DAVICOM Semiconductor Inc. - DACOM West

30
Total mass of part Unit 187.22 mg Die UMC 8-inch wafer Si 7440-21-3 100.00% 1.067000 1.067000 0.569930 2 Ni 7440-02-0 4.20% 1.687140 Si 7440-21-3 1.20% 0.482040 Mg 7439-95-4 0.30% 0.120510 Cu 7440-50-8 94.30% 37.880310 Epoxy ResinA Trade Secret 2.50% 3.638750 Epoxy ResinB Trade Secret 2.50% 3.638750 Phenol Resin Trade Secret 5.00% 7.277500 Carbon black 1333-86-4 0.30% 0.436650 Silica fused 60676-86-0 79.40% 115.566700 Silica fused 7631-86-9 10.00% 14.555000 Silica, crystalline 14808-60-7 0.30% 0.436650 Ag 7440-22-4 60-100% 0.038080 Epoxy Resin 9003-36-5 15-40% 0.016065 t-Butyl phenyl glycidyl ether 3101-60-8 5-10% 0.004165 Phenolic resin 92-88-6 0.5-1.5% 0.000595 Butyl cellosolve acetate 112-07-2 0.5-1.5% 0.000595 Cu 7440-50-8 98.00% 0.000980 Pd 7440-05-3 1.90% 0.000019 Ag 7440-22-4 0.10% 0.000001 Plating on Lead SHENMAO H99.99S Sn 7440-31-5 100.00% 0.368439 0.368439 0.196799 26 Updated: 2014/06/03 DAVICOM Semiconductor Inc. Part Number: DM9161EP-NT/9161AEP-NT/9161BEP-NT/9161BIEP-NT/9161CEP-NT/9161CIEP-NT/9162EP- NT/9162IEP-NT, DM9000AEP-NT/9000BEP-NT/9000BIEP-NT/9000CEP-NT/9000CIEP/9000DEP-NT, DM9008AEP-NT, DM9331AEP-NT Section Supplier Name Item No. Substance constituting section CAS No. Composition (%) Weight (mg) Total Material Weighting (mg) Total Material Weighting (%) MSDS Page# Lead & Leadframe pad ASM C7025 40.170000 21.456506 6 Die Attach Material SUMITOMO CRM-1033BF 0.059500 0.000534 0.031781 15 Bond Wire MK ELECTRON Copper Wire 0.001000 Epoxy Mold Compound SUMITOMO G631H 145.550000 77.744449 10 MSDS - LQFP48L (7x7) Green Product 20

Transcript of DAVICOM Semiconductor Inc. - DACOM West

Total mass of part Unit

187.22 mg

Die UMC 8-inch wafer Si 7440-21-3 100.00% 1.067000 1.067000 0.569930 2

Ni 7440-02-0 4.20% 1.687140

Si 7440-21-3 1.20% 0.482040

Mg 7439-95-4 0.30% 0.120510

Cu 7440-50-8 94.30% 37.880310

Epoxy ResinA Trade Secret 2.50% 3.638750

Epoxy ResinB Trade Secret 2.50% 3.638750

Phenol Resin Trade Secret 5.00% 7.277500

Carbon black 1333-86-4 0.30% 0.436650

Silica fused 60676-86-0 79.40% 115.566700

Silica fused 7631-86-9 10.00% 14.555000

Silica, crystalline 14808-60-7 0.30% 0.436650

Ag 7440-22-4 60-100% 0.038080

Epoxy Resin 9003-36-5 15-40% 0.016065t-Butyl phenyl glycidyl

ether3101-60-8 5-10% 0.004165

Phenolic resin 92-88-6 0.5-1.5% 0.000595

Butyl cellosolve acetate 112-07-2 0.5-1.5% 0.000595Cu 7440-50-8 98.00% 0.000980Pd 7440-05-3 1.90% 0.000019Ag 7440-22-4 0.10% 0.000001

Plating on Lead SHENMAO H99.99S Sn 7440-31-5 100.00% 0.368439 0.368439 0.196799 26

Updated: 2014/06/03

DAVICOM Semiconductor Inc.

Part Number: DM9161EP-NT/9161AEP-NT/9161BEP-NT/9161BIEP-NT/9161CEP-NT/9161CIEP-NT/9162EP-NT/9162IEP-NT, DM9000AEP-NT/9000BEP-NT/9000BIEP-NT/9000CEP-NT/9000CIEP/9000DEP-NT, DM9008AEP-NT,

DM9331AEP-NT

Section Supplier Name Item No.Substance constituting

sectionCAS No. Composition (%) Weight (mg)

Total MaterialWeighting

(mg)

Total MaterialWeighting (%)

MSDSPage#

Lead &Leadframe pad

ASM C7025 40.170000 21.456506 6

Die AttachMaterial

SUMITOMO CRM-1033BF 0.059500

0.000534

0.031781 15

Bond Wire MK ELECTRON Copper Wire 0.001000

Epoxy MoldCompound

SUMITOMO G631H 145.550000 77.744449 10

MSDS - LQFP48L (7x7) Green Product

20

MSDS/SDS Ver.04

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1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY

1.1. Identification of the product: Finished wafer _ Al process

1.2. Use of the product: Components of electrical and electronic equipments

1.3. Company identification: Company name: United Microelectronics Corporation ( UMC ) Address: No. 3, Li-Hsin Rd. II, Hsinchu Science Park, Taiwan 300, R.O.C. Telephone number: 886-3-5782258 & FAX number: 886-3-5784641 Sheet prepared by: Yuan Wei Tsai & E-mail: [email protected]

1.4. Emergency telephone: 886-3-5782258 ext: 31557

2. HAZARDS IDENTIFICATION

2.1. GHS classification & symbol: NA

2.2. Hazard statement: Physical and chemical hazards: NA Human health and environments effects: NA Principal hazards: NA Specifics hazards: NA

3. COMPOSITION/ INFORMATION ON INGREDIENTS

ELEMENT CAS NUMBER CONTENT (% Weight) Boron (B) 7440-42-8 0.000023 Aluminum (Al) 7429-90-5 2.654975 Titanium (Ti) 7440-32-6 0.008089 Tungsten (W) 7440-33-7 0.290804 Silicon (Si) 7440-21-3 97.227292 Arsenic (As) 7440-38-2 0.000061 Magnesium (Mg) 7439-95-4 0.000007 Potassium (K) 7440-09-7 0.000029 Calcium (Ca) 7440-70-2 0.000043 Iron (Fe) 7439-89-6 0.000029 Copper (Cu) 7440-50-8 0.000093 Zinc (Zn) 7440-66-6 0.000029 Sodium (Na) 7440-23-5 0.000020 Phosphorus (P) 7723-14-0 n.d. (not detected) Fluorine (F) 7782-41-4 n.d. (not detected) Nickel (Ni) 7440-02-0 0.000001 Cobalt (Co) 7440-48-4 0.000001 Tantalum (Ta) 7440-25-7 0.000001 Antimony (Sb) 7440-36-0 0.000004

Sum in total 100

MSDS/SDS Ver.04

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4. FIRST AID MEASURES

4.1. General information: Inhalation: NA Skin contact: Flush with water Eye contact: Flush with water Ingestion: NA

4.2. Symptoms/Effects: Acute: Slight irritation by mechanical effects is possible. Delayed: No information on significant adverse effects.

