Binder 2 of 2, Davis-Besse Nuclear Power Station, Unit No. 1 ...

I

Enclosure C - Binder 2 of 2

Davis-Besse Nuclear Power Station, Unit No. 1 (DBNPS)

Letter L-1 1-165

References

of 3

Enclosure C - Binder 2 of 2L-1 1-165 of 3

Hydrology

Browser-Morner Associates, Inc., 2002, letter J. Hewlett, Senior Geologist, to First H 1Energy Service Co. c/o Toledo Edison Company, regarding Preliminary WetlandEvaluation, Proposed Temporary Containment Area, Davis-Besse Plant, July 19.

Centerior Energy, 1994, letter from L.F. Storz, Vice-President -Nuclear, Davis-Besse, H 2to T.O. Hickin, Division of Emergency and Remedial Response, Ohio EnvironmentalProtection Agency, in, regarding Submittal of Information Regarding Spill of Gasoline,Identification Number 01-62-0180, February 22.

Davis-Besse Nuclear Power Station, 2004, Periodic Test.Procedure DB-CN-04032, H 3Wastewater Treatment Sludge Holding Tank Analysis, Revision 01, prepared byR. Edwards, October 28.

Davis-Besse, 2004, National Pollutant Discharge Elimination System (NPDES) H 4Program, Administrative Procedure DB-CN-00030, prepared by S. Chimo, June 21

Davis-Besse, 2007, Business Practice DBBP-CHEM-2005, Spill Prevention Control H 5and Countermeasure (SPCC) Plan, approved by V. Capozziello, March 16.

Davis-Besse, undated, Condition Report #04-01719, "In 20 04-05 Spent Fuel Pool H 6Leakage to Onsite Groundwater," discovery date 3/5/2004

Davis-Besse, undated, Business Practice DBBP-CHEM-2009: Storm Water Pollution H 7Prevention Plan, Rev. 00, 28 pages

Environmental Resources Management, 2007, Groundwater Flow CharacteristicsReport, Davis-Besse Nuclear Power Station, Oak Harbor, Ohio: prepared for H 8FirstEnergy Nuclear Operating Company, January 16.

Environmental Resources Management, 2008, Groundwater Monitoring Well H 9Installation & Monitoring Report, Davi s-Besse Nuclear Power Station, Oak Harbor,Ohio: prepared for FirstEnergy Nuclear Operating Company, March 18.

First Energy, 1998, letter from J.H. Lash, Plant Manager, Davis-Besse Nuclear Power H 10Station, to C. Zipp, State Fire Marshall Office, regarding Underground Storage TankOverfill Release Report, Incident Num ber 6281145-00, September 18.

FirstEnergy Nuclear Operating Company, 2007, letter from V.A. Kaminskas, H 11Director-Site Operations, to A. Gall, Division of Surface Water, Ohio EnvironmentalProtection Agency, regarding Submittal of 2006 Annual Sludge Disposal Report forthe Davis-Besse Nuclear Power Station, January 29.

FirstEnergy Nuclear Operating Company, 2008, letter from V.A. Kaminskas, H 12Director-Site Operations, to R. Zuzik, Division of Surface Water, Ohio EnvironmentalProtection Agency, regarding Submittal of 2007 Annual Sludge Disposal Report forthe Davis-Besse Nuclear Power Station, January 18.

FirstEnergy Nuclear Operating Com pany, 2009, letter from B. Allen, Vice President - H 13Nuclear, to A. Gall, Sewage Sludge Coordinator, Ohio Environmental ProtectionAgency, regarding Submittal of the 2008 Annual S ludge Disposal Report for theDavis-Besse Nuclear Power Station, January 23.

Enclosure C - Binder 2 of 2L-1 1-165 of 3

FirstEnergy Nuclear Operating Company, 2010, letter from P.M. Boissoneault, H 14Manager, Site Chemistry, to A. Gall, Sewage Sludge Coordinator, OhioEnvironmental Protection Agency, regarding Submittal of the 2009 Annual SludgeDisposal Report for the Davis-Besse Nuclear Power Station, January 21.

FirstEnergy Nuclear Operating Company, 2011, letter from P.M. Boissoneault, H 15Manager, Site Chemistry, to A. Gall, Sewage Sludge Coordinator, OhioEnvironmental Protection Agency, regarding Submittal of the 2010 Annual SludgeDisposal Report for the Davis-Besse Nuclear Power Station, January 25.

FirstEnergy, 2010, letter from S.F. Brown, Senior Engineer, to R. Zuzik, Division of H 16Surface Water, Ohio Environmental Protection Agency, regarding National PollutantDischarge Elimination System Permit Renewal Application, Davis-Besse NuclearPower Station, EPA ID No. OH0003786, Permit No. 21B0001 1*D, October 21.

OEPA, 2010, letter from E. Swindall, Division of Water, to FirstEnergy Nuclear Gen H 17Corp - Davis-Besse, regarding Preliminary Compliance Review of DischargeMonitoring Report, Novem ber 20.

OEPA, 2010, letter from E. Swindall, Division of Water, to FirstEnergy Nuclear Gen H 18Corp - Davis-Besse, regarding Preliminary Compliance Review of DischargeMonitoring Report, Septem ber 21.

Davis-Besse, undated, Graphs of tritium in wells H 19

Socioeconomics, Environmental Justice & Land Use

EJS4, 5_Support Payments &Property Values S1

EJS3_Site Pop List_2-25-09 (county sort) S2

EJS3_ATTCH EJS-3 S3

EJS2_L10-120 2009 Annual Rad Effluent Release Rpt S4

All 3 U.S. Government Leases for Ottawa Wildlife Refuge S5

Formal documentation for land swap agreement does not exist --

Cultural

Copies of photographs (6, 7, 15, 18, and 19 on flash drive at audit) demonstrating the C 1level of disturbance on the industrialized portions of the plant.

Draft Final Preliminary Assessment Report: Locust Point Anti-Aircraft Artillery Firing C 2Area, FUDS Property No. G050H0996, Nov 2010, 2 volum es, prepared by ShawEnvironmental for Army Corps of Engineers. Request for Docket.NOTE: Volume 1 (Main Body) of C 2 is provided in hard copy.

Volume 2 (Attachments) of C 2 is provided on Compact Disk due tothe size (>2,000 pages) of Volume 2.

FOR INTERNAL USE ONLY

FileNet Information for Letter L-11-165

FileNet Keywords: Correspondence; License Renewal Application; Request foradditional information; RAI response; environmental report; air and metrology; aquatic;terrestrial; hydrology; socioeconomics; environmental justice; land use

BOWSER-MORNER1419 Miami Street • P. 0. Box 838 * Toledo, Ohio 43697-0838

(419) 691-4800

Environmental Service Report

Client: First Energy Service Co.c/o Toledo Edison Company

Attention: Mr. Peter MainhardtDavis-Besse Plant Storeroom5501 North State Route 2Oak Harbor, Ohio 43449

Project: PRELhMINARY WETLAND EVALUATION, PROPOSED TEMPORARYCONTAINMENT AREA, Davis-Besse Plant, 5501 North State Route 2, OakHarbor, Ottawa County, Ohio

Job No.: 125959 Report No.: 125959-0702-420

Date of Report: July 19, 2002 Author: Julie K. Hewlett

Report Consists of 3 Pages

Ladies and Gentlemen:

We are pleased to submit the following environmental service report documenting ourpreliminary wetland evaluation of the proposed temporary containment area. MVis. Julie K.Hewlett, Senior Geologist from Bowser-Morner, evaluated the study area on July 19, 2002. Theweather was hot and cloudy at the time of the site visit. No significant precipitation had occurredfor several weeks.

The study area consisted of a narrow 2/10-mile long parcel. The attached First Energy drawingshows the general location of the study area. The study area was bounded on the south by a ditchand associated dike. Farther to the south was the open water edge of the Ottawa NationalWildlife Refuge. The eastern terminus of the study area was the beach station pump house. Thestudy area was bounded on the north by a service road and intake canal.

The intake canal is scheduled for dredging. Temporary dikes are proposed to completelysurround the study area perimeter. Dredge spoils pumped into the temporary containment areawould be allowed to settle. Clear water would be pumped back into the intake canal and also beallowed to naturally decant. Dried spoils would be moved to a permanent storage location andthe temporary dikes removed. It is our understanding that the roadway between the study areaand intake canal would remain open for traffic.

Study area observations indicate local topography is sloped from the roadway, in a southerlydirection towards the ditch. The ditch and associated dike most strongly appear in the westernportion of the study area, and fade away towards the east. Wetland hydrology (standing water)was noted only in the bottom of the ditch and in the open water edge of the Ottawa NationalWildlife Refuge located nearby to the south of the study area.

The vegetation community friom the roadway towards the ditch and dike appeared to consist ofupland grasses and weeds. Shrubs and bushes consisted of willow, dogwood, and cottonwood.The ditch west end contained Phragmites, indicating wet conditions during part of the year.

All Reports Remain The confidential Property Of Bowser-MomerAnd No Publication Or Distribution Of Reports May Be Made Without OurExpress Witten Consent, Except As Authorized By Contract. Results Contained In This Report Are Reflective Only Of The Items

Calibrated Or Tested. Vnless Otherwise Agreed, Samples Or Specimens Will Be Discarded Or Returned At Bowser-Morner's Discretion.

Study area soils consist of cut and fill materials placed to raise the roadway and dikes above the Wlevel of Lake Erie, when Davis-Besse was originally constructed.

In our opinion, an upland community exists from the edge of the roadway across the study areatowards the south to the dike arid associated ditch. The ditch appears to have been constructed todrain surface water form the roadway. Due to tile man-made character of the study area, lack ofhydric soils and lack of near surface water, it does not appear to meet the requirements of ajurisdictional wetland.

In our opinion, a temporary containment area could be constructed in the upland area between theroadway and the dike in the southwest portion of the study area. Where the ditch and dike appearto fade away in the southeastern portion of the study area, the upland community appears toextend all the way to the open water edge of the Ottawa National Wildlife Refuge.

To facilitate settlement of suspended solids, temporary containment should offer sufficientvolume and retention. Retention of suspended solids could be enhanced by configuration,deflector curtains, wing walls, and polymer injection. If additional engineering or scientificconsultation is required, Bowser-Morner could provide these design services through a changeorder.

We hope that this preliminary wetland evaluation of the proposed temporary containment area issufficient for your project management needs. If you have any further questions, please contactour, office.

¶Respectfully submitted,

÷.;•61 • BOWSER-MORNER ASSOCIATES, INC.

\ .' Julie K. Hewlett, CPG 6661Senior Geologist

JKH:ahltjkAttachments: Sketch3-Client

0BOWSER

Report No. 125959-0702-420 -2- MORNERo

. I

ell

J-0 b It I ?- Sq S-1

IlowseF-- Mo(ý3,31eP-

7-)q- 07-

S

'.3

CENTERIOR14 ENER~GY

300 Madison AvenueToledo, OH 43652-0001419-249-2300

Louis F. SlorzVice Piesident-NucleorDovis-Besse

RAOG 94-09

February 22, 1994

Timothy 0. HickinEmergency Response Unit SupervisorEmergency Response SectionDivision of Emergency and Remedial ResponseOhio Environmental Protection Agency1800 Watermark DriveP.O. Box 1049Columbus, OH 43266-0149

Subject: Submittal of Information RegardingIdentification Number 01-62-0180

Spill of Gasoline

Dear Mr. Hickin:

In accordance with Section 3750.06(D) of the Ohio Revised Code and Rule3750-25-25(A)(2) of the Ohio Administrative Code, enclosed is theinformation on the onsite release of unleaded gasoline at the Davis-BesseNuclear Power Station reported on January 18, 1994; spill eventidentification number 01-62-0180.

Should you be in need of any further information, please contactMr. W. T. O'Connor, Manager - Regulatory Affairs at (419) 249-2366.

Sincerely yours,

JCS/lkg

Attachments

(FS

cc: M. Gerber, Ohio Environmental Protection AgencyLocal Emergency Planning Committee (Ottawa County)

Operoling Companies:Cleveland Eleclric IlluminatingToledo Edison

RAOG 94-09EnclosurePage 1

TOLEDO EDISON RESPONSE TO OHIO EPA SPILL EVENT IIDENTIFICATION NUMBER 01-62-0180

JANUARY 18, 1994DAVIS-BESSE NUCLEAR POWER STATION

1. Reporting and Event Summary

Question:

a) Time, date and duration of release or discharge.b) Time and date of discovery of the release or discharge.c) Indicate the Ohio EPA spill number and the National Response Center case

number.d) Provide an event summary.

Response:

a) The actual time, date and duration of the release is unknown. Therelease most likely occurred between approximately 0300 hours onJanuary 16, 1994, (the last recorded vehicle refueling) and 1130 hoursJanuary 17, 1994 (the first recorded observation of pump malfunction).

b) The actual time and date of discovery of the release of gasoline wasapproximately 1800 hours on January 18, 1994.

c) The Ohio Environmental Protection Agency Spill Response Number is01-62-0180. The National Response Center Number is 217385.

d) On Monday, January 17, 1994, approximately 1300 gallons of gasoline werefound missing from the above ground gasoline storage tank at ServiceBuilding 4. The gasoline is used to service site vehicles; pool cars,snow plows, etc. On the morning of January 17, the gasoline pumpappeared to be malfunctioning. Gasoline was pumped from the tank andabout eight gallons were pumped and the flow stopped. The storage tanklevel was checked and measured approximately 100 gallons. Themeasurement of the tank on Friday, January 14, indicated approximately1470 gallons with 88 gallons being dispensed over the weekend. The lastgasoline was pumped from the tank on January 16, 1994, at 0300 hours.

Industrial Safety and Environmental were notified of the missinggasoline. The site was checked for indications of a gasoline spill.There was no evidence of gasoline in the concrete dike surrounding thetank, or of any amounts around the gasoline pump or inside the pumphousing, or in any of the areas' storm water outfalls (i.e., marsh orponds). No gasoline odors were present. Security was notified forpotential theft investigation.

On January 18, 1994, the tank and underground piping to the gasoline pump'were pressure tested with no evidence of any leaks. The gasoline tankwas partially filled and the pump was tested by pumping gasoline throughthe pump. When the pump was stopped, gasoline was observed to besiphoning through the gasoline pump fire safety valve's atmospheric vent.This leak path was established when a diaphragm failed in the fire safetyvalve. This confirmed that the gasoline had been released to theenvironment, not stolen as was previously suspected. It is suspectedthat the fire safety valve's diaphragm failed due to the extremely cold


weather on January 16, 1994, and at 0300 hours, when the pump was lastused, gasoline siphoned through the atmospheric vent until the pump'ssuction was uncovered (100-gallon tank level).

At 1800 hours on January 18, 1994, notifications were made in thefollowing sequence: the National Response Center, the State EmergencyResponse Center, and the Ottawa County Sheriff's Department as requiredfor the local fire department and local emergency planning committeenotifications.

At approximately 2120 hours on January 18, 1994, the OEPA Division ofEmergency and Remedial Response representative arrived onsite andinspected the spill area.

Collection activities to date have recovered approximately 500 gallons ofgasoline and determined how far the gasoline has spread. The gasoline iscontained in the porous fill underneath the Service Building 4 parkinglot and poses no environmental concerns as it has not entered the marsharea, and is confined within Toledo Edison's property. The leak has beenisolated and repaired. See Attachment 2 for a sketch of the incidentscene.

2. Location

Question:

a) Location of the facility from which the release or discharge occurred.b) Location of the release or discharge.c) Longitude and latitude

Response:

a) Toledo Edison CompanyDavis-Besse Nuclear Power Station5501 North State Route 2Oak Harbor, Ohio 43449

b) Ottawa CountyCarroll TownshipOak Harbor (nearest village)

c) The longitude and latitude of the Davis-Besse-Nuclear Power Station is410 36' N, 830 05' W. Attachment 1 contains a map showing thesite location. The release was not transportation related.


3. Product Release

Question:

a) Chemical name (common name or technical name) and Chemical AbstractsService (CAS) registry number of the substance involved in the dischargeor release.

Response:

a) The material released was Gasoline, BP Super Unleaded (No CAS Number isavailable because the product is a mixture). The Material Safety DataSheet (MSDS) is attached (Attachment 5). The material is not anextremely hazardous substance. The estimated release quantity wasapproximately 1300 gallons.

4. Environmental Impact

Question:

a) Identify the environmental medium or media impacted and the extent ofthe impact.

Response:

a) The gasoline was released into the soil underneath the gasoline pump.The estimated area of contaminated subsurface soil is 2500 square feet.There appears to be a zone of gasoline-contaminated soil approximatelysix inches wide. This zone is approximately three feet below the groundjust above the clay substrate. The spill is 400 feet from the nearestwaterway, no navigable waterways have been or are anticipated to beaffected.

Collection activities to date have recovered approximately 500 gallonsof the gasoline and determined how far the gasoline has spread. Thegasoline is contained in the porous fill underneath the Service Building4 parking lot and poses no environmental concerns as it did not enterthe marsh area and was confined within Toledo Edison's property.Additionally, the soil beneath the porous fill material is composed of aclay substrate which is very dense and has prevented the gasoline frommigrating deeper. Area storm water drains have been isolated to preventthe potential of the gasoline from being released off site.

5. Monitoring and Detection

Question:

a) If the release or discharge was monitored, indicate the method ofdetection and concentrations.


Response:

a) As described in Section 1.d., Event Summary, the gasoline leak isthought to have occurred during the weekend of January 15 and 16, 1994.The release path. to the ground is not a monitored pathway and wasunnoticed by site personnel. For event detection specifics, refer toSection i.d., Event Summary.

6. Mitigation and Containment Action

Question:

a) Amount recovered or neutralized.

b) Describe any actions taken to reduce the impact of the release ordischarge.

c) Actions taken to respond and contain the release or discharge.

Response:

a) To date, approximately 500 gallons of gasoline have been recovered fromthe-gasoline recovery sumps that were dug to collect the gasoline, andstorm water oil interceptors. These low collection points are beingmonitored and the material is being collected throughout the remediationprocess.

b),Veather conditions (-IOF) predicted a low probability of migration atc) the time of the release. The storm water line oil interceptors were

pumped out for initial recovery. Recovery sumps were dug to recoveradditional bulk gasoline which may be present and to determine how farthe gasoline had spread. Attachment 2 contains a sketch of the incidentscene. Approximately 500 gallons of gasoline has been recovered todate. Gasoline recovered from the recovery sumps has slowed. Theremaining gasoline appears to be contained in the porous fill beneaththe parking lot. Additionally, the storm water lines have been pluggedto prevent any gasoline from leaving the site from this pathway. Furtherremediation activities to remove the residual gasoline contaminationfrom the soil are currently being evaluated.

7. Preventive Actions

Question:

a) Provide plans to preventa recurrence of the release or discharge.

Response:

a) The pump and above ground storage tank were taken out of service. Thegasoline pump will be repaired and redesigned to ensure that any futurepump failure would be captured in secondary containment.


8. Health Risks

Question:

a) Describe any known or anticipated acute or chronic health risksassociated with the release or discharge.

b) Advice regarding medical attention necessary for individuals exposed tothe substance released or discharged.

Response:

a) No known or anticipated acute or chronic health risks are associatedwith the release as long as the plume is contained in the soil substrateand completely removed or remediated, and there is no migration intowaterways or exposure to cleanup personnel.

b) N/A

0

9.

Question:

a) Indicate any air, water or other permit numbers which may be pertinentto this incident.

Response:

a) The National Pollutant Discharge Elimination System (NPDES) permitnumber for the Davis-Besse Nuclear Power Station is 2IB00011*ED. Thegasoline was contained to the Davis-Besse site. The gasoline did notenter into the "waters of the state" and posed no environmentalconcerns.

Question:

a) Provide a chronological summary of the incident. Include a chronology

of communications with the state and local government agencies.

Response;

a) Chronological Review

10.

Date Time Event

January 17, 1994 ~1130 Measured tank level and noticed -1300gallons of gasoline missing.

0


Date Time

January 17, 1994 .1200

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

-1000

-1730

-1830

-1903

-1918

-1948

Event

Environmental and Safety personnelresponded to scene and commencedinvestigation. No evidence of spillageon ground or in marsh area, or siteponds. Pump housing inspected and noindication of gasoline. No gasolinepresent in concrete dike surrounding thetank. Theft of gasoline was suspected.

Piping between tank and pump pressuretested. No indications of leak in pipe.Still no indication of gasoline spill atscene.

Refilled tank and tested pump.Identified leak from fire safety valvein gasoline pump. Leak immediatelyisolated and capped, pump and tank weretagged out to prevent use and furtherrelease.

Notified plant management of gasolineleak and spill. Commenced notificationof regulatory agencies. Commencedproduct recovery. Recovered ~300gallons of gasoline from oilseparators.

Notified National Response Center (PettyOfficer Floyd) of the release ofgasoline. No release to "waters of theState" occurred.

Notified Ohio EPA.

Ohio EPA Night Dutycalled and gasolineprovided.

officer (Tom Buchan)release information

-1955

-2010

Ohio EPA, Division of EmergencyResponse, Emergency Response Coordinator(Mike Gerber) called to get releasedetails. Indicated he would come onsiteto investigate.

Ottawa County Sheriff (Deputy Sauvey)was notified of gasoline release.Ottawa County Sheriff is point ofcontact for Ottawa County EmergencyManageieent Agency (EMA) for localfire department and LEPC (localemergency planning committee).


Date Time

-2120

Event

January 18, 1994 Division of Emergency Response,Emergency Response Coordinator (MikeGerber) arrived onsite for releaseinvestigation.

11.

12.

Question:

a) Provide manifest, bills of lading, laboratory analyses which weregenerated which are germane to the incident.

Response:

a) See Attachments 3 and 4 for sample results and manifests.

Question:

a) Describe any extenuating circumstances which caused the discharge.

Response:

a) The cause of the failure of the gasoline pump fire protection valvediaphragm is believed to be the severe cold weather conditions thatoccurred during 'the weekend of January 15 and 16, 1994.

0

Io'

* -a.

Pr-I.

- - 4 4- .4-

- ~-*- -

'S -*

- - - -- A

1- -- 4.. 4- -4 , ,.q ,,...T... ,vc

. \. -

- -~

- *- a-

* NO Tff: ... AA'

ALL CL(VATIONV. ARE FEFEIRAqE TO .,T.LL.iI t IIV x

OG A;.Map Reproduced from Updated Safety Analysls Report Volume 3

ý TO MR%

aLECTRI C

INCH

~TTH

RAOC 94-09Atcachmena 2

0

1PM nRaDel rw.tlm buod m~ i&wvatiwcof tint Its mly. koo MW b ro-&ffriod t 1= 91ri cItrvo

(in =ancrts)

WJNTIWE1 -AWGE FACILIfY

MICHIGAN DEPARTMENTOF NATURAL RESOURCESA

RAOG 94-09 1969"01- as a..enaeo ag ACt 1:e^ . I,,..

Attachment 3 Failure to ilel Ispunishable undersection M995.48 MCI or section 10 of

DO NOT WRITE IN THIS SPACE Act 136, PA. 1969.

ATT. ] DIS. F) REJ. [] PR. E]Form Approved. OMB No. 2050.0039 Expres 9.3Up4

erator's US EPA ID Noa 2 in the shaded areasss not required by Foderal

~ 6I7of ~o~ ~ of / law.

Up leases prin or type. -- LWI

ik UNIFORM HAZARDOUS 1.Gen. WASTE MANIFEST AO

J]l .inerators Name and Mailing Address"OLF-Po -PIpA'l /- .,-r ,.TOP .5 O

4. Generator's Phone 1 &4?I :o,

A. Stale Manifest Document Number

MI •3078050.B..State Generator's ID

-..........-...........................-........... "...

!

5.Traensporter I Company Name' 6. US EPA ID Number C.- State Transporters IIY!*1;,Oý:%w-r

7 ~ ~ ~ ~ ~ )j 10 COMP/1 CO&P. DO/DI¶ý$'h. Transportor's Phone o.foTr-nspotter 2 Company Name 8. US EPA ID Number -E.'.State Transporter's ID

.Li-i I I I I I -I L-_ F. Transporter's PhoneFacility Site 1o. US EPA ID Number G. Stlie Facility's ID

g 0, Pfw•,,.47a. i-A-0 LL

I r K/...V / O H. FaciIlty's, hone - .

1 I. US DOT Description (including Proper Shipping Name, Hazard Class, and 12.Containers 13. 1 . WasteDecitin(ncuigTotal

Un " NO.

H._ ID NUMBER). No. Type Quantity N/H

_I -of u 0I0 (A I_ " •" I•:

C.

IJ I- I ... 1d.

ik.J<'.dditional Descriptions for.Materials Usted Above, . . K. ,adllng 9pdes.-for ýstel at/ /..SC.... bl Ied Aboieb

l15 ..Spcial Handling Instructions and Additional informationIL / f rM A o, rt 'u1 d CG. C4; M ' FF II?!, -. ,W - Pp /5ob IO 1/' c Q 4PilibdLs bl Ifp.O6Lr, , r6A ., _,

16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignment are fully and accurately described above byproper shipping name and are classified, packed, marked, and labeled, and are in all respects In proper condition for transport by highwayaccording to applicable international and national govemmenl regulations.

If I am a large quantity generator, I certify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determinedto be economically practicable and that I have selected the practicable method of treatment, storage, or disposal currently available to me which minimizes thepresent and future threat to human health and the environment; OR; if I am a small quantity generator. I have made a good faith effort to minimize my wastegeneration and select the best waste management method that is available to me and that I can afford.

I Date

iPrintod/Typed Name Signature "Month D Ye0

I -!S eP-k-e, A•,, M,~,;("A C,• ,dýCLJ,10._I, 9 ý K 19 -031c/I /Piti4T 17.Transporer I Acknowledgement of Receipt of Materials Date

P0 1S. Transporteo 2 Acknowledgement or Receipt of Materials Dole-T Printed/Typed Namemonth Day Year

19. Discrepancy Indication Spac5 ,, -71r-

i 20. Facility Owner or Operator: Certification of receipt of hazardous materials covered by this manifest except tis noted inItem 19. Oai

Printed/Typed Name Signature month Day Yea,

/[ LLL -i • I i

EPA Form 8700-22 (Rev. 9188) To he mailed by Michigan DNRG,,imor to- Box 30038

PR SIl o

Rev. 10,S2

*1

pieie soprinl or type. IFO~ em irso~d fu vsa on Mea (12-Petnrfi W Urmt4

(9 " Qj4 -7 -7A- Am~sdM8N* 2o~toA

1.UNIFORM HAZARDOUS 7t. Generator's US EPA ID No, Manifest 2. Page Information inhe shaded areas 7WASTE MANIFEST OHD00)72r050.8.__ . . . L. 094 N of I I Is not required by Federal law.

3. Generator's Name and Mailing Address A. State Manifeat Document Number

S:'r -. ! , ; ; . '. '"- . "

WJAK HARPOR. 011. B. State Generator's I0

4. Generalor's Phone ( 419 ) "•'"4-- i4' ," l . - .- -,

5. Transporter 1 Company Name 6. US EPA ID Number C. .Ste lp.Tnsdq' M@W_*k _f

RESEARCH OIL COM'PANY O H00OC4178612- 0047. Transporter 2 Company Name 8. US EPA 1D Number

. .. F4-Transpborter aPhone,9. Designated Facility Name and Site Address 10. US EPA 10 Number G0 SiateFecta Wa'jID .. ,,-

O2655 TRANSPORT RD.CLEVELAND _. Facility' Phne.

__________________________ 415'(216) 6237 8383 ______

I Unt14.

1t. US DOT Description (Jncl•diing Proper Shipping Name, Hazard Class, and ID Number) 12. Containers 13. Uni - ..HM No. Type Total Ouantity wssVot Was•e No..

e. Iastr Ctomb•p.stiblr. Liquid. ti.c.t u.mbUtrlb~e Li-A'Th~; U1N1993. F'Si!!

(301 TY G

C'

d.

•.. ' •enuin Codes, .Ic: i.,-',

0I

AT0R

t.!Descriptiroiss toe Mater"t Listed Above K Hadln Code Jo( ...... Wastes s Aoe,..

EMERGENCY'24 HR. RESPONtiE #-0-9922 ERM7- 1 :Ti.E IRS

IS. Special Handling Inslrrctions and Additional Informalion P01* VERBAL "EL#USE GLOVES & GOGGLES: PLIMP TANK NEED 60' OF HOSE CALL 419-321-7149 AND STEVE WILL. MEET Y--OU TO LOAD AREA4

ACCEPT 0 (a) - (r0lr,-85ALL SPILLS MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER AT (800) 424.8802, 24 HOURS PER DAY. ~ X ,

/ -.16. GENERATOR'S CERTIFICATION, I hereby declare that the contents of thIs consignment are fully and accurately described above by proper shipping name and areclassified, packed, marked, and labeled, and are in all respects In proper conddlk>n to tforanspo by highway according to applicable international and nalionat governmentregulations.Ill am a large quantity generator, I certify that I have a program in place to reduce the volume and toxicity of waste generaled to the degree I have determined to beecoomically praclicable and that I have selected the practicable method oetrealment, storage, or disposal currently available to me which minimizes the present andfuture threat to human heallh and the environment; OR, if I am a small quanlity generator, I have made a good faith effot to minimize my waste generation and selectthe best waste management method that is available to me and that I can atford.

PrintedfTyped Name Signature Month Day Year

17. Trandporter I Ackonwledgement or Receipt of Materials - DaleR Prinje'd--~y. esignatfe'I Monrh Oay year

o l6. dn •~oneer 2 Acknýledefen o(r ReceipI or Materials - - DateiI Printed/Typed Name Signature Month Day YearER

19. Discrepancy Indication Space

FAC

L 20. Facility Owner or Operator: Cenilhcalion ot receipt of hazardous materials covered by ihis manifest except as noted in Item 19.

Dale

y PrinledlTyped Name Signature Montr Day rearI I ! I ya0

EPA Form 8700-22 (Rev. 9-88) Previous editions are obsolete. GENERATOR'S COPY

I Please print or type. (F"nr ~dewýt, W'Veo asiar f;2.pvh) qP-Afer)1 Fc, Abam a No. 005000" &c&" O

LINIUM H Generator's US EPA t0 No. Manifest 2. Page 1nDoc ent No.f ation in the shaded areasWASTE MANIFEST 1H is7 05 ...... .. 09278 - t 1 i not required by Federat law.

3 Generator's Name and Mailing Address A. State Manifest Document Number

1.iAK HARBOR, OH. B. State Generator's ID

4 344-.4. Gemirat•f'sPbena( 419 )321-7•4A-c ) ':;">'::'! ••;"

5. Transporter I Company Name 6. US EPA I0 Number C-St-7e'.reitsSorer'e. .

RESEARCH OIL COMPANY CHDO04178612. O. .h...1 - .-- 83S3.7. Transpode-,2 Company Name 8. US EPA ID Number ,S-eii.- T' ." -rte. -0

F Zrasporter'a Phone n."

S. Designated Facility Name and Site Address to. US EPA ID Number G.State Facility's 10

RESEARCH OIL CO.265'5 TRANSPORT RD. :_.CLEVELAND H. Facility's Phone -

OH 4•4115 I OH;O(94178612 ..... . (216)623-8383

11. US DOT Description ((nctudinr, Proper Shrpp(ng Name, Hiazard Cfass, anr 10 Number) 12. Containers 13. UnitHM No, Type Total Ouantity WtJVoI Waste No.

a. --7te Flaimrable Liqu.rid. nr.r. rt.ocr.ain' t.so1 me)

(101 TT _20

d,

J, ddilo Decritfo~ioMaerilsEistd 2ove.- - . N artdlng Coe tar Wastes Listed Above .....

S USn E ,REsPORTED TTE OA R1-8O0-ON-9 EC252 ERG#27 ?. E

- ,. ~ j~.JIhE OUT./,~

t5. Speciat Handling instructions end Additional Information F-04 VERBAfL FiELiII5 3L.(ItES &. 60636L.F.S. pl-trrpw ti-nl. .6ic" c.1 hrse centac:t Steve: Chirnc' V l-'4

ALL SPILLS MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER AT (800) 424-8802, m4 HOURS PER DAY. \2 .)/

A

/16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignment are fully and accurately described above by proper shipping name and are

classilied, packed, marted, and labeled, end are in all respects in proper condition torlransport by highway according to applicable internationat and national governmentregulations.If I am a targe quantity generator. I certify that I have a program in place to reduce the volume and toxicity (t waste generated to the degree t have determined to beeconomically practicable and that I have selected the praclicable method of treatment, storage, or disposal currently available to me which minimizes the present aridfuture threat to human health end the environment; OR, if 1 am a small quantity generator. I have made a good faith effort to minimize my waste generation and sel-ctthe best waste management method that Is available to me and that I can afford.

PrintedfTyped Name iMonth Day teat

17. Transorter 1 Ackonwtedgement or Receipt of Materials - - Date

peSin Month Day Yea,, 4 /1X ).. ., I I 4/vo T8. YraislýD '• Ac"no~iMlgement or Receipt o Materials ' Date

T PrintedrTyped Name Signature Month Day tear

IS 519. Discrepancy Indication Space

A

20. FaCtbly Owner or Operator: Certification ot receipt or hazardous rmaterals covered by this manifest except as noted in Item 19.

T "DatePrinredftyped Name Signaltue Month Day Year

EPA Form 8700.22 (Rev. 9.88) Previous editions ate obsolete. GENERATOR'S COPY

RAOG 94-09Attachment 4

JONES & HENRY LABORATORIES, INC. / 2567 TRACY ROAD, NORTHWOOD, OHIO 43619/(419) 666-0411

February 1, 1994

Toledo EdisonDavis B1sse Nuclear Pwr. Sta.300 Madison Ave- MS 3360Toledo, Ohio 43652ATTN: Mr. Steve Chimo

Dear: Mr- Chimo:

Below are the results of analysis of 3 samples received for examinationon January 28, 1994:

Sample I.D. AC16141 Location code: TEDDBMProject account code: 285Location Description: North interceptorSample collector: RR Sample collection date: 01/28/94Lab submittal date: 01/28/94 Time: 16:32

TEST UNITS TEST DETECTIONPARAMETER RESULT LIMIT---------------- -------------------------------- 0HYDROCARBONS (gasoline) by GO mg/L -5 (trace) -

Multicomponent analysis: BTXBENZENE ug/L 210 5.0ETHYLBENZENE ug/L 89 5.0TOLUENE ug/L 550 5.0o--XYLENE ug/L 130 5.0rn+p-XYLENE ug/L 280 5.0

Sample ID. AC16142 Location code: TEDDBMProject account code: 285Location Description: North catch basinSample collector: RR Sample collection date: 01/28/94Lab submittal date: 01/28/94 Tifme: 16:32

TEST UNITS TEST DETECTION

PARAMETER RESULT LIMIT

HYDROCARBONS (gasoline) by GC ing/L Not detected 5

Multicomponent analysis: ETXBENZENE ug/L 4.9 1.0ETHYLBENZENE ug/L 6.0 1.0TOLUENE ug/L 20 1_0c-XYLENE ug/L 10 1.0m+p-XYLENE ug/L 21 1.0

. Page: 2February 1, 1994

Sample ID_ AC16143 Location code: TEDDBMProject account code: 285Location Description: South interceptorSample collector: RR Sample collection date: 01/28/94Lab submittal date: 01/28/94 Time: 16:32



HYDROCARBONS (gasoline) by GC mg/L Not detected 5

Multicomponent analysis: BTXBENZENE ug/L Not detected 1.0ETHYLBENZENE ug/L Not detected 1.0TOLUENE ug/L Not detected 1.0o-XYLENE ug/L Not detected 1.0zn+p-XYLENE ug/L Not detected 1.0

Please advise should you have questions concerning these data.

Respectfully submitted,

Fred W- DoeringPresident

1994 01-1- is,-37 #Ins P.03/09ORMB IlL TECH4 RESEPtRCH TO S I7

INGESTION:M~ODERA.TELY TOXIC.. AA ol~a1 LDLO - -10-30 gina. a"pixati-On Into 1=90I MAY 4COudApxQqWT~it1i. m~ay calms* gnat-tointoutina']. disturbanoo. symptGýfll laY inoludo IN171tation,naugoa, vomiting andi diarrhea. Ma~y o~-% hafu central naXTvOUB system &ffe.~tg - 92factaWaY iioclrdO Oditatl±Qn, BflPbori* hea~dmab, dizziness, drowu3.neahl, blux~od yVflioflfatiguie, txnzr~ora conuligorn, loan of Oon~acionfne~s, c±oma, WOUPIX~toxy arroflt an4 doatb..

SKIN:PRATICXLLY IfO1N-TOX140, Rabbhitz d~xua1 LDSO ->9 mi/kg. aLZICMY XXRIATIMt. 2a~eateUd Or0:o1on~ged contact may result, ii dafattiag, 2adflana, itcliing, 3mflammzxtjon. o=ackino' andPoSgible VOCO~4ary Infafctimf. ff:gh pressuire alcim Wjcitions ara BFPRXOXB lEDICA4MMOMCZ1ES. XAlury may not appeoa seriouna 4t fixntj Vithin a feow h~urna, tiague Will.fr-domea woqlo~n-, dLuooorod and e treine.y painful. (suo Mlotao tQ Pl3ya±ciaU uoction) .

EYE;ILRY c" a light transient inritatio~a.

INI-ALATIN:M~LY catIsa retopixatoay txact iritai~ton. nV03=61X )Udy CaUae Co~t-374 nerVOu9 "YasMB5P=tc s zimilt= to tjidoa :kiv~t*4 undoxr 0"2g~ata~.n (0** Mrigaffion aoetla) - M~AY -1-0CELAG ano ~mia aVA ±r'j-alam hoax¶t x-wt-bm. Ru&?aatad or prolo)ngod ftouat nay datlockbaliaviore. lag.

I

SPEOIALTPXTC EFFECTS:VIY ay a dvarge ULVer and kidney nefooto baitud. on itesto wtth 1boaot nml.Arxof~tat'04 xLviýa composition lims ben ouv to bax.o Inogmran to x8 oraitoxy animalewhe (giye by inhalation.' Aslo, a vArioty or nutagaziaity anosey havre b~ou ox. uitod that:bkve riblded conflict~jag resnltu.

XUOba detozmiznd that thEex* ie limited evidaoxns for the caxcizo niotty of gavoline inex~e-iaucntal AMAnIna and inLoqkUa~ta ey±~.oaoo for the Oax~inogeaicity of g~ao1±ne iaIhun~n. (IARC cleaaa--2M).

TWAVfIdi Tbg ue cg.am .fy bzydocaranb fual In an. mvea. Witbout adnquata ven~tilation mayxresvlt in hazardous 1eelaJ. Of combugtion pzoductoan~d inadeq~uate oxy-ge avolv 1AY1A- 1 bagd3.eto~inuw1 tlaaz gavoline engine erxia'ttl is pouu;Wly csacixcgaj3Ac to hlumansl. (A

Thia Product dontAini beUZQO.n luwozona isa Oaz'cinogenio to laboratoiy axdinala wbeno givenby intubation or by inh~1ation. Thera :is an asnoajAtioXX betWeeia QOcupationAl OXpoDUrS toben~zene and hum=ax la'Uceiia. Caraitoslania detoiminationt: 1ARC--RnmAX and, PAniaalBuffEiciOZht evidenlce of <do .cnogeuicj1ys (~MAO Clann--i); UTP--ftown cVXcinogQxL;

Acute borjzeiA6 paimuning aaus-bfi central tbervouz Systle deprsagaon. Ox-4 eZPosvoattects Ltha hommtapohitic u)(stem camming blood diagordera incluibilaxf ifupancpszi3?OW. JHntagunic an olanto~$2aiQ IJ mw~miz and noxx-MW=malAM teaft xymwtezWP-PxWdUUcTQ toricaant =lY atl dosdeS that &=a matornally taxts, based on tooto with

ND - No DataNA = Not Appricable

. 149/Pag 2 of 8

.,VOK IB RP I1L TFC ESAC TO 2478 1834.01-18 XSt 8 #I1S P.04/09

INGES.TON:DO NIOT fllYCCM VOXXT22fl wmSAUSS OW DAMICR OF ASPIRATING LIQUID flMO .LN0$. Cet inmediate

inodial Stenzt±Qn. XC sponcneoas omitting occurs, monitor for breathing difficulty.

SKIN CONTACr;Wimova contw•zzatd clothing immediatoly, Wash area of cont•at thoroughly wi-h 0oa0 azdwater. cat rne4ical attention if irritatiou perzists. High pressurQ akin injactions axroSfZOI NZDICX. 3URQMENdIBS. Got mediate medical attention.

EYE COHTACTIFlush imaediately with laarge monts of 1rater for at least i-s mitteo 1e. Eyelids ahoulqd bheld nwy from the eyeball to ensure thorough rinsing- Cot me.ioal attention ifirritation zucault4.

INHALATIO•N:RACOVe affected parsoli £xom sourco of axpoannu- If not breathing, anflrm open aiti4 andinsbitulo cardiopulmonary resuscitation. (CPR) . it breathing in &liffi AuXkuit,oxygent f Av'ai1bl,. cet immediate medical. attention.

fl*QMflO2... via Mont inportant gink to "agses is theG extent of aspiration of the prodtldtnt:O the 3.tings sGinsa Ba Acute chemical pnmUmonitis can rapidly trooo its roapik-atory

faiux'[ •spnq~:qog~igAnd OholtSng arek presumptive evidwnpa oft usý±ratian. xtsgge9sted that all patioe.t suspected of bydrooatbch aspiration hare ba~s lIne chest'

*--~y0 Iameiate hosrpital~xation shlould he considered for asymvipkmatio child~raz mitt anabnoXmAl chest x-ray, obt1=nd*c or byporxid patients, intentional or masdire ingest~ions, andlSPatients 'With abpozl, yhout. x.rays with clinically significant pulmonary disease.

CantroiztestinAl syllptoana are usually uklur vnd pathological abangee of -the liver andkidney aei rlp•rted to bh un-ozn- in acute intoxications-. Dacohtazination (inducedotin %5U lavag•) is qontrovargial and should bh sonsidarod on the moerit•s of eachindividual canej of aouxp& the usual precaution of an endotraoheal tube should be0onsided p=ior to lzavao.

Rydrocarbox s may incIroaoe the annsitivity of the myocax-diu to .ate!oholwinus;oleotrocardicgraphia m=ntoring my'be indicated and careful aonsidsration should be given

to the selaction of bronchodilalAtors.

Acute central huorous syatem signs £nd aymptoma my result from largo iugeastiona ora spiration- dued •hypozia.

flWALLTION ?EUSEi aavoliuo ins one cC the solvants used by chemical substance ab oim, .Thofts Paientp my present .wth acute. anv/or chroniu cuntrAl nervous system zoian orzf)Lmtomes. They 1-Y Ma9 present With arrytlhmias.

In c-aseUf o kin iuJAotion, ConMider prompt dCe0bridaat of the wound to iminizq n€crosid44d tissue loss.

NoD No Data"NA Not Applicable

109tPage ,8 of U8

FROM 9BP OIL TECH RESEPRCH TO I FRtIIB OL EC FESRRH O24713 1934.01I- is; 38 #10S PABS/09

EYE PROTECTION;Avoid 8Ya cozitect With~ thisa material. Wear safety gla~aaa or chm2iý'e'j goggeia. P=ovideafaciii±es in the work aren for irniedIately flughini the eyes.

SKIN PROTE-T[ON:Avoid skin ooxibkct. Z-nadin contact in antci~atad, protective cl6thIM9, initeliMJgimp~erv'ious gloves, shotad be wozn. Wash hands if thay came in contact wi-th this, matexia1.Vous good varsan~. byg:ione. wE~n= regularly 010*4mned work Cloting-i. suv~zu anld C4ainginto strQat clothing A~fter WZX) is degitab Ia. Product apilt on clo~thing' ma&y rol idaluiAyed evaporation a&cl a oubJsoquixta 91ru hatard. Wash acont12inat~d cl~oth1ing "B3atlIt clothing~ in Lo be laundered by mc~ozzea olue, Wqa=,r lawxdvror of yropcw rocdr

RESPIRATOR1Y PROTECTION:Xf exposure li.mits aria excadede or U~ irrita~tion in experieanced, RJOSH approvedrespiratory protec~tion should be worn. Vcentilatiozu and othJer f ozm Of engineer-flgoo~tro010 aze often the pref erred ihana for controAl~zg chemical ex-poaure . AnapiratprPx-vtoction ma be needed for ni -routineor0 ema2~gnc~ny Situationz.

~O1ING POINT: 26,.670- 226.'700 C~ (80 - "0 7)SPEC!ICGCRAVITY:- 0.720ý-- 0.740 a 60 F'MEIJING POINT;

*%VOLA11ILM.~ 100.000 G84347 9VAPOR PRESSURE.' 760-000 MHa RG 0o 10E~VAPORATION4 RATE (WATErt-1): >-lvAPO6I ub-mirr (AIR~i); 1.200 AS V?.OR

OCTANOLIWA.TER PARTITION COEFFICIENT: NDPOUR POINT; ~pH:APPEARANCEIODOR: CLEZHR LXPIDti W=~ 2L =sT1o~ upmO.YmO1 ODOR.

.I

FLASH POINT! -37.000 C (-35 1 ) TOOAUT01GNMON TE.MPERAThRM: 444.000 a (8SS J?)FLAMMASHLITLIMITS IN AIR (%BY VOL) LOWER: 1.400PLAA4MABIUT UMITS IN AIR (11 BY VOL.) UPPEFI! 7.600

13ASIC FIREFIGHTING PROCEDURES;Vise d)7y chaicml.i alcohol foa'm, all Puxpapa AmF or car'bon dioxida o nuali.Wa~ter vmy be ineffecti~ve 1at atkould be used to coal fire-ex~oLed cdontainars, arftulva~Mdc to prtect personznal. Xf La~k or $pill hA0 n~ot igni~ted, v'ozrilsat area and Use Watea'tBprw. to disee qe.5 or vapor and to protzeat poruonnel attempting to otop a leak4. U00water t 4il. d3uzt npi~u# And( to 1¶ush thoa amWs frion aouxi-ee of jignitiont. Do bot fluxlxbcoiQpublic newarx or ocher 4r2ainage ayotomg. gxgoge4 firefight~ers muot wea~r XiSHA(NO0approva~d pooitiva pragaure volt -aont~jined breathingq appaxatiie wi~th ful~l face Mawk az~d fullprotect~ive o;lothJlng.

I1W No Dat 1049/Page 4 of 8NA Not A&Vpcmble

FRO14 - BP 0 1 L_ TECH RESEPRCH TO I 2478 1994,01-M s: ±:39 810S P,0'e

UNUSUAL FIRE AND EXPLOSION HAZARDS:Dangorous whoa axpoui~d to boat or Clam. VapOrC -form fla~mable or oxplonivO mixturas withair at: room teanperatUrs- Vapor or gas may spread to distant igsnition aourciQ and flaflhback. Va•pras may concentrzate in aouf.ine areas. Runloff to 0ewer etay cause L•ire orexploaion hbazad. Contatiders may explode in heat of firs. Zrritatingr or toxcio oubstanaesmay be emitted upon thermal decomposition.

STAB •[YA/INCOMPATIFBLY.:Stabla under normal .oonditiona of use. Avoid oontaot withb strong oxi<dizrs.

HAZARDOUS REACTIONOMDEOOMPOSrnON PRODUCTS:cCinbuaeion may produca co, coZ and reaciva hydrocarbons.

SPILL OR RELEASE TO THE ENVIRONMENT:If your facility or operation ban an wOOl or Hazardous Substance ContinigenyPlan", a;timar its prooeuro0.

T- ak inmedlets steps to atop and contain the flpll,- Cautioa sho•ld beexaroisad ragardig 1ersnounal safety an4• xpoaUzr to the spilled material.

-- on b tehnical advise and a .alstance -elate4 to che•mnail, CdoZ1Vot C0MýTKC(80VA24-9300) an4 your lIcOl fi-e department.

-- toify the National Response canter, if required. Also notify appipariatastat4s ad local =ogmlatory agtencies, the LEPO and thn G=UC. 'Contact tbalocal CoaIst Guard if the release is into a waterway. -

EMeorgency Action:Yiap unnecessary people arw4y isolate huzard area and deny -qnt7 stay U" ; keep outde low ate"'. (Alao oea Pprwonal Protection Thfornat•ou ooctioa.) 1Isolaro for 342 mile inall .dizectiona if tank, rail car or tank truck is involvd ,in fixe.

Spill or Leak Prooecfure:ShuL off ignition siourcas; no fluxes, swaliug or flame• in hazard araa. stop leak. if youca8n do It without risk.. Wuter spray my reduce vapuri but it may net pr••tnt ignition incloase apaced . Small Spills: Takee Up with. sand orother noncombuatibie a"sorbentmaterial &nd place into containers for lat6r disposal. Larga Bpills: Dike-far ahoAd of

,liquid spillifor lator disponal.

Notificatlon:Clean Water Act ((il u± p1s) aAny apill or ro1easa, or nubstnarjl. threat of releaso, of this material to navigablewater (virtually any anfxr€ice wtoer) suutti£aut to cause a visibla sheen upon hha watermust be r6e5rted I=ndiately to the National Response Conaer (00/424-A802), as requir• dby U.S. Vederal Law. Failure to repo= my result in iubstantial civil and criminalpanalties- Also Contact this Coast G4urd and appropriate state -nd 1oaI raeg-ulatoryagoacias.

CERCLA/SAKR1 (Cem;ýcAl spills);ThO reortalg quuntity for tDin mateirial in 333 * pouLCd(oý.

ND = No DataNA m Not Applicable

1049/Page 5 of 8

FR~OM 28P OIL TECH RESERRCH TO 2478 ISS4,01-18 Ls*.40 I0P.70

T~iv =atsrial conlta-ins one or ynora Couthj~tUO r Xs nlt~ed zBa hazardous ou~at=,uQ ulrderU7.S- Federal1 Law- AIW wpilX2 or other tuZG1#-g*' or subatan~tia]. throat of reiea.86i of thiscmatorial to the air, water or 1ancd (lUnlood Gflt±rey corutalned in the workplace) equial to0= ixA OXOOa3 of the 770ortn3,ie quantityl n=ue be reOVttad 5inmmdiately to th. NationalaIAQuPonse Cantor (000/424-8802). Alljo coutnot Appzopriate state zand local r6M91AtO±%Ya17encdan. Cotacnt the Coast gUard if xpilJled ýnb navigabije w-aerWAys %nder theirjUriadlction. Failur~e to ropoxt may raault in qub ttiazii 4&vlvi and cr1 zzal Penalties-.

Calcu-Iat*4 On th* bagis tor Whicheymq hazardoua compmonaft pro~v'dQa theL10WA'et Value for.-

RQ I %~ 13 MiiXtUX

WASTE DISPOSAL:* higi Substance, Whol djiscarded or disposed 'ef im not szpacifiqa2.ly Uat04 ada hagad

w-.ata in yedex-Al rou~i" hLOWaver it could b6 hroer o . hazardous If it: it,*Connid~ted tojo.ic coXsXVgoV, ignitabl.e, or zoati e~cordixng to Fds"I dafinJ±3-ona (40

CPR 261). AdditionaAly, it could be danignata&- a~n hnaXdot accoordinsV to statoreguleaiona. ~Th2is subitanco could aloo badcma a hazazdouo waoto if It La mixed with or

cmnin contact -with a bkzwxdoua vast&. Mubck 40 COR 261 to dstermina whethie= It is 2%hazardous Waste. it it lo a. hagax.2ous waste, reqnlatiorts at 40 CPR 262, 26ý 26~A, 260, and

*270 Apply. c~homical MaddIhIons, proceagingi or otjherWiseQ aMterlaag th~is iiatarpnL =*ay =mks.thO waste genaqo=fl. inforiation pressented in this RSpDS incomplete', inAcouxlt* or /otberw=4 ipr2rao.a

The trazportation4 . istoraga, tieatneont, and dis~aal of this MAWt(d Mat8La1 MIugu beconucted. in aomp:liaiica with all app~licable Federal, utate, and local regul~iato2a.

SARA 7lME 1U INFOF(MATION;Li-sted baloiw a±'e tlia bzazd catagorian for~ the ejxperftund IAmendmant'* Ax4F"Vkthorizat461 Act (SMM)J Section 317,1312 (40 CFR 270J)rfmmedlate Hazrd: X -betsye4 Hard:L X Fim Kszrd: X Pressuire H~ard- AeaQcvtty Iaznrd: -

~nQ Product coutaina the folljowing toxic chmnio& (s) ouxbject: to theQ ra~portingrequirOZ-2nts of the Svparrutid Anandmcuts and RtauthOrizatiou Mit (SXAF)Saat5.on 313 (40 CFR 372):

TeueO AS mtniberz . MWxlinw */%Coluipelal 108-~8". . 12-000Xylons 1380-20-7 V2.000Beflzene 71-43-2 3.0001,PZ4z-Thmhytlenzene 95M- 3.000Fhibemnzre 10-142.000

Cyclohexans 110-82-7 1.000'

ADDIMOcNAL ENVIRONMENTAL REGULATORY INFORMATION.Ohis 75AteXial cotains4i o uhbtancia listed an a hazarcdoit" 4ir pollutazt aundWr U.S. Podueral

regulut~oSe e 40 cFRn part 6:i for! rastrictionn whicah mAy apply to its Unse.

*Thiff mata"J. cuntaiua a 21xtu~ra of cabJtances, fffae -0f whiAch ~*an aisted an toxicPcl11at~at0 pursuvr~t to 40 CF =~2.21, Apedidix D, Tsil-a~n XX/Zfl/V. A.ny tmusa).introductiokl of th$.x o'ihntanae 3zto tho fagilitY'a procefisS tbAW5A, StorMW'tvetr and/97Z

v~t4%wAt&' dotld result ia tho voabion of 17*S. Fadaral. LAW. Fdllitias kniult XxOtify the2Cr=IPA -3 soon. Ac thwo knowr, or hvay rse~sou to believe, that a.n3Y activity has ocourred. orwill occur, wqbicb would rnsu.j~t in'the diacharge of a toxic pollu~tant which La hiotro!Qlated in the facility-'s IPOM3 permit. iHotigication l.avela are dosribod in 40 CP~R122.42 (a) Ui) and 122.42 (aH) (). Refer to spill. vection for additional raug toxsyreuironants.

ND No Data 1049fPage 6 ofNA -Not Applicable

FrIOM ssnp OIL TECH RESEPJW" TO 2478 i34,081-18 IS41 010,S P.08/09

Thera Way ba specific regul1tiona at the local, rogionAl or 9tate level that pertain tothis bintorivl..

This Product contaiks ingroadant (s) known to the State of CaJliforni4 to caUDO cancer,birth defec•ts or other reproductiyo harm.

continn Uanzenos . ' Cosult Os0l Standard 1510.1028- Initial air initring should beconducted to datozmdne if exposures ar• above 0.A ppm action mhit: or 1 pmn PHL. If

'poattres are above, OSUA recquire1aenta apply for trainjtw, medical survillanc•.,peiszonul/protect-ive equipment, regulatead areas, eta -

The following Canadian Workplace Hazar4oun Materials Xnfonamtion System (JWnIS) aatagoriesapp~ly to this k~rodaetiCompressed On5 - ai-nmable/Combu.tible x Oxidizer - Acutely Toxic -Othler Toxic Effects x BlofaHrduos - Corrosive - Dangerously Reactive

Store gasolina only in approved, alaarly labeled containern. ayar sztore in glass orunapprovgd plastzc contai•ne•s

sltrihtihtl .loadcontainersj in cool, dry, isola~ted, woil-venti1;%ta4 aroa awvay =,orhfoat, sources o0 ig9itioln a.zd incantatiblas. Garund lines and oecdixmaint u.sd duriig

Stranfe= to re21zg nho possibility of statica spa.rk-initiatd fi5 or eaplosion.

U"t g004 PdlSO41 bW±iOU6 tz.actices. Wash hands ýbefare eati35gr drinking, Smoio~ng, orusing toS•t' facilities.. • amoyo contaminatud clothiug and clean bafore6 reute. shower"lter work usixag •o'zp and water. Do not ciphon this product by mouth. U6e only as alvOtor fuel.- Do not use for cleanixg, prossure appliance riel, or" a•y other use. Do notstore, in, zuxablled containers. Seep out of reach-of children.

* EMPTY CONTAINERS;Empty cotki s MVa oo1otatin toxic, floawzle/ombustible or eoxplnivo re4idme o"r vapors.DO n•t .cut, grind, drill, wald,. 2:Iue or dt'spcnte containors unless adequate procautions

rar tnkatn against those hazardn."

D,O.T. PROPER SHIPPING NAME (49 CFR 172.101):D.O.T. HAZARD CLASS (49 CFR 172.101):UN/NA CODE (49 CFI1 172.101)!PACKING GROUP (411 O`13 172.101):BILL OF LADING DESCRIPT1ON (4.9 CFR 172.202):D.O.T. LABELSFIQUIRED.(49 CFR 172.101):D,O,.T PLACARDS REQUIRED (49 CFR 172L504).

I

G"Arl0E;XI, 3, UNI.203, PG XV

3

ON 1203

GASOL•Ih 3,r MNL 1203, Wo IS

LAM L LIGQUID

FLMARLPý t'IQtID

ND = No Data'NA Not Applicable

1049/Paog 7 o08

FROI 13P 0 1 L TVCH RESEPRCH POI d- EfcH TO 9 2478 1994.01-113 15:42 files P.09/09

. CO-.-POnrW1 I •_A 1O. I % I EXPOSURE buxMTTS - REF.

Ga'soline gQ~g61-9 99.99-100 300 pprn (ago lngr/MA) =V; 500 PX=

200 ppuk (900 ing'fl3) My 500 'PP(1,500 fZ/'nA STDZL losf&)

Tolixwan 108-80-3 3.0-12 100 PP= (977 xw1W~) MV1. 150 PPM

(55t00 /M 8MM ((ACGM&))~i IO p

100 pm~ (375 -gfR3) I10 -50~ PP(960 pplmi. (560 40s"A ) L(c

1330-20- 1.01 -1.00 ppan (4375 mingi[) T1i-j15 pMY

(651 mg/Zx3)1 STL (os!=)l00 prM (435 =rC/1431 PEL: x~0

Bezel ~71-43-2 0-3 10 pm (32 ,aQjJ13) Thy (ACGZIH)*I ppm PEL, 5 ppm STRt COSBA.)

±,2,-T~y:Lbuzo~a95-63-6 0-3 25 ppm (1.23 Za4/M3) TLV (A.COM~2S pra (125 xa" ) (OS=

100-41--4 0-2 .100 ppm (424 2zq/1=) WVAV,. X1 25 ppm

109 ppM (4&5 Mgqi2t2) I>,q 125 PPf4(545 mgf3M1) 'STEL (0awi)

c~yt1ohezimx=*0~- 0-:L 300 ppm (1,030 &ngf*L3 TLV (Ac=~)300 ppm (1,050 mg/Ur$) PEL (05HAL)

hazardouu compoenats Proe=at lagsz t1~ii 1.0% (0.1%~ fox

,REVISION DATE! I7-apr-1992 REPLACES SHEET DATED: 21-jan-1991COMPL-ETED BY: BP O1tL HSEQ DEPARTMENT

"paep&on of ft¶ Mate~vi 6SIt Uaia sheetL 1owavr. noumfa o~nntr to enmmion,'exproas orbpip~ed. is rnsdaa to i th acwmay or camplaunMs of 010 fgwugclin data and safeti' Inbrnna6on\ notis any autwoizatin given ortffipt~ed W to pucv ay pwxf~tpd Iiwentlonwfi utal1aO, In ft&~on.no ro~ponsibflity can be assumed~ by vencbc for any datvg ot k~jur ras~ddnq fromi 6ýxrrnsd use, from anyblutum to adkhare to recommentivd pm~4c-dm, or from any h~azartds MeInt in itra come of Wli pmduaL

ND - No DataNA - Not Applicable

1049/Page 8 of 8

0

of 6

Davis-Besse Nuclear Power Station

PERIODIC TEST PROCEDURE

DB-CN-04032

WASTEWATER TREATMENT SLUDGE HOLDING TANK ANALYSIS

REVISION 01

Prepared by: Richard Edwards

Procedure Owner:

Effective Date:

Supervisor - Nuclear Chemistry Services

OCT 2 8 2OO4

Procedure Classification:

Safety Related

X Quality Related

Non-Quality Related

LEVEL OF USE:

STEP-BY-STEP

2 DB-CN-04032Revision 01

WASTEWATER TREATMENT SLUDGE HOLDING TANK ANALYSIS

TABLE OF CONTENTS

Page

1.0 PURPOSE AN D.. .......... ................................................................................................... 3

2.0 LIMP ITS AND PRECAUTIONS .......................................................................... ................ 3

3.0 PR E R E Q U ISITE S ........................................................................................................................ 3

4.0 PROCEDURE ............................................................................................ 4

5.0 A CCEPTAN CE CRITERIA ...................................................................................................... 6

6.0 R E FE R E N C E S ............................................................................................................................. 6

7.0 RE C O R D S .................................................................................................................................... 6


1.0 PURPOSE

1.1 This procedure provides for the monitoring of sanitary wastewater sludge for thepresence of radionuclides.

2.0 LIM1TS AND PRECAUTIONS

2.1 None

3.0 PREREQUISITES

INITIALS

3.1 Collect as a minimum a 1 (one) liter representative sample from the each sludge holdingtank to be pumped.

3.2 Record collection time and date.

Time Date

3.3 Record holding tank number.

Prerequisites completed by DatePrerequisites completed by Date


NOTE 4.0

Section 4.0 is performed for each sludge holding tank to be pumped.

4.0 PROCEDURE

INITIALS

4.1 Label a 1 liter liquid marinelli with volume marks in 100 cc increments.

4.2 Weigh the marinelli.

Balance LI No.

Check Due Date

Tare Weight g.

4.3 Obtain the sludge holding tank sample for analysis by:

a. Shaking the sludge sample and filling the marinelli with sample to the 1000 ccmark.

4.4 Weigh the filled marinelli.

Balance Li No.

Calibration Check Due Date

Gross Weight g.

Net Weight g.

4.5 Analyze the sample for radionuclides in accordance with DB-HP-01 113 CountroomAnalysis System (CAS) Operation, using the following:

* Volume of 1000 cc

* Sample Time at time of counting

0 Minimum count time of 8000 seconds

0 Obtain a MDA (Minimum Detectable Activity) report.


NOTE 4.6

% sludge = cc sludge x 1001000cc

4.6 Record the % sludge volume after analyzing the sample on the gamma spec printoutand below.

4.7 Attach a copy of the analysis with MDA report to this completed procedure.

4.8 Forward this test to a Radiation Protection Supervisor for review and approval forrelease.

4.9 IF the sludge can be released,THEN obtain Radiation Protection Supervisor's approval.

DateSupervisor-Radiation Protection

4.10 IF the sludge is not approved for release,THEN notify Nuclear Chemistry Services personnel immediately.

4.11 Submit a copy of gamma spec analysis and MDA report to Nuclear Chemistry Servicespersonnel.

Section 4.0 completed by Date


5.0 ACCEPTANCE CRITERIA

5.1 The analysis of the holding tank(s) content has been completed.

Verified by Date

6.0 REFERENCES

6.1 Developmental

6.1.1 Nuclear Regulatory Agency IE Notice 88-22, Disposal of Sludge from OnsiteSewage Treatment Facilities at Nuclear Power Stations.

6.2 Implementation

6.2.1 DB-HP-01 113, Countroom Analysis System (CAS) Operation.

7.0 RECORDS

7.1 Following the requirements of NOP-WM-2003, Work Management SurveillanceProcess, for records capture and processing.

ADMINISTRATIVE PROCEDURE TITLE SHEETED 7171-2

I TITLE NO. DB-CN-00030National Pollutant Discharge REVISIONElimination System (NPDES) 00S Program PAGE

cI I OF 19EFFECTIVE DATE

1,, JUN 2 12004E C L ESUPERSEDESEXCELLENCE QUALITY TEAMWORK DB -CH-O0030 Rev 0 1

Prepared by: Stephen Chimo

Procedure Owner: Manag

Procedure Classification:

Safety Related

X Quality Related

Non-Quality Related

er - Environmental and Chemistry

LEVEL OF USE:

GENERAL REFERENCE

REVISION LOG

Revision Number Revision Summary

Rev 00 Incorporated the contents of DB-CH-00030. NationalPollutant Discharge Elimination System (NPDES) andECG-10, National Pollutant Discharge EliminationSystem (NPDES) Permit Requirements, into DB-CN-00030 under new ownership.

ED 7575A

DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER. National Pollutant Discharge Elimination System 3 00 DB-CN-00030

(NPDES) Program

TABLE OF CONTENTS

Page

1.0 P U R P O S E .................................................................................................................................... 4

2.0 APPLICABILITY/SCOPE ..................................................................................................... 4

3.0 REFERENCES ............................................................................................................................. 4

4.0 DEFINITIONS ............................................................................................................................. 5

5.0 RESPONSIBILITIES .......................................................................................................... 7

6.0 PROCEDURE .............................................................................................................................. 8

6.1 General Information ................................................................................................... 8

6.2 Conduct of the Program ............................................................................................... 8

6.3 Periodic Reports ................................................................................................ .............. 9

6.4 Change in Discharge ....................................................................................................... 11

0 6.5 Diversion or Bypass of Facilities ................................................................................. 12

6.6 Approval to Use Non-Contact Cooling W ater Additives ........................................... 13

6.7 S pill R esponse ................................................................................................................. 13

6.8 Non-Compliance Notification and Reporting Requirements ....................................... 14

6.9 Perm it R enew al ............................................................................................................... 15

7.0 RE C O R D S .................................................................................................................................... 15

ATTIACHMENT 1: OBSERVABLE NPDES PARAMETERS AND SAMPLINGFREQUENCIES .............................................................................................. 16

ATTACHMENT 2: EXAMPLES OF NPDES REPORTABLE EVENTS .................................... 17

ATTACHMENT 3: OHIO EPA NPDES DATA CODES ............................................................. 18

ATTACHM ENT 4: NPDES SPILL RESPONSE FLOW CHART ................................................ 19

ED 7575A

DAVIS-BESSE ADMINISTRATIVE PROCEDURE PAGE REVISION PROCEDURE NUMBER

National Pollutant Discharge Elimination System 4 00 DB-CN-00030(NPDES) Program

1.0 PURPOSE

This procedure establishes the requirements, responsibilities, and processes for the administration of theOhio Environmental Protection Agency (Ohio EPA) National Pollutant Discharge Elimination System(NPDES) Permit, No. 21B0001 1, for the Davis-Besse Nuclear Power Station (DBNPS), and implementsthe requirements of NG-DB-00501, Environmental Compliance Program, for NPDES activities.

2.0 APPLICABILITY/SCOPE

This procedure applies to those Environmental and Chemistry personnel responsible for NPDESactivities.

3.0 REFERENCES

3.1 Developmental

3.1.1 Clean Water Act of 1987

3.1.2 40CFR 121-125

3.1.3 Ohio EPA OAC 3745-33-01 through OAC 3745-33-10, Ohio NPDES Permits

3.1.4 Ohio Environmental Protection Agency, National Pollutant Discharge EliminationSystem Permit No. 21B0001 1, for the Davis-Besse Nuclear Power Station

3.2 Implementation

3.2.1 NG-DB-00501, Environmental Compliance Program

3.2.2 NG-RA-00807, Regulatory Reports

3.2.3 NG-NS-00808, Regulatory Agency Communications

3.2.4 NOP-NL-2001, Condition Report Process

3.2.5 DB-CH-04028, NPDES Program

3.2.6 RA-EP-02850, Hazardous Chemical and Oil Spills

3.2.7 Environmental Compliance Guideline (ECG -05), Spill Prevention Control andCountermeasure (SPCC) Plan

3.2.8 ECG-04, SARA/CERCLA Hazardous Chemical Locations and Spill Event NotificationRequirements.

3.2.9 ECG-09, Storm Water Pollution Prevention Plan.

0

ED 7575A


. National Pollutant Discharge Elimination System 5 00 DB-CN-00030(NPDES) Program

4.0 DEFINITIONS

4.1 BIOCHEMICAL OXYGEN DEMAND (BOD) - The amount of oxygen used by micro-organisms to metabolize the organics in wastewater.

4.2 BYPASS - The intentional diversion of waste streams from any portion of the treatmentsystem.

4.3 DAILY - As used in this procedure, refers to workdays of Monday through Friday, excludingholidays.

4.4 DISSOLVED OXYGEN - The amount of oxygen in the water, varying by the physical,chemical, and biochemical activities in the water body.

4.5 HYDRAZINE - A colorless, fuming corrosive strongly reducing liquid which scavengesoxygen for corrosion control.

4.6 NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) - A federalprogram administered by the Ohio Environmental Protection Agency that provides for thepermitted discharge of pollutants to state or federal waterways.

4.7 NONCOMPLIANCE - A failure to satisfy permit requirements regarding concentrationlimitation, designated sampling frequencies, or report submittal.

4.8 OIL AND GREASE (0 & G) - Any material recovered from the sample as a substance solublein trichlorotrifluoroethane.

ED 7575A



NOTE 4.9

Conditions may dictate that Station drains be routedthrough the settling basins (Outfall 602).

4.9 OUTFALL - The location where an effluent is discharged into receiving waters. The permittedoutfalls for DBNPS are as follows:

Designation Description

001 BEACH STATION: At point representative of discharge to LakeErie.SOURCE OF WASTES: Low volume wastes (Outfall 602),Wastewater Treatment (Outfall 601), circulation system blowdown,turbine building sumps and occasional service water.

002 AREA RUNOFF: Discharge to Toussaint River.SOURCE OF WASTES: Stormwater runoff, turbine building drains,boiler drains, and circulating pump house sumps.

003 SCREENWASH CATCH BASIN: Discharge to Navarre Marsh.SOURCE OF WASTES: Wash debris from water intake screens.

004 COOLING TOWER BASIN POND: Discharge to State Route 2Ditch.SOURCE OF WASTES: Drainage of Cooling Tower Basin.

588 SEWAGE TREATMENT PLANT Sewage Treatment Plant Sludgeshipped offsite for processing.

601 SEWAGE TREATMENT PLANT POND: Discharge fromwastewater treatment system pond.SOURCE OF WASTES: Site sanitary system.

602 LOW VOLUME WASTES: Discharge of settling basins.SOURCE OF WASTES: Water treatment residues, condensatepolishing resins, condensate pit sumps.

801 INTAKE TEMPERATURE: Intake water prior to cooling operation.

Permit limitations, outfall parameters, and sampling frequencies are delineated onAttachment 1.

4.10 pH - The negative logarithm of the hydrogen ion concentration used to express acidity andalkalinity on a scale of 0-14.

4.11 PROCESS WASTEWATER - Any water which, during manufacturing or processing, comesinto direct contact with or results from the production or use of any raw material, intermediateproduct, finished product, by-product, or waste product.

4.12 TOTAL RESIDUAL CHLORINE - Combination of free chlorine and combined chlorine. Freechlorine consists of aqueous molecular chlorine, hypochlorous acid, and hypochlorite ion. Freechlorine reacts readily with ammonia and certain nitrogenous compounds to form combinedchlorine.

4.13 TOTAL NONFILTERABLE RESIDUE (TNFL) - Method, described in "Standard Methods forthe Examination of Water and Wastewater", of filtering a sample through a glass fiber filter andweighing the dried residue retained on the filter [also known as Total Suspended Solids (TSS)].

4.14 TOTAL RESIDUAL OXIDANTS - Combination of Total Residual Chlorine and residualbromine compounds.

4.15 UNAUTHORIZED DISCHARGE - The release of unpermitted pollutants, including bypassingwhether deliberate or accidental.

4.16 UPSET - An exceptional incident that results in unintentional and temporary noncompliancedue to factors beyond reasonable operator control. This excludes operator error, improperdesign, lack of maintenance or careless or improper operation.

5.0 RESPONSIBILITIES

5.1 The Manager - Environmental and Chemistry shall

5.1.1 Provide overall administration of this procedure.

5.1.2 Make required onsite and offsite notifications.

5.1.3 Provide technical assistance during NPDES permit unauthorized discharges andnoncompliance events.

5.1.4 Ensure submittal of any required regulatory reports.

5.2 The Project Leader or designee shall be responsible for the implementation of this procedure.

5.3 Other actions for the discharge of pollutants through NPDES outfalls as required byRA-EP-02850 may occur concurrently with implementation of this guideline. These actionsmay include:

5.3.1 The Shift Manager or designee may make required onsite notifications and determine ifa spill or discharge has occurred which requires implementation of HAZWOPER.

5.3.2 The Supervisor - Nuclear Chemistry Services in conjunction with the Supervisor -

Safety may prescribe personnel protective equipment and practices during anemergency response.

ED 7575A



5.3.3 The Superintendent - Maintenance may isolate site discharge pathways and providecleanup of spilled materials.

6.0 PROCEDURE

6.1 General Information

6.1.1 Under the Clean Water Act, it is not permissible to discharge any pollutant to a state orfederal waterway.

6.1.2 In obtaining a NPDES permit, DBNPS is now allowed to discharge those industrialprocess wastewater pollutants specified by the permit (see Attachment 1, ObservableNPDES Parameters and Sampling Frequencies). Those pollutants may only bedischarged to the outfalls designated in the permit and discharge pathway may not bechanged/diverted from the designated pathway unless first approved by the Director ofthe Ohio EPA.

6.1.3 The following conditions constitute a violation of the NPDES permit and are reportableto the Ohio EPA:

a. Any discharge of pollutants in excess of the limits specified in the permit(noncompliance).

b. Any discharge of unpermitted pollutants (not specified in the permit) above theanalytical detection limit (unauthorized discharge).

c. Any flow changes/diversions that exceed permit limits and/or cause thedischarge of any unpermitted pollutants (bypass).

6.1.4 Examples of possible situations which are reportable are included as Attachment 2,Examples of NPDES Reportable Events. These are only examples and should not beconsidered an all inclusive list.

6.2 Conduct of the Program

6.2.1 The NPDES Monitoring Program consists of:

a. Taking measurements and representative samples of liquids as required by thepermit.

b. Analyzing these samples and evaluating measurements in accordance withstation procedures.

d. Reporting results to the Ohio EPA as discussed in this procedure.

ED 7575A



6.3 Periodic Reports

6.3.1 General Requirements

a. Data for Outfall 001, 002, 003, 004, 601, and 602 shall be provided toEnvironmental on a weekly basis as follows:

1. Chemistry Section performs DB-CH-04028, NPDES Program, weekly.

2. A copy of the completed DB-CH-04028 is submitted by Chemistry forpreparation of the monthly report.

b. Samples or values for data analysis shall be collected from the followinglocations:

1. Outfall 001 samples shall be collected at the DBNPS beach samplingstation.

2. Outfall 002 samples shall be collected at the discharge of the TrainingCenter pond.

3. Outfall 003 samples shall be collected at the overflow of thescreenwash catch basin, north of the settling basins.

4. Outfall 004 samples shall be collected at the discharge of the CoolingTower Pond, as applicable.

5. Outfall 588 samples shall be collected from the applicable operatingSewage Treatment Plant Sludge Holding Tank(s).

6. Outfall 601 samples shall be collected at the overflow of thewastewater treatment basin.

7. Outfall 602 samples shall be collected at the overflow of the NorthSettling basin.

8. Outfall 801 water temperature values shall be obtained from acomputer point located in the forebay.

6.3.2 Data Collection

a. Nuclear Chemistry Services may use the following forms to collect data and totransmit the finalized report to distribution:

1. NPDES Weekly Data Acquisition Form

2. NPDES Monthly Report Form (EPA-4500)

ED 7575A



b. If data values are unavailable or an analysis was not performed:

NOTE 6.3.2.b. 1

The use of Ohio EPA NPDES data codes in lieu ofdata values should be avoided whenever possible,especially regarding the use of the "AH" codefor outfall 001.

I. Document the discrepancy appropriately using codes shown inAttachment 3, Ohio EPA NPDES Data Codes.

2. Report the discrepancy as soon as practicable to the Project Leader.

6.3.3 Determination of Flows and Water Temperatures for Outfall 001

NOTE 6.3.3.a

Converting from thousand gallons per minute (KGM) tomillion gallons per day (MGD) can be accomplishedby multiplying by 1440 then dividing by 1000.Example: 18.6645 KGM X 1440 + 1000 = 26.8769 MGD;to 3 significant figures = 26.9 MGD.

a. Obtain value from computer program for point F201, Collection Box Flow.

1. Convert KGM value to MGD Flow.

2. Shorten value, if necessary, to three significant figures.

b. Obtain value from computer program for point T190, Discharge Temperature.

1. Shorten value, if necessary, to three significant figures.

c. Repeat 6.3.3.b for point T413.

6.3.4 Determination of Flows for Outfall 002

a. Obtain the daily rainfall data for the reporting month from the MeteorologyProject Leader and identify those days upon which precipitation was recorded.

b. Enter data into computer program for flow calculations.

ED 7575A


National Pollutant Discharge Elimination System I1 00 DB-CN-00030(NPDES) Program


a. The daily flow for Outfall 003 is constant at 0.222 MGD.


a. Obtain timer reading values from the Wastewater Treatment Plant Inspectionforms (maintained by Nuclear Chemistry Services).

b. Enter timer reading values into computer program for flow calculations.


a. Obtain station sump timer reading values for timers BE3162 and BF3163.

b. Enter timer values into the computer program for flow calculations.

6.3.8 Data Entry into the "EPA" Monthly Reporting Computer Program

a. Enter the collected NPDES reporting data to the appropriate EPA form on thecomputer.

b. When all data is entered and correct, and sums are tabulated:

1. Print each form onto the NPDES forms supplied by the EPA.

2. Ensure all information is legible.

NOTE 6.3.9

The completed NPDES reporting data for the month, asprinted on the Ohio EPA Forms and the attached covermemorandum are combined to make the Ohio EPA NPDESMonthly Wastewater Report.

6.3.9 Report Review Process

a. Submit report for review according to the Report Requirements Tracking Sheet(RRTS - PS) for the monthly NPDES report.

b. All correspondence relating to the implementation of the NPDES program shallbe retained for a minimum of three (3) years.

6.4 Change in Discharge

6.4.1 Discharges shall remain consistent with the terms and conditions of the Permit.

ED 7575A



6.4.2 When any pollutant is discharged more frequently than, or at a level in excess of, thatwhich is authorized, or when any pollutant not described in the permit is dischargedabove the analytical detection limit, that discharge shall constitute a violation of thePermit and shall be reported to the Ohio EPA.

6.4.3 Before any flow paths are changed, new chemicals are used in systems, treatmentdevices are installed, etc., the potential need for a permit modification must beconsidered. A permit modification is required for:

a. Any anticipated facility expansion.

b. Production increases.

c. Process modifications that will result in new, different, or increased dischargesof pollutants.

6.4.4 Following such notice of facility or production changes, the Permit may be modified tospecify and limit any pollutants not previously limited.

6.5 Diversion or Bypass of Facilities

6.5.1 No diversion from or bypass of facilities necessary to maintain compliance with termsand conditions of the Permit shall be permitted, except:

a. To prevent loss of life, personal injury, or severe property damage.

b. There are no feasible alternatives to the bypass, such as the use of auxiliarytreatment facilities, retention of untreated waste, or maintenance during normalperiods of downtime. This condition is not satisfied if adequate back upequipment should have been installed in the exercise of reasonable engineeringjudgment to prevent a bypass which occurred during normal periods ofequipment downtime or preventative maintenance.

c. To allow essential maintenance to be performed according to a scheduleapproved in writing by the Ohio EPA Northwest district Office.

d. When excessive storm drainage or runoff would damage any facilitiesnecessary for compliance with the effluent limitations and/or prohibitions of theNPDES permit.

6.5.2 Diversion from or bypass of facilities shall be reported according to the event and meetthe requirements of Subsection 6.8.

6.5.3 Unanticipated bypasses must be reported to the Ohio EPA Emergency ResponseHotline within 24 hours.

6.5.4 If the need for a bypass is known in advance, prior written notification to the Ohio EPAis required at lease ten days before the date of the bypass, if possible.

ED 7575A



6.5.5 Bypasses which do not cause effluent limitations to be exceeded are permissible if they

are for essential maintenance to assure efficient operation.

6.6 Approval to Use Non-Contact Cooling Water Additives

6.6.1 When it is requested to use different non-contact cooling water additives than thosecurrently allowed by our permit, such as alternative amines for pH control, prior OhioEPA approval must first be obtained.

6.6.2 The following information must be supplied to the Ohio EPA in writing;

a. The name of the additives(s) to be used and general product information,including a copy of each material Safety Data Sheet (MSDS).

b. The concentration(s) of the additive(s) to be used, including the frequency andduration of application.

c. The expected concentration(s) of the additive(s) contained in the discharge orblowdown immediately prior to entering state surface waters (in mgfL).

d. The average flowrate (MGD) and the outfall designation of each outfallcontaining the additive.

e. The name of the state surface water receiving the discharge.

f. Toxicity and environmental information, such as 48-hour and 96-hour LC50 orEC50 values from acute toxicity tests.

6.6.3 This information should be complied and submitted by Nuclear Chemistry Services forapproval as necessary.

NOTE 6.7

A simplified flow chart for NPDES spill actions and notifications isshown on Attachment 4, NPDES Spill Response Flow Chart.

6.7 Spill Response

6.7.1 The discharge of pollutants through NPDES outfalls in excess of the concentrationlimits specified in Attachment 1, or the discharge of pollutants not listed on Attachment1 in excess of the analytical detection limit is a violation of our NPDES permit.

6.7.2 Reporting requirements for NPDES violations are described in Subsection 6.8.

ED 7575A



6.7.3 Although NPDES discharge violations are reported under Subsection 6.8, the requiredclean-up requirements are the same as for land spills and air releases. Theserequirements are detailed in the following locations:

a. RA-EP-02850, Hazardous Chemical and Oil Spills, describes HAZWOPERactivation requirements and small spill/discharge clean-up information.

b. ECG-04, SARA/CERLA Hazardous Chemical Locations and Spill EventGuidelines, describes how to clean up chemical spills/discharges, such ashydrazine, sodium hypochlorite, sodium hydroxide, sulfuric acid, etc.

c. ECG-05, Spill Prevention Control and Countermeasure (SPCC) Plan, describeshow to clean up oil and diesel fuel spills/discharges.

6.8 Non-Compliance Notification and Reporting Requirements

6.8.1 The Ohio EPA must be notified in accordance with NG-NS-00808.

NOTE 6.8.2

The Ohio Emergency Response Hotline number is 1-800-282-9378.

6.8.2 The Ohio EPA must be notified by telephone of the following items within twenty-four(24) hours of discovery:

a. Any noncompliance or unauthorized discharge events.

b. Any unanticipated bypass (no prior written approval) which exceeds anyeffluent limitation in the permit.

c. Any upset which exceeds any effluent limitation in the permit.

6.8.3 The Ohio EPA must be notified within 24 hours of any violation of any maximum dailydischarge limitations as listed on Attachment 1.

6.8.4 Telephone notifications must be confirmed in writing within 5 days of the dischargeand submitted to the Ohio EPA Northwest District Office, including the followinginformation, unless directed to do so otherwise by the agency:

a. Limitation(s) exceeded

b. Extent of the exceedence

c. Cause of the exceedence

d. Period of the exceedence

ED 7575A



e. If uncorrected, the anticipated time to which the exceedence is expected tocontinue

f. Steps to be taken to reduce, eliminate and/or prevent recurrence of theexceedence.

6.8.5 Instances of noncompliance not detailed above are to be submitted with the monthlyNPDES reports in accordance with Subsection 6.3, Periodic Reports.

6.9 Permit Renewal

The Manager - Environmental and Chemistry or designee shall ensure that the application forthe renewal of the current version of DBNPS NPDES Permit No. 21B0001 1 is submitted at leastsix months prior to the expiration date.

7T0 RECORDS

7.1 The following quality assurance records are completed by this procedure and shall be listed onthe Nuclear Records List, captured, and submitted to Nuclear Records Management inaccordance with NG-NA-00106:

7.1.1 NPDES Permit

7.1.2 NPDES Permit Application

7.1.3 Ohio EPA NPDES Monthly Wastewater Report

7.1.4 Non-Periodic Reports, if generated

7.2 The following non-quality assurance records are completed by this procedure and maintained bythe Environmental Unit:

7.2.1 NPDES Weekly Data Acquisition Checklist

7.2.2 Regulatory Reports - Review and Approval Report

7.2.3 NPDES Monthly Review Cover Memorandum

ED 7575A



A• T- A C'-IP NIT I. fl1~I~PVAT~T 1~ NIPThI~ PAl AMT~T1~D'~ AIJTh ~AMPT ThJ( FRFO1TFNCW'~

Page 1 of 1

SITE PARAMETER TESTED OBSERVABLE PARAMETER FREQUENCYFOR

30 DAY AVG. MAX DAILY001 Total Chlorine/ Oxidants NA 0.02 mgfL/0.05 mg/L Daily/Grab See Note 1

pH NA >6.5 & <9.0 Daily GrabDissolved Oxygen NA 6.0 mg/L (Min) 2/Month GrabCopper NA NA Qtrly/24 hr. Comp.

002 TSS 30 mg/L 100 mgfL Weekly/GrabOil & Grease 15 mg/L 20 mg/L Weekly/GrabpH NA > 6.5 & < 9.0 Weekly/GrabDissolved Oxygen NA 6.0 mg/L (Min) See Note 2Silver NA NA Qtrly/24 hr. Comp.

003 TSS No Limits No Limits 1/Month Grab

004 Total Chlorine/ Oxidants NA 0.02 mg/L/0.05 mg/L Daily Grab See Note ISee pH NA >6.5 & <9.0 Daily GrabNote 3588 Sludge Solids, % Total No Limits No Limits Each Sludge disposal

Sludge Weight No Limits No Limits Each Sludge disposal601 TSS 30 mg/L 45 mg/L Weekly/Grab

BOD5 30 mg/L 45 mgfL Weekly/Grab602 TSS 30 mg/L 100 mg/L 2/Month Grab

Oil & Grease 15 mg/L 20 mg/L 2/Month Grab801 Temperature NA NA Daily

NOTES1. Collect samples for Total Residual Chlorine when system is being treated with only chlorine. Collect

samples for Total Residue/Oxidants when system is being treated with bromine.2. Collect samples twice per month if hydrazine-containing water directed to Outfall 002..3. Sampling is required only during discharge from the circulating water system (i.e. Cooling Tower Basin

Drain).

GENERAL EFFLUENT LIMITATIONS:1. There shall be no discharge of polychlorinated biphenol compounds.2. The effluent shall, at all times, be free of substances:

a. In amounts that will settle to form putrescent, or otherwise objectionable, sludge deposits or thatwill adversely affect aquatic life or water fowl. ;

b. Of an oily, greasy, or surface-active nature, and of other floating debris, in amounts that willform noticeable accumulations of scum, foam, or sheen;

c. In amounts that will alter the natural color of the receiving water to such degree as to create anuisance;

d. In amounts that either singly or in combination with other substances are toxic to human,animal, or aquatic life;

e. In amounts that are conducive to the growth of aquatic weeds or algae to the extent that suchgrowth growths become inimical to more desirable forms of aquatic life, or create conditionsthat are unsightly, or constitute a nuisance in any other fashion;

f. In amounts that will impair designated instream or downstream water uses.

ATTACHMENT 2: EXAMPLES OF NPDES REPORTABLE EVENTSPage 1 of I

A. NONCOMPLIANCE (Listed in Attachment 1, but discharged above specified limits)

1. Oil drained through east and/or west condenser pit sumps to the settling basins and out Outfall602 to the collection box in excess of 20 mglL or with a visible sheen.

2. Shock chlorination activities resulting in the discharge of total chlorine at Outfall 001 (beachstation) in excess of 0.2 mg/L or the discharge of any detectable amount (>0.05 mg/L) for morethan two hours per day.

B. UNAUTHORIZED DISCHARGE (Not listed on Attachment 1, but discharged above analyticaldetection limit)

1. Inadvertently draining a system containing sodium hypochlorite to the Training Center Pondand out Outfall 002 in a detectable amount (>0.05 mg/L), since there is no chlorine limit listedfor Outfall 002 on Attachment 1.

C. UNANTICIPATED BYPASS (Unplanned)

1. Failure of the wastewater treatment plant effluent pumps, resulting in the discharge of rawsewage to the Navarre Marsh Pool 3.

2. Failure of the North Settling Basin pumps, resulting in industrial process water overflowing thesettling basins and discharging into the Navarre Marsh Pool 2.

D. ANTICIPATED BYPASS (Planned drainage in a manner inconsistent with the NPDES permit.

1. Draining the cooling tower basin to the cooling tower pond for outage work without obtainingprior Ohio EPA approval. (This water may contain chlorine, which may only be discharged viaOutfall 001 beach station).

E. UPSET (Unintentional and temporary noncompliance)

1. During the spring months, Outfall 601 (Wastewater settling basin) may become overgrown withalgae. This is a natural part of tertiary sewage treatment, but it may result in the discharge oftotal suspended solids above the permit limit, which is reportable.

2. During the spring months, when intake water from Lake Erie has a high pH, the Outfall 001 pHmay exceed the maximum daily limit of 9.0 S.U. which is reportable, even though the intake pHis also high.

ED 7575A

DAVIS-BESSE ADMINISTRATIVE PROCEDURE

National Pollutant Discharge Elimination System(NPDES) Program

PAGE REVISION PROCEDURE NUMBER

18 00 DB-CN-00030

ATTACHMENT 3: OHIO EPA NPDES DATA CODESPage 1 of I

CODE

AA

AB

AC

AD

AE

AF

AG

AH

AJ

AK

AL

AN

COMMENT

Below detectable limit

Analytical Data lost

Plant not operating

Automatic analyzer out of service

Analytical data not valid

High stream water inundated sample site

Trace

Sample not taken, explanation in remark section

Above range of automatic sampler

Biological Sample - too numerous to count

No discharge for the month

Sample not taken, plant not normally staffed

EO 7575A

DAVIS-BESSE ADMINISTRATIVE PROCEDURE

National Pollutant Discharge Elimination System

(NPDES) Program

PAGE

19

REVISION PROCEDURE NUMBER

o0 DB-CN-00030

ATTACHMENT 4: NPDES SPILL RESPONSE FLOW CHART

Page 1 of I

0

DAVIS-BESSE BUSINESS PRACTICE Number *" DBBP-CHEM-2005

Title: Revision: Page

SPILL PREVENTION CONTROL ANDCOUNTERMEASURE (SPCC) PLAN 01 1 of 57

SPILL PREVENTION CONTROL AND COUNTERMEASURE(SPCC) PLAN

ý'). L C2ý-Ti /i .AILApproved: Date: s/__ _ _

MAR 2 8 200hEffective Date

DAVIS-BESSE BUSINESS PRACTICE Number:____________________________________ DBBP-CHEM-2005



TABLE OF CONTENTS

Paqe

1.0 PURPOSE 3

2.0 APPLICABILITY/SCOPE 3

3.0 DEFINITIONS 4

4.0 RESPONSIBILITIES 7

5.0 OIL DISCHARGE INITIATING CONDITIONS AND NOTIFICATIONS 8

6.0 SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN 12

6.1 General Information 12

6.2 Discussion of Oil Spill Containment 13

6.3 Oil Locations and Specific Oil Spill Situations 20

7.0 RECORDS 36

8.0 REFERENCES 36

ATTACHMENTS

ATTACHMENT 1 - DISCHARGE NOTIFICATION TABLE

ATTACHMENT 2 - DBNPS SITE AREA AND NEAREST TOWNS

ATTACHMENT 3 - DBNPS FINISHED SITE TOPOGRAPHY

ATTACHMENT 4 - DBNPS SITE MAP

ATTACHMENT 5 - DBNPS OIL LOCATION

ATTACHMENT 6 - CERTIFICATE OF THE APPLICABILITY OF NON-SUBSTANTIALHARM CRITERIA

ATTACHMENT 7 - RESPONSE EQUIPMENT / CONTRACTOR LIST

ATTACHMENT 8 - CERTIFICATION OF THE SITE SPECIFIC SPCC PLAN

ATTACHMENT 9 - SPCC COMPLETION OF REVIEW OF SITE SPCC PLAN

ATTACHMENT 10 - SPCC REVISION RECORD

ATTACHMENT 11 - SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLE

DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005



1.0 PURPOSE

1.1 The purpose of this business practice is to provide written documentation ofcompliance and countermeasures (such as equipment, workforce, and/orprocedures) for minimizing the potential of discharges of oil or oil related productsin harmful quantities into or upon navigational water of the United States, theadjoining shorelines or contiguous zones, or that may affect natural resources.

1.2 This business practice identifies all bulk containers of oil or oil related products andcountermeasures to be taken in the event of oil discharges from non-transportationrelated incidents, such as activities from transferring, distributing, using, orconsuming oil or oil products at DBNPS. Countermeasure contingencies forminimizing harmful discharges are required for both bulk storage containers and oilfilled electrical equipment.

1.3 This business practice, in conjunction with RA-EP-02850, Hazardous Chemical andOil Spills, the DBNPS Emergency (E) Plan, and requirements of the National Oiland Hazardous Substances Pollution Contingency (NPC) Plan, fulfills therequirements for the Spill Prevention, Control, and Countermeasure (SPCC) Plan.This plan is required for facilities storing greater than 1320 gallons in above groundstorage containers or when greater than 42,000 gallons is stored in an undergroundstorage container and the location provides potential for a harmful discharge of oil.

2.0 APPLICABILITY/SCOPE

2.1 Adherence to this Business Practice is Mandatory. Reference Section 5.0 forreporting, reference Section 6.2.5 for general oil clean-up actions, and referenceSection 6.3 for specific system responses.

2.2 This business practice applies to personnel who may be responsible forimplementation of the SPCC Plan. The scope of this business practice is to provideinstructions and required information for oil spill prevention and mitigation fromreleases of all above ground containers greater than 55 gallons, which includes allbulk storage containers, all Underground Storage or Bunkered Tanks, and all oilcontaining electrical or operating equipment.

2.3 For Hazardous Waste Operations Emergency Response (HAZWOPER)implementation, activate RA-EP-02850. The Off-Normal Emergency ResponseOrganization procedure provides detailed actions for immediate response to spillsor discharges from oils and/or chemicals.

DAVIS-BESSE BUSINESS PRACTICE Number:

DBBP-CHEM-2005Title: Revision: Page


2.4 Oil discharges may require additional response and mitigation actions if mixed withother regulated constituents.

NOTE 2.4.1

Hazardous substances 'inherent' to crude oil,gasoline, or oil products are not reportable under theComprehensive Environmental ResponseCompensations Liability's Act (CERCLA) orSuperfund Amendments Reauthorization Act (SARA).

2.4.1 Consult the Resource Conservation and Recovery Act (RCRA) ContingencyPlan/Spill Notification Requirements Business Practice (DBBP-CHEM-2003) for alisting of Reportable Quantities (RQs) for hazardous chemicals.

2.4.2 Consult the CERCLA/SARA Hazardous Chemical Locations and Spill EventGuideline (ECG-04) for response plans and clean up of hazardous chemicalstypically found at Davis-Besse.

2.4.3 For oil spills occurring from Polychlorinated Biphenyl (PCB) equipment, performcleanup per required Toxic Substance Control Act (TSCA) standards found in thePCB Activities and Response Plan (ECG-07).

3.0 DEFINITIONS

3.1 BULK STORAGE CONTAINER - Any container used to store oil (equal to orgreater than 55 gallons), including prior to use, while being used, seasonal storageor temporary storage, stand-by storage, or prior to further distribution in commerce.Bunkered and completely buried tanks are considered bulk storage containers. Bulkstorage containers require a regular schedule of integrity testing and when repairsare made as defined under the definition of "Repair" (such as tank repairs).

3.1.1 Oil-filled electrical or operating equipment is not considered a "bulk container" perthe SPCC regulations regarding secondary containment or integrity testing,however, countermeasures to prevent harmful discharges are required.

3.2 DISCHARGE - Includes but is not limited to any spilling, leaking, pumping, pouring,emitting, emptying, or dumping, of oil no matter where it occurs. The dischargehowever may not be reportable if the oil never escapes secondary containment oris fully contained on site and is promptly cleaned up. A harmful discharge isreportable to the National Response Center (reference Section 5.0). Dischargesgreater than 25 gallons in a 24-hour period that originate from an UndergroundStorage Tank, and do not meet any other 'harmful discharge' criteria, are onlyreportable to the Bureau of Underground Storage Tanks (reference step 5.4.2).




3.3 EMERGENCY RESPONSE - A response effort by employees from outside theimmediate release area or by other designated responders (i.e. local firedepartments or contracted responder) to a spill event which results or is likely toresult in an uncontrolled release of a hazardous chemical or oil. Responses toreleases of oil (or hazardous chemicals) where no potential safety or health hazardexists or the potentials for harmful discharges are mitigated and no regulatoryagency notifications are required, are not considered emergency responses.

3.4 ENVIRONMENT - For the purpose of this business practice, means outside of thesystem or diversionary structures (drum, container, tank, pipeline, process vessel,etc.) intended/designed to contain a hazardous chemical or oil or prevent it'srelease such that it becomes a harmful discharge.

3.5 ENVIRONMENTALLY EQUIVALENT METHOD - An alternate method for integritytesting that must effectively minimize the risk of container failure and allowdetection of leaks before they become significant (reference (112.7(a)(2). Examplesinclude: Elevated drums or shop built containers (shell capacity less than 30,000gallons), when a frequent visual inspection is accompanied by additional actions toensure containers do not come in contact with soil, such as, elevating thecontainers so all sides are visible during inspection, or placing on a barrier(synthetic liner) between the container and the ground.

3.6 HARMFUL DISCHARGE - A 'harmful discharge' is a discharge that escapessecondary containment and can reasonably be expected to be discharged inharmful quantities into or upon navigational water of the United States, theadjoining shorelines or contiguous zones, or affect natural resources. Examples ofharmful discharges include discharges that violate applicable water qualitystandards (causes a film, sheen or discoloration of water surface, or a sludge oremulsion deposited beneath water surface), or discharges which have migrated outof control of or off of company property.

3.7 NAVIGABLE WATERWAYS - Indicates the following:

3.7.1 All navigable water of the United States (U.S.), and adjacent wetlands (for example,the marsh surrounding DBNPS).

3.7.2 Tributaries of navigable waters of the U.S. (including adjacent wetlands).

3.7.3 All other waters of the U.S. such as intrastate lakes, rivers, streams, and wetlandswhich may be used for recreational or commercial (including commercial fishing)purposes.




3.8 OIL - Includes petroleum; gasoline; fuel oil; oil refuse; and mixture of oil with wastesother than dredged oil.

3.8.1 Oils contaminated with PCBs or hazardous chemicals, not inherent to the oil, shallalso be considered hazardous chemicals. The RCRA Contingency Plan(DBBP-CHEM-2003), SARA/CERCLA Response Business Practice Guideline(ECG-04) or, the PCB Activities and Response Plan (ECG-07), as appropriateshould also be consulted.

3.9 OIL BOOM - A floating device that confines oil spilled on the surface of a body ofwater.

3.10 PERMANANTLY CLOSED - Containers are considered 'permanently closed' afterall liquid or sludge is removed, connection line(s) and piping are disconnected andblanked off; all valves (except ventilation valves) have been closed and locked, andsigns have been posted stating closure with a notation of the date of closure.

3.11 REPAIR - Any work necessary to maintain or restore a container to a conditionother than that necessary for ordinary day-to-day maintenance to maintain thefunctional integrity of the container and that does not weaken the containerintegrity.

3.12 SECONDARY CONTAINMENT - Countermeasures such as, cathodic protection ofburied piping, double-walled pipes, earthen or natural structures or berming, oilinterceptors, containment pallets, diversionary or drainage structure, employed toensure containment of oil from breach of a container or piping, and is applied inaccordance with good engineering practice and judgement. Secondarycontainment is required for all bulk storage containers.

3.13 SMALL SPILL OR DISCHARGE / INCIDENTAL RELEASE - Small spills ordischarges (i.e. incidental releases of chemicals or oils) which can be absorbed,neutralized, or contained at the time of release by trained employees in theimmediate release area or by maintenance personnel. An incidental release ordischarge poses no safety or health hazard (i.e. fire, explosion, or chemicalexposure), cannot be reasonably expected to be discharged in harmful quantities orpose a potential harmful discharge off-site, and do not require off-site notificationsof the release. These spills/discharges/releases are not "spill events" and do notrequire "emergency responses. Note however, that in accordance withAttachment 5 of RA-EP-02850, even listed typical small or incidental releases mustbe reported to the Control Room.





4.1 The Supervisor - Nuclear Chemistry Services shall:

4.1.1 Provide overall administration of this business practice.

4.1.2 Make required onsite and offsite notifications and prepare regulatory reports.

4.1.3 Provide technical assistance during response and clean-up efforts to ensure timelymitigation of spill.

4.1.4 Ensure that spill equipment or kits for use with potential oil discharges on site arestocked with emergency response equipment, or contractual arrangements aresecured for emergency response.

4.1.5 Designate site individual(s) as 'Emergency Coordinator'/'Oil Spill ResponseCoordinator' (primary and alternate).

4.1.6 Complete a review and evaluation of the SPCC Plan at least once every five yearsand:

1. Amend within 6 months of changes in facility design, construction, operation, ormaintenance, that materially affects the potential for oil discharge in harmfulquantities of oil to into or upon navigable waters, adjoining shorelines shore-lines, contiguous zones, or that affect natural resources. Notifications may bemade in accordance with Regulatory Applicability Determinations andEnvironmental Evaluations. Examples of activities potentially requiringamendments to the SPCC Plan include decommissioning of tanks orcontainers, replacement, reconstruction or movement of containers,reconstruction, replacement or installation of piping systems, and, changes inproduct or service or revision of standard operation or maintenance proceduresaffecting the plan.

2. Amendments to the SPCC Plan must be implemented as soon as possible, butno later than 6 months following preparation of the plan amendment (no laterthan 12 months after the change or activity causing the amendment.)

3. The review shall include amendments to the plan within 6 months to includeeffective prevention and control technology if the technology has been fieldproven at the time of the review, and will significantly reduce the likelihood of adischarge in harmful quantities. The reviews shall indicate if amendments arerequired, and if amended, certified by a licensed Professional Engineer (PE).




4.2 Other actions for an oil spill response as required per RA-EP-02850 may occurconcurrently with the SPCC Plan implementation. These actions may include:

4.2.1 The Shift Manager or designee may make required onsite notifications anddetermine if a spill event has occurred which requires implementation ofHAZWOPER.

4.2.2 Industrial Safety may prescribe personnel protective equipment and practicesduring an emergency response.

4.2.3 The Superintendent - Nuclear Maintenance Services may direct isolation of sitewaterways during a spill event and provide clean up of spilled materials.

4.2.4 All DBNPS personnel shall immediately report oil spill events or observed oil

discharges to the Shift Manager.

4.3 All oil discharges shall be mitigated as soon as possible after discovery.

5.0 OIL DISCHARGE INITIATING CONDITIONS AND NOTIFICATIONS

5.1 If an 'incidental' release or discharge of oil does not meet conditions of reportabledischarges listed under Step 5.2, and poses no threat of migration to the offsiteenvironment or of becoming a "harmful discharge", then the SPCC Plan is notrequired to be implemented. Actions for immediate mitigation and cleanup of all oildischarges are still required. Reference RA-EP-02850, Attachment 5 for additionalinformation for appropriate PPE or disposal information for incidental releases.

5.1.1 Reportable NPDES violations which pose no threat of migration of oil or hazardoussubstance in harmful quantities or harmful discharges, do not require SPCC Planimplementation. Only the NPDES notification requirements as specified in thepermit are imposed.

5.2 The SPCC Plan notifications and appropriate mitigation responses shall beimplemented as directed by the Supervisor - Nuclear Chemistry Services (orEmergency Coordinator designee) when one or more of the following conditionsinvolving oil discharges has occurred:

5.2.1 Any oil release greater than 25 gallons within a 24-hour period originating from aregistered Underground Storage Tank (UST) or associated piping.

5.2.2 Any oil release greater than 25 gallons within a 24-hour period not solely containedwithin the facility.

5.2.3 Any oil leakage which is suspected to be contaminated with a hazardous substanceexceeding a Reportable Quantity, which is not solely contained within the facility.

DAVIS-BESSE BUSINESS PRACTICE Number:DBBP-CHEM-2005



5.2.4 A volume of oil in "harmful quantities" or designated as a "harmful discharge" hasreached a navigable waterway, entered a National Pollutant Discharge EliminationSystem (NPDES) pathway, or discharged to affect natural resources (has migratedoff of company property.)

5.3 If a discharge event as listed in Step 5.2 has occurred, the Supervisor - NuclearChemistry Services (or Emergency Coordinator designee) will perform the followingOnsite/Company Notifications as necessary. These notifications may bedocumented, on the Spill Notification Form (ED 7892.) Additional phone numbersmay be found in the DB or E Plan Telephone Directory (Section 2.2), or Attachment1 (Discharge Notification Table) of this Business Practice.

* Manager - Site Chemistry

• Manager - Site Regulatory Compliance

" Director - Site Engineering, as applicable

* Superintendent - Nuclear Electrical Maintenance, Nuclear I&C Maintenance,Nuclear Mechanical Maintenance, or Nuclear Maintenance Services, asnecessary, if the discharge originated from electrical or mechanical equipment,or for additional support

" Director - Site Operations

" FirstEnergy Environmental Permitting and Compliance (courtesy call)

* Public Affairs (optional notification - this office will contact Governmental Affairsif required, reference E Plan Telephone Directory)

5.4 If a discharge event as listed in Step 5.2. has occurred, the Supervisor - NuclearChemistry Services (or Emergency Coordinator designee) will perform the followingOffsite/Regulatory Notifications as necessary. These notifications may bedocumented on the Spill Notification Form (ED 7892.) Additional phone numbersmay be found in the DB or E Plan Telephone Directory and either Attachment 1(Discharge Notification Table) or Attachment 7 (Response Equipment/ContractorList) of this Business Practice.

5.4.1 IF an oil release has occurred in accordance with Step 5.2.1 from any of thefollowing registered underground storage tanks:

1. TA153-01 or TA153-02; 40,000 gallon Emergency Diesel Generator Fuel OilStorage Tanks, or,

2. 8,000 gallon DBAB Emergency Diesel Generator Oil Storage Tank

DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBB P-CHEM-2005



THEN within 24 hours notify the State Fire Marshal (1-800-686-2878) and CarrollTownship Fire Department (419-898-4906). Ensure notifications listed underStep 5.4.2 are also performed if the release is a 'harmful discharge' (referenceStep 3.6 for detailed description of a harmful discharge).

5.4.2 IF a discharge or release, as listed in Steps 5.2.2 or 5.2.3 has occurred, such as:

1. An oil or gasoline discharge greater than 25 gallons which poses a threat topersonnel outside of the site boundary, or could possibly migrate outside of siteboundaries "to become a harmful discharge", or,

2. Any amount of PCB oil (>50 ppm) or "harmful quantities" of gasoline, ornon-PCB oil have spilled directly into a waterway or may become a "harmfuldischarge", or,

3. Oil mixed with a hazardous substance (which is not inherent to the crude oil,gasoline or oil product) greater than the reportable quantity, and is notcontained within site boundaries (reference ECG-04 for 40 CFR 302 or 40 CFR355 RQs of materials typically stored on site),

THEN within 30 minutes notify the Ohio EPA Emergency Response Center(1-800-282-9378), the Ottawa County Sheriff to activate the Local Fire Departmentand Ottawa County Local Emergency Planning Committee (LEPC) notifications(419-734-4404), and the National Response Center (1-800-424-8802).

5.4.3 IF an oil or PCB event, has occurred in accordance with Step 5.2.4. which:

1. Affects NPDES water discharge pathways, or,

2. Is a bypass of the normal route of NPDES discharge,

THEN within 24 hours notify the OEPA Emergency Response Center(1-800-282-9378) in accordance with DB-CN-00030.

5.4.4 IF the oil discharge affecting NPDES pathways is a PCB discharge, or dischargesgreater than the RQ,

THEN they must additionally be reported within 30 minutes to agencies listed inStep 5.4.2. EPA may assign the same case number to discharges meeting criteriaof 5.2.3 and 5.2.4.

5.5 Contact the Supervisor - Nuclear Chemistry Services (or Emergency Coordinatordesignee) for determination of the required response for oil discharges not listed.




5.6 The following information shall be available for reports to offsite regulatory

agencies:

* Name and telephone number of facility's reporter

* Name and phone number of the facility and owner

" The exact address of the facility

* The date and time of discharge

* The name, source and type of material discharged, estimating the totalquantity, and the estimates of quantities that are considered a "harmfuldischarge"

* The source and cause of the discharge, to what medium the release occurred,and damages or injuries

* Actions to stop, remove, or mitigate the effects of the discharge,

" Whether evacuation may be needed,

" The names of individuals or organizations contacted.

5.6.1 In addition to the required information to be reported, insure the followinginformation is also provided for oil discharges involving hazardous substances(reference Step 5.2.3 and Note 2.4.2)

Possible hazard to human health (known or anticipated, acute or chronic) or to

the environment outside the facility, and

• Where advice or medical attention may be obtained, if required

5.7 Follow-up reports should be submitted in accordance with NG-RA-00807 andNG-NS-00808 for the following:

5.7.1 In accordance with 40 CFR 280.62(a) and (b), written reports for reportable USTreleases shall be submitted to the governing agency within 20 and 45 days,summarizing abatement, and corrective action plans, respectively. Ensureadditional reports as required in steps 5.7.2 - 5.7.4 are prepared if the releasemeets the conditions specified as a 'harmful discharge'.




5.7.2 In accordance with Environmental Compliance Guideline ECG-04, a written reportas defined in OAC 3750 25-25 shall be submitted within 30 days of a reportableSARA/CERLA spill. The report must be submitted within 15 days if the reportablehazardous oil spill discharge originated from the Chemical Waste Storage Area oran accumulation area.

5.7.3 In accordance with DB-CN-00030, a written report shall be submitted within 5 daysfor all NPDES violations.

5.7.4 A written report shall be submitted within 60 days for discharges more than 1000gallons in a single discharge, or two discharges of more than 42 gallons each withina 12 month period that are considered a 'harmful discharge". The report shall beprepared in accordance with requirements of 40 CFR 112.4.

6.0 SPILL PREVENTION CONTROL AND COUNTERMEASURE (SPCC) PLAN

6.1 General Information

6.1.1 The plan shall be reviewed not less than every 5 years and:

1. Amended and certified within 6 months of facility changes which affects thepotential for discharge of oil into or upon navigational waters of the U.S. oradjoining shore lines, or affecting natural resources (reference Step 4.1.6 forexamples of facility changes that may affect the plan.)

2. Amended and certified if control technology which reduces the likelihood of adischarge becomes available and is field proven.

6.1.2 Name and location of facility:

Name: Davis-Besse Nuclear Power StationLocation: 5501 North S.R. 2, Oak Harbor, Ohio 43449-9760Emergency Telephone Number: 419-321-7283

Direction and distance to nearest town - Oak Harbor (SW - 6.5 miles)

Township: Benton-Carroll County: Ottawa State: Ohio

Nearest Major Roadway: State Route 2 (Contiguous on the West)

Nearest Watershed: Navarre Marsh (Contiguous on the North, East, and South)

Nearest River: Toussaint River (1 mile South)

A site area and nearest towns diagram is provided in Attachment 2.




6.1.3 Direction of Surface Flow and General Topographic Description: The naturalsubstrate surrounding the facility and indigenous to the area is blue clay, limitingnatural permeability. The facility drainage is installed such that oil interceptors andcatch basins discharge via storm sewers or diversionary systems to site controlledbasins or ponds. The natural substrate under the operating facilities was excavatedduring construction and replaced with a low permeable highly compacted crushedstone. The parking lots are asphalt covered, and limited areas have concretecovers (such as the Dry-Fuel Storage Pad.) There are no significantly treed areasand only sparse areas of shrubs or grasses on the operating premises. Thecontingent marsh is densely forested and maintained by the U. S. Wildlife Service.A site topographic diagram is provided in Attachment 3.

6.1.4 Name, address, and phone number of owner or operator:

Name: FirstEnergy Nuclear Generation CorporationCounty: SummitAddress: 76 South Main St. State: OhioCity: Akron Zip: 44308-1890Telephone Number: 800-633-4766

6.1.5 Name or title of person in charge of facility:

Name or title: Director- Plant Operations

6.1.6 Name of person responsible for oil spill prevention/mitigation at facility:

Name or title: Shift Manager

6.1.7 Certification

The Plan requires certification to attest the information contained in the plan is true,complete, and accurate, and prepared in accordance with good engineeringpractices. The plan does not require re-certification for plan changes that do notrequire engineering judgment. Attestations for the PE certifications are includedunder Attachment 8.

6.2 Discussion of Oil Spill Containment

6.2.1 Security Considerations

All the oil tanks at the Davis-Besse Nuclear Power Station are located in an areathat has a security lighting system and is patrolled 24 hours a day by securitypersonnel. Most of the tanks are located behind the inner fence within theProtected Area. The possibility of vandalism and tampering is minimized throughcontrolled access to the site via the Service Road and by virtue of the plant'sdistance from the highway. A site map is provided in Attachment 4.




6.2.2 Personnel Training

Designated Operations, Maintenance and HAZWOPER personnel responsible forresponding to an oil spill are on site or on call continuously to ensure immediateresponse to site spills or contracting outside support if required. Site responsepersonnel are trained in the following and receive annual refresher training.

1. Known failures or equipment malfunctions, and prevention procedures,practices, and opportunities to improve compliance,

2. Proper operation and maintenance of equipment to prevent discharge of oil

3. The proper procedure to follow in the event of an oil spill situation

4. Applicable Spill Prevention Control and Countermeasures (SPCC) PollutionLaws, Rules and Regulations, and site procedures for implementation.

NOTE 6.2.3

Oil-filled electrical, operating and manufacturing devicesor equipment are not exempt from integrity testingrequirements of 40 CFR 112.8 (c)(6).

6.2.3 Discussion of Oil Tank and Piping Testing/Inspection/Protection

1. 40 CFR 112.8 (c) states bulk storage containers must be regularly integritytested. Integrity testing is a combination of visual inspection plus one othertesting technique and is required for all above ground bulk storage containers.Testing techniques include visual inspections plus hydrostatic testing,Ultrasonic, Radiographic, Acoustical, or other non-destructive shell thicknesstesting. Integrity testing includes leak testing for valves and piping. Tanksupports and foundations should be included in these inspections. Also, thetank exterior shall frequently be observed for signs of deterioration, leaks thatmight cause a spill, or accumulation of oil in diked areas. Acceptabledocumented methods include Hybrid Testing, Industry Standards, andEnvironmental Equivalent.

a. The integrity testing applies to large field-constructed or field-erectedwelded metal above ground tanks (AST); name-plated as field-erected ifless than 50 feet high and a 30 foot diameter (or without a name-plate ifgreater than 50,000 gallons), and small welded-metal shop fabricated ASTnot otherwise identified as field-erected with a volume less than 50,000gallons.


Title: Revision: Page* SPILL PREVENTION CONTROL AND

COUNTERMEASURE (SPCC) PLAN 01 15 of 57

b. Industry Standards for containers built to specified design in accordancewith recommended industry practices may be used for integrity testing byfacility owners and operators and by the certifying PE as references of goodengineering practice for assessing the fitness of service for containers, orevaluating the suitability of containers for continued service. IndustryStandards for recommended practices for piping, valves andappurtenances, may also be applied. The PE may also implement "Hybrid"inspection programs based on professional judgment for uniquecircumstances, or when industry standards are not specific for a tankconfiguration.

