Annexure - Environmental Clearance

Annexure

M/s Crystal Surfactants & Chemicals Annexure

EIA/CSC/Final/2018/02

EIA Consultant: sd engineering services pvt. ltd. {Aurangabad, MH} A.1

Annexure 1{I}: ToR Compliance chart

Approved Terms of Reference (ToR) issued by Ministry of Environment, Forest & Climate

Change (MoEF&CC) vide letter Ref. IA-J-11011/66/2018-IA-II(I) Dated: 24th

May, 2018.

Sr.

No.

Approved TORs Compliances

(All Chapters, Sections, Figures & Tables,

referred here are from EIA Report)

Standard Terms of Reference (ToR)

1. Executive Summary Executive summary is presented in Chapter- 11,

Page No. 217

2. Introduction

i. Details of the EIA Consultant including NABET

accreditation

Details of EIA consultant is presented in Chapter-

12, Section-12.1, Page No.229

ii. Information about the project proponent.

Information about the project proponent is

presented in Chapter-1, Section- 1.2, Page No.1.

iii. Importance and benefits of the project. Importance of proposed project is given in

Chapter-1 Section-1.4, Page No.4 and benefits are

presented in Chapter-8, Section-8.1, Page No.191.

3. Project Description

i. Cost of project and time of completion. The total estimated Cost of the project is Rs. 718.9

Lakhs. Time of completion of the project activities

and expected commercial production will be

commenced during 2019-20

ii. Products with capacities for the proposed project. Proposed products with their capacities is

presented in Chapter-2, Section-2.1, Table No.

2.1, Page No.13.

iii. If expansion project, details of existing products

with capacities and whether adequate land is

available for expansion, reference of earlier EC if

any.

New Project

Land break up is presented in Chapter- 2,

Section 2.2.2, Table No.2.3, Page No.19.

iv. List of raw materials required and their source

along with mode of transportation.

List of raw materials and their source along with

mode of transportation is presented in Chapter-2,

Section-2.3, Table No.2.4, Page No. 19.

The raw materials required for the process are

bought from the local market. Mode of

transportation of raw materials to the project site

by road.

v. Other chemicals and materials required with

quantities and storage capacities

List of raw materials and their source along with

mode of transportation is presented in Chapter-2,

Section-2.3, Table No.2.4, Page No. 19.

vi. Details of Emission, effluents, hazardous waste

generation and their management.

Details on air emissions, effluents and hazardous

waste generation and their management are

presented in Chapter-2, Section-2.9, 2.10 & 2.11

Page No.44, 47 & 48.

vii. Requirement of water, power, with source of

supply, status of approval, water balance

diagram, man-power requirement (regular and

contract)

Total fresh water requirement is 38.50 CMD, the

source of water from MIDC Paithan.

Power requirement with source of supply is

presented in Chapter-2, Section-2.7, Page No. 43




Water requirement and water budget is presented

in Chapter-2, Section-2.8, Table No. 2.7 Page

No.43.

Manpower requirement will be 400 nos. of skilled

& unskilled workers Chapter-2 Section-2.7, Page

No.43.

viii. Process description along with major

equipment’s and machineries, process flow sheet

(quantative) from raw material to products to be

provided.

Product wise process description, chemical

reaction, flow diagram, material balance is

presented in Chapter-2, Section-2.4, Page No.20

Major equipment’s and machineries are presented

in Chapter- 2, Table No.2.5, Page No.42

ix. Hazard identification and details of proposed

safety systems.

Hazard identification and safety systems details

are presented in Chapter- 7, Section 7.2, Page

No.176

x. Expansion/modernization proposals:

c. Copy of all the Environmental Clearance(s)

including Amendments thereto obtained for the

project from MOEF/SEIAA shall be attached as

an Annexure. A certified copy of the latest

Monitoring Report of the Regional Office of the

Ministry of Environment and Forests as per

circular dated 30th May, 2012 on the status of

compliance of conditions stipulated in all the

existing environmental clearances including

Amendments shall be provided. In addition,

status of compliance of Consent to Operate for

the ongoing existing operation of the project

from SPCB shall be attached with the EIA-EMP

report.

Not Applicable

d. In case the existing project has not obtained

environmental clearance, reasons for not taking

EC under the provisions of the EIA Notification

1994 and/or EIA Notification 2006 shall be

provided. Copies of Consent to Establish/No

Objection Certificate and Consent to Operate (in

case of units operating prior to EIA Notification

2006, CTE and CTO of FY 2005-2006) obtained

from the SPCB shall be submitted. Further,

compliance report to the conditions of consents

from the SPCB shall be submitted.

Not Applicable

4 Site Details

i. Location of the project site covering village,

Taluka /Tehsil, District and State, Justification

for selecting the site, whether other sites were

considered.

Proposed project is located at Plot No. B-31/2,

MIDC, Paithan, Tal. Paithan, Dist. Aurangabad

Chapter-5, Section-5.1, 5.2, Page No.162 Other sites were not considered.

ii. A toposheet of the study area of radius of 10 km

and site location on 1:50,000/1:25,000 scale on

an A3/A2 sheet. (including all eco-sensitive areas

and environmentally sensitive places)

Toposheet of 10 km radius Study Area in 1:50,000

scale on A3 sheet is shown in Chapter-3, Fig. 3.1,

Page No. 53.

iii. Details w.r.t. option analysis for selection of site Not Applicable for this project




F Co-ordinates (lat-long) of all four corners of the

site.

Co-ordinates of all four corners of the project site

is presented in Chapter-2, Section-2.2, Table

No.2.2, Page No.14.

v. Google map-Earth downloaded of the project

site.

Google map is shown in Chapter-2, Fig. 2.2 Page

No.16

vi. Layout maps indicating existing unit as well as

proposed unit indicating storage area, plant area,

greenbelt area, utilities etc. If located within an

Industrial area/Estate/Complex, layout of

Industrial Area indicating location of unit within

the Industrial area/Estate.

Layout maps indicating proposed unit indicating

storage area, plant area, greenbelt area, utilities

etc. is presented in Chapter- 2,Fig.2.3, Page

No.17. Layout of Industrial Area indicating location of

unit within the Industrial area/Estate is presented

in Chapter-2, Fig. 2.4, Page No.18

vii. Photographs of the proposed and existing (if

applicable) plant site. If existing, show

photographs of plantation/greenbelt, in

particular.

The proposed site photograph is presented in

Chapter-1, Photograph-1.1, Page No. 4.

viii. Land use break-up of total land of the project site

(identified and acquired), government/ private -

agricultural, forest, wasteland, water bodies,

settlements, etc shall be included. (not required

for industrial area)

The land use break-up of the total land of the

project site is presented in Chapter-3, Section-

3.3.10, Table No. 3.15, Page No.79

ix. A list of major industries with name and type

within study area (10 km radius) shall be

incorporated. Land use details of the study area

List of major industries within 10 km radius study

area is enclosed as Annexure 2 [I].

Land use details of the study area are presented in

Chapter-3, Section- 3.3.10. Page No.79

x. Geological features and Geo-hydrological status

of the study area shall be included.

Geological features and Geo-hydrological status of

the study area is presented in Chapter-3, Section-

3.3.7., Page No.72.

xi. Details of Drainage of the project up to 5km

radius of study area. If the site is within 1 km

radius of any major river, peak and lean season

river discharge as well as flood occurrence

frequency based on peak rainfall data of the past

30 years. Details of Flood Level of the project

site and maximum Flood Level of the river shall

also be provided. (mega green field projects)

Drainage map of the project site is shown

Chapter- 3, Fig.3.12, Page No.84

There is no major river within 1 km radius of the

project site.

xii. Status of acquisition of land. If acquisition is not

complete, stage of the acquisition process and

expected time of complete possession of the

land.

Land is in factory’s possession. No additional land

is acquired for the project

xiii. R&R details in respect of land in line with state

Government policy.

Proposed project is in MIDC premises, hence there

is no R& R involved.

5. Forest and wildlife related issues (if applicable) – Not Applicable

i. Permission and approval for the use of forest

land (forestry clearance), if any, and

recommendations of the State Forest

Department. (if applicable)

Not Applicable




ii. Landuse map based on High resolution satellite

imagery (GPS) of the proposed site delineating

the forestland (in case of projects involving

forest land more than 40 ha)

Not Applicable

iii. Status of Application submitted for obtaining the

stage I forestry clearance along with latest status

shall be submitted.

Not Applicable

iv. The projects to be located within 10 km of the

National Parks, Sanctuaries, Biosphere Reserves,

Migratory Corridors of Wild Animals, the project

proponent shall submit the map duly

authenticated by Chief Wildlife Warden showing

these features vis-à-vis the project location and

the recommendations or comments of the Chief

Wildlife Warden-thereon.

Not Applicable

v. Wildlife Conservation Plan duly authenticated by

the Chief Wildlife Warden of the State

Government for conservation of Schedule I

fauna, if any exists in the study area.

Not Applicable

vi. Copy of application submitted for clearance

under the Wildlife (Protection) Act, 1972, to the

Standing Committee of the National Board for

Wildlife.

Not Applicable

6. Environmental Status

i. Determination of atmospheric inversion level at

the project site and site-specific

micrometeorological data using temperature,

relative humidity, hourly wind speed and

direction and rainfall.

Site-specific micrometeorological data using

temperature, relative humidity, hourly wind speed

and direction and rainfall is presented in Chapter-

3, Section-3.3.2., Table No.3.1, Page No.55.

ii. AAQ data (except monsoon) at 8 locations for

PM10, PM2.5, SO2, NOX, CO and other parameters

relevant to the project shall be collected. The

monitoring stations shall be based CPCB

guidelines and take into account the pre-

dominant wind direction, population zone and

sensitive receptors including reserved forests.

AAQ data for post monsoon at 9 locations for

PM10, PM2.5, SO2, NO2, CO has been collected.

The monitoring stations are located taking in to

account the pre-dominant wind direction,

population zone and sensitive receptors including

reserved forests is presented in Chapter-3,

Section- 3.3.3., Page No.58.

iii. Raw data of all AAQ measurement for 12 weeks

of all stations as per frequency given in the

NAQQM Notification of Nov. 2009 along with -

min., max., average and 98% values for each of

the AAQ parameters from data of all AAQ

stations should be provided as an annexure to the

EIA Report.

The baseline AAQ field data in study area results

of all locations for the study period are presented

in Annexure- 3{II}

Baseline status of study area and min., max., mean

and 98th percentile values are presented in

Annexure- 3{II}.




iv. Surface water quality of nearby River (100 m

upstream and downstream of discharge point)

and other surface drains at eight locations as per

CPCB/MoEF&CC guidelines.

River Godavari is @ 7.6 Km towards South

direction.

Jaikwadi Dam is @ 2 Km towards South West

Direction.

There is no discharge of effluent to water body.

Baseline study of the 8 Surface water location is

presented in the Chapter- 3, Section- 3.3.6, Page

No. 70

v. Whether the site falls near to polluted stretch of

river identified by the CPCB/MoEF&CC, if yes

give details.

Not Applicable.

vi. Ground water monitoring at minimum at 8

locations shall be included.

Ground water monitoring at 9 locations are

presented in the Chapter- 3, Section- 3.3.6, Page

No.68

vii. Noise levels monitoring at 8 locations within the

study area.

Noise levels at 9 monitoring locations are

presented in the Chapter-3, Section-3.3.4, Page

No.60

viii. Soil Characteristic as per CPCB guidelines. Soil samples at 9 locations are presented in the

Chapter- 3, Section-3.3.9, Page No.75.

ix. Traffic study of the area, type of vehicles,

frequency of vehicles for transportation of

materials, additional traffic due to proposed

project, parking arrangement etc.

The vehicular traffic of existing plant and

proposed expansion and prediction of impacts

presented in Chapter 4, Section- 4.12, Page No.

158

x. Detailed description of flora and fauna (terrestrial

and aquatic) existing in the study area shall be

given with special reference to rare, endemic and

endangered species. If Schedule-I fauna are

found within the study area, a Wildlife

Conservation Plan shall be prepared and

furnished.

The flora and fauna (terrestrial and aquatic)

existing in the study area is described in Chapter-

3, Section- 3.3.11, Page No. 87. As such there are no any rare or endangered or

endemic species within the study area. None of the

species either spotted or reported is included in

Schedule-I of the Wildlife Protection Act.

xi. Socio-economic status of the study area.

Socio-economic status of the study area is

presented in Chapter-3, Section-3.3.12, Page

No.112

7. Impact and Environment Management Plan

i. Assessment of ground level concentration of

pollutants from the stack emission based on site-

specific meteorological features. In case the

project is located on a hilly terrain, the AQIP

Modeling shall be done using inputs of the

specific terrain characteristics for determining

the potential impacts of the project on the AAQ.

Cumulative impact of all sources of emissions

(including transportation) on the AAQ of the area

shall be assessed. Details of the model used and

the input data used for modeling shall also be

provided. The air quality contours shall be

plotted on a location map showing the location of

project site, habitation nearby, sensitive

receptors, if any

Impact on Air quality due to fugitive emissions,

process emission boiler, Thermo-pack & DG sets

emissions; Air quality modeling results, air quality

impacts is described and presented in Chapter-4,

Section-4.3.2. Page No. 133

ii. Water Quality modeling - in case of discharge in Not Applicable




water body

iii. Impact of the transport of the raw materials and

end products on the surrounding environment

shall be assessed and provided. In this regard,

options for transport of raw materials and

finished products and wastes (large quantities) by

rail or rail-cum road transport or conveyor-cum-

rail transport shall be examined.

Crystal Surfactants and Chemicals Ltd. is located

in MIDC Paithan, Tal. Paithan, Dist. Aurangabad,

for transportation of raw materials, finished

product & waste transportation only road is used.

The traffic is generated will be of 7 to 10 trucks

per day. There will be marginal increase in the

traffic. Chapter-4, Section-4.12.2, Page No. 159

iv. A note on treatment of wastewater from different

plant operations, extent recycled and reused for

different purposes shall be included. Complete

scheme of effluent treatment. Characteristics of

untreated and treated effluent to meet the

prescribed standards of discharge under E(P)

Rules

Brief note on wastewater treatment & complete

effluent treatment scheme is presented in Chapter-

2, Section-2.9, Page No.44.

v. Details of stack emission and action plan for

control of emissions to meet standards.

The stack emission details are presented in

Chapter-2, Section-2.11, Page No.48

Mitigation measures are presented in Chapter-4,

Section-4.3.3.6, Page No.137.

vi. Measures for fugitive emission control

Fugitive emissions are presented in Chapter-2,

Section-2.11, Page No.48 mitigation measures are presented in Chapter-4,

Section-4.3.3.3, Page No.136.

vii. Details of hazardous waste generation and their

storage, utilization and management. Copies of

MOU regarding utilization of solid and

hazardous waste in cement plant shall also be

included. EMP shall include the concept of

waste-minimization, recycle/reuse/recover

techniques, Energy conservation, and natural

resource conservation.

Hazardous/solid waste generated from different

sources, their storage, utilization and management

is presented in Chapter-2, Section-2.10, Page No

.47 Proposed waste-minimization measures, reduce,

recovery and reuse concepts are described briefly

in Chapter-9, Section-9.10 & 9.11, Page No. 204

&205

viii. Proper utilization of fly ash shall be ensured as

per Fly Ash Notification, 2009. A detailed plan

of action shall be provided.

Fly ash generation & utilization is described in

Chapter-2, Section-2.11.1, Page No.50.

ix. Action plan for the green belt development plan

in 33 % area i.e. land with not less than 1,500

trees per ha. Giving details of species, width of

plantation, planning schedule etc. shall be

included. The green belt shall be around the

project boundary and a scheme for greening of

the roads used for the project shall also be

incorporated

Green belt will be developed areas is depicted in

plant layout in Fig. 2.3 (Page No. 17).

The green belt development has been described in

Chapter-9, Section-9.13, Page No. 206.

x. Action plan for rainwater harvesting measures at

plant site shall be submitted to harvest rainwater

from the roof tops and storm water drains to

recharge the ground water and also to use for the

various activities at the project site to conserve

fresh water and reduce the water requirement

from other sources.

Action plan for rainwater harvesting through

collect and storage of roof tops and storm water

drain to recharge the groundwater. Chapter-9,

Section-9.12, Page No. 205.




xi. Total capital cost and recurring cost/annum for

environmental pollution control measures shall

be included.

Total capital cost is Rs. 28 Cr. and recurring cost

(operation and maintenance) allocated towards

environmental pollution control measures is

Rs.1.98 Cr. The item wise break-up of estimated

cost for capital and recurring cost is presented in

Chapter-9, Table No. 9.7 Page No.204.

xii. Action plan for post-project environmental

monitoring shall be submitted.

Action plan for Post-project environmental

monitoring is described in Chapter-6, Section

6.52, Table No. 6.1; Page No.166

xiii. Onsite and Offsite Disaster (natural and Man-

made) Preparedness and Emergency

Management Plan including Risk Assessment

and damage control. Disaster management plan

should be linked with District Disaster

Management Plan.

Disaster management plan for On-site and Offsite

emergency preparedness plan is presented in

Annexure -7[V]

8. Occupational Health

i. Plan and fund allocation to ensure the

occupational health & safety of all contract and

casual workers

Fund allocation for the occupational health &

safety is presented in Chapter- 9, Section- 9.9,

Table No.9.7, Page No.204.

ii. Details of exposure specific health status

evaluation of worker. If the workers' health is

being evaluated by pre designed format, chest x

rays, Audiometry, Spirometry, Vision testing

(Far & Near vision, color vision and any other

ocular defect) ECG, during pre-placement and

periodical examinations give the details of the

same. Details regarding last month analyzed data

of above mentioned parameters as per age, sex,

duration of exposure and department wise

The annual medical check-up of the employees of

all the departments are as per the prescribed

format including various diagnostic services will

be carried out and record will be maintained after

commissioning of plant.

iii. Details of existing Occupational & Safety

Hazards. What are the exposure levels of hazards

and whether they are within Permissible

Exposure level (PEL). If these are not within

PEL, what measures the company has adopted to

keep them within PEL so that health of the

workers can be preserved.

As per consequence of MCA analysis, heat

radiation and toxic exposure level is presented in

{Annexure-7 (IV)}

iv. Annual report of health status of workers with

special reference to Occupational Health and

Safety.

The annual medical check-up of the employees of

all the departments are as per the prescribed

format including various diagnostic services has

been carried out and maintaining the record.

Chapter- 9, Section 9.14.1, Page No.210.

9. Corporate Environment Policy

i. Does the company have a well laid down

Environment Policy approved by its Board of

Directors? If so, it may be detailed in the EIA

report.

Environmental Policy is presented in Chapter- 9,

Section 9.7, Page No.202.

ii. Does the Environment Policy prescribe for

standard operating process / procedures to bring

into focus any infringement / deviation /

violation of the environmental or forest norms /

Environmental Policy is presented in Chapter- 9,

Section 9.7, Page No.202.




conditions? If so, it may be detailed in the EIA.

iii. What is the hierarchical system or

Administrative order of the company to deal with

the environmental issues and for ensuring

compliance with the environmental clearance

conditions? Details of this system may be given.

Environment Management cell is presented

Chapter- 9, Section- 9.8, Page No.202.

iv. Does the company have system of reporting of

non compliances / violations of environmental

norms to the Board of Directors of the company

and / or shareholders or stakeholders at large?

This reporting mechanism shall be detailed in the

EIA report.

Yes. The System of reporting of non-compliances

/ violations of environmental norms to the Board

of Directors of the company is presented Chapter-

9, Section 9.7, Table No. 9.6 Page No.207

10. Details regarding infrastructure facilities such as

sanitation, fuel, restroom etc. to be provided to

the labour force during construction as well as to

the casual workers including truck drivers during

operation phase.

Details infrastructure facilities for labor force is

presented. Chapter-9, Section-9.14.1, Page

No.210.

11. Enterprise Social Commitment (ESC)

i. Adequate funds (at least 2.5 % of the project

cost) shall be earmarked towards the Enterprise

Social Commitment based on Public Hearing

issues and item-wise details along with time

bound action plan shall be included. Socio-

economic development activities need to be

elaborated upon.

Amounts of Rs. 14.37 Lakh (2 % of project cost)

are earmarked towards CSR/CER activities.

The proposed socio-economic developments

activities are presented in Chapter-9, Section-

9.16.1, Page No.211.

12. Any litigation pending against the project and/or

any direction/order passed by any Court of Law

against the project, if so, details thereof shall also

be included. Has the unit received any notice

under the Section 5 of Environment (Protection)

Act, 1986 or relevant Sections of Air and Water

Acts? If so, details thereof and compliance/ATR

to the notice(s) and present status of the case.

There is no litigation pending/ order passed by any

Court of Law against the project.

13. A tabular chart with index for point wise

compliance of above TOR.

Indexing is presented for point wise compliance

B. Specific Terms of Reference (ToR)

1. Details on solvents to be used measures for

solvent recovery and for emissions control.

Solvent recovery measures and for emissions

control is described in Chapter-2, Section-2.4.1,

Page No. 41.

2. Details of process emissions from the proposed

unit and its arrangement to control.

Process emissions with their quantities and control

measures are presented in Chapter-2, Section-

2.11, Page No.48.

3. Ambient air quality data should include VOC,

other process-specific pollutants* like NH3*,

chlorine*, HCl*, HBr*, H2S*, HF*,etc.,(*-as

applicable)

Ambient air quality monitoring report is enclosed

as Annexure-3{II} Page No. 245.

4. Work zone monitoring arrangements for

hazardous chemicals.

Work zone places have been monitored regularly.

Chapter-9, Section-9.14.1, Page No.210.

