Hydrogeochemical characterization of major factors affecting the quality of groundwater in southern...

8
HYDRODYNAMIC BEHAVIOR OF CAVES FORMED IN THE FRESH·WATER LENS OF CARBONATE ISLANDS E. Raeisi' and J. E. Mylroie' 'Departmem of Geology, College of Science, Shiraz University, Shiraz, Iran 'Department of Geosciences, Mississippi State University, Mississippi State, MS 39762 ABSTRACT: Flank margin caves are developed in carbonate islands at the edge of the fresh-water lens during sea-level highstands. The development of these caves in the Bahamas was constrained by the short period of glacioeustatic sea-level highstand available during the last interglacial (10,000-15,000 years), and by the small size of the fresh-water lens at the lime of the sea-level highstand. The mixing of fresh and saline water, and bacterial oxidation and reduction of organic matter are the chemical processes that drive the origin of the flank margin caves. In the fresh-water lens, the average specific discharge (discharge per unit volume of aquifer) drastically increases at distances less than 100 m from the shoreline, as the lens thins. This area is named the active edge of the fresh-water lens. The higher specific discharge results in enhanced dissolution, which, coupled with the chemistry of the distal margin of the lens, increases porosily and hydraulic conductivity. As a consequence the thickness of the fresh-water lens decreases with time and the average specific discharge continues to increase at the active edge of the lens. Mapped flank: margin caves in the Bahamas show short penetration distances into the eolian ridges containing them (averaging 29 m), perpendicular to the paleoshoreline, indicating development within the active edge. INTRODUCTION Flank margincavesareoneofthe unusual cavetypes in late Pleistocene carbonate rocks which havebeen studied extensively in the Bahamas (Mylroie and Carew1990; Vogel et al. 1990; Mylroie et al. 1991). A review of flank margin cave form and development is presented in this volume (Mylroie and Carew 1995a). Flank margin caves are ramiform-type caves (palmer 1991). The caves are found in thehillsides of eolian calcarenite ridges in the Bahamas. They are phreaticcaves oflimited vertical extent, but commonly of appreciable horizontal development. Theygenerally havea main chamber adjacent to the edge of the eoliancalcarenite ridgein whichtheyare contained, withsmaller chambers and passages radiating inward towards the ridge axis. Mylroie and Carew (1990) suggested that the margin of a past fresh- waterlens,elevated bya past highersea level, was the area of intensive dissolution in which the flank margin caves devel- oped. As the caves are believed to have developed in the margin of a fresh-water lens, just underthe flank of an en- closingridge,theywerenamed flank margin caves by Mylroie and Carew (1990). Flank margin cave development is the result of the convergence of twoprimary areasof dissolution in the fresh- waterlens:the topof the lenswhere vadose and phreatic wa- tersmix,andthe bottom of the lens (halocline or mixingzone) wherefreshand salinemarine watermix. In vadose/phreatic mixing,evenif the unmixed waters areindividually saturated withcalcium carbooate, theirmixing produces renewed chemi- cal aggressivity for dissolution if their initial saturation oc- curredat different carbon dioxide concentrations (BOgli 1980). Mixing of fresh and salinewater at the halocline produces a chemically complex brackish waterthatis capable of renewed calcium carbonate dissolution (plummer 1975). Flankmargincavesof the Bahamas havebeendocu- mentedtohave formed in the 10,000 to 15,000 yearlongtime Carbonates and Evaporites, v. 10, no. 2, 1995, p. 207-214 span of the last interglacial sea-level highstand (oxygen iso- tope substage 5e,circa 125,000 yearsago) (Carew and Mylroie 1995a). However, on thebasisof inorganic mixing, Sanford and Konikow (1989) predicted thatthe amountof dissolution shown byflankmargincaves cannotoccurduringsucha lim- itedtimeor withinsmall,lowdischarge lenses(suchas those found in Bermuda). Bottrell et al. (1991; 1993), and Mylroie and Balcerzak (1992) havedemonstrated thatbacteriaare capable of penetrating carbonate aquifers and enhancing dissolution in Bahamian limestones. Oxidation of organic materials in the water increases the amountof carbondioxide, which pro- duces carbonic acid that drives limestone dissolution. When the oxygen in the wateris depleted, anaerobic processes be- gin. Anaerobic bacteria reduce sulfate in the sea water to produce hydrogen sulfide, which upon subsequent oxidation to sulfuric acid causes additional dissolution of the limestone. The dissolution mechanisms of flank margin cave develop- ment,suchas the fresh -saline watermixingandbacterial oxi- dation-reduction, are almost uniformly distributed through- out the fresh-water lens boundaries; however, the largestdis- solution cavities, the flank margincaves, develop at the mar- gin ofthe fresh-water lens. Therefore, some additional mecha- nismsmaybe involved to produce such big cavesat the edge ofthe fresh-water lens. The object of thisstudyis to introduce additional mechanisms which mayenhancecavedevelopment at the edgeof the fresh-water lens. HYDROGEOLOGICAL SETI'ING The Bahamas are a series oflow-lying carbonate is- lands that extend from neartheFloridaPeninsula south-south- east to Hispaniola (Fig. 1). The islands are the subaerial ex- pression of portions of shallow-water carbonate platforms up to 10km thick that havebeen collecting carbonate sediments since the Mesozoic. Subaerially exposed rocks in the Baha- mas are composed of a variety of marine and eolian lime-