Examples of accepted Industry Standards include: API 653, STI SP-001,API 650, API 12C, API 12R1, API RP 575, API RP 12R1, API 570, API RP574, API RP 1110, API RP 579, API 2610, ASME B31.2, ASME B31.4-2002, and DOT 49CFRParts 173.28, 178.803, or 180.605.

c. The Environmental Equivalence provision applies to the inspection andappropriate integrity testing of bulk storage containers. The PE has theflexibility to offer environmental equivalent integrity testing options for allclasses of tanks, including shop-built tanks above 30,000 gallon capacityand field-erected tanks, if the rationale is provided or appropriate industrystandards are referenced.

d. In cases where a regularly scheduled inspection and testing program is notcurrently identified, no baseline information is available, and noenvironmental equivalence or Industry Standard for integrity is documented,the Industry Standard or strategy for regular testing must be identified andcollection of baseline information testing must be scheduled within 10 yearsfrom tank installation, or within the first five-year review cycle of the SPCCPlan (within 5 years from effective implementation date of August 18, 2006and completed by August 18, 2011) in order to establish a regular integritytesting schedule based on current container conditions. Testing isperformed under the site Work Management Program, or tracked forcompletion under the site Corrective Action Program/SAP Activity TrackingItems for integrity or baseline testing to be initiated (reference Attachment11 notes for individual ASTs).

2. All areas (zones) containing operational equipment, oil storage tanks andstorage containers at DBNPS are periodically visually inspected by variousgroups, i.e. Operations, Maintenance, and/or Engineering. PeriodicMaintenance and Testing activities for specific tanks, such as the EmergencyDiesel Generator Fuel Oil Storage Tanks (40,000 gallon capacity each), areperiodically drained and inspected internally. The requirements for theinspections and testing are managed and documented through the Work

,hk Management Process.

DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBBP-CHEM-2005Title: Revision: Page


3. The oil storage tank transfer lines at DBNPS are wrapped and cathodicallyprotected. Inspections are performed on a standard preventative maintenanceprogram, or as excavation activities allow. Any storage tank transfer lineleakage from offloading of bulk oil would discharge via the storm system and oilinterceptors to onsite secondary containment. Leakage from onsite transferlines would be identified as indicated in Step 6.2.4 discussion.

4. Protection is additionally provided by the use of monitoring controls andsecondary containment. Tank levels are monitored visually, and by use ofgauges and high level alarms. Level devices are regularly tested. Effluentsdischarged into navigable waters are site monitored by a NPDES permit.Portable storage tanks are required to have sufficient secondary containment.

5. The concept and nature of nuclear operations, training and frequent zonewalkdowns ensures above ground valves and pipe-lines are subjected toregular visual examinations. Station drainage and discharge is procedurallycontrolled.

6. Vehicular traffic within the protected area is minimal. IF vendor vehicles areallowed access, THEN the vehicle is accompanied by Security personnel.

7. Integrity testing, secondary containment, or new requirements are verifiedagainst 40 CFR 112.8 criteria pursuant to the 5-year required review.Deficiencies are tracked under the site corrective action program forimplementation of acceptable corrective actions or countermeasures inaccordance with Step 4.1.6. (example: tracking through completion ofapplicable corrective actions for addition of brittle failure evaluations when field-constructed tanks of shell thickness greater than 1/2 inches are repaired.)

6.2.4 Discussion of Oil Interceptors

1. All drains in the plant, where oil contamination is postulated, discharge to theStorm Sewer System via a Josam Oil Interceptor (exception is the East andWest Condenser Pit Sumps, which are redirected to the Settling Basins). Thereare six (6) Oil Interceptors (01) strategically located to accommodate the drainsin the station. Oil Interceptors 1, 2, 3, 4, 5, and 7 drain to the Training CenterPond. There are two (2) Oil Interceptors 6A and 6B, which are located in thenortheast parking lot and which drain to the marsh. The parking lot by thePersonnel Access Facility (PAF) does not have Oil Interceptors.

The Oil Interceptors are located in the following areas:




Oil Interceptor #1:

Oil Interceptor #2:

Oil Interceptor #3:

Oil Interceptor #4:

Oil Interceptor #5:

Oil Interceptor #6A:

Oil Interceptor #6B:

East of the Turbine BuildingReference Drawings: C-55250 Gallon CapacityInfluent Drain Source: Turbine Building Sump PumpDischarge

North of Station Turbine BuildingReference Drawings: C-55250 Gallon CapacityInfluent Drain Source: Turbine Building Sump PumpDischarge

Near Station Valve Room No. 2Reference Drawings: C-55100 Gallon CapacityInfluent Drain Source: Diesel Fire Pump RoomSump Pump Discharge

Near the Diesel Fuel Oil Pump HouseReference Drawings: C-55100 Gallon CapacityInfluent Drain Source: Diesel Oil Pump HouseSump Pump Discharge, Diesel Oil Storage Tank

North of the Auxiliary BuildingReference Drawings: C-55250 Gallon CapacityInfluent Drain Source: Multiple Floor Drains in EDGRooms

Main Parking Lot by ServiceBuilding 4Reference Drawings: C-55100 Gallon CapacityInfluent Drain Source: Parking Lot Storm DrainsTotal Capacity (including Storage Tank): 1300gallons

Main Parking Lot by ServiceBuilding 5Reference Drawings: C-55100 Gallon CapacityInfluent Drain Source: Parking Lot Storm DrainsTotal Capacity (including Storage Tank):1300 gallons




Oil Interceptor #7: Service Building 6Reference Drawing C-55100-159 Gallon CapacityInfluent Drain Source: Station Blackout DieselGenerator Fuel Storage Tank

NOTE 6.2.4.2

Preventive Maintenance records are generated bymaintenance services to document pumpingactivities. Such records list, at a minimum, the date,area, and quantity of liquid pumped from theinterceptor storage tanks.

2. Each oil interceptor is equipped with an oil storage tank. These oil storagetanks collect and contain the oil accumulated from leaks, accidents or rupturesof oil systems, oil tanks and equipment containing oil. Levels in these tanks areperiodically checked and pumped out in accordance with Work ManagementProcess.

3. If any of the oil interceptor storage tanks are overfilled in the event of oil spill,observe the south settling basin or Training Center pond for evidence of oil.Contain the oil by closing flapper gates in the Training Center Pond and/orturning off north settling basin pumps and using oil booms and absorbentmaterial. Also, oil booms and absorbent material may be used at the spillsource to contain and prevent more oil from entering, the oil interceptors.

6.2.5 Oil Discharge Cleanup - General Actions and Commitment of Manpower,Equipment and Materials

1. Symptoms

a. Visible oil slick on surface of floor, ground, or water.

b. Leaks from equipment containing oil such as pumps and lubricating lines.

2. Specific Action

a. Identify and mitigate fire, explosion or vapor hazards (implementRA-EP-02850 if HAZWOPER response is required).

b. Isolate waterways if applicable.

c. Visually inspect release site, monitor and mitigate further hazards.


DBBP-CHEM-2005Title: Revision: Page* SPILL PREVENTION CONTROL AND

COUNTERMEASURE (SPCC) PLAN 01 19of57

d. Use any equipment available, such as absorbents, oil booms, and sandbags, to minimize the leak, contain the released material, and preventfurther release to the extent possible (Reference system specific responseslisted in Section 6.3).

e. Contact available vendors for supplies and equipment to control, contain,minimize, remove, and clean up the harmful discharge. If support inaddition to the established contracted agreements are required, listings ofsupplemental Commercial firms may be located in the DBNPS EmergencyPlan Telephone Directory.

f. Remedy hazards posed by contaminated soils or waste, and determinepresence of release and free product removal techniques if applicable.Soils and wastes shall be disposed of in accordance with the site wastehandling procedure for Hazardous and Non-hazardous wastes, NG-DB-00504.

g. For PCB oil spills, or hazardous substance oil spills, refer to EnvironmentalCompliance Guideline ECG-07, or ECG -04, as appropriate, for clean-upresponse.

h. For Oil spills within the RRA, follow ALARA precautions and useappropriate Radiation Protection procedures in addition to the applicablerequirements of this procedure.

3. Discussion

a. The station is equipped with retention areas and oil interceptors to preventany oil discharges and procedural controls (DP-OP-06272, StationDrainage and Discharge System) for Chemistry notification when drainagerouting is altered. If an accident causes an oil spill on the roadways andparking lot, or the drainage system becomes contaminated with oil, everyeffort shall be made to determine the source and curtail any additionalspillage. Most of the storage containers have secondary containment byuse of a containment dike, berm, or retaining structure, cathodic protection,or oil interceptors. The registered Underground Storage Tanks (UST) arenot completely regulated under 40 CFR 280 Regulations due to exclusionsfor Nuclear Power Emergency Generator Status. The site-USTs aretherefore regulated under both the SPCC Plan requirements and the USTregulations. Storage containers have been verified to be discharged to sitecontrolled diversionary structures or ponds, which are monitored under thesite NPDES permit, or contained within curbing or sumps inside the facilityto prevent a harmful discharge. Countermeasures are required for theDBAB Emergency Diesel Generator Storage (and Day) tanks. The storagetank lines are not cathodic protected or wrapped, and the day tank does nothave secondary containment. The tanks are designed to discharge to site




Pond 19, located just west of the Cooling Tower. The pond does have agate valve to prevent uncontrolled outflow and the out-fall is also amonitored release path under the site NPDES permit. For additionalcompensatory measures, outside contractor agreements are in place.Reference each specific discussion for a prediction of the direction, flowpath, and total quantity of oil that may be discharged from each sitecontainer.

b. Transfer operations are performed under strict security and controls.Fugitive overfills will discharge to site diversionary structures. Referencethe specific discussions for each container. Total containment from thelargest tanker discharged is required.

c. Portable containers must have sufficient secondary containment for theentire contents and appropriate precipitation freeboard.

d. Precipitation will accumulate in the retention areas and is periodicallypumped out by Maintenance Services.

e. Various locations are equipped with oil spill pads, booms, or absorbants.Water booms are used in conjunction with an oil weir at the dischargeponds from the oil interceptors. Contractual agreements ensureunnecessary delays are not encountered when outside support is required.Oil discharge response and cleanup are included in HAZWOPERpersonnel training. Reference the HAZWOPER procedure, RA-EP-02850for additional site staged resources.

6.3 Oil Locations and Specific Oil Spill Situations

6.3.1 Diesel Fuel Oil Storage Tank (DFOST) T45 Leak/Rupture(100,000 Gallons, Drawing 7749-C-34-18-5, Plant System 26-01)

1. Symptoms

Oil accumulation within the Diesel Fuel Oil Storage Tank retaining structure, orother evidence of tank leakage in the surrounding soils or down stream ofcatchbasin 31.

2. Specific Action

a. Utilize means available (drain covers, booms etc.) to keep oil away fromcatchbasin 31 (located just Northwest of the tank).

b. Observe the Training Center pond for evidence of oil. Contain oil in thepond by closing flapper gates and using booms. Contact Environmental foradditional support.




c. Isolate the tank or suspect lines from the system.

3. Discussion

The Diesel Oil Storage Tank is designed so that in the event of a leak orrupture, the retaining structure around the tank will contain the entire 100,000gallon capacity of the tank, plus an additional 15,000 gallons of precipitationand fire water. Periodically, the retaining wall area is checked and anyaccumulated precipitation is drained to the Diesel Oil Pump House Sump, Forthe diesel oil storage tank, Computer Alarm L378 receives data from tankcontents level transmitter LT 1441 (Foxboro Electronic Transmitter, DP Cell).LT 1441 is located in the southeast quadrant of the retaining moat, about 1.5feet above the moat floor, near the moat floor access ladder. A local levelindicator gauge is also located in the southeast quadrant of the moat area,about 6 feet above the moat floor under the tank access catwalk. This levelgauge (LIS-1 102, Varec Figure #2500 Series, Model B) is used to determineamount stored and to monitor amount in tank during filling operations. Any oilleakage into the backfill/catchbasin 31 is routed via the storm sewer to theTraining Center Pond. The pond has a weir at the influx and is able to beisolated.

6.3.2 Diesel Fire Pump Day Tank T47 Leak/Rupture

(350 Gallons, Drawing M-140-00028, Plant System 26-03, Intake Structure 575')

1. Symptoms

Oil accumulation within the Diesel Day Tank retaining curb.

2. Specific Action

a. IF the Diesel Oil (DO) Transfer Pumps, P8-1 and PB-2, are transferring oilto the Diesel Fire Pump Day Tank

b. THEN stop the DO Transfer Pumps P8-1 and P8-2

1) P8-1 is powered from MCC E12B (BE 1257), control switch HIS105.

2) P8-2 is powered from MCC F12B (BF 1257), control switch HIS1106.

3) The control switches may be placed in lockout positions.

3. Discussion

The Diesel Fire Pump is the backup fire safety system to the electric fire pump.The Diesel Fire Pump Day Tank may be filled with the use of the Diesel OilTransfer Pumps P8-1 and P8-2. The Diesel Fire Pump Day Tank (capacity 350

DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________{ DBBP-CHEM-2005Title: Revision: Page


gallons) is designed so in the event of a leak or rupture the retaining curbaround the tank will contain any accumulated oil.

6.3.3 Emergency Diesel Generator (EDG) Day Tank(s); T46-1 and T46-2 Leak/Rupture(12,000 Gallons Each, Drawing 7749-M129-1-3, Plant System 26-02, Rooms320A/321A)

1. Symptoms of Leakage

Oil accumulation within a Diesel Generator Day Tank Area (Room 321A-DayTank 1 / Room 320A-Day Tank 2)

2. Specific Action

a. In the event of a rupture in the Day Tank(s) 1-1 or 1-2, respectively:

1) Stop EDG Fuel Oil Storage Tank 1-1 Transfer Pump P195-1 with localbreaker BE1298 (MCC E12F)

2) Stop EDG Fuel Oil Storage Tank 1-2 Transfer Pump P195-2 with localbreaker BF 1230 (MCC F12A)

b. Use portable pumping equipment to pump the fuel oil from Oil Interceptor

#5 directly into appropriate containers.

3. Discussion

a. Due to special seismic construction in the area where the Diesel GeneratorDay Tanks are located, a rupture is very unlikely. Any fuel oil accumulatedfrom leaks in the Day Tanks (total capacity 12,000 gallons, 6000 gallonsper tank), Diesel Generators, or associated piping, are removed by the floordrains to the station process drains/storm sewer system via Oil Interceptor(01) #5, and containment at Training Center Pond in the event of OE #5overflow (250 gallon capacity). Also refer to Step 6.2.4.3 for furtheractions/discussions in the event the oil interceptor storage tank overfills.

b. In the event of a rupture, oil may be pumped to the Transformer CollectionTank and removed to appropriate containers.

6.3.4 Emergency Diesel Generator (EDG) Fuel Oil Storage Week Tanks T1 53-1, T1 53-2Leak/Rupture (40,000 Gallons Each, Drawings 7749-M129A -2-8 and 7749-M129A-1-6, Plant System 26-02)

1. Symptoms

Oil accumulation on the ground in the vicinity of the Emergency DieselGenerator Fuel Oil Storage Tanks.

S1

0

0

DAVIS-BESSE BUSINESS PRACTICE Number:___________________________________ DBB P-OH EM-2005



2. Specific Action

a. Utilize all means available (storm sewer drain covers, booms, etc.) to keepoil away from Catch Basin 17 (located just south of the tanks), andCollection Box 32 (located off the Northwest Corner of the tanks).

b. Observe the pond by the Davis-Besse Training Center for evidence of oil.Contain oil in the pond by closing the flapper gates, and using oil booms.The 40K DFOST spill equipment: sewer covers, pads or booms, arelocated in Service Building 2. Contact Environmental for additionalequipment.

c. Isolate the tank from the system.

3. Discussion

Each tank has a 40,000 gallon capacity. if a rupture or leak occurred below thelevel of liquid, the fuel oil would leak into the ground, requiring extensivecleanup. Local level indicators (analog meters) are located adjacent to the fillingpoint for each tank. Input for each indicator is received from a capacitanceprobe that is located within the tank (Indicator LI 4891 receives input fromprobe in Tank T1 53-1; Indicator LI 4892 receives input from probe in TankT1 53-2). The indicator registers from 30,000 gallons (0%) to 40,000 gallons(100%) on an inverse logarithmic scale, with a high level local alarm lightsetpoint of 39,850 gallons and a low level local alarm light setpoint of 38,000gallons. Periodic monitoring of tank inventories and close monitoring of fuel oillevels during filling procedures should prevent overfills from occurring. Thetanks are registered as Underground Storage Tanks.

6.3.5 Miscellaneous Diesel Generator Day Tank T168 Leak/Rupture(750 Gallons, Drawing 7749-M-1 25-114, Plant System 99-06)

1. Symptoms

Oil accumulation in Room 331, Miscellaneous Diesel Generator Day TankRoom.

2. Specific Action

a. Operations is notified that a High/Low Oil Level Alarm has been receivedfrom the Miscellaneous Diesel Day Tank.

b. Verify if there is (or is not) a tank leak/rupture.




c. IF a tank leak/rupture exists, close Isolation Valve DO 112, MiscellaneousDiesel Day Tank Isolation Valve, in the Miscellaneous Diesel Day TankRoom,

d. THEN stop the Diesel Oil Transfer Pumps, P8-1 and P8-2, if they arerunning.

1) P8-1 is powered from MCC E12B (BE 1257), control switch HIS 1105.

2) P8-2 is powered from MCC F12B (BF 1257), control switch HIS 1107.

3) The control switches may be placed in lockout positions.

3. Discussion

a. The Miscellaneous Diesel Day Tank Room is a retaining structure with nofloor drains that will easily contain the contents of the 740-gallon CapacityTank.

b. Valve DO 112 should be opened only when filling the Miscellaneous DieselDay Tank.

c. Normally the tank is gravity-filled from the Diesel Fuel Storage Tank.

6.3.6 Turbine-Generator (T-G) Lube Oil (LO) Storage Tank T32 Leak/Rupture(2 Tanks;- 14, 0000 Gallons Each, Plant System 89-01, Room 432,)

1. Symptoms

Oil accumulation within the T-G Lube Oil Tank Room, or actuation ofAnnunciator, Computer Points 9-6-1 (ref OS-024A, SH 2)

2. Specific Action

If a temporary pump is in the sump, ensure the pump is also shut off.

3. Discussion

The tank is equipped with Annunciator (computer point 9-6-D) and LevelAlarms (LSH 1165 and LSH 1250) tested per Maintenance Program (PM 1544).Visual inspections by periodic system walk downs are also performed. Any oilaccumulation from a leak or rupture in the T-G Lube Oil Tank Room or theLube Oil Storage Tank Room will drain into the Lube Oil Storage Tank RoomSump. The Sump pumps for that sump have been permanently disabled, so theaccumulated oil would be contained in the Lube Oil Storage Tank Room, thuspreventing any oil from reaching the storm sewer system. In the event the oilinterceptor storage tank is overfilled, refer to Step 6.2.4.3 for further actions.

S

0




6.3.7 Main Feed Pump Turbine (MFPT) Lubricating Oil (LO) Tanks (2) or MFPT Used LOTank Leak/Rupture (MFPT-LO-1200 Gallons Each, MFPT Used LO is 2800Gallons, Plant Systems 36-04, 565 Elevation)

1. Symptoms

Oil accumulation in MFPT LO Tank pit or West Condenser Pit Sump (drains tosump via floor drains).

2. Specific Action

a. Stop Condenser Pit (west) Sump Pumps by, opening the breakers at MCCE32B (BE 3289) for Sump Pump P 33-A and F32B (BF 3289) for SumpPump P 33-B.

b. If there is a temporary sump pump installed in the West Condenser Pitused to pump to the East Condenser Pit, ensure the temporary pump isalso shut off; it will be powered via a lead cord from a nearby 1 10Vreceptacle.

3. Discussion

a. Some oil leaks from the MFPT LO Tanks #1 and/or #2 will accumulate inthe MFPT LO Tank Pit. The Pit has drain plugs in place to prevent oil andliquid draining to the West Condenser Pit Sump through the floor drains.The West Condenser Pit Sump Level is automatically controlled by SumpPumps P 33-A and P 33-B, which may either discharge to the SettlingBasins if the redirect is in place or discharge to the storm sewer via OilInterceptor #2, which has an oil storage tank capacity of 250 gallons.Normal discharge path is to the Settling Basin. Sump pump discharge flowto 01 may be approved by Chemistry (per DB-OP-06272, drainage line-upchanges require Chemistry notification). In the event the oil interceptorstorage tank is overfilled, refer to Step 6.2.4.3 for further actions.

b. In the event of a large rupture in the MFPT LO Tanks (1200 gallons each),or the MFPT Used LO Tank (2800 gallons), stopping Condenser Pit (West)Sump Pump 1-IA at MCC E32B (BE 3289) and for Sump Pump 1-1B, MCCF32B (BF 3289) will cause the following events to occur:

1) Oil level in the sump will reach a High level.

2) High oil level will start the Condenser Pit Flood Pump P 174-1, whichdischarges to the settling basin.




6.3.8 Main Transformer Leak/Rupture (24,470 Gallons, Drawings C-78 through C-82)

1. Symptoms

Oil accumulation within the Main Transformer retaining structure andTransformer Collection Tank.

2. Discussion

In the event of a rupture in the ' Main Transformer, which contains 24,470gallons of oil, the retaining structure will collect the leaking oil and drain into theTransformer Collection Tank, which has a capacity of 41,400 gallons. This willprevent oil from reaching any waterway.

Station personnel should consider notifying TE Power Systems for possible

reclaiming of oil from the Transformer Collection Tank.

6.3.9 Auxiliary Transformer Leak/Rupture (4,600 Gallons, Drawings C-78 through C-82)

1. Symptoms

Oil accumulation within the Auxiliary Transformer retaining structure andTransformer Collection Tank.

2. Discussion

In the event of a rupture in the Auxiliary Transformer, which contains 4,600gallons of oil, the retaining structure will collect the leaking oil and drain into theTransformer Collection Tank, which has a capacity of 41,400 gallons. This willprevent oil from reaching any waterway.

Station personnel should consider notifying TE Power Systems for possiblereclaiming of oil from the Transformer Collection Tank.

6.3.10 Startup Transformer 01 Leak/Rupture (10,700 Gallons, Drawings C-78 throughC-82)

1. Symptoms

Oil accumulation within the 01 Startup Transformer retaining structure andTransformer Collection Tank.

SDAVIS-BESSE BUSINESS PRACTICE Number:__________________________________j DBBP-CHEM-2005



2. Discussion

In the event of a rupture in the 01 Startup Transformer, which contains 10,700gallons of oil, the retaining structure will collect the leaking oil and drain into theTransformer Collection Tank, which has a capacity of 41,400 gallons. This willprevent oil from reaching any waterway.

Station personnel should consider notifying TE Power Systems for possiblereclaiming of oil from the Transformer Collection Tank.

6.3.11 Startup Transformer 02 Leak/Rupture (10,700 Gallons, Drawings C-78 through

C-82)

1. Symptoms

Oil accumulation within the 02 Startup Transformer retaining structure.

2. Discussion

In the event of a rupture in the 02 Startup Transformer, which contains 10,700gallons of oil, the retaining structure will contain the leaking oil, preventing oilfrom reaching any waterway. Station personnel should consider notifying TEPower Systems for possible reclaiming of oil from the Transformer CollectionTank.

6.3.12 Bus Tie AC or BD Transformer Leak/Rupture (2,000 Gallons Each)

1. Symptoms

Oil accumulation within the affected Bus Tie Transformer Retaining Structureand Transformer Collection Tank.

2. Discussion

In the event of a rupture in the AC or BD Bus Tie Transformer, each of whichcontains 2,000 gallons of oil, the retaining structure will collect the leaking oiland drain into the Transformer Collection Tank, which has a capacity of 41,400gallons. This will prevent oil from reaching any waterway. Station personnelshould notify TE Power Systems for possible reclaiming of oil from theTransformer Collection Tank.




6.3.13 Spare Main Transformer (24,470 Gallons) and Spare Start-Up (16,865 Gallons)

1. Symptoms

Oil accumulation noted within the Spare Transformer retaining berm locatedoutside of the Protected Area near Service Building 2.

2. Discussion

In the event of a rupture in either 'Spare' Transformer, an earthen bermretaining structure will collect the leaking oil. A rain run-off drain in the berm isable to be isolated with a temporary drain cover to prevent storm run-off of oil inthe event of oil leakage, or during maintenance activities posing concerns for oilleakage.

6.3.14 Electro-Hydraulic Control (EHC) System Leak or Tank T79 Leak/Failure(800 Gallon System, Plant System 93-01)

1. Symptoms

For a leak, perform a visual inspection.

2. Specific Actions

a. Operations performs those actions required by alarm procedures.

b. Identify and cover floor drains in the area of the spill.

c. Dike and protect grating area near EHC Sump on 585 Level.

d. Soak up spilled material with Absorbal, clay, sawdust, or fuller's earth.

e. Flush spill area with detergent and water.

3. Discussion

The EHC system provides hydraulic fluid at sufficient pressure to operate theturbine valves; turbine stop and control valves, and combined intermediatevalves. Because of the high temperature involved, normal hydraulic fluid wouldpose a fire hazard. To avoid this, the EHC system utilizes "Fyrquel EHC" as anoperating medium. The EHC skid capacity is 800 gallons. Fyrquel - EHC hasan open cup flash point of 4550 F and is a Tri-Aryl Phosphate Ester. Thematerial is not corrosive to glass or metals, but will soften and deteriorateplastics and elastomers. The product is not considered a hazardous wasteand is not regulated by the EPA, however, hazardous by-products may bereleased when exposed to extremely high temperatures (i.e. steam). Wear

S1

S




suitable protective clothing to prevent skin and eye contact. The floor drain inthe vicinity of the EHC Skid flows to the West Condenser Pit Sump, ultimatelydraining to the South Settling Basin. The system is visually inspected throughperiodic walkdowns, and integrity tested under the Predictive MaintenanceProgram, PM 474 every 6 years. System level alarms are Annunciators 15-6-8 (3" from the top), 15-3-13 (24" from top), LSHH-2343 and LS2323.Reference OS-023-SH2.

6.3.15 Lubricating Oil Drum Storage Room (Room 337)

1. Symptoms

Oil accumulation within the Drum Storage Room.

2. Specific Action

Plug/patch or overpack the leaking container, if possible. The drain located inthe room has been closed permanently, therefore, no actions are required tokeep the oil away from the drain.

3. Discussion

A maximum of twenty-two (22) 55-gallon drums of oil can be stored on theirsides in racks. Site glasses/tubes which can be used to determine drum contactlevel and an outlet are located at the bung openings. The room has a retainingcurb located inside the door to prevent oil from spreading out of the room.

6.3.16 Personal Shop Facility (PSF) 2000-Gallon Waste Oil Storage Tank Rupture

1. Symptoms

a. Rapid lowering of tank level as indicated on Petrometer level indicatorlocated on wall inside door 365B.

b. Gradual lowering of tank level as indicated by inventory control methods.

2. Specific Action

a. Pump out waste oil remaining in tank.

b. Excavate tank to determine condition and remedial action.

3. Discussion

Twenty-one floor drains throughout the PSF feed a gravity-fed cast iron oilinterceptor located just inside and north of the roll-up door on the east wall ofthe PSF. Oil run-off from this oil interceptor goes to a 2000-gallon waste oil




storage tank located-just-outside the east wall of the PSF, online with the oilinterceptor. The 2000-gallon tank is Underwriters Laboratories (UL) listed,constructed of Fiberglas, installed below-ground, and carries a 30 year warrantyfrom the date of purchase (1987). Total failure is unlikely. See SSOE drawingsM-1 550 and 1551 for SSOE project number 84816. Routine inspections of thelevel gauge have consistently indicated de minimus only amounts of oilaccumulated in the tank. The tank has been deferred from registered USTstatus.

6.3.17 Station Blackout Diesel Generator (SBODG) Fuel Storage Tank T210 Leak/Rupture(1977 Gallons, Drawing M-180-AN-8-2, Plant System 26-05, Service Building 6)

1. Symptoms

a. Rapid lowering of tank level as indicated by inventory or level indicator.

b. Oil accumulation within containment dike.

2. Discussion

a. In the event of rupture of the 1977 gallon-tank, the retaining structure willcontain the oil, preventing the oil from reaching any waterway. If the oildoes overflow, the oil would discharge to oil interceptor #7 which has an oilstorage capacity of 100-159 gallons. (In the event the oil interceptor storagetank is overfilled, refer to Step 6.2.4.3 for further actions.) Volume verifiedper Calculation # CALC-ME-26.05-001.

NOTE 6.3.18

The containment vessel is not accessible duringplant operation, therefore entry forinspection/verification purposes is not possible.

6.3.18 Lubricating Oil Spill Within the Radiologically Restricted Area (RRA)

1. Symptoms

Oil accumulation on floor of containment or other locations within theRadiologically Restricted Areas (RRA), such as adjacent to reactor coolantpumps (RCP), oil drums, etc.

S

0

0




2. Specific Actions

a. If abnormal conditions exist for the RRA, the appropriate abnormaloperations procedures shall be initiated.

b. For other oil leaks/spills within the RRA, contain with absorbent materials orbooms.

3. Discussion

a. Each RCP has a lubricating oil reservoir consisting of two sumps, oneupper (capacity 200 gallons) and one lower (capacity 25 gallons).RCP 1-1-1 (P36-1) and 1-1-2 (P36-2) oil drains into RCP Motor Oil DrainTank 1-1-1 (T-156-1) (capacity 250 gallons). RCP 1-2-1 (P36-3) and 1-2-2(P36-4) oil drains into RCP Motor Oil Drain Tank 1-1-2 (T-156-2) (capacity250 gallons). Both drain tanks are designed to completely contain bothRCP oil reservoirs sumps and are equipped with a manual level indicator.The drain tank levels are checked when containment entry is possible.

b. Various pumps and equipment located in the RRA may contain smallamounts of lubricating oil. Any of this oil, if spilled, would accumulate in thearea of the equipment or flow to a floor drain which is connected to themiscellaneous Liquid Radwaste System. ALARA precautions and RPprocedures shall be followed in the RRA in addition to other stated cleanupmethods of an oil spill.

6.3.19 DBAB Emergency Diesel Generator (EDG) Day Tank Rupture(300 Gallons)

1. Symptoms

Oil accumulation within the Diesel Day Tank room or flow under building door toground outside.

2. Specific Actions

a. Pump out the remaining diesel fuel to an appropriate storage container.

b. Contain the oil using booms or other absorbent material.

3. Discussion

The DBAB EDG Day Tank (capacity 300 gallons) is constructed with aninlet/isolation valve (D-01) from the DBAB EDG Fuel Oil Storage Tank, an8,000-gallon tank. The tank is equipped with a manual level gauge.

DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ___ ___ ___ ____ ___ ___ ___ ___ ___DBBP-CHEM-2005



6.3.20 DBAB Emergency Diesel Generator (EDG) Fuel Oil Storage Tank Rupture

(8000 Gallons)

1. Symptoms

a. Loss of diesel fuel oil as indicated by manual tank gauge readings.

b. Accumulation of oil on surface of Training Center Pond.

2. Specific Actions

a. Pump out the remaining diesel fuel to an appropriate storage container.

b. Contain the oil using booms or other absorbent material.

c. Notify contracted response organization for control, removal, and cleanupof discharge as appropriate.

3. Discussion

The DBAB EDG Fuel Oil Storage Tank (Capacity 8,000 gallons) is anunderground storage tank constructed of fiberglass reinforced plastic with nointernal tank protection and piping is of bare steel (no cathodic protection). Thistank is registered as an Underground Storage Tank. Leakage is routed to siteTraining Center Pond that is able to be isolated. Temporary TransportationLoad Pad is available for use during loading/offloading fuel.

6.3.21 Fuel Tanks Located At Service Building 4(Diesel is 1,000 Gallons and Gasoline is 2,000 Gallons)

1. Symptoms

Diesel fuel and/or gasoline has accumulated within the concrete dikesurrounding the fuel tanks.

2. Discussion

The diesel fuel storage tank (capacity 1,000 gallons) and gasoline storage tank(capacity 2,000 gallons) are contained in a concrete retaining structure. Thisstructure is designed to contain the total volume of both tanks plus anadditional 15% capacity for precipitation and fire water. Periodically, the dikedarea/structure is checked and any accumulated liquid is removed to theappropriate waste drum or rain/storm water is inspected to ensure complianceof no oil sheen or other water quality nonconformance prior to superviseddrainage. In the event the tanks are taken out of service, two 500 gallontemporary storage tanks with secondary containment may be staged.




NOTE 6.3.22

a. The Chemical Waste Storage Area (CWSA)is located outside of the Protected Areanortheast of the Switch Yard.

b. Chemical Waste Accumulation Areas(CWAAS) may be located at the followingareas:

1) Self-contained storage buildingadjacent to the north Train Bay Door ofthe Turbine Building, within theProtected Area

2) Self contained storage/containment padoutside the Mechanical Shop (oil/refuseonly).

3) Self contained storage outside ServiceBuilding (SB) 6, SB 4, and the 100Kand 40K DFOST storage tanks.

6.3.22 Waste Diesel Fuel/oil in Containers in Chemical waste Storage Area (CWSA),Chemical Waste Accumulation Areas (CWAA), or Warehouse Storage

1. Symptoms

a. Oil accumulating within the curbed, concrete pad, self-contained building,or floors of the CWSA, the CWAAS, or warehouse.

b. Oil overflowing the curb or containment part of the building andaccumulating on the gravel, stone, asphalt, grass, or other ground surfacessurrounding the CWSA or CWAAS.

2. Specific Action

a. Use any equipment available, such as absorbents, oil booms, and sandbags, to minimize the leak and contain the spill.

b. Contact the Supervisor - Nuclear Chemistry Services if any leaking orspilled diesel fuel/oil drums are found at the CWSA or CWAAS.




3. Discussion

a. The station is equipped with retention areas and oil interceptors to containany oil spills. The oil interceptors may be utilized in the event of a large oilspill or leak from 55-gallon drums at the CWAAS.

b. Any oil leak or spill from 55-gallon drums at the CWSA is contained in thecurbed concrete pad. Oil should be removed, thus preventing eventualaccumulation to a volume that could enter the nearby drainage ditch whichdrains to the Training Center Pond.

c. Any oil leak or spill in the warehouse storage from 55 gallon drums wouldbe contained within the building. Oil should be removed preventingaccumulation or storage hazard using absorbents and/or booms.

6.3.23 Equipment Containing Dielectric Fluid

1. Substations containing transformers are located through the plant. Alltransformers on site have been either retrofilled or replaced with non-PCBunits. However, some large pumps, such as the Condensate Water Pumps,have been found to contain PCB capacitors. The exception are the fourCirculating Water Pumps; which have been replaced with non-PCB capacitors,and the four Reactor Coolant Pumps; which are Non-PCB - dry pumps.Currently, it is unknown if the other pumps of this size or larger contain PCBcapacitors. Therefore, it is prudent to assume the capacitors are PCB in a spillsituation until determined otherwise. This equipment includes the following:

a. Condensate Pumps 1-2 and 1-3 motor capacitors (pump 1-1 has beenreplaced with non-PCB capacitors)

b. Service Water Pump motor capacitors

c. Component Cooling Pump motor capacitors

2. Other equipment which may contain PCB oil includes Cyberex invertercapacitors, and overhead lighting capacitors. Is it therefore prudent to alsoassume the oil from these and/or unknown sources are PCB in a spill situationuntil determined otherwise. Reference Environmental Compliance Guideline-ECG-07 for currently known PCB containing equipment and mitigationinstructions.




6.3.24 Seal Oil Tank T100 Leak/Rupture

(410 Gallons, Plant System 90-01, Room 333)

1. Symptoms

Oil accumulation in the Seal Oil Tank Room (Room 333/Turbine Building Level585').

2. Specific Actions

a. Dike or cover floor drain in seal oil room.

b. Pump out the remaining seal oil to an appropriate storage container.

c. Contain the oil using booms or other absorbent material.

3. Discussion

The Hydrogen (H2) seal oil tank (TI00), has a capacity of 410 gallons. Theroom is designed so that in the event of a leak the retaining curb will containsmall amounts of accumulated oil. The two floor drains are connected to theEast Condenser Pit Sump The system is visually inspected by periodic plantwalkdowns, and is tested under the Plant Maintenance Program, PM 429,performed during odd numbered Refueling Outages. Level alarms installed areannunciators 16-4-H and LSHL 2454 (ref OS-025).



7.0 RECORDS

7.1 The following quality assurance records are completed by this business practiceand shall be listed on the Nuclear Records List, captured, and submitted to NuclearRecords Management in accordance with NG-NA-00106.

7.1.1 None

7.2 The following non-quality assurance records are completed by this businesspractice and may be captured and submitted to Nuclear Records Management, inaccordance with NG-NA-00106.

7.2.1 None

8.0 REFERENCES

8.1 Developmental

8.1.1 29 CFR 1910.1200, Hazard Communication

8.1.2 40 CFR 112, Oil Pollution Program

8.1.3 40 CFR 280, Subpart F, Release Response and Corrective Action for UST SystemsContaining Petroleum or Hazardous Substances

8.1.4 40 CFR Subchapter J (Parts 300-373), Superfund, Emergency Planning andCommunity Right to Know

8.1.5 49 CFR Subchapter C (Parts 171-178), Hazardous Materials Regulations

8.1.6 Ohio Revised Code, Chapter 1301:7-9, Underground Storage Tanks


8.2 Implementation

8.2.1 40 CFR 112, Oil Pollution Program

8.2.2 Ohio Administrative Code, Ohio Environmental Protection Agency (OEPA)Regulations Chapter 3750-25, Emergency Release Notification

8.2.3 DBNPS National Pollutant Discharge Elimination System (NPDES) Permit

8.2.4 DB-CN-00030, National Pollutant Discharge Elimination System (NPDES)Program

8.2.5 DB-OP-06272, Station Drainage and Discharge System




8.2.6 NG-RA-00807, Regulatory Reports

8.2.7 NG-NS-00808, Regulatory Agency Communications

8.2.8 NG-NA-00106, Nuclear Records Management

8.2.9 RA-EP-02850, Hazardous Chemical and Oil Spills

8.2.10 DBNPS Emergency Plan

8.2.11 DBNPS Emergency Plan Telephone Directory

8.2.12 DBBP-CHEM-2003, RCRA Contingency Plan/Spill Notification Requirements

8.2.13 Environmental Compliance Guideline ECG-04, CERCLA/SARA HazardousChemical Locations and Spill Event Guideline.

8.2.14 Environmental Compliance Guideline ECG-07, PCB Activities and Response Plan.



ATTACHMENT 1: DISCHARGE NOTIFICATION TABLEPage 1 of 1

DISCHARGE TYPE: PCB Oil Discharge (>50 ppm) Non-PCB Oil Dischargeamount >25 gallons UST Release Oil Mixed with

in "harmful off co. prop >25 gal. Haz. Subs.,any amount into >1 lb. PCB quantities Discharge

NOTIFICATIONS: Phone Number: a waterway on land into waterway > RQ

Government Agencies: w/i 30 mins. w/i 30 mins* w/i 30 mins. w/i 30 mins. no w/i 30 mins*1. Ohio EPA Emerg. Response 1-800-282-9378

2, Sheriff Dispatch 1-419-734-4404 w/i 30 mins. w/i 30 mins* w/i 30 mins. w/i 30 mins. contact w/i 30 mins*(Satisfies Ottawa County Carroll Town-LEPC and Carroll Town- ship Fireship Fire Department Dept. (419-notifications) 898-4906)

w/in 24 hrs.

3. National Response Center 1-800-424-8802 w/i 30 mins. w/i 30 mins* w/i 30 mins. w/i 30 mins. no w/i 30 mins*

4. U.S. Coast Guard 419-418-6050 + no + no no +

5. NWDO & OEPA (NPDES 1-800-282-9378 w/i 24 hr. if no w/i 24 hr. if no no w/i 24 hr. ifpermit violation) NPDES violation NPDES NPDES violation

violation

6. State Fire Marshall 1-800-686-2878 no no no no w/i 24 hrs. no

Company Contacts: 419-321-7283 + + + + + +7. Control Room8. Env. Department 330-384-5160

denotes make the notification only if not entirely contained within some type of structure, (i.e., building, tank, dike, etc.) which prevents the possibility of migration from the site or exposureto personnel outside of the site boundaries. UST = Underground Storage Tank.

The information that must be reported to all agencies is the time, source, and location of the release, material and volume released, the pathway of the release, health risks, precautions,name and phone number of person to contact for further information. PCB (or other hazardous constituent) concentration is obtained via analysis by a vendor laboratory. The pounds ofhazardous substance spilled are calculated as follows:

pounds spilled = (gallons spilled) x (concentration in ppm) x (d)1,000,000

(d) Reference the MSDS for the density factor of the material.

Examples:

1. d = 8.4 lbs/gal for water or low conc materials

2. d = 13.5 lbs/gal for Aroclor 1260 (i.e., worst case PCBs)

+ Courtesy call - not required.

0 0 0

0

A

mz--i!Y

0-

0- Im X

mU m~m m f

MC- mCl)

C.l)

r-

zoz

CDLn.30 C

CD

0

0

z

m

m

z0zm

70C'

0zCln 0 0C

Cio

H

CD

C)0czz-H

m

rnC

Cf)

0Z

-u

0

z0

zC)0

CD

0

mC13

m

U,)

m

-D

m

zC)

UD

CD

C)

0

ft

0

0-

~ m

> jZ MO

2, 0Z

Z3 - c

8 303~~ ~ Z

-_ 0 *

6- -. 1 o

ADN 0131 LM01508

AOC BMA IC ID FFORD -7POND(0

_37 Nt

(ED

CIO

1 01




ATTACHMENT 5: DBNPS OIL LOCATIONPage 1 of 1




ATTACHMENT 6: CERTIFICATE OF THE APPLICABILITY OF NON-SUBSTANTIALHARM CRITERIA

Page 1 of 1

CERTIFICATION OF SUBSTANTIAL HARM DETERMINATION FORM

FACILITY NAME: Davis-Besse Nuclear Power Station

FACILITY ADDRESS: 5501 North State Route 2

Oak Harbor, Ohio 43449

1. Does the facility have a maximum capacity greater than or equal to 42,000 gallons and do the

operations include over water transfers of oil to or from vessels?YES NO x

2. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000)gallons and is the facility without secondary containment for each aboveground storage area

sufficiently large to contain the capacity of the largest aboveground storage tank within the storagearea?

YES NO X

3. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000)gallons and is the facility located at a distance such that a discharge from the facility could causeinjury to an environmentally sensitive area?

YES NO X

4. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000)gallons and is the facility located at a distance such that a discharge from the facility would shut downa public drinking water intake?

YES NO X

5. Does the facility have a maximum storage capacity greater than or equal to one million (1,000,000)gallons and within the past 5 years, has the facility experienced a reportable spill in an amount greaterthan or equal to 10,000 gallons?

YES NO x

If an alternative formula is used, documentation of the reliability and analytical soundness of thealternative formula must be attached to this form.

CERTIFICATIONI certify under penalty of law that I have personally examined and am familiar with the information submittedin this document, and that based on my inquiry of those individuals responsible for obtaining this information,I believe that the submitted information is true, accurate, and complete.

Professional Engineer

Signature Title

Charles T. Daft . PEName Date




ATTACHMENT 7: RESPONSE EQUIPMENT / CONTRACTOR LIST

Page 1 of 2

WAREHOUSE SPILL EQUIPMENT (WAREHOUSE LOADING DOCK SPILL KIT)

* SHOVEL

" NYLON ROPE

" FIRST AID KIT

" SPILL RESPONSE SUIT

" RUBBER GLOVES

• BOOTS

" BAGS OIL DRY

" ABSORBENT BOOMS, PILLOWS, PADS

* DISPOSABLE BAGS FOR WASTE

0 WIRE TIES

STOREROOM / TOOL CRIB

* SORBENT MEDIA, BAGS OF ABSORBANT, PADS

" WINTER GLOVES

* ROPE

" PAPER TOWELS

SERVICE BUILDING 2

" SPILL KIT REPLENISHMENT MATERIALS

" SUITS

" WATER BOOMS

" LARGE CONTAINMENT POOLS



* SPILL PREVENTION CONTROL ANDCOUNTERMEASURE (SPCC) PLAN 01 45 of 57

ATTACHMENT 7: RESPONSE EQUIPMENT / CONTRACTOR LISTPage 2 of 2

OFF SITE SUPPLIES / RESPONSE

1. Cousins Waste Control (Emergency Response - Vac Trucks), (419) 726-1500, or,for transportation related spill response call (800) 567-7455

2. Clean Harbors (Emergency Response), (800) 645-8265

3. New Pig Corporation (Spill Response Equipment), (800) 468-4647

4. Columbus Steel Drum Company (Containers - Drums), (614) 864-1900

OTHER KITS - INSIDE PROTECTED AREA

Turbine Building

* 585' Main HAZWOPER General Spill Kit (located against the South Wall)

OUTSIDE PROTECTED AREA - Chemical and Oil Spill Kits

Warehouse

* 585' General Spill Kit, Z-Building #3 (General Spill)

INCIDENTAL CLEAN-UP MATERIAL - SMALL KITS FOR GLOVES AND ABSORBANT

PADS

Turbine Building

* 603' Oil Spill Kit outside Room 428

* 623' Oil Spill Kit (located in the feedwater heater bay area)

Auxiliary Building

* 585' Oil Spill Kit - EDG Room 321 (Enter through Turbine Building)

* 585' Oil Spill Kit (40,000 gal. Diesel Fuel Tanks) -located in SB2 vestibule




CERTIFICATION OF THE SITE SPECIFIC SPCC PLANATTACHMENT 8:Page 1 of 1

Certification of the Site Specific SPCC Plan

In accordance with 40 CFR 112.3(d) and 112.5(c), this plan has been certified as follows:

CERTIFICATION

SPILL PREVENTION CONTROL AND COUNTERMEASURE PLAN

I hereby attest that 1 (1) am familiar with the provisions of 40 CFR, Part 112 (2) have examined or agent has

examined the facility (3) am of the opinion that this SPCC Plan has been prepared in accordance with good

engineering practices, including consideration of applicable industry standards and with the requirements

of 40 CFR, Part 112 (4) am of the opinion that procedures for required inspections and testing have been

established and (5) am of the opinion that the Plan is adequate for the facility.

Charles T. Daft

Printed Name of Licensed Professional Engineer

(Seal)

Signature of Licensed Professional Engineer

Date: Registration No. State

DAVIS-BESSE BUSINESS PRACTICE Number:____________________________________ DBBP-.CHEM-2005Title: Revision: Page


ATTACHMENT 9: SPCC COMPLETION OF REVIEW OF SITE SPCC PLANPage 1 of 1

COMPLETION OF REVIEW

40 CFR 112.5(b)

In accordance with 40 CFR 112.5(b), this plan has been reviewed as follows:

I have completed review and evaluation of the Davis-Besse SPCC plan and

will / will not amend the Plan as a result.

K. N. Mominee

Printed Name of Reviewer

Signature of Reviewer

Date:




ATTACHMENT 10: SPCC REVISION RECORDPage 1 of 1

REVIEW & REVISION RECORD

SITE SPECIFIC SPCC PLAN

FACILITY NAME:Davis-Besse Nuclear Power Station

Review Date Revision Number Revised Reviewer's NamePages/Section

12/20/2005 0 Entire Procedure K.N. Mominee12/20/2005

3/15/2007 1 Pg 32 Sec 6.3.20.1.b. S. M. ChimoPg 32 Sec 6.3.20.3 3/15/2007

Pg 48 Att. 10

0 0DAVIS-BESSE BUSINESS PRACTICE Number:

____ ___ ____ ___ ___ ____ ___ ___ ____ ___ ___DBBP-CHEM-2005



ATTACHMENT 11 - SPCC OIL STORAGE LOCATIONS COMPLIANCE TABLEPage 1 of 9

I SPCC OIL STORAGE LOCATIONS I COMPLIANCE

OIL LOCATION MAP NUMBER1-2-3-4-

5-6-8-7-

10-

DIESEL FUEL OIL STORAGE TANKDIESEL FIRE PUMP DAY TANK

EMG DIESEL GENERATOR DAY TANKSEMG DIESEL GENERATOR WEEK TANKSBUNKERED STEEL USTsMISC DIESEL DAY TANKTG LUB OIL STORAGE TANKMAIN/AUX/SU TRANSFORMER/BUS TIESMFPT LO and USED LO STORAGE TANKSLO DRUM STORAGE ROOM (TURB BLDG)

11-12-

13-14-15-16-17-9-

18-

PSF FIBERGLASS WO TANKSTATION BLACKOUT DIESEL GENERATORDBAB EMG DIESEL GENERATOR DAY TANKDBAB EDG FOST FIBERGLASS TANKSB4 DIESEL TANK and SB4 GASOLINE TANKCWSA WASTE OIL STORAGETG SEAL OIL TANKTG EHC FLUID STORAGE TANKMISC OIL FILLED EQUIPIWAREHOUSE STRG

DBBP.CHEM-2005 Description 6.3.1 6.3.2 6.3.3 6.3.4 6.3.5 6.3.6 6.3.8- 6.3.7 6.3.15 6.3.16 6.3.17 6.3.19 6.3.20 6.3.21 6.3.22 6.3.24 6.3.14 6.3.23Step 6.3.13

System Number 26-01 26-03 26402 26-02 99-06 89-01 87-1,3 36-04 25-01 25-01 26-05 25-01 25-01 19-01 NA 90-01 93-01 20-03Tank Number (if Applicable) T45 T47 T46 T153 T168 T32 3-1-3 __T _ T210 T100 T79

Oil Location Map Number 1 2 3 4 5 6 8 7 10 11 12 13 14 15 16 17 9 18b, Facility Drainage -Requirements in accordance with 40 CFR 112.8 (b) I

Capacity of Container in Gallons 100K 350 6K 40K 740 14 K 24470 1200 55 gal 2000 1977 300 8000 1000 55 gal 410 800 RCP-

Each Each Each 107004 (1&2) Drum 2000 Drum 225(2) (2) (2) 600 2800 Tranf-

2000 * (LO) Varies(1) Is the Storage area

diked ? YES NO NO NO NO NO YES' NO NO NO YES NO NO YES NO NO NO NO

115K RC STP UST RC Sump only Part STP Demin Conlin Conlin 3450 RC STP STP SumpSump Plan Plan Curb

a. IF DIKED, are valvespresent to prevent No NA NA NA NA NA *No NA NA NA No NA NA YES NA NA NA NAdischarge into drainage Valve Valve Valvesystem No J

Drain

b. Manual Pumps orEjectors to Drain YES NA NA NA NA NA YES * NA NA NA YES NA NA NO NA NA NA NA

c. Visual Exam RequiredBefore Discharge or YES F NA NA NA NA NA YES F NA NA NA YES F NA NA YES NA NA NA NADisposal _ _ .

DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ____ ___ ____ ___ ____ ___ ____ ___DBBP-CHEM-2005




Oil Location Map Number 1 2 3 4 1 5 6 8 7 10 1 1 12 13 14 15 16 17 6 9 18(2) Drain Valves for Dikes

a. Manual Open and NA NA NA NA NA NA NA NA NA NA YES NA NA. YES NA NA NA NAClose Only ? " ___-__... . .__ __-._____ .._._..:__-_

b. Flapper Valves ? "NA'(Not Allowed) NO NA NA NA NA NA NO NA NA NA NO NA NA NO NA NA NA

c. To prevent harmfuldischarges, is drained NA NA NA NA NA NA NA NA :NA. NA NA- NA NA,: YES NA NA NA NAuncontaminated DikeStorm or Rainwater -Inspected. Supervisd,Adequately Recorded &Valves Closed _._" ___ •_:.. ____

(3)a. Are UNDIKED areas (with apotential for discharge-Piping off containment,walls or truck discharge YES YES- YES YES- NA NA- YES- YES- YES NA- YES- NO- NO- NA- NA NA NA' NAareas off pad.etc) designed Pad Vault STP Bitum Vault Vault Collcn Vault - STP De-min RC 01 Encls Fibergl Pipng RC RC Encls Enclsto flow into Ponds/CB/ CB31/ RC- 015 Coatd Full Full Tank 012 01/2 UST - 7 TCP Room UST - Encls ALL No ,SCP Roorir RoomLagoons/designed to retain or#4 STP TCP CB17 Cont- Cont- for all TCP I SSB Piping Bare in dike Drain SSB WCP, Tanksthe oil? TCP O1#3 TCP No No WCP Wrap Piping SS.: S STP

Piping TCP Piping Drains Drains SSB CB CB . TCPCathd (DO Cathd Pipg Piping Pond Pond

Cath) Cath Encls 19 19

b. Drainage System CBs in NO NO NO NO NA NA NO NO NO NA NO No No NO NO NO NO NOa Flood Plain ?

(4) Final Discharge of facilityditches has diversion YES YES YES YES NA NA YES YES YES NA YES YES- YES- NA F YES YES YESsystem to retain oil in the TCP TCP TCP TCP TCP TCP I TCP/ TCP Gated Gated SSB SSB TCPfacility I C II _Ionly SSB SSB I Pond Pond

(5) Is drainage systemengineered to prevent a YES YES YES YES- YES YES YES YES YES NO YES YES YES YES NA YES YES YES'harmful discharge' ? C E E

0

0DAVIS-BESSE BUSINESS PRACTICE Number:




Oil Location Map Number 1 1 2 1 3 I 4 I 5 1 6 I 8 I 7 1 10 I 11 I 12 1 13 I 14 I 15 I 16 I 17 I 9 1 18c. Bulk Storage Requirements in arcordance with 40 CFR 112.8 (c)

(1)Oil Storage Container Material

and Conditions Compatible YES YES

to Contents YES YES YES YES YES YES YES YES YES NA YES YES YES YES YES YES

(2) REQUIRED SecondaryContainmenta. Entire capacity and

freeboard impervious to NO NAcontain discharged oils YES- NO NO NO YES- YES- YES- NO NO NA NO NO NO YES YES NO

Dike Vault Vault Tanks I

b. Alternate System(Drainage Trench enclosure) YES - YES YES YES NA NA YES YES- YES NA YES- YES YES- NA . NA . YES-

arranged so discharges Piping RC and RC CB17 TCP STP STP RC CB CB . RC

terminate/are confined in a CB 31 01 #3 STP To only TCP/ TCP/ 017 POND POND STPcatch-basin or holding pond TCP TCP O1#5 TCP WCP WCP TCP 19 19 , ECP STP NA

TCP SSB SSB SSB WCPSSB

(3) Diked Drainage to Stormdrain: Valves NC. WaterQuality Pre-inspected, NA NA NA NA NA NA YES NA NA NA No NA NA YES NA A :NA NA

Drainage Supervised & ValveRecorded _ _ . ____'_,_ :___.___

(4) Buried Metallic Tank (Installpost1974)) NA NA' NA NA NA NA :NA NA NA NA NA. NA NA NA NA NA NA

a. Coatings/Cathodic ___.. . .._ . . ... . .. _ __,

b, Regular Pressure Testing

NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA

(5)Partially Buried or BunkeredTanks are Coated or NA NA NA YES NA NA NA NA NA NA NA NA NA NA NA NA NA NA

Cathodic Protected Coat&compatible with local soil Cathdconditions

(6) a. Containers RegularlyIntegrity Tested, and whenrepaired by Visual and oneother method, such asHydrostatic, Radiographic, G G G G G G G M NA M, G G NA M M PM NA NAUltrasonic Acoustical, or No PM NA No PM NA Flbergl Raised Flberg9 NA NA. 429 Equip Equcother NDE Elec Raised No Oil Rack/ UST Raised DOT Odd Equip Equip

Equip Racks/ Stored Full Racksl Regs RFO PM 474DOT View Full 6 yrsRegs a I I View I I I I

DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ___ ___ ___ ____ ___ ___ ___ ___ ___DBBP-CHEM-2005




Oil Location Map Number 1 [ 2 3 4 5 6 8 7 10 i11 12 [ 13 [ 14 15 16 [ 17 9 18b. Comparison Records AreREQUIRED tobe YES I YES I YES I YES I NA YES I YES No NA NA YES I YES I YES I YES I NA YES I YES I NAMaintained only .. _:__

c. Inspect ContainersSupports & Foundations G G G G G YES YES No NA NA G G NA M NA YES YES NA

Period on•..Period PeriodWalk Walk WalkDown _ _ __•____ Down Down

d, Frequently Inspectcontainereotenior for G G G G G YES YES No NA NA G G NA; M NA YES YES NAdeterioration, discharges or Period G Period Periodaccumulation inside dike Walk Pony Walk Walki

areas, Down • Down Down

e. Inspection RecordsMaintained for 3 years YES I YES I YES I YES I YES I YES I YES I No NA NA YES I YES I YES I YES I YES I YES I YES I INA

Ionly I_.__

(8) Good Engineering Practicesto avoid discharges by atleast one of the following(Engineered or update YES NAcontainers to satisfy) YES YES G YES G YES YES YES- NO No NA NA YES YES YES YES NA YES Annun

a. High Level Alarms w/ Period Comp *only Annun 15-6-Baudible, or visual signal if Walk Point 16-4-14 andconstantly monitored Down 9-6-D 15-3-B

b. High Liq Levi pump cut-offdevice to stop flow atpredetermined containerlevel

No No No NA No No NA NA NA NA No NA G NA NA NAc. Direct audible or codesignal between containerguager and pumping station

No No No YES No Annun NA NA NA NA No NA G NA NA NA NA NA

S

0DAVIS-BESSE BUSINESS PRACTICE Number:DBBP-CHEM_2005




Oil Location Map Number [ 1 ] 2 3 4 5 [ 6 8 7 I10 11 12 13 J 14 1 15 16 17 9 18d. Fast Response Systemto determine Liq Lvl of YES Yes G YES NA Annun NA No NA NA YES G YES YES INA Annun Yes NAeach contnr (computers, and 1 6-4-H

telepulse, direct vision Compgauge) Requires a person Point I LSHH-monitor gauges and filling LSH- 2343

1165 LS-_2323

e. Regularly Tested liquid G YES G G G PM- NA No NA NA G G G M NA , LSHL PM NAlevel sensing devices 1544 " 2454 8

LSH- . PM1250 3437

(9)Effluents Systems are CheckedFrequently to detect system YES YES YES YES NA NA YES YES YES NA YES NA NA NA YES YES YES YESupsets causing a harmful TCP TCP TCP TCP No No TCP* SSB SSB No TCP No No No TCP SSB SSB TCPdischarge (NPDES) STP STP Coll'n STP STP STP STP SSB

Dischr Dischr Tanks Discr Dischr Dischr Dischr

(10) Visible discharges whichresult in any loss of oil in YES B YES B YES B YES B YES B YES YES B YES NA NA YES B YES B YES YES B YES B YES B YES YEScontainers are Promptly B B B B BCorrected, including promptremoval of oil from dikes _: . _.

d. Transfer Operations Requirements in accordance with 40 CFR 112.8 (d_(1) Buried Piping:

a. All new or replaced pipingis Protectively Wrapped YES YES NA YES YES NA NA NA NA NA NA YES YES NA NA- NA NA NAor Coated and provideCathodic or othercorrosion Protection

b. Buried Piping isExamined forDeterioration if ExposedAND implement H H YES NA H H NA NA NA NA NA NA H H NA NA NA NA NAcorrective actions YES YES YES YES YESindicated by themagnitude of thecorrosion.





Oil Location Map Number J 1 2 3 4 5 6 8 7 I 10 11 I 12 1 13 14 15 16 17 9 18(2) Cap or blind flange Terminal

Connection YES NA NA YES NA NA NA NA NA NA YES NA YES YES NA NA NA " NA

b. Marked Origin whennot in service YES NA NA YES NA NA NA NA INA NA YES NA YES YES NA NA :NA NA

(3)Pipe Supports are designed tominimize abrasion and G G G G G NA NO No NA NA G NA NA NA NA NA NA NAcorrosion and allow forexpansion and contraction _____ : .. "__-_. "

(4) Regularly inspect and assessall above ground Valves,Piping & Appurtenances:

a. Flange Joints, Period PeriodExpansion Joints Supr SuprValve GlandsValve Bodies G G G G G Period NA No NA NA G G NA M NA Walk Walk NACatch Pans Supr Dowm Dowm

Pipeline Supports WalkLocking of Valves DowmMetal Surfaces

2. Regular Integrity and leaktesting of buried piping, at G G G G G NA NA NA NA NA- NA NA G NA NA NA %NA NAinstallation,

- Deminmodifications/construction, relocation, orreplacement if drainagecould lead to a HarmfulDischarge _______....

(5) Provide vehicle warnings forAboveground Piping YES D YES NA YES D YES D NA NA NA . NA NA YES YES 0 YES D YES NA NA NA NAProtection I

0DAVIS-BESSE BUSINESS PRACTICE Number:

DBBP-CHEM-2005Title:

SPILL PREVENTION CONTROL ANDCOUNTERMEASURE (SPCC) PLAN

Revision: Page

01 55 of 57


Oil Location Map Number I 1 I 2 I 3 I 4 I 5 I 6 I 8 I 7 I 10 I 11 I 12 I 13 I 14 I 15 I 16 I 17 I 9 1 18e. Additional Facility Tank Car and Tank Truck Loading and Unloadinl Rack (Requirements in accordance with 40 CFR 112.7 (h))(1) Where Loading / Unloading

Drainage does not does not K - NA NA Temp NA NA NA NA NA NA K- NA K- NA NA NA NA NAflow into catch-basin or Load Loadtreatment facility designed Pad Pad LPad LPad

unloaded Ref Ref Pad Ref Ref

112.7 112.7 • : ":112.7 ." 112.7" .i( •.(c) . • _ _ I:,•:•: c) (c) _ .. . * : :, :(2) Mechanisms (Interlocked u a shall a t sh

warning light or physical 0 N A 0 N A N A N A 0 N A -N A Nbarrier system, wheel to fA fully

chocks, or vehicle break f full

interfock system) in Place to i. : 1'=: .Prevent Departure prior toDisconnect of lines ._"_:_ " "_ _•

(3)Prior to filling or departurelowpermstoteles warheclsel D NA NA D NA NA NA NA NA NA D NA D D NA . NA NA NAinocspete for deischargesand

orterepksytm) laced topren

ensure tightened, adjusted,-

onstruplcted aboprve 9ont

dischargesr rpa dint transit.prv n :: ::.1"i':i-••i " ;/ ; i"I:'

f. New "Brittle Fracture" Failure Evaluation Requirements (Field Constructed Containers greater than W" thick) per 40 CFR 112.7 (j)

Evaluate Container ri•,k and G G G G G G NA " G N NA G GA NA NA .I GNA N

take appropriate action for G.....G N A A G GNA N NA A N

discharge/failure when field-constructed above ground .

containers are repaired,altered, reconstructed, orservice changed as toaffect the risk of a dischargedue to brittle fracture failureor catastrophe.


Title: Revision: Pag



Oil Location Map Number 1 I 2 I 3 I 4 I 5 1 6 I 8 7 1 10 1 11 1 12 1 13 1 14 I 15 I 16 17 I 9 1 18g. Additional Security Requirements per 40 CFR 112.7 (a)(1) Storage Area is Fully Fenced

wand Locked or Guarded YES YES YES YES YES YES YES YES YES YES YES YES NO D YES YES YES YES YESwhen Unattended

(2) Master Tanks Flow and DrainValves (which could allowflow to Surface) are Lockedand NC not operating. YES YES YES YES YES NA YES NA : NA NA YES YES NA YES NA NA NA NA.

(3) Starter Control for oil Pumpsare locked and I only YES YES YES YES YES YES NA NO- NA NA YES YES YES YES NA ,NA NA NAAccessible to Authorized FloodPersonnel Pump

174-1 "

(4) Loading/UnloadingConnectors of Pipelines are YES NA NA YES NA NA NA NA NA YES YES .NA YES YES NA .N NA NAeither Capped or Flangedwhen not in use or onstandby, including emptiedpipelines........ '____ _.._-

(5) Adequate Lighting isAvailable for:1. Discovery of Spills in the YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES

Dark I I I 1 12. Vandalism Deterrence

YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES YES

0 0

DAVIS-BESSE BUSINESS PRACTICE Number:____ ___ ___ ____ ___ ___ ___ ____ ___ ___ ___DBBP-CHEM-2005




LEGENDS A. Due to storage of oil drums only, and discharge controls through station process drains, this is N/A.

B. HAZWOPER Incident Commander and Technician level. Personnel receive training on applicable regulations and spill critiques in accordance with RA-EP-02850. HAZWOPER Awareness training for oil

spills is provided site-wide in Hazard Communications Training. The Corrective Action Process may also be used for spill reporting. Spills may also be identified by housekeeping practices, and routine plant

walk-downs.

C. Although a drain system is not employed, the clay soils around the tank or catch basin, and flow or requirements to discharge via pumps or storm line to onsite ponds, ensure any spilled material does not

enter navigable waters or natural resources as a harmful discharge. Regulatory Notifications may still be required however (example: UST overfill)

D. Procedure checklists or signs are employed to ensure applicable containment, outlets and disconnects are checked, DOT regulations are employed, and Security maintains vehicle control at all times.

E. The room contains the total contents.

F. Oil drainage is to drums and records are maintained as disposal records for oil disposal (i.e. drum receipt at the CWSA).

G. Engineering maintains testing documentation, or maintained in PM Program or Work Order documents. Each AST or container identified with this code shall be annotated with the description and frequency

of the integrity testing requirements, or applicable industry standard citation or environmental equivalency documentation by the next five year review interval from the original regulatory 5-year review

implementation date of August 18, 2006 (no later than August 18, 2011).

H. Back-fill procedure requires inspections if excavated.

I. Inspections are maintained with environmental files, Work Orders, or site records, Procedures and training records (i.e. cleanliness & housekeeping, HAZWOPER, PM inspections, excavations, operations

walk-downs, etc.) are maintained in accordance with terms of the DBNPS Operating License and commitments (i.e. USAR, NQAM, etc)

J. The Spare Main Transformer has an earthen dike to contain discharge. The equipment is not operating, but in stand-by.

K. Periodic Plan or System Review requires initiation of a Condition Report for tracking or implementing system evaluations and/or upgrades.

L. Review requires initiation of a Condition Report for tracking or implementing system evaluations and/or upgrades.

M. Environmentally Equivalent method: Elevated drums or shop built containers (shell capacity less than 30.000 gallons), with frequent visual inspection, container does not come in contact with soil and is

elevated so all sides are visible during inspection, or is placed on a barrier (such as a synthetic liner) between the container and the ground.

UNK- UNKNOWN

NA - NOT APPLICABLE

STP - STATION PROCESS DRAIN

WCP - WEST CONDENSER PIT

CB- CATCH BASIN

RC - RETAINING CURB

TCP - TRAINING CENTER POND

o0 - OIL INTERCEPTOR

DEMIN- DEMINIMUS / NO OIL STORED

SSB - SOUTH SETTLING BASIN

UST- UNDERGROUND STORAGE TANK

NOP-LP-2001-O1 Site: G201CONDTIO REPRT R NumberCONDIION RPORT04-01719

TITLE. IN 2004-05 SPENT FUEL POOL LEAKAGE TO ONSITE GROUNDWATER

DISCOVERY DATE I TIME I EVENT DATE TIME SYSTEM I ASSET#

31512004 N/A n/a N/A N/A N/A

EQUIPMENT DESCRIPTION N/ASystem IFLOC JAP-913:

DESCRIPTION OF CONDITION and PROBABLE CAUSE (if known) Summarize any attachments. Identify what, when,

O where, why, how.

R The U.S. Nuclear Regulatory Commission (NRC) is issuing this information notice to inform! addressees of the recent identification of a longstanding leak to onsite groundwater from the spent

G 'fuel pool of an operating pressurized water reactor facility. It is expected that recipients will review

the information for applicability to their facilities and consider actions, as appropriate, to avoid similar

N problems.A This Condition Report will evaluate IN 2004-05 for similar concerns at Davis-BesseT IMMEDIATE ACTIONS TAKEN I SUPV COMMENTS (Discuss CORRECTIVE ACTIONS completed, basis for closure.)

O Evaluate per NG-NA-00305 Attachment 4

NQUALITY ORGANIZATION USE ONLY IDENTIFIED BY (Check one) El Self-Revealed ATTACHMENTS

EV Individual/Work Group El Internal OversightQuality Org. Finding LI Yes EL Supervision/Management [] External Oversight EI Yes [] No

ORIGINATOR ORGANIZATION IDATE ISUPERVISOR DATE PHONE EXT.SADLIER, D P1 315/2004 HENNESSY, B 3/5/2004 8592

SRO EQUIPMENT EP EQUIP OPERABILITY ORG. IMMED ORG. MODE CHANGEp REVIEW OPERABLE ASSESSMENT NOTIFIED INVEST NOTIFIED RESTRAINT

REQUIRED REQUIREDL ETYes }No [EYes EllNo E]NW E-Yes E]No [-Yes I No N/A I EYes E] No N/A [E Yes NoA MODE ASSOCIATED TECH SPEC NUMBER(S) ASSOCIATED LCO ACTION STATEMENT(S)N pA ;INIT #

0 DECLARED INOPERABLE REPORTABLE? One Hour N/A APPLICABLE UNIT(S)

P (Date / Time) ,.-es Hour No -IAaN/A e EIght Hour N/A W-ui EL U2 [: Both

R El Eval Required Other -N/,AAT COMMENTS

I N/A0N Current Mode - Unit I Power Level - Unit I Current Mode - Unit 2 Power LevelN- Unit 2

S N/A N/A NA N/ASRO - UNIT I SRO - UNIT 2 DATE

Approved By Supv NIA 3/5/2004

Page 1 of 2

NOP-LP-2001-01 Site: G201

CONDITION REPORT CR Number1 04-01719

TITLE: IN 2004-05 SPENT FUEL POOL LEAKAGE TO ONSITE GROUNDWATER

CATEGORY! EVAL ASSIGNED ORGANIZATION DUE DATE R REPORTABLE?NF PES 514/2004 E El Yes E1 No El LER No.G

CRPA TREND CODES Comp Type i ID Cause u REPORTABILITY REVIEWERI Process I ActivityI Cause Code(s) (if Cause T or W) Org A Wolf, G

TSUPV LP2 3450 NA NONE o DATE

I RMRB Y 03/09/04

INVESTIGATION OPTIONS CLOSED BY DATEEl Mair•t.Rule [EOE Evaluation [] Genedc implications LI Part 21 11/13/2004

Page 2 of 2

RitAr• . 2f1

CORRECTIVE ACTION CR Number:

NOP-LP-2001-05 04-01719

CR Category: Action Type: Schedule Type: CA Number:

NF ( ) I (A) Owner Assigned/Controlled 1

Corrective Action Type: Cause Code: Resp Org:

( ES ) Evaluation Support (NA) Not a Deficiency DBRC

R Description:I Obtain approval of the completed (i.e., CARB approved) evaluation by the Senior Leadership Team.

GI

NAT0R

Completed By: Organization: Date: Phone: Attachments:

SADLIER, D PI 3/10/2004 7541 EV Yes [I No

If a Refueling Outage Is required, Other Tracking # Corrective Action Due Date:

ACC- Enter the Refueling Outage number: N/A N/A 3/31/2006EPT Approval: (Enter Name and Sign) Section: Date:

MCALLiSTER, A DBRC 4/23/2004

QUAL Quality Organization Approval: Date:-ITY

I Response: (i) Completed as written 0 Revised/Alternate Solution 0 Not Performed

M The Site Management Team (previously known as the Senior Leadership Team), approved theP completed evaluation with comments. In attendance were, B. Boles, S. Loehlein, M. Bezilla, R.L Schrauder, R. Hruby, M. Stevens, M. Murtha and C. Hengge. The comment did not requireE incorporation into the evaluation. As a result, no follow-up Condition Report is required (See StepM 6.5.6 of NG-NA-00305). See attached agenda.E Alternate Corrective Action or Justification if Corrective Action not performed:NTI

NG Corrective Action Implementation Date: 11/9/2004

j Signature indicates Corrective Action complete:

0 Completed By: JOHNSON, J Date: 11/9/2004

R j Signature indicates verification for SCAQ CRs:

G Verified By: Date:j Enter Name and Sign:

Implementing Organization Approval: HENNESSY, B Date: 1119/2004

Q v Comments:U EA RL II FT IY E

RApproval: Date:

Page 1 of 3

-qifo- ngni


NOP-LP-2001-05 04-01719

CR Category: Action Type: Schedule Type: CA Number:

NF ( ) I (A) Owner Assigned/Controlled 2


( ES ) Evaluation Support (NA) Note Deficiency PI

R Description:I After review by the Corrective Action Review Board (CARB), notify the Regulatory Commitment

G Tracking System (RCTS) Administrator that the CR is completed

NAT0R


SADLIER, 0 P1 3110/2004 7541 W] Yes El No

If a Refueling Outage Is required, Other Tracking # Corrective Action Due Date:

ACC- Enter the Refueling Outage number; N/A N/A 7/16/2004EPT Approval: (Enter Name and Sign) Section: Date:

HENNESSY, B P1 4/1912004

QUAL Quality Organization Approval: Date:-ITY

I Response: (ýD Completed as written 0 Revised/Alternate Solution 0 Not PerformedM The Corrective Action Review Board reviewed and approved the evaluation to this CR on June 8,P 2004. Following that date, R. Slyker, the Regulatory Commitment Tracking System Administrator,L was notified via email that the CR is complete.EME Alternate Corrective Action or Justification if Corrective Action not performed:NT

N Corrective Action Implementation Date; 6/2112004

Gj Signature indicates Corrective Action complete:

o Completed By: JOHNSON, J Date: 6/21/2004

R j Signature indicates verification for SCAQ CRs:

G Verified By: Date:

j- Enter Name and Sign:Implementing Organization Approval: HENNESSY, B Date: 6/21/2004

Q v Comments:U EA RL II FT IY E

RApproval: Date:

Page 2 of 3

Sitea G201


NOP-LP-2001-05 04-01719

CR Category: Action Type: Schedule Type: CA Number:NF ( ) (A) Owner Assigned/Controlled 3


( ES ) Evaluation Support (NA) Not a Deficiency DBPE

R Description:I Create an activity (PM) to implement the Site Management Team suggestion to periodically sample

G the groundwater from the well nearest the Spent Fuel Pool for tritium concentration.I

NAT0R


HENGGE, C DBPE 11/11/2004 7898 El Yes R No

If a Refueling Outage is required, Other Tracking # Corrective Action Due Date:ACC- Enter the Refueling Outage number: N/A N/A 6/30/2005EPT Approval: (Enter Name and Sign) Section: Date:

HENGGE, C DBPE 11/11/2004

QUAL Quality Organization Approval: Date:.ITY

I Response: (•) Completed as written 0 Revised/Alternate Solution 0 Not PerformedM DB-REV-05-0778 has been created to add a PM activity to periodically sample the groundwaterP from the well nearest the Spent Fuel Pool for tritium concentration.LEME Alternate Corrective Action or Justification if Corrective Action not performed:

NTI

N Corrective Action Implementation Date: 6/1612005G

.--J Signature indicates Corrective Action complete:

0 Completed By: HENGGE, C Date: 6116/2005

R 1 Signature Indicates verification for SCAQ CRs:

G Verified By: Date:j Enter Name and Sign:

Implementing Organization Approval: MARLEY, J Date: 6/16/2005

Q V Comments:U EARL II F

T IY E

RApproval: Date:

Page 3 of 3

Site: G201

INVESTIGATION SUMMARY CR Number:04-01719

NOP-LP-2001-06

Category / Eval: NF Assigned Organization: PES Quality Finding: El Yes OV No

For Fix irvestigations Only: --

JHardware/IDegraded Condition Resolution Required? Ys No If Yes: ld*Repir UýiScrapS. IdRework U Use-As-Is

.J Acceptance of the CR Investigation signifies acceptance of the following items, as applicable:

Originator Identification Date

Corrective Actions ( listed below) (listed below, if any) (listed below, if any)

Cause Analysis

Generic Implications

10 CFR 21 Decision Checklist

Acceptance of Investigation: Date: Quality Approval: Date:MCALLISTER, A 4/23/2004

Site-VP Acceptance: Date:

Closure Comments:

Problem Statement:The U.S. Nuclear Regulatory Commission (NRC) is issuing Information Notice (IN) 2004-05 to Informaddressees of the recent identification of a longstanding leak to onsite groundwater from the spent fuelpool of an operating pressurized water reactor facility.Undetected leakage of radionuclides outside the facility could have potential health and safetyconsequences to workers and ultimately the public.

Scope:The 5' thick south wall of the Spent Fuel Pool and Cask Pit which forms a portion of the outside wall of theAuxiliary Building.

Evaluation:This IN describes the same incident that was described in INPO Operating Experience (OE) 15788. ThisOE resulted in CR 03-2360 being generated to evaluate the OE for Davis-Besse.OE 15788 described the condition at Salem where the leakage detected by their Spent Fuel Pool (SFP)leak detection system gradually diminished to zero over time. Salem uses a system of tell-tale drainssimilar to that used at Davis-Besse. After workers got contaminated on their shoes, investigation found a"calcium like substance" adhering to the wall of the room adjoining the Spent Fuel Pool. It was discoveredthat the leak detection system had plugged with boron over time and caused the water to accumulate untilit migrated to other locations.Procedure DB-SP-04400, Spent Fuel Pool, Fuel Transfer Pit, and Cask Pit Leak Detection System Test, isperformed monthly to quantify a leak rate from the 21 leak chases for those three pools/pit.Review of the results of the leak detection testing is performed by the SFP system engineer. Leakageoutside the leak chase drains has been seen in several places over the years (ref. CR 02-01364, 01-02309 and 01-00253). The most extensive visible evidence of leakage was on the wall and ceiling of #1ECCS Pump Room, Rm. 105 during the period 2000-2001 (note: this leakage has since been stoppedand the area cleaned). The ceiling in this room is at 563' elev. which is the approximate level of thebottom of the pool (563.5'). Based on the evaluations associated with this past leak and the work done aspart of the Containment Health there are no concerns regarding the strength or integrity of the concretestructure associated with these leaks.During the reracking of the SFP during Cycle 13, underwater divers used a vacuum box of the weldseams in the SFP to determine if there was any detectable leaks. None could be located.At the time that there was the very visible leakage in the #1 ECCS Pump Room, little leakage was being

Page 1 of 3

Site: G201

INVESTIGATION SUMMARY CR Number:

NOP-LP-2001-06 04-01719

seen in the leak chases. WO 00-5281 -00 was used to open/ verify open the 21 leak chase valves andpiping in Feb 2001. Six of the chases were found to be totally blocked. A significant amount of trappedfluid was found in several of the blocked leak chases. As part of this the normal position of the leakchase valves was changed from OPEN to CLOSED. This should reduce the likelihood of the boric acid tosolidify and block the valves and piping. To be certain this has not occurred again, an order to open/verifyopen the valves and piping has been initiated as CA 1 for CR 03-02360.While the zones with significant fluid were not the zones that cover the walls adjacent to the exterior (i.e.southern ends of the SFP or Cask Pit (CP)), several of these zones were shown to be blocked and thesezones do show leakage during the monthly test. Based on this it is prudent to verify the soil does notshow contamination which would be indicative of past and/or present leakage. This is being done by CA 2to CR 03-02360.The 5' thick south wall of the SFP and CP form the outside wall of the Auxiliary Building. Much of theflooded portion of the SFP and CP are below grade and not visible. There Is a waterproof membrane onthis outside wall (ref. DWG C-230 Section C) to keep outside groundwater from leaching into the AuxiliaryBuilding. This membrane would also likely act to keep any potential fuel pool leakage from escaping intothe soil.Thus while It Is unlikely that there would be leakage into the soil, without a some type of excavation or soilborings to gain access to the soil in this area it can not be conclusively determined that there has or hasnot been leakage.Should leakage be detected a further CR will be generated in accordance with, and required by, procedureNG-DB-00244, Radioactive Material Control Program, section 6.2.10. This section deals withcontamination in and around the facility to ensure that the requirements of 1 OCFR50.75(g) are met.Contacts:None

Source Information:IN 2004-05CR 03-02360DB-SP-04400, Spent Fuel Pool, Fuel Transfer Pit, and Cask Pit Leak Detection System TestVarious site drawings including: C-230 and C-211

Most Probable Cause:This is an information notice and thus there is no most probable cause.

Preventative/Corrective Action:No specific corrective actions are required by this CR as the corrective actions specified in CR 03-02360adequately address the Issue.A copy of those are provided below.1. Implement Order 200057114 to verify the SFP, Cask Pit and Fuel Transfer Pit leak collection isolationvalves, SF99A through SF99U (located on the 545' elev. of Aux Bid) are not clogged with boric acid. Ifnecessary clean and/or replace the valves.

2. PES to develop a plan and supporting actions (CAs, Orders, POs, etc.) necessary to obtain theappropriate number, size, location of soil samples to confirm there is or is not any evidence ofcontamination in the soil due to leakage of the SFP or CP. Should leakage be detected a further CR willbe generated in accordance with procedure NG-DB-00244, Radioactive Material Control Program, section6.2.10. This section deals with contamination in and around the facility to ensure that the requirements of1OCFR50.75(g) are met.

Quality Comments:

CORRECTIVE ACTIONS

Page 2 of 3

Site: G201

INVESTIGATION SUMMARY CR Number:

04-01719NOP-LP-2001-06

RespCA Sched CA Cause Org. Accept Due Completed

Number: Type: Type: Code: Codes: CA Acceptance: Date: Date: Date:

I A ES NA DBRC MCALLISTER, A 4/23104 3/31/2006 11/9/2004

2 A ES NA PJ HENNESSY, B 4119104 7/1612004 6/21/2004

3 A ES NA DBPE I HENGGE, C 11/11/04 6/30/2005 6/16/2005

Page 3 of 3

UNITED STATESNUCLEAR REGULATORY COMMISSION

OFFICE OF NUCLEAR REACTOR REGULATIONWASHINGTON, DC 20555-0001

March 3, 2004

NRC INFORMATION NOTICE 2004-05: SPENT FUEL POOL LEAKAGE TO ONSITEGROUNDWATER

Addressees:

All holders of operating licensees for nuclear power reactors (except those who havepermanently ceased operations and have certified that fuel has been permanently removedfrom the reactor vessel) and for research and test reactors, and all holders of fuel storagelicenses and construction permits.

Purpose:

The U.S. Nuclear Regulatory Commission (NRC) is issuing this information notice to informaddressees of the recent identification of a longstanding leak to onsite groundwater from thespent fuel pool of an operating pressurized water reactor facility. It is expected that recipientswill review the information for applicability to their facilities and consider actions, as appropriate,to avoid similar problems. However, suggestions contained in this information notice are notNRC requirements; therefore, no specific action or written response is required.

Description of Circumstances:

On September 18, 2002, the licensee for the Salem Nuclear Generating Station identifiedevidence of radioactive water leakage through an interior wall located at the 24-meter (78-foot)elevation of the Unit 1 auxiliary building mechanical penetration room, a radiologically controlledarea. The leak location, about 3 meters (10 feet) up a wall surface, was identified while thelicensee was following up low-level shoe contamination of personnel who had traversed theroom. The licensee established a comprehensive task action plan to identify and stop thesource of the leakage and evaluate possibly undetected leakage outside building structures.The licensee did identify other locations where radioactive water was leaking through interiorwalls or penetrations into both the Unit 1 auxiliary building and the Unit I fuel handling building(FHB).

On February 6, 2003, the licensee identified the radionuclide tritium (H-3) in groundwater in twotest locations near the Unit 1 FHB. The test locations were within the licensee-controlledrestricted area. The licensee identified other locations of groundwater contamination in thegeneral vicinity of the Unit I FHB and within the restricted area. No other reactor-producedradionuclides were detected in the groundwater sampling test locations.

ML040580454

04-01719

IN 2004-05Page 2 of 4

The licensee obtained technical support and concluded (based on leak testing of suspectsystems, chemical analysis of water samples, system and building configuration reviews, and ageohydrological evaluation) that the likely source of the tritium was the Unit 1 spent fuel pool(SFP). The licensee believes that the leakage was the result of the obstruction of the leakagedetection and collection system of the SFP stainless steel liner.

Discussion:

The Salem Unit 1 FHB is a seismically qualified structure that contains the Unit 1 SFP. Unit 1SFP support systems in the Unit 1 auxiliary building pass through adjacent building walls to theUnit I FHB. The walls are separated by a Styrofoam® -filled 15-cm (6-inch) seismic gap andthe support systems traverse the seismic gap.

The Unit 1 SFP is a concrete structure with a stainless steel liner. The SFP includes an integralliner leakage detection and collection system, consisting of an extensive network of collectionlines running both horizontally and vertically within the narrow gap between the SFP liner andthe concrete SFP structure. The collected liner leakage is discharged to a collection troughthrough 17 drain lines (tell-tale drains). The tell-tale drains provide a means to detect, monitor,and quantify potential leakage from the SFP liner. The collected leakage is subsequentlydirected to the liquid radioactive waste system for processing.

The licensee's reviews discovered that over the years since initial facility startup, materials suchas boric acid residue and minerals accumulated within the leak collection and detection systemand restricted the normal drainage of liquid. The reviews also found that a modification to thetell-tale drains in 1998 resulted in the inadvertent introduction of sealant into the tell-tale drains,further restricting the free drainage of leakage from the liner. As a result, through-liner leakageaccumulated between the SFP liner and the concrete structure of the SFP. The accumulatedwater, containing tritium, subsequently migrated to other locations through penetrations,concrete construction joints, and cracks. The seismic gap was confirmed to contain water withradionuclides characteristic of Unit 1 SFP water. The water is believed by the licensee to havemade its way to the groundwater in the restricted area via the seismic gap.

The licensee cleaned the tell-tale drains, improving the drainage of the accumulated waterbetween the liner and spent fuel pool concrete structure and stopping the through-wall andpenetration leakage. After the cleaning effort, the leak rate from the tell-tale drains increasedfrom about 19 liters per day (5 gallons per day) to about 380 liters per day (100 gpd). Theleakage was properly collected.

The NRC conducted a special inspection of this issue (NRC Inspection Report 50-272/2003-006; 50-311/2003-006, ADAMS Accession No. ML032890212). The NRC's and the licensee'sreviews identified the following information about this situation.

0

IN 2004-05Page 3 of 4

1. The licensee took actions to identify specific leak locations, repair and mitigate the leak,and assess potential health and safety impacts. A comprehensive groundwatersampling and analysis program was implemented. Although the licensee believes, witha high degree of confidence, that the leak originated from the SFP, the licensee iscontinuing evaluations to confirm this conclusion. The leakage itself was notaccompanied by large fluctuations in SFP water levels and was likely masked byapproximately equal volumes of evaporation from the SFP.

2. The licensee stopped the identified through-wall leakage by cleaning the tell-tales andresumed controlled collection of SFP liner leakage via the installed leakage detectionand collection system. Extent-of-condition reviews revealed no apparent accumulationof water between the SFP liner and concrete structure at Salem Unit 2.

3. The licensee's evaluations did not identify any immediate health and safetyconsequences to onsite workers or members of the public. No radionuclides associatedwith the leakage were detected outside the onsite areas administered as access-controlled areas for purposes of radiation protection. The licensee did not detect anytritium associated with this leak in areas accessible to the public (i.e., the unrestrictedarea). The licensee subsequently developed and implemented an onsite groundwaterremedial investigation work plan in conjunction with State of New Jerseyrepresentatives.

4. The Unit 1 SFP had exhibited detectable leakage from the tell-tales since initial plantoperations. To monitor leakage from the tell-tales, the licensee established asurveillance program. Over the years, the leakage from the tell-tales diminished but thelicensee was not able to tell from leakage changes if they needed further evaluation.There was also a missed opportunity to evaluate earlier through-wall contaminatedleakage for possible accumulation of water between the Unit I FSP liner and concretestructure.

5. There was no periodic maintenance of the SFP leakage detection and collection systemto ensure that drainage channels remained free and clear so that the system couldperform its design function of preventing water from accumulating behind the FHB walls.The licensee initiated actions to develop a cleaning and maintenance process.

6. The licensee conducted evaluations of potential short-term adverse impacts to the SFPstructure. The preliminary evaluations did not identify any adverse effects that wouldimpact the design bases of the SFP or FHB structure. Nonetheless, the licenseeinitiated laboratory testing of the effects of boric acid on concrete. The results of thesetests are being evaluated by the licensee for potential long-term effects.

The licensee developed numerous corrective action documents to track the review, evaluation,and correction of identified deficiencies.

IN 2004-05Page 4 of 4

This information notice requires no specific action or written response. If there are anyquestions about this notice, contact one of the persons listed below or the appropriate Office ofNuclear Reactor Regulation (NRR) project manager.

IRA!William D. Beckner, ChiefReactor Operations BranchDivision of Inspection Program ManagementOffice of Nuclear Reactor Regulation

Technical Contacts: Ronald Nimitz, Region I(610) 337-5267E-mail: rlnc)nrc.gov

Suresh Chaudhary, Region I(610) 337-5335E-mail: skc0)Žnrc.qov

Stephen Klementowicz, NRR(301) 415-1084E-mail: sxk(@nrc.cqov

Jason Jang, Region I610-337-5220E-mail ici(,nrc.qov

Attachment: List of Recently Issued NRC Information Notices

a

AttachmentIN 2004-05Page 1 of 1

LIST OF RECENTLY ISSUEDNRC INFORMATION NOTICES

Information Date of

Notice No. Subject Issuance Issued to

2004-04 Fuel Damage During Cleaning 02/24/2004 All holders of operating licenses fc)rat a Foreign Pressurized WaterReactor

2004-03

2004-02

2004-01

Note:

Radiation Exposures toMembers of the Public inExcess of Regulatory LimitsCaused by Failures to PerformAppropriate Radiation SurveysDuring Well-logging Operations

Strontium-90 Eye ApplicatorsNew Calibration Values and Use

Auxiliary Feedwater PumpRecirculation Line OrificeFouling - Potential CommonCause Failure

02/24/2004

02/0512004

01/21/2004

light-water reactors, except thosewho have permanently ceasedoperations and have certified thatfuel has been permanentlyremoved from the reactor.

All well-logging licensees.

All U.S. Nuclear RegulatoryCommission (NRC) medical-uselicensees and NRC mastermaterials license medical-usePermittees.

All holders of operating licenses orconstruction permits for nuclearpower reactors, exceptthose that have permanentlyceased operations and havecertified that fuel has beenpermanently removed from thereactor.

NRC generic communications may be received in electronic format shortly after they areissued by subscribing to the NRC listserver as follows:

To subscribe send an e-mail to <Iistprocp~nrc.,ov >, no subject, and the following commandin the message portion:

subscribe gc-nrr firstname lastname

O OL = Operating LicenseCP = Construction Permit

STORM WATER POLLUTION PREVENTION PLAN

Approved: Approved: Date: __________Date: -1-h Ak

Effective Date MAR 1 0 2011

TABLE OF CONTENTS

1.0

2.0

3.0

4.0

5.0

5.2

5.3

5.4

5.5

6.0

7.0

8.0

PURPOSE

SCOPE

DEFINITIONS

RESPONSIBILITI ES

DETAILS

Storm water Management Controls

Site Storm Water Inspections

Employee Training

Storm Water Spill Response

REFERENCES

RECORDS

SCOPE OF REVISION

Page

4

4

4

5

6

7

8

8

9

9

10

11

ATTACHMENT 1:

ATTACHMENT 2:

ATTACHMENT 3:

ATTACHMENT 4:

ATTACHMENT 5:

ATTACHMENT 6:

ATTACHMENT 7:

ATTACHMENT 8:

ATTACHMENT 9:

POLLUTION PREVENTION TEAM

SITE MAP

MATERIAL INVENTORY

DESCRIPTION OF EXPOSED SIGNIFICANTMATERIAL

LIST OF SIGNIFICANT SPILLS AND LEAKS

NON-STORM WATER DISCHARGEASSESSMENT AND CERTIFICATION

EXISTING MONITORING DATA

SUMMARY OF POLLUTANT SOURCES

BEST MANAGEMENT PRACTICES

12

13

14

17

18

19

20

22

24


DBBP-CHEM-2009Revision: 0 Page

00 3 of28 ITitle

Storm Water Pollution Prevention Plan

TABLE OF CONTENTS (Continued)

ATTACHMENT 10: ANNUAL SITE INSPECTION CHECKLIST

ATTACHMENT 11: STORM WATER DISCHARGE FLOW CHART

Page

27

28

1.0 PURPOSE

1.1 The purpose of this plan is to consolidate all storm water pollution preventionrequirements into one location. This will meet the Ohio EnvironmentalProtection Agency (EPA) requirements for a Storm Water Pollution PreventionPlan (SWP3), assure compliance with the site's storm water discharge permit,provide a quick reference in the event of an emergency situation, and ensurethat all personnel involved in storm water activities are knowledgeable of theserequirements as specified by the Ohio EPA.

1.2 The specific objectives of the plan are to 1) identify potential sources ofpollution which may reasonably be expected to affect the quality of storm waterdischarged from the facility and evaluate their significance and 2) describe andensure the implementation of practices which are to be used to reducepollutants in storm water discharges at the facility.

2.0 SCOPE

2.1 Applicability

1. This guideline applies to all personnel who may be responsible forimplementing the SWP3.

2. Adherence to this Business Practice is mandatory.

3.0 DEFINITIONS

3.1 DISCHARGE - Includes, but is not limited to, any spilling, leaking, pumping,pouring, emitting, emptying, or dumping, but excludes:

* Discharges in compliance with a NPDES permit.

Discharges resulting from circumstances identified and reviewed andmade part of the public record with respect to a NPDES permit issued ormodified and subject to the condition in such permit.

Continuous or anticipated intermittent discharges from a point source,identified in a NPDES permit, which are caused by events occurringwithin the scope of relevant operating or treatment systems.

3.2 NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM (NPDES) -Afederal program administered by the Ohio Environmental Protection Agencythat provides for the permitted discharge of pollutants to state or federalwaterways.

3.3 OUTFALL - The location where an effluent is discharged into the receivingwaters by a discernible point source.

3.4 REPORTABLE QUANTITY (RQ) - A minimum quantity that may be harmful tothe environment and/or human health and requires notification to a regulatoryagency when spilled/discharged.

3.5 SIGNIFICANT MATERIALS - Substances associated with industrial activitieswhich have the potential to be released with storm water discharges. Thesematerials include: raw materials; fuels; materials such as solvents, detergents,and plastic pellets; finished materials such as metallic products, raw materialsused in food processing or production; hazardous substances designated underSection 101 (14) of the Comprehensive Environmental Response,Compensation, and Liability Act (CERCLA); any material the facility is requiredto report pursuant to Section 313 of Title III of the Superfund Amendments andReauthorization Act (SARA); fertilizers; pesticides; and waste products such asashes, slag, and sludge that have a potential to be released with storm waterdischarges.

3.6 STORM WATER - Storm water runoff, snow melt runoff, and surface runoff anddrainage.

3.7 STORM WATER DISCHARGE ASSOCIATED WITH INDUSTRIAL ACTIVITY -The discharge from any conveyance which is used for collecting and conveyingstorm water and which is directly related to manufacturing, processing or rawmaterials storage areas at an industrial plant.


4.1 The Manager-Site Chemistry shall:

4.1.1 Provide overall administration of this guideline.

4.1.2 Make required onsite and offsite notifications.

4.1.3 Provide technical assistance during storm water mitigation activities.

4.1.4 Ensure submittal of any required regulatory reports.

4.1.5 Ensure compliance with storm water permit requirements.

4.1.6 Ensure SWP3 contents are up-to-date by conducting monthly andannual inspections and making changes as needed.

4.2 The Storm Water Pollution Prevention Team (Attachment 1) shall:

4.2.1 Prepare required regulatory reports.

4.2.2 Coordinate employee training programs.

4.2.3 Conduct storm water pollution prevention inspections.

4.2.4 Update SWP3 as storm water pollution sources. Locations. Or bestmanagement practices change.

4.2.5 Continually evaluate best management practices and pollutionprevention strategies to better prevent the discharge of pollutantsthrough storm water outfalls.

4.3 Other actions for the discharge of pollutants through storm water outfalls asrequired by RA-EP-02850 may occur concurrently with SWP3 implementation.These actions may include:

4.3.1 The Shift Manager or designee may make required onsite notificationsand determine if a spill or discharge has occurred which requiresimplementation of HAZWOPER.

4.3.2 The Manager-Site Chemistry may prescribe personnel protectiveequipment and practices during an emergency response.

4.3.3 The Manager-Maintenance may isolate discharge pathways and provideclean-up of spilled materials.

4.4 All DBNPS personnel shall immediately report pollutant spills and discharges tothe Shift Manager.

5.0 DETAILS

5.1 Description of potential storm water pollution sources and pollution preventionpractices.

5.1.1 A site map is included in Attachment 2, depicting storm water outfallsand materials which are or may be exposed to storm water.

5.1.2 An inventory of all materials on site which are or may be exposed tostorm water is included in Attachment 3. This material inventory isbroken down to the following outfalls:

a. Outfall 1-NPDES Outfall 002, which includes all of the ProtectedArea and most outlying Areas.

b. Outfall 2-Wastewater Treatment Facility, which includes outdoorstorage near the wastewater Treatment Facility.

c. Outfall 3-Parking and Service Building 4, which includes thegasoline/diesel fuel dispensing area and materials stored outsidenorth of Service Building 4.

5.1.3 A description of significant materials exposed to storm water is includedas Attachment 4.

0

DAVIS-BESSE BUSINESS PRACTICE Number.DBBP-CHEM-2009

Title: Revision: PageStorm Water Pollution Prevention Plan 00 1 7 of 28

5.1.4 A list and description of past spills and leaks related to storm waterdischarges is includes as Attachment 5.

5.1.5 Storm water and non-storm water discharges fall under differentregulatory requirements, with non-storm water discharges requiring aNPDES permit. Outfall 1 is a combined storm water and non-stormwater discharge outfall, so it is included in this guideline and the NPDESpermit. Outfall 2 and 3 contain only storm water discharges and arecontained in this guideline. An attachment to verify these dischargeswas conducted as required and is included as Attachment 6.

5.1.6 A summary of existing storm water monitoring data is included inAttachment 7. Monitoring data summaries for Outfall 1 and Outfall 3areprovided. Monitoring for Outfall 2 is not provided as there was no flow.Outfalls 1 and 3 monitoring data show no pollutants in levels of concern.

5.2 Storm water Management Controls

5.2.1 A summary of pollutant sources and current practices to minimize thepotential discharge of such pollutants to storm water outfalls is includedin Attachment 8.

5.2.2 A list and description of new Best Management Practices (BMPs)discovered during development of this SWP3 and subsequentinspections is include din Attachment 9. At a minimum, BMPs mustinclude:

a. Good housekeeping

b. Preventative maintenance

c. Inspections

d. Spill prevention response

e. Sediment and erosion control

f. Management of runoff

g. Employee training

h. Record keeping and internal reporting

5.3 Site Storm Water Insr)ections

5.3.1 A detailed suite inspection will be conducted by the Storm waterPollution Prevention team on an annual basis to verify that the SWP3contents are accurate.

a. Attachment 10 includes a list of items to be included in the annualinspection.

b. All incidents of noncompliance will be documented on theinspection report.

c. If no noncompliance incidents are noted, the inspection willcontain a certification that the site is in compliance with the plan.

d. Annual inspection reports will be in memorandum format andsigned by the Manager-Site Chemistry.

e. A copy of the annual inspection will be maintained by SiteChemistry as part of the plan.

f. Annual inspection reports will be maintained in recordsManagement for at least three years.

5.3.2 A visual inspection should be conducted by the Storm water PollutionPrevention Team on a monthly basis of all areas of potential storm eatercontamination as identified in Attachment 3.

a. Visual inspection should be documented on ED8028,Environmental Compliance inspection Form.

b. A copy of the visual inspection form should be maintained byEnvironmental as part of the plan.

c. Visual inspections forms will be maintained in records

Management for at least three years.

5.4 Employee Training

5.4.1 Employees attend site specific training for spill response and clean-upaccording to their specific job titles and functions. Detailed trainingprograms exist for HAZWOPER and Chemical waste management.

5.4.2 Employees involved in storm water pollution prevention practices will betrained to these additional requirements by required reading of this plan.

5.4.3 Copies of those employees completing required reading will bemaintained by Site Chemistry as part of the plan as well as in Recordsmanagement.

NOTE 6.5

A simplified flow chart for storm water clean-up and notificationrequirements are shown on Attachment 11.

5.5 Storm Water Spill Response

5.5.1 The discharge of pollutants through storm water Outfall 1 is covered bythe site's NPDES permit. The allowed discharge limits, situations whichmay result in noncompliance, and notification and reporting requirementsare detailed in DB-CN-00030.

5.5.2 Storm water contamination by discharges to Outfalls 2 and 3 and therequired clean-up and reporting requirements are detailed in thefollowing locations:

a. RA-EP-02850 - Describes HAZWOPER activation requirementsand small spill/discharge clean-up information.

b. ECG-04 - Describes how to clean up chemical spills/dischargesand the associated reporting requirements. (For purposes of thisplan, ECG-04 applies to gasoline, paints/solvents, sodiumhypochlorite, and miscellaneous laboratory chemicals whenexpose dot storm water.)

c. DBBP-CHEM-2005 - Describes how to clean-up oil/diesel fuel

spills/discharges and the associated reporting requirements.

6.0 REFERENCES

6.1 Developmental

6.1.1 Clean Water Act of 1987

6.1.2 Comprehensive Environmental Response, Compensation, and LiabilityAct (CERCLA) of 1980

6.1.3 Oil Pollution Act of 1990

6.1.4 40 CFR § 110, EPA Regulations on Discharge of Oil

6.1.5 40 CFR § 112, Oil Pollution Program

6.1.6 40 CFR § 116, EPA Regulations on designation of HazardousSubstances under the Federal water Pollution Control Act

6.1.7 40 CFR § 122, 123,and 124, National Pollutant Discharge EliminationSystem Permit Application regulations for Storm water Discharges

6.1.8 40 CFR § 117, EPA Regulations on determination of ReportableQuantities for Hazardous Substances

6.1.9 40 CFR § 302, EPA Designation, reportable Quantities, and NotificationRequirements for Hazardous Substances under CERCLA

6.1.10 Ohio Administrative Code (OAC) Section 3750-1, State Emergencyresponse Commission

6.1.11 OAC Section 3750-25, Emergency Release Notification


6.1.13 RA-EP-02850, hazardous Chemical and Oil Spills

6.1.14 Storm Water Permit Manual, Thompson Publishing Group

6.2 Implementation

6.2.1 DB-CN-00030, National Pollutant Discharge Elimination System(NPDES) Program

6.2.2 ECG-04, SARNCERCLA Hazardous Chemical Locations and Spill Event

Guidelines

6.2.3 DBBP-CHEM-2005, Spill Prevention and Countermeasure (SPCC) Plan

7.0 RECORDS

7.1 The following quality assurance records are completed by this guideline andshall be listed on the Nuclear Records List, captured, and submitted to NuclearRecords Management in accordance with NG-NA-00106.

7.1.1 None

7.2 The following non-quality assurance records are completed by this guidelineand may be captured and submitted to Nuclear Records Management inaccordance with NG-NA-00106.

7.2.1 Pollution Prevention Team

7.2.2 Material Inventory

7.2.3 Description of Exposed Significant Materials

7.2.4 List of Significant Spills and Leaks

7.2.5 Non-Storm water Discharge Assessment

7.2.6 Existing Monitoring data

7.2.7 Summary of Pollutant Sources

7.2.8 Best Management Practices

7.2.9 Annual Site Inspection Reports

7.2.10 Monthly Inspection Forms

7.2.11 Non-Periodic Reports, if generated.

8.0 SCOPE OF REVISION

Rev. 00 The Fleet Program Manager has concurred with the issuing of thissite-specific business practice.


DBBP-CHEM-2009Revision: Page 4I-

Title:

Storm Water Pollution Prevention Plan 00 I 12 of 28

ATTACHMENT 1: POLLUTION PREVENTION TEAM-Page 1 of 1

Leader:

Responsibilities:

POLLUTION PREVENTION TEAM MEMBER ROSTER

V. N. Capozziello, Supervisor-Nuclear Chemistry Services

Coordinate all stages of plan development and implementation, ensurerequired reports are submitted, and coordinate employee trainingprograms.

Members:

1) S.M. Chimo, Senior Nuclear Specialist

Responsibilities: Conduct inspections, develop plan, and prepare required reports.

2) A.M. Percival, Senior Nuclear Specialist

Responsibilities: Help conduct inspections for plan development.

3) J.J. Eccleston, Nuclear Engineer

Responsibilities: Oversee inspections and plan development, verify discharge locations,oversee preventive maintenance.

4) Group Activities

Responsibilities: Developing the plan elements, choosing storm water managementoptions.

DAVIS-BESSE NUCLEAR POWER STATION-I

-I c

m

o m< _00 (D

zz

CD --

_L ro

wi-=uulas~ o 0

-- W"A"~ -MEMý&si =5MIC 3MaAL Lr 0"M M

orILso Dli= * O-anc WL ~-- ~UCI.

a)Snsm "Ea~U 0~I.DICIG -NG3 ~ 1 t Iw~ e

ATTACHMENT 3: MATERIAL INVENTORYPage 1 of 3

Outfall 1 (NPDES Outfall 002)

Quantity Likelihood ofPurpose/ Exposed in Contact with Storm Past Significant

Material Location Quantity Last 3 Years Water Spill or Leak

Sodium Above ground 7,500 gal No Possibility during Nohypochlorite tank with 115% chemical delivery15% solution dike

Sodium bromide Above ground 4,300 gal No Possibility during No43% solution tank with 115% chemical delivery

dike

Warehouse New chemical Varies No No-area diked. Nochemical bldg. storage Insufficient

containment butgate for drainage

ditch cdn be closed

Chemical Waste Various Varies No Building has NoStorage Area chemical containment curb.

storage prior to Possibility duringtransfer off-site chemical

transfer/shipment

Storm Water Pollution Prevention Plan


Outfall 1 (NPDES Outfall 002) (Continued)

Chemical waste accumulation::

Quantity Likelihood ofPurpose/ Exposed in Contact with Storm Past Significant

Material Location Quantity Last 3 Years Water Spill or Leak

1) Turbine Accumulation Varies (-5-8 No Possibility during NoBldg.(North): 55 gal chemical transfer.used oil, Unit has self-diesel fuel, containment.filters/debris'

2) Diesel Accumulation 2-55 gal No Possibility during Nostorage chemical transfer.tank: Unit has self-diesel fuel oil containment.

3) EDG diesel Accumulation 2-55 gal No Possibility during Nofuel area: chemical transfer.diesel fuel oil Unit has self-

containment.

4) PSF Mech Accumulation Varies (-3-5 No Possibility during NoMaint.(used 55 gal chemical transfer.oil, filters/ Unit has self-debris containment.

5) SBODG Accumulation 1-55 gal No Drum is overpacked No

Fuel:

1) Diesel oil Tank above 100,000 gal No Leaks/spills and Nostorage tank ground with delivery accidents

dike would go through oilinterceptor

2) Diesel fuel Underground 2-40,000 gal No Yes-no containment Nostorage tanks

3) DBAB Diesel Underground 8,000 gal No Yes-during fuel Nofuel storage deliverytank

Salt Pile De-icing 100-125 No Area is covered Noroadways tons/year



Storm Water Pollution Prevention Plan 00 16 of 28


Outfall 2 (Wastewater Treatment Facility)

Purpose/ Quantity Likelihood ofMaterial Location Quantity Exposed in Contact with Storm Past Significant

Last 3 Years Water Spill or Leak

Sodium De-chlorination 900 gal No Yes-during NoBisulfite chemical transfer or

tank /pipe leak.Spilled material

would most likelyenter soil rather

than storm drain.

Outfall 3 (Parking and Service Building #4)

Purpose/ Quantity Likelihood ofMaterial Location Quantity Exposed in Contact with Storm Past Significant

Last 3 Years Water Spill or Leak

Diesel fuel Fleet fueling. 1,000 gal No Possibility-during Notank Above ground fuel delivery

tank w1115%dike

Gasoline Fleet fueling. 2,000 gal No Possibility during YesAbove ground fuel deliverytank w/115%

dike

Chemical waste accumulation:

Used oil Accumulation 2-55 gal No Possibility duringchemical transfer.

Unit has self-containment.

ATTACHMENT 4: DESCRIPTION OF EXPOSED SIGNIFICANT MATERIAL*Page 1 of 1

Based on the material inventory, the following describes the significant materials that wereexposed to storm water during the past three years and/or are currently exposed.

Description ofExposed Method of Material

Significant Period of Currently Storage or ManagementMaterial Exposure Exposed Location Disposal Practice

*There have been no events of significant materials exposed to storm water within the past

three years.

DAVIS-BESSE BUSINESS PRACTICE Number:DBBP-CHEM_2009

Title: Revision: BPageStorm Water Pollution Prevention Plan 0 0 18 of 28

ATTACHMENT 5: LIST OF SIGNIFICANT SPILLS AND LEAKSPage 1 of 1

Record all significant spills and significant leaks of toxic or hazardous pollutants that haveoccurred in the past three years. Significant spills include, but are not limited to, releases ofoil or hazardous substances in excess of reportable quantities. --

* There have been no significant spills or significant leaks of toxic or hazardous pollutantsthat have occurred in the past three years.

Previous significant spills and significant leaks of toxic or hazardous pollutants that haveoccurred.

MaterialNo

Amount. Longer PreventativeDate Spill/Leak Location Quantity Source Reason Recovered Exposed Measures

to Storm TakenWater

Gas Leaking GasDispensing 1,300 gal Gas Line True-in Put Pump in

1/15/94 Leak area Gasoline Tank Diaphragm 500 gal soil Dike

Overfill DrumDiesel fuel during level staged

Spill 40,000 gal calibration True-in during level8/21/98 (overfill) tank 50 gal Overfill activities -25 gal soil calibrations

ATTACHMENT 6: NON-STORM WATER DISCHARGE ASSESSMENTAND CERTIFICATION

Page 1 of 1

%

Workshset #6NON-STORM WATER DISCHARGE Completed by: S.H. Chimo

ASSESSMENT AND CERTIFICATION Title: Environmental Special 1nr(Saction 2.2.41 Date: November 4. 1998 -_

Outfall DirectlyDate of Observed During the Method Used to Describe Results from Teas for Name of Person WhoTest or Test ows-0y .. thas..,d Tast or Evaluate the Presence of Non-Stolm Identify Potential Condbcted ithe Teast or

SEvaluation Ole egg m.9t Discharge Water Discharge Significant Sources Evaluation

Visual Discharge mixed with10/91 Outfall I Inspection NPDES Outfall 002 NONE T.K. Wasch

Visual

10/91 Outfall 2 Inspection qo diacharse obaerved NONE T.K. Wanch

Drawing ao non-storm water

1/19/95 Outfall 3 Schematics .onnections observed NONE T.K. Weech

CERTIFICATION

1, John K. Wood (reeponsible corporate ofliclall. certify under penalty of law that this document and all atachmenta wareprepared under my direction or supervision In accordance with a system designed to assure that qualified personnel property gather and evaluate theInlorrnation submitted. Bsaled on my Inquiry of the person or persona who manage the system or those persons directly responsible for gatheringthe.informatlon, the Information submitted Is, to the beat of my knowledge and belief, true, accurate, and comphdte. I am awore that there eraof-nnihfiI nt •,ldtt for iume lttlnnt fals,-tiformation. Iniludino the posslblty of fine and Imorlsorment for knowing violatlons,

A. Name & .OfficlafTitle (typb or prinli, B. Area Coda and Telephone No.

Johil K. Wood. ViPe Pregidetr-Nuclaar 419-n249-2300

c. Snatura . I Si,.gned.,I il all O I I

'; . " 7


Title: Revisidn: Page


ATTACHMENT 7: EXISTING MONITORING DATAPage 1 of 2

EIPA ID Nmi (OPY ftM Item I OtForro 1).. 03706-SW Outfali 002

Forn Approved. OM No. 2040-00•0Approvul excis 5-31-92

VII. Discharge Information (Continued from page 3 ofForm 2F)

Part A - You must oride the resulb of at least one analysis far very pot•t.leo In this table. Cornptete one table for each cutt.a Saa Insbuotlns for addlonel deoal.

Maximum Values Average ValuesJ~ieU1919) JOnclude EsV/a) Numiber

Polutant GrOb Sample b gm'eofand Taker) During Taken Dur, Storm

CAS Number First 20 Flow-Wlgtrlad Fbt2O tow4WA)hted Ewnt*flfavaftblo) MIna Cornposofe Minutes Composlie Sampled Sourcas of Patutants

03 and OrG e <5 mg/i NWA

Biological OxygenDemand eDDS) 3.3 U•/Cicemal OxygenDemand (COD) 11..1 mTotal SuspendedSoW3 (TSS) 13 /

Total Nitrogen .0.20 g/1 1

Total Phosphoras -0.05 mg/i I

pH Minimum -7.'.7 Maximum 7.97 Mi Mamum trarnum iPert 8 - Lst each podutant that Is Winiled In an effluent guldelne whiich the faaliy ts subject to or any pollutant listed In the fadity's NPOES Permit for tit process

walawator (if the facilty It operating under an existing NPDES pernmt. Complete one tabMe for each oufialL. See the In•Aaucone far addtional delaia and

Maximum Vatues Average Values- m rud uns) OJickr do 1u1,11) Number

Pollutant Grab Sample Grab Sampe ofand Taken Du:ig Take DInt: Stoflr

CA$ Number Firlt20 Fow-blighled " Flnt 20 Flow-Welghted Events(ifovailable) Minutes Composlit Minutes Composait Sampled - Sources of Pollutants

Di.•, Osygen 7.6 ppm 1

TOC .O.os mg/i

fluorida 0.4 m9/iAlurlUosm 530 __l_

Acaanla sin rlg/lBariume 70 ug/1

Boron 112 ug/1

Copper <3 %g/1

Xron 471 ug/i

Silver <1 u/g/1Ammoia ý0.2 mg•/l "

T0 <0.2

EPA Form 3510-2F (1-92) Page V11-1I Continlue on Revoers




ATTACHMENT 7: EXISTING MONITORING DATAPage 2 of 2

V. PA ID ombe-r.11 .l aIoF- 1n) Form AptPovod. OMB No. 2040-008Approval exprs s-31.92

VIl. Discharge Information (Continued from page 3 of Form 2F)

Part A - You must povde the results of M lenst one enaals fot er pollthant in Ohi tae. COplieta one Wa for each oulra0., See Inslbrlions for eddillonel details.

Maximum Values Average ValuesWifagmts) J uslrd. nhl) Number

Polutant Grab Sample Grab Sample ofand Taken During Taken During alom

OAS Number First 20 Floo.-Wagsloed First 20 Filoiy-W hted EWtstOiflveleA4) Minutds Comt Minutas Compoale Sampled sources of Polutaets

Oland Geaasi <5 Xe/1 WA

Bohoaica" OxygenDemand (BOG5) ~ a/Chemical OxygenDemand (O) 54.9 rae/iTotal SuspendedsoLIds (Trs) :s~ =m1/

Total NItrogen 0.45 V3/1 I

Total Phosphorus 0.27 ,g/i 1

pH Mnilmum ,.OO Maximum -. 092 Wrnoum MaximumPart 8- List each pollutant tuat Is llmlltd Int a effluent putallrre BIch the tacilly Is subject io or any polutani lbted in the faclIyA NPDES permit for iu process

westewaler t fIte faclity Is operamlr under an exiting NPDES permll|. Complete one table for each outf11. See the Instructons for Acd.ltioral deala aendteo lmrntn

Maximumvalvee Avege ValuesM~l unb~) emin~de, un9t2) Nn

Pollutant Grab Semple Grab Sample ofend Taken Durn Duken Duringt

CAS Number Firet 20 Flow-W6ted Fl120 Flow-Welhted Ewait(flavallable) Mlnutas Minutes Comoposite Smpled Souro, of Pollutaent

Diae. ,Oxygen 4.5 ppm 1

TRC 0.1 i_/1Fluoride 0,8 raq/iAlumi.umn 1377 U9/1

Arsenio <10 Um/1

Barium 98 ug/

BOron 77 U9/1

Copper 14 U91/

Iron 14706 UV/1 _________ ____

Silver <3 ug/_

TIOS 1.2 mn/1

EPA Form 3610-2F (1-92) Paes V11.11 Contin~ue on Revers

ATTACHMENT 8: SUMMARY OF POLLUTANT SOURCES- Page 1 of 2

The following significant materials have been stored on-site within the last three years withinthe described storm water discharge areas:

1. Outfall 1 (NPDES Outfall 002)

a. Chemical Waste Storage Areas (CWSA)

The CWSA is an enclosed structure with a curbed concrete pad to contain anypotential leaks. The pad is divided into three separate sections as follows: 1)hazardous waste, 2) waste oil and non-hazardous wastes, and 3) chemicalidentification. In the event of a large quantity leak, the flapper gates for thedrainage ditch behind the facility can be closed to isolate the spill. Also, theCWSA is inspected on a weekly basis.

b. Chemical Waste Accumulation Areas (CWAA)

There are two CWAAs in this storm water discharge area. These two CWAAsare only for diesel fuel. They each consist of two 55-gallon drums contained inthe water-tight plastic storage containers.

c. Sodium Hypochlorite (NaOCI) Tank

The NaOCI tank, which is located at the site water treatment plant, has amaximum capacity of 7,500 gallons and contains a 15% solution. This tank hasa dike structure designed to contain 115% of the tank capacity.

d. Sodium Bromide (NaBr) Tank

The NaBr tank, located at the Water Treatment Plant, has a 4,500 galloncapacity and contains a 43% solution. This tank has a dike structure designedto contain 110% of the tank capacity.