5. Detailed effluent treatment scheme including Mother Liquor Recovery Plant is presented




segregation of effluent streams for units adopting

'Zero' liquid discharge Chapter-2, Section- 2.9, Page No.44

6. Action plan for odor control to be submitted. Action plan for odor control is presented in

Chapter- 2, Section-2.13, Page No.50

7. A copy of the Memorandum of Understanding

signed with cement manufacturers indicating

clearly that they co-process organic

solid/hazardous waste generated.

Not Applicable.

8. Authorization/Membership for the disposal of

liquid effluent in CETP and solid/hazardous

waste in TSDF, if any.

Industry is already having ETP. Chapter-2,

Section- 2.9, Page No.46

9. Action plan for utilization of MEE/dryers salts. MEE salts will be disposed off through

CHWTSDF.

10. Material Safety Data Sheet for all the Chemicals

are being used/to be used.

MSDS for all the chemicals are provided as

(Annexure 7 {IV})

11. Authorization/Membership for the disposal of

solid/hazardous waste in TSDF.

Agreement with Membership of TSDF will be

entered after commissioning of proposed project.

12. Details of incinerator if to be installed There is no proposal of installing incinerator for

the proposed expansion.

13. Risk assessment for storage and handling of

hazardous chemicals/solvents. Action plan for

handling & safety system to be incorporated.

Risk assessment for storage and handling of

hazardous chemicals/solvents is presented in

Chapter-7, Section-7.5, Page No. 180.

14. Arrangements for ensuring health and safety of

workers engaged in handling of toxic materials.

Health and safety of workers engaged in handling

of toxic materials is described in Chapter-9,

Section-9.14, Page No.210.




Annexure I : List of Surrounding Industries

Sr. No. Name of Industry

1. Ajanta Pharma (Pharmaceutical)

Paithan MIDC, Mudhalwadi, Maharashtra

2. Fainger Leser (Metal Fabric)

D3, MIDC, Aurangabad, Maharashtra

3. Encore Healthcare Pvt. Ltd (Pharmaceutical)


4. Apex Medichem (Pharmaceutical)


5. PepsiCo Ltd


6. Hindustan Composite Ltd


7. Tooba Pharmaceutical Pvt. Ltd. (Pharmaceutical)


8. Navonor Pharma


9. Sant Eknath Sahkari Sakhar Kharkhana

Eknathnagar, Paithan

10. Shalini Chemicals

Wahegaon, Maharashtra

11. Fouress Engineering


12. Aventis India Ltd. (Pharmaceutical)


13. Aurangabad Paper Mills




EIA Consultant: sd engineering services pvt ltd {Aurangabad, MH} A.11

Annexure 3 {I}

The National Ambient Air Quality Standards prescribed by CPCB are presented below:

CENTRAL POLLUTION CONTROL BOARD

NATIONAL AMBIENT AIR QUALITY STANDARDS

New Delhi the 18th November 2009

In exercise of the powers conferred by Sub-section (2) (h) of section 16 of the Air (Prevention and

Control of Pollution) Act, 1981 (Act No. 14 of 1981), and in supersession of the notification

No(s).S.O.384(E), dated 11th April 1994 and S.O.935(E), dated 14

th October 1998, the Central Pollution

Control Board hereby notify the National Ambient Air Quality Standards with immediate effect.

Pollutant

Time

Weighted

Average

Concentration in Ambient

Air

Methods of Measurement

Industrial,

Residential,

Rural and

other Areas

Ecologically

Sensitive

Area

(Notified by

Central

Government)

Sulphur Dioxide (SO2),

µg/m3

Annual *

24 Hours

**

50

80

20

80

-Improved West and Gaeke

Method

-Ultraviolet Fluorescence

Nitrogendioxide (NO2),

µg/m3

Annual *

24 Hours

**

40

80

30

80

-Jacob &Hochheiser modified

(NaOH-NaAsO2) Method

-Gas Phase

Chemiluminescence

Particulate Matter (Size

less than 10µm) or PM10,

µg/m3

Annual *

24 Hours

**

60

100

60

100

-Gravimetric

-TEOM

-Beta attenuation

Particulate Matter (Size

less than 2.5µm) or

PM2.5, µg/m3

Annual *

24 Hours

**

40

60

40

60

-Gravimetric

-TEOM

-Beta attenuation

Ozone (O3) , µg/m3 8 Hours *

1 Hour **

100

180

100

180

-UV Photometric

-Chemiluminescence

-Chemical Method

Lead (Pb) , µg/m3 Annual *

24 Hours

**

0.50

1.0

0.50

1.0

-AAS/ICP Method after

sampling on EPM 2000 or

equivalent filter paper

-ED-XRF using Teflon filter

Carbon Monoxide (CO),

mg/m3

8 Hours **

1 Hour **

02

04

02

04

-Non dispersive Infrared

(NDIR) Spectroscopy

Ammonia (NH3), µg/m3 Annual *

24 Hours

**

100

400

100

400

-Chemiluminescence

-Indophenol blue method

Benzene (C6H6), µg/m3 Annual *

05 05 -Gas Chromatography (GC)

based continuous analyzer

-Adsorption and desorption




* Annual Arithmetic mean of minimum 104 measurements in a year at a particular site taken twice a

week 24 hourly at uniform intervals.

** 24 hourly or 8 hourly or 1 hourly monitored values, as applicable, shall be complied with 98% of the

time in a year. 2% of the time, they may exceed the limits but not on two consecutive days of monitoring.

NOTE: Whenever and wherever monitoring results on two consecutive days of monitoring exceed the

limits specified above for the respective category, it shall be considered adequate reason to institute

regular or continuous monitoring and further investigations.

followed by GC analysis

Benzo(a)Pyrene (BaP)

Particulate phase only,

ng/m3

Annual *

01 01 -Solvent extraction followed

by HPLC/GC analysis

Arsenic (As), ng/m3 Annual *

06 06 -AAS/ICP Method after



Nickel (Ni), ng/m3 Annual *

20 20 -AAS/ICP Method after






Annexure 3{II}: Ambient Air Quality Analysis Report

1] Project Site




2] Waghundi




3] Dhorkingaon




4] Kapuswadi




5] Wahegaon




6] Wadala




7] Pachalgaon




8] Mudhalwadi




9] Rahatgaon




Annexure 3{III}: Average Noise Level Quality at various Locations

M/s Crystal Surfactants & Chemicals

Average Noise Quality at Various Locations

Sr .no Location Day time Day time

Leq (dBA) Night time

Night time

Leq (dBA)

1 Project Site Crystal Surfactant &

Chemical 6.00Am-10.00Pm 67.6647 10.00Pm-6.00Am 61.64286

2 Waghundi 6.00Am-10.00Pm 52.0059 10.00Pm-6.00Am 41.78571

3 Darkingaon 6.00Am-10.00Pm 51.7941 10.00Pm-6.00Am 42.07143

4 Kapuswadi 6.00Am-10.00Pm 52.3824 10.00Pm-6.00Am 41.78571

5 Wahegaon 6.00Am-10.00Pm 51.8118 10.00Pm-6.00Am 41.77143

6 Wadala 6.00Am-10.00Pm 52.4118 10.00Pm-6.00Am 41.4

7 Pachalgaon 6.00Am-10.00Pm 52.1765 10.00Pm-6.00Am 42.2

8 Mudhalwadi 6.00Am-10.00Pm 52.2 10.00Pm-6.00Am 41.91429

9 Rahatgaon 6.00Am-10.00Pm 52.2588 10.00Pm-6.00Am 41.92857




Annexure 3{IV}: Analysis Reports of Ground Water Quality

Sr. No Parameters Unit

Isarwadi Paithan Karanj Kheda Dhorkin Gaon Rahatgaon Warwandi budruk Kupuswadi Narayangaon Mudhalwadi

1 Temprature °C 28.6 28.1 28.1 28.6 28.1 28.6 28.6 28.7 28.2 28.40 28.10 28.70

2 Colour Hazen < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 0.00 0.00

3 Turbidity NTU 0.2 0 0.8 1.9 0.2 4.7 6.5 0.2 0.2 1.63 0.00 6.50

4 Total Suspended Solids mg/l 19.6 0.4 4.2 4.4 5.4 9 34.6 0.6 1.8 8.89 0.40 34.60

5 Total Dissolved Solids mg/l 634.05 192.45 378.26 392 247 367.9 168.33 134.19 214.85 303.23 134.19 634.05

6 Total Solids mg/l 676.65 215.85 405.46 419.4 275.4 399.9 225.93 157.79 239.65 335.11 157.79 676.65

7 pH pH Unit 6.76 7.52 6.95 6.75 7.16 6.67 7.46 6.9 7.28 7.05 6.67 7.52

8 Total Hardness (as CaCO3) mg/l 536.5 159.8 332.9 340.4 212 314 103 112.6 174.9 254.01 103.00 536.50

9 Total Alkalinity (as CaCO3) mg/l 416 348 280 280 174 330 160 200 208 266.22 160.00 416.00

10 Chloride (as Cl-) mg/l 125.96 61.96 155.95 99.97 83.97 120.96 75.98 41.99 81.97 94.30 41.99 155.95

11 Chemical Oxygen Demand mg/l <10 <10 <10 <10 <10 <10 <10 <10 <10 - - -

12 Biochemical Oxygen Demand

(at 27degC for 3 days)

mg/l 2.9 3.0 3.1 3.2 3.2 3.1 3.0 2.9 3.0 3.04 2.90 3.20

13 Sulphate (as SO4-2) mg/l 309.77 53.68 86.09 156.78 67.74 103.79 24.6 38.05 42.53 98.11 24.60 309.77

14 Fluoride (as F) mg/l 0.018 0.025 0.025 0.014 0.012 0.023 0.017 0.017 0.029 0.02 0.01 0.03

15 Silica(SiO2) mg/l 10.2 16.76 19.56 16.06 21.8 30.94 19.94 12.32 27.16 19.42 10.20 30.94

16 Phosphate (as PO4) mg/l 1.213 0.036 0.053 0.105 0.069 0.27 0.033 0.046 0.063 0.21 0.03 1.21

17 Dissolved Oxygen mg/l

18 Total Kjeldhal Nitrogen mg/l 15.7 16.1 15.4 13.2 12.4 13.5 14.1 15.2 13.2 14.31 12.40 16.10

19 Aluminium (as Al) mg/l 0.017 0.017 0.031 0.023 0.01 0.004 0.043 0.013 0.017 0.02 0.00 0.04

20 Arsenic (as As) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

21 Calcium (as Ca) mg/l 142 42.3 88.1 90.1 56.1 83.1 27.25 29.8 46.3 67.23 27.25 142.00

22 Cadmium (as Cd) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

23 Chromium (as Cr) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

24 Copper (as Cu) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

25 Iron (as Fe) mg/l 0.05 0.05 0.05 0.1 0.14 0.33 0.12 0.01 0.23 0.12 0.01 0.33

26 Mercury (as Hg) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

27 Magnesium (as Mg) mg/l 34.5 10.3 21.4 21.9 13.6 20.2 16.524 7.2 11.3 17.44 7.20 34.50

28 Manganese (as Mn) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

29 Nickel (as Ni) mg/l 0.001 0.004 0.003 0.004 0.005 0.002 0.003 0.004 0.001 0.003 0.001 0.005

30 Boron (as B) mg/l 0.015 0.002 0.005 0.004 0.007 0.005 0.007 0.006 0.007 0.006 0.002 0.015

31 Sodium (as Na) mg/l 0.15 0.13 0.16 0.12 0.15 0.16 0.12 0.32 0.14 0.16 0.12 0.32

32 Selenium (as se) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

33 Potassium (as K) mg/l 0.04 0.09 0.02 0.08 0.06 0.08 0.09 0.01 0.05 0.06 0.01 0.09

34 Zinc (as Zn) mg/l Nil Nil Nil Nil Nil Nil Nil Nil Nil

35 Total Coliform /100ml

Nil

NA

Nil

Nil

Nil

Nil

M/s Crystal Surfactants & Chemicals

Average Min Max

NA

Nil

Nil

Nil

Ground Water

Location Name




Annexure 3{V}: IS 10500:2012: Indian Standard DRINKING WATER — SPECIFICATION

Sr. No Test Parameter Unit As per IS : 10500 : 2012

Acceptable Limit Permissible Limit

1 Color Hazen Unit 5 15

2 Odour - Unobjectionable -

3 Taste - Acceptable -

4 Turbidity NTU NTU 1 2

5 Total Dissolved Solid mg/l 500 2000

6 Electrical Conductivity µS/cm - -

7 Total Alkalinity mg/l 200 600

8 pH Value - 6.5 to 8.5 No Relaxation

9 Total Hardness (CaCO3) mg/l 200 600

10 Calcium (as Ca) mg/l 75 200

11 Magnesium (as Mg) mg/l 30 100

12 Copper (as Cu) mg/l 0.05 1.5

13 Iron (as Fe) mg/l 0.3 No Relaxation

14 Manganese (as Mn) mg/l 0.1 0.3

15 Chlorides (as Cl) mg/l 250 1000

16 Sulphate (as SO4) mg/l 200 400

17 Nitrates (as NO3) mg/l 45 No Relaxation

18 Fluoride (as F) mg/l 1.0 1.5

19 Phenolic Compounds mg/l 0.001 0.002

20 Mercury (as Hg) mg/l 0.001 No Relaxation

21 Cadmium (as Cd) mg/l 0.003 No Relaxation

22 Selenium (as Se) mg/l 0.01 No Relaxation

23 Arsenic (as As) mg/l 0.05 No Relaxation

24 Lead (as Pb) mg/l 0.01 No Relaxation

25 Zinc (as Zn) mg/l 5 15

26 Chromium (as Cr+6

) mg/l 0.05 No Relaxation

27 Residual Chlorine mg/l 0.2 1

28 Boron mg/l 0.5 1

29 Total Coliform MPN/100 ml Nil

Shall not be

detectable in any

100 ml sample

30 E.Coli Nos./100 ml Absent Absent




Annexure 3{VI} Surface Water Quality Analysis Report

Sr. No Parameters Unit

Godawari

River D/SBorgaon Pimpalwadi Kapuswadi Waghundi

Godawari

River U/S

Canal A

paithan

Canal B

paithan

1 Temprature °C 28.5 28.2 28.6 28.5 28.8 28.7 28.6 28.4 28.54 28.20 28.80

2 Colour Hazen 10 10 10 10 10 10 10 10 10.00 10.00 10.00

3 Turbidity NTU 7.8 3.5 2.5 1.8 2.9 4.9 0.8 0.9 3.14 0.80 7.80

4 Total Suspended Solids mg/l 53.8 50 10.2 6.4 14.6 57.8 6.8 8 25.95 6.40 57.80

5 Total Dissolved Solids mg/l 134.67 103.66 82.04 101.3 108.12 133.21 106.98 105.6 109.45 82.04 134.67

6 Total Solids mg/l 195.47 160.66 99.24 114.7 129.72 198.01 120.78 120.6 142.40 99.24 198.01

7 pH pH Unit 6.89 7.63 7.73 7.25 7.68 7.03 7.89 7.9 7.50 6.89 7.90

8 Total Hardness (as CaCO3) mg/l 114.8 89.6 67.9 81.2 91.9 114.8 89.8 91.1 92.64 67.90 114.80

9 Total Alkalinity (as CaCO3) mg/l 140 116 128 136 124 140 112 112 126.00 112.00 140.00

10 Chloride (as Cl-) mg/l 45.98 35.6 28.2 30.1 39.99 45.99 37.99 37.99 37.73 28.20 45.99

11 Chemical Oxygen Demand mg/l <10 <10 <10 <10 <10 <10 <10 <10 - - -

12Biochemical Oxygen Demand (at

27degC for 3 days)mg/l 2.8 2.6 2.5 2.4 2.6 2.4 2.7 2.5 2.56 2.40 2.80

13 Sulphate (as SO4-2) mg/l 39.08 27.93 20.1 30.23 26.78 38.05 27.82 26.78 29.60 20.10 39.08

14 Fluoride (as F) mg/l 0.012 0.009 0.011 0.016 0.011 0.011 0.01 0.011 0.01 0.01 0.02

15 Silica(SiO2) mg/l 8.5 8.1 7.74 11.3 8.64 8.5 9.26 8.52 8.82 7.74 11.30

16 Phosphate (as PO4) mg/l 0.178 0.023 0.03 0.023 0.03 0.023 0.022 0.036 0.05 0.02 0.18

17 Dissolved Oxygen mg/l 6.8 6.2 1.2 1.2 1.5 2.8 1.2 2.5 2.93 1.20 6.80

18 Total Kjeldhal Nitrogen mg/l 12.2 11.8 13.5 15.2 16.1 36.5 11.3 11.4 16.00 11.30 36.50

19 Aluminium (as Al) mg/l 0.03 0.034 0.013 0.007 0.045 0.064 0.037 0.004 0.03 0.00 0.06

20 Arsenic (as As) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

21 Calcium (as Ca) mg/l 30.1 23.5 17.8 21.3 24.1 30.1 23.5 23.9 24.29 17.80 30.10

22 Cadmium (as Cd) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

23 Chromium (as Cr) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

24 Copper (as Cu) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

25 Iron (as Fe) mg/l 0.03 0.14 0.4 0.04 0.06 0.02 0.11 0.01 0.10 0.01 0.40

26 Mercury (as Hg) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

27 Magnesium (as Mg) mg/l 7.3 5.7 4.3 5.2 5.9 7.3 5.7 5.8 5.90 4.30 7.30

28 Manganese (as Mn) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

29 Nickel (as Ni) mg/l 0.0012 0.0008 0.001 0.002 0.001 0.008 0.004 0.002 0.00 0.00 0.01

30 Boron (as B) mg/l 0.007 0.001 0.007 0.004 0.001 0.001 0.002 0.001 0.00 0.00 0.01

31 Sodium (as Na) mg/l 0.2 0.12 Nil 0.15 0.14 0.03 0.12 0.11 0.12 0.03 0.20

32 Selenium (as se) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

33 Potassium (as K) mg/l 0.05 0.08 0.09 0.012 0.011 0.5 0.09 0.06 0.11 0.01 0.50

34 Zinc (as Zn) mg/l Nil Nil Nil Nil Nil Nil Nil Nil

35 Total Coliform /100ml 25 21 22 1600 25 17 25 30 220.63 17.00 1600.00

M/s Crystal Surfactants & ChemicalsSurface Water

Average Min Max Location Name

Nil

Nil

Nil

Nil

Nil

Nil

Nil

Nil




Annexure 3{VII}: IS: 2296:1992 for Surface Water

Classification Type of Use

Class A Drinking Water source without conventional treatment but after disinfection.

Class B Outdoor bathing.

Class C Drinking water source with conventional treatment followed by disinfection.

Class D Fish culture and wild life propagation.

Class E Irrigation, industrial cooling or controlled waste disposal.

Water Quality Standard in India {IS: 2296:1992}

Sr. No Characteristics Designated best use

A B C D E

1 Dissolved Oxygen (DO) mg/l, Min 6 5 4 4 -

2 Biochemical Oxygen Demand (BOD)mg/l,

Max 2 3 3 - -

3 Total Coliform organisms MPN/100 ml, Max 50 500 5000 -

4 pH Value 6.5-

8.5

6.5-

8.5

6.0-

9.0

6.5-

8.5

6.0-

8.5

5 Color, Hazen Units, Max 10 300 300 - -

6 Odour Unobjectionable - - -

7 Taste Tasteless - - - -

8 Total Dissolved Solid, mg/l, Max 500 - 1500 - 2100

9 Total Hardness (as CaCO3) mg/l, Max 200 - - - -

10 Calcium Hardness (as CaCO3) mg/l, Max 200 - - - -

11 Magnesium Hardness (as CaCO3) mg/l, Max 200 - - - -

12 Copper (as Cu) mg/l, Max 1.5 - 1.5 - -

13 Iron (as Fe) mg/l, Max 0.3 - 0.5 - -

14 Magnesium (as Mn) mg/l, Max 0.5 - - - -

15 Chlorides (as Cu) mg/l, Max 250 - 600 - 600

16 Sulphates (as SO4) mg/l, Max 400 - 400 - 1000

17 Nitrates (as NO3) mg/l, Max 20 - 50 - -

18 Fluorides (as F) mg/l, Max 1.5 1.5 1.5 - -

19 Phenolic Compounds (as C2H5OH) mg/l, Max 0.002 0.005 0.005 - -

20 Mercury (as Hg) mg/l, Max 0.001 - - - -

21 Cadmium (as Cd) mg/l, Max 0.01 - 0.01 - -

22 Selenium (as Se) mg/l, Max 0.01 - 0.05 - -

23 Arsenic (as As) mg/l, Max 0.05 0.2 0.2 - -

24 Cyanide (as Pb) mg/l, Max 0.05 0.05 0.05 - -

25 Lead (as Pb) mg/l, Max 0.1 - 0.1 - -

26 Zinc (as Zn) mg/l, Max 15 - 15 - -

27 Chromium (as Cr+6

) mg/l, Max 0.05 - 0.05 - -

28 Anionic detergents (as MBAS) mg/l, Max 0.2 1 1 - -

29 Barium (as Ba) mg/l, Max 1 - - - -

30 Free Ammonia (as N) mg/l, Max - - - 1.2 -

31 Electrical Conductivity, Mircomhos/cm, Max - - - - 2250

32 Sodium absorption ratio, max - - - - 26

33 Boron, mg/l, Max - - - - 2




Annexure 3{VIII}: Soil Quality Result

Particle Size Distribution and Physical Characteristics

Sr.