4.3. Advice to doctor: NA

5. FIRE-FIGHTING MEASURES

5.1. Suitable extinguishing media: NA

5.2. Unsuitable extinguishing media: NA

5.3. Specific fire and explosion hazards: NA

5.4. Additional information for firefighters & protection equipments: NA

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions: NA

6.2. Environmental precautions: NA

6.3. Methods for cleaning up: Use dustless method (vacuum) and place into closable container for disposal, or flush with water.

7. HANDLING AND STORAGE

7.1. Handling: Keep container closed when not in use. Keep away from incompatible substances.

7.2. Storage: Keep container tightly closed and properly labeled. Store in a cool, dry and well-ventilated area away from incompatible substances. Avoid heat, flames, sparks and other sources of ignition.

7.3. Specific use(s): NA

8. EXPOSURE CONTROLS/ PERSONAL PROTECTION

8.1. Exposure limit values: TLV: NA

8.2. Exposure controls: 8.2.1. Occupational exposure controls:

Respiratory protection: Use NIOSH approved dust respirator. Hand protection: Impervious gloves Eye protection: Safety or chemical tight goggles Skin protection: Wear suitable protective clothing.

8.2.2. Environmental exposure controls: NA

MSDS/SDS Ver.04

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9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. General Information: Physical state: Solid Color: Iron gray Odor: Odorless

9.2. Important health, safety and environmental information:

pH: NA Boiling point/ Boiling range: 2230 °C Flash point: NA Flammability (solid, gas): NA

Explosive properties: NA Oxidizing properties: NA Vapor pressure: NA (air=1) Relative density: 2.2 g/cm3 (specific gravity) Solubility: NA Water solubility: Virtually insoluble in water

Partition coefficient: n-octanol/water: NA Viscosity: NA Vapor density: NA Evaporation rate: NA

9.3. Other information: NA

10. STABILITY AND REACTIVITY

10.1. Stability:Stable

10.2. Conditions to avoid: Contact with powerful oxidizing agents such as Fluorine, Chlorine Trifluride, Oxygen Difluride, may cause fires.

10.3. Materials to avoid: Strong oxidizing agents.

10.4. Hazardous decomposition products: Silicon will dissolve in Hydrofluoric acid and produce a corrosive gas- Silicon Tetrafluoride.

11. TOXICOLOGICAL INFORMATION

Acute toxicity: NA

Locals effects: NA

Irritation: NA

Corrosiveness of skin: NA

12. ECOLOGICAL INFORMATION

12.1. Ecotoxicity: NA

12.2. Mobility: NA

12.3. Persistence and degradability: NA

12.4. Bioaccumulative potential: NA

12.5. Results of PBT assessment: NA

12.6. Other adverse effects: NA

MSDS/SDS Ver.04

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13. DISPOSAL CONSIDERATIONS

Waste disposal: Landfill or recycle in accordance with local pollution regulations.

Caution: NA

14. TRANSPORT INFORMATION

14.1. Classification according to ADR: Not regulated as a hazardous material.

14.2. Classification according to IMDG: Not regulated as a hazardous material.

14.3. Classification according to IATA: Not regulated as a hazardous material.

15. REGULATORY INFORMATION

Health, safety and environmental information shown on the label according to Directives 67/548/EEC and 1999/45/EC: NA

16. OTHER INFORMATION

A material safety data sheet (MSDS/SDS) is a form with data regarding the properties of chemicals. Semiconductor wafer is not a chemical substance nor preparation and will be further processed to become components of electrical and electronic products. This MSDS/SDS is not necessary to serve the same purpose of chemical MSDS/SDS but to fulfill our customers' needs in information of wafer property. The format of this MSDS/SDS follows the requirements of Regulation (EC) 1907/2006 the Registration, Evaluation, Authorization and restriction (REACH) and Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

Revision date:2010/08/18

Product name

Date prepared : 4/23/08

1. Product Identification

2. Composition / Information of ingredients (% by weight)

C7025BAL

--

0.25-1.20

-2.2-4.2

-------

0.05-0.30

--

0.5-0.8

3. Physical properties

Si

Emergency assistance ASM Technology Singapore Pte Ltd2 Yishun Avenue 7,Singapore 768924Phone: (65) 67526311

Co

ConstituentCuFe

PdAu

Ag

ZrSnPZn

MgCrPb

C

MnNi

: 1L02005 (Ag platedC7025 Leadframe)

Material Safety data Sheet

ASM Assembly Materials Ltd.4/F, Waston Centre, 16 Kung Yip St.,Kwai Chung, Hong Kong.Phone: (852) 2619 4262

1L02005 (Ag plated C7025 Leadframe)Ag plated leadframe

Product nameChemical familyManufacturer

Page 1 of 4

Product name

Date prepared : 4/23/08

: 1L02005 (Ag platedC7025 Leadframe)

Material Safety data Sheet

4. Fire, explosion, stability and reactivity information

5. Health hazard information

6. Emergency and first aid procedures

Incompatibility(Materials to avoid)

Skin contact with this material may cause, in some sensitiveindividuals, an allergic response if element such as copper andnickel are present.Particulate metal (dust) may be dangerous to the eye andsurrounding tissue.

Strong Acid (hydrogen gas envolved if contact)

Not applicableNot applicable

Inhalation

Ingestion

InhalationIngestionSkin

Swallowing metal power or dust can be treated by having the affected personswallow large quantities of water and attempting to induce vomiting ifconscious. Obtain medical assistance at once.

Breathing difficulty caused by inhalation of dust requires remove to fresh air.If breathing has stopped, perform artificial respiration an dobtain medicalassistance at once.

There is no information on the toxicity of this material. Undernormal handling and use of the solid form of this material there arefew health hazards.