ATTACHMENT 8: - SUMMARY OF POLLUTANT SOURCESPage 2 of 2

e. Oil Containment

Oil Containment consists of the following:

MaximumTank/ Equipment Capacity (gallons)_ Physical Controls

Diesel Oil Storage Tank 100,000 Diked

Emergency Diesel Generator Collected in an Oil(EDG) Day Tanks 2-6,000 each Interceptor

Emergency Diesel Generator 2-40,000 each None- Underground(EDG) Fuel Oil Storage Tanks

There are five oil interceptors which service plant drains and sumps entering theOutfall 002 Discharge System. Those storage tanks or equipment whosecontainments are not directly associated with the interceptors, would ultimately beserviced by an interceptor via adjacent plant floor and service drains. Theunderground storage tanks listed are not serviced by oil interceptors.

2. Outfall 2 (Wastewater Treatment Plant)

Sodium Bisulfite (NaHSO4) Tank

The NaHSO4 tank, that is located near the station collection box, has a 900 galloncapacity and contains a 40% solution. If any NaHSO4 is spilled during chemicaldelivery, it would be absorbed in the surrounding soil. Storm water contact is not likelyfrom this location, since the area is not paved.

3. Outfall 3 (Service Building 4)

a. Diesel Fuel Storage Tank and Gasoline Storage Tank

Used to service fleet vehicles, the diesel fuel storage tank has a 1,000 galloncapacity, and the gasoline tank has a 2,000 gallon capacity. They share thesame concrete dike, which is designed to contain 115% of the total capacity.

b. Chemical Waste Accumulation Area (CWAA)

This outfall area has one accumulation area for automotive oils and antifreeze.This CWAA is a self-contained unit designed with a spill pan underneath.

DAVIS-BESSE BUSINESS PRACTICE Number.DBBP-CHEM-2009Title: Revision: |PageStorm Water Pollution Prevention Plan o:0 0 24 of 28

ATTACHMENT 9: BEST MANAGEMENT PRACTICES

Page 1 of 3

A. Good Housekeeping

Weekly Chemical Waste Accumulation Areas (CWAAs) and Chemical waste StorageArea (CWSA) housekeeping inspections as conducted by the Environmentalpersonnel. Problems are corrected as they are identified.

Maintenance Supervisors are assigned as responsible for various areas throughout

the site. This includes cleanliness of the area.

B. Preventative Maintenance

Various engineers on site are assigned specific systems. The engineers are thenresponsible for oversight of all aspects of the system, including preventativemaintenance scheduling and tracking as well as conducting weekly visual inspections.Some "systems" in this program include various chemical and oil tanks, stationdrainage and the oil interceptors. All preventative and scheduled maintenance itemsare tracked in a site-wide database.

Oil interceptors are checked periodically by pumping out the associated collectiontanks. These tanks rarely contain any oil, which shows that the tanks are notdischarging oil to the storm water system.

Warehouse and Maintenance Services personnel are trained in loading/unloadingprocedures and must complete Chemical Waste management training. If a spill wouldoccur as a result of these activities, these personnel; are also trained in cleanupmeasures.

C. Visual Inspections

In addition to the system inspection by the engineer and the weekly CWAA and CESAinspections previously mentioned, a visual inspection will now be conducted by thePollution Prevention Team on a monthly basis of all potential storm water pollutants aslisted on the materials inventory. A copy of the inspection form will be maintained withthis plan by Environmental.

A more detailed annual inspection will also be conducted by the Storm water PollutionPrevention Team. All problems identified and the corrective actions taken will bedocumented in memorandum format and signed by the Manager-Site Chemistry. Acopy of each annual inspection may be maintained with this plan by Environmental.

ATTACHMENT 9: BEST MANAGEMENT PRACTICESPage 2 of 3

D. Spill Prevention and Response/Management of Runoff

Detailed spill response and cleanup, measures are described in RA-EP-02850,hazardous Chemical and Oil spills; ECG-04, SARA CERCLA Hazardous ChemicalLocations and Spill Event Guidelines; and ECG-05, Spill Prevention Control andCountermeasure (SPCC) Plan. Items specific to storm water spill prevention are alsodescribes below:

1. Outfall 1 (NPDES Outfall 002)

The two chemical storage buildings are diked. Although this will not contain theentire contents of either building, both have a drainage ditch with a closablegate to contain any spills.

The six CWAAs are all enclosed in either a building or a plastic containmentstructure. Small spills would be contained in the CWAA.

The three bulk chemical storage tanks have diking sufficient to contain theentire tank contents, so storm water discharge is unlikely.

The 100,000 gallon diesel oil storage tank has a dike structure sufficient to holdthe entire tank contents. Also, deliveries occur on a concrete pad which drainsto an oil interceptor prior to discharge.

The 2-40,000 gallon diesel fuel storage tanks and the Davis-BesseAdministration Building diesel fuel storage tanks are underground storagetanks, so they do not come directly in contact with storm water. They areincluded in this plan due to the potential for a spill during bulk fuel deliveries.

Salt storage is contained inside a three-sided building.

All storage tank bulk deliveries are performed in the presence of site personnel.If a spill would occur, these individuals would know the required actions forresponding to the incident.

At Outfall 1 drainage goes through the Training Center pond prior to discharge.This is a 12 million gallon holding pond. It has a discharge gate which can beclosed for cleanup actions to prevent any discharge.

All large tanks contain spill kits nearby for use during spill response procedures.Such kits contain oil and chemical absorbent booms and pads, drain coversand/or plugs, and protective clothing as necessary for cleanup.

ATTACHMENT 9: BEST MANAGEMENT PRACTICESPage 3 of 3

D. Spill Prevention and Response/Management of Runoff (Continued)

2. Outfall 2 (Wastewater Treatment Plant)

The sodium bisulfite tank has 900 gallon capacity and is stored in a metalbuilding. If any NaHSO4 is spilled during chemical delivery, it would beabsorbed in the surrounding soil.

3. Outfall 3 (Service Building 4)

There is one CWAA in this area. It is a small plastic shed with a containmentstructure. Small spills would be contained in this area.

There is a 1,000 gallon diesel fuel tank and a 2,000 gallon gasoline tank.These tanks and their associated pumps are contained inside a single dikestructure, which is designed to contain the entire contents of these tanks. Spillsare possible during fleet fueling from these tanks or during bulk deliveries. Anoutdoor telephone is installed nearby for contacting the control room should aspill occur. There is an oil interceptor which can contain up to 1,500 gallons.

E. Sediment and Erosion Control

Potential erosion areas are graded and grassy. The majority of the facility is paved orcovered with gravel.

F. Employee Training

Applicable employees who may come in contact with spills and discharges are trainedin HAZWOPER and chemical waste management. Training specific too storm waterpollution prevention will also be conducted by required reading.

G. Record Keeping and Reporting

All information pertaining to any spill, follow-up actions, inspections, sampling andtraining is maintained by Environmental.

I fA\/IS-RFSS 13RI INFES PRACTICEP Number:

Title:

-- DBBP-CHEM-2009Revision: Page


ATTACHMENT 10: ANNUAL SITE INSPECTION CHECKLISTPage 1 of 1

1. Is there evidence of pollutants entering the drainage system?

2. Are current BMPs sufficient to reduce pollutant loadings?

a. Are additional BMPs needed/recommended?

3. Are structural measures (Ponds, dikes, curbing, dischargegates, etc.) in proper operatibn?

4. Is all spill response equipment properly staged as specified inthe plan?

5. Are there any new sources which may cause storm watercontamination?

6. Have any storm water sources, drainage pathways, structuralcontrols or BMPs changed/moved since last inspection?

Yes

Yes

Yes

No

No

No

NA

NA

NA

Yes No NA

Yes No NA

Yes No NA

Yes No NA

ATTACHMENT 11: STORM WATER DISCHARGE FLOW CHARTPage 1 of 1

SMTPWLOIMSAFESTFORMVrR.Cdr1115M9

Groundwater FlowCharacteristics ReportDavis-Besse Nuclear PowerStationOak Harbor, OhioFirstEnergy Service Company

16 January 2007

www.erm.com

- MOel ER

~ERMDelivering sustainable solutions in a more competitive worl,

I FINA REPOR

Groundwater Flow CharacteristicsReportDavis-Besse Nuclear Power StationOak Harbor, Ohio

FirstEnergy Service Company

16 January 2007

ERM Reference: 55194

J o h n W . M ~ g e A § ,,

Principal-in-Charge

VY~ I6~Matthew Daly, P.G.Project Manager

Environmental Resources Management

399 Boylston Street, 6th FloorBoston, Massachusetts 02116

T: (617) 646-7800F: (617) 267-6447

TABLE OF CONTENTS

EXECUTIVE SUMMARY III

1.0 INTRODUCTION 1

1.1 BACKGROUND 1

1.2 PURPOSE & SCOPE 1

1.3 LIMITATIONS 2

2.0 SITE VISIT AND DATA REVIEW 3

3.0 FINDINGS 5

3.1 AREAS OF POTENTIAL CONCERN 53.1.1 Power Block 53.1.2 APCs Outside the Power Block 63.1.3 Non-radiological APCs 7

3.2 TRITIUM DATA 8

3.3 SITE GEOLOGY AND HYDROGEOLOGY 93.3.1 Site Geology 93.3.2 Site Hydrogeology 11

3.4 SURFACE WATER AND GROUNDWATER USAGE 12

3.5 CONCEPTUAL SITE MODEL 133.5.1 Overview 133.5.2 Plan View 143.5.3 Section View 153.5.4 Summary 16

4.0 RECOMMENDATIONS 17

ERM/DADE MOELLER 1 FIRSTENERGY - DAVIS-BESSE 55194 1/16/07I

TABLES

Table 1

FIGURES

Figure 1

Figure 2

Figure 3

Figure 4

Figure 5

Areas of Potential Concern 0

Site Locus Map with Hydrogeologic Features

Areas of Potential Concern

Existing Monitoring Wells and Grout Curtain

Conceptual Site Model and Proposed Monitoring Locations

Conceptual Site Model - Section View

APPENDICES

Appendix A Letter from Davis-Besse Engineering

ERM/DADE MOELLER II FIRSTENERGY - DAVIS-BESSE 55194 1/16/07

EXECUTIVE SUMMARY

On behalf of FirstEnergy Service Company (FirstEnergy), as agent forFirstEnergy Nuclear Operating Company (FENOC), EnvironmentalResources Management (ERM) and Dade Moeller & Associates (DadeMoeller) conducted a Groundwater Flow Characteristics Study for theDavis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio.The purpose of the Groundwater Flow Characteristics Study was toevaluate the geology and hydrogeology at DBNPS in order to gatherinformation necessary to design a monitoring program to minimize thepotential for an unmonitored and/or undetected radioactive release togroundwater due to plant operations.

Activities completed included a review of DBNPS site files, physicalfeatures, plant operating infrastructure, identification of potential areas forinadvertent radiological release, available tritium data and the sitehydrogeology. This Groundwater Flow Characteristics Study is apreliminary step in the process of complying with the Nuclear EnergyInstitute guidance titled "Industry Ground Water Protection," dated June2006.

Historic releases of tritium to ground have been documented at DBNPS.Groundwater samples collected from existing bedrock wells within thePower Block indicated tritium in groundwater at concentrations up to2,410 pCi/L.

Potential releases from DBNPS have the potential to migrate vertically orlaterally within the fill (structural or earthen), Glaciolacustrine Deposit,Till and Dolomite Bedrock towards marshes and ultimately Lake Erie.Initial evaluation of site systems, geology and hydrogeology suggest a lowpotential for releases to groundwater at the site to adversely impactdrinking water receptors given the likely up-gradient, distant location ofpotential receptors and the most probable migration pathway being fromthe site to marshes and Lake Erie. Once in the marshes and Lake Erie, theimpacts would immediately be diluted due to the volume of thegroundwater discharge relative to the volume of water in the lake.

Based on ERM and Dade Moeller's review of the available site data, thefollowing recommendations are presented to monitor for inadvertentreleases to groundwater at DBNPS:

1. Inventory and Monitor the Existing Well Network

ERM/DADE MOELLER III FIRSTENERGY- DAVIS-BESSE 55194 1/16/07

2. Develop an Integrated Monitoring Program

3. Install and Sample Monitoring Wells, including eight well tripletsand 15 temporary grab groundwater samples.

4. Develop a Quality Assurance Project Plan

5. Define Internal and External Reporting Requirements

6. Develop a Communication Plan

ERM/DADE MOELLER FIRSTENERGY - DAVIS-BESSE 55194 1/16/07ERM/ DADE MOELLER IV FIRSTENERGY - DAVIS-BESSE 5519L4 1/16/07

1.0 INTRODUCTION

1.1 BACKGROUND

On behalf of FirstEnergy Service Company (FirstEnergy), as agent forFirstEnergy Nuclear Operating Company (FENOC), EnvironmentalResources Management (ERM) and Dade Moeller & Associates (DadeMoeller) conducted a Groundwater Flow Characteristics Study for theDavis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio(Figure 1). DBNPS contains one pressurized water reactor that wasconstructed in the 1970s and went on-line in November 1977.

The Nuclear Energy Institute (NEI) initiated a voluntary policy in May2006 to enhance detection, management and communication aboutinadvertent radiological releases in groundwater at nuclear power plants.As part of the initiative, nuclear power plants are expected to:

"Put in place a company/site-specific action plan(s) to help assuretimely detection and effective response to situations involvinginadvertent radiological releases in groundwater to preventmigration of licensed radioactive material off-site and quantifyimpacts on decommissioning."

This Groundwater Flow Characteristics Study for the DBNPS is apreliminary step in the process of complying with the NEI initiative.

1.2 PURPOSE & SCOPE

The purpose of the Groundwater Flow Characteristics Study was toevaluate the geology and hydrogeology at DBNPS in order to gatherinformation necessary to design a monitoring program to minimize thepotential for an unmonitored and/or undetected radioactive release togroundwater due to plant operations. The Study included a review ofDBNPS site files, physical features, plant operating infrastructure,identification of potential areas for inadvertent radiological release,available tritium data and the site hydrogeology. The inter-relationship ofplant operations, areas of potential concern (APCs) and estimated sitegroundwater flow patterns is used to develop a Conceptual Site Model(CSM) and initial groundwater monitoring strategy.

ERM/DADE MOELLER 1 FIRSTENERGY - DAVIS-BESSE 55194 1/16/07

The groundwater monitoring recommendations outlined in thisGroundwater Flow Characteristics Report follow NEI guidance titled"Industry Ground Water Protection," dated June 2006.

1.3 LIMITATIONS

This Groundwater Flow Characteristics Report (Report) provides apreliminary evaluation of site characteristics necessary to support thedesign of a groundwater well network for monitoring existing or potentialreleases of radioactivity to groundwater at the site. The professionalopinions presented in this Report were developed under a limited scope,schedule and budget (ERM Proposal, 11 August 2006). This Report isintended to represent the first phase of a series of studies and activitiesthat will be required to develop an effective groundwater monitoringprogram for the site. As such, the results, conclusions andrecommendations in this report are subject to change as the results ofsuccessive, iterative phases of site investigation, sampling, datamanagement, interpretation and stakeholder outreach progress.


2.0 SITE VISIT AND DATA REVIEW

As part of this project, the team conducted the following activities:

* Conducted a site visit at DBNPS on 10 and 11 October 2006.

* Reviewed the following documents:

* Updated Safety Analysis Report (Revision 25, June 2006), Sections2.4 (Hydrology), 2.5 (Geology and Seismology) and Appendix 2C(Geology, Seismology, Subsurface Conditions and GeotechnicalDesign Criteria).

* Supplement to Environmental Report Operating License Stage(1970s).

* Annual Radiological Environmental Operating Report (2005).

* Technical Report 14 "Groundwater Injection Recharge Report Units2 and 3 Construction Dewatering" (17 March 1980).

" Potential Condition Adverse to Quality Report #90-0404"Discovery of Dye from the Condenser Dye Test in the Area Southof the Intake Structure" (11 May 1990).

" Intra-Company Memorandum titled "Meeting Minutes - RupturedCondenser Backwash Receiver Tank Discharge Line" (29 October1991).

* Potential Condition Adverse to Quality Report #97-0628 "WhilePumping North Settling Basin to Collection Box, the Hose Goinginto the Collection Box Dropped Out of Collection Box Pumping -

12,000 gallons onto the Ground" (13 May 1997).

* Condition Report (CR 04-01719) "Information Notice 2004-2005Spent Fuel Pool Leakage to Onsite Groundwater" (5 March 2004).

" Letter from Davis-Besse Engineering documenting the identity ofDBNPS systems/components which are vulnerable to potentiallyinitiating an unmonitored release to the environment (seeAppendix A for the letter).

" Letter titled Groundwater Protection - Data Collection Questionnairefrom FirstEnergy summarizing inadvertent releases of radioactiveliquids documented in DBNPS 10 CFR 50.7 5(g) files (31 July 2006).

ERM/DADE MOELLER 3 FIRSTENERGY- DAVIS-BESSE 55194 1/16/07

" Reviewed facility engineering drawings and aerial photos related tothe facility layout.

* Participated in a walking tour of portions of the interior and exterior ofDBNPS.

* Spoke with DBNPS representatives from Chemistry Department.

In addition to the information provided by FirstEnergy, ERM obtainedinformation from the following data sources:

* Environmental Data Resources Inc. (EDR) reports including historictopographic maps, environmental records near DBNPS and physicalsetting.

* Ohio Department of Natural Resources Geographic InformationSystem (GIS) databases.

ERM/DADE MOELLER FIRSTENERGY - DAVIS-BESSE 55194 1/16/07ERM/DADE MOELLER 4 FIRSTENERGY - DAVIS-BESSE 55194 1/16/07

3.0 FINDINGS

3.1 AREAS OF POTENTIAL CONCERN

APCs represent locations at the DBNPS where there is a possibility that arelease of radionuclides and/or oil and hazardous pollutants (i.e., non-radioactive contaminants) to groundwater either has, or could occur. TheAPCs identified at the DBNPS are summarized in Table 1 and are shownin Figure 2. Each of the primary APCs are discussed below.

3.1.1 Power Block

The Power Block represents the area that contains the reactor vessel andassociated primary and secondary water sources in a pressurized waterreactor. The Power Block includes the following APCs as potentialradiological sources:

* Containment Building

0 Auxiliary Building

o Miscellaneous Waste Drain Tank

o Spent Fuel Pool

o Cask Pit

o Liquid Radwaste Treatment System

o Clean Waste Receiver and Monitor Tanks

o Spent Resin Storage Tank

o Detergent Waste Drain Tank

o Boric Acid Evaporators

o Concentrates Storage Tank

0 Turbine Building

o East and West Condenser Pits

o Sumps

o Condensate Demineralizer Tanks

0 Fuel Transfer Canal

* Circulating Water Pump House

* Borated Water Storage Tank


0 Nitrogen and Hydrogen Supply Area

3.1.2 APCs Outside the Power Block

Several radiological APCs were identified outside the Power Block assummarized below (Figure 2):

* Condensate Demineralizer Tank Discharge Line - In May 1990, a breakin the discharge line exiting the Condensate Demineralizer BackwashReceiver Tank was discovered east of the Power Block. Contaminatedresin was released to soil at the connection between the CondensateDemineralizer Backwash Receiver Tank discharge line and a ten inchpipe that conveys the resin to South Settling Pond.

* Liquid Radwaste Discharge Line - This pipe conveys liquidradiological waste from the Power Block to the Collection Box fordilution prior to release.

* Collection Box - The collection box receives tritiated water from theLiquid Radwaste Discharge Line, along with water pumped up fromthe North and South Settling Basins. In 1997, water pumped fromNorth Settling Basin to the Collection Box was inadvertently spilledonto the ground surface adjacent to the Collection Box.

* Collection Box Discharge Pipe - This pipe is the primary discharge linefor release of permitted discharge of tritiated water to Lake Erie. Thedischarge pipe is 72-inches in diameter and constructed of concrete.Leakage of tritiated water from the Discharge Pipe to the subsurfacecould result in the inadvertent release of tritium to groundwater.

* South Settling Basin (Settling Basin No. 1) - This settling pondhistorically received radioactive resins from the CondensateDemineralizer Backwash Receiver Tank.

" North Settling Basin (Settling Basin No. 2) - This settling pond isconnected to the South Settling Basin via piping and pumps, allowingradioactive effluents from the South Settling Basin to enter the NorthSettling Basin.

* Low-Level Radwaste Storage Building - This building is identified asan APC based on the handling of low-level radiological wastes in andaround the building.

° Dry Fuel Storage Area - This area is identified as an APC based on thehandling of wastes in and around the area.


* Secondary Demineralized Water Storage Tank - Steam used to heatthis outdoor tank during winter months contains tritium. This tank isan APC based on the potential for leakage from the steam system.

* Fire Water Storage Tank - Steam used to heat this outdoor tank duringwinter months contains tritium. This tank is an APC based on thepotential for leakage from the steam system.

* Sanitary Wastewater Plants and Lagoon - The historic and currentsanitary sewage treatment plants, associated piping and wastewaterlagoon are an APC due to the potential for inadvertent co-mingling oftritiated water with the sanitary wastewater.

* Stormwater Management Systems - Impacted water has the potentialto enter the any one of the three stormwater management systems andleak into groundwater through the associated catch basins, manholesand oil interceptor tanks:

o Training Center Pond (NPDES Outfall 002) - Stormwater from thePower Block, several parking lots, the transmission yard and on-site ponds is routed via subsurface piping into the Training CenterPond. A stormwater outfall (NPDES Outfall 002) exits thesoutheast corner of the Training Center Pond to the marsh andultimately discharges into the Toussaint River

o Wastewater Treatment Plant (NPDES Outfall 601) - Treatedwastewater from the sanitary wastewater plants exits theWastewater Treatment Lagoon at NPDES Outfall 601, and thenflows into the sump of the North Settling Basin. This has thepotential of mixing with the water in North Settling Basin and backflowing into the Sanitary Wastewater Lagoon during periods whenthe discharge pumps are out of service and the North Settling Basinwater level becomes high.

o Service Building 4 - Stormwater from Service Building No. 4 andsurrounding parking lots discharges to the marsh and ultimatelyLake Erie.

3.1.3 Non-radiological APCs

Although the focus of the study is on potential radiological releases, thefollowing areas were also identified as APCs for non-radiologicalconstituents to impact groundwater quality:


* Diesel Storage Tanks - Three areas of diesel tanks represent non-radiological APCs.

o A historic release of diesel fuel to soil occurred adjacent to the100,000 gallon aboveground storage tank. This release resultedin the contamination of soil and shallow groundwater adjacentto the storage tank. Remedial activities (bioremediation andfree product recovery) were conducted in response to therelease.

o Emergency Diesel Generator Fuel Oil Storage Tanks - Two40,000 gallon tanks are present northwest of the Power Block.

o Diesel Tank - One 6,000 gallon diesel tank is located within theStation Blackout Diesel Generator Building.

" Service Building No. 4 - This building is considered an APC due to thepresence of an above ground gasoline storage tank and historicalremedial activities related to overfilling of the tank.

* Transformer Oil Collection Tank - Located north of the Power Block,an underground storage tank collects transformer oils.

* Chemical Waste Storage Area - This area includes the temporarystorage of drums and containers that are used to store hazardouswaste and used oils including waste oil, oil filters, paints, solvents,Mineral Spirits (parts cleaner) and asbestos.

* Machine Shop - Mineral spirits are used in the machine shop locatedat the ground level of the Personnel Shop Facility

3.2 TRITIUM DATA

Historic tritium samples have been collected from potential source areasand from miscellaneous groundwater monitoring wells. Site features thatrepresent large potential source areas of tritium include the following:

* Spent Fuel Pool - Tritium has been detected in a water samplecollected from the Spent Fuel Pool at a concentration of 0.0552microcuries per milliliter (pCi/ml). For comparison to EnvironmentalProtection Agency (EPA) drinking water standard of 20,000 pCi/L,this detection of 0.0552 ýtCi/ml converts to 55,200,000 picoCuries perliter (pCi/L), above the EPA standard.


* Borated Water Storage Tank - Tritium has been detected in a watersample collected from the Borated Water Storage Tank at aconcentration of 80,000,000 pCi/L.

In addition to the above contained potential sources, a known release oftritium occurred in 1997, when water pumped from North Settling Basinto the Collection Box was inadvertently spilled onto the ground surfaceadjacent to the Collection Box. The estimated volume of water that leakedonto the ground surface was approximately 12,000 gallons. Theconcentration of tritium that would have been leaked to groundwaterduring this event can be estimated from a water sample collected in NorthSettling Basin on 12 May 1997, which detected tritium at 6,850 pCi/L.

Groundwater monitoring efforts have included two distinct eventsconsisting of collecting samples from existing wells. In November andJanuary 1991, groundwater samples were collected from seven wellslocated near the Hydrogen Addition System near the Borated WaterStorage Tank following leakage of tritiated water onto the ground surface.It is not known which seven wells were sampled, or whether the sampleswere collected in wells installed in the shallow or deep Dolomite Bedrock.Tritium concentrations in these seven samples ranged from 250 pCi/L to2,410 pCi/L, with an average concentration of approximately 1,000 pCi/L.

In 2004, a groundwater sample from well MW-18, located south of theSpent Fuel Pool, Cask Pit and Fuel Transfer Canal (all located withinPower Block APC) was collected to evaluate tritium concentrations ingroundwater nearby these potential sources. It is uncertain whether thegroundwater sample was collected from the well installed in the shallowor deep Dolomite Bedrock. Tritium was detected in the groundwatersample at concentrations of 667 ± 112 pCi/L and 728 ± 104 pCi/L, whichaverage to a concentration of 698 pCi/L.

3.3 SITE GEOLOGY AND HYDROGEOLOGY

3.3.1 Site Geology

The DBNPS site geology is primarily composed of three units, consistingof the Glaciolacustrine, Till and Dolomite Bedrock (TymochteeFormation). Monitoring wells, test borings and piezometers installedduring construction of DBNPS indicate the relative thickness andelevation intervals for each unit in the area of the Power Block:


Unit Approximate Depth Approximate Elevation

Interval(s) Below Ground Range (feet above mean sea

Surface (feet below ground) level)

Glaciolacustrine 0 - 10 feet 574 feet - 564 feet

Till 10 feet - 20 feet 564 feet - 554 feet

Dolomite Bedrock 20+ feet 554 feet and below

The hydrogeologic description of each unit is described below:

" Glaciolacustrine Deposit - the shallowest unit that occurs naturally atground surface, this deposit contains inter-bedded fine sand, clayeysilt and silty clay. The Glaciolacustrine Deposit represents sediments ofa complex, unconsolidated nature that were deposited within atemporary lake during recession of glacial ice from Lake Erie.

* Till - located beneath the Glaciolacustrine deposit, Till consists of grey,silty clay and some sand. The base of the Till is characterized by aboulder layer, which is comprised of silty sand and boulders.

* Dolomite Bedrock - located beneath Till, the Dolomite Bedrockconsists of argillaceous dolomite that has been subdivided into tworock types: a massive dolomite and a laminated dolomite. The massivedolomite is approximately 8-10 feet thick of hard, fine graineddolomite and is present approximately 10 feet below the top of thedolomite. Laminated dolomite occurs above and below the massivedolomite, and consists of thinly interbedded intervals of gypsum,anhydrite and shale. The upper surface of the dolomite bedrock wasremoved in the area of the Power Block during Unit #1 construction,and geologic mapping of the exposed bedrock surface determinedjointing in bedrock with orientations to the northeast (N45°E) andnorthwest (N50°W). Dolomite beds within the bedrock naturally dipto the south, with the angle of dip less than one degree.

The surfaces of the Glaciolacustrine, Till and Dolomite Bedrock depositsslope towards Lake Erie.' Several marshes are located between DBNPSand Lake Erie, including the Navarre Marsh section of the OttawaNational Wildlife Refuge. The marshes represent flooded areas ofvegetation. The elevation of water in the marshes is generally consistentwith Lake Erie, except when FirstEnergy operates pumps to control thewater level on behalf of the Wildlife Refuge. The marshes are separatedfrom Lake Erie by dikes and a barrier beach along the shoreline of LakeErie.


3.3.2 Site Hydrogeo logy

Groundwater flow in the Glaciolacustrine and Till deposits hashistorically been considered insignificant. Preconstruction monitoringwells were installed only in the Dolomite Bedrock, indicating that regionalgroundwater flow in the Dolomite Bedrock is towards Lake Erie.

Groundwater flow within the Dolomite Bedrock occurs within beddingplanes, joints, fractures, lineaments and solution cavities. In order tounderstand the direction of groundwater flow in the Dolomite Bedrock, itis critical to understand the orientation of these structural features. Thepredominant orientation of bedrock fractures trend from southwest tonortheast. The dip of the beds within the Dolomite Bedrock is less thanone percent to the south.

A lineament analysis (Figure 1) depicts the orientation and/or expressionof linear features at ground surface that often mimic structures in thebedrock. Such linear features in bedrock can act as preferred migrationpathways for groundwater flow and contaminant transport. Figure 1shows that the majority of surface lineaments are orientated southwest-northeast; however, additional lineaments identified beyond the limits ofFigure 1 are oriented southeast-northwest. The orientation is consistentwith one of the joint orientations mapped during the preconstructionexcavation. Preconstruction groundwater elevation data indicated thatthe depth to groundwater in the Dolomite Bedrock is 2-3 feet above theelevation of water in Lake Erie.

During ERM's site walk of the DBNPS, historic monitoring wells werediscovered at the property (Figure 3). These monitoring wells werehistorically used to measure groundwater levels within shallow and deepintervals of the Dolomite Bedrock to assess the effectiveness of adewatering system which operated during plant construction. Thedewatering system included a series of pumping wells to dewaterexcavation areas, a grout curtain (extending 60 feet into the DolomiteBedrock) and recharge wells to inject water back into the DolomiteBedrock. The monitoring wells were within and outside the limits of thegrout curtain to assess the effectiveness and impacts of the dewateringsystem during excavation activities.

Static (i.e., non-pumping) groundwater elevation data from thesemonitoring wells were last collected in November 1979. The staticmeasurements, which could be used to anticipate current flow conditions(i.e., no ongoing dewatering and the grout curtain presumably remain),indicate a localized mound of high groundwater elevation beneath thePower Block. The mound is present in both shallow and deep bedrock


wells. Groundwater flow directions would be orientated in a radialpattern away from the mound. 0The presence of a mound may be related to recharge to the DolomiteBedrock beneath the Power Block, and the presence of the grout curtainaround the Power Block. The grout curtain would essentially act to retardthe outer movement of groundwater flow from the Power Block. Leakagethrough or under the grout curtain is expected, as the average dewateringrate inside the excavation area (i.e., inside the limits of the grout curtain)during construction of Unit #1 was 350 gallons per minute.

The 1979 groundwater elevation data also indicates a downwardcomponent of vertical groundwater flow (i.e., flow from shallow to deepbedrock) beneath the Power Block. South of the Power Block, thegroundwater elevation data indicates a component of upward flow fromdeep to shallow bedrock. Given the hydrogeologic position of the DBNPSadjacent to the regional groundwater discharge body (marshes and LakeErie), it would be anticipated that upward groundwater flow from deep toshallow bedrock would be present across DBNPS under naturalconditions. The presence of downward flow conditions beneath thePower Block is likely a reflection of recharge to the Dolomite beneath thePower Block and the grout curtain around the Power Block.

3.4 SURFACE WATER AND GROUNDWATER USAGE

Marshes and Lak•eErie, both located east-norteafvt of the .tation, are theprimary dischargelocation for grouindwater at, DBNPS. Stormwater andsurface ater at D'BNPS are rouited through three different outfallsinrtotihiemarshes east of DBNPS. Lake Erie is the source of drinking watersupply for communities and residents within five miles of DBNPS. Theintake closest to DBNPS is Carroll Township Water Plant, located at LocusPoint, approximately 3 miles northwest of the site. Lake Erie is alsoactively used for swimming, fishing, and other recreational activities.

The Carroll Township Water Plant was activated in 1998, and offersresidences near DBNPS a reliable source of quality drinking water. Theintake for the Carroll Township Water Plant is approximately 1,100 feetoff Locus Point, which is located approximately two miles northwest ofDBNPS. Based on the most recent Radiological Environmental OperatingReport, the Ottawa County Health Department has verified that there areno registered drinking water wells within five miles of DBNPS. One welllocated in Sand Beach (approximately 1.5 miles NW of DBNPS) isseasonally used as a source for non-drinking water. Historically,approximately 50 percent of the houses along Sand Beach used private


wells to obtain domestic water. Other historical wells in the vicinity ofDBNPS include 18 wells located within 2-3 miles of the site at the time ofplant construction. Water usage from these wells was for sanitary andfarm irrigation. Water quality from these wells was considered poor (i.e.,high levels of carbonate, total dissolved solids and hydrogen sulfide gas)and not suitable as a source of drinking water.

The areas closest to DBNPS where water supply wells were identified inthe USAR are highlighted on Figure 1. The current status of these wells isnot known. The areas shown on Figure 1 are located upgradient or cross-gradient from the DBNPS, with the exception of the southwestern end ofSand Beach. Water supply wells in the southwestern end of Sand Beachcould potentially be downgradient of DBNPS; however, these wells arereportedly in the shallow beach sands, rather than the Dolomite Bedrock.Based on the geographic position (i.e., upgradient) of a majority of wellsand shallow construction of wells at Sand Beach, releases to groundwaterat the DBNPS are expected to maintain a low potential to impact nearbywells, if still in use.

ERM also obtained information on registered wells from the State of OhioDepartment of Natural Resources Geographic Information System (GIS)database. The only wells identified in that database included additionaldomestic use wells located more than one mile west of DBNPS(upgradient of the DBNPS; Figure 1).

3.5 CONCEPTUAL SITE MODEL

3.5.1 Overview

This section presents a CSM to describe how potential releases ofcontaminants at DBNPS could enter the groundwater, how they may betransported in groundwater and where transport could result inhypothetical exposure to humans or environmental receptors. The CSMacts as a working hypothesis of possible contaminant migration pathwaysto aid in designing an effective monitoring well network that willultimately identify and monitor for actual groundwater impacts. Resultsof successive phases of field investigation conducted during wellinstallation and subsequent monitoring are used to adjust or calibrate theCSM for site-specific conditions until the CSM is in reasonable agreementwith field data. The CSM thereby validates the processes used, increasingconfidence that the results obtained are a reasonable characterization ofsite conditions and acts as a valuable tool in stakeholder communication.


3.5.2 Plan View

The CSM begins with a plan view of the DBNPS and the juxtaposition ofgroundwater flow paths with potential radiological and non-radiologicalAPCs (Figure 4). Although groundwater flow in the Glaciolacustrine andTill deposits was historically believed to be minimal, there is likely acomponent of flow within each geologic unit. Flow within these shallowunits would be largely controlled by the presence of surface water bodies(i.e., ponds, marshes and Lake Erie), as these features representgroundwater discharge bodies. Since a majority of the DBNPS is largelypaved and covered by buildings, recharge to these deposits would behighest in areas west of the Power Block. The potential for leakage fromplant piping and storm drains beneath paved areas could result in directrecharge of water to the Glaciolacustrine and Till deposits, or to thestructural fill where native deposits were excavated during plantconstruction.

A significant component of the plan view CSM is the regional direction ofgroundwater flow in the Dolomite Bedrock and localized flow influencedby the Grout Curtain. Regional flow is east-northeast towards themarshes and Lake Erie, while localized flow beneath the Power Block isrepresented in a radial pattern, largely controlled by the grout curtainsurrounding the Power Block. Figure 4 shows there is a component ofgroundwater flow to the west from the Power Block; however, theultimate discharge sink for groundwater is the marshes and Lake Erie tothe east.

Potential APCs falling outside the Grout Curtain and within the influenceof the regional flow system include the Dry Fuel Storage Area,Wastewater Treatment Plants, Condensate Dernineralizer BackwashReceiver Tank Discharge Line, Collection Box and Discharge Pipe,Secondary Demineralized Water Storage Tank, Fire Water Storage Tank,North and South Settling Basins. Groundwater migration beneath theseAPCs would theoretically flow towards the closest marsh, and ultimatelyLake Erie.

The Discharge Pipe (72-inch concrete pipe) represents a linear APC, whichis generally aligned parallel to the direction of regional groundwater flow.Potential leakage from the Discharge Pipe would likely migrate into theearthen fill surrounding the buried pipe, ultimately migrating towards themarshes south of the Discharge Pipe.


3.5.3 Section View

The CSM includes a representation of potential radiological APCs in thecontext of the vertical hydrogeologic environment. The path of the crosssection (shown in Figure 5) begins west of the Power Block and isorientated eastward through the Power Block. To highlight the elevationchanges between the Power Block, intake canal, marshes and Lake Erie,gaps in the section were included through stretches of continuous sectionsof the swamp. The cross-section was developed using a 2:1 verticalexaggeration, as the vertical scale (1 inch equals 20 feet) is two timessmaller than the horizontal scale (1 inch equals 40 feet). Figure 5 showsthe base elevation of the excavation area, station buildings, native geologicunits, excavation backfill units, existing monitoring wells, wave protectiondikes and DBNPS infrastructure.

The cross-section indicates that the excavation for the Power Blockextends into the Dolomite Bedrock. The elevations of groundwater in theDolomite Bedrock and Lake Erie are higher than the base elevation ofbuildings within the Power Block.

Although DBNPS construction reports indicate that the Glaciolacustrineand Till units are not water bearing, ERM/ Dade Moeller's experienceindicates that till can support groundwater flow and transport ofcontaminants. This characterization has been observed at other siteswhere the migration of tritium in a till aquifer occurred in a boulder layerlocated within a till. Boulder layers represent discrete intervals of higherhydraulic conductivity and porosity over bulk sediments within a till. Anadditional migration pathway for contaminants in till includes fractureswithin the till, which could develop in response to the rebound of landsurface following the retreat of glacial ice that was responsible fordeposition of the Glaciolacustrine deposit.

Analysis of DBNPS excavation depths and building components (Figure5) yields important considerations regarding the potential for leakage ofradionuclides to the structural fill, Till and Dolomite Bedrock. Theseobservations are summarized as follows:

0 Vertical migration of tritiated water to the structural backfill is possiblewhere radiological sources within the Power Block immediatelyoverlie the structural fill. (Figure 5). For example, leakage of tritiatedwater from the Borated Water Storage Tank and CondensateDemineralizer Backwash Receiver Tank or 3-inch Radwaste DischargeLine (not shown in Figure 5) could release radionuclides to thestructural fill. Once in the structural fill, migration from these sources


would be anticipated towards the east, or potentially downward to theDolomite Bedrock.

* Vertical leakage from the 72-inch Discharge Pipe could result inleakage to the earthen backfill surrounding the concrete pipe. Arelease through the Discharge Pipe would be anticipated to ultimatelymigrate in a southeast direction towards the marsh adjacent to theDischarge Pipe.

" Vertical leakage directly to the Dolomite Bedrock is possible throughreleases at sumps and floor drains within the Containment Building,Auxiliary Building and Turbine Building that are constructed directlyover Dolomite Bedrock. Migration from these potential sources wouldbe anticipated to be outward from the Power Block, and possibly todeeper bedrock. Once in the Dolomite Bedrock and outside theinfluence of the Power Block and grout curtains, tritium would likelymigrate to the east towards Lake Erie, corresponding with thedirection of regional groundwater flow.

3.5.4 Summary

Potential releases of tritium from DBNPS are anticipated to migratevertically or laterally within the fill (structural and earthen),Glaciolacustrine Deposit, Till and Dolomite Bedrock. Migration withinthese units would be towards marshes that are located between the PowerBlock and Lake Erie, with Lake Erie representing the regionalgroundwater discharge point. Initial evaluation of site systems, geologyand hydrogeology suggest a low potential for releases to groundwater atthe site to adversely impact drinking water receptors given the likely up-gradient, distant location of potential receptors and the most probablemigration pathway being from the site to marshes and Lake Erie. Once inmarshes and/or Lake Erie, the impacts would immediately be diluted dueto the volume and concentration of naturally-occurring tritium in the lake.


4.0 RECOMMENDATIONS

Based on ERM and Dade Moeller's review of the available site data, thefollowing recommendations are provided to support development of aneffective groundwater monitoring program at the DBNPS:

1. Inventory and Monitor the Existing Well Network

DBNPS has an extensive network of monitoring wells outside thePower Block. The wells, installed during excavation of Unit #1 andplanned Units #2 and #3, provide a starting point for the developmentof a groundwater monitoring well network at the site. The existingmonitoring wells should be inspected to evaluate their currentcondition and suitability for use as groundwater monitoring wells.Wells that are deemed suitable should be surveyed and thenincorporated into the groundwater monitoring program. This workshould be conducted prior to installation of additional monitoringwells to further guide the selection and placement of new wells. Thisevaluation should also focus on the extent to which existing wells mayact as preferential pathways for contaminant migration to identifythose wells that should be properly abandoned.

2. Develop an Integrated Monitoring Program

DBNPS should consider developing a program to collect groundwaterlevel measurements from suitable existing wells. The program shouldinclude monitoring on a quarterly basis, to evaluate the seasonaleffects on groundwater flow elevations and directions. In addition, theprogram should incorporate measurements of surface water in nearbymarshes to fully integrate the groundwater and surface waterinteractions at DBNPS. The sampling of the surface water within eachmarsh, on-site ponds, and Lake Erie and gauging surface water andgroundwater elevations simultaneously should also be incorporatedinto the sampling program.

In order to evaluate the potential contribution of gaseous emissionwashout on tritium levels, DBNPS should monitor tritium inatmospheric water vapor and/or precipitation at indicator and controllocations. This data should be combined with the monitoring programto develop and integrate knowledge of tritium discharges togroundwater.


3. Install and Sample Monitoring Wells

The following table summarizes recommended locations and targetunits for potential installation of new groundwater monitoring wellsfor the DBNPS site. The wells are shown in Figure 4. The number ofthese locations selected for installation should be re-evaluated basedon the inventory of existing wells and sampling and gauging resultsobtained and the results of additional site source evaluation.Monitoring locations may need to be added or deleted as results areobtained and the CSM is refined.

Well Location Construction and Rationale

A West of Well TripletPower Block " Shallow - monitor background conditions

" Mid - monitor background conditions

* Deep - monitor background conditions

B West of Well TripletPower Block " Shallow - monitor Power Block

" Mid - monitor Power Block

" Deep - monitor Power Block

C North of Well TripletPower Block " Shallow - monitor Power Block

* Mid - monitor Power Block


D Northeast of Well TripletPower Block " Shallow - monitor Power Block

* Mid - monitor Power Block


E East of Well TripletPower Block " Shallow - monitor Condensate Demineralizer Tank

Discharge Line, Radwaste Discharge Line and PowerBlock

" Mid - monitor Condensate Demineralizer Tank DischargeLine, Radwaste Discharge Line and Power Block


18 FIRSTENERGY - DAVIS-BESSE 55194 1/16/07ERM/DADE MOELLER 18 F1IRSTENERGY - DAV&SBESSE 55194 1/16/07

Well Location Construction and Rationale

F South of Well TripletPower Block P Shallow - monitor Low Level Radwaste Storage Area and

Power Block

" Mid - monitor Low Level Radwaste Storage Area andPower Block


G Northeast of Well TripletPower Block

" Shallow - monitor Power Block



H Southeast of Well TripletPower Block P Shallow - monitor Power Block


* Deep - monitor Power BlockNote: Shallow = Fill (structural or earthen), Glaciolacustrine or Till

Mid = Shallow Dolomite BedrockDeep = Deep Dolomite Bedrock

The methodology for installing and constructing the monitoring wellsshould incorporate the latest environmental drilling technologies toallow for the collection of representative groundwater samples and toprevent the drilling activities from exacerbating any potential impactsto groundwater. For example, drilling successively deeper into thesubsurface can result in advertent communication of shallow and deepaquifers if precautions are not incorporated into the drilling program.This cross-communication is also referred to as cross-contamination inthe event that shallow contamination is brought to deeper depths thatwere previously not impacted. There are a variety of drillingtechniques that could be utilized at the site that should be evaluatedwith regard to time, cost, integrity of well, ability to collect soil andgroundwater samples during installation, minimization of workerexposure and generation of wastes requiring management anddisposal.

In addition to the monitoring wells, the following temporary grabgroundwater samples are recommended to allow field screening ofgroundwater quality at each location:


TemporaryGrabGroundwater Description and Rationale

Location

East of Outfall 3 One shallow grab sample - monitor Outfall 3

South of Eight Shallow samples - monitor 72-inch ConcreteDischarge Line Discharge Line (grab samples collected every 100 feet

along the length of the Discharge Line)

East of North One shallow sample - monitor North Settling BasinSettling Basin

East of South One shallow sample - monitor South Settling BasinSettling Basin

East of Sanitary One shallow sample - monitor Sanitary LagoonLagoon

East of Current One shallow sample - monitor the Current SewageSewage Treatment PlantTreatment Plant

Training Center Two shallow samples - monitor the Training Center PondPond

Temporary grab groundwater samples are collected using a discreteinterval drive point sampler to allow collection of shallowgroundwater samples for laboratory analysis. The technology is veryeffective as a screening tool for evaluating groundwater quality inareas of low likelihood of groundwater impact and over a larger area(i.e. approximately 800 feet of Discharge Line). The screening datafrom the grab groundwater samples is used to focus laterinvestigations, including the installation of permanent monitoringwells.

During the field component of the groundwater investigation

program, the intervals for monitoring well screens and depths for grab

samples should be based on field observations and testing conducted

during boring advancement. Since geologic deposits are inherently

heterogeneous, the depth of well screens and sample depth should

correspond with the most permeable intervals, rather than a

predetermined depth. The ability to adapt and modify screen settings

and target depths based on field data will allow for a representative

well network for monitoring potential inadvertent releases.

4. Develop a Quality Assurance Project Plan

All the components of a groundwater monitoring program should beaddressed in a Quality Assurance Project Plan (QAPP) specifically

ERM/ DADE MOELLER 20 FIRSTENERGY- DAVIS-BESSE 55194 1/16/07

designed to address potential groundwater issues at the site. DBNPSmonitoring programs (i.e., REMP and tritium tracking) should haveconsistent Lower Levels of Detection (LLDs) and reporting criteria.

Consideration should be given to the required sensitivity for tritiummonitoring in groundwater. DBNPS monitors to 330 pCi/L, and theState of Ohio monitors to 300 pCi/L. Looking forward to publiccommunication of the new groundwater monitoring data, it would beprudent to coordinate the sensitivities of the measurements so as tomake data comparable among the stakeholders. It may also beprudent to report some data in dual units (i.e., ptCi/ml and pCi/L) tofacilitate comparisons and eliminate confusion.

5. Define Internal and External Reporting Requirements

As data are collected, it is important that the thresholds andtimeframes for internal and external reporting purposes be clearlydefined. A written summary of the internal and external reportingrequirements, including NRC, NEI and State of Ohio criteria, for allparameters that will be monitored should be developed to support theimplementation of the groundwater monitoring program. Thereporting requirements should be applied consistently acrossFirstEnergy's three nuclear power plants.

6. Develop a Communication Plan

Stakeholder communication is a key component of the NEI initiative.Therefore, a communication plan should be developed to identify anddefine the stakeholders related to the tritium in groundwater issue andto determine who is responsible for the various types ofcommunication and how the results will be communicated. As withthe reporting requirements, the communication plan should bedeveloped consistently across FirstEnergy's three nuclear powerplants.

ERM/DADE MOELLER FIRSTENERGY - DAVIS-BESSE 55194 1/16/07ERM/DADE MOELLER 21 FIRSTENERGY - DAVIS- BESSE 55194 1/16/07

Tables

Table 1Areas of Potential ConcernDavis-Besse Nuclear Power StationOak Harbor, OH

Category Area of Potential ConcernRadiological - Power Block Containment Building

Auxiliary BuildingMiscellaneous Waste Drain TankSpent Fuel PoolCask Pit

Turbine BuildingEast and West Condenser PitsSumpsCondensate Demineralizer Tanks

Fuel Transfer CanalCirculating Water Pump HouseBorated Water Storage TankNitrogen and Hydrogen Supply Piping

Radiologial - Outside Power Block Condensate Demineralizer Tank Discharge LineLiquid Radwaste Discharge LineCollection BoxCollection Box Discharge PipeSouth Settling Basin (Settling Basin No. 1)North Settling Basin (Settline Basin No. 2)Low-Level Radwaste Storage BuildingDry Fuel Storage AreaSecondary Water Demineralized Water Storage TankFire Water Storage TankSanitary Wastewater PlantsStormwater Management System

NPDES Outfall 002 (Training Center Pond)NPDES Outfall 601 (Wastewater Treatment Plant)Service Building No. 4

Non-Radiological Diesel Storage TanksService Building No. 4 (Gasoline Tank)Transformer Oil Collection TankChemical Waste Storage AreaMachine Shops

0

Tables

0

0

Table 1Areas of Potential ConcernDavis-Besse Nuclear Power StationOak Harbor, OH

Category Area of Potential ConcernRadiological - Power Block Containment Building

Auxiliary BuildingMiscellaneous Waste Drain TankSpent Fuel PoolCask Pit

Turbine BuildingEast and West Condenser PitsSumpsCondensate Demineralizer Tanks

Fuel Transfer CanalCirculating Water Pump HouseBorated Water Storage TankNitrogen and Hydrogen Supply Piping

Radiologial - Outside Power Block Condensate Demineralizer Tank Discharge LineLiquid Radwaste Discharge LineCollection BoxCollection Box Discharge PipeSouth Settling Basin (Settling Basin No. 1)North Settling Basin (Settline Basin No. 2)Low-Level Radwaste Storage BuildingDry Fuel Storage AreaSecondary Water Demineralized Water Storage TankFire Water Storage Tank

Sanitary Wastewater PlantsStormwater Management System

NPDES Outfall 002 (Training Center Pond)NPDES Outfall 601 (Wastewater Treatment Plant)Service Building No. 4

Non-Radiological Diesel Storage TanksService Building No. 4 (Gasoline Tank)Transformer Oil Collection TankChemical Waste Storage Area,Machine Shops

Figures

0

Legend

Reside ntiallCom mercia I Wl11s

® Unknonm

! Domestic

() PubicWater Supply(non potable)

Aea wth Private Wels

Protected Area

SSite Boundary

Lneaments

SOURCE: USGS Topographic Quadrangles(o41083e2, o41083el)

1:24,000

0 2,000 4,000

,m m IFeet

Figure 1 - Site Locus Map withHydrogeologic Features

Davis-Besse Nucear Pover Station, Oak Harbor, OHwERM

I

Emergency Diesel Fuel-il T.ank

Se-ndary DemineralizedWae t aeTank

Condensate DemineralzeJTan k Dischargle Line

Legend

71i Radiological Area of Potential Concern

Non-Radiological Area of Potential Concern

-Cross-section Ihe

Low Leve I RadWaste Storage Buildw c

Collection BoxDi.,rhwrae Pinee

1:3,000bandc

0 125 250 500 750- ý Feet

Tra ning Center PondNPDES Outfall002

i

C

C

Figure 2 - Areas of Potential Concern atDavis-Besse Nuclear Power StationDavis-Besse Nuclear Poer Statbn, Oak Harbor, 0

hR.\m

0 0

0

Legend

Limits of Grout Curtain

4& Existing Monitoring Well Couplet(Shallow and Deep Bedrock)

1:2,400200 100 0 200

F= !Feet

Figure 3 - Existing Monitoring Welsand Grout Curtain

Davis-Besse Nuclear Power Station,Oak Harbor, OH

i~.RMm I

.0 "AlLegend

SRadiological Area of Potential Concern

Non-Radiological Area of Potential Concern


A "'Proposed Moni toring Wei0 Proposed Grab Groundwater Sample

Regional Groundwater Flow Directionin Dolomite Bedrock

, Localized Groundwater Flow DirectionAdjacent to Power Block

1:3,000

250 125 0 250

I • Feet

r ~Figure 4 - Conceptual Site Model andProposed Monitoring Locations

Davis-Besse Ntclear Power Station, Oak Harbor, OH

* 0

West East

... - ---- -, :-- ----------

LegendI G.nd fldWote evatio

(Dolo. slle Bedrck)

ExIsthig •Porinhg WPotontol Mi• atod ofTreted Woter

Fbw o.t Groud WmletP~psedMoohtodngWd

. P p o*ee G rab G , = n d W a tb r S a rff l

1,W 0 fte Figure 5 - Conceptual Site Model - Section View0e •,,IEsggteon 2Davis-Besse Nuclear Power Station, Oak Harbor, OH ERM N

Appendix ALetter from Davis-BesseEngineering

Response to the prescribed questions and to identify those Davis-Bessesystems/components which are vulnerable to initiating an unmonitored release to theenvironment:

Question #1 - For those contaminated systems within structures, explain the design andoperation of the sump/liquid waste system. This description should provide reasonableassurance that any system leakage will be properly contained and processed prior to itsrelease to the environment.

Response #1Sumps in the Auxiliary building collect liquid from floor and equipment drains in roomscontaining contaminated systems. All sumps discharge to the miscellaneous waste draintank (MWDT). There are several areas with the auxiliary building that contain floordrains which discharge directly to the MWDT without going into a sump. These roomsin the auxiliary building contain systems that interface directly with the reactor coolantsystem. The systems are High Pressure Injection, Low Pressure Injection/Decay Heat,Decay Heat Coolers, Containment Spray, and the Makeup System. Leakage from any ofthese systems will therefore be contained in the MWDT. Liquids collected there areprocessed as described below.

The detergent waste drain tank (DWDT) is also located within contaminated areas. Itreceives influent from the laundry facility and various other floor drains in the auxiliarybuilding. This tank discharges to the miscellaneous waste monitor tank and is processedas described below.

A past primary to secondary coolant leak has cause the station to conservatively declareall feedwater, condensate, and auxiliary steam systems in the turbine building aspotentially contaminated. Therefore, all rooms containing these systems are consideredpotential sources of contaminated water leakage into the turbine building sumps anddrains system.

The Component Cooling Water (CCW) System Heat Exchangers are cooled by theService Water (SW) System. Due to past leakage from the Letdown Coolers, the CCWsystem is considered to be contaminated. If a leak were to develop in the CCW HeatExchangers, the contamination could reach Lake Erie through the discharge from theCollection Box. The Collection Box discharge line contains a radiation monitor. Anyleakage from the CCW System would be identified by loss of inventory in the CCWSurge Tank.

Question #2 - Describe the normal liquid effluent pathway, including the downstreamdischarge pathway such as circulating water or river water.

Response #2

Question 2.a - Where does the liquid waste discharge to?

Response 2.a - Sumps in located throughout the plant collect drainage from equipmentand floor drains and discharge to one of several places:

(1) Turbine Building East and West Condenser Pits - These sumps are routed to thesettling basins. The settling basins are sampled and are released to the collectionbox outfall to Lake Erie. Weekly samples are taken using procedure DB-CN-04039 to insure radioactivity is within applicable limits including a tritiumanalysis. A list of potential tritium sources is attached.

(2) Turbine Building - Sumps and drain risers discharge to the storm sewer systemwhich goes to the training center pond, a marsh pond, and ultimately to theTouissaint River. The inlet to the training center pond and the marsh pond aresampled weekly for tritium and other radioactivity. A list of potential tritiumsources is attached.

(3) Auxiliary building - Sumps that are in contaminated/radioactive areas dischargeto the miscellaneous waste drain tank (MWDT). This tank is processed to themiscellaneous waste monitor tank (MWMT) through a demineralizing skid. It isthen recirculated in the MWMT and sampled in accordance with 1OCFR20, theOffsite Dose Calculation Manual, and Operations Procedure DB-OP-03011.When it is determined acceptable, the liquid is discharged to the collection boxoutfall to Lake Erie. A composite sample from each batch release is collected inaccordance with DB-OP--0301 1, Radioactive Liquid Batch Release, Step 4.18.3for monthly tritium analysis as required by DB-CN-03012, Liquid Releases,Monthly Monitoring Analysis. The monthly composite is analyzed in accordancewith DB-CH-0 1804, Tritium Determination, to achieve a Lower Limit ofDetection of I x 10-5 uCi/ml. The tritium activity from the composite sample isentered into the RETSCode program which calculates the tritium released foreach batch release for the month.

Question 2.b -Does the liquid waste discharge line traverse any non-license ownedareas?

Response 2.b - The liquid waste discharge line is contained on the licensee ownedproperties. Reference drawings: C-46, C-49 and C-52

Question 2.c -Are there any vacuum breakers or relief valves on the discharge pipingand are they monitored for potential leakage?

Response 2.c - There are no vacuum breakers or relief valves on the discharge piping.

Question # 3 - Provide a description of the spent fuel pool, including liner constructionand leakage monitoring. Identify any vulnerability to an unmonitored release.

Response # 3 -A description of the spent fuel pool, including liner construction and leakage monitoringis as follows:

The SFP stores irradiated fuel assemblies under water. The spent fuel racks are sized tostore 1624 spent fuel assemblies. The SFP is connected to the Fuel Transfer Canal via an80001b gate and gateway. An identical gate arrangement exists between the SFP and theCask pit. The Fuel Transfer Canal is connected to the refueling canal via two 30-inch-outer diameter fuel transfer tubes. The SFP is flooded to 23 feet of water over the top ofthe irradiated fuel assemblies seated in the storage racks (pool surface Elevation 601' 6").The spent fuel pool, fuel transfer pit, cask pit, liners, and all supporting structures aredesigned for seismic loads.

The 5' thick south wall of the Spent Fuel Pool (SFP) and Cask Pit (CP) form the outsidewall of the Auxiliary Building. Much of the flooded portion of the SFP and CP are belowgrade and not visible. There is a waterproof membrane on this outside wall and under thebuilding foundation (ref. DWG C-202 and C-230) to keep outside groundwater fromleaching into the Auxiliary Building. This membrane would also likely act to keep anypotential fuel pool leakage from escaping into the soil.

The fuel pool, fuel transfer pit, and cask pit are lined with stainless steel and equippedwith a leak chase system and tell-tale drain connections for leakage detection. ProcedureDB-SP-04400, Spent Fuel Pool, Fuel Transfer Pit, and Cask Pit Leak Detection SystemTest, is performed monthly to quantify a leak rate from the 21 leak chases. Leakage isdetected during this monthly test from several of the leak chases. The highest leak rate isapproximately 1.5 ml/min.

Tritium concentration in the SFP is 0.0552 uCi/mL based on the latest sample. Agroundwater sample was obtained from an existing monitoring well located near thesouth wall of the SFP in 2004. The test results using site equipment were inconclusive asthe values measured were at the minimum detectable levels of the site's equipment. Aportion of this sample was sent off-site and tested by Environmental Inc. The values were667 +/- 112 pCi/L and 728 +/- 104 pCi/L. These values are substantially below thosemeasured at other plants with known fuel pool leakage. A PM activity was created toperform sampling from this monitoring well every 5 years.

Question # 4 - Identify those contaminated tanks, below above and below grade, locatedoutside of plant structures (i.e., outside of plant drainage/sump system). Identify the run-off pathway to the environment.

Response # 4 - The following tanks are contaminated tanks, located outside of plantstructures with the run-off pathways to the environment identified:

The Borated Water Storage Tank (BWST) is a contaminated tank above grade andlocated outside of plant structures. The tank base is surrounded by gravel. Tankoverflow is routed to the Miscellaneous Waste Drain Tank. Tank leakage would be ontoto the gravel and into the ground surrounding the tank. Some tank leakage may becollected into the storm sewer system and directed to the Training Center pond and,ultimately, into the Touissaint River. Tritium concentration in the BWST is 0.08 uCi/mLbased on the latest sample.

The Demineralized Water Storage Tank and Fire Water Storage Tank are above grade andlocated outside of plant structures. Both are provided with steam heaters to maintaintemperature during winter months. The steam provided to these heaters is contaminated.If a leak were to develop in the heater, the water in the tank could become contaminated.Tank overflow or leakage would be onto to the pavement or gravel and into the groundsurrounding the tank. Some tank leakage may be collected into the storm sewer systemand directed to the Training Center pond and, ultimately, into the Touissaint River.

Several small pipes connect the nitrogen and hydrogen supply systems to variouscontaminated systems and components (P&ID M-0 19 and 044). The nitrogen andhydrogen supply tanks are located outside of plant structures. Back leakage throughvalves could result in contaminated water entering these pipes. Leakage of thiscontaminated water from these pipes would be onto the gravel or into the ground. Somepipe leakage may be collected into the storm sewer system and directed to the TrainingCenter pond and, ultimately, into the Touissaint River.

ERM has over 100 offices

Across the following

countries worldwide

. ArgentinaAustraliaAzerbaijanBelgiumBrazilCanadaChileChinaFranceGermanyHong KongHungaryIndiaIndonesiaIrelandItalyJapanKazakhstanKorea

MalaysiaMexicoThe NetherlandsPeruPolandPortugalPuerto RicoRussiaSingaporeSouth AfricaSpainSwedenTaiwanThailandUKUSVietnamVenezuela

ERM's Boston Office

399 Boylston Street, 6th FloorBoston, MA 02116(617) 646-7800(617) 267-6447 (fax)

ERMERM consulting services worldwide www.erm.com

FirstEnergy

Groundwater Monitoring WellInstallation & Monitoring ReportDavis-Besse Nuclear Power StationOak Harbor, OhioFirstEnergy Nuclear Operating Company

18 March 2008

www.erm.com

ERMDelivering sustainable solutions in a more competitive world

I FINA REPOR

FirstEnergy Nuclear Operating Company

Groundwater Monitoring WellInstallation & Monitoring ReportDavis-Besse Nuclear Power Station

Oak Harbor, Ohio

18 March 2008

ERM Reference 0065992.2

Gregg Demers, P.E., LSPPrincipal-in-Charge

~ ~1 k~$(~~

Matthew Daly, P.G.Project Manager

Environmental Resources Management399 Boylston Street, 6th FloorBoston, Massachusetts 02116

T: (617) 646-7800

F: (617) 267-6447

TABLE OF CONTENTS

EXECUTIVE SUMMARY 1

1.0 INTRODUCTION 1

1.1 BACKGROUND 11.1.1 Site History 11.1.2 Prior Findings 2

1.2 PURPOSE & SCOPE 3

1.3 REPORT ORGANIZATION 4

2.0 METHODOLOGY 5

2.1 INVENTORY & MONITORING OF HISTORIC WELLS 52.1.1 Well Inventory & Gauging 52.1.2 June 2007 Groundwater Monitoring Event 5

2.2 JULY/AUGUST 2007 GROUNDWATER MONITORING EVENT 7

2.3 WELL INSTALLATION 82.3.1 Overview 82.3.2 Advancement of Soil Borings 92.3.3 Monitoring Well Construction 92.3.4 Monitoring Well Development 10

2.4 SEPTEMBER/OCTOBER 2007 GROUNDWATER MONITORINGACTIVITIES 10

2.5 SURVEYING 12

2.6 DATA USABILITY ASSESSMENT 13

3.0 RESULTS 14

3.1 SITE GEOLOGY 14

3.2 HISTORIC WELL INVENTORY 15

ERM/ DADE MOELLER i FIRSTENERGY - DAVIS-BESSE 65992.2 18 MARCH 08

3.3 NEW MONITORING WELLS

3.4 GROUNDWATER FLOW

3.5 GROUNDWATER QUALITY3.5.1 Groundwater Field Parameters3.5.2 Analytical Results3.5.3 Tritium Source Assessment

UPDATED CONCEPTUAL SITE MODEL

KEY FINDINGS

15 0

16

19192022

24

25

4.0

5.0

ERM/DADE MOELLER ii FIRSTENERGY - DAVIS-REESE 65992.2 18MARCH08ERM/DADE MOELLER ii FIRSTENERGY - DAVIS-BESSE 65992.2 18 MARCH 08

LIST OF TABLES

TABLE 1 MONITORING WELL LOCATION AND CONSTRUCTION SUMMARY

TABLE 2 SUMMARY OF SAMPLING PROGRAM - JUNE, JULY/AUGUST ANDSEPTEMBER/OCTOBER 2007

TABLE 3 SUMMARY OF ANALYTICAL PROGRAM - JUNE, JULY/AUGUST,AND SEPTEMBER/OCTOBER 2007

TABLE 4 SUMMARY OF GROUNDWATER GAUGING DATA

TABLE 5 SUMMARY OF GROUNDWATER FIELD PARAMETERS

TABLE 6 SUMMARY OF GROUNDWATER ANALYTICAL RESULTS

ERM/DADE MOELLER oo° FIRSTENERGY - DAVIS-BESSE 65992-2 18 MARCH 08

LIST OF FIGURES

FIGURE 1 SITE LOCUS MAP

FIGURE 2

FIGURE 3

FIGURE 4

FIGURE 5

FIGURE 6

FIGURE 7

FIGURE 8

SITE LAYOUT

GROUNDWATER ELEVATIONSTILL UNIT- SEPTEMBER/OCTOBER 2007

GROUNDWATER ELEVATIONSUPPER DOLOMITE - SEPTEMBER/OCTOBER 2007

GROUNDWATER ELEVATIONSLOWER DOLOMITE - SEPTEMBER/OCTOBER 2007

GROUNDWATER SAMPLE ANALYTICAL RESULTSJUNE TO AUGUST 2007

GROUNDWATER SAMPLE ANALYTICAL RESULTSSEPTEMBER/OCTOBER 2007

CROSS-SECTION SHOWING GROUNDWATER ELEVATIONS ANDSAMPLE ANALYTICAL RESULTS

ERM/ DADE MOELLER iv FIRSTENERGY - DAVIS-BESSE 65992.2 18 MARCH 08

LIST OF APPENDICES

APPENDIX A BORING LOGS

APPENDIX B DATA ASSESSMENT - JUNE & JULY/AUGUST 2007MONITORING EVENTS

APPENDIX C DATA ASSESSMENT - SEPTEMBER/OCTOBER 2007MONITORING EVENT

APPENDIX D LABORATORY ANALYTICAL REPORTS

V FIRSTENERGY - DAVIS-BESSE 659922 18 MARCH 08ERM/DADE MOELLER V FIRSTENERGY - DAVIS-BESSE 65992 2 18 MARCH 08

LIST OF ACRONYMS

APC radiological area of potential concernASL above sea levelCSM conceptual site model0C degrees CelsiusDBNPS Davis-Besse Nuclear Power StationDO dissolved oxygenEPA United States Environmental Protection AgencyERM Environmental Resources ManagementFD field duplicateFENOC FirstEnergy Nuclear Operating CompanyFSP field sampling planNEI Nuclear Energy InstituteMDC minimum detectable concentrationNTU nephelometric turbidity unitORP oxidation-reduction potentialPID photoionization detectorpCi/L picoCuries per literPVC polyvinyl chlorideQA/QC quality assurance/quality controlR remREMP Radiological Environmental Monitoring Programus/cm microsiemens per centimeter

ERM/DADE MOELLER vi FIRSTENERGY - DAViS-BESSE 65992.2 18MARCH08ERM/ DADE MOELLER vi FIRSTENERGY - DAViS-BESSE 65992.2 18 MARCH 08

EXECUTIVE SUMMARY

On behalf of FirstEnergy Nuclear Operating Company (FENOC),Environmental Resources Management (ERM) has prepared thisGroundwater Monitoring Well Installation and Monitoring Report todocument the development of a groundwater monitoring program at theDavis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio.The purpose of the groundwater program is to assess whether there havebeen any inadvertent radiological releases from the Power Block that mayhave impacted site groundwater or have the potential to migrate towardLake Erie or any other human or environmental receptor.

Activities completed included an inventory and assessment of existing sitewells, the installation of five groundwater monitoring well triplets and awater table well (i.e., 16 new wells), the preparation of groundwater fieldsampling plans, the sampling of groundwater monitoring wells (threeevents), and the evaluation of groundwater monitoring results in thecontext of the hydrogeologic regime.

The key findings from the groundwater investigation include thefollowing:

Geology

* The surficial geology beneath the DBNPS consists ofGlaciolacustrine and Till units. The Glaciolacustrine unit ischaracterized as cohesive, brown silt with some sand and clay. TheTill is characterized as brown to dark-gray, silty clay.

* Beneath the Till is Dolomite Bedrock, subdivided into a LaminatedDolomite and a Massive Dolomite. The Laminated Dolomite,which is encountered above and below the Massive Dolomite,contains thin layers of interbedded dolomite, gypsum, anhydriteand shale. The Massive Dolomite is approximately 10 feet thick,hard, finely grained, and located approximately 10 feet below thetop of the Dolomite.

Historic Well Inventory

A total of 54 wells (27 couplets) were located and inspected duringthe well inventory and 24 wells (12 couplets) could not be found.Each well couplet consists of a shallow and deep well within the

ERM/DADE MOELLER ES-1 FIRSTENERGY - DAV&BESSE 65992.2 18 MAR 08

Dolomite Bedrock. The shallow bedrock well is screened withinthe Upper Dolomite and the deeper bedrock well is screened in theLower Dolomite. The Massive Dolomite unit separates wellsscreened within the Upper and Lower Dolomite.

The historic wells, by themselves, were not sufficient to create aneffective groundwater monitoring program at DBNPS because theydid not provide adequate lateral and vertical coverage. In addition,due to the age of the wells, their construction quality andsubsurface conditions are not known.

Groundwoater Flow

" The ability to develop groundwater elevation contours and flowpatterns is complicated by several factors, including the presence ofa grout curtain, the flow of groundwater within discrete fracturesin bedrock, the large area of excavated bedrock beneath the PowerBlock and the high degree of mineralized groundwater andassociated low yield observed in the new Lower Dolomite wells.An additional uncertainty is the usability of historic elevationsurvey data that were used to calculate groundwater elevationsfrom the historic wells.

" Based on the distribution of groundwater elevations, groundwaterflow in the Till, Upper Dolomite and Lower Dolomite units is fromwest to east across the site.

* The ultimate discharge point for groundwater in the Till, UpperDolomite and Lower Dolomite is the marshes and/or Lake Erieeast of the Power Block.

Groundwater Quality

" Strong hydrogen sulfide odors were noted in site groundwater,particularly new Lower Dolomite wells MW-101C, MW-102C, MW-103C and MW-104C located east of the Power Block. The hydrogensulfide is believed to be naturally occurring and caused by theweathering of gypsum and anhydrite minerals. Groundwater fieldparameters at these wells are characterized by high specificconductance, low ORP and high turbidity water.

" High hydrogen sulfide gas levels at wells MW-101C, MW-102C,MW-103C and MW-104C may be inadvertently trapped due to theuse of expansion plugs at these wells. The sulfide gas may limit the

ERM/DADE MOELLER ES-2 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

ability for the well screen to communicate with the LowerDolomite. Future modifications to the expansion plugs to allowventing of the sulfide gas will be evaluated in effort to obtain moreaccurate groundwater elevation data from these wells.

Reported concentrations of tritium in groundwater between 178pCi/L and 348 pCi/L represent statistically insignificant activity atthe 95% confidence level and are considered representative of localbackground conditions. Factors influencing local backgroundcondition may include the historic atmospheric bomb testingprogram, cosmic ray interactions in the earth's atmosphere andlocalized washout from continuous and batch gaseous releasesfrom DPNBS. Reported values above 348 pCi/L representconcentrations that are statistically greater than local backgroundconditions.

" Tritium concentrations above the 348 pCi/L background valuewere located primarily in monitoring wells east of the Power Block.

* Tritium concentrations in the wells screened in the Till ranged fromless than the minimum detectable concentration (MDC; <193pCi/L) to 1,832 pCi/L. The highest concentrations were detecteddown-gradient (northeast) of the Power Block, including MW-102A(387 pCi/L), MW-103A (495 pCi/L), and MW-105A (1,832 pCi/L).

" Tritium concentrations in the wells screened in the Upper Dolomiteranged from less than the MDC (<193 pCi/L) to 7,535 pCi/L. Thehighest concentrations were detected down-gradient (east) of thePower Block, including MW-31S, MW-32S, MW-33S, MW-34S,MW-37S and MW-30S. Two detections above local backgroundconditions were detected at well MW-30S (1,307 pCi/L) and wellMW-37S (2,961 pCi/L), located north of the Power Block.

* Tritium concentrations in the wells screened in the Lower Dolomiteranged from less than the MDC (<193 pCi/L) to 3,271 pCi/L. Thehighest detections were located east/southeast of the Power Block,including wells MW-33D, MW-34D and MW-12D.

* No gamma emitting radionuclides were detected above MDC inany of the groundwater samples collected during the June,July/August 2007 or the September/October 2007 monitoringevents.

ERM/DADE MOELLER ES -3 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

* Tritium concentrations in groundwater during the June, July andAugust and September/October 2007 monitoring events werebelow the Environmental Protection Agency's drinking waterstandard of 20,000 pCi/L.

Updated CSM

" Groundwater flow within the Till, Upper Dolomite and LowerDolomite units at DBNPS is generally from west to east towardLake Erie with groundwater discharge to the marshes and/or LakeErie.

" Potential inadvertent releases from within the Power Block,including the Spent Fuel Pool, would migrate vertically downthrough the unsaturated zone to the water table. Potential releasesfrom structures below ground could release tritium directly to theUpper or Lower Dolomite unit.

* Elevated detections in Upper Dolomite wells MW-31S and MW-32Sare located on reported southwest to northeast fractures thatproject back to the Power Block.

" Tritium in groundwater will ultimately migrate into Lake Erie,where the concentrations will be diluted due to the volume ofgroundwater discharge versus the volume of water in the lake.

" Historic monitoring of Lake Erie by DBNPS indicates that therehave been very few detections of tritium above local backgroundconditions, and they are not likely to have been caused bygroundwater contributions.

Based upon the above findings, FirstEnergy should further evaluate thehydrogeology and influence of plant features on site groundwater flow.In addition, tritium detections above local background conditions shouldbe evaluated to establish a reliable monitoring well network for long-termmonitoring.

ERM/DADE MOELLER ES-4 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

1.0 INTRODUCTION

On behalf of FirstEnergy Nuclear Operating Company (FENOC),Environmental Resources Management (ERM) has prepared thisGroundwater Monitoring Well Installation and Monitoring Report todocument the development of a groundwater monitoring program at theDavis-Besse Nuclear Power Station (DBNPS) located in Oak Harbor, Ohio(Figure 1).

The groundwater monitoring program was implemented to comply withthe Nuclear Energy Institute's (NEI) Groundwater Protection Initiative,dated August 2007. The Groundwater Protection Initiative was developedto enhance the detection, management and communication of inadvertentradiological releases to groundwater at nuclear power plants. As part ofthe initiative, nuclear power plants are expected to:

"Put in place a company/site-specific action plan(s) to help assuretimely detection and effective response to situations involvinginadvertent radiological releases in groundwater to preventmigration of licensed radioactive material off-site and quantifyimpacts on decommissioning." (NEI, May 2006).

As a first step toward the completion of its action plan, FENOC hiredERM and Dade Moeller & Associates (Dade Moeller) in 2006 to conduct anevaluation of potential radiological sources and groundwater flow atDBNPS. Results of this study were presented in a report titledGroundwater Flow Characteristics Report - Davis-Besse Nuclear Power Station,Oak Harbor, Ohio (ERM, 16 January 2007). The January 2007 reportprovided an overview of DBNPS physical features, plant operatinginfrastructure, potential areas of radiological releases, available tritiumdata and site hydrogeology.

1.1 BACKGROUND

1.1.1 Site History

DBNPS consists of a pressurized water reactor unit that was constructedin the 1970s and went on-line in November 1977. The facility is located ona 954-acre parcel of land that abuts a National Wildlife Refuge and LakeErie. An intake canal, which provides cooling and process water to

ERM/DADE MOELLER 1 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

DBNPS, is located 250 feet east of the Power Block and is hydraulicallyconnected to Lake Erie.

1.1.2 Prior Findings

The Groundwater Flow Characteristics Report presented a Conceptual SiteModel (CSM) describing potential source areas, migration pathways andboth human and environmental receptors at DBNPS. The CSMconsidered site physical features and included the following key findings:

1. Radiological areas of potential concern (APCs) at DBNPS, defined aslocations where a release of radionuclides to groundwater has, orcould occur, include the Power Block, Low Level Radiological WasteStorage Building, Dry Fuel Storage Area, Training Center PondNPDES Outfall 002, Sewage Treatment Plants (abandoned andoperating), NPDES Outfall 001, Sanitary Lagoon, North and SouthSettling Basins, Collection Box Discharge Pipe, Collection Box, LiquidRadwaste Discharge Line, Condensate Demineralized Water StorageTank, Secondary Demineralized Water Storage Tank, Fire StorageTank, and Service Building 4 Outfall (Figure 2).

2. Inadvertent releases from DBNPS have the potential to migratevertically through the fill (structural or earthen), Glaciolacustrine unit,Till unit and Dolomite Bedrock.

3. The basement of buildings within the Power Block extends down intoexcavated portions of the Dolomite Bedrock. Potential inadvertentreleases at depth from within the Power Block could discharge directlyto the Dolomite Bedrock.

4. Regional groundwater flow is from west to east-northeast towards themarshes and Lake Erie. The ultimate discharge sink for groundwateris the marshes and Lake Erie east of the property.

5. Initial evaluation of site systems, geology and hydrogeology suggest alow potential for releases to groundwater at the site to adverselyimpact drinking water receptors given the likely up-gradient, distantlocation of potential receptors and the most probable migrationpathway being from the Power Block to the marshes and Lake Erie.

6. Concentrations of tritium in groundwater would be diluted at themarsh and Lake Erie due to the large volume of surface water relativeto the volume of groundwater discharge.


1.2 PURPOSE & SCOPE

The purpose of this Groundwater Monitoring Well Installation andMonitoring Report is to document the development of a groundwatermonitoring program at DBNPS. The groundwater monitoring program isintended to assess whether any inadvertent release from the Power Blockhas the potential to migrate toward the adjacent marshes and/or LakeErie or any other human or environmental receptor. The program wasimplemented using a phased approach, including the use of historic andnew wells to collect groundwater samples. The intrusive investigationsfollowed an outside-in, top-down approach to address gaps identified inthe CSM.

The following activities were completed during development of thegroundwater monitoring program:

" inventory of historic wells;

" preparation of groundwater field sampling plans;

" screening and confirmatory groundwater sampling of historicmonitoring wells;

• installation of five well triplets and a water table well (i.e., 16 newwells);

" groundwater sampling of comprehensive monitoring well network(three rounds);

* survey of well reference measuring points for determination ofgroundwater elevations;

* evaluating groundwater elevations and flow directions; and

• evaluating groundwater monitoring results in the context of thehydrogeologic regime.

The groundwater monitoring program was developed using a team ofcontractors, including the following:

* BETA Laboratory - FirstEnergy's in-house provider of fieldpersonnel to collect groundwater samples;

ERM/DADE MOELLER 3 FIRSTENERGY - DAVIS-BESSE 65992.2 18MAR08ERM/DADE MOELLER 3 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

* Bowser-Morner, Inc. - Well drilling service provider under contract 5with FirstEnergy to advance, construct and develop groundwatermonitoring wells;

* ERM - FirstEnergy's provider of groundwater and hydrogeologicconsulting services. Dade Moeller provided data evaluation andtechnical support under subcontract to ERM; and

" MidWest Laboratory - Laboratory analytical service providerunder contract to FirstEnergy to analyze groundwater samples.

1.3 REPORT ORGANIZATION

The remainder of this report is divided into the following sections:

* Section 2.0 - Methodology

* Section 3.0 - Results

* Section 4.0 - Updated Conceptual Site Model

* Section 5.0 - Key Findings

* Section 6.0 - References

For the purpose of this report, wells installed prior to 2007 will be referredto as "historic monitoring wells." Wells installed in 2007 will be referredto as "new monitoring wells."

0ERM/DADEMOELLER 4 FIRSTENERGY- DAVIS-BESSE 65992.2 18 MAR 08

2.0 METHODOLOGY

2.1 INVENTORY & MONITORING OF HISTORIC WELLS

2.1.1 Well Inventory & Gauging

On 9 and 10 May 2007, ERM conducted a site visit to inspect historicmonitoring wells at DBNPS and to determine if those wells werepotentially suitable for use as part of the plant groundwater monitoringprogram. The well inventory included a site walk to locate the monitoringwells and conduct the following activities:

* confirm the well location and designation against historicdocuments;

* collect spatial coordinates using a hand-held global positioningsystem device;

" assess the physical condition of the monitoring well;

* establish a measuring point for future depth to groundwatermeasurements;

" measure the well diameter, depth to groundwater and total depth;and

" attach an identification tag to the monitoring well.

Physical measurements and observations made during the well inventorywere tabulated (Table 1) and compared to historic documentation. Resultsof the well inventory were used to determine which historic monitoringwells were appropriate to use in future groundwater monitoring activities.

2.1.2 June 2007 Groundwater Monitoring Event

Upon completion of the well inventory, a Groundwater Field SamplingPlan (FSP) (ERM, 8 June 2007) was prepared to outline procedures forgroundwater sampling at select historic monitoring wells. The purpose ofthe FSP was to document the sampling locations, methodologies,analytical techniques and quality assurance/ quality control (QA/QC)measures for the collection of representative groundwater samples.

ERM/ DADE MOELLER 5 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

The purpose of the June 2007 monitoring event was to conduct apreliminary (or screening) round to evaluate the potential for tritium andgamma emitting radionuclides in groundwater and to support finalselection of the new monitoring well locations. Sampling locationsrepresented a subset of the historic monitoring wells at the property. Therationale for selecting the wells is included in Table 2.

Groundwater samples were collected using low-flow methodologies asdescribed in the FSP. Sampling depths were specified for each well as themid point of the saturated screened interval. Quality Assurance/QualityControl (QA/QC) procedures were specified for both the field andanalytical program.

From 11 to 27 June 2007, BETA Laboratory personnel conductedgroundwater monitoring at 17 historic monitoring wells: MW-1S, MW-1D,MW-7S, MW-12S, MW-15S, MW-15D, MW-18S, MW-18D,MW-20S, MW-20D, MW-26S, MW-26D, MW-30S, MW-32S, MW-32D,MW-33S, and MW-33D.

On 11 June 2007, prior to sampling, the depth to groundwater wasmeasured in each well using an electric water level meter. Low-flowsamples were collected using a peristaltic pump with disposable tubing.

During low-flow purging, geochemical field parameters were measuredwith an in-line flow-through-cell at regular intervals for stabilizationcriteria. Field parameters included temperature, specific conductivity,pH, dissolved oxygen (DO), and oxidation-reduction potential (ORP). Thegeochemical field parameters were recorded using a multi-parameterwater quality instrument that was calibrated at the beginning of each day.Turbidity samples were collected upstream of the flow-through-cell andanalyzed using a field turbidity meter. After stabilization of the fieldparameters, the flow-through-cell was disconnected and a groundwatersample was collected.

All field information and parameters were recorded on Low-FlowGroundwater Sampling forms and observations were recorded in a logbook.

Water samples were collected in one-liter containers. No filtration orpreservation was performed or required. All samples were packaged andshipped under chain-of-custody procedures to MidWest Laboratory ofNorthbrook, Illinois for analysis of Tritium (EPA Method 906.0) andgamma emitting radionuclides (EPA Method 901.1). Gamma isotopesincluded manganese-54 (Mn-54), iron-59 (Fe-59), cobalt-58 (Co-58), cobalt-


60 (Co-60), zinc-65 (Zn-65), zirconium-niobium-95 (Zr-Nb-95), cesium-134(Cs-134), cesium-137 (Cs-137) and barium-lanthanum-140 (Ba-La-140).

QA/QC procedures during the June 2007 monitoring event included fieldand laboratory methods to assess the overall analytical results. QA/QCprocedures included collection of the following additional samples(Table 3):

" Field duplicate (FD) - a QA/QC sample collected and analyzed toevaluate analytical precision. Two duplicate samples were collected inJune 2007 (MW-12S and MW-20S). The duplicate samples weresubmitted for analysis; however, the duplicates were labelled withunique names (i.e., DBD-01 as a duplicate of sample MW-12S andDBD-02 as a duplicate of MW-20S), such that the laboratory was notaware of the sample's origin. (i.e., these were blind duplicate samples).

* Matrix Spike/Matrix Spike Duplicate (MS/MSD) - a QA/QC samplecollected and analyzed to evaluate the potential for matrixinterferences on analytical accuracy. Matrix spike and matrix spikeduplicate samples were collected at MW-26D by collecting twoadditional samples. The June 2007 samples were spiked at thelaboratory with standards of 5,639 pCi/L of tritium, 59.3 pCi/L ofcesium-134 and 66.3 pCi/L of cesium-137 and analyzed to compare theanalytical results to the spike concentration.

2.2 JULY/AUGUST 2007 GROUNDWATER MONITORING EVENT

Upon receipt of the June 2007 groundwater monitoring results, anadditional round of groundwater monitoring was performed to confirmthe June results and to aid in finalizing the location of the proposedmonitoring wells.

Groundwater samples were collected using low-flow methodologies asdescribed in the June 2007 FSP. Sampling depths were specified for eachwell as the mid point of the saturated screened interval. QA/QCprocedures developed for the June sampling event were followed.

From 31 July to 6 August 2007, BETA Laboratory personnel conductedgroundwater monitoring at 14 historic monitoring wells:

* Re-sampled wells: MW-12S, MW-30S, MW-32S, MW-32D, MW-33S,MW-33D; and


* Additional sampled wells: MW-12D, MW-30D, MW-31S, MW-31DMW-34S, MW-34D, MW-37S, and MW-37D.

On 31 July 2007, prior to sampling, the depth to groundwater wasmeasured in each well using an electric water level meter. Low-flowsamples were collected using a peristaltic pump with disposable tubing.

Purging, measurement of field parameters and sample collection forlaboratory analysis in July/August 2007 were performed in a similarmanner as during the June 2007 sampling event (see Section 2.1.2).Samples were packaged and shipped under chain-of-custody proceduresto MidWest Laboratory of Northbrook, Illinois for analysis of tritium (EPAMethod 906.0).

QA/QC procedures during the July 2007 monitoring event included onefield duplicate sample (MW-32S, see Table 3). The duplicate sample wassubmitted for analysis; however, it was labelled with a unique name, suchthat the laboratory was not aware of the sample origin (i.e., DBD-01 as aduplicate of sample MW-32S).

2.3 WELL INSTALLATION

2.3.1 Overview

The purpose of the well installation program was to characterize andconfirm existing documentation of site subsurface geology andhydrogeology and to establish a reliable monitoring well network capableof evaluating the potential for inadvertent releases of radioactivity fromthe Power Block.

The new monitoring well network includes an up-gradient well triplet torepresent background conditions and 13 wells located between the PowerBlock and Lake Erie to evaluate groundwater quality down-gradient andcross-gradient of the Power Block.

Prior to initiating the drilling activities, DBNPS conducted utilityclearance activities at each of the proposed drilling locations. A sitewalkover was completed with Bowser-Morner, Inc. to verify access toeach location with the drilling equipment. In addition, a kick-off meetingwas conducted on 7 August 2007 to address site-specific logistics andhealth and safety issues.

ERM/DADE MOELLER 8 FIRSTENERGY - DAVIS-BESSE 65992.2 16MAR08ERM/ DADE MOELLER 8 FIRSTENERGY - DAVIS-BFSSE 65992.2 18 MAR 08

2.3.2 Advancement of Soil Borings

From 8 to 29 August 2007, sixteen soil borings were advanced at DBNPSby Bowser-Morner, Inc. using a truck mounted Sonicor K-50 drill rig.Boring depths ranged from 28 to 90 feet below ground surface. Theborings were advanced using sonic drilling technology, which is a dual-case drilling system that employs simultaneous high-frequency vibrationand low speed rotation, coupled with down-pressure to advance the drillbit. The drilling method advances a uniform borehole while providingcontinuous, representative and relatively undisturbed core samples. Thedual casing system was used at all locations and was advanced in 10-footincrements.

Each 10-foot core sample was collected within polyethylene sleevesallowing for visual logging and field screening. The sleeves were cutlengthwise to allow visual logging of grain size, degree of sorting, colorand relative moisture content of the recovered materials. Field screeningfor low level gamma emitting radiation was performed using a Ludlummicro R meter scanned over the core sample. Field screening for totalvolatile organics was performed using a MiniRAE 2000 photoionizationdetector (PID).

Following completion of each soil boring, the inner and outer drill rodswere thoroughly steam cleaned to remove residual solid and liquids fromthe drilling equipment. Drill cuttings were collected and containerized in55-gallon drums and labeled to identify the origin and type of material(i.e., boring identification, soil and/or water). DBNPS managed theinvestigation derived waste by discharging the water into the SouthSettling Basin, an APC that has historically contained tritium, and placingthe soil south of the Power Block. Borehole logs were prepared and areincluded in Appendix A.

2.3.3 Monitoring Well Construction

Each soil boring was completed as a monitoring well by installing two-inch inside diameter polyvinyl chloride (PVC) screen (0.010-inch slot) andriser. After installation of the PVC well materials, the outer casing of thesonic drilling system was slowly removed from the soil boring. Theannular space between the PVC and the inner wall of the drill rod wasfilled as the drill rods were removed. The annular space around the PVCwas filled as follows:

0 Sand filter pack - coarse grained silica sand around the PVC screen.


9 Bentonite seal - bentonite pellets above the silica sand.

* Grout seal - bentonite/cement slurry to ground surface.

Ten of the monitoring wells were capped with lockable expansion plugsand finished with flush mounted road boxes. The remaining sixmonitoring wells were capped either with a lockable expansion plug or aPVC slip cap and finished with a steel stick-up pipe secured in a concretepad.

2.3.4 Monitoring Well Development

Following construction of the new wells, Bowser-Morner Inc. developedthe wells to remove water and sediments introduced to the screen andriser during well construction. Well development was completed byremoving groundwater using either a dedicated, disposable polyethylenebailer with nylon rope or a Whaler submersible pump. Non-dedicatedequipment (pumps and tubing) was decontaminated between each well.

Prior to development, the volume of water inside the well was calculated,with a goal of removing 10 well volumes. Lower Dolomite wells MW-101C, MW-102C, MW-103C, and MW-104C purged dry several timesduring the development activities, resulting in the removal of less than 10well volumes from these wells. Strong hydrogen sulfide odors were notedfrom the development water pumped from these wells. The presence ofsulfide is believed attributed to the dissolution of naturally occurringgypsum and anhydrite minerals within the Lower Dolomite. Regionally,the occurrence of these minerals within the Dolomite Bedrock is attributedto high concentrations of hydrogen sulfide in water wells (WaterResources of Ottawa County Fact Sheet, Graham et al., 1998).

Groundwater from the development activities was containerized in either55-gallon drums or 250-gallon totes and labeled to identify the origin ofthe water. Samples from the containers were collected and analyzed atDBNPS to support waste management.

2.4 SEPTEMBER/OCTOBER 2007 GROUNDWATER MONITORINGACTIVITIES

Upon completion of the new monitoring wells, a Groundwater FieldSampling Plan (ERM, 20 September 2007) was prepared to outlineprocedures for groundwater sampling at the new monitoring wells, aswell as select historic monitoring wells. The purpose of the FSP was to


document the sampling locations, methodologies, analytical techniques,and QA/QC measures for the collection of representative groundwatersamples.

Sampling locations identified in the September 2007 FSP represented allthe new monitoring wells and select historic monitoring wells. Therationale for selecting the wells is included in Table 2. The list includedwells screened in the Glaciolacustrine, Till, Upper and Lower DolomiteBedrock.

Groundwater samples were collected using low-flow methodologies.Sampling depths were specified for each well as the mid point of thesaturated screened interval. QA/QC procedures were implemented inboth the field and analytical program.

The purpose of the September/October 2007 monitoring event was toevaluate if tritium and gamma emitting radionuclides associated withinadvertent releases from plant operations had migrated intogroundwater at DBNPS. From 24 September to 10 October 2007, BETALaboratory personnel conducted groundwater monitoring at 32monitoring wells:

" Historic monitoring wells: MW-12S, MW-12D, MW-15S, MW-15D,MW-20S, MW-20D, MW-23S, MW-30S, MW-30D, MW-31S,MW-31D, MW-33S, MW-33D, MW-35S, MW-35D, and MW-37S;and

* New monitoring wells: MW-100A, MW-100B, MW-100C,MW-101A, MW-101B, MW-101C, MW-102A, MW-102B, MW-102C,MW-103A, MW-103B, MW-103C, MW-104A, MW-104B, MW-104C,and MW-105A.

On 24 September 2007, prior to sampling, the depth to groundwater wasmeasured in each well using an electric water level meter. Low-flowsamples were collected using a peristaltic pump with disposable tubing ora non-dedicated bladder pump.

Purging, measurement of field parameters and sample collection forlaboratory analysis in September/October 2007 were performed in asimilar manner as during the June 2007 sampling event (see Section 2.1.2).Wells MW-101C and MW-103C were purged dry during low-flowpumping. Field parameters at these wells were collected during thepurging activities and the groundwater sample was collected after thegroundwater level had recovered to within 90 percent of the original level.


QA/QC procedures during the September/October 2007 monitoringevent included field and laboratory methods to assess the overallanalytical results. QA/QC procedures included collection of thefollowing additional samples (Table 3):

* Field Duplicate - duplicate samples were collected at four wells (MW-12D, MW20S, MW-31S, and MW-103B) to evaluate laboratoryanalytical precision. The duplicate samples were submitted for thesame analysis as the actual samples with unique names such that thelaboratory was not aware of the samples' origin. (i.e., DBD-01 as aduplicate of sample MW-12D, DBD-02 as a duplicate of sample MW-20S, DBD-03 as a duplicate of sample MW-31S, and DBD-04 as aduplicate of sample MW-103A).

* Matrix Spike/Matrix Spike Duplicate - two additional samples werecollected at MW-30S and MW-100A and spiked at the laboratory witha standard of 17,185 and 27,496 pCi/L of tritium and 65.6 and 98.4pCi/L of cesium-137.

* Laboratory Duplicate - outside of the FSP requirements, the laboratorycollected and analyzed split samples to evaluate laboratory precisionof tritium analysis. The laboratory duplicate samples (i.e., MW-33Sduplicate and MW-102A duplicate) were collected by splitting samplesfrom MW-33S and MW-102A, respectively.

* Equipment Blank - a rinseate sample was collected afterdecontaminating the bladder pump at MW-103C to evaluate theeffectiveness of decontamination procedures and the potential forcross-contamination between wells introduced by the samplingequipment.

2.5 SURVEYING

Select historic wells (MW-14D, MW-18S/D, MW-19S/D, MW-21S/D,MW-30S/D, MW-38S/D and MW-39S/D) and all new monitoring wellswere surveyed on 11 and 12 December 2007 by B.E.C. Associates, Inc., aprofessional survey company retained by ERM. Elevation data werecollected relative to NAVD 1929 sea level vertical datum. Historic wellswere selected for elevation surveying was based on observed physicalalterations to the well casings during the initial inspection. Documentedsurvey data in DBNPS files was used for the remainder of the historicwells.

ERM/ DADE MOELLER 12 FIRSTENERCY - DAVIS-BESSE 65992.2 18 MAR 08

2.6 DATA USABILITY ASSESSMENT

An assessment of the June, July/August 2007 and September/October2007 analytical data was performed to determine the usability of thegroundwater data for the intended purpose of the monitoring event. Theusability of groundwater data was evaluated by initially conducting areview of the Low-Flow Groundwater Sampling Forms against methodsoutlined in the FSP in order to assess deviations from the original FSP.Secondly, the analytical results were evaluated in terms of data qualitystandards termed "PARCCs" parameters (i.e., precision, accuracy,representativeness, comparability and completeness of the data).

Additional data review and verification included a statistical analysis ofthe radiological data reported by MidWest Laboratory to determine therange in the local background concentration of tritium in groundwater atDavis-Besse. The need for a statistical evaluation was based on thedetection of low level tritium concentrations reported by the laboratoryand follows industry guidance (EPRI, 2005).


3.0 RESULTS

3.1 SITE GEOLOGY

The surficial geology beneath the DBNPS property is characterized asGlaciolacustrine and Till units underlain by Dolomite Bedrock. Althoughnot encountered in the new boreholes, a layer of fill is reportedly presentwithin the area excavated during construction of the Power Block.

Based on field observations during the recent drilling activities as well asinformation presented in historic reports, the relative thickness andelevation of geologic units encountered at DBNPS are summarized below.

Summary of Geologic Units at DBNPS

Unit Approximate Depth Approximate Elevation

Interval(s) Below Ground Range (feet above mean sea

Surface (feet below ground) level)

Glaciolacustrine 0 - 10 feet 574 feet - 564 feet

Till 10 feet - 20 feet 564 feet - 554 feet

Dolomite Bedrock 20+ feet 554 feet and below

The Glaciolacustrine unit is characterized as brown silt with some sandand clay. This formation consists of sediments of a complex,unconsolidated nature that were deposited within a temporary lakeformed during the recession of glacial ice from Lake Erie. The underlyingTill unit is defined as a brown to dark gray silty clay. The surfaces of theGlaciolacustrine and Till deposits slope towards Lake Erie.

Beneath the Glaciolacustrine and Till units is the Dolomite Bedrock. Thisbedrock unit consists of argillaceous dolomite that has been subdividedinto a Massive Dolomite and a Laminated Dolomite. The MassiveDolomite is approximately 10 feet in thickness, hard, finely grained, andpresent approximately 10 feet below the ceiling of the Dolomite. TheLaminated Dolomite is encountered above and below the MassiveDolomite and includes thin layers of interbedded dolomite, gypsum,anhydrite and shale. Bedrock joints oriented to the northeast (N45°E) andnorthwest (N50°W) were reportedly observed in the bedrock during

ERM/DADE MOELLER 14 FIRSTENERGY - DAVIS-BESSE 65992.2 18MAR08ERM/ DADE MOELLER 14 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

excavation of the Power Block. Beds within the Dolomite Bedrock have anatural dip of less than one degree to the south.

3.2 HISTORIC WELL INVENTORY

Table 1 and Figure 2 present a summary of historic monitoring wellsevaluated during the well inventory. The monitoring wells wereoriginally installed during construction of DBNPS to assess theeffectiveness of a dewatering system that operated during plantconstruction. The historic wells were installed as couplets with screenedin the Upper and Lower Dolomite and are located north, east, south andwest of the Power Block. The historic wells consist of 3-inch diameter, 20-foot screen wells installed at depths varying between 29.37 and 49.65 feet(Upper Dolomite wells) and from 72 and 86 feet (Lower Dolomite wells).Based on historic documentation, the Upper and Lower Dolomite wellsare separated by the Massive Dolomite unit.

The following monitoring wells were not located during the wellinventory and therefore were not evaluated further: MW-8S, MW-8D,MW-9S, MW-9D, MW-10S, MW-10D, MW-13S, MW-13D, MW-16S, MW-.16D, MW-17S, MW-17D, MW-24S, MW-24D, MW-25S, MW-25D, MW-27S,MW-27D, MW-28S, MW-28D, MW-29S, MW-29D, MW-36S, and MW-36D.

3.3 NEW MONITORING WELLS

A total of 16 monitoring wells were installed at five locations at DBNPS toassess existing data gaps and to increase the reliability of the historic wellnetwork (Figure 2). The new wells were located to characterizegroundwater quality up-gradient and down-gradient of the Power Block.Five well triplets and a single well were installed. Each triplet ischaracterized by three individual monitoring wells that are screenedacross a specific target depth interval at each location: Base of Till, UpperDolomite, and Lower Dolomite.

The following table summarizes the newly installed monitoring wells andtheir location relative to the Power Block.


Summary of New DBNPS Monitoring Wells SWell ID Location/Hydraulic Position Relative Target Depth of Well Screen

the to Power Block

MW-100A

MW-100B

MW-100C

MW-101A

MW-101B

West/ Up-gradient

Base of Till

. Upper Dolomite

Lower Dolomite

Base of Till

Uper Dolonmitte

Lower Dolomite

East/ Down-gradient

MW-101C

MW-102A

MW-102B

MW-102C

Base of Till

Northeast/Down and cross-gradient Upper Dolomite

Lower Dolomite

MW-103A Base of Till

MW-103B Northeast/ Down and cross-gradient

MW-103C

Upper Dolomite

Lower Dolomite

Base of Till

-..---.....Upper Dolomite

MW-104A

MW-104B Northeast/ Down and cross-gradient

MW-104C Lower Dolomite

MW-105A Northeast/ Down-gradient Glaciolacustrine / Base of Till

Table 1 includes a summary of well construction details for the new andhistoric monitoring wells at DBNPS. Micro R and PID field meters didnot yield any increased detections when scanned over the core samplesduring the drilling activities. Borehole logs and well constructiondiagrams for the new monitoring wells are included in Appendix A.

GROUNDWATER FLOW

Table 4 presents a summary of depth to groundwater measurements andcalculated groundwater elevations during the well inventory andgroundwater monitoring events. During each monitoring event, theelevation of groundwater was generally higher than the elevation ofsurface water in Lake Erie, indicating regional groundwater flow is fromwest to east at DBNPS.

U

3.4

ERM/DADE MOELLER 16 DRSTENERGY - DAVIS-BESSE 65992.2 18MAR08ERM/DADE MOELLER 16 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

Surface Water1 and Groundwater Elevations

Date Range in Surface Water Range in Groundwater

Elevation Lake Erie (feet above Elevations in the Site

sea level) Monitoring Wells

9 May 2007 571.80 - 572.48 570-54 - 575.91

11 June 2007 571.72 - 571.91 570.52 - 574.79

31 July 2007 571.10 - 571.42 569.97 - 573.90

24 September 2007 570.87 - 571.17 517.62 - 573.96

1National Oceanic and Atmospheric Administration station 9063079 in Marblehead, OH

As indicated in the above table, groundwater elevations below theelevation of surface water in Lake Erie were observed during eachmonitoring event. The occurrence of low groundwater elevations likelyreflects site-specific conditions at DBNPS that complicate the ability toevaluate groundwater elevations and precise flow directions.Complicating factors include the presence of a grout curtain, the flow ofgroundwater within discrete fractures in bedrock, the large area ofexcavated bedrock beneath the Power Block and the high degree ofmineralized groundwater and associated low yield observed in the newLower Dolomite wells. An additional source of uncertainty is theusability of historic elevation survey data that were used to calculategroundwater elevations from the historic wells.

Low groundwater elevations were measured at Lower Dolomite wellsMW-101C, MW-102C, MW-103C and MW-104C, located east andnortheast of the Power Block. As previously indicted, each of these wellsdemonstrated a low yield during the well development activities andcontained high levels of hydrogen sulfide gas. The use of expansion plugsmay be inadvertently trapping sulfide gas inside the wells and around thewell screen, thereby limiting the screens ability to communicate with theLower Dolomite. Future modifications to the expansion plugs to allowventing of the sulfide gas will be evaluated in effort to obtain moreaccurate groundwater elevation data from these wells.

Figures 3, 4, and 5 present groundwater elevations for the Till, UpperDolomite and Lower Dolomite, respectively, during the September 2007monitoring event. Groundwater elevation contours were not developeddue to the complicating site-specific factors and their potential to impactgroundwater flow. However, groundwater flow directions at DBNPS

ERM/DADE MOELLER 17 FIRSTENERGY- DAVIS-BESSE 65992.2 18 MAR 08

within the Till, Upper Dolomite and Lower Dolomite can be evaluated bycomparing groundwater elevations in new across the site.

Groundwater elevations in Till wells MW-100A, MW-101A, MW-102A,MW-103A and MW-104A are presented in Figure 3. The highestgroundwater elevation in the Till was 573.91 feet measured up-gradient(i.e., west) of the Power Block at MW-100A. The lowest groundwaterelevation was measured at MW-105A at 568.73 feet, which is below theelevation of surface water in Lake Erie. Based on the distribution ofgroundwater elevations, groundwater flow in the Till is from west to eastacross the site. Approximate flow directions in the Till (Figure 3) areorientated perpendicular to the shoreline of Lake Erie.

Groundwater elevations in the Upper Dolomite are presented in Figure 4.The highest groundwater elevation in the Upper Dolomite was 573.96 feetmeasured up-gradient (i.e. west) of the Power Block at MW-100B. Thelowest groundwater elevations in the Upper Dolomite were locatednortheast of the Power Block (MW-31S at 571.08 feet) and southeast of thePower Block (MW-12S at 570.98 feet). Based on the distribution ofgroundwater elevations, groundwater flow in the Upper Dolomite is fromwest to east across the site. Approximate flow directions in the UpperDolomite (Figure 4) are orientated perpendicular to the shoreline of LakeErie.

Groundwater elevations in the Lower Dolomite are presented in Figure 5.The highest groundwater elevation in the Lower Dolomite was 573.56 feetmeasured up-gradient (i.e. west) of the Power Block at MW-100C. Ingeneral, lower groundwater elevations in the Lower Dolomite werelocated east of the Power Block. Based on the distribution of groundwaterelevations, groundwater flow in the Lower Dolomite is from west to eastacross the site. Approximate flow directions in the Lower Till (Figure 5)are orientated perpendicular to the shoreline of Lake Erie.

Groundwater elevations decreased in site wells from May to July, andagain from July to September. This trend mimics the decline in elevationof surface water in Lake Erie over the same period, signifying that themarshes and/or Lake Erie are the discharge boundary for groundwater.

Comparison of groundwater elevations between the Till and UpperDolomite allows for assessment of vertical groundwater flow gradients.Using data from the new monitoring wells, an upward flow gradient isobserved from the Upper Dolomite to the Till unit. As previouslyindicated, the elevation of groundwater in all three units is higher than theelevation of surface water in Lake Erie (except where anomalies are noted)

ERM/DADE MOELLER is FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

further indicating that groundwater within all three units is ultimatelydischarging to the marshes and/or Lake Erie.

3.5 GROUNDWATER QUALITY

3.5.1 Groundwater Field Parameters

Groundwater field parameters collected at the time of groundwatersampling in June 2007, July/August 2007 and September/October 2007are summarized in Table 5. A summary of the field parameter data ispresented below.

" Temperature - Groundwater temperatures ranged from 13.6 to 25.6degrees Celsius (°C). In general the highest temperatures weremeasured in wells located directly down-gradient of the PowerBlock. The highest temperatures were observed at MW-34S/D(25.6, 24.1oC), MW-33S/D (25.5, 25.20C), and MW-31S/D (24.5,23.1oC). Groundwater temperatures in other areas were below20oC.

* Specific conductivity - Groundwater specific conductivity rangedfrom 113 uS/cm to values greater than 10,000 uS/cm. The highestspecific conductance values (i.e., greater than 50,000 uS/cm) weremeasured in Lower Dolomite wells MW-101C, MW-102C, MW-103C and MW-104C. As indicated earlier, these wells were notedwith high hydrogen sulfide gas, low yield and low groundwaterelevations. The high specific conductance measured at these wellsrelative to other wells further suggests that the well screens at thesefour locations have limited connection to the Lower Dolomite.

* Dissolved oxygen (DO) - Several DO measurements were rejectedfrom the monitoring events due to probe interference withhydrogen sulfide. Accepted DO levels in groundwater ranged from0.04 to 4.24 milligrams per liter (mg/L). The reported odors ofsulfide are indicators of anaerobic and depleted oxygen conditions.

" pH - The pH of groundwater ranged from 6.0 to 8.8 standard pHunits. The limited variations in pH values are most likely due tothe influence of the Dolomite Bedrock. Dolomite is a carbonaterock and is anticipated to buffer pH changes in groundwater.

* Oxidation Reduction Potential - ORP values ranged from -368 to 87millivolts (mV). ORP values were generally below 50 mV in all of


the wells, indicating that site groundwater is subject to reducingconditions (anaerobic). A trend shows that values decrease withdepths.

Turbidity - With the exception of wells MW-101C (798), MW-102C(10) and MW-104C (38), the turbidity of groundwater was low (i.e.,less than 10 nephelometric turbidity units). High turbidity valuesat MW-101C, MW-102C and MW-104C are consistent with the highspecific conductance at these wells and the well screens limitedability to communicate with the Lower Dolomite.

3.5.2 Analytical Results

Data Summary

Groundwater analytical results from the June, July/ August 2007, and theSeptember/October 2007 groundwater monitoring event are summarizedin Table 6. Figure 5 presents a summary of the June, July/August 2007tritium results, while Figure 6 presents a summary of theSeptember/October 2007 tritium results. Appendix C and Appendix Dinclude an assessment of the usability of the groundwater analytical datafor the June, July/August, and September/October 2007 monitoringevents, respectively. As indicated in Appendices B and C, the analyticaldata presented in Table 6 meet the data quality objectives in the FSPs andare usable for the intended purpose of the groundwater monitoringprogram. Appendix D also includes a statistical evaluation to determinethe range in local background concentrations. Laboratory analyticalreports are included in Appendix E.

Local Background Conditions

As presented in Appendix C, reported tritium concentrations between 178pCi/L and 348 pCi/L represent statistically insignificant activity at the

.95% confidence level. Therefore, values at or below 348 pCi/L wereconsidered to be representative of local background conditions. Factorsinfluencing local background conditions may include the historicatmospheric bomb testing program, cosmic ray interactions in the earth'satmosphere and localized washout from continuous and batch gaseousreleases from DBNPS.

June and July/August 2007 Results

Analytical results of tritium samples collected in June 2007 ranged fromless than the minimum detectable concentration (MDC, i.e., <330 pCi/L)

ERM/DADE MOELLER 20 FIRSTENERGY - DAVIS-BESSE 65992.2 18MAR08ERM/DADE MOELLER 20 FI RSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

to 5,838 pCi/L (MW-32S). Tritium detections during the July/August2007 confirmation round ranged from 108 pCi/L (MW-31D) to 7,535pCi/L (MW-32S). No gamma emitting radionuclides were detected abovetheir respective MDCs.

Tritium concentrations detected above the 348 pCi/L background valuewere located primarily in monitoring wells east of the Power Block. In theUpper Dolomite, the highest concentrations were present east of thePower Block, including MW-31S, MW-32S, MW-33S, and MW-34S.Elevated detections above local background were also measured in theUpper Dolomite north of the Power Block at well MW-30S (1,307 pCi/L)and well MW-37S (2,961 pCi/L).

In the Lower Dolomite unit, the highest detections were locatedeast/southeast of the Power Block, including wells MW-33D, MW-34Dand MW-12D.

September/October 2007 Results

In September/October 2007, tritium concentrations ranged from less thanthe MDC (149 pCi/L) to 3,149 pCi/L (MW-31S). The concentrations oftritium in new wells MW-100A, MW-100B and MW-100C, which arelocated hydraulically up-gradient of the Power Block, were <193 pCi/l,<193 pCi/L and <149 pCi/l, respectively. No gamma emittingradionuclides were detected above their respective MDCs in any of thegroundwater samples collected during the September/October 2007sampling event.

Concentrations above local background in the Till were detected down-gradient (i.e., northeast) of the Power Block, including MW-102A (387pCi/L, Till Unit), MW-103A (495 pCi/L, Till Unit), and MW-105A (1,832pCi/L, Glaciolacutrine/Till Unit).

Tritium concentrations above local background in the Upper Dolomitewere detected north of the Power Block in wells MW-30S and MW-37S,consistent with the June and July/August 2007 events. The highestconcentrations in the Upper Dolomite were detected east/northeast of thePower Block including wells MW-31S and MW-33S. Elevated tritium inthe Upper Dolomite was not detected in new monitoring wells MW-102B,MW-103B and MW-104B, located to the northeast of MW-31S/D.

For the Lower Dolomite, the highest concentrations above localbackground were detected in wells MW-12D, MW-15D and MW-33D,located east/ southeast of the Power Block. Tritium was not detected

ERM/DADE MO0ELLER 21 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

above local background in any of the new monitoring wells east of thePower Block within the Lower Dolomite (i.e., MW-101C, MW-102C, MW-103C and MW-104C). As previously indicated, groundwater at thesewells may not be connected to the Lower Dolomite due to the presence ofhydrogen sulfide gas.

Comparison to Drinking Water Standards

Tritium concentrations in groundwater during the June, July and Augustand September/October 2007 monitoring events were below theEnvironmental Protection Agency's drinking water standard of 20,000pCi/L.

3.5.3 Tritium Source Assessment

As indicated in the January 2007 Groundwater Flow Characteristics Report(ERM, 16 January 2007), potential sources of the elevated tritium detectedin groundwater may be associated with plant operations in the followingareas and/or documented historic liquid releases (Figure 2):

* Power Block - consisting of potential sources within the ReactorContainment, Auxiliary Building, Circulating Water Pump House,Turbine Building and Borated Water Storage Tank.

* Spent Fuel Pool, Fuel Transfer Canal and Cask Pit - as outlined inthe investigation summary of DBNPS Condition Report # 04-01719,several instances of leakage from the Spent Fuel Pool have beenrecorded. Since the elevation of the pool is from 563.3 to 601.5 feetabove sea level, leakage from the Spent Fuel Pool and/orinterconnected Fuel Transfer Canal and Cask Pit could potentiallyrelease tritiated water to the structural backfill surrounding thePower Block or to the Upper Dolomite.

* Condensate Demineralizer Tank Discharge Line - as documentedin the DBNPS 10 CFR 50. 75(g) file, in May 1990 a break in thedischarge line exiting the Condensate Demineralizer Polisher Tankwas discovered east of the Power Block. Contaminated resin wasreleased to soil at the connection between the CondensateDemineralizer Backwash Receiver Tank discharge line and a 10-inch pipe that conveyed the resin to South Settling Pond.

* Collection Box - as documented in the DBNPS 10 CFR 50.7 5 (g) file,approximately 12,000 gallons of water was spilled to the ground


adjacent to the Collection Box in 1997. It was estimated that theconcentration of tritium in the release water was 6,850 pCi/L.

Hydrogen Addition System - as documented in the DBNPS 10 CFR50.75(g) file, primary grade water was spilled onto the ground nearthe Borated Water Storage Tank while draining the HydrogenAddition System in 1991.


4.0 UPDATED CONCEPTUAL SITE MODEL

The spatial distribution of tritium in groundwater and groundwater flowpatterns can be used to update the CSM regarding the potentialinadvertent release, fate and transport of tritium at DBNPS. The CSM wasoriginally presented in the Groundwater Flow Characteristics Report - Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.

Groundwater flow within the Till, Upper Dolomite and Lower Dolomiteunits at DBNPS is from west to east toward Lake Erie. Highergroundwater elevations within these units compared to the elevation ofsurface water in Lake Erie indicates that groundwater discharges to themarshes and/or Lake Erie.

Potential inadvertent releases from within the Power Block, including theSpent Fuel Pool, would migrate vertically down through the unsaturatedzone to the water table. Upon encountering the water table, tritium wouldbe transported laterally through the Till in an easterly direction towardsLake Erie. Potential releases below the water table could release tritiumdirectly to the Upper or Lower Dolomite unit.

Reported mapping of jointing and fractures on the upper surface of theDolomite Bedrock indicated orientations southwest to northeast and asecondary orientation from southeast to northwest. These fracturesrepresent the direction of potential preferential migration pathwayswithin the Dolomite Bedrock. Elevated detections in Upper Dolomitewells MW-31S and MW-32S are located on fracture projections that traceback (i.e., southwest) to the Power Block.

Tritium in groundwater will ultimately migrate into Lake Erie, where theconcentrations will be diluted due to the volume of groundwaterdischarge versus the volume of water in the lake. This is supported byDBNPS Radiological Effluent Monitoring Program (REMP) data thatindicates tritium levels typically below 330 pCi/L in surface watersamples from Lake Erie.