No. Sampling Location

Particle size distribution (%) Textural class

Total sand Silt Clay

1 Project site 24 48 28 Loam

2 Akhat Wada 27 51 22 Loam

3 Kapus Wadi 26 50 24 Loam

4 Pachal Gaon 29 48 23 Loam

5 Paithan 30 49 21 Loam

6 Balanagar 25 48 27 Loam

7 Darkin Gaon 26 50 24 Loam

8 Wahegaon 29 48 23 Loam

9 Waghandi 24 50 26 Loam

Soil Physical Characteristics

Sr.


Bulk density

(gm/cm3)

Porosity

(%)

Water

Holding

Capacity

(%)

Moisture

Content

(%)

Total

Organic

Matter

(%)

1 Project site 1.35 49.2 38.6 2.35 1.39

2 Akhat Wada 1.32 43.2 42.1 2.5 1.29

3 Kapus Wadi 1.31 37.8 43.2 1.24 0.22

4 Pachal Gaon 1.28 35.2 40.1 3.77 0.44

5 Paithan 1.35 38.1 36.3 1.93 0.55

6 Balanagar 1.34 36.3 37.8 3.01 1.28

7 Darkin Gaon 1.38 37.1 38.9 1.39 1.18

8 Wahegaon 1.32 39.1 38.2 6.92 1.34

9 Waghandi 1.34 38.6 38.4 3.38 1.15

Chemical Characteristics of Soil

Sr.


pH EC Ca++

Mg++

Na+

Cl-

µS/cm mg/Kg

1 Project site 7.72 0.43 16.2 3.88 40 3.32

2 Akhat Wada 7.09 0.54 18.1 5.56 53 12.96

3 Kapus Wadi 7.33 0.19 20.2 2.92 12 11.9

4 Pachal Gaon 7.22 0.23 24.1 2.92 30 9.82

5 Paithan 7.36 0.67 16.3 3.86 24 4.92

6 Balanagar 8.16 0.21 20.2 2.90 21 5.36

7 Darkin Gaon 7.34 0.22 24.2 3.82 42 3.86

8 Wahegaon 7.74 0.44 18.6 2.88 32 4.16

9 Waghandi 7.76 0.27 24.2 3.92 46 3.76




Macro nutrient Status of Soils in the Study Area

Sr.


Organic Carbon

(%)

N P K

(mg/Kg)

1 Project site 0.81 184.5 11.9 587

2 Akhat Wada 0.54 159.1 7.6 371

3 Kapus Wadi 0.22 156.3 6.9 245

4 Pachal Gaon 0.26 125.6 5.3 196

5 Paithan 0.32 153.4 7.4 334

6 Balanagar 0.74 168.9 12 543

7 Darkin Gaon 0.69 174.3 11.8 504

8 Wahegaon 0.78 179.6 11.9 581

9 Waghandi 0.71 221.5 11.7 596.3

Heavy Metals in Soil Samples

Sr.

No. Sampling

Location

Fe Cu Ni Zn Pb As Al Cr Cd Se Hg Ag Mn

(%) Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

Mg/

kg

1 Project site 6.23 0.43 ND 0.26 ND ND ND ND ND ND ND ND 4.13

2 Akhat Wada 4.26 0.38 ND 0.23 ND ND ND ND ND ND ND ND 2.41

3 Kapus Wadi 4.12 0.29 ND 0.23 ND ND ND ND ND ND ND ND 2.31

4 Pachal Gaon 2.96 0.26 ND 0.15 ND ND ND ND ND ND ND ND 1.98

5 Paithan 4.53 0.35 ND 0.22 ND ND ND ND ND ND ND ND 2.53

6 Balanagar 5.23 0.39 ND 0.26 ND ND ND ND ND ND ND ND 2.49

7 Darkin Gaon 5.3 0.38 ND 0.25 ND ND ND ND ND ND ND ND 3.21

8 Wahegaon 6.42 0.41 ND 0.25 ND ND ND ND ND ND ND ND 3.24

9 Waghundi 6.5 0.41 ND 0.25 ND ND ND ND ND ND ND ND 5.23




Annexure 3{IX}: Socio Economic Primary Data

Socio Economic

Indicators

Dhorkin Isarwadi Wahegaon Narayangaon Muddalwadi Pimpalwadi Katpur Karanj

Kheda

Dhangaon Pachalgaon Warudi Bk. Akhatwada Wadala Wawa Kapuswadi Balanagar Takli

(Paithan)

Paithan

(Urban)

Amrapur-

Waghondi

Borgaon Dhakefal 74 Jalgaon Rahatgaon Kasarpadali

Population- (Primary Data) 4500 4600 4200 1450 5500 8300 5100 709 1810 1000 1773 2250 622 469 855 5600 919 11507 773 901 2300 977 3000 539

Male 2300 2350 2170 774 2900 4300 2700 369 936 527 899 1170 329 244 439 2900 430 6107 395 455 1200 519 1550 268

Female 2200 2250 2030 676 2600 4000 2400 340 874 473 874 1080 293 225 416 2700 489 5400 378 446 1100 458 1450 271

Total SC population 864 950 660 319 670 1100 2200 131 208 172 317 432 0 40 195 512 53 2523 117 40 458 60 548 91

Total ST population 109 100 2 1 52 224 52 0 117 0 0 51 30 43 20 6 45 178 128 76 285 4 73 69

No. of Families / Households 900 950 850 300 1140 1660 1100 159 346 256 327 423 126 100 170 1100 169 2546 158 191 500 231 540 110

Drinking water facility Water supply

scheme

Water

supply

scheme

Water supply

scheme

Water supply

scheme

Water supply

scheme

Water supply

scheme

Water

supply

scheme

Water supply

scheme

Water supply

scheme

Water supply

scheme

water supply

scheme

Water supply

scheme

Water

supply

Scheme

Water

supply

Scheme

Water supply

Scheme

Water supply

Scheme

Water supply

Scheme

Water supply

Scheme

Water supply

Scheme

Water

supply

Scheme

Water supply

Scheme

Water Supply

Scheme

Water supply

Scheme

Health Service Yes Yes Yes Yes Yes Yes Yes No Yes No No Yes Yes No No Yes No Yes Yes Yes Yes No Yes No

Veterinary Services Yes Yes Yes Yes Yes Yes Yes No Yes No No Yes Yes No No Yes No Yes Yes Yes Yes No Yes No

Education facilities Primary

School, High

School,

College

Z. P.

Primary

School,

Z. P. Primary

School, 7th

Std., High

School.

Z. P. Primary

School,

Z. P. Primary

School, 7th

Std.,

High School.

Z. P. Primary

School, High

School

Primary

School,

High

School.

Z. P. Primary

School.

Primary

School,

Primary School. Primary

School.

Primary School,

High School

Primary

School,

Primary

School.

Primary School. Primary

School, High

School

Primary

School,

Primary

School, High

School,

College, ITI,

Engineering

Primary

School,

Primary

School,

Primary

School, High

School.

Primary School, Primary School,

High School

Primary School

Anganwadi centre 5 4 4 1 5 9 5 1 2 1 1 2 1 1 1 6 2 12 1 2 3 1 3

Crops in Kharif Season Cotton,

Sugarcane,

Maize,

Bajra, Tur,

vegetables,

Horticulture

Plants etc

Sugarcane,

Cotton, Tur,

Mung,

Vegetables,

Cotton,

Sugarcane,

Maize, Bajra,

Tur,

vegetables,

Horticulture

Plants etc

Sugarcane, Cotton,

Maize, Tur, Mung,

Vegetables,

Cotton,

Sugarcane,

Maize, Bajra,

Tur, vegetables,

Horticulture

Plants etc

Sugarcane,

Cotton, Tur,

Mung,

Vegetables,

Cotton,

Sugarcane,

Maize,

Bajra, Tur,

vegetables,

Horticultur

e Plants etc

Sugarcane,

Cotton,

Maize, Tur,

Mung,

Vegetables,

Cotton,

Sugarcane,

Maize, Bajra,

Tur, vegetables,

Horticulture

Plants etc

Cotton,

Sugarcane,

Maize, Bajra,

Tur, vegetables,

Horticulture

Plants etc

Cotton,

Sugarcane,

Maize, Bajra,

Tur,

vegetables,

Horticulture

Plants etc

Cotton,

Sugarcane,

Maize, Bajra,

Tur, vegetables,

Horticulture

Plants etc

Cotton,

Sugarcane,

Maize,

Bajra, Tur,

vegetables,

Horticulture

Plants etc

Cotton,

Sugarcane,

Maize,

Bajra, Tur,

vegetables,

Horticulture

Plants etc

Cotton,

Sugarcane,

Maize, Bajra,

Tur, vegetables,

Horticulture

Plants etc

Cotton,

Sugarcane,

Maize, Bajra,

Tur,

vegetables,

Horticulture

Plants etc

Sugarcane,

Maize, Tur,

Mung,

Vegetables,

Sugarcane,

Cotton, Tur,

Mung,

Vegetables,

Sugarcane,

Cotton Tur,

Mung,

Vegetables,

Sugarcane,

Cotton, Tur,

Mung,

Vegetables,

Sugarcane,

Cotton,Tur,

Mung,

Vegetables,

Cotton, Bajra,

Tur, Mung,

Vegetables,

Sugarcane,

Cotton,Tur,

Mung,

Vegetables,

Sugarcane,

Cotton,Tur,

Mung,

Vegetables,

Rabbi season Wheat,

Jawar, gram,

Vegetables

and fodder

Wheat,

Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables and

fodder

Wheat, Jawar,

gram, Vegetables

and fodder

Wheat, Jawar,

gram, Vegetables

and fodder

Wheat, Jawar,

gram, Vegetables

and fodder

Wheat,

Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables and

fodder

Wheat, Jawar,

gram, Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables and

fodder

Wheat,

Jawar,

gram,

Vegetables

and fodder

Wheat,

Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables and

fodder

Wheat, Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables

and fodder

Wheat,

Jawar,

gram,

Vegetables

and fodder

Wheat,

Jawar, gram,

Vegetables

and fodder

Wheat, Jawar,

gram,

Vegetables and

fodder

Wheat, Jawar,

gram, Vegetables

and fodder

Wheat, Jawar,

gram, Vegetables

and fodder

Summer season Vegetables,

fodder

species and

Horticulture

plants.

Vegetables,

fodder

species and

Horticulture

plants

Vegetables,

fodder species

and

Horticulture

plants

Vegetables, fodder

species and

Horticulture plants

Vegetables,

fodder species

and Horticulture

plants

Vegetables,

fodder species

and Horticulture

plants

Vegetables,

fodder

species and

Horticultur

e plants

Vegetables,

fodder species

and

Horticulture

plants

Vegetables,

fodder species

and

Horticulture

plants

Vegetables,

fodder species

and Horticulture

plants

Vegetables,

fodder species

and

Horticulture

plants

Vegetables,

fodder species

and Horticulture

plants

Vegetables,

fodder

species and

Horticulture

plants

Vegetables,

fodder

species and

Horticulture

Vegetables,

fodder species

and

Horticulture

Vegetables,

fodder species

and

Horticulture

Vegetables,

fodder species

and

Horticulture

plants

Vegetables,

fodder species

and

Horticulture

Vegetables,

fodder species

and

Sugarcane.

Vegetables,

fodder

species and

Horticulture

Vegetables,

fodder

species and

Horticulture

Vegetables,

fodder species

and

Horticulture

plants

Vegetables,

fodder species and

Horticulture

plants

Vegetables,

fodder species and

Horticulture

plants

Grampanchyat Office Yes Yes Yes Yes Yes Yes Yes No Yes Yes Yes Yes Group

Grampanch

ayat

Group

Grampanch

ayat

Yes Yes Yes Yes Yes No Yes Yes Yes Group

Grampanchayat

Village Library (Public) Yes Yes Yes Yes Yes Yes Yes No Yes No Yes Yes No No No Yes Yes Yes No No Yes No Yes No

Credit co-operative society Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes No No Yes Yes Yes No Yes Yes Yes Yes No

Community Hall Yes Yes Yes No Yes Yes Yes No Yes No Yes Yes Yes No No Yes Yes Yes No No Yes No Yes No

No. of roads connecting the

village

2 2 3 2 2 2 3 1 2 2 2 3 2 2 2 4 1 5 2 2 2 2 3 2

Total Literate Population 2700 3000 2700 880 4000 5321 3600 462 1115 656 1031 1370 358 289 509 3400 543 7354 460 564 1365 627 1766 320

Total Illiterate Population 1800 1500 1600 560 1500 3020 1550 247 695 351 742 882 264 180 346 2250 376 4153 313 337 1003 350 1248 219

Total no. of Workers

Population

2150 2000 2250 700 2000 3400 2000 405 819 645 1002 1050 386 222 381 2800 401 4198 380 541 1142 348 1745 313

Total no. of Cultivators 378 525 725 500 500 298 300 335 274 432 661 466 319 139 111 1225 132 254 118 386 329 194 995 205

Total No. of Main Workers

Population

1697 1890 1900 750 1875 3100 1400 392 680 566 893 990 375 218 359 2550 350 3859 370 540 1111 324 1696 313

Total no. of Non workers 2500 2400 1900 725 3400 4890 2990 304 991 362 771 1200 236 247 474 2840 518 7309 393 360 1226 629 1269 226

No. of SHG groups Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes

Exising Village

Infrastructure -

Grampancha

yat Office,

Samaj

Mandir,

Anganwadi

Centre,

Connecting

Road,

Private

health clinic,

Drinking

Water

Supply

facility, Milk

co-op Dairy,

market Place

Grampanch

ayat Office,

Drinking

water

supply,

Connecting

roads,

Primary

School ,

Credit Co-

operative

Society,

Milk co-op.

Dairy,

MIDC area.

Grampanchaya

t Office,

Drinking water

supply,

Connect roads,

, Primary

School and

High School,

Credit Co-

operative

Society, Milk

co-op. Dairy,

Sugar Factory

and MIDC area

etc.

Grampanchayat

Office,

Drinking water

supply, Primary

School Credit Co-

operative Society,

MIDC area etc.

Grampanchayat

Office,

Drinking water

supply, Primary

School and High

School, Credit Co-

operative Society,

Banks, Industrial

area etc.

Grampanchayat

Office,

Drinking water

supply, Primary

School and High

School, Credit

Co-operative

Society, Milk co-

op. Dairy,

Banks, MIDC

area etc.

Grampanch

ayat Office,

Samaj

Mandir,

Anganwadi

Centre,

Community

hall,

Private

health

clinic,

Drinking

Water

Supply

facility,

Industrial

Samaj

Mandir,

Anganwadi

Centre,

Drinking

Water Supply

facility,

Industrial area

and sugar

factory.

Grampanchayat

Office,

Drinking water

supply,

Connect roads,

Primary

School, Credit

Co-operative

Society, Milk

co-op. Dairy,

Industrial area,

Sugar Factory

etc.

Grampanchayat

Office,

Drinking water

supply, Primary

School, Credit

Co-operative

Society, MIDC

area.

Grampanchaya

t Office,

Anganwadi

Centre,

Drinking

Water Supply

facility, MIDC

area.

Grampanchayat

Office,

Drinking water

supply, Connect

roads,

communication

facilities,

Primary School

and High

School, Credit

Co-operative

Society, Milk co-

op. Dairy,

Banks, Sugar

Factory etc.

Drinking

water

supply,Prim

ary School,

Credit Co-

operative

Society,

MIDC area.

Group

Grampanch

ayat Office,

Anganwadi

Centre,

Drinking

Water

Supply

facility,

MIDC area.

Grampanchayat

Office,

Anganwadi

Centre,

Drinking Water

Supply facility,

MIDC area.

Grampanchaya

t Office,

Anganwadi

Centre,

Drinking

Water Supply

facility, market

place, weekly

market, Bank,

MIDC area.

Grampanchay

at Office,

Drinking

water supply,

Primary

School, Credit

Co-operative

Society,

MIDC area.

Nagar Palika,

Anganwadi

Centre,

Drinking

Water Supply

facility,

MIDC area,

Bus stand,

School,

colleges, ITI,

Jaikwadi

Dam,

Godavari

river, Holy

Place, Tourist

Place.

Grampanchay

at Office,

Drinking

water supply,

Primary

School Credit

Co-operative

Society, Sugar

Factory etc.

Group

Grampancha

yat Office,

Drinking

water

supply,Prim

ary School,

Credit Co-

operative

Society,

Sugar

Factory,

MIDC area,

Jaikwadi

dam.

Grampancha

yat Office,

Anganwadi

Centre,

Drinking

Water

Supply

facility,

sugar

factory,

School, High

School,

weekly

Market, Bust

Stop,

Jaikwadi

Grampanchayat

Office,

Drinking water

supply, Primary

School, Credit

Co-operative

Society, Milk

co-op. etc.

Grampanchayat

Office,

Drinking water

supply, Primary

School and High

School, Credit Co-

operative Society,

Milk co-op.

Dairy, Banks,

MIDC area etc.

Group

Grampanchayat

Office,

Anganwadi

Centre, Drinking

Water Supply

facility, MIDC

area.

Banks Yes No Yes No Yes Yes Yes No No No No Yes Yes No No Yes No Yes No No Yes No Yes No

Post Office Yes No Yes No Yes Yes Yes No No No No Yes Yes No No Yes No Yes No No Yes No Yes No

Bus stop Yes Yes Yes No Yes Yes Yes No Yes No No No Yes No Yes Yes No Yes No No Yes Yes Yes No

Weekly Market Yes No Yes No Yes Yes Yes No No No No Yes No No No Yes No Yes No No Yes Yes No

Project: M/S Matrix Fine Sciences Pvt. Ltd, Paithan MIDC, Aurangabad. (10 KM radius villages Socio-Economic survey by Primary data )




Annexure 4{I}: Quantification of environmental impact assessment methods

A component wise approach to environmental assessment and mitigation measures is applied for

each environmental aspect through a series of steps as follows.

Step 1: Review and Assessment of the Specific Aspects Generating Environmental Risk

Several scientific techniques and methodologies are used to predict impacts on the environment.

Mathematical models are useful tools (where applicable) to quantitatively describe the cause and

effect relationships between sources of pollution and different components of environment. In

cases where it is not possible to identify and validate a model for a particular situation,

predictions are arrived at through on logical reasoning / consultation / extrapolation or overlay

methods.

Step 2: Quantifying the Environmental Risk, Identifying Aspects Causing Unacceptable

Levels of Risk and Prioritizing Aspects Requiring Mitigation Measures

Once a general understanding of the impacts has been studied and understood, efforts are made

to compare different impacts so as to prioritize mitigation measures, focusing on those impacting

activities (i.e. aspects) that require urgent mitigation. For ease of comparison across different

activities, a summary environmental risk score is calculated. Two key elements are taken into

consideration based on standard environmental risk assessment methodologies:

Severity / consequence: The resultant effect of an activity and its interaction with the

physical, biological and/or socio-economic environments

Probability: The likelihood that an impact may occur due to the project activity/aspect. A

combination of severity/consequence with probability gives a reasonable measure of

environmental risk, which aids in decision making. It must always be kept in mind that any

scoring methodology however well defined is subjective and different persons can arrive at

different impact risk scores based on their experience understanding / opinion. Therefore,

results should be evaluated against past experience as well as professional judgment and

activity specific conditions to ensure adequacy and equity. The steps in identifying

environmental risk follow.




1. Scoring the Impact Severity / Consequence

The consequences on various environmental receptors have been ranked into 5 levels ranging

from insignificant to catastrophic consequence and are given in Table 1.

2. Quantifying the Probability of Occurrence of the Impact

After identifying the consequence severity as shown in given Table 1, the probability of

occurrence also needs to be estimated to arrive at a complete picture of environmental impact

risk. Table 1 provides probability / likelihood ratings on a scale of 1-5. These ratings are used

for estimating the likelihood of each occurrence.

Table 1: Probability of Occurrence

Description Environment/Health and Safety Probability

Rare Very rarely encountered during the operation activities and

production

1

Possible Might occur during the operation activities and production 2

Likely Might occur at least once during the operation activities and

production

3

Often Occur several times during the operation activities and

production

4

Certain Continues or will happen every time during operation

activities and production

5

3. Quantifying Environmental Impact Risk

The level of environmental impact risk is calculated by multiplying the consequence score and

the probability of occurrence together. Thus Significance of Impact = Consequence Score ×

Probability of Occurrence. The final score is in relative point score, rather than actual impact.

The impact estimation is carried out assuming a well managed exploratory program with the use

of standard safety measures. Below assigns significance criteria, based on the scale of 1-25, used

for prioritizing mitigation measures for reducing the environmental impact risks and thereafter,

formulating and implementing Environmental Management Plans (EMPs) given in Table 2.




Table 2: Impact Scoring System – Consequence Assessment

Sr.

No.

