

/g] . . . A d s o r p t i o n

oact ive

MX-80MX-80 +MX-80 +

- 8. 2,

BentonWaste

15KFe3(]

0. 5%Fe

T o t a l= 123mg/l= 600mg/l

B. Al l a r d and U. O l o f s s o ni t e B a c k f i l lManagement V, 659 -668 , 1982

3 0 4 ) z

S a l t = 306mg/ l )

= 123mg/l + 10mg/l-Humic Acid

* $t@r-t = Water(20-25ml)/Clay(0. 5-1

7zm

S rC sT hP aUU

uuuN pPuAm

±mS o i l - AS o i l - AS o i l - AS o i l - AS o i l - AS o i l - AS o i l - AS o i l - BS o i l - CS o i l - AS o i l - AS o i l - A

mmSG-1SG-1SG-1SG-1SG-1SG-2SG-3SG-1SG-1SG-1SG-1SG-1

tmmB1. OX1. OX1. OX1. OX1. OX1. OX1. OX1. OX1. OX1. OX1. OX1. OX

, S N a

y^v-

. 0g)

ELmoI/l

10""10"'"10 14

10"13

10"'

io-"10"8

10"8

10 8

10"'J

10"9

lO9

KTDttWS

] Kd

2900140060005000

93————

12035006600

- 71 -


scm3 8

S. C. Sheppard and W. G. EvendenThe Assumption of Linearity in Soil and Plant Concentration Ratios: AnExperimental EvaluationJ. Environ. Radioactivity, 7, 221-247, 1988

A

Peat (Parent Material: Sphagnum Moss)Bulk Density 110 kg/nf Moisture Content 5 I/kgpH(in a slurry with distilled water) 4.8Exchangeable Cations (3. 9gCa/kg, 2. 5gMg/kg, 0. 15gK/kg)Chelate-extractable Cations (0. 27gFe/kg, 0. 09gMn/kg, 0. 08gZn/kg)Ex tract able P (0. llg/kg)5 7C^(I. Se, Cs, Pb, U)tIO^T&20-tf>7°;i^)5L ^n^tl^^itm£§I('"I£0-100mg/kg), Se (ni"Se£0-600mg/kg), Cs (mCs£0-600mg/kg),Pb(n"Pb^0-10000mg/kg), U(M1US:0-10000mg/kg)

Eh.Pore WaterComposi t ion[mg/l](Na, K, Mg, Ca, Fe, Cl, N(L, SO , HC0,) = (17, 15, 37, 60, 0. 5, 80, 15, 5. 9, 24)

AE[ I, Se, Cs (Neutron Activation/Gamma Spectroscopy)Pb (Inductively Coupled Plasma Spectroscopy)U (Neutron Activation/Delayed Neutron Counting)

... Desorption

I S e C s P b U

137 ( 9) 105 ( 5) 20 (16) 9000 (40) 180 ( 8)49 (18) 110 (18) 94 (16) 1300 (14)

310 (17) 160 (16) 1400 (15)230 (14) 170 (15) 1300 (13)

- 7 2 -


3 9

D. H. Denham, D. A. Baker, J. K. Soldat and J. P. CorleyRadiological Evaluations for Advanced Waste Management StudiesBNWL-1764, 1974K. J . S n e i d e r , A . M . P l a t t : H i g h - L e v e l R a d i o a c t i v e W a s t e M a n a g e m e n t A l t e r n a t i v e s ,B N W L - 1 9 0 0 , 1 9 7 4

B

T y p i c a l w e s t e r n d e s e r t s o i l o f USAS a n d (CEC 5 m e q / 1 0 0 g ) t o S a n d y L o a m (CaCOs l m g / g . pH 7 . 0 - 8 . 2 )

Eh,Typical nonsaline groundwater

pH Concentration[ppm] (SO*, NO:,, Cl, HCO3, Na, K, Ca, Mg)6.8-8. 2 ( 15, 1, 8, 125, 20, 5, 25, 5)

E s t i m a t e d e q u i l i b r i u m d i s t r i b u t i o n c o e f f i c i e n t s b e t w e e n w a t e r a n d s o i l

"KM Kd 7tM Kd 7U^ Kd

3HB eCNaC 1A rKC aF eC 0N iS eK rRbS rYZ r

0752100035151507580200

12520

20002000

NbMoTcPdCdS nS bIC sPmSmE uHoT 1P bB iP 0

200050

2502000250150

2006006006006002

40001025

A tRnF rR aAcThP aUNpPuAmCmB k

00

2001001000150004000300015

20002000600700

- 73 -


&

4 0

D. J. Brown"Migration Characteristics of Radionuclides Through SedimentsUnderlying the Hanford Reservation", Disposal of Radioactive Wastes inthe Ground, Proceedings of a Symposium, Vienna 29, May-2, June 1967,International Atomic Energy Agency, pp. 215-228, 1967

A'UUnconso1i da ted Sediment (Pasco Basin, Hanford)

fluvial, glaciofluvial, lacustrine sediments

(PH, Eh,Groundwater

soi l bed (sediment 5g, length 3cm, 0. 15 M Ci/g-90Sr,0. 43^Ci/g- l 3 7 Cs) , 50 column volumeCOGroundwater£i§zM!£, $column volumeWGroundwater^rjlTk

; so i l (non-RI), solution(10"VCi/cm'-^'Sr or -l37Cs)

K d ( S r ) = 50K d ( C s ) = 300

- 74 -


A< ( f i l c h ? : 1 4 d a y s / 2 8 d a y s , j f i i®/0 . 4 5 ^ m ; m e m b r a n e or D e c a n t a t i o n )

4 14 1 - 1

m [m] [g/cm3]5-10 1.195-10 0.92

btmmm CEC[mVg] [meq/lOOg]10.96 4 .671.30 18.7

EXC - Ca, Mg, K[meq/lOOg] [weight-X]

75.2 45.1 5.95 <0. 05279 58. 4 5. 90 <0. 05

SiO2 AhOs Fe2O3 FeO MgO CaO Na2O K20 P;O5 S C63. 20 13. 05 2. 79 1. 64 0. 40 0. 64 0. 23 0. 35 0. 02 0. 12 0. 28 3. 1637. 47 22. 88 8. 02 1. 30 0. 34 0. 62 0. 22 0. 10 0. 08 0. 08 1. 01 15. 70

No. 1No. 2No. 3No. 4No. 5No. 6No. 7

i . Eh.

m fflJffli

No. 1No. 2No. 3No. 4 jjNo. 5 INo. 6 INo. 7 1

A

[mg/1]2.98. 82.7

18.91.93.04. 3

[mg/1]2.02.81. 62. 11. 51. 81. 7

[mgtth/l]3. 5

21. 93. 9

61. 61.54. 59. 5

4. 2-5. 37. 3-8. 54. 2-5. 37. 3-8. 5

29

11

Mg4. 27

12. 52.06

15.430.4

1.720. 16

Ca15.040. 7

3.528.258. 1

2.770. 26

Na6.44

19. 34. 31

26.07. 696.91

15.0

K<0. 10<0. 10

0. 270. 912.860.340. 15

Al<0. 20<0. 20<0. 20<0. 2031.8<0. 20

1. 18

Fe<0. 10<0. 10<0. 10<0. 10

6.36<0. 10

0. 51

Si4. 757. 195. 75

18.446. 7

4. 394. 29

P<0. 70<0. 70<0. 70<0. 70<0. 70<0. 70<0. 70

SOr56. 8

12915. 589.5

70415. 014. 1

C l "4. 7

31. 22. 1

28. 12.92. 52. 2

HCOf1. 7

191. 6

81<0. 1

2.59.4

ICPC15°C

: 5013/min• pH, E L EC,

- 7 5 -


4 141-2

• u?

mNo.No.No.No.No.No.No.No.No.No.SiSiNo.No.SiSi

2) mmm.No.No.No.No.No.No.No.No.No.No.No.No.No.No.No.No.No.NoNoNoNo.

^ ^2222444444tt44tt

lllllllllllllll222222

)( )Wc

Kd1700015000

372304

221910132831

2012404348

341411

ml/5g. tKd

400005700

99000400009900049000

45009800

200001200036001800150091001100

170008000

20000130063007000

t o : 14days/28days, ill

Adsorptior

mmmmmmmmmmmmm.mm

ummmm^mm

Dent(3h)mm

Dent (24h)m.mmm

Dent (3h)m.m

Dent (24h)mmmm

Dent (3h)mm

Dent (24h)mmmm

Dent (3h)mm

Dent (24h)m.mmm

•7 — > nazzm

1

=140, m.mU if! Jit; [ppm](20) 0.011(20) 0.013(20) 0. 50(20) 0. 61(20) 6. 1(20) 6. 5(20) 9. 8(20) 8. 5(10) 2.7(10) 2. 5(10) 0. 50(10) 0.42( 2) 0. 40( 2) 0. 36( 2) 0. 060( 2) 0. 050

1=280, mmU y l ^ [ p p m ](20) 0. 005(20) 0. 035(20) 0.002(20) 0. 005(20) 0.002(10) 0.002(10) 0.022(10) 0.010(10) 0.005(10) 0.008( 2) 0. 005( 2) 0.010( 2) 0. 012( 2) 0. 002( 2) 0. 017(20) 0.012(20) 0. 025(20) 0. 010(20) 0. 015(20) 0. 032(10) 0.015

jfi/0. 45

Sftfti

PH6. 86. 87. 67. 16. 97.07.97. 17. 17. 17.47.47. 17. 37. 57. 5

PH5.55. 55.65. 65.75. 65.65. 75. 75.85. 55.55. 65. 65. 87. 67. 67. 57. 57.36. 2

Mm;membrane or Decantation)

It

Eh[mV]183207210157186196233168159193265254215216258263

Eh [mV]234234240240228237237249249233238238254254229217217240240255232

EC U S / c m ]387377392375370389382373367384441432364373458432

EC[/iS/cm]165165166166162157157161161161153153158158155384384392392384390

DO [ing/1]9. 29. 27. 68. 08. 59. 28.08. 18. 77. 68.47. 58.68. 58. 37. 8

DO [ing/1]8. 08. 08. 08. 08. 08.08. 08. 18. 1C 10. 0

8. 38. 37. 87. 88. 18. 78. 78. 58.58. 88.0

- 76 -


(Mto : I4days/28days, jttjtfl/O. 45/ / m; membrane or Decantation)

4 141-3

. . . Adsorption2)$ft@Jt=50ml/5g,

H&# KdNo. 2 4800No. 2 3700No. 2 1800No. 2 1700No. 2 1400No. 2 1000No. 2 2100

5g.Kd

49000130000330000200000

180017001600150035003100

• 5g,Kd1270150

150563417613057117

329046234951113542321262525

D.

No. 1No. 1No. 1No. 1No. 2No. 2No. 2No. 2No. 2No. 2

No. 3No. 3No. 3No. 3No. 3No. 3No. 3No. 3No. 3No. 3No. 3No. 3No. 4No. 4No. 4No. 4No. 4

Dent (3h)Dent (24h)

Dent (3h)

i=28s, mm%U M C p p m ](10) 0.022(10) 0.028(10) 0.058( 2) 0.012( 2) 0.015( 2) 0. 020( 2) 0.010

pH EhQnV] E C O S / c m ] D 0 [ m g / i ]6. 26. 36. 47. 07. 06.96. 9

232219227201201191210

390366364366366368361

H4B,

(20)(20)(10)(10)(20)(20)(10)(10)( 2)( 2)

pH Eh[mV] EC U S / c m ] DO [ing/1J0. 0400.0150. 0030.0051. 0501. 1200. 6300.6380. 0580. 065

7. 27. 06.97.06. 76. 86. 86. 96. 96.9

222222185170154154152185212222

U M t p p m ](20) 0. 16

Dent (3h)

Dent (24h)

Dent (3h)MM

Dent (24h)mm

Dent (3h)Dent (24h)MM

Dent (3h)mm

Dcnt(24h)mm

(20)(20)(20)(20)(10)(10)(10)(10)(10)( 2)( 2)(20)(20)(20)(20)(20)

1.20. 130. 310. 110.0320.780.0300.210.0280. 150. 0506. 26.45. 75. 75. 8

PH6 . 06. 06. 16. 16. 26. 36. 36. 36. 36. 56. 56. 67. 17. 17. 17. 17. 1

56574647

342348350363356345

Eh [mV]272272258258266257257232232247245248193193179179184

8. 99. 39. 19.49. 39. 29. 29.09. 39. 2

EC[juS/cm]686869697263636363645760

363363365365369

8. 07. 67. 78. 08. 07. 37. 9

DO [rag/1]7. 97. 98. 28. 28. 38. 08.07. 97. 98.48. 68. 3

7. 97. 9

- 77 -


-5 :14days/28days, . 45 Mm; membrane or Decantat ion)

4 141-4

D

A d s o r p t i o n4)S£@Jt=50ml/0. 5g,

UMfo KdNo. 4 28No. 4 28No. 4No. 4No. 4No. 4No. 4No. 4No. 4No. 4

No. 5No. 5No. 3No. 3No. 6No. 6No. 7No. 7

U « £ [ p p m ] pH Eh[mV] EC U S / c m ] DO [nig/1]

3231304341475148

Dent (3h)MM

Dent (24h)

Dent (3h)

Dent (24h)MM

(10)(10)(10)(10)(10)( 2)( 2 )( 2 )( 2 )( 2)

2.72.82.52.52.60.400.420.360.350. 36

Kd0.420.49

3088308827761773

10672

224499

11

U(10)(10)(10)(10)(10)(10)(10)(10)

Cppm]9.49. 30. 0300. 0300. 0320. 0500. 841. 2

7. 17 .17. 17 .17 .27. 17 .17 . 37 . 37. 3

pH2. 62 .66 . 45. 76 . 46. 59. 29. 1

159159193193210215215216216229

Eh[mV]577577295203208220192201

367367384384365364364373373336

EC[/iS/cm]16611673757688839091

8. 78.77. 67.68.78. 68.68.58.58. 7

DO [ing/1]9. 79.49. 39. 09. 19. 19. 18. 9

- 78 -


4 2

B

m

*

K. Bsrci, J. Deak, V. Friedrich, E. HazSafety Assessment and InvesFaci1i ty in Hungary

tigations

Proc. of a Symp. on the Management ofactive Wastes 1988, Vol. 1,

• Concrete ... 350-PPC-10 (Port

163-178,

land type

, J. Juhasz, E.Maleczki, A.Mojzesfor a Shallow Land Disposal

Low and Intermediate Level Radio-1988, IAEA-SM-303/145

with 10% fly ash), w/c=0. 5,g/c=4. 76, <2mm (7days concrete was crushed and pulverized.)

• Loess/Sandstone• Clay

iftTzK ttfoH. Eh, mi*>m&. us• Tap water (with 5MBq/ml)• Deionized water (carrier free, high salinity solution)• Groundwater model (carrier free, high

• Ge(Li)-Detector

^•SS#^[ml/g] ... Adsorption

• Concrete + Tap wateri £ @ J t l37Cs 58Co 125I

2:1 3 1194:1 26 532 0.37:1 32 582510:1 33 3137 1.4

• Soi sampleDeionizedCs Co

Carrier freeLoess/Sandstone 4700 1430Clay 4200 2300

High salini ty solutionLoess/Sandstone 6. 9 0.4Clay 5.0 0.7

8iSr

48275352712

waterSr

186352

0. 20. 3

salinity solution)

Groundwater modelCs Co Sr

1550 1140 353760 1730 51

1.8 0. 6 0. 35. 0 0. 9 0. 6

- 7 9 -


($Ht: 1 day/1 week/2months, flfl or j

4 343-1

B. Torstenfelt, R. S. Rundberg and A. J. Mi tchel 1Act inide Sorption on Granites and Minerals as a Function of pH andColloids/PseudocolloidsRadiochimica A d a 44/45, 111-117, 1988

A

Grani te (Stripa, Finnsjon, We s t e r l y ) , Hornblende, Albite, Anorthite,Microcline, Bentonite, II liteCrushed and sieved, the size fraction 0. 106-0. 250mm was collected, thenwashed with distilled water.

Eh,Natural groundwater (J13-groundwater; pumped from drilling hole J13 atthe Nevada Test Site, Nevada, U.S.A.)Chemical composition : pH(in situ)=7

Cations Concentration[mg/l]Li 0.06Na 45Mg 1. 76Al 0.02Si 31.8K 5. 3Ca 11.5 0* 5.7Mn 0. 01Fe 0. 01

nionsFClS04HC03

NOs

Concentration[mg/1]2. 16.418. 114310. 1

25ml/0. 5gjfF^TrOflSfJc^ft (fSttBvfP^: 1 day, lweek, 2months)OTD-65 Ul t racent r i fuge /swinging bucket ro to r /4 . 5ml tube

0 - 1 2B#rm^S (111 i t e, Bentoni te&RfcOO-2 jH'O#-8i(8000-10000rpmX8-10minutes) . . . II1 i te, Bentonite2) ]S 'L^^I(20000rpmX 1. 2hours)3) jS 'L^H(60000rpmX 2. 3hours)

•The size of particles removed from solution [nm]C. speedtrpm] C. time [mi n] Grani te (2.65g/cm3) Hemati te(5.2g/cm3) Polymer (9. Og/cm3)

8000 5 77 48 358000 7 65 41 2910000 10 44 27 2020000 72 8. 1 5. 1 3. 740000 138 2.9 1.8 1.342000 138 2.8 1.8 1.350000 138 2.3 1.4 1.060000 138 2.0 1.2 0.9

- 8 0 -


(#g:lday/lweek/2months, or

4 343-2

B. Torstenfelt, R. S. Rundberg and A.J.MitchellActinide Sorption on Granites and Minerals as a Function of pH andColloids/PseudocolloidsRadiochimica A d a 44/45, 111-117, 1!

Adsorption

?K»

0 11.000(jpnO

P%. i. Uftmum torpiioo on Strips (n

•0.000

• ' '

I-f

*«pM 11.1

« 30.000 iO.ooo t«,oooIrpm)

V"™

0 20,000 40.000 00,000O»rti

F«. 3. Urifliun: mption «n ilblx

so

• " » M :

0 20.000 40.000Irtrn)

Ffc. 4. Urantvm

•DH 7.18

SO

20.0CC 4&.0D0 «0.O0C

iiam mptiofi «n mKMdint.

4 0 3

MO

100

0 - i

A

4*»H I.T -

Ff. (. UJiiUom isrptoi on t

0 W.000 40,009 MvMO

Fl(. 7, Urtnfciai tw^il*) «• itht.

- 81 -


(M:lday/lweek/2months, or

4 343-3

B. Torstenfelt, R. S. Rundberg and A. J. MitchellActinide Sorption on Granites and Minerals as a Function of pH andColloids/PseudocolloidsRadiochimica Acta 44/45, 111-117, 1!

m

MO

too

100

•

• •<* 1.M- • • !*<«.*

* - D « 10.1

-

•

.. Adsorp

- -

0 10.000 40.000 «0,OOOIrani

ion

F«. 1 Ncpuinum uipmt on Strip cwW-

W 9 I.

toor >

0 20.000 44.000 «0.000

. NeprenWm wsc^Uon en Finntj

JO.OOO 49.000(run)

-11 . Ntynnitnti ttf*(l«D

aao

100

100

A i -

-

5

1-S

A *•

10.000 W.OC0 «0.CO0 4Q.D0O(rpn)

t'H. I t N«(aooiutB xxptiiui en iltin.

i-too

0 •

i

ft' ' '*

* • "1 1 y

JB.OCO 40.000 «.K>0

«. 13.

c ioxioo *o.ooo eo.oco

F^-14. N^ptiiniwn aorptipn oa

400

100• • "!

•jo n.ooo 40A00 00.000

. 1^ Ncplunimn nrptkH Mt i

- 8 2 -


ii: lday/lweek/2months, or

4 343-4

B. Torstenfelt, R. S. Rundberg and A. J. Mitchel 1Actinide Sorption on Granites and Minerals as a Function of pH andColloids/PseudocolloidsRadiochimica A d a 44/45, 111-117, 1988

Adsorption

IOC

100

too

n

*

*

• -pH 2J» "

I t 'o K . 0 0 0 40,000 so.ooa

F<|. 11. rtutuikun MtptiMaon Suip* pinitc.

MO

t »

100

so

0

1

A

h •

T

A*

* . p H 7.« -A . P H 1 M

i • 1

Fif. 21.

20.000 40.0*0

o

<<*">4M0Q BO,«H3 o

. Plutonium

2C.000 40,000 00,000

B J

J100

SO

e 2tUK»trpn)

It.* •

Hrly jnnite,

0 aOSOO 40.AM 10.000

<fpmJ

P^. 22. Ffailonoiin l

DO

H

DO

50

0

*

-

D

*

•

1 t10.000 *<X000

Inn)

•

•

S 3 ' - '

-

•eo.oco

900

f *ao

c

-

0t 1

90,400 40.000Irem)

• -pH t.t"

BO.OOO

Pig. 30. nuHHiiuni tmpiwa on homblmli Fij 34 ftuwrrium lorpiwit on bcntiwiilc.

0 » W 40X100 «0.0OI

- 8 3 -


3cm

4 444-1

m

*

nv*m mmJ. L. SwansonEffect of OrganRadionuclides iPNL-3927, 1981

g<^:150cycle

ic Complexants on then Soils: Status Repor

• Hanford soi1 (calcareous, sandy 1pH=~8. 2, 75-150(^500) Aim

±feTzK!$:'t£(pH, Eh. Pil• Distilied water +

• Air-equi1ibrated• Gamma count ing('S2l

?-f*>aa. fift«

oam)

Na2EDTA. 2H*0 or DTPA

solution, 21*C:u,'"Cs, 85Sr, 60Co), beta

• Screw-capped polypropylene cent150 cycles/min ;

• Fi11rat ion(2nm fi

Eu (Adsorption)

held horizontaHer) + Centri

Eu m & Na2EDTAiiS Steffiffl[mol/1] [mol/1] [days]

2. 7E-7 0. 08. 6E-8 4. 5E-78. 6E-8 4. 5E-78. 6E-8 4. 5E-78. 6E-8 4. 5E-72. 7E-7 4. 5E-62. 7E-7 4. 5E-62. 7E-7 4. 5E-68. 6E-8 4. 5E-58. 6E-8 4. 5E-5

4. 5E-64. 5E-64. 5E-54. 5E-54. 5E-54. 5E-64. 5E-64. 5E-64. 5E-6

3112253970152828122515427142271413

rifuge

Mobilt

It)

ity of Low-Level Waste

or humic acid

counttube

ing(63Ni)Reciprocal

lly ; half-fullfugation

mmtt[ml/g]

3030303030303030303015015033330303030

PH

7. 98.48. 18. 1

8.08.08.08.48. 18.07.98. 48. 38.28.58. 38.88.7

[Mm]

<500<500<500<500<500<500<500<500<500<500<75<75<500<500<500

150-500150-50075-15075-150

ing shaker ;

Kd[ml/g]

100000120002100028000100000

120014001500110903205202002803301100110080180

- 84


xm4 444-2

J. L. SwansonEffect ofRadionuclPNL-3927,

5^@H^^c[ml/g]Eu(Adsorpt ion)

Organicides in1981

Eu M& Na.EDTA«g[mol/1]

Eu(Desorpt ion)2. 7E-72. 7E-72. 7E-72. 7E-72. 7E-9

Ni (Adsorption)Ni itkfx. Na[mol/1]

1. 1E-71. 1E-51. 1E-51. 1E-71. 1E-71. 1E-71. 1E-71. 1E-71. 1E-71. 1E-71. 1E-71. 1E-7

Ni (Desorption)1. 1E-71. 1E-71. 1E-71. 1E-71. 1E-71. 1E-71. 1E-7

[mol/1]

4. 5E-64. 5E-64. 5E-64. 5E-64. 5E-6

4. 5E-64. 5E-64. 5E-64. 5E-54. 5E-5

ILJU 1 Af/pc /-3i

[mol/1]

0.00.00.00.01. 0E-61. 0E-63. 0E-63. OE-61. 0E-51. OE-53. OE-53. 0E-5

1. OE-51. 0E-51. 0E-51. OE-51. 0E-51. 0E-51.0E-5

- - 5 : 1 5 0 c y c es/nun,

C o m p l e x a n t s on t h eSoi I s : S t a t u s Repor

: rnmmrn[days]

7147

1423

1528282725

i mmmm[days]

37

2055

8146

177

146

17

363

316691021

mm it[ml/g]

3030303030

3030303030

[ml/g]

100100100100100100100100100100100100

100100100100100100100

Mobilt

PH

8. 58. 38.58. 18. 2

8.07.98.07.98.0

PH

9.27.88. 58. 18. 98.79. 18.77.88.69.08.6

8. 88. 28.6

8. 1

8. 1

ity of Low-Level Waste

[Mffl]

75-15075-150

<75<75<75

<500<500<500<500<500

mm[fin]

75-15075-15075-15075-15075-15075-15075-15075-15075-15075-15075-15075-150

75-15075-15075-15075-15075-15075-15075-150

Kd[ml/g]

900980

220033005000

130013001200

70110

Kd[ml/g]

950071004300

12000210019001801801301206452

5200260

33001200300

23001500

- 8 5 -


4 444-3

mm iI. L. SwansonEffect oRadionucPNL-3927,

^•SH^ictml/g]Cs

Cs mm N;[mol/1]

1. OE-81. OE-7. OE-7. OE-7

cs mm[mol/1]

. OE-7

Sr

sr mm N<[mol/1]

3. 9E-75. 9E-63. 9E-7

sr mm[mol/1]

3. 9E-74. 1E-6

Organicides in1981

: o :150cyc

Complexan

es/min,

ts on theSoi I s : Sta tus Repor

. . . Adsorption

isEDTAiUls[mol/1]

0.00.09. OE-53. 3E-3

DTPA»S[mol/lf

4. 5E-4

hEDTA/M[mol/1]

0. 00.09. 0E-5

mvhmm[mol/lf*

1. OE-45. OE-4

[days]

7777

[days]

7

[days]

777

[days]

77

[ml/g]

30100100100

[ml/g]

30

TO ft[ml/g]

10030

100

mmit[ml/g]

10030

MM

Mobilt

PH

9. 08. 58. 45. 1

PH

7. 8

PH

7. 76. 37.6

PH

8.47.8

m)

i ty of Low-Level Waste

[wm]

75-15075-15075-15075-150

n%[win]

75-150

[win]

75-15075-15075-150

lz?I[wm]

75-15075-150

Kd[ml/g]

14000740055002000

Kd[ml/g]

8700

Kd[ml/g]

18016

180

Kd[ml/g]

18058

- 8 6 -


(

E. R.Graham and C. G. SilvaLabile Pools and Dist r i b u t i o n Coefficients for Soil Calcium, Magnesium,and P o t a s s i u m Determined with Exchange E q u i l i b r i a and RadioisotopesSoil Sci.. 128(1), 17-22, 1979

Clay(soi 1 from the uplands of Missouri)Depth 0-15cm, air-dried and crushed to through a 10-mesh/2. 25cm screen

. Eh,0. lM-SrNOs s o l u t i o n

f5g/10ml, 50ml screw-cap centrifuge tube"K and 45Ca were equilibrated overnight, "Mg was equilibrated 20min.Centri fugat ionWell-type Nal ... 42K and "Mg / Liquid scint i I lat ion ... 4iCaAtomic absorption ... Stable K, Mg and Ca

... Adsorption

Soil No. pH CEC[meq/100g] Kd(Ca) Kd(Mg) Kd(K)

123456789

10

5. 7 '5.36. 24.66.36.35.35.56.05.9

2. 95. 66. 98. 1

14 .917. 216. 21 9 . 019 .82 2 . 6

1. 22. 01. 33.34.86. 75. 67.68.99.8

1. 62.03. 62.03. 26. 43. 63. 85.46.4

2. 03.44. 05.07.47.68.06. 89.08. 6

-87 -


4 6

m

&

3k

AUCode

MUS

BUR

RITZ

Fl

F2

F3

HF-A

HF-B

ID-A

ID-B

ID-C

ID-D

ffi ( Ie] i£lSt '5 :250rpmX50days.

J. C. Sheppard

Determ inat ion of D i s t r i bu t ion Ratios

Neptunium, Americium and Curium in

RLO-2221-T-12-2, 1976

7tt(DSoil

S i l t

Loamy

S i l t

Sand

Sand

Sand

Sandy

Loamy

Loam

Sandy

Loamy

Sandy

Sc

ffl.fi

&

and Di ffusil

Class Locat ion S a n d [ l

Loam Muscat ine, 111 ino i s

Sand Richland, Washington

Loam Richland, Washington

Barnwel 1, S. Carol ina

Barnwel 1, S. Caro l ina

Barnwel 1, S. Ca ro l ina

Loam Richland, Washington

Sand Richland, Washington

Idaho Fal 1, Idaho

Clay Loam Idaho F a l l , Idaho

Sand Idaho F a l l , Idaho

Clay Loam Idaho F a l l , I d a h o

(PH. Eh. a # - r * > a s . umm)• Radioisotope solut ion(1 Oml, 0. 25 At Ci)

)ftH• 50ml pol

• S

12.

76.

32.

91.

91.

94.

65.

83.

42.

60.

83.

49.

+

ycarbonate v ia l , l g ( a i r - d r i e d 5

i s u r f a c e b a r r i e r p a r t i c l e d e t e c t o r

g] . . . Adsorption

S o i l Code Kd(Z41Am) KdC37Np)

MUSBURRITZ

FlF2F3HF-A

HF-B

ID-A

ID-B

ID-C

ID-D

4830 127

714 15.4

971 20.2

476 33. 8

417 37.2

249 32.4

125833

3920

43500

37000

10900

6

0

0

2

6

6

2

6

6

4

4

2

Di

oi

-Aquat ic

S i l t M

65. 8

21. 2

56.0

7.8

5. 4

1.6

29. 0

12.6

39.4

19.4

8.8

28.4

s t i l l e d

l ) /20ml

Kd (244Cm)

1330106704

185018501240

500

ion

rpm/3

Coef

Envi

• ~

3 m in

f i c i

ronment

C l a y M pL

21.

2.

12.

1.

3.

3.

5.

3.

18.

20.

7.

22.

6

8

0

0

0

8

8

8

0

2

8

4

water

5.

8.

6.

4.

6.

5.

8.

8.

8.

8.

8.

7.

)

e n t ss

i, at

Of

i. mCEC[meq/100g]

3

1

5

0

7

2

1

4

3

4

4

7

( 1 0 m l )

16.

5.

10.

2.

1.

0.

6.

4.

15.

10.

6.

18.

88

94

76

01

79

69

14

95

04

44

38

36

SOOrgtt)

3.

0.

0.

1.

0.

0.

0.

0.

0.

0.

0.

0.

61

43

84

19

99

21

45

17

60

18

16

98

- 88 -


4 747-1

J. Bel 1 and T. H. BatesDistribution Coefficients of Radionuclides between Soils and Groundwaters and Their Dependence on Various Test ParametersThe Science of the Total Environment, 69, 297-317, 1988

A UMoisture Content [X] CEC[meq/100g] Size[mm]

Clay (Glacial Till) 16 2. 3 <=5Fine Sand 7. 3 0. 8 <=5Gravel Sand-1 5. 8 3.0 <=5Gravel Sand-2 3. 1 2. 7 <=5Gravel Sand-3 6. 2 2. 9 <=5

Borehole water(spiked with radionuclides), Se1lafield and Drigg sites.Ion Cone, [ppm]Na K Ca Fe Mg Cs Sr Cl NO., SO, C03 PO4 Org. C26 1 38 <0. 2 9 <0. 1 0. 1 54 12 30 78 <0. 1 0.8

Eh [mV] pH200 5. 7

Act ivi ty[Bq/lOml]l06Ru m C s 8 i S r " 9 Pu+ ! 4 0 Pu 228Th "3U1667 16670 1667 167 167 167

20ml vial, lg/lOml, gently agitated continuously at 15°C, pH=6

.. AdsorptionSoil 8iSr l06Ru 137Cs "8Th "3U 239Pu

Clay 50 800 7500 24000 46 7600F. Sand 9 5 1700 280 560 340G. Sand-1 40 490 3800 5800 46 1800G. Sand-2 30 82 2600 280 900 80G. Sand-3 8 34 2800 5800 2200 32

89-


fflfe&i

scm4 747-2

A" V ^

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£ (St-

and T. H.

5 : Hdays,

BatesD i s t r i b u t i o n C o e f f i c i e n t sw a t e r sThe Sc

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t

a

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• " V

<. E aContaci tirn*

I 10, IVt. )tl.

m « •

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—— —7

» 12 - .tdoyi)

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J^ll/2500rpni/10niin)

Radionucon Various

Envi ronment,

, /Ku

Th

J

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•

•

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i

j|1

j

-:

1

ides between SoiIs and, Test Parameters69, 297-317,

we

r

! t nXh /

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1o

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/ : / ,e—5—r

ru) H

RtliHPWM r

13,000- ,

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1,000

1

i1

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1988

\

pH

•trlkwtlM e*ii* **. k

Htfp 1*10, t?"C, M H I

i

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i t IDpH

Ground-

•

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JAERI-Data/Code 2(X) 1-005

4

4k

w

ft

Fi

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/^y^tiz (iSI£ o :4-6weeks, M.'bftWk or

J. A. Berry, P

M ) te<£

J. Bourke, H. A. Coates, A. Green, N. L.A. K. Li 11 leboy and A. J. HooperSorption ofRadiochimica

A*'J7*J©«3a{t

Radionuclides on SandstonesActa 44/45, 135-141 (1988)

Darley Dale Sandstone (hard rock type)Crushed using a ballmill and selected par

London Clay (soft rock type)U trasonic disaggregation for 30 minutes

ifeTzK^'tt(pH. Eh>Synthetic Groundwater

and Muds

Jefferi

tones

t i d e size range

contacting 'AnalaR' water with crushed rockmonthde-oxygenated

• aerobic condi t• polypropylene

by bubbling an argon-hydrogen

3D

es,

im

of

or disaggregated

mixture through

ion (sandstone, clay), N2 atmospherecentrifuge tubes, ig/lOml

•very gently agitated, 18°C, 4-6weeks• centri fugat ionfiltration (0.

• 1iquid scint i 1

at 4000rpm for 30 min ...sandstone45//m, 30000 molecular weightlation (Beckman 1801) ... K

a-spectroDietry (Nuclear Data 7184) ... u

r-spectrometry (PGT detector) 8s

Soil Nucl

Sandstone CsSrAmAm

Clay CsCsCsCsCsCaCaClClCl

(Oxford) NiNb

trationClay (no) Cs

(0. 45 win) Cs(30000MW) Cs

AdsorptionConcentrati

ide Atmosphere Initial

Air 9. 0E-9Air 6.0E-9Air 2. 1E-7Air 6.0E-9Air 1.0E-10Air 1.0E-9Air 1.0E-8Air 1.0E-7Air 1.0E-6

Nitrogen 1. 9E-7Ni trogen 1. OE-4Nitrogen 1. 1E-6Nitrogen 3. 4E-5Nitrogen 3. 3E-4Nitrogen 3. 4E-8Nitrogen 2.0E-13

Air 8. 7E-8Air 8. 7E-8Air 8. 7E-8

Cl'ADSr

on

cut off, 45Ca,n, 95Nb,

[mo 1/1]Final

4.9.1.8.5.7.1.6.2.3.4.1.2.2.'1.1.

3.4.4.

2E-116E-108E-109E-116E-126E-127E-110E-104E-104E-61E-9OE-68E-51E-4OE-125E-15

1E-96E-106E-10

(clay)

, 'Cent63Ni

l37Cs

PH

6.6.6.6.7.7.7.7.7.8.8.8.8.8.9.8.

8.8.8.

ataWO

?*. fell. &7Ktt^)

100-200 urn

clay for a

for 30 min.

ricon') ... clay

7753000000505850

000

Kd

4700140

2400014004403400156004400110006201000

4410

13006000

30001300013000

- 91 -


4 9

49-1

K5>B

ffl

A'U

Sal

A v f-

W. Bode

Invest

m m*-- b. o :2-3weeks, M'i

C. Wol f rum

i g a t i o n s

Program and

Proc. of the

1986

7tf«mine ASSE i

northern part of

Samp Rocks

Anhydr. Dolomite

R5/2

a lc i

R5/4

R5/5R6/1

R6/2

R6/3

R6/4

R6/5

R6/6R6/7

R6/8

R6/9

Anhydr

t. Dolomi

Do 1 om.Do 1 om.Ankeri

Fi

2nc

s

600CG/15mi

on R a d i o n u c l i d e R e t a r d a t i o n a t ASSE

"S

1

si

the

. Limestone

te

Anhydri

Anhydri

te Marl

Anhydrite

Dolomi

Marly

Marly

Dense

Marly

MarlyMarly

Samp.

R5/1

R5/2

R5/3

R5/4

R5/5

R6/1

R6/2

R6/3

R6/4

R6/5

R6/6

R6/7

R6/8

R6/9

te Marl

Lime

Lime

Lime

Lime

DolomiiDolomi t

SiO3

10. 9

2. 1 0.8.8

19.9

14. 7

21. 2

1. 4

14. 2

8. 3

8. 8

1.4

8.3

5. 0

12. 1

te

te

e

e

Al

3.

6

2.

4.

4.

7.

0.

4.

2.

3.

0.

3.

1.

3.

t Resul ts

Inter. Con

tuated

Federa

mca

1

Depth [m]

770

815

914 7.

Marl 1022

Marl 1045

203

1

0.

9

9

6

7

3

5

8

4

4

0

8

6

125

402416

476499

506

551

590695

Chemical

K2O Na

1. 2 0.

1 1.6

1. 1 2.

1. 5 0.

1. 6 0.

2. 0 0.

0. 1 0.

1. 7 0.

0. 8 0.

1. 0 0.

0.08 1.

1. 0 0.0. 6 0.

1.6 1.

5

f. on Radi oactive Waste

. 20km southeast

Republic

-mmof

of Germany

n)

Sa1t Mine

Management,

Braunschwe

S. Surfac [m!/g] Densi ty[g/cm']38 + 0. 33

4. 00 + 0.

03 + 0. 267. 54 + 0.

5. 26 + 0.

17. 10±0.0. 32 + 0.

15. 67 + 0.

5. 65 ±0.

8. 84 + 0.

0. 83 ±0.

5. 59 + 0.

2. 48 ±0 .

4. 49 ±0 .

Composi t i o n

2O

6

0.

4

69

3

1

5

3

3

0

4

8

1

FeO MnO

1. 1 0. 02

2 0.01 51

1. 4 0. 03

1. 6 0. 03

1. 3 0. 03

2. 7 0. 05

0. 1 0. 001

1. 3 0. 02

0. 8 0. 01

0. 9 0. 01

0. 2 0. 01

0. 9 0. 01

1. 7 0. 03

1. 3 0. 04

2.

34

2. 82 '16

11

93

05

54

30

05

03

40

27

31

866

2.

2.

2.

2.

2.

2.

2.

2.

2.

2.

2.

2.

weight-^]

CaO

25.4

. 1 0.

30. 7

27. 2

28. 5

30.4

40.3

25.0

46. 7

46. 4

52. 0

46. 3

26. 9

24. 0

MgO

16.4

8

11. 9

3. 9

6. 6

4. 40. 1

10. 6

1. 1

1. 0

1. 0

0. 9

17. 2

14. 5

732

16929

907

699

944

835717

719

736

720

856

857

SO

4.

3.9

2.

36.

33.

2.

55.

15.

2.

1.

3.

1.

3.

9.

6

. 75

6

40.

2

8

1

8

6

9

3

49

9

9

2

ig, in

Porosityffl.27

25.

2.

2.

2.0.

8.

6.6.

20.

1

5.

1.

19.

CO,

37.

6

37.

4.

9.

28.1.

26.

37.

36.

41.

37.

41.

33.

8

7

1

4

6

1

0

7

3

5

7

4

6

75

0.

35

3607

4257

6480

13

53

13

86

- R It D

121-130,

. eg.the

P_abil

0. 3160

0.

1240

0.

0.0.

0.

0.

0.

0.

40.0.

0.

0.

ity[cm/s]R5/l

0750nr /n p

Kb/o L

0390

00270016

0018

0270

0060

0035

55000060

0610

0790

- 92 -


4 949-2

K#B

m

Ik

ft

A* V 3

W. Bode, C.Inves t iga

Wol

imci

[rumions on

Program and FProc.1986

AU7tf<7

Samp.

R5/1

R5/2

R5/3

R5/4

R5/5

R6/1

R6/2

R6/3

R6/4

R6/5

R6/6

R6/7

R6/8

R6/9

• Synthettainers

Samp.

R5/1

R5/2

R5/3

R5/4

R5/5

R6/1

R6/2

R6/3

R6/4

R6/5

R6/6

R6/7

R6/8

R6/9

• s o i l / s o

i r s t

^ :2-3wee

RadionuclResults

of the 2nd Inter . Conf.

Sr

4601100

1600

3800

1100

3001080

5304200

9501100

1500

3460

1120

Chemical

Ba

7058

1108575

no13

150607040857486

Eh.

Pb

_

156

15402560254022454041

ks, m^m

ide Retardat

/ 6 0 0 (

ion c

)G,

it

/15mi

ASSE

n)

Sal t Mine

on Radioactive Waste Management,

Compos i t ion [ppm, ppb(P)]

Cu Zn Mi

10 17 14

12 14 9

13 22 20

24 22 13

20 28 16

21 35 34

5 8 7

13 24 18

11 16 10

12 33 12

8 18 7

8 23 20

8 14 14

10 25 19

t >'/§!£, m

Co V P

6 23 350

3 16 350

8 34 900

5 27 650

8 31 900

12 50 1250

2 6 80

9 35 980

4 13 370

6 24 430

3 13 220

7 29 470

6 16 340

8 30 790

ic groundwater(5g rocks into 50ml, 8days)Contents

Si

4640345333803255272917342932

Fe

2215

34

81610

0. 3

1516

14

[ppm]Mg

50070

47026030

13036

31435359554

410340

Ca Mn

8300 0. 29

620 0. 57

3910 0. 19

9650 0. 28

340240

8300 0.01

570 0. 04

450370

7300 0. 28

5201760

8600

lution=4g/10ml , aerob

Na K 1

1470 170 0.