ERM/ DADE MOELLER 24 FIRSTENERGY - DAVIS-BESSE 65992.2 18MAR08ERM/ DADE MOELLER 24 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

5.0 KEY FINDINGS

The key findings from the groundwater investigation include thefollowing:

Geology

The surficial geology beneath the DBNPS consists ofGlaciolacustrine and Till units. The Glaciolacustrine unit ischaracterized as cohesive, brown silt with some sand and clay. TheTill is characterized as brown to dark-gray, silty clay.

" Beneath the Till is Dolomite Bedrock, subdivided into a LaminatedDolomite and a Massive Dolomite. The Laminated Dolomite,which is encountered above and below the Massive Dolomite,contains thin layers of interbedded dolomite, gypsum, anhydriteand shale. The Massive Dolomite is approximately 10 feet thick,hard, finely grained, and located approximately 10 feet below thetop of the Dolomite.

Historic Well Inventory

" A total of 54 wells (27 couplets) were located and inspected duringthe well inventory and 24 wells (12 couplets) could not be found.Each well couplet consists of a shallow and deep well within theDolomite Bedrock. The shallow bedrock well is screened withinthe Upper Dolomite and the deeper bedrock well is screened in theLower Dolomite. The Massive Dolomite unit separates wellsscreened within the Upper and Lower Dolomite.

* The historic wells, by themselves, were not sufficient to create aneffective groundwater monitoring program at DBNPS because theydid not provide adequate lateral and vertical coverage. In addition,due to the age of the wells, their construction quality andsubsurface conditions are not known.

Groundwater Flow

The ability to develop groundwater elevation contours and flowpatterns is complicated by several factors, including the presence ofa grout curtain, the flow of groundwater within discrete fracturesin bedrock, the large area of excavated bedrock beneath the Power


Block and the high degree of mineralized groundwater andassociated low yield observed in the new Lower Dolomite wells.An additional uncertainty is the usability of historic elevationsurvey data that were used to calculate groundwater elevationsfrom the historic wells.

0 Based on the distribution of groundwater elevations, groundwaterflow in the Till, Upper Dolomite and Lower Dolomite units is fromwest to east across the site.

* The ultimate discharge point for groundwater in the Till, UpperDolomite and Lower Dolomite is the marshes and/or Lake Erieeast of the Power Block.

Groundwater Quality

* Strong hydrogen sulfide odors were noted in site groundwater,particularly new Lower Dolomite wells MW-101C, MW-102C, MW-103C and MW-104C located east of the Power Block. The hydrogensulfide is believed to be naturally occurring and caused by theweathering of gypsum and anhydrite minerals. Groundwater fieldparameters at these wells are characterized by high specificconductance, low ORP and high turbidity water.

* High hydrogen sulfide gas levels at wells MW-101C, MW-102C,MW-103C and MW-104C may be inadvertently trapped due to theuse of expansion plugs at these wells. The sulfide gas may limit theability for the well screen to communicate with the LowerDolomite. Future modifications to the expansion plugs to allowventing of the sulfide gas will be evaluated in effort to obtain moreaccurate groundwater elevation data from these wells.

" Reported concentrations of tritium in groundwater between 178pCi/L and 348 pCi/L represent statistically insignificant activity atthe 95% confidence level and are considered representative of localbackground conditions. Factors influencing local backgroundcondition may include the historic atmospheric bomb testingprogram, cosmic ray interactions in the earth's atmosphere andlocalized washout from continuous and batch gaseous releasesfrom DPNBS. Reported values above 348 pCi/L representconcentrations that are statistically greater than local backgroundconditions.

ERM/DADE MO0ELLER 26 FIRSTENERGY - DAVIS-BESSE 65992.2 18 MAR 08

" Tritium concentrations above the 348 pCi/L background valuewere located primarily in monitoring wells east of the Power Block.

" Tritium concentrations in the wells screened in the Till ranged fromless than the minimum detectable concentration (MDC; <193pCi/L) to 1,832 pCi/L. The highest concentrations were detecteddown-gradient (northeast) of the Power Block, including MW-102A(387 pCi/L), MW-103A (495 pCi/L), and MW-105A (1,832 pCi/L).

" Tritium concentrations in the wells screened in the Upper Dolomiteranged from less than the MDC (<193 pCi/L) to 7,535 pCi/L. Thehighest concentrations were detected down-gradient (east) of thePower Block, including MW-31S, MW-32S, MW-33S, MW-34S,MW-37S and MW-30S. Two detections above local backgroundconditions were detected at well MW-30S (1,307 pCi/L) and wellMW-37S (2,961 pCi/L), located north of the Power Block.

* Tritium concentrations in the wells screened in the Lower Dolomiteranged from less than the MDC (<193 pCi/L) to 3,271 pCi/L. Thehighest detections were located east/southeast of the Power Block,including wells MW-33D, MW-34D and MW-12D.

" No gamma emitting radionuclides were detected above MDC inany of the groundwater samples collected during the June,July/August 2007 or the September/October 2007 monitoringevents.

* Tritium concentrations in groundwater during the June, July andAugust and September/October 2007 monitoring events werebelow the Environmental Protection Agency's drinking waterstandard of 20,000 pCi/L.

Updated CSM

" Groundwater flow within the Till, Upper Dolomite and LowerDolomite units at DBNPS is generally from west to east towardLake Erie with groundwater discharge to the marshes and/or LakeErie.

* Potential inadvertent releases from within the Power Block,including the Spent Fuel Pool, would migrate vertically downthrough the unsaturated zone to the water table. Potential releasesfrom structures below ground could release tritium directly to theUpper or Lower Dolomite unit.


" Elevated detections in Upper Dolomite wells MW-31S and MW-32Sare located on reported southwest to northeast fractures thatproject back to the Power Block.

* Tritium in groundwater will ultimately migrate into Lake Erie,where the concentrations will be diluted due to the volume ofgroundwater discharge versus the volume of water in the lake.

" Historic monitoring of Lake Erie by DBNPS indicates that therehave been few detections of tritium above local backgroundconditions, none of which are believed to be attributed togroundwater releases.

Based upon the above findings, FirstEnergy should further evaluate thehydrogeology and influence of plant features on site groundwater flow.In addition, tritium detections above local background conditions shouldbe evaluated to establish a reliable monitoring well network for long-termmonitoring.


6.0 REFERENCES

EPRI, 2005. Groundwater Monitoring Guidance for Nuclear Power Plants.Palo Alto, CA. 1011730.

ERM, 16 January 2007. Final Report - Groundwater Flow CharacteristicsReport Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.

ERM, 8 June 2007. Final Report - June 2007 Groundwater Field SamplingPlan - Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.

ERM, 20 September 2007. Final Report - September 2007 GroundwaterField Sampling Plan - Davis-Besse Nuclear Power Station, Oak Harbor,Ohio, Pennsylvania.

Graham, G.W., N'Jie, N., and Brown, L. Water Resources of OttawaCounty. Ohio State University Fact Sheet. Available at:http://ohioline.osu.edu/aex-fact/0480_62.html

NEI, August 2007. Industry Ground Water Protection Initiative - FinalGuidance Document. NEI-07-07.


0

Tables

S S

Table IMonitoring Well Location and Construction SummaryFirstEnergy Nuclear Operating CompanyDavis-Besse Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

Well Designation Date Installed Well Condition Hydrogeologk Position MP Elevation Well Diameter Screen Length Constructed Well Depth Screen Interval Elevation (feet) Getlogic Unitfor Monitoring Relative to Power Btorks (feet ASL) (inches) (feet) (feet below gromnd) Top Bottom Monitored

New WellsMW-iAIVA 9-Aug -2lX7 Funrlonl Up-gradient 586 3 2 10 28 569.33 559.33 TillMW-iI )B 9-Aug-21107 Fun"u ton: l Up-gradient 58674 2 10 45 552,24 54224 Upper Dolom-teMIW -IlF1C 9-Aug-2107 Funltiomnal Up-rlradient 586.27 2 10 85 511.77 501.77 Lower Dolomite

MW-IllA 15-Aug-2l817 Functional Down-rgrado-ol 586.96 2 101 28 569.46 559.46 TillMW-lI IB l5-Aug-2 7 FuPo tiorrl Dowen-grado-n 586.89 2 10 45 552.39 542.39 Upper DolomiteK1W20IIC 15-Aur-2l)7 Pow Ioroal Dowg:n-grad2nl 587.18 2 10 811 517.68 507.68 Lower DolomiteMW.1i2A 16-Aug-2!)17 Fun, tlional Down-gradoent 585,12 2 10 29.5 566.12 556.12 TillMW-lI12B 16-Aug-X2107 Functional Down-gradient 585.04 2 10 44 551.54 541.54 Upper DolomiteMW-1I 2C 16-Auh,-2187 Fuowrwonal Downgradteon 595.31 2 15 78 3. . 517.81 507.81 Lower Dolo-mtr ,MW-1013A 21-Aug-2107 Fun, bronal Down-gradient 589.24 2 I0 M 55N 555.24 TillMW-103B 21-Aug-2(007 Fun, tonal Down-i'radrent 589.19 2 10 48.5 551,19 541.19 Upper DolomireMW-1il3C 21-Au|,-2(17 FunP tr-Iol Down-pradient 588.87 2 10 78 521.37 511.37 Lower DolomiteMW-114A 24-Aug-21017 Funtol Down-grad t 2 10 32 5637 553.75 TillMW11841 24-Aug-21(17 Ponr lonal Dow"-gradren2 514.98 2 0 46 550.48 539.48 Upper D(rloolteMIW-1t84C 24-Aug-20087 Functional Doown-=radhn1 584.84 10 _T 775 517.84 . (17 Lower DolomitMW-10G5A 28-Auii-21007 FuPo tioral Dows-gr-doen 585.46 10 27.5 568.46 558.46 Glaoiolarutrrlrwý / TillHistoric Wr'ellsMW-IS Prorr lt March 1979 Furoulroor Dotwn-gradrrnt 584102 3 20 41.7. 562.4 542.4 Upper Dolom ie

MW- D Pre CMaeoh 197 P5w5M we,MW 1DProro Marnh_ 97'9 _ Fu.,om . .. .Down:gradiet•.!37 .... ... 3 .. ... .. 20 ..... .. . 80,6 . . . . 52,1 ................. 02 2 . ... o e Dol___ ___ t

M3V-2S Prior o Maech 1979 Functionri Down-gradient 584.46 3 20 40.5* 563.9 543.9 Upper DolomiteMW-2D Prior 1o Man h 1979 Pow tio.nal Dowo-gradient 584.55 3 20 80,5* 524.0 504.0 Lower DolomiteMW-3S Prior to March 1979 FunPlional Deown-gradrernt 584.81 3 20 41.7' 563,1 543.1 Upper DolomiteMW-3D Pr-or to Marrh 1979 FunPw . .o.. Doon--gradltl-t 584.73 3 20 79.4" 5.5 .. .. 53 505.3 Lower DolomrteMW-4S Pr:or tor Marr'h 1979 Po n, -Ir-al Down-gradint 588.59 3 2D 46.3' 562.3 542.3 Upper DolomiteMW-4D Prro 1o Mar.ch 1979 Fuorooroal Down-gradi-1n 588.57 3 20 85.6' 525.0 50M 0 Lower DolomitLeMW-SS Priornlo Marrch 1979 FuPo tiorn Down-gradlnt 5384.85 3 210 42.3* 562.6 542.6 Upper DolomiteMW-3D Prior to March 1979 Functional Down-gradient 584.A6 3 211 81.6' 524.3 5014.3 Lower Dolomite

MW-6S Prorr Mrorh 1979 Funrial Dt5o7-gradoon 379.86 3 211 34.4' 364.5 544.5 Upper Dolomole6W-sD PrFor 1o Murrrh 197u9 Furoor-ral Droso-gradrenl 578.95 A3 211 72`4 526.6 586.6 Lower Doloorhl

MW-7S Prior to Ma. h 1979 FPwr tionarl Croo.-gradirrnt 57769 3 20 34.4- 563.3 543.3 Upper DolomiteMW-7D Poror to, Mir. h 1979 FuP, tiornl Croso-gradient 577.62 3 25 72.9' 524.7 5(W.7 Lower DolomiteMlW-SS Pror lr Mrlarh 1979 Welo roulid ntool h1-,lvrle during the May 21537 well rvenory. Well most likely derstroyed Upper DolomrteMW-8D Prortooe Manrh 1979 Well olrl ernr- he orxated duog the May 2(1X7 well mvenrtoWell most likely destroyred Lower.DolomiteMNW-_95 Prorr to Mar-.oh 1979 Well could not hr loroted during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMW_ Z Prior to Marrh 1979 Vell rrould not hbe alted during the May 2807 well inventory. Well most likely derslroyed Lower DolomiteMW-1:l Prior to Mach 1979 Well r ould note hr wated during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMW-1ID Prire, 1o Mach 1979 Well Crould not he located durir h- May 2157 well irmr tor.oWoilI mosl likely dtestroytd . Lower Dolomite

MW-I IS Prrror- to March 1979 FPno Ionrl Dowo-gradient 586.31 3 20 - 42.6*Uppee olrroi ..MW-iI D Pror to Marth 1979 unr lioal Dwn-gradient 5. 80.7 525.3 505.3 Lower DolomiteMlW-12S Prior to Manh 1979 FNo, tional Down-gradrlnr 585.96 3 20 42.10' 564.0 544.0 Upper DolomiteMW- I 2D Prro ro Ma'h 1979 FunP tional Down-grad-r~ e 85.98 3 20 81.1* 524.9 504.9 Lower DolomiteMW-r-1 Prrrr to Macsh 1979 We" 'otild not N. lohartd during the May 20(17 weoll worvetory. Well most likely destroyed Upper DolonrteMW-13D Prior to March 1979 Well could ot o he located durrr the May 20(17 well vvrrntory._Well mostlikely destroyed Lower DolooiteMiW-145 Prror- o Mar h 1979 Fown tIroal Down-gradiont 586.24 3 J 20 , 42.2 36-1 544.1 Upper DolomiterMW-14D Prror I. Macnh i979 oFu, .ional Down-gradint 385.¶ 3 2111 79.9' 526.1 5116.1 Lower DolomiteMW-1SD Prror to March 1979 Fur-tioal Down-gradienl 585,84 3 1 2111 42.6* 5&1,3 543.3 Upper DolomiteMW-I5D Pri5r V r March 1979 FPio nal D:own-gradtoet 38584 3 Ij 2 I.42.6' . 5653 . . .3 Upper D_ 20oteMW-165 Prior to March 1979 Well crould not be located during the May 2157 well inrentory. Well wool lirey destroyed Upper DolomiteMW-16D Prior to Manch 1979 Well could not hN lot aLed during the May 2()07 well inventory. Well most likely drtotroyed Lower DolomiteMW-I7S Priror lo March 1979 Well, ould not N, lotIated during the May 21017 well inventory. Well most likely drtroyed Upper DolomiteMW-17D PrNro br March 1979 Well 0ouad nr- he oared dlorr he May 21817well rn t 11o o st likely-I drstroyed Lower Doloirlte.......... 18 ii I - 294.' [ -576.2 556.2UprDlmtMW-18D Prior to Mach 1979 Pun- ltonl Cr"" 58539 U51er DolorreMIW-19D Prior-ro Mach 11979 Funoltornal Cross-gr0diunt 58539 3 20 77" 531.7 5.Lower Dolomiter

MW-19S Prior- t Manh 1979 Funt tional Up-gradiento 585.77 3 41S564.0 544.0 Upper DolomireMW-19D Prror tr Mach 1979 Fwiro t nal Up-gradien P 85.77 3 2 775: 328.3 508'.3 Lrwer Dolorole

Table 1Monitoring Well Location and Construction SummaryFirstEnergy Nuclear Operating CompanyDavis-Besse Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

Well Designation Date Installed Well Condition Hydrogeologic Position MP Elevation Well Diameter Screen Length Constructed Well Depth Screen Interval Elevation (feet) Geologic Unitfor Monitoring Relative to Power Blocks (feet ASL) (inches) (feet) (feet below ground) Top Bottom Monitored

MW-21)S Prior to Man'h 1979 Fonthional Up-gradielt 586.06 3 20 42.4* 563.6 543.6 Upper DolomiteMW-20D Prior to March 1979 Functional Up-gradient 585.96 3 20 80.3* 525.7 505.7 Lower DolomiteMW-21S Prior to March 1979 Functional Up-gradient 585.40 3 20 43.2' 562.2 542.2 Upper DolomiteMW-21 D Prior to March 1979 Funtional Up-gradient 586.62 3 20 81.4' 525.3 505.3 Lower DolomiteMW-22S Prior to March 1979 Functional Up-gradient 585.51 3 20 42.1' 563.5 543.5 Upper DolomiteMW-22D Prior Io March 1979 Functional Up-gradient 585.59 3 20 81.2' 524.4 504.4 Lower DolomiteMW-23S Prior to March 1979 Functional Up-gradient 584.97 3 20 42.2* 562.8 542.8 Upper DolomiteMW-23D Prior to March 1979 Functional Up-gradient 585.34 3 20 80.8* 524.6 504.6 Lower DolomiteMW-24S Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMW-24D Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Lower DolomiteKIW-25S Prior I, Manrh 1979 Well tcold not he located during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMW-25D Prior to March 1979 Well could not he located durine the May 2007 well inventory. Well most likely destroyed Lower DolomiteMW-26S Prior to March 1979 Functionat Up-gradient 585.68 3 20 42.3' 563.3 543.3 Upper DolomiteMW-26D Prior to March 1979 Functionat U -gradient 505.65 3 20 80.5' 525.2 505.2 Lower DolomiteMW-275 Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMW-27D Prior to Mlarh 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Lower DolomiteMW-28S Prior to March 1979 Well could not he located during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMW-28D Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Lower DolomiteMW-295 Prior to March 1979 Well could not be located during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMW-29D Prior to Manrh 1979 Well could not be located dorm the May 2007 welI inventory. Well most likely destroyed Lower DolomiteMIW-305 Prior to March 1979 Functional Cross-gradient 587.20 3 20 40.9* 566.4 546.4 Upper DolomiteMW-301D Prior to March 1979 Functional Cross-gradient 587.20 3 20 81.0' 526.2 506.2 Lower DolomiteMW-315 Prior to March 1979 missing cap Down-gradient 586.11 3 20 42.9' 563.2 543.2 Upper DolomiteMW-31 D Prior to Manrh 1979 Functional Doon-gradient 586.39 3 20 81.2' 525.2 505.2 Lower DolomiteMW-325 Prior to Manrh 1979 Fu-ctional Dowg'radient 586.05 3 20 42.6* 563.5 543.5 Upper DolomiteMW-32D Prior to March 1979 Fuoctional Down-gradient 586,17 3 201 80.Ll 525.2 5(05.2 Lower DolomiteMW-33S Prior t1 March 1979 Functional Down-gradient 585.,5 3 20 42.2* 563.6 543.6 Upper DolomiteMW-33D Prior to March 1979 Functional Down-gradient 505.89 3 20 80.7* 525.2 505.2 Lower DolomiteMW-345 Prior to Martch 1979 Forctional Dosr--gradiwnt 586.01 3 20 42.8* 563.2 543.2 Upper DolomiteMW-34D Prior to March 1979 Functioal Down-yradient W55.87 3 1 20 80.7* 525.2 505.2 Lower DolomiteMW-35S Prior to March 1979 onctioral Crss-gradient 592.97 3 20 49.7' 563.3 543.3 Upper DolomiteMW-35D Prior to March 1979 Functional Crass tradient 592.05 3 20 86.3' 526.5 506.5 Lower DolomiteMW-36S Prior to Marnh 1979 Well could not he l[•catesl during the May 2007 well inventory. Well most likely destroyed Upper DolomiteMIW-36D Prior to Wtanh 1979 Well could not be lo(wated durino the May 2007 well inventory. Well most likely destroyed Lower DolomiteMlW-375 Prior to March 1979 Functional Cross-gradient 585.79 '3 20 42.7' 563.1 543.1 Upper DolomiteMIW-37D Prior to March 1979 Furctional Cross-5radient 505.77 3 20 80.6* 525.1 515.1 Lower DolomiteMW-318 Prior to March 1979 Functional Cross-gradient 586.00 3 20 40.3' 565.7 545.7 Upper DolomiteMW-38D Prior to March 1979 Functional Cross-gradienrt 586.16 3 20 79.0* 527.2 507.2 Lower DolomiteMW-395 Prior to March 1979 Functi:*ra Up-gradiet 585.38 3 2( 40.3* 565.1 545.1 Upper DolomiteMW-39D Prior to Mar:h 1979 FPon:oional Up-gradient 585.33 3 2(1 81 2' 524.3 504.3 Lower Dolomite

No.esAll -lesti*,o iore otnaiv t,, no,-ano level (ASL-ahonwoa leer-)KIP h MIeoriong P,,inI

N= -- ' t, depth avalalle, VAl.-o n-,-,red -r, 9 ond 10 Mop 2007- - Data nol ava

,or 2 ý,2

0 0

Table 2aOSummary of Sampling Program - June 2007FirstEnergy Nuclear Operating CompanyDavis-Besse Nuclear Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

Well Groundwater Sampling Sampling

Designation Sampling Well Selection Rationale MethodHistoric Well

MW-1S X Yes - Down-gradient from Power Block Low-FlowMW-1D X Yes - Down-gradient from Power Block Low-FlowMW-2S No - Sample MW-1 Couplet NAMW-2D No - Sample MW-1 Couplet NAMW-3S No - Sample MW-1 Couplet NAMW-3D No - Sample MW-1 Couplet NAMW4S No - Sample MW-12S NAMW-4D No - Sample MW-12S NAMW-5S No - Sample MW-12S NAMW-5D No - Sample MW-12S NAMW-6S No - Sample MW-12S NAMW-6D No - Sample MW-12S NAMW-7S X Yes - Close to South Settling Pond Low-FlowMW-7D No - Sample MW-7S NAMW-11S No - Sample MW-12S NAMW-11D No - Sample MW-12S NAMW-12S X Yes - Close to inadvertent release in 50.75(g) Low-FlowMW-12D No - Sample MW-12S NAMW-14S No - Sample MW-15 Couplet NAMW-14D No - Sample MW-15 Couplet NAMW-15S X Yes - Down-gradient from Power Block Low-FlowMW-15D X Yes - Down-gradient from Power Block Low-FlowMW-18S X Yes - Previous tritium detection Low-FlowMW-18D X Yes - Previous tritium detection Low-FlowMW-19S No - Sample MW-20 Couplet NAMW-19D No - Sample MW-20 Couplet NAMW-20S X Yes - Previous tritium detection Low-FlowMW-20D X Yes - Previous tritium detection Low-FlowMW-21S No - Sample MW-20 Couplet NAMW-21D No - Sample MW-20 Couplet NAMW-22? No - Sample MW-20 Couplet NAMW-22D No - Sample MW-20 Couplet NAMW-23S No - Sample MW-26 Couplet NAMW-23D No - Sample MW-26 Couplet NAMW-26S X Yes - Upgradient of Power Block Low-FlowMW-26D X Yes - Upgradient of Power Block Low-FlowMW-30S X Yes - Cross-gradient of Power Block Low-FlowMW-30D No - Sample MW-30S NAMW-31S No - Sample MW-32 Couplet NAMW-31D No - Sample MW-32 Couplet NAMW-32S X Yes - Down-gradient of Power Block Low-FlowMW-32D x Yes - Down-gradient of Power Block Low-FlowMW-33S x Yes - Down-gradient of Power Block Low-FlowMW-33D X Yes - Down-gradient of Power Block Low-FlowMW-34S No - Sample MW-33 Couplet NAMW-34D No - Sample MW-33 Couplet NAMW-35S No - Sample MW-7S NAMW-35D No - Sample MW-7S NAMW-37S No - Sample MW-30S NAMW-37D No - Sample MW-30S NAMW-38S No - Sample MW-30S NAMW-38D No - Sample MW-30S NAMW-39S No - Sample MW-26 Couplet NAMW-39D No - Sample MW-26 Couplet NA

Note

NA = Not Applicable

Page 1 of 4

Table 2b

Summary of Sampling Program - July/August 2007FirstEnergy Nuclear Operating CompanyDavis-Besse Nuclear Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

Well Groundwater Sampling SamplingDesignation Sampling Well Selection Rationale Method

Historic WellMW-12S X Confirm June 2007 sampling result Low-FlowMW-12D X Down-gradient from Power Block Low-FlowMW-30S X Confirm June 2007 sampling result Low-FlowMW-30D X Cross-gradient from Power Block Low-FlowMW-31S X Down-gradient from Power Block Low-FlowMW-31D X Down-gradient from Power Block Low-FlowMW-32S X Confirm June 2007 sampling result Low-FlowMW-32D X Confirm June 2007 sampling result Low-FlowMW-33S X Confirm June 2007 sampling result Low-FlowMW-33D X Confirm June 2007 sampling result Low-FlowMW-34S X Down-gradient from Power Block Low-FlowMW-34D X Down-gradient from Power Block Low-FlowMW-37S X Cross-gradient from Power Block Low-FlowMW-37D X Cross-gradient from Power Block Low-Flow

Note

NA = Not Applicable

Page 2 of 4

Table 2c. Summary of Sampling Program - September/October 2007FirstEnergy Nuclear Operating CompanyDavis-Besse Nuclear Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

Well Sampling Groundwater Sampling SamplingDesignation Well Selection Rationale Method

New Well

MW-100A X Yes - New well for Groundwater Protection Initiative Low-Flow

MW-100B X Yes - New well for Groundwater Protection Initiative Low-Flow

MW-100C X Yes - New well for Groundwater Protection Initiative Low-Flow














Historic Well

MW-1S No - Concentration below detection limit (June 2007) NA

MW-1D No - Concentration below detection limit (June 2007) NA

MW-2S No - Sample MW-101 Triplet NA

MW-2D No - Sample MW-101 Triplet NA

MW-3S No - Sample MW-101 Triplet NA

MW-3D No - Sample MW-101 Triplet NA

MW-4S No - Sample MW-12 Couplet NA

MW-4D No - Sample MW-12 Couplet NA

MW-5S No - Sample Couplet MW-35 and Triplet MW-101 NA

MW-5D No - Sample Couplet MW-35 and Triplet MW-101 NA

MW-6S No - Sample Couplet MW-35 and Triplet MW-101 NA

MW-6D No - Sample Couplet MW-35 and Triplet MW-101 NA





MW-12S X Yes - Previous tritium detection (860 pCi/L in July 2007) Low-Flow

MW-12D X Yes - Previous tritium detection (1,155 pCi/L in July 2007) Low-Flow



MW-15S X Yes - Up-gradient of tritium detections at MW-12 and MW-34 Low-Flow

MW-15D X Yes - Up-gradient of tritium detections at MW-12 and MW-34 Low-Flow





MW-20S X Yes - Up-gradient of tritium detections at MW-12, MW-33 and MW-34 Low-Flow

MW-20D X Yes - Up-gradient of tritium detections at MW-12, MW-33 and MW-34 Low-Flow



MW-22S No - Sample MW-20S and MW-23S NA

MW-22D No - Sample MW-20 and MW-23 Couplets NA

MW-23S X Yes - Up-gradient of tritium detection at MW-37S Low-Flow


Page 3 of 4

Table 2cSummary of Sampling Program - September/October 2007FirstEnergy Nuclear Operating CompanyDavis-Besse Nuclear Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

Well Groundwater Sampling SamplingDesignation Sampling Well Selection Rationale Method

MW-26S No - Sample MW-20 Couplet NAMW-26D No - Sample MW-20 Couplet NA

MW-30S X Yes - Previous tritium detection (1,149 pCi/L in July 2007) Low-FlowMW-30D X Yes - Previous tritium detection at MW-30S (1,149 pCi/L in August 2007) Low-Flow

MW-31S X Yes - Previous tritium detection (7,322 pCi/L in July 2007) Low-FlowMW-31D X Yes - Cross-gradient of tritium detections at MW-32 Low-FlowMW-32S No - Sample MW-31 Couplet NA

MW-32D No - Sample MW-31 Couplet NAMW-33S X Yes - Previous tritium detection (2,702pCi/L in July 07) Low-FlowMW-33D X Yes - Previous tritium detection (3,271pCi/L in July 07) Low-HowMW-34S No - Sample MW-33 & MW-12 Couplets NA

MW-34D No - Sample MW-33 & MW-12 Couplets NAMW-35S X Yes - Cross-gradient of tritium detections at MW-12 Low-Flow

MW-35D X Yes - Cross-gradient of tritium detections at MW-12 Low-Flow

MW-37S X Yes - Previous tritium detection (2,961 pCi/L in July 2007) Low-Flow

MW-37D No - Relatively low tritium detection (135 pCi/L in July 2007) NAMW-38S No - Sample MW-37S NAMW-38D No - Relatively low tritium detection at MW-37D NA

MW-39S No - Sample MW-20 Couplet NAMW-39D No - Sample MW-20 Couplet NA

Note

NA = Not Applicable

Page 4 of 4

Table 3Summary of Analytical Program - June, July/August, & September/October 2007FirstEnergy Nuclear Operating CompanyDavis-Besse Nuclear Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

lone 2007 Sampling Event

Well Tritium (EPA Method 906.0) Gamma (EPA Method S01.1)Designation N MS/MSD FD LD EB N MS/MSD FD LD EB

MW-1S X XMW-ID X XMW-7S X x

MW-12S X X X XMW-15S X xMW-15D X XMW-18S X XMW-18D X xMW-20S X X X XMW-20D X XMW-265 _ xMW-26D X X X X

MW-30S X XMW-32S X XMW-32D X X

MW-33S X X

MW-3A X X

MAW-EIB x x

|uly,/August 2007 Sampling Event

well Tritiu (EPA Method 906.0) Gamma (EPA Method 91.1)Designation N MS/MSD FD LD EBl MS/MSD _FD LD EB

MW-125 XMW-12D XMW-30S XMW-30D XMW-31S XMW -31 D X

MW-32S X XMW-32D XMW-33S XMW-33D XMW-345 XMW-34D XMW-37S XMW-37D X

September/October 2007 Sampling Event

well Tritium (EPA Method 90.0) Camma (EPA Method 901.1)Designation N MS/MSD FD LD EBl N MS/MSD FD LD EBl

MW-12S X XMW-12D X X X XMW-15S X XMW-15D X XMW-20S X X X XMW-20D X xMW-23S X XMvW-3OS X X X XMW-30D X XMW-31S X X X XMW-31 D X XMW-33S x x X XMW-33D x XMW-35S X XMW-35D X XMW-37S X XMW-100A X X X XMW-100B X XMW-100C X XMW-101A X XMW-101B X XMW-101C X XMW-102A X X X XMW-102B X XMW-102C X X

MW-103AMW-103BMW-103CMW-104A

x

xxX

x

xXX7 X

MW-104B x x

MWE-104C X ____ _____ IMW-10'A _____ _____

xx

X -WdI- ..vldnd., gv..&t. FD - Eidd Dýplikt

5tS/NID - M-i. Spik,'/M-,i.Spkph,-c ID -bN1,Doy D~ph-,. N-No"`,-'s"vr'

FH q.ip.- B h.vE

Table 4Summ.ry of Gro.ndwater Gauging DataFirstEnergy N-l-ar Operating CompanyDavis-Besse Noclear Power Station5501 N. State Route 2 P053085, Oak Htrbor, OH 43449

Well Measring Measuring Geologic Unit Depth to Water (feet below MP Groundwater Elevation (feet ASL)

Designation Point otee tion Monitored 11 June 2007 31 July 2007 24 September 2007 11 June 2007 31 July 2007 24 September 2007toeet ASLI

MW-10(B Top of PVC 586.4 Upper Dolnmoi' NA NA 12.78 NA NA 573.96MW-IXIC To, of PVC 586.27 1Uoe Dolotite " NA NA 12.71 NA NA 573.56MWl-I (A A 38VC . . 56197. . . Til NA NA 1 5.15 Aý NA .1... 71192

MO250 . . T5SI1'f VC... 5869.0 . U0TDl nw NA NA 1ItO NA NA 572:00MW-hlI1C ToPVC 58....587.18 LWooD1linit, NA NA 22.73 NA NA 54A5.m W. 02A ---. ý- Pv -T pT"Y . . 5-.(,T. -Till ------ N-A------- 13 "-NA 572-9 -M IT::-1:82 ............................. Tp - c VC ......... 585 ....... ... . ... ni. NA NA i. 1A.8. NA ... . 573.23.MP5.o . . . N. . . . .1PV.t5.5. [...............NA...2....ANAt55 .. ................A: NA 172.17pv 5151N:N 2.8N 5

W 3Tfl. .A. . . . . . . ...5..1.. ..T.l. . . NA .. NA - - - NA .. 517.01 .17MW0M T ;p i PVC q....592..2. ............... tii . N A .......... NA 1..27 A.... . NA.. NA: .mW-11tIC . , .. . .5....T, NA NA ,. . . . . A............ NA ..... 517.62MW-104A Top ,i PVC 585.25 Till NA NA 12.73 NA NA 572.52M115-1114B T!!pol! PVC. . . 5841.98. . .Ipp, -ISSSiI, NA NA 11.91 NA NA 573.507

- .1C-I8.IC.............4.....4U•' 'ltI,. NA. NA 51.6 A.NA.....1.37.65191.1)5A 1 p5I . . . .5,55146. . Ca53i595 T NA: NA 116777 NA: NA 5875 .

M W-t T15" MAC 58p7 t, OLii 1195 NM) NM5183 N M NM

61WIS. . . . TpFP1C . . .5.9. ...p .OS 1 N... NM N.. . .N NM NM 5.....Mt-ID T5~SPC . .97 MINOSSiiSN NM NM NM N NMMWI2S- T 'poIV 5,44.4 UpN~lol NM N M N M N M N M N M6115-10 To PVVC r.rv.r9 . . o8 5 ........ i~ NM NMrrN-.. . . .N,,, NM NM-

W S T o o P V C 8 .I 9i iDM M . ............ ... ... ................ ...... N M N .... ...... ... ...... K M -N M ............. N m ............. . . . . . . . . . . . . . .

... O T .PVCN. . 8 6 .G Iii.;N N M .......................... ...... N7 m....... NM -- NM--. .. .NMM61 -lO .. .. 583.79. . 4 m

780 ... . .. . ... . . M.N. .N.............. N M .K............

MIW-45.TI.. . . f PVC 588.69 Upperr Dloite. . . .57 NM NM 571.M7 NM.NM NM.MI V- 0 0 Ti ;'f PV C 588.. . ... 7.. .. o......i ... N M N M N M N M.....N M N M.

NRS-11S.....Tr,f 5PVC 5M-O88 Upps~ iDeM-ii NM NM NM NM NM NM

M.....o. . . . ......... 56 T. or 'ol . . . . NM NM W. NM ....................... NM NM

S --------12 . . . Top ýf o Ppvcc 58599 . . .... .. Lo- e O D ,Iorni . . .Nf14 91 7 N Mo 7.5 7 2

..... ...........VC24..... . ....... NM ' NM . NM.. -NM

M W -4 S " T o ,n f P V C 5 88 .5 9 . . . .. . ;:tp , D o lo:il 91 "9'r I I-... . rM 9.. .. . .. [ -r N. I¢I: . ... .............. .. .. ... . .. .. M... .. ..... . ... ..... M . ... . ... .... . . N M . . .. ..... ... ......... .. ... . .... . ... .. .

MW-61)D To o PVC5 7 ....... ' .. . . . o i NM..N............................ 37 . N NM NMM NMMIS-I.O T.....P.C... . . . .. .. . . . .. . . . .N . ..13. .~1418........... 57M7 NM5

NJ0 -15 . . . . DV 16m i : 554.M147712 NM 57M56161210. . . . . pof PVC. . 5775.62Upe D:oloini. . . 27 NM NM 5747 NM NM

S 59 110 .. . T. p PVC 5,46. . .. , ...- - --..... .... NM..44......................... m. - . . . .................... I I. ............ ,.............. NM 54 4........ M ....................... .. ............................

MiS-S T,,p,,fPVC- - - - 5 -79toi~Ii NM NM NM NM ___ MNlnl -T,,pSPPVC 589 U r, O Di79O it, i7 ~ 1 4:1 - - - - - - - - - - - 4.98-50 ------- 571.457

M.. W- 2D Tpi, ,f PVC 5.5.96........c..n.....1..41 M.14...5725. 1....6 D ..-. . . . T 6pol50..... 4NN. ....................... N.. ...... ...N N M

MW-7 I . . . To ,f PVC 5S7.9 .....5... .. U •, D .olo.t... . ..NM NM NM NM.N .. ... .... NM NM NM..

MW1 5.5 . . . fPVC . 5&5p.. . .. . .I . .-13... .. . MM ............ ... .. . ..........................M . -2l ... .............. ... . . . . .. . ... 1. . .......... -9 N M.. .. N M.. ............. N M ........................

MW.'35TopsI6fPVC 5m49."i.I~jjCO5-S 13M4 NM ._ _ . 193 .M NMý2 57 571627

"IMW- ...D .. . .. T..PVC .5574. . .... oe Io.... ....... 1n ......................... . NM "NM .............. 7..... NMI .... NM 9 NM

619130 . . . T,,pfif PVC. . . 5847. ..6o Up t~. . . . 50 147N19M547538 75

M.......M............5.......... I ..........MN 17 .. . . .. ........................... 5-- -r .... ................

616-11 Topol PVC 596.M9 U0- DO,06 . . N 1500 150- NM 571305709

. 5 ..-. ..NT f piIi.5 9.l. 1 9S.ToUp5 55$ 7 9 L ; . , . i 3 ... . . .15...1 00.... ...... ... ... 1 4r1 N M 5 7 2 2 3 . . .......... 4 N M I I "I

6161-...T.....V 55.7 . .to . oo~ . . . 34 410 I 577 57 177 9N

. 1 ..2 Tio fPVC r.. . . 575 . .............. U iDI ............. ..ii .5 14 M 149. • 57270 5 1 571..... 7215 ............. 0 TNM f 588M . . r9 ............ ........................ N1N85 ........... -N .- N .. NM

MW-21 D Top of PVVC 588.58 m1 Up oiiOr5,mit NM N MN MN

.. ..-.4. TT I PVC'581.97 - 1 . ................................. . NM -- ....... ......... W . . . . . . ............. . NM 5 2 .-. .. N NM

M W - 2 0 D . . . . T • "hi~? P P V C 9 9 -.... 9 9 99 r 9 9 . 5 8o 5, 9 ... .. ..... .. . . . . . . . ... -n i . d " D 1 • i i t { . . . . . ...... ..... ....... ................ .. ........ . . .... .. .. . .. . ... . .. .. .... ...m4 .M M .... .... .... .... ... . .... .... .... .... ............... . .... ... . .. . . .. . . . . .......... .... .... .... .... ... . .... .... .... .... ............ .... ... . . ...

6V-219-50 . . To -iPC529 per Ooý,tifNMNM2119N NM 5186109-310 . . . T:ýpi6f PVC . . . .- 59284. . . .121,j. Di'lSt 66 NM 20.. . . N .... .. I NM '. 57211 .

. 1 .. . ..70~Tp kl~~568.7 .~U 1 clPD ii. .~1323.... N14 N.. 5. ....... NM 5.5751MW61-21D T(p ,iPVC7555..7-... I Sw-D S N-15. . N ... . . NM 564 -. . .--.... 5.-.

-r 55---- o Ti u --- -2 -- -- NM- NM~ ~4o616.-... T3p68 .V 58.2 . ... e'~lo l NM.N NM . . .NIN M

MW-6959. T:p, " PV.V5. oNM ............................. M .NM NM 5. NMN..... M.M V-31D ......... .. T, ...00 ....... N NM 5N ... ..... . W - 1 . . . . . . . ... . . . . . .. .. . . . 1 ,: J rP V C -.. .. . . . . .. . 5 -8 8 12 0 -... .... . . . . . . . . U p r -i LI,7 • L ,~•¢ - . . . . ...... ................ 3 8- .. . .. . . . . . .. ... . . -1 4 ý .. ..... . . ... . ..... .. . 154 2 .. . ...... .............. ..... N7 4 - - -.. .. . . . . . . . . . 5 7 1 -6 g .. ..... .. . ... .. ....ý%9

MW-32D T,,p,,f PVC ~~~586.17 U ý o - .21:052NM W -3 2 T I o.P... . ................ T 5e'i D o l,~ 1 . .. . .. . ... ............ . . 13 .17 .. . . . . 14 :5 ,1 ... .......... .. .. .. .. ......... 5.... ..... ... .. ........ ................ .. .... ......... ......... ......... ...... ...I S '

-, ----A - -o Applicabl01 tMW-34 rSTo, V58.1U jM1 r N

Ocalos Tolphet PV- b85.d. Po-oo Ds.16.oedt NMeo e 1405N ll718

... fSV2 3 .... ... . .. .. . ..... T f VC -... .. . .,58 -.. . ..... . ... .311 ia ,•;'er Do31 omih • N M I""4 ........... "I""""' 13 20.... ... .............. N M1 . . . . . ... . 571 15 . .. . .M A 3 4 .1 S ....... TT- p 99V .. ... . .. ... 95 8 6" ) 7q -. U ti'f~ b iij { .. . .. .. . ..... .. N M r .. ... .. .......... .. .. .......1.1 ........ ...... ... . ... . .... ..... i.......................... .. . . ...O R .. .. ............ ..... ..................N M1-3 .. .......... ............................. hi ......... .. ..

MM W D . . . . . . . . T p V . .. . . . . . 8 . 7 .. . . . . . . . . a w } D i i ti .. ... .... ... . . . . . N . . . .. .. ..... ... ... 4 0 .. ...... .. .. . . .. ... U , ............ ... .... ...... .. .. . . M .. .. .... ..... ... ... ......... 558:. .. .. ............................. ........... 1'6M ................

MW-55Ti of Pc 585.2. pe Dolnmilim NM NMM N11 i IA . .518

- M -88..................NM N M-.................-..................- .....'.. .... I-...... ....... r- . ............... ........ .......... __ . .. N- .. ..--- -- .....

N te.Al h-~wtwvat , !I,fi -Ltl, t,, n h-m' ~ el(e -I -v .,lw)NA -No, A pp~wltb,NM I N".m, -e~ndMP -- Mis~ng PNin': Re...i1-.mighed b.- bi.•-d. P--,•sr ,+,-d uN ,po oenig wel1

0

Table 5Summary of Groundwater Field ParameterFirntEnergy Nuclear Operating CompanyDanis-Besse Nuclear Power Station5581 N. State Route 2 MS3085, Oak Harbor, OH 43449

New Monitorina Wells

Parmete Well ID MW-100A MW-100B MW-100C MW-101A MW-101BI MW-IOIC ,fW-102A MW-102B MW-102C MW-103A MW-103B MW-103C" MW-104A MW-104B MW-104C MW-105ASampling Date 24-Sep-07 25-Sep-07 25-Sep-07 02-O0t-07 02-Oct-07 02-Oct-07 25-Sep-07 27-Sep-07 27-Sep-07 01-Oct-07 01-Oct-07 01-Oct-07 28-Sep-07

28-Sep-

0 7 28-Sep-07 8-Oct-07

Temperature ("C 16,5 17.4 17.0 14.1 14.6 15.4 181 15.5 16.1 15.1 14.1 14.5 14.1 14.2 16.2 19.8Specific Conductivity (uSfcmn) 2,958 2,746 8.883 1,980 2,091 161,500 2,635 2,482 140,700 2,421 2.458 121,000 2,506 2477 21,210 2,381D1ssotved Oxyg-n (.g/1) 4.24 1313" 1.58 2.07 3.08 <.00 25.07" 3.47 <2.00 5.92 2.88 0.92 15.01" 971" 6.12" 1.74

H (-) 71 7 1 7.3 6.8 7.3 6.0 6.9 7.2 6.8 7.1 7.2 6.8 6.9 7.1 7.3 6.9Oxidation Reduction Potential (mV) -127 -213 -322 -4 15 -315 -191 -213 -368 -196 -232 -259 -120 -288 -70 -108Turbid~tv (NTU) 0.47 129 1.01 0.39 2.94 798 NM 1.3 104 1.8 1.2 9.b 22 24 384 3.8

Historic Monitoring Wells

Parameter S el 151 MD W-IS MW-1 D MW-75 MW-12S MW-12D MW-ISS MW-15D MW-18S MW-18D MW-20SrSamtin Date 12-Jun-07 12- un-07 13-jun-07 14-juno07 06-Aug-07 4-ct-07 06-Au -07 04-Oct-07 26-jun-07 O 10-Oct-07 26-jun-07 108-Oct-07 14-jun-07 14-jun-07 _ _-jun-07 09-Oct__ 7

Temperature (C) 140 16.1 16.5 17.5 20.2 179 208 18,8 21.7 21.0 21.2 20.3 16.2 18.4 14.8 18.9Spef. Conductivt (uS/cex) 2.696 6-2,57 1,982 2,187 2,185 2,101 3.762 3,633 2,434 2,327 5,168 4,790 1,260 6,997 1,901 2,233Dissoced Oxygen (rg/l) 210 033 034 0.34 5.52" 38601 0.23 6 30" 041 1.68 0.46 13.68" 8.42" 0.27 0.78 1.71rH (-) 70 70 72 72 73 73 7.2 7.1 7.3 7.2 7.2 7.0 8.8 7.7 7.3 72Oxidation Reduction Potential (mV) -116 -67 4 19 -44 872 -307 -293 -161 42 -320 -321 53 -155 83 -31Turbidity (NTU) 09 1 0 0.5 0.9 0.2 0.5 1.6 2 0 0.3 4 0 4.2 1.8 0.2 0.1

Well ID MW-20D MW-23S MW-265 MW-26D MW-3OS MhW-30D MW-31 S MW-31D MW-325

i Sampling Date 25-jun-07 10-Oct-07 10-Oct-07 13-jun-07 13-jun-07 27- jun.07 02-Aug-07 8-Oct-07 03-Aug-07 09-Oct-07 31-jul-07 5-Oct-07 31-jul-07 8-Oct-07 25-jun-07 31-jul-07

Terper-ture CC) 180 160 138 15.8 17.2 178 172 17.6 17.7 16.7 23.5 245 23.4 Z2.3 22.7 21 6Specific Conduct ...ty (uS/era) 2,150 2,309 2,402 2,216 43,394 2Z224 2,529 2Z365 34,778 38,860 7,484 2,288 22,410 20,110 2.362 1-492

Dssolved Oxygen (.g/I) 024 1.26 1.51 0.43 0.04 071 NM 132 NM <200 0.66 4.52" 0.55 2.40 0.21 775"PH (-) 73 72 7.1 7.2 7.6 70 7.3 7.1 6.9 6.7 7.2 7.1 7.1 7.0 7.4 7.2

Oxidation Reduction Potential (mV) .28 -56 7 37 -303 -66 -105 -25 -366 -356 -116 -148 -287 -316 -04 -92Turbiditv (NTU) 30 0.3 081 1.1 0.9 04 0.3 0 0.4 0.3 1.8 4.1 0.4 0.4 2.6 0.8

Parameter Well ID M17-32D3 MW-33S MW-33D MW-34S MW-34D MW-35S MW-35D MW-375 MW-37D ISampling DOt 26-)un-07 I-Aug-07 27-jun-07 I -Aug-07 5-0,:t-07 27-jun-07 I2-Aug-07 5-Oct-07 2-Auga37 02-Aug,)7 03-Aug-07 03-Oct -07 3-Aug-07 9-Oct-07 6-Aug-if7

Temperature (TC) 20n 21.5 253 255 25.5 24.9 25.2 25.2 25ý6 24.2 19.1 18.4 177 15.2 198Specific Conductivity (uS/cr) 15,235 15,050 2,615 2,554 2,325 7,471 6,337 6,600 2,589 11,031 2,776 6,564 2,477 2,255 113DissoIved Oxygen (mg/ 1) 0.29 NM 1.00 NM 7.07" 0.42 NM 4.93" NM NM 3.24 1.70 NM NM 0.08pH (-) 6,9 68 7T2 7T2 7 1 7= 0 6.6 69 7.2 7ý0 7.2 7.2 7.4 736Oxidation Reduction Potential (mV) -338 -351 -I -96 37 -322 -298 -340 -125 -317 -50 -286 -134 -188 -256

Turbiditv (NTU) 03 04 1.8 07 059 0.3 04 0.25 04 0.4 86 1 5.6 0.4 33

'c -,In,g, G 1,

N U- -n,hl,m.,, 1, ,.

NM - t..m....- -c,,,d,

Table 6Summary of Groundwater Analytical ResultsFirstEnergy Nuclear Operating CompanyDavis-Besse Nuclear Power Station5501 N. State Route 2 MS3085, Oak Harbor, OH 43449

New Monitoring Wells

ISamplee Location I MW-100A MW-10OB MW~v-10C MbAl~w l0A I 51W-1OI1B MW-101 C MWD-102A MW-502B MW-182G MW-103A MW-503B MWV-103C MW801-104AI MW-104B MW~-104G M cW-105ADate Sampled 24-SeL-O7 25-Sep-07 25-Se '-7 2-Oct-07 2-Oct-07 2-Oct-07 25-Sc -07 25-Sep-07 27-Sep-07 27-Sep-07 1-Oct-07 1-Oct-07 1-O-Oct-0 7-Oct-07 28-Sep-07 28-Se -07 28-Sep-07 8-Oct-07SampleTe N N N N N N N LD N N N N FD (DBD-04) N N N N N

Tritius <193 <193 <149 237 207 <193 344 387 394 <193 495 362 394 <149 237 250 <193 1832Gamma IN D NO I ND I ND DI N I ND I N NO I ND I NO I NO I ND I ND DI NO I ND I ND N ND N

Historic Monitoring Wells

Sample Location IMtFb'-IS I MW-1D I MW-7S I MW-S 045-120 MW-15S I MW-OD I MW-I8S MW-IDate Sam Wled 12-jun-07 1 12-1 n-07 1 13-jun-07 1 14-Jun-07 14-oun-07 6-Aue-07 4-Oct-07 6-Au -07 4-Oct-07 4-Oct-07 26-jun-07 10-Oct-07 26-Jun-07 10-Oct-07 14-1on-07 14-jun-07SampleT e e N N D (DBD-01) N N N N FD P DBD-01) N N N N N N

TritiumL <330 <330 426 1 657 764 860 276 1,155 1 738 1 769 375 301 704 442 277 1 204Gamma NO ND ND D ND NA ND NA ND ND ND ND ND ND ND ND

Sample Location ItVW-20S MW-20D I MW-23S MW-26S MW-.26D MW-30S MW-30D MW-31SSample Type N ED (0 -02) N ED (080-02) N N N N N N N N N N N N

Tritium 255 279 189 218 328 <174 306 341 <330 1,307 1149 494 231 <174 7,322 3,149Gamma J ND ND ND ND ND ND ND ND NO ND NA ND NA ND NA ND

Sample Location MW-31S NTW-31D MW-32S MW-32D MW-33S MW-33D ] b41344SDate Sampled 5-Oct-0

7 - 31-jul-07 8-Oct-07 25- un-07 31-j <-07 31-jul-07 26-jun-07 I 1-Aug 7 27-un-07 I1-Aug-07 3-Oct-07 5-ct-07 27-Jun-07 2-Aug-07 5-Oct-07 2-Aug-07

Sample Type FD (DBD-03) N N FD (BD0-01 N N N N N LD N N NTritium 3,012 108 183 - 5838 7,535 7,185 466 507! [ 2,287 2,702 1,110 1,230 2,975 3,271 1,934 2,839Gamma ND NA ND ND NA NA ND NA ND NA ND ND ND NA ND NA

Sample Location MW-34D lstW-35S MW-35D MIA-37S MW-37DDate Sampled 2-Aug-07 3-Oct-07 3-Oct-07 3-Aug-07 9-Oct-07 6-Aus-07Sample Type N N N N N N

Tritiun, 1,076 227 368 2,961 1,231 135

Gamma NA ND NO NA ND NA

NAtesUnt,ý are pC/L ( pii!us pl51,1 Id ll nIni k ah •nc-ntsrat,, Ios{n'hrlhn l}cl, eab*ciry di h i'tinimi t

ND = N,- dnlintiii~ns aoy,-, lobirstiry hlu-. ]inst ni d•,tctirs,NA = N- i endly ed

FD (DBDl) - Fi,-d Optint (Dininn it dupliexui 55-mph- in Iboratory n~pfrl)LD = LbonLry DiDpliisjDi i -mph! in leh'rat-y epir')

Tritium, -nlysiý by EPA MWd-ld 906 (1GDmma innung rdi,-nulides analyois by EPA Metbid 901.1Acelyni prfenud by Midwest L.berte,,yG,,nn< imitting eadi nlclid-tsnalysis innluds:Mn-4, F4-59, C-,58, Co-60, Zn-65. Zr-Nt-95. C,134. C-137, Be-Le-140

0

Figures

7,

Eý

.0

Legend 1:24,000EI- Protected Area

E Site Boundary

0 1,000 2,000 4,000I Feet

Figure 1 - Site Locus MapDavis-Besse Nuclear Power Station

Oak Harbor, OHSource: USGS Topographic Quadrangles(o41083e2, o41083e1)

0

Legend

- Limits of Grout Curtain

,4 Monitoring Well Installed in August 2007,g Historic Monitoring WellA: Till WellBis: Upper Dolomite WellCID: Lower Dolomite Well

L Radiological Area of Potential Concern

Radlologlcal Areas of Concern:

Low Level Rad Waste Storage Building

Dry Fuel Storage Area

Training Center Pond NPDES Outfall 002

Sewage Treatment Plant (Abandoned)

NPDES Outfall 001

Sewage Treatment Plant (Current)

Sanitary Lagoon

South Setting Basin

North Setting Basin

Collection Box Discharge Pipe

Collection Box

Liquid Radwaste Discharge Line

Condensate Demineralized Water Storage Tank

Secondary Demineralized Water Storage Tank

Fire water Storage Tank

Service Building 4 Outfall

1:3,0000 125 250 500 750

Feet

Figure 2 - Site Layout

Davis-Besse Nuclear Power StationOak Harbor. OH

ERM

Legend


-$ Monitoring Well Installed in August 2007

• Historic Monitoring Well

A: Till WellBas: Upper Dolomite WellC/o: Lower Dolomite Well

E Groundwater Elevations24 September 2007

" Approximate Groundwater Flow Directionin Upper Dolomite Unit

Note:

Lake Erie surface water elevation on24 September 2007 fluctuated between570.87 and 571.17 (NOAA MarbleheadGauging Station, OH).

1:2,400

200 100 0 200

Feet

Figure 3 - Groundwater Elevations

Till Unit - September/October 2007Davis-Besse Nuclear Power Station,

Oak Harbor, OH

Legend

- Limits of Grout Curtain

46ý Monitoring Well Installed in August 2007

5,' Historic Monitoring Well

A: Till WellBaS: Upper Dolomite Wellcio: Lower Dolomite Well

Groundwater Elevations24 September 2007 - Monitoring Wells B/S

' Approximate Groundwater Flow Directionin Upper Dolomite Unit

Note:

Lake Erie surface water elevation on24 September 2007 fluctuated between570.87 and 571.17 (NOAA MarbleheadGauging Station, OH).

1:2,400200 100 0 200

Feet

Figure 4. Groundwater ElevationsUpper Dolomite - September/October 2007

Davis-Besse Nuclear Power Station,Oak Harbor, OH ERM

.1

Legend


- Monitoring Well Installed in August 2007


A: Till WellBIS: Upper Dolomite WellC/D: Lower Dolomite Well

Groundwater Elevations24 September 2007 - Monitoring Wells C/D

\ Approximate Groundwater Flow Directionin the Lower Dolomite Unit

Note:

Lake Erie surface water elevation on24 September 2007 fluctuated between570.87 and 571'.17 (NOAA MarbleheadGauging Station, OH).

1:2,400200 100 0 200

IT Feet

Figure 5 - Groundwater ElevationsLower Dolomite - September/October 2007

Davis-Besse Nuclear Power Station,O a k H a r b o r , O H , , ,, .

ERM

Legend


4 Monitoring Well Installed in August 2007

S Historic Monitoring Well

A: Till Well/ss: Upper Dolomite Well

CID: Lower Dolomite Well

Results:

46 Tritium Activity in pCVL

F- Tritium Activity Below Laboratory LowerLimit of Detection (value indicated)

pCi/L picoCuries per Liter

Field Duplicate taken. Highest result shown

- Confirmatory sample taken at the locationin July/August.

Analysis performed by Midwest Laboratoryusing EPA Method 906.0

Notes:

Groundwater monitoring samples were takenbetween 12 and 27 June 2007 during the Junesampling event.

Groundwater monitoring samples were takenbetween 31 July and 6 August 2007 during theJuly/August sampling event (confirmatorysampling event).

Highest results of the two sampling events areshown.

1:2,400200 100 0 200

Feet

Figure 6 - Groundwater Sample Analytical Results

June to August 2007


Legend


- Monitoring Well Installed in August 2007


A: Till WellBiS: Upper Dolomite WellCID: Lower Dolomite Well

Results:

W Tritium Activity in pCV/L

F Tritium Activity Below Laboratory LowerLimit of Detection (value indicated)

pcL picoCuries per Liter

Field Duplicate taken. Highest result shown

Analysis performed by Midwest Laboratoryusing EPA Method 906.0

Notes:

Groundwater monitoring samples were takenbetween 24 September and 10 October 2007.

1:2,400200 100 0 200

FIM Feet

Figure 7 - Groundwater Sample Analytical ResultsSeptember/October 2007


0

F7

A A'

6504 -

584 -

MW-i 52A.B&C

564 - oaIet I =10' 375 0 75 150 350

544-

524-

Legend

Grou.nwator Elevation(Upper Dolornite

I Potential Migration of Tdtiated Water

Groundwater Flow Direction

V Monitoring Wea Installed in August 2007Weon projected on croso-oection

Results (SepternmbanOctber 2007)Triiumr Ac00dt0In hr irng wels (pCIVL)picoCures per Liter

Grourndwater Elevation

FU' and Geologic Units

7' Concrete FI'

General Backfil (Earthen)

Sttuctrat Backlai (Crosned Rock)Wave PFrotacon Dlke FM (Topsoff

Glacolacustrioe UniT51 Utni

Lamninated Dolomite

MacsNve Dolomde

504 -

Z, HitoDr Monitoring Wea' Weo projected on crors-neacon

484 -SGrout Curtain

_• Gap hr Section

464 -

60 0 60 120 240Horizontal Scale (11=120')

15 0 15 30

Figure 8 - Cross-Section ShowingGroundwater Elevations and Sample Analytical Results

Davis-Besse Nuclear Power Station, Oak Harbor, OH

Appendix ABoring Logs

ERM MW-100A MW-100B MW-100C399 Boylston St. 6th FloorBoston, MA 02116 PAGE 1 OF 2

Telephone: 617-646-7800ER/ Fax: 617-267-6447

CLIENT First Energy - Davis-Besse Power Station PROJECT NAME Well Construction

PROJECT NUMBER 0065992.02 PROJECT LOCATION Davis-Besse

DATE STARTED 8/8/07 COMPLETED 8/9/07 GROUND ELEVATION WELL/BORING DIAMETER 2"

DRILLING CONTRACTOR Bowser-Momer, Inc.

DRILLING METHOD Sonic

LOGGED BY G. Ayres CHECKED BY M. Daly

NOTES Boring size is 6" in overburden and 4" in bedrock

I W -- WELL DIAGRAM WELL DIAGRAM WELL DIAGRAMQ > 0 MATERIAL DESCRIPTION M AWOMo

0 _

SILTY CLAY withsome coarse sandand gravel, cohesive,firm, dry, brown withgray mottling.

CL-ML88

< IIz 1

'C0

7.0

10

CL-ML

SILTY CLAY withsome gravel,cohesive, gravelcontent decreaseswith depth, firm,brown.

<a.z 11

18.0

SILTY CLAY withgravel, brown.20

CL-ML

80 23.0Z II

0SII -

CL-ML

CLAY WITH SILT

25.0 and some sand, dark

26.0 graY.dolomite.

laminated dolomite,light gray.

Bentonitechips

-Sand

- Screen

- End cap

- Lement

0)

Cd)

W

C-

(-Xda:

- u.ement

30

40

50

100

38.0

< 00

02

< 00z 1IitO0.-0

- Bentonitechips

- Sand

- Screen

- End cap

- Nativebackfill

E.200

laminated dolomite,becomes fractured at42', light gray.

i_

- Cement

- Bentonitechips

10044.0

no recovery.

(Continued Next Page)

ERM MW-IOOA MW-1OOB MW-IOOCBoston, MA 02116 PAGE 2 OF 2

Telephone: 617-646-7800ERM ] Fax: 617-267-6447

CLIENT First Energqy - Davis-Besse Power Station PROJECT NAME Well Construction


Sn "-D M R .D WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM0j" MATERIAL DESCRIPTION Of MW-00A MW-100B MW-00C

00 _

50 a-__ _ _ _ _ _ _ _ _ __ _ _ _ _ _

I

no recovery.(continued)

60

58.0

6059.0 massive dolomite,

highly fractured, lightgray.

laminated dolomite,fractured, dark gray.

64.0

<2"

ICOC

< IZI

0

70

50

laminated dolomite,fractured, olive gray.

73.0

laminated dolomite,fractured, dark gray.

S82.0

C,

E020

E.2

0)

EM0j

Zz I

80

[Al

50Z II

- Sand

- Screen

- End cap

- Bentonitechips

- Nativebackfill

90

Wwi

COCO

CO

U)XICO

80

laminated dolomite,89.5 dark gray.

massive dolomite,light gray.

Bottom of boring at98.0 feet.

=<Iz 1

C-it

100

11

ERM MW-101A MW-101B MW-101C399 Boylston St. 6th FloorBoston, MA 02116 PAGE 1 OF 2Telephone: 617-646-7800

EW/ Fax: 617-267-6447



DATE STARTED 8/14/07 COMPLETED 8/15/07 GROUND ELEVATION - WELL/BORING DIAMETER 2"





I ~ o~ -(~)..-c

( W . . WELL DIAGRAM WELL DIAGRAM WELL DIAGRAMa-ip > MATERIAL DESCRIPTION 0) ' MWllOo < 2 W MW-101A MW-101B MW-101C

00 f __ 0 ý

10

15

20

SILT with some sandand clay, firm,cohesive, dry,reddish brown.

90ML

-C:

Ci"C

"U

9.0

SILTY CLAY withtrace sand, firm,cohesive, tight,brown.

100 CLEL{

•-rn--0

20.0

0

LL

0)

a-

F-0)

25

30

35

40

CLAY WITH SOMESILT and trace sand,firm, cohesive, tight,moist, dark gray.

ME

- Bentonitechips

-Sand

Screen

- End cap

- Cement - Cement

CL-1001ML

oLn•II

-u O

- Bentonitechips

-Sand

- Screen

NOW- Cement

29 504-,"- -

weathered dolomiteand clay, very tight

Eýand firm, light gray.laminated dolomite,light gray.

10

C,-

o2.E0

0

E0

- Bentonitechips


ERM MW-IOIA MW-101B MW-101C399 Boylston St. 6th FloorBoston, MA 02116 PAGE 2 OF 2Telephone: 617-646-7800

ERM Fax: 617-267-6447



L.w .2 MT L Ro WELL DIAGRAM WELL DIAGRAM WELL DIAGRAMw •o 6 < ",° MW-101A MW-101B MW-101C

0 ý of 0)0 z40D U) Z a

40 FT

I

massive dolomite,fractured, light gray.

45

50

55

60

65

70

75

80

85

0O

-End cap4. n80

70

laminated dolomite,gray.

48.0

laminated dolomite,light gray.

57.0

laminated dolomite,light gray to darkgray.

65.0

laminated dolomite,dark gray.

79.0

0

C5

02

0 I

0F0

.2

E0aM

E0C)

_j

0I

5002

EL-

W

U)U)w

(D0ý

waaU)

90Ec

- Sand

- Screen

-End capBottom of boring at

80.0 feet.

0:

ERM

ERM399 Boylston St. 6th FloorBoston, MA 02116Telephone: 617-646-7800Fax: 617-267-6447



DATE STARTED 6/16107 COMPLETED 8/16/07 GROUND ELEVATION - WELUBORING DIAMETER 2"





0

>-

0C,wu

C6b C)

0-0

(D

SILT AND SANDwith trace clay, firm,

CLAY WITH SILTand some sand, firmto hard, cohesive,tight, dry, brown.

laminated Dolomite,fractured, gray.


ERM MW-102A MW-102B MW-102C399 Boylston St. 6th FloorBoston, MA 02116 PAGE 2 OF 2

Telephone: 617-646-7800EIM Fax: 617-267-6447



~Ez--I~~C 'El) 0-L

I- w j ._o WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM(6 < 0 MATERIAL DESCRIPTION MW-102A MW-102B MW-102C

4D U_

0

45

50

55

60

65

70

75

80

85

massiveDolomite with somefractures, light gray.

45.090

90

laminated Dolomite,dark gray.

49.0

laminated Dolomite,light gray to darkgray.

59.0


69.0


78.0

Lfn

FooI

U.,co

E

E00

(0

E)

-J

-End cap

aQ- Nativebackfill

IA)

90

oU.'0 1

02FL .._

- Sand

- Screen

- End cap

- Nativebackfill

U)

LU

0-

a-(If

U)W

80ZII

02

II r."___


ERM MW-103A MW-103B MW-103C399 Boylston St. 6th Floor

• Boston, MA 02116 PAGE 1 OF 2

Telephone: 617-646-7800ERIN4 Fax: 617-267-6447

CUENT First Energqy - Davis-Besse Power Station PROJECT NAME Well Construction







0E-C '

W C DSRPI .N2 WELL DIAGRAM WELL DIAGRAM WELL DIAGRAMu MATERIAMW-103A MW-103B MW-103C

0

No recovery.

0

<2z 1iZ II

II .r

0)

C

U

0U

010.010

60

CL-ML

SMCL-ML

CL-ML

SILT AND CLAYwith some sand and

13.0 trace gravel, firm to1 soft, cohesive,14.0 brown.

16.0 \ SILT AND SAND1 6 .0 w-.wit h s o m e g r a v e l,

firm, cohesive, gray.CLAY with silt,orange motteling,firm, cohesive, gray.

and some sand, firm,cohesive, brown.

---

20

30

100

C

26.0

- Cement

- Bentonitechips

- Sand

- Screen

- End cap

CLS

CLS

- Cement

V CLAY with somesand and cobblefragments, firm,

30.0 cohesive, tight, dark... gray.

CLAY with somesand and cobblefragments, firm,

34.0 cohesive, dark gray.

weathered dolomite,36.0 white.


100

C IIac

Bentonitechips

- Sand

- Screen

- End cap- Native

backfill

- Cement

- Bentonitechips

0.

0

0 40 40.0

I laminated dolomite,gray.

44 n

80 I massive dolomite,gray.

00"

C E0o

48.0

50


ERM MW-103A MW-103B MW-103C~4L. 399 Boylston St. 6th FloorPAE2O2

Boston, MA 02116 PAGE 2 OF 2Telephone: 617-646-7800

ERM Fax: 617-267-6447



- E-c-~

w D R I • . WELL DIAGRAM WELL DIAGRAM WELL DIAGRAMw 0 V5 _< M MW-103A MW-103B MW-103C

~ 2: 0" "J w

0

52.0 laminated dolomite,\dark gray.

(continued)

laminated dolomite,brown to white.90

030

02

58.0

60

80

• 59.0 laminated dolomite,

~laminated dolomite,__ 62.0 brown.

laminated dolomite,

dark

gray.

laminated dolomite,

1 79.0

dark gray.

-o0-

E20

_j

70

90

02II 11

80Bottom of boring at

80.0 feet.

- Sand

- Screen

- End cap

- Nativebackfill

11

0

uiV)Cr

90

100

PI~L.LJLL 1 4.

ERM MW- 04A MW- 04B MW- 04C39 Boston, MA 02116 Floor

PAGE 1 OF 2•"• 39Boyston, St. 016tFor

Telephone: 617-646-7800ER.4 Fax: 617-267-6447








•MS WELL DIAGRAM WELL DIAGRAM WELL DIAGRAMW 0 <MW-104A I MW-104B MW-104C

W 0 )

0 F__ _ _ _ _ __ L __ _

FILL M1.0 GRAVEL.

5

10

15

20

25

30

35

4n

10

I2

II iDC Co

Uii_

09

CL-ML

SILTY CLAY withsome sand, tracegravel and cobbles,cohesive, dry, brown.

14.0 cc.

55

U)U)0j10

LU

a-

U.i

(n

LI

-- II

MC.LL 15. CLAY with trace silt • _CL- and sand, soft,

cohesive, black.

CLAY with some siltCL- and sand, firm,ML cohesive, brown.

...23.0CLAY with some silt Cand trace sand and C:I

gravel, soft, IIcohesive, dark gray. 0

CL-ML

M30.0•,•//,,••., CLAY with some

CLS sand, wet at 32 ft,32.0 firm, cohesive, dark

weathered dolomite,light gray. 1

35.0 C n-

- Bentonitechips

- Sand

- Screen

- End cap

- Cement

100

100

- Cement

- Bentonitechips

- Sand

- Cement

- Bentonitechips

laminated dolomite,gray to light gray.

0102

0

-j

4An n


ERM MW-1 04A MW-1 04B MW-1 04C399 Boylston St. 6th Floor PAGE 2 OF 2Boston, MA 02116Telephone: 617-646-7800

ERMV Fax: 617-267-6447



MT ER I A ._2 WELL DIAGRAM WELL DIAGRAM WELL DIAGRAM0.~ -- a) )

MATERIAL DESCRIPTION o MW-104A MW-104B MW-104C

40 F.

P

45

50

55

60

65

70

75

80

85


- Screen

49 0

50

70

masisve dolomite,light gray.

.. .45.0

laminated dolomite,dark gray to white.

... 57.0


69.0

laminated dolomite,gray to dark gray.

' .79.0

0

I-

0

E

to

"0

E0

0

-J

- End cap

- Nativebackfill

Il)

90

I-0

IIC

Eu -Sand

- Screen

- End cap

- Nativebackfill

C)

co)

CD

90

(C

CL


Il)

ERM MW-105A399 Boylston St. 6th FloorBoston, MA 02116 PAGE 1 OF 1

Telephone: 617-646-7800E]RM Fax: 617-267-6447








E•-

a U ý_ W ._o WELL DIAGRAM> o L 6 MATERIAL DESCRIPTION ) " o WELDAA WELL DIAGRAM WELL DIAGRAM

(D

0 ___________________ _______________

5

10

15

20

FILLSANDY SILTYAsphalt sub-base,

2.0 loose, dry.

20

cZ

0_2

0J

U

0Um0

CLAYEY SILT withsome sand and tracegravel, gray mottling,moist, brown.

100 ML

20.0

(D

0

U)a-

U)

25

30

35

40

CLAY WITH SILTand some gravel andsand, wet at 27 ft,weathered bedrockfragmetns starting at6.5 ft, dark gray.

Cement

Bentonitechips

Sand

Screen

-Nativebackfill

CL-ML100

28.0weathered bedrockand clay, light gray.


Appendix BData AssessmentJune &July/August 2007Monitoring Events

0

1.0 INTRODUCTION

This section presents a quality assurance and quality control (QA/QC)review of the Davis-Besse June and July/August 2007 well groundwatersampling events. This evaluation was conducted to assess and enhancethe reliability and validity of the groundwater analytical data. Theverification process was conducted to identify the most common samplingand analytical problems that could affect the quality of the results. Ingeneral, the results met the data quality objectives.

2.0 QUALITY ASSURANCE

Quality assurance involves planned and systematic actions necessary toprovide confidence in the analytical results. The goal of the program is tohave a program that is operating within acceptable criteria; therebyenhancing the representativeness and comparability of the results.Qualitative measures include items related to the field as well as thelaboratory activities.

2.1 SAMPLING PROGRAM

The procedures used to collect the groundwater samples were detailed ina FSP (ERM, 8 June 2007). Specifications, such as well locations, wellconstruction, sampling intervals, sampling and analysis techniques wereitems among others that were described to help collect a useful data set.A list of sampling locations and analytical program summary tables wereprovided for the July/August 2007 groundwater monitoring event.Groundwater samples were collected by personnel from BETALaboratory. Field notes were reviewed to confirm that the procedureswere executed properly. The following information reviews items thatwere included in the field sampling quality assurance program.

Sampling documentation - The sample team maintained a fieldnotebook (bound weatherproof logbooks) that was filled out ateach location where a sample was collected. It contains the sampledesignation, collection time, description, and field instrumentcalibration log. The team also completed a Low-Flow GroundwaterSampling Form at each monitored location. The forms presentinformation regarding location, weather, time, well construction,

ERM/DADE MOELLER 1 FIRSTENERGY - DAVIS-BESSE 0065992.218 MARCH 08

sampling depths, sampling device, field parameters and samplecontainers. The completed Low-Flow Groundwater Samplingforms are included within Appendix B.

" Sample Identification - Well IDs were used to identify thegroundwater samples. The same codes were used to complete thechain-of-custodies (COCs). Duplicate samples were recorded asblind samples. Actual duplicate sample IDs were recorded on eachLow-Flow Groundwater Sampling Form. COC records are includedwithin Appendix B.

" Decontamination - Dedicated high density polyethylene (HDPE)tubing was used at each location. Wells were sampled using aperistaltic pump (no decontamination required).

* Calibration and Preventive Maintenance of Field Instruments -Sampling team personnel calibrated the geochemical parametersprobe every day before starting the sampling. Calibration logs weremaintained in the notebook. ORP readings did not stabilize duringJune sampling of well MW-20D. The ORP probe was cleaned afterthis sampling and the meter accuracy was successfully checkedutilizing calibration solution. Dissolved Oxygen reading could notbe taken for about 57% of the wells sampled in July/ August 2007due to probe interference with hydrogen sulfide.

* Sampling locations - All locations were sampled as planned in theFSP.

" Gauging - A synoptic water level gauging round, including all ofthe monitoring wells selected for the evaluation of tritium andgamma emitting radionuclides, was performed on 11 June 2007prior to sampling.

* Sampling Depths - Sampling depths were reported on theindividual Low-Flow Groundwater Sampling Forms. Samplingdepths were consistent with sampling depths recommended in theField Sampling Plan.

" Field Duplicates - All duplicate samples were collected inaccordance with the FSP.


2.2 ANALYTICAL PROGRAM

Groundwater samples were analyzed by MidWest Laboratory for analysisof tritium by EPA Method 906.0 and gamma emitting radionuclides byEPA Method 901.1 as specified within the FSP. MidWest Laboratorycurrently performs radiological environmental monitoring for over 20nuclear power plants in 11 states. In addition, the laboratory is certified toperform analysis of drinking water for radionuclides in Illinois, Indiana,Wisconsin, and Kentucky. Midwest Laboratory maintains a QualityAssurance / Quality Control Program based on 10 CFR Part 50, AppendixB and Reg. Guide 4.15.

3.0 QUALITY CONTROL

The analytical data were assessed in terms of precision, accuracy,representativeness, comparability and completeness (PARCCs) to evaluatethe usability of the results generated. Quality control items wereevaluated through laboratory checks (e.g., matrix spikes, duplicatesamples), and sampling method reviews (equipment blanks, trip blanks).In addition, MidWest Laboratory has participated in interlaboratorycomparison (crosscheck) programs since the formulation of their qualitycontrol program in December 1971. Results of the interlaboratory programare presented at the end of this appendix.

The following information provides background on the types of QCsamples that were used to assess if the data quality objectives of thesampling program were met.

Equipment Blanks - Equipment blanks are samples collected toevaluate the potential cross-contamination of samples due to thesampling equipment. They are collected by pouring deionizedwater over the sampling equipment which comes in contact withthe groundwater sample. During the June and July/August 2007sampling event, all monitoring wells were sampled with dedicatedequipment. Therefore, no equipment blanks were collected.

Field Duplicate Samples - Field duplicate samples are analyzed tocheck the accuracy and reproducibility of the laboratory analyticaltechniques. A field duplicate sample is taken from the samemonitoring well, one immediately after the other using the samesampling device. Field duplicates are typically collected at locationswhere concentrations of COCs are expected to be present. Asrecommended in the field sampling plan, two duplicate sampleswere collected during the June 2007 sampling event (sampling


locations MW-12S and MW-20S), and one during the July/Augustsampling event (sampling location MW-32S).

Laboratory (Split) Duplicate Samples - A laboratory duplicatesample is created when the laboratory splits a normal field sample.It is conducted to evaluate the precision of the laboratory. Thelaboratory conducted the analysis of one laboratory duplicatesample for the July/August sampling event (duplicate of fieldduplicate sample from location MW-32S).

" Matrix Spike and Matrix Spike Duplicate samples - Matrix spikesamples and matrix spike duplicate samples are normal fieldsamples to which a known quantity of a chemical constituent isadded in the laboratory. Spike samples are used to evaluate theprecision of the laboratory and the effects of matrix interference onthe analysis. MS/MSDs are typically collected in areas whereconcentrations of COCs are expected to be low. Spike samples werecollected at MW-26D by collecting two additional samples asidentified in Table 3. Samples were spiked by the laboratory with atritium standard of 5,639 pCi/L and analyzed as actual samples.

Assessment of data quality based on compliance with PARCCs criteria ispresented below.

* Precision - United States Environmental Protection Agency (EPA)guidance suggests that the Relative Percent Difference (RPD) offield duplicates should be less than 30 percent in water samples.The RPD is calculated as:

RPD = I Sample - Duplicate I

(Sample + Duplicate) / 2

Calculated RPD values for the tritium results were withinguidelines, as presented in the following table.

Field Duplicate RPD Calculations

Sample Duplicate Sample Duplicate RPDID ID Result Result

MW-12S DBD-01 657 764 15 %

MW-20S DBD-02 255 279 9 %

MW-32S DBD-01 7,535 7,185 5 %

FIRSTENERGY - DAVIS-BESSE 0065992.218 MARCH 08ERM/DADE MOELLER 4

" Accuracy - Matrix spike/matrix spike duplicate (MS/MSD), andlaboratory duplicate sample are documented in the attachedlaboratory reports. These indicators are used to assess if the matrixmay be biasing the reported results high (generally based ongreater than 130 percent recovery) or low (generally based on lessthan 70 percent recovery). RPDs are generally expected to be lessthan 30 percent between MS and MSD results.

As shown in the following table, all RPDs for tritium and cesiumwere within acceptable ranges.

Matrix Spike/Matrix Spike Duplicate RPD Calculations

Sample Spike + SampleID Compound Duplicate ID Initial Sample Result RPD

Activities

MW-26D Tritium MS01-MW-26D 5,639 5,000 12%

MW-26D Tritium MSDO1-MW-26D 5,639 5,055 11%

MW-26D Cs-134 MS01-MW-26D 59.3 62.9 6%

MW-26D Cs-134 MSD01-MW-26D 59.3 59.1 0.3%

MW-26D Cs-137 MS01-MW-26D 66.3 64.2 3%

MW-26D Cs-137 MSDO1-MW-26D 66.3 70.0 5%

No Cesium was detected in the actual samples. Values indicate actual spikeactivity.

" Representativeness and Comparability - The representativenessand comparability of analytical data was qualitatively evaluated bycomparing samples from the same locations for the June 2007 andthe July/August 2007 monitoring events.

Groundwater Tritium Results Comparison - 1st & 2n5d Sampling rounds

Monitoring June 2007 |ulv/August 2007 RPDWell

MW-12S

MW-30S

MW-32S

MW-32D

MW-33S

MW-33D

H-3 Activity

764

1,3075,838466

2,2872,965

H-3 Activity

8601,149

7,535507

2,702

3,271

12%

13 %25 %

8%

17 %

9%

NA: Not Applicable

Consistency between the monitoring events indicates that thesample results are representative of the site conditions.


" Completeness - Based on review of sampling and laboratory check-in procedures, as well as field and laboratory QA/QC results, thedata is considered to be complete and useable.

* Sensitivity - The MDCs were consistent with data qualityobjectives for the gamma emitting radionuclides as they rangedbetween 1.4 and 14.7 pCi/L. The MDCs were consistent with dataquality objectives (at least 200 pCi/L) for tritium with the exceptionof detection limits of 330 pCi/L at 4 locations during the June 2007sampling event (MW-1S, MW-1D, and MW-26D). The 200pCi/Lvalue corresponds to an environmental level that would allowevaluating an eventual release of tritium to the environment.

4.0 CONCLUSION

Based on the review of the QA/QC information summarized above, thedata meet the data quality objectives defined in the FSP and are usable forthe intended purposes of supporting the final selection of locations fornew monitoring wells at the site.

ERM/DADE MOELLER 6 FIRSTENERGY - DAVIS-BESSE 0065992.2 18 MARCH 08

Site Name: n 0Low-Flow Groundwater Sampling Form

Wpflfl IT): ZWell ID, / -4Z'

Date: to,/la 975amrilinePersclmiel: "",-, .-A~~ !f/,ttA Aiil~Weather Condition: S &- ,z-. . A-/,; Y" .. _- 4rrime: &~~~~C'OTFile Name:

Iotal Depth (I.D.): •4/,. ... Screen Lenjh:

Depth to Water (D.T.W): . 'r<HKP Well Diameter: -"Total Volume Purged: 5' '. Casing Type: fC ;.Purge Rate: 17C, • Sampling Device: /-#5(%-., /t•i)/Tubing Type: P -- Measuring Point: c0 ef Le.Pump Intake (ftbelo;* M.P.): color: odor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mlin) (feet) QC) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note +I- +1- +i- +1- +J- +A-Criteria4 below)e 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 /I, r2.,, • _. z ,/. 7 ,"/ .,k " ./, 7-5:00 13H 1 q ?i L1/,,'-•.. " "'-j % 1)-

10:00 77 -5c- 72Z ,1175-u ix;o ~~15001 .5}?-:Th./a,/3 .47CPJ i •, "Z/ H•3 i,7.•15:00 1 I ;'"'

25:00 i3 4/ 7 , 17.L 5/ &A5 7,,29 iih30:00 , -- ,',, /-,. jiC., , 7,-2.. -79 / o,-35:00 &L Zt'iA . /si - -7-a& -c?Z-33 1-57

65:00 ;12 .l,,/..2,•' L ";3 ....70:007 rSC 1/2~J~ 2,11 AZ7oI&. 7ý0Z e7

75:00 70 _ al 17' . ,.2•5.1 6•4 . __.60:00 .2.L1 1/1-1,~sal .j r19 atC

85:00 ... ?q ;iv;c I q4g -7 O;z90:00 iff) ~ iLi' C-1q 1,7 /6, A), /C LOY1 -j' j e~

100:00 _____ ___________ ___ ___ ___ ___ ___

105:00 ____ __________ ___ ___ ___ ___ _ __

110:00 ____ ___________ ____ ____ ____ ___ ___ _ __

r 115:00 _ _ _ _ __________ _ _ _ _ _ _ _ _ _ ___ _ _ _ _ _ _

120:00 ____ ________ __

Sampling lime: ; ~ .~ $6Samp~les Collected: Analysis Requested: Preservative: Holding lime: Lab:

Notes:01 :Do nsot ieaasuae depth to bottore of weH utslt after puarging Ind -ptrspig to reduce mesuspeedrlig fine, that array be resting on the wrell brottaom(2;. Starblitearor criteia hased -r three oustwl eoet Cseemrt,,e reneassn ere,())- Total dar-dsssaiarraellto beteroatthan 01to rrrWnft) Purgingat, to belowered asenecsaryto keep d -arros below 0.lalo(032ftr)(4) -/- 10% ehear toahid it s ..e 10 lITI.

Site Name: pLow-Flow Groundwater Sampling Forn

Well ID: nfltJP -- D)Date: /I lo, Ir'7-sampline P&sonnel: C., . LX1hxk Y rlCoc' LLr'-r t, A. P-_rc'i deSWeather Conditions.: ji.y A 'F-C-.0'

File Name: M IU : I b

lotal Depth (I.D.): •-'6 Sci eeenggth: 7 C)Depth to Water (D.T.W): a ) . •: Well Diameter: .'"Total Volume Purged: ý q eQ, Casing Type: PV 'Purge Rate: g 3•At p,- n.L Sampling Device: •J4rca• '# Pitr-.Tubing Type: ff-"'A'J,-'As2, Measurin Point: C)- O•PC.Pump Intake (ft below M..P.): -70' ,,"dor

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mir) (feet) M(C) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +I-- +/_ +/- +I- +/. +/_Critefia, below)

' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 2. ý13 Kir- (A/4S ,ý4 r - '0,,~-~ . ,5:00 19,A' j,.2 ,of7/,0 , / ,S -. ' )70 -_12,G.10:00 -,3 1 .V jq/,/5,,.5, ILt.a i7 17 V.33 G& .' .-/3k? X.6_4

20:00 ]1 . fj I /1., 1 I-. /M&K- i2/5/11 .-4 1 &•t. .42-5:00 /,..q ,O, /n.,...,i." Azoq [A,:W e..ý -;,' ',

30:00 .15-.13 . . . /i=,33 t,-7 v-.3.5 1,,, 7

35:00 I5,L /2 ti.. Vie. Z qi,,i, V_:.5" ,,$" .7rI 6og•

55:00 /c.7 ,:~ ~n-' ~i/ ~ 7 _45:00 , _" /;•.- ,,,. / //"a 63 4, q-5.-1 . e, X.-7

60:00 -_-65:0070:0075:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00

Sampling Time: ]37- -3f9q

Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:

- MfV.Ili I ') J.A-rIUIL, .AAPV.1A P3 c:,.-2.

Notes:(1) - Do not - teatore depih to bottom of we-1 .ntit oe- po.rging and mmptig to rodooe -eou pntrding Fine that nay be rtMettfg oo ho wel- bottom(2) - Sbabilkat-oe rietceia b.tdon three none aecetý t co-oecvo ut nOO•renreto(3) - Total dtawdown in elle to be ess thatO 8t )m(032 ft) Porging rote to be looened as noosntry to keep deowdo o below 0 tlm (03.2 it)(4) -/, 10% nbh-n totbidity in o-er 10 NTTU. ot Ot0..

-, n 1 .t./. Ot-

Site Name: LLow-Flow Groundwater Sampling Form

Well ID: Ms i t- -*7-'Date: /-. I ).' 1 cs-i

Sampling Persdnnel: C L6ieO-1./b,-u,-,, A .vo2lc/ ,Weather Conditions: M-.- A)~r7Time: 13"O-File Name: Ibf3fAW -7S

Total Depth (I.D.): _?Y.' 413 Scren : Lnfg,-.Depth to Wate, (D.T.W): 5L. •/ Well Diameter: 3"Total Volume Purged: , Casing Type: ''Purge Rate: ,21t1 /• o Sampling Device: 171-a 5 -td Rte *-;,4-%-0

Tubing Tye: •.Measuring Point. 7 oj tor f'CPump Intake (ft belo•'•LP.): ýJqif color: fdd,ý odor: d.t-g .

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (QC) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note +/.. +/- +1- +/- +/- +/-Criteria' below)" 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 5.'76 Jl 70~ ote /"4 /117- M--,z-5:00 .5,-74o .21.Q•/,.• /6-.q - iJr17-7 4.5 7. 71- .-/,o i. 6-110:00 _4", -5.S f2 A,2,x f-7,V 00 ;?/ ~Y,3 73' 7. Y d: -IF15:00 ,-.74 .2/0 A ,"ve-v i"•7.cq )J79 q, 5fa 7-31 )o,7 o,'Y720:00 a#,5 ?04 &Ji / i7g/ !7 7,3i - •/- ,25:00 .5I,7& 4 .qM •.68- ikJ.5. /7 7,ý 1 ii 6, "30:00 S,7 -7 Z/• '.. j?.Y? /S641 %.N 7,3, zI/•/35:00 4 1 A b/t740:00 jj4A 16.93 / 7e 7 & -7145:00 A1 7L e 5At& V-7 60-5 7-AO

50:00 -7

65:00 ___ _ __ __70:00 -V, -7 b It qy

95:00I00:00

75:0080:0085:0090:0095:00 ____ ______________ ___ _ __

100:00 ____ ______________ ___ _ __

105:00 ________

110:00 ________ ___

115:00 ____ ___ ___ __ __

120.00 _____ ____________ _ __

Sampling Time: /.3• / %.$-

Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:

/•f•t '75i giri ,,: , n-s'ji.

Notes:

(I) - Do not measore depth to bottom of well unti after purging and Sm'tpttg to reduce remsupending fines that may be restfig on the wett bottom(2), Stabillzation criler. bated,,n three 01St tere t otreouthve mteastrementst.

(3) -lToet dmawdom ,o, wtel to be let dhano, lt m0.32 it). Purging rate totbe (owered a, setre.sary M keep detwdo-e below I m to(D.32 i0).(4) o/- 1 /0 when turbidity is over 10 NTUs

Site Name. 1) Z25[ ow-Bow Groundwater Sampling Form

'Well ID.: MI/., I -[Date: &II//WC 7Sam-oling Personnel: rý ,~ R~r~~--i . 1-L1%--1eb'

Weasthmr Cooinins 7V 7,2

TileNme: T• 4'/,.

Depth toWatez. (D.T.W): ' ,j ;15 WeU Diaete,: 3Total Volume Purged: V•. Sz, :•2asing Type:. )0 V"•C"

Pump Intake (ft below 1VLP.): 3color: e,& - odor: /t"A e

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) CC) (uS/cm (mg/L) std units mV NTU

Stabalization (see note +/- +I- +1- +1- +1- +J-Criteria' belowf 3% 3% 10% 0.1 unit 10 mV 10%i

0:00 0 ,13- 16,£ ql / iO, 7 V--5:00 i,.. / Z .e,, , //,Y-0 I

10:00 , , / ,'fe{ a/Oi ,•di ', 7f/, ,'?'

15:00

50:00 V44 7_0__ _ 3__ 0

25500 190___ A7__________ f___7,_P1

60:00 11L.4 P,&' -7,11 -L/,9 1-4,9

65:0070:00 /7vk75:0080:0085:0090:0095:00

100:00105:00110:00 [

115:00120:00

Sampling lime: 6 .'79 /VO 7


b6- -ra, 1m GMA

Notes:(I) - Do -r neasre depth in bottoni O wri9 ..nil afien purging ared snmplineg to reduce resuspendlng fines that may he esting [n he well bod0nm(2). StnbBadton criteria bard n three ment recent c€nneeeu•vneam eirernn.(3) Tetal drnwdonn in wel ito be lens tlina O]lm (032 ft) Purging rae to be inoered as necessary to keep drawdorn below 0 I o (0.32 It)(4) ,/- 10% niwhen turbidity in oner 10 NTUs

Site Name: _ _ _ _ _ _£ ow-Flow Groundwater Sampling Form

Well ID: n'l. i j 1 i. S-,SiDate: ±&2Sampling Personnel: (S., "?j)t4qb ietzf'rgr -- , 'r , C-laWeather Conditions: -7 7" - .ua..z•i E Cah-vTime: jVL-, UFile Name: jfdM

Iota]l Depth (ID.): Screen ength: 3-.lDepth to Watei (D.T.W): 01 Well Diametei: =$ "Total Volume Purged: Al' W?,f.. Casing Type: P Vt-Purge Rate: 6215" ,aw-/u" Samplig Device., t-t-vY'Tubing Type: - Measuring Point: " O FPump Intake (ftbelow-M.P.): ,. color: e,&d-e odor: AC1.-

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (Q) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note +1- +1- +/- +/- +/- +/-Citezia2 below)

t 3% 3% 10% 0.1 tnail 10 mV 10%,

0:00 MAWA-V -,/. - 7,0 , . -W 2 Zy .

•5:oo00 ..Y who•.-/-,, 'W'/ a, A-,615-; 7.,311 . &!g ••.50:00 14/ • ~ ~ A& ? 46C

15:00 4 1673 --/7162 R,20:00 q, Y-6ft/t, ~ ~ 7 ~20:00 /,ý ____Id?_ __? j t2.7 ZZ '/ :P4Y

50:00 /3,k /,-'i . aM'S •377 0. •Y 7.ge '0,'7155:00 2 0,4-- -1117,760:00 44,;?60:00 al & - 4-/;-O-- a .014W,75:00 4 . 0,/9'

80:00 /9-46 aqK 9185:00810:00815:00

90:0095:00 _____ ___________ ___ ___

100:00 ________

105:00 _____ ___________ ___

110:0 _________D___

115:00 ___________ ___

120:00 1____ _______

Sampling lime: -/4f." /936SamplesCollected: Analysis Requested: Preservative: Holding Time: Lab:

1_ ) -J - 15" 4z"7k1 , r•L•,intAM 14 A

Notes:(I).- Do rot measom depth to trottont Ot well tstti after purginrg ted nanmptig to reduce tenoopendlog foes thsal may Ire aretiog on the ro] ottIoflm(2)- Shbilimto criteria bated on three mos,- reent coecuftvte measurements.(3)- Tota drondore as welt to be et than 01 es (032 It) Psrging rate to he lotered -s recesooty to beep drowdowo belw III m (a 32 It).(4) t/- 10% shent trbidity Is ovet 10 NTUs.

Site Name: X> .bL ow-Flow Groundwater Sampling Form

Date: a•t2 4,Ic"Sampling Personnel:. 'o ,_7j~Y . (cC ,,z.r'+6i . ___,__,____-_

Weather Conditions: I-E5 - " '

Time: i3 JCCrite Name: DbelW•)'_0 % %0t V

IDphSScreen Length: 7Depth to Water (D.T.W): (1) i3,.?;/" Well Diameter: ,

Tubing Type: [Jd • 2"Measuring Point:"T,"- DPd.... : ,

[Pump Intake (ft b ový-M.P.): '2,.color: ý ., odor: • ,U

Time: DTW: Commnents: Temp SpC DO pH ORP Turb(rain) (feet) i'cQ (uS/cm) (rag/L) 'std units mV Nr'U

Stabalization. (see note+- +- +- +- +- +-

Criteria' below)'* 3% 3% 10l% 0.1 unit 10 mV 10%,

30:00 , , / __,_ __- _

40:00 A 74Q/34250:00 4a WO ., 7 Y . 7,4S , 5 307,$ 3

75-00 wi A S/W

65:00 IgY v'7o~o l•'Tq qa .,d{•,_ • I.j4 Q'/d q~#6 7,f/` --3t9 $.1Z-75:00 i -_j 4"71

80:00TO5:00

90:00

95:00100:00105:00110:00115:00120:00 1-

Sampling lime: / -. " qj5

Samples Collected: AnaLysis Requested: Preservative: Holding lime: Lab:

Noteiss

(1) Do not measure depth to botlom of well until alter purging and sampling to reduce -ennsprding Inmse that may be resting on the well bottom(2)- Stalllaatjon criteria based on hree most recent ronsectutive measurenotus(3)- Tol drawdown in well to be les that 0.l or (0.32 ft). purging raet to be lowered no ccesnry to keep lwdown below 0.1 m (0.32 flt(4) +-/ 10% when turbidity is oer 10t NWo

Fite Name: -06Low-e tlow Groundwater Sampling Form

WeT otID; ed:- C an eDate: / IS D -YSapuing Personnel: eau. Point: r- ,,,,, - f

Fle Name- (,tV9`74c11_f5Total Depth (I.D.): ý,g •* at/ Sth: W)S5f

Depth to Water (D.T.W): (') /• ••iWell Diameter: ••

Toa ouePurged: ,•- ,•y.' Casing Type: y'0Purge Rate: j,€•v~/••..Sampling Device: R,-'• e.aTubing Type:t• . /-, Measurina Point: " oq :

Pump Intake (ft belov M.P.): ,Z5' color: odor:

Time: DTW: Comments' Temp SpC DO pH ORP Turb(rain) (feet) (`C) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +- +1- +/- 4- +1- +/-Criteria' belowla 3% 3% 10% 0.1 unit 10 mV 10%'

0:00 /3.'1/ VaOV-/4,, )5.77 123q 12,50 -9,6 1 13,7 -:, D5:00 /i,&O 16_ ht IA I5gl' / aljq i40 'r, 44 ig, I q,7 I

10:00 j4 1 J4 ji Qo / is.03 #. 22-7 t /I ' (".'7 3 ,. 5.70

200 ____/__(_,_ S•q •-•?q •. -_. &.•

30:00 /Ph i& 0S 0 1t /oigtn . Y,,4.4 , ,, 27 1.3 7 4

30o0 :, /j3q g57 166 .40:00 /o,5• /9,.a4•5•. /5,O" /~t•,9 , 0 -1.2..q. 7 .r,35:00 7gj30j 777P / 7 I5/,5• ia57 g, Y '1;7 6 - -7,,

55:00 - 17 X, 7

60:00 !!rl 5.6,

75:00 I _____7_

80:00 /A_ _ 3__3.2

85:0090:0095:00

100:00805:00

110:00915:00

115:00 _____ ______ ___

120:00

Sampling lime: /".O0"- / -.30


m/r2.-/ z .

Notes.,(l .- Do not measure depth to bottom of well until after purrginn and amperling to reduce ronuopending fine thW otay be restingon the well bottomr(I) -Stabilization criteria ,ased o three moSt oecert coerecutive ,rcasurremei(3)- ol'tl drawdown in well to helw hanl or(032ft) Purtogratthbe lOwered as neressary to keep droawdowolobeloso 0. nm ((.32 It)(4)./- t( swheon turbidity Is twor 1 N'Ir.

Site Name: r26'3Low-Flow Groundwater Sampling Form

Well ID: •/V/I -- 2?)zell ID: lVbl,,e I -I VI)

Date: 4//'/il07Sampling Personne: C . 4'0id J7,:Ar./ A. A r%'IViWeather Conditions: 7' r, ' . .Y .Time: ,',Yf .File Name: 2A.•,d-/,Z)Total Depth (I.D.): 74-,e'Z' /gth:

Depth to Water (D.T.W): (1) /ý.q. 7 Well Diameter: 3"Total Volume Purged: _W1 Casing Type: N4purge Rate: f[e0411?/Atd4 - Sampling Device: fi/VY/.U'i C iPubing Tye: Of 4 Measuring Point: 51aW0" .Pump Intake (ft belo-w M.P.): 13 color: &,.1d, odor: A,/ai/]

Time: DTW: Comments: Temp SpC DO pH ORPI Turb(min) (feet) ('C) (uS/cm) (mg/L) std units mV NIU

Stabalizatdon (see note +/_ +/- +1- +/ ÷/- +/-Criteria4 below)' 3% 3% 10% 0.1 mnit 10 mV 10%,

0:00 ,3. -1 :a I a 7.L/o,1. 3 t,•i -,9 1,5 i0 7.- ( / qS.T o35:00 /3. P& , Ac-/7b /7.,56 A *"467,'• -1=0 -. 62-

10:00 1qz _,-o / 7.0Id9.T d,30... 7. &S -////0 -4.J15:00 17S,• 30 •f /r '• 17.g V 6 g~ 4' [ Y"l,1 7.&7 _Igq~d.1,*•20:00 ',/-..S&n ' -. 17.76 Tq'Q Q05/ "• .,25:00 _gq i___ý "A_;/7 7

30:007.& 4,,• Rg* ) •t/O •f.•.3q. 7/,q '-5?,y? !,3935:00 -/. q , i- Y aL lJab. 17,91 6,/.5 2q 71,q - 46/ 0

40;00 76T a•5,.•' I h%4' /9,30 bq,7 O,,A,-i 7.7-00, i.77•

45:00 &9,, /• (.0O O,2 7 7,70 A k./50:00 179 30 % __17

55:00 #,, 4, -f 31 7,70 -,,60:00 /17. /-If 71 . _• 7Ml3 oO 7,70 .. do1 L?65:00 17, / 23/0, 1707d r, , 1 •,,

70:00 77,__ /__,_____,__ /Y_.________ 7.71__'_._l75:00".. .i-c80-.0085:0090:0095:00100:00105:00110:00115:00120:00

Sampling lime: 1-/006 /Ii(7

Samples Collected: Analysis Rfequested: Preservative: Holding lime: Lab:

5AI6fL

Notes;1) - Do not tea.ut. depth to bottoml owelt until after purgtng and sampling to reduce - pending ren; that may be tesing on the we-1 bottom

(2) - Stbiliztion criteria based on theer most recent cousecutive mebucements.(3) - Toutu drandown in well en be lem than 0.1 m (OM 11). Puging rate to be luoered ., n-e-essry to keep druwdowe below 01 o 10.32 it).() 4/- 10% when turbiditlyls ver t0 NTIJs.

Site Name.: L.13Low-low Groundwater Sampling Form

Well ID: IAW-2 1) •Ibate: Id /2 5 102Sampling Personnel: C.nl ,ei~ /70fpi/r . i.AAV4-.. d/Weather Conditions: 1.5 ..•-44g-i e CTime: a&File Name: J, /44/0.l, 5

Total Depth (I.D.): 4-2. j Screen Length:

Depth to Water (D.T.W): (1) /3P• '/ Well Diameter: 3iTotal Volume Purged: 5." .- Casing Type:Purge Rate: .DAIWIO, * Sampling Device: /zr :/ -Tubing Type: 2W - Measuring Point: oF " .

Pump Intake (ft below M.P.): .32 ' color: 9j,,jp odor: 464 <

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (`c) (uS/m) /L std units mV NIU

Stabalization (see note +/- +/- +/- +/- +/- +(-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 - 2, ,L , ," 1.77 , i ,

10:00 13141 215 I ./ ;.- !q.ý if I 6..1 ,/,.93 L b o .15:00 Jj 2--5 A4" 1 4,26 171 0. J-9 6-9 I.TT O.(a320:00 0311L 225" /,A" 14,q i -" .13 6ýS Z7 -¶,-1 i4-, 0,1'25:00 13,21 .235 ,-a i 8 (P{R O.9-1 ?,D(, M-, 9 .3c30:00 13. t iiJ1 -2 35 Adn If" 145z Z _0,'r 0,~o~t 3235:00 13.,i 2L 1444 ti.i'6 1?- 1 2-1 u. i - ,.22.40:00 1. .qIS" ZzO AUo 1•.5-3 .6 egl 146 04 -a 6, 3245:00 1-3.,01 ,2-5--_ .ga•[A.• i 4,5-(, 1 r< 91 0-•-?ý, .i.t 4im-s- ,3" 950:00 J3,AL" 2 ýV 4 j Z9 14fp 7 i~jy 6,'q ,L.

55:00 13. Ii 1 9 i/k , 14.I I-R9 b-.<5 131-2 "-Q0 o'60:00 j,3?eJs- 25-o ,2- 2ts: q%-±. .•L L..u • o65:00 I341 6- . 14A,- 1418-. 1 S-2-a 7-? -4R. 2 -.7-Z70:00 l.3.,4i ;26.r) .P&,•3• ljýi -• t,161 0-7-9 2-,27I q2 -• N5 ,75:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00

Sampling lime: Oq9/- /1iSamples Collected: Analysis Requested: Preservative: Holding Time: Lab:

/<I-'4t "I A"t

Notes:(1)- DO no• nasunre depth to bottom of telr "nti after pa-ngig and samping to redaese rtuspending Onet that may be restring ott the wenl botom(2) - Stabilln-oin criteria bated on three most recent coaenostive measurements.(3) - Total drawdown in well to be le-s thoa 0 1 m (0 32 fi). Purging rute to be lowered as -ncemary to keep dcrawdown below 0 I m (0.32 fl)(4) +/- 10m% when trbidity is oer 10 NT

Site Name: .DJLow-Hlow Groundwater Sampling Form

Well ID:MW,.0.b.Date: 6,J4.: /a 7Sampling flersct;Tel: 6c. Zsoi4 ,lA/,A A A-(. &6'O7skWeather Conditions: ý7,K- AAq,ý Ala Zl-_5rfL"Time: /0:Z -5 4File Name: D6Al~l

lotal Depth (I.D.): . Screen Length: 70Depth to Watei (D.T.W): 0) /3,73 Well Diameter: 3 "lTotal Volume Purged: " Casing Type: ,/,Purge Rate: / 9 m' /X.//k.cý Sampling Device: V"'O.l,Ž..C )Tubing Type: Measurin Point: 7)-1 9l PI/- ,Pump Intake (ftbelUw M.P.): 70 ' color:`-/6j&e1dor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (°C) (uS/cm) (mg/L) std units mV NIU

Slabalization (see note +/- +/- +1- +/- +/- +/-Custeria' below)' 3% 3% 10% 0.1 unit 10 mV 10%9

0:00 //._ q . ,?/•, ,,0 7,3& /I5,; 4.7.lO:00 14,135 2#,• ma.1• • ) 7, 31,•75 A9•15:00 I'M, ,.,r 17-15,MI,•. - 1,•' AY.OR -•,a,. iT d .,0-Y,., 5;2.-20:00 ,9Q_/'__t•,Z# ,25:00 0.iZ O,' . 7, '

30:00 i ieeV 735:00 /osb A91f • -7,,9 ,/ ,,40-00 BU MMAýV f-7 251f .

50:00 __4/_ ,. 1_-_ 17- R 633 7__ 7,. ,55:00 Al 1 ~ ~ 1,~..L• S1 7,,// 2052 ,4 7,Y X;,/, I S .5-6i-460:00 Ad .,VVZ•,v M 0.2016a/ U0 /q,7 r,7965:00 1t-q5. S5 1,q 4-"Md AtA , )•.7. A d• qb VA,• 7.-229 d , 7 -_fIl

70:00 /W.,%(17 ] /Z YS ,7, ,ýIx75:00 1 Y, -547 D id-ZA1p7. /20 ,AM/l, D,J 3/780:oo -10 '2 qffA6 D/r. ,h/.. - ! Z Z11 0il o,d5 7,60 52, -6-6•,"85:oo /p.S /M , ///,,,• t,10 M/ ,l"Id Od 6 1 L =I,0•, •90A00 / ,5 7z 7,../ ,/95:00 /11.I 41 -. 7,Lq1 3, qff

105:00 qt t ~ J3110:00 7,120:00 /155 / j7, - 3 ,Z -3 A3

Sampling lime: I 23O I-"


Ma-a-r- I-~rI64 61,,&A U00

0

Notes,(1)- Do not meas.re depth to bottom of -el autil - fter pu gieg and esnpling to reduce reauspendotg tImes that may be resting on the well bottom(2). Stabltlltion criteria based on three most recent conseontive tnaeremnnts.(3) . Totot d-aodown in well to be nea than 01 o (0 32 ft) Pueging rate to be lowrered as ncesosr y to keep drewsdowo below 0.1 m (0.32 ft((4) ./- 10% wern torbidity a over 10 t"TUs

Site Name: . _ _ t3low-Flow Groundwater Sampling Form

WeU ID 01 W 413v

Sarn ling Prsonnel: Ci, Li,~.t~ nLr,,& A .Pe lVZWeather Conditions. FhW-zt aTinme- 03o- , ZFile Name: .Ž M~ao!

Iotal Depth (1.D.): scre,. ••Aentf

Depth to Water (D.T.W): [ .L Well Diametei: 3 "iTotal Volume Purg ed t , Casing Type: MaPurgeRate: 4e,• / ,_ .*U. Sampling Device:Tubing Type: Measuring Point: /--Z• 9,,c OF .Pump Intake (ftber w M.P.):. color: C/lezZt- odor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(Mrai) (feet) (°C) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +1- +I- +I- +1- +I- +/-Criteria' below) 3% 3% 10% 0.1 unit 10 mV 10%,

5:00 /2,7.1 • ALI /___ A' 11..-57 7./Y afed .10:00 /,f v Qq,' 10/ 7 ~L_*715:0__!5-x_ -jgj 7, £5 ýL/ O,//15:00 i (I.& I 9_5,-S/¢rt 1/, 'IS /// 'ii07 3 1 .,) ; ,5720:00 ,. l , •45L 7,11 s

35:00 X.53 !,P /,Z ). 13.OO ,157 00 ,,)-, 0,l040:00 /d ,,Jz•l Z3 _77.3 1g1 ,•cI45:00 1AV.7,3 i 1- -, 9/A o7 A2I7 /7 7.,7 1,3;50:00 52 q3 l ,i/ , 53/ ',.eb ,.6q " j3a, v57,3

60:00 1. 17-5 3-Y •Y O.3' 7.hf • ,.7/65:00 12-3 1'7•'!nL•f.1.- jA.4", 6W 0,;d a37 3 1 ¢,Oa

70:00 112q3 .! .5/,S1 .Aao 0,3 7.1,F ', I.

80:00 1c2,,3 l'5 .Z/,L /5.13 .,L , 7,A / 4,6 Jl"85:00 !; '•, /75 -..i , aalk O.JI3 7."7 17 /J L7,90:0095:00100:00105:00110:00115:00120:00

Sampling Tire: 09 q7-101"7Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:

5bla4 I

Notes!(1). DO not measure deptih to •e mom of sel unti} after parging and sampling to reduce resdSpenddg fines tist may be resting on the wele bottom2)- Stabilization criteria based on three emos re•eo econsecutive measuerements.

(31 -Th•l deawdo • ta eetotbe teuthan5 I nm)032 (t). Prgstgrate to b., uek-ede e as cen-ety to keep dea enbele 0o (0 32 It)(4) e/- i(n. when turbidity is ocee 10 Nfrus

Site Name: 4Vt5Low-Flow Groundwater Sampling Form

WeallD- lL3- I'l. . bDate: A-1,41//0?7SamplinePersonnel: (G.I, / W/'/,,LT A .4 t.,Weather Conditions: 5"SzTime: 10/03F 6/ __

File Name.4M &P,

Iotal Depth (I.D.): 4 & - Screen Legth 7,2Depth to Water (D.T.W): (1 )7 -'70(dJ Well Diameter: .3"/Total Volume Purged: ,,_-, Casing Type: P v c.Purge Rate: j"'/ftYL,. Sampling Device: .ra AL62s •kzi/TubinrType: Measuring Point: "/-7;lO 014' .Pump Intake (ft belovV M.P.): 7JO / color: k eI Jir) or: _-'r

Time: DTW: Comments: Temp SpC DO I pH ORP Turb(mri) (feet) (M) (uS/c-m) (mg/L) std units mV NTU

Stabali2ation (see note +/- +/- +1 +1- +/- +1-Criteria' below)• 3% 3% 10% 0.1 unit 10 niv 10%,

0:00 Wq7. Ty .67"YT, , , i7••, 7 t.i 0 •¢g 'O 367639ý 7. V-5 29. V5:00 11,73 •i7 Z. W4. 8 3 ±L 7;1' ,;f(.A _-77

40:00 110/j$ n.&5I 37u M41 -5 -64

50:00 4 L ~ ;~'73'~6;?2S _

20,00 A79,3 1&0,, LP ../ V,- 32-1-1 -T1 P., fY 7,.5a- -. 4 a-. -7q

25:00 /1, f 3b . ,j 344/a./ , 7-,, -'ii.2 04.80760:00 7.f,,, L1a,- , 0 3/ 1// ,, '5 --V9/ I 1.__35:00 i. . -7 1 3 66If G,.o z.0 .50- --A,-i71 --,7140:00 7, ., j.S 'r , ýu / .• i6. i61 311a,5 G.iD -7.52 -Sv z•l Q€.y,5",

5:on Time:oo .... ,/. / ,,13- ,_.55:o00 7 4; t 5,[5 r @ nZ '/• t 11,95 11771 - .05 7 -5n '-53t.l i,0 '760:oo !.0g I.0d.•w• 1q.q 31S0101/ -;'IS I,5 - I£q1,

65: e Clctd Inay'i•e d reer -at/ve: 7H55g T'',m ,

80:0085:00

I 90:0095:00

100:00105:00110:00115:00,.120:00

Samping z Time: l "/3

Sam,!e~s Collected: Analysis Requested: Preservative: Holding Time: Lab:

P-Wo -m -. 1>-(,)e,

r5 01[ - mcLt,- ,_,T

ý9,ntyg:

Notea,1•) -Doool - eure depth to bWft of -M -111 .-loaer purging and s-,mplig to reduce -pending F- that -y be resting -£ the .- 9l bottom(a) - Stabilition critcria based on three -t reet -eoe.ofive eeas£ remnts.(3) - Toute drdown d 6 well to be bWm than 01 m (0 32 ftS Purging rate to be lowered as neces-ry to keep drawdown below D] l (0.32 f3 )(4) ./- 10% whe. turbidity in o.er 10 NTDk

ii

Site Name: DaL ow-flow Groundwater Sampling Form

Well TID f/kiey -ýt 1.SDate: g.k/,•t.;'2/O 7Sampling Personnel' ý 1? ) vi,-V ''L.Weather Conditions:Time: /4rFile Name: DA,610 J" ,

lotal Deth (I.D.). Screen Length: ,~Depth to Water (D.T.W): mt) -C Q3' Well Diameter: 02

Total Volume Purged: -A,!,i5-t~e CainTa:

Tubing Type: • Measuring Point: -7",, O (2 / --Pump Intake (ft beloi 7M.P.): .- ' - color: &4,j4- odor: A?-4-

Time: DTW: Comments: Temp SpC DO pH ORP Turb(main) (feet) 0

C) (uS/cm) (mg/L) std units mV NTUStabalization (see note 41- +/_ +1- +1- +1- +/-

Criteria0

below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 jf,4 2/O,-/?/6 /-AH? 9 3Q.I./Q,77 ,-7 Z 7,i.T 406

10:00 ! ..6L 1,,5 _7,_,_ 44 7,_ _7,. .?Q 12.7"15:00 141,.'3' 4,9,2 ),• . __ / 7,, .7,/.Z.l -(,,,,q 1,20:00 Z7f .- , ..

40:00 j4',,• -17/.50• ]'T a~l &. i7.' //O z.45:0035:0, jf .Aý"," /5 6, 1, 1t/44 d,,?,

60:00 IAAS 249 elfii j 7,5fO ~.c2 MA -96f A /079 A-~45:00 Ud.' 5 i '051 .217b 7,," bc, -44 ,

70:00 .41'232i~7~ jl55:00 j&." 9;; /~•. /,d.3••i q 7:,r: V,:6•" 0, &,60:00oA- -0,:-• .. /?-".',Lg 12+- 0"• Pf7• :7.604 __31H q q

65:00 770:00 d 7A4,q75:00 7-80:00 0 V

805:00910:00

115:00-120:00

stmpling Time: aql/O ... / V


,na) - )A&

(1) - Do no measure depth to bottom of well ot! aflter pwriog and sampling to educ resuspending finea that may be resting on Oe well bottom(2)- a~b flatioo criteria based - three mt re-ent I enon• tire mea . ,met(3) -otaldrawdow in well less thanS I m (

0 32 ft). P-rging rate to be lowered as ece-sary to keep drawdown lbelw 1 m (0.32 It).

(4) 1/- 10% when turbidity t over 10 NTUs

0ýSite Name: _)/51 ow-Flow Groundwater Sampling Form

Well ID: /)"Iz • ._Date:Sampling Pers nnel: C>Lep AZp~~- 4L -d KOIe4Weather Conditions: 3 5 ,Time: I3/ - 1--File Name: .'l Y,,

lotal Depth (I.D.): Screen th: Legh

Depth to Water (D.T.'At):() /43/. Well Diametez: 3_•Total Volume Purged: ,*,.-,40 Casing Type: P YCPurge Rate: , Sampling Device: ,L,ý . &&4Tubing Type: Measuring Point: 7•O . LOPump Intake (ft belo IvLMP.): W ,_:& " color:/ #_ odor: O

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (qc) (uS/cm) (mrg/L) std units mV NIU

Stabalization (see note +/- +I- +/- +1- +/- +1-Criteria

0 below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 1.110 1U1 GM41 670 a?, o5 7.' Wb 4 >9

10:00 f~ A;U a? Zfd Q -0 7 72f 9'15:00 "//7 /0 U? I,4v - .. 37/ ,.3 -Z77 .20:00 j j t~ ,-25:00 7,y30:00 Fig MPl /fO a35• •?K y 6-,3735:00 /6 oI&"L-23 -- 740:00 {.J4 .'..#j., 5 i7, .e%/ .45:00 Jq47j 0 ~ I50:00 -755:00 i-27 ,, ./ 7-3 -•,60:00 Iq,j7 IA96 6_a Y ,3/ - 1.65:00 1q,17 - -7 o,,23 7,5. -97,7 ,7.70:00 1/,7 " , 1 -0 M , --A.? 09,aA175:00 1- R/ , 5 ole d , 180:00 77 5 9 785-00 4 5ý90:0095:00

100:00105:00110:00115:00120:00

Samplingflime: Ijz/ -- )qs6Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:

W3. 60 !E

Notes:(I) - Do not meos- depth c bottot of o wen tol after p-rgieg and sampling to reduce re- ppenditg ftoa thaot ay be rfessg on the well bottom(2)- Stabilization criteria based en three aost recent cottcetive measuremecnt(3) ToWl d-re, wdown in -e1 to be less thor0 1 er (0.02 ft) Prging rate to be lowered as nccessory to keep drawdown hlows 01 m (032 ft).t4) +/- 10% when torbidiryis cem- 10 MTtl.