Toxicity

Eye

AppearanceOdor No odor

None

Solid

None (LFL: not applicable, UFL: not applicable)Leadframe is noncombustible. Use extinguishing media appropriateto the surrounding fireLeadframe is a stable material

Flash pointFlammable limitsExtinguishing media

Chemical stability(conditions to avoid)

Not applicableNot applicableNot applicableInsoluble in water

Not applicableNot applicable

Evaporation rate

Melting point / Boiling pointSolubility in waterVapor density (Air=1)

Freezing pointVapor pressure (mmHg)

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Product name

Date prepared : 4/23/08

: 1L02005 (Ag platedC7025 Leadframe)

Material Safety data Sheet

7. Exposure control / Personal protection

8. Handling and storage

9. Environmental protection information

10. Transportation information

Additional Information

Not a hazardous material for shipping

Dust or powder should be flushed from the eyes with copious amounts ofclean water. If irritation persists obtain medical assistance. Contact lensesshould not be worn if working with metal dusts and powders.

Transportation andhazardous materials

Prior to disposal consider if the material has recovery value. Dispose ofmaterials in compliance with governmental regulations

Waste disposalmethod

In solid form this material poses on special environmentalproblems.

Environmentalhazards

Good housekeeping in order to prevent the accumulation of dustStore in original vacuum sealed packing.Storage condition: 19 to 25 °C and relative humidity <= 60%

HandlingStorage

Good general ventilation should be sufficient for most conditions.

For most conditions, no respiratory protection should be needed;however, in dusty atmospheres, wear a NIOSH approved respiratorto protect from dust.

Wear safety glasses when risk of eye injury is present, for example,metal powder handling.Wear clean body covering clothing. Wear gloves to prevent metalcuts and skin abrasions.

Ventilation

Respiratory protection

Eye protection

Skin protection

Skin

Eye

Skin cuts and abrasions can be treated by standard first aid. Skincontamination with dust or powder can be removed by washing with soapand water. If irritation persists, obtain medical assistance at once.

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Product name

Date prepared : 4/23/08

: 1L02005 (Ag platedC7025 Leadframe)

Material Safety data Sheet

This information in this document is believed to be correct as of the date issued. However, nowarranty of merchantability, fitness for any use, or any other warranty is expressed or is to beimplied regarding the accuracy or completeness of this information, the results to be obtainedfrom use of this information or the product, the safety of this product, or the hazards related toits use. This inforamtion and the product are furnished on the condition that the personreceiving them shall make their own determination as to the suitability of the product for theirparticular purpose and on the condition that they assume the risk their use thereof.

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SAFETY DATA SHEET

1. Product and company identification

Product name SUMIKON® EME-G631H Type Q

Company information

SUMITOMO BAKELITE CO.,LTD.

Tennoz Park Side Bldg.

5-8, Higashi-Shinagawa 2-Chome

Shinagawa-ku, Tokyo 140-0002, Japan

Phone: +81-3-5462-4267 e-mail: [email protected]

++++++++++++++++++++++++++++++++++++++++++++++++++

EMERGENCY CONTACTS:

SUMITOMO PLASTICS AMERICA, INC. Phone: +1-408-243-8402 (U.S.A.)

CHEMTREC (24hours everyday) Phone: +1-800-424-9300 (U.S.A.)

SUMITOMO BAKELITE SINGAPORE PTE.LTD. Phone: +65-6755-5550 (Singapore)

N.V. SUMITOMO BAKELITE EUROPE S.A. Phone: +31-2-709-2139 (Belgium)

SUMITOMO BAKELITE (SUZHOU) CO.,LTD. Phone: +86-512-67613850 (China)

SUMITOMO BAKELITE (TAIWAN) CO.,LTD. Phone: +886-7-787-1285 (Taiwan)

SUMITOMO BAKELITE (SINGAPORE) CO., LTD. MALAYSIA Branch Office.

Phone: +60-3-7660-8022 (Malaysia)

++++++++++++++++++++++++++++++++++++++++++++++++++

Product uses Epoxy Molding Compound for Encapsulant of Semiconductors.

Intended use For Semiconductors.

 

2. Hazards identification

GHS classification

The product is not classified according to GHS.

*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".

GHS label elements

None.Symbols

Signal words None.

Hazard statement None.

Precautionary statement

Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Use personal protective equipment as required.

Response IF exposed or concerned: Get medical advice/attention.

Storage Store in accordance with local/regional/national/international regulation.

Disposal Dispose of contents/container (in accordance with related regulations).

 

Chemical Name PercentageCAS #

3. Composition/information on ingredients

1 - 5Trade SecretEpoxy Resin A

1 - 5Trade SecretEpoxy Resin B

5 - 10Trade SecretPhenol Resin

70 - 8060676-86-0Silica(Amorphous) A

5 - 107631-86-9Silica(Amorphous) B

0.1 - 11333-86-4Carbon Black

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Composition comments The range of Concentration is greater than or equal to the lower limit but less than or the upperlimit.Silica(Amorphous) of Raw material contains a very slight Silica(Crystal).

 

4. First aid measures

First aid measures for different exposure routes

Inhalation If dust from the material is inhaled, remove the affected person immediately to fresh air. Call aphysician if symptoms develop or persist.

Skin contact Rinse skin with water/shower. Get medical attention if irritation develops and persists.

Eye contact Rinse with water.

Ingestion If ingestion of a large amount does occur, call a poison control centre immediately.

Most important symptomsand effects

Not available.

Personal protection forfirst-aid responders

First aid personnel must wear protective gloves/protective clothing/eye protection/face protection.IF exposed or concerned: Get medical advice/attention.

Notes to physician Symptoms may be delayed.

 

5. Fire-fighting measures

Extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Extinguishing media to avoid None known.

Specific hazards during firefighting

Development of hazardous combustion gases or vapours possible in the event of fire.

Special fire fightingprocedures

Cool containers exposed to flames with water until well after the fire is out.

Protection of fire-fighters Wear suitable protective equipment.Use personal protective mask and fight fire from upwind, to avoid fumes upon combustion.

 

6. Accidental release measures

Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spillagescannot be contained. Avoid inhalation of dust from the spilled material.Wear a dust mask if dust is generated above exposure limits.

Environmental precautions Not available.

Spill cleanup methods If sweeping of a contaminated area is necessary use a dust suppressant agent which does notreact with the product.Sweep up or vacuum up spillage and collect in suitable container for disposal. Collect dust using avacuum cleaner equipped with HEPA filter. Avoid the generation of dusts during clean-up.Following product recovery, flush area with water. For waste disposal, see section 13.