Transcript of Hydrogeochemical characterization of major factors affecting the quality of groundwater in southern...

HYDRODYNAMIC BEHAVIOR OF CAVES FORMED IN THE FRESH·WATER LENSOF CARBONATE ISLANDS

E. Raeisi' and J. E. Mylroie'

'Departmem of Geology, College ofScience, Shiraz University, Shiraz, Iran'Department ofGeosciences, Mississippi State University, Mississippi State, MS 39762

ABSTRACT: Flank margin caves are developed in carbonate islands at the edge of the fresh-water lens during sea-level highstands. Thedevelopment of these caves in the Bahamas was constrained by the short period of glacioeustatic sea-level highstand available during thelast interglacial (10,000-15,000 years), and by the small size of the fresh-water lens at the lime of the sea-level highstand. The mixing offresh and saline water, and bacterial oxidation and reduction of organic matter are the chemical processes that drive the origin of the flankmargin caves. In the fresh-water lens, the average specific discharge (discharge per unit volume of aquifer) drastically increases at distancesless than 100 m from the shoreline, as the lens thins. This area is named the active edge of the fresh-water lens. The higher specificdischarge results in enhanced dissolution, which, coupled with the chemistry of the distal margin of the lens, increases porosily andhydraulic conductivity. As a consequence the thickness of the fresh-water lens decreases with time and the average specific dischargecontinues to increase at the active edge of the lens. Mapped flank: margin caves in the Bahamas show short penetration distances into the

eolian ridges containing them (averaging 29 m), perpendicular to the paleoshoreline, indicating development within the active edge.

INTRODUCTION

Flankmargincavesareoneoftheunusual cavetypesin late Pleistocene carbonate rocks which havebeen studiedextensively in theBahamas(Mylroie andCarew1990; Vogelet al. 1990; Mylroie et al. 1991). A review of flank margincave form and development is presented in this volume(Mylroie and Carew 1995a). Flank margin caves areramiform-type caves (palmer 1991). Thecaves are found inthehillsides ofeolian calcareniteridges in theBahamas. Theyare phreaticcaves oflimited vertical extent, butcommonly ofappreciable horizontal development. Theygenerally haveamain chamber adjacent to the edge of the eoliancalcareniteridgein whichtheyare contained, withsmaller chambers andpassages radiating inward towards the ridge axis. Mylroieand Carew(1990) suggested that the margin ofa past fresh­waterlens,elevated bya past highersealevel, was theareaofintensive dissolution in which the flankmargin cavesdevel­oped. As the caves are believed to have developed in themargin of a fresh-water lens, just under the flank of an en­closingridge,theywerenamedflankmargin caves byMylroieand Carew(1990).