2360 220

8840 410 0.

830 140 0.

1580 200

280 220

150 37 0.

2650 300

1300 130

1550 210

4300 68 0.

2700 240

3100 135

5700 230 0.

i c cond i t ion

B

4340556875759063244026545450

d i s t

Hr

i l

n Ba

1 0.

0.6 0.

3 0.

0.0.

1 0.

0.0.0.

1 0.

0.0.

1 0.

42756156442416

yy

led water

Sr

78750750

82280

12170160250740430120450100

Cu

0.

0.0.0.

0.0.0.0.0.0.0.0.

7

145

64313313

mm

p l a s

E

5.8.9.9.

114.5.

205.

102.

115.7.

4638

35

5

8

26

- R

1 2 1 -

tic

so,

2202070

1520

1250

381600

1130

4955

5302775

340

& D

130,

con-

Cl

18090

55050

1703050

1207060

220110140290

- 93 -


-~9

4 949-3

K#B

W. Bode,

* (E

C. We)1frumInves t iga t ions onProgramProc. of

Samp.

R5/1R5/2R5/3R5/4R5/5

R6/1

R6/2

R6/3R6/4

R6/5R6/6R6/7R6/8

R6/9

andthe

F i r s t

. -5 :2-3weeks,

RadionucResults

2nd I n t e r . Conf

]

Concentra t ion[mo 1/1]

HC1

000001E-51E-41E-3IE 21E-100000000000000000000001E-51E-41E-31E-21E-1000000000

NaCl

000000000001E-81E-61E-41E-2000000000000000000000000001E-81E-61E-41E-20

C a r r i e r

0000000000000001E-81E-71E-61E-51E-41E-3IE 201E-81E-71E-61E-51E-41E-31E-20000000000000000

l i d e

. on

>II/6C

R e t a r d a t i o n

R a d i o a c t i v e

Se-75Rs

0. 050. 060. 030. 80. 380. 100. 120. 100. 090. 140. 040. 080. 070. 070.080. 080. 050. 070.080. 090. 090. 110. 400. 320. 380. 390.400. 350. 490. 740. 10. 080. 070. 050. 070. 050. 060.080. 10. 070. 100. 140. 130. 130. 120. 3

Rd

0. 10.60. 11. 33. 202.082. 162. 142. 102. 220. 100. 200. 200. 140. 130.090. 130. 220. 180. 120. 340.403.52.22.42.62.92. 23. 24. 11.01.031.842.292.422.612.790. 20.20.40.450.450.490.540.561. 6

0 0 G / 1 5m in)

a t ASSE S a l t M i n e - R & D

W a s t e

Tc-95m

Rs

1.91. 11.00. 070. 811.331.341.331.351. 131.401.251. 321. 281.22

0. 1

0. 11. 271. 191. 151. 241. 331. 231. 10. 51. 31. 080. 690. 660.660. 640. 2

Rd

5. 02. 92.00. 81. 132. 362.312. 542. 452. 403. 102.542. 552. 552.48

0. 8

0.93. 233. 503.713. 733. 773. 792.81.32. 94.001. 311.421. 261. 330.6

Management, 121 -130 ,1986

Pb-210

Rs

9050

130908036507880

15014012090

105125193240310439505

509519

13412039

5010.9.9.9.

11.9.

705080

1208275797020

Rd

10060

19012016015813817215558

150160172158150115139215270541

10068

1011338496

no0 605 813 732 546 354 54

13080

12014027115969

10350

- 9 4 -


5 050-1

m

M. I. Sheppard, D. H. ThElement Leaching andResults

ibau I t and J.Capil lary Ri

J. of Environmental Quali

• Sandy soi1 (Gleyed Dys

Soil horizon depthBulk density[Mg/m:1]pll(l :1 , s/w paste)CEC[cmol/kg]M o i s t u r e r e t e n t i o n

0. OlMPa0. 03MPa0. 05MPa0. IMPa0. 3MPa

Porewater analysisNaKCaMgFeFClNO,SO,HC03

PH

t lTTK^ttCpH. Eh. *7

[cm]

t r i e

in *[g/kg]

[mg/1]

-ms.• Groundwater and Rainwater

• Cores were taken60. 0cm) into the58cm.

• Cores were spikedTc-99 5. 55E+5Tc-95m 3. 15E+5Cs-133 240Cs-137 1. 03E+4U-238 445. 8Th-232 386. 31-127 12001-125 9. 25E+5

ty, 16(3)

H. Mitchellse in Sandy Soi

273-284, 1987

B r u n i s o l ) , s o u t h e a s t e r nL i t t e r

0-4

Ae

4-150. 29±0. 04 1.34±0. 025. 2 ±0. 1

81. 2 ±8 . 3

103.4 ±7. 278. 3 ± 1 . 767. 2 + 2 . 059. 2 ±6. 037. 3 +2. 0

5. 2 ±0. 367 ±3

170 ± 532 ±3

1. 9 ±0. 110. 8 ±0. 367 ± 424. 7 ± 1 . 6

111.0 ±2. 0

5. 7 ±0. 1

by p u s h i n g t he cu ts o i l

wi thBq/6.Bq/6.mg/6.Bq/6.mg/6.mg/6.mg/2.Bq/2.

to a

96ml96ml96ml96ml96ml96ml10ml10ml

depth of

5. 1 +0. 12.9 ±0. 2

4. 1 ±0. 42. 1 ± 0. 11. 8 ±0. 21.7 ±0. 11. 4 ±0. 0

8. 2 ±0. 38. 5 ± 0. 3

18.9 ±0. 54. 7 ±0. 30. 8 ±0. 10. 45 ±0. 03

14. 4 ± 1 . 3<0. 16

50. 2 ± 1 . 013 ±26. 7 +0. 1

t ing head wi th

1 Cores: Experimental

K gMani toba,

Upper

15-451. 47±0.5.2 ±0.2. 1 ±0.

2. 1 ±0.1. 3 ±0.1. 2 ±0.1. 1 ±0.1. 0 ±0.

15. 6 ±0.8. 7 ±0.

15. 9 +0.2. 7 ±0.0. 6 ±0.1. 50±0.

18. 2 ± 1 .<0. 16

27 ± 17 ± 26. 7 ±0.

ac ry l i c60cm without turning.

Np-237 7. 3E+3Cr-52 2530Mo-100 202.4

0317

10100

33531043

1

is. i§Canada

I

1.6.1.

1.0.0.0.0.

26.3.

26.4.1.0.

11.

14.124

7.

tubes (5

.ower

>4544 + 0.2 ±0.7 ±0.

6 ±0.8 ±0.6 ±0.7 ±0.5 ±0.

0 + 0 .6 ±0.0 ±0.6 ±0.6 ±0.37 + 0.3 ±0.<0. 2

0 ±0.±2

4 ±0.

7jCtttP)

0014

10

100

429021037

3

1

. l e m xCores were 52-

Bq/0. 25mlmg/2 3.mg/2 3.

0ml0ml

r spec t ro scopy : Tc-95m, Cs-137, INeutron act ivat ion:AtomiICP:

-125U-238, Th-232

c absorpt ion: Cr-52Mo-100

, Np-237

- 95 -


5 050-2

M. I. Sheppard, D. H. Thibault and J. H. MitchellElement Leaching and Capillary Rise in Sandy Soil Cores: ExperimentalResultsJ.of Environmental Quality, 16(3), 273-284, 1987

Groundwater. DesorptionKd (sample)

L i t t e r Ae Upper Lower

TcICsNpCrMoUTh

198. 0 ± 0 . 9( 5)

6. 0 + 4. 4( 3)20.8 + 2. 8( 3)

Rainwater(Leachate)Litter

8. 2 + 1 . 1(18)0. 3 + 0 ( 1)5. 8 + 0 ( 1)

35. 0 ± 3 . 1(14)15. 8 ± 2 . 6(11)

171. 8 + 3. 1( 3)

Kd(sample)Ae

0.8 + 1.4(28)

0. 8 ± 0 . 5(11)160. 2 + 2. 5(26)

7. 7 ± 1 . 8(18)226. 2 + 2. 0( 6)

Upper

0. 2 + 1. 3(22)0. 1 + 1. 1( 9)1.5 + 1.0(30)0. 5±0. 9(44)8.9 + 3. 2(46)

14. 2 + 21. (46)69. 7 + 2.4(11)

223. 3 + 7. 2( 2)

Lower

TcICsNpCrMoUTh

367. 8 + 0. 4( 9)43.8 + 0 ( 1)

262.9 + 4. 4( 3)50. 3 ± 3 . 5 ( 2)

2. 3 + 1 . 7( 3)80.7 + 1.0(13)32.4 + 0. 6( 9)

4. 2 + 1 . 0(11)91. 1 + 2. 3(27)26. 1 + 1. 7(27)

1 .4±0 ( 1)8. 7 + 0. 8(24)

17. 2 + 0. 5(14)1.6 + 0. 7(20)

134. 5 ± 1 . 3(29)51. 9 + 1 . 3(28)

1028. 6 + 8. 6( 2) 1271. 0 + 2. 3( 5)

0. 1 + 1. 4( 9)0. 5 + 1. 6(34)6.5 + 0. 7( 7)0. 6 + 0. 6(20)

53. 1 + 2. 5(39)14. 2+1 .8 (22)19. 8 ± 0 ( 1)

- 96 -


(l&to :l-8days)

5 1

D. Klotz und F. OlivEine einfache Methode zur Bestimmung der Verteilungskoeffizienten vonRadionukliden im Grundwassergwf-wasser/abwasser, 124(1983)H. 3

A

Sand (Federal Republic of Germany)

. Eh.Groundwater

14cm3 Polypropylene tube, 4g/10cm3

... Adsorption

Kd(85Sr)Contact Time Combined Circulation-Batch-Method Circulation-Batch-Method 1 d

1.3 1.42 d3d5 d8 d

1. 31. 31. 31. 3

1. 51. 51. 61. 7

- 97 -


tsvhtk

5 2

A. S a a s : P r o c e s s u s d e S o r p t i o n et de D e s o r p t i o n d e s R a d i o i s o t o p e s sur les M a t e r i a u xS o l i d e s a P a r t i r d e s R e j e t s L i q u i d e s et d e s D e p o t s A t m o s p h e r i q u e s . N o t i o n D ' u t i 1 i s a t i o n d uC o e f f i c i e n t d e P a r t a g e o u de D i s t r i b u t i o n (Kd) L i m i t e s D ' u t i 1 i s a t i o n et A p p l i c a t i o n sP r a t i q u e sCEA-R-4952, 1979

Sediment, eau du Rhone (Adsorption)Concentration en Sediment [mg/l]

25100500

2000Schiste(Schist) altere de La Hague,

PH124567910

Kd (Sr-85)

80110240

eau de LaKd (Sr-85)

1. 8

13346570500

Kd (Cs-137) Kd44000350002000010000

Hague (Adsorption)Kd(Cs-137)

7202300

5500

9000450200

(Ru-106)1500045001200300

- 98 -


xm5 3

J. T. M a r u m o and A. A. SuarezThe D e t e r m i n a t i o n of the Ce s i u m D i s t r i b u t i o n Coefficient of the InterimStorage Soil from A b a d i a de G o i a s , GO, BrazilINIS-BR—2351

n* U

Clay-1 (Storage)Clay-2(57thSt.)

Clay-1 (Storage)Clay-2 (57thSt.)

Wtr Cont. [%] Density, Bulk(dry) [g/cm3] Porosity[%] pH22.20 2.65 1.45 45 4.417.67 2.68 1.44 46 4.9

Coarse Sand Medium Sand Fine Sand S i l t Clay[%]- 13 28 33 265 5 46 7 37

Eh,Cesium Chloride Solution (distilled water and Cs-137)

100cm3 polyethylene flask, 10g/97cm3

3 X 3 in well type scintillation detector

Kd (Cs-137)Concentration of Cs-137[mol/1] Clay-1 Clay-2

1E-21E-31E-41E-51E-61E-71E-8

1.40 + 0.0414. 58 + 0. 16

106281326752857

+ 22+ 11+ 8±32+ 17

1.6.2247298398458

28 + 0.0480 + 0. 03

+ 0. 2±1±8+ 26+ 7

- 9 9 -


5 454-1

Kfl-B

M

A - y ^ i (fab "5 :21-24hours,

R. C. Rout son, G . S . B a r n e yMeasurement of F i s s i o nSediment TypesRHO-LD-73. 1978

A*'J7#©&gfl:¥M!8tt({fc*So 1 CaCOsLmg/g] Sil

Burbank 0.8 10Sand

Tank Farm 26.0 29Sandy Loam

ffi F7K^tt(PH. Eh. JH^t>mA• Calcium n i t r a t e or sodium

•?•<£) ft!l• 250ml p o l y e t h y l e n e s c r e w• 4 - i n c h wel1 type c r y s t a l

^ • E ^ ^ [ m l / g ] . . . AdsorptionKd(Sr)

Na[mol/1] Burbank Tank3. 0 0. 49 0.1.5 0.6 1.0.15 5.60. 1 6.0.015 39.40.01 55.0.0015 173.00.001 146.

Cone, [mol/l] Kd(Sr)Na Ca Burbank

0.15 0.02 1.40.15 0.004 4.40. 075 0. 02 2. 90. 075 0. 004 5. 10.015 0.02 2.90.015 0.004 14.0

and

&fr#«/4000rp

R. 0. Seil

m/30min)

P r o d u c t S o r p t i o n P a r a m e t e r s for Hanfo rd

[%]. i

.5

!. US

C l a y M CEC(pH70. 5

4.9

im)n i t r a t e so lu t ion

cap centrifuge b o t t l e

0) [meq/lOOg]4. 9

4.0

, 25g/Z5ml, ir - c o u n t i n g spectrometer

Farm9342

74

4

0

Ca [mol/l]0. 20. 10.050.010.0050.002

Cone, [mol/l]Na Ca

0 . 1 5 0 . 0 20 . 1 5 0 . 0 0 20 . 0 1 5 0 . 0 20 . 0 1 5 0 . 0 0 20. 003 0. 020. 003 0. 0020 . 0 0 1 5 0 .020 . 0 0 1 5 0 .002

pH(0

)H=soi

Kd(Sr)Burbank

0. 661. 251.97. 72

11. 913. 3

Kd(Sr)Tank Farm

1.44.41.8

14. 01.8

17.01.9

23.0

Tank0.1.2.5.

12.26.

200 Area

MS. JS7K1t^). 01M, CaCh)7.0

8.0

1 pH±0. 1

Farm4324218564

- 1 O O -


WSEfc

xm5 454-2

A**;

R. C

( Jg£5:21- <s4hours,

Routson, G.S.Barney and

M'i.

R. 0. SeilMeasurement of F i s s i o n Product SorptSedimentRHO-LD-73

#E0MBc[ml/g]35- to 255-foot

NaNO:,[mol/1] Cs-1370. 00100. 00150. 0100. 0150. 100. 150. 53.0

ConcentNaN03

0. 0010. 0010.0010.0010. 0010. 0010. 0010.0010.0011. 51.51.51.51.51. 51.51.51.53.03.03.03.03.03.03.03.03.0

1590

1480

1410

1170

568351

64. 8

26. 0

r a t i o nCa(N03

0.0020.0020.0020. 10. 10. 10. 20.20.20.0020.0020. 10. 10. 10. 10. 10.20.20.0020.0020.0020. 10. 10. 10.20. 20.2

Types1978

. . . Adsorpt ion

|/4000rp

ion Parameters 1

level of well E17-4 sediment (medium sand)Kd

Sr-85 Co-60

49.2 2120

41. 8

49. 7 1400

41. 5 1060

15.5 1290

11.5 2230

1. 74 4760

0. 60 4700

[mol/1]) : KN03

0. 0020. 10. 20. 0020. 10. 20.0020. 10.20.0020. 10.0020. 10. 10. 10. 20. 10.20.0020. 10. 20.0020. 10.20.0020. 10.2

Ca (NO,) •

[mol/1]

0. 0020

0. 0050

0.010

0. 050

0. 10

0.20

Cs-137244. 0

13. 36. 28

368. 09.886. 03

88. 012. 74.49

47.45.0

36. 36. 156. 006.452. 614. 053. 25

29.44. 44

26. 221.0

3. 22.98

15. 14. 721.84

KdCs-137 Sr-85 Co-60

2170

2380

2100

1360

1100

793

18.10.4.1.0.0.

KdSr-856.2.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.

892197351812161209380481516131008937032324300510810208101502918

6 3870

2 2500

53 2000

58 640

50 366

28 222

Co-6081.0

2020. 045. 5

259. 073.3

190.062. 3

143.051. 1

3222.059.784.4

241.0204.0179.0

67. 254. 7

135.041 .0

1219.081.6

326.082.0

217.055.3

145.060.4

KNO:<[mol/1]

0. 0020

0. 0050

0.010

0.050

0. 10

0. 20

or Hanford

Cs-137

283155

92. 1

23. 1

11.6

5. 78

KdSr-85

36. 2

29. 8

23. 4

7.89

5. 12

3. 71

200 Area

Co-60

549663774

3410

3400

3410

- 1 0 1 -


5 5

K.Bunzl and W. SchultzDistribution Coefficients of l37Cs and 85Sr by Mixtures of Clay and HumicMaterialJ. Radioanal. Chem., Articles, 90/1 (1985)23-37

A

A UCEC[meq/g dry]

Humate(Ca-humate, sphagnum peat) 2. 7 + 0. 2Clay (Ca-saturated bentoni te, Manchen) 0.7

, Eh.Pure water + tracer(Sr, Cs) + supporting e 1 ectro 1 yte(0. 01N CaCh)

fr Capped polystyrene vial, 50mg/2ml, pH=7.5-8, 2O±2t:Well-type scintillation counter

... AdsorptionPure water + Sr or Cs

Initial Cone, ofSr(or Cs) [mo 1/1]

1E-65E-41E-35E-31E-2

Initial Cone, ofSr(or Cs) [mo 1/1]

1E-65E-41E-35E-31E-2

Kd(Sr)umate

400550500400300

. 01N CaChKd(Sr)

umate

350200150130110

Clay

750700550200100

Clay

3010104535

Kd(Cs)Humate

10020101010

Kd(Cs)Humate

10010101010

Clay

100001300700280150

Clay

1600040027013090

- 1 0 2 -


5 656-1

W.D.Reynolds, R. W. Gi 1 lham and J. A. CherryEvaluation of Distribution Coefficients for the Prediction of Strontiumand Cesium Migration in a Uniform SandCan. Geotech. J., Vol. 19, 1982

A

A'JG l a c i o l a c u s t r i n e s a n d ( C h a l k R i v e r , O n t a r i o ) , 0 . 5 - 3 . O m ( d e p t h ) , 0. 0 1 3 c m ( a v e . s i z e ) , q ua r t z ( 5 0 - 5 5 9 ! ) , f e l d s p a r ( 1 5 - 2 0 % ) , h o r n b l e n d e & p y r o x e n e ( 2 0 - 2 5 W , g a r n e t ( 5 - 1 O 5 K ) , b i o t i t e & m u s c ov i t e ( l X )

CEC & EXC [ m e q / l O O g ] S o l u b l e C a t i o n s [ m g / 1 ] C a r b o n a t e O r g a n i c pHK Ca Mg Na K Ca Mg [wX] [wX]

1 . 0 6 1 . 0 6 4 . 3 7 0 . 2 4 1 . 8 0 4 . 7 4 8 2 . 7 0 4 . 6 3 0 0 . 5 1 6 . 3

Eh,Groundwater(Ca:5. 1, Mg:l. 9, Na:10. 8, K:3. 2 [mg/1] + Chloride salt

S r C h . . . 8. 5E-8~4. 4E4 [mg/1] CsCl ... 1. 1E-8-—1. 3E4 [mg/1]pH=6. 9

Nuclear Chicago Model 1085 r-counterpH=6. 9 (by addition of HC1), 25±2 CC, 20deg. oscillation wrist-action

. . . Adsorption

Kd(Sr) = 15 + 0. 6

10* j -

_ 10-'

O

Kd(Cs)=77±2

to'

tO°

to-*

I

I . I • I I I . 1 1 1

10-" 10-*C

10*2

-

-

-

. . . .J.. 1 .

/

\ • 1

s *

*

•

, i

a

I

10''° 1O'» 10"' 1O-«

C10" 10

FlC. 2, Strontium batch sorption isotherm (at Chalk Kivcrsund.

Fic. 3. Cesium batch sorpxion isotherm for Chalk Rivsand.

- 103 -


5 656-2

W.D.Reynolds, R. W.Gil lham and J. A. CherryEvaluation of Distribution Coefficients forand Cesium Migration in a Uniform SandCan. Geotech. J., Vol. 19, 1982

the Prediction of Strontium

A

Chalk River Sand (particle densi ty:2. 67g/cm3, size:<2mm)

Groundwater

Column : 5.0cm long, acrylic tube, single passSand pac characteristics

Bulk density Porosity Void volume

No. 2No. 3

[g/cm3]1. 7461. 726

34. 6135. 35

[cm3]57. 20558.437

Pore-water veloci ty[cm/sec]1. 5E-37. 1E-3

. Adsorption

Sand pack No. 2Kd(Sr)=28. 3

Sand pack No. 3Kd(Cs)=167. 4

. - . , - • — • • — '

no WO

POM UO.IJWS

Fie. 8. Strontium influent curve simulations, sand pack No-. Dn - JO-^cm^r*; V? = 1.5 X HT5 on-t"1'. a - 0.033 cm.

Fio. 9. Cesium inRuent curve simulations, sand pack No. 3,Dm * l O - W - r " ; P - 7.J X lO-'cra-s-1; n « O.023cm,

- 104 -


icm5 7

A

M

Si

%i

ft

A~>y fidf-fit or M ^ / D > ^ , ^iii/O. 45 M m )

M.F.Lima and B. P. MazzilliDetermination of the Distribution Coefficients for I34C<in the Pinheiros River Sediment-WaterJ.Radioanal. Chem. .Articles, 177/1(1994)139-147

AU7tt«t)SHbW^f±(^*iM, tt±Jfe«&/*, #«**#*. *>•Pinheiros River Sediment (Clay, oven-dried at H O t for 1

Mineral Analysis ... quartz, i11ite, chlorite, halloysiteGranulometry ... >0. 25mm 10%, 0. 05-0. 25mm 49%, <0. 05mmMacroanalysis[%] ... Si: 39, Al:9. 86, Fe:3. 82, Mg:2. 12,

Na: 1. 82Microanalysis[ppm] ... Mn:336, Cl: 248, V: 102, La:41. 3.

,, 60Co and

week)

40%K:l. 65. L

Co :32. 8,Sc:13. 4, U:4. 54, Sb:3. 30, Cs:4. 25

CEC[meq/100g] ... 11+3Activi ty[Bq/lOOg] ... Cs-134:<2E-3, Co-60:<3E-3, Th-234

±feT7K#14(pH. Eh. a#-r*>*ft. m&m•Pinheiros River Water (0. 45 Mm, stored in polyester tanks

pH ... 5. 5-6. 0Ions[mg/1] ... Fe: 12. 9, P: 1. 08, Mn:0. 27, Ni: 0. 05, Pb: 0.

Cr:0. 05, Zn:O. 27Act ivi tyCBq/1] ... Cs-134:<0. 17, Co-60 :<0. 21. Th-234:<8

• HpGe detector

^BS^^[ml/g] ••• Adsorption•Bubbling of air/nitrogen : 50mg/500ml, 45 hours

Co-60 Cs-134 Th-234Air 424 + 26 21.3 + 1.6 2610000± 110000Nitrogen 666 + 32 22. 2±1. 0 2780000 + 250000

•Effect of pH : lOmg/lOOml (or 50mg/100ml), 15 dayspH Co-60 Cs-134 Th-2344 46.9 + 2.1 147000 + 90006 ' 21 ± 78 1660+150 33 + 4 2330000 + 90000

:<8. 1

at 4°C)

10, Cu:0.

. 1

234Th

i:0. 53,

Th: 16. 8,

07,

105 -


5 8

c

ffl

ft1

A>

G. W.Beall, W. W. L.Americium SpeciatGround WaterMat.

• Quart/• Bioti

Res. Soc. Symp.

7

e

ftt(pH. Eh. rt#^l• Synthet ic Grani t ic

HC03

SiO2SO4Cl

Kd (Am)PH

45678910

Cone, [mg/1]60-4005-603-405-50

Lee andion and

Proc.,

Ground

A. E. Van LuikDistribut ion

Vol.50, 1985

Water : pH=7.Cone, [mg/1]

CaMgKNa

nl/g] ... Adsorpt ion

Quartz

80490130014001000490100

10-602-251-10

10-100

Biotite

2501778

100002100016000668158

Coefficients in a Granitic

2-8. 5Cone, [mg/1]

F 0.01-5HPO4 0. 01-0. 5Fe 0. 5 -20

- 106 -


5 9

B

m

&

fir

H. Wanner, Y. /Project CaesDis t r ibu t ionSKB-TR—94-H

A-U7tf0$)S{t:'• Wyoming MX-80 I

CEC[meq/100g]EXCM Na

KMgCa

%T7k#tt(PH. Eh_

Ubinssonum - AnCoeffici

), 1994

ientoni te1081.70.33.9

14. 1

and E. W i e l a n dIon Exchange Model for the Pred ic t ion ofents of Caesium in Bentoni te

Densi ty[g/cm:i] Dry :Water sa tu ra ted :

Porosi ty[%] :Sol id/Pore-water

[g/cm3] :

• Allard Groundwater : pH=8. 12Cone.

AllardNa 2. 26E-K 1.00E-

[mol/1]Asps

i 1. 31E-11

Mg 1. 90E-4 2. 06E-3Ca 4. 64E-4 1. 10E-1

# B E # & [ m l / g ] . . .• Pure Bentoni t e

Adsorpt i

S/W[g/cm3] W a t e r - t y p e pH0.01 A l l a r d Wtr0 .18 Aspo Wtr0. 102 1M NaCl0. 104 0. 5M NaCl0. 104 0. 5M NaN03

0.011 0. 5M NaCl0. 104 0. 05M NaCl0. 104 0. 25M CaCl

9. 537. 167.387.417.558.818. 126.61

0. 103 0. 25M Ca(N0,)» 6.610. 103 0. 025M CaC0. 010 0. 25M CaCl0. 1 1M KC10. 1 0. 5M KC10. 1 0. 05M KC10.01 1M KC10.01 0. 5M KC10.01 0. 05M KC10. 1 1M MgCh0.1 0. 5M MgCh0.1 0. 05M MgCl0.01 1M MgCh0.01 0. 5M MgCh0.01 0. 05M MgCl

h 7.397. 158.078.038.669.439.349.336. 967.057. 727. 547.628.09

on

2. 00 Impuri t i e s [w2. 30 CaCC-3 : 1.30. 0 CaS04 : 0.

NaCl : 0.6.7

, Aspo Groundwater : pH=7. 38Cone, [mol/1]

AllardCl 1.48E-3SO4 1. 00E-4SiO2 1. 39E-4Alk 1. 80E-3

Aspo3. 40E-17. 40E-3

1. 80E-4

• lOSfc-Bentonite + 90%-QuartzKdQnYkg] S/W[g/cnf

1. 00. 1720.0340. 0560.0540.0800. 3100. 0530.0470. 1830. 1480.0150. 0360. 3420. 0150. 0280. 2800.0360.0450. 1170. 0840.0890. 150

0. 20. 10. 10. 10. 10. 10. 10.0100.010

• Bentoni

%]434007

Sand] W a t e r - t y p e pH KdDnVkg]Aspo Wtr 7.451M KC1 9. 300. 5MKC1 9.100. 05M KC1 9. 301M MgCh 7.000. 5M MgCh 7.310. 05M MgCh 8.010. 25M CaCh 7.900. 5M_NaCl 9 .13

0.0.0.0.0.0.0.0.0.

te , 0. Olg/cm3, 0. lM_NaClCs [mol/1] Kd pH Cs [mol/1]

1E-13E-21-E23E-31E-33E-41E-43E-5

0.010 9.13 1E-50.030 9.11 3E-60.072 9.12 1E-60.124 9.14 3E-70. 133 9. 16 1E-70. 133 9. 18 3E-80. 140 9. 18 1E-80. 152 9. 18

[m'/kg]

030001003020015018025093033

Kd0.0.0.0.0.0.0.tm

158167188200222224231/kg]

PH9.9.9.9.9.9.9.

18181818181818

- 107 -


6 0

A

ffl

/£

%.

A*•No12345678910111213141516

m•

•

#SENo12345678

b

R. W.Gil lham,Cesium DistrHealth Phys.

Canadian soilLocationPinawaPinawaPinawaPinawa

LeamingtonLeamingtonChalk RiverNorth BayNorth BayPinawaPinawaBruceBorden

LethbridgeLethbridgeLethbridge

TzK#i£(pH. EhDouble-deioni2

1.0g/5. 0ml, 1C

t. o :4-20hours,

J. A. Cherry andibution Coeffic, 39, 637-649,

SoilLight ClayLight ClayLight ClaySandLight Clay 'SandSandHeavy ClayHeavy ClaySandy ClaySandy ClayLight ClaySandLight ClayLight ClaySandy Clay Loam

##-f*>**. used water + NaOH

MM Bi/200

L. E. Lindsayents i1980

)rpm/

n Unconsol i

Depth [m] CEC5.05.05.02.04. 53.04.06.00.90. 71. 28.02.51.04.010.0

and Ca

)0ml-polypropylene centNuclear Chicago model 1085 automatic

Adsorpt ion. Kd(Cs) BG(Cs)[mg/l]

27000

25000120

130085081

6300

1. 2E-5

4. 6E-59. 4E-61. OE-41. 1E-45. 5E-31. 3E-5

No.910111213141516

8.8.8.1.5.1.1.1.

10.1.2.0.0.32.31.21.

2t, Mg"

ri fuge

10

da

#

EXC(K,43326240900619592587207237714817

and K

tuber-counter

Kd(Cs)260001200

10000240540

700041004100

BG

1.1.1.0.1.1.0.0.0.0.0.0.0.0.0.0.

t

(1

min)

ted Geological Materials

Ca, Mg) [meq/lOOg] pH6 6. 25 6.46 6. 39 5. 24 6.01 4.47 5. 12 7. 64 24. 23 6. 52 38.63 35. 12 6.65 44. 75 46. 16 35.8

4. 74. 64. 80. 20.80. 20. 21. 16.70. 51. 51. 50.44. 64. 76. 3

is chloride sal

Omin. count)

(Cs) [mg/1]

5.8.2.5.1.1.6.

N. D.9E-65E-61E-51E-68E-54E-52E-6

8. 18. 18. 18.37.76.37.85.06.76. 57.68.08.07. 77.87.8

ts

- 108 -


6 1 Vol. 3K No. 10, 1989

A

T-3os1-11-2

<980

Eh,

=7. 5~7. 7, 185~195mV

2g/51mlO r t e c t t f i ( M o d e l 8101). 58. 5cc

. . . Adsorpt ionKd(85Sr) Kd(137Cs) Kd (54Mn) Kd(MZn) Kd ("Co)

T-3Os1-11-2

2.4 + 0.4. 0 + 0.180±2025 + 3

35

170 + 40330 + 40

2700 + 5001500 + 400

4600 + 200020000+14000230±301100+1000

1800±2002400 + 3008300 + 3300630+160

4800 + 150019000± 14000900± 160950±720

- 109 -


fflfetii

6 2 , 17, 3 - 9 , 1982

A

. 63g/cm3)

, Eh,0 C o C l » ,

. 573oNaKTl) t, 5" d> X4"h)

. . A d s o r p t i o nR a d i o a c t i v e Cone. [ # C i / m l ] Chemical Cone, [moI / I ] Kd

"To

18iSr

37Cs

. O E - 2

.OE-2

.OE-2

.OE-2I 1E-6. O E - 2.OE-2.OE-2. OE-2.OE-2.OE-2.OE-2

. OE-3

.OE-4

.OE-5

.OE-6

. OE-12

.OE-3

.OE-4

.OE-5

. OE-3

.OE-41. OE-51. OE-6

7 .3160600770950

1. 72. 12 .44 . 4

1554

260

- no -


6 3] ( I )

t * £ ! £ . Vol. 18, No. 1, 1976

A

/\*'J

ii 255/im, ^ 2. 64g/cm\ CEC 9. 7 + 0. 6u eq/g

. Eh.

. . A d s o r p t i o nS o i l - b e d

N u c l i d e He igh t Weight P o r o s i t y[mm] [g] [X]

I n f l u e n t s o l u t i o n E l u t i o n KdH a r d n e s s pH A c t i v i t y r a t e- [ m e q / 1 ] [ j tzCi /ml] [ml / cm7min] 90Sr 59.

0.0 33.160Co 7 0 . 0

137Cs 2 0 . 0

1.5850.020.0

7.18 3E-344.932.8

1.971.63 7.061.61 7.20

4.93E-33E-3

2. 201.48

25.4694.6

- Ill -


(£g<h^:24hours, i l 1 i p o r e HA)

76 4

, ItBB IfTOj±<Df£m'M%.. 22 , 1 7 9 - 1 8 7 , 1987

A

Tokai Depth [cm]T-01 0-45T-ll 405-420T-17 650-700

Type

Clay sandSandy ClayLoam

Kibune Depth [cm]Ya-01Ya-03Ya-07Ya-14

0-2040-60120-140500-520

TypeLoamy sandLoamy sandLoamy gravelGravel

Konno Depth[cm] TypeYb-01Yb-20Yb-27Yb-39

0-20380-400520-540760-780

Humus loamSandy loamSandy loamTuffy loam

Eh,CaClz + SrCh(3E-4, 1E-3, 3E-3/ieq/ml) and 85SrCh(0. 0 U Ci/ml)

®inmm, t&^T46m) : PH=6. 8Cl:17. 6, Cu:<0. 01, Fe:O. 11, Mn:O. 01, Zn:<0. 005, Pb:<0. 01Cd:<0. 005, COD: 1.6 Total Hardness:45. 8, SS:89.0

5. 0g/50mK H 22t;, Aloka ARC-301)

Kd(Sr). . Adsorpt ion

CaCh solu t ionSr=3E-4 Sr=lE-3 Sr=3E-3[Meq/ml]

T-01T-llT-17Ya-01Ya-03Ya-07Ya-14Yb-01Yb-20Yb-27Yb-39

28. 635. 5

114. 2172. 2

99. 1115.651.987. 738.6

147.586. 2

25. 732. 8

110. 6169. 8

89. 3111. 848.983. 532.4

128. 177. 6

28.033.3

170. 1166.489.3

111.848.993.337. 2

148.389. 7

Groundwater

26.433. 199.3

173.579.595.942.3

130. 245.9

227.6107.3

- 112 -


6 5

B

m

%

A>

L. P.EvalProc

A*'J78

Kaolin11 iteMontmoiSand

Sol-1Sol-2Sol-3Sol-4So -5Sol-6

Solid

Bentoi

f-m (48

Buckley,

hours)

G. M. Arbique, N. B. Tosellouation of Backfill Materials for. of the

te ClayClay*illon ite

"14 (pH. Eh.

2nd Inter. Conf. on Radioac

CEC[meq/100g] Dry3-1515-40

Clay 80-100

Bituminized Sodium Phosphate LeaDemineralized WaterChalk River Groundwater

and B. L Woodsa Shallow-DeptlI Reposi torytive Waste Management, 212-216, 1986

t. *F«ftS*rft. -rDensity[Mg/m3]

1. 3-1. 4

I. 65

chate Solution

Chalk River Groundwater with PhosphateCementCement

lite Clay

Equilibrated Chalk RiverEquilibrated Chalk River

Adsorpt ionSolution Kd(60Co)

Sol-1 170Attapulgus Clay Sol-1 220Illit(; ClayKaoloin ClaySandSand2% 11i% 115% 115% II5X 115% 116% 118% II10% I

ite Sandite Sandite Sandite Sandite Sandite Sandite Sandite Sand

Sol-1 145Sol-1 50Sol-1 100Sol-2 250±30Sol-2 350+10Sol-2 460±10Sol-3 900 + 60Sol-4 64 + 5So 1-5 63 + 2Sol-6 31.6 + 0.5Sol-2 460+20Sol-2 380±20

lite Sand Sol-2 380+10

Solid/Solution Ratio = 1:15

GroundwaterGroundwater wi

Kd(8iSr)

9. 7±0. 415.3 + 0. 7

22 + 214±1

>10000025 + 2

>10000035+158±182±1

* > £ $ W * . fig. iS7Xtt )

th Phosphate

Kd(i:i7Cs)

5102200110039040085 + 4

1300±2007000+10007300 + 200520 + 30

18000+100035OO±70O14000 + 200030000 + 900038000+10000

- 1 1 3 -


6 6

J. L. Means, D. A. Crerar, J. 0. DuguidMigration of Radioactive Wastes: Radionuclide Mobilization byComplexing AgentsScience, 200, 30, 1477-1481, 1978

A

Weathered Conasauga Shale (ORNL burial ground)

H. EH.0. 22Aim Filtered Groundwater

... Adsorption

Well Code Kd(60Co)

RS7T7-11T7-12T7-13T7-14T7-15

65.332.652. 330.029. 16. 9

- 114 -


6 7

A

m

*

D. RanconComparative Study of Radioactive IodineExper imental and NaturalRadiochimica Acta 44/45,

A*'J7ft<7• Grain s

#6H#Sc[inl

Category

SilicaAlumino-si1icate

Mixture

Aluminum& Iron

Ores

Copper

LeadOres

ize <0. 1 mm

fctpH. Eh. &^*>®&.

/g] ... Adsorption

Mineral, Soil, Ore

QuartzAttapulgiteBentoniteClinopt ilol i teIlliteKaoliniteSepioii teVermiculi teZeol i te

Cadarache soi1

Bauxi teGoethi teHematiteLateriteLimoni teSideri te

ChalcopyriteChrysocol la

Cerusi teGalena

Condi t ions187-193, 1988

ffifiJc. tt±K*fifilE.

pH Contact=

7. 27.58.47. 37. 26.96.86. 76

7.6

7. 37. 6

76. 57. 6

7. 27. 2

78. 6

Behavior in Soi

lday

01.51.42. 50. 50. 52. 434

1. 3

215

315

Kd(I)2days

021.52. 5242. 435

1. 3

0. 710.70. 260. 2

31510

850

Is under Various

3days

02

24

35

1210. 56

70040

890

- 115 -


6 8

A

m

#

nv*m (fiK<h^:8days, 3tf i) *?

J. Bors, R. Martens and W. KiihnStudies on the Role of Natural andthe Mobility of Radioiodine in Soi 1Radiochimica Acta 44/45, 201-206, 1

AUTtfO^Sf• Podzol soi1, Hannover, F. R. G.

Soil Depth [cm] pHGLO) org.0 0-5Ahl 5-15Ah2 15-25Ae 25-50B 50-80Cl 80-120C2 120-200

i&TzK#tt(pH. E

3. 7 6.3. 7 4.3. 7 4.4. 1 0.4. 3 0.4. 3 0.4. 3 0.

• D i s t i l l e d water, 0. OlM CaCh,esponding to 0.

-?"©ftk• 10g/20ml

Column Methodglass column,

l /zgI720ml.

5. 5cm(J) xi0cm-hporosity(0:78%, Ah:49%, B:42%

S o i l D i s t i

0 26Ahl 13Ah2 12Ae 2.B 8.Cl 1.C2 0.

. Adsorption

lied water CaCl

± 0 . 3 143± 0 . 5 91± 0 . 4 36

4 + 0.02 17l ± 0 . 0 2 362 ± 0 . 1 129 ± 0 . 01 1.6

era c2660521610206

m)

C

Anthropogenic (s988

ay[X002. 20000

0. 5M NaOH, 0

, seived, C:44%)

Kd2(0. OlM)

±31± 8± 1± 2± 5± 0. 1± 0.05

(2mm)

(I)

rtt

]

mist

Sil7.

12.7.4.2.3.3.

1M Na

s o i l ,

tra7186423

P2O7

NaOH(0. 5M)

0.0.0.0.0.0.0.

34383853456238

)rganic Substances in

Sand[%]92.387.990. 095.497. 696.896. 7

with 63kBq IZ5I as Nal corr

Na4P207(0. 1M)

0. 10. 10. 10. 10. 20. 10. 1

- 116-


6

it9

69-1

A

m

A>« (151*3

K. H. Lieser and

Sfc5:l- gOda1

TH. Steinkopf f

ii/0.45^ m/Mill ipore)

Chemistry of Radioact ive Cesium in the Hydrosphere and iiRadiochimica Ac

• S a l t domeSed. Depth 5

[m]SI 9-12

We i c h s e t g l a c i a l

S2 97-99Myocene

S3 114-116Elsterglacial


S5 137-140Myocene



^ T T K # 1 4 ( P I• S a l t dome

Wtr Depth pH[in]

Gl 106-109 7.0.

G2 91-94 8.0.

G3 106-119 7.0.

G4 116-119 7.0.

G5 140-143 7.0.

G6 209-214 6.0.

G7 235-238 6.0.

• i n i t i a l co

at Gorl. S. Area[cmVg]113±3

126±3

137 + 3

181+4

189 + 4

252 + 5

119 + 3

l. Eh, m

ta 46, [

eben, F.