 

7. Handling and storage

Handling

Technical measures None known.

Local and generalventilation

Provide adequate ventilation. Provide appropriate exhaust ventilation at places where dust isformed. In case of insufficient ventilation, wear suitable respiratory equipment.

Precautions Keep formation of airborne dusts to a minimum.In case of insufficient ventilation, wear suitable respiratory equipment.

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Safe handling advice Do not breathe dust.Avoid contact with eyes.Avoid prolonged exposure.

Storage

Technical measures Guard against dust accumulation of this material.

Suitable storageconditions

Store in a well-ventilated place. Keep container tightly closed. Guard against dust accumulation ofthis material.Keep dry and cool below 5°C for quality.

Safe packaging materials None known.

 

8. Exposure controls/personal protection

Exposure limits

Taiwan. OELs. (Standards on Workplace Atmosphere of Dangerous and Hazardous Materials)

ValueComponents Type

TWA 3.5 mg/m3Carbon Black (CAS1333-86-4)

Occupational exposure limits

US. ACGIH Threshold Limit Values

ValueComponents FormType

TWA 3 mg/m3 Inhalable fraction.Carbon Black (CAS1333-86-4)

Engineering measures Ventilation should be sufficient to effectively remove and prevent buildup of any dusts or fumesthat may be generated during handling or thermal processing.If engineering measures are not sufficient to maintain concentrations of dust particulates belowthe OEL (occupational exposure limit), suitable respiratory protection must be worn.

Personal protective equipment

Respiratory protection Wear respirator with dust filter.

Hand protection Use protective gloves as required.

Eye protection Use tight fitting goggles if dust is generated.

Skin and body protection Use personal protective equipment as required.

Hygiene measures Do not breathe dust. Avoid contact with eyes. Handle in accordance with good industrial hygieneand safety practices.

 

9. Physical and chemical properties

Appearance

Physical state Solid.

Form Tablet. Powder.

Colour Black.

Odour Epoxy.

Odour threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Boiling point, Initial boilingpoint, and boiling range

Not available.

Flash point Not available.

Auto-ignition temperature Not available.

Flammability limit - lower(%)

Not available.

Flammability limit - upper(%)

Not available.

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Vapour pressure Not available.

Vapour density Not available.

Evaporation rate Not available.

Specific gravity 1.8 - 2.2

Relative density Not available.

Solubility Not available.

Partition coefficient(n-octanol/water)

Not available.

Decomposition temperature Not available.

 

10. Stability and reactivity

Stability Stable under recommended storage conditions.

Possibility of hazardousreactions

Hazardous polymerisation does not occur.

Conditions to avoid Avoid spread of dust. Keep away from heat, moisture and sunlight for quality.

Incompatible materials Strong acids, alkalies and oxidizing agents.

Hazardous decompositionproducts

No dangerous reaction known under conditions of normal use.

 

11. Toxicological information

Components Test results

Acute Oral LD50 Rat: > 8000 mg/kgCarbon Black (1333-86-4)

Acute Oral LD50 Rat: > 22500 mg/kgSilica(Amorphous) A (60676-86-0)

Acute Oral LD50 Rat: >= 22500 mg/kgSilica(Amorphous) B (7631-86-9)

Routes of exposure Inhalation.

Symptoms Not available.

Skin corrosion/irritation Not available.

Serious eye damage/eyeirritation

Dust in the eyes will cause irritation.

Respiratory sensitiser Not available.

Skin sensitiser Not available.

Carcinogenicity Risk of cancer cannot be excluded with prolonged exposure.

IARC Monographs. Overall Evaluation of Carcinogenicity

Carbon Black (CAS 1333-86-4) 2B Possibly carcinogenic to humans.

Silica(Amorphous) A (CAS 60676-86-0) 3 Not classifiable as to carcinogenicity to humans.

Silica(Amorphous) B (CAS 7631-86-9) 3 Not classifiable as to carcinogenicity to humans.

Toxic to reproduction Not available.

Specific target organtoxicity - single exposure

Not available.

Specific target organtoxicity - repeatedexposure

Not available.

Aspiration hazard Not available.

Chronic effects Prolonged inhalation may be harmful.Prolonged exposure may cause chronic effects.

 

12. Ecological information

Ecotoxicity There are no data on the ecotoxicity of this product.

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Persistence anddegradability

No data is available on the degradability of this product.

Bioaccumulation Not available.

Mobility in soil Not available.

Other hazardous effects Not available.

 

13. Disposal considerations

Residual waste Dispose of in accordance with local regulations.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

Local disposal regulations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose ofcontents/container in accordance with local/regional/national/internat ional regulations.

 

14. Transport information

IATA

Not regulated as dangerous goods.

IMDG

Not regulated as dangerous goods.

Special transport precautionsand conditions

Keep containers tightly closed. And take care leaks, spills or collapse of cargo, not to avoid damageof containers.Keep cool below 5°C.

 

15. Regulatory information

Applicable regulations This material safety data sheet was prepared in accordance with the Rules on HazardousCommunication of Dangerous Materials and Toxic Materials. Additional information is given in theSafety Data Sheet.

Taiwan Hazard - Toxic Materials: Classification

Silica(Amorphous) A (CAS 60676-86-0) Other designated chemical

Silica(Amorphous) B (CAS 7631-86-9) Other designated chemical

 

16. Other information

References NLM: Hazardous Substances Data BaseHSDB® - Hazardous Substances Data BankIARC (vol. 1~100A)ACGIH (2011)Taiwan. CNS15030 Z1051: Classification and Labeling of ChemicalsUN. Globally Harmonized System of Classification and Labelling of Chemicals (GHS)ST/SG/AC.10/30/Rev.3Japan. GHS Classifications of Regulated Chemicals (NITE)

Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable. SUMITOMO BAKELITE CO., LTD. cannot anticipate all conditions under which thisinformation and its product, or the products of other manufacturers in combination with itsproduct, may be used. It is the user’s responsibility to ensure safe conditions for handling, storageand disposal of the product, and to assume liability for loss, injury, damage or expense due toimproper use.

Material name: SUMIKON® EME-G631H Type Q

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SAFETY DATA SHEETPRODUCT NAME : "SUMIRESIN EXCEL" CRM-1033BFMSDS NO. : MSDS-CRM-421DATE PREPARED : Jan. 30, 2001 according to 93/112

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1.PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME : "SUMIRESIN EXCEL" CRM-1033BFCHEMICAL NATURE: Preparation. Epoxy Silver pasteMANUFACTURER : SUMITOMO BAKELITE CO., LTD.