Site Name: D15Low-Flow Groundwater Sampling Form

WeIlID: rnw ,,kDate: (__I a- 1CI do7Sampline Personnýl:C'. I tJ MYt-ryir4-k#4t MWeather Conditions: "7 -"i`'CGZTime: Of,)."F20'•k .. ...

File Name: "D~T- _=t3'2• b

rotal Depth (I.D.): ,,./ ScreenLength: Y7Depth to Water (D.T.W): (1) I ' Well Diameter: .-3Total Volume Purged: 3 , Casing Type: PVQ4,Purge Rate: e- -t Sampling Device:. .Tubing Type: P-:c•I - Measuring Point: -i.oy O(F Pif C-CPump Intake (ft belown.P.); color: 4' It. odor: 4

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (c) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +/_ +/- +/- +/- +/- +/-Criteriax beiow)' 3% 3% 10% 0.1 unit 10 mV 10%°

5:00 LI aOU _ . 7L -ACZ -,17 42..85 - ','3"

10:00 'at 1s0 r"i T j E . JL.-U, i 'I,= o,'7c &,97 -3qI,& 1.-4315:00 InJI , O.0l i3C&I Q,5"4 &E .20-00 ,I alA a.15 ,', .o.'1 ,CL o.qa Ora -S•.1I i.50.25:00 15,_ aQM h t -s m ~Q0,Io7 iall 0m,3e eif -361.3 0:730:00 _i___ .V.?0 fIi UA, . ja A 6,+b31W 5 bOi 6,qif 0.q7 40,_

35:00 i J5 .4 3L0. IS.1, j 3 t, 0 j I•-L,3 o.,fY40:00 11C5 .3o5 P 7 &19,1 ,3'5. 1 nA 5450:00 1~I V. L41 IiJ

55:00 a-k3 c30I &~%er i~ 35 Qi3S &.1 C ~-2078 _,560:00 -

65:0070:0075:0080:0085:0090:0095:00100:00105:00110:00115:00120:00

Sampling lime: Oi30 "'• 5-c)Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:

j ý j q,-p -py,

Notes:(P)- Do not -oeasre depth to boltom of well ntil ther purgin•gid stp ieg nto rrsedue stsnding f-e that -sy be rnthing an the well bottom(2) -Stabilinlion criteria based on three most recent coosecutive measu-r ns.(3)- Tot.l drasdown in _el to be loss thon 0D1 o (0.32 ft) Purgog ral to bs towered .s neessory to keep dfaowlow, below 0t1 sm (032 It),(4) ÷/- 10% when furbtdity is over 10 NTUs.

Site Name. _ A __ _-_tow-f-low Groundwater Sampling Form

Well ID: 21 -_ Q ..Date: L_.;I. __-71, -7Sampling Personnel: . z/QWeather Conditions: ,_/- !i//YL, "L_.VCtIt.Time: l/"File Namer:/~Q~

Total Depth (T.D.): ,/.'Screen Length: _3ZDepth to Water (D.T.W):*1 j)34,) Well Diametei: .Total Volume Purged: -1t, I ." Casing Type: AMAPurge Rate: , , ,.. Sampling Device: ?c-,• A- "Tubing Type: Measuring Point: -/oil 6'/'Pump Intake (ft below M.P.): coIor: •;t odor: AA•i'/

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) M_) (uS/cm) (mg/L) std units mV NJIU

Stabalization (see note +/- +/- +/_ +/- +/_ +I-CriteriaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%

5:00 _13,•t ,2Qa',X - "Q5 .263 ,5 7. / 7.2,70:00 __ _2_;_2_/P 7 1610:00 J?91 /15:00 1364.5 &O laIA4i - "qY 7,17 ,,- 7.0-r20:00 jJ./l -.Z, r j, zt,•L ••.a.,i '7,/7 1 . ,. V '625:00 /. /2/ .- 4, off30:00 7./& 4 3d35:00

40:00 lgý;77 /. 1

40:00 3 M6/ 7(

850.

45:00 tia 1 1160 7 has5000 .3.L5.. O,&u/Y- 1, i 11- 07/ '~ Pi) .~ ,

55:00 j3U- ~ atiS 7L 710 (%, KL60:0065:0070:.00 ____

75:400 ____

80:0085:0090:0095:00 ____ __________ ___ _ __

100:00 _____ ___________

105:00110:00115:00 _____

120:00 ________________

Sampling lime: iND -


Notes:(1) - Do notomeasure depth to bottom ot welt until after purging sod satrpling to redoet re-supeodiog frees that oay be restng so de wu[e botom•(2) -Stabilzatfon citerna based -n th0-e most re-ent consecudve rneasoroeeo.(3). Toldra'daowt i, wetl to be loss than Ito (,33 it). t'oagiog rate she tonlred nonecesoary to keep dlrowdoosbelow 0.1 tm (0.32 ft)(4),-/- ]0',•we turbldity is -1o0er Ts.

Site Name: ..D,8Low-Flow Groundwater Sampling Form

WeIIID: _______"_-3_ ___

Date: 612•/' 7Sampling ersonnel: , , .,

Weather Conditions: 4 A ., -cTime: i•.File Name:

Total Depth (l.D.): 0 ScreenLength: 740Depth to Water (D.T.W: & 3,9 L7 Well Diametei: "Total Volume Purged: #/V4. tQ-V Casing Type: 9?te• -

Purge Rate: Sampling Device:Tubing Type: Measuring Point. 740 AO/'L'"Fun.p Intake (ft below M.P.): '7 color: £Cý odor:

0

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mim) (feet) C) (uS/rcm) (mg/L) std units mV N'TU

Stabalization (see note +/_ +I- +/- +/_ +/_ -t/-Critenia' below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 410.2"• / /6 -•o 1 i . t5 -2•76,6 h 75:00 PI &lX 547,2 7,.. 0o -3W.2

15:00 ,Iq 7, H,5L _7 oY .-- 0-91Y20:00 "1[0J ;2ý;V7,-2u.•!7q 4QSV/ 0,4 0 7.05L• 0 ,25:00 g 2L, .,• / ,_O ,2 ZOO V -34 e 0_ 70-

20:00 At, OSO 7-- 32- U35000 J[/j, ti •O/tg/x• j~~r_• iQg O I¢,q..33/A[ O, YLLS

45:00 BI-L ..- T. . 7, ,4 0 : 0 0 Y / -,q " ,. -,50:00

__ __ __ ___

jPýt

55:00 t•LL&o Iq _g.6,7 tI, _y"I .. U/ 037 L60:00 Ik. U0 7AIX TV e. K, 765:00

70:00

75:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00

Sampling lime: 13'7...- ,9WSamples Collected: Analysis Requested: Preservative: Holding lime: Lab:

--rPvau, Gonq J 0g ie

Notes:(1)- Do not teas-re depth to bottom of well unitl a re pargingd saopling to redoce tesupending fares mat eay be reeting n the wnll bottom(2) -Sltebiautiot ceteria based an three moss recent consecutive measoremet.(3) Total drawd-wt in well to be les btehan1 m (0.32 Ar) Purging rate tube Int as necary t keep drewdorn betow 0. or (032/i).(4) ./- 10% -nnen ýItrbidity is -,e 10 NTUu.

Site Name:Low-Flow Gromudwate-r Sampliig Form

WeI1 W.".3 1"2D ,_-

Date: -SamplingPersonnel Q:Movr AS A~ -(

WeatherConditions: V ,. iIsO•"rL_"' ('dJ,.•-r' 9l. 1_ ,__L

Time: DWCmet ep SC D H OT Tr

File Na-me:.,2•" ' •

Sotab Depth (I.D.): n ; W Screen Length: - +.I

Depth to Water (D.T.W) Well Diamete%: "i%

Purge Rate: A-c " Sampling- Device: fe .•,&-q- UA • a.6DIrubin...T)2e: eo, 1Ph, e,. Measuring Point: -I-V: a• P c_

Pump Intake (ft below M.P.)- ,1 3.1, color:_, odor:• . 1--Time: DTW: Coixmaents: Temp SpC DOI pH IORP T-rb

(mt) (fet)@C) (u/-)i (m-g/L) [std unitsl mV INrU

Stabalization (seetnote +I- " +1- ft/- +- +- +-

Criteria below)' 3% 3% 3% .. i 1

5:00 119'/ ' q / / -,; • '.14--12a -a •70 / W Y 1-7.a '7 4 -;r?. 0 10 .'_7 _

10:00 / .. / a a.oý 7 3. a v 7.a--7 .6 0.q7

15___o /•.,•K rX•- •# .31 /€ 7.• -5'.4 -{

2b,-2- --,, i/4L•-

75:00 4___ 1________ ft.- , , " , 7 - ,

W-601?9YI 3Y71-,W7-. 9,, 4 1 /7

20:00 1?361 1_0'__ i1-7..,7 e, i 4.<"- ,_,_ I_,__

85:00 1Y. 45 QK90:00 1 .6._k_09___________9_1_(;_,_195:00 _fc_ 19.661 -1

45:00 W I 1 2811S2 -ý7 --.

100:00 kwi in605:00 1__ _ _ _

110:00115:00120:00

Samplig Time: / 3Eo•- / 3sS"Samples Collected: Analysis Requested: Preservative: H-oldinge lime: Lab:

(vM\) -1Ž5- - e Pia), ,I/AFit%- WT ýTl

4A tr, a-ncý L

Notes;~

(t> Do -ot -a.s- deopth ccbortnn of -11l otit after p ingio cnd -Tim.-n to roduon :cottensi-o dross that aye he reLn. on Lhoedwl botion,()-S~bfitm tios -ite, based on thre momst tennt consecutive toes-otenrnts.

(3; -lot,? dr-,d- in ic tonbe lobs sothan Odorm (0-32th) Poegiograte h to ber1n..d a ssr--ay to np &naodo rm treto, 0t Sn (0 32 h)(4) 1f- 10l c .hen -obid it i, eve, 10 m-t~s

SiteName: D avllS bS-low-Flow Groundwater Sampling Form

Wel .ID ..Date:Sampling Personnel: 1, c AAY-o, •. -o F , ? IOA .Weather Conditions:T im e : " ! ý ,f,-, -• ' • •/ / 4 4

,File Name. ý J2.

Iotal Depth (I.D.): 1., I .. Scrleen l "g KDepth to Water (D.T.W): t "4, l o Well Diameter: 3Total Volume Purged: r' (0 Casing Type: t v CPurge Rate: 18 0 A .I h , Sampling Device: P\-V c. OOr.,0 -c>Tubing Type: -.qo Measuring Point: -rT -c •, p.Pump Intake (ft belov M.P.ý: -1 / color:(Je. , odor: &L-- r- ,-n. 0

Time: DTW: Comments: Telnp SpC DO pH ORP Turb(man) (feet) _ (C) (uS/cm) (mg/L) 9td units mV NIU

Stabalizatlon (see note +/- 0 +/- +/- +/- +/- +1-Criteria' below)' 3%fC 3% 10% 0.1 unit 10 mv I0%•

0:00 14/10 It-Že~ :3 90"13; 5'1 -1 , ,) cl45:00 " 2 °&,0A 1 Cm . ', & -k 2. -7. 1 G'2. t ,"A

10:00 14, 31 1-I•2 I I.Ii 1-2,69 .,'cý% it b+ -1,Ih -111 Al, ,.Z25:00 14. 3 et t .,g"I,, 2Q -56A 12-4,,6'

30:00 t4,, i£ wl A A J 3 _ LS k C." ..Q S3,

55:00 3S 'i60:00 4_11AA465:00 7-0, 2-4 __&I&____1q

70:00 ____________._52

75:00 1-r34 o.2-5- :;,r+- -_3a__480:00 n,85:0090:0095:00100:00105:00110:00115:00

120:00

Sampling lime: /s-3 .-. /10 7Samples Collected: Analysis Requested:

,Tý,, + 4 j AA

Preservative: Holding lime: Lab:10 'f f, ! ,jC.k .4

f~ ~ s~ ~

Notes:

(1) -Do not -easur depih thboft of 'ell unitil rft purging -d -pliag to redc re pending fi-eotht iony bt resiag orn the well bottom,(2) - Sabi~i L~ioan criteria baed on three moost 0ecml0 ctst c onhve lfl-~re-nto(3)- Total drardo'n in wt Tclbeblekst thn 0 1 mt (0 32 fiL. Pt-giC, rate be aoweed aa. -- ye.esy toke-p drtdon bMo., 01 n (0 32 1t)(4) +/- TOY. when trbidiry is o.-r 10 NrTU

Site Name: T-)ari• -T •e•._Low-Flow Groundwater Sampling Form

WellID: M~ Vp - _Z .SDate: a-- Oi--

Sampling Personnel: JZ. (Mi~ Ac ,A IWT (iA AWeather Con tiction: - I. ..Jt L. 4 - 4c

Time: Oa, 71417-File Name: fL 2 g o lS

Total Depth (f.D.):. q 2z..' ZZ Screen Length:

Depth to Water (D.T.WM: I ,-•2/ Well Diameter: 2"Total Volume Purged: 3 j •,,4 - Casing Type: ?IPCPurge Rate: 20R ,A-w Sampling Device:Tubing Type: O4•t , ld.t Measuring Point pfb q p ' _Pump Intake (ftWbelod M.P.4 f ' color: cAe- odor: 1 -, ,

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (°C) (uS/cm) (mg/L) std units mV NTU

Stabalization (see naote +/- 44- +/_ +I/_ +/- +/-

Cniteria2 below)' 3% 3% 10% 0.1 unit 10 mv 10%,

0:00 q,7..q2. 1,--k.•,• i.49! 25-3 -1-15• U9-3,1 95"-55:00 1.44 ZQ ]vX..r.,U"1 R-_1 I a?3E

10:00 - -4'_J 194,4 2X2615:00 1 1 !?,. - -:J- Z2 O._I

20:00 ejJ- h4 il-LCs>t4. Z oo.z.25:00 I Z1O M Irvan I Zvn /_ 51X I 130:00 JqJA 2- eWJ/h vI 9 1 1_:21 s35:00 , 1 - h-3440:0045:0050:0055:00

60:00

65:0070:0075:0080:0085:00 . ......

90:00 ...

95:00 ____ ___ ___ _ __

100:00 ____ ___ ___ ___

105:00 _____ ___________ ____ _______

110:00 _________________ ___

115:00 _____ _______________ ___

120:00 _____ _______________

SampLing lime: / -


avWD31 1oA A-~ ft;ýr= t j-.',-4~

Notes:

l) - Do not memrc depdWs bottom of well phaterl to pouging-sd-~pling I. .edoce ,eoopodicg Fo- tlwmaocy to reciog- One -11ro' bottomo(2). isboto erjtsria bsoed on, Iloe, most rocent - .6-soiv osaooe- efltt(3).-To'. doocodocoin welt 1.lon loes tlooo 0 sm(0,32 ft) Poogio51sst to be lo,,eeso " --ceOto3keep diaw'- sbelow 0 1n 05.32 ft(4) +/- 10% otheo trobidloy 1, -c )0 oTMt.,

Site Name: IsA ý 9?&-2L ow-Flow Groundwater Sampling Form

Well]]: MB-U "-Date: ' B t.1%Sampling Personnel: l r• •CtA• < MZ, _0 SZ'O AWeather Conditions: Fa; -, S•-•r Lý-I S.)0 - M g¢

Time: 14 &ýAt ;he.-7 0 ?3,0File Name: L% 30 D

otal Depth (I.D.): .. Screen Length:

Depth to Water (D.T.W): iA. Well Diameter:Total Volume Purged: ? r5 a - Casing Type: t'a.c.PurgeRate: 2.OOA !i s, Sampling Device: (r-s-V1I1 C. PJo-

TubingType: eA!a , Ai 1 MeasuringPoint: -ton -C, eq- ' -Pomp Intake (ft below M.P.): "701 color: LT G;Aq odor' e. , o -

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mill) (feet) (MC) (uS/cm) (mon/L) std units mV NIU

Stabalization (see note +1- 0 +/- +[- +/- +/- +/-COiteria

2 below)' 3%/• 3% 10% 0.1 unit 10 mV 10%,

5:00 ie4-. Z..-wi , "t Yi. ,A. ff.-*.2. t10:00 Al

25:00 4.. ".. 2 -41,9,4 1. 70

55:00 ________________60:0065:0070:00 j -f I0.75:00 f___80:0085:0090:0095:00

100:00105:00110:00115:00120:00

SampLing lime: .)a 7,/ -

Samples Collected:LA -`-- 3. .h Analysis Requested: Preservative: Holding Time: Lab:(-10 Ae- rt3A E ýC(,oA#r,-e lZAC,,

F-

Notes:() -Do notmeassr depth io bottomr of wct until fWer purging and rnmpUiegt.oedeen renn- pendtng tines that neoybbenotinegn & e-wettbottonm,(2) -Stabifiation criterin bosed on thrce moot recent coOseotive me-nremectt.0)- Tot] drnn•,osn in -e11 to be lens thn 0 1 o (0.32 It) Pungi.g rate to 1- -oweed - - ynce, to keep dr.ndo.- bneo 0 1 o (0 32 ft)t4) -o" 10. hen I.trbidity i" one, 10 M.S

j

0Site Name:. iOL4 /3eSVg.•Low-Flow Groundwater Sampling Form

lWell IH>- MY i

Date: 713/ /07sawtvlina Pers'onniel: C, - Lza)no6 VV, E"I/1440-0flt0SCA' , yl-'c L'/-CIV M in57Weather Conditions: RD0" .- < 1,I-'•tAu . - An-Time: Y/D.'< -

File Name: ) l3 , -'

Iotal Depth (ID.): V L73. •-// Screen Length: :3.-;L

Depth to Water (D.T.W): 0) ,2q / Well Diamete: 3"Total Volume Purged: .•-_ Casingr T pe 'V'--Purge Rate: iqe 0 1*e Sampling Device: Perd-51z~k-, aTubing Type: U&Measuring Point 1V/,D P f'o !V(Z.Pu•pIntake (ft below M..): 3 , ,color:/4. " odor: 2

Time: DTW: Comments: Temp SpC DO pH ORP Turb(rain) (feet) (C) (uS/cm) (mg/L) std unitr mV NTIU

Stabalization (see note -i-I +1- +/- +I- +1- +1-Criteria' below)t 3%(C[ 3% 10% 0.1 unit 10 mV 10%,

0:00 b mn 04 a3-3 ____ aq.:?e -7106. . Zq"25:00 43, Y3 ,/,3 -qS03 0 ,9 -7,Jq -//gI 6,S30:00 1/ 1/3 /__- _C._/ -Q 0,60 -,13 -15,, R,015:00 1• ./0 9/- , ?3 ,/ .-1 4-0!;2il iL7i,•-i3 / T,20:00 ,.-, "il7• 6,41125"00 1q, q q,, !2 f ,gN • I3,3 •?(qL? 0J ,:• Z -/W% ,,"3o:oo _I 4. 12 W•/).'M, ,1AL,,, ,G--3 aZzO5-" /." =,• -.I- q~ /. q335:oo00q /NV ,7.e///]ak - 3 4,1¢0 AM , 7.9y/-1¢,•1& 7ol

60:00 it). 1;___ -065:00 //0 A A 070:00 40_/A&

75:00

80:0085:0090:0095:00

100:00105:00110:00115:00

120:00

Sampleng Time: Lab:

Samples Collected: Analysis Requested: Preservative: Hojldin~glie Lab:

0

Notes:(1)-Do not measore depth to bottost of wel tnIj alsor porging and ..attplosg to s~te d a-spendiag fsest tht ay h -sog tbewl1 boltom(2)- Stabiljoaiomtsn ont asd os th0re most recent morsscotits mcot.ermonts.3)- Total dsasodoots trwll tohe loss thon m.1032 Is) Posurga rate to be lossed us--T)sso to keep drtdot below 0 1 m (

532 ft)

(4) +/.- lo.when sorbidiy is os-eI 10 NTL

Site Namer Da.IIF) -t al-.L ow-rlow Groundwater SampfingFornz• •, • '•lPI67

iAJ•n Trk. M'ALI•i~ 21| I)

Date: 7 13(10-7 fC7 , LSamp!ITn Personnel: Cr; r 6tr ParWeather Conditions: S ct. r ,,,, - t, .! _.. ...iTime: 4c•, f -File Name: 0 E _ 1 .0 .. .

Iota] Depth(T.D): F Screen Length: 71Depth to Water (D.T.W): ( 10/ Well Diametei: 3• 2Total Volume Purged: :;3 Casing Type:__Purge Rate: /&. 0,/, /," Sampling Device: . e3/] "'Tubing Type: P)I VL//Rs4e Measuring Point 'Tc, j .c i a-a-P1 ,Pump intake (ft Jelow M.P.): c -0, color: IVa.,- odor:' V'j,; -g

Time: DTW: Comments: Temp SpC DO p14 ORP Turb(Min) (feet) (5C) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +/- 0 +/- +/- +/- +1- +/-Criteria' belowP 3%(r 3% 10% 0.1 utit 10 mV 10%,

15:00 • -2. -t4.a! ,. "3.,j• , 72L4 -3.-1} 7.1 7

25:00 17,73 /-.. , , .' 0.73 7.a-. ,1S, O30:00 0Z' .k . 67t 3. 9 q ,,0, LiL,.-' "-501'1 7 -St.35:00 1,,2 -1 JJ I z-O ý 7itA -4, 1.6 ,•,,3.50:00 ___,__ A3._ I& _7../ -1%_,3 __'_

40:00 '~~,5 .•W 1)/t Z3V .z.Ai', /2 A-- U3.?7 r,2.O 0.73 77,0 d-.4 ,55:00 17, 73 __ A _._ Q,60:00 A.3.3o___ 061,65:00 M___ V- 3 2/270:00 _____-_75:00 23.111 ___0W 480:00 ]#1 b2 105,85:0090:0095:00

100:00105:00110:00115:00120:00

Sampling rime: i~a5 .- Y/Jq'

Samples Collected: Analysis Requested: .Preservative: Holding; Time: Lab:_

Notes(1)f- Pm not tmeasure depth to bottom of wct I utttf otter purg ng sod .namptittg to red oce rennnspending bites that nu' bc restingntr, the woel! bottom(2)f Stabilization stiteejo based on tftree roost recen•t tonncctstice meassotemen~ts.

(3) - Totl drawdo.. in -11 t sbe Icm then 0. n, f0.3I- ft). Prgng r~tt to be too-red snes osty to keep d,-downn bosow t. 1 m (032 (tf(4) +/- ft . when turbidifo, i oer -O Ntrus

0* Site Name: D -J ,•,

Low-Flow C~-undzwater'•ampfiing Form

Well ID;: M U 3QDate: 7 ISampling Personel. C-1 't1 4 i -~ .

Weather Condlitions: f p'!jTime:* " 1' 2(,e 1 -

File Name: P 232S

Total Depth (I.D.): s3 "creenoet- t "Depth to Watei (D.T.W): (1) /4/ / Well Diameter: . '

Total Volume Purged: ,•,•f e ..Casing Type: C-,-'PurgeRate: ,0,tZ1p,• 4e• Sampling Device: 1_-,,& :-•.- x'-,Tubing Type: POi '• •. p-.a._J Measurin Point: - .

Pump Intake (ftbelow M.P.): ! 2' ' color: -- /j odor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(main) (feet) ('C) (uS/cm) (mg/L) std units mV NIU

Stabolization (see note +1- o +1- +1- +I- +1- ÷/-

Criteria below) 3- 3% 10% 0.1 unit 10 mV 10%,0:00 Z "-. -28• WS.• • ,r?.r. .9 3 .. "t A -. Q 1 7. aq - 70 'q! ,. q

5:00 l42-j, z .2 IV *t f ,WA. 2.-19 2507, 16-4- .4-4 1-&&M. f. 1210:00 Z, .Z7' 2i ,RALf,ýA - 21,7 2SIO z 18 1t.2 1 7z_ -72o1o 1.'1

25:00 tf, '.e yLjrq•,1 22. z2Lj' I 3•.=(,2 ...i . -o o30:00 IV.2•I 2 (A J,-/ 24 y In, . " Z•-335:00 1 I A 2q ')I- 7,2 -q I::-

30:00 aOR -,k,(q -7 2,45:00

50:00 1 200 1 19 71 7 2z47( -¶a. 0

55:00 ____ ________ __

60:00 ____2- 8_7- -- - -I 0,12

65:0070:0075:0080:0085:00

110:00115:00120:00

Sa~mpling Time: IS /d0.- /5'9,DL

~Afj6t~


aqw- 3-ý -To- I Tl cu}t

bep-o t -rp IT I ill

Notes:(1) -,Dorset oeass~e deptlh to bo:tor af well util terrporgingssd samplng o redoce resussprnding fieo• thai nay tre restmg o, th, werif bottoe.

(2) .. Stahitira tiot eriteri, based on three moto receta consecotihe rreosurtements•

3- Total drewdordsn i- 1el to he leos than 0.1 m t0 32 ft) Ptgting rawe to be lowered ms -reresary to koep drewd ovo bM-ars 0.1 m (0.32 ft)(4) .!" 10'X wb•e t-rbidi3y iseer _ 0 NTtLIk 0

Site Name: U-7f N - -L ow-Flow Groundwater Sampling Form

WellD: M \AJ--'AA DSamp Ling Personnel: St ,vzdc. YZVr OC , ,RSW EWeather Conditions: 7&' F', :,i f'ryf)•Time: I -t4 -- l;File Name: 0(3,3 3a. ...

Can~erTotal Depth (I.D.): g Screen Length:

Depth to Water (D.T.W) m Well Diameter:Total Volume Purged: X. Casing Type: FN C.Purge Rate: I 2C- .... / 'D , Sampling Device: r.;f,,i4 tI jL..fMTubing Type: P-/ e,1.q-fe"1.•e, Measuring Point * +6 f iz I -

Pump Intake (ff belofw M.PK): '7 t' color:a4e"r odor: jff.'r s&,,z,

Time: DTW: Comments: Temp SpC DO pH FORP Turb(ain) (feet)() (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +/- +1- +/- +/_ +-" +1"Criteria' below)' 3%la- 3% 10% 0.1 unit 10 mV 10%4

10:00 11-.-4If 132 AriiL/n, 2-OZ3 I(,.4O J2 Ii2 336a2,-oO5:00 5. 3' 7-i&4 ,,Lv.j•. Zio4 Itq"$fta Lo.4..f) -a#AL-4 n 21)

10:00 f2..,-, 2,12,_ - nrQ 21-0 43Ub _!5. 1 a&_-4-•' -_iAf. 0 0.21.15:00 1.1-3 2-Co r,'.g, ..j A .. t-2.1 i0 jG2.C -ZL ,,1 t

250:00 15-V Z2 y L /L 2o.63 160110 l y..g (; -339,0 Z

30:00 / "eb4Ie..L~ 4.~L2.L .,f A35:00 j 5 ~ Jw L~L• eA9~

40:0035:00 5.5' &-.997955:00 22 zr4WA2 .. li~e f5I.20. &,_ 4 -9_3___QJ

45:00

600:00 5 4'A I lo(Ie .V

t05:008I0:00

115:00"'

120:00

Sampling Time: /7-'/-/

Samples Collected: Analysis Requested: _Preservative: Holding time: Lab:

.

,- I t

itl, Ik-32- 6 'I. t1n WM W/A 464dw~2sf Eý I

Notes:

(1) - Do not - -easoe depth Io bottoo of dell coil Itie, purging .. d sampliog to ed-ce -eecpon gtne flos thaty tbe cottog oo the -11f botsom(2). Stbiliear-.t criteria based on three mee recet cenetiee .- en areo-enLs.(3) - Totl dtandowe it well to be 1er than 0 t (032 It) Pargtno rate to be tierted a. -e-etry to keep d,.aordonn below 01 or (0 32 fly(4) /.* 10% whet,0 lutbdity Ls over 10 Nrr'Us.

0Site Name:- Grnwae aplin j-gForL ow-Flow Groundwater Sampling Form

Wel ID: LO - .k , SDate: 02sampling Personnel: t, (Ca. A-ct ~Weather Conditions: S LIP. rlV S6 I) 4yTime: • , '44,,---"File Name: '3

Total Depth (.D.): " 2.. • S'Length: 3b

Depth to Water (D.T.W): ) •, . Well Diameter:ypeTotal Volurne Purged: .0 r Casing T ye:PurgeRate: f'1 2, /j ,. Sampling Devi e: alA.,a MAJ t4n .Tubing Type: :V•o tXy ed/IA f.• ... Measuring Point: Iip j a j2 104a-PumpIntake(ftbeloGvM.P4.: ,'.V color:n4,.A', odor: &tw!¢,• "

Time: DTW: Comments: Temp SpC DO pH ORP Turb(rin) (feet) M(C) (uS/cm) (mg/L) std units mV NrU

Stabalization (see note +/- 0 +/_ +/- +1- +/- +/-Criteria' below)' 3%IC. 3% 10% 0.1 unit 10 mV 10%,

0:00 /37,7, 9 .i.,nvp•,). ;4-, •,T_ -- 6 7- 16- -A/1` a 7,Q

45:00 /,-7 ,€E,ý-dcnr•.,;21sý & '- ls/1.: f 2l .S•t l7e 10,,A.A...

10:00 17 Q•2 . o/•• 4 3,-0. I 1 "7.IC- A7. 3 1/a315:00 .2 " M#20:00 3 QJGOU Lut 3 4

25:00 W32 5ca1a P-1615. 09

30:00

105:00 '

140:00 -95 Q jj vF 7 -_

45:00 2__50:00 1 1-7-- 7. t55:00 13-7 Ln A . J 1vV ~ ~ 3. .51' -~7,17_

60:00 2S.L4 jW 1Ii165 -?-, I__t

65:00 ]i_7 ;;u___ ~-t 5 i ±A -L~ -5,

70.00 S1 Z 2_5 L jp -4, :! - OeI,5 -1

80:00 _1.3-33 11--Mý1,AW 2S,531 2_5S- 0~~ 1 71 •85:00__________ __

90:00__________ __

95:00 ___ ___________ ___ ___

100:00 _____ ___________

105:00 _____ ___________ ___

110:00 _____ ___________

115:00 ______ __________ __

120:00 _____ __________ ____ ______ __

Sampling Time: /'A7-/o-

Samples Collected: Analysis Requested: Preservative: Holdini lime: Lab:

r6fhnTtA--

', ý-l r ~g --,&PUMIrAL LA7 C.

I;ý

Notes;(-)- Do snt ecas-ee depth to bors, of well until aicr purgin and sampling to reduce r- spe tding fines thatI may hS rsinag on the well bo]tus.(2)- Stabiliuahion critet•i based on 1ree mast recoat •aetive messurements.W-. oral d-aedowan in well to be les than 0 1 m (0.32 It) Puging .ae to ae lo.wered neeemars' to keep drswd0- trelo',0 1 . (032 11)44) I/- 10'hs-hes Iorbidity is o- 10 NrfltT s 0

Site Name: )ANIS, TSSfI ow-Flow Groundwater Sampling Form

Sampling Personnel: F-.McL - '~5 ___

Weather Conditions:

File Name: 3) b M LQ 3 -T otal Depth (I.D.,: U .0 Scr•# een n igth:_7L1

Depth to Water (D.T.W): (3) lie* jaI Well Diameter: ý,Total Volume Purged: 5. 0 Casing Tye: P - ,Purge Rate: t b 5 Sampling Device: - . . ,Tubing Type: 0o t //I/e1 ae. ., Measuring Point t i. Jj,'V" pýAjPump intake (ft elow'M.P.): - color: c,* tv odor: L L.F, r: t\I

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mim) (feet) (0c) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note + +1- 41- +1- +I.. +l-Criteria' below)' 3%lI& 3% 10% 0.1 unit i1 MV 10%

0:00 ,1.4 , -3).¢d,/,9.,. Ob.'S 6,T3q q I. 6-90 ?u.3a.

15:00 31 'to 94-4 -10:00 /z. 3% ,, ,. ',A. k f,

25:00 V4..2 - 513 , ' :.io • 4 - 1 •.7_._30:00 j,4.1 i"il " " ' ... .35:00 /.,3J,,, 64 6A,74 <JL! -V7 .- . . -740:00 A5ý16& 7CQ ~,(145:00 /. 3-_Y __j 3-50:00 /_/_ _______55:00 1Y. 3s•- 12 , Y.. -7,,4 (a,317e• OL q 9z ;--2'.7r.s460:00 /4/,• / iV65:00 _iS e22:A- ".•,,,/ ,#, 171.• 63T•.71 qq 4 /oIL, "-,9,??1X e.• 570:00 /"1"-," / " _ __

75:00 , , ... ,

80:0085:0090:0095:00100:00105:00110:00115:00120:00 _

Sampling lime: aP1 lveJ:iLm: aSamples Collected: Anayi~s Requested: Preservative: Holding- lime: Lab:

A) FThk.~i ~c~a~g~az#4Li

Notes:(1 -Do not mesanre depth to bottom of ell [l;]a frprginrg and .amrpling tedur .e.pe ndmr fin.n th.1 tay bh -estLgno the well botto.(2) .-Slabiliza ton criteria bated on three rort recent ce Innecer nmeatrecents.(3)1o3-1 danwdoc isn c ell 1o be lens than 0 1 (0.32 It) Purging rate to be lowered en necessary to keep drnwdoe. below s . 1 ho (V 32 It)(4) r /- 101' when httltidity t noer 10 NTUn

SSite-Name- Qrounwi - N, 5a4pin FormLow-Flow Groundwater Sampling Form

Well • b/i b'4 -" ..5 "CdCJDate: Z(;/k7 - IA/Sam ling ersbn "k 7_ ... . M ,-, rWeather Conditions: k.flP , qvvý'

Time: ~ ~ I4 -757 3 ________

File Name: -sii

Total Depth (I.D.): /ie-n Length: _"

Depth to Wate (D.T.W): / 33 Well Diametei: '3Total Volume Purged: Casing Type: £"fC..-Purge Rate: I ý Sampling Device: .,tG.r "-', €- 6")f

Tubing Type: tb k e.,-idt-qfl*. Measuring Point) -I j n-" QA ,__ , (Pump Intake (ftbelod M.P.): 3 -.. color:,C[C & odor: I,, ,.

Tine: DTW: Comments: Temp SpC DO pH ORP Turb(rain) (feet) ('C) (uS/cm) (mag/L) std units mV NIU

Stabalization (see note +/- 0 +1- +/- +/- +/.. +/-

Criteria' below)' 3%/L• 3% 10% 0.1 unit 10 MV 10%,0:00 t5, ¢" 01 1, TA.. C1c 1 ý....is',• t£X.. '-I ,* A: -3, 12 4 Iq_'•

5:00 1•e...z f I., //l,' 2,j " ' "2OS .-

20:00 7 oL5LM.', !.C1b "k,1 tW 1 1d4 2 ,25:00 2".7 2-cV2 ,L/ro .,t --. Yr lI3•. 'i'ji 4--> "i

25:00 15 •._S-e Z2_L-.,1Ilj l., ýn A4.'Ar 3-(L3 Z. q "-1~• •Socl'30:00 ",511/ ,o I. 26QI Jqq -7, I -10744' -22Zi, .•-935:00 (~i¶ 2 '.4.91- IG I-2[ _S R ,.ý i 14- "*t 01.r,

40:00 '1% j-ZAr f '15,o) 25cj4- 15 t4 A45:00 x5, t ' .(15 154"6, 2-- 1 /L_ ' -7,.; c5 13. -I .Z. c , CI50:00 ,s1!5.C i•, 3 -5,578 -'1 , 7,t5- ,55:0060:0065:0070:0075:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00

Sampling Time: /1¢/ I4


o. N-A 5• LO i+ H

0ict,_-P',

ý,- - ) kD ýOJ -r ý' uJm rkh i '~ n.i Pýi /Jr) . lvi idw~s1

Notes: - ~0 r~i !)FD.) - Do ttot meusure depth -11 miott oltwell pnuil afterprgiing ad Umplintg Wt educe remaspending fiels h.,, maybs rettiog\tre well bo~om (

(2) -Stobilinatino crilteia boed on three most recent consecutive measoemsnlo.

(0)- Total-d1rdo d n inell ob1 le, s b than a I mt(032 ftl Porgintg r-to tmob 1ote-d snoetaty to keep drwdot.- belo 0 1 m (0 32 ft)(4)nI- 10 whee trtobdl iriover 10 N1TUs

Site Name: [J ViL -xLLow-Flow Groundwater Sampling Form

Sam pling Pe rs onnreF -AL Ei II',2 . 7 ,,5 tWeather Conditions.:~ ~A '.Z~tiF ~ n/~~ A)WiA) iTime: -g 7(JR'7 /-File Nami: -- -6 "

lotal Depth (I.D.): $0a7-.I Screen Length:

Depth to Water (D.T.W): (1 ) -. Well Diameter:Total Volume Purged: " .Casi•r Type:Purge Rate: 1 9• ý.J" Sampling Device: r -¶s tf ao"' &-.Tubing Type:~ 0-(V MeasuringPoinr.t: a)trbPump Intake (ft belovi M.P.): I color: . odor. C- I v L( -rsf

Time: DTW: Comments: Temp SpC DO pH ORP Turb(rmin) (feet) MC) (uS/cm) (mg/L) std units mV NWU

Stabalization (see note +/- 0 +1- +/- +/- +/- +/_Criteria2 below)' 3% 11 3% 10% 0.1 unit i0 mV 10%,

0:00 0 0"1 23-c -321. e) L5:00 1 3 " _ "2 .1 ,, j--*3.,e j Iecrl . ,.'1 .' 0 O.lt1:00 /:030 3' •,-I-i, , a iq 10.292 "1 "7. -32-73T le 0. 1-

__T0_.0_ -- V. Q`-'4

25:00 IiLl jI 4R /I3!&~ ~2k '3-a0350 ll- _q. _ _ 32

40:00 /~ 4 ~ ~ Ji ? & L~~Q45:00 ____ __________ __ __

50:00 ___ ___ _ __

55:0060:00 _____ _____ ___

65:00 ___ ___

70:00 _____ ___ ___

75:00 _____

80:00 _____ ______________

85:00 _____ _______________ ____ ____ ___

90:00 ________

95:00 _____ ___________

100:00 ___________ ___

105:00 ________

110:00 _____

115:00-j_____

120:00

-oo //. 5-7,g•f.,L, •~a,••÷?9•q-.,m

Sampling lime: ....

Samples Collected:M: u) - -ýql

Analysis Requested: Preservative: Holdinge lime: Lab:A) 1A y ,

Notes) -- Do not - -tnenete depth to bottoe of -1ott -nit after purging aot saopling to tedtte resuspending fines that nay •e resting on the wnet bottomt

(,)-tbitaon criteria W aned on three .. ,e recent or-eacette oteonnreoenotn( 3 ) +- T o o t e it at wd o tn n n w ell so b e t e h a t ] m ) 03 2 I t) P u rt in g t aL e to tt e lo wr e d en e e s e te k e e p d r wd o s n h e t lo w m ( 0 3 2 I t)(4)÷n/- 10% shon tttrbidiey noner 10 tJTUe

0Site Name: GroundwteSa llow-Flow Groundwater Sampling Form

Well ID: -- I ":Date: :l1 n

SaplngPdrsnne: EG 1 W* ae K -- TP , Vr) TPWeather Conditions: OT F ,{O A~o'VLŽ1 St) W- YJTime: avfq lýý'File Name: IN P0 ;1.

1otal Depth (I.D.): q2- J'2 Screen Length: "

Depth to Watez (D.T.W): () ._ £f .' Well Diameter: 3"Total Volume Purged: 1., or,4 Casing Type: - Cif6Purge Rate: m, - ./ \ Sampling Device: - Stpi~i- €'JA..Tubing Type: - Measuring Point: -t% e-- .XC.Pump Intake (ftbbIow .LP.): '3 2 i" color: o,.'na:.e odor: r )


Stabalization (see note +/-o * +/ +/- +/_ +/- +/-Criteria' below)' 3%IC. 3% 10% 0.1 unit 10 nMV 10%

0:00 i,3-. qf'5:00 4~~3 -11 Y'ei I ~ ?Y31 'If~ C, j~ -7"1, %1 8>i~10:00 1• +3 "ZCZm,,/o,•,In, 1.{ 4 c" 1 q5 -7 345 --- :3 t,• 3'.r

15:00 13.43 - 'o- i -/ rc i-7,2F Z4 1 -1 -7, 3" ' -I .20.00 .,,A 44- 24,4Imlra ,.i i -1y L*I '3V 1,3+ -0fl 3, /,C25:00 ,3 .. - isIn/n,, ý , I Z477 e0 7. 31 3. fa 6,0Z30:0035:0040:0045:0050:0055:0060:0065:0070:0075:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00 _

Sampling Time: /4( -l'

Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:S(ii ,,• •' L 7,

Lfvi.!'

Notes:

(1) Donut measure dep:h to bottom of wet until after purgitg and eceopting to reduce .e.,rpendmrg 6o-s tfat may be resting on the well botfonm

) -Stabigiation criteria based on three most recent oonseonlive measurements.3f 'Total dr-wdocot in eell 0 be I.. than 0 1 m e0 32 ft). Purgilng rite to be loweered s necessary to beep drawtdoen beelow 0.1 m (0.32 ft)(4) e/- 0M. whein turbidity is .-er 1O fTU.

Site Naine: - 5eASR..Low-Flow Groundwater 5amplingFonn

WellJD: I -I3D _-_ _Date: '•/ . / 01

Samnpling Pers'onnel: ~( . ~ ~ -

Weather Conditions: .4[-0 n~, Lse.,~' ~ ot~(4 r ~ ~ ! t

Time: IQu t/yoFile Name: _

lotalDepth(I.D.): ScreenLength: 7 '

Depth to Water (D.T.W): (• 4 ' Well Diameter: 2Total Volume Purged: 4- , Casing Type: T-- ___-._

Purge Rate:.. Sampling Device: Qfsn ~ ~ ~.Tubing Tye: # ) "•']/yo Measuring Point .' _, . '.Pump Intake(ffbelou M.P.5 : -o color: &!Li -r, odor: I r*

Cie i, rTime: DTW: Comments: Temp - SpC DO pH ORP Turb(-in) (feet) I C) (uS/cm) (mra/L) std units mV NIU

Stabalization (see note 0 +/- +/- + - +/_- -Cxiteuia2 belowY 3%Ici 3% 10% 0.1 ýt 10 V1 10%,

0:00 %_ 1",• 1-4. 3•x,. A. I t3 4 1;, c-A 1

5:00 f t, ýqrdii _s ~ ~ ~ >fS

10:00 L-6,j O. -t/.a ' t9,<7 c4,ftc o 4 (0'f? •:Ž45 1.1515:005 Z --a4e, '1 .6r,

°l.-o -•.( =•z _: 20_00 I: ,c r k--- 25:00 -z ! ' /, -

I t 'I ý2,2 I llb_ mo I o. , i I I t-.-,4 ý 2si . (ý I J, s. II H:2I L90;.P61 ') I, I I ft" .

30:00 _.• I,• i U Cm (1,A A I i~i~a~ ~ I e'. 4r~F 10 i ~( ,,)e;:4 ~.

40:00 2LL. /iab 3 e 13 4 j

1 45:00 17 -ý 743 I.e<L A- kv - . '1 50:00 7ý ~ I/eri~~v4 ' ~ j. ~ e~7 o

55:00 Q2t"' ~ ~ '' ~ ~ ~ 7' 1~

65:00 ~ re er/..i js~ i)'~70:00 j "-$:,o,-7., z Ul /3/ I* - ý j/. l ~tb?/7. o'. I I fDaI0*7;: f'_iS '-'- 1

€75:00 I 1 I I I80:00 _________ __

85:00 __ __

90:0095:00 _ __

100:00 _____ ___________

105:00 ________ __

110:00 ___________

11-500 __ __

120:00 _____ ___________ ___

Samplnhg lime:

Samples Collected: Analysis Requested: Preservative: Holdin Timre: Lab:

Notes:(])- Do tot meatere dept, t bottom of wb[I 00th after ptu1 tnr ted -nplint to reduce erereihtg Sues that mey be ztsg on the te!] boson(2)- SýIailietion crheria bused on three mstoneceutoecutive mesurements.(3)- Tetel dt6edo-n i well to he le then 1 to (In i It) P.rging ate to bo uunend as tekenrary en ktep ds'dnnot hefoe 51 . (052 hf(4) o•/_ T.v when h-th id h, e:or 10 NjTUe

- • Environmental, Inc./ Midwest Laboratory

- an Allegheny Technologies Co.

700 Landwehr Road - Norlhbrok, IL 60062-2310ph. (847) 564-0700 - fax (847) 564-4517

APPENDIX A

INTERLABORATORY COMPARISON PROGRAM RESULTS

0

NOTE: Environmental Inc., Midwest Laboratory participates in intercomparison studies administered byEnvironmental Resources Associates, and serves as a replacement for studies conducted previouslyby the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada. Results arereported in Appendix A. TLD Intercomparison results, in-house spikes, blanks, duplicates andmixed analyte performance evaluation program results are also reported. Appendix A is updatedfour times a year;, the complete Appendix is included in March, June, September and Decembermonthly progress reports only.

October, 2006 through September, 2007

Appendix A

Interlaboratory Comparison Procgram Results

Environmental, Inc., Midwest Laboratory has participated in interlaboratory comparison (crosscheck)programs since the formulation of it's quality control program in December 1971. These programs areoperated by agencies which supply environmental type samples containing concentrations of radionuclidesknown to the issuing agency but not to participant laboratories. The purpose of such a program is to providean independent check on a laboratory's analytical procedures and to alert it of any possible problems.

Participant laboratories measure the concentration of specified radionuclides and report them to the issuingagency. Several months later, the agency reports the known values to the participant laboratories andspecifies control limits. Results consistently higher or lower than the known values or outside the controllimits indicate a need to check the instruments or procedures used.

Results in Table A-1 were obtained through participation in the environmental sample crosscheck programadministered by Environmental Resources Associates, serving as a replacement for studies conductedpreviously by the U.S. EPA Environmental Monitoring Systems Laboratory, Las Vegas, Nevada.

The results in Table A-2 list results for thermoluminescent dosimeters (TLDs), via InternationalIntercomparison of Environmental Dosimeters, when available, and internal laboratory testing.

-Table -A-3-lists-resultsof-the analyses-on-in-house-"spiked"-samples-forth e-pa st-telve-rnO-th-s.-All-pplesare prepared using NIST traceable sources. Data for previous years available upon request.

Table A-4 lists results of the analyses on in-house "blank" samples for the past twelve months. Data forprevious years available upon request.

Table A-5 list results of the in-house "duplicate" program for the past twelve months. Acceptance is basedon the difference of the results being less than the sum of the errors. Data for previous years available uponrequest.

The results in Table A-6 were obtained through participation in the Mixed Analyte Performance EvaluationProgram.

Results in Table A-7 were obtained through participation in the environmental sample crosscheck programadministered by Environmental Resources Associates, serving as a replacement for studies conductedpreviously by the Environmental Measurement Laboratory Quality Assessment Program (EML).

Attachment A lists acceptance criteria for "spiked" samples.

Out-of-limit results are explained directly below the result.

Al

Attachment A W

ACCEPTANCE CRITERIA FOR "SPIKED" SAMPLES

LABORATORY PRECISION: ONE STANDARD DEVIATION VALUES FOR VARIOUS ANALYSESa

One standard deviationAnalysis Level for single determination

Gamma Emitters 5 to 100 pCi/liter or kg 5.0 pCi/liter> 100 pCi/liter or kg 5% of known value

Strontium-89b 5 to 50 pCi/liter or kg 5.0 pCi/liter> 50 pCi/liter or kg 10% of known value

Strontium-90b 2 to 30 pCi/liter or kg 5.0 pCi/liter

> 30 pCi/liter or kg 10% of known value

Potassium-40 > 0.1 g/liter or kg 5% of known value

Gross alpha < 20 pCi/liter 5.0 pCi/liter> 20 pCi/liter 25% of known value

Gross beta < 100 pCi/liter 5.0 pCi/liter->-l-(ei•ter 5%/-otkiwrlue

Tritium < 4,000 pCi/liter 1 la = (pCi/liter) =

169.85 x (known)0°0 933

> 4,000 pCi/liter 10% of known value

Radium-226,-228 ? 0.1 pCi/liter 15% of known value

Plutonium > 0.1 pCi/liter, gram, or sample 10% of known value

Iodine-131, -< 55 pCi/liter 6.0 pCi/literIodine-1 2 9 b > 55 pCi/liter 10% of known value

Uranium-238, s 35 pCi/liter 6.0 pCi/literNickel-63b > 35 pCi/liter 15% of known value

TechnetiUM~99b

Iron-55 b 50 to 100 pCi/liter> 100 pCi/liter

10 pCi/liter10% of known value

20% of known valueOthersb

a From EPA publication, "Environmental Radioactivity Laboratory Intercomparison Studies

Program, Fiscal Year, 1981-1982, EPA-600/4-81-004.b Laboratory limit.

A2

TABLE A-1. Interlaboratory Comparison Crosscheck program, Environmental Resource Associates (ERA)a.

Concentration (pCi/L)

Lab Code Date Analysis Laboratory ERA Control

Result Resultc Limits Acceptance

STW-1 104STW-1 104STW-1105STW-i 105STW-1 105STW-1105STW-1 105STW-1106STW-1 106STW-1 107 0STW-1 108STW-1 108STW-1108STW-1109

STW-1121STW-1 121STW-1 122STW-1 122STW-1 122STW-1122STW-1122STW-1 123STW-1 123STW-1124STW-1 125STW-1 125STW-1125STW-1125

STW-1 127STW-1 127STW-1128STW-1 128STW-1 128STW-1 128STW-1 128STW-1 129STW-1129STW-1 130STW-1 130STW-1130

10/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/0610/06/06

04109/0704/09/0704/09/0704/09/0704/09/0704/09/0704/09/0704/09/07

04/09/0704/09/0704/09/0704/09/0704/09/0704/09/07

07/09/0707/09/0707/09/0707/09/0707/0910707/09/0707/09/07

07/09/0707/09/0707/09/0707/09/0707/09/07

Sr-89Sr-90Ba-133Co-60Cs-134Cs-137Zn-65Gr. AlphaGr. Beta1-131Ra-226Ra-228UraniumH-3

Sr-89Sr-90Ba-1 33Co-60Cs-134Cs-137Zn-65

Gr. AlphaGr. Beta1-131H-3Ra-226Ra-228Uranium

Sr-89Sr-90Ba-133Co-60Cs-1 34Cs-1 37Zn-65Gr. AlphaGr. BetaRa-226Ra-228Uranium

38.4 ± 1.315.5 ± 0.564.9 ± 2.861.6 ± 1.029.0 ± 0.977.8 ± 2.4

293.0 ± 2.423.9 ± 2.523.7 ± 1.428.4 ± 1.214.5 ± 0.56.6 ± 0.42.9 ± 0.1

3000.0 ± 142.0

30.7 ± 4.339.3 ± 1.830.0 ± 2.4

118.5 ± 3.952.6 ± 2.349.5 ± 3.891.7 ± 6.333.8 ± 3.5

24.2 ± 2.319.2 ± 1.2

7540.0 ± 255.013.0 ± 0.619.9 ± 2.74.5 ± 0.2

51.7 ± 5.021.4 ± 2.319.4 ± 2.232.8 ± 2.067.0 ± 2.961.6 ±3.855.6 ± 7.519.2 ± 1.6

9.1 ± 0.97.0 ± 0.59.2 ± 2.3

23.9 ± 1.1

39.916.070.262.329.978.2

277.028.720.922.114.45.93.2

3050.0

35.442.129.3

119.054.350.388.656.525.318.9

8060.013.418.24.6

58.219.019.433.568.961.354.627.111.57.79.1

25.1

31.2 - 45.77.3 - 24.7

58.1 -82.353.6 - 71.021.2 -38.669.5 - 86.9

229.0 - 325.016.3 -41.112.2 -29.616.9 -27.310.7 -18.13.3 -8.40.0 - 8.4

2430.0 - 3670.0

PassPassPassPassPassPassPass

PassPassFail

PassPassPassPass

26.7 - 44.133.4 - 50.820.6 - 38&0

109.0 - 129.045.6 - 63.041.6 -59.073.3 - 104.032.0 -81.016.6 - 34.013.7 -24.1

6660.0 - 9450.09.9 - 16.9

10.3 -26.10.0 -9.8

49.5 - 66.910.3 -27.710.7 -28.124.8 - 42.260.2 - 77.652.6 - 70.045.2 - 64.015.4 -38.8

2.8 -20.25.7 -9.75.2 -13.1

19.9 -30.3

PassPassPassPassPassPassPassPassPassPassPassPassPassPass

PassPassPassPassPassPassPassPassPassPassPassPass

Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency

testing in drinking water conducted by Environmental Resources Associates (ERA).b Unless otherwise indicated, the laboratory result is given as the mean ± standard deviation for three determinations.

Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits

as provided by ERA.The reported result was an average of three analyses, results ranged from 25.36 to 29.23 pCi/L'

A fourth analysis.was performed, result of analysis, 24.89 pCi/L.

Al-1

STABLE A-2. Crosscheck program results; Thermoluminescent Dosimetry, (TLD, CaSO4: Dy Cards).

mRLab Code Date Known Lab Result Control

Description Value ± 2 sigma Limits Acceptance

Environmental, Inc.

2006-2 11/6/20062006-2 11/6/20062006-2 11/6/2006

2006-2 11/6/20062006-2 11/6/20062006-2 11/6/20062006-2 11/6/2006

2006-2 11/6/20062006-2 11/6/2006

30 cm.40 cm.50 cm.60 cm.75 cm.90 cm.120 cm.

150 cm.180 cm.

55.6131.2820.0213.908.906.183.48

2.221.54

60.79 + 1.3235.93 + 3.7021.55 + 1.2014.90 + 1.428.03 + 0.516.88 ± 0.682.90 ± 0.20

1.99 ± 0.071.79 ± 0.94

38.93 - 72.29

21.90 - 40.6614.01 - 26.03

9.73 - 18.07

6.23-11.574.33 - 8.03

2.44 - 4.52

1.55 - 2..89

1.08 -2.00


PassPass

'Environmental, Inc.

2007-1

2007-1

2007-12007-12007-12007-1

2007-1

2007-12007-12007-1

2007-1

7/13/20077/13/20077/13/20077/13/20077/13/20077/13/20077/13/20077/13/20077/13/20077/13/20077/13/2007

30 cm.40 cm.50 cm.60 cm.70 cm.

80 cm.90 cm.100 cm.110 cm.120 cm.150 cm.

54.2530.5119.5313.569.967.636.034.884.033.392.17

60.56 ± 5.54

34.23 ± 0.96

17.95 ± 1.86

16.61 + 0.60

9.72 + 0.90

7.79 + 0.33

5.53 + 0.72

5.32 ± 0.173.49 ± 0.14

2.64 ± 0.14

2.13 ± 0.87

37.98 - 70.5321.36 - 39.6613.67 - 25.39

9.49 -17.636.97 - 12.955.34 - 9.924.22 - 7.843.42 - 6.342.82 - 5.242.37 - 4.411.52 - 2.82

PassPassPassPassPassPassPassPassPassPassPass

A2-1

TABLE A-3. In-House "Spike" Samples

Concentration (pCi/L)8

Lab Code b Date Analysis Laboratory results Known Control2s, n=1 c Activity Limits d Acceptance

W-120106W-120106SPAP-9476SPAP-9478SPAP-9478SPW-9480SPW-9483SPW-9486SPW-9488SPW-9488SPMI-9490SPMI-9490SPF-9492SPF-9492

W-30707W-30707S PAP-1566SPAP-1566SPW-1568SPW-1678

SPW-1 595SPW-1595SPW-1595SPW-1595ASPW-1595BSPMI-1597SPMI-1597SPMI-1597SPMI-1597ASPMI-1597BSPCH-2839SPW-2847SPW-2847SPW-2847SPMI-2849SPMI-2849SPMI-2849SPCH-2922SPW-2847SPW-2847SPW-2847SPMI-2849

12/1/200612/1/200612/29/200612/29/200612/29/200612/29/200612/29/200612/29/200612/29/200612/29/200612/29/200612/29/200612/29/200612/29/2006

3/7/20073/7/20073/23/20073/23/20073/23/2007

3/28/2007

4/5/20074/5/20074/5/2007415/20074/5/20074/5/20074/5/20074/5/20074/5/20074/5/20075/17/20075/17/20075/17/20075/17/20075/17/20075/17/20075/17/20075/17/20075/18/20075/18/20075118/20075/18/2007

Gr. AlphaGr. BetaGr. BetaCs-134Cs-137H-3Tc-99Fe-55Cs-1 34Cs-137Cs-134Cs-137Cs-134Cs-137

Gr. AlphaGr. BetaCs-134Cs-1 37H-3Tc-99

Cs-134Cs-1371-131(G)1-1311-131Cs-134Cs-1371-131(G)1-1311-1311-131(G)Cs-1 34Cs-1371-131(G)Cs-1 34Cs-1371-131(G)1-131(G)1-131Sr-89Sr-891-131

22.40 ± 1.0363.70 ± 1.1457.51 ± 0.1426.84 ± 1.23

110.54 ± 3.1268972.20 ± 748.00

29.43 ± 0.8417168.00 ± 410.00

61.35 ± 1.6560.30 ± 2.7658.99 ± 5.4354.16 ± 7.85

0.64 ± 0.012.61 ± 0.03

19.51 ± 0.4067.45 ± 0.4925.35 ± 1.31

107.52 ± 3.0265595.00 ± 672.00

28.44 ± 1.12

54.48 ± 2.1259.03 ± 2.9483.11 ± 3.5178.40 ± 1.1078.97 ± 1.1054.03 ± 2.1559.81 ± 4.7583.97 ± 4.0779.53 ± 1.0383.51 ± 1.0578.70 ± 7.3655.43 ± 1.6859.86 ± 2.7163.95 ± 2.6951.37 ± 1.6560.42 ± 4.3162.44 ± 3.1480.00 ± 6.4060.14 ± 0.89

104.93 ± 6.6446.72 ± 1.9767.97 ± 0.88

20.0865.7353.1630.06

117.1072051.60

32.9819712.50

60.1056.8060.1056.800.602.34

20.0865.7327.82

116.4871118.00

32.35

54.9958.1982.0782.0782.0754.9958.1982.0782.0782.0770.4052.8558.0370.8752.8558.0370.8770.4070.87

121.9046.0870.87

10.04 - 30.1255.73 - 75.7342.53 - 74.4220.06 - 40.06

105.39 - 128.8157641.28 - 86461.92

20.98 - 44.9815770.00 - 23655.00

50.10 -70.1046.80 - 66.8050.10 - 70.1046.80 - 66.80

0.36 - 0.841.40 - 3.28

10.04 - 30.1255.73 - 75.7317.82 - 37.82

104.83 - 128.13-56894.40 - 85341.60

20.35 - 44.35

44.99 - 64.9948.19 - 68.1972.07 - 92.0765.66 - 98.4865.66 - 98.4844.99 - 64.9948.19 - 68.1972.07 - 92.0765.66 - 98.4865.66 - 98.4860.40 - 80.4042.85 - 62.8548.03 - 68.0360.87 - 80.8742.85 - 62.8548.03 - 68.0360.87 - 80.8741.60 -99.2056.70 - 85.0497.52 - 146.2836.08 - 56.0856.70 - 85.04

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

A3-1

TABLE A-4. In-House "Blank" Samples

Concentration (pCi/L)a

Lab Code Sample Date Analysisb Laboratory results (4.66a) Acceptance

Type LLD Activityc Criteria (4.66 c)

W-120106 water 12/1/2006 Gr. Alpha 0.11 0.066 ± 0.072 1

W-120106 water 12/1/2006 Gr. Beta 0,30 0.093 ± 0.16 3.2

SPAP-9477 Air Filter 12/29/2006 Gr. Beta 1.13 -0.37 ± 0.66 3.2SPAP-9479 Air Filter 12/29/2006 Cs-137 0.87 100.SPW-9481 water 12/29/2006 H-3 146.2 63.2 ± 80.1 200

SPW-9483 water 12/29/2006 Tc-99 0.95 -1.20 ± 0.56 10SPW-9489 water 12/29/2006 Cs-1 34 2.30 10SPMI-9491 Milk 12/29/2006 Cs-134 3.10 10SPMI-9491 Milk 12/29/2006 Cs-1 37 2.90 10

SPMI-9491 Milk 12/29/2006 1-131(G) 8.00 20SPF-9493 Fish 12/29/2006 Cs-134 7.6 100

SPF-9493 Fish 12/29/2006 Cs-137 7.9 100

W-30707 water 3/7/2007 Gr. Alpha 0.04 0.00 ± 0.03 1W-30707 water 3/7/2007 Gr. Beta 0.08 0.01 ± 0.05 3.2

SPAP-1567 Air Filter 3/23/2007 Cs-134 0.79 100SPW-1567 Air Filter 3/23/2007 Cs-137 1.01 100SPW-1568 water 3/23/2007 H-3 176.10 -26.16 ± 91.62 200

SPW-1596 water 4/5/2007 Cs-134 3.28 10SPW-1 596 water 4/5/2007 Cs-1 37 3.45 10SPW-1596 water 4/5/2007 1-131 0.27 0.02 ± 0.18 0.5SPW-1596 water. 4/5/2007 1-131(G) 2.91 20

SPMI-1598 Milk 4/5/2007 Cs-134 3.30 10SPMI-1598 Milk 4/5/2007 Cs-137 5.08 10SPMI-1598 Milk 4/5/2007 1-131 0.26 -0.10 ± 0.17 0.5

SPMI-1598 Milk 4/5/2007 1-131(G) 4.10 20SPCH-2839 Charcoal Canister 5/17/2007 1-131(G) 2.24 9.6SPW-2848 water 5/17/2007 Cs-134 3.14 10SPW-2848 water 5/17/2007 Cs-137 1.37 10SPW-2848 water 5/17/2007 1-131 (G) 5.34 20

SPMI-2850 Milk 5/17/2007 Cs-134 3.32 10SPMI-2850 Milk 5/17/2007 Cs-1 37 2.60 10SPMI-2850 Milk 5/17/2007 1-131(G) 4.77 20SPW-2848 water 5/18/2007 1-131 0.34 -0.06 ± 0.19 0.5SPW-2848 water 5/18/2007 Sr-89 0.81 -0.02 ± 0.65 5SPW-2848 water 5/18/2007 Sr-90 0.53 0.01 ± 0.25 1

SPMI-2850 Milk 5/18/2007 1-131 0.45 0.20 ± 0.26 0.5SPMI-2850 Milk 5/18/2007 Sr-89 0.96 -0.73 ± 1.02 5SPMI-2850 d Milk 5/18/2007 Sr-90 0.58 0.96 ± 0.38 1

A4-1

TABLE A-4. In-House "Blank" Samples

Concentration (pCi/L)e

Lab Code Sample Date Analysisb Laboratory results (4.66a) Acceptance

Type LLD Activityc Criteria (4.66 a)

SPAP-2914 Air Filter 5/22/2007 Gr. Beta 0.004 -0.002 + 0.002 3.2SPAP-2916 Air Filter 5/22/2007 Cs-1 34 2.84 100SPAP-2916 Air Filter 5/2212007 Cs-137 2.24 100SPF-2923 Fish 5/22/2007 Cs-134 8.71 100SPF-2923 Fish 5/22/2007 Cs-137 8.35 100SPW-3224 water 5/24/2007 Ni-63 1.61 -0.30 ± 0.84 20W-60507 water 6/5/2007 Gr. Alpha 0.04 0.00 ± 0.03 1W-60507 water 6/5/2007 Gr. Beta 0.08 0.00 ± 0.05 3.2

SPW-4328 water 7/18/2007 Tc-99 6.41 -3.12 ± 3.84 10SPW-5477 water 8/17/2007 Ni-63 0.00 4.38 ± 1.01 20W-92107 water 9/21/2007 Gr. Alpha 0.04 0.01 ± 0.03 1W-92107 water 9/21/2007 Gr. Beta 0.08 -0.03 ± 0.05 3.2

a Liquid sample results are reported in pCi/Liter, air filters( pCi/filter), charcoal (pCi/charcoal canister), and solid samples (pCi/kg).

b 1-131(G); iodine-131 as analyzed by gamma spectroscopy.

c Activity reported is a net activity result, For gamma spectroscopic analysis, activity detected below the LLD value is not reported.d Low levels of Sr-90 are still detected in the environment. A concentration of (1-5 pCi/L) in milk is not unusual.

A4-2

TABLE A-5. In-House "Duplicate" Samples


Averaged

Lab Code Date Analysis First Result Second Result Result Acceptance

MI-6760, 6761G-6797, 6798G-6797, 6798G-6797, 6798 b

AP-7531, 7532

AP-7552, 7553AP-7573, 7574SO-7103, 7104SO-7103, 7104DW-60759, 60760

MI-7037, 7038VE-7058, 7059VE-7058, 7059VE-7058, 7059SS-7079, 7080

SS-7079, 7080SS-7079, 7080MI-7208, 7209DW-60809, 60810DW-60797, 60798DW-60797, 60798CF-7450, 7451LW-7945, 7946

F-7971, 7972SWU-8194, 8195BS-8017, 8018BS-8017, 8018TD-8173, 8174LW-8215, 8216F-8345, 8346BS-8366, 8367MI-8083, 8084WW-8259, 8260VE-8149, 8150

VE-8149, 8150

DW-60877, 60878DW-60990, 60991

MI-8484, 8485

DW-60925, 60926SO-8619, 8620

SO-8619, 8620

SO-8619, 8620

SO-8619, 8620

10/2/200610/2/200610/2/200610/2/200610/3/2006

10/3/200610/3/2006

10/4/200610/4/200610/5/200610/10/200610/10/200610/10/200610/10/200610/10/200610/10/200610/10/200610/11/200610/16/200610/17/200610/17/200610/18/2006

10/26/2006

10/29/2006

10/31/2006

11/1/2006

11/1/2006

11/1/2006

11/1/2006

11/2/2006

11/2/2006

11/6/2006

11/7/2006

11/8/2006

11/8/2006

11/14/2006

11/20/2006

11/22/2006

11/22/2006

11/27/2006

11/27/2006

11/27/2006

11/27/2006

K-40Be-7Gr. BetaK-40Be-7Be-7Be-7Cs-1 37K-40Gr. AlphaK-40Gr. AlphaGr. BetaK-40Cs-137Gr. BetaK-40K-40Gr. AlphaGr. AlphaGr. BetaK-40Gr. BetaK-40Gr. BetaGr. BetaK-40H-3Gr. BetaK-40K-40K-40H-3Be-7K-40Gr. AlphaGr. AlphaK-40Gr. AlphaCs-1 37Gr. AlphaGr. BetaK-40

1413.10 ± 113.204.70 ± 0.316.89 ± 0.265.39 ± 0.350.07 ± 0.010.08 ± 0.020.08 ± 0.020.25 ± 0.05

12.95 ± 1.124.93 ± 0.97

1326.10 ± 115.200.18 ± 0.119.21 ± 0.34

10.90 ± 0.650.04 ± 0.01

12.23 ± 2.467.23 ± 0.36

1295.20 ± 116.901.44 ± 1.060.84 ± 0.700.86 ± 0.56

20.40 ± 0.841.30 ± 0.373.63 ± 0.541.84 ± 0.28

10.54 ± 1.7210.00 ± 0.53

580.00 ± 110.002.23 ± 0.612.84 ± 0.42

13.69 ± 0.661295.00 ± 121.20337.00 ± 95.00

1.26 ± 0.244.17 ± 0.47

48.03 ± 5.326.70 ± 2.03

1405.80 ± 87.063.87 ± 1.130.74 ± 0.08

16.54 ± 5.6524.99 ± 3.8812.21 ± 1.11

1187.30 ± 155.204.56 ± 0.417.04 ± 0.244.36 ± 0.470.08 ± 0.010.08 ± 0.010.08 ± 0.010.27 ± 0.06

12.22 ± 1.075.04 ± 1.03

1251.40 ± 115.700.32 ± 0.148.83 ± 0.36

10.42 ± 0.800.04 ± 0.02

11.76 ± 2.237.37 ± 0.40

1386.90 ± 119.101.65 ± 1.191.03 ± 0.671.33 ± 0.60

19.54 ± 0.991.44 ± 0.363.33 ± 0.431.43 ± 0.28

10.17 ± 1.739.60 ± 0.69

599.00 ± 110.001.64 ± 0.372.89 ± 0.40

13.61 ± 0.781374.80 ± 162.80295.00 ± 93.00

1.25 ± 0.224.49 ± 0.45

47.26 ± 6.773.41 ± 1.34

1390.70 ± 103.603.04 ± 0.990.69 ± 0.06

12.24 ± 4.9028.66 ± 3.9512.92 ± 0.83

1300.20 ± 96.054.63 ± 0.266.97 ± 0.184.88 ± 0.290.08 ± 0.010.08 ± 0.010.08 ± 0.010.26 ± 0.04

12.58 ± 0.774.99 ± 0.71

1288.75 ± 81.640.25 ± 0.099.02 ± 0.25

10.66 ± 0.520.04 ± 0.01

11.99 ± 1.667.30 ± 0.27

1341.05 ± 83.441.54 + 0.800.94 ± 0.481.10 ±+0.41

19.97 ± 0.651.37 ± 0.263.48 ± 0.341.64 ± 0.20

10.36 ± 1.229.80 ± 0.44

589.50 + 77.781.93 ± 0.352.86 ± 0.29

13.65 ± 0.511334.90 ± 101.48

316.00 + 66.471.26 ± 0.164.33 ± 0.33

47.65 ± 4.315.06 ± 1.22

1398.25 ± 67.663.46 ± 0.750.71 ± 0.05

14.39 ± 3.7426.82 + 2.7712.57 ± 0.69

PassPassPassFail


PassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPass

0

A5-1



AveragedLab Code Date Analysis First Result Second Result Result Acceptance

DW-60902, 60903SWT-8641, 8642DW-60937, 60938S-3437,3438S-3437,3438S-3437, 3438DW-8929, 8930SWT-9436, 9437

E-20, 21E-20, 21CF-41, 42CF-41, 42CF-41, 42P-9516, 9517LW-9579, 9580DW-70085, 70086DW-70037, 70038. DW-70054, 70055DW-70122, 70123DW-70122, 70123DW-70098, 70099DW-70110, 70111SWU-676,677DW-70148, 70149SW-600, 601SW-601, 602DW-1138,1139MI-721, 722SW-847, 848SW-847, 848DW-70175, 70176DW-70187, 70188SWU-1162,1163DW-70205, 70206PW-1117, 1118PW-1117, 1118W-2122,2123W-2122,2123W-2085,2086W-2085,2086DW-70232, 70233

11/28/200611/29/200611/30/200612/6/200612/6/200612/6/200612/8/200612/26/2006

1/2/20071/2/20071/2/20071/2/20071/2/20071/3/20071/4/20071/9/20071/11/20071/18/20071/18/20071/18/20071/25/20071/25/20071/30/20071/30/20072/1/20072/1/20072/9/20072/13/20072/13/20072/13/20072/14/20072/14/20072/27/20072/28/20073/1/20073/1/20073/5/20073/5/20073/6/20073/6/20073/8/2007

Gr. AlphaGr. BetaGr. AlphaGr. AlphaGr. BetaK-401-131Gr. Beta

Gr. BetaK-40Gr. BetaK-40Sr-90H-3Gr. BetaGr. AlphaGr. AlphaGr. AlphaGr. AlphaGr. BetaGr. AlphaGr. AlphaGr. BetaGr. AlphaK-40Gr. BetaH-3K-40Gr. AlphaGr. BetaGr. AlphaGr. AlphaGr. BetaGr. AlphaGr. AlphaGr. BetaGr. AlphaGr. BetaGr. AlphaGr. BetaGr. Alpha

5.06 ± 1.102.83 ± 0.472.65 ± 0.921.77 ± 0.903.98 ± 1.102.83 ± 0.210.58 ± 0.272.39 ± 0.64

3.70 ± 1.052.89 ± 0.45

1.59 ± 0.88

2.33 ± 0.90

3.21 ± 1.03

2.98 ± 0.220.42 ± 0.26

2.25 ± 0.60

4.38 ± 0.762.86 ± 0.332.12 ± 0.642.05 ± 0.643.60 ± 0.762.91 ± 0.150.50 ± 0.192.32 ± 0.44

1.76 ± 0.07

1.49 ± 0.2418.02 ± 0.4111.68 ± 1.120.04 ± 0.01

270.78 ± 91.740.91 ± 0.317.95 ± 1.20

55.47 ± 3.992.68 ± 0.884.30 ± 1.144.22 ± 0.703.27 ± 0.902.19 ± 0.921.77 ± 0.394.65 ± 1.371.24 ± 0.120.89 ± 0.37

2707.00 ± 161.001330.40 ± 117.60

3.82 ± 1.677.33 ± 1.37

11.72 ± 1.686.79 ± 1.183.63 ± 0.690.88 ± 0.803.79 ± 1.917.12 ± 1.406.10 ± 4.16

10.65 ± 2.152.51 ± 2.29

11.02 ± 1.854.75 ± 1.28

1.70 ± 0.06

1.57 ± 0.27

18.81 ± 0.42

12.67 ± 0.97

0.03 ± 0.01

301.18 ± 92.99

0.93 ±+0.30

7.92 ± 1.42

52.87 ± 4.02

1.88 ± 0.78

6.25 ± 1.16

5.33 ± 0.75

1.97 ± 0.92

1.69 ± 0.79

2.11 ±0.39

5.20 ± 1.81

1.20 ± 0.12

1.02 ± 0.25

2700.00 ± 161.00

1316.40 ± 116.50

2.61 ± 1.24

5.89 ± 0.90

8.84 ± 1.32

6.47 ± 1.08

2.61 ± 0.44

1.31 ± 0.79

3.62 ± 2.09

7.20 ± 1.39

3.80 ± 4.30

13.11 ± 2.42

1.10 ± 2.78

9.50 ± 2.01

5.98 ± 1.31

1.73 ± 0.05

1.53 ± 0.1818.42 ± 0.2912.18 ± 0.740.03 ± 0.01

285.98 ± 65.310.92 ± 0.227.94 ± 0.93

54.17 ± 2.832.28 ± 0.595.28 ± 0.814.78 ± 0.512.62 ± 0.641.94 ± 0.611.94 ± 0.284.93 ± 1.141.22 ± 0.080.96 ± 0.22

2703.50 ± 113.841323.40 ± 82.77

3.22 ± 1.046.61 ± 0.82

10.28 ± 1.076.63 ± 0.803.12 ± 0.411.10 ± 0.563.71 ± 1.427.16 ± 0.994.95 ± 2.99

11.88 ± 1.621.81 ± 1.80

10.26 ± 1.375.37 ± 0.92

PassPassPassPassPassPass

PassPass

PassPassPassPassPassPass

PassPassPass

PassPassPassPassPassPassPassPassPass

PassPassPassPassPass

Pass

PassPassPassPass


A5-2



Averaged

.Lab Code Date Analysis First Result Second Result Result Acceptance

WW-1477,1478WW-1498,1499W-2140, 2141W-2140,2141DW-1626,1627MI-1647,1648DW-70248, 70249W-2150,2151W-2150, 2151LW-1941, 1942

MI-1824,1825MI-1824, 1825AP-2170, 2171WW-1850, 1851AP-2198, 2199AP-2370, 2371DW-70300, 70301DW-70300, 70301DW-70335, 70336DW-70335, 70336SW-1898,1899SW-1898,1899SW-1898,1899DW-70346, 70347DW-70346, 70347DW-70376, 70377DW-70376, 70377DW-70311, 70312WW-2349,2350WW-2461, 2462LW-2437, 2438LW-2917, 2918SO-2583,2584SO-2583, 2584SO-2583, 2584SO-2583, 2584SO-2583, 2584S-2620,2621MI-2610,2611

3/12/2007

3/15/2007

3/19/2007

3/19/2007

3/21/2007

3/21/2007

3/21/2007

3/26/2007

3/26/2007

3/31/2007

4/2/2007

4/2/2007

4/2/2007

4/3/2007

4/3/2007

4/3/2007

4/4/2007

4/4/2007

4/5/2007

4/5/2007

4/10/2007

4/10/2007

4/10/2007

4/11/2007

4/11/2007

4/11/2007

4/11/2007

4/12/2007

4/17/2007

4/25/2007

4/26/2007

4/30/2007

5/1/2007

5/1/2007

5/1/2007

5/1/2007

5/1/2007

5/2/2007

5/3/2007

Gr. BetaGr. BetaGr. AlphaGr. BetaH-3K-40Gr. AlphaGr. AlphaGr. BetaGr. Beta

K-40Sr-90Be-7H-3Be-7Be-7Gr. AlphaGr. BetaGr. AlphaGr. BetaGr. AlphaGr. BetaH-3Gr. AlphaGr. BetaGr. AlphaGr. BetaGr. AlphaGr. AlphaH-3Gr. BetaGr. BetaBe-7Cs-137K-40Gr. AlphaGr. BetaH-3K-40

6.41 ± 1.480.83 ± 0.312.31 ± 1.574.26 ± 1.00

4973.00 ± 209.001448.80 ± 120.20

11.10 _ 1.183.56 + 2.209.26 + 1.001.35 - 0.43

1316.10 _ 110.601.20 ± 0.500.08 ± 0.01

-5.83 + 102.290.08 ± 0.010.07 ± 0.013.78 ± 0.892.93 ± 0.61

24.37 ± 2.8920.26 ± 1.37

3.86 ± 1.406.31 ± 1.36

241.99 ± 93.351.83 ± 1.084.62 ± 0.721.81 ± 0.801.84 ± 0.62

10.82 ± 1.500.71 ± 0.56

190.30 ± 100.312.71 ± 0.501.97 ± 0.79

544.99 ± 247.70119.22 ± 36.61

17825.00 ± 749.9011.49 ± 3.9631.02 ± 3.74

277.90 ± 126.701549.20 ± 184.20

4.10 ± 1.250.97 ± 0.331.33 ± 1.645.58 ± 1.02

5190.00 ± 213.001439.30 ± 126.00

9.90 ± 1.163.30 ± 1.81

10.17 ± 1.901.36 ± 0.41

1229.80 ± 110.501.10 ± 0.360.08 ± 0.01

150.05 ± 80.140.08 ± 0.010.07 ± 0.013.66 ± 0.962.91 ± 0.64

22.72 ± 2.9118.33 ± 1.344.78 ± 1.517.03 ± 1.42

318.10 ± 96.482.54 ± 1.044.01 ± 0.711.66 ± 0.862.24 ± 0.61

13.20 ± 1.560.62 ± 0.52

115.95 ± 97.652.15 ± 0.452.78 ± 0.81

601.13 ± 192.2087.46 ± 23.97

17672.00 ± 724.308.04 ± 3.88

26.10 ± 3.40304.40 ± 101.00

1388.80 ± 128.20

5.26 ± 0.970.90 ± 0.221.82 ± 1.144.92 ± 0.71

5081.50 ± 149.211444.05 ± 87.07

10.50 ±20.833.43 ± 1.429.72 ± 1.071.36 ± 0.30

1272.95 ± 78.171.15 ± 0.310.08 ± 0.01

72.11 ± 64.970.08 ± 0.010.07 ± 0.013.72 ± 0.652.92 ± 0.44

23.55 ± 2.0519.30 ± 0.964.32 ± 1.036.67 ± 0.98

280.04 ± 67.122.19 ± 0.754.32 ± 0.511.74 ± 0.592.04 ± 0.44

12.01 ± 1.080.66 ± 0.38

153.13 ± 70.002.43 ± 0.34

2.38 ± 0.57573.06 ± 156.76103.34 ± 21.88

17748.50 ± 521.299.77 ± 2.77

28.56 ± 2.53291.15 ± 81.02

1469.00 ± 112.21

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

A5-3



Averaged


W-4469, 4470SS-2697, 2698SS-2697, 2698MI-2790, 2791W-4505, 4506DW-3219, 3220SO-3416, 3417SO-3416, 3417SO-3416, 3417F-3561, 3562SL-3311, 3312SL-3311, 3312SL-3992, 3993SL-3992, 3993SL-3992, 3993W-5087, 5088SW-3710, 3711W-4062, 4063W-4062, 4063AP-4448, 4449SG-3735, 3736SG-3735, 3736SG-3735, 3736SG-3735, 3736LW-4175, 4176

SG-5422, 5423SG-5422, 5423AP-4656, 4657AP-4763, 4764WW-4298, 4299DW-70612, 70613WW-4918, 4919MI-4742, 4743VE-4939, 4940VE-4939, 4940VE-4939, 4940SW-5218, 5219WW-5310, 5311SW-5393, 5394SW-5393, 5394W-5468, 5469

5/7/20075/8/20075/8/20075/14/20075/14/20075/26/20075/31/20075/31/20075/31/20075/31/20076/4/20076/4/20076/4/20076/4/20076/4/20076/11/20076/14/20076/28/20076/28/20076/28/20076/30/20076/30/20076/30/20076/30/20076/30/2007

7/2/20077/2/20077/3/20077/3/20077/12/20077/23/20077/25/20077/26/20078/1/20078/1/20078/1/20078/7/20078/9/20078/14/20078/14/20078/15/2007

Gr. BetaCs-1 37K-40K-40Gr. Beta1-131Cs-137Gr. BetaK-40K-40Be-7K-40Be-7Gr. BetaK-40Gr. BetaH-3Gr. AlphaGr. BetaBe-7Be-7Cs-1 37Gr. BetaK-40Gr. Beta

Gr. AlphaGr. BetaBe-7Be-7Gr. BetaGr. AlphaH-3K-40Be-7Gr. BetaK-401-131H-3Gr. BetaH-3H-3

10.60 ± 1.900.06 ± 0.028.03 ± 0.57

1694.30 ± 126.20

3.30 ± 1.70

0.62 ± 0.32

0.15 ± 0.03

22.88 ± 2.33

12.26 ± 0.80

3.06 ± 0.39

0.61 ± 0.29

5.78 ± 0.67

0.75 ± 0.19

13.61 ± 1.12

2.43 ± 0.36

8.70 ± 1.90

9571.51 ± 287.22

0.76 ± 0.63

0.97 ± 0.53

0.10 ± 0.02

0.84 ± 0.12

0.07 ± 0.01

29.51 ± 2.22

9.41 ± 0.31

2.18 ± 0.60

10.31 ± 1.98

18.59 ± 1.46

0.09 ± 0.02

0.11 ± 0.02

1.74 ± 0.74

4.54 ± 1.11

240.43 ± 111.12

1820.30 ± 134.10

0.39 ± 0.21

5.50 ± 0.14

3.36 ± 0.45

1.31 ± 0.24

644.00 ± 106.00

2.32 ± 1.31

190.06 ± 86.80

262.58 ± 108.43

11.10 ± 1.800.05 ± 0.037.36 ± 0.68

1627.60 ± 128.80

3.90 ± 1.50

0.69 ± 0.31

0.15 ± 0.03

22.46 ± 2.37

12.36 ± 0.65

3.37 ± 0.45

0.55 ± 0.25

4.87 ± 0.25

0.74 ± 0.32

14.06 ± 1.08

2.29 ± 0.40

7.70 ± 1.90

9879.21 ± 291.42

0.32 ± 0.66

0.58 ± 0.57

0.09 ± 0.02

0.82 ± 0.18

0.07 ± 0.01

30.81 ± 2.22

8.90 ± 0.48

1.93 ± 0.68

10.57 ± 1.99

20.97 ± 1.49

0.10 ± 0.02

0.10 ± 0.02

2.22 ± 0.804.19 ± 0.97

216.68 ± 110.27

1802.90 ± 199.50

0.45 ± 0.20

5.76 ± 0.13

3.36 ± 0.21

1.42 ± 0.24

831.00 ± 113.00

1.71 ± 1.27

69.05 ± 80.88

346.53 ± 111.42

10.85 ± 1.31

0.05 ± 0.02

7.70 ± 0.44

1660.95 ± 90.16

3.60 ± 1.13

0.66 ± 0.22

0.15 ± 0.02

22.67 ± 1.66

12.31 ± 0.52

3.21 ± 0.300.58 ± 0.19

5.33 ± 0.36

0.75 ± 0.19

13.84 ± 0.78

2.36 ± 0.27

8.20 ± 1.34

9725.36 ± 204.59

0.54 ± 0.45

0.78 ± 0.39

0.10 ± 0.01

0.83 ± 0.11

0.07 ± 0.01

30.16 ± 1.57

9.16 ± 0.29

2.06 ± 0.45

10.44 ± 1.40

19.78 ± 1.04

0.10 ± 0.01

0.11 ± 0.01

1.98 ± 0.55

4.37 ± 0.74

228.56 ± 78.27

1811.60 ± 120.19

0.42 ± 0.15

5.63 ± 0.10

3.36 ± 0.25

1.37 ± 0.17

737.50 ± 77.47

2.02 ± 0.92

129.55 ± 59.32

304.55 ± 77.74


PassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPass

PassPassPassPassPassPassPassPassPassPassPassPassPassPassPassPass

A5-4


Concentration (pCi/L)aAveraged


ve-5553, 5554

WW-5643,5644

SWU-5799, 5800

DW-70752, 70753

VE-5917, 5918

VE-5917, 5918

DW-70718, 70719

DW-70718, 70719

SO-6156, 6157

8/22/20078/22/20078/28/20078/31/20079/4/20079/4/20079/12/20079/12/20079/14/2007

K-40

H-3

Gr. Beta

Gr. Alpha

Be-7

K-40

Gr. Alpha

Gr. Beta

H-3

1.89 ± 0.33259.00 ± 110.00

2.64 ± 1.1814.41 ± 1.480.94 ± 0.173.73 ± 0.37

23.04 ± 3.7116.13 ± 1.59

181.99 ± 90.67

1.89 ± 0.22266.00 ± 110.00

3.62 ± 1.0612.90 ± 1.500.83 ± 0.203.58 ± 0.36

23.22 ± 3.6117.36 ± 1.69

232.19 ± 92.95

1.89 ± 0.20262.50 ± 77.78

3.13 ± 0.7913.66 ± 1.050.89 ± 0.133.66 ± 0.26

23.13 ± 2.5916.75 ± 1.16

207.09 ± 64.92

PassPassPassPassPassPassPassPassPass

Note: Duplicate analyses are performed on every twentieth sample received in-house. Results are not listed for those

analyses with activities that measure below the LLD.a Results are reported in units of pCi/L, except for air filters (pCi/Filter), food products, vegetation, soil, sediment (pCi/g).

b 200 minute count time or longer, resulting in lower error.

A5-5

TABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP)a.

Concentration b

Known ControlLab Codec Date Analysis Laboratory result Activity Limits d Acceptance

STW-1110 01/01/07 Gr.Alpha

STW-1110 01/01/07 Gr. Beta

0.45 ± 0.080.90 ± 0.14

0.330.85

0.00 - 0.650.43-1.28

STW-1111 e

STW-1111STW-1111

STW-1111

STW-1111

STW-1111

STW-1111

STW-1111

STW-1111

STW-1111

STW-1111

STW-1111

STW-1111STW-1111

STW-1111

STW-1111

STSO-1112'

STSO-1112STSO-1112STSO-1 112STSO-1112STSO-1112

01/01/0701/01/0701/01/0701/01/07

01/01/07

01/01/0701/01/0701/01/07

01/01/0701/01/0701/01/07

01/01/07

01/01/0701/01/07

01/01/07

01/01/07

01/01/07

01101107

01/01/07

01/01/0701/01/0701/01/07

Am-241

Co-57

Cs-134

Cs-137

Fe-55

H-3

Mn-54

Ni-63

Ni-63

Pu-238

Pu-239/40

Sr-90

Tc-99

U-233/4

U-238

Zn-65

Am-241

Co-57

Co-60

Cs-134

Cs-I 37

Mn-54

2.80 ± 0.21151.60 ± 10.0079.20 ± 8.00

168.70 ± 12.10130.30 ± 19.90262.20 ± 9.10130.60 ± 11.50127.80 ± 3.60127.80 ± 3.60

2.03 ± 0.172.27 ± 0.179.60 ± 1.408.80 ± 1.502.44 ± 0.212.44 ± 0.21

123.70 ± 17.00

46.40 ± 9.00501.20 ± 2.90285.90 ± 2.10325.90 ± 7.40855.70 ± 4.60750.90 ± 4.70

0.27 ±0.040.57 ± 0.05

0.10 ± 0.033.51 ± 0.072.98 ± 0.104.02 ± 0.162,75 ± 0.123.94 ± 0.120.07 ± 0.010.08 ± 0.010.58 ± 0.180.09 ± 0.010.09 ± 0.012.70 ± 0.10

1.71143.7083.50

163.00129.30283.00123.80130.40130.40

2.252.228.87

88.002.492.48

114.80

34.80471.20274.70327.40799.70685.20

0.600.44

0.102.892.914.202.573.520.070.080.610.100.102.68

1.20 -2.22100.60 - 186.8058.50 - 108.60

114.10 - 211.9090.50 - 168.10

198.10 - 367.9086.70 - 160.9091.30 - 169.5091.30 - 169.50

1.58 -2.931.55 -2.896.21 -11.537.40 - 13.701.74 -3.241.74 -3.22

80.40 - 149.20

24.40 - 45.20329.80 -612.60192.30 - 357.10229.20 - 425.60559.80 - 1039.60479.60 - 890.80

0.00 - 1.200.22 - 0.66

0.07 -0.132.02 - 3.752.03 - 3.782.94 - 5.451.80 - 3.342.46 - 4.570.05 - 0.090.06 -0.110.43 - 0.790.07 -0.130.07 -0.131.88 -3.49

Pass

Pass

Fail

Pass

Pass

Pass

Pass

PassPass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Fail

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

.Pass

Pass

Pass

Pass

Pass

STAP-1113 01/01/07 Gr. AlphaSTAP-1113 01/01/07 Gr. Beta

STAP-1 114

STAP-1 114

STAP-1114

STAP-1 114

STAP-1114

STAP-1114

STAP-1 114

STAP-1 114

STAP-1 114

STAP-1 114

STAP-1 114

STAP-1114

01/01/07

01/01/07

01/01/07

01/01/0701/01/07

01/01/07

01/01/07

01/01/07

01/01/0701/01/0701/01/0701/01/07

Am-241

Co-57

Co-60

Cs-1 34

Cs-1 37

Mn-54

Pu-238

Pu-239/40

Sr-90

U-233/4

U-238

Zn-65

A6-1

STABLE A-6. Department of Energy's Mixed Analyte Performance Evaluation Program (MAPEP)a.

Concentration b

Known ControlLab Codec Date Analysis Laboratory result Activity Limits d Acceptance

STVE-1115STVE-1115STVE-1115STVE-1 115STVE-1115

01/01/0701/01/0701/01/0701/01/0701/01/07

Co-57Co-60Cs-134Cs-137Mn-54

8.90 ± 0.20

6.50 ± 0.20

6.90 ± 0.308.20 ± 0.30

10.10 ± 0.30

8.195.826.216.998.46

5.73 - 10.644.08 - 7.57

4.35 - 8.07

4.90 - 9.09

5.91 - 10.98

PassPassPassPass

Pass

O

Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the Department of Energy's

Mixed Analyte Performance Evaluation Program, Idaho Operations office, Idaho Falls, Idahob Results are reported in units of Bq/kg (soil), Bq/L (water) or Bq/total sample (filters, vegetation).

c Laboratory codes as follows: STW (water), STAP (air filter), STSO (soil), STVE (vegetation).

d MAPEP results are presented as the known values and expected laboratory precision (1 sigma, I determination)

and control limits as defined by the MAPEP.e Result of reanalysis, 2.08 ± 0.13 pCi/L.

f The test samples were recounted on lower background detectors. Result of the recounts: 41.4 + 6.3 Bq/kg.

A6-2



Lab Code b Date Analysis Laboratory ERA ControlResult c Result d Limits Acceptance

STAP-1116 03/19/07 Gr. AlphaSTAP-1116 03/19/07 Gr. Beta

34.64 ± 2.5693.41 ± 3.20

25.879.5

12.4 -3948.8 -116

STAP-1l117

STAP-1117

STAP-1117

STSO-1117 e

STSO-1117

STSO-1117'

STAP-1117

STAP-1l117

STAP-1l117

STAP-1 117

STAP-1 117

STAP-1117

STAP-1117

STSO-1 118

STSO-1118

STSO-1 118

STSO-1118

STSO-11 18

STSO-1 118

STSO-1 118STSO-1118'

STSO-1 118

STSO-11 18STSO-1 118

STSO-1118

STSO-1118

STSO-1118

STSO-1118

STSO-1118

STSO-1118

STSO-1118

STSO-1118'

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

03/19/07

Am-241

Co-60

Cs-134

Cs-137

Fe-55

Mn-54

Pu-238

Pu-239/40

Sr-90

U-233/4

U-238

Uranium

Zn-65

Ac-228

Am-241

Bi-212

Co-60

Cs-1 34

Cs-137

K-40

Mn-54

Pb-212

Pb-214

Pu-238

Pu-239/40

Sr-90

Th-234

U-233/4

U-238

Uranium

Uranium

Zn-65

56.04 ± 3.901610.00 ± 8.401340.40 ± 48.84

345.30 ± 8.20< 134.0< 5.0

43.32 ± 2.2835.23 ± 2.24

156.10 ± 6.6042.22 ± 1.8442.00 ± 1.8485.79 ± 3.60

363.80 ± 11.90

3097.77 ± 94.961000.70 ± 156.102467.87 ± 114.337847.40 ± 86.607910.60 ± 356.884635.00 ± 99.10

12201.60 ± 423.20< 34.0

2046.80 ± 127.204142.80 ± 110.401099.20 ± 73.101586.10 ± 82.006163.30 ± 791.604329.40 ± 569.103236.70 ± 106.003425.20 ± 134.006787.80 ± 240.006787.80 ± 240.00

0.00 ± 0.00

57.51300.01120.0255.0

0.00.037.431.6156.047.847.497.3245.0

2790.0927.02500.07330.07560.04300.011100.0

0.01730.03330.0857.01360.07500.03590.03620.03590.07380.07380.0

0.0

33.1 -801010.0 -1620732.0 -1380

192.0 -336

25.7-4922.9 -4166.6 -246

30.1 -7130.2 -68

49.5 -155

208.0-412

1790.0 - 3930

548.0 -1200

658.0 -3730

5340.0 -9820

4850.0 - 9070

3290.0 -5580

8050.0 - 15000

1120.0 -24301980.0 -4980490.0 -1200

928.0 -18102610.0 -12400

2190.0 -4560

2280.0 - 4520

2190.0 -45604210.0 -99304210.0 - 9930

0.0 -0

PassPass

PassPassPassFail

PassPassPass

PassPass

PassPassPassPass

PassPassPassPassPassPassPassPass

PassPassPass

Pass

PassPass

PassPassPass

Pass

Pass

A7-1



Lab Code b Date Analysis Laboratory ERA ControlResult c Result d Limits Acceptance

STVE-1 119STVE-1119STVE-1 119STVE-1 119STVE-1119STVE-1 119STVE-1119'STVE-1119STVE-1 119STVE-1119STVE-1119STVE-1119STVE-1 119STVE-1 119

STW-1 120STW-1120STW-1120STW-1 120STW-1120STW-1120'STW-1 120STW-1120STW-1 120STW-1120STW-1 120STW-1120

03/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/07

03/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/0703/19/07

Am-241Cm-244Co-60Cs-134Cs-1 37K-40Mn-54Pu-238Pu-239/40Sr-90U-233/4U-238UraniumZn-65

Am-241Co-60Cs-134Cs-1 37Fe-55Mn-54Pu-238Pu-239/40Sr-90U-233/4U-238Uranium

3249.60 ± 150.301860.70 ± 91.502827.90 ± 62.40

654.80 ± 48.403307.30 ± 58.80

40814.20 ± 618.80< 27.6

2762.00 ± 251.102156.60 ± 83.408999.70 ± 580.902821.90 ± 73.502896.10 ± 50.705718.00 ± 124.15

474.30 ± 45.70

133.50 ± 10.60541.40 ± 9.00

1623.80 ± 66.101839.10 ± 17.90829.50 ± 226.80

<8.1123.30 ± 4.3095.10 ± 3.80

949.40 ± 16.70164.20 ± 6.58169.20 ± 8.22339.60 ± 10.66

2009.00 ± 36.40

3550.01840.02600.0579.0

2920.037900.0

0.02430.01900.08890.02940.02910.05980.0366.0

179.0536.01750.01850.0671.0

0.0116.090.9989.0192.0190.0391.0

2020.0 -4890

905.0 -28701760.0 -3720

308.0 -822

2150.0 - 4060

27200.0 - 53600

1250.0 -36001180.0 -2600

4900.0 -11800

1930.0 -39202090.0 - 3610

4110.0 -7770267.0 -500

123.0 -243467.0 -631

1290.0 -20201570.0 -2220392.0 -896

87.6- 144

70.3 -113630.0 -1320

145.0 -247145.0 -236282.0 -521

PassPass



PassPass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

Pass

0

STW-1120 03/19/07 Zn-65 1910.0 1600.0 -2410

a Results obtained by Environmental, Inc., Midwest Laboratory as a participant in the crosscheck program for proficiency

testing administered by Environmental Resources Associates, serving as a replacement for studies conductedpreviously by the Environmental Measurements Laboratory Quality Assessment Program (EML).

b Laboratory codes as follows: STW (water), STAP (air filter), STSO (soil), STVE (vegetation).

c Unless otherwise indicated, the laboratory result is given as the mean ± standard deviation for three determinations.d Results are presented as the known values, expected laboratory precision (1 sigma, 1 determination) and control limits

as provided by ERA.

eA high bias (- 20%) was observed in gamma results for air filters. A composite filter geometry was used in the

calculations vs. a single filter geometry. Result of recalculation. Cs-1 37, 305.8 ± 6.0 pCi/filter.f Included in the testing series as a "false positive". No activity expected.

A7-2

Appendix CData AssessmentSeptember/October 2007Monitoring Event

RADIOCHEMICAL DATA REVIEW

The purpose of the radiochemical data review is to determine the range ofbackground concentrations of tritium in groundwater at Davis-Besse andto identify the concentration above which would signify detections abovebackground in the data set. Since tritium was the only radiologicalcompound detected in water samples above the MDC, the analysis is onlyperformed for tritium.

Low level concentrations reported by the laboratory may reflect 1.)uncertainty in the sample and laboratory analysis; 2.) tritium from historicatmospheric bomb testing; 3.) tritium from cosmic ray interactions in theearth's atmosphere; or 4.) localized tritium washout from continuous andbatch gaseous releases. In order to assess these local backgroundcondition levels, a statistical approach was used following industryguidance (EPRI, 2005) to evaluate the significance of the low leveldetections.

Local background concentrations can also be defined by comparingreported tritium values from wells upstream of potential radiologicalsource(s) of release. For example, wells MW-100 is located hydraulicallyup-gradient of potential source(s) of liquid tritium released from thePower Block. The reported concentrations of tritium were: <193, <193 and<149 for MW-100-A, -B and -C, respectively. The mean value is <178pCi/L. This low level concentration limit provides a reference at which toevaluate reported results from samples collected down-gradient andcross-gradient of the Power Block. It is noted that MW-100A, -B and -Cwere sampled once; therefore, the background reference may change ifmore up-gradient wells were available.

Additional evaluation of background can be performed by evaluating thereported concentrations in groundwater against concentrations in surfacewater from Lake Erie.

A statistical approach was also used to define local backgroundconditions. The results reported by Midwest Laboratory were comparedagainst 2-sigma (o) total propagated uncertainty (TPU) of the analysis,with a 95% confidence level. The 2-o TPU value combines countinguncertainty and any other factors that contribute to the overall uncertaintyincluding uncertainties in the sample mass, chemical yield anddetermination of calibration factors.


The 2-a TPU was estimated by calculating a raw standard deviation usingthe field and laboratory duplicate data collected during both the June 2007and September/October 2007 event (Table 7). Both sets of data were usedto provide a sufficient number of comparisons (i.e., population statistics)that could not be achieved if only using the September /October 2007data. The field duplicates and laboratory duplicates from both eventswere used to measure the total uncertainty and evaluate the quality of theTPU estimate.

The raw 2-o standard deviation was calculated at 87.3 pCi/L. The raw 2-ostandard deviation includes the effects of stochastic variations, volumemeasurements, calibration errors, and chemical factors. A Student's tcorrection factor was calculated (1.9432) because the sample size is lessthan 30 sample pairs. The correction factor was applied to calculate theupper 95% limit of the TPU, which was thereby established to be 170pCi/L. Given the limited sample population, the 2-u TPU values arepreliminary and their robustness will increase with future monitoringevents as more duplicate sample pairs are included in the analysis. As thenumber of duplicate sample pairs increases, the correction factor willdecrease.

Statistical analysis and verification of the June and September/October2007 results for tritium are summarized in the following table:

Value Concentration (pCi/L) Comment

Up-gradient well 178 mean LLD from well MW- 10

Typical MDC 183 Reported result from well MW-31D

2-G TPU 170 Upper 95% confidence level

Statistical decision level Data reporting convention (EPRI, 2005);348sum of background well and 2 -G TPU

The TPU and the sub components of the TPU were evaluated forreasonableness and internal consistency. The data satisfy all qualityrequirement considerations. For the data presented here, individualmeasurements between 178 and 348 pCi/L represent statisticallyinsignificant activity at the 95% confidence level.

Individual measurement results above the decision level (i.e., 348 pCi/L)represent concentrations that are statistically greater than background andlikely warrant additional monitoring. Monitoring wells where the netconcentration was detected above the action level included MW-12D (738


pCi/L), MW-15D (442 pCi/L), MW-30S (494 pCi/L), MW-31S (3,149pCi/L), MW-35D (368 pCi/L), MW-102A LD (387 pCi/L), MW-102B (394pCi/L), MW-103A (495 pCi/L), MW-103B (362 pCi/L), and MW-105A(1,832 pCi/L), (Table 7).


QUALITY ASSURANCE - QUALITY CONTROL

1.0 INTRODUCTION

This section presents a quality assurance and quality control (QA/QC)review of the Davis-Besse September/October 2007 groundwatersampling event. This evaluation was conducted to assess and enhance thereliability and validity of the groundwater analytical data. The verificationprocess was conducted to identify the most common sampling andanalytical problems that could affect the quality of the results. In generalthe results met the data quality objectives.

2.0 QUALITY ASSURANCE

Quality assurance involves planned and systematic actions necessary toprovide confidence in the analytical results. The goal of the QA program isto have a program that is operating within acceptable criteria; therebyenhancing the representativeness and comparability of the results.Qualitative measures include items related to the field as well as thelaboratory activities.

2.1 SAMPLING PROGRAM

The procedures used to collect the groundwater samples were detailed ina FSP (ERM, 20 September 2007). Specifications, such as well locations,well construction, sampling intervals, sampling and analysis techniqueswere items among others that were described to evaluate therepresentativeness of the groundwater samples collected. Groundwatersamples were collected by personnel from the BETA Laboratory. Fieldnotes were reviewed to assess if the procedures were executed properly.The following information reviews items were included in the fieldsampling quality assurance program.

* Sampling documentation - The sample team maintained a fieldnotebook (bound weatherproof logbooks) that was filled out at


each location where a sample was collected. It contains the sample Vdesignation, collection time, description, and field instrumentcalibration log. The team also completed a Low-Flow GroundwaterSampling Form at each monitored location. The forms presentinformation regarding location, weather, time, well construction,sampling depth, sampling device, field parameters and samplecontainers. The completed Low-Flow Groundwater Samplingforms are included within Appendix C.

" Sample Identification - Well IDs were used to identify thegroundwater samples. The same codes were used to complete thechain-of-custodies (COCs). Duplicate samples were recorded asblind samples. Actual duplicate sample IDs were recorded on eachLow-Flow Groundwater Sampling Form. COC records are includedwithin Appendix C.

* Decontamination - Dedicated high density polyethylene (HDPE)tubing was used at each location. Wells were sampled using eithera peristaltic pump (30 wells, no decontamination required) or abladder pump (2 wells, pump decontaminated after each use). Anequipment blank sample was collected from the bladder pumpafter sampling at monitoring well MW-101C.

* Calibration and Preventive Maintenance of Field Instruments -Sampling team personnel calibrated the geochemical parameterprobe every day before starting the sampling. Calibration logs weremaintained in the notebook.

* Sampling locations - All locations were sampled as planned in theFSP.

" Gauging - A synoptic water level gauging round including all ofthe monitoring wells selected for the evaluation of tritium andgamma emitting radionuclides was performed on 24 September2007 prior to sampling.

* Sampling Depths - Sampling depths were reported on theindividual Low-Flow Groundwater Sampling Forms. Samplingdepths were consistent with sampling depths recommended in theField Sampling Plan.

" Field Duplicates - All duplicate samples were collected inaccordance with the FSP with the exception of sample duplicateDBD-04 that was taken at monitoring well MW-103B and not MW-

ERM/ DADE MOELLER 5 FIRSTENERGY - DAVIS-BESSE 0065992.2 18 MARCH 08

104B because of the unexpected low groundwater elevation at MW-104B. This change did not affect the data quality.

2.2 ANALYTICAL PROGRAM

Groundwater samples were analyzed by Midwest Laboratory for analysisof tritium by EPA Method 906.0 and gamma emitting radionuclides byEPA Method 901.1 as specified within the FSP. Midwest Laboratorycurrently performs radiological environmental monitoring for over 20nuclear power plants in 11 states. In addition, the laboratory is certified toperform analysis of drinking water for radionuclides in Illinois, Indiana,Wisconsin, and Kentucky. Midwest Laboratory maintains a QualityAssurance / Quality Control Program based on 10 CFR Part 50, AppendixB and Reg. Guide 4.15.

3.0 QUALITY CONTROL

The analytical data were assessed in terms of precision, accuracy,representativeness, comparability and completeness (PARCCs) to evaluatethe usability of the results generated. Quality control items wereevaluated through laboratory checks (e.g., matrix spikes, duplicatesamples), and sampling method reviews (equipment blanks, trip blanks).In addition, Midwest Laboratory has participated in interlaboratorycomparison (crosscheck) programs since the formulation of their qualitycontrol program in December 1971. Results of the interlaboratory programare presented at the end of this appendix.

The following information provides background on the types of QCsamples that were used to evaluate if the data quality objectives of thesampling program were met. Assessment of data quality based oncompliance with PARCCs criteria is presented in the following.

0 Precision - United States Environmental Protection Agency (EPA)guidance suggests that the Relative Percent Difference (RPD) offield duplicates should be less than 30 percent in water samples.The RPD is calculated as:

RPD -I Sample - Duplicate I

(Sample + Duplicate) / 2


Calculated RPD values for the tritium results were withinguidelines and are presented in the following table.

Field Duplicate RPD Calculations

Sample Duplicate Sample Duplicate RPDID ID Result Result

MW-12D DBD-01 738 769 4 %

MW-20S DBD-02 189 218 14 %

MW-31S DBD-03 3,149 3,012 4 %

MW-103B DBD-04 362 394 9%

0 Accuracy - Matrix spike/matrix spike duplicate (MS/MSD), andlaboratory control/ laboratory control duplicate sample aredocumented in the attached laboratory reports. These indicatorsare used to assess if the matrix may be biasing the reported resultshigh (generally based on greater than 130 percent recovery) or low(generally based on less than 70 percent recovery). RPDs aregenerally expected to be less than 30 percent between MS and MSDresults. As shown in the following table, all RPDs for tritium andcesium were within acceptable ranges.

Matrix Spike/Matrix Spike Duplicate RPD Calculations

Sample ID Compound MS/MSD Spike + Initial Sample RPDID Sample Activities Result

MW-30S Tritium MS1-17,185 16,321 5%MW-100A

MSD01-MW-30S Tritium MW-bOA 17,185 16,925 2 %

MW-100A

MW-30S Cs-137 65.6 68.6 4 %MW-100AMSD01-

MW-30S Cs-137 MW-bOA 65.6 70.2 7 %MW-100A

MS0O2-MW-100A Tritium MW- 27,990 26,895 4 %MW-30S

MW-100A Tritium MS0-27,990 26,895 4 %MW-30S

MW-bA Cs137 MS02-MW-100A Cs-137 98.4 109.1 10 %MW-30S

MSD02-MW-100A Cs-137 MW-30S 98.4 108.4 10 %MW-30S

No Cesium was detected in the actual samples. Values indicate actual spikeactivity.

* Representativeness and Comparability - The representativenessand comparability of analytical data was qualitatively evaluated by 0

ERM/DADE MOELLER 7 F1 RSTE N ERGY - DAV IS- BESSE 0065992.2 18 MARCH 08

comparing sample results from the same locations between theSeptember/October 2007 and the June and July/ August 2007monitoring events.

Groundwater Titrium Results Comparison - 1st, 2"d & 3rdSampling rounds

Monitoring June or lulv/August 2007 Sept/Oct 2007 RPDWell

MW-12S

MW-12D

MW-15S

MW-15D

MW-20S

MW-20DMW-30S

MW-30DMW-31SMW-31DMW-33SMW-33DMW-37S

NA: Not Applicable

H-3 Activity

8601,155375704279328

1,149231

7,322108

2,7023,2712,961

H-3 Activity

276738301442189

<174

494

<174

3,149183

1,1101,9341,231

103 %44%

22 %

46 %

39 %

NA80 %

NA80 %180 %

84 %

54 %44%

Tritium activities decreased in average by 29% between theJune/July/August and September/October sampling events.Additional monitoring will be necessary to evaluate if this trend isrepresentative of long-term groundwater quality.

Tritium was not detected in the equipment blank above theminimum detectable concentration (MDC), signifying that tritiumwas not cross-contaminated between samples. The absence ofcross-contamination signifies that the reported results are mostlikely representative of groundwater quality at each monitoringwell.

" Completeness - Based on review of sampling and laboratory check-in procedures, as well as field and laboratory QA/QC results, thedata is considered to be complete and useable.

* Sensitivity - The MDCs were consistent with data qualityobjectives (at least 200 pCi/L) as they ranged between 149 and 193pCi/L for tritium and 1.4 and 14.4 pCi/L for the gamma emittingradionuclides, which allowed to establish if results were below sitebackground. The 200 pCi/L value corresponds to an environmentallevel that would allow evaluating an eventual release of tritium tothe environment.


4.0 CONCLUSION

Based on the review of the QA/QC information summarized above, thedata meet the data quality objectives defined in the FSP.

S


Site Name: "DA / 1-BE:S-yFLow-1-ow Groundwater Sampling Form

Well ID:

Date:

WeatherConditions: - t .•• . (,Xfl "

Thne: OqR3o0 1 -10 "AFile Name: T5B - "2. S f

IotalDepth(I.D.): -. ,5•" ScreenLenth:.

Total Volume Pursed: . Casing Type:Purge Rate: "OOPSamplin Device: t| . , ThTubing TYe: oll, \a" Measu-ringnPoint.

Pump Intake (ftbelowMP.): 3 '_, color: Qkc.Y-" odor:. orlu t

Time: DTW: Comments: Temp SpC DO jYH ORP Turb(min) (feet) __ (C) (uS/cm) (mg/L) std units "mV NTU

Stabalization (see note +/- +/_ t/- +/_ +/- +/-Criteriae below)Y 3% 3% 10% 0.1 uit 10 mV 10%V

5:00 1~j 5ý s (Onr A (A~,09 2,12 6 '2,8 0 1.2ja ii ±~I II10:00 i 'Loom% li/wn I' -" 1 2. io•1. •. 14..2415:00 1t 'tOm rtA Ip. j0z-,1 S 3-41 2j2- 9 "2. a. rO 1.o o._S20:00 VI'," •,4 Z05,-111 (T 2I A 'PI - 3,44 -r,&-7 vi .'• 2,oS525:00 1514 t o" P-01"7 i, 11% ZA.1 I R to -I. ZI _q•d. • Z,ZS30:00 J9A± l 2-10 CA Q fn 1 .87 x'tt 1 3.(,g -. Z '1 't,3.3 lo'j-35:00 15. IA '407aM, p, 1, i7, 7X .Z. lt 3.,7 9 -' 7,2S J.. . 3 1. . --740:90 7,00"-o '1• elb -'•C ,,/ 7.,2_ o3 , i

45:.00 5_ , _ ,_ ',• . ,5 -7. 2 j3 Q,- , -

50:00 ______ zog&Q-'-n i .j1Q Z,1O ct IS 1E2. j*I,55:00 5.2-~00A- I" / /,hý W% -) los!iý -?% ' Ia ;IA -A. .60:00 z_,, ZO1,c- or, t ,c ,o3 3.0 "7,O 1 n o, 4

"65:00 13% %41 ~ j"A1112~ 3.Lo -Z -1.2 C,5070:0075:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00

Sampling Time: 107,X .8 0-4


Mv UJ - i Z G.-,M Ma h 6 n't-,

Notes:""

(])- Do not - ,e d&pth to bottom of well until after purging and saropling to reduce resuspendmg fmes thit may be reting on the weil bottom(2) 1- St1l0% wooion etiteea baoed on three 10 ost rocret oorecutive meaSotentr. "-"•(3( - Total drosodoset tn welt to he toe.s theeII 0,1ra (032 ft) Pureging rote. to be Ioae eeos ot necetoory to heep crawdose hetowe 15 .Im (0 32 It)(4)} /-1-10% wehen torbidity] is sor• 13 NI~r.~&"":

SiteName" A oL ow-flow Groundwater Sampling Form

Well ID9: tvU 3- t 2,• ...Date: 1.01|4 010

WeatherConditions: , 4 - °..ij 5 2 .

FileName: . - 2."D

Iotal Depth (I.DG): 1 -. 3 1 Sc"een Lengft ' .Deoth to Watea (D.T.W): 1••o' Wel Diametex: -311Total Volume Purged:- q, 7 "Casing Type: VC

Purge Rate: .0 L.Z Sampling Device:- f iz-t-OZtl<ýo P __TubingType:: Measur a Poin; 4 o- eC n

umpi Intake.(ftbelow M.P.):' color:rhqg+ ca,-odor:. : (M•eAlor-

Time: DTW: Comments: Temp SpC DO 'pH ORP Turb(rmin) (feet) CC) (uS/cir) (img/L) std units mV NTU

Stabalization (see note ++- +/- +1- +I- +1- +I-Criteria2 below)

0 3% .3% .10% 0.1 tnit 10XmV

0:00 .. 4., 4i I. Ib IS-1S q . 3 . 7 3%Q 7-1R '. 3.-35:00 C'-n• /h• ,, 1^,•- -, iS " C.A 7. 1 # -"178.s -Z.•310:00 6 24,9. " %' 5. -2A2.1 3.1015.00 . 24,, 31 0 ,t 1/L ,. 18. -A.545 ,4-. 1, 7 5 -s0, 3.72 t20:00 '11,• -4Zer.•,•, 0•Z A• A# .i.,4 -i, &g34,3

25:00- _ _ 1 /. 5 ,, I,+c 3 12G 4,.n '7,.tI -ji_ , _ " 3,18

40:00 mb 1A I A-7 '3' 4411 7113 -m+.~ I.%4-z45:00 4, q 1~~'c -3 - 4-640:00 ', IOIo, 1%1•,:^ . 3,7Y-1 4,4-7 -7,13 -2-50i 4.Ots45:00 14f.'L, 1Mgc8 f c•,I t9,12' "733 4,77 '. t 3 -2".5 .,0850:00 AA,6 "1CI I, M IA iScz MUMjj 6,1'L t3 --1-19. 0~$

755:00- j4'jj f-~ I8(t AJ~JA -v323, 3.