Flank margincave development is the resultof theconvergence of twoprimaryareasofdissolution in the fresh­waterlens:the topof the lenswherevadose and phreatic wa­tersmix,andthebottom of thelens(halocline ormixingzone)wherefreshand salinemarinewatermix. In vadose/phreaticmixing,evenif theunmixedwaters areindividually saturatedwithcalcium carbooate, theirmixing produces renewed chemi­cal aggressivity for dissolution if their initial saturation oc­curredat different carbon dioxide concentrations (BOgli 1980).Mixingof fresh and salinewater at the halocline produces achemicallycomplex brackish waterthatiscapable ofrenewedcalcium carbonate dissolution (plummer 1975).

Flankmargincavesof theBahamas havebeendocu­mentedtohaveformed in the 10,000 to 15,000 yearlongtime

Carbonates and Evaporites, v. 10, no. 2, 1995, p. 207-214

spanof the last interglacial sea-level highstand (oxygen iso­tope substage5e,circa125,000yearsago)(CarewandMylroie1995a). However, on thebasisof inorganic mixing, SanfordandKonikow (1989) predicted thatthe amountofdissolutionshown byflankmargincaves cannotoccurduringsucha lim­itedtimeor withinsmall,lowdischarge lenses(suchas thosefound in Bermuda).

Bottrell et al. (1991; 1993), and Mylroie andBalcerzak (1992) havedemonstrated thatbacteriaarecapableof penetrating carbonate aquifers and enhancing dissolutionin Bahamian limestones. Oxidation of organic materials inthewater increases theamountofcarbondioxide, which pro­duces carbonic acid thatdrives limestone dissolution. Whenthe oxygen in the wateris depleted, anaerobic processes be­gin. Anaerobic bacteria reduce sulfate in the sea water toproduce hydrogen sulfide, which uponsubsequent oxidationtosulfuric acidcauses additional dissolution ofthe limestone.The dissolution mechanisms of flank margin cavedevelop­ment,suchas thefresh-saline watermixingandbacterial oxi­dation-reduction, are almostuniformly distributed through­out thefresh-water lensboundaries; however, the largestdis­solution cavities, the flank margincaves, develop at the mar­ginofthefresh-water lens. Therefore, someadditional mecha­nismsmaybe involved to produce suchbig cavesat the edgeofthefresh-water lens. Theobject of thisstudyis to introduceadditional mechanisms which mayenhancecavedevelopmentat theedgeof thefresh-water lens.

HYDROGEOLOGICAL SETI'ING

TheBahamas are a series oflow-lying carbonate is­lands thatextend from neartheFloridaPeninsula south-south­east toHispaniola (Fig.1). The islands are the subaerial ex­pression ofportions of shallow-water carbonate platforms upto 10km thickthathavebeen collecting carbonate sedimentssince the Mesozoic. Subaerially exposed rocks in the Baha­mas are composed of a variety of marine and eolian lime-

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whereh is the fresh-water head abovesea level,z is the dis­tanceof interfacebelow sea level, Pf and P.are, respectively,the fresh water and salt waterdensities, and a =p/{P.- pf ) .

Flow in coastal aquifers can be described by means of theDupuit equation in combination with the Ghyben-Herzbergprinciple. For one-dimensional steady-state flow, a homoge­neous andisotropic aquifer receiving rechargeat constantrate,R, with a width equal to W, the head of the water table isobtained by Henry(1964) and laterauthors(Child 1968; Fet­ter 1972; Bear 1972;Vacher 1978)as follows:

GHYBEN· HERZBERG FRESHWATER lEt'S IN A POROUSC'ARBONATE ISLAND (2)

hI = h: + 1 R I [2M (x - a) - (x 2- a)] (4)

l K2 (1 + a) l

whereh is the head ofwater tableabovesea levelat any dis­tance, x, from the shoreline, K is hydraulic conductivity andM is halfof the island width.