Tennoz Parkside Bldg., 5-8, Higashi-Shinagawa 2-chome, Shinagawa-ku,Tokyo 140-0002, JapanPhone: 81-3-5462-4037

SUPPLIER : SUMITOMO BAKELITE CO., LTD.Tennoz Parkside Bldg., 5-8, Higashi-Shinagawa 2-chome, Shinagawa-ku,Tokyo 140-0002, JapanPhone: 81-3-5462-4037

EMERGENCY ASSISTANCE : (Please contact any of following sales offices)

NAME & EMERGENCY PHONE NUMBER ADDRESSSumitomo Plastics America, Inc.Phone 408-243-8402 (USA)

900 Lafayette Street, SUITE #510Santa Clara, CA 95050

Sumitomo Bakelite Singapore Pte, Ltd.Phone 65-755-5550 (Singapore)

1 Senoko South Road,Singapore 758069

Sumitomo Bakelite Europe B. V.Phone 020-691-10-86 (The Netherlands)

New Amsterdam BuildingHoekenrode 2, 1102 BR Amsterdam

CHEMTREC Phone 800-424-9300 (USA) 24 hours everyday

2.COMPOSITION / INFORMATION ON INGREDIENTSCOMPONENT CAS No. by weight (%)Silver 7440-22-4 60~100Epoxy Resin 9003-36-5 15~40t-Butyl phenyl glycidyl ether 3101-60-8 5~10Phenolic resin 92-88-6 0.5~1.5Butyl cellosolve acetate 112-07-2 0.5~1.5

Labeling according to EC directives:Hazardous components: noneHazard symbol : No symbol and risk phrases are required.Risk phrases : noneSafety phrase : none

3.HAZARDS IDENTIFICATION*** EMERGENCY OVERVIEW ***

Silver gray paste and slightly odor.The vapor irritates the eyes, the skin and the respiratory tract. Combustible liquid.

Epoxy Resin is a substrate known to be positive by Ames test.Foam, carbon dioxide and dry chemicals can be used on fires.

SAFETY DATA SHEETPRODUCT NAME : "SUMIRESIN EXCEL" CRM-1033BFMSDS NO. : MSDS-CRM-421DATE PREPARED : Jan. 30, 2001 according to 93/112

PAGE 2 of 5

POTENTIAL HEALTH EFFECTSEYE : Cause irritating to eyes.SKIN : May cause harmful if absorbed through the skin.INGESTION : Small amounts (teaspoonful) swallowed during normal handling operations are not

likely to cause injury; swallowing amounts larger than that may cause injury.INHALATION : Heated product may produce generate vapors. May be harmful for respiratory

tract if inhaled.

4.FIRST-AID MEASURESINHALATION : Immediately remove to the victim from the contamination to fresh air.SKIN CONTACT : Wash off thoroughly the affected areas under flowing water or shower with soap.

If irritation occurs,get medical attention.EYE CONTACT : Immediately flush eyes with large amounts of water for at 15 minutes. Get medical

attention.INGESTION : Do not induce vomitting. Rinse mouth with plenty of water and immediately give

the victim milk or water. Get medical advice.NOTE TO PHYSICIANS :

Treat symptomatically. Treatment may vary with condition of victim and specificsof incident.

5.FIRE-FIGHTING MEASURESEXTINGUISHING MEDIA:

Use foam, carbon dioxide or dry chemicalsPROTECTION OF FIREFIGHTERS:

Wear full bunker gear inducing positive self-contained breathing apparatus in anyclosed space.

6.ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTION:

Use personal protective equipments.ENVIRONMENTAL PRECAUTIONS:

Do not flush into surface water or sanitary sewer system.METHODS FOR CLEANING UP:

Ventilate spilled area. Remove all sources. Take up with absorbent,inert material(e.g. paper towel, sand) with suitable protective equipment and place in suitable,closed impervious container.

7.HANDLING AND STORAGEHANDLING : Use with adequate ventilation. Keep away from heat, sparks and open flames.

Avoid contact with eyes and skin, and avoid breathing of vapor if generated.Practice good personal hygiene after using this material, especially before eating,drinking smoking or using the toilet.

STORAGE : Keep container tightly closed in a below -15 degC, well-ventilated dark place forquality separate from strong oxidents, and protect from direct sunlight.

SAFETY DATA SHEETPRODUCT NAME : "SUMIRESIN EXCEL" CRM-1033BFMSDS NO. : MSDS-CRM-421DATE PREPARED : Jan. 30, 2001 according to 93/112

PAGE 3 of 5

8.EXPOSURE CONTROLS/PERSONAL PROTECTIONEXPOSURE LIMITS:

EXPOSURE GUIDELINES(mg/m3)COMPONENT ACGIH(TLV-TWA) OSHA(PEL)Silver 0.1(respirable) 0.01Epoxy Resin Not listed Not listedt-Butyl phenyl glycidyl ether Not listed Not listedPhenolic resin Not listed Not listedButyl cellosolve acetate Not listed Not listed

ENGINEERING MEASURES:Provide general and/or local exhaust ventilation to control airborne levels belowthe exposure guidelines. Good general ventilation should be sufficient for mostconditions. When processing at elevated temperature, provide local exhaustventilation. Good general ventilation should be sufficient for most conditions.

PERSONAL PROTECTIVE EQUIPMENTS:Respiratory protection - Wear an approved respirator to protect from vapors or fume.Hand protection - Chemical-resistant gloves.Eye protection - Chemical splash goggles or safety glass with side-shields.Skin & body protection - Clean clothing, long sleeves, apron, full-face cover or legs-covering clothing

as appropriate.

9.PHYSICAL AND CHEMICAL PROPERTIESAPPEARANCE : Silver gray paste with slightly odor.pH : No information available.BOILING POINT : 165~170 degC/14mmHg (as t-Butyl phenyl glycidyl ether)

191.5 degC (as Butyl cellosolve acetate).DECOMPOSITION TEMPERATURE : No information available.FLASH POINT : 259 degC (as Epoxy Resin)

71 degC (as Butyl cellosolve acetate)AUTOIGNITION TEMPERATURE : 340 degC (as Butyl cellosolve acetate).EXPLOSION PROPERTIES : Not applicable.VAPOR PRESSURE : 0.31 hPa (as Butyl cellosolve acetate).VAPOR DENSITY : 5.5 (Air=1, as Butyl cellosolve acetate).DENSITY : 3.4~3.6SOLUBILITY : Moderate (1.7 g/100ml at 200 degC, as Butyl cellosolve acetate) in water.