Na200.44±0. 020.92±0.050. 96±0.051. 24±0. 061. 28±0.062. 14±0. 111. 52±0.08

at Gorleben, F.Eh

[mV]4 4301 15

0 3701 15

9 3501 15

9 4001 15

9 2851 15

8 190I 15

8 2701 15

59-47

R. G.

KzO1. 05±0.050. 82±0. 040. 26±0.010. 11±0. 010. 64±0.031. 19±0.060. 37±0.01

R. G.Concentra

Na K0. 35 0. 030. 02 0. 01

11. 5 0. 060.5 0.01

3. 01 0. 050.15 0.01

1. 30 0. 050. 07 0. 01

1.460. 07 <0. 002

1377 10. 34 1 3 0 . 5

2618 23. 27 8 5 1 . 2

ncen t r a t i on of• polye thylene tube . 3g/7.• sh ie lded Ge(Li) de t ec to r

Mg0. 100. 01

0. 070. 01

0. 110.01

0. 130.01

0.090. 01

22 .81.1

34. 31. 7

1989i the

Main Chemical Composition[%]MgO0. 16±0. 010. 12±0.010. 29±0.010. 31±0. 020.42±0.020.05+ 0.01

0. 17±0.01

m)

CaO Ah0. 36 5.±0. 02 ±C0. 23 5.±0.01 ±C0. 33 6.±0. 02 ±C0. 42 7.+ 0. 02 ±(

0. 17 7.±0.01 ±C

0. 44 6.±0.02 +(0. 80 6.±0. 04 ±C

ions[mmol/l]Ca

0. 85 0.0. 09 0.

0. 60 0.0. 06 0.

0.35 00. 04 0.

0.78 00 .08 0.

0. 60 00. 16 0.

51. 9 02. 6 0.

46. 9 02. 3 0.

Cs in t he5ml,for

Sr Fe001 0.002

0005 0.001

001 0. 0050005 0.001

001 0. 0010005 0. 001

001 0.0100005 0. 002

0010005 <0. 001

24 0. 07001 0. 005

20 0.01001 0.002

03 SiO2 TiO?60 91..11 +074 91..11 ±0.53 90.. 13 ±010 90.. 14 ±080 88.. 15 ±006 88.. 12 ±073 89.. 13 ±0

Mn0. 00280. 0007

0. 00070. 0003

0. 00400. 0002

0.0120.002

0. 00050. 0003

0.0600.015

0.0250.005

7 0. 019 ±0.011 0. 039 +0.017 0.019 +0.01

1 0. 139 ±0.028 0. 109 ±0.02

8 0. 179 ±0.03

8 0 .029 ±0.01

Cl NO,0. 62 0. 0060. 03 0. 001

10. 2 0.030 .5 0.01

2. 20 0. 0020.11 0.001

1. 15 0.0020. 06 0. 001

0. 70 0. 030. 04 0. 01

143143 <0.001

290087 <0.001

spiked groundwater : 10"3 samples each10m in.

PJOJ

0. 07±0.010.03±0.010.03±0.010.01±0. 010. 02±0.01

0.05±0.010. 01±0.01

HCO,1. 1 0.0. 1 0.

2.6 0.0. 1 0.

1.9 0.0. 1 0.

1.9 0.0. 1 0.

2. 1 0.0. 1 0.

3. 1 20. 2 0.

Geosphere

MnO0.06±0. 00. 12±0 .0 '0. 10±0.00. 10±0. 00. 10±0.00.08±0.00. 12±0.0 '

Fe2O3

0. 54±0.050. 86±0. 090. 76+ 0.08

0.45> ±0.05

0. 67> ± 0 . 0 7

1.02' ±0. 10

0.45±0. 05

50, Si Oz PO,34 0.

05 0.

01 0.01 0.

05 0.01 0.

02 0.01 0.

01 0.01 0.

5. 1 0.

8 0.

3. 7 49. 6 0.0. 2 1.

8DlOl/l

5 0.

24 0. 00605 0.001

37 0. 02607 0. 003

43 0 .01608 0. 002

37 0 .01007 0.001

4208 <0. 003

1202 <0. 003

1403 <0. 003

- 1 1 7 -


6 969-2

A

/

K H. LiChemis

hM.t.0 :l-90days, -^JIS/O.

cser and TH. Steinkopftry of

Radioch

• AfterSampl

Gl/SlG2/S2G3/S3G4/S4G5/S5G6/S6G7/S7

• AfterSampl


fc[ml/g]1 weeke pH

8.6.7.8.8.6.7.

0962091

mica

fRadioactive Cesium in theActa 46, 39-47

Adsorptionof equi1ibrat ionEh[mV]

390340320380315210290

3 months ofe pH

8.6.7.8.8.6.7.

0962091

Eh[mV]

390340320380315210290

CEC[Aieq/g] wi

5.0 + 0.71.0 + 0.21. 8 + 0. 50. 7±0. 20. 5 + 0. 25. 2±1. 13. 8±0. 8

cqui1ibrat ionCEC

[/xeq/g] wi

5.0 + 0.71. 0 + 0. 21. 8 + 0. 50. 7 + 0. 20. 5±0. 25. 2 + 1. 13. 8±0. 8

1989

thout filt.

50 + 53. 6 + 0. 418 + 35 + 1

3. 6±0. 50. 9 ± 0. 10. 2±0. 1

thout filt.

54 + 54. 5 + 0. 521 + 37 + 2

4. 0±0. 51.0 + 0. 10. 3±0. 1

45Aim/Mil lipore)

Hydrosphere

Kd(Cs)0. 45Aim-fi

177 + 85. 7±0.55±318 + 316 + 2

1. 2 + 0.0. 3±0.

Kd(Cs)0. 45 //• m—f i

233±127. 1 + 1.130±1028 + 419±2

1. 7 + 0.0.4 + 0.

and

It.

6

11

It.

1

21

in the Geosphere

0. 002Aim-f

278±188. 5 + 0.79 + 825 + 322 + 4

1.3 + 0.0.3 + 0.

0. 002Mm-f

360 + 289. 5+1.154 + 2141 ±428±41. 9±0.0. 4 + 0.

ilt.

9

11

ilt.

3

11

118


7 0

A

ffl

%.

ft

nv

K. H.

?nI (MLieser and TH. Steinkopff

ChemistRadioch

A*'J7#

Sed.SIS2S3S4S5S6S7

t&

ry ofimica

it;

Radioactive Iodine inActa 46, 49-55, 1989

the

45/zm/Mi llipore)

Hydrosphere and in the Geosphere

Org. C[mg/g] Carbonate[w%] Carboniferous particles[mg/g]0111161

9±02 + 02 + 09 + 00±04±07±0

)H. Eh,

1 0.4 + 01 0.5 + 01 1.2 + 02 1.6±01 0.3 + 06 1. 9±02 1.6±0

Groundwater Consumption ofGlG2G3G4G5G6G7

• After varSample


• DifferentSample

G2/S2G3/S3G4/S4G6/S6G7/S7

1/g

7. 6±0. 4102. 9 + 5. 146. 8 ±2. 348. 3 + 2. 412. 5±0. 622. 1 + 1. 126. 8+1. 3

Adsorpt ion

. 1

. 1

. 1

. 1

. 1

.22

KMnO4[mg/l]

0. 5 + 0.0. 9 + 0.0. 9 + 0.2. l±0.0. 3±0.5. 9±0.1. 7 + 0.

Concentr

cr0. 62 + 0. 0310. 2 + 0. 52. 20 + 0. 111. 15 + 0. 060. 70 + 0. 041431+432900 + 87

• 3g/7. 5mlious times of equilibration (meansPH

7.87.57.88. 18.06.97. 1

EhLmV]

410360330390300210290

after Id

0. 22 + 0.050. 13 + 0.050. 15 + 0.051. l±0. 2

0. 14±0. 020. 35 ±0. 150. 14 + 0. 05

pretreatment of the

Kd(I)after 30d

0. 58 + 0.7. 7 + 0.

0. 95±0.3. 1+0.

0. 36±0.1. 20±0.0. 42 + 0.

sediments

158155041506

lll2162

at i on[ramol/1]

r(4+1) X 10"5

< 2 X 1 O 4

(5+DxiO'5

(4+1) X 10 5

(3+l)X10"s

0. 0034 + 0. 00080.0061 + 0.0012

of 3 determinations)

after 90d

2. 4±0. 27. 5 + 0. 511. 5+1. 540+15

1. 60±0. 062.5 + 0. 5

0. 70 + 0. 10

(40d-mean of 3no treatment 110°C/24h before

7.51.5

+ 0. 8±0. 2

4.4 + 0.41. 6 + 0. 20. 5±0. 1

0.38 + 0.0. 70 + 0.2. 2 + 0.1. l±0.

0. 30±0.

05104405

determinations)use WashGLOO&dry before use

0. 23 + 0. 100. 26 ±0.050. 15 + 0.050. 05 + 0. 010. 02 + 0. 01

- 1 1 9 -


:100rpmX20hours, jl'L>:fr8t/3500rpin + 3 i i / 0 . 45M

7 1

H. Yasuda, S. Ambe and S. UchidaDistribution Coefficients of Platinum Group Metals between Soil Solidand Liquid PhasesEnvironmental Technology, Vol.17, 1151-1154 (1996)

A

CEC[mmol/kg] AEC[mmol/kg] EXC(K, Ca) [mmol/kg] (Al, Fe) [mmol/kg] (C, N) [g/kg]120 1.5 5.2, 34.7 132, 145 14, 1.2

. Eh.' X ^ g g - C f e t c z K L / c M z K , 0. 45/2 m-membrane f i

pH EC[mS/cm] C a t i o n Cone. (Na\ NH1\ K\ Mg", Ca2t) [mmol/L]4 . 5 0 . 0 6 5 0 . 3 2 7 0 .096 0 . 0 1 3 0 .041 0 . 0 4 4

Plastic bottle(50ml), soil 3g, solution 30ml + multitracer 0.2ml21CCGe^tBi§(Ortec, GEM-30185)

... Adsorption

Kd(min. median max. geometric mean)

10lRh189Ir191Pt

121515

0.1.

12

580

3.2.

22

18

291183

4.3.

24

00

- 120 -


:150rpmX7days, + 45//m)

7 2

H. Y a s u d a , S. U c h i d a , Y. M u r a m a t s u a n d S. Y o s h i d aS o r p t i o n o f M a n g a n e s e , C o b a l t , Z i n c , S t r o n t i u m , a n d C e s i u m o n t oA g r i c u l t u r a l S o i l s : S t a t i s t i c a l A n a l y s i s o n E f f e c t s o f S o i l P r o p e r t i e sW a t e r , A i r , S o i l P o l l u t . , 8 3 , 8 5 - 9 6 ( 1 9 9 5 )

A

A'Upaddy soils, 18 upland soils)?:

Water Cont. pH(H20)[L/kg]

Al l 0 . 0 2 5 5 .85Upland 0 . 0 2 4 5 .85Paddy 0. 025 5. 85

CEC & EXC(Ca, K) & (Ca, K, Fe, Al)[mmol/kg]

121 34. 5, 2. 5 293, 240, 667, 3192107 29 .0 , 2 .5 322, 205, 679, 3214137 41 .0 , 2 . 4 265, 275, 653, 3170

NH" (C, N)[L/kg] [g/kg]1.94 15.6, 1.51.23 13.1, 1.33.05 18.6, 1.8

H, Eh ,

pH4.5

EC[mS/cm]0.065

Cat ion Cone. (Na\0.327 0.096

, 0. 45 i±

0. 013Mg!t, Ca2t) [mmol/L]0.041 0.044

Polyethylene bottle(50mlK soil 3g, solution 30ml + lOkBq each of 5nuclides

Ge^tH§s(Ortec, GEM-30185)

... Adsorption

Kd(All)/Median KdCAll. Upland, Paddy)/Mean

54Mn6 0 Co6 5 ZnS5Sr

137Cs

27117351756

1631896

_1837^2027,

166,1849,

_

1914!2317,

156,2109,

_17621770177

1626

- 121 -


7 3

B

SO

ft

KURRI-KR-1,

A U 7 # c D t j S i

37-40 (1995)

•Hemati te , Magnetite, Calc i te ( 0

ifeT7K^tt(pH. Eh. * # - r ^ > i S S . &&m)• 0.OOlN-NaCl,

torn

# E « * [ H / * ] . .

Kd(Se) . . . 0*

HematiteMagnet i teCalci te

Kd(Cs) ... m*

Hemat i teMagneti teCalc i te

0. 001N-NazS04 (^©ffi

a j t = 40ml/lg, 15t:

. Adsorption

0. OOlN-NaCl160, 150110, 10040, 40

L 0. OOlN-NaCl300, 400400, 400

0, 0

mmc£?J f 8 S # , 1995^10^30-310

tt±£ o it A)

0. 001N-NazS0460, 6060, 6030, 30

0. 001N-Na2SO4500, 500400, 400

0, 0

- 122 -


7 4

B

ffl

KURRI-KR-1

* ^

ifeT7K^'l4(pH.

#B2fi*Sc[ml/g] •

mmtt[cm'/g] fi

10

fflj±[cm3/2. 55

102550

tta*, 37-40 (1

fine30cm;0

Eh, rt£tracer

sand

:1ZiI)

. . Adsorpt

37

1014

g]

fl[da^

995)

(10

ion

/s]

r (Kd11368

.0

. 8

. 9

m

&f&.

M.

ffiClK

"Htm

*m

\5°C0. 60.71. 52. 1

Kd(r)32t1. 82. 13. 04.0

S EC[mS/cm])0.0.0.0.0.

12812115112111

&(

552.1.3.2.

1

t2502

gfe#, 1995^10^30-31

25mmJ^T^t)^

ist:6

151620

I) . #

Kd(I03

32t;8898

B

-)55t5.2334

IO;|" (Kd & EC[mS/cm])8

12108

10

0.0.0.0.0.

1351312118117

- 123 -


:3-168hours)

mm7 5

• • C oRADIOISOTOPES, 4 5 , 753-760 (1996)

A

^ [g/cm : i]2 .67

f [mVg] CEC [meq/lOOg] EXC (Kf, Naf, Mg2), Ca") [meq/1 OOg]1.5 1.2 0 .09 0 . 0 3 0 . 1 5 0 . 6 0

. Eh.0. Olniol/din'-NaClzKi^^C^llSpH 4, 7, 10)

25T:. = 200cmVl0g.

. . . Desorption

60Co Desorption Ratio

Mt^mm[hours] #)$pH Desorption RatiotX]

3168

3168

3168

4477

1010

5.07.37. 17.99. 78. 5

8.02. 82. 71. 70.41. 2

Kd&L

- 124 -


:60X168hours)

7 6

A

T. Tanaka, S. Nagao, Y.Sakamoto, T. Ohnuki, S. Ni and M. SenooDistribution Coefficient in the Sorption of Radionuclides onto AndoSoil in the Presence of Humic Acid - Influence of the Molecular Size ofHumic Acid -J. Nucl. Sci. Technol., 34, 829-834 (1997)

* Utz Ando s o i l . 37-1000;* mKffjfUfrft, I$K *

A ^ ^ f t CEC, AEC Organic-C Chemical Compos i t i on [%][g/cm3] [meq/100g][mgC/100g] SiO2 AhO:. T1O2 Fe2O3 CaO MgO FeO Na2O foO P2O5 MnO H2O0. 69 17. 2 1. 9 3200 51. 59 21. 28 1. 23 3. 66 1. 15 1. 71 6. 54 0. 59 0. 59 0. 32 0. 15 11. 24

, Eh,• 0. 01mol/l-NaN03f£$ttCHA(Humic Acid, 3. 5, 13. 0, 35. 0, 65. 5, 131mg/l)

5(-6. OHCiHSE.• MCo, S5Sr, "'km^BiN* (lkBq/ml = 4X10 9 , 4X10"\ 8X10 8 mol/1)

pH5.

$£@J£ = 50ml/2. 5goORTEC r - r a y de t ec to r 0

HAJtS[mg/1]

0. 03.5

13. 135. 065. 6131

™Co

580580480580600340

Adsorption

Kd85Sr

525255657580

"'Am

350180100605035

- 1 2 5 -


:168hours, 4 5 M m - m e n i b r a n e f i l t e r )

nm m7 7 JAERI-Research 98-018

B

[mgC/lOOg]

t t M CEC[meq/10Og] Che. Comp. ffl (SiO2. AI2O3, TiO2, FejOs. CaO, MgO, FeO. NajO, K2O, P2O5, MnO, H2O) HA

2. 65 1. 8 73. 88 10. 85 0. 23 1. 47 2. 31 0. 86 1. 12 1. 58 0. 40 0. 05 0. 05 3. 35 1

2. 75 3. 4 74. 83 12. 37 0. 30 3. 80 2. 43 1. 82 1. 72 1. 72 0. 42 0. 06 0. 07 4. 07 2

2. 81 24. 8 38. 48 14. 63 0. 77 18. 71 9. 65 5. 24 2. 88 2. 22 0. 87 0. 13 0. 08 3. 53 <1

2. 57 16. 5 62. 89 14. 15 0. 34 4. 99 3. 20 1. 68 1. 29 2. 56 2. 18 0. 05 0. 06 6. 34 <1

Eh,

PH

6.4

6.5

8.6

6.8

Eh [mV]

420

470

320

450

1 0 : * B q / c m 3 ( 2 x 10 ' m o l / 1 . 8 x 10 s m o l / l ) I

Cone, [ m g / 1 ] (K*. Na*. Mg2t, C a " HCOs^ Si02, Fe, AD HA[mgC/l(

0 . 1 7 2 . 2 0 . 1 3 0 . 1 5 2 . 8 5 . 9 <0. 05 <0. 5 <1

0. 32 3. 0 0. 23 0. 55 3. 6 7. 4

4 . 7 4 8 . 2 0 . 1 9 0 . 7 9 136 3 4 . 8 <0. 05 <0. 5 <1

1.5 5. 9 0. 60 0. 87 8. 3 35. 4 <0. 05 <0. 5 <1

= lOcm'/O. 5g

A d s o r p t ion

Desorplion

pH Eh [mV]6. 4 3409.0 2207.2 310

pH Eh[mV]6. 4 3409.0 2207.2 310

Kd(2"Np)2. 37.44. 1

Kd("7Np)132117

Kd(Z41Am)540029002000

Kd(24'Ani)>10000>10000>10000

- 126 -


: 1 6 8 h o u r s , 5 j i / 0 . 45 w i n - m e m b r a n e f i l t e r )

7 8 JAERI-Research 98-017

[mgC/ lOOg]

tfcS2.69

2. 65

2. 75

2. 72

2 .73

2. 74

2. 81

2.57

C E C [ m e q / 1 0 0 g ] Che. Comp. [ « (S iOj , AI2O.1, T1O2. FeiOs, CaO, MgO, FeO, NazO, K2O. P2O5, MnO, H2O)

1.9 7 8 . 2 0 8 . 3 1 0 . 3 6 2 . 4 6 1 .95 0 . 9 8 - 2 . 5 5 2 . 7 0 - 0 . 0 7 2 . 0 4

1.8 7 3 . 8 8 1 0 . 8 5 0 . 2 3 1 .47 2 . 3 1 0 . 8 6 1 .12 1 . 5 8 0 . 4 0 0 . 0 5 0 . 0 5 3 . 3 5

3. 4 74. 83 12. 37 0. 30 3. 80 2. 43 1. 82 1. 72 1. 72 0. 42 0. 06 0. 07 4. 07

17. 2 51. 59 21. 28 1. 23 3. 66 1. 15 1. 71 6. 54 0. 59 0. 59 0. 32 0. 15 11. 245.2 76.72 8.60 0.70 3.80 0.06 0.28 1.49 0.08 0.39 0.07 0.01 7.16

8. 7 66. 57 19. 71 0. 53 4. 79 0. 01 0. 41 0. 32 0. 09 1. 25 0. 07 0. 03 5. 89

24. 8 38. 48 14. 63 0. 77 18. 71 9. 65 5. 24 2. 88 2. 22 0. 87 0. 13 0. 08 3. 53

16.5 62 .89 14.15 0 .34 4 .99 3 .20 1.68 1.29 2.56 2 .18 0 .05 0 .06 6.34

HA

1

1

2

1347

38. 7

Eh.

* > 7 K H ! : " N p , !38Pu, 103Bq/cm3('

PH

7. 5

6. 4

6. 5

6. 4

4. 8

4. 8

8. 6

6. 8

Eh[mV]

240

420

470

370

370

360

320

450

Cone, [mg/1] (K+, Na*, Mg", Ca ! t. HCOs, SiOz, Fe, AD

1. 4

0. 17

0. 32

7.9

0 .80

0 .20

4. 7

1.5

0. 600. 130. 230. 500. 10

0. 40 <0. 1048. 2 0. 19

5. 9 0. 60

1. 22. 23.00.500.40

0. 15

0. 55

3. 5

1. 4

<0. 10

0. 79

0. 87

2. 92. 8

3. 6

1. 3

1. 3

0. 50

136

8. 3

5. 97. 4

12. 5

1. 7

2. 8

34. 8

35. 4

0.9

<0. 05

<0. 05

<0. 05

<0. 05

<0. 05

<0. 05

1.3

<0. 5

<0. 5

<0. 5

<0. 5

<0. 5

<0. 5

HA[mgC/l)

1. 4

= l O c m ' / 0 . 5 g, 241Am)

600TR(218Pu)

Adsorption

Kd (23TNp)Kd("8Pu)Kd (!4lAm)PH

12180330

2. 3780

9500

427100

>10000

3. 4 5. 03200 4005500 >10000

7. 5-8. 0 6. 5-6. 8 6. 0-6. 4 4. 8-5. 0 4. 8-5. 2

7. 4 4. 1200 210560 1800

8. 6-9. 1 6. 8-7. 2Eh[mV] 240-300 340-470 350-400 400-420 400-410 220-270 270-310

- 127 -


7 9

A

vflllMi

All

F££ ([UfcSli: "5 :60rpmX

T. Tanaka and S. MuraokaSorptJ.Rad

• c o a s t a l

ion Mechanisms ofiochimica Ada

^SftWHftiKftsand, ando so i 1

• tuff, sandstone ( T t t )tfc

Coast. S. 2.

Tuff. S. 2.

2.Ando So. 2.

Yellow. 2.

Reddish 2.

Tuff 2.

Sandstone 2.

id-uaJTB i-- -f-

Hfe±

P>g

• 25'C, 71• ORTECIS

[ (H, ivd 1 v

Adsorpt ion

Kd (Z3!Np)Kd (™Pu)

Kd ("4 Am)

Desorpt ion

Kd(!3;Np)

Kd (iISPu)

Kdf'Am)

H7Np, M"Pu

lmmi^TiS CEC[meq/100g] Che. Comp. [W (SiOz.

69 1. 9 78.

65 1.8 73.

75 3. 4 74.

72 17 2 51

73 5. 2 76.

74 8 7 66

57 16 5 62

81 24.8 38.

l(pH, Eh. VkU-i-Xy'-B.

pH EhOnV]

7.5 240 1.4

6.4 420 0.17

6. 5 470 0. 32

6. 4 370 7. 9

4. 8 370 0. 80

4. 8 360 0. 20

6. 8 450 1. 5

8. 6 320 4. 7

20 8. 31

88 10. 85

83 12. 37

59 21 28

72 8. 60

57 19. 71

89 14 15

48 14. 63

m. &m(I2 ; t !Np,

0 .36

0. 23

0. 30

1 ' 3

0. 70

0 53

0 34

0.77

m)mPu

Cone, [mg/1] (K

1. 2

2. 2

3.0

0.50

0.40

0.40

5.9

48.2

tfflit = lOcmYO. 5g

Coastal Tuffaceous12 2.3

230 780

1200 5800

25 13

2000 5400

MOOOO M0000

0.60

0. 13

0. 23

0. 50

0. 10

<0. 10

0. 60

0. 19

- ^ ( m N p , "

Ando42

9000>10000

72>10000MOOOO

i ^ :

o u r s > 5 i M i / 0 . 4 5 ^

a n d Ml

yellowi

M2O3, TiOj

2. 46 1.

1. 47 2.

3. 80 2.

3 66 1

3. 80 0.

4 79 0

4. 99 3

18. 71 9.

, Na , Mg .

8. 8

0. 15

0. 55

3.51.4

<0. 10

0. 87

0. 79

Am)

x^TRI-

Yellowish

3.445009500

1398009500

\m in Sedi

sh soi 1,

.m-mil l ipore fi

mentary

reddish

Fe2O3, CaO, MgO, FeO, NazO,

95 0. 98 -

31 0 .86 1. 12

43 1. 82 1. 72

15 1 71 6 54

06 0. 28 1. 49

01 0 41 0 32

20 1. 68 1 29

65 5. 24 2. 88

2. 55 2. 70

1. 58 0. 40

1. 72 0. 42

0 59 0 59

0. 08 0. 39

0 09 1 25

2 56 2 18

2. 22 0. 87

fetoU 103Bq/cm3CIl?

Ca", HCOs", SiO2, Fe, AD

2.9

2. 8 5. 9

3. 6 7. 4

1.3 12.5

1.3 1.7

0. 50 2. 8

8. 3 35. 4

136 34 .8

0. 9 1.

<0. 05 <0.

<0. 05 <0.

<0. 05 <0.

<0. 05 <0.

<0. 05 <0.

<0. 05 <0.

•CARB 1600TR("8Pu)

Reddish5.0

430>10000

102100

>10000

Tuff4. 1

2808200

17420

>10000

l t e r

M a t e r i a l s

s o i l (S

M

0.

0.

0

0.

00

0.

Ic

3

5

5

5

5

5

5

[mgC/lOOg]

), P2O5, MnO, H2O) HA

0. 07

05 0. 05

06 0. 07

32 0 15

07 0. 01

07 0 03

05 0 06

13 0. 08

Desor

2.

3.

4.11

7.

6

3.

HA[mgC/l)

1

<1

<1

<1

<1

<1

<[

4

Sandstone7

16007200

201500

MOOOO

4

04 8 .7

35 1

07 2

24 1347

16 38. 7

89 <1

34 <1

53 <1

- 128 -


8 0

A

T. Ohnuki, T. Tanaka, H. Ogawa and T. Yamamo t oRetardation Factor of a Radionuclide for Undisturbed and DisturbedSandy SoilJ. Nucl.Tech., 88, 55-63 (1989)

Sandy soil(3£fcfc&, $J£cfc O5OOm0J&&T$®), * 4 i & ± « > f£?S 1.Sampling Depth[m] A 0. 5 - 1 . 7, B 1. 7-2. 9, C 2. 9-4. 1 « pH=8. 21CEC & EXC(Mg2t, Ca", Na\ K+) [meq/lOOg]

1. 9 0. 3 1. 6 0. 6 0. 5Chemical Composi t ion[wt%] (SiO2, A12O3, MnO2, CaO, NajO, H20, TiO2, FeO, MgO, K20, 078.20 8.31 0.07 1.95 2.55 1.04 0.36 2.46 0.98 2.70 0.15

. Eh,Distilled water(pH6. 0) + 8iSrCh(110Bq/ml, IX 10"2mol/l)

fr

120cmX30cm(f> Polyvinyl chloride tubeGamma-ray spectrum analyzerFlow rate 1. 5ml/sec, Total 660L

.. AdsorptionKdtt Retardation factor i O R f = H K d X p / 0 , 0 = s x f

Psf

bulk density = 2. 6 [g/cm3]degree of water saturationporosity

Rf s f Kd(8iSr)Sample-A 2010 0.74 0.41 230

B 2420 0.78 0.43 310C 2440 0. 80 0. 42 320

- 129 -


C. K. Park, S.I. Woo, T. Tanaka and H. KamiyamaSorption and Desorption Behavior of MCo, 85Sr and 137Cs in a Porous Tuff: Mechanisms and Kinetics

J.Nucl. Sci.Tech., 29, 1184-1193 (1992)

A

Tuff ( T i t ) , p o r o s i ty=O. 3 1 - 0 . 4 9feg[ Mm]

Sample L 1000-3000 30M 7 4 - 148 34S < 37 39

Main P l a g i o c l a s e , AmorphousS e c o n d a r y Q u a r t z , S m e c t i t e ( 9 % )T r a c e K - f e l d s p a r , Amphibopar

Chemica l composi t i o n [ w t W (SiO-, AhO:., TiO?, FezOs, CaO, MgO, FeO, Na2O, K?0, MnO)6 2 . 9 1 4 . 2 0 . 3 5 .0 3 .2 2 . 6 1.3 2 . 6 2 . 2 0 . 0 6

n, Eh,Synthetic groundwater

pH Component [mg/l] (Na.SCu, NaHCOs. NaCl, KCl, CaCh, MgCIO7.5 9. 17 8.54 9.01 1.58 5.5 7.44

Radioactivity 370 Bq/ml (60Co, 8iSr and i:f7Cs)

25°C

Adsorption DesorptionKd(MCo) Kd(8iSr) Kd(l37Cs) Kd(60Co) Kd(85Sr) Kd(l37Cs)

Tuff-L 841 800 4300 2653 802 6956Tuff-M 2422 792 4871 1531 682 3280Tuff-S 6829 1018 6386 9371 1073 6400

- 130-


8 2

T. Tanaka, K. Sriyotha and H. KamiyamaSorption Mechanism of Radioactive Nuclides in Sedimentary RocksThe Third International Conference on Nuclear Fuel Reprocessing andWaste Management RECOD '91 Proceedings Vol.2, Apr. 14-18 (1991)

B

A*

S a n d s t o n eT u f f r o c kS a n d y s o i l

S a n d s t o n eT u f f r o c kS a n d y s o i l

/ i s a n d s t o n e , t u f f m W & l - 3 m m \ z m ^ } t f > S & ) t s a n d y s o i? g g [g / cm : ' ] CEC & E X C U C Na', Mg", Ca ! l ) [ m e q / l O O g ] t t g f f i « [ m 2 / g ]

2. 81 24. 8 12 2 0 9 1. 6 4 . 0 4 1 . 42. 57 16. 5 3. 8 26 4. 9 4 . 4 30 . 02. 65 1. 8 0. 8 9. 6 1. 9 2. 8 2 3 . 8

C h e m i c a l c o m p o s i t i o n [ w t ^ ] (SiOz, AhOs, TiCh, Fe2O3 , CaO, MgO, FeO, NazO, KzO, PzOs, MnO, HzO)3 8 . 4 8 1 4 . 6 3 0 . 7 7 1 8 . 7 1 9 . 6 5 5 . 2 4 2 . 8 8 2 . 2 2 0 . 8 7 0 . 1 3 0 . 0 8 3 . 5 36 2 . 8 9 1 4 . 1 5 0 . 3 4 4 . 9 9 3 . 2 0 1 . 6 8 1 . 2 9 2 . 5 6 2 . 1 8 0 . 0 5 0 . 0 6 3 . 3 47 3 . 9 3 1 1 . 3 4 0 . 2 3 3 . 8 0 2 . 4 3 0 . 8 8 1 . 1 2 1 . 7 2 0 . 4 7 0 . 0 6 0 . 0 5 3 . 3 5

Eh, &£-f:t>

"Co, !iSr, ''

K*0. 84

Na'8. 6

Mg"1.9

Ca;l

2. 0Cl15. 2

HO6.0»~2

so;'6. 2

5 c m X 2 . 5cm<f>, polyvinyl chloride, _hFlow rate lml/min. Total 5000ml

|5cm

m-membrane f

dw©C

SandTuffSandy

stonerocksoi 1

.. Adsorption

Kd(60Co)8801700

290

Kd(85Sr)63093086

KdTCs)1200

3300460

- 131 -


8 3

T. Tanaka, K. Sriyotha and H. KamiyamaMigration Behavior and Sorption Mechanisms of Radionuclides inSedimentary Sand Stones - Influence of Particle Size and WeatheringJAERI-M 93-109

D e n s i t y [ g / m l ] CEC & EXC(K\ Na\ Mg'\ Ca")[meq/lOOg]Fresh 2.81 24 .8 0 .12 2.1 0 .016 0 .040Weathered 2 .77 35 .6 0.041 0 .34 0 .076 0 .18

C h e m i c a l c o m p o s i t i o n [ w t % } ( S i O z , A h O s , T i O z , FezOa . C a O , MgO, F e O , N a 2 O , KzO, P2O5, MnO, HzO)F r e s h 3 8 . 4 8 1 4 . 6 3 0 . 7 7 1 8 . 7 1 9 . 6 5 5 . 2 4 2 . 8 8 2 . 2 2 0 . 8 7 0 . 1 3 0 . 0 8 3 . 5 3W e a t h e r e d 3 9 . 1 6 1 3 . 2 9 0 . 4 7 1 1 . 8 5 1 3 . 5 4 4 . 9 6 1 . 2 9 1 . 6 7 0 . 5 8 0 . 1 5 0 . 0 8 2 . 6 3

Eh,

K* Na* M g " C a " C l " H C O , ' S O / "0 . 8 4 8 . 6 1 . 9 2 . 0 1 5 . 2 6 . 2 6 . 2

" C o , 8 S S i \ n 7 C s ^ - ^ n ^ ' n 6 9 . 9 , 7 4 . 4 , 5 4 . 8 B q / m l C O j f ffi-e

5cmX2.5cm<2>, polyvinyl chloride, _hT(3 5£im-membrane filFlow rate lml/min. Total 5000ml

Adsorpt

<i1-3

ion

] Porosity0. 500. 60

Bulk density[g/tnl]1.1.

4112

60Co1400880

Kd85Sr

990630

l37Cs49001200

Fresh sand stoneFresh sand stoneWeathered sand stone <1 0.55 1.25 4300 2100 8600

- 132 -


Wfetk

8 4

A

m

£ (

Radioisotopes,

EXC(K\~0.82

Chemica78.20

• Jin

C a 2 t l6.6.1.2.6.9.1.9.1.

1.Mg2t,15

^:3days, mi

43, 389-396

Ca2t) [meq/lOOg0. 30 5. 80

1 composi t ion[wt%] (S8.

Eft

£ [2XOX5x8XOXOX9XOX9x

31

Eh. i

m

. . I

mob10"6

10" 5

10"1 0 4

10"10""10s

1 0 3

10"2

0. 36 2.46 1

v, L/ / _ 0 1 /JN. {-tj"fix.

" • S B t t =

\dsorption

M] K d (230702422119511

^il/3000rpm/20min)

(1994)

]

i ( k AhO3 , TiO2 , Fe2O3, CaO,95 0 . 9 8 2 . 5 5 2 . 7 0

(3700Bq/ml), 4114(3IK!J

200ml/10g, 25°C

85Sr)

44

MgO, Na2O, K2O, MnO, M )0. 07 2. 04

- 133 -


R/168hours. 3s'L (5400G)/20min)

8 5

B

T. Tanaka, H. Ogawa, Z.Li, H. Wang and H. KamiyamaDetermination of Distribution Ratio for fi"Co, S5Sr and "4Cs in LoessMediumJAERI-M 94-077

D e n s i t y [ g / c m 3 ] P o r o s i t y P e r m e a b i 1 i t y [ x 10" 4 cm/s] C E C [ m e q / 1 0 0 g ]2 . 6 4 - 2 . 7 4 4 5 . 3 - 5 3 . 0 0 . 6 4 - 6 . 9 3 1 1 . 7 - 2 1 . 3

C h e m i c a l c o m p o s i t i o n ^ ] (SiO2 , AhO3.Fe2O3.TiO2, CaO.MgO.K2O, Na2O, Co, S r )5 8 . 2 - 6 6 . 0 10 .9 -11 .5 3 . 0 - 3 . 6 0 .63 -0 .70 6. 3-9. 6 1.6-2.2 2 . 0 - 2 . 3 1 .7-2 .0 0.002 0 .03

i. Eh,

pH Eh[mV] m&tt\ Na*. Can, Mgn, Cl". Co, Sr, Cs) [mg/1]7 . 0 7 - 8 . 0 0 336-372 0 . 4 0 - 5 . 0 2 6 4 . 6 - 1 1 0 . 9 2 3 . 0 - 5 6 3 . 5 1 8 . 2 - 1 6 6 . 0

« & ( C 1 - , Co, Sr, Cs) [mg/1] ?IS(CO 32 - , HCOr) [mg-CaC03 / l ]

2 3 . 8 - 5 1 . 9 <5X10" J 0 . 5 8 - 6 . 6 2 < 5 X 1 0 " 0 . 0 0 - 3 7 . 6 1 1 8 . 4 - 2 9 4 . 7

P o l y c a r b o n a t e t u b e ( 2 5 m l ) , ^ @ J t = 1 0 m l / l g , 25°CCWell type N a l ( T l ) d e t e c t o r

60Co85Sr

i:i7Cs(134?)

A d s o r p t i o n980130

3100

D e s o r p t i o n2800

1606900

- 134 -


8 686-1

m

%.

ft

A* t

No.567813141516

No.12345678910111213141516

No.12345678910111213141516

It

1*

JAERI-Researcli

Depth

[m]0. 5

.0

. 52.00. 5

.0

. 5

2. 0

,m

lit:

•5

a.Tf

94-009

Quartz K-feldspar

3025-30

20-25

3025

25-30

25-30

Typical Name

sandysandy

sandysandy

sandysandy

sandysandy

sandysandy

sandy-sandy

sandy

sandy

sandy

sandy

clay loam

clay loamclay loam

loam

clay loamclay loam

loamloam

clay loamclay loam

clay loamclay loam

clay loam

loamloam

loamSpectrometric

Cu0.0020.0020.0020.0020. 0020.0020.0020. 0020.0020. 0020.0020.0020. 0020.0020.0020.002

15-20

15-2015-20

15-20

15151515

Depth

[m]0.1.1.2.0.1.1.2.0.1.1.2.0.1.1.2.

5050505050505050

fdays,

\m /) w

#>±&!|

MineralPlagioclase

2520-25

SiO2

66.59.59.60.61.58.60.59.58.59.60.59.62.58.59.59.

analysis

V Zr

0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.0. 008 0.

02020302040304020404030304040404

Co0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.

002002002002002002002002002002002002002002002002

04062425259064482444085682923254

MSr

0. 030.030. 030. 030. 030. 030.030.030.030. 030.030. 030. 030.030. 030. 03

202025252525

AhO:.11. 4111.02

11. 1811. 25

11. 2810.99

11. 1511.47

10. 9111.01

11. 2711.05

11. 33

11.00

11. 27

11.35

Cr0. 0080. 0080.0080.0080. 0080. 0080. 0080. 0080.0080.0080.0080.0080. 0080.0080.0080.008

1 Calci6- 1

101010510

7- 8

7- 8

FejOs

3. 613. 023.07

3. 31

3. 232. 99

3. 31

3. 403. 15

3. 113. 143. 48

3. 14

3. 07

3. 15

3. 37

Ni0. 0020. 0020. 0020. 0020. 0020. 0020. 0020. 0020. 0020.0020. 0020. 0020.0020. 0020. 0020. 002

a-(K/6000rpm/20inin)

115/

composition [%]te Ch1 or i t£

55-10

55-10

5555

> OtherClay I

5101010

10-15

1510

10-15

3ioti te

-2-222

1-2222

Chemical composition [%]FeO1.02

1.361. 01

1. 02

0. 981. 04

0. 860.98

0. 920. 89

0. 980. 98

0. 980. 97

1.01

1. 01

Mn0.080. 080.080. 080. 080. 080. 080.080. 080.080.080.080.080. 080.080.08

Ti02

0. 70

0. 650. 65

0. 65

0.640.65

0. 70

0. 700. 68

0. 63

0.650. 65

0. 68

0. 64

0. 630. 68

Ga0. 0030. 0030. 0030. 0030. 0030.0030. 0030. 0030. 0030. 0030.0030.0030. 0030. 0030.0030.003

Ca(7.9.8.7.7.8.7.8.9.8.8.7.6.8.8.7.

Ti0. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 50. 5

) MgO52 1. 71

09 1.6489 1. 92

91 2.0623 1. 92

89 1. 6496 2. 03

21 1.7157 1. 78

55 1. 89

11 1.99

52 2.2125 1. 78

89 1. 85

30 1. 92

52 1. 99

Be0. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 00020. 0002

K202. 262.20

2. 242. 26

2. 202. 17

2. 20

2. 262. 11

2. 172.05

2. 152. 12

2. 002.05

2. 18

Ba Y

0. 06 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.0. 04 0.

te

1, m.% 4*>

Hornblend Fe-oxide

1-2-1211121

Na201. 70

1. 65

1. 651. 73

1. 731. 73

1. 751. 80

1. 701. 80

1. 932. 00

2.00

1.881. 93

1. 80

1

MnO0. 071

0. 0680. 071

0. 074

0. 0680. 068

0. 0680. 068

0. 0650. 071

0. 0710. 077

0.071

0.068

0. 074

0. 078

2-222-2-222

P2O50. 13

0. 110. 12

0. 110. 13

0. 100. 20

0. 180. 13

0. 11

0. 120. 11

0. 14

0. 18

0. 110. 13

Yb Pb002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.002 0.

0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.0002 0.

002002002002002002002002002002002002002002002002

- 135 -


8 686-2

ffl

/£

mt

JAERI-Research

B. Densi tyNo. [g/cmJ]

1 1.632 1.493 1. 414 1.375 1.456 1.457 1.458 1.439 1.51

10 1.4111 1.4412 1.4213 1.6114 1.4815 1.4216 1.41

Date pH1988/06 8.211988/08 8.071988/10 8.031989/05 8.0361989/09 7.961989/10 7.92

Date CO.,"1988/06 0 .01988/08 15.61988/10 15.41989/05 22.51989/09 9.551989/10 37.58

• N a i r n ) , :

Speci fieGravi ty2.642. 682.642. 692. 722. 732. 742. 742.662. 682. 692. 692. 642. 692. 692. 69

i Eh, ft

Eh ([mV]

310. 8396. 8451. 6330. 7451. 5336. 1

o :H#^?/7days,

94-009

Wtr. Content T.[X]

13. 157.917.238.068.45

10. 178. 80

11.4311.44

6. 397.48. 39

12. 127.456.678. 69

agiO 4]onductanc<

[AiS/cm]460560460510460470

Cone. [CaCO5-mg/L]HCO3"238. 22 1 4 . 0197. 12 0 4 . 52 1 2 . 81 9 7 . 4

E. um

K2. 10.450.400. 320.400.40

Hardness A c i d i t y101.0158. 3158. 7155.8153.8153.8

0.000. 540. 000. 000.000.00

iI'L^$t/6000rpm/20min)

%-hW.