Environmental

Component

Impacted

Impact and Score

Insignificant

Consequence

(+/-) 1 point

Minor

Consequence

(+/-) 2 points

Moderate

Consequence

(+/-) 3 points

Major

Consequence

(+/-) 4 points

Catastrophic

Consequence

(+/-) 5 points

C1 C2 C3 C4 C5 C6 C7

1 Land Use /Land

cover

Very short term (< 3

months) and

reversible

change in Land Use

and /

or land cover

Short term (3

months – 1

year) and reversible

change in Land Use

and / or land cover

Medium term (1 -

3 years) and

reversible change

in Land Use and /

or Land cover

Long term (>3

years)

irreversible

change in Land

Use and / or land

cover

Permanent and

irreversible

adverse change in

Land Use and / or

land cover

2 Air Quality Temporary nuisance

due to controlled /

uncontrolled release

of air emissions,

odor / dust or

greenhouse gases

Minor

environmental

impact due to

controlled /

uncontrolled release

of air emissions,

odor / dust or

greenhouse gases

with no lasting

detrimental effects

Moderate

environmental

impact due to

controlled /

uncontrolled

release of air

emissions, odor /

dust or

greenhouse gases

leading to visual

impacts, at

significant

nuisance levels

Significant

environmental

impact due to

release of air

emissions, odor /

dust or

greenhouse gases

leading to

exceedance of

limits specified

in EP Rules’

Unacceptable

environmental

impact due to

release of air

emissions, odor /

dust leading to

possibility of

chronic / acute

health issues,

injuries or

fatalities

3 Ambient Noise -

give the mean

score from the

three categories,

rounded to the

nearest decimal

Background Noise Levels, with respect to Applicable Limit as per The Noise Pollution (Regulation

and Control) Rules, 2000, as Measured at Boundary of Relevant Noise Generating Unit

<10% or more Between <10 to

<5%

Between <5% or

the limit

Upto 5% above

the limit

>5% above the

limit

Incremental Noise Levels, as Predicted at Boundary of Relevant Noise Generating Unit

1 dB(A) or less 1 dB(A) – 2

dB(A)

2 dB(A) – 3 dB(A) 3 dB(A) – 4

dB(A)

4 dB(A) or more




Incremental Noise Levels, as Predicted at Boundary of Nearest Human Settlement / Sensitive

Receptor from Boundary of Relevant Noise Generating Unit

0.5 dB(A) or less 0.5 dB(A) – 1

dB(A)

1 dB(A) – 1.5

dB(A)

1.5 dB(A) – 2

dB(A)

2 dB(A) or more

4 Surface Water -

give the mean

score from the

three categories,

rounded to the

nearest decimal

Water Consumption (KL/D)

< 50 51 – 100 101 - 250 250 – 500 501 and more

Water Consumption, Duration

< 1 year 1 – 3 years 3 – 5 years 5 – 10 years 10 years or more

Wastewater Discharge Quality

No wastewater

generation

Zero Discharge Discharge to an

authorized,

functional

CETP

Other discharge

within limits

specified by the

EP Rules

Other discharge,

outside limits

specified by the

EP Rules

5 Ground Water -

give the mean

score from the

three categories,

rounded to the

nearest decimal

Location of Drawl, as per CGWA / CGWB Regulations

Safe Semi-critical Critical Over-exploited Notified

Water Drawl (KL/D)

< 50 51 – 100 101 - 250 250 – 500 501 and more

Water Drawl, Duration

< 1 year 1 – 3 years 3 – 5 years 5 – 10 years 10 years or more

Wastewater Discharge Quality

No wastewater

generation

Zero Discharge Discharge to an

authorized,

functional CETP

Other discharge

within limits

specified by the

EP Rules

Other discharge,

outside limits

specified by the

EP Rules

6 Soil Quality Loss of upto 20%

topsoil, or minor

contamination of

soil that can be easily

restored close to

original condition for

volume <10 m3

Loss of upto 40%

topsoil or actual or

possible

contamination of

soil volume <25

m3 but below

Dutch Intervention

Values

Loss of upto 60%

topsoil or actual or

possible

contamination of

soil volume <25 m3

but above Dutch

Intervention

Values

Loss of upto

80% topsoil, or

actual or

possible

contamination

of soil volume

>25 m3 and

above Dutch

Intervention

Loss of upto

100% topsoil, or

actual or possible

contamination of

soil volume >25

m3 and above

Dutch

Intervention

Values and




Values, but not

deemed to

require urgent

remediation

deemed to require

urgent

remediation

7.1 Ecology and

Bio-diversity:

Terrestrial

Insignificant

Environmental

Impact.

Occasional damage by

erosion, or of flora

and fauna. Some

disturbance to flora

and fauna habitats

Minor impact on

flora/fauna and

habitats, but no

negative impacts

on ecosystem

function. Limited

damage to

minimal area of

land .Temporary

damage (<

1month) to flora

of fauna habitats.

Significant changes

in flora/ fauna

population and

habitat. Disruption

to or some death of

rare flora and

fauna, but not

resulting in

eradication of

endangered

species. Non

persistent but

possibly wide

spread damage to

land, damage that

can be remediated

without long term

loss, localized

persistent damage;

or significant

temporary

damage (< 1 year)

to ecosystem.

Continuous and

serious damage

by erosion or to

flora or fauna.

Major

disruption to or

frequent death

of rare flora or

fauna. Major

destruction of

ecosystem.

Long term and

significant change

in population or

habitat with

negative impact

on ecosystem

function.

Widespread

destruction to a

significant area of

land, rare flora

and fauna and/ or

ground water

resources.

7.2 Ecology and

Bio-diversity:

Aquatic

Occasional short term

impact and / or

disruption to aquatic

flora and fauna

Minor impact on

aquatic ecosystem,

including flora,

fauna and habitat.

No significant

impact on water

Significant

localized

impacts but

without long

term impact on

aquatic ecosystem

Significant

widespread

impact on

protected

wildlife or

aquatic

Damage to an

extensive

portion of aquatic

ecosystem

resulting in severe

impacts on




resources. and/or short term

impacts on water

resources.

ecosystem of

moderate

duration

aquatic

population and

habitats and or

long term impact

on water

resources.

8.1 Socio-economic

Environment:

Social Aspects -

give the mean

score from the

categories,

rounded to the

nearest decimal

Possible Temporary or Permanent Migration, Persons as a % of Population of Study Area

<0.5% <1% <1.5% <2% 2.5%

Possible Change in Ethnicity, vis-à-vis Major Existing Ethnicities Present in Study Area

Not Likely Possible Limited Significant Severe

Gender Imbalance, as a Proportion to Existing Sex-Ratio

Not Likely Possible Limited Significant Severe

Possibility of Return to Original Status in Terms of Any or All of the Above Changes

<1 year <2 years <3 years <5 years Permanent

Change

8.2 Socio-economic

Environment:

Economic Aspects

– give the mean

score from the

categories,

rounded to the

nearest decimal

No of Jobs Gained or Lost

<50 Up to 75 Up to 100 Up to 250 Up to 500 or

more

Persons Having Loss or Gain in Income

<50 100 250 500 1000 or more

Land Losers

<10 <20 <50 <100 >100

Losers of Homesteads

<5 <10 <25 <50 >50

8.3 Socio-economic

Aspects: Cultural

Minor repairable

damage to

commonplace

structures

Minor repairable

damage to

structures / items

of cultural

significance, or

minor

infringements of

cultural values

Moderate damage

to structures/ items

of cultural

significance, or

significant,

infringement of

cultural values/

sacred location

Major damage

to structures /

items of cultural

significance, or

major

infringement of

cultural values /

sacred locations

Irreparable

damage to

highly valued

structures / items

/ locations of

cultural

significance or

sacred value




9.1 Occupational /

Community Health

and Safety:

Community Health

and Safety

Insignificant impact

on surrounding

communities

Minor complaints

or exposure to

community.

Maximum

occurrence limited

to two times per

year

Ongoing

complaints from

community.

Significant

emission or

discharge that

impacts on

surrounding

population

Major ongoing

long term health

effects likely to

surrounding

communities

and workers

Extreme health

risk potential for

death in

Community

9.2 Occupational /

Community

Health and Safety:

Occupational

Health and Safety

Near miss incident or

trivial injuries, this

may require self

administered first aid.

Injured personnel can

continue to perform

normal duties

Injuries requiring

onsite treatment

by medical

practitioner.

Personnel unable

to continue to

perform duties

Serious injuries

requiring off site

treatment by

medical

practitioner or

immediate

evacuation to

hospital. Potential

long term or

permanent

disabling effect

Single Fatality Multiple Fatality




To do this, environmental impact risk levels are first scored and identified as mentioned

earlier and then evaluated on the evaluation scale that follows in Table 3.

Table 3: Environmental Impact Significance Criteria

Probability

Consequence

Insignificant

(1)

Minor

(2)

Moderate

(3)

Major

(4)

Catastrophic

(5)

Rare (1) 1 2 3 4 5

Possible (2) 2 4 6 8 10

Likely (3) 3 6 9 12 15

Often (4) 4 8 12 16 20

Certain (5) 5 10 15 20 25

4. Identifying Activities Causing Unacceptable Levels of Environmental Risk

Environmental risks are now clubbed into four levels from extreme risk to low risk activities.

Extreme risk activities are unacceptable and therefore need to be either stopped or modified

such that they are brought to a lower level of environmental risk.

High and moderate risk activities, although acceptable, require being evaluated and mitigated

in a manner that their consequences / probabilities are lowered, with more focus on high risk

activities vis à-vis moderate risk activities. Low risk activities do not require further

mitigation. This is summarized in Table 4.

Table 4: Environmental Risk Categorization

Score Type of Risk Action Required

15-25 Extreme Risk Activity should not proceed in current form

8-12 High Risk Activity should be modified to include remedial planning and

actions and be subject to detailed EHS assessment

4-6 Moderate Risk Activity can operate subject to management and / or

modification

1-3 Low Risk No action required unless escalation of risk is possible

Mitigation Measures

Mitigation measures require being formulated and implemented for all high risk and

moderate risk activities. A programme to implement all mitigation measures is then prepared

and presented as an Environmental Management Programme, presented in Chapter 9.




Annexure 7{I}: Hazardous Materials store in drums or Bags

Sr.

No.

Chemical Liquid/Gas

at storage

Conditions

Maximum

Quantity

required

Per month

Maximum

Quantity

stored

MT/Kgs/

liters

Size of

Drum

/carboy

Number

of drums/

carboys

Nature of Hazard

Toxic/Reactive/

Fire (From NFPA

rating )

1 2, 5-Dichloro Nitrobenzene Solid 33390 Kg 20 MT 50 Kg Bag 400 Bags Toxic

2 2, 3-Dichloro 5-Trifluromethyl

Pyridine Liquid 13200 Kg 10 MT

250 Kg

Drums 40 Drums Toxic

3 8-Chloro Quinaldine Solid 11250 Kg 5 MT 25 Kg Bag 200 Bags Toxic

4 4-Chloro 2 Nitro Aniline Solid 30000 Kg 10 MT 25 Kg Bag 400 Bags Toxic



7 2-Nitro Aniline Solid 25000 Kg 10 MT 25 Kg Bag 400 Bags Toxic

8 2-Amino 3 Chloro 5 Tri Floro

Methyl Piridine Solid 12000 Kg 5 MT 25 Kg bag 400 Bags Toxic

9 4-Nitro Meta phenyline Dimine Solid 2000 Kg 2 MT 25 Kg bag 80 Bags Toxic

10 8-Amino Quinaldine Solid 10000 Kg 4 MT 25 Kg Bag 160 Bags Toxic

11 Albendazole Solid 20000 Kg 5 MT 25 Kg Bag 200 Bags Toxic

12 Fenbendazole Solid 20000 Kg 5 MT 25 Kg Bag 200 Bags Toxic

13 Ammonia Gas 25000 Kg 5 MT 50 Kg

Cylinder

100

Cylinders Hazardous / Toxic




Annexure 7{II}: Safety Measures in handling Cylinders

Risks and Hazards from Gas Cylinders:

Gas cylinders can be hazardous due to both their physical (size and weight) and chemical

characteristics. Hazards from gases are also subject to the chemical properties of each gas.

These may be one or more of the following:

1. Fire or explosion from the release of flammable gases near ignition sources (e.g.

acetylene or LPG). Refer to MSDS for Upper and Lower Explosive Limits (UEL and

LEL)

2. Spontaneous combustion from oxidizing gases (e.g. Oxygen or Nitrous Oxide),

Exposure limits for all gases, especially toxic or corrosive gases (e.g. Anhydrous

Ammonia); refer to MSDS for Time Weighted Exposure Limit (TWA) and Short Term

Exposure Limit (STEL), Asphyxiation from non-toxic, non-flammable gases by

displacement of Oxygen (e.g. Nitrogen, Carbon Dioxide or Argon), Incorrect storage

3. Leakages

Each compressed gas cylinder has unique hazards based on its contents. Some are filled with

inert gases; especially those used in arc welding. Many gases are flammable, explosive, toxic, or

a combination.

Bulk Cylinder Storage: Gas stores should be located outdoors, preferably in a secure, cage

protected from sunlight. Storage indoors is not recommended unless the building has been

designed for that purpose with appropriate fire rated walls and ventilation. Where gases are

stored indoors, additional safety considerations and control measures need to be given

consideration.

Specific Storage precautions Requirements in manifolds: Cylinders in Use shall be in an

upright position. If cylinders have been lying on their side, place the cylinder in the upright

position and wait for 60 minutes before using. If Acetylene has been laid on its side, then it is

recommended that the cylinder shall not used be for 12-24 hours.

Secure cylinders using a special purpose built non-abrasive coated chain, strap or cable that will

not scratch the cylinder markings and paint work or a racking system.

Completely close the valves, and keep the valve protection devices, such as caps or guards,

securely in place when cylinder is not in use.

1. Store cylinders in a dry, well-ventilated area. Place them in a location where they will

not be subject to mechanical or physical damage, heat or electrical circuits to prevent

possible explosion or fire.

2. Keep cylinders away from pedestrian traffic.

3. Full and empty cylinders should be stored separately in clearly marked areas.

4. Objects should not be stored on top of gas cylinders




5. Gases denser than air need to be stored with caution to avoid storage where these gases

can accumulate in low lying areas.

6. Gas cylinders should not be located where they may block stairs, exits, ladders or walk

ways. Ensure an up to date and accurate inventory is kept. Keep inventory quantities as

low as possible.

7. Segregate Incompatible Gases

Using Gas Cylinders

Always use gas cylinders in well ventilated areas. Do not use gas cylinders in confined spaces

unless qualified to do so and the appropriate PPE is used. Know the gas you are using and

possible reaction products. Additional mechanical ventilation may be required. Seek expert

assistance in designing and installing mechanical ventilation systems. Ensure the correct

regulator is used for the purpose.

Ensure there is a suitable emergency response procedure in place. Wear appropriate

PPE for the gas been used, refer to MSDS. Ensure connections, fittings and lines are

leak tight and suitable for use.

Ensure that flammable and oxidizing gases are not used near ignition sources.

Disconnect empty cylinders from equipment to avoid backflow issues. Always close

the cylinder valve when not in use. DO NOT use an empty cylinder as a waste

receptacle. Fit non-return valves in line if required.

Do not use a gas cylinder that shows evidence of damage or corrosion. The gas cylinder

is a rented item; its integrity is the responsibility of the gas supplier. If the cylinder

contents cannot be clearly identified, Do not use it.

Leaks

Leaks from gas cylinders are potentially very dangerous, depending on the properties of the gas.

If a gas cylinder is found to be leaking then appropriate measures should be put in place to limit

risk.

If a flammable gas is found to be leaking then it should be treated as if the cylinder were on fire.

Leaking toxic gases are extremely dangerous. Immediately evacuate the area and follow the

normal school/faculty emergency response procedures. The fire brigade shall be called and

informed of the type of leaking gas. DO NOT re-enter the area until it is deemed safe to do so by

professionals.




Annexure 7{III}: Measures for Handling Ammonia

"Ammonia is a natural constituent of the atmosphere but exists in concentrations below the level

which is hazardous to humans, animals, plants or materials.

High concentrations of Ammonia gas are corrosive to mucous membranes; can cause damage to

the eye, throat and upper respiratory tract; and can produce residual damage and even death to

humans and animals.

High concentrations are also toxic to most plant life and have corrosive effects on materials."

Concentration in Air Effect

20 µg/m3 (0.027 ppm) - Average atmospheric background concentration.

30 - 36,000 µg/m3 (0.04 -

50 ppm)

- Odor threshold.

1.44 mg/m3 (2.0 ppm) Max

one hour concentration

limit

A limit of 0.50 ppm may be desirable if a surrounding buffer is not

possible.

18 mg/m3

(25 ppm) Threshold limit value to which it is believed workers may be

exposed continuously for 8 hours without adverse effects

280 - 490 mg/m3 (390 - 680

ppm)

- Concentration range where Ammonia gas produces eye, nose and

throat irritation and may injure respiratory mucous.

360 mg/m3 (500 ppm)

- Suggested maximum short-term atmospheric concentration due

to uncontrolled release of ammonia resulting from equipment

failure, safety valves discharging or any other single release.

The flammable limits of Ammonia are from 15% to 25% by volume in air; however, Ammonia

is difficult to ignite in spite of this. Gaseous Ammonia will dissolve readily in water at a rate of

approximately 700 volumes/volume of water.

Melting Point: -77.4°C

Boiling point: -33.4°C

Density: 0.677 g/cc

* Due to the chilling effect of evaporation, ammonia vapor resulting from a large spill may move

downwind as a visible cloud some distance before dissipating or rising.

Vapour

Concentration(ppm)

General Effect Exposure Period

(1) (2) (3)

1-5 Odour detectable by most

person

Prolonged repeated exposure produces

no injury

25 No adverse effect for average

worker

Maximum allowable concentration

for 8 hour working exposure

35 No adverse effect for average

worker

Exposure should not be longer than

15 minutes and should not occur more




Vapour

Concentration(ppm)

General Effect Exposure Period

than four times per day

400 to 700 Nose and throat irritation

Eye irritation with tearing

Infrequent short (1/2 hour) exposure

ordinarily produces no serious effect

2 000 to 3 000 Conclusive coughing Severe

eye irritation

No permissible exposure. May be fatal

after short exposure

5 000 to 10 000 Respirator spasm. Rapid

asphyxia

No permissible exposure. Rapidly fatal

Liquid Anhydrous Ammonia produces skin burn on contact.

ACGIH Short Term Exposure Limit (STEL) – 35 ppm

Notes

1. ACGIH (TLV-TWA) – The TWA concentration for a conventional 8 hour work day

and 40 hour work week, to which it is believed that nearly all workers may be

repeatedly exposed, day after day for lifetime without adverse effect.

2. ACGIH (TLV-STEL) indicates Short Term Exposure Limit. A 15 minutes TWA

exposure that should not be exceeded at any time during a work day, even if the 8 hour

TWA is within the TLV-TWA. Exposures above the TLV-TWA up to the TLV-STEL

should be less than four times per day and there should be at least 60 minutes between

successive exposures in this range.

Labelling

Consignments or smaller containers shall carry an identifying label or stencil depicting the

symbol given in Fig. 2 of IS 1260 (Part 1) and the following information shall also be given in

the lower half of the label.

Ammonia Warning ! Hazardous Liquid And Gas Under Pressure

Liquid Causes Burns; Gas Extremely Irritating

Do not breathe gas.

Do not get in eyes, on skin, on clothing.

In case of contact, immediately flush skin or eyes with plenty of water for at least 15

minutes. Call a physician at once in case of burns, especially to the eyes, nose and throat,

or if the patient is unconscious.

Keep cylinders away from heat and sun. Do not store with flammable or explosive

materials. Never drop cylinders.

Be sure connections are tight. Use no oil or lubricants on valves.

Never refill cylinders.

Keep the cylinders up-right (vertical) with its valve at the top and secure it properly.




Preventive Measures

Employee Education and Training

Safety in handling Ammonia depends, to a great extent, upon the effectiveness of employee

education, proper safety instructions, intelligent supervision and the use of safe equipment.

The education and training of employees to work safely and to use the personal protective

equipment or other safeguards provided for them is the responsibility of supervisor. Workers

should be thoroughly informed of the hazards that may result from improper handling of

Ammonia. Each employees should be fully informed as to what to do in an emergency.

Employee education and training should include the following:

a. Instruction and periodic drill or quiz regarding the locations, purpose and use of

respiratory protective devices and other personal protective equipment and action to be

taken during emergency.

b. Instruction and periodic drill or quiz regarding the locations of safety showers, eye

baths, bubbler drenching fountains or the closest source of water for use in

emergencies.

c. Instructions to avoid all unnecessary inhalation of vapours of Ammonia and all direct

contact with the liquid.

d. Instruction and periodic drill or quiz regarding the location, purpose and the use of

emergency fire fighting equipment. Instruction to strictly prohibit smoking in storage

area.

e. Instructions to report to the proper authority all equipment failures and any unusual

odour of Ammonia.

Personal Hygiene

Emergency showers and eye baths should be placed at convenient locations wherever Anhydrous

Ammonia is used in quantity. Every employee should understand that direct contact with the

chemical requires the instant application of large amounts of water to the affected area. These

safety showers should be tested periodically for their proper functioning. Skin, eye and

respiratory protective equipment will often be necessary.

Physical Examinations

Pre-placement Examinations:

Most employees may be assigned to processes in which the use of Anhydrous Ammonia is

carefully controlled. Under some circumstances the physician carrying out pre-placement

examinations may wish to exclude from exposure people with the following disabilities:

a. Those with only one functioning eye;

b. Those with severe faulty vision; and

c. Those with chronic diseases of the nose, throat or lung.




Periodic Health Examination

Usually periodic health examinations will not be conducted solely by reason of the employee

exposure to Ammonia.

Personal Protective Equipment

Availability and Use:

While personal protective equipment is not an adequate substitute for good, safe working

conditions, adequate ventilation and intelligent conduct on the part of employees working with

Ammonia, it is, in many instances, the only practical means of protecting the worker, particularly

in emergency situations. One should keep firmly in mind that personal protective equipment

protects only the worker wearing it, and other unprotected workers in the area may be exposed to

danger.

The correct usage of personal protective equipment requires the education of the workers in

proper employment of the equipment available to him. Under conditions which are sufficiently

hazardous to require personal protective equipment, its use should be supervised and the type of

protective equipment selected should be capable of control over any potential hazards.

Eye Protection

Gas-tight chemical goggles or full face mask should be worn when handling Ammonia where

leaks or spills may occur. Water wash or water sprays should be available in areas where

ammonia leaks, spills or splashes may be encountered.