SAFETY DATA SHEETPRODUCT NAME : "SUMIRESIN EXCEL" CRM-1033BFMSDS NO. : MSDS-CRM-421DATE PREPARED : Jan. 30, 2001 according to 93/112

PAGE 4 of 5

10.STABILITY AND REACTIVITYSTABILITY : Stable under recommended storage conditions.CONDITIONS TO AVOID :

Keep away from heat, open flame, sparks and sunlight for quality.MATERIALS TO AVOID :

Oxidizing agents or base. Butyl cellosolve acetate reacts with strong oxidantscausing fire and explosion hazard.

HAZARDOUS DECOMPOSITION PRODUCTS :Mainly: Carbon oxideSlightly: Carbon monoxide, various hydrocarbons and chlorine compounds.(over 400 degC)

11.TOXICOLIGICAL INFORMATIONACUTE TOXICITY : Epoxy Resin ---- orl-rat LD50: >2,000 mg/kg

skin-rat LD50: >400 mg/kgt-Butyl phenyl glycidyl ether --- orl-rat LD50: 3.73 ml/kgPhenolic resin --- orl-rat LD50: 9,850 mg/kgButyl cellosolve acetate --- orl-rat LD50: 2,400 mg/kg

skin-rbt LD50: 1,500 mg/kgLOCAL EFFECTS : Irritating to eyes and skin.SENSITIZATION : May cause sensitization by skin contact.CHRONIC TOXICITY: Potential carcinogenIARC : Not listedNTP : Not listedOSHA : Not regulated

12.ECOLOGICAL INFORMATIONMOBILITY : No data is available on the product itself.ECOTOXICITY : May cause long-term adverse effects in the aquatic environment.

13.DISPOSAL CONSIDERATIONWASTE FROM RESIDUES :

Can burn in a chemical incinerator equipped with an afterburner and scrubberin compliance with government or local disposal regulations, also contaminatedpackagings do so.

14.TRANSPORT INFORMATIONNot a hazardous material for D.O.T. (Department Of Transportation) shipping.Not dangerous by any mode of international transport.UN No. : None assigned.

SAFETY DATA SHEETPRODUCT NAME : "SUMIRESIN EXCEL" CRM-1033BFMSDS NO. : MSDS-CRM-421DATE PREPARED : Jan. 30, 2001 according to 93/112

PAGE 5 of 5

15.REGULATORY INFORMATIONTSCA(TOXIC SUBSTANCES CONTROL LAW):

The ingredients of this product are all on the 8(b) inventory list.

EINECS(EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES)This product complies with the provisions of the European Inventory.EINECS No. Silver: 231-131-3

t-Butyl phenyl glycidyl ether: 221-453-2Phenolic resin: 202-200-5Butyl cellosolve acetate: 203-933-3

NLP No. Epoxy Resin: 500-006-8

Labeling according to EC Directives:Hazard symbol: No symbol and risk phrases are required.Risk phrases: noneSafety phrase: none

16.OTHER INFORMATIONDISCLAIMER : The information presented herein was prepared for your reference to be best of our

knowledge. It is given in good faith but no warrantly expressed on implied is made.

DATA PREPARED BY :N.OSUGA, QA MANAGERUTSUNOMIYA PLANTSUMITOMO BAKELITE CO., LTD.

Common name Palladium Coating Copper Bonding Wire Code Not available Supplier MK ELECTRON CO.,LTD MSDS# Not available Synonym Cu Wire, Bonding Wire, Bumping Wire, Copper Wire Print Date Jan 25, 2010 Trade name Not available Material Uses Industrial applications : Bonding, Bumping In case of

Emergency Korea & International Manufacturer MK ELECTRON CO.,LTD Tel : (82)031-330-1900

316-2, Kumeu-ri, Pogok-eup, Cheoin-gu, Yongin, Gyeonggi-do, Fax: (82)031-338-6817449-810, Korea

Min 98%

below 20ppmPalladium 7440-05-3 0.5 ~ 2.0%

Material Safety Data SheetSection 1. Chemical product and Company Identification

Section 2. Composition and Information on Ingredients

7440-50-8 CAS# Name Type of Copper Bonding Wire Percent Weight

PC Copper

- Page : 1 of 6 -Continued on Next Page

7440-22-4Silver

I. PRODUCT IDENTIFICATION

Product Name : Palladium Coating Copper Bonding WireSynonyms : Cu Wire, Bonding Wire, Bumping Wire, Copper WireDescription : MetalManufacturer : MK ELECTRON CO., LTD.Address : 316-2, Kumeu-ri, Pogok-eup, Cheoin-gu, Yongin, Gyeonggi-do, 449-810, Korea

II. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Ingredients (% by Weight)

III. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW: Moderate eye irritant. Will not burn. Toxic by inhalation. Moderate gastrointestinal tract irritant. Moderate respiratory tract irritant. Causes skin irritation.

ROUTES OF ENTRY: Inhalation ; Ingestion ; Skin Contact ; Eye Contact ; Absorption.

TARGET ORGANS: Blood ; Digestive tract ; Kidneys ; Nervous System.

MEDICAL CONDITIONS AGGRAVATED: Digestive tract disease ; Kidney disease.

IMMEDIATE (ACUTE) SYMPTOMS OVER-EXPOSURE BY ROUTE OF EXPOSURE: - Eye Contact : Can cause moderate irritation, tearing and reddening, but not likely to permanently injure eye tissue. - Skin Contact : Can cause slight skin irritation. - Inhalation : Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea and headache. - Ingestion : Irritating to mouth, throat and stomach. Can cause abdominal discomfort, nausea, vomiting and diarrhea.

LONG TERM (CHRONIC) HEALTH EFFECTS: - Carcinogenicity : None of the substances have been shown to cause cancer in long term animal studies. Not a carcinogen

according to the NTP, IARC or OSHA. - Reproduction : No data available to indicate prooduct or any components present at greater than 0.1% may cause birth

defects.

7440-05-3 0.5 ~ 2.0%Silver 7440-22-4 below 20ppm

MATERIAL SAFETY DATA SHEET

Continued on Next Page - Page : 2 of 6 -

Ingredient CAS Number Percent WeightCopper 7440-50-8 Min 98%

Palladium

- Mutagenicity : No data available to indicate product or any components present at greater than 0.1% is mutagenic or genotoxic.

HMIS CODE : (Health : 2) (Flammability : 0) (Reactivity : 0) (Protection : B)

NFPA CODE : (Health : 2) (Flammability : 0) (Reactivity : 0)

IV. FIRST AID MEASURES

EYE: Immediately flush eyes with plenty of water for at least twenty minutes retracting eyelids often. Tilt the head to prevent chemical from transferring to the uncontaminated eye. Get immediated medical attention.