Thefresh-water lensmaybeconsidered as two aqui­fersinsidea strip islandofinfinitelength and finitewidth,aspresented byVacher (1988), wherethe aquifersare composedof two adjacent vertical-strip sectors of different hydraulicconductivities, with a boundary at x equal to a, both parallelto the islandmargin. Vacher (1988)obtainedthe solution forstripsof different K, as follows:

whereh, and ~ are the headof watertableabovesea levelofthestripsnearand far from theshoreline, respectively, K, andK" are the hydraulic conductivity of the strips near and farfromthe shorelinerespectively, and ha is the head above sealevelat the boundary of strips of different K (x equal to a).The discharge per unit width of aquifer (Q) is calculated bythe equation:

(3)

(5)

I R I (2Mx _ x2)1 K1 (1 + a) l

Q = R(M - x)

FRESH·WATER LENS EQUATION

stonesof Pleistocene and Holocene age. The islandsare tec­tonicallystableand appear to be isostatically sinkingat a rateof no more than a few meters per hundred thousand years(Carew and Mylroie 1995a). Therefore, anycavesthat occurabove sealevelin theBahamasmusthavebeenproduced whensealevelwas higherthan today. The deposition ofQuaternarylimestones on the Bahamasbanks is tied to glacioeustatic sealevelfluctuations (Carew and Mylroie 1995b).

The flank margin caves are found 0 to 7 m abovepresent sea level. They occur mostly in the flanks of Pleis­tocenedunes (eolian calcarenites) and are alignedparallel tothe duneaxis. The upperlimit of thisvertical rangeofcaverndevelopment coincides with the +6m maximum sea levelhighstand of the last interglacial that occurred 120,000­132,000 years ago, based upon uranium/thorium dating offossil coralreefs(Chenet, al. 1991; CarewandMylroie 1995a),correlating to oxygen isotope substage 5e (Shackleton andOpdyke 1973). At a sea-level riseof 6 m above the presentlevel,onlythe topsof the eolianridgeswereexposed. In thissetting,the Bahamasislandswerereducedtoa seriesofsmallseparateislands, and the flank margin caveswouldhavede­veloped at the fresh-water lens margin of their shorelines(Mylroie and Carew 1990).Each cave generally consists ofan irregularchamberor chambersnear the marginofa dune,with a network of passages that extend inward toward thedune axis. These inward-extending passages, in somecasesquite large, terminateabruptly, indicatingthe position of thesiteofactivecavedissolution whensealevelfelland thecavesweredrained (Mylroie and Carew, 1990).

Figure 2. Diagrammatic representation ofanidealizedfresh­water lensin a porous carbonate island.

The averagespecific discharge (q) or discharge perunit vol­umeof aquiferis calculated as follows:

The main physicalcontrolson the salt-water/fresh­water interfaceare givenby the Ghyben-Herzberg model, asshownin figure2. It shows that understaticconditions, thefresh-water head above sea level depresses the interface be­lowsea levelaccording to the relationship:

q = Qt

(6)

z = r PI 1h = ak1 Ps - PI l

(1) where t is the thickness of aquiferwhich is equal to z + h.

209

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Figure 3.Average specific discharge versus distance. Hydrau­lic conductivity is 8.2 mJday. W is the island width.

Distance Inland Perpendicular to the Shoreline (m)

Figure 4. Average specific discharge versus distance. Hydrau­lic conductivity is 821 mJday. W is the island width.