Respiratory Protection

Severe exposure to Ammonia may occur in tanks during equipment cleaning and repairs, when

decontaminating areas following spills, or in case of failure of piping or equipment. Employees

who may be subject to such exposures shall be provided with proper respiratory protection and

trained in its use and care. Available types are described below.

NOTE– Respiratory protective equipment shall be carefully maintained, inspected, cleaned and sterilized at regular

intervals and always before and after use by another person.

Self-contained breathing apparatus:

It permits the wearer to carry a supply of oxygen or air compressed in the cylinder (the self-

generating type produces oxygen chemically) and allows considerable mobility. The length of

time a self-contained breathing apparatus provides protection varies according to the amount of

air, oxygen or regenerating material carried.

Compressed Oxygen should not be used where there is danger of contact with flammable liquids

or vapours, especially in confined spaces such as tanks or pits. A special type of self-contained

breathing apparatus may be used which is provided with a small cylinder of compressed air for

escape but is supplied with air through an air line for normal work purposes.




Positive pressure hose masks

These are supplied by blowers and require no internal lubrication. The wearer shall be able to use

the same route for exit as for entrance and shall take precautions to keep the hose line free of

entanglement. The air blower shall be placed in an area free of contaminants.

Air-line masks

These are supplied with clean compressed air and are suitable for use only where conditions will

permit safe escape in case of failure of the compressed air supply. These masks are usually

supplied with air piped to the area from a compressor. It is extremely important that the air

supply is taken from a safe source and that is not contaminated by oil decomposition from

inadequate cooling at the compressor. The safer method is to use a separate compressor of the

type not requiring internal lubrication. Pressure reducing and relief valves as well as suitable

traps and filters, shall be installed at all mask stations.

Chemical cartridge respirators

These may be used to avoid inhaling disagreeable but relatively harmless concentrations of

Ammonia vapour. These respirators, however, are not recommended for protection where toxic

quantities of Ammonia may be encountered. While using cartridge care must be taken to check

the oxygen content in the area. It should be more than 16.5 percent (v/v) and chemical cartridges,

whose life is over, must not be available for use.

Caution: Filter type respirators do not offer protection against gases and are unsuitable for use

when working with Ammonia.

Head Protection

Where there is no danger from falling objects, safety or ‘hard’ hats are considered unnecessary,

soft, brimmed hat or caps should be worn to give protection against liquid leaks and splashes.

Foot Protection

Rubber boots or safety-toed rubber boots should be used as required. Rubber boots should be

thoroughly cleaned and ventilated after contamination.

Body, Skin and Hand Protection

Rubber or other protective gloves should be worn where any danger of contact with Ammonia

may occur. Impermeable wears may also be used.

For the protection of the skin, cotton shirt, trousers and underwear should be worn (cotton resists

alkalis better than wool).

In case of emergency, a rubber apron or rubber coat may provide sufficient protection, but in

areas of high Ammonia concentration a complete gas suit should be worn.

For optimum protection of the body, the collar should be kept buttoned, glove (gauntlets) should

be tucked inside of sleeves, and trouser legs should be left outside of boots.

It is also suggested to have a valcro type tight fitting strap to have the legs and arm areas tight

enough to avoid Ammonia gas entry into the protective suit.




In area of high Ammonia concentration, Ammonia may be absorbed by perspiration on the body

even though appropriate protective clothing is worn. Severe discomfort may be minimized or

prevented by the application of protective oil to such body areas in addition to the wearing of

protective clothing.

8.5 Spills and Leaks

Leaks of Ammonia should be searched for, preferably with Hydrochloric Acid solution or with

either Chlorine gas or Sulphur Dioxide gas using a small cylinder of the compressed gas. A

white cloud is produced in the presence of Ammonia. Because of the fire risk, Sulphur candles

should not be used.

If leaks or spills occur, only properly protected personnel should remain in the area. In cases

where leaks cannot be valved off, use large volumes of water sprayed directly on the leak and

maintain contact until the contents have been discharged and the tank is empty. Leaking

cylinders should be removed to the outdoors or to an isolated, well-ventilated area and the

contents transferred to other suitable containers. All spills should be flushed away promptly with

water.

In handling or operating any type of Ammonia system, always be sure that all valve connections

and pipe lines are in proper order and condition before starting the operation. Keep compressors

and motors clean and in good condition.

During cold weather keep all steam traps warm, whether or not tanks are in service.

Never, under any circumstances, close all valves on a full line of liquid Ammonia unless

protected by pressure relief or liquid expansion device.

9 FIRST-AID

9.1 General Principles: After severe exposure to Ammonia gas, it is important to move the

patient from the contaminated area promptly. In case of contact of the liquid with the eyes or

skin, immediate flushing with large quantities of running water is imperative. In all cases of

serious injury, call a physician at once giving him a complete account of the accident.

9.2 Contact with Skin and Mucous Membranes: Speed in removing Ammonia from contact

with the patient and in moving the patient to an uncontaminated atmosphere is of primary

importance.

If skin contact is extensive and emergency showers available, the employee should get under the

shower immediately. Contaminated clothing and shoes should be removed under the shower. In

other instances flushing with large amounts of running water should be continued for at least 15

minutes.

9.2.1: Under no condition should salves or ointments be applied to the skin or mucous membrane

burns during the 24-hour period following the injury. Subsequent medical treatment is otherwise

the same as for thermal burns.




9.3 Contact with the Eyes: If even small quantities of ammonia enter the eyes, they should be

immediately and continuously with water for a minimum of 15 minutes. The eyelids should he

held apart during the washing to ensure the contact of water-with the tissues of the eye surface

and lids. A physician should be called at the earlier possible moment. After the first 15 minutes

period of irrigation, if a physician is not available, the irrigation should continue for a second

period of 15 minutes. It is then permissible as a first-aid measure to instill 2 or 3 drops of 0.5

percent Pontocaine solution or an equally effective aqueous topical anesthetic. No oils or oily

ointment should be instilled unless ordered by a physician. The employee should be sent to a

physician, preferably an eye specialist, as soon as possible.

9.4 Ingestion: If liquid Anhydrous Ammonia has been swallowed, call a physician immediately.

If the patient is conscious and able, he should drink large amounts of water to dilute the

chemical. Do not induce vomiting if the patient is in shock, extreme pain or is unconscious. If

vomiting begins, place the patient face down with head lower than hips, this prevents vomitus

from entering the lungs and causing further injury.

9.5 Inhalation: Exposed persons should be removed at once to an uncontaminated area. If the

exposure has been to minor concentrations for a limited time, usually no treatment will be

required.

9.5.1: When there is severe exposure to higher concentrations and if Oxygen apparatus is

available, oxygen may be administered but only by a person authorized for such duty by a

physician. If the patient is not breathing, an effective means of artificial respiration should be

initiated immediately. Call a physician.

9.5.2: The patient should be kept comfortably warm but not too hot and should be kept at rest.

9.5.3: Never attempt to give anything by mouth to an unconscious patient.

10 Cleaning and Repairs

10.1 Preparation of Tanks and Equipment

10.1.1: Tank and equipment cleaning and repairing should be done under the direction of

thoroughly trained personnel who are fully familiar with all of the hazards and the safeguards

necessary for the safe performance of the work.

10.1.2: In addition to the precautions generally recommended for tank work, such as

procurement of written approval of supervision, testing for Oxygen content, use of rescue

harness or life belt and life line, provision of grounded equipment in good condition for portable

lights and power tools and stationing of thoroughly trained ‘watchers’ outside and tank entrance,

additional precautions are recommended as follows:

a. Make sure that all pressure has been relieved from tank. Use of compressor is

frequently made to remove bulk of gas remaining after the liquid has been removed.




b. Pressurize and depressurize the tank with air till Ammonia content inside the tank

becomes nil. After stopping the compressor, slowly vent the tank. Make sure that any

gas escaping does not enter working area or expose other person.

c. Fill tank completely with water and drain out. Repeat if any Ammonia gas remains.

d. Keep adequate vents in open condition to avoid vacuum formation during filling the

tank with water.

e. If oil is found in the tank and requires to be removed, it should be done by steaming and

draining and not by the use of solvents.7

f. Provide adequate fresh air supply.

g. Use proper personal protective equipment.

h. Flush all lines completely with water until no ammonia remains.

i. Blank off lines; do not depend on shut-off valves.

10.2 Entering Tank

10.2.1: No one should enter a tank or confined space until a work permit has been signed by an

authorized person, indicating that the area has been tested and found to be safe. Furthermore, no

workman should enter a tank or vessel that does not have a manhole opening large enough to

admit a person wearing his safety harness, life line and emergency respiratory equipment. It

should be ascertained that the tank or vessel can be left through the original entrance.

10.2.2: One man on the outside of the tank should keep the men in the tank under observation

and another man should be available nearby to aid in rescue if any of the men in the tank are

overcome.

10.2.3: A supplied-air respirator or self-contained breathing apparatus, together with rescue

harness and life line should always be located outside the tank entrance for rescue purposes,

regardless of the type of respiratory equipment or air supply which is provided for employees

inside the tank.

10.2.4: If a tank cleaner or repairman is overcome, he should be removed to fresh air

immediately, artificial respiration should be applied if breathing has stopped, and a physician

summoned at once.

10.3 Repair Work

10.3.1: No welding and cutting of any type should be conducted on tanks or lines until they are

completely free of Ammonia and certified by competent person as well as safety work permit

issued.

10.3.2: Before refilling the tank with Anhydrous Ammonia, the tank should be thoroughly dry

and vented to safe location.

11 Waste Disposals:

11.1: Waste disposal of Ammonia and materials containing Ammonia depends to a great extent

upon local conditions. Be sure that all central, state, and local regulations regarding health and

pollution are followed.




11.2: If not prohibited, waste may be disposed of by diluting with large quantities of water and

washing into sewers.




Annexure 7 {IV}: Material Safety Data Sheet for Products & Raw Material

{Products}

Sr.

No.

Raw materials/

products

Formula State Odor Mol.

Wt

(g/mole

)

Flash

Point

(0C)

Meltin

g

Point

(0C)

Boilin

g

Point

(0C)

LD50

(mg/k

g)

Stability Hazard Color Sp.

Gr.

(g/cc)

UEL

%

LEL

%

Odor

threshold

(ppm)

1. 2- Nitro Aniline C6H6N2O

2

Cryst

als

slight

odor

138.13 168 70 - 74 284 NA Stable Irritation to

eye, skin,

inhalation,

ingestion

orange

to

brown

1.1 NA NA NA

2. 4- Chloro 2-

Nitro Aniline

C6H5

ClN2 O2

Powd

er

Weak,

charact

eristic

172.57 191 114-

118

>290 400 Stable Irritation to

eye, skin,

inhalation,

ingestion

Orange 1.37 NA NA NA

3. 4- Nitro -2-

Chloro Aniline

C6H6N2O

2

Solid NA 138.12 198.9

0

148.5 331.7 450 Stable Irritation to

eye, skin,

inhalation,

ingestion

Yellow 1.424 NA NA NA

4. 2-Amino 3-

Chlro 5-

Trifluoro

Methyl Pyridine

C6H4ClF3

N2

Solid Odorle

ss

196.57 NA 90.00

93.00

NA NA Stable Irritation to

eye, skin,

inhalation,

ingestion

White NA NA NA NA

5. 5- Chloro-2-

Nitro Aniline

C6H5

ClN2 O2

Solid NA 172.56 NA 126 -

129

NA NA Irritation to

eye, skin,

inhalation,

ingestion

Yellow-

orange

NA NA NA NA

6. 4- Nitro-m-

Phenylene Di-

Amine

C6H7N3O

2

Powd

er

NA 153.14 NA 196-

201

NA 681 Stable Irritation to

eye, skin,

inhalation,

ingestion

Brown-

red

NA NA NA NA

7. 8-amino

Quinaldine

C10H10N2 NA NA 158.2 NA NA NA NA Stable Irritation to

eye, skin,

inhalation,

ingestion

NA NA NA NA NA

8. Albendazole C12H15N3

O2S

NA NA 265.33 NA NA NA 2,400 Stable Irritation to

eye, skin,

inhalation,

ingestion

NA NA NA NA NA




Sr.

No.

Raw materials/

products


Wt

(g/mole

)

Flash

Point

(0C)

Meltin

g

Point

(0C)

Boilin

g

Point

(0C)

LD50

(mg/k

g)


Gr.

(g/cc)

UEL

%

LEL

%

Odor

threshold

(ppm)

9. Fenbendazole C15H13N3

O2S

Solid Odorle

ss

29.3 NA NA NA >100

00

Stable Irritation to

eye, skin,

inhalation,

ingestion

Brownis

h-Grey

NA NA NA NA




{Raw Materials}

Sr.

No.

Raw

materials


Wt

(g/mole

)

Flash

Point

(0C)

Meltin

g

Point

(0C)

Boilin

g

Point

(0C)

LD50

(mg/k

g)


Gr.

(g/cc)

UEL

%

LE

L

%

Odor

threshold

(ppm)

1. 2- Nitro Aniline

1. 2,5 Dichloro

Nitro

Benzene

C6H3Cl2

NO2

Flake

s

NA 192 152 52.8 267 1210 Stable Irritation to

eye, skin,

inhalation,

ingestion

Yellow NA 9.2 1.5 NA

2. Ammonia NH3 Liqu

efied

gas

Ammo

niacal

17 NA -77.7 -33 4000 Stable Corrosive Colorless NA NA NA As low as

5 ppm

2. 5- Chloro-2-Nitro Aniline

1. 2,4-

Dichloro

Nitro

Benzene

C6H3Cl2

NO2

cryst

alline

NA 192 130 29 - 32 258 NA Stable Irritation to

eye, skin,

inhalation,

ingestion

Light

Yellow

NA NA NA NA

2. Ammonia NH3 Liqu

efied

gas

Ammo

nical


5 ppm

3. Methanol CH3OH Liqui

d

Alcoho

l

32.04 NA -97.6 64.5 NA Stable Flammable colorless 0.791

5

36.5

0

6.7

2

NA

3. Ortho Chloro Para Nitro Aniline

1. 3, 4 Di

Chloro Nitro

Benzene

C6H3Cl2

NO2

Need

les

NA 192 123 40.50 -

42.00

255.0 -

256.0

NA Stable Irritation to

eye, skin,

inhalation,

ingestion

Yellow

to Brown

NA NA NA NA

2. Ammonia NH3 Liqu

efied

gas

Ammo

nical


5 ppm

4. Ortho Nitro Aniline

1. Ortho Nitro

Chloro

Benzene

C6H4CIN

O2

Solid NA NA 126 31 - 33 246 NA Stable Irritation to

eye, skin,

inhalation,

ingestion

Slight

yellow

NA NA NA NA

2. Ammonia NH3 Liqu

efied

Ammo

nical


5 ppm




Sr.

No.

Raw

materials


Wt

(g/mole

)

Flash

Point

(0C)

Meltin

g

Point

(0C)

Boilin

g

Point

(0C)

LD50

(mg/k

g)


Gr.

(g/cc)

UEL

%

LE

L

%

Odor

threshold

(ppm)

gas

5. 4 Nitro Metaphenylene Diamine

1. 2,4-

Dichloro

Nitro

Benzene

C6H3Cl2

NO2

cryst

alline

NA 192 130 29 - 32 258 NA Stable Irritation to

eye, skin,

inhalation,

ingestion

Light

Yellow

NA NA NA NA

2. Ammonia NH3 Liqu

efied

gas

Ammo

nical


5 ppm

6. 2-Amino, 3-Chloro, 5-(Trifluoromethyl), Pyridine

1. 2, 3

DiChloro 5

(Trifluromet

hyl)

Pyridine

C6H2Cl2F

3N

Liqui

d

NA 215.99 79 NA NA NA Stable Irritation to

eye, skin,

inhalation,

ingestion

Colorless NA NA NA NA

2. Ammonia NH3 Liqu

efied

gas

Ammo

niacal


5 ppm

7. 8-Amino Quinaldine

1. 8-Chloro

Quinaldine

C10H10N2 NA NA 158.2 NA NA NA NA Stable Irritation to

eye, skin,

inhalation,

ingestion

NA NA NA NA NA

2. Ammonia NH3 Liqu

efied

gas

Ammo

niacal


5 ppm

8. Albendazole

1. 4-Phenyl

Sulphanyl

Benzene

1,2-Diamine

C6H8N2 Solid NA 108.14 NA 62 284 67.7 Stable Irritant to

skin, eye

Inhalation &

ingestion

NA NA NA NA NA

2. Cyano

Crabamate

C12H14N2

O2

NA NA 218.25 NA NA NA NA Stable Irritant to

skin, eye

Inhalation &

ingestion

NA NA NA NA NA




Sr.

No.

Raw

materials


Wt

(g/mole

)

Flash

Point

(0C)

Meltin

g

Point

(0C)

Boilin

g

Point

(0C)

LD50

(mg/k

g)


Gr.

(g/cc)

UEL

%

LE

L

%

Odor

threshold

(ppm)


d

Alcoho

l

32.04 NA -97.6 64.5 NA Stable Flammable Colorless 0.791

5

36.5

0

6.7

2

NA

4. Acetic Acid C2H4O2 Liqui

d

Punge

nt

60.05 39 16.6 118 3310 Stable Irritant to

skin, eye

Inhalation &

ingestion

Colorless 1.049 19.9 4 0.48

9. Fenbendazole

1. 4-Propyl

Sulphanyl

Benzene

1,2-Diamine

C6H8N2 Solid NA 108.14 NA 62 284 67.7 Stable Irritant to

skin, eye

Inhalation &

ingestion

NA NA NA NA NA

2. Cyano

Crabamate

C12H14N2

O2

NA NA 218.25 NA NA NA NA Stable Irritant to

skin, eye

Inhalation &

ingestion

NA NA NA NA NA


d

Alcoho

l

32.04 NA -97.6 64.5 NA Stable Flammable Colorless 0.791

5

36.5

0

6.7

2

NA

4. Acetic Acid C2H4O2 Liqui

d

Punge

nt

60.05 39 16.6 118 3310 Stable Irritant to

skin, eye

Inhalation &

ingestion

Colorless 1.049 19.9 4 0.48




Annexure 7 {V} On-site emergency Plan

CRYSTAL SURFACTANTS & CHEMICALS

Plot No B-31/2, MIDC Area, Paithan

District Aurangabad – 431107, Maharashtra, India

ON SITE EMERGENCY PLAN

YEAR 2018




OBJECTIVES OF THE PLAN

The object of the plan is to lay down steps to handle emergency situation that may arise due to

leakage/spillage, explosion and fire of the various chemicals, fuels in the plant, which may have any

adverse effect on employees and public at large is to minimize and normalcy is restored within shortest

possible time.

Emergency Response Plan (action plan) has been drawn to fix responsibility & actions to be taken by

various groups to meet & contain the emergency within shortest possible time & within minimum loss to

men, materials, machines & property.

It is responsibility of all individuals in their respective areas to ensure success of this plan.

of various personnel and agencies to control the emergencies This plan shall be circulated for

benefit/training of all individuals working in plant.

The plan is a basic document which provided information required at the time of emergencies, roles and

responsibilities.

Some of the important objectives of the plan are:

To control the emergency, localize it and if possible eliminate it.

To avoid confusion, panic and to handle the emergency with clear-cut actions.

To minimize loss of life and property to the plant as well as to the neighborhood.

To make head count and carry out rescue operations.

To treat the injured persons.

To preserve records and to take steps to prevent recurrence.

To restore normalcy




1 INTRODUCTION

1.1 Name and Address of the Person Furnishing the Information:

Mr. G.D.Agrawal : Occupier – Partner

Mr. A,V, Deshmukh : Partner

Reg. Office & Factory Crystal Surfactants & Chemicals

B-31/2, MIDC Area Paithan, Dist - Aurangabad – 431148.

Maharashtra

Tel. No. +91 9325213509.

1.2 Company Profile

Mr. G.D. Agrawal is the occupier and the Partner, Mr. A.V. Deshmukh is partner of the

company.

Company will run its activities in General Shift along with A Shift ( 07:00Hrs to 15:00

Hrs) & B Shift (15:00 Hrs Hrs to 23:00 Hrs.) shifts & C Shift (23:00 Hrs to 07:00 Hrs.).

Approximately 40 employees will be employed for running the plant.

Distribution of Employees required in proposed plant:

1) Company employees: 25 nos.

2) Contractor’s employees: 10 nos.

3) Security : 03 nos.

Occupier : Mr. G. D.Agrawal

Production & capacity details

No. Class Of Goods Proposed Installed

Capacity

Proposed

production in 1st

year

1 PARA CHLORO ORTHO NITRO ANILINE

(PCONA) 30 MT / Month 60 % of Capacity

2 5 Chloro 2 Nitro Aniline 20 MT / Month 60 % of Capacity

3 ORTHO CHLORO PARA NITRO ANILINE

(OCPNA) 20 MT / Month 60 % of Capacity

4 ORTHO NITRO ANILINE (ONA) 25 MT / Month 60 % of Capacity

5 4 NITRO METAPHENYLENE DIAMINE

(4NMPD) 2 MT / Month 60 % of Capacity

6 2 AMINO 3 CHLORO 5 (TRIFLUOROMETHYL

PYRIDINE) 12 MT / Month 60 % of Capacity

7 8 AMINO QUINALDINE 10 MT / Month 60 % of Capacity

8 FENBENDAZOLE 20 MT / Month 60 % of Capacity

9 ALBENDOZOL 20 MT / Month 60 % of Capacity




1.3 Key Management Persons

Sr.no Name Designation Cell

1 Mr.G.D.Agrawal Partner +91 9325213509

2 Mr.AV.Deshmukh Partner +91 9370097701

1.4 Brief Manufacturing Process

Process in General for all the above products:

27% Ammonia solution is prepared by passing NH3, at controlled flow from the NH3 cylinder through

the water in a tank, connected to the NH3 absorber. And 27 % ammonia solution is to be charged in an

autoclave. 2, 5-Dichloro Nitrobenzene is charged in the ammonia solution. Heat the resultant mixture to

160-170 °C and pressure developed of 30-32 kg/cm2 is maintained for 8 hrs. Cool the reaction mass and

vent pressure of ammonia through a tank where the ammonia is to be collected. The reaction mass is

cooled to ambient and then filtered on nutch filter. Mother liquor is collected. The wet product from nutch

filter is to be centrifuged and washed with plane water. The wet product is to be dried in tray dryer. Dry

product is to be unloaded and packed.