&±&®Porosi

m45. 4548. 5150. 9452. 6050. 7352.0151.4553. 1145. 8650. 1850. 1850. 9245.4548. 7850. 2751. 39

§0

K-

ty

fljj

Permeab l i t y[xioVs] [

6

2. 183.936. 016. 932. 102. 851.601.214.615. 275. 203. 140.641. 211. 791.06

Concent ra t ion[mg/L!Na82.0

12178.871. 5

127. 573. 8

ComSiO?3.54

21.7521.6912.9414.512.75

Ca12.29.28.29.29.29.

220796872329

Mg17.2320.7821. 1619.7419.6419.60

:. [mg/L]COD9.5.0.3.8.4.

206237513566

ml

DO2.296.91.764. 664. 241.50

/lg>

Cl57. 9717. 2012.6515. 9314. 1923. 79

25t:

fflf|

CECmeq/lOOg]

16.21.14.18.12.13.12.12.13.17.17.11.12.14.13.12.

mmSr

0.460.5550. 680.600. 67

09305726393701619117397484242650

M

Co0.0.0.0.0.0.

005005005005005005

I

;§

PH7.7.7.7.

7.7.7.7.7.7.7.7.

t

84858586

8486858784838586

I . m

Cone. [N-mg/L]Mi

5.804. 242.881. 772.880.44

NOs4.3.4.5.

16.17.

807259517109

I0.0.0.0.0.0.

<02

155032006002006163

1 3 6 -


xm8 686-3

No.123456789

10111213141516

ttium ULJ*,

JAERI-Research 94-009

;^C[ml/g] . . . Adsorption

Kd(6"Co)5000530057005700490055005400570052005400570055005200510056005800

Kd(85Sr)77858177759880808875829174817886

iys, ii^§i/6000rpm/20nnn)

twu aauj;-. /nilgai, a*** m

Kd('34Cs)76007900

100009700720092006500730069005800660086006800560075007500

- 137 -


:60rpmX7days)

8 7 37, 51-58 (1995)

A'U . i n s t i l * . . fefi.CementSandy soi 1ChromosorbSand stoneResinZeol i teSi 1ica gelToyoura sand

> h &?l:500~3000Mm)300 m)

7 t l : 177-250/z m)fe: 1000—3000 u m)

50W-X8, f i l l : 149-300Mm)

-> U g : 177 — 250 u m): 250-300//m)

F.h.

0. 84

CementSandy soilChromosorbSand stone

86275.103168

Na\ Mg2t, Ca21,8.6 1.9 2 .0

?[ /^S/cm]ResinZ e o l i t eSi 1ica ge lToyoura sand

cr,15. 2

89. 8213

68. 878. 8

MCo, Si<". HCOJ"

6. 2 6. 2

Synthetic groundwater

\ 25°C. $

CementSandy soilChromosorbSand stoneResinZeoli teSi 1 ica gelToyoura sand

... Adsorpt ionKd(6nCo)

1801 600

1600790

4800016055

1900

Kd(85Sr)326254

730180000

5408027

Kd(i:t7Cs)190

39001100610010000160051

1800

- 138 -


T. Tanaka and T. OhnukiInfluence of Soil/Solution Ratio on Adsorption Behavior of Cesium onSoilsGeochem. J., 28, 369-376 (1994)

A

A UCoastal sandy soi 1 (M6JflfC^Ml5f*K aS£3m<fc

f i g l . 68mm^T\ l£# ) l f l j # (Major: Quartz, Medium, P l o g i o c l a s e , Minor:K-fe ldspar , Trace:Hornblende, Ser i c i te, Chi or i t e)

Kaol ine(Georgia , U S A T J i ® , pure)S i l i c a s a n d d i f t l U j M t p T f T T ' M . SiO2:96%> AhO3:3X)

, Eh,

7 7 X 3 , 300Bq/ml('37Cs), 25±0. 1*C^M^Jfal Coastal sandy soil = 56daysGamma-ray spectrometry

Kaoline & Silica sand = 3days

.. Adsorption

Na*. Mg", Ca2t)/1^0. 01

50020010050201052

Coastal sandy soil2515-2022-2630

Kaoline9-63. 5-3.53. 2-

Si lica sand-0. 25-0. 20. 15-0. 20. 2

- 139 -


8 9S r

, 1, 169-176 (1995)

A

/t u . mm, s

£ 2. 6 [ g / c m 3 ] I r k ^ f l ' l t 1. 4 [ m V g ] CEC 1. 0 [ m e q / 1 0 0 g ]-X] S iO ? AU0» TiO2 Fe2O3 CaO MgO Na2O K20 MnO H20

7 8 . 2 0 8 .31 0 . 3 6 2 . 4 6 1 .95 0 . 9 8 2 . 5 5 2 . 7 0 0 . 0 7 2 . 0 4

H, E h ,

pH=5. 5, 0. 01mol/l-NaNO3

, 25"C#: r

03123565

.. Adsorpt

* [ppm]

ion

Kd(8iSr)3534313231

- 1 4 0 -


(M&Mto :60rpmX7days, 5ii/5000~300000MW-Mi 11 ipore)

9 0

T. Tanaka and M. SenooSorption of 6OCo, 85Sr, l37Cs, "7Np and 241Am on Soil under Coexistence ofHumic Acid ; Effects of Molecular Size of Humic AcidMat. Res. Soc. Symp. Proc., 353 (1995)

2. 6[g/cm3] tt^jgfft 1.4[m7g] CEC 1. 0[meq/100g]%] S1O2 A I J O J T i O s F e . 0 . C a O M g O N a 2 O K , 0 M n O H ?O

7 8 . 2 0 8 . 3 1 0 . 3 6 2 . 4 6 1 . 9 5 0 . 9 8 2 . 5 5 2 . 7 0 0 . 0 7 2 . 0 4

. Eh,

7 5K ' "CsCl ,

[ B q / m l ] 5 0 0 0 0 50000 5 0 0 0 0 5 0 0 0 0 5 0 0 0 0[ff lol /1] 2 X 1 0 " 2 X 1 0 6 3 X 1 0 " 7 8 X 1 0 ' 3 4 X 1 0 6

. 5g, 25°C, pH=5. 5

.. Adsorption

KdC'Co) Kd(8SSr) Kd(l37Cs) Kd(mNp) KdC1lAm)[D0C-mg/l]

0 250 32 1100 2 1503 170 31 1100 1 2213 80 30 1100 1.5 1135 23 30 1200 1.4 6.565 11 30 1100 1.3 5

- 141 -


: tt:7days)

1 S i S

9 1 R a d i o i s o t o p e s , 4 5 , 2 9 3 - 3 0 2 (1996)

A

No. 1 :

No. 2 :

No. Sf f i CEC[g/cm:1] [meq/lOOg] Si0- AhO» Ti0 : FeA/FeO CaO MgO Na ;0 LO P.O., MnO H:0

1 2. 6 1. 9 78. 20 8. 31 0. 36 2. 46 1. 95 0. 98 2. 55 2. 70 - 0. 07 2. 042 0 . 6 9 17 .2 5 1 . 5 9 2 1 . 2 8 1.23 1 0 . 2 0 1.15 1.71 0 . 5 9 0 . 5 9 0 . 3 2 0 . 1 5 1 1 . 2 4

, Eh.8 3SrCh, 24l

^ S : lOOOBq/ml60Co 3 x 10 9mo 1 / 1 ,

: 0-130mg/l

SiSr 3X lO^mol / l , L'4'Am 8X10-Smol/1

pH=5. 5,

Adsorpt ion

[mg/1]0312356503123565

Kd(6nCo)

270170802312600480580600340

Kd(85Sr)

33323030305054607080

Kd(24lAm;

16022126. 55

350110655534

- 142 -


9 2

K. Yamamo t o, T. Yanagi, M. Senoo and Y.SakamotoSorption Behavior of Neptunium(V) Ion on Clay SorbentJ.Nucl. Sci.Technol. , 27, 626-630 (1990)

• Beg .Takadate loamOuffaceous loam), J&&,

, Eh.

Rd=l+ (1-£) p K d / e £ : void fract ion of column sorbentp : loam density = 2. 64g/cnf

... Adsorption

pH Flow rate Column length Void fraction

3. 15.56.47. 59.0

11.07. 07.06. 9

[ml/min]0. 20.20. 20.20.20. 20. 10. 20. 5

[mm]777775777

fract ion

0. 720. 720. 720. 700. 730. 780. 690. 700. 71

Kd

31640220370

1100706248

Dispersion Coeff[cmVsec]

1.21.61.02.01.35. 12.81.64.0

- 1 4 3 -


Wfetk '6months,

9 3

137C s . " C iJAERI-memo 05-183

y >? u t&ffilt

D

nu

- h o \ LTttM,

, Eh.

, SSHJt=200ml/4g

2®

... Adsorpt

PH12. 2912.31

E 12.38n 12.38

PH12.3312.3012. 30

n 12.33

ion

Kd ("Co)134014501690198016901740

Kd (60Co)380042103710427039304180

Kd(137Cs)370390430550620570

Kd('37Cs)550620580690710680

PH11. 9311. 9512. 0512. 05--PH

10. 029. 859. 859. 07--

Kd (60Co)233025302780339029603030

KdCCo)462053007240754073308100

Kd(l37Cs)760840850113011701070

Kd(l37Cs)272029502950320034403500

- 144 -


9 4 JAERI-M 9432

m

B

544

-y

Eh,

(300ml),

Adsorption

C s0. 25-0.0. 25-0.2. 0 -4.1. 19-2.0. 25-0.0. 25-0.0. 25-0.0. 25-0.

4040252525252525

nmmm, w-m)iw^ Kd1 0.357 18.01

10 4.62 11.6510 4.6 11.710 3.6 17.810 4.17 13.9820 11.3 7.7050 34. 6 4.45

100 74.4 3.44

- 145 -


, Jl4>M/6000rpm/30niin)

rn9 595-1

D

I

n

ft

> 9 U - hCEC

[meq/lOOg]

14. 6

18. 6

PH

7. 2

7. 3 2

2

Na

1.4

1.8

EXC[meq/lOOg]

K

1.

1

Ca

2 256

2 272

Mg

4. 4

4. 5

Sr

0.

0.

Dneq/lOOg]

0. 6

0. 7

CO2

0. 8

0.6

CaO A

7. 81

8. 68

ft]82.

80

5

44

m.5.

7.

68

37

2.

2.

:i±S

24

12

S i O ; A h O a T i O 2 F e z 0 3 F e O C a O M g O K 2 O N a z O P z O s M n O H ; 0 ( + ) H i O ( - )

7 2 . 4 4 7 . 5 5 0 . 2 8 1 . 3 7 1 . 3 1 8 . 9 4 1 . 1 4 1 . 2 6 1 . 1 8 0 . 0 7 0 . 0 6 3 . 4 5 0 . 2 7

5 6 . 2 6 1 2 . 8 3 0 . 7 6 3 . 2 0 2 . 9 5 1 2 . 4 2 2 . 2 6 0 . 7 5 2 . 5 7 0 . 1 2 0 . 1 2 3 . 6 4 0 . 1 9

[kg/ra3]

283•fe/>Hkg/m3]

537

& [kg/m3

1350 5. 75 3~4

, Eh,

pH[22°C]

11.9

EC[25°C]

[/iS/cm]

1600

Na* K* Ca2t Mg2* So4! HCOs COs2" OH" Si02 Al3* F e " Fe3*

[mg/ 4 ]

41. 1 40. 2 65. 4 ~ 0 . 1 6. 2 115 55. 7 2. 6 2. 1 ~ 0 . 03 ~ 0 . 03

: 0. 11 —0. 25mm

: 2g, 5g

i"Co

9"Sr

m'Cs 0.

1.

7Kft

5cm3

0cm3

1800g>

2 O°C

- 1 4 6 -


>L>#i£/6000rpm/30min)

9 595-2

D

Adsorption

ABCDE

eft PcZ3 ^y ^7 W — p

m Z/ ty 'J*— b*

h

II[g]52222

$?fl£[ml]100100100100100

10000^432B#fH1432B#fH1432B#Tf^

P H111 0 - 1 1

6 - 81111

AAAABBCCDDDEEE

mm60Co6"Co

137Csl 3 7Cs6"Co

l 3 ?Cs6"Co

137CsMCo

137Cs9 0 Sr6"Co

l 37CsMSr

mmiu c\/g]

————

0. 00270. 00910. 00270. 00930. 00290. 00450.0010. 00290. 00440.001

w-mm9. 2 x 10 4

2. 5 x 10"3

1. 8 x l O 3

8. 2 x 10"3

K d

0. 215

300500

92000

153000

35003013

1000140

- 147 -

IK

T3O

U

i2UJ< 1

m?

CO

\\

AJ

"H4

V

I

§§&

£ 3 TJIijJJJ

Hip"tsr fliis "13

US!

- £ ^ —s _f~>

-fc? — T N- ^ 'rs~ KL_,

^ ^ in

#

JViv>

A•fvV

nrimfl

*

•(IF

I

A J

G

K

IB

m j | ?

Btanlfllzil

«5ftnlr

•

J]Jx Jllx

mm

C O

COCO

C O

C O

- 1 -

f—1

+j

n -^ ^"rS "IS

TMnnr iMDrtr

C O

t — •

ICTi

|

•+•

O H^ - <

K B

"TN *TS

— -

&

oo

CO*

L O

1

IB+1

C O

1

TOT

ft!G r

&

S

C Dc =

• ^

crcua

c_>XUJ

CEC

[S/UID

1 1

[ (

^ Q1 '

CO

1 — '

PI ]

CO

CO

i—i

t o

neq/1

i 1

Xen{=>

CN3

t oL O

- :

(TO

' '

t o

oo

oo

oo

oo

CO

°CD

c~o

s

o

XCJiCD

" ^

OO

CT)

—

cn"^

ooCO

CO

L n

t -

L O

=

13.

Oi—J

X

CO

OO

COL O

CO

—

CO

CT>CO

CO

CO

—

CZ3

CO

on_ J

L)X

L O

, 1

' —

L O

C DCO

1

t —

C S 3

c—

CO

t o

C D

C D

— '

CD

E—«

— 1

C D

Xt o

C DCO

t o

CD

L O

cr>t o

C v j

ooCvj

IT—

• — '

Cvl

CD

L O

CD

OO

t o

OD

C D

XooL O

C D

L OL O

C DC-0

t —LOLO

CD

t o

_ ^

t o

C-3

OO

C D

C O

t o

C D

OO

C D

L O

O J

Iin

i

CO

ion

—'

E

•

en

L O1—'

• — '

1 — '

. ,

oo

od

C O

C O

OJ

^ ^

gioc

CS

L O

<o

L O

C O

od

^ :

^ .

oo

oo

co'

I—,

caQ .

elds

fed

oo

C O

r -

.—i

C O

_ ;

— •

_ ^

od

cd

11

cr>

co

o .C O

111

ral

E3

B

ica

oo• < *

en

C O

C O

_J

C O

CO

, I

CD

- a

nble

I - H

oBC

C O

L O

O O

14.

C O

r—

111

1

1

111

CU

<uX

o

hopy

°

111

11

11

1

1

111

CU

GCU

olAd

OL

—

11

—

—

d >

111

1

1

111

dote

o.

C O

L O

C O

L O

C O

co'

CO

CU

oti

OQ=acu

CU

oo

111

C O

— '

L O

co

CU

orit

C O

C O

C O

- #

CO

CO

C O

COOC1

C O

*

oo

1—(

CUE3IID

A

cd

1

11

C O

L O

C O

LO

od

C O

C O

ral

OJ

E3

e

que

ca

°

CO

C O

^ _

L O

c^

111

111

111

C3CU

EW)cd

« * - 1

C J

o

C O

C O

1

' C O

1 L O

1

in

! U1 Ml

r — (

1

1 ^1 Si jmilHIT

Prt1

^ ^

C J

cd 1t—i tSI

— «C

O O

IOO


9 696-2

D

m

&

%

ft

S iSr6"Col37Cs

(2)3i?

8 5 Sr60Co137Cs

(1)#-

85Sr60Col l7Cs

8 i S r 2.60Co 5.l 3 7Cs 1

Cl : Wfo

Na+

22

±m (

(pfl

5.1.2.

4.1.3.#J

h i

2.5.1.

s#SflClOx0.2)

pH

M

(ffi

&*

, Eh

12x5x5x

£ O

14x5xOx^ P

1Ox0Ox

t •

10'

< 1 0 '

45.5

K5.

103

10 : t

103

103

103

103

H5. 5 -

•$—$•

10'

10'/T\ L 1\fj 1 |

HI

2. Ox

5.01. Ox

H1-H8

1

m

i~7

m

>«

5.4.2.

4.1.3.

-6 .

mi.3.8.

10'

10'

Mg8. (

2Ox9x8x

\&2

4x5xOx5,

mi2

5x00

-+(-yy <

H2

2. 0

5.0

1. (

50ml25CJc

g. i

102

102

102

102

102

10'

m%10'

xlO"'

)

Ca56

riir

mwmm3

2. 5 x l O 2

1. 5 x l O 2

1. O x l O 2

rnwik

m4

4. 9x5. 4x3. Ox

3 [mg/1]8 . 7 x 1 0 '3. O x l O '6.0

pH6. 5

31. O x l O 1

1. 06.0

H32 .0x10" ' 2.

5. OxlO"2 5.

1.0x10" ' 1

H6—H8 : 3

2+

[mg/1]

45.0

4.0

H4

OxlO"2 2

OxlO"3 5

OxlO"2

10'10'10'IS

H5Ox

. 2 x

, 2 x

10"

10"

10s:

9.1.1.

3 2.4 5

"3 1

586xl x

5

2.

H6Ox4x

. l x

10'10

0

10"5

10"5

10"4

[mg/1]

[mg/1]

H72. OxlO"5

5. 4x lO" 6

1. l x l O " 5

2.5.

1

H8Ox4x

1 x

[mg/1]

10"6

10"7

10"5

- 149 -


9 696-3

D

Adsorption

Kd = (Co - 0 V / ( C * W )Kd : ft-IE^Ifc (ml/g)Co: ^#£#J#]J$IIJS: (mg/l)C : 1&$.®WWM!k (mg/l)W : ±mm (g)

Kd = KrfC-1 (3) i t

^ : Lcl£®

[mg/l]86Sr 4700060Co 1500017Cs 3000

Kd=(3) :Kd=Const :

Mus

8 'Srfi"Co

i : t7Cs

[mg/l]46000140002400

SiSr60CoCs

Kd Kd=(3) Kd=Const

1.9 68002.9 51004. 9 42000

[mg/l]

As-1&2

[mg/1]^

[mg/l]

[mg/l]

Kd

1643

670

Kd

9. 6420610

- 150 -


9 696-4

D

Lc,

H, Eh,

85Sr60Col37Cs

14.1.3.

(L-4)7 x l O 4

5 x l O 4

O x l O 3

f£l2

4.1.3.

(L-5)6 x l O 3

5 x l O 3

O x l O 2

34.1.3.

(L-6)7 x l O 2

5 x l O !

2

[mg/1]

0Co, "X

1.5ml/day

0 22mm x HI 70mm

- 151 -


9 696-5

D

. . Adsorption

L-lL-HIL-2L-3L-4L-5L-6Y-DlY-D2

[day]64659564

9

36

[gcm3]1. 141. 161. 241.241.271. 261. 271. 641. 64

[ml]7. 5

10. 131. 518

(44)(12)(30)(24)

54

0. 57

0. 56

0. 54

0. 57

0. 63

0. 49

0. 54

0. 37

0.37

7. 56 . 3

1112

02. 1

241.0

0. 2

Kd60Co7. 56. 3

1112

00 .938.90. 30.2

137Cs

7. 5

6. 3

28

12

3. 4

3. 2

0. 4

Sr=0. 5, Co=0. 5, Cs=0. 6«Ci /g

±*Lc. :

- 152 -


(tm,

9 797-1

D

as n tm tts caora so3[«

YL1YA2

2 . 3

2 . 2

6 . 0 4 . 3

2 8 . 0 2 8 . 2

<0. 05<0. 05

1439.1 0.4 0.03

, Eh,

10. 0±0. 5°C

I 4c8 iSr90Sr

-. 7 s m

- 153 -


9 797-2

D

. . Adsorption

Kd=Cs/Cl

Cs: [nCl/g]

mm Kd

, 4 C

8 5 S r

MSr

YLlYA2YLlYA2YLlYA2

[g]10.010. 010. 010. 010.010.0

[ml]

100100100100100100

ait=100ml/10g

9.

7.

10.

[nCi/ml]

16

95

0

Ht@ [nCi/g] ?StB LnCl/ml]

57. 686. 845. 722.8

10036.0

3. 920.01823. 515. 602. 256. 68

14. 74. 7 7 x l 0 3

13.04. 07

44.45. 39

- 1 5 4 -


9 898-1

D

SGW-B3,

Eh,

±K : 100mlg : £ f t 7 7 X 3 (200ml)

: 20m1/g

- 155 -


9 898-2

D

. . . A d s o r p t i o n

1234567

60Co:

y-i h

( 5:95)(10:90)(30:70)( 5:95)(10:90)(30:70)

& 185Bq/ml

m. 4B 14B 21B 35B 42 BL 343 157 141 156 160L 86 58 58 53 5345#m 753 391 302 324 32420 um — — — — 1730t 153 107 112 116 10345 u m 489 349 408 448 57220 um — — — — 1660L 142 119 142 126 10045 //m 345 327 524 855 85520 m — — — — 3320t 94 64 — — 4145um 213 86 — — 43L 38 23 21 35 5745jum 67 30 23 35 69L 23 37 52 77 864 5 u m 31 40 60 92 116

- 156-


mto, m>b

9 898-3

D

±i

l7Cs :

12

Adsorpt ion

±it±

h

( 5:95)(10:90)(30:70)( 5:95)(10:90)(30:70)

185Bq/ml40 140 210 350 420459 816 643 623 845

30 67 47 113 1193 i l 0 . 45//m 90 183 203 193 220

m — — — — 30615 57 60 89 110

5HO. 45/ /m 104 183 196 389 589m — — — — 733

8 12 15 26 162). 4 5 / / m 201 151 136 146 481). 20/ /m — — — — 1100

623 557 — — 405•3310. 45/ /m 733 881 — — 756

1055 1485 707 382 1000). 45 / /m 2820 816 — 881 957

750 881 316 589 3973310. 45/ /m 421 881 1234 459 589

- 157 -


9 898-4

Kfl-D

t±

i3Ni : Wfflm

±m^>^>^>•v-t

rt. 4

ft

bb4 5 A/20A/b4 5 A/20A/b4 5 A/20A/b4 5 A/b4 5 A/b4 5 A/

Adsorption

mn•hihihi

-A* h-< h-A1 h' h'

370Bq/ml

mm

mm

mm

m

m

m

401052023

912

742

8693104885352

( 5:95)(10:90)(30:70)( 5:95)(10:90)(30:70)

14013820198

12124

1652

11316212318764142

21015729158

17130

9133

15421316223273131

35022122172

16147

7120

14827914821861141

42023326267315142652831012755717126717324969174

- 158 -


9 898-5

D

I PI 1

±m1234567

Adsorption

hhh

( 5:95)(10:90)(30:70)( 5:95)(10:90)(30:70)

14C : 370Bq/ml4B 14B 21B 350 420

19 24 28 24 2811 27 41 35 23

. 4 5 / / m 25 51 45 40 28

. 20/7 m — — — — 279 8 10 10 119 10 12 13 13

•3J!0 . 20/im — — — — 133 i ! f t b 8 7 10 9 95iii0.45/im 8 13 12 11 13

. 20//m — — — — 139 14 12 12 12

/Ym 13 14 13 14 159 8 11 10 11

^ m 9 9 12 12 13S i f i f t L 9 8 10 9 105 i ® 0 . 4 5 / i m 9 9 12 12 12

- 159 -


mw, 20rain)

¥•!$. 4

9 999-1

D

2 - 0 . 15mm

mmmtm o.tti CaOB] S03 [%]

NANBFAFBFC

LALB

2.2.

2.

2.2.

2.2.

20

0

203

4

21.018.5

22.928.016. 6

6.0

15.7

21. 318.3

23.528. 2

16. 64. 3

14. 1

<0.<0.

<0.

<0.1.

<0.1.

050505

051

05

3

1463.1360.

1373.1575.

1484.

1439.1675.

65

997I0

2.10.

9.

1.0.

0.

0.

46

8

1

441

0. 160.780.71

0.070.03

0.03

0.01

, Eh.

\zm-tz>( M ) : 0. 1N-HC1

£ : 20. 0±0. 5°C

i 3 7cs 6 o c o :UC : l. 3, 7, 14, 21, 28,4256, 70, 84 0

- 160 -


20min)

9 999-2

D

l37Cs6"Co14C

Adsorption

441.5

404015

AAB

330

B :

7Cs

"Cs

(50ml)

0Co

NANBFAFBFCLALB

349272

234220

2670322

2879085925364851866900

8250202003670014500729026

4345

0Co 14C

NANBFAFBFCLALB

117163661981990110

24921027514610753

2540259012401390138011598

- 161 -


'L^^i/3000rpm/20min)

1 0 0100-1

D

u m^m (Phase n)

A'U

ABCDE

A, B,D,

Eh,

pH Mg2t Ca" Na* K* SOr" HCO3- Cl [mg/1]7. 4 2. 0 8. 4 6. 8 1. 8 6. 9 34. 1 8. 28.7 — 0 .6 5 2 . 4 0 . 3 12.1 101 .8 19 .07.6 13 .4 5 9 . 0 2 6 . 9 6 . 7 2 1 7 . 5 6 4 . 0 12 .1

10100.5 *' |J7' n^ S : 25°cmm: r^a«> $

, 20min)- (0. 1 jti m)

200100

50

r, 100 .5

10050

: 25°C:1D»E

- ( 0 . 4 5 , 0.- (0. l jum)

m)

- 1 6 2 -


1 0 0100-2

D

®6 ( 1Co,

" ' A n

&MCo

"'Ai

.A

ECEE

BA

AECEE

B#irf

^ffc[ml/giU.n : A,

m85Sr, l37Cs

$m&$\ •• A

m8 i S r , l 3 7 C s

S&-fir$l§!-'4

» M 1 4 C © F|Sf- 1

3. 20. 6

40 .0) 1.6

1. 3

& i2. 21.0

8 8 . 0) 2. 5

0. 4

60CoA 3015ECEE

1215

) 32978

, ifrC

] . . . AdsorptB. C

200/10: 100/10

50/0. 5, D, E

100/10: 100/10

50/0. 5

72.00. 0

ml/g]

ml/g]

142. 80. 0

54 .0 136.00.60.0

72.80. 2

81. 0 11.50.0

85Sr401

59558

567481

0. 00. 0

t14

3. 30.0

59 .01. 20. 2

137Cs5412161820503389615

ion

25

S?m

^ S

(HR/J3C L v j

25'if B

211.60. 0

196.00.00.0

214. 20.0

229. 01. 10. 0

I4C (*50.

2351.0.

3000rpm/20min)

lEMi^ (Phase n

«lS[Bq/inl] "•

1. 70x l0 3

3.00x10'

2. 50x l0 3

« £ [ B q / m l ] -1

1. 70x 103

3. 00 x io'

2. 50x l0 3

30 [day]5.00. 0

235.01. 60.0

30 [day]3.40.0

268. 00.00.0

m) 14C (*r«)3

0 0. 0254

6 0. 00 0. 0

)

fl

l

l

fl

l

l

mm

2,8, 11.

7, 14,21

7, 14,21

> 7° U >

7, 14, 21

7. 14, 21

7, 14,21

Z 4 lAm4300

31037300

1693867

t

16.22,31

,30

30

^JS!Rfl [day]

,30

, 30

30

- 163 -


1 0 1101-1

D

. as.

±J 2. 602.612.66

21. 0

9.88

[g/cm3]1. 77

1.07

CEC[meq/lOOg]14. 822. 255. 3

0.0.

0. 2mm

. Eh,

pH Na Mg K Ca Cl" S042" [mg/1]

7 . 3 6 .2 2 . 6 1.7 1 2 . 8 18 .0 1 6 . 4

Co Sr Nb Cs I Br [mg/1]<0. 05 <0. 05 <0. 2 <0. 1 <0. 1 <1 . 0

0.

: 22±2°C

- 164 -


1 0 1101-2

D

Adsorption

"Co

0Sr

137Cs

0Br

[mg/l]600

1030

1024

1200

1250

[mg/l]591586589

1000981980959979928

125011901480106013001230

Kd pH

60Co9 0Sr137Cs1 29 T

[mg/l]60. 2

102108105121

[mg/l]57. 896. 374. 0

104112

0. 81. 20. 91. 52. 52. 63. 22. 24. 7

2. 13. 0

230. 050. 4

1. 5

1. 5

1. 5

0. 04 —>K 6. 60. 9 —

0. 08 6. 6

Kd pH

2. 72. 72. 76. 86. 8

SftBI[day]

137137137137137

[day]77777

[ml/g]50/1

«

50/1na

50/1aa

5/1na

5/1nn

ftHJt[ml/g]50/150/150/15/15/1

1- v

5

5 ft5 ft5 ft

- 1 6 5 -

JAERI-Dala/Code 2001-005

1 0 1101-3

D

60Co9"SrmCs1291

80Br

Adsorption- 3

[mg/1]5. 98

10. 310. 7

9.812. 6

[mg/1]2. 314.041.41

10.710.0

Kd pH

7977

330

1.4

6.26.26.27.07.0

[day]77777

[ml/g]50/150/150/15/15/1

- 4Kd pH

60Co9 0Srl37CsI 2 9 T

mBr

[mg/1]0.551. 111. 110. 911.00

[mg/1]0. 0620. 370. 110. 911. 00

3901004500.00. 0

7. 27. 27. 27. 17. 1

[day]77777

[ml/g]50/150/150/15/15/1

m5

- 166 -


SCffi

1 0 1101-4

m TO:' - , TO3¥3

D

... Adsorption

"Co

90Sr

'"Cs

129 T

8"Br

[mg/1]600

1030

1024

1200

1250

[mg/1]585567596993982986891886855120012301180106014201370

V>FHM5«

60Co9 0 S rl 3 7 CsI 29 T

[mg/1]60. 2102108105121

[mg/1]53.588.062. 0108112

Kd pH

1. 32. 90.31. 92. 42. 27.57.89. 90. 0•*•0. 080. 9• * •

6. 38.0

37

0.4

1. 5

1. 5

1. 5

7.9

7.9

Kd pH

2. 92.92. 98. 38. 3

[day]137137137137137

: mm& mmm[ml/g]

50/1 ±mw.

50/1 tmw.

50/1 ±.M'&

n n

0/ I JZ.i3.ilX

II ?) W.II II

0/ 1 JZ.i3.vGL

n -5 ^// //

[day]77777

[ml/g]50/150/150/15/15/1

- 167 -


1 0 1101-5Ktt-D

60Co9 0 Srl 37CsI 29 T

80Br

60Co9 0 Sr137Cs129 T

80Br

Adsorptionlft±-3

[mg/1]5.98

10. 310. 7

9.812. 6

[mg/1]0.621. 201.07

12.010. 0

Kd pH

430380450

1. 3

[mg/1]0.551. 111. 110.911.00

Kd[mg/1]0.068 3500. 16 3000. 40 890. 95 *•1.00 l . c

7. 17. 17. 18. 38. 3

PH

7. 87. 87. 88. 38.3

[day]77777

[ml/g]50/150/150/15/15/1

55

m

[day]77777

Kd pH

mm it mmtu[ml/g]50/1 5 m50/1 5 m50/1 5 m5/1 5 m5/1 5 %

60Co9 0 Sr137Cs.»!SOgj.

[mg/1]600

10301024930

1250

[mg/1]551906543

10001120

4.6.

44.JS0

480

. 6

1.1.1.9.9.

66611

[day]77777

[ml/g]50/150/150/15/15/1

;35

5

- 168 -


Wfetk 1 [Hi 1 Tt-t1 Jafc. tffj- / 7 [~j

1 0 2102-1

D

m at ± ^ : uns?

?±Jf- 1 M M Na Mg Ca[mg/1] [ppm]

Co/Sr/Csjlft 1000

1000

Co/Sr/Cs^& 100

100

[±1-3Co/Sr/Csjgffi 10

I/Brigft 10

Co/Sr/Cs*gi

I/Br^gffi

7.88.4

315308

7. 68.4

39. 67. 2

7.48. 0

10. 613 .4

7. 28. 17.89.9

2. 66. 22. 3

2 1 . 8

2. 56. 32. 56.6

2. 54. 92. 53. 5

2.53.72.53. 1

12. 119. 111. 23 1 . 4

12. 016. 91 2 . 0

8. 7

11.911 .811. 74.4

13 .68.9

11. 63.9

2. 23. 7

320212

1. 93. 1

3 3 . 012. 4

1. 82. 05. 02. 0

1. 71. 82.01. 3

- 169 -


&/\* u1 0 2102-2

D

Co/Sr/Cs^ffi

Na

[mg/1]1000 7 . 8

36. 01000 315

480

Mg CaLppm]

2 .6 12 .15. 9 28. 12 . 3 11 .26 . 4 1 7 . 4

K

2. 24 . 0

320144

Co/Sr/Cs^ft

fr

Co/Sr/Cs^iffi

100 7 .6 2 . 5 12 .0 1.931 .2 5 . 3 2 2 . 3 3 .5

100 3 9 . 6 2 . 5 12 .0 3 3 . 033. 2 1. 2 1. 8 6. 2

10 7 .4 2 . 5 11 .9 1.83 2 . 9 2 . 4 9 . 7 2 . 3

10 10 .6 2 . 5 11 .7 5 .02 5 . 8 5 . 5 2 . 6 1.7

1 7. 2 2. 5 13. 6 1. 730. 5 2. 7 6. 2 1. 9

1 7 . 8 2. 5 11 .6 2 .0126 9 .1 3 . 9 1.5

. Eh.

- 1 7 0 -


i a i N, t§ 7 0 , m>b

m1 0102-

D

... Adsorption- 1

"Co

"Sr

l 37Cs

997. 6

1004.0

5SEP :

0Co

"Sr

7Cs

[mg/1]101. 6

100.4

103.0

[mg/1] [mg/1]1010.6 1006

10011016

996986999

965942947

[mg/1]90. 191. 190. 9

94.094.493. 5

76.076. 674. 6

Kd

0. 230.45

0. 340.080. 59

0. 342.03. 33. 02. 8

6.45. 85. 96.03. 43. 23. 73.417171918

6. 9

6.9

6. 9

7. 1

7. 1

7. 1

[day]7

[day]7

[ml/g]250/5

250/5n

n

250/5

7. 2

7. 2

7. 2

mm it[ml/g]250/5

250/5

250/5

7.5

7.5

7.5

- 171 -


S 10, 7 0 , m>b

TO 5

1 0 2102-4

D

Adsorption±mz3

"Co

™Sr

37Cs

7Cs

[mg/1]10. 74

0 . 5 9

1 0 . 7 2

[mg/1]60Co 1. 06

°Sr 1 . 13

1.22

mm:

[mg/1]4.744.814. 88

6. 566.556.67

4.084.004. 13

Kd

636260623131293081848082

Kd[mg/1]0. 13 3600. 14 3300.12 390

¥•%} 360

0.56 510. 57 490.56 51

50270270270270

0. 190. 190. 19

7. 3

7. 3

7.3

7. 3

7. 3

7. 3

[day]7

&[day]

7

WM\t[ml/g]250/5

an

250/5

250/5

WM\t[ml/g]250/5

n

250/5

250/5n

7. 7

7. 7

7. 7

7.9

7.9

7.9

- 172 -


S 1 HI, B,

1 0 2102-5

D

0Co

0Sr

"7Cs

llCo

0Sr

7Cs

Adsorption

[mg/1]1010.6

997.6

1004.0

mmmm[mg/l]101.6

100.4

103.0

[mg/1]100710011005

994986995

897890888

[mg/1]76.576.376.8

82.481.781.8

62.460. 655.0

0.180.480.280. 310.180. 590.130. 306.06. 46. 46. 3

1617161611111111

33354437

7.3

7.3

7. 3

7.6

7.6

7. 6

[day]

[day]7

[ml/g]250/5

mmm

" 7. 2

250/5

" 7. 2

250/5// —" 7. 2

250/5

250/5aa

250/5

7. 5

7.5

7. 5

- 173 -


1 H 1 M, IB ?#Bi/3000G)

1 0 2102-6

D

7C*

6 1 1Co

9"Sr

!37Cs

11Co

0Sr

37Cs

Adsorption— 3

[mg/1]10. 74

10. 59

10. 72

- 4

[mg/l]1. 06

1. 13

1. 22

[mg/l]1. 641. 621.75

3. 483. 433.53

Kd

280280260270100100100

¥•£} 100

3 .45 1103.20 1203.50 100

110

Kd[mg/l]0. 07 7000. 10 4800. 06 830

¥-&) 6700. 29 1400.33 1200. 29 140

¥«i) 1300. 24 2000.31 1500.26 180

180

7. 9

7. 9

7.9

8. 1

8. 1

[day]7

[ml/g]250/5

250/5

250/5n

7. 7

7. 7

7. 7

[day]7

mm it[ml/g]250/5

250/5n

250/5

7.9

7.9

7. 9

- 174 -


1 0 3

to#E.%\

A

h

Smect i46-49

Quartz29-38

Plagioc2. 7 - 5 . 5 2. 1-2. 6

Dolomi2. 0 - 2 . 8 3. 0-3. 5 0. 5-0. 7

0.8 1.4 1.6 2 .0 [ x l 0 3 k g / m 3 ]1.5 2 .1 2 .4 3.0

, Eh.

Cs

ICs


HitDnl/g] %)$,50 7

8868

00 2477368

UX

X

X

X

X

XX

X

xX

X

X

i^[mol/io - 7

1 0 6

lO" 5

10" 4

1 0 3

io-9

109

107

106

105

104

lO"3

' 1 ] Kd4x8x5x4xl x1 x2x3x2xl x3x4x

102

102

102

102

102

103

103

103

103

103

10!

10'

- 175 -


1 0 4104-1

A

ffl

ft

A*U7$

SiO2

TiO2

AhOsFe«O.FeOMnOMgOLhOCaONazOLOP2OaH*OF

MgCaNaK

CEC

mm.

rm a*

cot; lift

Sca-354.45

0. 1716. 10

1.420.050.036.38

0.701. 150. 510.018. 38

65. 724. 232.027. 2

109.7 1

#5mM©C

f 25, 100,

Saz-153.61

0. 1816. 19

1. 370. 060.095.05

2. 610. 580. 530. 01

20. 11

18. 191.4

2. 71. 5

03. 6

s, Sr,

200°CE

iI'L>friii/1 OOOOrpm/10m i n)

1, 53-65

Bengel55. 84

0. 1318. 874.170. 110. 012.04

0. 673.010.590.03

13. 76

5.921.594. 7

1. 1

80. 4

(1994)

X. tt±ftMMfUS. *

31 Kunipia F56. 39

0. 1420.49

1. 830. 370.003. 14

0.473. 180. 110. 01

14.07

9.019.0

103. 02. 0

110.0

mm)

FT24B#fmf5o

Swa-146.56

0.618.3021. 65

0. 100. 021. 96

1. 852. 270. 520.0315. 53

31.666. 6

2.30.6

91.7

NG-143. 95

0.044. 54

32. 150.000.010.87

1.970.000.070.01

17.06

29. 666.5

2.41. 3

89.6

• « ,

J r n g * *

DP I-AW53. 77 [wtX]

0. 292. 731. 140.070.03

21. 731. 702. 713.060. 490.02

12.213. 19

[meq/lOOg]57.590.588.60.8

[meq/lOOg]92.0

- 176 -


1 0 4104-2

A

Sca-3

Saz-

Bengel_31

Kunipia_F

Swa-1

NG-1

DP I-AW

*?v

mm°c251002002510020025100200' 25100200251002002510020025100200

Adsorpti

KdCs22011815126618520377653312811510882865277976611810259

^gi/10000rpm/10min)

7ACZ)53-65

on

Ca665057847174846650575181666675667558650

m(i

Sr373335523345424241464639373541423750423324

994)

Na191818291117181101514132112520201544430

- 177 -


, T. T. Vandergraaf. 8

1 0 5 Canada, Mani tobail+ILac du

$L, K 67-76 (1994)1-f]kiiiiUf

A

: 180-850 u in

, Eh,

pH:9Eh:160mV

: F*Sl¥!i2. 54cm,

- •?•# v v x

- (lOOOnm, 50nm)

mo 1/1] : "7Np 26"8Pu 1. l. 17

adsorption

desorpt ion

day

13101310

Kd ("7Np0. 71. 52.0400600700

"8Pu102030200200200

- 1 7 8 -


1 0 6 , K 91-97 (1994)

A'U

h : > 7 -

H. E h .

pH : 8. 2V/m : 5~l00[ml/g]

... Adsorption

lAml x lO 'M

V/m[ml/g]

510204058

110

Kd

300600600

120012002000

0 .45 ;50012001500260042007000

2nm7600820010000100001000010000

- 179 -


tm1 0 7 99-105 (1994)

A

A* u

Allophane

Attapulgite

Montmori 1 loni te

Chalcopyrite

Cinnabar

[mVg]29317119. 84.792.88

20

74

74

74

Si Al25. 8 22. 1

30. 2

27.9

0

25.0

8.4

15.02. 8

2. 8

Mg

0

6. I

1. 4

0

0. 1

Ca Fe

0 1. 6

0. 4 1. 60 0.9

0 14. 8

0. 1 0. 3

Cu

0

0

0

19.4

0

Hg [wt«000016.0

Eh,

20ml25°C

: 0. 2g0.