.. :o_ , - I2 7 3.69 I. 5 "I, , .* - 3. I i560:00 A4,9t zoo,,,([.f,,,, 18.44 -!N'(6 G.SO -7A1 -••-I q4 .1 24165:00 14. %,, toc f fu ,7 , q ,Z( 7.U 1-A -1,7 3, 1Z70:00 14,A6 7-5,l'-'M,,^ 19.(20 -• a.so -7,t3 .-'c,+ 3,g.75:00 i4MG M-_T.__16, (0,t__ -A 53 -7.13 -1 2 _ _. 13280:00 14____ (2_1__. _____-_•ý '_,, ,. -11.1 :-12.85:00 14.21 Iq5-L..,q1,, i ,t,5" s'tnz .{ tt z . o.

95:00100.00105:00

110:00115:00

S120:00 ... ... _.... .

Sampling ime: i 2_5Z- 3'3Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:

Notes-

(1). Do- Io .oroo- depýbl bot 611 ofoot nal i, porgin$ .. d i-tpio sosdoor-oP-sd g fisor (tot sopbe t6negon Owe -e1

I b--tse(2) Stsbilioation criteflabased o three most 10o-t t ortoeomufw oeOOufcment.,(3) -Totl dra;-owd ' i.. -ll to be ke. td- 0 7 . (0-32 fIt) fort g rate to be 16w•-e1 's, ece o-y to e or below tL 1 m (0,32 W(4) e/- 1fY,,*0 io.ilorftty is oser lb - J

Site Name: jA Vi •jLow-Flow Groundwater Sampling Form

Wel ID= tV,, j 7 S,Date: /!,4VO 7sam'ine P&rsnnel: C, . L,-, - l 1n,,.r.4 •,vl P' - . Alwkh,,'/k. J. Z).,'f/UWeather Conditions: %n/ PJ'--.Tacte: al. VFile Name: /

IotalDepth(I.D.): t2. S 63 S'•A 92

Depth to Water (D.T.W) -n) iry, 7 1 Well Diameter: 3'1Total Volume Purged: `* c2 q " Casing Tye: /IF-"Purge Rate: 2. ji *- Sampling Device: F~i,~k;/~Z

Tubin Type: I-Measuin Point:- ~ cPump Intake (ft below-M.P.): J, color- odor: g, n(7

Time: DTW: Comments: Temp SpC DO pH ORP Turb

(-in) (feet) (TC) (uS/cm) (mg/L) std units mV NTLJStabalization (see note +/- +I- +/- +1- +I- +/-

CriteriaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 J-1f j &._ _ %g ,4 1 441

10:00 rL.ý1O X _

15:00 143 ,,O ~Z 1i,3Z '1- X AL-125:00 ./.•L . .ito7 "-,-7 Lt.7,,o.30:00 f•1.Al, 22./" 9,,0 LL7Z U ;. / A qzA1 _

35:00 13 All Z4,LIMiAJ ,1•Jhf 3I3.z 7.1 ;,•6- I7.16_________ -- -; ' 1~-

0-- ~-

0 0-t -

40-00 I

45:0050:0055:00-.60:0065:0070:0075:0080:0085:0090:0095:00

1M0.00105:00

110:00115MO

120:00

Sampling lime: i.J . 14 1.


1 •.. - ,' ' . ..l . . ii , 1 .. . : • ./(... . -

Notes:(3) - Do cot omeito r depth to bottoo of well ootil after purging and samopling to 1 rodeCsoopoadieg floe, that tay he rooog on the ro~l bottom

(2) - StabliM UMc oflelt ba-ed Me three. met reeoet aoooeca tve M ttroMnts.(3) • Total droedoto hI well to he toe the 52 1 (.325) Purging rote 0 be towo.d at ceoetry to kep dawdoon bo Dl - (532 ft).(4) 0/- 1O5 whoet'oihtlhy t oero 10 NTt~e

0Site Name; b~j A. 4 eZ

Low-flow Groundwater Sampling Form

Well ID'. i•fq r'-1. .Date: / ýl 0/0 .

Sa I- er~nehQýG-- 0tArIr Ah 'n Al A~t ) g i Vr- I I . 9 =

w 1--e 'Cy I.. v,..& ~ ~~~i.A ,l

Timne: 1* 2-0 1'i6File Name- 1A5 I .

lotal Depth (I.D.): I Sreen tr 7n

Depth to Water (D.T.W)'• q. qq Well Diamete "Total Volume Purged: .. Casing Type;. (I'CPurge Rate: &'SmJn eieTubirg Type: " [J•gJ .- Measuring Point: O -

Pump Intake (ft beloWMl.'. )f color: I- ~- odor: (I., r

Time: DTW: Comments: Temp "SpC DO pH ORP Turb(min) (feet) (C) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note +/- +/- +/- +1- +/-C-"iteria' below~t 3% 3% 10% 0.1 untit 10 mV 10"/o

0:00 lq!:,4t j_?1.7 ',• 7-1. 1& 2115" q.*&., 7tIS -"21,.31 0,5:00 1 qLt q4 ý;2_24 /xPlemi• -a~•q[ .?7,! -4,77-7,,AI ).OO I41q:ý" , q3 týl/ L4, NJ ~ q 42.-0 ..Q,• 7.1,& --4/1,9 0. 6515:00 I/ q04 .' ,.:1 /241 1 ,,i- 116-16 7. - , 013_

20:00 /g5 -/ , - .k L,7•- ) I-.52%

Ls4oo it5- 4(ýIZ -2q Dd/u , M6~/. q7.' 3,172 -7, //-'-395 d,ia5:00 iz, 4q /*__ q0aO 7d,-r ,340.00 1j 42'~t~- ~ L445:00 1 41, Vtt - -1 . 12 t "•/l/vte aMq P'A 1111 0 4 , 7 ,oT "-•9& a o, z ,50.00 ,ý a6 •? A.•.., & 3 Z --'Z , 55 ,0,.

7o:.00. /14"-•..5 ',, IM& :5, ., a~T 9 ,-4V .a7, -Y.O i a .

60:00 Z, W -3-. g -- f.7&

7195K:00 - ~-~57~ .h~-Z 07

75:00 p . 2O-.'/ r. ;o.St (9 %i0 7.o -&726,5M.80:.O0 1~.411 4 01i4,.,• &'ad 3 -L/, a -410 .7,1 •.,g PLO 1

8o5:o00 - q, 0, 1' 6 I a 4,,• -. , Y3 / 706 .- AU. 0.C, 1 1920:00 q7 J c- /0 AL." -Z .. ' / - -7. .3


l•'•JQ -L -,619 7.06u, /&/:•¢a o

9: 0 -7 o .. N , 407,0:..:,.,;....:. . - . ! _ . . : ..: • : . . ... . .. . . . .;. .:

Notes:{1) -•. not noosote depth to hoeoor of .e.U .. 61 alter prgiong and •npling to rednoe Meoperufdng fi•es that may be •esoing on he ,11 boothot(2)- Stabohnk ro=ltrlo based on thre mott re Cent 0 o tofi eroeent.(3) Totol drootoonro 0 well to ho leo thon 0.1 0(.32 Ii) Porgiop to lobe loseered 00 tetary to kep do n below 0 in (0n2 tm)(4) T/- 10% when torbidity i. oor 10 NTUs.

ýsite Name: tA. s -~Lovw-llow Groundwater Sampling Form

WellID: J1 t.,-ISTDate: O Oitdt47Sampling Personnel: C1,L1W 5:-7M A1. D.Weather Conditions:Time:File Name:. jD66 I j"

IOtal Depth (1.D.): Screen Length.

Depth to Water (D.T.W): Well Diameter.Total Volume Purged: f._ 4"- . # Casing Type:Purge Rate: I Sas n Device:Tubing Type: Measuring PointPump Intake (ft below YP.): color: odor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(main) (feet) ICM) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +I- +1- +1- +/- +I- ÷/-Criteria3 below)? 3% 3% 10% 0.1 unit 10 mV 10%

0:00 11. a ALZ .~ %O ,'*- T0V - 0-:4f &25:00,, rs 1D• xxxxx'''''• .id31 q' j,, #q 7l,6'1 •Z O,tff

15:00 a a

20:0025:0030:0035:0040:0045:00

55.00-

60:0065:0070:0075:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00

Samplfing lime: Z ,j (~


Notes:

() - D.o - d~lloo epth 0boto WW oi -. 0e end)f obePnobg -d - lxg tord-o -peoding boos th1 -7eob onestti.S. the weft bojto_(2) -5mbillotinot aitoeri boed con kIeen moot emot cooweneodo mooe-menl(3 - Toed datd. Loo n woell to be I los, 03o I.)o (0.32 %I P-gio5 atelo lbe lowred wo nnontooy to keep drosedowo below D I m 0.32 ft).

Site Name; rojnwae S)mJpin FoLow-Flow Groundwater Sampling Form

Well ID.- MI i I -- I .Dlate:_ |,,\- 0 Id"•Date.-oIQ 1 0 1, 0•Sampling-Personnel: f. I ay Ma~~rLt &C~(l ~cz... .O ~ 10 W Co.-KxWeather Conditions: "Time: 1. _-1- /.oy -ZFile Name:- 67 f):;

Iotal Depth (I.D.): Screen Length: 3,21Depth to Water (D.T.W): o4 , gi Well Diameter: "Total Volume Purged: a. - C/ Casing Type: .Purge Rate: m91XIiIGf~~. Sampling Device: j ttLC0 W6Tubng Type- ý4t-Qý Measurin Point: - o0- v,Pump Intake (ft below M.P.):' color. odor: I' •

Time: DTW: Com.ments: Temp SpC DO pH ORP Turb(main) (feet) ('. (uS/cmr) (mg/L) std units mV NTU

Stabalizafion (see note +1 +/- +1- +/- +/- +/-Cditeda' below)' 3% 3% 10% 0.1 unit 10 mV 10%,

o0:00 R031 ,g, 5k --. 1-7fl 1,.,.-LI,5:00 11.31 ,2 0.3,1Q1"X4H•-'. /I,7 A1-' .bf 7,1R -3YZ,,V 5-,•q

10:00 iq,31 137 &.1/•RIA A.95.. 1/7€ *1PI,// 7,/f O•.,/0X;?15:00o Iti 3,,ny 1 Aej.A7 ,Yl 1~,,7 *7,11-3,? ,g20-00 -315 0_10.25:00 ',3W "_ . 0.-t3' 1 77, I .-3/,4 d,

35--00 i, € ,"/ /•./ 7g. i7230. l~ 2 7-,/ 1, ,40 i I- 30,3 ,A

45:00.iof&1 • !;71 .I/, /I oIl

55:00 -....60-.00

65:0070:00O75:0080:0085:0090.0095:00

100:00105:00110:00115:00120:00 "

Sampling lime: i/ O•' (44ýSamples Collected: Analysis Requested: Preservative: Holding lime: Lab:

-11 M~TIWV,~ &4PA.4AA A[0)

-::i :- ., - r":i " - • . . .e -:.. .- A 4, i . - .....- 'V:.A , : . :'

(1): Do Wst _oo~ dopth W botomo of well uni fer pugn aod aaopladi, to reduce re-edn finer, that inabe ,,kng on Ow -eoll heotoo(2)- StabiWolion aiterio batod won threoOSt rooeet ooeonseutb ,o04,roewoi(3)-. Total d""down in well tobe Imftho0 1 to (032 ft) Purgfotramt beltoweredcooo o o0keep jd or Ieohi .1 .o(03

2ft).

(4) -.1- 10% when toibidity is orer 10 NTU,.

Site Name: h x k 1 klsr e-Low-Flow Groundwater Sampling Form

Well HD. M'L -,10 - . .Date: O0- ( " 01. PSampling Personnel: gC,',. et , a 0,C54 A r ,l A%Weather Conditions:. 3 " - U 1,•.-j tý K STime: 00' / V .1io ,- /0/4/File Name: b•)0,

IotalDepth (I.D.): qCj Screen Length: "70

Depth to Water (D.T.W): " .34o - Well Diameter: I "Total VolumePurged: -.,.v 6Xt,," Casing Type: fVC,Purge Rate: ,-7 I Dt• t, Sampling Device: Pe'ar

Tubing Type: f-- 4 P 4 le.Ae_ Measuring Point 'T,' f 0. 2 i , .Pump Intake (ft below R.P.): -1 o i color: 4f ej_4j odor: /I...a.

Time: DTW: Comments: Temp SpC DO pH ORP Turb(rain) (feet) (t) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +/- +4- +/- +/- +-/ +/-

C-iteria below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 iT 7-7 6, 0 li .~26 q1 4,3 )... W~2 is- ."-5:00 Alqa, y A" &4t AL .,7 l -,7 7.2. 7d-/ & 2, /Zw,

10:00 j -, ;7 /6A4L/ _____3_/_3

15:00 "./ 7, -N V;5- A[20:00 1P ,W-10-A i1,11_ 3l A" 4 , 7,2 2/,* /A/I25:00 0• . ,Z.Z, ti,.1 LIZ 7Z._,27 fll.

55:00 14- 23 Xdl, ._IiJ t-1j, IL 7,274, 4 70, 059-40:oo00 •' M.o/ .-:v 164,o 2'1• 2, 7,,-2 99 ,i A, 6.60:00 /-3 7 /1), -6s~ ~ ~ WS I&%3 1Vo/ f/,. - / ,&A"' :W;f JZI 7,•4". Z2,_

5:o00 7"j . '_ ;,22 4,L Z,2 -. , _. .70:00 J41-1 ,4 -IOQ Y-.. I,: ,b~ - -'7r-;.n c. ~; ]'r) A 70.f/€ ,X i .9 ')Y 7._1 4? -4 -/41 n, Wid'll qMA,80:00 -

85:0090:00 [95:00

100:00105:00110:00 _

115:00120:00

Sampling I ime:/)5-' s0

Samples Collected: Analysis Requested: Preservative: Holding Iime: Lab:

Notes:(1)- Do not mea-rse depth obomr of wool w ounl alter parging anr .aropliog to red-ce muspendiag fiees that maybe restgon the well bottom.(2) - Stbifiwation criteria baed on three mot recent consecutive rroasmutents.(3) -- Total dowdotn at waefl to ho let thaai 0.1 an [.33 [, Par-ging late to be lowered as r'-oeary to keep donawd•owo "h• ll. to (032 ft).

0Site Name- 3) DO06~Low-Flow Gro-undwater Sampling Form

well ED- M~A -•ýDate:lo Irudae I apln For

Saxnn~lne Pei'sonn~1: C1. /V e.~ 6IM A&,yUfit.1iOei. J" -), HetyIrf5Weather Conditions: -4--1~A Z-J4' fS~J/AAiTime,,,,: iO' ,7 ? ...F?7e Name:.f

IotalDepth(.D. Screen gt" -2o .Depth to Water (D.T.W): 13. ' Well Diameter: .Y"Total Volume Purged: ' .... ,Ca Type: A C.

Pump Intake (ft beldiv Mhl.): color: odor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(man) (feet) (CC) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +/- +/.- +/- +1- +/- +!-Criteria:• below)' 3% 3% 10% 0.1 unit 10 mV 3D%'

5:00 '..-•if€s a-),. i 2 .2,1,7 7,10:00 0I, W/4 2Qa-4. I/ 41 IV it

15:00 7A , q-7- [Y O ;d/ . • -/..1[,73 2 , 2._Z. 7,0/1 -Z I-3-1 ,4- ,220-00 o 3 -. •/b IH.'s 1 j3 Z .,o L 7,?, iL,42 .21

30:00 3.@ /¢,/,+ •z € :Q€ i.3q7 1.o9 %L ,.•f.

35:00 13,_ . , 13+73 " 7-10" I,7-2- ,2 •,.45:0040:00 70 7 . L1 7 P50:00 1 2 A /,ie 7 U L6ZZ

155:00. . 6 4 7, 1h4' I60:00 rl 01 ., j40 7,.~' e j

05:00 1* Y 7ýZ 2-'& 6~ 1.5 %,0 144

75:00 FA I/& Q IIAX 7,07 3' 111380:0085:0090:00 •95:00 _____ ___ ___

100:00 _________________

105:00 _____ ___________ ___ ___

115:00 ________ ___ ___ ___ ___

Samipling Time:j).O


/1 k -' "7 ' -m: . ..."e :::" . .." " " " .,:':'

Notes.

(2) - Denot rreý,ee e dtrpe). ole... wall -. bteiler p-0,g- d sampling ma .d-~ noepandiig fewiloC eo.y-be ef~i,,ee C).. well bcw.,(2) - Stafliýdon crileel basdmn thnn, moet rewe,, -we.le Ov easme-ements.(3)- Tom) derowdeý in well to be lee Os. 0.1 m, (0 32 1) P'agieg raeO m be lowered as neseswy Co kseep deasedose below Q Ie n;a032 fC)(4) +./. 10% when nnbibdity tsowee 10 NTis.

Site Name: PJRVLI L2 &6Low-Flow Groundwater Sampling Form

Wellif): .130Date: ,DSaMplingfPesonýneL .rWeather Conditions: AlMTime: i q14- 0FileName: 0jJ_ C JS

I otal Depth (I.D.): 4-31)3' /cer egI

Depth to Water (D.T.W): ( -- Well Diameter: .3 -,

Total Volume Purged: ¢ Casing Type- PPurge Rate: I4p t 01% k J Sampling Device:Tubing Te: Measuring PointPump Intake (ft belovV M.P.>/ go color: odor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(rain) (feet) ,(QC) (uS/cm (mg/L) stcd udits mV NTU

Stabalization (see note +I- +/- +I- +I. +I- +/-Criteria

3 below)ý' 3% 3% 10% 0.1 umit 10 mV 10%,

0:00 - ,4 4 - .5:00 =,T K

15:00 Z.7- PLV~rAe- f, J?5 ý&Z? -4, j~ el2 -7,4

20:oo 21z)-Iya/•-Az/,k z744. -4-" :. -,a,/ X,4,. ,-,.30:00 NAM:~- a?, ;1-90 6&77~O __ _

35:00 1 1/ fl 0,x 9-11Y -7 '( 4 A640:00 / I V Aa77 Z 7,Z2 , ,

IIIoo "I. E2- ,• /2r3 - I.#5 5 , -7,7z-2-.15,f! 01.7#55.00. 7,2420560:00 H.9L -~7,.20 -20 1/ 4),A0

70:00 /4U. i72. 1,:92- 17 /41- IC•"., & I•u4 -~ - - ~ 4-~ 4- 4±~ 4~' .1. ... ~L 4- ~ I

75:00r -r -~ -t--1 4 4- 4

80:00-- r t f-------4--f85:00

I t + 4 4 0 4 490:00

-I -I----*----- 4-.----.---4 -4 I. 4 495:00

+ + -I- S L~L ______ I _____100:00105:00110:00

115:00120:00

Sampling Time: i• -" 15 I 5Samples Collected: Analysis Requested: Preservative: Holding Iime: Lab:

mfXot 1(h~ O 1rW TiCAvof 6,evA k1eWf' - I

Notes(1) -0Do noit in,•ne depth tohbotto of wee tetll .fte, purging e atphngse redtee re F."pendig firesthat -aybe e.rtotg on the " 11 bolom(2) - Sabiliatinr criteria baed on three nost recent - nutve - ieanrements.(3)- Totald-d-o in melt to be heen thn (.11 e (0,32f t Peepie rat to 1- 1r-de,e on nee e-1ry to keep dmwdoen beow L I . (0.32 it)(4)./- 10.Mnmhe- rbidityis, IoNtr 1

Site Name: ~s 6esSe-Low-Flow Groundwater Sampling Form

Well ID- (At1l3) -3107Date: 10 -"1 , .Sa-xnp.hK Personnel: h-g .o" , t MmL(AekiyWeather Conditions: £w 4' t . ),-ods ,o-,I N' 5t•jATime: AF - 3/File Name: 3DdI'otalDepth(l.D.): 1 •4 I ScreenLengtfr: 10'Depth to Water (D.T.W):/ ~"?-A Wel Diameter 3Total Volume Purged: , 'aA Casing Type: V/ LPurgeRate: .2 tSampling Device: f ertc-m6ti-ýc. _ &12T ;Type: i -,Measurn Point "[e ct 9V "CP p!L Intak -e (ftb eok, UP ): -1 0 colo r. d /AOI_¢, odor:. • '. n

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) __C) (uS/n) (m,/L) std units mV NTU

Stabalizalion (see note +1- +1- +1- +1- +1- +il-

Cri~tria' below)• 3% 3% 10% 0.1 unit 10 my 10%40:00 ' )_ , 1 9 .. . .7 j'

ihO•./ -cO 16q .qO •b &W 4'7, i,0

200 S. 6L,5 - ,:.• 0 7]

25:00 jl•,jq Ot, • b,094, '1-€b&" .& .3¢SPm L30:00 OlJf%% 1% 3Uit 0 1%35:00.

60:00 is. 9 A

65:00 2 17 34 &NO #

7&000

55:00 ___10:00 ______A_3

65:00 16,061

70:00 _ __

75:00 _______85:00 P*__ It____30:00

00:00 70 Vc/IR.


450 .0 66 SAM.

Noles:

(1) -Donot meaue~ depth Io boamm of~o re nt~il a/ke pu•g'ieg ad sampling le redue r~e•spe,,dg Irees tht ea7be •' 6-eg an dhe well bo~tem

.(2) - Su~bilization criteria hated on three riost recent conecuve rgea-nrmerr s.(3) - Tohl ddondown • wel •beksthate0.1 c.(05225) Pre~g at ekeedyan=aymkeepd d-eweowbelowS n t O •.2ft

(4)! l•/. v0'twhn tubidity is oser 10 NTUu

0

Site N~ame'- -ýAII ow-flow Groundwzter Sampling Fonn

Well ID: M( J, 3 1 .S,Date: o 150-7-Sampling Per§onnerl: 41 •.t).e-- . a _ • "Weather Codtos N,Time- -/

File Name; .Z>A4!1,

Iotal Depth (I.D.): 43•,OO Screen Length: 33Depth to Water (D.T.W): O1 [ 1 1 Well Diamete: 31•Total Volume Purged: 4, Z Casing Tye: PvcPurge Rate: ,•5.o/ Samplinp Device: fe, t C ••-h 4,,oTubing Type: go q ": n e . Measuring Point: "C o PC.Pump Intake (ft below M.P.): color:, odor:

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mmn) (feet) ..... (°C) (uS/cm) (mg/L) std units mV NIU

Stabalisation (see note +1- +f. +/- +/- +/- +/-Criteria' belowp 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 /5- 0, .&0 ta l0W) -441S,2 .2290 A ,W -716 -)., //,.D

10:00 '22A9~ 2 J ?R9 -42 -7 /-A,41-20:oo 40'', g Lq • ;'fJ . fa .l /0 = 9 3-,(4 74. ' -la •,l 10 .Q25:00 i',07 :2I_5 / n, - O•aTeY 9.02. 7./Y -/•'77 8,4-g30:00 &4 o 7 __.__,g_4,- . ' ,YY,¢. /W7 4.Y7 -7.11d -3 40 , ,3 , 6d35:00 J '.T 7 zg /.- ,.l /40:00 0

50:00 I5,iD7 Jpf -A&5 ____'-.1f /,?10 & Q55:00 0 nI37 / ,9 i9

60:00 i~al AF v- Q 7 ,f 775:00 1 _ 1_70:0080:00 ____ __________

85:0090:00 " __95:00 _____ _________

100:00 ________________

105:00 ____ ___

110:00115:00- ___

120:00 -___

Sa ln ilm 331/ -- /./


Notes:(I) -Dote eeroe ea~rlepth to bottorr owcs• Until ,r PurgiegorrndamPfln• orerduce st~supondin•t ni ts-armry restieg th-wcll•trem(2)-- S1obiliznlknn eriterto booed not three moot recent consecut.ve emeasremeenet,(3) .- Todrorwdo.- ie -elt .o be I- It 1. (0.32 ft) Ptreg ramt. to he lowered Is uet ese ry to keep dor -doee bhlow 0 1 m (032 ft)(1) +/- Ott, whoc- turbidity is o-er 1W MN

Site Name: j [A -JLow-Flow Groundwater Sampling Form

wen HI Ik) td AI •....Date: 10g/-

amliny _ersori-nel: E,~ P. MIWdCJ k .(iWeather Conditions:Time: 0 IR-:- - 5 - a

File Name: ,6-;3"n

IoWa Depth (I.D.): 6 1 p4(,A Screen Length: 7/&Dpth toWae DTW:Wl imt:

Total Volume Purged: / Casing TPurgee Rate: L-w,--_' . SamplingDevice: c ,.Si hc. pu-~'nPTubingType: poly eAh.Vlen-' Measurin Point- N."Pump Intake (ft 6elonM.P.): o7/' color: U • odor:.' ,y

Time: DTW: Comments: Temp SpC DO pH ORP Turb

(WinL (feet) (*C) (uS/cn) (mg/L) std units mV NTLJStabalization (see note +/- +I- +1- +/- +/- +/-

Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 11 Z .-ý wx-; gagL A___1.55:00 /, - / .10:00 156 14-7 419/, .,07._la_-_ V Y15:00 1 r i20:00 /-?,D-? 70 -il,, - 725:00 7, . 2 ,1// Q 7. 07 -319,.5 d. A-i

45:00

55:00 ___55-WO.-

60:-0065:0070:00 ___ __________

75:0080-00 ____ __________ _

85:0090-0095:00

100:00105:00110:00115:00120:00

Sampling lime: - 69'/7Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:

Notes:(I)- Donoto-ea.ere depth botm of we] uIe l ug r pae- .ad -opling to reedee , dendigfn es th,, be = eyIngeo .e -11 bottom

(3)- Total deewdown well to Se lens de 01 n 532 It). Peg rate to be Inwornd as noee y to keep deoawdoee, bela 0s1 e (0o12 01r t

(4) ÷1--10. then tubldityOi over 10 NTl~s.

Site Ntnsc Vawls- 9?!rL ow-Flow Groundwater Sampling Form

WeHl ID M '"Date: /1 ,5 0.77Sampling Personniel C. 'arOeWeather Conditions: a,-trfwu5 aUn V-1 0-1Time: ORD -; 9ý *•

File Nane.: -3 3e,

rowa Depth (1,.D): Sc-2.3p'Scr : --0:2Depth to Watex (D.T.W): o) /q( , Well Diameter. C3-4Tbtal Volume Purged- ,• Casing Type: ••i'

Tubin.- Type: P .Measuring. Poin . •"p._.

PumpE Intake (ft below M.Y•): ..5_;, color: 14 odor. tl•

Time: DTW: Comments: Temp SpC DO pH, ORP Turb

(min) (feet) _ (C) (uS/ca (mg/L) std units mV NIUStabalization (see note 4-I- +1. +1.. +1- +1 -

Criteria! bejow)• 3% . 3% *. unit 10mV 10%V

.5:00 ,. -7. , A,7q-- 71i 9o ,10:00 0?I/ M11,.zA a ,•,. d1 a4, 5 7,% A ?-2z _ ,-7.15:00_ _ adI,'•,•. -rs 451 ý" a%7,2- 71F ., 7, 10"

amls Coo.lectd: Analsi.s eqetd:• Preservativ Hold 7,g lim e: Lab:

20:00 -3,q eero .,I/c, c,,5co -8e,60 7, /'t 1X " d,7bc217

• ,oboI~jn, 5q o'(D2 - eneb lo-ndSS,e ,s .po kepdedee _bleo'5 ( ,19-324-).7•

25:00 A

70:00. A5 21;?-W#960037.5:00 1,6 4 qftlmvtn

40:00 )1,0 aGk A.(A3%4.070 #70,V485:00 i nR 7v_-74 W750:00 -7,04955:00 1 3160:00165:00

110:00115:00

120:00

sa9in 5::00.•&"" 05

100-C.00 e: .navi eqetd reevtve odn !m: Lb

105eS:0

Sam le Co.h l, l ec*' o,6xted:n ree nalr vstco~•uis ercaulested: Prsraie"o iglm . Lb

f } 1 Il lr'•dt,* } llW¢IIlt b l'• hl Im 03 f}Purpng 1.1k 1. N, Ioweed 1- e1-~ay 1. keep &dta -•oq eoW-0. I. (D.32 III[I -• - Z "Owl~1I ~~iy our] -•

0

TSiteNme: ]BEZ 1.

l ow-Flow Groundwater Sampling Form

ToawDet (I.D,7• Scre.f5" '7'

P ate: " IM O . S De

Wthe: CondtioW: C7s ommets•. To eCf , DO p S;;r

Totl h( i.D):/# Seff h: 70

Depth to Watex (D.T.W): 0)lt•, €Well Diametet: '

Tota Volume Purged: _?,• a 3 Casing Type- Pve_•

T-bing Type: ._ ,,Measuring-roit 7 •OOp . -F O v*c-_P um p I n (ta k h p~ o u M . P . T 7 0 ' c •o l o : ( I J ,A , o do r :

Tun~e: DTW: Comments: Temp spC DO PH ORP Turb

(rin) (feet) (C) (uS/cm) (mg/L) 'std units mV NIUStabalization (see note +/- +/- +1- +/- +1- +/-

Critexia" below)' 3% 3% 10% 0.1 unit 10 mV 10%'

0:00 1__73 *OAQ•h &.?-7 &AX ,5:00 1 17~ p$J~ ____nLIt~ 19 M10:00 11179 j aO MGD 4 1.7 a.0 f ,15:00 i / Z jq,-7 s:; IVx4.__ o20:oo 0 , 7q -t laOrD yUhi4. A 5, O T,7 6,525:00 V.1 -7 9_ aq__7 ,:,Zo0.3 o :o o0,0 P 7, i - T t Yk . MI %3 , I O N _5 & 6 k ; L ý3 0 , L % 4 3- 5 ,_6 6: , 7 7

35:00 L1 O 4•, G•7 4,37 65,09 -3•90•,• q440:00 LLL QO IV-I45:00 ' 7 k

50:00 J6? jj O ? * 4

5500:00& _ _

60:00 ~I65:0070:0075:0080:00 ...... _ _ " __85:00 _______ ___ __ _

90.00 ____ ___ __

95:00 ____ _________ ___ ___ _____

100:00 ____ _ __

,105:00 ____ _ __

110:00 _____ ___

115:00 ____ __________ ___

120:00 7____ _____

s~ a p lin Ti m e ,, / 1 . 3 3Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:

Notes:fl) Do not oseosur deps0 to bo1on of wenl u-til 0t1er ptogng -od sampling to reduce htnnnrnending lie s th atee t es ting on to welt bottona(2)- Stabilibooslo crterla baoed on tiree moa re-et coenecutive mennumemelts.P3)l--tott-dra-down in ýt tbet e thn D 5.2 m (0 32 1t). Purging rtte Iolv lowered - -7 tokepdrawdown bewaj]m(037 f.)(4) -Of 3W.V when trhbidity is o-r, I0tim )re "n" t p r o f

Site Name: {T/4iJ A 4X6SL ow-Flow Groundwater Sampling Form

Well ID: Yhi1'IDate: I 1 4e1e) Sa. h :

SampingT Pe~nel: Mau on:

Weather Conclitonsf & ••!'¢ ,/1-2-<• •,_maTime: D" W: C nT p " pT

ToW epth(L.:..So.O• Scee Length: .)Depth toWater (-.T,W): ( u)/c),tsm Well DiameteV.U

STotalaVolume Purged .. Casing 1 ype: - .. ..Purge Rate: /.70jl•/gev •, Sampling Device: ]•/-•j-• 1TtbinTye " • ... .. " MeasaEh&gPoint: n-+X ID: JbibkA YVlC--

Pu~plna~k~ftelo~qMF• ..z- coor odr . . ..

Time: DTW.- Comments: Temp SpC .DO p_•I"ORP Turb

" .(rai) (feet), MI - ° ( uB/on) Crag/L) std.units mV N•[U

Stabalization '(see note +/- -4•- +1- , 4-1- .+1- +l

Criteria' below), 3% 3% 10% 0.1 unit 1 mV 'i0%

0o:00 &1 /. 9 .'7.¢ 1Y15,rV.L_ ./.1,60a !,1 ,,-l514 .q5;00 1 74 , 010:00 7Z1 815:00 P1'.911-?, A2 .-,,7 7,,Q z,20:00 7,' 7A0 540 ? /f

__9_ no-W I7~q ~ 7.o 0

30:00 0L, /), lw•-i•. l•,,ligd .277/ A ,, /Q " 7,('t35:00 I'?- A/ 2 Q6 3, Ar 7,;?, -2,,q 0

40:00 JL2 7y0t/;t, 0,•. /gAl 2 F77-•, 7+,;..- 11,11/ A/z45:0050-00 A -~xm ~q 7 -Y0?d60:0065:00 ___ ____ _____ _

75:0080:0085:0090:0095:00

100:00

105:00

110:00115:00120:00 ____ _______ __

Sampling Iime: /)0- 12 /0)..


. flcJ-L "; _ ._ •___. .

Notes:(1)- DO -ot &easoe depth to bottom olsM aetu-l alter purgieg snd sanplitg to redost tersupetding fties trat mty be cee~ingeo the weet bottot(2) -Sta-bladon criterlo based on three most re-e-t co- 6-etive m--efubents.(3) Total drowdoe a mell be lest t 51 m (052 I) Ptgiei tale to be lowered S necesr, to keep drwddon below Tt 7m (0.32 it)(4) --I" tlt oc hee turbidity ti oce- 10 0Jrth -

0Site Name: DA'JLA !S'_9Low-Row Groundwater Sampling Form

Well 11): MU/ -35 -Da - to / Wae .... W

Sauping TPerote: AMA Mauin ont

Weather Contons: .L 4-It' -7 c2 l , d- o.Time: D Comments: T C . "File Name D. .@., ..'/..

Total izpth (TsDe) , , Sre +1- ' , _ + . + 1

CD.epthto. Wate(DT.W): 3Well Diamete% :R % 0. ..Total Volume Purged: •d, . "Casing Type, •'-PVC.. A ,Purge Rabe: 1^-7 A L/.J 4 ,- Sampling Device:,- lpe,^,. 1 _-fj{Tubing Type: ]g,/ /L-Measuring Point:"TQ, ' •]"

00mp Intake (ftbeoVM.P.)_,6"- color.. odor. ..

Time: DTW: Comments: Temp SpC DO P.H" ORP Turb(Min•) (feet) "("Q) (uSlq. (m) /L tstd untits mV NTFU

Stabalization (see note +- +- +- +- .1 /Criteria below)" 3% i 3% 10% .0.1 ..uit u0 mv 1°

0:00 4, .• 7,12, .6V15:00 ___ f M. 9ý/ 7&?*. k1A --4 g

15:00 A32 fO~ 7t,0i2, e6.3 j. z3000 I -i70 , . , /777. I02ý &ý 0 /"

3500o _,___• /d g7 ',. 47, ./.gg3 A,40.00* . E-I~,_.7,

45.00 •.q 1"0 -1i.3. 1~,7j 7•; -( I,. Ii7-gg /),

60.00 eR:3.Zq IL~~t/•..•g• b• i.70 7.2 i 7Vi0 7 L',A'

65:00 7 a" 4

75:00 7S- 20MIS 7.0380-00 1079& h d7 &Y1 &815.00 _ Qz520:00 10 -it)______I ______'7 07 , 7t72. & 1,#-

Samples Collected: Analys7is Requested: Preservative: Holding Tme: Lab:

65:0 -139 170. ~iV&AZAz~-i.2-, ,f1n,,04

85i:00 43. W7 ,-11f ,i7 I... 5 1,V "1 59:0. . ..... ... ,. pl f L 70. -7.. .. . . • :!::. ., .. :. .... -,e . 0 0 ....

NDtes,(- Do net meas- depth 0o bottom~ of wellutld after purging and sampling to oeduce re- pending ti-~ tht maybe-ig the(05. woeoll bottomw

(-I) Setbibzolion criterH. b-sd on three woo roconlcoo- .6-e noseoorcNns. -(3)-_ To",tdeoldwn me well to he 1010 t10n 0.1 w (0.32 hIj Purging at to01 be le-ered 00

0C000m 0 hoo drenoel-4- belýow 0.1 an (032 R)(

(4) /IOP305when turbidity is odr 10hffllo.

Site Name-: Iwa'\r S l Ferm1Low-Flow Grou n-doater Sampling Form

Date: j 0 - -. - 0 aSampling Personnel: ,-p., O I f N\T YWeather Conditions: /,,t/.' , 4/ /s

File Name: /J RA 3 7.•

Total Depth•(•.D.): 4. .- . ? '"Depth to Water (D.T.W): C-~1. Well Diameter. ~Total Volume Purged:...5 .i. Casing Type: t"//CPurgeRate: -240^47 Sampling Device:Tubing Type: 1-14 a . Measurig Point: to~ I j-P/rl.Pump Intake (ft beIK,IvLP.Y. / color: or-:11Ukr *'AD/l

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (Q) (uS/cm) (mrg/L) std units mV Nru

Stabalization (see note +/- +/- +/- +/- +/- +]-Criteeia, below)' 3% 3% 10% 0.1 unit 10 mV 30%'

5:00 _ATa w9 t7 ,020:00 '-. Xi).a aa35 2,30 z,.ao -16. ,. A25:00 0,3j& . l , 7;U-& --/',9 z'&

30:00 "1,i, -I, /5 O 24 37 T, 7-.410;1 ,9'•35:00 . I -I / 0 /Yu i,7t 2-2.3•1 .5 7,z.127 ,•/. A Z5a

45:00 q[J 4,1 i* I'. q& /,50:00 TiI .RUT /5,2. L 25~ -4 JL.2 . 1A55-00-- !r2 a-a,65L a- , 3iY, '7,3,2 -/7Z h I, •60:00 2 1• ' .- ,/.,,65:00 -IMi .. •O tYYA'u - W•I• /? I .a,0 ,91 7,Iq.-/,17, /,. '2.z70:00 -,XI4 /t d4~1 _2S__/5 __ 74.75:00 13 Jo23,7 -7 3 /9V., C W,, Y&

90:00 ' I-.. /no.40

95:00100:00105:00110:00115:00 __________________

120:00 " •_______________

Sampling lime: /v?29 L7 i2• 9'Samples Collected: Analysis Requested: Preservative: Holding Fime: Lab:

Notes:(1) 00 Do not~0 dopi ro b ofs, 0r -61 aft"~ pis'ng .d ý.5pinsg Iv redO -s 'pe"'"d io Io- l tht y b ist oOgs .. th -i b. ft.-(2) - S .ubwos, crilosi booed -o Ih-s wo -t00 -- ti-, oanms(3) _ 7ouIdrsdoss' ita o e loe- 0-s 0s.1 . (132 ft) Poo&og teto ocloiwed 7 tsyo k~ej, d-~dosbel- a fI . () 32 f)(4) -.1- Kr. h" rbidjty is so., 10 NMl&s

6Site Name: "AO) _5Low-Flow Groundwater Sampling Form

WellJID: MY 1Ii.Date:

Weather Conditions: 7170 aSWiAtl -3aTime: j -)_- U

File Name: D• iOO/q

Total Depth (I.D.): 2,. cr in : -2Depth to Water (D.T.W): 1 ,q, ( 1-, Well Diameter ý3Total Volume Purged: , j Casing Type: PVC.Furge Rate: 9.MlldtSampling Device:Tubing Type: Pc-L Measuring Point: -7 b I' DA"V'C..Pump Intake (ftbelowWA.P.): _ color: & odor: V 'jj.!

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (0C) (uS/cm) (mo/L) std units mV NTU

Stabalization (see note +1- +/- +1- +I- +I- +1-Criteria4 below)' 3% 3% 10% 0.1 unit 10 mV 10%,

O:O0 i•.(•3 ~ ~ _ q••'_fL 97 3,• 5-43fq, 7 W " "-.• •/.l,&(

5:00 i/A Q.i IC1 ktch, .7a533,6=10:00C15:00 ,a 3 1nk 3v"/ - -4 ,a,•, , S 1,30:00..U3/25:00 ,L16.9 3035 . o,,S ý7.00 -00I 0 - 130 735:00 w 0, . .I ,7

50:00 .. L _3 /.7 Y7,( 75,67

60:00 /3,; 10 j/d.l1' 3,8 7,O. a-a2, V, Il?65:00 Ia, 11 -29Z &,•m$ ,2t . ,qI__ 7- " 7.06D - /2,9 býq70:00 i ? k/ l 1.7 c 0 4 , 771, L -a,5 , e.75:00 acz 242 bV101, 165 AV57 A-01 '7. -1,,4A -7&

80:00 J91 j.?/t9 • /, iS/& i1 ý2!7k 2 aAo " ea -2,1.585:00 2,1_ _7 7, 17,i~ 0. jjq

95:00 __,__ .3qdl27.•, 5••,,#• 7/--17,30,'Y100:00 '_ -/ . t_ _

105:00

110:00115:00120:00

sm• lin7•gls.•e i,3m.3 "- i(t.)

Samples CoUected: Analysis Requested: Preservative: Holding lime: Lab:

ma.\L i 00A i -Ti &N6im tmAJ

Note.(I) -Do tot masure depth Mo bonoe of welf ont1 a fier poglg aod sapu pigig to r-ede tr ,nsperding Irt. that ay be rrestig on .•t well buottonQ) - StabilIzation criteria baed on three -oo teeet co-set tive c,rnesoeoets.(3)-Total drawdo-w inwell to be teo than 01w (032 fI) Porging rate to be lowered as neoeoary to keep dsowdowo below 0 1 m (032 t}(4) +/- 10% when torbidity is -'er 10 NTI~s

Site Name: L)t, i S P-0 ow-]low Groundwater Sampling Form

WlIDat: 24IV

Sampling Personnel: (.,I-, .k,¶ fl]zrieN"i /L- ,1. k--p_/ec.-Weather Conditions: '2'-e ' I

Tihne: ![2 -File Name. 4

1otal Depth (I.D.): 9Y. 7,qj SCf9*iSrth:3•.Depth to Water (D.TW): Well Diameter: -!Total Volume Purged: , Casing Type: f./.

ITubiri;fype: qJ/a4/ .-- Meas-urin~g Point: %'.# p f-'a•FPu~m Intake (ft beloNv M.P.): •3 • " color- d,•_zj/- odor:iz•l-

Time: IDTW: 'Comnments: Temp ISpC' DO pH ;ORP Turb

(rrin) (feet) ('C) (uS/cm) (mg/L) stdwmnits rmV NIUStabalization (see note +(- +/- +1- +I- - .

Criteria' below)' 3% 3% 10% 0.1 uanit 10 mV 10%4

0o:00 Id. t- n /'/,•4w - /~ •a.' "¢ ¢1 16,Y'/ 7, /__5 :00 J23 4 o213oQ 703 2:, 1'i -7, ___Z S

15:00 zl- ey 3_5_5 9 •.l L i f - / V ol e

1 0 :0 0 , ,. 4a- 7 6 1 7 5 , 1 0 ., -1 ,

15:00 iJ9 7.• - ,,/X,•_zkl.,¢. -- 7.•[ 0 g• 7[ M , & , i/4 -4a/ L.2 7 ,i20.00 i,.2 -.A 73" A L-eJ,14-44- • ,q 7 - rd 7 17, / -1-4.6, 0-5'25:00 c 0 YI 77 6g0

30-.00

Jillilv~ ,?. /aDa 7 ni

35:00 0 JA 4 ma~sz. 1 /-9 -aa40:00

50:00 112, V15 t_1___15355in li: e 0 ~ L 0- 13107/)

S 00:rm

105:00110:0 0115:00

100:00

Sampling lime: i-3&• /Z

Samnples Collected: Analysis Requested: Preservative: Holding lime: Lab:

1

>, -7-k , .~,-.-w A :l .

5~4Pe~

Notes.I1I - Do 2ot t.onre depth a to bo"o o.e - nat.6 after prgiteg and ssaplirg to redo•ee - spdiog Ia th -t -y be r-tig -n the we2 bottoa"(2)- Stabiliati.on criteria based on three roost reoent cosecutive measurements0) .-Total drawdown in worl to be ess t1hn 0 1'm (0.32 ft). Purging a•to behloered as ee- ary to keep drawdoe beeow 0 1 m(a.32 (t)M() ./- IM0. whe. torhidity it o.r- 10 INFtU,

6Site Name: "]7,91/,.5 "'A$$L ow-F-low Grorndznater Sampling Form

Well ID: i - CDate: - :?Samplin~ Personnel: A A RE<, -We ather Conditions: 7 I . ,i .. / ,q4Time: 6F7Y-3iD , /f~e

File Name: D)A • k/o...

Total Depth (ID.): Sce-ngR 511,5

Depth to Water (D.T.W): () lz ? Well Diameter: a A

Total Volume Purged: Casing Type: P2C,.Purge Rate: Sampling Device: XZ;k-.. _ 6 &'ee,'yZ,Tubing Type: .. V Measuring Point -7-0,0 F,'A1 ,,/ CPump Intake (ft belowU.P.): , color: Z•Zitzl odbr: ,

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mri) (feet) CC) (uS/cm) (..rg/L) std units mV NIU

Stabalization (see note +/- +1- +/- +1- +/- +/-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%,

20:00 7,7/- ,.C 8 i76A•7• e/ -,'7, a ?J••3, I,

45:00 la.7k , I-Oz7 M 4 . .". gJY7 , 7 "55:00 ia & . 4t,4ý J.., A MI "-- .33, £,(

15Mo 1,9,75 AN .. -,76ý 22,04l IF.qY '.-71 ya.-/1 -2-.K; ,3Y

70:00 -76 q& i/r-'/ " Z Lz -34, , --3

95:00 I~ ~ R 1/~ '-7, ~ /i

15:00 ILL 6. f,. 46,A 9, ., V ,24 -,

10:00 a2 ,7(- /F,41•/ 4•/ , t!,?I 910. W, 7312 4- ,3-g ,

115:00 ____420:00 ______ --21

Sampling Time: / WA

Samples Collected: Analysis Requested: Preservative: Holding. lime: Lab:

Notes: .3 " " "

(I) - Do not ceneu re depth ts battonc of te8 ntl soa etee purg~ig antI samepl 5ing ett e~ue traesupendiog iene that ceay he g ontiso the wet)hll oot.u•(2( .- Slabuislizion criter'ia b~a ed tcm three eost recent conseecutive ,neattt menntts.•(3) .*Total d raseooee in woll to be loes than 0 tto (0 32 it). Pursing r ate to he loicecedl tsneressary to keep cdrasedoon below 0Otto (0.32 It)•(4) +/- l5;, wohen srbidity it ever 10 N3•s" ":

Site Name: _ VqIJ--S 8IES5E.I ow-r-low Groundwater Sampling Form

Well ID: r(Uj '-- 10 1 A

Date: j ()-7Seatepling : /7e WSa" Devic:rho(/X ,bjc)•.

TotaLl Depth (I.D.): .940,6 n Lc~e•Lngth: a:;la-5Depth-to Water (_ .T.W): (1) J-5.•. (q WeU Diametet: a ,v

Total Volume Purged: -': •Casing Type: eVC,.

Tubing Type: •J•.• •9•. Measuring Point: "rgnp, 0-:ý PPump Intake (ft belowv M.I: ,'.$O' color: Z. odor: AO•e.

Time: DTW: Comments: Temp SpC DO pH ORP Turb(ain) (feet) (1c) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +I- +1" +1- +/- +I- +1-Criterial belowr' 3% 3% 10% 0.1 unit 10 MV 10%,

lO500 "i3,4• " i a',v•, I• q1', '7 bA 7• / - '40,00 &7,5 726_ Zi jW4.. i4b( 41,

45:00 17,, j __._ INA( ;z i 11 •7 ,7g -7 1.34

50:00 4~~ A0A"L 119 V9L ,&ZR-~ L

15:00 i5,c / "" ; ., ;df 07 - 4r" &• .i320:o00 ,q "lg 1• gi7,• cy /;z,5V ta af 6•-., AV 6a.- q ,s7 .

_ i.L,q " I Z_ '1 #3 1E105:00 f,,,7?nt-6_ _. t4_[ ,,,,Al ? 11521 -1,_ i7 6-_ ,61' ____ _&

50o:00 __I___M. /__ __i , -A, .,_ 67 .a.9, zz_.,_15:00 P, N,0 V1_ ,_46/s, _

10:00 L ,______-

pli:00 lm q j .S C5:00 A iesd. Pva H m Lab:

175:00 " Yd '94 A s, ,u

815:00120:00

95pin:i00 Jl0i'-/d•

Samnples Clece: AayiReuse:Peevte: Hlig'ime: L

Note,-1)- Dom -o'eeere depth tobottan, of o'eJ -folt attte por~iog otnd-osphoe~ mdo -eteesopending fines fhat omybe eesting on the Rbo~tt omo

-)Stabittostion cri-to hosd on th-e - d- ee,,cneotv ~ot~oen(3)-Ttltode. toP,! h, notont u oO~ 0 niog t,, to~bo to,edit otssonoy toktosp deeodooýnheeo (t O).32(tO)(4).o/- 10% the. tobidity s ov- It Nflj

SFSite Name; ph ylls- .6iSLow-Flow Groundwater Sampling Form

Well1D. MO - 1 i a.Date: iO/r/t? 7Sampling Personnel:

Weather Co-nd-itions: ii-/A<i4,e ji.. FI'~~-Wz

Time: /) 1ŽFileName: Dd /0.A

Total Depth (1 .D.): Screen~:..A2

Depth to Water (D.T.W): (I) ill 0 7"[ Well Diameter:Total Volume Purged: 1"6 Casing Type:Purge Rate: K~tJ) Atn(//i% Sampling Device: jýv16ie iA~TubingT : Measurina Poin'~ j ePump intake (ft oWM.P.).. 3% " color: 8&LVV odor:' .

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) 0) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +4- +/- +/- +/- +/- +/-CriteuiaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%,

5:00 J•LL 1 / , i . 3,4. .23 /,£, 7.l3

10:00 J.4.. 1z3 I f40,77

20:00 !4,k3 17.g' q5/ /l. . 7.2 1 3. Z4, • Z, JiL25:00 /N.1 HAW,•,•'n , iq a ,t 4.-7 "].; 1•.6,3 J ,

30:00 14,11- /7.,j•. 17t,@ Qif ; ,9 7-257 R.,,31 .,,35:00 N,. , i3 45 1.01 CY 7. 2 ._ _.; 6 .•.7,5 V40:00

45:00

50:0055:00

60:00

65:00

70:0075:00 -

80:00

85:00

90:0095:00

100:00 ' '

105:00 . ... .

110:00

115:00120:00 ________________

Sampling lime: .... /i¢qSamples Collected: Analysis Requested: Preservative: Holding lime: Lab:

mtJL - /0/ 6 -71W1 ,14A 1~ 0 AS4 JOIA'6

Notes,(I) - Do -el et-u o depth to bot1om ol - o9 l a.6 er puogiesg -d saassplieg to redone r peodig fei tnl. may be -ectig a. the eel botton.(2)- Stlit -E• Mcrt. based on three m oeoncoectine -,eeacmeeas.(3) Total d-adost. e in -e11 to be ke. ttan 0 1 e (032 fi) Purgeig rate L.be lweed .. --ceory to boyp detadortc belcW 0 1 . (03? It)(4) +1- 1T, when torbidity is over 10 NTUs

S Site Name: JUVL', ýB&SAeLow-Flow Groundwater Sampling Form

WeIIID: tAUV o i CIODate: 0) 7

Sa Pn Personnel: 6 ajA tr4Weathier Conditions: (q-2 0 2ATime: Jac; - 10V6•

File Name: JZ IO.,/i..

.otal Depth (..D.): Sc,,e .gth: NcsioDepth to Water (D.T.W): ,, 1.9'. Wefl Diameter ;,"Total Volume Purged: M 3tj-, Casing Type: .OVePurge Rate: /sT) ,e1/ d Sampling Device:, ýid)cp. i4Tubing Type:, - Measuring Point --I b.Pump Intake (ft belw M.P.): .. q,•' color. t odor' , ..

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) ("C) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note +1- +/_ +f- +/- +/- +/_Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%

5:00 . jq5 '. ?4. iiZ .± _,__

10:00 1243:0 _,W& __. -15:00 - f,66 ,(/.4., •. r:2

25:00 1,-6,,0'€ 41 &Y;l?])T we "l3./ _W 5/" "f.b -afte.•'1)4o~~~oof 2g/o . 4Wti,h 14,q t.0~ c~ 5~¢ Yy• 5";.y t. 91 t,520:00 - ,-I, ,.

35:00 S.s-,O J 3Ot/'5ta& dlA"33 ;qX.••, /25:0030:00 7-,2 icYO IdW

950:00 IR10 AD1" ka LjS9 74

105:00 ox I 7 0r//n-7

60:00 7~i - _ .bf.5Z

60:00 4 4

80:00 Yi 0 2 /a~ki i-5 7o3133L75:00 ;Ij54 U7_110 b7 385:0090:0095:00 _____ ___________ ___ ___

100:00 ________________

105:00 ____ ______________

110:00 ____ ______

115:00 ____ __________

120:00 ____ __________

Sampling lime: /3'/i-'A ,L


Notes:(1)- Do not eresur depth to bottom of wen until after purging and saepling to redoce r-supeenbdg fees that semy be ereing on thr well bottom(2)-"• Stb l tizntioe Cruerin basd on •tree rets. receot co-se cutive meresueree~tst.

(3) -Tota dnrodo in well tobe eo bthar 0.1 em 0.32 it). Psrging orte to be loweesed s necemry to keep drairdsore beiuow 0 Jor z F532t)(4) ./- 1l% when trbidiiy none- In NTL

aSite Name: "i9, V/i .Low-Flow Groundwater Sampling Form

Well ID: -izni -,/ 4oDate: ylz/ý'llv 7Sampling Personnel: 0'. •/.4 /V:v-O- A.AL' /,0d_,-,0

Weather Conditin:, ... /• ~ "'"_$(•.

Purge Rate: 13e2 9- Sampling Device:Tubing Type: i, _ ,.Measuring Point: R ePum Intake (ftbelo. M.P.): , color: Lr odor: V

....... {) •, • • -• .. ' , " .

Time: DTW: Comments: Temp ISpC DO pH ORP Turb(min) (feet) M(t) (uS/cm) (mg/L) std units mV NIU

stabalization (see note +/- +/- +1- +/- +/- +/-Criteta'. below)' 3% 3% 10% 0.1 unit 10 mv 10%'(o:00 T.3q, 4 ,.-? 4 , L,,'.', j7,77 iý-,•7 -7..? /;•..- -• LZo 7.

10:00 14,-5 i.gW.4/0 .,4 -Z , A-& _,_ -.

15:00 -L1~~ J&/) 6~ /V17 IZZ6 -i4l -677

35:00 li 95 /9,0- il ,/ .. l K&al, 9,9 t.,,'7 .f Z-4,90

65:00 f57 , ,25.'/a/',4s f,,7 ;2A' 7•/ -.7,// i 157.S

65:00 •-d i,•''z_/g _S, ',14 ,;9bO iqd, PIt,• -/g, 7,$/2,.

90:00 45j -45-95:00 _____Q6 g & i

100:00105:00110:00 QJ5 A&-45_____________1__2115:00 133 1,17120:00


80:-' 00 _____20 ____7_ 1, V /-A

85:00 4.. . . ...il90.:: .. :-. 00:: . . .. . :i::-:. •.: . :i.i!:!': : : : : : i: . . " . ... :i ...: .

Notes:i(1) Do tot -esre depth to bottom of oeti ooti fie- poegiog ond oamprng to redao rens pendteg fino that -y be .esting.o the s-el bottoto(2) .: St•btittion airiler.a bosed on ose t r - I -ecent conoecotive -fleaS-ementS .(3) - Totoa dotdo.- in t eot to be Ies than 0t1 o (032 it). Puorgiog rtte to be lo-reed s .necessry to keep draodno eow, 0 1 . (032 ft):(4) +/- 10% ,hte torbtidty is ovn 10 NTUS. 0

Site Name:- _DAUJ.5' ~ '

L ow-Flow Groundwater Sampling Form

Well ID: V1L() -iO,2ADate: 4 137 C 7.SamE ung PersonnlWeather Conditionms: ;'f , • • $d a L.Time: ol GO __

File Name: Dj6/19Q

Total Depth (I.D.): 9,2,9g ' Scr, A frh: 3 ,. .Depth to Water (D.T.W): • / "72' Well Diameter: d /Total Volume Purged:- Casing Type: PV.'Purge Rate: j-7~#t/Z. Sapn Devie r-I4 fQTubing Type: MeasuringPoint- 6,k: P1.1"Pump Intake (ft below'V.P.): 53 CY.' color. ZIav oor:_,

Time: DTW: Comments: Temp SpC DO pH ORP Turb(.min) (feet) CC) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +I- +/- +I - +1 - +1- +l-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 P-J .41PnJmj /,4,1L. ? o5:00 A !t PO•Y - X43 .?,751/qa2• 7-,1I

10:00 o I, real R7 44(,iZ 1,,.' I/,- -1,2a, -igy I?

20:00~25:0 a. q055al30:00 OR -, .,01 -206. A, 3340:00 1/1g .• !q d,, 06 zQ4g.i.9 '. ,45:00 ] ,P. (e2a /n • -2-!!h2 --2,• ! , ,q4 715&-0L!,• 4,_5"50:00 tgm I m. , 15,3,L a53 Q.q ;1-•z7,,55:00 il, am- a5// 9 -.zl . 7,. . /,60o00 ii, , iq.nja. --Z5 72,;2 , 7,a -Ib9,c L.0 O65:00 q -,- -7 /) ivýeva I , 7L ]-/I*'D 1,IZ3-970:00 It7, -- ' aL zo.L IZL.4 i, 7175:00 11,,•g iT7,n i.5"I.I J ;2 7V , 7, .1/ .-t7R,5 1,0680i~o "]l-70 jv"/.L - 15,,Vb a.q-,I a,T7q .7,-I..-•], ,.'80:00 .4 I7e _ 1gq a,-85:00 1, ..... /10 XS. Q W6-',76,0 1 ',S.95:00 j/. o65¾ "/.-/. 1•-7-.7,, /

100:00 A L2- .14,9 A'/,IN, J-5-,60 a._WE 3,0 zal -4•9'gA,./ &105:00 i, t7-h,•,.. '1/ 4517 A,.69 7.; 2 ,110:00 ,-7 /9 8 7 3,415,/ ,;1-al3 106110:00 ts I6120-00 !f1g 7,6A/ l// l -•I C•q . ,ý. 1-1"=,o. IJ -r,•,.i•

Sampling Tune: /'7- /O'5$


5 6 4'~A1L

Notes;(1) - Do not tru-un, depth to bottom of wen until after purging ard atrnpLring to ndour re-punding fires that ray be restig on the weo bonom(2) -Stabiizaton criteria based .o three most recent consrcutive rsea•-reOets.(3) - Total drowdocs hc sot to be [ec thao 0 1 (032 it) Prging rate to be lowered aso rcenary to keep drawdow- below1 aT m (032 f)(4) -/- 10/ whecn turbidity it ocre 1O NTU.

SSite Name: DcYLow-Flow Groundwater Sampling Form

we~ila "rw l -L, - c.o a- 0,•"

Date: C4 Ia-7 -...Sampl- Personnel: Mn tia t-4tr.zcA-c(Jc

Weather Cond ti9gx .JTimne:~4/IsfFile Name: DA M;-P

Deth to Water (D.T.W: , Well Diameter: "Total Volume Purged: . Casing Type: PPurge Rate: /Ur AX Sampling Device: tf1Tubing Type: j)* fý04k_._ Measurinj Point: 7 t + 12 Vj2-Pump Intake (ft below .P.): 7 - / color: ,/ 0 odor: . .,

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) X.) (uS/cm) (mg/L) 'std units mV NIU

Stabalization (see note +1- +1- +1- +1- +1- 4/-

Criteria5 -eow), 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 1•_____ ..,AQ./l.2• 0 0,61 6,17 . 6,5:00 i_,4 -6 qAllL!;' 4 1. 7/4.-, C/ Z,"-4 3• I V/0

10:00 J•/sk 3 / A/_ 3, . " .7;3 ,,15:00 /" /A'Z, 11.30 -eijaj,08 A,7i:A-.340M , .t•&,20:00 ;q, " t A-'- 3 •r!-C - 6, -72 ,-S/.9_ _,_

25:00 _,2 _q /Z~ 4q Iiica( le2 11~30:00 n4,{o . l3 fm S,4o1," -735:00 J1 -53 ,Q0 /6,701117,00 /,.27 ,7,2 -:;. e,,

40:00 a Y, q y P!.e' -l/, - -be7. 65(a d . 3,', 7. 4,,02 34. 1 q JAI?'45:00 ,n34A'- I,67,-/t•.. 7.3•¢ 350:00 6,77o• , /%30 N73&00 67-.Z.65:00- 7 1 L i'65:00 l .--70:00 95 A-O W1460d S -,R L,, tZ5-O

7amp 00 Colcted Anlss euse d:- Preserva3ý tive Holin me I-,,77 -b , -c 0

80:00 r;/4 etIIA412 iZjf I1~ W7Z f-5- -- 6/i_385:00 !J•,,6 V-•/4- . k. b7,36 S2

95:00 -5-•6 A5 •. 7e ; 47 .. a 94..5100:00 AM A1htJ--6 / -14,M l-7 1,74 ---M "k105:00 It 0 S14 /12~I &s, 3 72 1-7.

115:00 01.(~~'YO__

Sampling lime: /9L10 -/5CO•


-s~ee46ky

II

U~

Notes:(3)- Do rot oeasure depth to bottom of well utol after purging ad sxatpling to reduce -pending frees that my be teeting or the well bottom(2) S-abilisassto riteria based -o three .-at rec-st rsnertie -ete reemens.(3). Total drawdo- . well to be les thos 51 oI (0.32 ftt Pinging rate to be lowered as nee ry to keep drawdowno below 0 1 m (0.32 it).(4) +/- IM., when rerbidity is oer 10 Nfl)s

Site Name- D)6hI-r. b;cst[ow-F low Groundwater Sampling Form

Well ID: rn i )- jo;:)-(.Date: q ID7/-710-Sampling P~ersonnel.- O2. Laf %bk ( iojYan'. 1 i )Weather Conditions: b-':

File Name: lO.C(

Total Depth (T.D.): scr., r 9:Depth to Water (D.T.W): (1 POW" Well Diameter:Total Volume Purged: '4 v Casing Type:Purge Rate: Samplmg Device:Tubing Type: I Measuring Point:Pump Intake (ft below M.P.): color: odor.


Stabalization (see note +/- +1- +/- +1- +/- +/-Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%,

0:00 < /7 .;, / I 72M 6 5 7 - , ,

5:00 & MI ,Y to_10:00 10 2_0__4Z, 0

20:00 ,,6 725:00 7_&__*Y,.30:00 , /9 1_3_ 7 .7 _ , ,35:00 -as

40:00 Ok o -77 /045:00 -;?,30o /2P7.z.l2 13, 100 Y,& 4,79' -349, A,•/ f,450:00 ~3h 9;6 q & ___i55:0060:0065:0070:0075:0080:0085:0090:0095:00

100:00105:00110:00115:00120:00

Sampling Iime: /qqo -


~4A1A~$

Notms(1) Doe nor -me depth to bOom ofwlt unfit after puroge and sarplingt a mduee nnasprrrding fino that? ay be mafbr on the well bottom(2) -Stabil~izatoncriteria bavd Z hnrr moal -t .1,~o e me. .eOmrb.(3) -Toaaldrawdomn in l toI kw tmmban0 m (03

2 (t), P.'0oýg r,. tobe loweemd~ - y to k..pdrmdow belaow0. m (032 f)

(4) /1* I0% mhe. ourbidhly it over 10 NflJ

aSite Name- _.A// /1 ±.ŽL ow-Flow Groundwater Sampling Form

Well ID: 17/-9U lio'Date: 21/ý 7Sampling Personnel: 01Ž 4&L7&6 z"~,vt C (. ZT~cWeather Conditions. 1'7 V4ý -9-igTime: 09b•3- i1&05 -61File Name: .b/ 3A4/

Iotal Depth (I.D.): - Scr g8th,- :-5Ž. 7.Depth to Watei (D.T.W): '; [ )7C! Well Diametei.Total Volume Purged:$ie3d- Casing Type: (2Purge Rate: /7 ' Sampling Device: fr ,A,5 .e Jo7eTubing Type: j44,4 . Measuring Point "•- 1- '745 A .1FPump Intake (ft below M.PVf: ,ý 7..' color: ý#-#tp odor: nt.d.

Time: DTW: Comments: Temp SpC "DO pH ORP Turb(min) (feet) (*) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note +. +I- +- +I- +/- +1.CruteiaZ below)' 3% 3% 10% 0.1 unit 10 mV 10%

0:00 43lJ'i~ tiq'6 2 -iz e. C)T a &;5:00 -f 17,fh0P N4-7 ~ At5'f 6 i MF. /I-//5 I

10:00 jjý75 -O~ ~7,6 -)d 'd. 0 ~ 4(015:00 J,52 Iko~ 4%.0f25$ ~ ,t~ ~3~25:00 i7-,x. -I -,Ž/ -S.:...,- /93 x t.7 ,.-5- zo1/ .7' cq . 1!3 r I30:00 17, - - W Y i7 , = 255h4 1, I -Q.6- 3240

40:00 J 37. ui. i -JL= I..__t___4-V i o34:00 j7-5,9 -7 g rZl ,4,,7 _ q7 2,-51-3 /,6.0 7&5

350:00 *j. ii 2A& U t Aq ~550" 7rIvt, 2•L2 .Le/ AV" --Z•. IZ-.?40:00 tT7 jS- i 74V•I41 ,-6Y" 1,.. .,q r"45:00 ,. 7 -7 ir¢,. 3., L ' 7,•-- •f 13,4&

70:00 i7,sZ$ - 7" L' f L! /RI /. 6-3 T 713 Z

50:00 QQ5 I~217 4 'i .ii-3 -4V-7- 1i~.73 -2 a'5 7KI 1__4__1

60:00 17,51__. _ _, _ _ i,•_ _ _ ?, L'79 -7.6L - , , "

65:00 171--.. hldt -'T ti.Y!O., 24S6'& 1,qt~ '•. M ,• - 70.5 -1 ,Q V ;,Y

10:00 i a7,56_ i7ZI__,_._. iY,76 ___ 1._ 2 0f"- '-1 :__ 3 ?,•

105:00.

810:00 ?7 4 49

115:00

120:00

Sampling Time: i'.*~//Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:

rc .W A 7

Notes:(I) - Do not meosure depth to bottom ol well unil alter pýr•ing .n

4d tnpling to rede -e-uspndag 1me. that -yq be retng-on the -el I bottom.

(2) . Suobilirton criteria hued on three moi recent conecutive mnu•ureme OIS.(3) - Tote) 4ado. in well o be letos than 0 2 . (03

2 I) Pufgieg t. to be Ioow-ered . --ecesy to keep dr...doon below 1 m t032 Ill

(,) +/. 0I whn thbn jedi soer 10 N71U.1

Site Name: ._.(4Vi5 ),SjaL ow-Flow Groundwater Sampling Form

Well ID: MIAh - JW 2,•qDate: 104 107Sampling Perionndl: /f A~j',. L~~A/i~ &-4Weather Conditions: h, 7'z i. ;_ s4•a ,AJ/AL4 .-: 10-xTime: iclt3 1-5,91 V

File Name. -, t) 0i,'Iotal Depth (r.D.)Sc LSena•gth: I4Depth to Water (D.T.W): I 421..2 Well Diametei: .=."Total Volume Purged: _-,- . , C Casing Type:Purge Rate: / l 2 Sampling Device:

Pump Intake (ft balov lM.'.):rJ Li . • color: Cte-•g4 odor: - ,

Time: DTW: Comments: Temp SpC DO pH ORP Turbrn) (feet) CC) (uS/cm) (mg/L) std units mV NIU

Stabalization (see note +1- +1- +/- +/- +1- +-

Criteria.' below 3% 3% 10% 0.1 unit 10 mV 10%l

5:00 LL d. 4 R I ,L 7,c-'.2/,jA Lq.710:00 .. l..x, 7.3 •/ 2..,15:00 AOq• 41X/mc 21d_¢;•d ,., 2 -.?,z Y _, 117

20:00 p - -LŽ 1l 'Z __-~~~ 7.// ...^6n, a

25:00 [q t.3,sJv j,75" . , .!5 7, Z J3-i4 I-j -0-30:00 A10 i_2 -h/16 ,q,i9 • 6 •,Y 17,23 - ,35:00 4b.qL <2 1.•4, q "7 1 q-7 I 7,99' 1 7,1,9 .. /,"

55:00 ib,,/7 ,._-e~d,,, 2e./q ~€ - #'/ oq %Z•/X €7 /,6

45:00 y 17 O V. q-1,70:00 J4 " 1 /* 44__65:00 164 t7( A,.- j~80:00 ____ ___

85:0090:00 /'Rq I__95:00

100:00105:00110:00115:00120:00

Sampling lime: ,.. 5 2--Samples Collected: Analysis Requested: Preservative: Holding lime: Lab:

-rim. PJr.LAJ,•ii'3 -.O o"z P.- 1', ,w,,.•,t ,.4 jed

Notes:(1)- Do =ot Ieoasue dcpth to botorm oftwell ontil aftar porging and ootophig to -cd ,e respending Frees hat mey be resting on the tell bottom(2) - Stabiliotion cilteiA ae.-d as three mon recent co-- octcive meaootemeos(3) - Total drnodon in -oell to be les thin 0 a I (0 32 ft), Porgin, rare to h. loweerttd ot ootocry to keep dratodoto b 0 1 m h 0t32 ft)(4) 1/- 107' whon ourbidity t o4er IB SNMJT

aL ow-Flowt Groundwater Sampling Form

Date: A 11 0Sampling Personnel:Weather Conditions:

Time: DW C TFile Name. _ [> O -, ...

(otal Depth (I.D t): (C) (uScm 7m-/L uDepth to Watei (D.T.WM : Qii 6 ,S Well Diameter. OfZ

TotaliVolume Purged: + Casing Type: +1 +- , / +Purge Rate: -, -••-.Sampling Device 4l,;qg,, r 11"/'•l¢Tubing Tye .•, Measuring Point: :7•cl c) If -/ VOLI 'Pump Intake (ftbeloW•M.P.): •: ,•f color: odor:

"Timne: DTW: Comments: Temp SpC DO pH ORP Turb

(rmin) (feet)! ('Q (uS/-m) (rag/L) std units mV NTUStabalization (see note / +/- +/- +I- +/- +/- +/-

C0iteria. below)' 3% 3% 10% 0.1 unit 10 MV 10%,

0:00 -,a yo Z 13/73ýL el/lb -5175:00 i__,v_ g.Y_ -_•_ _.__3,z 14.9

25:00 7 ,eZ a , /k.,,., I€•2 i#kZ1 LLZ z,,L -ii:•Ž I•.

30:00 ____ __ ___ 1j,7 1(ztcC •.' z;;O 4%.,6 5",•35:0o •/.4 4 ___ _ •~

40:00 ftid *1 __-__ .___ -

45:00 ___&__50:0055:00 7e, filoI'db_ _____

60:0065:00 ;.,L, a_9c .1_30:00 47 _______ 0v__1 kF

75:00 A A_1___80:0085:0090:00

95:00 ________________ ___

105:00110:00115:00

820:00

Sampling lieced: Anlss- -

Sape olctd nlssReq~uested: Preservative: Holding lime: Lab:

Notess

(1) -- Dto not mcsusore depth to hottom of weoO utstt aftet porging and tasamlog to teduce oetoopeodiog toot thot ott, ho teoting Ott ho weti botomoc(2) - Stanilization criteria hosed ott three most reocett consecutive teasureotents.(3)- Iotsl drossdossts itt sweP to ho foo than 0.1 to (0 32 It) Puoghog rit• to ho scowred 's ssccreowcryo heep sferwotwfo• hbeow (51 t (i.32 it)

(4) *-tI 0(5i whnit turbdshity ft over 10 N'TUt

j~

9

SiteName:. Th"Is- 'ýf3S-lLow-jlow Groundwater Sampling Form

Well ID:-IZIf2Date: ' I I .Sampling Personnel: ,-It -a Iv' (tý_~A QJA

Weather Conditions: Mon•Time: O~.5-~) ,:,

File Name: -0 toirC

Total.Depth (I.D.): J..7 ' z%" n: 6-Depth to Water (D.T.W): M /g'p YO' Well Diameter: o 2,Total Volume Purged: Casing Type:Purge Rate: • ,. ./ j , -Sampling Device: j r/ .••: ,Y ,

Tubing Type: Measuring Point: ',OPmnp Intake (ftbeloMYM.o•2U , / color: odor: .,

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) Xc) (uS/cm) (mg/L). std units mV NTU

Stabalization (see note +!- .1- +I- *+I +I- +I-Criteria' below)' 3% 3% 20% 0.1 unit 10 mV 10%,

5:00 1i1 d,- " 7 Z .f f,50:00 /,1_ ; ll,,. , &) 4•o(' ,1i-/ .6".0F 6,9Y., 7k~gi,o0

10:00 =; xuizfZ91~S qb 29y Y1ý15:00 i,L~L 1~4~ /.tL _A9/ 'OS/ ý2_5420:00 13,i2 .. / kr_, I i•/Z . ",/1 1.,,?9 -f-1 a25:00 fi $f -

30:00 /3EZUAZ/Zs ,7i? 4.L~ i3 MYI &? t1. 035:00 M-100 ;!/ 7/ 7S YZ #J&'~o40:00 m / A1WIP__M_2_951____L, V.645:00 1Y.13 _,-1 iA ,o ,9s .1/,9750:00 3,17 , .- ,- !,,1,o A ..55:00 -41, 11 - __79. r 6_, ,60: 1 ,/./! ,S7 1g,15,65o 2,3 Q •// , '/,5? ___•/&,,& ]a, ~95:0070:00 ___._M_

75:0010:0085:00

100:00105:0011I0:00

115:00120:00

Sampin, Time: '(00 1,V1Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:

• . : ': .. ..

Notes:(1)-D . nort otnoonre dept~h to bonhor ot eonellsunt)] ahter purgiotg aend osepltirg to reduce r ensspetelieg titso.s that snay he renting on the owel) bottom.

(2),- Stohiiotion cirenia based on three rcns recent connecotine re-ast.oote eot.(3) -, ohtdr as doaonio e elitot be n er the 0- e (O32tt) P0 . we t obe neoweieds en0y to keepde -aedoeoobeoo wfl r ,

0. ,

2 O t)(4).÷!-10 wO.hen enhisit1y is osee tO (dThe

Site Name: -f .B ECLow-Flow Groundwater Sampling Form

Well Ia.D 790EDate: W&ro"Samplink ersonniel: XL.te49 (WeatherConditions: 6 -4••el .Time: 1049•- fi,'74File Name: L•• 9/,••..6Total Depth (I.D.) Scee Le-th

Depth to Water (D.T.W): m /1., Well Diameter:Total Volume Pur ed: 0, 4-A.Z. Casing Tye: 1O/c.Tubing Type'. kýý•_".•,'rYAY€/1-.ttL•- Measuring Poin 00 Ir lf[

Ti-me: DTW: Comments: Temp iSpC, DO pH ORP [ Turb

(mn) _feet) (I) (uS/cm) (mg/L) std units mV NIUStabalization Isee note +I- +/- +/- +/- +1- +/-

Criterlia' below)'

3% 3% 10% 0.1 unit 10 mV 10%,

1:00 A -7. /D,. 7,9V -, ' - , .-5-05:00 AA07 ,l-.60' -l,4t. ti• 2 Y541 --/,_7z _-_ 3,_ -a_10:00 1,,, a_./Z ,. 4, f€ 7 M

15:00 ?..5IV,.-' 4 9,07 l"d - , 0

25:00 _____0 i'i 07 10// IWI& 1 330:00 i&o42 2 , i-/1 '/ g., 7/ 7-. .35:00 20,16 9_a__/__ I V,__ _2_41.67. q, f.Y -7, /9•?-/ , "M

405:00 ddg___ ____________ ___ '7. ,? 7,I A-19

45o.00 aa a -•-a /,..,Vf,'TV q,-Q# -7, // .•, '9055:00 iaff ; //9•l/• 7¥/ R 17 , 71 -7,05? -,&,•r7ag60:0065:0070:0075-.0080.0085:0090:0095:00

100:00 t.. ..

105:00110:00115:00120-.00

Sampling Time: 1/1/ i1141


/tfw- tO'k 0.W ~ tvi d~,

5,4&14*6

Note-~(1) -Do rot me-ooo depthi tobottoo of wroo orltil ofter poorgl0 adoomolig to tocior roooopondio5 k frthat o=y o tbe elioga hoý roet bftto(2)- S~tAiiotioo oritofo booed othrotmot octotcosoobntoOw ttoýf..3)-_ Totoldawcdocon lowel e Veto Coo 0 o(032 Vt). Poogirtg 00 lo be lo-roeod oooooocoy Cop dmwrdowbelowCL 01 t 12 ft).(4)4 lýfr 10-= n teridity b, -oo 10 Nr~lo 9

--....CA~k:~-~iA;.~----. -

Site Name: "' a% IL ow-Flow Groundwater Sampling Form

Well ID: M tz) - V) W rý_Date: Q1-:0 C? cIL'7.. i • • Iv A ml L • • •

Sampling PWsonnelý V,. 6deMh ffk3,-jOL/-jRj (4Weather Conditions:

Tune: 1/26cf L.ý, ý D i::4 !L * J,1410File Name: n j-fl/C

Iotal Depth (T.D.): 2Zd? Screen Length7 -

Depth to Water (D.T.W): ~ 3~Well Diameter: 5JTotalVolume Purged:A d.j Casing Type: ,

Purg eRate: I ~ -Sam uIn Device:fe&rg k

Tubing Te: nT- Measuin Point Ta0 -F ;0 VCPump Intake (ft bel w M.5.: color: odor: o,

Time: DTW: Comments: Temp SpC DO pH ORP Turb(mi). (feet) (MC) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +/- +1- +1- +/- +/- 44-

Criteria' below)' 3% 3% 10% 0.1 unit 10 mV 10%4

0:00 4EA ,/SW P t;q4P7 7,K -6.7", 7 F, d5:00 1,A,.9 5, 62, YN ?,e, - 7. 97 -710, t

10:00 ý I_4,_"15:00 VIP'> J1a.5W -/AL-Z __- 16-, 27 -,7,• A ___ý 520:00 7,0 , ,., Z7-9 -•0 -Vo.l,25:00 _5,6'3 ,O ,-[.1 7.-R' -XS, 55, (o30:00 & /,',/7W . i7, -• Y -_7,a4 -_ b 6-6,!35:00 _37,791 /,-- 7,/1f -041M 4,,040:00 0Y -a-4 -7671 74.-45:00 7"9'q; Y,

55:00 ,t .ifEYq533: -

650:00 . 6,71 4_5& 6//7 7,/Y---QO -7,1

65:.00 q/1Y, /, 490_/,u 14,1176 Y/N4 00 -,71 1, /- Y91,d .9 Y"60:00 11?wt i 4,,79 7, -Ie ,75:00 __ lU/v 71__~ LK-A/ 280:00 1i3,71;2z,9 w22 -fQw, i9 1,85:00 3;_11 1aelO , il, 7 ;27 -7.,z 0. -7'h 290:00 A 1-5'0 i1m/.Liqo -,c 5 7, Ai -7-, 2, z-L95:00 1 -__ _61-41 n/C 3 1 7dlOO:OO 4t•-#<•le/)l•,Ztft• U b l•qjj &.,T7a .7. g -7a.54•,.

105-00 17•, t30D nMjjot.) i,&bvA,o 250 • o,,kg ., • -7, a 36,9t110:00 -7,

12o:000 . /, . ,a//o ,,a -,,7-70/ ,;


rnu}-iig

/

Notes:(1):Do. Io oooodpl ob~n ~'f p-&g,0M m ~pttmgt.,,-4 '--pe,'ttgfxnt thal ay be roioong -the aell boltorm(2)- tbtzto atrobsdo be o5tnn osctn eaonon(3) -2nnt~lderonoo x. nelw obe etathan01 o(032f4a boogitra5 ao obe iowered noatonseymtokep taoaaonaoelono ( to(032tt).(4) ./. 102. noto toatdity i, oct 10 NTtUo

Site Name: ~ls21E-sqLoaw-Flow Groundwater Sampling Form

Wel HiD.: -- I ADate: 1-12JO-7Samp!Mn ersonel: C, . yjWeather Conditions: 5d e ký.Time: 1014, /,7 / ý

To tal Depth (I.D.): R• 7,61 , , S~cr een : enth

Purge Rate: z•. fv(./l •Sampling Device: "I •-_jr. ,b

Tubing Type: M QXIA 0 , .?'*e N[easu i•Point:• O IQ•. ia~ k c

Pump Intake (.tbeloOM..).• a. '6 color. odor: '/rt , Y4 f.j~to,,a

Time: DTW: Comments: Temp SpC DO pH ORP Turb(min) (feet) (tC) (uS/cm) (mg/L) std units mV NTU

Stabalization (see note +I- +/- +/- +/- +/- +/-

C-iteria' below)r 3% 3% 10% 0.1 unit 10 mV 10%'

0:00 _

5:00 P7___10: 00 1 90 1AV,8 /' 1, aL, { *0; 7 ,J'• R~ 75,-.:-:& 6.

15:00 3 v/Z ., 90?, (A20:00 -1 ,24 I, Pe) 0to • /m •• gz.,. ! --9~ ,. -.2 X.• ,q $ 41ý519 i? ,1

1500020:00 .l, .

25.00 144u, jZ750,IZ3 j/7 AJL ____

40:00 / • 1. q, 2431. 07 In A &. Z1,7

45:00 1 -;zi .,xO hný &-x 4 ,7V L,,ql-Y/,0 /1, q45:00 .1,3 ;?. / ;411 1,,,Y , -q//J _

55.L0 0 jql Iq i,. ,60:00 1. a ,,,, -7 2- -4 f-, q_565:00 19 -;oA 2a/Wt/0& -Z .,17 2J(1 /I'_A_ /770:00 yo 51 ._3171 AL , b,Y -3 A,5-75: 00 /:. -4 ý 2 w s u • •,, l . . • o i, 5 • .¢ - ,a , /-I n

80:00 I3,.C) 0 Y 4q41 -I2b.0

95:00 1j,3 " -/ 1-A2.L 9 F - SY./-__90:00 _,3 1-.2 q3-I ý J.-7t b95o:00 1g37 PA'- t/••, Al,•' 4, T V3? i, 5 .17 5,q -! al - "

100:00 J LL.i S 3 /3 /

105:.00 3,; .'49. ,d;ll& -'475! t,_ ,110:00 134 pl/7- :

120 00j, ;Z.:,1 T"T' j

Samplinglime:W'/; /Samples Collected: Analysis Requested: Preservative: Holding Time: Lab:

Notes:(1)- Do sto-re depth to s b otin f wel o,• laft~or lugir and sampfing bo red une rmsesd•itg fmo thia ouyte restin on the well botton,(2) .Stainbo•staiter•iabasd on three tosot o.ce•ol ooe•otise ,eo.osemnmt.(3) -To ol d wt too -1 tobe h1.t th.. 0 1 . (0.32 ft). P.rgg r.a.e o be n•e- ed a. n--nboty to eeop drswdows below 0 1 o (0.2 It)..(4) .1- 10% when ithidity Is -ose 10 NTU.

S

0

Appendix DLaboratory Analytical Reports

S- ~ Environmental, Inc.

Midwest Laboratoryon Allg heny Technologies Co.

700 Landwehr Road " Northbrook, IL 60062-2310

ph. (847) 564-0700 - fax (847) 564-4517

Mr. Al Percival LABORATORY REPORT NO.: 8003-100-362FirstEnergy Corporation DATE: 07-10-07Mail Stop 1041 SAMPLES RECEIVED: 06-22-075501 North State Route 2 PURCHASE ORDER NO.:

Oak Harbor, Ohio 43449

Dear Mr. Percival

Enclosed are results of the analyses for tritium and gamma-emitting isotopes in five ground water samples,one matrix spike and one matrix spike duplicate.

Should you have any questions or other concerns, please do not hesitate to call.

Si ce ly,

S.A. Coorlim,

Quality Assurance

roi o, M. S.

SAMPLES RETAINED THIRTY DAYS AFTER ANALYSIS

Report: 8003-100-362Page 1 of 1

Table 1. Results of analyses for tritium and gamma-emitting isotopes in five ground water samples,matrix spike and matrix spike duplicate.

Sample Location MW-IS MW-ID MW-26S MW-26D MSO1-MW-26DDate Collected 06-12-07 06-12-07 6/13/2007 6/13/2007 6/13/2007Time Collected 10:49 13:09 10:17 13:13 13:13

Lab Code TXW-3910 TXW-391 1 TXW-3912 TXW-3913 TXW-3914 a

Isotope Concentration (pCi/L)

H-3 < 330 < 330 341 ± 101 < 330 5000 ±208

Mn-54 < 2.1 < 3.3 < 4.1 < 3.3 < 2.0Fe-59 < 6.4 < 6.2 < 9.0 < 6.1 < 4.1Co-58 < 3.1 < 2.7 < 5.7 < 3.1 < 2.3Co-60 < 3.1 < 2.3 < 3.1 < 2.5 < 3.5Zn-65 < 3.2 < 5.9 < 7.5 < 5.2 < 5.6Zr-Nb-95 < 2.5 < 3.4 < 5.9 < 3.8 < 2.9Cs-134 < 2.7 < 3.3 < 3.6 < 2.6 62.9 ± 4.5Cs-137 < 2.0 < 3.3 < 2.9 < 2.9 64.2 ± 6.9Ba-La-140 < 3.9 < 4.5 < 5.3 < 3.3 < 3.9

Sample Location ViSDO1-MW-26r MW-7SDate Collected 6/13/2007 06-13-07Time Collected 13:13 14:53

Lab Code TXW-3915 a TXW-3916


H-3 5055 ±209 426 ± 104

Mn-54 < 3.1 < 3.7Fe-59 < 6.1 < 5.7Co-58 < 2.9 < 2.0Co-60 < 1.4 < 2.7Zn-65 < 5.9 < 2.7Zr-Nb-95 < 6.3 < 4.3Cs-134 59.1 ± 4.5 < 2.9Cs-137 70.0 ± 6.9 < 3.5Ba-La-140 < 5.9 < 4.2

The error given is the probable counting error at the 95% confidence level.

Less than (<), value is based on a 4.66 sigma counting error for the background sample.

a Known spike activity (pCi/L): Cs-134.59.3 Cs-137.66.3 H-3, 5639

- - Environmental, inc.Midwest Laboratoryan Allegheny Technologies ro.

PRG-33Form LS-4 Vez. 10

TR1TLTMLSP-2000C-A []

LSP-2?550TRI/AB ELSP-2800TR S

Init. & CountDate: tb• t 06 /9 /07.0.10032- STPD T-36

BKG .BKG Sample STD TD - STD Date

Time Counts Time Time Counts Acbvity IssuedI (pci) _

qto i00 42o eLtGtIKOI1003.78 01/18/2001

Sainple EDi Volume Sample Remarks(nml) Counts

Z q ,0

G alt-j66__ 14 607C

__ ______ __ K_ ___ __ I0 0__ __

..-.;vv .- X.... k

Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.PRG-33Version No. 1.0 06/17/97Programmed by Rick Lesko

Sample Count Time (min.):

Background Count Time (rmin.):

Background Counts:

STRITIUM

RESULTS SHEETFor any sample counted on the LSP-2550TRI/AB,

LSP-2000CA or LSP-2800TR Reviewed and Approved by.2-ý

Date approved:

100

200

912

Standard Count Time (min.):

Standard Counts:

200

64469

0.205

Date Counted: 6/28/2007

Calculated by: Rick

Counter Efficiency: Date Calculated: 7/5/2007

Sample Coll. Vol. Sample Corr. pCi/L 3.00 4.66

ID. Date (ml) Counts Factor Sigma Sigma

TXW-3910 6/12/2007 13.0 495 0.998 66.176 + 91.250 91.693 108.702 168.851TXW-3911 6/12/2007 13.0 465 0.998 15.271 ± 89.337 89.361 108.702 168.851TXW-3912 6/13/2007 13.0 657 0.998 341.007 ± 100.941 111.085 108.685 168.825TXW-3913 6/13/2007 13.0 496 0.998 67.862 ± 91.299 91.764 108.685 .. 168.825TXW-3914 6/13/2007 13.0 447 0.998 -15.269 ± 88.156 88.180 108.685 168.825TXW-3915 6/13/2007 13.0 481 0.998 42.414 ± 90.348 90.532 108.685 168.825TXW-3916 6/13/2007 13.0 707 0.998 : 425.835 ± 103.754 118.823 108.685 168.825

1 =Best probable result.

--. , -Environmental, Inc.'Midwest Laboratoryan Alleghany TechnO1DgieS Co.

PRC-33Form LS-4 Ver. 10

*.0.10032g STD T-36

ThJTUMLSP-2000CA [-

LSP-2?5501TRI/AB 9

SLSP-2800TR [

Inlit. & Co~unt Date: PIfX2 M) (>/3 7/

BKG BKG Sample STD • STD DateTime Counts Time Time Counts Ac5vity Issued

_ (pCi)boo -7q_5-- 100 ©bO 1003.78 01/182001

Sample ID Volume Sample Remarks-(ml) Counts

&~.- 7JR~t~ ____ 4A-/• ýIPn_

____. ______ 2% __________ •

._.__________________._,_ % I ___________ ___,_____________-________,_-___.

_____________________________________________________________

_ _ _ _ _ 1 _ _ _ __ _ 1 _ _ _ _

•.; :..,.... .......

.-. ;...... Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.PRG-33Version No. 1.0 06/17/97Programmed by Rick Lesko


Background Count Time (min.):

Background Counts:

0TRITIUM

RESULTS SHEETFor any sample counted on the LSP-2550TRl/AB,

LSP-2000CA or LSP-2800TR

S

Reviewed and Approved by.

Date approved:

100

300

795


Standard Counts:

Counter Efficiency:

300

85421

0.182


Calculated by: Rick

Date Calculated: 7/5/2007

Sample Coll. Vol. Sample Corr. pCi/L 3.00 4.66ID. Date (ml) Counts Factor Activity Error T.P.U. Sigma Siga

TXW-3914 6/13/2007 13.0 2881 0.997 4999.840 ± 208.295 711.166 93.339 144.986TXW-3915 6/13/2007 13.0 2910 0.997 5055.267 ± 209.309 718.672 93.339 144.986

•" =Best probable result.

0EG&G ORTEC G V - I ( 175) WAN32 14W02.96 28-JUN-2007 15:39:30 PageEnvironmental Inc S nCpectrunm name. 17403. Ani

I1

Sa)Ample descriptionTXW--3916 3.5 LITER13-JUN--2007 Ii4 53 PMS

Spectrum Filenameg C:\Wser\17403.An1 -7Acnqu..tisition in formation

Start time,Live timeReal timeDead timeDetect or/Geo metry IDs

.840C,8417.13%

0~

Detector systemrMCB I Input :1.

Cal ibrat ionFi I ename: d I I. CIbCreated: 14-Mar-2007 13W36-4-9 & 20-Mar.-2007 13:52:52MG -23 Geometry #135 Lite-r water iTn MB.

Zero offsetQuadrat ic,

-I.980 keV; Gai rn.120E-,0'7 k qc a n l'

.501 eV / ch anne 1.

Library FilesMain analysis librtarygLibrary Match Wii dth:

Analysis pavr:ametersStart channel,Stop channel.P e a k rejection levelPeak search sensitivity:v

Sampl)e Size.Activity scaling factor

2.'-.. li b. 5 00i

120 for an energy of 58° 13keV4048 for an energy of [email protected]

30. 000%

3. 500I1,21 OE+06/( I .2 r]01 E+0 0-x +)0)

.2, 657 1E-+--15Detection limit method'

RI S HO methodc)Addi.tional randrc:)m error.1 .0@00080E+N211Additional systeSml-atic error: 1,,0000000El+00Fraction L.. i 0 i. t 2,990%Background width: best Iethod (..based on spectvnum.

Correct ionsDecay correct to dateDecay during acquisitionDe-.:cay dluring collectionPeaked background cor".rection

st at usYESYESNO

YES

13.S- Ju n -'200i,7 142•53:00

hkg.w -I. pbc-I

.l7 '" A i:r -::l'lr:@ I -ii ,.. l1: 1 :5

h.I! "

ll, ý. n CI 0 ii1 1-1 In III I. I I y I m k..

SOEG&6 ORTEC G V -- I ( 175) WAN32 14W •2.96 28-JUN--2007 15:39:30 Paqe 2EnT V 1 i T) Irnm en tal 1 Ci Sp [):..-t Iruli nam e• I 1 ,e2t7403, A-n1 1

Energy calibration normalized dif.ference:'o . 1125

***--'****-.- U N I D E N T I F I E D P E A K S U M M A R Y ********

PEAK CENFROID BAC•GROUND NET AREA EFF.IC I ENCY UNCERT FWHM SUSPECTEDCHANNEL. :-NERGY COUNTS COUNTS * AREA 2 SIGMA % Ik<eV NUCLIDEf-I ... +...b-"+ F -- -f - - + . .I. .-+ -- + -- -- -+. +-- --f - + -- ..... --- -+" --- + - -f-... .... I--" -...--1- 4'-"-"t--"+ . .. .... I,- -4 -- +-..--- +.... --++ - -" +-- --.+ -... +

706. 55 351.97,122, 0 10 609.,24

130.30i.

93. 7.4.6Z4.E03110. 1.275E4.4

55. 09 2.027 P9-214,2832 1.622 BI-214

sI::'De ak fails shape t e ; tstsD Peak area decoT-voloI .,ed

I D E N T I:

NUCLIDE PEAK CENa.R O IDCHANNEL ENERGY

F I E D PBACKG ROUND

COUNTS

E A KNET AREACOUJNTS

S. U. M IIl A R. Y, *******INTENSITY UNCERT FWWHICTS/SEC 2 SIGMA %/ keV

CE--144CE-. 14 11-131

O B A'" -- I --14 •1'

LA---1.401I -. 3 1

BE'-7LA- 140RU-103BA- 140CS- 134RU-103RUJ- 1 06

CI-.1 t211Z R-" --),..

-.,rJ .'i::-E.95C---l1 34ZI

CO0--- 5 8

MN-54FEL...--...

110-6

K--40

rD Peak

271 .•00.292.0Z9571.3,:'5--E, 14. 9.-4

C-,C-'l0 17.177-..30. Q7177960,,45976.0

993'. 85

31,-[1 "'3• :

107, . 71

1 244. 0912 E72.:, 001332. 05

L.5 1 , 3-81536... 71

.1. 2 5 ! 3. L1;?

I'' ".i I. -112

166L,1.35"

234. 00'-577-99,2.6E2:,:. 0 5

7120 35

133. 781 44, 34284.24z!2546 L8

2 8 6 S,3,CS3,. 7 5

4. 79,1. "7'486. 96

5-38. 1L5

604. 02.,1

621. 26635.2;F5

7 •57. 2-3,." 4,"0

7 (7.8617 9 0, 6C

8 .. 0, 26830. 30

1115, ') 'i.i'

1 1. 1. 1 "1170 .8,1

1331.6!46t. 0 C.

15 (7-, :1. 7

7.93320

E9.

5a.50'.

37.

it.

30,35.32.

32.7.a.

23,,

6,20

7.,

3.

11.

12.

0.71.

3.1

5.

15.

7.

54,,

1.9.

52.

5.1,

0,

.000

.00817210 0200000•4

00 11201.

000

0014"QI0 310012

(1310 13

.003

00 1..

2101

080012,71.17.10'.•

.0 1.".2.I

12001

:1 777. 641125. 36F,74,, 5412 2. 8432. 60191. 56176. 1120800 00309. 191402.55

9.05

269.321

12 1. 01.565.69SI1.1. ii.69,, 12

4LIM. 90161,1::.,, :12-1''

6oo. 00103.02184. 7:34E., 41:I

1 7.81187.,08C15....,::,,73

. 71200. D1

7835

1.31.4443s566s

1. 0124s

467s.740s

1. 8451. 822D

.646s

.000s423s.751 s

9"725s

501 s,

1 .046s

1. 00. 2s.000s501s

:1. 549s000S

f a i I. s h a Up es t ... S .tare' a A ,oSF1 '-- 1 ,.1t: e :.

0EG&G ORTEC G V - I ( 175) WAN32 I4WO2.96 2B-JLUNJ-E:0117 15:39-30 PacoeEnvironmernta.l Inc Spectrum name: 17403, PnI

... *- S U M M A R Y 0 F N U C L I 1 E 3 I NTIME OF COUNT TIME CORRECTED UNCERTAINTY

NUCLIDE ACTIVITY ACTI VITY COUNTING

P S P L. E9 1 I G M A"

-- * * * ..

BE-7K-4121MN--54FE-59C0-58CD-SOZZ 1\1-- E,5

ZR-95N.,1B-95RU- 103RIU-1 616

--131CS- 134CS-137BA.-. 140LA- 140CE-- 1 41CE- 144

2. 8662E+017. 70137E.+013. 5681 E+004,5100E+001., 764SE+X100

. 1 7 1 4+ 0 624. 01 7SE+0Z023. "121 E+002"0927E+00-. 0885E+01.

3.3945E+00

3. 494•9E.1-0

9. B,193E:+00

1. 9567E+01

pCi/L I TER

W° 482BE-Z1..1% 70137E+0 1:1; 68 8 4E'IIIIW&. 6884E+002,5 64261+00

'47 13 E66.0Q. 7304E+00

1". 3154E+00'-" 0257E+0(113° 176SE+01

1.2339E+012%8570E+002, 4982E:-002. 1. 651 !--01.4,. 1761E+00

10. 914E+01

p C :i / L I TE R

0

( Ih1)f•. v .a u e l:)r i n t e ,A Activity printed, but acti'vity ( MDA,

........... . ... -.. ................. S i I P R Y ........... ....

TOTAI. ACPTTIVTY C 53. 1 to 2026. 1 keV) 0. 0a210000010E+00 pCi/LITEIROT"AL DECAYEO ACTI'VIIT]Y ( 58. 1 to 260.62. 1 k e V 1 ) 0. 0001700ZE"--06 0 pi Ci/LITER

.********* 1 LJ U M N.- R Y 0 F D 1 9 C A R D E ) P E A K SI:t.:r2- 5,4 CE .-. 144 145.44 & CE--141 834. 30 %,, I. 1 304.834 BA-- 140328.76 L L.A-.140 364.48 % 1-1.3:1 477.61 & BE-7 487.02 % L.A-.L.0497,.8 RU-1.3 537.3 % BA'-140 610.33 & RU,103 .,I1I. % 1t-- OG',

636.97 1 -131. 661.- 6EI & CS-137 72418. :1 , 2 )R.-.95 75EC-! % Z R-.95765.79 NB-95 795.84 % CS-134 810.77 % CO-58 834. 8/4 & tN%--54

1.099.25 % FE---59 1115. 55 % ZN--65 1173. 24 g CC -60 1291.610 & FE-6591332. 50" % O.-60 '4:a0 . .. , 81 % W--.420 159 I. 1B % : .40

.-Peak is part of a .tiplet- and this area wentn ega.,.-•ti:.v e d~luri ngD d ec:-o nv ,1.ut i ,.n.

e -- a..k :i s to(:) n arI -'OV4.SPeak s " u wide at FW'51:,, bEmt ok at F.H.M,

% ... F.:eak 'fails sensitivity tesi.t.$ .....: l.- 1i nt if ie , bLu.t first ot e I- of i n.c. itdhe

f ail. ]. o e d ;" or more qc: u&a I fi" i cati :i. o ' ; e "ts.- Peak. activity hi g h t L harn count i ng ',rcorta . et 'a r,.o,

EG&G; ORTFEC B~ V - .1 ( 17 WAN32 4 4102.96 0 ) 2--jUL.--:20'I7 14:36:2 0'Pae~ 1.

Samplce diescriptio

F X W I t_ 1 3 iT5 T

Sp ct u F-ilIT' a-'k A,

DteXt ~c'tor'/G~eometry !Ds; I

aI . E: 5

CEP I inputI 1

Cr e t ed .Li n-MiT aHrji E2l:T1. 13:6 4 & Ma ;- ?!0

M C-3 11-5!3 ".3~'r e! 0 mie I.- ;, :2_5'' I'S it wzt el in M

Zero offset:

QuIa dra~t ic

-1.980i k eV Gain 13 Ma ~ keY/chnn

Main l'' Jibrary

PI)o s p3 iar iam te-

Strt channel,

Sto channel

Pek e jecstion 1level:Pea s* earTch sensrC it ivity:;I

Sampl.e Siz,Ac ivi''tye scaling faciV..tor

. 5•1. •

1201 fcv-' anf Eon:r g 121 L fa'41/ ` - 1') 4 C 0 "ne g " f f

-11 1 -n n 2iF -1. ;C

3.. 500G3.5@1IOO2Ei+00)

Bakron wWLEEIEJ'~Iidth best method (baedi:v an spectir'iio

Peke backgro '~lun co rr ecti4:1on

SI r ;~'' i:v c ;I iIS/ r 2 25 C / iIi i .V

St atl- u s

'I

Y ES

N7 C

.' J1T 1 z'52; .1. "'D 1 "eI2

Mg I. I//,

NOC]N..O

EG&G ORTEC 13 V - I ( 175) WIAN,32 14W@2. 96 02-JUL--207 .436:2 PageEnvironmental Inc Spectrum name- 17+13 An1

2

0Energy c alibr'ation normalized difference: . 0913

****.-'.,.'**U N \ D E N T I F I E DPEAK CENTROID BACKGRILJrND NET AREOA

CHANINEL. Eh!FE'RGY COUNTS U:CLINTS

P E A KEFF IC I ENCY

* AREA

U M M A RUNCET FWHM

r-SIGMA1 % keNtSULSPECTED

NUClI IDEf- -f f- -f-+ +- -+-+-+-+ +- -+-f + + f- -f f- - - 1 -

1, 140. 5. ., 9. 7_1 .00. 1. 106E-.-04 40.. SB ,, 2. 027 PA -3-.4

s Peak fai 1. shape t e;tS1) Peak area. deconvoluted.

"::**** -:÷**** I D E N T 1

NUCLIDE PEAK CENTROIDCHAWNNEL ENERGY

F I E DBACKGROUNDF

COUNT S

P E P KNET AREACO U NT"S

S U 11 M P R Y ****..-,,--I N'ENS ITY ULCERT FW H1MC S-.', EC ii:::! SIDGMA % k..e

CE- 144CE- 14.

1-131BA- 140

LA- 1401-131WB-7L A-14

RU-103,A-140

CS- 134

RU- 103RU-1061-131

u.r, . 3: -- [,

MB-95

CS-13 I.4

ZN--54

FE..-59CO0-60FF

K --40D. I,

S[3 'ea[:

27 .00294. 41571 1 0060"7.00

662 487,31. 56955.799"75.72

!2 It 03

1222. 271241 •671272.',,21

13 24',; ,4314 5 Q;L 120.1513. 941535.75

1592..26

1624.9:: 3 9.S668. 71

22~i:00.53D.2;-26,. 16234.7. 79L2F*8&,. (" 5

;: 2 Cz; . - 1292 .3031 C)1.,.C2

1:34.,28! 45. 50

28 It.. 0730-2..! 0329. 8936 4. 5

4i'7C.6. 834.86. BE!496. 7853'8° 56

6S10. 33620.0.5635. ,, 35

661. 51724. 42756. 4E76'7.3,8795. 0:3812 ;:.: 068'33. 99

11•00.,43

1113.27! 1.74. 21.

12:90. 87

,.-i'-:3. , 9,41

140.22.'•9.

58.

116.9& ,

169.

106.

48.

90.,52.

6.1.

137,63.53.

10.

11.:t :: .

1.6.

5'7.12.

F.

594,14.

7,597.

i.-,16.28

454.14.

7.

6.

5E,.

1I. 5.

001... 00

001.001,,006."

00-:

,,1823

.004

QKZI 0

8008003:

0012(J63

001

0:81

001

02602H1

3,3. 39523'. 15304. 14.4,41. 70235.70

58

117'. ,87

99. 57204. 77

213;-i--o 7 7

.51.i,., 6,

117.22;2 1. 57 2'

' 5 B '

1.35, F!. 7

7 G";.6

.000s761'5 s

e 44s1. 4 6

8000sI.45D

1. 848D7 23 s

i.9s

.1.97

01 S

5,'1 ,,

:1.927,,734s

:1. 9201'. s

7 .1. &

41Z 3391-'7" 6- , "

deic,- n ;ap .. te:.,se .,,U ' ,'z .T do o-, n (1 v' 1".V 1 ] , :;, e Ci

EG&G ORTEC G V -. I i 175) WA-N32 14W 0 2. 96 02:--.JUL.--2i007 14.36:02. G, P-aeE'n v 1 -on m, ntec,. 1 a I nc. Sp ecti'um name- 17413,A nI.0

**** S U M M A R Y 0 F N U C L ITIME OF COUNT TIME CORRECTED

NUCL..IDE ACTI V ITY ACTIVI TY

U El S I NUNCERTA t NGY

C;OUNT IING

S. A.: M'' P L. W2- , 1...I F * . * .

pCi/_ .TL TER pCi /LI TTER pC i L ITER

B E-7K- 40MN -54FE-59CO""58CO--60ZN-65ZR--95NB--95RU- i 01RU-.- 1,61-131CS- 131CS- 137BA-1 4,LA-. 1[ 4QC E.- 141C E-144

A

I.

< 4,. 6663E+0ZI13. 0185E+02

S 3. 00@36E+004 4.= 55-••69-E+00

2. 4285E+0OO1 . 3740 (.E:+00~

4.1 E + 00

< '4. 3139E+00Z"4 429! E+00

,. ,s3. 294 5E+0 11 3. 951 .GE+00

5. 8056E+0 I1

S. 9929E+.0. :I< 1. 0558E+-0 I• 2..1.S I 14E +. 00

6. 5223E"E+00i 7-, 1•.2;-952E-:+0Z1

5S 9746E+0713.0185E+02&. 1330E+ (.71.

Q;, 1257E+012.9240E+001., 3.83,,4E,+OQI5.9273F.-E+00Z&@441.4E+00&. 2805E-+06" 1942E.÷-005.4414.5E+ 01.,2-. 0 06E+0.15 90Z79--E+01'7. 0013E'+0 1

S. 92:61E'+009. 7807E+00E'?, 437E+0 t

6. 067E-H-01

4Q =E-+006. 875E+00

Acrtfivity pr 1-inted, tut activ ity ( MDA..S ! M . i' l -: ! V

TOTAL ACTIVITY ( 58. 1 to 2026. I. keV) 4. 2983080E+02 pi./LITER

TO AL, I)ECAYED ACT'IVItTY ( . 15.1 to 2026. 1kV) 4.. 30e9.274,0E+02 p'i.L.]:TE F

328.76 &4-97.08 %636. 97 &8:10. 77 &

1[17,3.24 %

S U M 1CE- 144LA"- 140

RU- 1031-'131CO0-5 B:.::-60

A R Y 014,5.4.4364.4.8

724. 12.1 :.,. I +B3. 84 ~-

1291.

&

/"

%-

D I SCE.-.1 41

1-131B A- 14• 1

MN-54FE-.-59

C A R D E"284. 304•7'7.6.1.610. 33

1099. 251332.50"

D%/

%"%-

9"

&.

P E A::1- 131

BE-'-7

FIAl 1 3

Z [R'95F1 -59

'302.n 84 & BT-.!.404,B' 7'.~ 0;-- LPA-- 1 .4 r17

4-. 1. ,"- 4 1061

765 79 & N-.B--95111I.5.55 & ZN-65.

:1, 5 9 G :[8 & LA.-14

.Peak i part of a ml].tiplet and this area i entnega'trive during dec-onvolution.

'? - pe'at.( is too no.-._..-'r".C1" '.,@ - Peak :is too widle at F:'2N:S, WA ..,.I. ok at[ F'HV,4HM% Peak fails sen.itivity test,

$ Peak identif)i.ed: l,,, but fir-st" r.: iteak'.f t"i -uc d:failed one or more qualif~ication' test.Ls.

-+.•. Peak act ivit y h~i~gher ... than cou--t ing; un.:i:ra T'ty -angr-e,,

E~n V J. tr h M it =,I I nc S EýpeC't r UI! na m c- 3742,E-5, fAn 1

CIip I e de sc cmi ,T'XW L34 5 L.ITER1-3 -~ IJI .-.217i7 12 7:17 l1

0

Sect:rumr F i enam e C:\Lie "\ 37425.Ani

Live time 95011Real1 time 3512Deafd tim1 e .12%D:e t:ec.tor /Geomet ry IDs 3

5:1

DetectIor- systeMCB I1 Inrput 3

F~il enme: D3g I Cl U:Created:- 1 4--Ma--2)@7 1 4:21:31 & 1 4--Mar---5)7177 1.4,5 .42,MG 023 GEOMET~RY #I 13. 5 Liter in MBIl

Z..ero o)ffset: 110 liei I Gai( n .500)7 ke ch r 0Li bra~ry Fil1es

Min analys' eis; l.i bra--ysLibr.-zo-y 11..tt h W4idthi-

Peakc r eject io flelIvelI

Peak searc snitvityi:

Ac~ti1vit y scal-- 1ing factor

21:. 1 U

I 120 foran en ergyj of 59. 312IeV

40,6,8 for an)COeoj* of I2r4 173V'

307. 000217%

3. 5001!.@@@077E--06Z1/ ( 1 . 17301I0 E'- +I e1 -x-1 3. 5AI00E00

2. P, 57 1 E 0 5n, I - m i t II--* -mI) l et ld

RIS m ;i ei ŽthUodc

Addi t i on ' -Ta- I II er-rOV t 1.0000000/I71e~~'E-l-00tAd it o a nys.'*temat i.c error: 1.0000000l11I2i7E-+00717Fra tio L:im rit- . 0074

Baeckgrouv~-ndi wiLdths' best; method (e.! on sepcct-ruilr

.1)~~ t'

Deci q du ig : etjyý

Peke bacgrun correction1

NicYES--

Comments~.f~ 4

12 Ci.,....1

1 2 Z / "." A .1. Zi !

EG&G ORTEC ( V - I ( 175) WAN323 14W2. 96 02--LJL-2007 11g55:12 PageEnvironmental Inc Spectrum name: 37425.Ani

Energy calibration normal zeri :d differenc~e .,14 84

s**..***~*** U N I D E N T I F ! E DPEAK CENTROID BACKGROUND NET AREA

CHA!NNEL. ENERGY COUNTS COUNTS

P E A KEFFICIENCY

* AREA

S U I M A RUNCERT FWHA

2 SIGMA % keVSUSPECTED

NJUCL 1 DE

476,, 28137. 72

1213•. 0

238. 07568, 85609.39

180.67.6 1

171. 1. 001E+04105 1. 175E+04

47. 5. 559E+03

51. 9334. 365,4. G3it

1. 579 PBI-212.990 P4-234

1.3363 BI-214 )

s Peak fa il s shape tstS.D Pa;rek are deconvoluted.

*** i********** I D E N T INUCLIDE PEAK CENTROID

CHANNEL ENERGY

F I E D PBACKGROUND

COUNTS

E A KNET AREACOUNTS

S U M M A R Y *************INTENSITY UNCERT FWHMCTS/SEC 2: SIGMNrA % keV

....... i.- - +

CE- 144CE- 1411-131BA- 140LA-140il.E_ 7131

L.A- :L40RU- 103BA- 140

CS- 134RU- 103RU- 1061-13!rCS.o 137

Z R-9 5R N3-95

CS,-' ! 34.HF-5

k7-ý- 1 -4iF[--59Z~ 11. - S

L A 1

267. 00291.59

[email protected]

956. 1597.3.50991. SQ

1073-39

1209-''942:1220.681246.071271.98

132. 691/i,4*7. 0O151,3. 223:':1529o*711591-30

i2 1 o 196'1997. ,55

247.725

2.9 2 .. 7 2,•:.- 5 12',B. f-,7

(33.42145. 71285.66304.95327.65

363. ,j7478.054W6.72

495. B8

6!:04. 70610.3.362Z. 03S351 99661.35

723-51

795.67

1113..621173.68i;2.':1. 5 C

1460.93

110.385.153.

53.93.

its

53.

18.43.

198.51.

113.030 .65.

15.

5.9,.1

a.71.43.

11.

30.15.28.

0.

19.18.

1 9.

4.541.

0.

I 6.

,:440.7

11.

s.

13

.007

.005

001

.003

002

.31600

13002

.057

0 34 6

012) 1000

.000

02200W

501. 73176.39

1 7 5.2724G. n9

334 5.38141% 5848.53

236.99192. '97

8. 47

313, 93

10. 76600. 00123.,76

-11.

.1. 26 3160. .'00724. 19

24&. 37

177.95447.21:92,.26

157.08

500s;.781 s

.720s

. 5012s

1. 017G 37 s

.611Ts.583s,

1.333

.526s1. 3601D

00100

1.12181.576LsE

1. 4-46.167s.915s. 642F

1 ° 599

.535s.000s

i. 105s.458s.438s

.4,53s

s Pe, k f i1S a r. e., shape ,ests

E'C-o or• ORTEC s G V - 'I ( i.-.,5, I.4WO2;' 96 02-JUL-;'2007 11:55• 1 2 Pa e

S U M M A R Y 0 F N U C L _ I:D E S I NTIME OF COUNT TIME CORRErCm •- ICERT "IN'YY

NUICL I DJE ACT I V I TY ACT I V I TY COUNTI NG

S A M1 P L. E;..S."IG'°iA"

pCi /LITER

BE'-7K-40MN-. 54FEi-59•

CO- 58CO:-60

ZN-6,.5ZR- JNB'"95RU-" 10¢3RU L- 106 .:.

CG-.. 13

CS-. 137BA-I/+0W..¢- 14.0

CE-: 141CE-. !.44.

NP 7

2. 7357E+012. 93998E+021 1,94.6,8E+q00

( 3. 0231 E-t- 010< 1. 90370E+00•

( '34 El .7 F:, + 21.i 21, 5. 3479E-.'-'1

< 3. ":4661:.E+00

1 2. 0 1 212,OE+.,12 8. 99481:-+00t2 .2 3800E.+0 1

G. 9 35E+@'- IQ, 4169E+011.I 5411. E101•1 . 2800E+00

.{ 7,670 4,E.'+DD1 . 939SE1.0 1

:' A lu pl.i, nte~d.

p C i / L I TE R

3.47,/97SE+~.8

9*, 4..:998E+02;,01302E+00H.•

EN 2594E+00

2. 5005E-+071

5.64,28E.+00, 2525E+-2. 2.

2.9286E+0@4. ~IC:2OE-Fi21S

EN 4661E+01.2!. 0,36-E-S016.2 877E+016. 42E46E.I-O l

4.2+,94E>H2 :I12L 5708E+-0.I01.1475E+0I12n 02U9E+01

pC'i. I I TER

5. 714E+01

4.,, 539E+006. 946E-.'00

A Activ:ity prin. 'ted, but activity -. MDA." ............ S U -MAR Y ....... ..... . ......

TOTAL. nr I V TY ( 59.9 to 2024. 1 k e ) .4, 25_ 474•., 2-- pC i . : r5 pTOTAL DECAYED ACTI V : Y( 59. 9 to 2 4 " e V 4. 27106 1 W.Z' p .. /I T-- 3

.-."-. .--... :~S U M M A R Y 0: F D ! S C A R D E

.... 54 % C 145.44 % CE- [ ...o14.1 2 4328.::~ 76 & LA.'.-...4-0 3-64. 4.8 '% 1-.1.3.1 4.77.61,J497.017'8 & RU}-10 IZ-5:37.3;..2 "%' BA..,14-0Z 610•Z.332

636.97 & .-131 724.8 1% ZR-95 756.72810,, '% C :58 83.B,4 % MN-54 I.99.25

i 1.73.,24. % CO.-60 1291.60 % FE.-5'.1 13$32.50

13

D.

P E:

BE.--7

R*1 UI. 1 -1 'IZ R-95F" /I 5

L0--6

304. B4 % 13 A..-. 14 ;4- 21 7. 2•: % 1..R. 14.., 0S21. 2' '7 & I-J 1. 'j C'..765. 7 .& N .-9

t5 _y-.,, y---- _-'---.---

P I :is part of a i , ,t ai ti Ll Ar'i.:. a wen:;negati ve.- durJYing dec~on;voluttion.,

1-... . :, e +a k-' i : t o ,: -3 'Yow ,i ...Peak :is_ too wide at t::W2:5M, but ok at I:W'HM.