HYDRODYNAMICBEHAVIOROF CAVES IN CARBONATE ISLANDS

HYDRODYNAMIC BEHAVIOR conductivity inside the active. edge of the fresh-water lens.The relationship between K and porosity is not linear. Hy­draulicconductivity increases with the squareof the pore di­ameterin Darcian flow. Bradyand Brown (1985) observedthat if the widthof a fissure in a laminar flow increases by afactor of 10from0.05 mmto 0.5 mm, then its transmissivity(K. x fissure width) increases bya factorof 1000. Theprocessof faster K development inside the edge of the fresh-waterlensdivides theaquiferintoparallel stripsofdifferent K par­allel to the shoreline (in the caseof the Bahamas during thelast interglacial, alsoparallel to the eolianite ridgeaxis), suchthat the K in the strip of the activeedge (K) is greater thanthat of the interior (landward) strip ~). Equations 3 and 4can be used to calculate the profile of the fresh-water lens.The crosssection of a fresh-water lenswith K,and~ equalto 82 m/dayand 8.2 m/dayrespectively is shown in figure5.The thickness ofaquiferdecreases insidetheactiveedge,and

The average specific discharge is calculated usingEquations 2, 1,5 and 6, in sequence. The ratio (a) is 40, ifthedensities offreshwaterand salinewaterare takenas 1.000and 1.025grams per cubiccentimeter, respectively. Accord­ing to Vacher (1988), dimensionless R/K ratios of Holocenesandsand upperPleistocene calcarenites appear to be in therangeoflQ-6 to 104,whereRisO.3toOAm/yearand Krangesfrom 10 to 1000 rn/day. Budd and Vacher (1991) justifiedthis generalization. The currentwidthsof islandsin theBa­hamasat presentsea levelare measured in kilometers to tensofkilometers; however, during the sea-level highstandof thelastinterglacial onlythe narroweolianite ridgeswereexposedas islands hundredsof metersto at mosta few kilometers inwidth. Therefore, the hydrodynamic behavior of the fresh­waterlens is evaluatedfor islandswidthsof 1,2 and 10km,the upperlimitof island width for the last interglacial. Aver­age annual recharge is considered 0.3 rn/year (Vacher andAyers 1980). The averagespecific discharge versus distanceinlandfromshorelineforR/Kequalto 104(K.=8.2rn/day) to10-6 (K. =821 rn/day) are presented in figures 3 and 4. Thecurves showthataverage specific discharge increasesdramati­callyat the lens margin in bothcases.

Attheinitialstageofkarstdevelopment, thehydrau­licconductivity is expected tohavetheminimum value,there­foreR/Kequalto 104probablyrepresents thefresh-water lensduring the initial stage of cave development The averagespecific discharge increases greatly within the lensas thelensthinsat distanceless than 50 m fromtheshorelinein islandswith 1 km and 2 km widths. This area is named here theactive edgeof the fresh-water lens. The active edge of thefresh-water lens increases up to 100m in islandswith 10kmwidth. Thewidthof the activeedgedepends on the width ofthe island, recharge rate, and hydraulic conductivity. Highvalues of islandwidth,recharge, and K produce a moreland­wardposition of theactiveedgeofthe fresh-water lens. Aver­agespecific discharge at a distance of 1meterfromtheshore­line is almost10timesmorethan at a distance of 100meters.The 1 meterdistancefromthe shoreline mayappearto beanextreme case, as a dynamic and a static flow model for thelenswill approximately coincide except for smallvalues of x(distance fromthe shoreline). However, exploration of flankmargincaves consistently shows that theydevelop withintheeolianite ridgesat a location thatwasonlya few metersfromthe paleoshoreline (Mylroie and Carew1990; 1995b).

Sanfordand Konikow (1989) showed that the ratioofporosity development is linearly dependent on specific dis­charge in coastal carbonate aquifers; as a consequence theporosity development is muchfaster insidethe activeedgeofthe fresh-water lens,especially near the shoreline. Vacher etal. (1990) concluded that velocities are greatestat the watertable, whichmayenhanceporosity at andjust below the watertablewithin theactiveedgeof fresh-water lens.Theseporos­ity enhancements create an aquifer with a higher hydraulic

210

RAEISIANDMYLROIE

10

-60 '----'-_-I-_L---'-_-I-_L---L._...L.._L---!

o 50 100 150 200 250 300 350 400 450 500

Distance Inland Perpendicular to the Shoreline (m)

Figure 5. Cross-section of thefresh-water lens fora homoge­neous aquifer (K =8.2 m/day) andfor different strips of K(K} =82 m/day, ~ =82 miday).