AllophaneAttapulgiteMontmori1loni teChalcopyriteCinnabar

. . . Adsorption

1. 0xl0"6M

PH5.98.07.86.37.0

Kd3.070.958015. 12. OxlO4

- 180 -


1 0 8

A

•fill

AEl

>K

ft

T a d a o T a n a k a , S e i y a N a g a o Yoshiaki Sakamoto,

I n f l u e n c e of M o l e c u l a r S i z e of

• 7 D ^ ^ 7 ± (Ando Soi

[g/cm'1]

2. 6

SiOi AI2O3 T1O2

5 1 . 5 9 2 1 . 2 8 1 . 2 3

1. 24

t&T7K#'f4(pH. Eh, &??-i'7

50mlpH 5. 5 - 6 . 0

Ando s o i l : 2 . 5 g25°C

Reciprocal shaker :ORTECrray detector

lumic Acid 0

3< 41 -46 (1996)

!)

FejOa

3.66

60rpm

# K $ $ : [ i n l / g ] . . . Adsorption

lxlO3Bq/ml

Humic Acid[mg/1]

03

123665

132

Kd60Co580580450620650340

CaO MgO

[ w t «

1. 15 1. 71

7days

'Bl^bCDf8iSr525255607580

' o sh ih iko Ohnuki.

1 the Sorpt ion ol

FeO Na:0 KzO

6. 54 0. 59 0. 59

t^-t Ofi)2 4 1Am

350170110605535

S h i w e i Ni , M u n e a k i S e n o o

R a d i o n u c 1 i d e s o n t o Ando S o i l

P2O5 MnO HzO

0 . 3 2 0 . 1 5 1

CEC AEC

[meq/lOOg]

17.2 1.9

[ lumic A c i d—1601201207035

- 181 -


0, »'fr#lW/3000rpm/600sec)

1 0 9 3, 63-70 (1997)

A

A 'J . lafi.

CaO6 3 . 8

LO0 . 5

NasO0 . 4

MgO1.6

OPC

S i O i23.7

> h

AUO»5.0

Fe2O3 SO:,3 . 0 2 . 0

69wt%, 31wt%)1 5 0 / / m

H. E h .

: 50ml

]]t=10 (50ml/5g)2o°c

... Adsorption

: I4C 74kBq, 0. 5ml: ~4xlO" 8mol/ l

Sift [mo 1/1]5. O x l O " 8

6 . 0 x 1 0 "1 . 5 x l 0 " 6

7. O x l O 6

3. Ox 1 0 s

9. O x l O ' 5

4. O x l O 4

1 . 5 x l O ' 3

6. O x l O 2

7. O x l O 1

Kd160016001600150010001100600600

405

- 182 -


;* > h1 1 0110-1

u (IV). 4, 47-55 (1997)

A

: 44, 67,69, 71*

(105~250jum)

. Eh.

Na 2 SO 4 N a H C 0 3 N a C l KCl C a C h , 6H*0 M g C h , 6 H ! 0 [ m g / l ] ion ic s t r e n g t h [mo 1 / 1 ]7 . 5 4 1 9 . 6 9 8 . 5 6 1 . 5 2 2 . 0 2 1 7 . 5 6 6 x 1 0 "

pH : 1. 8 - 3 . 25 0 m l3 0 ° C

: 10~50mg>J7" Df ^ M i l '

- 183 -


Mfefe

1 1 0110-2

, 4, 47-55 (1997)

A

Adsorption

9Pu 2. 7x

PH3.3.6.6.7.7.8.8.9.

11.

774428468-10. 52-— 11. 6

Kd (Ucfcocos^ io f i )7080

150160200500

100010504. 0 x l 0 4 ~ l . OxlO 5

4. 0 x l 0 3 ~ 1 . 0 x l 0 5

VCti'APH

11. 7-12. 1Kd (®<fcO»S^£O{I)

1 x 104—1 x 106

237Np 2. 4xlO"5mol/l

pH Kd ( x - ;

- 1 8 4 -


Omin)

\ 1-1K RWM-86006 (1986)111-1

B

2.3.4.5.6.

8.9.

12.13.14.15.16.17.18.*Kcs CF:Distribution

Itado tuffOhya tuffSandstoneShaleAugite andesitePlagio rhyoliteOlivine basaltInada grani teRokko grani teLimestoneBiotiteChloriteHornblendeGrossulariteForsteri teK-FeldsparAlbiteQuartz

coefficient of carrier-free

CEC [meq/g]1. 39. 7 x 10 '2. 4 x l O " 2

1. 9 x l O " 2

1. 9 x l O 2

1. 2 x l O " 2

7. 5 x l O ~ 3

3. 5 x l O " 3

3. 3 x l O " 4

1. 2 x l O !

Q •) y I (1"!

0. o " 1 U

1. l x l O " 3

0. IX ID3 4 x 10 4

3. 2 x l O " 4

9. 8 x l O 5

l 3 rCs;32-60mesh

Kd(Kcs, CF)1. 1 x l O 5

1. O x l O 5

5. O x l O 3

2. O x l O 3

6. O x l O 3

5. O x l O '5. 8 x l O 3

9. O x l O 2

2. 6 x 1 0 *8 . 0 x 1 02. 2 x l O 3

1. 8 x l O 3

6. 3 x l O 2

4. 2 x l O 2

4. 6 x 1 0 '3. Ox 108 . 9 x 1 03. l x 10;25°C

, Eh.

: 50ml25°C

S|. : lg

- 185 -


, M 'L^§ t /12000rp in /10min)

, 1-1K RWM-86006 (1986)111-2

B

137Cs

[h]0. 72. 08.0

24. 090. 0

168. 0700. 0

1440. 02000. 0

... Adsorption

llppm Cesium onm Kd

Ohya tuff 11504001500

110002000025000—3000035000

rocks (0J:

[nada grani te152030100200600800800900

Cesium on

[meq/ml]

9. 0 x 1 0 " "5. OxlO"8

1. 5 x l O 6

3. 0 x 10"s

6. 0 x 1 0 4

igneousKd

A u g i t e a n d e s i t e50009001508015

rocks

[meq/ml]

2. 0x10" '°1. 5 x l 0 7

1. 5x lO" 6

7. 0 x 1 0 "7. 0x10""

KdO l i v i n e b a s a l t1000

200100

156

[meq/ml]

1. 5 x l O ' 8

2. 0 x 1 0 "5. 0 x 10"6

8. O x l O 5

7. 0 x l 0 ~ 4

Rokko grani te

1501003010

2

- 186 -


1 1 1111-3

, 1-1K -86006 (1986)

B

... Adsorption

Cesium on sedimentary rocks

[meq/ml]2 . 0 x 1 0 " '7. OxlO" 8

8. OxlO" 7

1. 5 x 10"5

KdI t a d o t u f f

90000800003000010000

[meq/ml]8 . 0 x 1 0 " "1 . 5 x l O " 8

1. Ox 10 6

2. OxlO" 5

7 . 0 x 1 0 "

KdSandstone70001700

700100

20

[meq/ml]3. O x l O 9

6 . 0 x 1 0 " '6. O x l O 6

8. O x l O 5

KdLimestone303030

3

[neq/ml]l . O x l O " 9

7. OxlO" 8

2. Ox 10"6

7. OxlO" 5

8 . 0 x l 0 " 4

Cesium on mineralsI Kd

B i o t i t e1200

7009015

3

[meq/ml]6. 0 x 10"8

7. O x l O 7

8. OxlO"6

8. O x l O 5

9. O x l O " 4

5. O x l O 8

7. Ox 10"7

1. O x l O 5

7. Ox 10"5

KdK-feldspa

2015

21

[meq/ml]6. O x l O 8

9. OxlO" 6

8. O x l O 5

9. OxlO" 4

KdQuartz10

0. 70 . 80. 1

- 187 -


mm1 1 2

(VI) (D1&W)^W)7 , 29-35, RWM-86006 (1986)

B

Inada Granite

, Eh,

: 30ml

Gelman Acrodisk filter (0.2urn)

U

gcLml/gJ

(VI) 4.filterdPH24610

... Adsorpt

8xlO"6M

Kd1550407

ion

unfiPH24567810

lterdKd15404040100127

188 -


scm1 1 3

-87008 (1987)

B

H. Eh ,

og Ca

[mol]-10-10-11-11-11

_o_ 0

-8-9-9

Adsorption

Timeday6970

15721321362536369

322

Kdb

0. 00. 05K

0.0010. 80. 010. 0935*0. 093h0. 125g

TcTcc

IId

ruuc

D'NpNpc

a:Number of moles initialy addedb:For total initial concentration of < 10 9 Mc:0. 5% Fe(s) initially added to the clayd:\% cinnabar in the claye:l% chalcopyrite/pyrite in the clayf: IX Fe3(PO4)2 (s) in the clayg:Same as in a reducing environment in rock assumed

- 189 -


1 1 4114-1KB

, 116-127, RWM-87009 (1987)

a®,CEC[meq/100g]

l . B e n t o n i t e ( W ' M / I ) 6 3 ( 2 5 0 / T > I ) 71 602. Sandttoyoura sand) 2 5 0 ( 6 0 " ) 43. Takadate loam 177( 80 " ) 128 1 0 ~ 304. Hatinohe loam 177 ( 80 « ) 63 30~1355. Z e o l i t e ( t * f ' H h ) 177( 80 " ) 179

Eh.D.W(Deionized water)S. W(Synthetic groundwater)

Na1 K* Mg" Ca" CT HCO3" S0^ SiO3!" pH

2.1 0.051 0.21 0.37 0.28 1.1 0.21 0.20 9.0 5 . 2 x 1 0 - 3

- 190 -


xm1 1 4114-2

B

aE«»[nl/g]

Bentonite

Sand

Takadate loam

Hatinohe loam

Zeolite

• 1 : 1 x*2 : 2x

/hSIE

) X ^ A "

//7days,

BIS, <f»&

U7, 11

. . . Adsorpt ion

Cs

Sr

Am'2

Cs

Sr

Cs

Sr

Am'2

Cs

Sr

Am12

CsSr

[mo 1/1]10"5

D. W//S.W//

D. Wn

S.Wn

D. W//S.WD. WS.WD. WS.WD. WS.WD. WS.WD. WD. WS.WD. WS.WD. WS.WS.W

6 - 1 2 7 ,

PH2.49. 32. 49. 42. 79.42. 79. 42. 06. 02. 06. 09. 07. 08. 36. 17. 76. 48. 06. 06. 68. 36. 58. 26. 58. 18.4

tRWM-87009 (1987)

Kd "140

1500160

110060

630040

40206800

230003800

11875

410014001800950

110001100280550260

130061000

840

- 191 -


1 1 4114-3

116-127, RWM-87009 (1987)

B

H, E h .

Kd

Cs

Sr

Cs+Sr

Cs+Sr

D.D.S.

s.D.D.D.n

D.//

W

wwwwwww

CsSrCsSr

[mol/1]7.510-43. 810-47.510-47. 510-41. 210-30.610-33. 810-40. 610-41.510-32. 710-3

[ml/min]4. 00. 54.04.04.00.50.50.54.04. 0

[cm]2. 251.01.01.02.00. 851. 231. 231. 121. 12

16037014012060

140150904627

- 192 -


Jlltfest

1 1 5115-1

- * , 2 5 - 3 3 , RWM-90014 (1990)

B

m (mm)lmA/cm2

1OV~1V10cm

pH Na K Ca6.9 2 5 . 4 5 .0 3 5 . 3

Mg ftIf CEC2.4 6 8 . 3 6 6 . 6

[meq/lOOg]

6.76.76.8

4 . 04 .1

14 .0

1.31.21.9

1.73 .8

14.2

5.96 .8

12 .0

12.9 6 8 . 816 .0 6 4 . 44 2 . 2 6 6 . 6

Eh,

Cs, Sr,pH4. 0 6. 0

[ppm]15

102050

Adsorption

A' '/k'N J rCs4001400170018001900

Sr7001600160016001600

Kd (E

Co600800110020001700

XMi fn

Cs6002100205020501000

Sr700

40002100700400

rCo400080001700500200

- 193 -


1 1 515-2

25-33, RWM-90014 (1990)

B

A'J

[g/cm3]1.1.1.

171513

[%}300~320~350~

320350450

[cm/sec]2. 0 x 10

[kgf/cm2]0. 1—0. 5

PH

5. 56. 37 .4

, Eh.

Cs, Sr, pH 6.

lkgf/cm2

77

CsSrCoCsSrCo

Adsorpt

Kf22.416. 116. 532.017. 816. 4

ion

Kd77. 154. 655.973.643. 736.2

Kf14.710. 510. 826.616.615. 3

Kd49. 234.435.342. 626.624. 4

1 9 4 -


1 1 6(VI) <Dj

'—9, 56-66, RWM-90014 (1990)

B

% : 32~60mesh

. Eh,

#

S0. 46cm,

SfcS : 0. 10-0. 20ml/hr^ 7 > / I ^ : 4. 8xlO-8mol/l

: 30~55%

... Adsorption

PH3579

1.1363130

- 195 -


S£?

1 1 7 25, 486-493 (1983)

A

, Eh.

137CsConditionedConditionedFine silt

Adsorption

soi1(without silt)soiKwith silt)

184318

3021

- 196-

JAERI-Dala/Codc 2001-005

1 1 8118-1

A

<0. 005mm5

43

0. 005-0. 074mm

1047

>0. 074mm85 2 .6710 2.59

CEC[raeq/100g]

0.913.2

, Eh,

WT :WN :

WTWN

Cond[/iS/cm]725125

'tfe

0

pH DOC[mg/1]

7. 3 2. 87. 7 2. 7

?' ?L2.

Ca2t Mgn Na( K+ SO42" HCOr Cl

[ m g / I ]6 7 . 8 2 3 . 3 4 2 . 6 5 . 1 1 2 6 . 7 1 9 8 . 9

6 . 8 3 . 9 8. 6 1 . 5 1 2 . 0 3 8 . 05 0 . 4

9 . 0

0.

±M : 0. 5g"9Pu : 50ml, 100—1 OOOpCi/ml

: 0. 01N HCl , 0. 01N NaOH

- 197 -


1 1 8118-2

A

Pu (IV)

1/gJ

PH1. 22. 22. 24. 55. 26. 46.46.78. 89. 1

... Adsorption

Kd10010012522050063015802500500012500

PH1. 53. 86. 36. 26.37. 07. 27. 77. 8

Kd250600

750010000350007500160001000050000

- 198 -


(Data

Review Data

1 1 9 , 651 (1993)

C

SeITTcPdSnCs

Ra

AcThPaUNpPuAm

110011

10010 (PI*

10 (EMc

10000100100100100

1000010000

1-501000-50000. 5-501-25

5036) 1-1000%d 50-5000fk) 250-10000fk) 500-5000

10-1000. 1-10010-10050-25000250-10000

10-25

0. 1-25

100—5001-10000

500-5000

250-25000100-10001-50

0. 1-5005-50050-250025-25000

1-50

1-5

50-25050-1000

1000-5000

10-100050-25050-25050-25050-25025-50010-1000

- 199 -


(10 days, M>b

1 2 0 , 654 (1993)

C

h))

f'ffecpH. Eh,0. OlM NaClO4, I0"7mol/l)

pH=2~8«

. . . Adsorption

- 200 -


(10 days, it/L^H/10000rpni/60min)

1 2 1 * 655 (1993)

C

0. OlM CHsCOONa, 2. 4X lO'M)

pH=5. 5,

50ml/0.

±^A±igB±IC

CECGneq/lOOg)0.90.83.0

18071

600

6040370

- 201 -


A* •;/•?& (48 hours, fltjfi/O. 2/zm)

1 2 2

Kfl-C

» 656 (1993)

, Eh,1O"4~5X 10

Adsorption

ixio*

1*10* *

a «E

O D '

O

'< h

a *D

•

0•AQ

0

JxJO'* ixlO"1 JJ(3O"J

&*$;£*

- 202 -


( iB t -5 ilOOrpmXTdays, ffiii/O. 45am)

1 2 3

C

» 657 (1993)

, 7KBB18 ;

Eh,

PH=4. 5, EC=O. 065mS/cmpH=7. 2, EC=O. 175mS/cm

. . . Adsorption

CDR=CEC/EC

500

400 "i

? 300

£ a»

too {-

_ • Uprtndio*

4- Rpprw witar

• 0 P*#f3Ot

•

> > •

Y*2.08X

r»0.87 ^

ft G •

50

M. li-f

10Q 150

CDR

(CDR)

200 250

- 203 -


(gj*:~200 days, Ji£>#ii/3500rpni/63niin)

1 2 4

C

^ 659 (1993)

A*u . -i•*

> hirtO. 55,1. Omnu

, Eh.l. 5X10zBq/m](7. 4X10""fflol/ml)

30g

Adsorption

SP* 1 1 * * * * *•Ti» • •

0 40 80 120 160 200Time (days)

(Rd)

- 204 -


1 2 5P)\\mml | > 550 (1997)

. Eh,

m

- 205 -


(1H]/B):1 week)

1 2 6 (4); & i- n, 551 (1997)

C

±

H. Eh ,

1000 •••

800

600 ^

k200

0

ACS-137

>±JL0 200

1

400 500 800 1000 1200

& M VS. iZ J: % & & (V / Jh 10)

- 206 -


:l week, i t i i / 0 . 45mm-Mi 11 ipore)

Samadfam Mohamad, m & i t fe

r ( I ) t E u1 2 7

C

> 554 (1997)

, 555 ( 1 9 9 7 )

h

H. Eh ,

, 2. 5g/dm3(Eu)

... Adsorption

10s

104

10'

• Oppmo 4(lppmA 200ppma 400pptn

W"

ur

2

19* -

8 10 12 \t

• Oppmo 5ppmA lOppma 20ppm

n-n-

1 • I

3 4 S 6 7 8 9

- 207 -


days)

ICtt.

1 2 8 (n ), 578 (1997)

c

H, Eh ,X 1 0 : i m o l / 1 )

35°CC

16

* >* .*a n fisvs

»/'Roasts* !»>*-,—4 , *.

1

- 208 -


(§81:30 days, 45 Mm)

1 2 9I . C s

, 581 (1997)

C

=4000cmVgo

-X b

- X h

Ca(OH): CaCOs AFm AFt C-S-H

OPC 18. 7 N. D. 0. 8 5.4 59. 0.3

BFS N. D. N. D. N. D. D. L. D. L. 0.2

PFA N. D. N. D. N. D. D. L . D. L. 1.8

MHP 15. 9 N. D. N. D. 7. 4 61 . 6 0. 4

N. D. Sttf D. L.

H, E h ,

Adsorption

C s : l~10 ml/g^ - X h

MHP^-X

(000

100

10

"

0.1

3-!

• <JPCV<"

* ii,0OE-0l

(M)

- 209 -


1 3 0 * 582 (1997)

A' U

C-S-H (C/SJt 1.0), C-S-H (C/SJt 1-2), C-S-H (C/Slt 1.7)AFt, AFm, C:(AH6

Eh,S r C l M , fi&=10. 3, 1, 0.3, 0. 1

PHC-S-H (C/SJt 1. 0) 11.4-11. 6C-S-H (C/SJt 1. 2) 12.3-12.4C-S-H (C/SJt 1. 7) 12. 5-12.6

PHAFt 11.2-11.5AFm 11. 9-12. 1C3AH6 12.3-12.5


Jf 100B

"""""•' -.-

-" WH^,,-*

• • *

- * -

t ) 1 1 ( [I l

i

' ^-—•- '•• :» ;-

*

• - . . « . . . . . " • • ' • • -

t 1 I i t tl I

:

; O C S H :in C-S-H 1 2• CS-H 1 7 -

+ AFm

^ • « . '

' " ' • * ' .

* •

•• . - a

0.0001 0.001

Concentration / M0.01

FigJ Concentration Uqxndencesaf Sr sorption bchnivior.

- 210 -


1 3 1i* (I)

, 583 (1997)(H)

, 584 (1997)

. Eh,

:i7Cs, MCo:Cs 1X1O"5M, Co

4. 0(f)X4.5cm=7. 1), j

tl

g = 0.09 ml/min. j(TO ->>^ I/- a

ml

mm137CsMCo

A'^^ft-15

> 100019

> 1000

- 211 -


:1 days,

1 3 2 > 764 (1999)

C

( L f c fc©o

H. E h ,lppm lOOBq/ml)

. 8g,jS>L^fSK3500rpm/15min)+Sl[jfl(0.

. . . Adsorption> h 150

602-102-10

- 212 -


1 3 3

A

m

*

ti

S.Co

Vakayama,lumn Exper

Radiochimica

A U 7

• M

$*(

AM?

• anaerobic

EluentDWDWDW

Na2SO4

Na2SO4

Na2S04

Na2S04

Na2SO4

Na2SO4

NazS04

Na2SO4

NazS04

[ml/g

Ini6.7.7.6.7.6.7.8.7.8.9.

10.11.

H. Arimoto, N. Yamada,imentsAc

<0. 04cm,

pH, E h .

7 ,1.

2ml/min

9flcp>l

c o n d i t

PHt i a l9109182294899

ta

S04$

6,(04g,

a^onD

on Migration14/45, 179-18!

?*, NP(v)«a

46cm(f> X5cm)^ H ^ 40%

Adsorp t ion

F i n a l6.6.6.6.7.6.7.7.7.7.9.

10.N.

215919196868D.

H. MoriyamaBehavior

! (1988)

: 5X1O"U

Pressure (kg/cm2)I n i t i a l I

555

305

10105

10401020

260

? inal555

305

10105

104010

120310

of

Kd22300001103

64110

and K. HigashiNeptunium(V)

(Np).34. 40. 93.39.36.56.54.07.01.95.48

- 213 -


xm1 3 134-1Kfl-A

m

ft1

A

t

[

K. H. Lieser and U. MohlenwegNeptunuim in the Hydrosphere andwi th NeptuniumRadiochimica Ac

U 7#©tl8{t¥fr

ta 44/45,

Sediment Depth(m) tt^fiflt(mVg)

till

GlG2G3G4G5G6G7

GlG2G3G4G5G6G7

•

•

D•

1 32 8 - 143 54- 574 57- 595 72- 786 87- 897 200-204

TZK#'I4(PH, Eh, ft?

216113137113252133142

Depth(m) pH Eh(mV) Na12- 15 7.0 30512- 16 6. 8 39036- 41 6. 7 3655 1 - 54 7. 5 33568- 70 7. 5 34000-105 7.0 325

193-221 6.8 230

tAn (±$ • 7K) tt GTV 'J )Vfl y XO&tl

sediment©^vK$ 1aerobic, anaerobic

12.12.8.

5893216

7.57680

NO

<o.0.

<o.0.

<0.

<o.<o.

o r l e b e n

y L. (5C

;PVC7°l

5«, m

2 9 - 1 3 3

in t h e

(1988)

SiOsfiU) A 1:0s88. 1890. 6796.4289.0992.4790. 9692. 85

mm)'(mg/DMg"966154

3

i -

01120118010101

salm<f>)

ISJ

2.433. 693. 18

34. 975

1. 24

5.473.021.746. 293. 973.353. 22

Ca"26. 617. 6320.4

262280

18. 5086 1861

S04-30. 1635.030. 135. 6

1882.49

2271

t dome.<6cm),

I 194-—

HC03

61. 035 .452 .0

198256

63. 7147

FRG. T-hjffi • ~

214g, i

Geosphere -

N1.0.0.1.0.1.0.

0001302

a;034552714775876

Srn

0500500548770306

Si02

14. 813.011. 314. 617. 714. 2

9. 6

K2O0.970.990.880.401.070.460.66

Column

CaO0.290.440. 210.470.450. 521. 12

F e 2 t / 3 ) Mn2

0.030.010.010.010.010.040.01

5mm (£> C

5 0 — 3 8 %

0. 0020.0020.0900. 210. 820. 124.0

o

m

Expe

ft. &MgO

0.0.0.0.0.0.0.

14312013341432

Cl17.15.10.

13545670

9.97429

P-m^< v

r i m e n t

mFe

0.0.0.0.0.0.0.

802

5

16210823311320

S

%)Mn

0.0.0.0.0.0.0.

Br0.

<0.0.0.2.0.

24.

0.0:

08020509030702

0170101491

3

0141

•f -i

- 214 -


1 3 4134-2

A

m

JffiT

K. H. LieserNeptunuim

and U. Mohlenwegin the Hydrosphere and in the

wi th NeptuniumRadiochimica Acta L

Eh. #&M

14/45,

ft

. . Adsorpt• Aerobic ConditionSampleGl/SlG2/S2G3/S3G4/S4G5/S5G6/S6G6/S6G7/S7

Ini. Cone1. Ox4. IX1. OX1. 7X0. 7X1. IX1. IX0. 4X

• Anaerobic CondiSampleGl/SlG2/S2G3/S3G4/S4G5/S5G6/S6G7/S7

Ini. Cone2. 9X3. OX3. IX4. 7X5. 2X1. OX4. OX

of Np(M)10"7

10"9

10"'10 9

10"9

10"5

10"9

10"'tionof Np(M)10'8

10"9

10~8

10 8

lO"8

lO'9

10 9

66777777

6777777

(m

mm

ion

PH. 0. 2. 1. 9.0. 7.7. 0

PH.0.5. 2.5.3.3.0

129-133 (1988)

. &mm

& Desorption

Eh(mV)470370480435420505520475

Eh(mV)13010

-100- 25- 259580

Rs(30d)1. 9 + 0. 4

—4. 3±0. 82. 5 + 0. 53. 8 + 0. 51.0 + 0. 21. 7 + 0. 42. 6±0. 5

Rs(30d)25 + 10MOOOMOOOMOOOMOOO70±15MOOO

Geosphere

Rs(60d)2. 3±0.4. 2±04. 6±0.4. 2±0.2. 4±0.1.8 + 0.2. 9±0.2. 8±0.

Rs(60d)5 + 2MOOOMooo>1000MOOOMOOOMOOO

48985455

- Column

Rs(90d)2. 1+0.4. 4±0.4. 6 + 0.4. 1 + 0.2.5 + 0.0. 8±0.2. 7 + 0.2. 7±0.

Rs(90d)10±5MOOO>1000MOOOMOOOMOOOMOOO

Experiments

49985255

Ro(60d)——

5. 5±1. 1—

3. l±0. 6—

4. 1 ± 0. 8—

R,,(60d)——

MOOO—

MOOOMOOO

- 215 -


1 3 5

K. H. Lieser and U. MohlenwegNeptunium in the Hydrosphere and in the Geosphere - Chemistry ofNeptunium in the Hydrosphere and Sorption of Neptunium from Ground-waters on Sediments under Aerobic and Anaerobic ConditionsRadiochimica Acta 43, 27-35 (1988)

A

, Eh,

... Adsorption

Sample No.

SampleGl/SlG3/S3G4/S4G5/S5G7/S7

Aerobic Condi t ionpH Eh(mV) Rs(90)

570480435420

Anaerobic ConditionpH Eh(mV) Rs(90)

6.07. 17.97.07. 0 475

1.9 + 0. 51. 4±0. 42. 6±0. 62. 7 + 0. 63. 7±0. 8

6.06. 87. 37.36.9

23075

21080110

21+ 61290±330168+ 42

1060 + 2601600 + 500

- 216 -


mm*

1 3 6

A

vHll

fRU

H. Me er, E. Zimmerhackl, W. Hecker,Measurement of Diffusion of

G. Zei tierRadionucl ides in

Radiochimica A d a 44/45, 239-244

A*'J7#<• Konrad

• 2~6mm

• Rift*

NuclideU-233U-233U-233U-233U-233Np-237Np-237Ni-63

iron ore mine, Asse sa

<t>\Zffi$tOiy?-). 4cm'X

tt(PH. Eh, & # f * > * 8 . S£sj-MilL&OtlTzk (X ttj;l0"5~10"Mo

t^fflTSi&TzKttO. 45/.

l/g]

SedimentLimestoneLimestoneDolomi t ic marlClay s toneClayAnhydr i t ic l imestoneAnhydri teLimestone

Water / f : freshws : weak s a l i n es : s a l i n eMW : model water

11 mir

0.5cm

WaterffwswsswswsMW

(1988)

e, Gor

® ^ .

l i p o r e

S i t eKKAAGAAK

leben

and P. MengeSediment Rocks

sa

w;

erT

t domejS

) .

1 sj\J o

Batch IRS9

1527

39111

99

. 9

. 7

. 7

RD11176.9

1352405.9

203

)i f f u s i o nKd16192.8

1487105.2

105

- 217 -


1 3 7

A

m

&

rtyffe (mto, jt'L^H/6000rpm/30min)

H. N. Erten, S. Aksoyoglu, S. Hatipoglu and H. GokturkSorption of Cesium and Strontium on Montmori1loniRadiochimica Acta 44/45, 147-151 (1988)

SI Mihalliccik Clay (Kaolinite)S2 Resadiye Clay (Montmori1lonite)S3 Saraykoy Soil

ifeT*^tt(PH. Eh. &t?i*>mm, &&m)pH Ini. Ion Cone, (mg/l) (Na* K> Ca2t

GWl 8.4 197 4.50 8.20 14. 9 19.GW2 8.7 336 13.4 13.9 81.4 7.GW3 9.1 103 7.20 46.0 27.0 41.

-€"<£> flil• longitudinal shaking(250strokes/min),ftt£cir

frSE#$C[ml/g] Adsorption, Desorption• Sorption, Sl/GWl, Cs

Particle size(//m) Ini. Cone, of Cs(mmol/ml)< 10 1.01X10"< 10 1. 19 X 10 s

10 - 20 1. 01X10"10 - 20 1. 19 X 10 s

• Desorption, S2/GW2, SrParticle size(u^) Ini. Cone, of Cs(mmol/ml)

< 1010 - 20

• SorptionKd(Sr) Kd(Cs)

Sl/GWl 120 2000S2/GW2 1500 3500S3/GW3 400 27000

Mg2t Cl2 39340 4347 137

te and Kaol

' HCO:f SO456. 994. 876. 1

vmuAm

ini te

. » g. i27Xtt§)

AnkaraAnkaraSaraykoy

n±mt®M(mt

cular shaking(150rpm)(Z)2 ffiO (Djj

Contact

Contact11

Time (days)5 ~o2 ~ou

Time (days)0 ~0 ~

Kd30

200025

1200

Kd4001000

- 218 -


:\ week)

1 3 8

K. H. Lieser, B. Glei tsmann, S. Peschke and TH. Steinkopf fColloid Formation and Sorption of Radionuclides in Natural SystemsRadiochimica Acta 40, 39-47 (1986)

A

A']

Sediment

. Eh.GroundwaterOow salt content) : pH=6. 8, Eh=180mV

Ini.Conc. = 5. 3X 10 9mol/l (CsO, 2. 3X 10 7mol/l (Sr2+), 3. 2X 10 7mol/l (Ce3+)

Smooth shaking(hand), Vigorous shaking(machine)Anaerobic Condi t ion (Ar/CO*, 99%-Ar, H-CO*, 60ppm-O2)

j©(0. 45Mm-mi 11 ipore membrane filter, ultrafiltrationCO. 002/xni))

C sfflit Jftifi&L 0.45 Mm 0.002 Mm

50ml/20g 46+ 5 180+18 285 + 2950ml/5g 117+12 308 + 31 316 + 3250ml/lg 320 + 32 300±30 310±31

S rMlt ftifi&l* 0.45 Mm 0.002 Mm

50ml/20g 2.1 + 0.3 2.8 + 0.4 2.7 + 0.450ml/5g 1. 6±0. 2 2. 2±0. 3 2.3 + 0.350ml/lg 1. 9±0. 3 2.2 + 0.3 3.0 + 0.5

C eftSHtt iSijiifeb 0. 45Mm 0. 002Mm

50ml/20g 5.4 + 0. 5 15. 3± 1.5 > 100050ml/5g 4. 3±0. 4 48 ± 5 > 100050ml/lg 4. 9 + 0. 5 253 ±25 > 1000

219


(1 day)

1 3 9

K. Shimooka, S. Takebe, H. Ii, F. Hirosue, K. Yamada, H. Miyahara, Y. Wadachi and K. HiranoPerformance Experiment of LLRW Disposal Concrete Vault - MigrationBehavior of Radionuclides in Backfill and ConcreteLow and Intermediate Level Radioactive Waste Management Vol.1, 581-586, ASME(1989)

A

A U . mm.Concrete, Carbonated-concreted W U 100-200/iin©|i!$t;

Eh,137Cs, 8iSr,

e: 12, Carbonated-concrete=7) f t

?S@|Jt=25inl/lg0

Adsorption

Sample pHConcrete 12Carbonated-concrete 7

Rd('"Cs)1684

Rd(S5Sr)4

21

Rd(60Co)9

34

- 220 -


day,

1 4 0140-1

RADIOISOTOPES, 37, 681-684 (1988)

A

C E C = 1 . 2 4 ( m e q / 1 0 0 g ) , p H ( H « 0 ) = 8 . 2 1 . p H ( K C l ) = 7 . 9 5C h e m i c a l C o m p . (%)= S i O 2 7 8 . 2 0 , T i O z 0 . 3 6 , A h O s 8 . 3 1 , F e O 2 . 4 6 , MnO 0 . 0 7 ,

MgO 0 . 9 8 , C a O 1 . 9 5 , K z 0 2 . 7 0 , Na 2 O 2 . 5 5 , C 0 . 1 5 , & 0 1 . 0 4

. Eh,

=20m/iog)Ge (pure) ^ (Canberra^)

Adsorption

J_ 1 i i

-35 -13 -It -9 ~7 -5 -i -I

- 221 -


1 4 0140-2

RADIOISOTOPES, 37> 681-684 (1988)

A

0 t 4 'i « !O 52 U

Fig. 2 VarsaStois «? distli^ijfkfii

1

a

Fig. -t

J0:

1It) 3-2 14 3

. T ! f /T l ) X10"

of **C»

" at pH 7).

10'

,5 Wist kmB :. '-'si (iMIHo;.

of" C J U a fuifcctsuit of Ca"". M K " >UKJ

- 222 -


1 4 1 1377-1382 (1989)

A

Coastal sand

Gl: Coastal sandG2: Loamy soil

Sand(%)

99.557.5

Si l t Clay(%) (%)

0.525.5 17.0

Loamy soi l

(g/cin3)2.732.69

(cm/s)9X10"3

1X10"3

CEC(meq/lOOg)

1.314

(m'/g)1.5

24.5

Eh,• S y n t h e t i c g r o u n d w a t e r + R a d i o a c t i v e s o l u t i o n

C a n M g " Na* Kf pH 60Co 8 5 Sr l 3 7Cs( p p m ) ( p p m ) ( p p m ) ( p p m ) ( / z C i / m l )

S I : 1 3 . 4 6 . 2 5 1 9 . 8 5 . 8 2 5 . 8 0 . 0 1 5 0 . 0 1 4 0 . 0 1 6S 2 : 8. 2 6. 4 6. 9 1. 0 6 . 3 0 . 0 1 1 0 . 0 1 1 0 . 0 1 1

G1/S2G2/S2

Retardat

Gl/SlG2/S2

Gl/SlG2/S2

ml/g

OnHrr

ouun

ion

m

',}... Adsorption

it /9firr

ll/ZUg

Kd (60Co)40

3200

factorKdC'Co)760

2300

gt^m mm

Kd(85Sr)30

1400

KdC'Sr)6202400^•i^mM

(cmVmin) (cm/min) (1/hr)0.0.

007 0.10004 0. 05

6.94.4

Kd(l37Cs)270

3500

Kd('37Cs)740

2400

(hr)10101600

mm*(o70007000

- 223 -


1 4 2

A

-/fillix'J

•

A'y^f f i (24 hours)

RADIOISOTOPES, 35, 70-76

A*'J7tta>&ig{L

Chemical Comp.MgO 0. 98, CaO 1• S i l t

JfeTzk&ttWi. Eh.• "CoCI,, 8 'SrCh,

• mm^ 25

^@E^^C[ml /g ] . • •

SampleSandSand + 3. 6%-SiltS i l t

m IV 1- (D ffl i?J> *mJbAX. WTEuy •&?

(X) = SiOz 78.. 95, Na2O 2. 55

l37CsCl©*3(Z34

°C, SHi:t=8

Adsorpt ion

Kd (60Co)77. 9

102. 7712

(1986)

2, TiO*, LO 2.

30ml/20g

Kd(S5Sr)47.449.8

134

^S=2

0. 36, AhOs 8. 30,70, H2O 2

tvfdZ. 7Bq

•

KdC"184.193.487

.04

Ml (DM

Cs)72

- — -

. 63g/cnf), zKilzKidcfc St5t

Fez03 2. 46, MnO 0. 07,

224 -


1 4 3

A

Y. Ohtsuka and S. TakebeMigration Behabior of Radionucl ides (60Co, 8iSr and 137Cs) in AeratedSandy Soil Layer - Difference of Migration Behavior and DesorptionProcess for RadionuclidesJ. Nucl. Sci. Technol.. 27(8), 750-755 (1990)

• C o a s t a l s a n d y s o i l ( T o k a i s e a s i d e i n J A E R I ) , u n d e r 2 m m ^ ( m o d e 7 0 0 / / m ) ,d e n s i t y 2. 6 3 g / c m ; i , CEC 1. 2 4 m e q / l O O g , pH(HzO) 8 . 2 , p H ( K C l ) 8 . 0

C h e m i c a l Comp. (%)= S i O j 7 9 . 2 2 , T i O 2 0 . 3 6 , A h O s 8 . 4 1 , F e O 2 . 4 9 , MnO 0 . 0 9MgO 0 . 9 9 , CaO 1 . 9 8 , K:O 2 . 7 4 , Na2O 2 . 5 8 , C 0 . 1 5 , H«O 0 . 8 0

Eh.Distilled waterrespect ively)

+ R a d i o a c t i v e s o l u t i o n C C o , 8 5 S r , 137Cs 1. O x 10 : t « C i / m l ,

Adsorption

6"Co8 5Sr

137Cs

7 56 2

3 1 4

- 225 -


scffl,

1 4 4144-1

B

mS1:SS2:<S3:1S4:lS5:1S6:!S7:lS8:(

3 / m i n

S. Takebe and X. DeyingStudies on Sorption BehavJAERI-Research 95-024

Sand(JAERI)>and (Shimoki ta).oam(Shimoki ta)'uff-sand (Shimoki ta)'uff-rock(Shimokita)5and-rock(Tohoku)(uroboku-soi1jley-so i1

Mineral Composition (wtW

SIS2S3S4S5S6S7S8

SiO2 AhO3 T1O263. 00 8. 50 0. 877 7 . 4 8 10 .68 0 . 1 95 0 . 5 6 2 1 . 1 6 0 . 9 15 2 . 2 9 2 3 . 7 7 0 . 5 76 8 . 6 2 1 3 . 6 8 0 . 2 37 2 . 8 9 11 .35 0 . 2 95 1 . 5 9 2 1 . 2 8 1.235 0 . 5 1 15 .11 0 . 7 1

Chemical Charac ter i s t ics

SIS2S3S4S5S6S7S8

CEC EXCNa1 K* Ca"

2. 7 1. 1 0. 8 8. 94. 6 0. 5 0. 4 0. 4

16. 9 0. 8 1. 5 0. 95. 0 1. 0 0. 5 0. 5

12. 8 2. 0 1. 7 4 . 029. 1 2. 2 1. 1 5. 019. 3 0. 6 0. 5 5 .433. 4 0. 9 0. 3 12. 5

Densi(g/cm2. 692. 682. 772. 672. 432. 742. 722. 69

FezOs3. 531. 836. 814. 621.062. 483 . 6 62 . 7 0

i o u r 0

fr$t/3000rpm/20min)

f

&

Technet ium in

ty G r a v e l O2000Mm)')

FeO3. 301. 042. 070. 511. 111. 326 . 5 43 . 9 0

(meq/lOOg)

Mg"0. 60. 61. 60. 75. 8

13. 30. 58. 7

AEC

0. 31. 21. 40. 50. 31. 40. 50. 9

42022311

(wtX)0.0.0.0.0.4.0.0.

CaO. 13. 22. 47. 60. 25. 33. 15. 15

so4!

0. 21. 82. 30. 30. 20. 61. 3

68. 6

5000000000000000

MgO2.450. 911. 301.730.671.461. 710. 59

EXA" HCOf

<0. 1<0. 1<0. 1<0. 1<0. 1<0. 1<0. 1<0. 1

Na6.1.0.1.2.1.0.0.

I<<<<<<<<

Soi

-mSand

?02161826178935956

O4

11111111

Is

m(74-2000) S

(wtW96.5088.00

8. 5087. 5026.0076. 0016. 00

4. 00

K«O5.410. 501.440.532.691.090. 590. 73

?i

0.0.0.0.0.0.0.

10200605083207

eft. salts)i l t - c l a y

(wtW3.00

12.0091. 5012. 5074.0020. 0084. 0096. 00

MnO0. 130.030.080.080.060.090. 150.04

Water Content(wtW0.1.

25.1.3.4.

13.63.

39272261

- 226 -


scm1 4 4144-2

B

m

&

it

S. Takebe and X. Deying

min. M

Studies on Sorption BehaviourJAERI-Research 95-024

A"'J7#CO

•111(1• SKJAERI

• Tcoroa

• '$.$• -> >

• Natural

• Natural soiContact time

(days)13113048

• ArtificialContact time

(days)13112745

¥«lfit 1surumicoalliHU, 1. 64mmJtako Pure ChemicalttM,sand) \Zfcf£m.X

(pH, Eh. rt#-f^>«MM.& 42Bq/ml,

t \ 25°C<Z)water

soilstl^V^T^J

4. 0X10

bath, ?