"% -.. P:eak. fai:ls s:e'nsitiv~ity test.

$ -. Pea!. ide t .tif'ied, but f:i st peak of thi.s n ,..idefa,::.ilIed on,':, e orY more Y , q u.alif':i c._at io n tes-••ts.-;

S- Peak: act:i.ity highe than counting unirc:taiT'ty rang]e.

O EG&G ORTEC G V - T ( 175) WAN32 14WO2.96 28-JUN-2007 35 35 D4 Pageron mvient al In c Spectr um name : 3741 F,- v1 I

I

Sample doecri pt ionTXW-3913 3•.5 LITER13-JUN-2007 13: 13* fMS

Spectrum Filename: C \U ser,\374IS. PiAnl

/ .-c)

Acquisition informationStart timeLive timeReal timeDead timeDetectorv//Geometry IDs

E-Jun-2007 13:.17:24-8251

°33%

0~

Deotect or systemMCB I Input 3

CalibrationFilename- D3g,. ClbCreated: 14-Mar-2007 :1421:31 &. 34-Mar--2007 14:50:43'M-1G #23 GEOMETRY l 1.3.5 Litei- in DB

Zero offset -. 110 keV; Gai nQuadratic -. 1250 7 4k- V / c h a n n e I "''.

Library FilesMain anal ys is s ibrary 2L.ib-braorry Match Wid dth:

.500 keV/channel.

5 l VI

Analysis parametersSt art channel.Stop channel.Peak rejection levelPeak search se'nsit ivity:Sampl e Siz ze.Activity scaling factor

1:l for an En erg y of4042 for an energy of

30.000%2024.09keV

3. 507 .1I. 0OO0E+06/( 1. 8000E+0010- 3,, 5800 0-00)

=2. 8?570E+05

Detection limit methodRISO met~hod

Additiona rand t i o n 0 )- '. Vdomi err)- or2 v,0 E+Additiona1 systematic error: 1i,0000000WiE+Fra ctio Limit: .000%Background width: best method (based on sp.:trueK

CorrectionsDecayd conrn reCt to date'

)a'r'eye during co llectiionPeaked backgraound cor'rect-ion

St at us

Y EF -,"NOC

0- V --.- i23'07 1 !4 3 04 4

~0EG&G ORTEC G V - I ( 175) WAN32 14W02.96 28B-JUN-2007 15:35:04 PageEnvi ronimenta;-il Inc Spectrui name- 37416. Ani

Energy calibration normalized difference:

****~i*****U NPEAK CENTROI D

CHANNEL ENERGY

1 C E N T I F I E DBACKGROUND NET AREA

COUNTS COUNTS

P E A KEFFICIENCY

* AREA

S U M M A RUNCERT FWHM

2 SIGMA % keVSU1. SPECTED

NUCL IDE+-+- - +-+-+--++--- - --- - +-+--+-+-+-+-+-+-+-+-+-+---- +--4--+--+--+-+----+---

185.23371. 29703.96

1218. 452240. 05

92-52185.57351.93609.22

1121/'. 08

196.136.99.33.15ý

145.119.76.76.31.

9% 531E+036. 045E+035. 921E+-038. 935E+0-l35. 705E+023

57.0958. 3955. 1431. 3150. 26

1.398 PB-2141.853 U-2351. 1057 PB-2141.362 B1-2141.650 BI-214

DD

s Peak fails shape tests.D Pea.k ar-ea deconvoluted.M Peak is close to a library peak.

***~****~..>:.**** D D E N T INUCLIDE PEAK CENTROID

CHANNEL ENERGY

F I E DBACKGROUND

COUNTS

P E A KNET AREACOUNTS

S U M M A R V **************I NTENS ITY UNCERT FWHMCTS/SEC 2 SIGMAI% keV

CE- 144CE- 14.11-131BA- 140LA- 140

1-131BE-7

LP.A- 140RU-!103SBA-140CS- 134RU- 103RU-1061 - 131CS-' 137ZR-95ZR-95

NB-95

COD5'MN--5z4FE-59ZN-65

FE-59

K-40I. -1' 4- O

28. 66290.645E7. 076019.39657.03730. 75955.00975. 17992. 5'5

1076.391209.421220.681243.o1612.74. 2C-1320. 78

1513. 11

1530.97I 5.:'i9. 2:1

1622,,00~16821

220 '212230. 992-34,7. 2 72522.53

†91 67-3192o812

134,25145.24283.4,8304.64

328. 46365.33477.47487. 56496 .0•,0538. 18604.70

610.33621.57637. 1366'I 39

756.S,57765.50

811. 02

1100. 151.11.555

11.73. 991291.31331,I"oB1460•_.91'•:159j 4.49

154.204.

I16.56.53.1-74.

15.:3;2

36.26.

2 .51.

15,

110.10.

71.

.t!.I1.

47iMI.

37.31.25.

/115,

17.21.

5.0.

16.5,

G.

12.

14 .

5.

013

00217.1014-Z

004

0017i 021

001

t17102I002-

003

001000

V00!

0101004

0101I,.1 I 'I

IZI2

142. 7 -.87.7

117.52132.69161.62,289. 50774.60392.52! 31. 53

I.0. 73

.00

1.23. 40280.31236.55

.000

16,9.971,47. .

52. 49565. C9139).00I1E3. 43790. 48180.28

JI. (Z1. , 694950

187. 08

1. 459s1. 579-;

.977

.942s

.684s.860

o000s...436s

1., 746s1. 28'!9s1. 3601)

.294D347641s

.,696-1

* 4'1 :i4

.82s

1.73s

2. 059:'s545s750,;

.542s!.648D1

844sI. 79'3.725s

2. 057. 676s

E6&G ORTEC G V - I ( 175) WAN32 14WO2..96-' 28-JUN-2007 15:35-15:4 PageEnv ironiment al Inc Spectrum, namieý 3741, fAn1

ePak fa-l. Pk shape tests.D Peak ar'ea leco-nvoluted.

*** S U M A R Y 0 F N ULC L I D E S ]: NTIME OF COUNT TIME CORRECTED IJNCE"RTAIINTY

NUCL IDE ACT I V I TY ACTI V ITY COUNTING

S A t P I E2: SOIIG MA

* * * * *

pCi/L.ITER

BE-7K--40MN-54F E-5,-9

CO-58CO-.60

ZN-65ZR-95

41R-1031RU- 106

1-131CS-134CS- 137DA- 140LA- 14.0CE- 141CE- 144

if)

( 1 82 I. 0E+0 12. 9357E+02

< 3. 1890E+00

< 4. 8372E+00< ;E2. 6415E+00

< 2. 5234E+00( 4, 9611 E+00

< 4. 07--76E+00< :2. 7900E+00

< 3. 1591E+00< ,,7467E'+01

< -, 454E+00K 2. 5938E+00

< 2. 9287E+00

1. 084.9E+01< 1. 44,S IE+0O< .6 4444E:'+00-' .54, E. .E t -i I

P vNalue privi.tei:,_ d,

pCi/L ITER

F. - I- - 4 -. -+ -+ -.

En213'4E+0121

EN 9557E+023, 970E+00

5, 1103E+003, 0593E+OC0EN 5371 E + 0Q

& 1772E'+001w, 7380E+v00

3.7534E-004, 1171EF£0.0

3: 8254E+-01'11.. 515.E 0 21.2" 6;-29E+01212h 9315E+002. 4509E+0 1& 2715E+00& 8"746E+01'4ý;2'. 6 37 8E +0!I~

6. 117E+01

pCi/LITER

A Activity printed, but activity K MDA..-----------------------------........... .. .... .... .. .. .. S U M M A R Y . . . . . . .. ..... .. . . .. . .. . .. . . .. .. .. .

TOTAL ACTIVITY ( 59,9 to 2024. 1 keV) 2.9556950E+02! pCi!L.-ITFR,TOTL DECAYED ACTIVITY ( 59.,9 tor 20224. 1 keY) W2. 9555-G95,'1E±"0... pCi LITER

:*.****** S U M M A R Y 0 F13. 54 & CE-.44 145.44 %

P28.76 % LA-140 36'4.48 &4.97.0B &I' - RU-103 537.32 &

621.84 % RU-106 E36.97 %7' , ,,.% ZR-95 F7-.. 7 ••',.L 79 %.834.84 % I-l54 1099°. 2i? &

12:91.,60 "% F.E--59: :1.332. 50 %Y

D I S 1.D ; F -P - 3. * **CE- 4.1 2184.30 & 1-131 34. 84 % BA- 140

-131 477. 61 % B4-7 ,.97. 02 ",% IA-.40BA- 14.0 6C04. 70 % CS- 134 G10. .3 & RL- 103

-1-31 681, 6E & CS- 17 724. IS % Z7R--95NB-95 795.84. & C -; -- 13 Z!. 81,0. 7 7 % C:O---58.9

FrE-59 1.15.55 ' ZN-65 H73. 24 % CO.-6SC-0-.. 10 1.5Egel % [ LA--1

ie-k is pay't of a mul.tiplet , and this area.- we'ntn ,ative durig deconvolut ion.

;::', 1-4 iarroto

Peak i-s tooat....... .-.... ... . 'but.. ok at FWH .% ... Pea -- f!. :a:il .:.s sens; ;i.t ivity t . e s ::,

0EG&G ORTEC G V .- I( 175) WfAN32 14WO2.96 28]-JUN-2i007 14:22:20 PageEnvironmental Inc Spectrum narpm manes 47317,7,An1

:1.

Sample, d:ac r i pt i onTXW-3912 3.5 LITER

!3-JU-28•} !PD!57 AMS

Spectrutii Filenam e: C:\User\47317. An1

Acqis ait ion~ Infornmat i on

Start time 28-Jun-2007 11.,'.28W2OLive time 10431Re a t i m e., 10444Dead time . Tn.Detector/M.3e!o inetry IDs 8" &

/d 10~

Detector s ys:t eMCB I Input 4

Cai brat i onFilename D),q. CIbCreated: 14-Mar-2807 15056:023 & 6-Mar-2207 15 !2'31MG 23 Geometry 4i413.5 Liter,, in ME,

Zero offset -. 130 kePU Gainuadratic -197 1 7 7E-17 eV / C /ch.nn T Il2

Library Filesain anaysistlibhrary, 2

LibaryMatch Width,:

.50 0 k e V /ch anne 1

i t:15 li.bo

Analysis par~amet ers,-Start channel.

Stop channel

Peak rejection levelPeak search sensitivity,Sampl e tizetActivity scaling factor,

120 for an energy of4048 for an energy of

30.000%

59. g9koe1V2121.4.14keV

3. 501,-1. 0000E+0G/ ( 1 o0000E+0- 3E 50O1E+80)

=7 2. 57E+05

Detectioion limit it method:RISO method

tAdditionca1l random er r or 1.. 008000E+0Additional systemtaatic erroro 1.000I0l0E+LOOlFraction Limit- 11911%.Bac: rkg•r.ound M U : M. bteh: be .-.st method (base-d 1ni spectIr.um).,

Correction;Decay correct to dateDecay duering acquisition

Decay dhuring collectionPeaked background correction

St at us

YESNOYES3

Comiment s13-bur-207 1k: 4: w.

Lik r '*wo * bCt(

2.0-Apr-287 1 42 •fi

Ohwn"nhinn lTntpvnAl'i

*EG&G ORTEC G V - I ( 175) WAN32 I4W02. 96 28-JUN--20.17 14:22:20 F.aeEnv ironmental nt.1S Inect Srp ct rum nae, :, 47317. An I

li:.

Energy calibration normalized difference: 1. 000 0

uNPEAK CENNTROID

CHANNEL ENERGY

i D E N T I F I E DBACKGROUND NET AREA

COUNTS COUNTS

P E A ItEFF TI C I ENCY

* AREA

S U M N A R~UNCERT FWlh

2 SIGMA % keV

YSUSPECTED

NUCLIDE

1021.44 510.72 80, 139. 2.457E+04 31. 77 2.498 TL-208 :

s Peak fails shape tests.D Peak, area deconvoluted .

**..******-. x** I D E N T tINUCL. DE PE.AK CENTRO I D

CHANNEL E"NERGY

F I E D PBACKGROUND

COUNTS

E A K'NET AREACO.UNTS

S U M 11 Ar R Y ****y . ,

I NTENS I TY L.UN CE RT F:'WHMCTS/SEC 2 S1(..M. :/% keV

3 1.-~f+l...........+*--I---~+........I--I--A.++A.+--+--+--+--+--4--4-l---4---F-.

CE"- 144CE- 14 1

1.- 31BA1402

S1 A il40BE-7L._A -1:.40

RU-- 103B A- 140

CS- 134RU-103

RIJ -. :[ 4

RUC- 1612

1-131

CS--137

SR--951Tr-.95

CC---, 5 8M N'-"54.

C. ":, 1,.1

F"E-59J :CO-"tE,81

L -A - 1 ....

266. 75292.24:L.4

5,7. 17612. 8,3

E59. 00730.,, 00954.~<~00

973. ! 4992.20

1078. 751.207. 461220. 621.242. 00[273,051.3 .ý I -,A .1322.00

1 450..571.514.001528. 541588. 961 (-.2 24..3 7

1669. 24'9 4. - .+4

2584. 00

2'9 2, 0. 1

.i1, 00

133. 28146.3"2:83.53

306.36

364.97476. 99486.56496. 10539.38

603.75610.33621.0 2636. 55

661. 03"72:5.3'"2

764.32794.53812.24834.68

"10Z97. '3"2

1113.88

1 2 2. 111. 3.3 32. 21 460.2 !159.J S3.. ..

213.

57.

C8,3&.

1V

24,64.33.

55.

31.

1.7.G.-,

217.17.

9.5.

10.

1&" ,

14.

12,,

0.

16.

1 4,

5.

0..11.:1. 2:.

1 5..:.

0.

1,

0030020 0000020008000

1 00t002002

Qt 002

201

000

1210 :51000

000001:

001.001;-

001

001.

000

216. 7930'i. 35

1060,, 5197. 72

1289.96, 9

24. 6297.6

200, 17:I. 34= 051 6. 17

010

220.:E,,69

:L631. C,4

4"70Z.34

16 .. .3 !

~,::,,1.4 P

:1,6. 7 B.1.2"9.21

1 91. 14A7. 21-i, (3I I 7

254.71i 0'5 . 71.

. 1210

1. 173.532s

367s689!;,.000s

167s713s

I.861:, D.204s.6E51s,333:-,

.000s,514-.:

1, 480. 89; -2S

:I..293s

1.t 14,75

1.67s780s

1. 86"7s0 00. .-

e k , -ei d c o r 0 "t- e d.

0 __ _ __ __ _... _ ...- _... -_ _.- _ __ _...

EG&G ORTEC G V - I ( 175) WAN32 I4WO2.96 28-JUN--2007 14:22:20 PageE ro nr inenta Inc Spectrum nam e: 47317. A)nI1

NUCL. I DE

SUMMMARY OF NUCLIDES INTIME OF COUNT TIME CORRECTED UJNCERTAINTY

ACTI V I TY ACT I v I TY CO U NTING

S A M P L. E2 S)I GM1A

pCi /I I TER pCi/L ITER pCi /1L I TER

4-- + - "- " + --+ -÷"-- --4 - ÷ -- '- - 4 -+ - 4 - + --.. --+ -- - ----'.. - + -" +---- - --+ " +"-- -+ -'++- " ---+'" -4. --÷ -- -+ -+ . ,+-- --+

BE-7K-. 40biN--54

FE-59CO-58.

ZN--65

ZR--95

RU-- 103RLJ-- 1061-131CS-- 134CS- 137BA-- 140L A - 14.2QCE- 141C E- :1 .44

2. 7630EW.0!1. 0076E+02

3.9634.E+00

7. 1148E+004. 9184E+003. 1199E+007. 1670E+009. 3722E+004,, 3607E+00,k. 472SE+00

E 79018E+01

3~. ":379E +020.

1. 5985E+01

3. 349.3CE.+01

X. 3593E+0:1I1. 0076E+M2iE:4-,, 0979E+00EN 9899E+O0511 6973E-003. 1368E+007. 4796E"001. 1028E+01.5. 8687E+007. 1 349E-.00Et 8709E+011. 2591E+0-1.it 607 1E+002'.923S7E+00124 5922E+01.L

5. 3382E+001, t210E9E+11 1.

z740E7+O 1

< MDA va.kilute printed.A Activity printed, but act:iv vity < MD)l.

TOT-ALe C ACTrVITY K 59. 9 t o 2024. 1. k e V) 02,. r211001271;IE41E+12N0 pCi /L I TERTOTAIL. DECAYED ACTI1VITY K 59.'9 to 202,4. 1 keV) 0.08010L4E-+.00 pC : /L.] I' :':..R

******.*-** S U! M M A.133. 54 % CE---I44

32a. 76 % LA-40

L7. 0 &.1I RU.-1062:1.24 % RU-..10675.6.72%ZR9B34•..84 % MN--54•

12'91.60 % F:-E-59

R Y 0 F D I S+,J, -44 % C. E I. ,. 1

364..48 % 1--1315.37.3'2 ,:& DAB - 140636.97 % I-13175.79 & NB-.95

1.099. 25 & FE.-.,591332. 50 % CO.-.,.-0,.

C A R D E284-. 304 7 7.6160.:. ,70661.,,66795. 84

1. 1 5.51460 81

D P E" ,.A K

C S- 1 3 4

%CS-"134

gZN-.65K -..-. 48

.304. f4 g BA-i1 4497. L A L -1-. 14.0,1. ' RmU- 10-3

73 24. 12 Z R'--95F:l gn 77 &C0-528

:11 .73. 24 % W0116

S-Peak :is pa'rt of a multiFlet. and this are.-,z- wenitnegat:ive du{r~inrg dec-onvo]Uttion.P. ... P aik is- too n-a',rrow.

S-Peak i~S 't~O, wide at F::W25M,j but ok at' PWHM.,% -. Peak fa il- s s e'--s:i.t i vi.t y t est.$ identified, but fir'st peak .of this nu$.-]i,::

fa-.iled o:,ne or more ,:•i.c. ion test .,-+ .... Peak' ac~tiv:ity higher thanm counting ,unrcer:t~ainty r'ange.

4 E0%&G TEC G V - I ( 175), WArN32 14W2.9 28-JUN-2•0l7 14I:00:26 PageErviconmental Inc., ecr nmam ii ,,: :73:. Rn

I.

Sample deo(cripti-)nTXW--..391 1. 3.5 L.IT.ERF12--JUN-W-207 1:3(1 ANMS

Spectrum Fi]1ename. C.\User\ g73E2.An1

A-cqui it i on inf-ormat i:onStart timle 28-Tr.3n-'. 7 1.376Live time 10001.Real time 10015Dead time ,, 14%Detector/Geometry IDs 8 &

-q - ~

Dt et etor sy s.t emMCB 5 Inpiut 4

cal. ib rat i onFi I ena. me : D E...1 I1. C I bCreatecd: 14-Ma r-.2007 15:20:41 & 15-Mar-2.@7 12607.CO6MG #23 Geomet rv y #13o5 L.it er water in ME

Zero offset . 105 keVq GainQ uad rat i a .3...-.7 .<e / k -h an no . ',

Li brary FilesMaivn ana].ysi lii brarvn,• 2Libhra ry Match W4 idt h

Anal.ysis paYram et ersStart channel 12;2) for aiSt orp channe 1 4048 forPeak r, eject ion level 3. 0000%Pe-ak searc,::.h sensitivityit SSample Size;A-ct-':ivity s.calin f torl: 1.00i0ilIF--IE+i

.500 . l<e /c:hanne 1

I I i b. 50 f2

- energy of 60. 1ikeVen o: ne'gy of1 ;E.7l;L::>,3( 0 V<e

W16 ( ! O002E+00* 3. 50riE+.00)E], 5 7 1571 £E+-t5

Detecat ion limi i:t method :R : m S ethod

Addit i onral ranc:om erro'r" I. @00000E+0@Ad d it i onal , 1 v at em at i c ev-.rror: 1 0030300E+00Fract i on Limit ,,000%Background width: best miet-hod (ba:ased ,on spec.atrum ),

co o rrec t c:' 1. i on sDecay cov"-r"ect to dateDec:,v dur ing a Lqu:i, sit:ionDeca. v C :.N inn C '. .L e Ct i onPea: ..ked backgr ound cor rect icon

St• at-U

Y! E_

Y E!--,

N. 01

YE

C I in n'i e i t .-)A :.i rur•*- .2312,Z7 1.3 33 0933

0 u ::u I: Cu Ti I ii t OuF I

2.0EG&G ORTEC G V - I ( 175) WAN32 14W02.96 28-JUN-2007 14"00:26 PageEnvironmi ental Inc Spectrum namue: 87392. AnI

Energy calibration normalized diffeorenc e: I 00121

&**.**.****** JU NPEAK CENTROID

CHANNEEL ENERGY

I D E N T I F I E DBACKGROUND NET AREA

COUNTS COUNTS

P E A KEFFICIENCY

* AREA

S UI WI M A RUNCERT FWHM

2 SIGMA % keV

Y ***********SUSPECTEDMi

NUCL I DE

185.32703.44

1021.3017 :17 72E

92.76351.80510.73608. 94

304.133.

7 9.

126. 9.517E+03136. 1. 168E+04222. 2. 531E+04

81. i. 061E+04

56. 0843. 94

24.2530.86

1.324 TH-2341.51.0 PB-2143,248 TL-2081.793 BI-214

Ss

s Peak fails shape t estsD ):1eak area deconvoluted.

NUCL.I DE EAKCH1AINNEL

CE- 144CE- 1411-131BA- 140LA- 1401-131BE-7LA- 140RU- 103BA- 140CS- 134RU- 103

1-131CS-137XR-95ZR-95NB-95CS- 134C0-58MN-5-4FE-59ZN-65

FE-59CO-6K-401.-1, 4

265.98293. 08569. 99

657. 36727.49"I51. l3

971.82994.09

1073.,001209.24.1220.,50

I 4. 9 81272.671323.7614"49. 55i517-361531. 701592.831619. 85I1E72. 9 229 5.8 9

2233.00

2584 IT!

012

2920. 8431 "'3J4,

D E N T I FCENT.%JIRO'.'D BA

ENERGY C

133.08

1%. 6.3285.08

3728 76363.83

475.79485.99497.12536. 58604.70610.233G621. .0 7636.41661.96724.8675a.777654 9A

796.50810. 028i36. 56

11098 ý071116.631.73 - 14

1292. W-,

,.3,J(, 1l

1460.61

I59r7 z56

I E DC0KG ROUN ELOUNTS

-l----+--+--4.l----1----l----l~--+--~4........'-I---.-,-...+.--.+-~+.--..+.-.+

P E A K.NET AREACOUNTS

U M M A R Y **************INTENSITY UNCEERT FWHWMCTS/SEC 2 SIGMA % keV

161.183.130.

30.

681.53.53.

2W.45.45.

104.37.37.217.

22.

218.15.27.

:1.0.

15.3.7..7'

3.

16.7.

17.

0.0.

15ý13.17.

8.0.

12.1.

16.14.17.

15.20.

4.I

12,

'7.

a .)151

.002j.001°@02

100000012101.

00 1..0011002

.001002

001

.001

. 002

.00012081

. 002

•000

000

- 000

. 002

229. 81609.139264. 10

1039 . 23.00

136. 03217. 90159. 391034.75

.00

170. 49.388 44.

175. 92163. 0126107.62122. 015i10.1. 960E.73. -."33

134. 33390. 90145.75

1 ,,7231,3,. *7;9,

14'. 4.!V

17. 0329t 6517. 76

63.6

. 663s

.4/801 001.s

000s000D566s713 s

-7:1. 1.

79OD

.71 I

1. 794D

456s.67s988S

98sf39..-.

1 04. /1.

376s7

417.s

.4512s

1. 575s

1. 015 1s

1 . IZ'7 5j

D F..,:. aresa Si 0cOOon o tt ed.

I &G ORTEC G Y - I ( 175) WAN32 14W02.96 28-JUN-2007 14:00:26 Pq-kgen ,, iro •lnetal. Inc Spectrum name.. 8(7792. Ant

-** .1 M RY 0 F N U CL I D E S I NTIME OF COUNT TIME CORRECTED U1NCERTAI NT Y

NUCL IDE ACT I: A i Tr ACT IV I TY COUNT ING

S A M P LIE2SIGMA

.Y... * .* *

pCi /L I TER

BE--"7K--47.0MN-154FE-59C00-58

CO-60ZN--65

N B-95

RU- 106

1-131CS- :1. 34

CS- 137BA-- 14 0

LA- 1.4-0CE-.,14.1CE- 144

2. 7705E+014- 2.4204E+02

3. 1437E+004.8075E+00;2. 3375E+00

I2.,,2586E+00.6792E.-00

5.6932E+002.4877E+00

.. 3799EW0029673E+013.5223E-+003. 2073E:+00Z3. 2613E+OVI

1 1. 179 E..011 1.88479E+-00

5. 7065E+0020. 4034E+01

pC i/L I "IER

4.1204E.I-0;.it 575EvD1,

E. 1595E+002.7343E+002. 2717E+005. 9437E+00.

6.7714E+003. 414GE.+00W 1577E+00

.058E1+011. 40+60E+013. 254.9E+00j3. 2646E+02.

08165E5+01.4, 5069E+00

8E 0304E+001..4.989E+01.

p Ci L. MI TER

60 196E+01,

# Alll peaks for act iv it y Calcu I at i on h-ad 1.,-1d "-Ac:tiv ity omitted from total

& Activ:ity omitteod from total .--and all pealk.s had bad shapeMDA value pri. nt _ed.

A Activity printed, but activity MDA.................................. .. SLJM A R . ..........-. ....

TOTAL ACTItITY 650. 1 to 2024.. 4 keV) 2. 4 ;2! 040"2-3E +02 pCi /LITER.TOTAL DECAYED ACTIVI'T'Y 6 03. 1 t o 20.2,4. 4 k e:.V) Z! 4 c*-' 0 -402-': '+'0 E0 pCi / LI Tf R

*****×***•,•,. S LU M M A R Y 0 F: D 1 c6 C A R D E D713. 5 ' - C E..--- 1 4 14.5. 44 & CE-1.4I. 2 4. 30. %,

32:_8.,76" ? L,,A.-.14.0 364.4-8 X 1..-131 477, .. ,1

497 08 % RU-103 537.32 % BA-140 6i4. 70 %

62. 84 % RU-.10. 636.9 % -'I 1. :,.l66 %-, S-.. .. . ' '_..= ?" 'I 7 "'Y NB....9 7c:jL fzi :/ ,75 6. & Zr- 95.. 76....7 . . NB-959.. . %,8'_,.'4 34.8 & MN-54 1;099.2.5 & FF.-59 1 115. 55 e:

1;-.91. 60 % FE-59 1. 33 2, 50 12 2 C 0--- (-,0 1.59 G, 8 I J

P E A K

C S- 134

-r'' 137CS-. 134,.ZN1\- ,51L. A -, '14(,

487z•. 02 L A-!140., . Z .._ ,.... 9- 0

724 i'8 ' ZR-95

f-:, 0.77 % C,0- 56:,1.7Z. '24 G% ID:..-62

Pr:eak is I:part of a mun.tip].et and this -area wetntnegative duri.r ng decornvolution.

? .- e i too rarrow.@ - Peak. is t. oo wtide at F "I:CM, hi-" bu k at FWHM.

EGMG ORTEC G V - I ( 175) WAN32 14W02.96 28-JUN-2007 13:13:11 PageEnvironmental Inc Spectrum name: 37415. An1

J.

Sa~mple deOcriptanOlTXW--7-S)10 -3.5 LITEr.H2.1-.JUN-~2007 1O.40-:49 fMS

Spectrum F ile orfame,. C\ U;e r\374:1 5,fn 1Al

Ac q uisition informationStart timeLive timeReal timeDead timeDetector/Geometry IH

20-Jun-200I7 10i~:49c428601

SE12

0

,Detector systemMCB I Input 3

CalibrationFilename: D3gl. ClbCreated: 14-Mar-2007 14:21:31 & 14-Mar-2007 14:50:43MG #:23 GEOMETRY -# I

-.. 5 Liter in MB-t

Zero offset -. 110 keV; GainQuadratic - .25E-07 k e V/chann e "2

Library FilesMain analysis lry2iLibrary Match Width4

500 keV/channe 1

.lib. 500D

Ainalyi s~;ac par'ame~t:ers.~F uil-r c+- r,annelStop channel.Peak reject~ion level

Pea serch n..ensitivittv'aSapl Size:

Activit y scaling factor

120 for an energy of41,)40 for nn energ y of

30. 000%

59. 90keV2'02-4. 0 91 k e

3. 500!.OOO0E+06,/ ( 1.0000EMM0

W 5716+05

Detection li mi:t inthod"RISO et h o d

Additional random error- 1.0000000 o E+0OAdditional systemattic error: 1.0000000E+00iFraction Limit: .000%Background width: best m ethod (hased on cspectrum.

CorrectionsDeccay corrrect to dateDecay during acc:iuisitionDecay during collectiionPeaked background correction

St at usYESYE-SNOYES

Commer I0nts:

1 2-Jun--20127 12:7 02

bkgc3wc. p bc-

18-Apr- 0`1121".:,) H cý ri 1--, r! ý: i r; -f--! ý T 'n !-. -rn n ';. I )

*0G&G ORTEC G Y -- I ( 175) WAN32 14W02, 96 28-.JL~jN%--2Q007 13., 13:11 Patqc,ErvirjrnmentAl Inc Spect rumi nae 74:1.5. 8n 1

En~e rgy cali brat ion normal ized di i.ffer ence: 02,05

*~1********U NPEAIK CENTROID

CHANNEL. ENERGY

1 D E N T I F I E DBAlCKGROUND NET AiREA

COUNTS11 COUNTS

P E 14 KEFFICIENCY

* AR EA

S; U N M A

UNCERT FWHN2 SIGMA %" keV

SUSPECTEDNUCL i DE

f-+--- -- ++ + +_ - -f + _+ -- + - 4- +-+-+--I - -+ -4-+- + -f- +- + -+ --4++- +- +_-I. _--++ _+_+ _+__-+---v _+ _..F--I-V

370. 66589.57703. 67

1218.58

185.25294.73351.79609.28

230.132.

74.38.

125. 6. 346E+0384. 5. 730E+0398. 6.815E+03

:106. 1. 249E+@A.

51.7258.9036.7925.34

1.265 U-2351.,341 PB-21 'I

.947 PB-21l41.362 BI`-2VF1 D

s P e -k -f-al i ; -,ha pe t e .Ft .D Peah-1 areai deCOTIVOlIItOCd.M Peak. is cl ose to a li brary peak.

**Fi******i~**I I) E N T INUCLIDE PEAK CENTRO:ID

CHANNEL. ENERGY

F I E DBACKGROUND

COUNTS

P' E A KNET AREACOUNTS

S U M N A R Y *************

INTENSITY UNCERT FWHMCTS/SEC 2 SIGMA % keV

1-131BA8-140LA140

I -1. 13BE-7

LA140RU- 103;

CE-1.34P.U _ 10,:RU-i I0f-*

I-1314CC' -j57

F E --5 9

26-5. 793190. 00570. 8B6 11.~00657. 0472.-'.8,81955.83T97. It

99.

I Q17 2. 7 3i 209. 42:

1. 2 .3G 28

1.3 23,L. -,;t1+ 447,. 0 01513. 00115.3:1. 6 7I 937 00

I ,16 .19, B81. 6 .."8. 0 02 J 19-,

2 22 1l 8 1-23,49) 2.5

.10I

132.~,8114 44. 321

305,45

364.36~4477. 89

497. WE

604.70610.3

636.0

661. 71

723 51

7z, E- .. 51

7I rý 5

7 L (',.5

It13 70

1 93.58

137

60.

26.

59,

10.1

140.

-4.

1 4.

5.*

.1 D..

141

15

C00612005002

.001

002

002CIO) 1.1

Q1001

0 01

Q000

03C1210

,000

1231.'17

2!0061301)l~

118, 7516 12., 45

1. 34. 39:1 119, 810

107. 40145. G9

159. 12416'. 2E"-'312. 0828.(h. 0121

111.126678. 54281. 88149, 11

1319. 44663.32

3346. 4 1.69. 61

346, 41.292. 62653, 1/

126 5022'0e. 7 3IL 2S. 603246 !o ;l'

27 5 ,, 6,-43.56 '

-,2 84

.600s083s

.869,000s

. •879so643s

I. 836s,36_3 s2 -E .1s,

706s1 3601

432:s493s469s1 i67-;

394s000,

1. 9.I. 38

1. 123sS0-s

....... - ... 4,. -. --- -,..4..al, 4 At.L it. a DC.. u0E

ES&G ORT'EC G V - I ( 175) WAN32 144W02. 96 28-JUN-2007 13:: 13: 1 PageEnvir, onmen.tal Inc Spectrum nameý 3741,. Avrl

3

- U M M A R Y 0 F N U C L I D E S I NTIME OF COUNT TIME CORRECTED UNCERTAINTY

NUJCL I AE ACT IVITY ACT I V II'Y COUNT I NG

SAMPLE2.-. S ISM A ** * * *

BE-7K-.40MN\- 54FE-59C0-58CO-SQ12ZN-65ZR-95

NB-95RU-' 103RU- 10,1-131CS-134CS- 137BA-- 14.0LA-140

CE-' 141CE- 144

pCi/LITER

2. 4577E+01G. I189E401

0: 00_-35E-+ 00

5.0262E+002. 6605E+003. 1. 2;E.6+003.0964E..-004. 0359E-00

1. 8261E+002.3752E+i00

2. 0464E+01 -.3. 331,E+002.6 357E+002... 0441E+00

1. 6390E+003. 5668E74 -i..2. 3 0 7 4 E_+ 0

pCi/LIITER

3.,, 0264E+01b, 1189E+0!1

Q.07602)E+003.4484E+003. 1115E+003ý 1441E+@A03., 2405E-''004. 7993,E5+002.5056E+003. 1505E-"•0.2.1089E+011 3279E-0. 12. 6747E+00'.0461E+00

2.348BE+0;.3.9090E+005.0174E+00

9C- 99EO+01

pCi/LITER

< MDA value pr'-inted.A c:tiv:. A ivty printed,, bat~ activity ( MDA.-.................... . ....... ...... S U 11 M A R Y .-.....

TOTAL ACTIV ITY 59 ( 5--' 2024. 1 k.V) 1. 000000 '0 pCi./LI TRTOTA:It DECAYED ACTIVITY' ( 59. 9 to 20I;24, 1 keV) 0. 0000000F:+00 pCi /LITER

133.54 &...... 8.76 %-4•97.08 %621,,84 %756.,72 %

B34. 84 &1291.60 &

8 U M Ml ACE-- 144

LA-. 140

RU•LI-" !03RU!-.1.06Z I-95

MN-54FE-.59

R Y [1 F D I S!45.4.4 % CE-14134. 48 % 1-1315 37 "' & B'A- 1. Z.I

636.97 & 1-1317",:,5.79 % -•Y N B- 95

1099.25 & FE-"3...50 & CO-.60

C A R 1 E284.30477.E1E04. 70661., 66795. 84

1.1.1.5,551460, 1.

I)&.4

1-131BE--7CS- 134

C S -- 11 3,7CS-- 1.3_4

ZN-65KI-- 4 i'I

K 3 -'-"'-•• .••

304. 84 & BA-- 140487102 % LA--140310, 33 % RU-0..724. 18 % ZR-95

1U'K 77 & CO--5811723. 24 & C0-601593, 18 % LA--140

"Peak is art of a multip.e' and this area wentne ative dur'ing decon-,o 'ution,

9 -- eakl.< J:." too Ta-' W@ ... Peak is too w~idce at ..... , b-" ,k at "".~ -" ..,.]c .;:V 14 o CM b t o' k • Ft:WHM,,,....- .Pea k fa :i ls ."1..s SenTs":it . i.v i t y 't;e st.,

-.. Peak :identifie-d, but first pealk, of thi- s nuclidefailedl ore or more qu. if:i.cation test;s,;

6/20/07

Tony:

Enclosed in two coolers are the first 3 well samples. They are all from outside theProtected Area of Davis-Besse.

MW-ISMW-ID

MW-26SMW-26DMSOI-MW-26D (for both tritium and gamma matrix spike)MSDOI -MW-26D (for both tritium and gamma matrix spike)

MW-7S

Please analyze to our normal REMP LLD of 330 pCi/liter. If you have any questions, wecan discuss at REMP/RETS Conference. I will bring a copy of our sampling plan.

Thanks.

Al PercivalDavis-Besse

J U N 2 2 2007

I-II•L--I 1/1 , 4y BETA LABORATORY

6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143SAMPLE ANALYSIS REQUEST / CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV- 05-07) El YES Fl NO PAGE / OF

El NOCOMPANY NAME

ADDRESS I LOCATION

BILLING ADDRESS

TURN AROUND TIME

(Surcharges May Apply)

A; ESAME DAY:-"~' El 24 HOURS

El 48 HOURSEWSTANDARD

ANALYSIS REQUESTED SAMPLE MATRIX

CITY STATE ZIP CODEi

A = ASBESTOS

AS = FILTER-ARSENIC

F = FUEL OIL& COAL

M = METAL0 = OIL

P = LEAD IN PAINTW = WATER

OT= OTHER

TELEPHONE NO. ,.'. FAX NO. RESULTS

REPORT ATTENTION E-MAIL [0 MAIL

PURCHASE ORDER__O._ ,_'_____ :_.____ , JFAX

PURCHASE ORDER NO. lEr-MAIL

PRESERVATI

VE

SAMPLEREMARKS:

(Conditions,Bottle Type, Etc.)

LAB

I.D.SAMPLE IDENTIFICATION COLLECTIONMATRIX DATE

COLLECTIONTIME

RELiNQUISHED BYý,Signature), . DATE TIME RECEIVED BY (Sn6 I e - DATE TIM ADDITIONAL COMMENTS!

RELINQUISHED BY. S(SignBature) (SignatureW) I TIME C N

/ I5ATou-"H' tTIM,-(,*ihaREre) VED BY DATE TIME

RELINQUISHED BY (Signature) DATE'4;'1

TIME REIIE ,TVED BY (Signatur ' ATE . TIME._ __ __ _ __ __ __ _ __ _ _ _ _ _ _ _ _ _ _ _ _ / / -#9 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

CFLPY DISTRIBUTf'ION: WHVTE - ACCOMPANIES SAMPLES, YELLOW - LAB COPY, PINK - CUSTOMER

WEBSITE FORM: ORIGINAL - ACCOMPANIES SAMPLES, CUSTOMER - RETAIN COPY

F .. 9..... <BETA LABORATORY

6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143

SAMPLE ANALYSIS REQUEST I CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07) .... If YES [] NO

SPAGE/1 OF/PAGE / OF /

COMPANY NAME

ADDRESS / LOCATION

TURN AROUND TIME


E SAME DAYE 24 HOURS

El48 HOURSESTANDARD

ANALYSIS REQUESTED

BILLING ADDRESS

A.

SAMPLE MATRIX

A = ASBESTOSAS = FILTER-ARSENIC

F = FUEL OIL& COAL

M = METALO = OIL

P = LEAD IN PAINTW= WATER

OT= OTHER

CITY',.~ STATE ZIP CODE

TELEPHONE NO. FAX NO.i.J•• '•• -• ,] • -•: •'' !<• •RESULTS

REPORT ATTENTION E-MAIL El MAIL

PUCt O . -]FAXc.• i i . d'. E FAXPURCHASE ORDER NO. E-fE-MAIL

PRESERVA

VE

SAMPLEREMARKS:


LAB

I.D.SAMPLE IDENTIFICATION MATRIX

COLLECTIONDATE

COLLECTIONTIME

• ',L - T .} . ... v• #.'.* ..... "4. 'j vj -'4l~ x

RELINQUISHED BY (Signature) DATE TIME RECEIVED BY (Signature) DATE TIME ADDITIONAL COMMENTS:

-fýLINQUISHED WX (S-gtEe I (D TIME t,-/IlE

. .. .... ...... ... .. .. .. . .. .. .. ... .. .. .. ... - . _...,y__- -,."

(

6.PY DISTRIBUTION: WHITE-',ACCOMPANIES SAMPLES, YELLOW - LAB COPY, PINk - CUSTOMER


0S! .Environmental, Inc.

-OMidwest Laboratoryoý Aftgh.ny T.chnobop.e Co.

700 Lndoehr Roa . Norhbrook, IL 60062-2310ph. (847) 564-0700 f.x (847) 564-4517

Mr. Al Percival LABORATORY REPORT NO.: 8003-100-363FirstEnergy Corporation DATE: 07-12-07Mail Stop 1041 SAMPLES RECEIVED: 07-03-075501 North State Route 2 PURCHASE ORDER NO.:Oak Harbor, Ohio 43449

Dear Mr. Percival

Enclosed are results of the analyses for tritium and gamma-emitting isotopes in fourteenground water samples.


Quality Assurance

M. S.


Report: 8003-100-363Page 1 of 2

Table 1. Results of analyses for tritium and gamma-emitting isotopes in fourteen ground water samples.

Sample Location MW-12S MW-18S MW-18D DBD-01 MW-20SDate Collected 06-14-07 06-14-07 06-14-07 06-14-07 6/25/2007Time Collected 10:07 12:30 14:27 14:27 10:16

Lab Code TXW-4117 TXW-4118 TXW-4119 TXW-4120 TXW-4121


H-3a 657 ± 118 277 106 204 ± 103 764 ± 121 255 104

Mn-54 < 2.3 < 1.8 < 1.7 < 3.6 < 3.0Fe-59 < 7.7 < 4.7 < 7.9 < 6.8 < 10.2Co-58 < 2.7 < 3.1 < 2.1 < 2.2 < 6.4Co-60 < 3.0 < 2.6 < 2.4 < 2.5 < 3.6Zn-65 < 5.0 < 3.9 < 5.2 < 3.0 < 5.5Zr-Nb-95 < 6.2 < 3.2 < 4.2 < 5.0 < 6.9Cs-134 < 3.1 < 3.5 < 3.2 < 3.3 < 4.3Cs-137 < 3.4 < 1.8 < 3.6 < 2.3 < 7.1Ba-La-1 40 < 8.9 < 5.1 < 6.9 < 7.8 < 6.2

Sample Location MW-20D MW-32S DBD-02 MW-32D MW- 5SDate Collected 6/25/2007 6/25/2007 6/25/2007 6/26/2007 6/26/2007Time Collected 12:50 12:00 14:58 9:50 12:00

Lab Code TXW-4122 TXW-4123 TXW-4124 TXW-4125 TXW-4126


H-3 328 ± 107 5838 ±237 279 ± 105 466 ± 112 375 ± 95

Mn-54 < 3.2 < 2.8 < 3.3 < 2.4 < 2.7Fe-59 < 9.5 < 11.0 < 11.3 < 4.2 < 5.5Co-58 < 3.2 < 3.9 < 2.6 < 1.7 < 3.5Co-60 < 3.3 < 2.8 < 4.1 < 2.4 < 2.8Zn-65 < 6.2 < 4.0 < 8.5 < 5.7 < 3.8Zr-Nb-95 < 6.2 < 4.9 < 3.1 < 2.7 < 4.4Cs-134 < 5.2 < 4.7 < 3.9 < 2.6 < 3.7Cs-137 < 6.1 < 3.3 < 5.4 < 3.4 < 3.8Ba-La-140 < 7.8 < 11.2 < 14.2 < 3.3 < 5.2

The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample.

0Report: 8003-100-363

Page 2 of 2


Sample Location MW-15D MW-30S MW-33S MW-33DDate Collected 06-26-07 06-27-07 06-27-07 06-27-07Time Collected 14:45 10:00 11:55 13:44

Lab Code TXW-4127 TXW-4128 TXW-4129 TXW-4130


H-3 704 108 1307 ± 128 2287 ± 154 2975 ± 171

Mn-54 <3.6 < 3.0 < 3.0 < 2.7Fe-59 < 9.5 < 7.9 < 14.7 < 5.6Co-58 < 3.6 < 3.8 < 5.1 < 2.8Co-60 < 3.8 < 2.7 < 4.1 < 2.8Zn-65 < 5.1 < 1.6 < 4.3 < 4.7Zr-Nb-95 < 4.7 < 2.8 < 2.8 < 2.8Cs-134 < 5.6 < 2.7 < 2.0 < 2.7Cs-137 < 3.6 < 1.7 < 3.0 < 3.9Ba-La-140 < 11.4 < 5.0 < 10.6 < 7.3


- ...-. nvironmental, Inc.Midwest Laboratoryan Aheaheny 7echnoflDpies Cc.

PRG-33Fom LS-4Vex. 10

TTR7TUM

,ounte- ID:

LSP-20oDC-A

LSP-25 800TRh/AB

LSP-28007-R

Init.& Count Date:<f) 0 7 / i1 /0•0.10032- STD T-36

BKG BKG Sample STD STD STD DateTime Counts Time Time Counts Acivity issued

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _C~i)

Lo0 q79 g I0 X1.o0 0 Ig•ý1 1003.78 :01/18/2001

Sample ID Volume Sample Remarks(ml) Counts

T/,( •tzF 7o_

T? \ b.i /2 . Iq

1 _ __

_ __ _ _ _ I _ __ ___

____________________I_____________________________ __________________

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ I4

.., ...- ... ..... .. •... ..:.:.. Environmental, Inc.

Midwest Laboratoryan Allegheny Technologies Co.

PRG-33Version No. 1.0 06/17/97Programmed by Rick Lesko



Background Counts:

TRITIUMRESULTS SHEET

For any sample counted on the LSP-2550TRl/AB,LSP-2000CA or LSP-2800TR Reviewed and Approved b

Date approved:

100

200

978


Standard Counts:

200

61688

0.196


Calculated by: Rick

Date Calculated: 7/12/2007Counter Efficiency:

Sample Coll. Vol. Sample Corr. pA i/L 3.00 4.66ID. Date (ml) Counts Factor Activity Error T.U. Sigma Sigma

TXW-4117 6/14/2007 13.0 859 0.996 657.061 + 117.983 148.004 117.809 182.997TXW-4118 6/14/2007 13.0 645 0.996 277.031 + 105.927 112.428 117.809 182.997TXW-4119 6/14/2007 13.0 604 0.996 204.222 ± 103.457 107.120 117.809 182.997TXW-4120 6/14/2007 13.0 919 0.996 763.611 ± 121.148 159.568 117.809 182.997

= =Best probable result.

- : Environmental, Inc.Midwest Laboratoryan Allepheny Technotogies Co.

PRC- 33Form L54- V'e. 10

0.1003 2 g STD T-36

Counter ID:

LSP-20DOC•A

LSP-250/TRI/ABTRITlIUMLSP-2800TR L

uit. & Count Date: tb M 0o2 / II /0"

BKG BKG Sample STD STD STD DateTime Counts Time Time Counts _kt-, Issued

__________ )OC 100 9fO ! • /1 1003.78 01/18/2001

Sample ID Volume Sample Remarks

(n-d) Counts

T,• G /ttG T__lbI______ _____

T•~ 1-fl?~O

I ______________________________________________________________________________ __________________________________________________________________________

____ __ {____ I ____

______ ___ I ______ I _____

_______________________________________________ I _____________________ ______________________________________________ I ___________________________________________

_________________________________________________________________________________ ___________________________________ _______________________________________________________________________________ I __________________________________________________________________________

I __ T_____ I _____

_______ I ___ _______ ______

______ ___ _____ _____ 1

........ --- ..

-. Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.




Background Counts:


For any sample counted on the LSP-2550TRI/AB,LSP-2000CA or LSP-2800TR Reviewed and Approved bS * -

Date approved: -


Calculated by: Rick

100

200

552


Standard Counts:

200

56219

0.180Counter Efficiency: Date Calculated: 7/12/2007

Sample Coll. Vol. Sample Corr. pCito 3.00 4.66ID. Date (ml) Counts Factor Activity Error TP.U. Sigma Sigma

TXW-4126 6/26/2007 13.0 470 0.998 375.031 + 95.334 108.120 96.348 149.660TXW-4127 6/26/2007 13.0 640 0.998 703.666 + 107.841 144.180 96.348 149.660TXW-4128 6/27/2007 13.0 952 0.998 1306.608 ± 127.627 218.782 96.333 149.637TXW-4129 6/27/2007 13.0 1459 0.998 2286.564 ± 154.483 347.231 96.333 149.637TXW-4130 6/27/2007 13.0 1815 0.998 2974.659 ± 170.836 439.145 96.333 149.637

,j- ,=Best probable result.

- --. z~Environmental. inc.Midwest Laboratoryan Allegheny -echnolopies Co.PRG-33Form L5.4 Ve. 10

0.1003 2 g STD T-36

Counter- ID:

LSP-2000CA

TRITIUM LSP-255UflRI/AB IDLSP-2800TR ED

Init. & Count Date: b V) 07 / ) /0 /1

BKG BKG Sample STDh STD LTD Date

Time Counts Time Time Counts Activity Issued__ (pCi)

0707 100 c90 oO 10bL 1003.78 01//18/2001

Sample ID Volume Sample Remarks-(ml) Counts

ThKL4.- 13i 99/1t•q/ ________OIQ 2/ J __ _____

/•/•d5-$0

1476W I. I I

T___ I__

_J I I

- Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.PRG-33Version No. 1.0 06/17/97Programmed by Rick Lesko



Background Counts:


For any sample counted on the LSP-2550TRI/AB,LSP-2000CA or LSP-2800TR Reviewed and Approved 11

Date approved:

100

200

707


Standard Counts:

200

53734

0.171


Calculated by: Rick


Sample Coil. Vol. Sample Corr. p- r. 3.00 4.66ID. Date (ml) Counts Factor Acvi Error T.P.U. Sigma Sigma

TXW-4122 6/25/2007 13.0 515 0.998 327.797 - 106.767 115.701 114.485 177.833TXW-4123 6/25/2007 13.0 3230 0.998 5838.446 + 236.937 828.626 114.485 177.833TXW-4124 6/25/2007 13.0 491 0.998 279.084 ± 104.899 111.554 114.485 177.833TXW-4125 6/26/2007 13.0 583 0.998 465.746 ± 111.875 128.562 114.467 177.806TXW-4121 6/25/2007 13.0 479 0.998 254.728 ± 103.952 109.572 114.485 177.833

=Best probable result.

&G ~ ~ ~ ~ ~ ~ ~ i ORE J 75 A3 4O.6 I..jJ-2i0t7 1:1. :3 Pagefloo viro ment l In nia e--.

I ! . ..... .. .,`?.4

I )I

Spectrum -1k1

I

Pij c- T., o 1Ca1, .

Dtector/Geome~rtliry Is

I---Ji tu E-E:C~207 D

9001

MOB I4 Inpu.1 t...1C.2HiT

Calibra ion: i3~CI ,,> ~

, fF Zer of se -. 98 ke~i7 nC:

Quadratic;

Lib ar Filesdl b

Starit channel.

fo-1 an oi.,4: Cj*~' C

58 ko

1.0 00 WE I I!0C.; (I 'h

1.

Ad it o a sy t ma i eroI 1. 0I -* 00,A4.0E. 4,2 .0

Fr cio CIi wit. . 0 0Wv'

14CIt. dat

PeakeI~ id backr w y =.IIJ1:2rrc it...ioi-I

1 .iiiý i s.CC iC F i~I.

EMS ORE F. " 75) WAN3~: i 2 1 O. 967 1.w'.,T .'.'21171 . .2 5 ýE1':: v4 J . -1- ( 11. IT[ C." Y. t 1 1", n i:,s p at , - u i Y i~i n i E.. ;i 1. 7 Q4 317 A n

Energ~ v fy ca1libration n4 iormali. e diif fer- re nc::'4 ,, *.,'7 f2

****w********U N I DE NT Ir F EDP:EAFK CENT ROD I C PlCREROUND) NET AREA

0-o " h9INN 1_ r-N E R GY COFU NT 'F, (- C) IN]" G

P. E A FKEFFIr :iCI:.ENCY"

-X All 9Ei

3 U] Mi rI'. A -,U N.c: C~ EF'.' FJ*.F

....1:% 1-" (,.- I)4['

V r4..4.444*4..4.k

SUSPCTEID

1219.295

351.52::510.1 85

170 i.89 4

100.1,

152.

941. 7.57E40310. 94i 1 . 854E. C-rf..I

62.. '7.1 48Es03

507.21

4', 1(3

AM49 PS-2'1 4Ti,73 'F..2081

L9.47 Bl -21.4 D

Di Periak ar'e a :1 c:'v 4o).ute 4:

1\1 LJI..' CLI Dr P:EAK CENT' 1ID:F~ I17:.DBA9CKG9ROFUN.DCOUNTS r ''

P7 E KNET AREA1~1

INTENITY N C(9 r" w 7M

CTS 9/S9E C 2 SIM ke F'sV+ - f-f-f- f-f - f-f-f- f- f- f-f- f-f-f -f-f-f -f-f -f-f-f- f- f- f- f-f-f -4--f- +-,-I,,

CE- 1 Vi'.F.E -1F41/

LA-140

R''- 1037BA-140.

/E13 '4'

'IC 10Y3

Z 5

1'414.474

271.52

295' 50

571.006,1 . ]'"!,

454.. 0

73.7.357I ?,9~761'.3

994.73'1027E.67

1 1.0

144.6

"1 :51 f

034 '. 12

5" 9.' 2 2

284.0"i7

'.'.'7*7. 1i 4

487 12 /

~496.34537.3

1.7

EM43

7 G W',"

7 "'

141 .

16.,

414

2:

14.4

5'.'

25..

7.

.4. '

174174471 471 27147191741741.474174/4.

4'.,'4 174171

I7.II;~.4.

1741741ri r: 1.

71731741741.174174471

474 .4.r~4 474

174 '~i"144~'.44"l

''''1174 4/4

17r414 4.

747

I1 742. 4

24'.54.4

k-,/. 77 :1.1.)

1 .1'443. 7149

174. 9

4 01

1 7 t3 719

].75

'76

'04s:.38&4s

's Pmak 'are I .(: ~Amn'4:ols''; s

3&G ORTEC G3 V -I ( 175) WFIN32 1 4WJ2. 96 11. -JUI 20-a07 Pag 1 3 -~qe1s11 r nmentI; im .If1;:iitrn namnn , 1. 7347'.: ý( :

S~ U~ M 1 AI F V 0 F N4 L C L 3E S I NTIME OI ~~r.rF :ricor COUNT TIM CRETED~ UN rEr F:A I

9: A~ M Pr.****-X-

NUCL..IDED ACTIVITY

pCi/LITER

ACIVI~TY

p5 i./LIT E P

COUNTrr:~INGC

fi:CI/L I "rE

I.........-l....................1-~.

0 7I

11R-95

RU-~ 103':1:ý L . 1 7i

CS- F :1.37BA-* 140

/

(I

4/

I

7 c.5231941.5

5. s0.9G3E+0?I2. . 117sERZ

12. 95S~1Et12)

5.220337E+00s

41 397E4 1117

3. 413E+0

7.9133E+01&S [email protected]

1749G3fO.O7I?

14.21 4 ;3 1: 7

W71 S7EH3C.1

1L 1336137E+001

1,':.2714SE r0u1.

4. ý - 41 .- 4. .- + - -I III ... .11 --.- .11-1 - .1 - + - + - 1+

A) Acti: 1,vi:t y pr~intend, Sot actUivit *I*;A,*

FoTOTAL ACTI:EV ITY ( 5 8. 1 t o 2 2 S. 51 k o V )70. Q1;7.1 0 Q. +71 0 r:C i / 1. :1 Trs E sF :TOTAL D)E.CAYED ACTI.~V IT (/ 51, B. i; t 2 0 26.3 1 kA e V ) 0 ',Zif, '' 1± , ~'.!i - p QO , i/ LI- 11'EP

621. 8 %

75.7 %fB34. 84 %

1216 &

S U IP

CE 4

A 1 'r? ,14 .4

I64.4537.3

F

*f . 9..

CE-I 111-131S•A- 1401 .- 131

FE-59CO-60Z

2B4 .307

C47~s7. 1.104.7

BE !. 66

CS-3 134,C -I 1 C .'i

30.8 %,,~ BA-14

487.0 %~ LA-i14

/1.3 % IRK

",7 P~ "' I

?~ is

k.,~ J.1

7'X W -- 411 J.L-ý3. 5 1.. 'TEV* R

SpectrumJ~1

Rea~ l tie73Dea ti m . 1 *1'Yý~

MCB'14 I~nput; 3

Created; 14 Mar-2007 14:1 &.,~1 I. 4 4\r -2007 10500,"',11G M23 E: INME 1 T. Y 41 1.

3. 15 L. it1 e r i n; Y/'i

1 i... 1 . ...) .AIry 1` al..' "h 1i.

Anailyi parameters~li'

Str channel.Stop hanne

Pelak 2 rjcion lelC 3vel.

Pea searc se113 iviF:

2:. 1i 1.)L

404 for an energ of' '

ii'* 130.000% 1: -i~:'.1IV o

.-N -eV12 0114. 0 9 k e

I:i243.:, 1.f~1'~111.1 3

2.857 1E3 05'

De e t o li i et o :1IS method':iI (t4.E2c~ i

Dea (luin s"qu si ioi-

Decay~~ duhq oletirPake bakron correctio

itatUf

V EIY03

1;,.1; 7 1 3 45f" I-, 11ý ý 1 1".. , , 4- -ý ý-ý " ý' T -" 1 K r"

&Gc~~ ORTEC G I ( 1.75) WAN32 ] 4WO29 1 --.JUL-00 .. .... ;-. V:YrZ! P

E neprgyi calibLvat;i ci n ormai zed i i.F ~ rcc . 1. :.

* ~~ 1-1*** 1 13 Ii 14 T 1 F I EPEAK CENT R~OIi BACKGR OUND NET AREAF

Ci*RNEI... ENE RGY COUNTS CQiJTEFEI C IENCY

, A Ir- ,'.ý

S i U i VI 11 A R Y ~ ~ .iUNiCE FT FWHMi' SUIJPEcTED2 SIMI OiX1 1,c V NUl~c i.. 11 [.F-

4, ... I.-ý"..-,.,.-Il...-ýi..'ý1--"!-.,ý.,-+.-+-+-+-+-+-+-+-+-f-f-f-f-f-f-f-f-f-f-f-+-"-+-+-+-"-"-"A-"-+-+-+--I.-

59i2,'3. 3 17121/,'i,. 2,3

1 021.012:18.0 1

;?.Ti)5. 13.

~2i .1. 0 3930.13~ 9¶:I

53. 3.596EF+03833. 6. 4E9F-i03.?

13.39. 1f.43!E3. 0451. G. 2i30E+Q'.,,7

W9. 3.33

1t 4.*"3 9 r-,n -- 2 1 z.

9: 5, r.:, B 4/75.

1)

ei r. e - cc ei c. C) ) v :: lit e d

iiui * *~ i <~i*I D E N Tr a

Nlt I- CL. 11:) CEhrT REIDI:C .- R L-F . ENE RGY

F I E" D P F A 'KNET AREA0COUNTi..i'Sr

S L3 1.3 1 I'l Ai 0 -ZI - '.I ** l * * . * *

'INTErSIT 112ry R i1!..i tf T Vl-ICTS,/31F: 2 33 R% V e V

CE 14I66 5 133 2 I.1 . 46 -1 . 0 1. 4 r:.4

CE- 1 41 29 .7 146.28 149 01. f"?l I", t" :1.t 'i3 .It9

*Si (Z" ry-3 50.p~i 1!100 1 B25 74 00-

BA 4 6 9 4 304 M'", 32 37. .0 92 50: i111 f 33 1. 49,-,LA 14 Y'75 '1.5 y:1 328 20o 50. 7 1. 7 7 f", . 9,B

,M]---- F.154 ., 59 4 7.2 1( 0 20 1 ~ ~ 7 c) 70LA - il40 ' .*'T;*ý.. in 1 f,1 .d .7li*1 .00,21 A 17.-)

RU 10 139 .2 49 .0 2'. 00 1. 1 1.12k

('"1 1" 1j i*'lG ' 3 4. .2136.9 22 1 ti 3 8:1. 1. li.5

RI *. 12 1.* 2 12)1 t i 35. 03 1

N7 IN! 25 0. 1.4 158s

1: 1.3 1~ 7. 4,i;'ý fZ 3 4 .l-0

3. 1 .1. C cc Li a 1::: p 1:*Cv"cI.-IC c:IcEc;ci:.li1\!C 3. .11

.;C'L2I..

ý'3 . 0EAS O~30RTE C S V - ( 175) WAN~32 I 4WO2.9 11.-JUL-20 1:3003 Page'EnvironmUjen ta *& Inc Spe :r name-. m - - ?

*S*~*~ IJ ii Mi A R r y ( ::) F` c11 t.) ..1OF COUNT f~(~;ITIME~i CORREPC Tr.- C

NUC:L IDE ACTIVT AC~i lT 1 VI I Y

I~ E 3 1\IjINCETZ"1711I N4j17'Y

CO0[JN T 'I N (3

Al M P' L E

BE-7Z

K-40M '4--51F:'[-- -- 5 9I

1\UB- 13 5I

rt-1I 1 1. 0 (1:-1. 31

CS- 13rCS- 137i

BA- 140

2. 950E+0G. 0769E+01

I.715EB

VG72192 +I (t

16EE0

599 7E0.3.5'74j3 Sh

4. -727 .00

E 043GE.'6 --i/0

K 37 3E-H/00

a.4695 E+00 /I/

1. 8360IIEEf-iD~4 /

1 1.05 E12EE 0~:1.IN 3300EFO:'%

::I /L I TER

A ctivit y p::r~i~nt:ed, bu A;,iott.v i.ty ( MDEF,

TOTAL.. ACI) SVIT SY T I 59. 9r tT a 202 .1; k e333, V) 0 .( PC J 3 /IJI15/5A5/F i

* I* * * 13 U V' I M' A I 0 F

'2.8 & 1 RU-F0 E36.97 %

75.7 % R9 757

D V1 6 C!C'E-141 28.30"

1-131 477.61

DA14 60.7

1-13 661.6

/,'

I"

'I',

'a,,

I .. 1 ..31

BE-

C9 13

1/.33 &/: Rh 0 - Ii

1:1. 7 ("l',I -G

1159E. 18 10-0

@- Pea is to ua -I1

Peak idnified, butl firstF peak wFt-snul

faile 'ane or. mor qualification.tests

* &G f ORTfEC G V If ( :175) VP 3: ;i. 4Wf2 93 .11 JL.i)271 34 Paqf,1T v i.ro met T i a i1 :1T Spocittr '- n~x~ 374 17,A7-n 1.

F XW- 4!t119~ 3. 5 LITER4 ?. I I,

Spectru F iTTinm.Hi~rT.I~'347 '"T

AI-',

Start t IIime

De tecito: r/Geomei~itry lID

Deeco Sytem

1 1. ~J u If ~2iZii2V7 11 T 4 :f 33(3 3. (3 1

(31(35;

8,4

. J. !-,i~T * J. 1.eI- VI t , r J. I- 111-'

Zerot c .1 offset ~ 11105 keV Gai .30 & .k4e'2iiZi uh1 = ;'G

Quad Tira't i c 2I9"1IL E.l? / Cli CTiC C

Librr Files.j~[la I iv 2 i fyT s iL rv . 1I :i

PeakA1 rejetio level(7

Peak serc senitviy.

Sa pl Siz ,,

Activit scain factor.~ I

f1r e:n e -r !,T-,ST C T 7 :1 is T

MIT4.: 000% ~' j~ i i 'k ~ ; ,1 i E, V-iii(

1.0000E 21 I3 1

2.871 E+0

[(J di ii oiC,1 .. ndo ; 0 0 0 V M.

F* I-r- T~~ui (I: [t'f J.ii'.:i ci- Liss c mi J. t'i.000

CoretinDea cmnnnA to

Deca d. .. . . .collect. .iIoi T

Peake backgron T c ::iini.-2ctio

Sta i

Y Et.

CT TitI.

EEl' I2T iTT El I. "I lIE ':11

E&G OFITEEIC8V- C 17. WAN:32~ 14WO2.9 11 -..JUL-20 13:56Ci41 PageEnvr onme , lH int;al l inc:: Gp c r-wuim lxY i 37i .C

2 .i

Energy c:alI.i.brat ion no~rmai zed1 d ;i.f ferece . 2MG2

U N

PEAK C(ENlT P01TI D E N TI F I E 1)BACCKGRPOUND NET ARE

P E itlIE.F:ICIENCY

S Li 11 M iP R'UN-CERT FW*123 SIGM scN keV AWUL Ti DE

+ - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + -- + --.. .I.- -.- 4- --- .-Ir --- 41 ..-, 4- - -4- ..-- A- - + - + - 'IV

70/3. 59102/11.6F71 1. t2 5 *`

C351.88(Tic.

783.7.01:3O

1., 027E+0Zi41. 676 131 2114

C

Zi~ 'i f'ails ' ha ~ 'D Pal.k *rea-1'v1u

M-~*~-~*;* 1**4~ 4* 4 14 D14 Ei N T: 1

NULIE EAKi~ C -r R~O :CHP[,NN EL. E:NFPC,-,,y

F I E2 1) PBACKGROUND4( i 1

CG UlN

E A itNT 3PF2

it 0.1 Ir y(- I;F',, Y' ~ 4 44

I P-r EN GI T Y m U r P ' 1,-,Wcns / GE C 2 1 G~ t-1 C1 1,; C3

+ - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + - + + - + - + ..- -I.-

1E 14

CE- 14

BA- 14

1, E. - --

LP- 1p

RU103) p

DA-14

OB13

1. I103

RU 106,P.I- '13

292.i 11.

6571.94 572.0954...

9( t ý! P/1-6

1 "i E . 2 -

.1, 5

0, 12 .

0 '.

146. 15~,

30.4.52

4 7 7. 27

610.33

623.35

W3 G. 7 2

5~.

p4.

p1 4~ ,*ý 2

-13 *.' p ..-ý"ý

1i-7

Ev11

5.1

15.:

4 .

'4

(/4,4IjQ

01.

I/I 0/

07(4

0// 0 0.

1Z.! 4/i f1

10 0

I L." 3

ZI ,,'

Z., 4

57Bs

59 7. 5 s

I , . p ;

s ~ . v ~ 7 4,, :

* B Ec RT' Gmo cV- 1: ( 17'5) WAN32E i 4WO2.9 11~i JL.22F 1 4 Pageli :tvircnnint; l4 Inc: E-i't'. n na iie 071. n

** S U M M~ A Ri ~ pY 0 F N UCLID. ~ ;ES 1~ NTIMlE 0F- COUNT T IME CORRTECTED UNCERTA INTY

S 4 E L.. E2) S(31(1q

***M,

NUCL ID AC"IYT I V 1 TFY

pCi /LITER13

COU LNT I NG

pCi/LITER

Kl .- 4 Z

C, (: ) --5IiCfl3.3

CS- 134

CS 137

B. "i4i300B o I''

-. 63 59

va. '83r 'I

2. 3502EWSAI~

4.797+0

.7.0825'iD

3. .. 480ENO . 4.

1. 3 6 E 0

2. :'3 7 3 'E+ (i2.15 ., 17 0 + 1

9.4756E !TIK .21. 8@ +0;,)'

A- 313E+0

7Q3. 6347E001

.j.I -.. 4 ;-. -. f-... I...... . ....I-- + .1 . .. .- I, -- 4 -- i -4.

...... ... ....; ... ....... .

TOTA DECA0Y ED: ACTIVIT C. F' 0.. 1; t o 2 24. 4 k V) Q 00 73, tr i "'-j 1:, -;-!"? '0 ;,:) Ci/ 1.. 1: 1FE F

145.4 %

364.4 &i'

537.32 %

S L 1 1 1

BA 140

to ,' R 4 0

1RB. 3

477.61

604.7 %

D 1 43i TI.,.,

724 114010. 7

117 .2

*Fi

K

'4,,

I,,

1R'' 103 Cn 4 RU- 16"'

W3 1. IS % i I: E -

Pea is par of1 aml ipe an sarawQ

(.AttI t , ol rlWj-W .

EAS ORTE 8 V~ -. 1 T ( 17)WN2 1 G 4,3f,'7Pg

SpcrmFileae Cv\U's .sr\:17431.AnIT1rl,-j

S

Star time53f( (Ti cr0ssIt ioLiv s 'time 85003 **~* ,

Rea time~s 0511i

M 3. I input

Ca I. i raiio

Zero offset -1.980 keVi Gaini2'ý [.'- .-.- (:) '71

.501 keMhannel.

I ~ Ti ý-, J .

S.kr ci I -A ; n l n 1ct

Pea Searc SenVT i. V c t I.

S ample Size,i.

Activit s;~~caling fac~ s~s:tor:)

2.1 Mb

.. i. 0

,-.i energy1 of 583, C.s W e

'[) CRISO methoi-I

1.0000000EM!Additional systematic erivn"; 1.0000000EM].1iFVactio" LimiW, .000%Background widths best method (based on speKrum).,

CorrectI;

Dea d uiJq acuiiio

'f

St a

YESi

Mqlk U :1 ,

.5 ,. Li i ~i'ii/i~ .55) 5 55. 3.5 CTs~.i..a rss; '~5 Int e n l

* @&G OsRTu: G V--- 1 175) WAI435N2 I 1W2 3,G 1:1 31AL. ----2Z''7 1-4.4Z5 '07 F~.

Eerg ca' l ibra~tio normaliz ~ed 3.i I .ifferene .2708,

U NPEAK &'.CE: ROIr DI

CI-. AINlJF E F.INERGY(3

TDF N 7 1F:I FBCKGR~OUN f-(L N ET AREA1

C 0 U N T MITS~

P E l-'EFFICIENC

* 1 AREAi-

S ;'' _J M A1 FR!LJIN- C-rE Fl TI F't ,)FRI [- 3 LD. JF-:F: C-1 D12 1.311A % ke. 1: DEUI..IS

[email protected] 51 9. 78 1 '3. 203,., 2.09!1 +O914 21 .742 [email protected] c-609'.0 32 0.106E0

s F:: (-? a !.,. f3A. 1., t7 !::Ix-t- eII s~~J4s 1.s s ~

NULIC.:L1 DI E-

f F-.j. . . . ..-f-

D E: N Tr 1 FT 1 E D P FE: A KCENT~FUM BAKRON N zr:F~ :fh- ET ARE

E9:NERGYI ' COUNT COUNTS 5.1I~ 1.-f-f-f-f-f-f -f-f-f-I-- - - -

S U N i-i (** 1`t Yl \ 4i*FF.,.*.-...

WlTNlSIT Y U.N1::EE-RT f7LflIICTS /SEC 11 SHMIA~I % Fk .'V

..F-+--- II .-- ,-1 -.11 4 F--J I. . . ..Af -1- f .f I

1L-140~

RU- 10

V131 1

9, )

:7 .. 3

(7L

59

E. -6.

2r7, JS

13 7 5 07

9 7 B~I 078.72

1211.0 ~3

-, 7

6 3.7

2GS5. 7it

... .... *2H .

318.7

1:317

0 4, t7t

G: 21 *73 7

53. 42:

", 11 :, 3 ".

7 i

itI

3.

'7t

67.

I..

75~3 3Cit:?' I

I

-, t7tti9-)2;~i;~t j.

K.'

-7LA~ith~tI 'ti,'~i J

ft

ii~'t'i

8At i ~t

At ~ Ct

3 '1

I-.'

iji.$ti ~

~

F'

'1 7 8

F-- Z(

'774 -; f 1.".Q

258.20

0-r-

137.4

324

4,fi

20.0

275.6ON M

27.0

1. 922

,,t 5Q.,

,13s;

.520

78-,71)

1.24s:

It I., 1

45t 11,-I

-. '60,.i;

EG13&G Oj:RflrC G3 V I C 1.75) WAN32~7 I4WO2.9 Ii I. -JUI --2.1.07 344 7Px ~S

*** S Ui M M A- RY 0CF N L.1 C L ITIM O:wsF~l: C01.31 TIM CORREsCTED

D3 E !H3 I 1\1

1, \COUNTI :NGSIS I L

f5C i/1..]:TER pCi/LITER p(~i /L ITER

+ -. + + -+ .` + -. + . ..+``.+ . .... .... ......... ........ .. ....................... . . . .... -........ ....... .......

BE-70,

FE-59

C .3

.3R-95

I"

CS-.. 13

.I- 144

4C. 467G[

3 19.5'3SF- 1- 1711

507.7 3 F ýu71

32.EW

5 ý,3 2'Eýf ý

3.94117+0

4 .15 Zt 5 ., 1

4.1 11 IQI

Ac ii ty p ,3A3.U3 rite, but& acivty.. DA

U M M A l~lR Y..... .

..1 to ;; 1' 202. C 1. ke W 7, 71107l10L 01'5:./1.. i :11 V I T YTWISI 11TC94YED ACTIVITV ( 5B- , .I t, o 202E. , -,, V , 0 .0......0..:....W ,XA L .Z.3TE'II

%,

32B 7G

13325 %

S 1 U ' 1 333 F1 Y 13

LA 14 36 .4 &''~'I

RU- 410 537.32 &+

1-131 66333*

NB9 795.84 3

FE-3 9 1 15.5...

CE-41 [284,.303

BA 14 61.3 3(

CE-13 7 3 24.19

CE-13 10.77

3 .3

33?

.3/

3,33

33

/33

/3

R- 103

C 0 3.

IL A-1

K /3 ******x

:W .3 4 BA-3 1 40

% Ir A -- 1

Pea is par of a )3 mut pe ... thi ar a

negai ve.~ durin L3IU 33.1 [.333

@ -3ek .3t o ie t F

% .. -3'33L' Peak fail Se si iv t t s .3 3f 3, 3.3.313:3$3 -Pe k i e t f e , but .,3I fi s p13,.th s u li e

fa le one or3 mor qu l f c t o 3333 3, 3,Uf.i3..I.' 3t'UiL

* S ORTE Go V -nI C 175 WAN3t4Iu22 :1'~ 4WO2.9 11-JULL.- 200i7 1 ;v'4:2 Pageilicivrronmenta Incac 14Lj7341-fIn

S~a Qp dŽ eci rJ On!c i p"r xw - J~ --,, . , !, '*5 L I T: E

25 .. '.-!J N1 2 0 ti2 1 .1217 1 ýl :1. C 2~i

ASp ct u i* ,i 1 en ame, .Jc -ý 3~.1 P

Str t imeI

Live tim

MC I inputt 4.

8612.1%

CaI i bratc i on ~Created: ci 4-Mar-20017 ICa 123& 1e -a 2 L7W17I 15 a. :1, 0I 31lyl(,`3 Gom ~e-It"*-ry *1

M1a~in analyi lirr: 2,

Lib ar M:K . !at:ch1 Wit h;:.i

;,54!",'[,oV / clan an ea [I

li~b. 50i?,

An ly i para etei -1

Start channel

Peakp reeto"ee

4 .J f a; 1 an en1g of 59. 891k e

[email protected]. : 2/( ; !.OOOOE+&D*1:.211 1: 21ý 2 .I5

D t cytion limi t it o ;

F I -tý .- J o n L J1 1 t ,, 2.000212%

Bacnkground' width::a best :1)ic mathad )1 (base an spctrumI. ) i,

.eaked ackgoudcorcto

St.c at: Us

YES~I~~ ~ 5, 1V ac;

.1. n11 t ~~:c~'aC N-,I.

EG&O ORTEC G V - I ( 175) WAN32 [email protected] 11-JUL-209.7 1204:28 PageEnviron.mental Inc, r Mf.i 47341nAn,

Energy calibration normalized difference', 1.0000

A.*. .*".'7f.s"-- : U NPEAK C[ENTROID

C7HA2NNELJ I. ENERGY

I D N T I F :1 E" DBACKGROUND NET AREA

COUNTSh i i~JI' CONS

P 1,7' Ai K

EFFICIENCYAREA

Si U. V Mj A RUNCERT FWNl-id

2 `SIFG,'PA -eVSUSEPECTED

NUCCL. 1ID)EIl -~l i--~ I- -- ti) 1 '-t---t--t--~ 1-P- H I' It----F--t+

1217.68 500.86 4.2., 41, .8399E+03 55.25 1.568 BI-214 Di

s Peak fails shape tests,S: e a r' Car a dcc:con vciu.. t F dci

NUCL -DE l NEAK L

D E N T I

ENERGY

F 1E D PBACKGROUND

COUNTS

E A itNET AREACOUNTS

S3 U 1 (l C k 1 Y ..a** a*3*** *fS:NTENS I: T3 Y ) 1%NCE1 RT FiaWHI-i

c:TciSE/ ;": : ci'. SIGMA % .keV

.I.I .~].I. I. ~-t*.I. )**. I.......I...........4.

CE-.. 144CE- 1411 -131'BA- 140LA- 1401 -- 131BE'-7L.A-.. 1i40RU-1:.03,BA-:I 40

CS,- 13 .•4-

CS" 137

N "i, (.95

C)9,, 12').

[ 0,,,.I '\ --5

Ft.NI- -. 5

%j J,..-6 t

l.-, t,LA .1i.;'

269.47290.075 69.80061.5.00659.02728.00951.51973,. 579 1.57

1 1.7

1238.301273 94

1324.85Sa"l,.,l .•-l

1 1. 1210Ia Q1 0

-'a c, .-':l'E15 1. -1!.

2,$I5., 8/!

a. I 1'*1 0B:921 7 B

3:" ,{,

134,,64,144. 9545C

307.45329.473G3.0.9.7475.7548G. 78495. 7

, 14. 7 Zi

4 t

a:1 Ia. 3 a•aaI + 19 ,,.5

{,5 1.

75, 5(

7j5a !7

79t 8

r8 88

:390.1116.

3, 4

606442.

a2'.1.

14.!2.

23

•I-l

55.

5.ý

1 7.

5,,

L.a

I!.1

8.

-7

a8.'

080701716",

.002

.002

0 01'2ý

a @01

a1003

088

A)0 1 ."

121/

2!i :1.

004888

333.6

248.,73

1268.82

-5. 6(7.

179.583 '0 B'

t39

I 14 .ija4

J7a,, 485114:. 8411Mý.**

529,, 15"

230.94

ii,713 i1

a.- 25s* 10t7'

8 4815!Vi

555s

1-;2., 4-4. C as1. 6 a)

83s

: . i s

a: a a9a1 a

1 •i'aC8a)

a!. . 12 3

at., I5

s Pak fails 0h0pM tests,4) F'52? ..U are.a 3. ecoh vol4 F !+',S

E& ORTEC: 6 V -I ( 1 75) WPN~h32 14W:. 96 1 1-JUL- 200Z7 12:24:283 PageWI Si. 1. mnental r~Ee: Incn name-~ 417*341 .A1.-

** i- M* M A Ri Y 0 F1 N Li f C L. I D E S 1 NTI ME OF COUJNT TIM i CO R REC:TED UNCtE RTAINT

1\IJCL 0 Et~ 1 DE ATVTY ACTI V ITY COUNT I NG

E! 11 11 P L ***K

pCi /iL i TER pi nER pCi / L ITER

F.-5

(.. 0. 1 !.5 Cjri 5.252

ZNI65fZR-95I~'NB- W.'

RU 10

9. Pf P2B '3

3.5342E+0

24 4917E+00

:1. 43-6-'A 1

3. -,`1373E01.

I.- ZI 17

6.~~~ 393W"11

S2. 9077' W L

W ¾ 1:1 S l I

TOA DE1 ':CA~YIED 'ACTIVT 59. to-r 2 53 2 4. 15 k~s~ e V ) 0. 0 312.10 Q; 0 le."E -I- (71571 :: pCi. L11IT

32B.7 % L-140 64.4 % 21-71 477.6 &l"

49 .08 & IUd 0 1573 % BA14 604~ n' 1'.7 %1

83.4 N51 1092 &. FE5 1155 %

1291.G0 % ~FE 59 1325 *G-016 8

II

13 7CS-134~~1 --(S1

K-40

:30 .8 &~* '5A5 -140

48 .0 % LI A - I14

61 C15 3 R ".

810.7 CO J

1296. 8 L - 14ji."

?s Pe k s tocJss i l.-1s5,5 j

-, Pe- k idntfid but fis peakn m t i u d

faile one r mor qus-s0 o tes. s.

EG[G ORTEC 0 V - 75) WAJ~N32~ I *WO;2 96 :11.I-UL. (20?.7 1. 8.7 Page

En~ ;viron~men a i. n:c-:I;vui ~ .'J4:,~ :

*X44 2 3. 5 L. I EfP"251 j* 2 'n' I.;f.5 APIS

Lietim 7921nl

Rea tim 79311.

Dea time .13%

Detector Syte

MB1 input

Ca I b a i r a -.- 0

Sto chne 404 for A UU 'r~

Ac ii t scal ring factor !.OOE0 / I.2rrOr+0

Fractio L imt. .00

/ . Z i ) .

WM~oO@.

Peake bakrun oreto

St at Uy ýý]:V E Shf)YES bL,<g% .,! pbu,

- i:-A -- 7 12 .,! :5 1 ;-UIII

'I

&G7 ORE G Vi -n r .i Sp tr1 ( 175 WA3 14 W7 0 2. 1 14-8 7

Ene g ca ir t o no m li e 1 d l1 55Y AI:.i.ffe sr' sNoa, uink1nown pak pa se snsii ;vity test,,

. 2433

1 D E N T Ir

S111P11\NEL. F'EN! E R 0Y

F I E DE'.A CK G RO U 1T[.

COU..NTS CO:UNT S

S U. M ("j A R Y A*~@*A*~~

INTENSITYNC r r' ..". . RT F WI-ICTS / 3E 2 ~SIM X k e 1

f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f-f +-+-+-+-+--1- 1+ ---- 4 ...... ..

CE- 144

CE~- 141,:

P111BA-140Z

LA140.1Y

00 ,1l3a

[Ba-7]c'

P' L)-1 lZfIC."

F1231.

I .CS- a13

Z N a)",

411.5i3

1377. 10

I;0.71.673

1327.1

3. 1')ý'

5.-,Q1 4 ZS

1595.6

211..1.,13 a . E

0~~ Qi

*iJ., 5 :1.3

.4.3284.77

305.7329 92 '

52 3 5. '

1. 0. r'3

7

6'1. 1. "al.

*1J

5C) a

27.

10"

41.

'10

12.

24.'

67

25.

18.

17.

13.

4F .

a'.

1210 1.~

0002/i0210

.0212 .

.02' 20 021]C2 )7

143 W"

1. 7 .it!-

379.9

12" M

:1.19 5 1. a

74I.5

5 9a

71. 0

0 0'! 1) I'

.4 2-) -.

70 1.,

"4 6,

OQ) 10

al III a±i' a1 I" 12 C:: a:1 II a,, '1 1 1: 12

a aU ý --, !"I "tI F.YE; F %' i C, 1a- *'I iM''-- DIF Ca 'l-N TIM CDR i .

D11{ E ACT 11 V I T'Y ACTIVITY.

p C i / 1 T . S F a, a 112.

.. '. II.. 1, a ''a '.. Y '8E+W i

1:1 .k,1 a

7 ~ ~ 4 5 Fý: 2.

Un 1 '!C - Z ,*41 kI a1,'

COUN1'aT ING

i::'f3 lxi F'

(1' ~I (2

Qi/LI:.-r p.I:::. I . I: ! .. 1.1.

ES&O (RTEC G V -I. ( 175) WAN32 I 4WO22. 96 11- JUL.--200'Z7 4:~38:47 PageqEn v:i.ro nmeonta 1:::ý G peoct I- u fit 4-734J 1n

3

U'O-60A7ZN-65

.R-95NB-1 95fR') 103iRU- 1061-131.CS i- 134.'CS- 13

B -1( 4 0IJLA 4

CE- 141OE- :144

/

4.

.5

/

3. 31S.O

1. 22 G t I

35.167.9t3E+00'

6., 139E6917

3. 33J6CTiOi'

1.1224E+01.

6.2437E+01.

M 22 '1656E +0 0

I 63912EW

*711.216 21

MD ' V alu pvit- InteAc i.v it;y prin~tedct, W EuAivity ( MDR,

.r .... ..... 'I' U, re M5 A Y9: ... ... ...... .... .... ....1 - .. .... ..... ..~A k1..31 I Vrr :r T FV 59. to 204 1 keV) 1. 0o QV 12.1 '007.1+I1 pPiL.

133.5 &

328.760

834.94 & it

129.0 % /

S ' 01 i/iJ - 44

LA-" 40Nfl10:

RU 10

45.44 & 5.

364.4' %

1332-50%

0 1SCCE141~ii1 -13,

DA- I1.0

1-131rjNB-95~

FE-59 V

284.30

477. G I

604.70' C66 1 . SE

795.8

Ill.51460~. ' r

9

I,'

IDE

BEl7CS134

C a -13

1"1-'34

ZWI6

7i""'!Z9 18 % ZF

1 *3. 24~ 1(1 0 I

is rIt -fu >

IS Pea 'i .to F ' 'Is H I c at I

EG& ORE - I ( 1.75) Na WZ2 1:1.. Jt..JI_-L!Q.-a17 1a ;7 4IP

E. n v i I- f-, (. ; m e nc t 1 :' a'~ 1; 171, nT (I. ar.3.

TXW-123 A54 L.I TIER-JUN ~.i7 :1. 1r'j IY1

Spetr m File1 n xiii 0 \U ~ er \5727.'/' n1 :.

Acqu(31 i ion norHwtin

Live tie B82 1

Real ~ ~ :1 tie88 ,:ý

Doeaid t-:.ime .01%

~A/l

-1"'

1. 000 G

IvC 5 E I' in u 1.

(. Al. I Vr. ?- n10 ,1

Cratd 19Mr20 1409:29

_," Ltoc: wate1 in MB'111 .1 : .19-1o . i . 1

Zeoro ofAfset3 :E_ 'ý 7 ke V/ ic:.-1Iiovii n el

.492 .M /ch:aonnel .

Library F ile

hAlrd.T1I 5-r 1 4 1JA:; -- a. :

Pla rejectiono lee

ID 0 , (-.a ;r- 211 0. 00 ( j. i , . v I. 1;f

Sample S~I0 3izes:

Activity scal. ingi facvt;or

2:. :1 .5.5Mt,!i

1 ~ V Fo n 0 I Q 'T r y '1 OfI12 (. .. energ7 7~3y Of

3!0.000%

65u. 9t 1Sk V'2231.42M

3.50?

::::; , 8 571.,-'+

e ;eC ln1 i J Ij, .. 1l :ýt

I t R '.IS methodi iror

Correct

Y~t (t ~J Itlil 0:it

tPi o

11 otat 'u

I1"K

I) ii ~ 77 ~;

I~.I ~it. ~s

EMS O RTE G V I: ( 175) WAN322 I 4Ws027. 96 11. i. -Ji.:.JL £717 12 27.467 PagE:~ m v .Jr ir3 e v- t O, I I ii 1::) (:- ct r-. Hi, vfi I e,-0 7 2ii7: B '.F nnY 1

Energ calibra t i'' o I .n n ormai zed3 oc diff...I ' -rey 1ý 1. . f17i 17 0 01

A~0*;.4*I D E N~ T. -I F I E7 D2 P El A K ; G U V1 41 A R Y '1**0

NU CL..ID PEA7!~K C:E~NT ROD :i AEiCliCvsROU1N NE A:C~ REA I NT T N:- 1,1 j'*",' UN1\ C': [_ F' FWHN1,7r:E3p3Jr\E N Ei:RICG.fY COUDLNTS COUNTS~r C' * r / FE__C;

I.. . [I+ -. +1_-. 11..f...,..............I , 4 F I~ A---.............. 1* - + - 11.

'•'SIGM keV

1~-C 1. 3n21

1.13

I. 'I7 fLA1 403 /

RU-103''

z 11 lii!'.ý'

Z R, 95'~'I' Dt 5l

r1.'0 r

rtlk 5

F" 5C'

Z.P. I

65.47 (I

7;)!. Oli

1 14.3 II

I. i'_' 0 . f" .

1.1 19 /. 91 9

1 ý'i`4 47

1."-,2 1 6

*15 11 1

304.4 1'

3'.`41 '7(-.:,?

4837.0

541. 3".

-67:7. (h9

/4 I 7 17. 0IZ

13F

1 17.

37.

0.4

4t.

171,

4.)

17

217100

.2112.11

011

012'11"!l17

01711i

.002 ~

44. 2, 111 . IG:U, 7. 3. J.1

V.35 7ý;:. 819.

5. G'.- Et

5 1. 1

:31 1V. 77 4 IC

12121 . 49 8

8 .36 1.1001r3

52 7. SID 2

33 47/ !.'

53.4 '.755s

r.2 ' F/.4( fV~ a aF t S(9 P3903K 4~~*'0 :1. S 9K:~ ." 1k71: c

.1/ 4.u NT 34 A~ R Y 2 1" NI U. C! L1-1171[I t:): (.(.F ) 1,JNT TI MEi CORRE I~cCTEDI:

NU..CLICDE. ACIVT ACTIn~VITY.

f) F' U; ::: N1.3I\ V[2 hI'i :~

5 '' !,! .4 ý" L4 . ý

pCi/LITER Q ii/L. I TERf-

B E

['IN - '',

F E-4

3022+1 3.7932E+031.417

EF&fG flRilC 0 V I ( 1 753) WAN~32. 141WO . 11-3JUL-2007 12:27:461 Pagej c

1*12rviro.nment a I nci 5pct rs-n:rne 727!.AnlI

ZN-65 <

RIU- 103~~:RU-10.61-131~

CB13 4

CB-137l

BA- 140li

LA-140

CE-14

E797E/j&b

3j.86? ii

* F3EM

I 2:1-,l t, 2. E -+ 0 1

Q~ Q7445 6F+ 21

6- 778~ :1 E4P00Z

4.52442MVLH I

1.0084E+01

* /.4621EN0

A Activ' ity prntd bu rt act ivit (. MOM

-...-........ . ....... ........... .... -- IS M1i1 ,.'1 R Y. ....... . . . . . .

TOTAL3 ACTIVITY 6 . 9 t4 2. 0 3$ :1., 4-k V 4.) 0. 01 0, 424 0 1": -1 Q41: 1) p i / I_. I'1 YE FPTO:TA:L. DECA2YED AC IV T ( 6F]~ y i F,5.9~lI to 2031.; keV ~) ,,4237 (7l7444 i(K "I/ T Fý C

8 4.,4

Si U m m

CE- 144A 140

A~ R Y

145.4

FI

BA- 141-4 13

NB-95~~'

C ' A 1 )284.30V

47.6604.7

~111551 '460. 1

D"I

I"

~.1

"I

/

1r '131. 84 % 1B A F-

CS-r. 3~7 7'' . l &' Z R-1k ""

Peak is part oAI fj a.. jfult ji.41" and this I4 Fr~

I I -I Peak idnife, but~ 113 frt ~ oF th44

4'fa led'' .1 I4 i one orfI3 mor qu l fi a ion t s .3 ( A34,.' ri ;>

*) - ~ Pea actvit highe thnE'Ycoutngue i yrag.

-f4 j 1- Pea ac iyt lowe than.4 con ing un n o~t range.

-. '. Pea waffd an ly h enryrn

1ISEG RT.6 1 ( .75 WAN3\2; i:4WOJi2.9 ;Ict1:-JUUi.. 200n~7' 1TWW I Page~ ~~

En io mn a :.

I X',--ý,.I'4,'?14 I-I ER

Sftartm

Liv time

Rea time

10 5'Th71 3. '

10 2 .

5'1~

,-. "J M 11

3. L

Zero offsetc 1.ud a J .-

E797 We~ Boa in T .49213. .3.cane

Library.;

*n e- .

2. i

1;ý . 3A'1` i-of"J

for 1 I I~ F1 2237; 7,

;~3K~33l: 000%,V

W ¶: 23 W 32i: . 3 O=1 2.8 5 12 E + V`

rnnk 2rro11 13. OOV OEO'

Adi tiona' l s ta ti:)/3; 3:'I :32 er or L3 1 .0000 00E:33

Decay/I durin wq istoi

Deca Tiing

Peke bakrudcreto

St at U.71. III .1 .7 I

:L;7;W23'333u

&S; ORTC V - 1 175) WA3 140102.9 'E *JL-~it ~ 2Pa-ejv i r c± n If en t;a 1. 1 iI S p~ t. -,- .ti i n -. 7 2 ' " P.) .

Ene rg ca i .~ bra~t rion normal~.i i. chd. -f Fr

*******U 1 DENT 1 F ED P! p F P. K, S U Ivl11. A! R ~*n~**

PEAKP C R ID BACKGOUND ET AEA FY P PEPC Q',: .F~ w 11 flet 5 It. 'i r IFI CE c17,'

1 P1 t ~~~~~~~~",, I J CtE~4 .7@, : ''

1: D(.h4 E~ N T 1 F 1 E D

I'E- 14. 2 8 '2). 1/173 1157t,,

LA-140F 64.00 3 2 .A- 7

.( ... 7 7! 6 4 7 091

L- 14 97 .0 471CS1

R !.1 11 (" J Zi Z .. 0:I,8

CB-13 1393 65.7

7*Fc',;..-z. 7 ;-

z IR 1 3,,.18 2., -.,

P: E: A K

.7

7,,

Cr B, E C' I Gh11i~l % k eI

.00 17.4 .01

0,i1 1.. C.

J.II: 1 2', 0

Q~ ? 1 1 1.* 7*,YV) ,1

f I 1. 17 CO91

A~~7 *3.

1 7/ ;'

.002; 749 1.75

/i . 7I11 Ki 81 s

J ( *~ 2. 1. ~ T ;5

T) 1:::1 c,~' c-. k.iII* 2 A ~ 5 ~

E(3&( ORTE:C Gi V. - I &. 175) WAiN32: [email protected] 1Ji i-JUL;-:0Q7 15:2008~ pag "IS

Ci U M 'M A R. Y 0 F, N!U EDL. I B .E.i S I N1-11 1'11--c~ COL.B\T T IME rz C RREC~TED IJNC:E: 4'Ty

S: A 1P .

2 :3 1 GM (1NUJC.I DE":

p i /L Ii3:n

AICTI VITY

p C i / L.. I TI E?

+-+-+ .111.1 +-+

BE7 A

FE-59

RU 103

CS 134.~

CS M137

S .4 145 E-t4'1ý

N'4 176SEW

2.274E' 0

4.394B~1/

&rr 976E

1-*-. .I. Q!

2.7.59GEW.

th 005*E+0

2 -i. 5

Q642E ¼',, ,!

3. 13 9 1'Z:'I ' '9 'W -

24 04 2EI " +05, ~ Ilf(4l~o F. i L. I.C.i

1iT 1 . ( 1 .C Y .. .... .... 1 1. ........... ..~ i ... :2.- -

335 & E 14 145.4 %

53.3 % BA14 64.0'

63 .9 % 4-3 6 1

7'579% N -9

109.2 & FE-39(

1 1 1477.61*

CS-13 72.4

K- /~40 15 . 8

1)

"/

P. E~ A

BE~w7

'rUv 4.4

ZR-9

L A 4 1U"

Un 4 %'A 1

'72 % Z 4 14"

5 9-i

Peak~~~~~l' is PatO amlipe n t re et

neat v du in dein a4to .

@ e k is .to ok al' [:::, (-fl11%1.~'

*I &zES ORTY S V -1 ( 1.7M ~WAN32 14WO2.95 1.. JI-L 20u0l7 :HOOK4: Page~vi .. e ta !nfc2trI Ti:::2 :374F4 1-A-Il:

Spctu Fienme M ., 2 '.U e 37441.AW. Ik ( 1"0

1eetrGo~r 11

1.:1 *.~ 1-3 ' 17 3f;530267241.

725071.

(12 12 22 C 4 12

rA t ~.2;

1 1 1;'n .A i

Cre ted CA Al"''-2i71717 1.02~1:31. ' i~ h ~2@:2~7 I 4. 2 53 43

Zer offset *

Quadratic;-. 1 k A GaIin

.125hIE-027i( k V !chav&'nne "

.500 keV/channel

Li r r Filw..,

c! "...kIA ej212

Pak reecio lee

Pea lero seuiuit

sapl S 1e

Actvt scain Factor

1.P an7 A2

.. tI'*~ .. A.121 I~i f* .3, A IC JX/ i

2.57 1EM11±5Detectli li i method,,,,

Additonalsystsaticernw

F r a c t i o L A ''i ''' 0, , 0 0A V 1 1

Bakron wdth bes mehd (asi petu)

17)I r C. c r , nA II c i J', L : i; o f-,~i

To a Iu hn VJ mAit.Irti m i:( i~-CftVIN

Comments

,, :*!z!i!7! :A 4A

EG& ORTE G V Is ( 175)~; WA3 14W2.9 1-JUL. 00 1554:1.4 Page4 2 0

Energy~~/~41.i c lib ai o normalized C flOr differemoeu t~n ' :1. 00

PEAR CE:NT R O ICFlif-) 111*11 .. El'! ESSRGV

1 f) ES Iq T :r1 E 1MWGROL~Žj~ UIT) NET ARE

COMT C:, EOUNTS7

P E A' itEF~F ICI ENiCY

* ARE

Bi U N1 11 A R

Ui'. 1,4 C~ [1ý r EU 7*i2 S .(3MYIA I-, iTV

Y T*~ *i***i

SLIC'"ECTfEI1'1LJ(C!.TDIE,

703.37 315K 1. 4 GZ 9 .5., 7.397ES+03C 45,, Z'5 1. 1.,4.-5 PJ,-3 141218.10 609.0421. 126. 1.48ESS04- 205 . 6 -V41

tests. vo o

1 1 E N T/

CE 14 26 .0 13 .W..:7);1

CE14 20. 30 145.071 1G.

1-31 56.0', 28 .4 24.

1 - * ,13 1 ~ 7 ':i t, j, 17' "1 o-',1.1

DA14 107.0 53691W)

Cir,* C1j!..!

011

B U Al M r;IT R. 'Y H

.Q I Q!IQ 16 3 3 I i

0ý.'12!. 5,..4

ýf'i F, -Ill" 9 .

5 1 ,1l,'l01D

Xi. 7.I"

0 I'll 7''. ,9 : . '

ID1

,71j~

.1~ G'... . 7~

* G ORr~CTE~C S: V~ I~ 175) WAN32 3:4iWO2, 95 1JL 07 55 4p 3

Si U N IA PRY: 0 F N U 0 L 11-11,1E c~: COUN 5T TIME COR:RECTCED

NI.CI Di E F1 T I V 1 T Y1 CrT IV I T VUNCEART4sI NiTYCOULNTrCING

S: A P! P: L.E2 S C CS

pCi/LITEl

.- f ..f .. . . . .. 4. ... .4.4.........4..f ..,.,.4 . L.. . ..

BE.

FE-591.

3C44.58

CO-60~L

ZR-9

CS- 137

1CR 14

12 . 34691:1-47.

3..

2. @14 'EI .

EN R5SE+0

3 .2197E;01~KL3 (742'.;.. !C

+:C 7C:

41 5 -.̀i'i'4-1

Q 54 8 00

1. ::? 49E,: V,

593 9 0P

331 3101.E 4- :50 1

2.5004+0011

G.2795E+@7'l.300749E3 +011.

S A76E:;3:-,..C.

A A c t v i t p r n t d b u t a ut (. . . . . .

TOTA A4H T 4 ,., 1,o Ci4' ./ 4. - ITOTAL~ DECAYE ACTII TY ( 5.9 o22.1 keV 1.69161GOWN p A>/ ITE

13 .5 & ' CE 4 45.44' %~

32

8. 76. % L7k!4 36 .1

32 .4 U 1 OS 43.9 &

1-13 477.6

FE -5 I I11 . ..,",

1-13 Z ~ 8 4 & . 4 CIC.

BE7W7 . 02 %I' L A- 1 Iý

Pea is; par of: a 4.. multip..;l. t and4~~ &p,4 avm wen,.4'4'.21

a.4

EM RE 7 )WN2 1W2.6 1-.2271 0 :4Pg,.Environmenta

C4 c~ I-J f4,

re

Live time 7 4 01.`

r ('I LIseaetry DS 0~ &

Crat& 4 Mar - 2 0 07 15 41 `. -, M a 5~'4\-~217 1. 1,717

3.,5~:1 i .in ..

J'. Hýi I Y 1 j

i ** " !!*-kt C1 ' , Ii, J

in a I 'y i:)iA" A .ill0t .,V

td C., a -1-- 1

FwakI reeto ee

an enrg of i Wi. 10k

!.OOOOE+06/( 1. Z

d. J i. t I i C

Frc io *Li t I .000

Bacgrun width bet at

Correction St: atv~ u

&S3 ORTETC 8 V - I:( 175) WAN372 1 [email protected] !,j.JL.-;T003Z7 16N022 14+F Paeil n c vi. vo:nmin c anc .i7nz : nc r'- ,cn :041.i

Enec~rgy'~ cal :ibrav ~t ion n orma: i zed c c di :.f ferev~nce n 1.3AC 7

PEA:3K OENTROID1.1; D N T1F I Ei 0:

B3AF;FBROUND~Jj7 NRITE A ~RFEA1C D, U Ill, .-r COL TDU 1

P: E: AF FF FCE:NIC Y

xAcnREA 2Si~ly"ID % C/nY

Yl : E FE

70.2 3513 65. 108 975$.2s79E+03~ 5:o, 1--s' i. DE.-' 421021.2 50.0 58. 1.50. 1.70GE:+0/ l.7. '-,7 :7.i- L 10121 .0 'r: 0923 09 129 7101. 1. 2)1 5IEc+2W i.2.5 :1. .'7 BF 1 j 1. D

Ann:-~~ D3 E3~,*.3 ~c *~; 3 :F N T 1 F: 1 E :) PNUCiLID PEA C E':' N~I:: T' C R OID r~2c~ I

CV-IF) t1I'll IF. 'WENERGY C COUNH'TS.I . 3 ,. ..ffl4 -+ - -- -I - -- -E- -.. I

COU F LNTS3

U3 LJ I"! 41 A R Y A 33'3*(

OTS/SEC 2 0PA % 33e V

32E-141

11731

DA- 141CS 34

CSl I"37

CB134'I'

E.3p

0 Pea

268.39

291.75

'3 ",. ! e

970.43 3,

:132.70

73.

134.29

.. 7'7. 3 [

604.3 7;'.3

lil' " ".

33 3 5"

63 TGI933

73 2Zi

795 36

II 3

.3.3

3,3"-33".,

:23

373

33 :

I 13,33

33

II

A.3'.3.

3n3 3':~3

('i 3333/:3.

373 C'~27~

3733;:)::3;33 3;;33

373323'~'3333.333

33 33..333 3 3373~:'3r33333333

33333333

3/33.333/333:33:3/2

3 33

.3733/3

33 3333,3

33* 3

3~333,3333, 33

3333 33 33

'733~~33 .3

32373

3/33 33 3

3333

333)33

16 . 3/ 1 j3.

: .3 4.C 4

1. 790i3

44.1 0 0 03

179.17

9.332, 611 s3

,2,/l / 17 3/K

a J, J.37 3333': ': C33 2

area.'3,,.'..ed

EGc~&G ORrEC G - 1 ( 175) WAN13,2 i 4WO2.963~ 1.1-*J1L-200~Z7 160214 PagejE~nvironmental in.-,.,~e~t u a'm (4 L inI

S:

SU M 01:(~3 FT 11U C::T.11F'! C'(ZUIXFT I M CORR ::ECHD

~:Do A CT IVITY AC1 VI~TY

1) E: S I NL\IC [-. 1- TiI N ""

UMUIJI\V

it A 41 L. E.:

pCi / F..Ti. 1 pCi/LITER ,K:1U/ TEE P

ývll"(... 1-Z+ ý,33, 5 :. 3 (.ý f,"

(::" (/'.j 3-./ I. *`' "; . 5

/11 7)- / Cý:Qr'S 1.'.;3 . e<

R-953 t 5.3500E+0

1\1 B .3. 5 .3.3 +F",-1 j1

RU 10 1 '" 0:1 12 L 1 "

Ft' .I 1- 4. 1 3 1Y

LA-140 1 2.2 1 935E0

74,1~ SEit5.5 1 W-137 1

K 41EW

6 E+

0 E 07

1. 5 71.493E+01

W" 7247E001

.10546EW1

to) :2024.4 .eV QI 17 ~.1 70 (0E-i (Z.10 i L -1..i I"60.1t3o, 70 2 A . I-'.: k 3 e0 02 Vr I XI IZ 0, 0. F 1?1

3& *~ 54 3

328-76*

497.08

13 U ~11"CE-14

L3 A3 1'53.32 &

6.36.97 %,. 33

76.7 %

.)"!

1332 50%

CE14 2430 &-~

1-3 47 .6

373.4 604703 %~3~:33

1-131. 661 .66N-S3

K3 1

Puak is part3' of a 3u e and-00; aea en

negative~ ~ ~ ~ duig3cnvlto,

$. Pea idetifed bu fis pea 3Ft

faile one r mo test.,

S 0:.c R T E~ Cz S V - ( 17 5 T ".4. 35' I4 G 11. -XULW N' I &, 47 .

viron enta W .: c tI.Iii'l r ,' - 1 1

W.---4127 1J'

Spctu Fion me M 'd~w L Is. .3.Ar1C

Star tim

Liv t im

3 0 1.*- .14 :4.1.g 12:

is `.-

Deec o ys.4

1,1 !,'I3.5 Liter in WE.

Ze o o f et-10.e ; G i

5C1 K't !"I

Stop channel -.".a

Pea serc sesiivty;

Sample Size-

Actvi5 suain fatr 100E

. EW keV/channel

.s. 1.

I IlK Of

3. 5 0 0060 1.0000EWN :3:1 0 *,

2. 5~71E+01E -

5a e t o limi t5' .o. .

RS O methods 5

,* .

Is: ' ' , ,5 '5 ' .5,, ,5llI5?~i5..5.5I

Additiona syseai eror 1.000000E+0;2

.rct o Li.w,.iO.~. rs ,

corec io'

Peaked bakron corcto

W),5

YES

.I' 555;

'T ?f *.'

b. k q4 pb.:,

.. ' 5 .5.5' 5.5555 5. 5

ES: &G ac O RiEC G V. - 1 ( IT75) ~ WA 3 QW: 2 96 11 ii.-. Ji JI.- 2 127 :[ !1 S:;t~:E v ironmental3 1w,1 473-.',*

0

Energy calibration normalized differenceN 1 ° 2%002.

1. i (,:,i q j I... ENERGY~: C;OUN.WJTS COU3:..NTS AREAP E-1 CM1P1 %l . V NUZL, I Df"C"

1 1. 3 . zi f.,:3 Ell 0 S3 . 2 E, '4 4 '. 9..221E+03 47M1 1.66 L B'; I-214 C

r-.Lj(ý..r . x1. D!:r ! '"? A ' NTR U,[1-C1%1NE ENE G

F 1 r'E1DBA. 4GR A..

CUNTS:(31

P; E A itNEI' AREA( :

COUNTS1 NI-1 ± I -1'

1-13 11] 'i -.-1.

LA-1 40

.2;13.

CS- 13

RU- 10

CII104'I"4 '

ZR-95'

26. BA

29.0

370J .4

11,j 17

1 1. 4,,, C1

1446.7

D*i! 1 7

1 4., MR4

327.43

604. 7Q.1?

61.3

622.904

63 .E,.

724.4

I VI255.

1133 17.4

0.4

4...

'1.4

7..

1.

00 1.1(

21.1 17.

7ID

0( 011-

0 J.117

;DFlI

G "4

•,25

I 1 (88

68".32. 136

125.98

12.700,8

...................................:.a....4(4.448

'4 o I

4e. 4s

:1, .

4~~~~~~~~s 1~I2;4 '. 4 ' 4;; 4. 4

EG&G6 OR*T(C G V T. ( .175) 1A)N2 VJ 4 2. 9 6 1:1. 1 JUL 1710 7 :1. 6, 5

6 U M [A.~ R 0F NULCL I DFE I NTIIT.(*"I t- :: C0L.pN T 1- 1 O CCI REo 1-'.ý1 R"cc I" f-i I N11 N

A 11 P L. E ;~. .~. .~. *

NUCL I DE ATVITY

p ~/ .I::

COUNT I NG

;" C ,'i .... R.

FE-59 <

CO-58 KCOI 0

ZN C-65ZR-9 A~j

RF..'0

10(tE 141 1

C -1 44

I. I'l 1 F W

4.881 ~1E-(1.';f"

.t.222E+0

j (1;:. W2 FEME!

'9( :. 4~ 9IE + 0

OL¶5: 54EM141.1

1,36 2 + ,.

t1 J. 37 1i ty 1MDAy. ... ..

Ac iv'i.ty9 Fr II

TO A CTFI VITY C 759 ).9 .to .,:11V5 51ICi 2024 1k V . 0 0 0.4.IDD 5:. / L 1 T E. ~ F-*)

I33.5 &

328 M &''

49.0 %'

I, U m

CE 14

LA 141

RU-103. IRU10

ZR -95I("1' '

to* to 11 0

145.44F

364..

537.32''

D I SCA FT1

1-131' 477. 1 &

DA-10 60.70 %i

'F E A it S1

11-13 3M 8 A 4

BE747 0 1 QZi,

B13 610 33&R-13

% ' -7R .1.11

Peak is par of a1 ,'~. mlipltmiti rawm

neative ,

t'oo ' ' iF~,

@ ea i too wid ok F"1.1K:.

EGM ORT F) V - 1 ( 1.75) WAN32 I 4 WD32: H-JULt 17 IM044 Pa e

Eniomna lnc- t7ý3~~~in1

(i 1- .!-)t J

rXUA 2 :3 1 LITE; 13Y1FZ

J TU ,4, 0 I1

10

Dedtim

DetetorGeoetr Ms:1

M I 1in u

M I n m gd g1.MLCreate 14-Mr-200

V 1 I. 1r~~~~14,5:2~7 I 3,4 .1 1+ w 3111

Zero offse -1.9 ')v; 7; nC :. C 7'');~Y12@E-0 ke / hanneM":

.501 keMhannsl

Librar Fie-,,

Start channel

StopH1 chne

Peakrejetio lvel 3Peak~ ~ ~ serc senitviy;

2apl Sz

2 . 2) l

F(:)I" an -' i1) ::7 5¶715

3. 501e'' .'ý; ;~ V C

0007I;,--

1~ ~ .. 0 0 7; 2: 0 3 -F 0

Additioal systmatic erorg i 0700%0EO2.

Pra:tio; LWO .000%&.

Correction

St at u,--,,Y EYNI ;']Y ET.", 9

1. 7 -i:i 1:.I v - -i" 0 " ;C*-.';.!. ", '.'5 i*ý*'I

&VS\@ Rr .C .G V I (1. WFN32 I14 2. !2.; n 1m -Je L-207 17 1001,1 441- Pa•: e ,2:

Energy . caibration normal.ize ,, 1. ,'614 11.

U N.. I r E .:t. N .T F 1 E r. P E.. A le, SOO IM A

CI " ; I '" . . , ! % I., I ' & I M L-' 1:.,I' ,: E

- 24. 79- 511. 4I 9A,. 157. t.6,, /Q), '1 .'-HI 4 .f i, ,-38: M E ' ?. a. 061 9 r', ... ..... 5. LIIE B1-214 D,

a--re'-a 1-2 f.'( f

~~*~ 1: i- ~-*-~ 1-1* In- D E N TC V I F ifE ) VCL, DE rPAi: K CENT ' O ID .,.,.,- ,. - ,.

2" /'~ IS

xi U: 'r (.~ ri u.:o" : 7 '4 r7 U Il R 11- in-

CI --IININEL..I EW. ROY F,.:NT 53-....... '',.'. -...... ....... ...1................ -

COUNTItiS CTFS I, T/ [:-:iC.S., .... .f ,- . .- -4 .. . .. .41..

FE- 144-I

LA.•q- .I ,40. f

1.3' f,' ! -. I •Zl- ,

I f~-' i " -t' :

.S-. 346 -.. .

i f ?3 " :' •

:14 N"0 .-

CS",-134T

2 . 0: 5 i'-

.f,3 8 If:I.

1477. 91"73, S '

. 1,1. 0,122S 21':i:;" ;

f " ' I " ,'

6i Z I Z ' 1 ,. ;. ..5 11. 0, .1." "1. 59A.") 00:""

E,68. 57.IIA

;5: 877 J.7!-'. 'Jr .. '. 9 , , ,h.

62 5, ':§, .•<

... C,., l , , 1

4' 4. 05

3 1 0 .O,.".

• ,+7.L7. 9,t-.+,

!-,3 •7,4. 5 .:-e.<.i- , I.

610. 3.

'""" " 7

6 Ii

-7!: 7 G,.7•

81 En 3 2

I V i.

J -•q .; i r

1~3W

41.6

/2M

7 ' ,

7,.•

Il.l

",

7.

3,6

l/'.1..

'ilt

!'.2 .

,, 1 .2I3(:.•

oo 12J~I,:

S!#12t11f 71,1

,, 1144!Z

S1 >1 .'4.',4

012 i:1. t

;"1;7-i.71;21121i

C) 0.9:"

7•i•.'.2

i1' .17. ;7

.. ...:= "

6• 1I ..7 ,, /

F'/ ;'; I'

. 1 J 5

`:`5, 3. 3

-i••I 4j2 "1

'1 7

I:1'. 5 .

6I.':07:',<'.36

!i-;'7 ;i Z. , .'7 7"e.85.1 !7 5 : ,°'

5 !.5:':ii

17 '•E , ::":

.'e V

875s

:1 (3.3 ),,!,, 4 7.... .

I I'f ",6

380',B •i

71 :.. C "I s'71I i~iI!3 ..;

A0 I 1 .. :.

" '., J

; '/73.

: i. 1]'¢T I

1; Plat11. f-Win 00$3 4.:,i~ tests.2

[E:1 *oG G~v V - 1 ( I 7¶5) WAN32;E QW0r2. 96 . 1 ,TUL -20077 1700:1 44. P ageEnviro m n a I nj~ c.,, . 1-74i,,.2. ltl1

'3 0

1 U, M -) !R Y D IF !' I Cý L. 1 1) E S 1 14 .1A.M P L..'X, ,• ,• <7.- .•

N U["; 1I DIMI* r,: " I V I "V"T ACI VITY

p(.;i./L 1T R

CXiUI\IT I N•t

C-58 1

(u-1 OG 4~

CS 14 1

CB13 1

BA-140 <LA-' 140(

CE- 44

.1.578E.0

4.097E0

2.60!vD:1.67 !E+0

&BB.7EW

khE47E.

r.5 4EoM

T3.8637E+u

9 E,Q"34. N1~4

&1 7803E? ;00

it 7064 E+04-!7 ,

& 54 2 '1 E+021X 808BEI(2

1.~. E1 I**'*

962GE.02[

S

toL Aciiy rned ut act iv ity- MDCV,

,TOTL.. AC44TIVIT Y 587., 1 t :7 2021, . 1 k e 1, V)77I~274 0.7 000 00 - fA /L . [1 T P+-,'R'''1 ''U D CKAYED ACTIVIT f 5~ B. I> t. 21 2724, G. 1 k e .V 7u ' I : -- !-21,71 ' .-K' i. / *:'1 1.". R

521.84

1'4

-- - 434.48

G36 37

76.7/,

A,- I Zi17

N! 1'!." -.. "'3 5FE-59. .[O,. S

28,S4.. 30•,'

4.77.6.

.-A,14. 70

'.G, 1. S:,G••, •f

ý7!1-131BE-7119 - 1 ""ý 4CS- 137

:304.~~I 84& -. 4,

" 4Ell 1 4

Peak I Fail sensti t tent.

4 t" W.4,I 4 44 -

S

EG&G [3FT'EC S; V 1 (3.75) W3AN32 I 401021. 96 :11 .3L.-2f7'2,71D7 3 .5(F"I,, U" F " ' F,-", ... ° I ' ...- : , . ..' r U'" :K.U " , r _ -;.n]: in-! A . . ..