MINOR PROCESSES CONTROLLING FLANKMARGIN CAVEORIGIN

The model of Sanfordand Konikow (1989) showsthat smallislandswithlowspecific dischargeare unfavorablelocations forporosity development. Bottrellet al. (1993)sug­gestedthat theexistence of flankmargincavesin thesesmallislandswas a resultoforganicprocesses and oxidation-reduc­tion reactions that enhancedlimestone dissolution. In addi­tion, the continuous process of porosity and hydraulic devel­opment, and hydrodynamic behavior of flow throughdissolutional passages presented in this paper, were not con­sideredin the Sanfordand Konikow (1989)model. Mylroieand Carew (1995b) have stated that flank margin cavesarenot trueconduits, in that theyshowno evidence of turbulentflow, and that theyreceive and discharge water througha pa­rousmedium. This is essentially correct; however, the devel­opment of dissolutional voids by mixing and by oxidation­reduction reactions resultsin a change in hydrodynamic be­haviorofthelens,thatenhances further dissolution. Thevoidsbecome chambers that, as a result of their lowresistance toflow, capturewaterfromadjacentareasof the lens, accelerat­ing chamberenlargement. As a resultof lens discharge per­pendicular to the shoreline, these chambers develop in theactive edge parallel to the shoreline, but do not necessarilyconnect witheach other. Furtherenlargement ofthesecham­bers thins the fresh-water lens sufficiently to allow marinewatertodominatethegeochemistryofthe chambers, at whichtimetheactiveedgeofthe lens"shifts" to thebackwallofthechambers. Continued dissolution produces passagesradiat­ing from the back wall of the chambers; they often developinto a second, and then a third, row of chambersparallel tothe shoreline, as observed in both the Bahamas and Isla deMona, PuertoRico (Mylroie and Carew 1995b).

The other processes that may cause differences inporosity development along the fresh water lens are theaggressivity variation ofinfiltratingwaterthroughthevadosezoneand the migrationoforganicmatter. The topography ofthe Bahama islands is dominated by a series of Pleistoceneeolianridges(Carewand Mylroie 1995b). Theseduneridgescurrently reacha maximum altitudeof40 meterson San Sal­vador Island; however the majority were between 10 to 14metershigh during the time of the last interglacial sea-levelhighstand(Mylroie and Carew, 1995a). The thickness of thevadose zone abovethe activeedge of the fresh-water lens isless than the areas more to the center of the lens. Palmer(1991) statedthat waterinfiltrating directlyinto limestone ofhighintergranular porosityquicklyloses itsaggressivitywithina fewmeters of the surface. The development of a shallowsurface karst or epikarstin carbonate islandsconsumes mostavailable dissolutional potentialin the vadosewater. There­fore the water which infiltrates above the activeedge of thefresh-water lens, where the surfacealtitude is lower, passesthrough a shortvadose distance, and is moreaggressive uponreachingthe topof thefresh-water lenscomparedto thewaterpassing througha greatervadosethickness towards the lens

E K]= 82 m/d.y

:: 10 4~- ),.s A,

81-20 ~(/J '4E '.'...e ·30 "~ ...........2~ -40

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As the various mixing processes dissolve the lime­stone, especially in the downflow parts of the active edge,achamberforms. Initiallythechamberactsasa mixingvessel,butas the chamberenlarges,the lens thins sufficiently in thislocaleto allowpenetrationby marinewater. The fresh-waterlens then migratestowardthe backwallof the chamber, andpassages continuetodevelop at thisnewlocation of theactiveedgeof the fresh-water lens. This modelexplainstheperva­sive existence of passages diverging inland towards the is­land interiorin mostflankmargincaves (Mylroie and Carew1990; 1995a; 1995b).

as a consequence the average specific discharge again in­creases. This cycleof increasingaveragespecific dischargeand consequent porosity development by dissolution contin­uesuntil irregularpassageswith laminarflow are formedin­side the active edge of the fresh-water lens. Once formed,thesepassages capturewaterradially, transferring a consider­able amount of water, especially during the periods of highrainfall intensity. Flank margincavesdevelop in this zoneofenhancedflow.