Albendazole

4-(Propylsulfanyl) benzene-1,2-diamine and ammonium salt of methyl-N-Cyano carbamate is to be

charged in methanol at ambient temperature. The reaction mass is to be stirred for 20-30 minutes and

acetic acid is added. Heat the reaction mass to reflux and temp is to be maintained at 50 to 60 deg C for

3-5 hrs. After completion of reflux cool the reaction mass to ambient temperature and centrifuged. The

product is to be washed with methanol and spin dried. The wet product unloaded from centrifuge is to be

dried in tray dryer to get dry Albendazole. Mother liquor is subjected to distillation to recover methanol.

Cool the concentrate reaction mass and filter to get Ammonium acetate which is sold to recycler. The

solvent residue is to be dried and recycled.

Fenbendazole:

Manufacturing Process: 4- Phenyl Sulphanyl benzene 1, 2 diamine and Cyano Carbamate are to be

charged in methanol and acetic acid in a stainless steel reactor and heated to reflux. The reflux is to be

maintained for 6-7 hrs and then cooled to ambient temperature. The reaction mass is to be centrifuged and

washed with methanol. The wet product is to be unloaded and dried in tray dryer.

Dry product as fenbendazole is to be unloaded and packed. The mother liquor is to be distilled out to get

recovered methanol which is recycled. The concentrates after distillation is to be cooled and centrifuge to

get solid ammonium acetate which is sold to recycler. Solvent residue of the mother liquor is to be

recycled to the next batch.




No Pressure Reaction or Run away or exothermic reaction.

Hazardous raw material solvent handled is Methanol and hazardous chemical is Acetic Acid.

No toxic and any other gas in generated during the reaction.

List of Raw Material Product Wise

Sr.

No. Name of Product Raw Materials

1 PARA CHLORO ORTHO

NITRO ANILINE (PCONA)

1. 2, 5 Di Chloro Nitro Benzene

2. Anhydrous Ammonia

2 5 Chloro 2 Nitro Aniline



3. Methanol

3 ORTHO CHLORO PARA

NITRO ANILINE (OCPNA)



4 ORTHO NITRO ANILINE

(ONA)

1. Ortho Nitro Chloro Benzene


5 4 NITRO METAPHENYLENE

DIAMINE (4NMPD)



6

2 AMINO 3 CHLORO 5

(TRIFLUOROMETHYL

PYRIDINE)

1. 2, 3 DiChloro 5 (Trifluromethyl) Pyridine


7 8 AMINO QUINALDINE 1. 8 Chloro Quinaldine


8 FENBENDAZOLE

1. 4-(Propylsulfanyl) Benzene-1, 2 -Diamine

2. Sodium Salt of Methyl –N-Cyanocarbamate

3. Acetic Acid

4. Methanol

9 ALBENDAZOLE

1. 4-(Propylsulfanyl) Benzene-1, 2 -Diamine

2. Ammonium Salt of Methyl –N-Cyanocarbamate

3. Acetic Acid

4. Methanol

1.5 LOCATION OF THE FACTORY

Crystal Surfactants & Chemicals is located at Plot No B-31/2, MIDC Area, Paithan, Dist-

Aurangabad. - 431107, Maharashtra. Nearest railway station Aurangabad is 40K.m. away from the

factory.

Medical Treatment is concerned which may be required during emergency and routine activities as well.

It will be rendered through Bhujbal Hospital, which is situated at 0.1 Km from factory premises. In case

of injury of moderate/major nature concerned injured person could be sent to nearby Hospital located at

Paithan10 Km and at 20 minutes distance by vehicle.

In case of Fire, Fire fighting services could be rendered by MIDC Paithan Fire Brigade which is situated

at 0.7 Km & Paithan Nagar Parishad Fire station at 10 Km.




1.6 SHIFTWISE (AVG) OF EMPLOYEES REQUIREDIN PROPOSED PLANT:

SHIFT&TIME MALE FEMALE TOTAL

A 07:00 to 15:00 Hrs.

10 00 10

B

15:00 to 23:00 Hrs. 10 00 10

C

23:00 to 07:00 Hrs. 10 00 10

GENERAL

9:30 to 18:00 Hrs. 10 00 10




2 KEY PERSONNEL OF THE ORGANISATION & RESPONSIBILITIES

Key Personnel Of The Organization & Responsibilities Assigned To Them In Case Details Of

Emergency Organization

Emergency organization is a part and parcel of a good On-Site and Off-Site emergency plan, without which

all resources, facilities etc. Even available with us, can not be put into services at a right time as time is the

key factor in tackling an emergency.

It is not possible to envisage and detail every action which should be taken in emergency and to harness the

basic elements of emergency preparedness such as gravity of emergency, communication of information, On-

Site action for process and emergency controls, mobilization of internal and external resources for fire and

toxicity control, warning people at right time, Evacuation, Medical Preparedness, Pollution control etc.

Emergency organization is set up specifying duties and responsibilities of all to make best use of all resources

and to avoid confusion while tackling the emergency.

On-Site emergency plan highlights the flow of information and co-relation among various action groups

within the factory.

Emergency organization and arrangements include:

Site Main Controller

Site Incident Controller

First Aid Team

Fire Fighting Team

Admin & Security

Emergency Control Centre (ECC)

Assembly Points

Responsibility will be automatically delegated in absence of concerned person/s in following

manner.

MAIN CONTROLLER:

Senior most person of Site will be the Site Main Controller for handling the emergency. The

Responsibility will be automatically delegated as per the following manner in absence of concerned

person.

Unit Head of Production site (G shift) Production Officer / Shift In charge (In Shift)




INCIDENT CONTROLLER:

The area in which emergency would occur, the senior most person / HOD will be the Incident Controller

for handling the emergency. The Responsibility will be automatically delegated as per the following

manner in absence of concerned person.

Production Manager ( G Shift) Senior most operator in shift (In Shift)

FIRST AID TEAM

There will be approx.6 employees in first aid Team. Employees will be selected from different shifts and

from all the departments. First Aid team shall be given an extensive training of handling of medical

emergency.

They have to play the role of first aider in an emergency.

FIRE FIGHTER TEAM

There will be approx.8 employees in Emergency Team. Employees will be selected from different shifts

and from all the departments.

Emergency team has been /shall be given an extensive training of handling of emergency including the

firefighting.

SECURITY TEAM

There will be adequate employees in Security Team.

RESPONSIBILITY DURING EMERGENCY:-

SITE MAIN CONTROLLER:

He will retain overall responsibility for the factory and its personnel. As soon as he is informed of the

emergency he shall proceed to the emergency control centre [Security Office] and meet the HR & Admin.

Manager. His duties shall be:

Assess the magnitude of the situation and decide if staff needs to be evacuated from their work

places.

Exercise direct operational control over areas other than those affected.

Maintain a continuous review of possible development and assess in consultation with Incident

Controller and other Key personnel as to whether shutting down of the plant or electricity or any

section of the plant and evacuation of persons is required.

Liaison with Senior Officials of Police, Fire Brigade, Directorate of Industrial Safety, MPCB

Officials and provide the advice on possible effects of the emergency on areas outside the factory

premises.

Control rehabilitation of affected areas on discontinuation of emergency.

Issue authorized statements to News media, and ensures that evidence is preserved for inquiries to

be conducted by statutory authorities.




To declare the emergency evacuation by blowing the siren and declaring the all clear position after

the emergency.

SITE INCIDENT CONTROLLER:

On receiving the first information of an emergency or incident he will rush to the scene of the occurrence

and take overall charge and report to Site Controller. On arrival he will assess the scale of emergency and

decide if major emergency exists or is likely and inform the Communication Officer accordingly.

Direct all operations within the affected areas with the priorities for safety of personnel and

minimum damage to the plant, property and minimum loss of materials.

In case of absence or Pending arrival of Site Controller, assume the duties of his post and, in

particular.

(a) Direct the shutting down and evacuation of plant and areas likely to be adversely affected by the

emergency.

(b) Ensure that all Key personnel and outside help are called in.

Provide advice and information to the Fire Fighting and First Aid squad & Security Officer and the

local fire service as and when they arrive.

Ensure that all non-essential workers / staff of the areas affected are evacuated to the appropriate

assembly points, and the areas are searched for casualties.

In the event of failure of electric supply and internal telephones, set up communication point and

establish contact with Emergency Control Centre.

Report on all significant developments to the P. & A manager.

Have regard to the need for preservation of evidence so as to facilitate any inquiry into the causes

and circumstances, which caused or escalated the emergency.

ROLE OFSECURITY STAFF

To announce through telephone or messengers to the Incident Controller and Site Controller that

incident has occurred in such and such zone.

On the sounding of the siren advises Fire Fighting and First Aid squad about the incident zone

Do not allow any vehicle or tanker inside the factory, except essential vehicles such as fire

tenders/foam tender, govt. agencies, mutual aid staff, ambulance etc.

Lead the external helping teams to reach the accident site.

Count and note down the fire fighters working in the operation.

To control traffic movements into the factory and ensuring that alternative transport is available

when need arises.

Do not allow any un-known / un-authorized person to enter in the premises.




Check about public in vicinity and ask them to evacuate.

Help fire squad team to evacuate non-essential personnel and non-technical staff.

FIRST-AID SQUAD:

Members of first-aid Squads will report to the Incident Controller on hearing of the alarm in day time.

They will administrate necessary First Aid to victims till Ambulance / Emergency Vehicle reaches the

site. The Ambulance / Emergency vehicle driver, if safe to do so, shall collect the emergency vehicle and

park nearest to the scene of the incident. First aider shall shift the victims in Ambulance / Emergency

vehicles & inform the incident controller that the Emergency Vehicle is leaving the site, giving the name

of the patient and destination i.e. hospital or and request the Site Main Controller / Site Incident

Controller to inform the destination (hospital, etc.) advising them about the casualties reaching there.

FIRE FIGHTING SQUAD

The duty Fire fighting Squad under the command of the Incident Controller shall be responsible for fire

fighting and rescue. On hearing the alarm, they shall proceed to the place of incident. The men at

security gate shall find out the location of the emergency and proceed to the site of the occurrence. At the

incident scene, a team members detailed for this purpose will check squad members against roll-call

sheet. At the site, all the squad members will respond to the advice and information given by the Incident

Controller On arrival of the local fire brigade, they will also assist in fire-fighting work with the advice of

the Incident Controller.

AMBULANCE / EMERGENCY VEHICLE DRIVER

Ambulance / Emergency vehicle driver is expected to do the following.

Immediately start vehicle and reach rescue squad assembly point (near security gate).

Take note of wind direction.

Take the injured to the hospital as directed.

GENERAL INSTRUCTIONS

Speed is essential.

Clarity of information and instructions to all concerned persons and authorities should be

maintained.

During emergency situations telephone systems are to be used only for essential communication to

combat the emergency.

In case of communication failure, send messengers by cycle or any other transport available.

Ensure that only trained persons are deputed for combating the situation and safety procedures are

followed strictly.

Ensure that MOCK DRILLs of the On-Site Emergency Plan are conducted regularly.




Adequate quantities of absorbents / materials for dangerous substances should be kept ready,

always, e.g. dry sand, dry earth, lime, blank granules etc.

EMERGENCY DO’S & DON’TS

Do’s Don’ts

Any One Notice An Emergency

Inform To Supervisor & Incident Controller

Immediately And Raise The Alarm

DO NOT Panic & Avoid Running All Over The

Place.

Get Back To Your Normal Work Place (If Safe) Or

Else Report To The Assembly Point

DO NOT Enter The Site Unless Informed, If You

Are Out Side & Emergency Siren Is Heard

Contractor Personnel

Stop Work In Safe Manner On Hearing Emergency

Siren

DO NOT Enter The Site Until It Is Cleared For The

Normal Work By Incident Controller

Assemble At The Assembly Point

Security

Keep The Main Gate Closed DO NOT Allow Visitors To Enter

Keep The Road Clear For The Movement Of Fire

Tenders & Other Emergency Vehicles

DO NOT Allow ANY VEHICLES OTHER THAN

Fire Tender & Ambulance

Control Traffic At Gates

Visitors

Leave The Place And Assemble At The Assembly

Point

DO NOT Enter The Site If Emergency Siren Is

Heard

All Other Employees On Site

On Hearing Emergency Siren Get Back To Work

Place (If Safe) And Get Instructions From The

Supervisor.

DO NOT Panic / Run Here And There

DO NOT Go To The Site Of An Incident Unless

Instructed Specifically By The Incident Controller.




CHAPTER 3 OUTSIDE ORGANISATIONS INVOLVED

A types of accident which are likely to occur in the factory are:

SPILLAGE OF LIQUIDS FROM THEIR CONTAINMENT

FIRE IN STORAGE AREA / PROCESS PLANT

FIRE IN ELECTRICAL INSTALLATION / TRANSFORMER

TOXIC GAS LEAK – AMMONIA

STRUCTURAL COLLAPSE

FLOOD

EARTH QUAKE

TERRORISM

SABOTAGE

FOOD POISONING

B The following outside organizations which will be required to help during the course of an

emergency mitigation.

Fire Brigade Paithan MIDC Fire Brigade

Fire Brigade Paithan Nagar Parishad Fire Brigade

Local Police Department Paithan MIDC Police Station

DISH Jt. Director DISH Aurangabad

M.P.C.B., Regional Officer M.P.C.B Aurangabad

Municipal Corporation, Paithan Municipal Corporation,

District Authorities District Authorities Aurangabad

Nearest Hospital Bhujbal Hospital




CHAPTER 4 LIASON BEWEEN THE ORGANISATIONS

Medical Treatment is concerned which may be required during emergency and routine activities as well,

it is rendered through Bhujbal Hospital, which is situated at 0.1 Km from factory premises. In case of

injury of moderate/major nature concerned injured person could be sent to nearby Hospital located at

Paithan10 Km and t 20 minutes distance by vehicle.

In case of Fire, Fire fighting services could be rendered by MIDC Paithan Fire Brigade which is situated

at 0.7 Km & Paithan Nagar Parishad Fire station at 10 Km.

The company will sign MOU with hospital & Ambulance services. The company will share the

information with MIDC Paithan Fire Brigade & Paithan Nagar Parishad Fire Brigade.

The following emergency facilities can be made available from neighboring industries during any kind of

emergency situation.

1. Ambulance Services.

2. Occupational Health Centre.

3. Doctors and Para Medical Staff.

4. Technical Staff to assist in emergency.

5. Neutralizing Compounds.

6. First-Aid equipment, Safety equipment, Self Contained Breathing Apparatus.

The company will share information with neighboring industries. The contact numbers of all Emergency

services & neighboring industries shall be displayed at ECC.




5 INFORMATION ON THE PRELIMANARY HAZARD ANALYSIS

A TYPES OF ACCIDENTS

1. Handling of Ammonia Cylinders and solution preparation, hazard is leakage of Ammonia through

piping, escape of unabsorbed Ammonia to the atmosphere while preparation of 27 % Ammonia

solution.

2. Leakage of Ammonia at High pressure through Autoclave.

3. Fire during unloading of Methanol tanker

B SYSTEM, ELEMENTS OR EVENTS THAT CAN LEAD TO MAJOR ACCIDENT IN THE

PROPOSED PLANT

EVENTS CAUSES EFFECT

Small Spill of Hazardous

Chemical.

Batch transfer hose / pipeline failure.

Gasket failure.

Pump gland leakage.

Localized.

Large Spill of Hazardous

Chemical.

Failure of bottom valve or nozzle of the

storage tank / spillage during Tanker

unloading

Localized.

Fire

Any spill of flammable chemical (Small or

large) may catch fire on finding source of

ignition. Methyl Alcohol, (Methanol) is a

flammable substances used in the factory.

Electric equipments like transformer, circuit

breakers & electric installations, etc. may

catch fire due to short circuiting.

Localized.

Explosion

Reaction parameters going wrong may cause

explosion in the reactor.

Failure of controls on Boiler may cause

explosion.

Air receiver of compressor may explode due

to improper maintenance and testing.

Local

Release of toxic gas.

Failure of gaskets or pipelines of toxic gas

may cause emission of toxic gas.

Ammonia will be a toxic gas used in the

factory

Local / Off-Site

potential.

Structural Collapse Earthquake, Poor Maintenance. Localized.

C HAZARDS

HAZARDS ARE SAME AS GIVEN IN TABLE A & B

D SAFETY RELEVANT COMPONENTS

1 Plant will be operated as per Standard Operating Procedure (SOP) after adequate training

2 There will be strict supervision by daily check of log sheets




3 Nobody will be authorized to change any procedure / SOP without permission of the owner &

Occupier of the factory. Procedure can be changed only after complete technical analysis.

4 After HAZOP study adequate instrumentation / alarms & interlocks will be installed & SOP will be

finalized after HAZOP study.

5 Adequate equipment & scrubbing system will be involved for absorption of Ammonia to keep air

concentration below TLV

6 Adequate warning system will be installed in case of any hazardous event.

7 Adequate PPE will be used & training will be given to plant personnel about use of PPEs & handling

of Emergency.




6 DETAILS ABOUT SITE

a ) LOCATION OF DANGEROUS SUBSTANCES:

Location of Storage of over ground tanks, underground tanks & Warehouse for hazardous

chemicals is given in the factory layout which is given in annexure.

Details about the quantity stored is given in the annexure

b) SEAT OF THE KEY PERSONNEL:

The seat of the key personnel will be located in the office building. This office building is located near the

main gate.

c) EMERGENCY CONTROL CENTRE / ROOM

Emergency Control Centre /will be located in the Security Main Gate. It is a focal point in case of any

major untoward incident. All the operations for mitigating the emergency will be directed from the

Emergency Control Room by the Site Controller. Emergency Control Room will be equipped with the

following items:

On-Site Emergency Plan.

List of key personnel with their telephone numbers

List of outside agencies such as Hospitals, Ambulances, Fire Brigades, Police Station, District

Authorities, MPCB officials, DISH officials with telephone numbers

Factory Layout Plan, Material Safety Data Sheets.

Note pads, pencils and register to record messages received and any instruction

Emergency lights / torches. Stretchers

Emergency protective wears such as SCBA, PVC suits, helmets, PVC hand gloves, Gas Masks,

gum boots, etc.




7 DESCRIPTIONS OF HAZARDOUS CHEMICALS AT PLANT

A Chemical (Quantities & toxicological) data:

Various types of hazardous chemicals are being used in the manufacturing operations in the factory.

These chemicals are flammable, toxic and/or corrosive. All these chemicals have potential to lead to

severe accident / incident such as fire, explosion, emission, etc.

Quantities and toxicological data of all these chemicals are given in the following table.

No. CHEMICAL

NFPA CODE TOXICITY

Nh Nf Nr LD 50 LC 50 TLV STEL

Mg/Kg - ppm ppm

1. 3, 4 DCNB 2 1 0 953 10 gm/m3/4H N/L N/L

2. 2, 4 DCNB 2 1 0 N/A N/A N/L N/L

3. ONCB - - - 144 3200 mg/m3/4Hr N/L N/L

4. Methanol 2 3 0 5628 - 200 250

5. Anhydrous Ammonia 3 1 0 - 7338 ppm / 1 Hr 25 35

6. 2, 5 DCNB 2 1 0 1000 N/L N/L N/L

7 2, 3 Di Chloro 5

trifluro Methyl Piridine 2 0 0 N/L N/L N/L N/L

8 8 Chloro Quinaldine 1 1 1 N/A N/A N/A N/A

9 4 Chloro 2 Nitro

Aniline 4 1 0 400 N/A 2 5

10 5 Chloro 2 Nitro

Aniline 4 1 0 N/L N/L N/L N/L

11 2 Chloro 4 Nitro

Aniline - - - 1250 - N/L N/L

12 2 Nitro Aniline 3 0 0 1600 2529 mg/ m3/4Hr 2 20

13 2 Amino 3 Chloro 5 Tri

Floro Methyl Piridine 2 0 0 - - N/L N/L

14 4 Nitro Meta phenyline

Dimine - - - N/A N/A N/A N/A

NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CODE:

Nh : Health

Nf : Flammability

Nr : Reactivity

Other Abbreviations

N/A - (Data) Not available

N/L - Not Listed




8 LIKELY DANGERS TO THE PLANT

The Causes for accidents could be as follows:

I) Disaster due to natural calamities such as:

- Flood

- Earth quake

- Storm/cyclone

II) Disaster due to external factors such as:

- Sabotage

- Civil Riots

III) Disaster due to Emergency on account of Plant & Process Hazards

- Heavy spillage of Flammable, Toxic chemical (Methyl Alcohol)

- Fire of Flammable (Methyl Alcohol)

- Uncontrolled Fire in Boiler, Boiler Fuel storage area

- Toxic Gas Release (Release of Ammonia gas)

- Electrical Fire

- All other fires

- Contact of Incompatible chemicals

IV) Disasters due to other Probable factors such as::

- Food poisoning

- Honeybee Attack

- Snake Bite

- Medical Emergency to any Employee




9 ENUMERATE EFFECTS

9.1 Stress and Strain during Normal Operation:

Like all chemical manufacturing plants, lots of operations are being carried out in the factory. This

includes unloading of Raw Materials, transfer of these raw materials from storage tanks to reactors,

Amminolysis (Amination), cooling, filtration, drying, distillation etc.