SKIN: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops persists.

INHALATION: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not breathing, give artificial respiration and have a trained individual administer oxygen. Get medical attention immediately.

INGESTION: Seek medical attention immediately.

NOTES TO DOCTOR: No additional first aid information available.

V. FIRE FIGHTING MEASURES

FLASHPOINT : N/A

UEL : Not determined

LEL : Not determined

AUTOIGNITION TEMPERATURE : N/E

FLAMMABILITY CLASSIFICATION : Not combustible.

FIRE-FIGHTING EQUIPMENT : Will not burn, no special instructions available. Use methods for surrounding the fire.

HAZARDOUS COMBUSTION PRODUCTS : Metal fumes, toxic fumes.

Continued on Next Page - Page : 3 of 6 -

VI. ACCIDENTAL RELEASE MEASURES

PRECAUTIONS AND EQUIPMENT: Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in section 8 of this MSDS.

METHODS FOR CLEAN-UP: Wear complete and proper personal protective equipment following the recommendation of section 8. Gather and store in a sealed container pending a waste disposal evaluation. Do not use broom or air cleaning etc.

VII. HANDLING AND STORAGE

HANDLING: Harmful of irritating material. Avoid contact and avoid breathing the material. Use only in a well ventilated area. As with all chemicals, good industrial hygiene practices should be followed when handling this material. Avoid contact with the material, avoid breathing dust or fumes, use only in a well ventilated area. Wash thoroughly after handling ; do not get in eyes, on skin and clothing ; Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation.

STORAGE: No special requirements. Store in a tightly closed container ; Keep away from food and drinking water.

VIII. EXPOSURE CONTROLS AND PERSONAL PROTECTION

EYE: Wear chemically resistant safety glasses with side shields when handling this product. Do not wear contact lenses. Wear goggles and a face shield. Have an eye wash station available.

SKIN: Wear protective gloves. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking and when leaving work. Where contact is likely, wear chemical resistant gloves, a chemical suit, rubber boots and chemical goggles, plus a safety shield.

INHALATION: Respiratory protection may be required to avoid overexposure when handling this product. General or local exhaust ventilation is the preferred means of protection. Use a respirator if ventilation is not available or sufficient to eliminate symptoms. Follow a respiratory protectionprogram that meet 29 CFR 1910.134 and ANSI Z88.2 requirements whenever work place conditions warrant the use of a respirator. Wear a NIOSH approved respirator if any exposure is possible.

ENGINEERING CONTROLS: Use local exhaust ventilation or other engineering controls to minimize exposures and maintain operator comfort. Engineering controls must be designed to meet the OSHA Chemical Specific Standard in 29 CFR 1910. Use process enclosures, local exhaust ventilation or other engineering controls to control airborne levels below recommended exposure limits.

Continued on Next Page - Page : 4 of 6 -

EXPOSURE GUIDELINES :

IX. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE AND ODOR : Gray. None.

pH : N/A.

SOLUBILITY IN WATER : Negligible ; 0 - 1%.

X. STABILITY AND REACTIVITY

STABILITY: Decomposition Products : Metal fumes ; Toxic fumes.

CONDITIONS TO AVOID: None known. Contamination. Contact with air. Contact with water.

MATERIALS TO AVOID: Strong oxidizing agents ; Strong acids ; Peroxides ; Metals ; Strong reducing agents ; Chlorince ; Strong alkalies.

XI. TOXICOLOGICAL INFORMATION

COMPONENT TOXICOLOGY DATA (NIOSH): Chemical Name LD50 / LC50

XII. ECOLOGICAL INFORMATION

OVERVIEW: Slight ecological hazard. In high concentrations, this material may be dangerous to plants and / or wildife.

XIII. DISPOSAL CONSIDERATIONS

WASTE DESCRIPTION: Spent or discarded material may be hazardous waste.

DISPOSAL METHODS: Dispose of in accordance with Federal, State, Local or Provincial laws and regulations.

- Page : 5 of 6 -Continued on Next Page

CopperPalladium

Silver

0.2mg/m3 TWA

0.1mg/m3 TWAN/E

ComponentTLV-TWA STEL

ACGIH Exposure LimitsCEILING

XIIII. TRANSPORTATION INFORMATION

SHIPPING BASIC DESCRIPTION: - DOT & IATA : Not restricted.

XV. REGULATORY INFORMATION

TSCA STATUS: All components of this product are listed on the TSCA Inventory of Existing Chemical Substances.

REGULATED CHEMICALS

XVI. OTHER INFORMATION

Country of Origin : the Republic of Korea

MK ELECTRON CO., LTD.316-2, Kumeu-ri, Pogok-eup, Cheoin-gu, Yongin, Gyeonggi-do, 449-810, Korea

This material safety data sheet and the information it contains are offered to you in good faith as accurate. We have reviewed anyinformation contained in this data sheet which we received form sources outside our company. We believe that information to becorrect but cannot guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequatefor all individuals and / or situations. It is the user's obligation to evaluate and use this product safely and to comply with all applicablelaws and regulations. No statement made in this data sheet shall be construced as a permission or recommendation for the use ofany product in a manner that might infringe existing patents. No warranty is made, either express or implied.

Palladium SARA 313

- Page : 6 of 6 -

Chemical Name Regulation

Silver SARA 313

Continued on Next Page

Copper SARA 313

Material Safety Data Sheet

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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Chemical product name: PLATING ANODE BALL

Other name:

Product identifier: Sn99.99%-BALL

Suggest purpose: For plating process or wave soldering process.

Manufacture: SHENMAO TECHNOLOGY INC.

Address: No.12-1 Gongye 2nd Rd., Guanin industrial area, Taoyuan County 328, Taiwan

TEL: (886)3-416-0177 FAX: (886)3-416-0133

Website: http://www.shenmao.com

2. HAZARDS IDENTIFCATION Goods hazard classification: -

Indication content: -

Other hazard: -

3. COMPOSITION, INFORMATION OR INGREDIENT □Pure substances:

Components name: Tin

Other name:

CAS No.: 7440-31-5

Hazards composition (wt. %): 100%

4. FIRST AID MEASURES First aid method in the different exposed way:

Inhalation

1. Moves the patient to the fresh air place immediately.

2. If patient stop breathes, gives the artificial respiration.

3. Keep the patient to be warm and the rest.

4. Send him to the hospital immediately.

Skin contact

1. Use the soap or the neutral cleanser and the water clean the skin immediately.

2. If seeps clothes, takes off clothes immediately, and uses the soap or the neutral cleanser and

the water to cleans the skin.