Flank margin caves develop parallel to the axis ofthe eolianite ridge enclosing them, adjacent to thepaleoshoreline of the last interglacial, just under the flank oftheridge (Mylroie and Carew1990; Mylroie etal. 1991). Themaximum penetrationlengthoftheseflankmargincavesintothe eolianite ridges, perpendicular to the paleoshoreline, ispresentedin table 1. This penetration distance is a measureof the position and subsequent migration inland of the activeedge as the flank margincaves developed. Penetration per­pendicularto the shorelinein all Bahamiancavesis less than100m, withan averageof 29 m, which corresponds with thewidthof the activeedgeof the fresh-waterlens, parallelto thepaleoshoreline, when the caves wereforming. Ifclimatere­mainsconstant,the thinning of thefresh-water lens is an out­comeof porosity and hydraulic conductivity enhancement.

211

HYDRODYNAMIC BEHAVIOR OF CAVES IN CARBONATE ISLANDS

Table1. Maximum penetration length of flankmargin cavesperpendicular to the shorelineof the enclosing eolianite ridges.

Islands Cave Name MPL* Source**

San Salvador Dance Hall 22 1George Storrs 25 1Beach 68 1Bug City 17 1Lighthouse 65 1Reckley Hill Pond 12 1Closet 7 2Garden 19 3Alter 48 4

New Providence Caves Point East 16 5Caves Point West 27 5Bat 16 5Harry Oakes 24 5Harry Oakes Annex 11 5Bahamas West 28 5Clifton East 10 5Hunts Cave 45 5

Long Island Stella Morris 25 5Salt Pond 79 5Benzie Hill North 12 5Benzie Hill South 9 5Hamilton 73 5

Great Inagua Maroon Hill 30 1Salt Pond Hill 19 6

Andros South Deep Creek 29 6Cluster 16 6Little Little Creek 10 6Deep Creek 9 6Archways 8 6Micholstown 55 6

Eleuthera Hachet Bay 59 6

Isla De Mona Cueva De Dona Gena 52 7Cueva De Dona Gena Arriba 32 7Cueva De Agua 92 7Cueva Neuvo 52 7Cueva Del Alemon Upper Level 62 7Cueva Del Alemon Lower Level 100 7Cueva al Gado Del Faro 240 8

* Maximum penetration length perpendicular to the shoreline** 1) Mylroie and Carew, 1990 2) Vogel et al., 1990 3) Kunze andMylroie, 1991 4) Mylroie, 1988 5) Mylroie et al., 1991 6)Mylroie and Carew, 1986 (unpublished data) 7) Mylroie et al., 19958) U.S. Geological Survey Map, 1972

212

RAEISIAND MYLROIE

ACKNOWLEDGMENTS

.700 '-.--i_--l_--L_-L_--L._-L_--L-_...L----.I

o 1 2 3 456 7 S 9

Distance Inland Perpendicular to the Shoreline (1000 m)

Figure 6. Cross-section ofthefresh-water lensfor two differ­ent islands widths.

W = 20 km

-600

geochemical activityand enhanced specific discharge at thelens margin, the porosity and the hydraulic conductivity ofthe lens margin increase. This area of enhancedporosity de­velopment is called the active edge of the lens. The activeedgethinsas a resultof its high hydraulic conductivity, againincreasing the specific discharge. Thisactiveedgeprovides acontinual positive feedback effectthat focuses discharge anddissolution, forming flank margin caves in a short time, ontheorderof 10,000years. Thinningof thefresh-water lensinthe active edge places the vadose/phreatic and the fresh/sa­line mixingzones in closeproximity. Vadose waterenteringabove the active edge has a short travel path and retainsdissolutional potential upon arrival at the top of the lens.Organic matter also has a short transfer path to the activeedgeof thefresh-water lens,and moreorganicmatterisavail­able per unit volume of aquifer at the active edge as well.Theseadditional minorfactors mayalsobe importantin form­ing flank margincaves.