3000rpm

of Technetium

lOOmesht it. I c:A c_ 1 , 0

F)"7mol/l0

/20min)

in Soi Is

(150#mmT), 10, 2

Mo

>^(Packard-2500TR)o

g] ... Adsorpt ionIs

SI S20 00 00 00 00 0

S30. 840.840.920. 970.85

2000 urn

S400000

soiIs (SI + Activated carbon /Act ivated

1% 5% 10%237 1230 1140238 1120 1210553 >3000 >3000443 >3000 >3000348 >3000 >3000

carbon20%815795

>3000>3000>3000

100%10501110

>3000>3000>3000

£JLT\zt

S500000

Reduced

1%4344620

>30002390

S600000iron)

0

S70.0.0.0.0.

Reduced5%135138930

>3000>3000

10%175185

2480>3000>3000

160907

e g . iS^Xtt^)

S83. 61

18. 78326. 5

13 >300008 >3000

iron20%269283

>3000>3000>3000

100%162170

>3000>3000>3000

- 227 -


. 45Mm-meinbrane)

1 4 5145-1

JAERI-Research 97-089B

(SO0.055.07

H75

PH20

.5

.4

(26°C)KC16. 34. 5

Eh(mV)+ 250+350

127

CEC EXCCNa, K,Gneq/lOOg)

. 1 0. 6 0. 7

.5 0. 4 0. 5

Ca

2.0.

. Mg)

6 0.8 0.

84

C06

Organic(%).02. 01

N(mg/kg)8.0

4300

0Co:2. 54-95 , 137Cs:4. 37 99)

ABCDEFGH

a •

t°

15 °C14. 2"C15. 0t15. Ot;19 t :is. or15 r14 r15 r

Hand-shake (lOminX 20/day)&mmto(smwHand-shake (1, 4, 70

- 228 -


jfi/0. 45/im-membrane)

1 4 5145-2


, m

Adsorption

1E+02 r-

IE+01

JE+OO

lfc-01

6 !

i x i I

• * -

i 1 iI ! i

! :

<> I

I

i !

i i i i i i iA B C D E F G H a b c d e f g h i j k l

1E+O4

IE+02

1E+0I

IB+00

1E-01

1 1 1 5

0<> 1 ffi

"S 88^ •0

i iA B C D f c F G H a b c d e f g h i j k l

- 229 -


, i i i i /0 . 45Mm-membrane)

1 4 5145-3


... Adsorption

IE+04

1E+O3 ~

1E+02 -

1E+0IA B C i) E F {'. II a h c <i e f g h i j k 1

KdSWSi?iS {Cs-WMM

IE+04

1E+02

1B+O)

i !

: o

o

J_L

<i> •

P

o

i iA B C I) t: F G II a l> c d e f g h i j k I

- 230 -

JAERI-Data/Ccxle 2001-005

1 4 6JAERI-M 93-034

± a2.2.6867

0.0.6445

0.0.9291

1.0.39

Kd rco)43001500

KdrSr)250110

Kd(l37Cs)55001500

- 231 -


1 4 7 JAERI-M 92-205

B

Ll:Loamy soil 1. 10-1. 70 2. 77L2:Loamy soil 2. 05-2. 65 2. 79Dl:Clayly sand 3. 30-3. 90 2. 68D2:Sandy tuff soil 4. 50-5. 10 2. 68

Eh,

pH6 . 4

C a "1 . 3 7

I o n C o n c e n t r a t i o n (ppm)Mg2t Naf K* SO4

2 HCOs1 . 0 9 5 . 9 3 0 . 2 8 1 0 . 1 5 2 . 8 5

CT6.28

LlL2DlD2

Kd rco)6500700074003100

Kd(8aSr)5600870061005000

Kd('"Cs)12000110001200082000

- 232 -


Wfetik

1 4 8148-1

JAERI-M 89-144B

US-1US-2US-3US-4

n-AH±g|i(m)

0 - 1 . 20 .8 -2 .01. 6-2. 82. 5-3. 7

S a n d S i l t C l a y

17.518.08 3 . 58 3 . 5IRH . 5 3 .

pHGW)) - 5. 6, 6. 3, 5. 9, 6. 9

(wtX)39.041.0

8. 58. 5

43.541.0

8. 08. 0

^jM. CEC(g/cm3) (meq/lOOg)2.772.762. 682. 67

14.111.6

3. 56. 0

(mVg)73.088.339. 623. 6

. Eh.

US-1US-2US-3US-4

Kd(60Co)2000120046002400

Kd(8iSr)37030028003400

Kd(l37Cs)5400500058005800

- 233 -


1 4 8148-2

J;

JAERI-M 89-144B

US-1US-2US-3US-4

PH(H20)

5 . 66 . 35 .96 .9

(cm/s)6. 5X10" 5

4. 1 X 1 0 4

2. 5X10" 4

9. 3X10" 5

(cmVmin)0.0770.0770.260.082

Eh,

US-1US-2US-3US-4

PH

6. 06. 16. 26. 2

60Co6. 54. 34 . 43 . 8

8sSr6. 14. 24. 24. 5

m C s7. 24. 84 . 43 . 7

(ppm)1. 62 . 53. 11. 1

(cm/min)0.0140.0140. 0200.015

(1/h)0.3860.5190. 2560.287

(h)622462937837

(1)240240240240

xi200mmh)

KSEIKO EG&GtttD,

Retardation,.. Adsorpt ion

factor6"Co

US-1US-2US-3US-4

51004700960011000

Retardat ion

siSr50004700960011000

137Cs54007100

2300013000

67. 5cm,

- 234 -


14 9149-1

JAERI-M 89-189B

U-AIUS-5US-6

pH(HzO) - 5.6,

TSR

(m)0 -1.20. 8-2. 01. 6-2. 82. 5-3. 7

Sand Silt Clay

15.515.088.087.5

(wtW42.541. 57.07.5

CEC(g/cm3) (meq/lOOg)

42.044. 55.05.0

2. 782. 772. 682. 67

13. 59. 3

12. 028. 3

(mVg)64.072. 642.430. 2

6. 3, 5. 8, 6. 8

. Eh.

US-5US-6US-7US-8

KdC'Co)1200200042002000

KdrSr)16043028003500

Kd(13'Cs)4300540056005900

- 235 -


scm1 4 9149-2

JAERI-M 89-189B

US-5US-6US-7US-8

pH (H-0)

5. 66. 35 . 86. 8

(cm/s)1. 51X10"-1

3. 38X10"5. 08X 10"1. 51X10"1

(cmVmin)0. 0770 . 0 7 70. 260. 082

Eh.

US-5US-6US-7US-8

PH

6.26.36.46. 1

6"Co2 . 93 . 02. 32. 5

S3Sr2 . 92 . 82 . 02. 2

137Cs3. 13 . 32 . 53 . 0

Na+

(ppm)(cm/min)3.6 0.0144.5 0.0144. 7 0. 0202.3 0.015

(1/h)0. 171 0. 2770. 255 0. 5150. 227 0. 2530. 195 0. 373

(h)234. 5 721.0156. 7 388.0176. 3 790. 7205. 5 536. 7

(Torr)350650200300

200Lo

x 1200mmh)

. . DesorptionRetardation factor

60Co 8 5SrUS-5 9200 9200US-6 4600 4900US-7 11000 11000US-8 8900 10000

Retardation

l37Cs110007300

160008900

<~> 7. 5cm, 12. 5cm©

- 236 -


( 2 4 h o u r s )

1OR

1 5 0 J A E R I - M 8 9 - 0 1

B

2. 63 g/cm

C h e m i c a l c o m p . (%) = S i O , 7 8 . 2 0 , T i O 2 0 . 3 6 , A h O > 8 . 3 1 , F e O 2 . 4 9 , MnO 0 . 0 7 ,MgO 0 . 9 8 , C a O 1 . 9 5 , L O 2 . 7 0 , N a 2 O 2 . 5 5 , C 0 . 1 5 , & 0 1 . 0 4

C E C = 1 . 2 4 ( m e q / l O O g ) . p H ( H z O ) = 8 . 2 1 , p H ( K C l ) = 7 . 9 5

, Eh,

PH37

11

IM, 25

Kd(5

514

± 2 ° C , j |

Adsorpt

60Co). 4. 5. 0

£EIJ

ion

Kd(8

83.90.83

5Sr)425

0ml/20g

Kd (137i157.202.158.

r

Cs)711

- 237 -


(Mto :90mn,

, m(i) -

1 5 1151-1 JAERI-memo 6969

D

A'U0 500m, t&T^3m) <t 0

2. GSg/cm3,,= > 1 6 8 0 / / m 0 . 4 , 1 6 8 0 - 1 0 0 0 5 . 7 , 1 0 0 0 - 8 4 0 5 . 7 , 8 4 0 - 7 1 0 8 . 3 ,

7 1 0 - 4 2 0 1 9 . 0 , 4 2 0 - 3 5 0 2 4 . 3 , 3 5 0 - 2 5 0 2 3 . 5 , 2 5 0 - 1 7 7 8 . 5 , < 1 7 7 4 . 5( w t % ) = S i O * 6 3 . 0 0 , T iO? 0 . 8 7 , A12O3 8 . 5 0 , Fe«O s 3 . 5 3 , F e O 3 . 3 0 ,

MnO 0. 1 3 , MgO 2. 4 5 , CaO 4. 1 3 , N a ^ 6. 2 1 , K20 5. 4 2 , H2O 2. 0 4

. Eh.

\ Z \ t , 0. 1M HC1h \ Z l . 0 X 1 0 - 1 * , p H = 5 . 8 00. 1M NaOH

3000rpm/10min (Cs), 2000rpm/5min (Co).

.. AdsorptionpH(initial) pH(final) i&g(/zin)

5.8 1680-10005. 8 1000- 7105. 8 710- 4205. 8 420- 3505. 8 350- 2505.8 250- 1775.8 177-

g(£iin) 420- 350pH(initial) pH(final)

2. 052.955.059.40

10.4011.45

3. 05.25 .45 .87 .8

11.2

Kd(60Co)0. 45

12201100

2926

Kd (60Co)1.511. 742. 113. 053. 914. 997. 66

Kd(i:"Cs)1. 732.493. 744. 174. 155. 257. 19

pH(initial) pH(final)2.03.04.510.012.0

4.85.45.65.8

11.2

Kd(l37Cs)191341453478260

- 238 -


austt

1 5 1151-2

D

$1

At!

/

Itt

MM-

JAERI-memo

ttTzi

ABCDEFGHIJ

IS

m)

ABCDEFGHII

PH2.3.4.5.5.7.8.9.

10.11.

ml/g]

420-

ic

6969

. Eh.

05001000851015050000

350pH(

2.3.4.5.5.7.8.9.0.1.

£J0.IN0.0.0.0.0.0.0.0.

9 0 m i n , j |

2M KC1 +1 CH:,COON<

sa

0.i t

2M CH:,COOH2M CH.COOH2M CH:,COOH

2Mzf%r>#

2M*^7?>

A d s o r p t i o n

n i t00001000900030051520

al) pH(f2.4.5.6.7.7.8.9.9.

10.

+++

\

tm

2N HCl + HzOIN HCl + HzO

+ 0. 2M CHsCOONa+ 0. 2M CH3COONa+ 0. 2M CH»C00Naf (0. 2M H3BO3 + 0. 05M NaCl )

0. IN HCl0. IN HCl0. IN NaOH0. IN NaOH

i n a l ) Kd(MCo)55800570409030007015

0 . 4 96. 166. 55

50. 9138

292233104

5 5 . 8

- 239 -


1 5 21 5 2 - 1 JAERI-M 7 6 4 2

B

A'U

ffl3 5 0 M m , 2. 6 3 g / c m 3

, %) = > 1 6 8 0 0. 3, 1 6 8 0 - 1 0 0 0 5 . 2 , 1 0 0 0 - 8 4 0 6 . 3 , 8 4 0 - 7 1 0 8 . 3 ,7 1 0 - 4 2 0 1 9 . 3 , 4 2 0 - 3 5 0 2 4 . 3 , 3 5 0 - 2 5 0 2 3 . 3 , 2 5 0 - 1 7 7 8 . 8 , < 1 7 7 4 . 2

Eh,7CsCl> . OX 10~ / m l )

¥(•

. AdsorptionV Ai-Af

Kd' = — XM AI

AiAfVM

PH3.07.0

12. 0

Kd' (60Co)270000

2128

Kd' (137Cs)

15001800

- 240 -


5 9 1 m i ;

1 5 2152-2 JAERI-M 7642

B

. Eh.

pH67

KdCCo)300

Kd(l37Cs)

680

- 241 -


1 5 3153-1 JAERI-memo 7203

D

; 02 . 6 3 g / c m 3

0

= > 1 6 8 0 w m 0 . 3 , 1 6 8 0 - 1 0 0 0 5 . 2 , 1 0 0 0 - 8 4 0 6 . 3 , 8 4 0 - 7 1 0 8 . 3 ,7 1 0 - 4 2 0 1 9 . 3 , 4 2 0 - 3 5 0 2 4 . 3 , 3 5 0 - 2 5 0 2 3 . 3 , 2 5 0 - 1 7 7 8 . 8 , < 1 7 7 4 . 2

= S i O , 6 3 . 0 0 , T i O . 0 . 8 7 , A h O : , 8 . 5 0 , F e ^ 3 . 5 3 , F e O 3 . 3 0 ,MnO 0 . 1 3 , MgO 2 . 4 5 , C a O 4 . 1 3 , N a 2 O 6 . 2 1 , K . 0 5 . 4 1 , H 2 0 2 . 0 4

Eh,0 . 1M HC1 0 . 1M N a O H

. Og,

A d s o r p t ion

Fig. 2 Variation of dMiUwtton cetfUcmit ua function of pH ( ta)

- 242 -


xm1 5 3153-2 JAERI-memo 7203

D

as.o 500m. tun^m)«t o

^ g 2. 6 3 g / c m : to

= > 1 6 8 0 M m 0 . 3 , 1 6 8 0 - 1 0 0 0 5 . 2 , 1 0 0 0 - 8 4 0 6 . 3 , 8 4 0 - 7 1 0 8 . 3 ,7 1 0 - 4 2 0 1 9 . 3 , 4 2 0 - 3 5 0 2 4 . 3 , 3 5 0 - 2 5 0 2 3 . 3 , 2 5 0 - 1 7 7 8 . 8 , < 1 7 7 4 . 2

C = S i O 2 6 3 . 0 0 , T i 0 ? 0 . 8 7 , A I « 0 s 8 . 5 0 , F e 2 0 3 3 . 5 3 , F e O 3 . 3 0 ,MnO 0 . 1 3 , MgO 2. 4 5 , C a O 4 . 1 3 , Na2O 6. 2 1 , K20 5 . 4 1 , H2O 2 . 0 4

Eh,

xi00mm)

i, lml)

. . DesorptionKd' =q,

C* :

400 800 1200Efflutnl vokima (ml)

1600 2000

g 12 Aoportnt dWflbullon co«fflelinlt of S.-.

' 0 200 400 600 800 1000 1300 MOOEfflu** volume !ml I

Fig.10 AppwwJ dtlrtbutlm nfflcfaolc of '"Ct mi "bo

-- 243 -


1 5 4

M. Kumata and T. T. VandergraafTechnetium Behaviour under Deep Geological ConditionsRadioactive Waste Management and the Nuclear Fuel Cycle, 17(2), 107-117 (1993)

A

A u• P inawa, M a n i t o b a , C a n a d a i £ < < Z ) i f e T 2 5 0 m T M L f c G r a n i t cZ£iXntz\ 8 0 - 8 5 0 M m W l S M o ( J & ^ i = f ? H M )• C h e m i c a l comp. (wt!K) = Na2O 3 . 0 2 , KiO 6 . 3 3 , MgO 0 . 6 2 , CaO 0 . 9 0 , AI2O3 1 3 . 6 ,SiOj 7 4 . 8 , TiO2 0 . 1 8 3 , P2O5 0 . 0 6 0 , MnO 0 . 0 1 6 , FezO> 1.65

Eh,Groundwater, Eh= 158 mV, pH= 9, EC= 1340 u S/cm0Chemical comp. (mg/1) = Na 190, K 0.71, Ca 3.6, Mg 0.31, Fe 0.037,

Si 3.58, Al <0. 1, Sr 0.053, HCO3 220, Cl 125. S04 51.9, Br 9,N03 <0. 1, NH4 <0. 1, Organic-C 1. 05

\IM. 1. 92X10"6mol/lo

= 1, 2, 4, 9, 16, 32 and 52 weeksc

Adsorption

(weeks) Kd("Tc)1 (-0. 01)2 (-0. 05)4 0.009 0.0616 0.1632 1.8352 2. 53

- 244 -


1 5 5155-1

T. Yamamoto, S. Takebe and H. OgawaLarge Column Test for Radionuclide Migration in Soil LayerThe Third International Symposium on Advanced Nuclear Energy Research- Global Environment and Nuclear Energy -, $

C

. -r±

Solid phase 58%, Liquid phase 9%, Gaseous phase 33%Gravel 0. 5wt%. Sand 97. 5wt%, Silt & Clay 2. Owt%

2. 69g/cm\ S z k i ^ 1. 3X10-'cm/s, CEC 1. 9meq/100g, 1. 8m!/g

Eh.

pH

CaselCase2

Radionuclide(xiO"VCi/ml) Na*60Co 8 5 S r 137Cs ( p p m )

3 . 0 2 . 7 3 . 2 0 . 1 4 6 . 3 32 . 6 3 . 0 3 . 0 0 . 1 7 6 . 0 8

30cm0 X120cmh0

mm m(cmVmin) (cm/min) (1/h)

Casel 0.155 0.502 5.70Case2 0.0236 0.124 1.49

(h)116443

mm660660

Adsorption

Coastal sand

A* y

CaselCase2

R e t a r d a t i o n f a c t o r60Co 85Sr l37Cs3410 3620 33102700 2430 2300

=800m 1/2 Og)60Co

51

LtzM85Sr l37Cs110 400

- 245 -


1 5 5155-2

T. Yamamoto, S. Takebe and H. OgawaLarge Column Test for Radionuclide Migration in Soil LayerThe Third International Symposium on Advanced Nuclear Energy Research- Global Environment and Nuclear Energy -, <%

C

(m)US-1 Loamy soil 0-1. 2US-2 Loamy soil 0. 8-2. 0US-3 Sandy soil 1. 6-2. 8US-4 Tuff soil 2.5-3.7

H. Eh,

#

R a d i o n u c l i d e ( X 1 0 " 3 M C i / m l ) Na* pH60Co 85Sr l37Cs (ppm)

US-1 6. 5 6. 1 7. 2 1.6 6. 0US-2 4. 3 4. 2 4. 8 2. 5 6. 1US-3 4. 4 4. 2 4. 4 3. 1 6. 2US-4 3. 8 4. 5 3. 7 1.1 6.

F 30cm(f> X l 2 0 c m h o

mm(l/h) (h) (1)

US-1 0. 386 622 240US-2 0.519 462 240US-3 0. 256 937 240US-4 0. 287 837 240

Adsorption

Retardation factor60Co 8 i Sr 137Cs

US-1 3500 3700 3700US-3 10000 9400 11000US-4 8900 11000 9600

246 -


1 5 (156-1

A

ffl

A*•

tz

m••

•

•"Tc

Ay^fi (filt'S, is

Z. Huie, Z. Jishu and

L^m/16000rpm)

Z. LanyingSorption of Radionuclides TechnetRadiochimica Ada 44/45, 143-145

^ H (China) ©tkJ^Tif £?t\tz§MM(D%

S t ibn i t e (SbA), Mo 1 ybden i te (M0S2),Pyrite(FeSz), rare-earth-Hematite

T Z K ^ ' I 4 ( P H , Eh, &.ft-i*->NHJcO^^dOOOBq/lOml^

Desorption Experiment}

©fifeMit=10rnl/0. 5g, SS

^ & [ m l / g ] . . . Adsorpt

mm. M&m

ium and Iodine on Minerals(1988)

fug. mymmfctiiit^ZiftftL, 60-120meshTlS(/ t tb

Chalcopyri te(FeCuSz),(r. e. -Fe,Oa)

) , NaIJ§?S(1660Bq/10ml)o RimWtV^i

ion

Minerals Contact time pHCsorpt(days)

St ibni te 17

14212842

Molybdenite 17

142135

Hematite 17

1421

5. 876. 224.534. 643.844.67

8.048.02

7kitmmLtzo^°

ion) pH(desorption)

5. 225.324.785. 154.715.99

Galena(PbS),

Rs(Tc)

143380520

103219801980

1.0.2.1.2.5.1.1.2.

366371208

- 247 -


1 5 6156-2

A

Z. Huie,Sorption

H/16000r

Z. J ishu and Z. Lanyingof Radionuclides Technet

Radiochimica A d a 44/45,

Minerals

Chalcopyr

Galena

Hemati te

Molybdeni

Stibnite

Pyri te

... Adsorption

Contact time(days)

ite 138152213815221381522

te 137152113715211371521

143-145

pH(sorpt

7.738.037.648. 118. 244. 274. 833.534. 646. 147. 918. 248.348.298.317. 707. 627.647.837.895.42

5. 664.724.547.057.838.038. 108. 10

pm)

ium and Iodine(1988)

ion) pH(desorpt

8. 157.717.848. 107.956. 716.626.446. 346.36

on Minerals

ion) Rs(I)

41. 547. 849.066.696.9118836362137

1. 21. 61. 2

1.30. 41. 13. 0

0. 92. 72. 82.61. 52.62. 72. 56.03. 65. 9

- 248 -


xm1 5 7

A

m

J. C. Balogh and D. F.Soi l ChromatographiMinnesota SoiSoi l Science,

A*'J7tf<D#lS{t^

Aquic FragiochreptCumulic Haplaquol1Typic EutroboralfAl fic UdipeammentAerie Calciaquol1Cumulic Haplaquol1Typic Haplaquol1Aquic Hapludol1Aquic Hapludol1Aquic Haploborol 1Udic Haploborol1

-?-COftb,• lmmTlfljl^U" L• ^^f^> 0 023 ii

•mmmr xn• Column £ 1 cmiHi CO• 0. lM-CaCh lOmml

#iE<&&[ml/g]

Is130,

Sand[dry53163

9599

374027778

fc±*

f r a c t

xm

AquicCumulTypicA l f i cA e r i eCumulTypicAquicAquicAquicUdic

Grigalc Movement of

278-282 (1980)

Clay Surface

Technetium-99 through

area pH Organic-Cwt-X] [mVg] [ d r y

12 8732 17817 46

2 5227 9234 18630 16022 15030 14412 10132 224

:c£ffiTFU &.IZ£Z®tii$:ft

on£U <£$(

Fragiochreptic Haplaquol 1EutroboralfUdipeammentCalciaquol1

ic Haplaquol1Haplaquol1Hapludol1Hapludol1Haploborol1

Haploborol1

5.47. 65. 55. 77.77. 7 17.86.05. 98. 36. 6

3.8.2.0.5.1.7.2.2.1.3.

wt-X]03324038481

<, # 7 X Hi ©column pi

S e l e c t e d

32$&M, figFe Oxide[drywt-X]

1. 10.41.40.60. 10.50. 30.70. 90. 21. 2

atefc**.

A , waterfront#^]£Tp|S=fcO10ciiLk

05t:, 12hours)

KdCTc)0. 1550.0280. 0680.0510. 1180. 1180.0760.0780. 0110. 0000.000

%•3

l o

CEC[meq/100g]

15. 227.011. 3

3. 216. 936.443. 520. 419. 311. 726. 8

- 249 -


1 5 8

A. Winkler, H. Bruhl, Ch. Trapp, W. -D. Bock and FU Berl inMobility of Technetium in Various Rocks and Defined Combinations ofNatural MineralsRadiochimica Acta 44/45, 183-186 (1988)

A

smectite, pyri te(FeS2, Meggen/Lenne,

Eh.I 6meq/l),

Reclrculatlon - column Inert gas overlay

10 cm langlh P,5 cm ?

R s (ml /g l

O «O SO

O.TcunfHlwad

120 160 200 240 200

. Tc lllt«*4(4S0 nm)

Iner t gas (Ar:CO2=99:1)

• .

12-

10-

8-

6-

4 -

2-

pH

1 1 r T 1—ConUct tlma (dayt)

—i 1 1 1 1 1 1 1 160 120 160 260

Fig. 5. Effect of contact time on Rs. Eh and pH in a recUculationcolumn filled with aeolian sand (inert gas overlay).

- 250 -


1 5 9159-1

A

m

All

A

K.

v*m (® %cMto :0. 3rpmX3~90days, M>b$

H. Lieser and CH. BauscherT e c h n e t i u m in t h e H y d r o s p h e r e and i n t h e G e o s p h e r eI. Chemistry of Technetium and Iron in Naturalt h e Redox P o t e n t i a l on t h eR a d i o c h i m i c a

• Gorltt<Dfy)M{teben, FRGcfc

Sediment Depth

SIS2S3S4S5

SIS2S3S4S5

SIS2S3S4S5

W5 4 - 787 1 - 78

8- 14178-180200-204

SiO2 A96.32 1.92 .15 3.93. 72 3.94. 96 2.93. 02 3.

Cr Mn93 46590 31091 230

167 23026 155

MfS.(PH, Eh.

Acta 42, 205-2

OJ^lXbfcSedimOrigin

MiozeneMiozeneWeichsel-glac

Sorption of Techne13 (1987)

e n t S o

Watersti

Speci f i c - sur face[cmVg]137. 2251. 6

ial 113.2Old-ple is tozene 133.2E l s t e r - g l a c i a l 141.5

Major consti;03 Na*0 LO73 0. 27 0. 8895 0.76 1.0712 0.57 1.0254 0. 43 0. 7423 0. 76 0. 66

Minor constiCo Ni Cu16 19 35143 33 35642 45 43248 54 23798 30 376

i t ££. ''K ~2c "V SS E& 913 f

Groundwater Depth [m] T [ t ]GlG2G3G4G5

36-68-12-

41 1 1 ( 1 1 . 2 ) 770 1 2 ( 1 2 . 6 ) 716 1 2 ( 9 .6) 7

198-200 12(16.6) 7193-221 11(18.2) 6

tuents [%}MgO CaO Fe0.20 0.21 0.160. 34 0. 44 0. 620. 32 0. 46 0. 430.31 0.40 0.310.32 1.12 0.40

t u e n t s [fig/gi

Zn Ga Rb102 8 14151 11 41233 11 36

2442 21 14382 12 26

pH Eh [mV]. 3(7. 3) 495(185) 8.. 7(7. 3) 385(175) 8.. 7(6.5) 420(317) 8.. 0(6.7) 385(245) 8.. 9(6.8) 215C 90) 7.

100000

Sr5889314239

O2

urn

i . -Y3

a/o. 45

and In

0rganic-C[w-X]0.0.0.0.0.

nos.05. 32. 12. 11. 23

Y212528

16844

[mg/1]4(0. 1)6(0.2)

25

(2.0)(2.6)

0(0. 1)

182227072179275

Zr204684620

1109917

^ )

fluence of

Carbonate[w-%]

1.0<0. 1<0. 1

1.61.5

P2Os500400200300700

Conduct ivi ty [/iS/cm]200

15250( 192)

( 16100)

220( 158)155000(136500)286000(168000)

- 251 -


3rpmX3~90days, 45/im)

1 5 9159-2

K. H. Lieser and CH. BauscherTechnetium in the Hydrosphere and in the GeosphereI. Chemistry of Technetium and Iron in Natural Waters and Influence ofthe Redox Potential on the Sorption of TechnetiumRadiochimica Acta 42, 205-213 (1987)

A

, Eh, T)

NYGl 0.G2 138G3 0.G4 1267G5 2509C/A-conc

HCOrGl 0. 75G2 4. 00G3 0. 60G4 5. 25G5 1.25

40Mg"0. 276.45

57 0. 2443. 57. 11

[mval/1]NO?

<0. 0010.0460.0060.001

<0. 001

Cat ion/An ion cone entrat ions[mva1/1]Ca"0. 98

13. 50. 37

81. 492. 9

PH7.37.77. 77.06. 9

Sr 4 Fe"/3t Mn"0.001 0.001 0.0030.080 0.001 0.0270. 002 <0. 001 <0. 0010.098 <0. 001 0. 0090.060 <0. 001 0. 150

Cr"0.

1470.

12242748

31

33

0.0.0.0.0.

Br033300001160300

NOs"

<o.0.

<o.0.

<o.

001130001290001

SO0.5.0.71.47.

1

41988643

EhDnV]495385420385215

Fe-conc. [mg/1]0. 029 + 0. 005( 3. 11)0. O27±O. 005( 1.20)

<0. 008 ( 1. 60)<0. 008 ( 2. 30)<0. 008 (11.0 )

±i

Gl/SlG2/S2G3/S3G4/S4G5/S5

Aerobic condi t ionspH Eh[mv] Fe-conc. [mg/1]

7. 36. 25. 87. 46. 8

490440475380415

0. 023±0. 0050. 015 + 0.005

<0. 008<0. 008<0. 008

Anaerobic condi t ionspH Eh[mV] Fe-conc. [mg/1]

6.2 220 0.087 + 0.0157. 4 125 0. 30 + 0 . 0 47.3 140 10.4 + 0 . 57. 5 200 1. 81 ± 0 . 0 96. 9 200 2. 06 + 0 . 10

ertmbrane filter,

Anaerobic condi t iontlfsgffl L fcinPolyethylene tube, M@l£=7. 5ml/3g, 0. 45Mm-me

10 6mol/l-NH499Tc040

Contact=60daysSampleGl/SlG3/S3G5/S5

Adsorption, DesorptionAerobic conditions

Rs[ml/g] Rntml/g]0.32 + 0.050. 29 + 0. 080. 08 + 0. 02

0. 30 + 0. 060. 18 + 0. 060.09 + 0. 02

AnaerobicRstml/g]890± 180770 + 130990+180

condi t ionsRD[ml/g]>2000>2000>2800

- 252 -


as-

1 6

Eft-A

m;

t

mft

0

A - y ^ S OlsiJKch "5 :0. 3rpmX 3

K. H. Lieser and CH. BauscherTechnetium in the Hydrosphere

~90days,

and in theII. Influence of pH, of Complexing Agent;Sorption of TechnetiumRadiochimica Acta 44/45, 125-1

\*U7#©WI{t¥W&tt(<t¥*us. «•Xittl59t^i;.

ftT/K#1$(pH. Eh. rt??-i'^>-Sg, ffl®^)• 3t$U 5 9 ilWICo

e©te• 0. lM-HCl lCi -SpHISIg^f j -^ , £ >

• 30mg/sample£)pyrrhotite, p y r i t e .

•m<D&mz*mi 5 9tmua

SE#$:[ml/g] . . . AdsorptionC o n t a c t = 6 0 d a y s A e r o b i c c o n d i t

(7days) pH Eh[mV]G3/S3(Low s a l i n i t y )

without EDTA 5. 7 ± 0 . 5 475 + 30with EDTA 5.6 + 0.5 385 ± 3 0

G5/S5 (High s a l i n i t y )

Time[d]7

306090

w i t h o u t EDTA 6. 9 ± 0 . 5 4 1 5 ± 3 0with EDTA 7. 4±0. 5 355±30

Pyrrhoti tepH EhDnV] R,[ml/g] pH

5.4 + 0. 1 430±15 677±23 5. 9±0. 14. 5±0. 1 490±15 620±35 5. 2 + 0. 13. 5±0. 1 510+15 526±80 5. 2±0. 13. 6 + 0. 1 490±15 443±61 4. 8±0. 1

28 (1988)

magnet i t

ionsR.[ml/g]

0. 43±0. 110. 29±0. 07

0. 17±0. 080. 09 + 0. 04

Pyri teEh [mV] R.540±15 0.555±15 0.575±15 0.620±15 0.

; Geosphere> and

7.8.

7.8.

[ffll/g]10 + 0.08±0.06 ±0.08 + 0.

5ii/0.45/zm

of Some M i n e r a l s

P L , -

*>£&??», 1

Anaerobic conditPH

4±0. 50±0. 5

l±0. 50±0. 5

05 7.04 7.03 6.04 6.

Eh [mV]

-100±30- 95±30

85 ±30105±30

Magneti

)

on t h e

,)

ionsR.[ml/g]

1145±1151050+105(172±67)

965± 97855± 86

(1. 5±0. 2)

tepH Eh[mV] R,[ml/g]6±0. 1 415±4±0. 1 450±9 + 0. 1 420±6 + 0. 1 390±

15 0. 08±0.15 0. 06±0.15 0. 05±0.15 0. 09 ±0.

04030305

- 253 -


1 6 1

A

ffl

£ mt

D. A. PalmerAdsorptand onJ. inors

ionandof

a Range;. nuc

• 1 0 0 - 1 7 0 m e s h ( 0

L1M 1 /j^^ *f \\ 1 *|

* NJU 1 J S '

• n* \y *—*v *

o :3weeks, jil'frfrSi)

R. E,. MeyerTechnetiof

1. Chem.

t¥. 152-0.

mi

Mineral NaCl[M]AlbiteApatiteAugi teAttapulgi teBasaltBerylBiotiteChalcociteChalcopyriteChloriteCorundumDolomi teEpidoteGalenaGraniteGibbsiteGypsumHemat teHornblendeIlmeni teIIIII

liteliteite

litei te

KaoliniteKaolinite

0. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10. 10.011.04.00.010.01

4.5.6.5.4.4.3.7.4.4.4.6.7.6.6.3.2.4.7.3.2.3.3.3.3.3.3.

3 y\

PH81-10-48-21-65-47-98-51-14-73-51-73-47-14-38-3 4 - 176-13-26-52-

urn on Selected InorganicNaturally Occurr, 43 2979-2984

088mm) i C t O O ^

Cl $:^sjP Isfz~4 B jJIi: o ~$~

^, Polypropylene

9. 259. 489. 308. 278. 909. 099. 049.088. 178. 728. 829. 389.057. 639. 531.069. 559. 139. 279.64

2 9 - 1 0 . 7 743-60-43-45-37-

8. 188. 648. 277.459. 16

9 8 - 1 0 . 6 2

Kd1. 8±1. 70. 8 + 0. 60. 2±0. 4

-0. 2 + 0.44. 7±8. 91. 0+1. 03.4±1. 71. 6 + 0. 61. 7±1. 01. 2±1. 10. 7 + 0. 30. 3±0. 30. 0±0. 13. 2 + 0. 90. 9±0. 42. 6+1. 81. 6+1. 35.4±1. 21. 3±1. 00. 2 + 0. 24. 8 + 0. 35. 1±3. 47. 7±4. 73. 7±2. 71. 5 + 1. 2

10. 8 + 5. 64.0 + 3. 7

ing Minerals(1981)

If-

»».

MineralKaolini teKaolini teLimoni teMagnet iteMicroclineMolybdeni teMonazi teMonazi teMonazi teMontmori1loniMontmorilloniMontmori1loniMontmori1loniMontmori1loniMontmori1loniMontmori1loniMuscovi te01ivinePyri tePyroxineQuartzSerpent ineSpheneTriphvli teZi rcon

Ion-exchange Mateiunder

NaCl

tetetetetetete

1.4.0.0.0.0.0.0.0. (0.0.0.0. (0. (1. (4. (0.0.0.0.0.0.0.0.0.

Oxic Condit

[M] pH) 3. 21- 8. 60) 3.41- 8.481 4. 88- 8. 231 4. 29- 9. 331 4. 82- 9. 771 3. 66- 7. 79

4. 70- 8. 623.71- 8.00

)1 4. 25- 7. 914. 57- 8. 244. 11- 8.436. 29- 8. 21

)1 4.44- 9. 10)1 4. 17- 9.21) 3. 84- 8. 72) 4. 00- 8. 351 5. 67- 9.02

6. 03- 9. 703. 39- 9. 705. 64- 9. 833. 91- 8.657. 55- 9. 275. 83- 9. 206. 34- 8. 715. 22- 9. 37

ialons

, JS

0.1.3.0.0.2.2.6.8.3.9.

-0.-0.262.3.4.1.1.0.3.2.0.1.0.

s

Kd8 + 0. 75±1. 28 + 0. 78±0. 85 + 0. 40+1. 30+1. 43 + 3. 22±4. 87 + 0. 90±6. 56±0. 16 + 0. 3. ±18.6 + 2. 10±2. 15±2.86±0. 86±0. 82 + 0. 24±3. 60±0. 45 + 0. 53±0. 79±0. 5

- 254 -


fflfefc

1 6 2

B.TorstenfeltMigration of the Fission Products Strontium, Technetium, Iodine andCesium in ClayRadiochimica Acta 39, 97-104 (1986)

A

A'JSodium bentoni te(MX-80, Wyoming bentoni te)

${LLfcfc<Z)£cylinder^lKl;:f iJtf l2. (2000kg/m3)\ minerals&<5 Wichemica l reagent S£$SJ!JDO

Eh.

clay) o• pH=8. 8-9. 0

CationK*Na*Ca!t

Mg2t

(preequi1ibrated with the

ppm11

6706.61. 7

An ionCl"N03"SO4

2

ppm132

6. 8870

ElementSrTcTcTcCsIII

I

Time[d]506970

21853

157218194213210225226224

Kd2900

05050

1400111111

800600

Additive

0. 556Fe0. 5%Fe

0. 5%FelKFe

ISSKM11O4Chalcopyri te

CinnabarPbO

frtl !»>«r o( 4iifu>int

mntpen Direction diltuuon crll (aUmUu su«l)

Fij. 1. leAcmiiic «^. of th< lilfuwi «eU («f.. ret. IJ)

I n i t i a l a m o u n t : 8 5 S r ( 1 0 1 2 m o l e s ) . 134Cs ( 1 0 - 1 2 m o l e s ) ,9 9 T c ( 1 0 6 m o l e s ) . I ! 5 I ( 1 . 8 x i 0 l 3 m o l e s )

- 255 -


1 6 3

A

SoilClayLoam

Summary

M. I. Sheppard and D. H. ThibaultDefault Soil Solid/Liquid PartiSoil Types : A Compend um

tion Coe

Health Phys., 59, 471-482 (1990)

: Soils: Soils: Soilspart ic

Organic soils

ElementAcAgAmBeBiBrCCaCdCeCmCoCrCsFeHfHoIKMnMoNbNiNp

classi

!$t[ml/g]Sand45090

19002501001555805004000607028022045025011550101604005

that containedthat contained

^ 7 0 % sand-sized^ 3 5 % cl

that had an even distriles or: Soil

c peat

Loam1500120

960080045050203040

810018000130030

4600800150080055575012555030025

m , *, c

consisted of ups thator muck

Clay2400180

8400130060075150560

20000600055015001900165

24001300

/751809090065055

:ontainec

ay-sizedbution oto 80% s

ffic ients

(Data Bas

Ls, for Four

part icles.part icles.f sand-,i 1 t-sized

> 3 0 % organic masoils, or the li

Organic540015000112000300015001807090800330060001OOO270270600

540030002520015025

200011OO1200

ElemenPPaPbPdPoPuRaRbReRuSbSeSiSmSnSrTaTcTeThUYZnZr

t ter hori

t Sand5

550270551505505005510554515035245130152200.

125320035170200600

icfjttt CR(=soil toi. ln(Kd) =4. 62+STEX-O.

STEX(sand)=-2. 51, STEX(loam)=-l. 26,5xln(CR)

STEX(clay)—0. 84,

clay- anc

P 1 **" v~i rr* P"w" Q )

Major

1 si 1t-sizedparticles.tter andzon of a

Loam25

1800160001804001200

3600018040

1OOO15050011080045020900

/ 0. 1500

33001572013002200

were e i thermineral soil.

Clay35

2700550270

30005100910027060800250740180

1300670110

1200/

72058001600100024003300

Organic90

660022000670730019002400670150

66000550180040030001600150

3300I

190089000410

260016007300

plant concentration ratio)^^

STEX(organic)=0

- 256 -


1 6 4

A

m

S. Yoshida , Y. Muramatsu andS t u d i e s on the S o r p t i o n ofWater, Ai

SampleAndosolKanuma so i1

Andosol =

ife FZK#'I4(PH.

• ? S S t b = lOir• Auto-wel1 N

#K«[ml/g]

AndosolKanuma soi 1

r, and So i l P o l l u t

L o c a t i o n MoiT o k a i m u r a / I b a r a k iKanuma/Tochigi

mwrnS. Uchidar(Iodide)

/ 4 0

and

OOi

10ion, 63, 321-329

s t u r e M29 515 6

Ando s o i l or Kuroboku s o i l

EH. a# - r*>»* . mc '"i \ 125io3\

M cr^

l / lg, polyethylene

. . . Adsorption

Kd(I) Kd1

1.5 1

«».

b o t t l e s .

"CD.

(Cl). 7. 5

PH.4.2

23t:

to4.0.

•pm)

sdodate) onto(1992)

-C[X] tot-N[%]4 0. 3056 <0. I

Andosols

CEC00

[eq/kg]. 20. 16

257 -


1 6 5 , 254, 37-48 (1976)

A

0.223mm)

, Eh.

. 0 1 / z C i / m l

... Adsorption

IO4

10*

Uptake period

3(hrs)• 4 0 ( * )• 168 ( • )

01

Fiff I The effect of land weifcamei free 1HC»

I 10Sand Wt, [g]

t on die dutnbution factor of

Fir

10" " " " 10 COmonovalent cation odded (*JHWil)

The effect of mi>nav*]«nt cntioa cooceotntioaon the dutnbution fictor of carrier free l"C§

Sand Wt ; ! gr

Solution ; i00 ml

Uptake period;7days

01

T\K 2 The efftct of muitivileot a t iao C

of cuncr free '"C«

xh* dutributtOB factor

000!

i f 4 Tht tActfeior of <:mrru

001

IfflR Hilt OOOCIrr ft** '"Ci

CsCIntniMM oc

0!Ccmi

i ilie *li

Ier oddedl^Vml)i*tnbg)i«M

- 258 -


yam.