Some kinds of stress and strain are always associated with these normal manufacturing operations of the

chemical plant. Unexpected incidents may occur during these operations either due to hazardous

chemicals, wrong operations or improper maintenance. The following incidents are considered:

1. Continuous release of chemical due to failure of transfer lines.

2. Overflow of chemicals.

3. Pressurization or failure of gaskets.

4. Failure of reactor / storage tank.

9.2 Fire and Explosion inside the Plant and Effect If Any, of Fire and Explosion Outside:

MAXIMUM CREDIBLE LOSS SCENARIO (MCLS)

Maximum Credible Loss Scenario (MCLS) is one of the techniques used to access the events in realistic

and practical way. An MCLS can be described as the most credible incident or as an incident with a

maximum damage distance, which is still believed to be probable. The analysis does not include

quantification of the risk involved in the incident and probability of occurrence of an incident.

Worst Case Scenario - Catastrophic failure of storage tank and continuous release of gas into the

atmosphere and leading to disastrous situation is considered. But the probability of such event is very

low

QRA for Methanol leakage

Road Tanker assumed to be of same volume as that of the storage tank and diameter of 2 meters and

length of 6.4 M

QRA has been carried out for three scenarios under the following conditions:

ATMOSPHERIC DATA: (MANUAL INPUT OF DATA)

Wind: 4 meters/second from NW at 3 meters

Ground Roughness: open country Cloud Cover: 0 tenths

Air Temperature: 35° C Stability Class: D

No Inversion Height Relative Humidity: 5%




Scenario 1: There is sudden leakage and ignition after release of 500 liters Methanol, before ignition and

there is pool fire

Scenario 2: The leakage of Methanol through 5 mm hole in the unloading hose, during tanker unloading

and there is pool fire

Scenario 3 (Worst Case scenario): There is total failure of unloading hose of 100 mm diameter (hose

getting disconnected), when tanker is 85 % full and there is fire

Threat zones predicted are:

Table

Scenario Amount

Released/burned

Flame

Length

10.0 kW/(sq m) =

potentially lethal

within 60 sec)

5.0 kW/(sq m) =

2nd degree

burns within 60

sec

2.0 kW/(sq m) =

pain within 60 sec

Scenario

1

390 kgs 4 M Less than 10

meters

Less than 10

meters

Less than 10

meters

Scenario

2

50.9 Kgs in 50

min

1 M Less than 10

meters

Less than 10

meters

Less than 10

meters

Scenario

3

12,627 Kgs

kilograms in 50

min

10 M 23 M 28 M 37 M

Consequences of Methyl Alcohol Spill:

It is a flammable liquid and its spillage / leakage may cause fire and / or explosion.

It poses moderate explosion hazard and dangerous fire hazard when exposed to heat, sparks or flames.

Vapours can flow along surface to distant ignition source and flash back. It is very sensitive to static

discharge.

During spill recovery and disposal, exposure to emergency responders is likely. Care needs to be taken in

this regard.

QRA FOR AMMONIA LEAKAGE:

Quantitative Risk analysis was carried out for following conditions:

ATMOSPHERIC DATA: (MANUAL INPUT OF DATA)

Wind: 4 meters/second from NW at 3 meters

Ground Roughness: open country Cloud Cover: 0 tenths

Air Temperature: 35° C Stability Class: D

No Inversion Height Relative Humidity: 5%




For following three Scenarios:

1. Scenario 1 Worst case Scenario: Failure of Pressure reducing Control and Gas flow rate through

pipe to the tank with water for 1 hr. without absorption.

2. Scenario 2: Same as above predicting distance covered till IDLH value

3. Scenario 3: MCS Leakage through 5 mm hole in piping with 6 atm ammonia pressure for a

minute

TABLE

Scenario

No

Amount

of NH3

released

(300 ppm =

IDLH)

1100 ppm =

AEGL-3 (60

min)

(160 ppm

AEGL-2 (60

min))

(30 ppm

AEGL-1 (60

min)

Scenario 1 ---- 79 M 208 M 523 M

Scenario 2 876 kgs for 1 hr 149 M 208 M 523 M

Scenario 3 3.01 Gms in 1

min

Less than 10 m Less than 10 m Less than 10 m




10 DETAILS OF SAFETY SYSTEMS

10.1 Warning Alarm:

Factory shall be provided with an Emergency Siren to alert people in and around the factory and also to

indicate to all such employees who are not assigned any job in the Emergency Control Plan, together at

the assembly point.

siren shall be installed in the factory premises as mentioned in the site plan. Switch is to be kept in the

security cabin. Security will blow the siren only in case of emergency that too permitted / instructed by

Authority mentioned in below table.

Emergency Siren:

Siren will be blown in the following style to give wailing sound so that everybody present in and around

the factory will come to know that something has happened inside the factory:

15 sec High 5 Sec Low for 2 Minutes

All Clear Signal:

All clear signal will be given by blowing siren continuously for 1 Minute.

Testing of Emergency Siren will be carried out during Mock Drills and on any other suitable days.

Sr. SIRENS INDICATES AUTHORITY

1. 15 sec High 5 Sec Low for 2

Minutes

On Site Emergency (Alert) Incident Controller

2. 1 Minute Continuous Emergency Controlled

(All Clear)

Site Controller

Testing of emergency siren shall be performed every week on any fixed day. Mock Drills shall be

conducted at least once in six months which is also a statutory requirement. Till all employees get familiar

with the On Site Emergency Plan, it is advised to conduct Mock Drills once in three months.

10.2 Assembly Point:

The management has identified Main Gate as Assembly point, location of which will be beyond the

distances predicted in the results given above. In case of an EMERGENCY the employees should

evacuate from emergency exits and assemble on the Assembly Points. Visitors are required to be directed

by their host.

All personnel on site will assemble in case of an emergency and the headcount will be conducted by the

security supervisor at the main gate.

Assembly point –In front of Main Gate




10.3 Reliable Measuring Instrument, Control Units & Servicing Of Such Equipment

Details regarding 10.3 have already been covered in earlier part of the report.

10.4 Rehearsal / Mock Drill:

In disaster management, time is very important factor. Initial few minutes are very critical and timely

action only can contain the emergency.

For persons to perform their assigned roles quickly, it is essential that each individual should be made

aware of emergency procedures and their roles through proper training.

The success of any plan depends on planned & unplanned Mock Drills. It is necessary to test through

rehearsals, which will impart necessary expertise to every individual to act quickly in case of a real

emergency situation. Rehearsals also help in identifying the deficiencies in the procedures /

implementations and likely difficulties that may be encountered during implementations. Besides this it is

also a statutory requirement to conduct Mock Drills of the On-Site Emergency Plan once in six months.

Hence rehearsals of the On-Site Emergency Plan shall be undertaken periodically & shall be

documented. Documentation shall consist of observations Response Time & Recommendations.

Mock Drill Procedure

Inform all the employees about the mock Drill to be conducted.

Depute the Performance Observers (Inside / Outside ) who are not involved in exercise.

Incident observer shall communicate to Emergency Control Centre (ECC) / Security by phone or

verbally.

Security will communicate to Site Main Controller (SMC) & Site Incident Controller (SIC)

The Site Main Controller will communicate with various teams with existing communication

system

First Aid / Fire Fighting Team members will move to the incident location & get in action to

control the situation.

Site Main controller will take information from Site Incident controller. In case Type II

Emergency SMC will instruct the Security to raise the alarm.

After controlling the situation All Clear Signal will be raised

The action, Co-ordinations of all teams & Response Time shall be observed & short comings are

noted for updating the plan.




10.5 Continuous Surveillance Of Operations

Details regarding 10.5 have already been covered in earlier part of the report.

10.6 Maintenance & Repair Work According To The Generally Recognized Rules & Good

Engineering Practices

Work permit system is implemented for doing HOT work , working at height , confined space entry etc.

Work order system is implemented for carrying out day to day maintenance work

10.7 Categories of Emergencies

Type I

The type of Emergencies which are restricted to one section of the only & which can be controlled by the

manpower & facilities in the section.

Type II

The Type of Emergencies though originating from the section which cannot be controlled by the facilities

available in section. These may require shutting down the plant & may require activation of On Site

Emergency Plan and/ or total evacuation. However the magnitude is restricted to factory premises only.

Off Site Emergency

The Type of Emergency though originated from the factory but its effects felt outside the factory

premises. The situation thus generated is called Off Site Emergency. This will need Coordination with

local bodies.

10.8 Emergency Evacuation:

Various kinds of emergencies that can warrant limited or total plant area evacuation are:

Severe Fire, Threatening calls, Civil Unrest or Curfew Earthquake , Flood.

The Site Main Controller shall use his judgment and discretion to decide, and as far as reasonably

practicable consult with the Management Leaderships, to effect a partial or total evacuation of personnel

from the site. If the incident is likely to affect people working in the plant, the Site Controller will initiate

evacuation. Evacuation of employees and contractors shall be initiated by alarm and then advising

appropriately, specific evacuation information and instructions. Evacuation routine shall be cross-wind and

up-wind relative to the gas cloud.

The following is a procedure for the evacuation:

Non essential workmen will be evacuated to the Assembly Point.

People (Employees and Contract Workers) from the affected site will be evacuated.




The evacuation will be along the escape route leading to Assembly Point.

Ensure proper head count

Maximum number of persons at any given time can be about 30. So evacuation arrangement for the same

number of people will be required in worst possible scenario.

.




11 DETAILS OF FACILITY

11.1 COMMUNICATION FACILITIES:

IMPORTANT TELEPHONE NUMBERS:

ORGANISATION CONTACT NO

FIRE BRIGADE:

Paithan MIDC Fire Brigade 02431-233001

Paithan Nagar Panchayat Fire Brigade 101

POLICE:

Police Station – Paithan 02431-232113

HOSPITALS / AMBULANCE SERVICES:

Bhujbal Hospital MIDC 9096068554

Ganesh Hospital MIDC 02431-232444

Shraddha Hospital, Paithan 02431-224052

Civil Hospital 02431-223037

Ambulance 108

Dattaji Bhale Blood Bank, Aurangabad 0240-2352371

ELECTRIC SUPPLY:

M.S.E.B. Paithan 02431-232039

M.I.D.C.:

M.I.D.C. Office Paithan 02434-232080

GOVERNMENT AUTHORITIES:

District Collector, Aurangabad 0240-2324800

Tahasildar Office Paithan 02431-223051

DISH Office, Aurangabad

M.P.C.B. Office, Aurangabad 0240-2473461




LIST OF TELEPHONE NUMBERS (INTERNAL):

Sr.

No. Name Contact No.

1 Mr. G.D. Agrawal +91 9422245677

2 Mr. A.V. Deshmukh +91 9403697323

DETAILS OF FIRE FIGHTING & OTHER FACILITIES:

Adequate fire protection facilities shall been provided in the plant.

FIRE EXTINGUISHERS

The following are the details of fire extinguishers with capacity and their locations:

SR. No. Area ABC

TYPE

CO2

TYPE

Foam

TYPE Total

1 Security Cabin 1 1 1 3

2 Parking 1 - 1 2

3 Green Belt - - - 0

4 Finished Good Stores 1 - 1 2

5 Office Building 2 1 - 3

6 Fire Hydrant Pump 1 - - 1

7 Transformer 1 1 - 2

8 Electric House 1 1 - 2

9 Canteen 1 - - 1

10 Toilet - - - 0

11 Main Plant Building 4 - 2 6

12 Cooling Tower - - - 0

13 Raw Material WH 1 - 1 2

14 Boiler House 2 - - 2

15 E.T.P. 1 - - 1

16 Solid fuel stores 1 - - 1

17 Effluent Storage - - - 0

18 UG solvent Tank 1 - 2 3

19 Solid Waste Stores 1 - - 1

20 UG water tank - - - 0




FIRE HYDRANT SYSTEM-

The Factory shall provide Hydrant System to provide fire protection to all plants storage tank farm

area, stores, utilities, Laboratory &office block.

The details of the proposed Fire Fighting system are as follows-

1. Water Storage capacity - 2.5 lakh lit.

2. Emergency water capacity- 1.25 lakh lit.

3.1 Electrical operated Jockey pump - 10HP / Head 70mtr / flow rate 10.8 M3/hr.

3.2 Electrical operated Main pump - 40HP/ Head 70mtr/ flow rate 54.0 M3/hr.

3.3 Diesel Engine operated pump - 40HP/ Head 70mtr/ flow rate 54.0 M3/hr.

4. Power back up DG Set= 65 kVA

5. Number of Employees Trained for firefighting- 6 no’s

6. D.G set - 125 KVA.

7. AFFF (Aqueous film forming unit)-200lit cap- 03 No

8. Fire Nozzles - 2 Nos

9. Foam Nozzles - 1 Nos

10. Fire Proximate Suit- 1 no’s

11. Ammonia Mask

12 SCABA sets = 1 nos

Details of location shall be fixed during design

Training shall be imparted to employees for fire fighting and handling of chemical as well emergency

handling.




Annexure 7 {VI}: Health Management Plan

For Crystal Surfactants

Health Management plan for Methanol and Ammonia and ONCB

Following solvents and chemicals used can have effect on workers’ health based upon NFPA

values, MSDS and available literature. Chemicals which have Nh values more than or equal to 3

are considered as chemicals which can affect workers’ health on long term exposure. The only

solvent used is Methanol and is stored in over ground tank:

NFPA rating for these solvents

Information about toxic properties of Methanol

Boiling Point: 64.7 deg C @ 760.00mm Hg

TWA =250 ppm

TLV=200 ppm

Potential Health Effects

Eye:

Produces irritation, characterized by a burning sensation, redness, tearing, inflammation and

possible corneal injury. May cause painful sensitization to light.

Skin:

Causes moderate skin irritation. May be absorbed through the skin in harmful amounts.

Prolonged and/or repeated contact may cause defatting of the skin and dermatitis.

Ingestion:

May be fatal or cause blindness if swallowed. May cause gastrointestinal irritation with nausea,

vomiting and diarrhea. May cause systemic toxicity with acidosis. May cause central nervous

system depression, characterized by excitement, followed by headache, dizziness, drowsiness,

and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due

to respiratory failure. May cause cardiopulmonary system effects.

Sr. No. Chemical Max. qty

required per Month

Maximum qty

stored

Nf Nh Nr

2 Methanol 10 Cu. M 20 Cu. M 3 2 0




Inhalation:

Harmful if inhaled. May cause adverse central nervous system effects including headache,

convulsions, and possible death. May cause visual impairment and possible permanent blindness.

Causes irritation of the mucous membrane.

According to this information available and other detailed medical information with

Occupational Health certified medical fractioned, the periodic medical tests will be finalized to

asses and control the adverse effects, in addition to all the engineering safety systems to be

installed, like Hydrocarbon detectors, tank will be provided with overhead condensers with

chilled water, transferring Methanol with mechanical seal pumps. And with BP of 64 deg C, it is

not likely to contribute to any VOCs spite.

Chronic:

1. Prolonged or repeated skin contact may cause dermatitis.

2. Chronic exposure may cause reproductive disorders and teratogenic effects.

3. Prolonged exposure may cause liver, kidney, and heart damage.

Solvents are likely to be present in air as VOC. Chemicals which can contribute to VOC. The

detailed measures which will be taken for keeping VOC from solvent storage have already been

submitted.

Health Management Plan for Solvents:

Depending on their physical characteristics, certain chemicals have an affinity for specific target

organs or body systems. Once deposited, they cause impaired functioning of the normal

metabolic processes, which if permanent, ultimately results in disease.

Following are the steps to prevent adverse effect on workers’ health.

1. Environmental monitoring and control: Measures the airborne concentration of the

chemical in the workplace environment and control concentration less than Permissible

levels. The plan has already been given

2. Medical surveillance: Aims to identify workers with early adverse health effects, which

are likely to be reversible or do not progress to significant functional impairment when

exposure conditions are improved. By carrying out regular medical examination of workers,

specifically medical tests which are aimed for checking the effects of chemicals which

affect target organs. These will be decided in consultation with qualified medical

practitioner




3. Following table shows effects of solvent, of these solvents, toluene will only be used.

4. Detailed stepwise plan for ASSESSMENT AND MONITORING OF EXPOSURE TO

CHEMICAL HAZARDS is given in Annexure 1.

Other Hazardous Chemicals Stored in Bulk:

Table

Toxic properties of ONCB:

Acute toxicity, Oral - Category 4 - Acute Tox. 4

Hazardous: Toxic on skin contact. Repeated exposure and absorption through skin can cause

significant harm.

Remove clothing, wash with plenty water soap and warm water. Call Doctor immediately.

Do not drink alcohol, smoke and eat while handling this product.

Proper PPES must be used.

M. P= 30-32 deg C

B. P. =246 deg C.

Since it is high boiling compound there will be no VOC increase due to this chemical

2,4-Dichloro-nitrobenzene

Boiling point 258 °C (496 °F)

NFPA Rating

Health Hazard: 2 Fire : 1 Reactivity Hazard : 0

Other raw materials handled are also solid and less toxic with Nh= < 2

Sr.

No.

Chemical Maximum

qty stored

MT/Cu.

M

Size of tank

in Diameter

and Height

Number

Tanks

Clear

Distance

between

each tank

NFPA

rating

2 2, 4

DCNB 23000 Kg.

DIA =2.5 M

Height= 4M 1 2 Meter

Nh=2 Nf=1

3 ONCB 23000 Kg. DIA =2.5 M

Height= 4M 1 2 Meter

Nh=3,

Nh=1,Nr=1




Gases Handled:

Ammonia and Hydrogen

Out of these only Ammonia is irritant and toxic. Detailed Annexure is enclosed here with

regarding handling precautions, toxic properties and medical consequences. This is enclosed as

an Annexure 2.

It is clear that exposures as high as more than 2000 to 5000 ppm are of serious consequence.

TLV limit is 35 ppm.

For Medical health management plan following is suggested:


Pre-placement Examinations

Most employees may be assigned to processes in which the use of anhydrous ammonia is

carefully controlled. Under some circumstances the physician carrying out pre-placement







exposure to ammonia.

Three types of effects on the human body given in the table are:

1. Acute

2. Chronic

3. Allergic

Acute:

The effect is exerted immediately or within a few hours of exposure (implies rapid accumulation

at the target organ site; the severity of the reaction is directly proportional to the exposure dose

rate) e.g. chemical asphyxiants (cyanide, carbon monoxide, hydrogen sulphide, nitrogen dioxide),

irritants (chlorine, sulphur dioxide, ammonia) and corrosives (acids).

Chronic:

The effect is exerted after months or years of exposure (implies gradual accumulation at the

target organ site; severity is directly proportional to the exposure dose rate) e.g. heavy metallic




toxins such as lead. Certain substances demonstrate a delayed effect following a prolonged

latency period (can occur with prolonged exposure or transient exposure) e.g. carcinogens such

as asbestos.

Allergenic:

The effect is exerted through the immune system (multiple initial doses result in sensitization

with the accumulation of antibodies; subsequent low-level exposure triggers a response;

pronounced individual susceptibility) e.g. respiratory and skin sensitizers (chrome, nickel,

platinum salts).

Annexure 1

Assessment and Monitoring of Exposure to Chemical Hazards

Assessment and monitoring of exposure to hazardous chemical substances is an important aspect

of initial and ongoing risk assessment and control. The primary prevention strategy should

always be to prevent exposure to agents associated with toxic effects. When it is not possible to

prevent such exposures, then the appropriate strategy is to limit exposure and minimise the

possibility of adverse health effects. Exposure monitoring encompasses two basic techniques viz.

environmental air monitoring (occupational hygiene) and biological monitoring.

Environmental and biological monitoring are ways of investigating different problems and

should be seen as complementary procedures. A practical approach in setting up an exposure

monitoring programme for hazardous chemical substances is outlined in Table 3.

Table 3. A stepwise approach to developing an exposure monitoring programme for

hazardous chemical substances

Step 1 What is the nature of the job? - outline the various activities.

Step 2 Identify the hazardous chemicals associated with exposure to chemicals in the various

activities.

Step 3 Identify the potential routes of exposure to the particular hazardous chemical

substance.

Steps 1-3 are part of the risk assessment process. If a potential health risk is identified, proceed to Step 4.

Step 4 If the exposure route is mainly airborne, proceed to environmental monitoring (EM).

Step 5 If the exposure route is mainly through non-inhalation routes (skin, ingestion) or if

major reliance on personal protective equipment, proceed to biological monitoring




(BM).

Step 6 Develop a sampling strategy for EM and/or BM based on exposure zone

characterisation (groups of workers performing similar activities). For EM, it is

preferable to do personal sampling. The timing of the sampling strategy for BM is

based on the biological half-life of the substance in the sample medium (blood, urine)

concerned. Conduct sampling in a standardised manner. Ensure that samples are

appropriately stored after collection.

Step 7 Identify the appropriate analytical test that has a high degree of validity, and a quality-

certified laboratory that will conduct the analysis of samples.

Step 8 Decide beforehand the criteria to be used to define an abnormal test result using the

DOL/ ACGIH/NIOSH OELs for airborne substances or Department of Labour

(DOL)/ACGIH BEIs for BM samples.

Step 9 Outline the process of referral to confirm abnormal result in the case of BM, removal

of the person from exposure; determining the presence of adverse health effects

through medical surveillance and/or diagnostic medical assessment; initiating treatment

in instances of acute toxicity; and where appropriate submitting a workers'

compensation claim (COIDA) should there be abnormal results.