Thedissolutional processes described heremayhelpto pinpoint the location of dissolutional porosity in ancientlimestones. Ifsubaerial exposure occurred in the past, it neednot be of a longdurationnorof broad areal extent to developappreciable dissolutional porosity. Such knowledge may beimportantwhenconsidering carbonates as potentialaquifersor hydrocarbon reservoirs.

The first author wouldlike to thank ShirazUniver­sity, Shiraz, Iran, for financial supportduring his sabbaticalat the Department ofGeosciences, Mississippi State Univer­sity. TheBahamianFieldStationon San SalvadorIsland,Dr.DanielSuchy, Executive Director, providedlogistical supportfor the field research that allowed us to develop these ideas.James Carew provided invaluable assistance in developingthe flank marginmodel, and ArthurPalmer provided a con­structive review.

100

E~-100

1..J -200Cl1Gl

C/)

E -300

,g&:: -400o~~ -500iii

As a firstapproximation, organicmatteris constantper unit area of ground surface. The organic matter perco­latesthroughthe vadose zoneand initially becomes suspendedat the top of the watertable,where oxidation-reduction reac­tions may occur. Water-saturated organicmatter may con­tinue to descend through the fresh-water lens, and becomesuspended at the topof thehalocline or withina mixingzone.Such organicloading,with subsequent dissolution, has beenreported from San Salvador Island (Mylroie and Balcerzak1992; Bottrellet al. 1993). The activeedgeofthefresh-waterlens is whereboth the top of the watertableand the mixingzone are closetogether, enhancingthe effect oforganicload­ing on limestone dissolution within the active edge and in­creasingporosity.

The magnitude and distribution of organic matterinput to the fresh-water lens are controlled largelyby the na­tureofkarstic permeability, volume of flow, and hydrologicalroutingat thesurfaceand in the vadose zone(Whitaker 1992).Organic input to the majority of the aquifer occurs via fis­sures, fractures and root channels,and it is their linear fre­quency, diameterand tortuosity which limits the particulateinput to the fresh-water lens. Therefore the high-permeabil­ity epikarst and the low thicknessof the vadose zone abovethe activeedgeof the fresh-water lens increases the possibil­ity of organicmatterreaching the watertable. As previouslydescribed, oxidation of this organic matter, and subsequentoxidation-reduction reactionscan increaselimestone dissolu­tion if the organicloading is sufficient (Bottrell et al. 1991).

(anddune)interior. This couplingoftheepikarstto thefresh­water lens at the activeedge of the lens has pronounced im­plications for porosity development (Mylroie and Carew1995b).

CONCLUSIONS

A large catchmentarea or high rechargeincreasesthe thickness of the fresh-water lens. Figure 6 shows crosssections of the fresh-water lens for islandwidthsof 2 km and20km. Although the specific discharge is higherin islandsofgreaterwidth,the wateris lessaggressive due to its longresi­dence time. In this case the aggressivity produced by a con­stant value of organic matter is widely dispersed in a thicklens whichmayreducethe porositydevelopment per unit vol­umeof aquifer.

The mixingof vadoseand phreaticwater at the topof the fresh-water lens and the mixing of fresh and salinewaterat thebottom of the lensenhancelimestone dissolution.The presence of organics produces carbon dioxide throughoxidation, which createscarbonicacid for further limestonedissolution. Thisoxidation can leadtoanoxicconditions andoxidation-reduction reactionsthat againenhancedissolution.Independent of these chemical processes, the natural thin­ning of the lens at the lens margin creates a higher specificdischarge than elsewhere in the lens. Asa consequence ofthe

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HYDRODYNAMIC BEHAVIOROF CAVES IN CARBONATE ISLANDS

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Received: May 6, 1995Accepted: September19, 1995

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