1 6 6166-1

A

mA*U• [E

sts

Soi

oiHest

mi

• #

S. Yoshida

(mfcsSi5:l

Y. MuramatsuA d s o r p t i o n of IRADIOISOTOPES,

7tt©$)P

(5samples,

i^T^i-y

uplandCode=

-type : A(Ando, GR(Gray

50rpm

and S. Uchida" and I03" onto 6344, 837-845

f ie ldsV)Jk.ZSSl$/'$? \s o i 1 ) ,

¥*&**

'4000r

Japanese Soi(1995)

(25samplesopen areasI 2mm <!> H'G(Gley soi

Code:

pm)

Is

: U ) , p a d d i e s ((11 samples, Code=0)

22samples,

1), S(Sand-dune Regosol),Lowland s o i l ) , V(Volcanogeneous Regosol),

s o i l ) , - ( o t h e r s

It oMW\=

Eh, M>• I 2 5 T -

= lh ,• Auto-wel1 Nal5> >

SampleCodeU-01U-02U-03U-04U-05U-06U-07U-08U-09U-10U-llU 12U-13U-14U-17U-19U-21U-23U-25

MBcLWg]Soil Kd(I~

or unknown)

125IO3\ 3

s. m6C1"£

polyethyleneId, 3d, 7d,

y a >

. . . Adsorption) Kd(IO

Type [ml/g]9. 183. 282. 681. 92

- 10. 33. 56

A 14. 7GR 10.6GR 2. 36A 262

3. 263. 36

S 0.25S 0.07RY 5. 82GR 1. 33RY 2. 98RY 2. 91A 26. 9

8. 134. 531. 891. 509.402.46

10. 84.402. 08

1273.463. 790.410.424. 841. 024.48

25.933. 8

0 SoilPH

5. 295. 385. 825. 847.316. 686.436.874. 925. 275. 875. 336.447.096. 216. 905. 365. 985. 80

CEC

£*)mm.

b o t tlOd,

AEC[meq/kg]11410011493

139144254216119166142208

1414

1048

60144239

0. 90. 70. 81. 82.83. 35. 23. 71.4

66. 91. 51. 01.0

<0. 51. 7

<0. 50. 93. 62.4

l e s , 23<C14do

' * '

tot-Al tot-Fe[mmol/kg]

3340334025502670316038604080364030504260357028502410280028402670278044203160

770756390408390503

2000981641

1150954613510405683614286

1620956

act-Al

Code=Ph fore

RY(Red a n d Y e l l o w sP(Peat so

act-Fe[mmol/kg]15515637355188

1960262180

2020789155129

1186734

1481530

279295

899085

1066795322495481951192818836727

102541

TOC

1),

ot-N[g/kg]

6. 96.5

16.517.524. 811. 160.419.010. 242. 725 .241.3

0.60. 6

10.07.98.2

11.592. 9

0. 80.71.61. 62.41. 14. 61. 01. 93. 22.44.60. 10. 11. 20.91.01. 24.4

B(Brown For

Wtr. Cont.[I /kg]0. 0240. 0220.0160. 0140.0280. 0360. 0730.0450. 0130.0820.0630. 0590. 0030. 0030. 0400. 0170. 0080.0270. 067

- 259 -


xm1 6 6166-2

SampleCodeU-27U-29U-31U-33Li-3 5U-37P-01P-02P-03P-04P-05P-06P-07P-08P-09P-10P- l lP-12P-13P-14P 15P-16P-18P-20P-22P-24P-26P-28F-14F-20F-38F-39F-400-020-030-040-050-070-080-090-100-300-310-32

A ' y

S. Yoshida,

mm%to :150rpm

Y. MuramatsuAdsorpt ion of IRADIOISOTOPES,

SoilTypeAAAGRA---

-----

AGR-

GGRAGRGRRYGGRAGGRARYBBBVVAVSSPRYSSRY

Bl/g]Kd(10

[ml/g]19. 830. 811. 2

6. 8416.9

2. 741. 861. 888.013. 929. 999. 74

10. 60. 52

48. 16. 596. 25

12. 727.099. 3

8. 706. 63

27. 01.609. 399. 07

13. 35. 667. 922. 532. 933. 763. 51

17.04. 81

58.00. 112. 821.059. 535. 670. 150. 11

13. 9

30. 136. 012. 27. 14

21. 72. 273. 863. 804. 312.455. 326. 406. 481.03

37. 34.904. 17

11.324.485. 9

7. 365. 38

25.31. 687. 33

10. 412. 3

5. 148.862. 339. 88

13. 116. 228. 9

9. 7744. 6

9. 162. 370. 77

13. 358.4

0.440. 36

17. 5

and 10and S. Uchida, onto 63

44, 837-845

O SoilPH

5. 745. 876. 498.345. 737. 115. 725. 935. 606. 525. 265. 536. 086. 885. 805. 547. 435. 694. 805. 065. 565. 956. 065. 956.427.045. 735.925. 145. 125. 085. 005. 035. 545. 454.345. 745. 565. 404. 944. 726. 787. 035.56

CEC

(1995)

AEC[meq/kg]34221713226796

16610610373

1618484

14080

178153390140122335

9011016028623542722218426286

21619918886

1403281562515

352181

141286

<0. 53. 21.41.43. 11. 41.61.71. 21. 61. 61. 40. 80. 61. 62. 2

<0. 50. 80. 71. 5

<0. 5<0. 5<0. 5<0. 5<0. 5

1. 6<0. 5<0. 5

4. 31. 6

<0. 51.01. 2

69. 821. 210. 214. 2

1. 20.8

<0.51. 70.50. 43. 5

'SE7>

'4000r[

(apanese Soi

to t -Al t o t - F e[mmol/kg]

41204340375032703210313033002950248035003210317033303000373034802870323032003650293029802850344033803600276030003300209032503240314051206000280056702020196018404590281023402520

93811901240859

1060802757795281677390372704415

1450870761863815

10301020455469641637854677621

1140695482483475

1530483881372256251402

1690426364786

)Dl)

Is

act-Al act-Fe[mmol/kg]

200017501600

4380467

12511962

10913313017939

164043711399

1242110

1653287

12359

19004683

137033

272276270

3360556021504740

3737

182164

1015

456

40834450748

16297

22622611021312814027261

64127421823514751217176

133103107453222

75367

2997

10193

9883104692455356

15680

613

258iftAl t

roc tot-N[g/kg]

96. 851.427.411. 316. 711. 5

9. 37. 3

14.323. 915. 614. 330. 0

4. 748. 720.420. 017. 015. 2

10221.613. 720. 619. 020. 077. 121.018.4

10115. 254.046. 154.014. 6

5. 1181

4. 48. 34. 5

21313. 80. 30. 39. 7

Fe#*a<

6. 14. 02.51. 41. 51. 41. 49. 91.41. 41. 61. 61. 70. 53.61. 82. 22.01. 97.22.61. 52. 32.01. 95. 12. 11.62. 60. 13.73. 73.61.50. 98.50. 80. 70. 2

16. 61. 70. 10. 10. 9

: t -AU

Wlr. Cont.[ I / kg ]0. 0990. 1080. 0890. 0450. 0410.0270. 0280. 0240. 0140. 0240. 0160. 0130. 0240. 0160. 0600. 0430. 0520. 0250. 0140. 1020. 0390. 0090. 0190. 0330. 0300. 0980.0450.0350. 0900.0170. 0440. 0500. 0430. 1210. I l l0. 2780. 1290. 0040. 0030. 1190. 0330.0030. 0040. 032

ac t -Fe o )

- 260 -


> 31 6 7 282026. (1982)

B

l l 0. ?^, 50~80mesh (0.24 - 0 . 36mm)

, Eh,

. . . Adsorption

10'

10'

m

a'

'Ao—o——• ~~^-Q^

^ ^ ^ \ i

Ok*.

1.

[ V

•V

• i

! . 1

I02

- 'o' —

5!

KT»

-*-_4 ^ - \ . --a"

\

-V-

\

\

Sr

Cc

Mn

Ci

«r» io";

3 - 7

NT'

C« 01 *10"' iO"J 10 •*

- 261 -


(Jf#:500rpm.

, Mffi

1 6 8 U86011, (1986)

B

A'U0. 3

' /g]

ft" O l d - Aallophanehal loysi te

91.865.7

CEC, EXC(Ca, Mg, Na, K) [meq/ lOOg]5 . 6 7 1 .27 1.49 0 . 2 8 0 . 1 1

2 2 . 5 1 0 . 2 1 0 . 6 0 . 7 8 0 . 0 9(20. 0)

H, Eh,

2, 5, 10

. l~20go t l

. A d s o r p t i o n

Fig. 4.15(a) Effect of initial Ca concentration onCo distribution coefficients

Fig. 4.15(b) Effect of initial Ca concentration on

Sr distribution coefficients

- 262 -


1 6 9 382024, (1982)

, Eh.

¥!•fc«

* (-0.64)%. (=2. 59 g/cm:!)

(-0. 80)

Kd(Pu) = 205(ml/g) . . . R,(Pu)=375J;f9

- 263 -


or

scm1 7 0170-1

K. I to and T. KannoSorption Behavior of Carrier-Free Technetium-95m on Minerals, Rocksand Backfill Materials under both Oxidizing and Reducing ConditionsJ. Nucl. Sci. Technol., 25, 534-539 (1988)

A'J. 7X, I. 4—0. 7mm: 15. 8%, 0. 7~0. 35mm:38. 6%, 0. 35 — 0. 21inra:24. 1%,

0. 21mra:7. 6%), ' O h t i ' F , Granular quartz (0. 83~0 . 50mm), MM^n ~? Y>f y~7

• Granite (W|t5]$£lll), Forsterite, Hedenbergite. Hornblende, Muscovite,Bio t i te, Albite, Microline, Grossularite, Augite andesite, Epidote,Chlorite, Limestone, Plagiorhyolite, Pumice tuff, Olivine basalt,Medium-grained sandstone, Vitric massive tuff. Shale ... # - T O

K O . 4 9 ~ 0 . 83mmf;:f$^#tto• J t ^ ® S f [ m 2 / g ] : 1400 (Act ive carbon), 15 (Bentoni t e ) , 0. 5 (Granular qua r t z ) ,

1 (Granite)0.2

Eh.

Oxidizing ConditionReducing Condition .

""TcO, ffiM (0. 16M-NaNO3, pH7~8)9 5 T c ^ ( 0 . lM-NaBH4 + 0. 16M-NaNO3, pH8~9)

U10l2M,

T V > W f § , Nal (TO > > ^ V- -> al t = 5 0 i n l / l g , 25°C (Oxidizing) or 10°C (Reducing),

AdsorptionADVANTEC TOYO No. 5C

10'

-c

1O3

10.

o.» : Ac""* carbona. • : Bcntonite

10 1O3

V / m

50 m/ o( 0.1 M NaBH, 3nd 0.1SW NaNO. ;pH S ~ 9 ; 20 h at 1O*C

Fig. 2 Dependence of Kt on quantity of sorbenlshown by Tc under reducing condition

20 40 60 80

Shaking time(h)

0.5 % of purified* active enrbon: 1 g of granite ;50 in; o( 0.1 M NaBH, »nd O.lfi M N*NO»;pH 8~9: 10*C; centrifuged• Purification : Active carbon washed three times

with water by decantation, anddried overnight at 120'C.

Fig. 1 Distribution coefficient of Tcon purified* active carbon andgranite under reducing condition

- 264 -


1 7 0170-2

A

J^vJ-fe (St3+§£

K. I to and T. KannoSorption Behavior ofand Backfill MaterialJ. Nucl. Sci. Technol.,

^SE^^ttml/g] ... Adsorpti

SorbentGranular quartzBentoni teAlumina gelActive carbonForsteri teHedenbergi teHornblendeMuscoviteBiotiteAlbiteMicrolineGrossulari teAugi te andesi teEpidoteChloriteGrani teGrani te(O. 016M-NaNO3)Grani te(0.66M-NaNO3)Grani te(l. 16M-NaNO3)Grani te (0. 104~0. 147mm)Grani te(l. 981~3. 327mm)LimestonePlagiorhyol i tePumice tuff01ivine basaltMedium-grained sandstoneVitrie massive tuffShale

!:20hours, jj

Carrier-Frees under both25, 534-539

on

PH8. 58. 78. 1-8. 89. 19. 09. 08. 78. 79. 88. 38. 79. 18. 58. 68.78.78. 78. 88. 89. 58. 78. 6

11. 08. 89.09. 3

TechneOx i d i z(1988)

OxidizKd1. 70. 20-2. 32. 93. 00. 30. 51. 92. 01. 24. 30. 62. 60. 1-----0. 94. 42.02. 32. 11. 92. 6

/25000G or KSlSift/UnO

tium-95m on Minerals, Rocksing and Reducing Conditions

ing ReducingKd

32. 647.2-

14012. 7+ 2.623. 5+ 2. 917. 1+ 1.456. 1 + 11.070.5+ 7.520.7+ 7.517. 1+ 7.318. 8 ± 5.425. 3± 8.023.6+ 7.026. 5±10. 145. 6± 4. 268262371. 0± 4. 521. 6± 4.717. 2+ 4.517. 7+ 6.431. 9± 4. 113. 7± 3.324. 3+10. 124. 7± 7.719.9+ 6. 1

- 265 -


t M1 7 1 (1999)

D

-rSample

m) Upland(fiH?M) Upland

CEC[meq/kg](Depth 0-5cm, 5-10cm, 10-15cm, 15-20cm)107 134 148 131181 213 130 10791.8 97.2 91.0 101118 71 137 151

K ( K U R )

, Eh.

(8700rpinXlhour, 4°C, 0.

s, Co, Cr, Zn, Sb, U ICP-MS?£(HP -450

*. r, Mg!t, Ca")

(cr, NO.-,

RdSample ADepth( 0-Depth( 5-DepthdO-Depth(15-Sample BDepthC 0-Depth( 5-DepthdO-Depth(15-Sample CDepth( 0-Depth( 5-DepthOO-Depth (15-Sample DDepthC 0-Depth( 5-DepthdO-Depth(15-

[ml/g] =

5cm)1Ocm)15cm)20cm)

5cm)1Ocm)15cm)2Ocm)

5cm)10cm)15cm)2Ocm)

5cm)10cm)15cm)2Ocm)

Rd(Cs)600060004000

Rd(Cs)28

59025003600Rd(Cs)93075029001500Rd(Cs)500060001200530

Rd(Co)233443

Rd(Co)37481164

Rd(Co)3. 77. 1

18069

Rd(Co)54451131

Rd(Cr)109. 8

5. 5Rd(Cr)

5. 75. 2

Rd(Cr)2. 24. 8

23Rd(Cr)

8.611278. 1

Rd(Zn)642817

Rd(Zn)24473389

Rd(Zn)2. 94. 8

4490

Rd(Zn)24581756

Rd(Sb)1817198. 5

Rd(Sb)3825128.3

Rd (Sb)36374030

Rd(Sb)27201416

Rd(Sr)728713056

Rd(Sr)16457170

Rd(Sr)4. 25. 1

2465

Rd(Sr)21425442

Rd(Na)2. 22.98.43.2

Rd(Na)0. 10. 10. 30. 6

Rd (Na)0.41. 11.01.5

Rd(Na)0. 20.30.61.0

Rd(K )38536043

Rd(K )11121630

Rd(K )8.0132330

Rd(K )13182435

K[meq/1])Rd(Mg) Rd(Ca)

68829995

Rd (Ca)

33415138

Rd (Mg)15383843

Rd (Mg)1. 21. 81229

Rd (Mg)9. 1172116

275289110

Rd(Ca)1. 82. 51854

Rd(Ca)18344532

- 266 -


1 7 2

Y.Inoue and S. MorisawaOn the Selection of a Ground Disposal Site for Radioactive Waste:An Approach to Its Safety EvaluationHealth Phys., 26, 53-63 (1974)

A

Sand (and a l i t t l e C lay )

. Eh.

N u c l i d el 37Cs9 0 Sr58Co60Coi4Mn5 9Fe

" O l Ag6iZn"Mo

131 T

Kd1000

71200200500

510

50051 (assumed value) . (Data BasefcttSI

- 267 -


1 7 3 U 15, 503-508 (1973)

A

m

At

, W ^ t $ = 0. 014mm,: 24. 3 u eq/g, 4iCa?£: 18. 3 u eq/g) „

. Eh.

Ca"Mg"Na1

K*tot-Cat ionHCOfcrF

1. 08 [meq/1]0. 58 [meq/1]

[meq/1][meq/1][meq/1]

0. 80 [meq/1]0. 82 [meq/1]

[meq/1][meq/1]

0.600. 032.29

0. 010.03

tot-AnionHardnessM-AlkalinityP - A l k a l i n i t yt o t -S i0 2

tot-Fetot-Zntot-MnpH (at 10°C)

0. 61 [meq/1]2. 27 [meq/1]1. 66 [meq/1]0. 80 [meq/1]

6. 50 [ppm]0. 1 [ppm]0. 9 [ppm]

7. 8

... Adsorption

Soil-bedHeight[mm]Weight[g]PorosityM

Influent solutionHardness [meq/l]PHSat. -IndexA c t i v i t y [ ^ C i / m l ]E l u t i o n r a t e [ m l / c m V m i n ]

D i s t r i b u t i o n f a c t o r Kd

"Co *Sr 7Cs

1610. 036. 3

1. 938. 10. 230.032.31

18. 8

1522.437. 1

_

--

0. 00292.936. 7

1810. 043.4

2. 477. 6

-0. 120. 00642.28

409.4

- 268 -


scm1 7 4174-1

17, 376-384i ( I ) r(1975)

A

A*U . -f= 2. 67g/cm\

t $ = 0. 51mm, : 9. 44weq/g)<

, Eh.

Can

Mg"Naf

K1

1.000.530.900. 03

tot -Cat ion 2.46HC03

crF'N(V

co3z-

Soil-bed

Influent

Dis t r ibu t

1. 040. 800.010.030

[meq/l][meq/l][meq/l][ffleq/l][meq/l][meq/l][meq/l][meq/l][meq/l][meq/l]

:] . . . Adsorption7 A

Height[mm]We i gh t [g]P o r o s i t y Msolut ionHardness[meq/l]PHA c t i v i t y E A t C i / m l ]Elut ion rate[ml/cmVmin]ion factor Kd

SCVtot-AnionHardnessM-AlkalinityP-Alkalini tytot-Pbtot-Fetot-Zntot-MnpH (at 15°C)

60Co

2290. 04 0 . 0

1.547.30 . 0 0 32. 84

2 5 . 6

0. 602 . 4 81.531. 04000. 10. 907. 1

90Sr

2284. 64 5 . 9

1.687. 1

[meq/l][meq/l][meq/l][meq/l][ppm][ppm][ppm][ppm][ppm]

0. 000752. 744.4

- 269 -


1 7 4174-2

I d ) A - :17, 376-384 (1975)

A

= 0. 51mm,,ft5W• Q 4 4

= 2. 67g/cm\

fr

1, Eh,

Ca"Mg2t

Na*K*tot-Cat ionHC(VClF"

1.00 [meq/1]0. 53 [meq/1]0. 90 [meq/1]

[meq/1][meq/1][meq/1]

0. 80 [meq/1]0. 01 [meq/1]0. 03 [meq/1]0 [meq/1]

0.032.461.04

sty-tot-AnionHardnessM-Alka1 ini tyP - A l k a l i n i tytot-Pbtot-Fetot-Zntot-MnpH (at 15°C)

0. 60 [meq/1]2.48 [meq/1]1. 53 [meq/1]1. 04 [meq/1]0 [ppm]0 [ppm]0. 1 [ppm]0. 9 [ppm]0 [ppm]7. 1

7 D -

2.0CoKtmritlen of <

Fig. 5 Variation of distribution factor in re-ference to concentration of Ca+Mg

- 270 -


Ofrtt:24hours,

1 7 5 18, 445-451 (1976)

A

Natural sand (JiO>JBiu&$dtl*l) Ca 0.51Resin (Amberlite IR-120B) Ca 0.45-0.60

2 .65CEC[meq/g]

0.0114.3

Eh,

= 50nil/ lg(ResinK ^fm (Sand)

(a) C* type cation exchange resinAmberlite IK-J2OB

(b) Sample sand as function of pH

Fig. 3 Equilibrium distribution

factor kt of »°Y

- 271 -


1 7 6 , 15, 157-166 (1980)

A

ffl^ mmt.

H. E h .ffiy No.

C h e m i c a l c o m p o s i t i o n [ g / 1 ]N a C l : 2 3 . 4 8 , Na^SCh: 3 . 9 2 , MgCl r . 4 . 9 8 , C a C h : 1 . 1 0

5.(Packard^)

Soil Porosity Density[g/cnf] pHWakasa Johgu 0. 42 2. 67 6. 5Toyoura Sand 0. 43 2. 70 6. 8Wakasa Johgu 0. 39 2. 59 6. 8

Soil Diffusion Coeff. [cmVsec] KdWakasa Johgu 3.6X10"6 ' 30Toyoura Sand 4.4X10~6 10Wakasa Johgu 3.6X10"6 2.0

OUT LET - — = ;

r=> - IN LET

SEA HATER(200 cc)

SANDY SOIL

— 5.0 CM

RUBBER PACKING

LUCITE CYLIKDEK

FLANGE

200-HESHSTAINLESS SCREEN

c. 2 Schematic diagram of the diffusion experiment.

272 -


1 7 7

Y.InouePrediction of Radionuclide Migration in Ground Water at the JapanAtomic Energy Research InstituteDisposal of Radioactive Wastes into the Ground, IAEA, Vienna,proc. symp., 29 May-2 June (1967)

A

Eh,RI-spiked ground water,,

Tokai SandKd(Sr)= 9.41Kd(Cs)= 250

Oarai SandKd(Sr)= 71Kd(Co)= 108Kd(I) = 0Kd(Cs)>1000

pparatus for Kd determination

- 273 -


MSffi

S *

1 7 8178-1

D

ffl

&

ft

II?PNC ZJ

A*'J7tfE>No.SI JH^cS 2 it^i^S"S3 MKSS4 #t/^cS5 ® 5 *

No.Li $;&%£L2 Ml^Si1 9 '£? 1717 y i JL

L4 TEllHcL5 ®5#i

-trc7)ft&• mmit=

Sl/LlS2/L2S3/L3S4/L4S5/L5S6/L6S7/L7S8/L8S9/I.9

S (M?«:3days

1564 96-001,

(Los Alamos)(Nevada Test Si

( * 7 K 5 # )

(pH, Eh. tt#-f ^ ^

3. 33ml/g, ^ M

g]

Kd(r)1. 70. 81.00. 9-0.60. 20.70.3

7X7r)]/hc(1996)

fetl [mm]0. 15-0. 250. 15-0. 25

te) 0. 15-0. 250. 15-0. 250. 15-0. 25

-«S. M&m)

tlfz7&+ R Itlfz7k+ R Itx/c7K+R ItlfcTK + R Ittfc*+RI

Kd(IOr)<0. 03<0. 03<0. 03

1.24.84.8-1.65.4

No.L6L7L8L9

No.S6 ^ 3 - ^ 7S7 Fn7< hS8 MSS9 i/)VVft

"f-B — V ttfjfeo"

•yJV hfitWlt)^)'

l i t $ [mm]0. 15-0. 25

X ' R S ) 0.15-0.250 .15-0 .25

Zs¥-'$Hz£tlfz7k+ R IpT¥ift'^tl7t7K+R Itf[;£tT.fc7k+ R ir^Fffitr^tlfcTK+R I

- 274 -


1 7 8178-2

D

m

ik

ft1

AW

PNC ZJ

A'U7M©

SI &JJ£ÊJS2 i.^,^S3 ffH^fcS4 5H>fcS5 iHMg-S6 I M S

No.LI SftîL2 SifcgiL3 feiaîL4 ^fa i^ iL5 WW.'etL6 ijgKgi

Sl/LlS2/L2S3/L3S4/L4S5/L5S6/L6S7/L7S8/L8S9/L9S10/L10Sl l /L l lS12/L12

& (?!?t:4days,

1564 96-001, (1

(Columbia River)(PNL)

fc$£(PNL)(Los Alamos)

X 7 7 )V996)

:mm. »1% [mm]

0. 15-0.0. 15-0.0. 15-0.0. 15-0.0. 15-0.

(Nevada Test S i t e ) 0. 15-0.

(pH. Eh, &#-f :*>»

l-2ml/g, XUM\

g]Kd(I)

2-

<1-

<1<1

-<1

-<1<1

<l

fc/K+ R Ifz7k+R IfzA+R Ifc7K+R Ifc7K + R I£7K+RI

Kd(I03)<1<1<1<1<1<1

45

16<1

15

)

252525252525

a.

No.S7 @SS8 ^ 3S9 5 KS10 K DSI IKSS12SS^j:

No.L7 m-G^tiL8 â-2lL9 S M ^ ' ^ HL10 HnV'f

* * * * * * * *

= (te/Jc^J^) 0— 9 05" (PNL) 0V-f h (Nevada T. S.) 0(Pierre) 0.

ijfe o T^fSr t $ tire7k + Rr ftfr fe -3 T^FH t ' 2 tl/tTfc +t fc o T^Pffii; ^ fi/iTK + R- tfflt>'3T5P^(C$tl7i7KJoT^Pffit^tl/cTK+R I

!mm]15-0.15-0.15-0.15-0.15-0.

IR II

K. 1

# ) No.

2525252525

- 275 -


X®

1 7 8178-3

D

m

ft-

r

i

<y?m mm-.

!ISil51i6. 25days,

toRzfrz

il'L

7 7PNC ZJ 1564 9 6 - 0 0 1 , ( 1 9 9 6 )

A* U 7No.SIS2S3S4S5/S6S7S8S9

No.L1/L2L3/L4

L5

L6L7L8/L9

• m

-HKg (Konrad)5 R £ (Konrad)-SKS" (Konrad)-H/^S (Konrad)

J te i t t^^ 1 (Kon^ ± 1 4 > ^ h ^->^hff>(Konra

c#i4(pH. Eh, mDepth [m]

iftTzK 28t fcT* 1244

tfeT^X 1244

t feT* 28L3/L4<h|Wli;ifeT7K 5

!lajt=2. 5ml/g,S « > <1O"6M(L1

Sc[ml/g] KdSl/LlS2/L2S3/L3S4/L4S5/L5S6/L6S7/L7S8/L8S9/L9

^Jg[g/CD1

2. 712. 712. 683. 232.71

rad)(Konrad)d)

'] s0.0.0.0.0.

. &%.

i o i J J ) W i-077 iiWO033 M 4 O

<-[%]

(92), -B(72), 5(75), £

195 MfO&KD7f0214 iiWO

JbJW F

pH Eh[mV] Cone, [mg/1] (Na7. 2 3586.0 195

6.0 195

6.0 195

7. 0 -64

,L2, L7).

( D { * :

0.

32,32,Sr2

32,Sr2t

32,

73,

4, 15, -,214, 2720,

(75), £

JWUtO.*MO

*. K*. Mgz

130, 0.13200,

458, FeVFe" 57,214, 2720,

460, FeVFe4 . 1 , 15, 1

- 26. 9, 1

13200," 57, t30, 57,

86, 94.

2 X 10"M(L3, L4, L5)« 1.

<0. 2mm 0. 2-2mm0.44. 400. 20. 26.8

0 5 - 02. 37. 2

0. 42. 200. 304. 3

1 0. 05-0.2. 37. 2

"*(2)*^(3)-(31),' ^ ( 5 -:(60),OO

*, Ca",002,

17i r&TJT'i 'f r (6), OO(8), JW'JtO(2. 5), OO&it'itO (20)1 i S£(40), OO&^iES'(15)10), OO&W)tO(20)5^(10),OO&t>:ElJntO(25)

c r , I ,HCO 3 , so/", sio2,co2)300, 130, 117, 265

125000, 25.3, 70, 767, 12.8, -NH/ 4, Br" 840, BOa3" 100

125000, 25, 70, 767, 13, -ffl/ 6, Br" 840, BO3

3" 1000.002, 300, 129, 17.4, 265

3, 0.

6 X 1 0

2-6mm}0. 10. 5000.013. 9

1 _--

1, 260, 377, -, -

8M(L6), TO(L8, L9)o

(iS'L>^"^|H30min.)(jS'L^HfS30min.)(^L^««30min.)

- 276 -


1 7 8178-4Kfl-D

m

ft

$k

A*UNo.SI fS2 iS3 /S4S5 ;

ffiTNo.

PNC ZJ '

7W©$

H • v^r

1564 96-001, (1996)

*if£[mesh]U s 20-25

20-25T-f h 20-50h 20-50

g^(Conasuga) 20-50

LI NaCliSML2 NaCljgStL3 }L4 f>L5 >

•€•£

l a C l ^ ^laCljgift

Sl/LlS2/L2S3/L3S4/L4S5/L5S6/L6

PH, Eh. m**>m&. urnCone. [M] I -Cone. [M]

0.01-0 .02 10"° 8.0 .01-0 .02 103 8.0 .01-0 .02 10"° 7.0 .01 ,0 .20 10"' 9.0 .01 ,0 .20 10"3 7.

*. * « « • « . ZM.

]Kd(D

<o<o

0. 0-0. 10. 0-0. 13 (0. OlM)

0<o

PH2-9.4-9.8-8.2-9.9-8.

, 0.

)

No. liflhesh]S6 -f 7 < h

No. Cone. [M] T-Conc. [M] pH3 S6 NaCl/§?g 0 .01-0. 1 10"5 4 . 5 - 6 . 85472

0-0. 1 (0. 20M)

- 277 -


A y

1 7 8178-5

D

PNC ZJ 1564 9 6 - 0 0 1 , (1996)

JVNo.SIS2S3S4S5

Depth [m]914

1022590

6141

No.S657 ii58 *fi±

Depth[m] f i l l [mm]12296

137

No.LIL2L3L4L5

Eh.pH Eh [mV]7. 7 4007. 7 4007. 3 405

No.L6L7L8

tc

tC

T *FzK

PH-7. 77.7

Eh[m-

400400

*@it=2.5ml/g,

Sl/LlS2/L2S3/L3S4/L4S5/L5S6/L6S7/L7S8/L8

Kd(r)0.52. 11. 20. 60. 20. 31.01. 0

- 278 -


1 7 8178-6

D

m

PNC ZJ

A*U7#£>t

• $JtT^K*Ca2t

Mg"HCO3"

Kd(I

6 (3

1564

J(H^

pH, Eh .

K65

3.18

4.123

0.. / .

]

') =

m96-001, (1996)

1 30v-X, U-Eifi

* # - f * > S S . US

[mg/1]9 [mg/1]

[mg/1]3 [mg/1]

[mg/1]

1.9, 1.4

3ov-s, mm®

crH^SiO,SO-,2"

PH

30v-X), Depth 130m, fell 2mm0

70129.60. 00858. 3-8. 5

- 279 -


1 7 8178-7

D

7l

?£

A

PNC ZJ 1

A ij 7• Boom0. 5,

NoSIS2S3

JfeTzK

siSISI

S2S2S2S2S2

S3S3S3

Clay

mm*

<S*K:lday

564 96-001,

(Boom clay5" -A" -^17-f l"

Depth[m]160200220

H. Eh, &#-T; tzK(Boom C l a y ± © fNa+ 55. 3 [mg/l]Ca" 3.03 [mg/1]

ml/g

[ml/g]

r-Conc. [M]7.7.3.

7.7.3.7.7.

7.7.3.

9X10"7

9X10"6

9X10"5

9X10"7

9 X 10~6

9X10"5

9X10"5

9 X 1 0 3

9X10"7

9 X 1 0 6

9 X 1 0 5

)

(1996)

70%,0. 1

No.S4

>m

%&!

Kd2.1.2.

1.1.1.1.2.

1.1.6.

n&&, tt±ffiiA* - ^ 1 7 0

) > lit? 0.Depth[m]

140S4tSBoom (

1 , pH-3)o

Mg" 3. 20K* 7. 71

(I")122504

2502782135

06312

0. 3, Hi5mm, CEC

[mg/l][mg/l]

IS4S4S4

0.25, XW^O^Omeq/lOOgo

C032" 201

CT 6 .40

"-Cone. [M]7.7.3.

9X10"7

9 X 1 0 6

9 X 1 0 "

I S S . fir®, 37Kit4^)0.2, ^-(H)!1) DtO

[mg/l][mg/1]

Kd(I")1. 85, 5. 170. 70, 0. 871. 63, 1. 69

- 280 -


(?i?t :10-20days)

1 7 8178-8

PNC ZJ 1564 96-001, (1996)

D

No. W&lm]51 #52 F>53 ?>54 #55 ?>

0. 17,0. 19,0.14,0.12,0. 14,

0. 260. 250.210.150. 18

Depth [in]3

96. 5- 98. 5120.5-122.5213. 5-217. 5215 -220 < fift&fi^,

Eh.No.LI &(D hL2L3L4L5

pH6. 17.58. 08. 17. 5

Eh [mV]

-5011030

125

Sl/LlS2/L2S3/L3S4/L4S5/L5

Kd(I-)0.82.88.05.00.3

- 281 -


4 x - * <r> tz. ffi-f 4 Bjffitt WO

1 7 8178-9

PNC ZJ 1564 96-001, (1996)

D

±(Nevada Test Site:Depth 250m,

h)

H, E h ,

Na' 66 [mg/1]K1 10 [mg/1]Ca" 18 [mg/1]Mg2t 5. 5 [mg/1]

HCO3" 170[mg/l]cr 23 [mg/1]SO*1" 41 [mg/1]SiO, 62 [mg/1]

pH 8Eh 330 [mV]

K d ( D = 24. 5

- 282 -


(SSI:3. 10, 30days,

1 7 8178-10

PNC ZJ 1564 96-001, (1996)

D

No.SIS2S3S4S5 HS6

MDnesh]2 0 - 5 02 0 - 5 02 0 - 5 0 (SiO* 37 .2%, Al,Oa 23 .0%, FeO 19 .5%, MgO 19. 2%, CaO 0.7%)2 0 - 5 02 0 - 5 02 0 - 5 0

Eh,No.LIL2L3L4

0. 03N-CaCl.&#tJif tT7K0. 03N-NaCl£*a&J£T7k0. 03N-NaHC03*5. 13N-NaC1^7K

pH777

natural

Kd(D

SIS2S3S4S5S6

LI000000

L2000000

L3000000

L4000000

- 283 -


(*4«:lday. i&fc

1 7 8178-11

PNC ZJ 1564 96-001, (1996)

D

No. fell51 5i£ 0. 045-0. 063 mm52 t>t'jDt-fh 20-50 mesh

—>

H, Eh ,No. I - C o n e . [M] C o m p o s i t i o n [ p p m ]

Na* Kf Ca z t Mgzt C I " HCO3" S O / "LI A l t f e T z k 1 0 " 1 6 5 3 . 9 18 4 . 3 70 1 2 3 9 . 6L2 4 M - N a C l 10"6

L 3 - & J 5 £ t f e T 7 k 1 0 " " 1 6 5 3 . 9 18 4 . 3 7 0 1 2 3 9 . 5

12

12

$0J£=9O-225ml/g (Data > 22°CC

Sl/LlSl/LlS1/L2S1/L2S2/L3S2/L2

PH797977

Kd

1

(I10.30.0.5

-)

6

166

- 284 -


- 9 <D rz

(jiffhlnight. JI>L

1 7 8178-12

*7X7PNC ZJ 1564 9 6 - 0 0 1 , (1996)

D

h ( & ? $ : 0 . 8 M m )

. Eh,

ft

Kd(IOr)1.1.2121

6X6X

XXXX

10s

10"8

108

10"7

10"6

10"6

7. 71.43. 33.43. 23.4

7. 25.95.73.95. 24. 1

000.0

±0.±0.

2 + 0.±0.

4111

<0. 9

- 285 -


1 7 8178-13

PNC ZJ 1564^Wi&TST7s796-001, (1996)

D

( l u l l : <50mesh)

H. E h .

ft

No.LIL2L3L4

0.0.0.0.

01M-NaCl05M-NaCl1 M-NaCl5 M-NaCl

^BSM.

LI 105

L2

L3

L4

LI

1(T

10"'

10 5

10"8

r$^pH5. 115.516.917. 247.649. 715. 017.064. 946. 975. 056.425. 526. 307. 529.59

Kd(I-)0. 1700.6

-0. 24-0. 180. 150.480.630.740.610. 510. 251. 141.090.470.02

- 286 -


1 7 8178-14

PNC ZJ 1564 96-001, (1996)

D

No.SI -fS2S3 <50raesh

H, Eh ,No.LIL2

Sl/Ll

S2/L1

S3/L2

[d]

10 5

1 0 s

10"10 5

10"5

pH7. 27. 27. 26. 76. 76. 7

5. 576. 186. 747. 848. 58

2222222222

Kd(I-)0.52.02.0333

00. 1811. 420.400. 24

- 287 -


1 7 8178-15

PNC ZI 1564 96-001, (1996)

D

. nm.No.51 Bournonite (Crushed)52 Boulangerite (Crushed)53 Tetrahedrite (Crushed)

No.54 Wood Charcoal55 Animal Charcoal56 Darco-G-60

Eh.

Compos it ion[mg/1] Mg Mn Si0. 036 0. 052 30

Fe Ba V Ti Ca K Al Na0. 17 0. 008 0. 015 0. 01 0. 46 5. 9 0. 1 92

2ppm. C0i<20ppm)

SIS2S3S4S5S6

PH8.15-8.588.15-7.818.15-8.548.15-8.498.15-8.498. 15-8.49

KdC'T)1401400.06, 17360, 320, 160, 320430, 500860, 520, 740

- 288 -


- 9 <D Iz

1 7 8178-16KD

PNC ZJ 1564 9 6 - 0 0 1 , ( 1 9 9 6 )

HKS(PNL)l u l l : 0. 15-0. 25mm, i $ £ h CaCO3, Si02

n, Eh,

l-2km/yearc

Kd(D= 6

- 289 -


1 7 8178-17

PNC ZJ 1564 96-001, (1996)

D

No.SIS2S3S4

09-0. 25mm)(NaM)£(10/90)

No.S5S6S7S8

h (0. 063-0. 090mm)- h (0. 063-0. 090mm)^ — X h (0. 063-0. 090mm)

H. Eh.

fr

• AlJftTzkComposi t i on [mg / l ] Ca"

18Mg"4. 3

Na*65 3. 9

HCOf123

Cl"70

SO^9.6

SiO,12

h U - U - l (Hl4C03")> pH 8. 0 ^ 8 . 2O

SIS2S3S3S3S3S4S4S4S4S4

3d - 6m3d - 6m

3dlw5w6m

0. 5h-24h3dlw5w6m

Kd(l4C)002 .81. 12 .67 .8

0. 2 -1 . 00. 81. 12. 62. 2

S5S5S5S5S5S6S6S6S6S6S7S7S7S8S8S8

0. 5h-24h3dlw5w6m

0. 5h-24h3dlw5w6m3dlw5w3dlw5w

Kd('4C)0. 7 -1 . 9

1.32 . 03. 02. 3

1 . 0 - 1 . 73 . 73. 59.0

835.3

1600>104

5. 31600

>104

290 -


(M?*:7days, &fr

1 7 8178-18

PNC ZJ 1564 96-001, (1996)

D

'J- h ( l u l l : <2mm)

Eh,

No. pH Composition[mg/l]Na* K* Ca" Mn" Mg" tot-Fc

Ll 7.3 2200 21 600 2.1 260 1.2 0.9F"1.3

CT NO."5200 1

SO42 SiO2 HCO,'

570 8 .9 83L2 7. 0 3 1 3 . 2 1 3 0 . 0 2 5 . 0 0 . 3 2 0 . 0 2 0 . 2 6 5 8 1 . 1 4 4 1 3 61

LIL2

Kd('4C)1850+ 6002040± 1100

- 291 -


xm1 7 9179-1

M. Kumata and T. T. VandergraafExperimental Study on Neptunium Migration under in Situ GeochemicalCondi tionsMigration'97, Sendai, 1997/10/27

B

Au , -r * >Granite rock0 URL(Underground Research Laboratory, near Pinawa, Manitoba)

feSl80-850p

, Eh.

p H = 9 , Eh = -330[mV]« Conduct i v i t y = 1 4 4 0 M S/cm0

2. 54cm<f> X 2 0 c m < Z ) T e f 1 o n - 1 i n e d S t a i n l e s s s t e e l c o l u m n s: \ t , 2 o c D m e m b r a n e f i 1 t e r ( lOOOnm, A,

w i t h 02<0. 5ppm)

Column No.

123

Flow Veloci ty[m/sec]3. 5X10"7

1. 1X10"6

3. 2 x 10"6

Flow

0.0.0.