Step 10 Outline the procedure for notification of employer, worker (ongoing worker

notification procedures) and enforcement agency (notify incident to DOL) as to the

outcome of the exposure assessment.

Step 11 Ensure input of the information obtained in this process into systems and procedures in

assessing the efficacy and improvement of existing control measures such as

engineering controls, work procedures, education and training.

Step 12 Ensure evaluation and audit of the programme on a regular basis.

Annexure 2

Measures for handling Ammonia

"Ammonia is a natural constituent of the atmosphere but exists in concentrations below the level

which is hazardous to humans, animals, plants or materials.

High concentrations of ammonia gas are corrosive to mucous membranes; can cause damage to

the eye, throat and upper respiratory tract; and can produce residual damage and even death to

humans and animals.

High concentrations are also toxic to most plant life and have corrosive effects on materials."

Concentration in Air Effect

20 µg/m (0.027 ppm)3 - Average atmospheric background concentration.

30 - 36,000 µg/m3 (.04 -

50 ppm)

- Odor threshold.

1.44 mg/m3 (2.0 ppm) A limit of 0.50 ppm may be desirable if a surrounding buffer is not




Max one hour conc.

limit

possible.

18 mg/m3

(25 ppm)

threshold limit value to which it is believed workers may be exposed

continuously for 8 hours without adverse effects3

280 - 490 mg/m3 (390 -

680 ppm)

- concentration range where NH3 gas produces eye, nose and throat

irritation and may injure respiratory mucous.

360 mg/m3 (500 ppm)

- suggested maximum short-term atmospheric concentration due to

uncontrolled release of ammonia resulting from equipment failure,

safety valves discharging or any other single release.

The flammable limits of ammonia are from 15% to 25% by volume in air; however, ammonia is

difficult to ignite in spite of this. Gaseous ammonia will dissolve readily in water at a rate of

approximately 700 volumes/volume of water.

Melting point: -77.4°C Boiling point: -33.4°C Density: 0.677 g per c.c.

* Due to the chilling effect of evaporation, ammonia vapor resulting from a large spill may move

down-wind as a visible cloud some distance before dissipating or rising.

Vapour

Concentration(ppm)

General

Effect

Exposure Period

(1) (2) (3)

1-5 Odour

detectable by

most person

Prolonged repeated exposure produces no injury

25 No adverse

effect for

average

worker

Maximum allowable concentration

for 8 hour working exposure

35 No adverse

effect for

erage worker

Exposure should not be longer than

15 minutes and should not occur more than four times

per day

400 to 700 Nose and

throat

irritation

Eye irritation

with tearing

Infrequent short (1/2 hour) exposure ordinarily produces

no serious effect

2 000 to 3 000 Conculsive

coughing

Severe eye

irritation

No permissible exposure. May be fatal after short

exposure




Vapour

Concentration(ppm)

General

Effect

Exposure Period

(1) (2) (3)

5 000 to 10 000 Respirator

spasm. Rapid

asphyxia

No permissible exposure. Rapidly fatal

Liquid anhydrous ammonia produces skin burn on contact.

i. ACGIH Short Term Exposure Limit (STEL) – 35 ppm

NOTES

ACGIH (TLV-TWA) – The TWA concentration for a conventional 8 h work day and 40 h

work week, to which it is believed that nearly all workers may be repeatedly exposed, day

after day for lifetime without adverse effect.

ACGIH (TLV-STEL) indicates Short Term Exposure Limit. A 15 minutes TWA exposure

that should not be exceeded at any time during a work day, even if the 8 h TWA is within the

TLV-TWA. Exposures above the TLV-TWA up to the TLV-STEL should be less than four

times per day, and there should be at least 60 minutes between successive exposures in this

range.’

LABELLING

Consignments or smaller containers shall carry an identifying label or stencil depicting the

symbol given in Fig. 2 of IS 1260 (Part 1) and the following information shall also be given

in the lower half of the label.

AMMONIA, ANHYDROUS

WARNING ! Hazardous liquid and gas under pressure

Liquid Causes Burns

Gas Extremely Irritating

Do not breathe gas.

Do not get in eyes, on skin, on clothing.

In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes.

Call a physician at once in case of burns, especially to the eyes, nose and throat, or if the patient

is unconscious.




Keep cylinders away from heat and sun. Do not store with flammable or explosive materials.

Never drop cylinders.

Be sure connections are tight. Use no oil or lubricants on valves.

Never refill cylinders.

Keep the cylinders up-right (vertical) with its valve at the top and secure it properly.

PREVENTIVE MEASURES

Employee Education and Training

Safety in handling ammonia depends, to a great extent, upon the effectiveness of employee

education, proper safety instructions, intelligent supervision and the use of safe equipment.

The education and training of employees to work safely and to use the personal protective

equipment or other safeguards provided for them is the responsibility of supervision. Workers

should be thoroughly informed of the hazards that may result from improper handling of

ammonia. Each employees should be fully informed as to what to do in an emergency.

Employee education and training should include the following:

a. Instruction and periodic drill or quiz regarding the locations, purpose and use of

respiratory protective devices and other personal protective equipment and action to be

taken during emergency.

b. Instruction and periodic drill or quiz regarding the locations of safety showers, eye baths,

bubbler drenching fountains, or the closest source of water for use in emergencies.

c. Instructions to avoid all unnecessary inhalation of vapours of ammonia and all direct

contact with the liquid.

d. Instruction and periodic drill or quiz regarding the location, purpose and the use of

emergency fire fighting equipment. Instruction to strictly prohibit smoking in storage

area.

e. Instructions to report to the proper authority all equipment failures and any unusual odour

of ammonia.

Personal Hygiene

Emergency showers and eye baths should be placed at convenient locations wherever anhydrous

ammonia is used in quantity. Every employee should understand that direct contact with the

chemical requires the instant application of large amounts of water to the affected area. These

safety showers should be tested periodically for their proper functioning.




Skin, eye and respiratory protective equipment will often be necessary.


Pre-placement Examinations

Most employees may be assigned to processes in which the use of anhydrous ammonia is

carefully controlled. Under some circumstances the physician carrying out preplacement







exposure to ammonia.

Personal Protective Equipment

Availability and Use

While personal protective equipment is not an adequate substitute for good, safe working

conditions, adequate ventilation, and intelligent conduct on the part of employees working with

ammonia, it is, in many instances, the only practical means of protecting the worker, particularly

in emergency situations. One should keep firmly in mind that personal protective equipment

protects only the worker wearing it, and other unprotected workers in the area may be exposed to

danger.

The correct usage of personal protective equipment requires the education of the workers in

proper employment of the equipment available to him. Under conditions which are sufficiently

hazardous to require personal protective equipment, its use should be supervised and the type of

protective equipment selected should be capable of control over any potential hazards.

Eye Protection

Gas-tight chemical goggles or full face mask should be worn when handling ammonia where

leaks or spills may occur. Water wash or water sprays should be available in areas where

ammonia leaks, spills or splashes may be encountered.

Respiratory Protection

Severe exposure to ammonia may occur in tanks during equipment cleaning and repairs, when

decontaminating areas following spills, or in case of failure of piping or equipment. Employees




who may be subject to such exposures should be provide with proper respiratory protection and

trained in its use and care. Available types are described below.

NOTE– Respiratory protective equipment shall be carefully maintained, inspected, cleaned and

sterilized at regular intervals, and always before and after use by another person.

Self-contained breathing apparatus

It permits the wearer to carry a supply of oxygen or air compressed in the cylinder (the self-

generating type produces oxygen chemically) and allows considerable mobility. The length of

time a self-contained breathing apparatus provides protection varies according to the amount of

air, oxygen or regenerating material carried.

Compressed oxygen should not be used where there is danger of contact with flammable liquids

or vapours, especially in confined spaces such as tanks or pits. A special type of self-contained

breathing apparatus may be used which is provided with a small cylinder of compressed air for

escape but is supplied with air through an air line for normal work purposes.

Positive pressure hose masks

These are supplied by blowers and require no internal lubrication. The wearer shall be able to use

the same route for exit as for entrance and shall take precautions to keep the hose line free of

entanglement. The air blower shall be placed in an area free of contaminants.

Air-line masks

These are supplied with clean compressed air, are suitable for use only where conditions will

permit safe escape in case of failure of the compressed air supply. These masks are usually

supplied with air piped to the area from a compressor. It is extremely important that the air

supply is taken from a safe source, and that is not contaminated by oil decomposition from

inadequate cooling at the compressor. The safer method is to use a separate compressor of the

type not requiring internal lubrication. Pressure reducing and relief valves as well as suitable

traps and filters, shall be installed at all mask stations.

8.4.3.4 Chemical cartridge respirators

These may be used to avoid inhaling disagreeable but relatively harmless concentrations of

ammonia vapour. These respirators, however, are not recommended for protection where toxic

quantities of ammonia may be encountered. While using cartridge care must be taken to check

the oxygen content in the area. It should be more than 16.5 percent (v/v) and chemical cartridges

whose life is over, must not be available for use




CAUTION : Filter type respirators do not offer protection against gases and are unsuitable

for use when working with ammonia.

8.4.4 Head Protection

Where there is no danger from falling objects, safety or ‘hard’ hats are considered unnecessary,

soft, brimmed hat or caps should be worn to give protection against liquid leaks and splashes.

8.4.5 Foot Protection

Rubber boots or safety-toed rubber booties should be used as required. Rubber boots should be

thoroughly cleaned and ventilated after contamination.

8.4.6 Body, Skin and Hand Protection

Rubber or other protective gloves should be worn where any danger of contact with ammonia

may occur. Impermeable wears may also be used.

8.4.6.1

For the protection of the skin, cotton shirt, trousers and underwear should be worn (cotton resists

alkalis better than wool).

8.4.6.2

In case of emergency, a rubber apron or rubber coat may provide sufficient protection, but in

areas of high ammonia concentration a complete gas suit should be worn.

8.4.6.3

For optimum protection of the body, the collar should be kept buttoned, glove (gauntlets) should

be tucked inside of sleeves, and trouser legs should be left outside of boots.

It is also suggested to have a valcro type tight fitting strap to have the legs and arm areas tight

enough to avoid ammonia gas entry into the protective suit.

8.4.6.4

In area of high ammonia concentration, ammonia may be absorbed by perspiration on the body

even though appropriate protective clothing is worn. Severe discomfort may be minimized or

prevented by the application of protective oil to such body areas in addition to the wearing of

protective clothing.

8.5 Spills and Leaks

8.5.1

Leaks of ammonia should be searched for, preferably with hydrochloric acid solution or with

either chlorine gas or sulphur dioxide gas using a small cylinder of the compressed gas. A white




cloud is produced in the presence of ammonia. Because of the fire risk, sulphur candles should

not be used.

8.5.2

If leaks or spills occur, only properly protected personnel should remain in the area. In cases

where leaks cannot be valved off, use large volumes of water sprayed directly on the leak and

maintain contact until the contents have been discharged and the tank is empty. Leaking

cylinders should be removed to the outdoors or to an isolated, well-ventilated area and the

contents transferred to other suitable containers. All spills should be flushed away promptly with

water.

8.5.3

In handling or operating any type of ammonia system, always be sure that all valve connections

and pipe lines are in proper order and condition before starting the operation. Keep compressors

and motors clean and in good condition.

8.5.4

During cold weather keep all steam traps warm, whether or not tanks are in service.

68.5.5

Never, under any circumstances, close all valves on a full line of liquid ammonia unless

protected by pressure relief or liquid expansion device.

9 FIRST-AID

9.1 General Principles

After severe exposure to ammonia gas, it is important to move the patient from the contaminated

area promptly. In case of contact of the liquid with the eyes or skin, immediate flushing with

large quantities of running water is imperative. In all cases of serious injury, call a physician at

once giving him a complete account of the accident.

9.2 Contact with Skin and Mucous Membranes

Speed in removing ammonia from contact with the patient and in moving the patient to an

uncontaminated atmosphere is of primary importance.

If skin contact is extensive and emergency showers available, the employee should get under the

shower immediately. Contaminated clothing and shoes should be removed under the shower. In

other instances flushing with large amounts of running water should be continued for at least 15

minutes.




9.2.1: Under no condition should salves or ointments be applied to the skin or mucous membrane

burns during the 24-hour period following the injury. Subsequent medical treatment is otherwise

the same as for thermal burns.

9.3 Contact with the Eyes: If even small quantities of ammonia enter the eyes, they should be

irrigated immediately and copiously with water for a minimum of 15 minutes. The eyelids

should he held apart during the irrigation to ensure the contact of water-with the tissues of the

eye surface and lids. A physician should be called at the earlier possible moment. After the first

15 minutes period of irrigation, if a physician is not available, the irrigation should continue for a

second period of 15 minutes. It is then permissible as a first-aid measure to instill 2 or 3 drops of

0.5 percent pontocaine solution or an equally effective aqueous topical anesthetic. No oils or oily

ointment should be instilled unless ordered by a physician. The employee should be sent to a

physician, preferably an eye specialist, as soon as possible.

9.4 Ingestion: If liquid anhydrous ammonia has been swallowed, call a physician immediately. If

the patient is conscious and able, he should drink large amounts of water to dilute the chemical.

Do not induce vomiting if the patient is in shock extreme pain or is unconscious. If vomiting

begins, place the patient face down with head lower than hips, this prevents vomitus from

entering the lungs and causing further injury.

9.5 Inhalation

Exposed persons should be removed at once to an uncontaminated area. If the exposure has been

to minor concentrations for a limited time, usually no treatment will be required.

9.5.1: When there is severe exposure to higher concentrations, and if oxygen apparatus is

available, oxygen may be administered but only by a person authorized for such duty by a

physician. If the patient is not breathing, an effective means of artificial respiration should be

initiated immediately. Call a physician.

9.5.2: The patient should be kept comfortably warm but not too hot and should be kept at rest.

9.5.3:Never attempt to give anything by mouth to an unconscious patient.




Annexure 7 {VII}: EHS Policy




Annexure 9.1

Table 1: List of plant species for Green Belt Development

Sr.

No.

Scientific Name Common Name Family Sensitive /

Tolerant

Habit Growth r

ate

Regeneration Evergreen

/

Deciduous

1. Achras sapota Chikoo Sapotaceae T Tree Quick

growing

Grafting Evergreen

2. Aegle marmelos Bell tree Rutaceae T Tree Quick

growing

By seed &

root cutting

Evergreen

3. Albizia chinensis Siris Mimoseae T Tree Quick

growing

By seed Deciduous

4. Albizia lebbeck Siran Mimoseae T Tree Quick

growing

By seed Deciduous

5. Albizia procera White Siris Mimoseae T Tree Quick

growing

By seed Deciduous

6. Alstonia Scholaris Chattiyan Apocynaceae T Tree Quick

growing

By seed Evergreen

7. Annona Squamosa Custard Apple Annonaceae T Small

tree

Fast growing By seed,

Grafting

Budding

Evergreen

8. Annona reticulata Luvuni Annonaceae T Tree Fast growing By seed Evergreen

9. Azadirachta indica Neem Meliaceae T Tree Quick

growing after

1st season

By seed Evergreen

10. Bauhinia purpurea Khairwal Caesalpinacea

e

T Tree Quick

growing

Through seed

11. Bauhinia racemosa Apta Caesalpinacea

e

T Tree Quick

growing

By seeding

12. Butea monosperma Palas Fabaceae T Tree Quick

growing

By seeds Deciduous

13. Cassia fistula Golden shower Caesalpinacea

e

T Tree Quick

growing

By seeds Deciduous




Sr.

No.


Tolerant

Habit Growth r

ate


/

Deciduous

14. Citrus aurantium Nebu Rutaceae T Tree/

shrub

Quick

growing

By seeds,

Stem cutting

Evergreen

15. Dalbergia sissoo Sissoo Moderate

during 1st

year and

rapid

afterwards

By seeds,

Root & Slum

cuttings

Evergreen

16. Delonix regia Flameboyant Caesalpinacea

e

S Tree Quick

growing

By seeds,

cuttings

Deciduous

17. Emblica officinalis Awala Euphorbiaceae T Tree Quick

growing

By seeds,

cuttings,

budding,

inarching

Deciduous

18. Ficus benghalensis Bargad Moraceae T Tree Quick

growing

By cutting

seeds

Evergreen

19. Ficus glomerata Umbar Moraceae T Tree Quick

growing

By seeds,

cutting

Deciduous

20. Ficus religiosa Pipal Moraceae T Tree Quick

growing

Through

seeds, cutting

Evergreen

21. Hibiscus rosa-sinensis Jaswand Malvaceae T Shrub Quick

growing

By seeds Evergreen

22. Lantana camara Lantana Verbenaceae T Shrub Quick

growing

By seeds,

cuttings

Evergreen

23. Mangifera indica Mango Anacardiaceae T Tree Quick

growing after

1st year

By seeds,

transplantatio

n, grafting,

budding, air

layering, root

cutting,

marcutting

Evergreen




Sr.

No.


Tolerant

Habit Growth r

ate


/

Deciduous

24. Nerium indicum Kaner Apocynaceae T Shrub Quick

growing

By Cutting Evergreen

25. Psidium guayava Amrud Myrtaceae T Tree Quick

growing

By seeds,

stem, cutting,

budding,

grafting

Evergreen

26. Samanea saman Rain tree Mimosaceae T Tree Quick

growing

By seed

cutting

Evergreen

27. Saraca asoka Ashok Caesalpinacea

e

T Tree Quick

growing

By seed Evergreen

28. Syzygium cumini Jaman Myrtaceae T Tree Quick

growing

By seed,

cutting,

Grafting,

Budding

Evergreen

29. Tamarindus indica Imli Caesalpinacea

e

T Tree Quick

growing

(Early)

By seed Evergreen

30. Zizyphus mauritiana Ber Rhamnaceae T Tree Quick

growing

By seeds Evergreen

31. Zizyphus xylopyra Katber Rhamnaceae T Staggler

shrub

Quick

growing

By seeds Evergreen

Source: “Guideline for Developing Greenbelt” Central pollution Control Board, Program objective series PROBES/75/1999-

200Table 2




Table 2: List of Birds associated plants for green belt development

S.no Scientific name Birds

1. Acacia catechu Coppersmith, Blue throated Barbets, Red vented bulbul

2. Alianthus excelsa Asian koel, Jungle babbler, Common Myna, Asian pied starling

3. Anthocephalus

cadamba

Cattle egret, brown crowned night heron, white breasted kingfisher,

pied kingfisher

4. Ficus religiosa Oriental white eye, common iora, long tailed shrike, rufous

woodpecker

5. Dendrocalamus sp. Greater caucal, black drongo, jungle babbler, green bee eater

6. Delonix regia Red-whiskered bulbul, lineated barbet, black drongo, asian koel

7. Ficus benghalensis Indian roller, common hawk cuckoo, brown srike

8. Lagerstromia

parvoflora

Great tit, red vented bulbul, purple rumped sunbird

9. Tamarindus indica Black rumped flameback, rose ringed parakeet, Indian cuckoo,

orange breasted green pigeon

10. Tectona grandis Red-whiskered bulbul, common iora, yellow footed green pigeon,

black drongo

11. Mangifera indica rose ringed parakeet, rufous treepie, black rumped flameback

12. Zizipus jujube Verditer flycatcher, plain prinia, oriental magpie robin

13. Thivetia peruviana Purple sunbird, purple rumped sunbird, great tit, rufous treepie

14. Terminalia cattappa Oriental white eye, purple sunbird, plain prinia

15. Hibiscus rosa-cinensis Red breasted parakeet, Sunbird

16. Cocos nucifera Baya weaverbird

17. Syzygium jamboanum Flowerpecker, red vented bulbul, Indian robin

18. Azadirachta indica Red vented bulbul, White browed bulbul, oriental white eye, House

sparrow

19. Bombax seiba Leaf bird, Purple sunbird, Golden oriole, green bee eater




Table 3: List of Butterfly associated plants for green belt development

Sr. No. Tree Species Associate Butterfly species

1. Polyalthia longifolia Tailed Jay

2. Annona reticulate Tailed Jay

3. Annona squamosa Tailed Jay

4. Aegle marmelos Lime Butterfly, Common Mormon

5. Citrus sp. Lime Butterfly, Common Mormon, Blue Mormon

6. Bauhinia racemosa Lemon / Common Emigrant

7. Butea monosperma Lemon / Common Emigrant

8. Cassia fistula Lemon / Common Emigrant, Mottled Emigrant, Common Grass Yellow

9. Cassia siamea Lemon / Common Emigrant, Mottled Emigrant

10. Albizzia sp. Common Grass Yellow

11. Cocos nucifera Common Palmfly

12. Areca catechu Common Palmfly

13. Phoenix sp. Common Palmfly

14. Acacia catechu Common Nawab

15. Albizia lebbeck Common Nawab, Zebra blue

16. Tamarindus indicus Tawny Rajah, Black Rajah

17. Pongamia pinnata Chestnut- Streaked Sailer

18. Bombax ceiba Chestnut- Streaked Sailer, Common Sailer

19. Careya arborea Common Sailer

20. Mangifera indica Common Baron

21. Anacardium occidentale Common Baron

22. Ricinus communis Common Castor, Angled Castor

23. Sida rhombifolia Lemon Pansy, Great Eggfly

24. Ficus sp. Common Map, Common Indian Crow

25. Calotropis gigantean Glassy Blue Tiger, Plain Tiger

26. Mimusops elengi Common Indian Crow

27. Ziziphus mauritiana Common Pierrot, Angled Pierrot, Blue Banded Pierrot

28. Ziziphus xylopyrus Common Pierrot, Angled Pierrot, Blue Banded Pierrot, Dark Pierrot

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