3. If still had Irritation feeling, take medical treatment immediately.

Eye contact 1. Clean eye by the massive clear water immediately and often opens the eyelid.

2. If still had Irritation feeling, take medical treatment immediately.

Swallowing

1. If the patient soberly, drinks the massive water immediately.

2. Urges to vomit by the finger insertion throat.

3. If the patient is insensible, don’t urge to vomit.

4. If still had Irritation feeling, take medical treatment immediately.

Most important symptom and harm effect: Irritation feeling

Material Safety Data Sheet

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Protection to first-aid personnel: Should wear the level C protection equipment in the safe area

implementation first aid.

Prompt to doctor: If the patient swallows, consideration gastric lavage and bowel movement.

5. FIRE FIGHTING MEASURES Applicable fire-extinguishing: Water. During fire fighting may cause special harm:

The tin is nonflammable, but in the powder status it is inflammable. Fire fighting procedure:

1. Move the container out to the safe area.

2. Cooling storing or container expose in a fire scene with water.

3. Do not let water enter container. The fire fighter's equip: -

6. ACCIDENTAL RELEASE MEASURES Person-related safety precautions:

The man who without wear protect equipping or clothes forbidden enter in the let out area before clean. Measures for environmental protection: Ventilate to the let out area. Measures for cleaning/collecting:

1. Recycle the material or bury with the qualified method in most convenient and safe way.

2. The liquid can be absorbed with the vermiculite, sand, soil or similar material.

7. HANDLING AND STORAGE Handling: During work avoids producing the dust.

Storage:

1. Storage to suitably container which has the label.

2. Storage it in a coolly, dryly and ventilate well place.

3. Keep the flammable away.

4. Keep the oxidant away, such as chlorine ...etc.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering control:

1. Partial air exhaust device.

2. Whole air exhaust device. Control parameter:

TWA STEL CEILING BEIs

Tin 2 mg/m3 4 mg/m3 - -

Personal protection device:

Breath protection: 0~10 mg/m3: Dustproof breathing mask.

20 mg/m3: 1. Dustproof breathing mask. 2. Air supply type breathing mask.

Material Safety Data Sheet

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50 mg/m3: 1. Dustproof and air filter breathing mask. 2. Continuous air supply type

breathing mask.

100 mg/m3: 1.Contain high performance filter and air filter breathing mask. 2.

Continuous air supply type breathing mask.

Unknown consistency: Continuous air supply type breathing mask.

Escape: 1.Contain high performance filter and air filter breathing mask. 2. Continuous air supply

type breathing mask.

Hand protection: Rubber or plastic glove.

Eye protection: 1. The safe goggles which can defend splash. 2. Face guard in an all-round way. 3. Don’t

wear the contact lenses.

Skin and body protection: Apron, long sleeves clothes. Hygiene measure:

1. Take off the clothes of pollution as soon as possible after the work, wear or abandon after cleaning, and

tell the person about the pollutant who washing the clothes.

2. Forbid smoking or diet in the workplace.

3. After work, must wash hands completely.

4. Keep the workplace clean.

9. Physics and chemical property Appearance: Silver gray solid Smell: Tasteless

Odor Threshold: - Melting Point: 232℃

pH: - Boiling point/Boiling Range: 2270℃

Inflammable(in solid, air): -

Decompose Temp.: -

Flash Point: -

Test Method: -

Auto igniting: - Explosion Limit: -

Vapor Pressure: 0 mmHg @ 20℃ Vapor Density: -

Density: 7.3g/cm3 ( 20℃) Solubility: Difficult to mix with water

Log Octanol-Water Partitioning Coefficient: - Volatility: -

10. STABILITY AND REACTIVITY Stable: Stable under the normal state, the powder state will be oxidized in the air. Possible danger reacts under the special state:

1. Metal tin and turpentine contact will produce fire and explode.

2. Plastics, rubber.

3. Acid, soda, oxide, sulphur, halogens.

4. When the tin powder mixed with sodium peroxide, contact with the moisture will produces the fire; contact

the carbon dioxide or ammonium nitrate (higher than 200℃) will produces explode.

5. Carbon tetrachloride Tetrachloromethane (moisture existence), halide, cupric nitrate solution, potassium

peroxide.

Material Safety Data Sheet

4 / 5

Avoid state: The powder state will be oxidized in the air. Avoid matter:

1. Metal tin and turpentine contact.

2. Plastics, rubber.

3. Acid, soda, oxide, sulphur, halogens.

4. Tin powder mixed with sodium peroxide, carbon dioxide or ammonium nitrate (higher than 200℃).

5. Carbon tetrachloride Tetrachloromethane (in moisture existence), halide, cupric nitrate solution,

potassium peroxide. Dangerous products of decomposition: -

11. TOXICOLOGICAL INFORMATION Expose way: -

Symptom: -

Urgent toxicity:

1. May cause the irritation of eyes, nose, throat, skin.

2. It is nonpoisonous to eat. But it will let the stomach to be uncomfortable by irritation.

Slow toxicity or long-term toxicity:

1. The person who has the following conditions is easy to be endangered: Dermatosis, breathe disease

chronically.

2. In animal's experiment, it can increase the meat swollen probability.

12. ECOLOGICAL INFORMATION Ecological toxicity: -

Persistent and biodegradable: -

Bio-accumulative: -

The fluidity in the soil: -

Other effect: -

13. DISCARD DISPOSAL METHOD DISCARD DISPOSAL METHOD: Bury with qualified hygiene.

14. TRANSORTS INFORMATION UN No.: -

UN transportation Name: -

Transportation hazard classification: -

Packing classification: -

Marine pollutant (Yes/No): -

Specially ships method and notice: -

Material Safety Data Sheet

5 / 5

15. Regulation materials Applicable regulation:

1. Labourer’s safe health facilities rule.

2. The harmful thing permits concentration standard in the labourer work surrounding air.

3. The undertaking offal stores and purge method and standard.

4. Dangerous thing and harmful thing rule.

5. Safety regulation of the road traffic.

16. Other information Reference Council of Labor Affairs Material Safety Data Sheets Database

Department: SHENMAO micro material institute-Alloy Development Add: No.12-1 Gongye 2nd Rd., Guanin industrial area, Taoyuan County 328, Taiwan Prepared By TEL: (886)3-416-0177

Author Title: Manager Name: Jim Wang Issued date 2008/6/16