Porosi ty

503592578

Kd ("71

-3000900

- 292 -


17 9179-2

M. Kumata and T. T. VandergraafExperimental Study on Neptunium Migration under in Situ GeochemicalCondi t ionsMigration'97, Sendai, 1997/10/27

B

A'UGranite rocko URL(Underground Research Laboratory, near Pinawa, Manitoba)

it, fifil80-850

, Eh,

pH=9, Eh = -330[mV], Conduct ivi ty= 1440n S/cm0

with 02<0. 5ppm),= U 3, lOdays (Sorptionh

, Sorption^^^ClOm

Sorption Time Kd("7Np) Desorption Time Kd("7Np)[day] [day]1 0.63 10 3683 1.70 10 49710 2.80 10 668

- 293 -


(gf*:3weeks, . 2 j

1 8 0

M. Kawaguchi, M. Kaminoyama, H. Takase and K.SuzukiStudy of Cation Adsorption Model on Sodium BentoniteProceedings of the 1989 Joint International Waste Management Coference,Volume 2 High Level Radioactive Waste and Spent Fuel Management,313-317 (1989)

A

Na-Bentonite powder (Kunimine Co.), <300/imo

. Eh,D i s t i l l e d w a t e r (pH: 7 - 1 1 ) , N a - C o n c e n t r a t i o n = l . 4 5 X 10 3 ~ 4 . 6 6 X 10"'Mo

I n i t i a l C s - C o n c e n t r a t i o n = 7 . 5 X 1 0 ~ 5 M 0

P o l y p r o p y l e n e ^ . $ t 0 i t = 5 O O m l / O . 5g , 20°C, membrane f i 1

... Adsorption

Na Cone. [M] Kd(Cs) [mVkg]1.45X10"'1. 54X10"3

2. 01X10 3

3. 36X10"'5. 11X10 '1. 36X10"'4. 44X10 2

1. 52X10"'4. 39X10"'4. 66X10"'

2. 121. 721. 941.560.830. 540. 260. 140. 100.07

PH8. 68.69. 39. 08. 88. 78. 89. 59. 39. 2

Na Cone. [M] Kd(Cs) [mYkg] pH3. 27X10"'3. 28X10 3

3. 31X10"'3. 16X10 '3. 39X10"'3. 18X10"'3.59X10"'

1.431.621. 711. 761. 902. 142.65

7. 98.69.49.7

10. 210.611.3

- 294 -


mm)

1 8 1

A

T. Ashida, K. Miyahara, M. Uchida, Y. Yusa and N. SasakiRadionuclides Sorption Testing of Granite Using Leachate from FullyRadioactive Waste GlassProceedings of the 1989 Joint International Waste Management Coference,Volume 2 High Level Radioactive Waste and Spent Fuel Management, 319-321 (1989)

Granite rock (8HL&, 250~420/zmt||V^^) . X? S-

. Eh,

Initial Concentrations

Li Na Al Si0.4 5. 3 ~1.0 12

[Bq /ml ]l37Cs 2MPu+240Pu "'Am l41Cm !44Cm

200000 3. 2 29 1. 8 18

^@it=30ml/lg. Contact t ime = l~24hours, 7,28,56 days, Ambient temp,a and 7 spectrometry.

Contact time = 56 daysRadionuclide Kd

137Cs 80

2020

2 4 lAm2 4 2Cm, 2 4 4Cm

- 295


($tt:10days)

1 8 2 JAERI-M 89-21K (1989)

B

A U

• i t £ = 1 .989 (Cement m o r t a r ) , 2 . 0 2 8 ( I m p e r m e a b l e c e m e n t m o r t a r ) [ g / c m 3 ] 0

C h e m i c a l c o m p o s i t i o n [wt%]CaO S iOv AlzO3 FejOs MgO Na2O L O TiO» SCh P2O5 MnO

5 1 6 3 . 8 2 2 . 1 5 . 0 3 . 0 1 . 6 0 . 3 5 0 . 5 4 0 . 3 0 2 . 0 0 . 1 1 0 . 1 35 2 3 0 . 9 2 0 . 3 1 . 7 4 . 3 1 9 . 4 5 . 0 0 . 1 5 0 . 1 8 1 . 0 0 . 2 0 0 . 0 65 3 2 . 7 7 8 8 . 1 6 3 . 4 0 0 . 6 3 0 . 1 3 0 . 7 6 2 . 1 4 0 . 1 7 -

SI: Portland cement, S2: Impermeable reagent, S3: Toyoura sand

Eh,

0. 13

pH Kd(l37Cs)Cement mortal 11. 6 1~ 4Toyoura sand 11. 6 2 ~ 8Impermeable reagent 11.6 1 — 12Impermeable cement mortal 11.6 2~14

Toyoura

- 296 -


-28days, 45,um-meinbrane)

1 8 3[83-1

T. Igarashi, Y. Mahara, N. Ashikawa and M. OkamuraEvaluation of Radioactive Strontium Distribution Coefficient byAnalyzing Background Stable StrontiumJ.Nucl. Sci. Tcchnol.. 35, 190-197 (1998)

A

SI: Sand in confined aquiferS3: Ground granite(0. 074-0. 42mm)

(SI, S (S3,

S2: Coastal sandS4: Ground shale(0. 074-0. 42mm)

0. 074-0.

Depth Specific Grain-size[%]

M51 052 553 40054 400

gravi ty2. 802. 612. 642. 74

Clay Silt Sand9089100100

PH(H«O) (KC1)7. 4 5. 17. 8 7. 18. 9 8. 17. 8 7. 7

CEC[meq/lOOg]

180.482. 64. 6

EXC[meq/100g]Ca

7. 91. 32. 111

Mg3.50. 180. 060. 52

Na K2.0 1.20. 21 0.040. 2 0. 090. 23 0. 36

Eh.LI: Spring waterL3: Groundwater inflow to the tunnel

L2: Groundwater inflow to the trenchL4: Groundwater inflow to the tunnel

pH ECCat 25*0 Concentrations [mg/1]

LIL2L3L4

8.07. 18.38. 1

[mS/m]12. 2

97311. 517. 3

Ca Mg6. 3 2. 4

520 27014 0 .8519 4. 8

Na12

12007.4

11

Cl"17

28001.2 6 .70 .43 <0. 1

K1.1

73

HCO,"32

3703990

SO/2. 1

11009.9

15

NOf0. 9

<0. 13. 10.3

Sr0 .0253. 50. 152. 6

+85SrCh). (85Sr 30Bq/ml, Sr 0. 025~10mg/l)• *@Jt=l~1000ml/g(50ml/0. 05~50g),•85Sr : G e ^ # # ^ f f i ^ Sr(stable) : I

o. IN-CH3COONH4X«O. IN-HCIICP-AESXttICP-MS(7° 7

- 297 -


:>24hours, . 45^m-menibrane)

1 8 3183-2

T. Igarashi, Y. Mahara, N. Ashikawa and M. OkamuraEvaluation of Radioactive Strontium Distribution Coefficient byAnalyzing Background Stable StrontiumJ. Nucl. Sci. Technol., 35, 190-197 (1998)

A

10000

I.

o

1000

10 100Stable Sr concentration

1000

o K,,(W=I e/L)K,,, (w=5eA)

W SI

100 1000 10000Stable Sr concentration (/ig/L)

O Kd.(a>=20g/L) A Kd,(a>=100g/L)• Kdr(co=20g/L) A Kdr(a>=1OOg/L)a ^ + R*

(c) S3

1000 10000

Stable Sr concentration

O K^(w=10g/L) A Kd.(oKdr (a»=50g/L)

a R. + R..(d) S4

- 298 -


:>24hours, . 45Mm-membrane)

1 8 3183-3

T. Igarashi, Y. Mahara, N. Ashikawa and M. OkamuraEvaluation of Radioactive Strontium Distribution Coefficient byAnalyzing Background Stable StrontiumJ. Nucl. Sci. Technol., 35, 190-197 (1998)

A

L, : Distribution coefficient ofstable Sr

Kar : Distribution coefficient ofSiSr

R<ia : Distribut ion rat io ofbackground stable Srusing 0. IN CH3COONH4

Rdh : Distribution ratio ofbackground stable Srusing 0. IN HC1

or'

o

o. 11000 10000 100000

Stable Sr concentration (/L<g/L)

K-r(o;=0.2e/ml)+ R.

(b) S2

0. 11000 10000 100000

Stable Sr concentration (fig/L)

OA

Kd.(t=1d)Kd,(t=28d)Kdr(t=7d)

O Kd,(t=7d)Kdr(t=1d)Kdr(t=28d)

- 299 -


:>24hours, - 45Mm-membrane)

1 8 3183-4

T. Igarashi, Y. Mahara, N. Ashikawa and M. OkamuraEvaluation of Radioactive Strontium Distribution Coefficient byAnalyzing Background Stable StrontiumJ.Nucl. Sci. Technol. , 35, 190-197 (1998)

A

1OOOO

10000

OJ=1K/L, t=1d A

L, t=7d A

(a) SI

, t=1d, t=7d

O a>=0.2e/ml,t=1d AD co=0.2e/ml,t=7d O• cu=0.2e/ml,t=28d A

(b) S2

tu=1e/ml.t=1d«u=1e/ml.t=7da>=1j/ml.t=28d

0 to=20g/L. t=1d• w=20g/L, t=28d

aj=100g/L, t=1dcu=100g/L, t=28d

O•

a»=10g/L, t=1dto=10gA, t=7d

AO

100

., t=1da>=50g/L, t=7da>=50g/L, t=28d

(c) S3 (d) S4

- 300 -


mm £ it. ^(H)

1 8 4184-1 33, 180-193 (1991)

A

, Co>

CoSrCsNaBr

[mol/l. 4L]1110. 20. 2

[mg/L]4210062600949003300

11400

SrCo, CsCa, MgNa, K

301 -


1 8 4184-2 33, 180-193 (1991)

A

Sr CONCENTRATION (meq/lOOg)

Co CONCENTRATION (meq/lOOg)5

X

LIQUID PHASE CONCENTRATION

EASILY EXCHANGEABLE SOLIDPHASE CONCENTRATION

C D UNEXCHANGEABLE SOUDPHASE CONCENTRATION

5 101 50 10"Kdt or Kd,. (ml/g)

(a) Sr

LIQUID PHASE CONCENTRATION

E 2 J EASILY EXCHANGEABLE SOUDPHASE CONCENTRATION

C Z ) UNEXCHANGEABLE SOLIDPHASE CONCENTRATION

Cs CONCENTRATION (meq/lOOg)

.0 1

LIQUID PHASE CONCENTRATIONEASILY EXCHANGEABLE SOLIDPHASE CONCENTRATIONUNEXCHANGEABLE SOLIDPHASE CONCENTRATION

0.5 10» 5Kdt or Kdr (ml/g)

(C) Cs

T h e Sr, Co, Cs c o n c e n t r a t i o n s w e r e d i v i d e d into 3 c o n s t i t u e n t s , and 2di f f e r e n t t y p e s of d i s t r i b u t i o n c o e f f i c i e n t w e r e c a l c u l a t e d .( t = 2 7 0 d a y s in n a t u r a l r a i n f a l l e x p e r i m e n t )V e r t i c a l p r o f i l e s of Sr, Co and Cs c o n c e n t r a t i o n and d i s t r i b u t i o n c o e f f i c i e n t

- 302 -


, ra s, H)ic(H)

1 8 4184-3 33, 180-193 (1991)

A

5 m1

§CO

310"3<3 . .

10'

Sr

• 10 days

D Mdays

H

82O

ro

101

10°

10"'

IO-2L_Jio-J

O 189 days

A 270 days

x 360 days• BATCH

EXPERIMENT

,,l nl r.10"1 10" 10l 102 10J

LIQUID PHASE Sr CONCENTRATION (meq/I)

10*

Co

• lOdaysO 38 days• 91 daysO 189 daysA 270 daysx 360 days

• BATCHEXPERIMENT

i l l III inl

i r" io° iol io2 ioJ

UQUID PHASE Co CONCENTPJVTION (meq/I)

Fi» 4 (W Co

10'E

102r

10' r

10° r

io-

: 1 1 l l l l l l |—1 1 • 11 Til 1

- "•* * *

'-

Or

: x

r

! i i mil l i i Mintl

i i mini—i i imn|

Cs

•

•O

(A* x x

•I

I i m i n i I I ' M i n i

1 1 II Mil 1 1 Mil :

10 days

Mdays "

91 days ]

189 days -270 days -z

360days =BATCHEXPERIMENT "

1 1 mini 1 i ' • •

10'

LIQUID PHASE Cs CONCENTRATION (m«i/l)Fig. * (c) C.

103

- 303 -


(it#:6days.

(E)1 8 4184-2 33, 180-193 (1991)

A

A'J

Hi. Eh.—»t(Sr, Co,

CoSrCsNaBr

[mol/1. 4L]1110.20. 2

[mg/L]421006260094900330011400

M (Fig. 4)

- 304 -


:l~28days, 31&/0 . 45,um-meinbrane)

scm1 8 5185-1

-U95025, (1996)

S5: Sand in unconfined aquifer S6: TuffS7: Sandy tuff

(S6. S7)te#H$L0. 074-0.

Depth Specif ic Grain-size[%] pH CEC EXC[meq/100g][m] g rav i ty Clay S i l t Sand (HzO) (KC1) [meq/lOOg] Ca Mg Na K

55 5 2. 62 9 4 87 7. 5 5. 1 18 8. 4 6. 4 0. 11 0. 2656 20 2.31 0 0 100 7. 8 6. 3 11 4. 9 3. 1 0. 11 0.4757 20 2.60 0 0 100 8.2 6.3 10 4.6 3.1 0.02 0.33

Eh,L5: Groundwater inflow to the tunnel L6: Groundwater inflow to the tunnelL7: Groundwater inflow to the tunnel

pH EC(at 25°C) Concentrations [mg/1] [ jug/H[MS/cm] Ca Mg Na K Cl"HC(V SOr" NO.f Sr Ni

L5 7.1 103 3.9 2.7 9.2 0.8 16 17 1.9 5.8 0.034 4.1L6 7.4 115 5.6 2.7 9.7 1.9 15 24 2.0 5.3 0.037 5.5L7 7.7 119 6.4 3.3 9.6 1.3 17 26 2.0 6.2 0.039 5.4

• 100ml;tf 5-7 . i JA"f 7J l /MtPVC^-f y~7)\z, 50ml©7Kj§^(tfeT7K48inlH, 60Co or '"Csor 6 3 NiCO^{b^5^^0. link JkZSCo or Cs or Ni<7)iii'ft$9^#£0. 1

f'"Co, 137Cs : lOBq/mL "Ni : 70Bq/mh Co, Cs, Ni te0~10mg/l«• i«@Jt= l~1000 jn l /g (50ml /0 . 05~50g) , 23±2°Co• 60Co, 137Cs : N a I ~ > > ^ l x - > 3 > ^ m ^ 63Ni

i £ 0 . lN-CftCOON&X&O. 1N-HC1 Sr\ ICP-AESX«ICP-MS(7°

- 305 -


IUUW

•Z. 1000

ml/

5 100

10

//*

< : / *

' • • / * .

e (a-lg/l, t-ldg/l, t-1d

0J-1g/l, t-7dai-5g/l. t-7d

A«-5g/l,t-1d. »-1g/l.t-7d

10 100 1000 10000

Kds (ml/g)

3—15 KWSC&TiCoCDK^fc r_

Fig. 15 Relation between K^ and K# of

cobalt for sample S

10000 F

o eo-1g/l, t - ldA o>-5g/l, t - ld• «-1g/l,t-7d. &)-5g/l, t-7d

100

100 1000

Kds (ml/g)

10000

3-18 Btfi5C#-f*Cs0>K().fcK<jri:0>Mffi

Fig. IS Relation between K^ and KA of

cesium for sample S

10

El-16

100 1000

Kds (ml/g)

Fig. 16 Relation between K4 and K4 of

cobalt for sample 6

1000

100• ai-ig/1. t-7d4 a)=5g/l, t-7d

10 100 1000

Kds (ml/g)

g—17

Fig. 17 Relation between K^ and KA of

cobalt for sample 7

10000

IE, 1000

100

o fc)-1g/l, t-ld

A en-5gA t-ld

• oj-lg/l, t-7d

. o)-5g/l, t-7d

100 1000

Kds (ml/g)

10000

3-19

Rg. 19 Relation between K^ and KA of

cesium for sample 6

- 306 -


28days, . 45//m-membrane)

1 8 5185-3

S> U95025, (1996)

B

#g2^$c[ml/g]

10000

1000

o a>-lg/t, t-ld

• a)-1g/l, t-7d. a)-5g/1,t-7d

100 1000 10000

Kds (ml/g)

0-20Fig. 20 Relation between Kfc and KA of

cesium for sample 7

10000

o co-ig/l, t - ldA a>-5g/l,t-1d• w-1g/1, t-7d. M-5g/l, t-7d

100 1000 10000

Kds (ml/g)

EI-22Fig. 22 Relation between Kfc and K # of

nickel for sample 6

10000

o <*—1 Q/1, t—1d

• M-1gAt-7d» «-5gA t-7d

100 1000 10000Kds (ml/g)

I-21Fig. 21 Relation between KA and KA of

nickel for sample S

10000

1000

loo

ow-lgA t- ldAu-SgAt-ld• oj-1 gA t-7d« ai-Sg/l, t-7d

100 1000 10000Kds (rrd/g)

l -23

Fig. 23 RelaUon between Kfc and KA of

nickel for sample 7

- 307 -


(Data

(a^:3hours, & 0. 45 urn-membrane)

1 8 6186-1

, U89002. (1989)

B

EXC [meq/lOOg]Ca Mg Na K17 1.5 45 120.13 0.06 0.29 0.090.71 0.12 0.03 0.04

[mm] [mVg]Bentonite <0. 074 65.5Kaolin <0. 074 7.5Toyoura sand 0. 15-0. 30 0. 34

pH CEC(HsO) (KCl)[meq/100g]10. 5 8. 1 76

3. 5 3. 5 11.77. 3 6. 5 0. 90

, Eh,

(Mill ipore)CJ; o T0. 45 m-membrane 7Co,

z

3 r

7; t5 2

Zo

101

10'

BENTO.\ITE:SANDA 2.0-30:0O 3:100D 3:200V 3:300• 3:500

pH 7.3-7.9

WITHOUT SAND

CALCIUM DISTRIBUTION COEFFICIENTOF BENTONITE Kdi.c'W'g>

Fig. 3.2 Effect of the mixing ratio of bentonite to sandon Sr-Ca exchange isotherm of bentonite. Solidstraight line was derived by the method of leastsquares using the results of simple bentonitesystem. The coefficient 1.7 means the selectivitycoefficient of bentonite.

- 308 -

SIKONTIUM UISTKIIIUTION .COEFFICIENTOF SAND Kd»"(«e/R)

STU0NI1UM D1STK1I1UT10N COEFFICIENTOF SAND Kila*'(»t/|j)

*> rt o

3 3 x 2 =-O -I•"2

o — S".

S.S- fa~Q

COIIAI.T DISTKIHUTION COKKKICIKNTOF HKNTONITK Kdi.':"(««/(!) STK0N11UM DISTRIIIUTION COEFFICIENT

OF KAOLIN KtlLs>(.t/|i)

8

i

z o

T o

1

,.

\ ^

\

J3 °

(, o 0 0

-

a \ (^0 o»

„ 0

s *OB

I

'*,

\> \

• LJ

. IT300

a

\

CD

5?... 3CM' x

H

SAN

100200

\

** •» PI3" X —in o — ,

P

° a

in " O

illno»<• r; 2. C ?-

CO

CDm

l Or Hr-M

-e-

co

o

8

3?

C n

•?=

3I

3

331

X

Ml

JO

n

OS

CO

FT


. 5 i l / N o . 5A)

1 8 7187-1Ktt-B

, U87003, (1987)

15-CECEXC-CaEXC-MgEXC-NaEXC-K

0.390.710. 12

[meq/lOOg][meq/lOOg][meq/lOOg]

pH(HiO)pH(KCl)

M9KJ££2 . 62).0.34 [m7g]7. 36. 5

0. 03 [meq/lOOg]0. 04 [meq/lOOg]

Eh,

SI:S2:S3:S4:

too [mi], co

i~ioo1, 2, 5, 10

pH 4 - 1 05~35t:

i , ! /In 1 / I ,C*10a «/ >liar/l.C'Itai/16/l

o sas

10-f/l.Ca h l / l

• Srigia>/l!ca»>t/i

iiO\

• UK 5~«n/l»H7.J~J.I

(I,,/C,,l-I.ll (la/Col111

oO• •M&SCf/'l

SrMMfl.t.lhi/1S.10.KW/1

RotO •Xiall •

ODOI I —O.OOI

B 3 1211 (Sr • Ca

( I / I )

. Sr

(l/f)

R, Sr.

- 310 -


. 5A)

1 8 7187-2

K U87003, (1987)

"

o, Co tmt/lO Co ii«/la co ix/iA Co S*Va Co fet/ta Co SM/IA ColOm/l• CO10M/I

• ColOw/lmmitpH6.l~7

Ci 5M/IC.10^/1Ca2ta(/IC. Sw/IC«10M/ICalOac/tC. S K / IC«10K/ICaiOx/l

S0S

0.01

A

A * °A0

D=°°'A L

A • * * 5,/1Oa• BMltSOi/l

.S, 10»</l

Hcl/Cci (l/l)

H3.13<«l (Co.C«-»*) (1)

0.01

• 3.131b) Co-C.St»*a»(Co-C».

0.1

0-1

3o

0.01

A /U t

mntms.A Co 2m*VI. MB 2mc/<A Co 2mc/ l . Mn Snc / IA Co t n f / 1 , MMOnc/tO Co Smc/ i . MB 2mi / lO Co Sm«/I, Mn S n i / I• Co Smc/I. MnlOmc/la ColOmg/l, Mn2m(/td ColOrat/l. Mn Smi/I• ColOmc/l, MnlOmc/'tX Co-Mo-*H**

5~lD0f/l

PH «.9~7.«

qeo/Cco -

0-001 0X11 01

H3.14 Co-Mn!2»»iaJt (Co- . Co-Mn.

- 311 -


1 8 7187-3

, U87003. C1987>

Eh,Run 9: Sr 5mg/lRunlO: Sr 5mg/lRunll: Sr 5mg/l

+ Ca 5mg/l+ Ca 10mg/l+ Ca 20mg/l=7. 0-7. 9

Run 9RunlORunll

[era]10.10.10.

511

IF464444

[cm/hr]23.25.24.

297

4.1

- 312 -


(Data

, maim-T R U J

1 8 8

Eft-B

•J: , U97017, (1997)

m h:M h

L,

CmAmPuNpUPaAcThRaCsSnTcIZrSeCNiCl

10101010101010100. 030.0030.0030. 00050.0020.0030.0030.50.30.002

1.010100. 10. 10. 11. 00. 10. 920.0010. 10. 00010. 00020. 10.0010.00.50. 001

0.50.0250. 050.0010. 00010.010. 250. 10.0430. 00570. 10.00010. 00050.050. 0010. 00540.001

- 313 -


stm1 8 9

Ktt-B

m

&

A^

H. Meier, E. Zimmerhackl,Signi f i c a n c e of E l e c t r o snuclAbstNucl

/s~U7M• IM7

63Ni63Ni"7Ac"7Ac

ides Released from a

G. Zeitier andtatic SorptionReposi tory

racts of 18th International Symposear Waste Management

14(PH, Eh, &^*>®&,

1/g] ,.. Adsorpt ionZeta-PotentialCmV]

-18.9-11.6-5. 8

-17. 5

P. Mengein the Retardat

ium on the Scien, Kyoto, Oct. 23-27, 137-138 (1

&

Temp DC]--550

*r««ifNr». f^>

Rs[ml/g]233114071190

ion of Radio-

tific Basis for994)

- 314 -


1 9 0

J. Bors, H. N. Erten and S. AssemiStudies of the Liquid-Solid Ratio Effect on the Distribution Ratio Rtin SorptionAbstracts of 18th International Symposium on the Scientific Basis forNuclear Waste Management, Kyoto, Oct. 23-27, 139-140 (1994)

A'JChernozem type soi

. Eh.

... Adsorption

0,5 1 1.5LogV/M

Fig. 2 The variation of Rd withV/M for the sorption of iodineon Chernozem type soil.

- 315 -


-L^Bt/3500rpm/lhour)

1 9 1

J. Matsumoto, T. Banba, S. MuraokaAdsorption of Carbon-14 on MortarAbstracts of 18th International Symposium on the Scientific Basis forNuclear Waste Management, Kyoto, Oct. 23-27, 141-142 (1994)

,M, 0.5-1. Omm)

Eh.

mmm 9mu

... Adsorption

10s

10*

110

10°

i-

t8

IF" v g o

Initial concentration

O

A•M

A:7.4x104MB:2.8x10*M .C :1x10 JMD:1x10*M

^

o

10'

104

101

• * • 1

% ! Hio3i?o °

10'

10'

"oo *•

.8°

! ! • (

O Beloro• Afwr

I 40 80 120 160

Elapsed Tim* [days]

Fig. 1 Sorption ratio of carbon-14 onto mortarat 15°C as a function of elapsed time.

40 80 120Elap»»d Tim* [days]

160

Fig.2 Comparison of carbon-14 Sorption raliobetween before and after cenlrifugation

- 316 -


(gflt

1 9 2

Kf t - B

M. Sazarashi, Y. Ike da, R. Seki, H. Yoshikawa and Y. TakashimaA Study on Adsorption of I" Ions on Natural Minerals for GeologicDisposal of I29I WastesAbstracts of 18th International Symposium on the Scientific Basis forNuclear Waste Management, Kyoto, Oct. 23-27, 143-144 (1994)

-rMineralsSI: AllophaneS2: AttapulgiteS3: Montmori1loni te

S4: ChalcopyriteS5: Spain-cinnabarS6: HgS reagent

Eh,LI:L2:L3:

5 X 1 0 U5X10-

.. AdsorptionpH of fi 1 trates(Soking time: day)

Sl/LlS2/L1S3/L1S4/L1S5/L1

16. 57. 68. 25.47. 1

56. 67. 58.86.47. 2

137. 28. 18. 75.46. 9

206. 77.89.36. 27. 1

Kd(Soking time: day)

1000

51.20000

50.0.01.

726877

2

131.0.0.5.

6034620200

201.1.0.4.

231696478

20000 20000 20000

, 25°C

S5/L2S5/L3S6/L2S6/L3

pH of filtrates9.48. 78.27.7

Kd470.00.00.0

- 317 -


(Data

1 9 3

D. Cui and T. E. EriksenReversibility of Strontium Sorption on Fracture Filling MaterialAbstracts of 18th International Symposium on the Scientific BasisNuclear Waste Management, Kyoto, Oct. 23-27, 149-150 (1994)

for

A UCrushed granitic fracture filling material separated with respect tosize and ferromagnetic properties.

Eh.Synthetic groundwater containing 10 fiM Sr !

... Adsorption, Desorption

Fig. 1. Si-* sorption/desorption data plotted as Rj versus time. The various mineral fractions

are represented by their specific surface area. The initial aqueous phase in sorption process

was synthetic groundwater coniaining ]O«M Sfi\ The solid to liquid ratio l:3(g/ml).

- 318 -


1 9 4

K. Idemitsu, K. Obata, H. Furuya and Y. InagakiSorption Behavior of Uranium(VI) on a Biotite MineralAbstracts of 18th International Symposium on the Scientific Basis forNuclear Waste Management, Kyoto, Oct. 23-27, 153-154 (1994)

8811N-HCUC

[m'/g] H C l M f f l ^ O : 21 .5 , H C l ^ a ^ b : 0 .29

\Z\

H, Eh.U 0 J ( N 0 3 ) s

Polypropylene^^

Adsorption

.510

10

10

V.V* O.2*-5Oml

• O.)g-5Oml

• O.lg-lSOmlO wiihomHCl

treatment

104 5 6 7 8 9pH

Fig.2 Sorption coefficients of biotite as afunction of pH. Open circles represent datafrom sorption experiments using biotite that

was not treated with HC1 solution

- 319 -


(Data

1 9 5

G. M. N. Baston, J. A. Berry, M. Brownsword, T. G. Heath and C. J. TweedThe Sorption of Uranium and Technetium on Bentonite, Tuff andGranodiori teAbstracts of 18th International Symposium on the Scientific Basis forNuclear Waste Management, Kyoto, Oct. 23-27, 155-156 (1994)

Bentonite, Tuff, Granodioritc

Eh, &&-i-t>m

-350—

Adsorption

#/10000NMWCO5 i i

BentoniteTuffGranodiori te

Bentoni teTuffGranodiorite

Kd(U)[mVkg]20- 60050-1000

5- 200

Kd(U)[mVkg]0. 03-0. 250.03-0. 150.001-0. 1

Kd(Tc)[mVkg]0. 6- 10

10 -40020 -200

Kd(Tc)[mVkg]0. 02-0. 2

<0. 0050. 02-0. 07

0.IK-f

- 320 -


( g J * : 1 0 d a y s , i l ' W > I t / 1 2 0 0 0 r p m / l h o u r )

1 9 6

N. K o z a i , T. O h n u k i a n d S. M u r a o k aS o r p t i o n B e h a v i o r of N e p t u n i u m on B e n t o n i t e - E f f e c t o f C a l c i u m I o n ont h e S o r p t i o n -A b s t r a c t s of 1 8 t h I n t e r n a t i o n a l S y m p o s i u m on t h e S c i e n t i f i c B a s i s f o rN u c l e a r W a s t e M a n a g e m e n t , K y o t o , O c t . 2 3 - 2 7 , 1 6 5 - 1 6 6 ( 1 9 9 4 )

B e n t o n i t e , N a - S m c c t i t c , C a - S m e c t i t e a

, Eh,

: 6 X I O 6 M )

, 20°C

A d s o r p t ion

10.

o BentoniteA Na-smocttieA Ca-smectte

O A *A

2 3 4 5 6 7 8

Final pH

Fig.l Distribution coefficient (Kj) of neptuniumfor bentonite and smectite in defferent pHsolutions.

- 321 -


(Data

35CHK

1 9 7197-1

KURRI-TR-361, 49-67 (1991)

. -fSI: 35~0 . 45S2: Glauconitic sandS3: y ' J A

, Eh.

LI:L2:L3:

Glauconit ic (Eh^-200mV)

10 -

10* -

10* -

110 -

1 -

10 -

10 -

-

o \

i I

I t

10DOC.mg/l

IO1

Fig. 4 Variation of the distribution ofTh(IV), U(YI), and Pu(tV) between watertnd particulitcs (35-0.45 m) u » functlooof the concentration of organic! In freshwater )«kei (expreited u the distributioncoefficient Kt, venui dissolved orftniccarbon, DOC) (Wahl(rea and OrlandinJ,19S2J; Th, open circles; U, solid circles; Pu,jqutrei.

- 322 -


(Data

1 9 7197-2

KURRI-TR-36K 49-67 (1991)3-4H

.2 103-

0.

• Fulvic acidOHA-Aldnch

- •— o-

0 10 20 30 40 50 60Concentration ol humic compound (ppm)

Figure 6: Adiorpclon of An (III)onco silica as a funcclon of pH andIonic scrcngch

2

1

rs

-3

-4

O(HAJ«

*(HA)>

o[HA|>10 mg/l

t a 0.01 M -3

-4

• |HA.)» 1 mg/l

»IHA|« S mg/l

•|HA|«10mg/l

i 0.1 M

6pH

10

Figure 8: Adsorption of An (III) onco silica 49 * funcclon of pH.Ionic strength (I) and humic concentration

3». I - 0.01 M 3b. I - 0.1 M

- 323 -


1 9 8 KURRI-TR-331, 32 -50 (1990), 1990^1^23-240

Eh.

10'

10,-2

10,-J

Ovortl f»«4«r

0••

60-100too-iso80-100

Me rim** (H)0005aoosa i <k

o

o•

surface/ charge ~

10'

oin

to1

5 6 7 8 9 10 II

pH

Id2

1912 HpOa*

- 324 -


1 9 9 KURRI-TR-362, 50-59 (1990)1990^11^26-270

. Eh,

MineralBorni teBournoni teChalcopyri teChrysocollaEnargiteGalenaPyriteTennant i teTetrahedri te

Tetrahedri te(argenti ferous)

KdtfcOr^3

200-2000<110- 20

1- 10^3^32- 16

300-2000<317

~ 325 -


Wfetik :50strokes/minX24hours)

2 0 0200-1

&mmmKURRI-TR-362. 60-65 (1990)

h 1990^11H26-27B

A'J

WOM

]0.59 - 2. 000.351- 0. 70

- 0.043

0. 51 - 2. 000. 043- 0. 074

, Eh.

. lg. 25°C<


10

10

Fit. S Relation to pH shown by distri-

bution coefficient of Tc between coco-

nut shell-based active c»rhon and solu-

tion*

SO ftl TcO^ solution, 0.1 f active car-

bon; D: acid free, A: 1 M {H,Na)Cl,

O: 0.001 H (H,Na)C104. •: 0.01 M (H,N»)

cio4.

Fig. 6 Relation to pH shown by distribution

coefficient of Tc between active carbon and

1 M (H.Na)Cl solution

SO ml TcO^ solution, 0.1 I active carbon;

o: coconut sh«ll-b«s«4 active carbon,

A: saw dust-based active carbon, A: pitch-

baaed active carbon, •: coal-based active

carbon, O: bone-based active carbon.

- 326 -


:50strokes/minX24hours)

2 0 0200-2

KURRI-TR-362, 60-65 (1990)1990^-11^26-270

... Adsorption

Pig. 7 Relation to pK shown by distributioncoefficient K of Tc between active carbonand 1 M (H.Na)NOj solution50 Ml TcO4" solution, 0.1 % i c t ive c»rbon;D: coconut shell-based active carbon,A: pitch-based active carbon, •: coal-basedactive carbon, O: bone-based active carbon.

8 20 2412 16Tlme/h

Fif. 9 Variation In t lae shown by distributioncoeff icient of Tc between coconut shell-basedactive carbon and solution10 ml TcO4 so lut ion, 0.1 f active carbon;o: 0.1 M H2SO4, O: 0.1 M HjSO^-OS K N»:SO4,A: 0.1 M HjSO4-l M N»2SO4, A: 0.01 M NaSCN.•: 1 M NaOH.

24

Fig. « Variation in tlae shown by distribu-tion coefficient of Tc between coconut shell-based active carbon and solutions of differ-ent sulfuric acid concentrations10 • ! TcO solution, 0.1 f active carbon;

• : 1 MI.1H H2SO4,S M H2SO4.

T: 0.5 M H2S04,

104-

12 16 20 24Tlme/h

Fig. 10 Variation in tiae by distribu-tion coefficient of Tc between coconutshell-based active carbon and solutionsof different hydrochloric acid concentra-tions10 al TcO" solution, 0.1 g active carbon;O: 0.1 M HC1,

o : i H HC1, 7• : 0.5 M HC1,

; 10 M HC1.: 1 H HC1,

- 327 -


:50strokes/minX24hours)

2 0 0200-3K5J--B

KURRI-TR-362, 60-65 (1990)1990^11^26-278

... Adsorption

103

X

10"

1 0 (

- f^>_O«ffftJ*

) 4 8 12 16Tim«/h

20 2 4

Fig. 11 Variation in tlat shown by dis-tribution coefficient of Tc between co-conut shell-based active carbon andsolutions of different nitric acidconcentrationslo »1 TcO^ solution, 0.1 f active carbon;

101

0 4 8 12 16 20 24Tlm«/h

Fig. IS Variation in tlae shown by di«-tributlon coefficient of Tc between coco-nut shell-based active carbon and solu-tions of different phosphoric acid concen-trations10 «1 TcO4 solution, 0.1 g active carbon;

0.1 H HjPO4,j 0 - S H

H 3 P O 4 , V". 1 - 5 H H j P O 4 . * :

O : 4 M H j T O 4 -

D: 1 K

2 M

1O1 8 12 16Tlme/h

O: 0.05HNOj, t

10*

1O1

•0X.

M HNG

>: 1 M

>

j , • : 0 . 1 M HNOj,

HNOJ.

1 ' ' '

< ^

0 : O . S M

O '—C«-

_ — - *

Fig. 12 Variation in tiae shown by dis-bution coefficient of Tc between coconutshell-based active carbon and solutionsof different perchloric acid concentra-tions10 al TcO* solution, 0.1 I active carbon;O: 0.01 M HC104, A: 0.1 M'HC1O4.M HC1O4, T: 1 M HC1O4-

0.S

10*

10*

10" 1Oa 1O31 1O1

Tlm«/h

Fig. 14 Variation in tia* shown by distr i -bution coefficient of Tc adsorbed by coconutshell-based active carbon with and withoutpratreataant with sulfuric acid10 al TcO4 solution, 0.1 g active carbon;open: no pretreataent, closed: pretreataentwith 10 M HjS04;O«: 0 .5 M HjS04 .

a.*.: 0 .1 M H2SO4 ,

- 328 -


3 II/K

-$ (200m

m-2<D*$i<Dtt^rzmm) I

Co, Sr,

TttU, Np, Pu.

Ac, Th, Pa, n

0 ^©ffi, ft< x - 3 7 ^ M 5 tlT £fc. T R

I, C. Nk T R U t

HBeC

* Na* Mg

AlCl

* ArKCa

* CrMnFeCoNi

* Cu* Zn

Se* Br* Kr

RbSr

* YZrNbMoTc

* Ru* Rh

PdAgL QSn* cv.

* DOI

11

43047372

22136

147238420

1060229

289

1281211

12356926

27971

1341

199

21 Qlo

501

11

114316148494

6810195211

842244

18511322Qo

26

CsBa

* CeLaNdPmSmEuHoHfReOs

* Ir* Pt* Tl

PbBi

* Po* At* Rn* Fr

RaAcThPaUNpPuAmCmBkCf

m &

13426

14--11

871---441

881111124

1721

226402221239

101-

7940

9534

-1141---1114111112374

1524172541

183

1) La, Nd, Hf. Re2) T*j

Os, Cf © 6

- 329 -


- 3

: - 3

Batch

Column*

Field

6798

379

517

246

7940

(51

(85.

( 4.

( 6.

( 3.

,)

6)

8)

5)

1)

155

35

9

6

205

* : D i fuf f u s i o n 0 ,

4.

330 -


ft,

, urn

(2000)

(1989)

: R

^ « * 4 ) (1997)

, JAERI-Tech 2000-012

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2)

3)

4)

5)

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7)

8)

U — X 2 C 1 9 9 0 )

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environment", Technical Reports Series No. 247, IAEA, Vienna (1985)

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28, 344-351 (1986)

- 331 -


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- ffi A U (1989)

U87063, (1988)

\ JAERI-

M 91-118, (1991)

Wt\ JAERI-M 93-113, (1993)

(1996)

-M 88-038, (1988)

JAERI-Research 96-004,

.\ JAERI

# \ KURRI-TR—15K (1977)

10, 79-86 (1975)

, 10, 203-210 (1975)

1&, 33 [4] (1991)

S, 30[10] (1988)

(1976)

l£, 18[8]

, 27,

123-134 (1992)

ffi, h

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99)

(PhascH) , (1996)

- , (1990

- , (1994)

, 1 [1] . 33-42 (1994)

53-65 (1994)

105) t f l l i f t - ftb, : "

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RWM-86006 (1986)

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\ 29 -35 ,

^ A * i J 7 , 116-127,

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, 551 (1997)

127)S. Mohamad i:Eu(IH) C K f l :554 (1997)

\ B

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, 555 (1997)

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145)MM&z to :JAERI-Research 97-089

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- to : "m^m±mum<D&i&%mmz&tt%>ntt&&m(D&?T&®\ JAERI-M

92-205

-\ JAERI-M 89-144

m±mi- \ JAERI-M

\ JAERI-M 89-01

- to : "i&%tftMm%>(DmMuig-®ift\zm-t2>m9i ( i ) - ® M

to :) \ JAERI-M 7642

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^ ^ : " M | £ ? f { 3 ; f c t f & 7 $ > t ) M i : : i n ^ K © ^ i T . KURRI-TR-36K 49-67

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ilil 5J

FP

rG

M

k

h

da

d

cin

/<

n

P

ra

(HO

l;l|f/ir J: 5 ; tztzL,\ cV1 u

flftl; A o / i

. ti'\ izii

3 . bar li, J I S -CliMtMiWI I: /J * li

ft I; Hi() M 2 « A f rf ' J - ! c

5 .

4 . FCISJflM'ff&ffi'frT'ii bar, barnfcj;

N ( - l O ' d y n )

9.80665

4.44822

kgf

0.101972

I

0.453592

lbf

0.224809

2.20462

1

lPa-s(N-s/iir) = 10P(.t;rX)(s/(cm-s))

lm- / s= l ( ) 'S l (X !- - V X)(cm-/s)

Jh

h

MPa( = 10bar)

I

0.0980665

0.101325

1.33322XR) '

6.89476x10 ''

kgl'/cm-

10.1972

1

1.03323

1.35951x10 :l

7.03070x10 -

a i m

9.86923

0.967841

1

1.31579x10 ;!

6.80460x10 -

m m H g ( T o r r )

7.50062 xlO:!

735.559

7C0

1

51.7149

lbf' / in-(psi)

145.038

14.2233

14.6959

1.93368x10 -

1

X.

iV

+'1

fl:'H

?&W

J(=107 erg)

1

9.80665

3.6x10"

4.18605

1055.06

1.35582

1.60218x10 '"

kgl'-m

0.101972

1

3.07098x10''

0.426858

107.586

0.138255

1.63377x10 -"

kW-h

2.77778x10 •

2.72407x10 <•

1

1.16279x10 "

2.93072x10 '

3.76616x10 7

4.45050x10 -"

cal(,i"|!iUl;)

0.238889

2.34270

8.59999x10"'

1

252.042

0.323890

3.82743x10 J"

Btu

9.47813x10 '

9.29487x10 :!

3412.13

3.96759x10 :i

1

1.28506x10 '•

1.51857x10 --

ft-lbf

0.737562

7.23301

2.65522x10"

3.08747

778.172

1

1.18171x10 '"

cV

6.24150x10'"

6.12082x10'"

2.24694x10--"'

2.61272x10'"

6.58515x10"

8.46233 xlOls

1

1 cal- 4.18605.1

- 4.184.1 {>>h{t't)

= 4.1855J (15C)

= 4.1868.1

= 75 kgf-in/s

= 73 5.499 W

IkW

m

Bq

1

3.7x10"'

Ci

2.70270x10 "

1

a Gy

1

0.01

rad

100

1

jiff

ii-ilit

c

2.58

/kg

1

xlO '

R

3876

1

''1w

Sv

1

0.01

rem

100

1

JAERI-Data/Code 2001-005 - OSTI.GOV

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Transcript of JAERI-Data/Code 2001-005 - OSTI.GOV