I

TXW-' 129 .5 LITER.... ' 1 ~ '5. "z'z'v "'= . ...0 q

.S'pe ''t 'um i: : ] iUI( CS \l..FF:iF rrh ,,5728'1 W !,': :

L. i.ve t:i me 82'?41:IRe al t.;i me 2: •.'4.Dead tim .F 0 3

.F.r/ e me r 1% F

FI> ., ;`]!:: 5 " N

B ; 5 r' In:put;

Ca..• 1 .:Lbr.at :i an

Cre d:. .9..-.0-.:.7 100 29 &. 19MGF Ii . G E IMETRY

Mar-2007 10105-`'ý

KPO 'fS

'uadraticF6.,79"7 keV... ; Gi:':i:.n, : , ' 7")..'"'V•., '- F • " : I. F-'*'] m.•. 2 :: .022 WVuhanA.

FLibr.ar F ilPlIa:i.n a ,,naliys•i s ]_ i.b r'ary, t,

•:.'1, ... .... ,A a ., parameter-,,. ,

ar. '• channStop hanne

Pekreetinlee

; i . i 'F, :.. 'I •.

440'i.'i f:or" a~n enw-"g"•':y of.' OR 0:3 .•;i 4. 2 k<..•"'S ".: ' u hlt

0.'I .

.... .! I ............. .li: ~ 'U .. .F'... .V•"v" F~ I

Adi: ua sytmai wn:1

F aF '' ý,, - FU

-- c gr un .. id.h bea me ho (:;-'].::: m. Om"ctrumhII gY"Y ::" , ,..- L•;hI:F,,

F ecay F: :ol:F] e : i.,

Pe ke bac U' ,:n, c reF- ion

<" F F

3YEiiS

Ni '[11 ,

YES ;'

0amU ;y '1s;.:: 7 "..' '.. - ."> : "'7 : .I. F"

F.... ...F K Fj i~

JF:"'I-<"'. ' T-1:',':

EMS OT1RTEC G V - I ( :1.759) WAN3h1C2 QW02~.9 1.1 JUL-J200~7 17 :43:19 PageiEnv ironmental. inc p1:t 3-.H >J3Zi

Energy 1 ca ib a ion nr mali 3;ze Cli.ff' CC il 0 1. 00 4.

No33 .f unknowni~f peas:~lC p:assed sensitivity.L test.

2 @

1 D E M~ T Ij F I E: 1) P.:

NUM1.J1 i DE FI[TE3 C:PIE3 ID BACKCVCROLUI)

ki N1.- fE RY '!(', 1 .

CE. 144

3..' 3 .1

BA-14

R 3 -. .. 1. 3'?

BA-6 14

RU10

23.00

*I'7'. 72

3, 1. 0

2113

7, 5'

134.0

Ell.

14 .

... i ..

20

33

12.

3.

22.3

,01,

121,

4..'

7.I

:r NTr~~.ENG I TY LAWER~T F1401

.00

I'Iii

03 ! -7.;'

Oct:;C

1:39' 1 E

E., 3

.IW

:14D".

:1. 6

E!

E6 , 17

2.5

1. 7,2

i 1.'

.755s

19. - ""o . .: , ,*oa.'.1',. 1 ;,

4/ 3M 42 A'.3 .R 1.F.4 . I3

3.:. ý 1 .,3 .:.,t,.1t..jvQT 31IM , CORRECTEDs; 4. 2. .

.. ""Di. -r: 43.C Y A T1V1TC O U NT2 1 N !3 .33.

2 131 SM11

;W MI3TER pCi L..TER

3 ' 3 i 3 I 1 1

912M 3, . . ..3

1- 79 E 1 ii3 r.43697E'. 01.

* S&G OTCl Guv V Q . ( I 75) WAN32' I 440W 52..6 !-'.j C.--2007 1 7N434[9 Page~m m 1 ,'p"n'men a 1'at• V n

Z N.., -(,,5

Z R.-.. W.";NB-,.95

FRUI--IQ113.:10 ?U- ! I :I.i

1..:'- 3:1. ;'

'A. -. i14 1"LA- 14CE-14

,i-, 401 E+0

zi,, .161,:L4 E +013. I. 5'.i,

4-.,9260 lE +03•

".4'9~~hfl' t,! 'l ': a.'.',

4 ", 0•, E: I -

4', 3099EM7

7: , ,939 E +O,:-3

.1{,, t I, Z i * : 7E "1 Z

.Q.2;:7:37 M1•': '•:

: F, ' & , 'j + I

1.2I0"'*I

4 Al pea:kssvi.; for a:ct;tievit c"'-•-~talcuationd Ku.l, Lo e!.s,,c al"shape,

A:: A:.ct' i.vit by pri' i.nte,': ::l, b .ut ac t;i vit. hy ( MDA.), ,... ...... .. ...... .... .. .......... .. .... .. ..... .. .. ...... ........ ..... ....................... .....-- . G ,.' U M" M .I A F,:. Y ....... ... .. .. .. ...... .. ... .. . ........ ........ .......... .... ............. ..... . . .. ....

TOTAL ACTIVITY 6,. 9 t o 2 .': 3 , A k e U ) 1, .3,- ;.i;tZE+r1 p "F[-: R"", DECA:YED' 'T'TY < .65) . . 1 t o' 2'3.4M) F,,99.'"-2,1 . 8 .I 0 i/LI T "

133.54 F C'•.4- -4,. 432?!8. 76.! %.' LA.,-..40r. 36-74.,,4.8

75 ,-. '- 765 7t.) %

83. 84 % '7ltN-.':Z4 :I I ,ý S.'1.332. 50 %:! B %•••:• (2 .. 8 •.:9 ,

D 1 ' 7 1'-IlCE-.1.41 2B4;.]: o30

1-13 47,/

.'I'0 60 i.4.I ,.I 7 ; .. 4

IZ '..-..• :iFi 3 , !i4

S"/

.. EF'.,(

CAT - 13"7,(D ::...:.3 q

MAI, 84 % B. W-- 4.g'..

4., 7 ,, %' ', : 1 -i6"10:. 8 3.3 & R Q"- 10.!,'[-

7;:-:4., t8 ';, , FZ f-.. ý5,81,:.877 %/, C{3.--58

:I i.' :9 1I m, (_1., %;, IF E --- "1". 9

... ".. I ...... j'i' ' ,' F: 4. ' •i'; ,'t; 91'"I'~f." F,'iN .I'"I .I.Pea F is par.t"'; o .'f ' , , u and, :i. are went

,.. . i n .to o , .F F : ' F I*.i. ,

$~~F1 Peak idn iid bu first''' peko F uc ie

failed one or .. F t••.

-- va b--ro n "W ac io

EG&G OR E G Yz - 1 ( 175 WAN3 1 /, WO 2. 1 !-,J UL ;G 1' 5 ~ I F.

A 1. ".T1!I F /011~-

IA

st r Lime1:.iu1 ,?0Qt7 J .,SA 14

L iv tiw 735.Itr ~t:~

Cal~~ ibf. iiI

"' j : . 2. 1 i

Librar MatchWidth :.5 1

fr ) Ill r .~

P e ' a k ct iAiIv 1

f? A q A. LIE! 2l i I T

3. 501,`.i.

2. -. 5 7 . A.:.

D t c io 1 II s ho ;

Adiioa Sytmtcarr

F~nicion I~i~t0 0

Background ~ ~ ~ ~ ~ ~ .1 witnbs ehd(W n nseirm

Decay durD11 anquisitio-i-iDecay durba collnctim.ýPeaked backgrow"! coromacUion

S t at U

Y OiKTI,Y E E:*,

aEB5 DOTEC GYV 1 ( 175) W1 !,i,!3E:-" I ,4W0a$. 2 11 JUL. 2j70 7 M52:51 Pae

U 11 iF DYV EL IN F 1E 0P ,*_*! ilA I

1 A VA' ki FI_ L !...NER COUNTS COLVIT * RA4 I I I L e' ~ 1% NL JC IT. EFf -+- f-f f f-' - -if f f-1 1- -' '- T- - If + -+ _- 1-_. .I. 1 -! --. . i.....+ 1 - Ai

70 .8 35 .7 83. :1.., 8.762E+03'i''' .1 . J. . 4.35 :1. 21 Z

44.1. lFi;liFijhIF/FT IU '*- fF2A4 Li CICLI V CL I ~.

1-13

BA- 140

LA- 142;I.

R2' 10

R.IL I If(.

R-F 0

Il-137

CS-1

D* ''

t'ý G,

K*;1 * 1(. 1I~pqpy

26.5

29. 4 /

569. '3

I3 7ji , !' i C!,

7393 00

TI.'- 0

-24'.,17

I i-i7

D NT

28 .1

305iD

32.7

I'4-1

4 B 0.

47~i

BA5KGROLMf'1 D[ NET ' -(''

5FU 17.lIh

12.

4T "",ý1.3

II1h

13 Li 11 M 4>1..4 FA(4 Y.

f1[l:I~ ~~~~F 11,E1"1 S U '<i c ~

ICT :,1 -. ' ]IL- [i

.002

is

i 5' : ,*'i

2'"'l13.0

'I G 7

f29.15

12. Di23 2 7r

Z+ 1

it 1I"7

BF,

000s

ES7

Moo

543sI

;81,

a , I ffII~ 4

E &S ORTEC V :r C: 173) WAN3 QW72.9 1 :11 -JUL.- i"F7FF77 [*7; 5 :i1. PlageEniv i.V ronment[al Ginec(tr:..km aF F~344 Fm1

3

* ** ~* S U M M~ A R 0 F NU CLIDE 1 NT .vNIE C:IF' ocu.C.U TIM CORRn EC:TED .iF~r: N

S; A 11' P L. E * * * Wvi-

ACTIVIT

p0 i/, i..TERr

ACTIVITY

pCi/LITER Qi/L E:

K 4 Qt

FE-59~ 10 "1 !!

U :1 . f'11'-3

RU-10

CS-13J 7FF (14

LA-14 'F

ICE-14I 4

CE-144~:j

SI. ~ .... V..................F.-.' 1~

S~ B222EF I--2'6SE+0

*. 'I5 C 7 V, 1,!iF

04 F1E0

EN* 4457E+01at W30.

F I 7G~ O63, ý I 3 3t3 .-

3.034Bc ~

2 , 1 E + 02.c:7CFF;: "E +

C,1 6 E + 0'/,Fl

1.151E+1.

W 811.-fN.

in ' SWE.+01F

.-. ! <l -K j. 2- 7L6 rzt,

.. .. .. .. . .. .... ..... ... . .. .. ' ...... .. ... ... ,:" ' i ' 'YF ..F.. . .. . .

TOTL ATIVTY 9.9to202. 1k eV) . 0959MOD 1(AnIn i a'';

TOF 59. 9 to 204 'I W) 'FFi)1.'~F 027460'0 QN.I ,F.l s1r(.~(F uvrivi. 'T' Fy- . ~ ~ VF .c>. 1 f

.2.8

756.72

834.'4

1291.6

13 U 1 P

F 1--' -'F' )""

AF R Y o..D.. CA RDED

109.2 FE50 1 '55

F-F7

ca-1 .

.............................'"" r." ' "

Pea is ' par ofF a~ F H iF V3.1.l.'.F

negatie durng deonvoltion,

iii .;, F: FF4.'oF ....oF . :V3; :.,I.i~'

- 1-7- E Environmental, Inc.Midwest Laboratorywn A~legkeny Technologies Co.

Mr. Al Percival LABORATORY REPORT NO.: 8003-100-366FirstEnergy Corporation DATE: 08-13-07Mail Stop 1041 SAMPLES RECEIVED: 08-08-075501 North State Route 2 PURCHASE ORDER NO.:Oak Harbor, Ohio 43449

Sample ID Lab Code Collection Date H-3 (pCi/L) LLD

MW-31S TXW-5194 07/31/07 7322 ±262 < 176

MW-31D TXW-5195 07/31/07 108 ± 97 < 176

MW-32S TXW-5196 07/31/07 7535 ± 265 < 176

MW-32D TXW-5199 07/31/07 507 ± 113 < 176

MW-33S TXW-5200 07/31/07 2702 ± 175 < 176

MW-33D TXW-5201 07/31/07 3271 ± 178 < 173

MW-34S TXW-5202 07/31/07 2839 ± 169 < 173

MW-34D TXW-5203 07/31/07 1076 ± 126 < 173

MW-30S TXW-5204 07/31/07 1149 ± 128 < 173

MW-30D TXW-5205 07/31/07 231 ± 100 < 173

MW-37S TXW-5206 07/31/07 2961 ± 171 < 173

MW-37D TXW-5207 07/31/07 135 ± 96 < 173

MW-12S TXW-5208 07/31/07 860 ± 120 < 173

MW-12D TXW-5209 07/31/07 1155 ± 128 < 173

DBD-01 TXW-5197 07/31/07 7185 ± 260 < 176

DBD-01 (duplicate) TXW-5198 07/31/07 7734 ± 268 < 176

The error given is the probable counting error at the 95% confidence level.Less than (<) vf •es are based on a 4.66 sigma counting error for the background sample.

/ SA Coorlim GrobManagerQuality Assurance

. -- Iva#I ,JI IIII I ,al. Inlc.Midwest Laboratoryan Ailegheny *Technotogies Cc,

PRC-S3Form LS-4 V-. 10

0.10032g STD T-36

TRITIUMLSP-2000CA /

LSP-2350TPRJ/AB .

LSP-2800TR L_

init. & Count Date: 0 /0 1

BKG BKG Sample STD STD STD 1 DateTime Counts Time Time Counts Act-Vit7 issued.(p-)

c%00 _________ 00 _O209 1o0 0o.78 S01/18/20D1

Sample ID Volume Sample Remarks

(m1d) Counts

91q6 5o-

51_ q_ 0__7

S,/o IGIq )_____ 1_____ ) ,cbqo 0 -4ECotAfl

_ __ __ _ _ I1_ _ _ _ _ _ __ _ _ _ _ _ I ___

- "•WE nvironmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.PRG-33Version No. 1.0 06/17/97Programmed by Rick Lesko



Background Counts:

0TRITIUM


LSP-2000CA or LSP-2800TR Reviewed and Approved by

Date approved:

100

200

681


Standard Counts:

200

52906

0.169


Calculated by: Tony


Sample Coil. Vol. Sample Corr. pci /L 3.00 4.66ID. Date (ml) Counts Factor Activity. Sigma SigmaID._ Vol. I_ I__ Fato Sigma S _ _ igma_

TXW- 5194TXW-5195TXW-5196TXW-5197TXW-5198TXW-5199TXW-5200TXW- 5194

7/31/20077/31/20077/31/20077/31/20077/31/20078/1/20078/1/20077/31/2007

13.013.013.013.013.013.013.013.0

3913393

401738464114588

16593908

0.9980.9980.9980.9980.9980.9990.9990.998

7321.848107.599

7534.9967184.5317733.798507.174

2701.8547311.600

±r

±

+

±

261.92897.281265.242259.770268.297112.854175.286261.767

1029.64498.376

1058.5301011.0381085.477132.264407.1201028.255

113.456113.456113.456113.456113.456113.439113.439113.456

176.235176.235176.235176.235176.235176.208176.208176.235

Best probable result.

L-uU/l'LTT 1t-:

r-nvironmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.

PRG--33Form LS-4 VE. 10

LSP-2000CQk DTIIT1UM LSP-25850TR/AB LD

LSP-2800TR -- 1

Irdt. & CountDate: b " 0e / 10 /Q70.10032g STD T-36

BKG BKG Sample STD STD) STD DateTime Counts Time Time Counts Ac9vity Issued

c200 -7qO 0 IGO50 1003.78 01/18/2001

.Sample ID Volume Sample Remarks(reil) Counts

T•-cJ-- £C9Ao( _____ •76

-•A0

5, 9o , 16 7)__ ___ 0. I00l%

r/#-9aoq 1%/0 9 7bAO 967

10 a

_ __ _ 9 0_ IV _ _ _ _ _ f__

______ I ___ ______ ______

__________________________________________________________________________________ ___________________________________ ________________________________________________________________________________ I ____________________________________________________________________________

S.-: Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.


Sample Count Time (rain.):


Background Counts:


For any sample counted on the LSP-2550TRIIAB,'LSP-2000CA or LSP-2800TR Reviewed and Approved by:

Date approved:

100

200

874


Standard Counts:

200

61036

0.195


Calculated by: Tony

Counter Efficiency: Date Calculated: 8/13/2007

pCi/LSample Coll. Vol. Sample Corr. Actvity± Error T.P.U. 3.00 4.66

ID. Date (ml) Counts Factor Sigma Sigma

TXW-5201 8/2/2007 13.0 2276 0.999 3270.792± 177.661 478.994 111.541 173.260TXW-5202 8/2/2007 13.0 2033 0.999 2838.599 ± 168.786 421.335 111.541 173.260TXW-5203 8/2/2007 13.0 1042 0.999 1076.035 ± 126.291 193.300 111.541 173.260TXW-5204 8/2/2007 13.0 1083 0.999 1148.957 ± 128.329 202.200 111.541 173.260TXW-5205 8/3/2007 13.0 567 0.999 231.179 ± 99.680 104.521 111.523 173.233TXW-5206 8/3/2007 13.0 2102 0.999 2960.865 ± 171.327 437.610 111.523 173.233TXW-5207 8/6/2007 13.0 513 0.999 135.088 ± 96.148 97.888 111.472 173.153TXW-5208 8/6/2007 13.0 921 0.999 860.299 ± 120.003 167.600 111.472 173.153TXW-5209 8/6/2007 13.0 1087 0.999 1155.360 ± 128.447 202.948 111.472 173.153

=Best probable result.

,1.5,:

I "=&--I "I ;BETA LABORATORY6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143

SAMPLE ANALYSIS REQUEST i CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTOO-•REQUED?FORM X-2189 (REV. 05-07) -vYES I- NO PAGE / OF/

F-1 NOCOMPANY NAME-.,,,

ADDRESS / LOCATION

BILLING ADDRESS • ..

TURN AROUND TIME


[E SAME DAY

[-124 HOURS

[ 48 HOURSE STANDARD

ANALYSIS REQUESTED SAMPLE MATRIX

CITY

TELEPHONE NO.7fV

STATE

Ž.#-,,eZIP CODE ,D4

A = ASBESTOS

AS = FILTER-ARSENIC

F = FUEL OIL& COALM= METALO = OIL


OT= OTHER

1-

IFAX NO.

REýORT A.TTENTION E-MAIL

RESULTS

[MAILEl -FAX

D-L-MAIL

PRESERVATI

VE

ZZ~N

PURCHASE ORDER NO. SAMPLEREMARKS:


LAB

I.D. ISAMPLE IDENTIFICATION

I COLLECTIONMATRIX . DATE

COLLECTIONTIME

.i: / ".7 u ,• i ...

f..... /.1 •L. /

RELINQUISHED BY (Signature) * - , DATE TIME .,P VED BY (Sign d), r, e DATE TIME ADDITIONAL COMMENTS:

REILINOWSHEb)"BY (Signatdreo, .-- •,7 DATE' ,TIME FqEQEIvED ,L.gareD•T TM_!

RELINQUISHED BYA(Signature) DATE TIME - BYIVEy. (Signature) DATE .TIM"/.L1 2 1 ' - -h J .... < ,'.' "*. Q3.-7-d .__._ .

COPY 01 RIYBUTION: WHITE - ACCOMPANIES SAMPLES, YELLOW -w.B COPY, PINK - CUSTOMER

WEBS'fTE FORM: ORIGINAL - ACCOMPANIES SAMPLES, CUSTOMER - RETAIN COPY

FirstEnergy/ BETA LABORATORY

6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143SAMPLE ANALYSIS REQUEST / CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440.604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07)' [VYES PAGE OF'iF' Mfl

M NOCOMPANY NAME

ADDRESS i/ LOCATION.. .. , fk, Yj• , •'T#- '

TURN AROUND TIME(Surcharges May Apply)

E[ SAME DAY[3 24 HOURS

El 48 HOURS2ISTANDARD

ANALYSIS REQUeSThD SAMPLE MATRIX

BILLING ADDRESS

CITY STATEr \... . , V " j•, r• , '

ZIP CODE 4

TELEPHONE NO. FAX NO. [ RESULTS

REPORT ATTENTION .. E-MAIL []MAIL

PURCHASE ORDER NO. " , . R -MAIL

PRESERVATI

V.E

N

It

A = ASBESTOS

AS = FILTER-ARSENIC

F = FUEL OIL& COALM = METAL0 = OIL 'P = LEAD IN PAINTW= WATER

OT= OTHER

SAMPLEREMARKS:


LAB

I.D.SAMPLE IDENTIFICATION MATRIXCOLLECTION

DATECOLLECTION

TIME

,c 2(.: :; NA. F~i. .. o"--- -i- -o-]-i-

v" .- ._5o

RELINQUISHE DtYA Signature) DATE ~TIME RECEIVED BY. (Sigihature), DAT ,E TIME ADDITIONAL COMMENTS:-L -7

C k). 3 ~ ~ I ~ Ic y.I "

/ATE TIME RECEIVED BýTgnature) .DATE TIME

0 J,": v"ý 91- 1- •0".3.> 6.

RELINQUISHED BY,-.ignature) DATE TIME . RE ED ' (Signature) DATE TIME

,-_,.2 APL, 7! _._._ _

COPY 51§S-FIB13TION: WHITE - ACCOMPANIES SAMPLES, YELLOW - VIB COPYp, PiN - CUST6MERWEBWSITE FO4M: ORIGINAL - ACCOMPANIES SAMPLES. CUSTOMER - RETAIN COPY

U 1

S -. .yBETA LABORATORY

6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143SAMPLE ANALYSIS REQUEST / CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07) " 'F•YES F- NO PAGE I OF

COMPANY NAME

ADDRESS / LOCATION

TURN AROUND TIME(Surcharges May Apply)

El SAME DAYEl 24 HOURS

El 48 HOURS• ý:TANDARD

ANALYSIS REQU'EST"ED

BILLING ADDRESSb. ý SX

SAMPLE MATRIX

A = ASBESTOS

AS = FILTER-ARSENIC

F = FUEL OIL& COALM = METALO = OIL


OT= OTHER

CITY STATE ZIP CODE

TELEPHONENO. FAX NO. RESULTS

REPORT ATTENTION E-MAIL . 1 MAILPURCHAS OARDER Nj•./ ý 1 E FAX

PURCHASE OR DER NO. .)9 L--E-ML

PRESERVATI

VE

SAMPLEREMARKS:


LAB

I.D.COLLECTIONDATESAMPLE IDENTIFICATION MATRIX

COLLECTIONTIME

2.t. - 1~ .f 1 _5

rny 4- S vv .,., -I

'Y\,Q V A/1 .1h /!7 )Lon__ __

RELINqUISHED BY (Signature) DATE TIME RE, B tur DATE TIME ADDITIONAL COMMENTS:________________ !___-_-_, ___, _ ohi::) i1925 , ,,, ..,>.,/.J : ,V .'q -b :• "-

RELANQYISHED BY (AT TIME R- DATE TIME

RýENO'UISHE6DY4Signature) DATE T TE EIV-61"BY (Signature) DATE TIME..... _________.__"___-__,_,__ I .- . _ _- _ _, __. _ .. . _-_ _ __PIE,

COP Y DISTRIBUTION: WHITE -ACCOMPANIES SAMPLES, YELLOW- LA•.6PY ,PN1W --t0SF4-1TER*- --


FýrstEnergqySAMPLE ANALYSIS REQUEST I CHAIN OF CUSTODYFORM X-2189 (REV. 05-07)

BETA LABORATORY6670 BETA DRIVE, MAYFIELD VILLAGE; OHIO 441431-800-470-BETA 440-604-9802 FAX440-604-9800 CHAIN OF CUSTODY REQUIRED?

I ~jýYES i-- NO PAGE f OF

D NOCOMPANY NAME

.•-.i.... -.., .,"•, ,*

ADDRESS I LOCATION

TURN AROUND TIME


El SAME DAYEl 24 HOURS

El 48 HOURS,9S"ANDARD

ANALYSIS REQ6ES`TED SAMPLE MATRIX

BILLING ADDRESS

CITY STATE ZIP CODE

A =AS=

F=M=

0=

W=OT=

ASBESTOS

FILTER-ARSENIC

FUEL OIL & COAL

METALOIL

LEAD IN PAINTWATER

OTHER

TELEPHONE NO. FAX NO. RESULTS

REPORT ATrENTION E-MAIL . El MAILAL . -- I , . - . .. ... ",- " E] FAX

PURCHASE ORDER NO. .-. , , , -. ' .!EMAIL

PRESERVAT

VE

Q;_.-

SAMPLEREMARKS:


LAB


COLLECTION COLLECTIONDATE TIME

2r)yi1 .Y 1 Z W. \ _' _ _._ __

s , • '

! .-i"n .J_ A

RELINQUISHED BY (Signature) DATE TIME R VED BY (Situ DATEi TIME ADDITIONAL COMMENTS:

RE(9i'OUISHED. BY ;Signature)) L DTE TIME RECEIVE,ý - ature)

RE)LINQUISP-EDi BY/(Signature) DATE TIME R Eý'IVEV' BY (Signature) •DATE TIME

A 47 'J) " ---< _

CqP'Y DrSTRIBUTION: WHITE - ACCOMPANIES SAMPLES, YELLOW - LAB COPY, PINK- CUSTOMERVWEBSITE FORM: ORIGINAL - ACCOMPANIES SAMPLES, CUSTOMER - RETAIN COPY

_,,...tne. gy. BETA LABORATORY6670 BETA DRIVE, MAYFIELD VILLAGE, OHIO 44143

SAMPLE ANALYSIS REQUEST/ CHAIN OF CUSTODY 1-800-470-BETA 440-604-9802 FAX 440-604-9800 CHAIN OF CUSTODY REQUIRED?FORM X-2189 (REV. 05-07) EYES F-1 NO PAGE t OF )COMPANY NAME

'-V.---.-- ,< &~, £

TURN AROUND TIME


ANALYSIS REQUESTED

ADDRESS I LOCATION [- SAME DAYEl 24 HOURS[E 48 HOURS9STANDARD

BILLING ADDRESS

SAMPLE MATRIX

A = ASBESTOSAS = FILTER-ARSENIC

F = FUEL OIL & COALM = METAL0 = OILP =. LEAD IN PAINTW= WATER

OT= OTHER

CI TY STATE:. • .

ZIP CODE

TELEPHONE NO. FAX NO. RESULTS

REPORT ATTENTION E-MAIL •l MAILPURCHASE ORDE. NO......... FAX

PURCHASE ORDER NO. - .. .' ... •, d.:Z•, .•E-MAIL

PRES

ERVATI

VE

r- SAMPLEREMARKS:


LAB


COLLECTIONDATE

COLLECTIONTIME

N V,../ -'-.

_______. ____..... .... __'____ _ -, -. .- D '7 ,, j . •:

7)

RELINQUISHED BY (Signature) DATE TIME RECEIVED BYP(St nature) DATE TIME ADDITIONAL COMMENTS:

RELINQUISHED B'Y(Sihature) -7 DATE TIME RECEIVED BY -nature) DATE TIME

~~~~~~'~~~o I"?- C"Z6 2//7 ýd)" . ~ u' ' J)~RELINOI6tSHEDOBEC(Signature) D1ATE' TIME • ECEIVE,[ BY (Signature) DATE TIME-.- ____ &XJC)......... Xi >Y) . __,_-.___ ____.______,_ ____.. ... ____

COPY'DISTRIBUTION: WHITE - ACCOMPANIES SAMPLES. YELLOW - LAB COPY, PINK - CUSTOMER

WEBSITE FORM: ORIGINAL - ACCOMPANIES SAMPLES, CUSTOMER- RETAIN COPY:A;• e y.":•

0

-'&-- Environmental, Inc.. Midwest Laboratory

SAlleghenyTeo og.ies Co.

700 Lancwehr Road . Northbrook, L 00062-2310ph. (847) 564-0700. fax (847) 514-4517

Mr. Al Percival LABORATORY REPORT NO.: 8003-100-370FirstEnergy Corporation DATE: 11-06-07Mail Stop 1041 SAMPLES RECEIVED: 10-06-075501 North State Route 2 PURCHASE ORDER NO.:__Oak Harbor, Ohio 43449

Dear Mr. Percival

Enclosed are results of the analyses for tritium and gamma-emitting isotopes in twenty-twoground water samples.


S.A. Coorlim,Quality Assurance


Report: 8003-100-370Page 1 of 3


Sample Location MW-102B MW-102C MW-IOOA MS02MW100A MSDO2MWI00ADate Collected 9/27/2007 9/27/2007 9/24/2007 9/24/2007 9/24/2007Time Collected 10:59 15:05 14:50 14:50 14:50

.Lab Code TWW- 6749 TWW- 6750 TWW- 6751 TWW- 6752 a TWW- 6753 a


H-3 394 1 114 < 193 < 193 16321 + 369 16925 8 375

Mn-54 < 2.2 < 3.8 < 2.5 .< 2.3 < 2.5Fe-59 < 5.7 < 8.2 <. 3.3 < 4.7 < 3.7Co-58 < 1.9 < 3.2 < 2.3 < 2.3 < 2.5Co-60 < 1.6 < 3.6 < 2.3 < 2.1 < 1.1Zn-65 < 3.9 < 7.2 < 2.9 < 1.9 < 4.1Zr-Nb-95 < 2.7 < 3.5 < 2.3 < 3.3 < 3.4

. Cs-134 < 2.5 < 3.2 < 2.0 < 3.0 < 2.6Cs-137 < 2.8 < 3.8 < 2.3 68.6 ± 7.6 70.2 ± 7.5Ba-La-140 < 5.8 < 7.2 < 4.1 <.4.1 < 2.1

Sample Location MW-101A MW-01B MW-101C RINSEATE BLANI MW-103CDate Collected 10/2/2007 10/2/2007 10/2/2007 10/2/2007 10/2/2007Time Collected 10:23 11:49 14:20 14:40 15:07

Lab Code TWW- 6754 TWW- 6755 TWW- 6756 TWW- 6757 TWW- 6758


H-3 237 89 207 108 < 193 < 149 < 149

Mn-54 < 3.9 < 3.1 < 6.8 < 3.1 < 5.8Fe-59 < 7.3 < 5.8 < 8.7 < 4.5 < 6.7Co-58 < 5.5 < 2.4 <ý 4.3 < 2.8 < 4.2Co-60 < 2.9 < 3.3 < 3.8 < 1.8 < 5.6Zn-65 < 5.0 < 3.5 < 11.8 < 2.4 < 7.7Zr-Nb-95 < 4.4 < 4.0 < 4.3 < 3.5 < 2.7Cs-134 < 5.3 < 2.9 < 4.3 <3.4 < 5.7Cs-137 < 6.8 < 3.7 < 6.0 < 2.8 < 6.3Ba-La-140 < 9.8 < 5.5 < 6.4 < 4.9 < 5.7

Known spike activ Cs-137, 65.6 pCi/L.• H-3, 17185 pCi/L.


0

Report: 8003-100-370Page 2 of 3


Sample Location MW-100C MW-100B MW-102A MW-102A MW-103ADate Collected 9125/2007 9/25/2007 9/25/2007 9/25/2007 10/1/2007Time Collected 11:06 0:00 15:21 15:21 10:31

Lab Code TWW- 6759 TWW- 6760 TWW- 67.61 TWW- 6762 TWW- 6763


H-3 < 149 < 193 344 ± 113 387 ± 114 495 ± 117

Mn-54 < 2.9 < 3.9 < 2.3 < 1.8 < 3.4Fe-59 < 2.0 < 5.6 < 4.9 < 5.2 < 9.0Co-58 < 3.3 < 3.9 < 3.1 < 2.1 < 6.6Co-60 < 2.4 < 3.6 < 2.9 < 2.2 < 1.8Zn-65 < 4.2 < 8.4 < 5.5 < 2.8 < 7.8Zr-Nb-95 < 2.8 < 5.2 < 4.7 < 3.1 < 5.7Cs-134 < 2.9 < 3.6 < 3.1 < 2.5 < 4.8Cs-I137 < 2.3 < 3.5 < 2.1 < 2.0 < 5.8Ba-La-140 < 5.5 < 8.3 < 9.4 < 3.6 < 10.9

.Sample Location MW-103B DBD-04 MW-104A MW-104B MW-104CDate Collected 10/1/2007 10/1/2007 9/28/2007 9/28/2007 9/28/2007.Time Collected 12:30 12:00 10:07 11:42 14:42

Lab Code . TWW- 6764 TWW- 6765 TWW- 6766 TWW- 6767 TWW- 6768


H-3 362 ± 113 394 ± 95 237 ± 89 250 ± 89 < 193

Mn-54 < 3.3 < 4.5 < 1.6 < 2.4 < 2.5Fe-59 < 5.8 < 7.7 < 5.0 < 6.4 < 6.6Co-58 < 3.5 < 2.5 < 2.1 < 1.9 < 1.8Co-60 < 3.5 < 3.6 < 2.6 < 2.1 < 1.4Zn-65 < 4.9 < 4.4 < 3.1 < 2.0 < 3.8Zr-Nb-95 < 5.0 < 4.9 < 3.8 < 2.8 < 3.5Cs-134 < 4.8 < 5.4 < 2.9 < 3.2 < 3.3Cs-137 < 3.8 < 4.8 < 3.3 < 2.6 < 3.6Ba-La-1 40 < 8.2 < 8.6 < 6.6 < 4.4 < 2.5


0Report: 8003-100-370Page 3 of 3


Sample Location MW-35S MW-35D'Date Collected 10/3/2007 10/3/2007Time Collected 10:26 13:00

Lab Code TWW- 6769 TWVW- 6770


H-3 227 ± 88 368 ± 94

Mn-54 < 2.9 < 1.8Fe-59 < 4.4 < 5.0Co-58 < 3.7 < 2.2Co-60 < 3.3 < 1.6Zn-65 < 3.5 < 5.6Zr-Nb-95 < 3.9 < 3.1Cs-1 34 < 4.5 < 3.9Cs-137 < 4.7 < 2.0Ba-La-140 < 5.0 < 2.5


- EEnvironmental, Inc.Midwest LabDratory

,* an Allegheny Technologies Co.

PRC-33Form LS-4 Ver. 10

ThUTIUM

.ounter ID:

LSP-2000CA "

LSP-25501TR/AB L_

LSP-2800TI I

0. 1003 2g STID T-36_nit. & Count Date: • -/

BKG BKG Sample STD STD STD DateTime Counts Time Time Counts Activity Issued

200 72,2 (00 200 5!303 1003.78 01/18/2001

Sample ED Volume Sample Remarks(ml) Counts

-t 7g2S 2 qo77

-7{ f -Il 1,,( 77f~~2~~ l 1 14 7 S _ _ _ _ _

_ _ __. .. _._ _ __.. ._ _ _

__ _ .... __ __ __ _ I _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ I_ _ _ _ _ _ _ _ _ _

_ _ _ _ ii 1 _ __ _ 1 _ _ _ _

_ _ _ _ _ _ _ _ _ _ _ _ _ _ i ___

' (UA/ 7S 2 4 6 7 ,S30 -)? 8 1ýý 4 '7 f 9 f1 7, 1 1 c /UL2 7, 14q ( L

Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.


TRITIIJMRESULTS SHEET

For any sample counted on the LSP-2550TRI/AB,LSP-2000CA or LSP-2800TR Reviewed and Anoroved bv:

Date anoroved:



Background Counts:

100

200

732


Standard Counts:

200

55038

0.178

Date Counted:

Calculated by:

Date Calculated:

11/3/2007

11/5/2007Counter Efficiency:

pCi!L

Sample Coll. Vol. Sample Corr. Activity - TPU 3.00 4.66

ID. Date (ml) Counts ,Factor Siema Sigma

TWW- 6752 9/24/2007 13.0 8717 0.994 : 16320.983 ± 368.751 2250.075 112.168 174.235TWW- 6753 9/24/2007 13.0 9026 0.994 2 16924.885 ± 375.097 2332.147 112.168 174.235TWW-7185 10-8-2007 13.0 14157 0.996 26894.847 ± 467.066 3687.399 111.927 173.860TWW-7186 10-8-2007 13.0 14595 0.996 27749.023 - 474.145 3803.536 111.927 173.860

= Best probable result.

S :",C~:~ .:I::i C: cV1 ! T :i1 4' 4W@ '0J~1 ~ 2. 9~ C., i 1 1'E

d2 .m :I ' escri p- :: 1 U :

/71

Start time

Liv time~

Rea timeC:

Dead time

:1.12347

. 12,,,"

'3 . 5' 1

Zero offset -1.980 kevq Gai"Quadratic c'h

Library File--:.ýI'll ai 2

. 5611 keU/Mayn-,e].

5 0 (,`l

Pea serh sensi. .ityn

fcv. of3 0. 0 0 0 *x*,

13

2 0 , I

3,. 50(.'.-C.OO111CCECcc0jK/( ., IJ.OOOOE+00$I*~C:( ' T*C C::...

BacgrondC widt P betmto ,nI w ~arm

Correcti: C.:.ý

DC :.Ij c':CIC'.;:::.:v

SWWýý.

Y' E

(, .3 Ci c, 1-.: 2 U 7J'e :.i:: 2c

('3*.-to A-; r -y (:.- o-f-- -f.. A.. J. cio 11-1 s u 1-1-1 j-1-1 i I N 0

V - I ( 175) WAN3R 14WOR. 96E. -I--1vJ. r oy-f T-nc.'

2

EnerMy calibration normalized differenceu M A-4

tj N I D E N T I F 1 1) Ill. S 1:'ý" YBACK(TOWND NET ARM EFFICIENCY UNCERT IRM SWSPECTED

C01.314TS COMM3 * RRE11 2. 11.1 IJ C* 1". 'T D....... ..... .. ...... ..... .4--l-4 ..... .. f-f-f-f- f-f -+-I -+-+-

1220.15 609.27 '13. 105. 1.2T8E+O,';; .3' (,*..), 11 ;'-1.j. (." 1.1 6,54"? BT, 'D2240.12 112 0. 2 6 -.35. 6. 213E+03 59.48 ENUM! BI-214 1)

I D E N T I FI E D1 P ( 13 LJ PI 11 ('t Yt3 N C" 1ý:: 1:".' T

3............................

3.

.4...........................................3...............

.4n F-li..' :1. ,,

1 *A '.', --- 1.4

T1 I11-0.

T i...J.

A.,

657. 44(;

""2 1 5

I'

*1 411 Z

32. 4

1. 2

1590.7

J. ".' 19

2 1.

S34 3

1, 4,43

430 44

496.

610.33

94.93

13 7

141.•

120.

'159

1.,,

•4,,

159,

'4

4,ý

2.,

i.* 0

4431i~it'4 I4)413,44

Iii) I

4,4

r i' '44

4411

1~.i 3~*

:1.

:1.

I/I

.43.4!413 II.

(44~

444

3.4(If A

...........................................................

I•7 , I3

295,, 9

40 , 48

'3 ,,', 3

1%i: ,6

fill ',1

:1.,, 6,,% 4I

fi ,,40 2

:1, 654 .

1 ,, 848)

3 ,, 30

.1. ,, 34,;

:1,. 4.

:1,, 466

:1. ,, 048

S,,( 4•i3

,,34 3.,.l~

I. 1. ~::.I

C`J V 1: ( it. _4 W

N * :aa: 13J II P R F' Y (3 F, H U ~ I:...:It D Ii:. F ,i 1.1 1

,1,1171111, OFt T111U. (:(~t~'Ct i )ý

II t't ::a

:t: ~

-)( )(- IXc `X .'(

J. / I..,TER pCi/LITER pCi/LITR

+ -+ + - -+ + - - -+ + - -+ + - + - -+ + - -+ + + - -+ + - -+ -+ + - ....-. - - I..-4.--, , .... .... I1 Ir- t.4

,1,1-311CS-13

U~ ,:

@ 1.. -- -31

(314

111

.2.t

4..

1.792511+0

(,?'J1 3i )t E 01..?

£2.. E& +3 0:1.

58. to 206. atV 3.35490+2 pI/1I~

145.4 X* CE-141 28 .3 X 1 :. (ý,)41 Il a (I rvt.~ {'7 ~~ a A :I..

16 . 1 ao io ta. (.taa a' 1 I I % 1 -3

109 a2 X FE-59aa aj 1115.5 XF61 11 3 2 % aO a' a." t. 9:1. F, F: . . I

Pea iS Pa t I il atl.a a' a IaI al

a Peak fa aa,-i. laatII tt, tl; a;ta

I t i dentifit edIaI. la , bu ai s peak of.~ W A;a l.1aH...lla:.?j~(

,a le on or ~~aa l l l iIIlit a~i'Il~I.a

c:GM : O .: C: 0 V r .I~i. ( 175) WAN32 I4WO' .9 2x7-OCT 2000? 1-J -I

7 :1. 5 1. 1

YAAIi

str tim

Liv tim

:1.1. :1.

142RIM 14C3E:0MEFk!"-( 0 1

Quadati I EI

Ia ' I I ,kI " IC? : 1. 1. f o

Peak reeto .e& 30 00'%

Pea iec s:enivty

.500 keWchannel

-11 o f, ::.' .)Ci- ('-

I-l --- q of 0 ket.

Additiona systemaic epprs :u : 1yi~ .0000 CC)I J Iflii 0OI

I .~. IIi I I liii II :i. I.:Iii I'

st tu.i - 0I::ii.•'. !ii •!•J-•J ,I I Ii,""

.. C.", - . ... ;ý- ........ 4 z"... .. .. .1 -

r

J. N 0::)

Uý:C-3,--',G OB!'TEC.'-, (*..,.i V I ( 175) WAN32 14WO2.96 27-OCT-2007 130400 PageIHý I--[ Y J, r o -1--t 1.1.1 -1-1 a l ',"*,.,"I:.ý*-,ý(:..ý-t.,.f-.]..ki-i-i *1-1--.%m llý-'.-ýý:

W:.'

Energ cal3. ibration noralze Od333:333e3 I em ~ ( .0374

*~ ~~ :' ' 3 3 S' N3*~1 D E 11 T I F I E DBACKBIRM11) hIET AREA

C*,*0IJIFP'*.3

EFFICIENC1'.Y.)( C1 13.(.*.;:i:

3 U I'17 * A( .1 3. A3 3 .3 3. At:43.4'3.33*)'?

*344.',4.333.3.3.3.3.3.3.33.AA..:3. A,

185.71

1021 R7~ i9R. W73

'l23.

191. ' 1.252E0

:13. 1~.065E.:..304 : 1. 81.890 TL-208

s Peah, fails Wape tests.D

I D E 1>1 T I F I E 1) P E P1 KI---IUC*,'t T DL: C-1 IH: I'll TR 01 f)

U II 11 I A R. Y 3.3.f3.* 3E'.

3.. A........ 3................ ,.....................3.A.3

CE- 1433

1-31DA-14

T

0-31cll 137.

Z k! .3

-0 !'5

.

*1 ;1-3? 43 Q

.1 6 Q.: 333S. 3

13'3 .24A

145 .423

363. W 1

33.'."

8343

C3

3. Q' 8'

it.3

1.3.

2"

1 -3'

C.3

'3.

2,

31.i•,

33. •",

:1.' ,

3A..3 it3~.

!J .'JO.

.331

'J'301

312.97;

3 . C)/~

3''.4

:1.5

124.32

2 2. f,'...4

A'. ,, 3A•.;•'

5I?' 6 S,.

: 1. ('3'•,!!,•

8' 7

". ' •.3 C". 0 1.-1

• ..., :3, ..1(3

1 ;"3,?• •

MOW.

53.: .

EBRO ORTEC 0 V - I ( 175) WAN3R 140102.96

.Environmental Inc-.

S U I'l M A R y 0 F, H U I :F'TIME" (:)I::' C.*0UNT TIME CORRECTED

I'DE ACTI V:): 1' Y ACTIVITY

F: `3 1: 1.uhicar.ufr'

CONIK"

14444444"*" :"

pC U i,. Fý...i 'I-Z p :/L TE.*,

... .. . . . . ..+ " + " +" + .4 + _" " '" ." + " -+..-+-+ I ....... * 1" ,'44".*..... -" "-..." - " - " I. .... .§. .... - .......

Fiii 59

i1 - ý`,i,G Ij -1 -(" aij

:: :1. 00

1. G4 1ST ' Ti

IQ.

1.9673E+0

2,0('-j4 '4, Li 0~

. 1 I I'i: 0

1. 881,L4 vr,:

4 ,,i(j

A Activity I"ID01"......... ........ ... - ...... ..... 111.1.1 .... ...... ..... ............ ......... ii'ý IJ M Irl A !:,ý. Y ... .... .... .... ................ .. ........ ................... ........... ....

p LA:1 liiý F:."TOTPH DF:(:*,'A'-(ED ACTIVITY 59. 9 to 2024. 1 keV) 0. 00( [:.ý 1:.",J. / I 1*1*[ý:I:""

.)(Li*****I *r

13:3 13

3PS 7

497.08

.I1 ý 84

j . y I

LAj14

RU 10

RU-ii0I

ZR-95

R. y

14.14

:11. 1 !iil

1-13

I ii.

C:A :.. F

28I.30

477.61I

60i.7

./.4

487.0 IJI-140

G :, 0 " -.is -.i;" 1kI 1.'-1

72 .1 ii " I

Ii . ..]i L IIIoc, i

@ I Pea is to wide at FI5N Np WI t W

V I ( 175) WAN3R [email protected] 27-OCT-2007 14HOU20 :1.

IMIJ~

Dea tie. I

j e e t v G o e r I 14s

Ca.41 I r t i

Me t d i I u ar.., I 10 20 41.

-3,,5i

Pea rejection ::I4e.Y'44e:

Peak ~ ~ ~ .serh.2.iiit~

Sampe Sze:

I. 5 0C.3

f(:).(, of4048 fow- a-i--i of

30.

(."0. 1.01-:,.eY4. 3 6 k e V

8 5 7 1 E + O,*-.-.iIJ.t,-i:iA-.-- method:;

RISO method

Additional systematic ewNný! 1.0000000MOOFraction Limiti; .000%Background widthr best c"n

DPeaked background correction

Status*'TI tH: I' ý.."

Y ESIs)YES bl w p"bI

F::U' i -. c,:: ýj(;43J. c1: .i1(1~c' I-[( 27ct w c:L(:; V 2U7 nI.7 :.4: 3 UK

"~~~~ 4 :~: f 3 ~u~ 1 :1: D: E NI T :I F: I: E: D: P: E: A ~ K 1 U i VI I:; 11 F13:333 yh:'~

1EM CENT:1 ROIf2: D: B CAWRO:UT) NE AM)2J: EFF: IC ::IE i:NC::Y Ui'.CER FWAr M 3..'51:

1021.8 51.9 7A 2513.. 2.860E3(44.2

1AUC-1.1 DE IDEAK:1 E 1 T F I E D E A V.,

NET AMBAU: i l' Il FI y2 X. -x. 31- x -xj.4 -4,.3,4 x- 4 (.j -ý

1 -A

BA-14

LA-140ii

T-34(~ 1

LA*10

.ýC.

117 9

- 3 3

1 I 3..}

:1. 5 1.

159. 86.44.

48.31

34 4-. 4

118659.38

7 9 6

1 J.~ f.71,

210.

.4M

514

3.3

348

331~~1''

33'

131~I

333 P 1Ill

13 I33 Ii

34

4(3:1.1)3

Il. 3J.(33

(II

.3

ci H:11.213:1

1 t-? 4 :1.

140.44

:1. 4.,(413,4) 4

444 1:1. 44 3

4311 111

1. 1 I::1.

44 .3,

413 ,~ 4C~.

311.31

(31

4 4.., 4

3.33 '34 1..

..41.3 .4

I. 41331

:I.

443 4

4 4 44

4.33443

44414 1.4:3. 1. 333 33314 v. I:)34~ t3:.y:3:,3:,:4:.43 ~.. 44 V .3:444:4.::. 43 3. 4434)33 4..33,::3.:.:3:1

i.'-) V I ( 175) WAN32 [email protected] 2**rjý-111)['.I"f'-.-.,(.,."[,'..-'.10",'It ý-.'J A-1-11

S LJ 1`1 1`1 ("t R Y 0 F, H U C L. I f". E 4'3 1OF* T :011E (*"(:.",I:ýl:zt:ýl(:"Ttiýý.'O

ACTIVITY ACTIVITY COUNTING

.(. It A.

pC:i./ L..ITEFil•'.' pCi/I[TER

4( .3 ... .. 4I ........ 44..444...1 .... ...-. ....... .A

B -'e"I

K1 - 3

N: B.: :

RU-103f

I..891E+0

:1.512E+0

J.. .?-*1 '* F.". 4.(1)1 .

3f 11i.-J.3: .-.'J E I0

A. 1 31 (3J .

04~~ (4(3+0

609.E.Ml

TOTAT.. .9.E ACIVT 60,.1 t 2024.4 keV~) : @,, ta0000V~E4Cj@ pf>/L.:iI,. TEI:N

II II m

49.8 R -0

621- ' IRU-106756.72 3 R-95

3 28 .3 I -13 :1 3I 4c.A

1537.3 % DA 14 604.70 :A . 4A A:1 -31

63 . 7 % I-3A6 1 6 M ..'-1.:'."? e 1 '. Z 1

76% 79l X B 9 7 5 41 3'' 1 -*."*-,'" ;." ('1--!.

Pa As part If a:.T.,1I mutpe ml sarawn

nea iv duin Wyn3 to

Pea is to wid at 3W M bu Wo at F

0jUG 1G .j: i V C (:':i V* T: (:.V :'WAN~32 1:4WOR. 96i Page5~ 1@ 5 2 ~41.I:~: I1

spectrum -:)c . h. ::F

,01,1

Start t.. imeiii l5

L ve : :tim 8F

Real tim F:: V. 6: 31.c':'i L' j )

MCB I Input -'.3

Ope ted 14Ma.I0 14 2 3 '.? :1.

Zer Of&)~fset ij1 keI 1TA e ca-

Qua ratc V:-h I 1 12 A :.Gi; .,/, ri

S a m p l e S i ze ::-. I. A ) I F: FF)'

2. i.

:1.5: I :......... F)V F F:' ~ )~:), 9 Vi 1.. F)

4048~ fo a o

Adiionl.) sysemti eF':r 1)F:FV0h ecFractio n F:)i .:V) F:) F

Bckgroun wAidth best metho (based on spetrm)

. .a d: F: (V J. F) a: :: - u J.: ...i.. t .Jo

*0 y i d Y :1-k .V1 !Fl C. o~ I. T F c : i~ oF1-

Peaked c I V backgon correctionF :)::VFF::F:-V. . :

Y EI i10

F:) ii U F)F') 1

bkq)w. pK:- 5 2 15 2:

EGRG ORTE Gi VI In (1 175) NA3 14O2 6 2

Enryclbainnrmli d f- . :

[j NJ

PEW CENITMIDXI D E ' *IN T I F I: E: D1

3::(: (l.j.I:RCti.113 N ET AREACl C)IJ[4 '.

cID E A K'.lc 323 IJ i FAWI VI pYSUSPECTED

I D fii:

W::

)2.. ~:1. ,, 5

3'~ 373 i3 (:32

122. 1.,, L195E+0452..49 :1484 PB-X3..2:.14

:1 -3(,1 x lik:* ~:1. .

I'~ 333k I ~' 3:: ~ 74 pr" h~.':3.ci c c: Ci 33 v (:3 I. u ~i~; c~ ci

.~~~.~ D3 E3f N3 T4! I4.3 F3. :: : : l :: I: E~ ) P: E: A: it 13 U I'll Ip1 ( 'A ' JR 3, Y 3..332*..(:(3..( 3.:,3 3.

11) ::IDEMi'i~l. iCihl-TIDiCi .3. 1.31.143AI NE:TJH ARE CI:.TEN3SEl: 2.:1 G'CER R[iNi3G 2 3. . . .3 G, I'l ('- X, .

.1 CE14

I (. :1. LX ai."

B,33 1,LA11'0

1i: j i l

W-31

0 03

.- :1.Ai0

5711 2 9

r-.,

07.33533

1322.371

:1. -4 4 B

3 3 , 4

16,1221 00)

2 ~4-2::

. I" .1/ 1 -1'-'-8

3' 80

.336.3 ,22

'1 ý"32I1.3

4I 8 (327.-

5136.26C

(, .6 2 1. 8

ES7.51.(3 1.36

2 34. 3

31

Ii

111.3 ' 9

I3'.

6.3

A3

~11.

310

31331 i

002 3

K) UI.D

0:1.

329'M)

:1. : .0L

R9.3 373

Iii) 0II0

4. 7

:3.6 4I.

4:1 3' .3~

32 ) 3)3<) f-

13 3l

53 1.2

:1. 4, 8

aV - I ( 175) WAM3R [email protected] RWOCT-0007 120041 Page

Environmental Inc:.,

'i. 11.1 U I 1 1) 1".: l'. I I ].-.II'll lyl Pf F "I, Y 0 F,i:.'110UI-1I*I' T J:

AC, I* I V 11, y

A I'll ID L H

pCiiLITER pCU~L ITER

.44 .4.4.,444.) .~44. ~4. 4. 4.4 4.44.

BE-

K-40

F(E 9

3.1)58

A,,

I ý I

GE 141

* 2..' 452E/+00~

i* !5 6 I H . 0 E~ (".1

2 .2 52:i;,E3I: 00112. 6I484E+0

103 E+00J: 4~Ž:

AN45 1E01.

:1.9304E s300

ON 201 3E4(.'lI*

1. 7372~' IE+0:1

EN 5746E.+0:1.31

AC IV T j. /I H u;

62.8 %I

756.72

3 l .~ f. -l

RU- 106I I) I

FE-59I~1332.5

I) *I~I (/~I

I $'I 3 1I I I

l'3i ' I'

II'3

CAI:.. D IE.

:1.: .6I' "-I5 8

I).2..

*,/A. CS-3

K 40

-43 r., 8 ( .. 4,4 ( '1 S : 1 0

41 .3 Md :jj. 0,3

7 I :1 F%

Peak. is paj of' a ~ r 14 i 43 ~ ~rI (.s:. .44'..4

n g t v duri n 4 'I r4., v44.*/ 1 i on.

4.4 . -.- to wi e abu'.

Peak - ~ 4Ir' '. fakls sen iti it test,3 :I.:: fUI.Ik. I.:len ifed but firs peW cx hs3nci

f ile on I i IO 4r,''*4r 4

EC 4(3 {::10 k :: 111) K (I I.' Z! W~~33 3: 3A2. 9i:vp¶ i:3. -n ~ vi -- i t: A.T, ]L :: :3. I 7 IiC' :.~ . j~ v 3

1:: J. :1. e m sC: sa \ t.. .i.r\ ," C;' " 1".1

i -,i I ':.; :7i . I-- L: I'm J::.

Star tim i: 3'?n'(3:3

,, II"'. "

at; a :: -I.; V (U. r::' 131

:3. I VI 3~~ii.A 3 :3.

Crevateir 14. :3:3.,. 7. M3624

Zero offsea

L..ib rar 3i e.-

Peak reject3 , ~ion level.3:

Actvit sc3. '.3a lt ing f .actora 3

R. I M..):

:3. 2 fYi .3~ C) 1 ,V. CC' I 1:3 C' 3 34 :3. .33*U ~y

III 111

l.13::l

:3. ,,. 113 Ir ~ 3:lFwQ,....,.. .3,, CCIYJIZIL. 4l.~il..Ci

:3. 3>. :* 37>3

Adiioa sytmtc 3.N1000O~

Fractio Limits3;3 .:':3 N

Bacgrun with bes method3 (based3(:l on spectrum)..

D a d3 uil J. 13C'.ia k(3 J.: J:: i~ o ic 13 C

Y E:

3:.:::;

:3.

F~f~C v~ 1: r c: o) -f- rY A .A .NI')

t.) I- : :1.: I -I-~ :J I::- :i. .. I", E ~ 11! S, U: C 1d 1 4: y, 3...5 .

PEA CENTRIID *,A'.::..'. MET AREA ~ 13. EFFIIENC UNCER F .I-

12 0 3 0 .3.6.P 4 2 .489E 04 to3 1 1. s i".11 CI::::4 el

2240.59~~~~~~~I. 1105 1:..I, ý0 . ,W..J

•1.ii*'~ . 1 1 1 L :kl y

CE-144 11711 33 1W.5

:I: ... 1. 8 ,`Z4 .' -

:1 ',* 4 -

1211 0]` (?.'1

FR9... !` I ts Ott 754.4

C, CI 2,3'4' .J ".1

F 6 . 8 1 1330

IF I E F P

1215

C 12

P89.,

29.

2 s

46"

U I 'll I' (-r` 1: Y ~*.~4 g..C4 ~*fiJ: N ii: I--I I3 Yi U.iIP'IC D41 I::*tI-,III'

Ci T .i5 I (:, 3H I

I 1 . 1. L i

t', A.l1

:3.3 1. 19f;

AI- 0 ~ f"' 64 . 2.

(:GRG OR :: 6 T ( :175) WAN32I~ 14O..) ' . '*.:~F~Y ?C I h7~

U* 1*11 IT r. Ri y 0 F, H 1.) C: I J: (2 t. ) IH "' :I: III

I t w:(3 (~:~l~t DF: ACTIVIT AC;T:FIVITYf D FINTIM."i Nr~2 ý13 :t: lf

*X * .X. X.).X

pCiiLITER p i./LIT"'ERl:. FWiMLI TERil

F, IK 5

It

I_ 1. A 0

641 E +00~

..

I . *:1589E C:,00

I.:3.54E 1O

1 :17MO

4.8 7. -,: -Qi (,

..

:1. 39 (3.M

9 . ;:'4:.4 17

A: Activity. pr in ~ted, i but a:ctiit <' M.}j:, 4FQ

TOTAL .1''x' n . ~ ci 7.C)2 ,,T 58,, ;j:i p Ci /I::4. 193 F (:1

****** ** 13 V! 1

13.5 X CE

83 .8(4 %'M -5

1) R.Y 0 F 1) 1 13

109 .2 NL*~ FE-59

33 2. 5 (,`1 C

66.6

795.84 Fi11 .5 M -(( ,.F

1460.8 1; % ' K-

610.33 IUF 01

Pea is par of a 1 'F ipt axiyl I this z*f~7ea we -I,,rF.

negat' i vl e durin.p .F I F de o v l tion cs.s..,'7 :.,I.',.lI . ý FI- I .(. civ)

S::(:~(~ f~' c~ :1 ~:.~:; ~ ~J{.:It'.~ ~ ~ ~T)~:?. ~94) cic:: V cN~:HzI 7 :i. 7 :1. 7 i' p :1.

cc@V* :.~ ~v;

FY2:':; F m :i. 1 :sv~~~ m '22' U *.. II ~:2'P :1. / 74 1. ii 1I/~1

/

D d

I I, t, c- /ICK' cluot I.,rV.

Cc.J ':

1. J. b ; J-, J.1 ; U : & I .~.iW I 1

iI, T : dA :1; c. 1. C L

f t; I,.J J.

I_ J, 1:.ý x F, i Ti v-, y I::'

.........................................'~2J

:;'f J ,A Ii t

p,' ~~ '&ie'½ I: c):1.

if: ::, fip2, i*P~

5 f.:)F11""i

F` ' t. J. o:~ J. J. t.:3P V2 . U tI(<UII:

c 1: c..n.:I I

y1(:

c t ) 1 : .'"

0c .* t: :;*ci'~: :. '

C`Junc) 1.1.1 c... .(., r c. cm -r- o-.,c.A : i o .1-1...a r-1 d c.) rn A [YI 11-11 V) 1:1

I•..C1

IH', (`J i f:::' fCI C(3 C i (:I/, 'T FJ:',.La C1 *,,. c I. .... 2.[3 ,& (J . . 4Gi :

I~~~~II J*C( ~ A: :. b:'' t '., Ji .:: )'1C: Ji . 7 d~.: di J. f -F c C :1. ,,

A 53 U IVI yiAr.""T PiRl"C'I UI-AC ERT F1,41--111 L J F, EC* "f'l::: 1)

C", 0 U I'll T, ý:.- IC, I -I AI I A H F., I I*.],,!FA1:,1J.j I Fl., PI 2 'ý':'3-T.GMA k. e V 11.11.3 C L. I, D 1,:.:,4 ............. .4 ..... .. ..... .. r --- .) ....... It ..... .. Ir. .... .1, ..... .. -4. J, ...... ...... I. ..... .. .......

2 8 :1, ".".5 6.1 :1. F I Y..." 2 :1. Ac1. 0 'E".. ,:3 5l:.'-.04 2 '];51 9 2 A. TI 2. (,*.-', 8

c.... r. c-ý ý.-k cl c cro vo J. u 1,.:

'i.X 'i. X. X)'*~. CA x. -)r3f . x-" -xf 4 -, :: I i T , ,: *(I F(.iii:'

U lyl III I:z ',I w.. x. -x- m.. x. -K N. k* M. -Y- -.1

T, II 't, F., 11 DT I I Im.P.ICIFT1,11T FW1.11,11

A ~ ~ ~ .4 ' A ' A A E. 1: A.

Z..

I-3,

f.. C I'I (30

'4 J

F:' .1 , e: M.

FA L''' I .E

9 '' A

A. 4 , . . ~ A. I . . 4.... .. .... .. ...... , . .A....

2 *."A , 31(, Ij ('j A , *I 4(,j1

(". 0 2 9 81. 4s*p

0.)2 :1 .38. 3

1 A (-D 1. (.1

(9Cil f-D 1. 1 46 1

1C ..1.fk ii

5 :t.:Ž3I kI1 0i CD :1 J I.501 J.(91 9

Jl .11r.' 'jW 1,3 11C. 1, 4

8. 0'31 A. I0C10A' .:' . -

S:;GMr ORTEC G V: 3:3 ( 1.75)i 4 lgNIL3 14W .. 9C C 1.67

S U I N A~ R :~(.I. Y 0 :1: Nii 4:Ur: : (::: Ir I:D li.ir: :j !i; 1 11 C-1. r~ .ID , E

.4.4)TýT' pCU.4. .4 4.4 4. .44 -44 444 )-i

K-40

F 1! 4...J iý

CIE: I kIji

CE 14-

2. 1977E+0

4.491E+0

2 . EA " ' Iii: ".(1)

1 ,.' 70 *.'.i F: + i1

4:.)4I 2 : f: ;

0 .3 Iii: + (J.i:

it0011+0

3.6842;E+0'~ :1.

10 15:'4911::(+01J

DII:~Y FF) C iT'..ITY 58 .1 : to RO Mp: 1 k e4,) ,,e:-. i@ 2:.: 1

3 _'1 4*I "' 1 _ '04

49.0 % R-10

'.4.44

,361 4 .4 ,1457. 24

E1441

IA- 140i1-13

NB4495

604.704.

66A. 664495. 8

(.4

'1'

A.

'1.'J: I.'.

K404

.4. . . .4:1 . F j .4

8:. I 7.? J

11 i. ''*..4 f"'.' 0 (1.) 4

4159 .1 I II 44

J.,.ý-.. C.)f a

negative dur-J.)-q1Peal--'. J-xjo

Peak fails sensitivity test.identified, but first peak mf OKA;

failed one exf,

&~0~ c: 3V I ( 1-75h) WAN34 4 F ~~ ,~ ~)*0 r@ 9 :y, :1.

I T.. Foo x I (00 Pilyj,ý3

Spectrum Fi. 1enme C (lIke$3;;'75 ;4.M.:kit

DetetorGeos~ty I

300 '-

Ca ( I i brat $3-

Cr at d I I -M ' *-200f~7 102143:1. :.~' ~ aa 4 ~

Zer ofstIv1 k, an.00kYda-

Qu d a i 12 E 0 I A K&'.'A .fŽamI I::.l':I'rt

Library Fie,ý

onyis paamt ers~i.'

Pea rejecionle

Ii "a-. 136 f or va energ y c- 2a; 4. f,"I, . VFj0.0001"

05 a.Y:1.,, i(3) 3. [M ., , f 3t*a4$~ ; ...

I.OOOO+06/. . '3.

a' J. a 11 .000$a(a

' f .' , :'. .:.":, I ,:a . •••:.'" !I ,••," ::'".. . : "

10)

commaenft.;.

5 ~ 3' ~f

bkg:w p&-.:

1:~3I *. -k o:3131 3.LI,uvffm J. 1-1

aIEf&S0 cOI:RTEC.: (3 V I ( 175Y~) IWlAiI 3E :1:4W29 29-O:T-P0: ,,245 Page{:(~.~>f~~ ~13 : v,' v i. -f, ý:: 3 1-) 31 ; r, T : ~ 1 'i 33 33'm' 2/'. f.

Ene 213rgy cai brat.iIj( ,' 1 ion:'f ~:v m: .:.2 i i:. F :.

PEAK CENTROIDI'll 1;i: (.3 Y

BACKGR(UW NET AREA

P E A K 13 U I'll M () 1:,e.EFFICIENCY

A- S1J."311r)l't!(1

.3.3~~4.4.333..31..33.~34.334.3.3.

73.02

102 .14I

I-3528:. .72

63. 03*66.2

9. 4('

231 . 2!~.-

I. 10 .53

. .. .. .. ...59.I

I0.-72"4;.

15p

2'14

278

1. 1::. 3 3<

:1. 25M.6

M'M

UIi. 117

I ED. 59;-18.9

(I.0c;

:4 ons

II. 25

:1. -423

f:, :1. i

J-I a3

B :1. 4.6

PI)

1)

1:)

I' t:~ 21k 1. :1. 2. ¶•lI .21 F-) '2- 3::. I:: ¶2

D E TC113)

F3r:r: I .1 E~ 31)1UN 11 Vlý f-,-1 :BACKGROUND3 NE ARE

H;U 11 Ny ()~ 1:;'. .Y.'.~ X' ,)( X. -X .- Y . j(-

T:N TENS:IT ~-' !::J:-4V 11-111NSI 3 3131 A? 31~31CMIA kekY

. 3 . 3. ¶ ., . v , , ,- `- 4, - -, ...... ', -.1 4 ...... It,...... .

TI 131BA-140

1 1 31

.' I

I31)

FE-5

z - -. (' I

.270.00

2318568.71

608.07 31 3 93

12

1 7 15. R

2 ,3 3,.

R84. 33''

303.; 38

60. 8513

12. :3. ý-

01..04 ,.,t .34

R0,''7. ,

1333

I44,

13'.

135

:1.4

-3'

35.

4-3,

4,,

1311 1'('I

33,11311,1

33.3 1

if~(III

II 3'

33131

333 1')

133113313,31

33313

3 if ''3

33331333131

3,33111

3 333)

:1.(13 (/3 (:23

2 3 1 .

-33

-,3 , 30

748331

:1.13 I Iifl

1.1 ,

:1. 3 113,

II. *, 1

.1.

:1..,. 'C 3313

II. .'i ~1J

r.'; >1

I.'(3

3 I

I (3,

I. *,3•1

v T T 4 W 0 L". 9 iDarje31

N '. i

213101."'"

2 4r 1

V: B 1-..

1.1 111::1 29

1.-46 .D .,I I I

.1 ::"."'IG H3

28t.

(IJ 0 1.

1. J. 8~

A. 5 . "3L 21

1:: 111

A.,,

2 1

F, 1-f. f J.

"ft M 1:. ("IF, C.Y Lkf T.T I'll"1 1) ~3 .1- ' I 1:: 1. I: .. . CI : . t f ~I: I: ( : : t 3 Ar 'T.1 Vi NC I3 ;

t::•C: :i. /I,.. i11 T li• I::.'. p 1: :'i. I. 3:""

.A.. , ... • ... .... ... • .•• .. • ....... ` A A...` ... . .( ..A..A. (.....• ... • ... .... . .. • .. . .... ... • ... • `.• ... • .. • ... .... .1.• ... • .`. .... ... • ... • ... ... •

@111--',

P1.: 1. G

1. 2' E. 0 (A .

J.I

Jf

:13 3. 13' . 5~A A I ~

o ('

2 '. 2, 8 1 I.: (1.')

1 J 1:' . (1

...i•,, l":.•'.3111iC3.:.) It.

ru~~ .51 FifI::~~f tI V I. K I--, J, d.J +.. t'~..': ~ . ~ ItI~:'

(ill ~ ~ ~ ~ ~ ~ t d butt~/ EI'CF . ~ (.''r:: 0 4 . . . : :.2311 I.Ify . :3:. .I.

4 •-i.C.', Z• , % l::..I..-L i•! I.." .~!? ,•;i'

. ,, .'" II.A .I,. I.................

LIC31t

t T C ('I Ft.. D, F".

.i, ii .5:: .. ,: :• i .L .• ,!!I::

I .-) A.

1~

'I I" ('it II It t CII

'~: ~,,

A,

SIIC3~(3 t: i V: -.: I' : 175) WArN32 1:4WO2.9@ 61 2 34 tY I1

:1. .:~

p c: k.Uii P 1. 1 in ~.: 24\ 1.3 c.~ :~ :~ a

Str t' i:mc!

Liv t: ime~

Re l .im 300E

Detector systei-i-,:1. '3

Cre~at ci: 1.4 .4dr.2007 IMMa.31, & :. -... vI a-f.2 (3th0 - :1. ýj- .. 7jpA

Zer ofse -. 110 keY G a i

I I ~ I .c..t~ ~ 1 , 1 . IJ :

Sa pl Size:::: :.,

I iL?

.50

of 5 9, (:) .--

Ad itina sytmai eyor 1.00000MFr c io Limit:: r c: : ~.P(321 IP.(i

Corecion

duf-.in Sau

I:

::Ic :. ; i3;'o., :"I,"

"T1

MAY

TI "TF

"T

"Ti 3F)~~l,(T T

("T

s' i3 0

''T F66'.'.

(".--j 3

000"11

0iI

T Ii)

T 0C)

(?)003FI

IIA.W

3-,0(.'.)

1311(.

0*.

0i

T1

10 OT

I.

.Q. F

I., ~

2(21

3;:j

::.Ff:.'IFF:.

F....' F..

s TT

0 1: I's

5!,. 9

T. I'T 13 1:'0 1-- T. -- -

T .., TI

TV T iIT ) Iý

+.-. ..... , ..---- ý .....e .- + F1 .... ,.... ................. ..... ....... l t.-.1... .ý... .j .. ..- ...+ -i ...ý -....-%-.- ... ... , ---e. .......l ... i....I I .,-- ' -,-.

3.,II..I3TI.:A. U4~ iI.3 I. r (h:Id. f :i3:A; u iI 2 Q33 3ýi..I

). (J;..::33.32

Q

QI ivT '' "

V3 1 3Vo.') "T

("I Td 11P

TZ (*--1 1

'3) 3~

Z. "'F?',

06"09'

VOMIT2

C4M'!. "

31;'I.J4 "9'VOME99 "

F i 1 U'3* G

VO+3: w""RV

F F

IF!

(:jC'4..

F...

0 16 a.

2 "86

"I. ý/ o.ý

T31/

20 NI:

'37)t, 11 r.3)41

9 :"F qlk3l.

c !i:(i .1. f J- :1( 11-lJ.: ]!.,:0 :!fl .. iia):.).). :,..,3.: 3 d:.,: s,: ,..n.s•. }

n'ay: .3 MO.~IS 2

WHMII"IN33::ý:l () 3. 3 f3 l 3 F

U;:.4U *4IT "33J

J33: 3a :,. : 3 :: .:: 3.3 i i (3- :ii 3a N n 444. 44444444

w a 1 0 w .. I F. ".UM

01-,IIA 0 '! f.) J..J. C)l .'. X . J, a : W A C) a

I,,...,

"4,4 I

4.~J4, ''"F':JI2';:' f.~ ii''

fYi 4~ '.42* t.44*T '~~: ,'~

.44. 4:4.4)'? 0 44 jf 41

N':,:•'b Z X'

>1 t'. ii~t ::1 ..

,', MIT.. 09-0 44'' "82' E '1 WA to" 09060T

ss "G I6 -J S CC.

99 "T9 '4T- A".1 t' ~ ". T*; 9

:1] C l U -'. D 4 ýD T G .:: C) 4i ) I' A -1 tý-

... ...... ...L) I1 4 2 41 4: @ :4 f .. ...... I ........ .. .. ....I... .. ......... .... .... ..... A U ~ 1 :.~ I. d 1- 1. *.4... ~ ..... ........... .... I..".. .. .. :....Y 1: 1 b........42 .4 .1..

4)u >. )

4,44.4 *1ý..ýiý-!.ýl',

Tk.4y.4 T 9a 4 '

I'll I P "T

(".4 + 1= "6

(Y10+10 0 No''

I 44 1 G~

001 11.4 '((" "I

44 0+ '.46 ''''.4

00+719:ps"

T44 I' 9 9 ' "

If)+116900'".00+3960v 4')" .

('4 91 EE"f(W IM "

V4 9 4 1 4M

'.4*4 .4

4,44 44

U4

' .4 44.

v 44 S-.:TE(**

'44.' b".

co -i

"I-HI 9 NZ

(I 9 4) 0

'I _, 4.4.

ISS I

.........4...4...............4... .... ....... ......4...4.-.......................................4... ..4`.......4...........4..........`...............4....•.`.•....•..`.....•

::l.4i.4 .T'1. , ' ","::}:iil.J.. :1: ""li" ".,': 0':.:1

4.4. 44. 4i4. .44. .44' ..-. ':1 1..I k:J

4:)I~I~.1.Ni''Ž224:2 ,4...F( 01 t.).24: .lf.("IT t.-)4

.i~.4:.: .4.;'i lll~ '. (4:1. ...:27H~I2:4:: ::.p.4 .4.1 HfI ::' 22' ::L) 1. '1 4.

H(T: 4 .I (f4 1' 1 3 "f I .:2. A. () JA .'l f(I E;.. ~'.

.4::~ ~ ~~~I c; :4 4I t4'4 444 :'V'+..J. 1'." ';j fc.+ " ::1 (1)

4:14:7:7:*1'

444..44'.....

+4.(A4):'p) ''

I'.! .4' '.4 I'

"."r:: "(."I. 12VOW:3214.' 440.

103 s4:q4""

rams' W N un.4'ov

-1):? "12u v.,4,.>

c:u"4q. '2'w M a t: .4:'3.uW U 9444"J.1A'4CI 2ENU 24:1 4. .) I 4 A, 9 3 1110 W

EGM ORTEC G V - I ( 175) WAN32 [email protected] 29 Page

T 1"J Iv ....... e" :1. "c" 4 '.3, L I TrER1. i'.? :: 0 C.) A I i I ý ý'5

A1.

Start timeLive timeReal timeDead timeDetectov/Geometvy TK

:1.c-2 0 IS W NI-e

Qu d a i I:, IIf V/ c 1:- a

Librar Fiei3

A w yis. parame/ Iv:'-'..,f..

Stop*~ channel ~ i~'

Pea reeto ee

Pea searc sesiiit,

Sample I i cc:.:w

2. 1i

.~( *Vi 1CCI .: C: q: y cif 1' H . Oke

4048for :-ýf36ke

I.J.1--11iA.RIS m'I.:.IiL:et o

Corrctions;Ic c

D cay. c .El~ :C

a l' 1 :C ~ ,:CU .cPeaked. c backlyrc- u).-id .c: : :.

Status

'YI:;:Y Ii ý'

c o 1111 C: ý-.

!:'.5 .- 0 (:, -

CM, :: D .

1* ' I I' "

SOOW4

I'il--ý "- "T

5069" i,

(F*ý'3 "

0 -

4i10(-f.*4Z."

@"T

E1 "t T4

r.* 4rj1.-ýe-.-,'ý

C-..

01.'E

11 9'"1:

"TST I4.T

61 90

Tf (.7

0 it

T .)(?

0 '.''

000

TOO

T (' ir';T 31111i

(-- 0 0

TOO

T ED(

TOO"

I jDi000 I

I?

47

'~.~7j.4:.

I:

I.'

'1

'.4

.

'4

(I

'.4

.sJ

'4 I:j

I:'

.1:

i:'.. 1:.*1*

I I

3

4 ~

T 0 :

'T

(DT ii

.?:

W4 t .0..4 I

Qm "049I*

lii aT q'*I:

.. ,) 6 1' 9 Z-

6") 11E R 0

04 0 )e1.

0 0 C,

Ti T

T Tf

T i D

. 7 ":A-I:)

S4........4........4. 4.` 4..``4 .`4`.``4.......`....`......`..`........4``` ````,.``` `.`...``4..........`````.`.``-``4 .````````````4...........4.`•````••``•````•```.•

w 14 n 03

11 U'.Af f : Qi~. I1 T .::I2T J, I- :i l (I :I:.. .. .X. ...~ 4. -K 'K : -X N.* 1 X.4

qj':~ '.io: -1 J..9 4':i (j

'24.1I- 264j*T

'2i'-D 1 O t: "

p

I'' ~:, I:..V '::, '7

:O211254"T M12OT5(2 4.'.1f. t77 9T

.4. 4. 4. I 4 '. ' ' ' .4. .4...........4................4.. .4............4. 4............................

22! (0 :13172 I N A: i % l~$ :1: S 2

~ 444 )(~: 4 .~.~':~:~ 4. 4.A 8: U .4 1.4 n E

.tfU :HI J .'U38W 131-AG :HI T ::1 1: .1. 1"1 3 0 1

(3212(2C':I IN z1:. 'AURAiIq 44 444 rf j..4 j .I... 4

ZA. :;~~. 1: :44:.i 2~WJO.4 110: ~ 1l~:4 A]~...t4:

I~i0c1 S~ 4 ~:4 : ~*' ~96 -90MI 1 ;f'.UM (!9.12 ) :I A 9 23i.J.Ž:O Ows:2ii

ION f~ :IIt. ' 4 .1 't 4 1 :p4 .4 ýj

ON!I..C 14:: ~...4)0 AJ.: ~ 4 :

W EG OR E Vt V -i I: (. 175 WANt32 141402 .9 29 IA : (-'Do .

I.)~~* i I'l 17 I, I *) F . :. ) lý ' IS j P :

Rs (MGM')

pCi..,L.IT'ERI; I:M:MI,. TERli•~'.

+ .. ...... .. ... .. .. .. .. ...... ..... . ..... ...... .

RL) :1.0

I J. 3 :1.

CF: :1.

:i.. 8'197E+01'I

1.1313E+01

1. 2512E+0

:10 8197E..3 0:(3.3

3,.

:1. 1.".I":1. F7 .I1(.

"FOTAL DIH5:COE ACTj~)~~IVIY (<' 60 i to 2024. 4 @0000 0.0 :C:i. ,.

ftM ("( .I:* F, () :I: "' (* A R ) L

28 .3 1-'I1~' 31 304.8 %c BA14 W8.76

Li

'I,

FKI M.'.

M - !.`.-,i4

FEIII

364 483 131

1. .?; 2*1, II' I

Peak is pavt of a multiplet mW WAY area wentnegative duri-i-Ig

Peak is too wide at L.ut, FW1.111.% Peak tý-.,St.

1, identified, but first of r, I..t dfailed one op more -tests..

.-.x(:.--Wvity higher than

TUW ?:1.75 3.5. I.:IT

Spectrum Filename 3.2 @ \B773.A1

I1

IC .4 1:l .k is J. 1:: Ji. (:)3 r, . -,-- fc'ms; t. ; J1. o:3n

Star ti :.me'

Live time

:1, J. ,:4.

Deeco system'

MC 5f Inpu 'C 133:1

Ca I i ba I onF i. D6m* I ., C"J I..)3

:4 eatc'du :1 4 1% -2007 3.M RW~.:4:1. & :1 l.5 1.2@@7 :1.MG 4,4.3 Geometr 0,4 'V :,:1.

.3 t O'.'43j .. 3 'I

Zer offse .105.:fl ko') Gai

Quadra~:ti 0' 4: , 3: ... "i 1.3;*,-', : V/ c 4y,3:

.500 keV/channel 44 Vi3~i0 1

I41 .. . J. 1' !

l.; a f., 44t . e. ;4 i c.4 4::) -. -]- -.1

C) I:1. C.' I :.- .kn Y :.

Peak reeto level:4 :4~.3.: ~j~0t.

R .I :.,

40148 for' an3 energ' y o-ft J4.- ,

30. 00%

3. 1iF

1 00000M3

Ad itoa sytmai errory~ 3-:43.1WO

Fr ci o LAW . 00.0"%3:l:'4i444444 1Background.44' 4;1:4443.'i~ wi th bes me ho (base cn~ih3) ;qmct *; 4,a

4:344 4' 4.33. I: j.

........................'~ 31.441:4:.tIlt 4.334:4 .434::4:14j.:i.444.:LI:;:i.4:,33

I 1 f~ 3 1'' i 34 4:~ c;:: I. .3:4.1:4.

I I I :1; 4:1 ('04.'. 4~3cI 4:: 4:4 0 F 44:' 4:: I.:: :1. 4::

Status

2Comen ' ts4

Ii)ie g A.: ~> 4:Y ii:b r Av::i c'rt -r, :r :. iz d d:.CCee '-: 1.7 1

r::

L. E." I I 1 1: "'. C-3 y

.1. D 1::., I-A 'Y 1 1:7I-AE"f F,: L:: /

it. j ,-.., E. C. 1 444 * FKT

]-,l-il I: U~:fi~ CI .T,1.

.i.... -.- .4 -..- +..--............ ...... 4........ .. 1 r . . . 4. 1 14........... .-... 4. 4 .---- +---+- 4 ...I...4.f. .-. 1...A.4.. .. .....4.... ..... f---ý )...4.4.4. ý

1 571, :1.341;~2. ~

I. '9)2:2,, 5422:1. ~ 55

9'.36 ') 1

6-9.

195.76: 9 (:, 1:'.' 4Jj

1-3 T.1 .2:1.4

'I

-f x :4..-k ': J. 4hit t ;

f::iF I Ac.? I- (.-I x'a e c:':c) -ri v c:j]. u J--

11 fl T (.). f c'.. - c) T.:: i Lf. y1 f:* p> I4.4

T D :: . f PHflUE F.T.'.- RJ19:

If)X14 r::ir::f,~r.;f:;:rf I fill)

EA K. U ITI III Pi 1:,ý. YI,.- T1.1 Ul"ICT T,'6 f F-1,41-Ilyl

S/ STC'..'il"elf) P. V

1: :1. 46.

1..1.

.C) D

0If

i:,:: ý-- 11,::,: R. (Dy.... ........ ..

21 (:D

E2 J. 9 4 C

44

4 9 , `-!

J. 1 J. Gr'"

1.4)

CI

(C

I,.,'II

'I,)

'4 1

1. :1.

I.:,

.11

J.

00f ):1.

(" :1.24 9

1kiI"i 0

("I il 02

8 1 4

:1. 5 4

0f

A, 02

0' f-1

6 4.44

1. K392)

:1.1.500

... 0 -

f2t f4

-f J::x.I ; .I. - ,...k x 1: : x i.

As 4 AI~l SIT Ivd

-X. 'Ji. '.,( X ~'A. v X,

"T

T)

1: U

¾

Ii ) 'IIl 11 I I 3

-X. X. -X .-A --X

Mal V"5202 Ow T "09........ .... ........ ........ .. ---... .... .... .. ..... ....... I'l I.tI I" 'I -- ... ............ ........... --..... ... ..............

WI.1.

"UQW > A4TAT43e 4nq......................................................... 4j/1 t Aw

I: 1 .•. .:i-:i ; • I:

...........................................................

, .!fy,.':}[:'i: •, :.'

....................................... .......... , .......-..4;

I: (.iiK!!I•?:-:¢X.: ":

~If >:U::., f l~~ 4ii I:i "

FIh ., il.i( •ir.,";i

........................................................................ ".

(,':f'.t,.. !l :- ': '2 I

(.l~••• ,:!I• ... •1.-' ,

'I ::•"-: I,,' f• " 'I :

., I: I -, ,: : )

w' T -I ')

!' : , .I )

I1.:"... ..I T... .. ....... TT', ".8

vs"*" I-l AW

.I. ....I. ................................ + +- + --+ -+ + + --d ...... ý.

3 1 J i.-.l "3).1- "'H". 3 <1 .I I .:) f 4 I., .:J C) f>I I) N 14 l 3

T1 U4.4 (J T k. JA~c

s 11's'u*r

0090001 Woa-4211-01squawwo...)

(''Ii ~ u .**f3 :5 o3::~ :s: e~q; PC~::(: L 4 &'3W :~ 5: ~ .5.3: : fS.3 ...I ~.:

WOO": @~ ~3J 453 .' I 3 3:

00+30000000: "'1C)i:53::) 53

x-00+:3 0000 ". 4 .f(13 s:''.3

3 '.. I .. 3" 3'.3 ... 3 liii

3 3 ~ ...~ I

'II

J3J131. ''''3

34 ::~. p i: t.~ c:'::j. C 3,3 ~.'.

.3.5 4 (p3: 3 33Y3~~~. A 3 '5' '.3

U T VY Mam OTT- qnsyla oaaz Tauue=Aad ORg"

i: ~..35)f3. **3 "

3:W1 & pI :53

i5'6. 105.

T3 1" .3l.'. '5.'33 C J '..!TA ).~ 3 ~ 3: :

Vi~f.34A: .0~T ("D 2 i. DO~ j. jj

Tl*3 w oa- 00-' 96 2a M I2 3 WI3N Afls;:U233 2 i .'5.3: A'..3)..

Ra v- d) u, f-11 :IJ. v-,~ q]

SEGM ORTEC 0 V I ( 175) WAN3P 14WO2.96

11) n :1.

Energy calibration norma:)J.x(..-.,d 2800

S*.'.

:4444:444 444 444:.44 I*J1: 1) E N 1 E: 1)

P: E1 it K:

P SIG ' i s 'V 4.KI * L.I)F

I. - - - - - - - - - - - - - - - - - - - - - - - .. . . I ... -.- --. ,1 ý -. .. . , . . .. .

'185.5

137 .692.68,

18 5 -. 7;*'.

:137.,1.44.,

121. 7. 906E+0390. 4.573E+0375. 8.

54. M~, '.33 TH. 20 0........3 ?,;l..E:: :€

D4 V4:O u. d.4:.4.:*4444*4 :44 :

F: I~ ED P E A) It

INE.IY4.T W,,,.

S4 . 4 .. 4 ..ff- -f- -f f 4 . 4 4.4.f- -f f-

1E 1 I4

k..JýY1 13

F1.) 1. .:i3

P.1

z Fe

1-f. :1

:1 20 .

41339

:1. j 5 9 . .

It.9,*:, :1.

C, 0

2 4 .. 1',Z

5 f. .1'

5 1.-.3 'U811 02;

834.7

4:C. 0 1) i

(4 141

1. IJ

4.,

34,

O:12

0)4-

(.".ji3, 2;l'

,4)

11,8913

101..4'*(.

:1.:.4 (14,

I. ,, .

4 II

1'-

11111

-.1-ill

4.

,44

1 1',

.1 1'4 JI 1

:1. .. I ~( II

4 I

~' I

:I..

:1. ,, I I

44'4~~.-

~~~~~~~~fe 01:: J:~c IP 1~* .t 'J" U r:.j

T3 "

2 S F 0c. " ý1' 3 ." .

T)E*T 1

T' 'III

4' I: U.

s ."6(.

x A, 6

v4 S.;

E x -A w 0%'

'i: ~ " W'.) I

[-,)0+30000000.0~~': (nay I*a ;0, s 442JY11'5,Ti 1u'.I~lCf U 01

TOMS=t itsi~C'"

f~''~3

."T

+,t~ B 9: 94 ' 9

O 1.TO6"T

(..".)0+306T9 W

00+OGT 13

M -04.:1'

(.7j XT Il~

I' E I -T

'I P

96/O

6 i il::

vsNk

+ + + + -+-+ +-+ -+-+ -+- +-+. 4 . + +__

J I'.I t..1.4 T 1-B :silQ Ts "'I ".) Cl I.- J: 0) A "A :.) 1.4 11.1 1"1 '.3

:~I ~ 4 :jr IN

::~~;~j ((.10'0a-7 *10.. o6& 96i "O ~4 I'V ;Nk.h 2/ (94T ) 1 n ~ C SI 11 )0

S

0

EG&G ORTEC G V -- 31 ( 1710) WAME 14WO2.96 Wl

"[WWi:.~ A :.1 ~m .l~' 7 47 1A

:1 c, f.11 u i i o -r-, i rl fa r fl-V -t., J, o I'lStart timeLive timeRealDead time

T.`C :12

1"IC."B :1. 1

Zer ofse .-. 8 e R Gin11k h r

Qu da i :1 V /I c -

Library Mw.':

Aayis paaetr

Pea reeto levwl

Pea serc snstiiti

Sample Siz

Atvt scln fco

fi:.ýv CY(' -

4048 for art energy of 2026. OMM"

30. @00'X,'

3.1. 00001VOW 1. OOOOEfOOK W SOOOE+00)

2. 8 5 7 1 E +

Additiona1 1 1.A. Eseaic: epar 1.. 22:JJ00'J iF +O

F'racytion U100

I.:ect

Y E.'ý

om mm i. i~j3FIT).

EBRO( c:I:F E:C 0 V 3 - 3.( 75) WrAi3R3 :34 U(E2.-96 29 0CCI '2 (EW37 P.ageEEn vi. r o t~ .I--[ mi -[- t'r.u n.)f,' :1 *''",-ý,2 , i,-:3.

En: vergy ' cal'i.bra..tion : norv-male i.:.::eC3ci FF+.~ ic .1 21 G-1 '..*)

uN I3 D1 E NF T 3 3: F 3 I E D) P E A: K< 13 VI 3 'l3 I') R SLC l:>1:3'Al'

1023.80 310.91 :1. 0i7 208. 2:.14E0 :'1:~ Vt (~33~

D 3: : PEA 3C:c x Ie ojV :O 3.u3.

~+ ':*:. * *i :+2+.y *+ : 13 1) El.ýFGF:: I lE D 1::'

BCK GR.OUND/•ii

F A

(11:C33..3i1

H.; 3.13 I"I A F.~ Y 2: x.) X. A-+ j .f N.) -Y- *:k A.p

4.A- - 4 .. +-+-+- +...........+...+................+....................+............ .-............... 1 z. .... .-..... - I-J

C~3 Iý:1 . 16; A

T :1. '31.

1,43

( 11.1 T1/5

13 Peal,-

6 :. -,, J fil

660.00

732.00

3 . 0

2 63

:L 1,3

4). 4'

2 Bn

49. 98, I '

537.60

(1 31

((.

3;.1

'i.", 2

33

19"

26..

011

3.:.J

i10001~

.0020c'?23F(E 0EI 3

c4fi -A .

31. 4

141.71

2l ('1

f"l` .3.

164. X?

2 -3

11 0 !*'.i -.-

5 I

2EAU

1(114

3 3 1., '.3~ .~ pc+ l.';+:'cl:.:c;

EG&B c:C:EC Gi V -- I*.~ ( 175 ) WAN32.C:~: [email protected] 29-O~~CiT-200.~7 1508 :50 Page

Env~' iron'Ymentl.:41 Inc-~~ Ai~V.' I'~ ./4 v~i

NUC 1 i:1) V: (::C:i.J* T i'Cy A (CT~IVITY i~ COUNT I1[ I: Nf(. C*'6 .E

pC~iiL.ITEI:'!"'EI: :C i./LtT"I:'.

•'"""•'"" ............... C•. C....•. ..... '- .•""•". . "".............--'" +.......'................." ÷"""1 " """.. ........ .C" . Ck " •'""","" •.......1.. .......'" '" . C"" .'"""" " 1"" .. C.C.. C",."C÷'- 1""

Z 114

ZR-95lu J~ <

RU10 <

RU:0

1-131Cs-~ K3CB-137

I.A:140LA-14

-4.

I . i, .t I

.4 7@85E :W

it 1096E+0

:1. (".10

2.6150E+00i i C:

2.770E+0:.

7.6249EI00

GL~ 2571E :1.

A:: ACct.;iviy A C p C i. ?IX:ci , butu. Ca:~ctivit*'y < C'iC (-- - ' .. .... ... ... ... ... ... .. ......... ... ... ....... ........ ý .3 CI I' ly C f.. :, y.. ..... .. . .. .. .. .. .. ........ .. .. ....

TOIS ACTVIT (1 58 .. .1 to 21~2026.1I :C:tiC.:CC~i.C kev j)*.. TTOTAL.. D:E:!i:CAY:ED; A:CT IVITY : C5 .1 to 2026( S.1 ikeV) 0.0000E0 pIA/ 1: . ITER.CL

13 . t CE-14

364.48 X -13

T.'*3¾ .i 32 X A C4

63 .9 % 1-13

76.7 % i NB91099.2 C % FE-59

13 05 C CO-60

("t ;. C ('. C 1) : S108 .3 X 'C- 'C

47.6 & BE.

S0C...0 %~ CS-13.

661.66 & CS Ca795.8 St * CS-13-

1.15.5 %. ZFi1460.81 .

610i. 33

7I4.1

81 7CC!5

1 (4 1ý 4k.

32 .7 L A) -' 144'f

497.08 ICii I84 Fý! .. i'IC C

Pea fal C mst t test,

CPCak iet ifiedi biut fis peak, of C CC A

fa'iledti one~ C or tCCI ,f iIt~~I~r

ci &c [:OTTEf GICC V I1 ( 1,75I) WANf32 14W(O2C.9 29, COCT-RO0f7 M~44:39~ Pag

T1,01,0 5 LA:Tf.',ýýR

k" I ", ý /

f- 4Ic l i I I 'i i i

Str tim R i

UW t "' ime

Rea t ime

Dead t Iime 1. I 1 1%

Ca I I i iaio-

IIIC, I. L

Cr Ied 14Ma -20 M5 0 IIPIr2 511M

I"IJ .Y1 aI *1,-I J, :. .

r a II C.. f ..

Pea rejecion lee

Sapl Sii,

Activity ~ I selig .jco

f1 T.. 1o r- n V

30.000ILI%,~,

1..~ ~ 3 5L~II / 1 .iifI i:W TWOOMOO

Frc ti 1 Li it L',; ': I. 000% 5 i ici:

tJ u I:-u s t o

Decay. duig oleto

St1t iii

it:Y E

c:~ ~::fYL I7I 2 :1.2 MU

S(D~i Vi: -l Ii ( 175~:) WAN32¼~9 14 LO@:..96 LR9-OCT-RNO0'7 fO'944M3)i 2:

Energy calibration normalized :1., f..?}7j} H-

C'I- _I'liLý: ~I( E:j V~ii : V"1 3jY.

Ii D E 4T I:F I IH 1:, Iii: :* K S lENJ I AMHY : ::

I- f f f f f f - -f f f f_ f f f f f f f f f f..A... ._. .r ... + -4 ... .... .i 44.... ... .34 1 ... .1 .i 4 4 i ... --

703. 3%; :1.1.44.'

PC Us 04610 J-IM3

I D E N

1PEA CENTRI, i

T 9..s :4 ý..` 4.* 7i~ 0

B~~iiii *..5 .P9 4 7 6

LA-140 974.9 48.4

CB137 1318 i'0.9

CB-14 M9 .67 '79.86

[:Ti: 9 5. 1i 109 .0

120.

174

Rio.

:16

13.4

1) AR.Iiii-

:1451.

13 U I11 IVI (", I;*. Y *f *34 fi* *, fy ~

3.

:1.f-I[1;

I lii

I~ I

t I,

ii ii

Ill

G(Cvi.

3 [4 [J

(I'll

I ii

ill

"IL" I

ii '1.1

ii

14 I. ' '3

44

124.46

2 8 . 0,4 I

Ii3

147.3 580

0

waT~nonuom Wjap WT4hak.

01V 1.4) %3 !..'i'I1C..3 . 0 ~ 3 39"M r6 -A 9"T6

0 .CD .111 4'4 z % 9I~I 9,' "9 '1 ri Tf G 3j .! NW .1, 61 Il I.,.- ý' 16

T :j.:; 3 M E 43~i jf~~f 1E -w 04, V02 ~ TVT :3. (7 ":.' ) 1 .1V "713 : 3 -I i U..U..

s':4:4>.4 N :.~I: U:1: 3. d u 3 a k o i A44 0 A l: , A.P,:. U wII w F 41 4

83 11 Td 0 30 a e*- (nay(: T-ao o.24. Gj. p .. 1 '' MX4 ATO W101::

....~~~~~~ ~ ~ ~ ~ ~ ... ... ..... ...... ............... ...... ..... ... .:... '.k `! U 41 :441 ~ ~ i . F1 ...... ... .... .4..... .. ................... ' ..... ..... ..... ..... .

0I 0 + 3 0 2v

T ~ ~ ) *3.-,..iý''1,-'..- "a

0 4 7

T3(3*) 4-B 0! *-3.>

("'4.o

T CD)4 .. rATq ,"."Yr

> E- 13 3D

>4 3E _

(YI:

S6- 1, > &-3 ]> s33

> ' 00 .. .

> HL.it: ~4~:3 3C' 4?

U Df. I. .*I" /,'!: cl

cI " .J 14 : kJ 101.4 1.1 FC' :: A 3 3 * ,3 .33 4. : kJ 34 3

.x334?::3 t,: 46.3 1 ..:: ..1 1i. 1f1ft i 1''Ii;3 i ~ :: .( D :: .)(3 S t

S

EGM ORE Giii V: iit (& 175) 44C3 p Lrun n2 m 77

Str imeLie ime

A.33 02

10 7 0

MB I Inpu

A I il. J.~

Pea reeto level

Peak~~I serhsnstvt

Sapl Size hf

3c

3. 5 (-`

IIf.OOOOE+06 1.00MM M5000E C{+(I0C 0)~~I!f* C..

Detectin limi methadv cFZ13 methodcv ~ A ~ i(&K 2:1.ii~~i ~

12::~~~~~~~ a -,,- d (iw 1 I:- 12 : i 1i b C ,i . : 1' i

Coret

Peke b 1:2-f.I 2-CCund corre.-2:cC:t::ionI

Y E iNOYE13 . v q. . , i ::-..

VV "I 99 TO T 411 1 11T

* . '' 4*, ) fI'p

I FT kE"099 000 - .I

1Y I~ T (I."If'J3 1- l'."C*. 4.11 J

S 462 avV 000 4.,

C) I: ý'', I: T

Cf',]I,(',1 0 '' I l

Q4)4 * *4444 :u 4.T 4', 4 4 1: (" II14 i

MTI

TI:'

"T7'

VK,T

.4.l

'I0' (-.; 1r )

96'. "T'''"!'"

c) z..p.j Kf 0~~ i'.I !

EJ(? "T 1.)

I- III Il

:1.1

. -I

t? 4 A

Ill'+.i-

I (1. :1 Tf J. T .1. I.JI :Hl U n.l 444.4.44 ) 4.4

"•i 1'i!:)"-l) .l,:: t:.ITU E 9v!! "WE "!W" 6 "NT'T•1 M O M' E9 ' O E:: -

,.""...................I...................4...............4................................."".........-..-,.................-'..4'--- " " -""1..... I "" •-"'• "" '•"'" ..-..,,-, ,, .',,,,-i '" " ..... ..... •""" " ..... "' 4

:, .l. JI.•,- .. .- 4• 1 .. Yi I., I 1 .t:I :J 1 ,3:: A I , I.IF MS-t I : : 1 3. 1. I ' ( 1 1f , -,. ... I- -,.,-i

44.4.44.4444.4444.4".:I.4 tj 4. IA 141 fl ". 1 4.) JI I. -.1 TI .:- T .1. [.4 Til 41.. :1 Il 1", 1 4 44444~4~4444*

4'. 4,i! C '1 "44::a u4 .' 44 j. j. p j:14. : j: W n Wa SMUC13v .4 .' '4: i j .q i .: ia.4. :i

4: I WI :.'.;.W:j:-1 4)4.IiD 9Ta '1 96 1Ii4 I: I .lIf (s.i W NU :I: A E) :'Y1 1 >14) 'Ž4

Mt,IC:' II 4. .4f ('.4 44 IE~ w c:' I::' 4.44.4 4:4 I: ::i. 4.4444,4.4 0.24 A .J.4:4444I 4:4 4:43

(*.'.11:ZT1i::(:'11 (.'-) V I ( 175) WAN32 14WOR.96 26-OCT-2007 103046 Page

Anvironmental

U 171 N A F-'. F, 11.1 U C L, I D E 5, 3 1 11-1

T:1:111E (:,*(:)I:',.RECTED UNCERTAINTYH U C' L. 1: 1) F*.' ACTIVITY ACTIVITY EML01TINC-3

1: I *1 *D I li 3:*:1

I:: U L• I.y T. : "'El;.. pC. .I..R

.'.' S.t.S.4.........t...........................t.............t................4.........

* '4.

K-40

CO-5

61 0

:: :1. -.3 1

S. 601E0

4 :1. Ei 0 (-t.ti)

1.it 4MOO1

t.T . 1.',.* C-t 0

1.76291+01

K?, 603:.2.i1E+-'"0:1.

2I. 0 764.1F:l- .

- :1. l4 3I: 0fi'. ", "J E i :i 0,ii•'-"()?

ENi' 7085;.. 1 •?E 0:1"".?•/-1.i 5906:. .,E-+0{:".•)

8'' ,0 1";'13) E•ii'.? " 011 . 1, 1,,- -t 11. 11,):I

:1. ,, "76IEW1i•..--/?

tJi I,, ..:':.-} ti"'j.U4::

.:,,2 4 f4 ii t:-. '•?l'!

,::., ,, I9! E "".)?

* ~ J -I-- t.

At Aciv ityI1 pr inte~s.d, bu.t; actvit < I .M

.. ........... .. ...... ... ............ ..... ............. ..... 11 11 F.1 Y... .....t ... .....t.. ... ... ........ ... ... ... ... ...

-)( ,( ). X II--). ' '- U 11 NI r) F..' Y ~ **D F, D ~ I ý.-- C 11 F" E 1

:1. IF 1-'t- 1. 284.30

49.0 % RU-10 53.2%B 411 64.7

12 1 6 & F -1 1 13 2. 1 'o' C 6 :1 4"' (. 0. a I %

I JI ý;

Z1

KI

14- ý1 .11 :.4

L 4 -:1. 4 '

Peak is part of anegative du'fýi-nq

Peak faih; sevylitivity test.1; F, a identified, but of uc.-IJ. d

failed one or more

T ( :1. 1;.) f: ) 1 -1 1: 4 1,4 C,".1 4.,ý C.11 C"." T' --2 (,.1 f..?s -7 J. ID A !jI eWvironmental Inc.-

in j I. T 1, ."F"

yoI

DeetrGoer IIIs

s :i, J;I'll C', :1. T T.-. :1,

CaIi a i wn ..

I Ited 14Ma -20 1*3 :3 N4 & 0Mr20 N2

Library

Ia':;I

Aayis paraeter

Pea reeto ee

Pea sarh enitviy:

2. 1i. 1:-.

3..

Detection lWit method:;

1 0 E: 14. (.,JAdditional systematic eprors 1.000000011+00Fraction Limit::Background widthN lest method (based on spectrumKI

Correct iStti,

Comments

22.W.

I., 1 "T

SUN

T I.',

16' S T T

I 1/T f. '*'I

3.) W

92 IM

T 03

OW'..f

T 0 ('D

200~f

S13.'"

Ti

TOO

0003

TOO'i

000"MI r

0) j

BOO"1

T3 010

3/00l

(4,

.T

"ET

"R 1

C 9

'1.'':

liP!

I?I I

1) '1

' r11

4.1

44

4'

9 OT

61 S

0 .." C.3

Z .4, 0

tIIT

i'., 1:3 JT

q: 6:,"T 41:.

I 4 IIi 1

('4' ' I

4, II

4..

4 III III

'44' (4 3

4(I'l4 I

I 'I

.44 I Ii I

.11 IS.,

I 33ff

I f1'I

/

I I

'.3'

I I)

-ý I i --i" ............. I,.. .... 4. ..... .. V.- .41. -.1. + 1... 71 ....... 11 1 11 ...... i, ..... .4 ...... ...... 11, .- --f ..... .. 11.1 -e- .- 4. -.. .ý ...... Ir .... " -, 4. .- -I.- -I Jr ý I'. .... + -.I. I.,,- I.. I.,,.. .--. .e- .-I. 'A. .- Ir I.- -Ir I... .- .-ý .n'..

.443.3. 44 y... ~ ~4444 A4 .)ISN31N11>31 1*0.*:) 31 0'.I:11 1 A(1 .1. (37( 3 N I :'lk:JUiI'::1 3121 .1. 124(1 N

J,~

a F

U ,

4,WI

9FI. a::

., 4 E ,

ROW1

E 1i)IO.(M "6.:

"91 TZ:, T, VT

'COME31: .1

'.4 (",1 :. .'.; I

20 i

4 .. 4..............3..4...3...3`..........................................................................3...............................".•.....• ....•...•....•.....•. ..... .......... ..... ..........

():311iJ:l'::Isfl)344.444. 344~ .44.7.7.4.4 .4444.44 .~. 4.

C ,*~ .~I'.4 4I'I'~lT

;:j 14 I'] i.1 V.1 4,34

( :ii 73A : (. .:.:::(I I .::I1 1. 1-j :A (I.,l Vi 44~ 44. 44 44.7.43.44.14.

E1 abe M U PU 34.4,i.4'4 I.Oo a 2E1. (Sp 341~.:L........ ) Ij (I'z q ~ 31 1,10 E

01,1I~u. o 13 4 .3" (3) ~. 4'::: 3:4 '3~.j, 4 4434:4(34434

EG& ORTE G - 1 175) WAN3 14WOR 96* :I 3 ::

*4*** S U N M A R Y 0 17 11 U C L I D E 13 1: Iq(DF, fll"KK (:"*C)I:ýl:,,,Iýi:(:."Ilýiý'ý)

HUC*1 1JAH: ACTIVITY ACTIVITY (TO U N T I N

l~i

pc';i /I f. f [J-1" 1: i. I... " E i ,"/ L ...

FE-59

4_111 6F"

RU 103'3 <

Cs! 13CB-r~13 4F

BA14 <

LA-14 <3E. 14 < '

CE 14 <i)~

1..5824E+ 1.

cc:. 7280E ' 00~

.31 001 <E+0

2% 0646E+.

11.328E0

4.4 .2E 0:1

EN3, 2797E 00

04 2557E+0(-'.-

3.4969E+00A2 A :

1.~ 890~:3 E+05;** ::1.

2.1

6.9989E+.005f)

2.0402E+01c~t

A A1cti it 3k0. <. 11, A. t's.)~.i* 41, : ii~~~..

........ ... ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ I. I ...... .......... .......... ..... .... ...... 1) 1 ii ,1 (_1 . Zi .....r.... .... ..... ....

U S 51S 5 11 PI~

13.5 X E1 44

14 FA ( F D

63 .9 1-31*~

76.7 % NB91092 S FE-59A

1325 & f 6

61.t 6 &) CS' 13

79 .84 &U. 3 3 1.

3,./' 5 .55 Rc

146.8. % K.40

60333 % Fabl W.3

'Pea' is: par . 5 ti of a1 mu ti le 4::'v thi area3;:1 ~negatives:: duin dcovoutoi..

Peak .. is too: w::d:: at:.': • 4t: F:325M bu ok at* u,..H M

EG&B ORTEC G V 1: ( 175) WAN32 14W02.96 26-OCT-2007.Jýi! ,.,IV i ýý*."I:)(-...,(:..-.t.....r-.k.ti-i-I n a m e ::

1

d c, ri !::CA F :~. ti o? V A e U .-I7

4 1 ~(

/Y~1/

Vt

C.****, .. ed.{7. 14-a10 7 1 N2 M A2 -',

3 i " '" .. . ,J

Ze : oiIffsetC

I.k,.. I -f-a -ý,: i: .

.105 kevg Gain .50 k ' cxh I x i ? :

I I i (4i d

Sto chne

Pea reecio levelH

Peakx\l x x::::. .c

Sapl Size:::i

R.:. I ::'

fc-'1 an cxcx i f'* (.,'0, 1. F et) c4048K~ 4f or o: 'xx x~ * :,f 2( IY124/..3GkeV~: L

30. ) x'

50(..;jf

I.OOOOE+06/3: I.'311.*MMOEB

RISO method1.0000000MOO

Additional systematic ewNyrn 1.00000OOEfOOJ-1.1i ýt.; t;

Background widthv best methiod

†or cion-,-,3

I I c 4 'x I I '-to ; 1Ifdu I . I :IxI:f c*C i cxJx.ix::x

Y. ME3.

KIO

Commen0i::

C3 ()r, I (. on -f% rm ci t J.]N

F",air~:: 1 :.1 d suv.-- J. .1 .. j I p4 NO ~, :: ic:~ 7@ F 7 F.

Energy cal~:i.bra ~t:i.on~ no rmn:. .aliz~ed c :i f feen e uv:a :. :11.6

*3~~ 14 1: Da Ec 11 Ti I~. F" IE ) F! : 1" -1lýFI IENC:: UNCER 54] V1'

Y *LISPECTE :D*~aa

185.0("9 92.64 92•.'8. 249. 1. B."SE1+04 50, 55 11.4i.;2 - -. 14 C-a . a.-: . ............ ', . "............(...... ..... , . . a a a

70R. . .: 5 1. 4.3 253 . 132: : ,. ,. 3)-71÷(1.i'4 14*7.,, ,', , i!; .E T. .I.•-:: " .

:1..1.7.82 0'8.99 :.-: . 129 .1.686E+04 2 9., :1.-4 1.. j,,93 1:..:1.. )

Pea i'ti 'I'

:~~~~~ D~ E' N~ T I *~i a: p a a: I ~ ]

11-IUCLAI:~i Tj~:CE ':M

F I L: 1) IDBACKGROUI,-ID

CCIL.11,11,S,

Iii: A KMET AREA

U Iyl III fl-A F.., Y -ýC- -x- -.1c. 16 -x -.0- .)(. )(. )(. )(.-

INTENSITY ummun, FWHVI

. E 144CE-141.1 -1: 1

BA-140.A14

I a1-3 a

IL) .1, ,3

h.. 1i

S(4 :1 4 C' .

.................. ............... V ..... a...............a....•...•"..............•...•...•..`•...•............"...•...•...•...•...•....F...•...•

266.90

56.86'

608.0.

656.55

729/i.52

la-i.,97.6

995.00

I P44. 3

lt. 0 .1 1 '(11a

1322.9'6a1 1 ,,

:1. 5:1 0

2 1 ' .

1593 a a

133. {3,541I. 1.1, 4..8.. . :1.

3i;•28.i, ,36I ''., 'a a,•,

a i I a ,"7 Ii

56 1. P2'S

622c .:,, 4:.[:

1115., 5-,, <.-:,

:1292.t!):. ,,912c1. . ,, i .

: I. r;. a;,.2

:[,<:6 ?), 1;!............ ...........

-3 a3

358.149.

153.

7.a'

J..

a.

il 6"

19'

C D02a

0: a

:349. al.

a-i"-

2(`a3a9. ! .

aL. .!}, ', ".

252.45

I I:""y " "

a , (.I-( l

aO.:

489•!;.,,90

... '.

C 'I)(a a

1. .1 I"I

:1...aKa(.'a C']'' I

a•aI'aa. a~

af alaa]]

r~aaja 1

/a* /''..a a,.C a a. U

I 'a

~ 'a-;

t I$

a::

(.~1( ala

D

I3GMc OR E G:. V -- I ( 175 W 3 141402.96 26-OCT2007 @&, $&7 Pap(.:..!,n ironmenta In(:.-.:i.T u 1 1; '.'.4*7 7(Ž) 4'. (" n 1.

[tIlIF: CIi: ~OU *. .1 F: (:.*(J:z:oF.FIl ,,(ýITED .~ini(:EF 2~ I::; *- j -'

pCi/LITIER" pCi/LMDQ :C i/LIER

I'll

B E*

FE-Wi

4:.

1. 3759E+0IH .:1. , 'I

:1..7865E+00

:1. 6 0 1E ti00

1.6202E+0:1.)

1. 011+01

A~lv Ac ivt :~nt.-e 'L'~.

4) 1 -. V toD pF) 4, /4 IJ 1,) F )))))) F: 1 FF) t./

3e; 2 6

497.108~

:1 9 J ~ , (,.-

S U~ [IN

RU-10

RU-106ZR-91MN-04(I

J: '],"I %' I *i:L

4-117 (~ /~ - T. I1:.' :1 0 3I

5)0. 8. 0 t".

Pea is part: of*1

{.i* a utpe a mae et

EG&G ORIEC 13 V I ( 175) WAN3P 14WOR. 96 26-OC'.-F 2(-*.ý)07VJ. r -1.1 1. name::

:1.

1 L4A :13 2 *."' I-T EBG ~'

"4 /

I I

C-1~~ ~ ~ c q I.ti J t. .o-,J.11f -- 111a a--

Str ime~

Live time26 It 2 0 r1:IM:;

4

MCB I Input 4

Ca libration3 I *2.*(

Iratd 14M:-O 1550 , & i'

Zer offset

Qu d a i 1 'I *,'?i fv~ ~

Library~ File-.

W 4:. i f:

3 I, 5~ 0

Additional systemat:i c U:*rr oru 1. . OOO+(

Correc 1:A onii

Deayduin .2accquisitio-ci. I

YE I.H."

YUH'.

(i:Comments '** I

ai.~ )-. d o4 1.'>' s : u f., I U) J. I. :' ! 1-4

En:.vironmental4 1: In(34:.- 47 (.*. 44: 8 IA~3. A .1-1

En4erg :y c::ali.:.bT\t~io nor34:mal. iz i~ed di f~feren ce:1 2603

34~~~~ N 1: D4 E4 14 T' :44 . 1: F' T [4 D' ID Iii K .i; U M4 34I () F', Y 4~ *

P A ............... R............3.4..........3.4.4 4....................D

P Iii *f-f f " 1 @-f54 :1. f -f 3f-: *, f--f/ - -) : .... t. 4. :3:--4

1020.89 510.14 4 p09 147 2.9E04 3.4S.u5:-33

1 1) E 41 T I F I E D F,I'lUCII T.I.) F: 1::IIH:AK D, ('.*, Cl< ýý3 V-1 D

T :1. "31. 1, 1 1.3.B I - 1 ..- 5

LA-40 656.5

RU-103~ 99.7

BA 141 I)

CS13 1 2 2

-T :1 4'

5/ :1. 5 / J/ f I

C t3 :1.2 (.A.

133.54 49. MI. ' :tL.

2 A . 4 . 1

.3 Q-Y.", J . 5 A.

496 38

C.-I .333

3l4 1 31

/1(13.,

7 ..) 61 .3 1

1 3* 4 3

,B U.. 11 11/ (."1 R ~ Y : ~ :.3; 34..

005f3I: 297.84I:;:1

001`ý ~ ~ ~ ~ ~ ~ ~ : :1. 4 i!*-* .(iJ .s

0 J.)-3 1.433-43.,0:1. 3 *r3 --.3;.:.

(---'-0 14. 76 4 . 1 e

01.3111 927.43 .6651

.00 14696 1. 6691

.0 3 211., 450.-:

1 . , i,* 1-

(;i) 2 12, 4 :1 ':..1 ",

0Iij '1 "'Y!.3'

(1) 1 1 7 513 ,j

'I .:::, 'Ii i~~'

3; fl ~ ,;i.j'. *::. 3'44 ci +-:c c::-~:: 33 Y''23 .1.

C) YJ I.:*..,!:~

qua vaa sjq pur 4alv'1 w Ii.w .)ea

%

qfl ý-..".l T "t414' y Z

fI.i. I I~ I ? z 9 GT

I E'.'Ifc 3:.D I

Z-1i:. DT 1.1"

'i :i l -J (Y il 'ýlI .-

CI., *f 1.1 Z.Ii

3 Il' J C 1U I id W i C '.

0- ,

9Ii I4 "WEE."

May TME 0.'I fH"

T fillj

-4 -D~ ("1 ..) (..

00+3999 7I k. I

0039W2

0 0

I'l' I :f.E ; W *

(.`.4a 9VrI 4'MLL

TOMMMj

00+390CRI

00+I;3())q)~.

00+3621M

f4I v I)T-

5.l' I.D T f

>)

>1

H31j1/n

"'I 'J 141 t---J '.31. T I :Hi ( : 1 * 'D A !-, .::I :: .!k :' 1 :() Id 1.1f"Iz ':i 3

:1J." : Y1jfff'

'1: U tj "'a '1: 3 C-) M e U '1111"1 'J. :) d (,( :1: -

aUnd W9SM 91 400a-130-9a 96"aOMVI aCMUM :l:

oqd -mqUqcj

0010012T (.*ý'..ý;.".,ý!...-,"I...,:,)(:.'I Isquawwo,:-.,f

*(Al

~1~

00+30000000"'1.

00+300000"

-t *! .* a

.~::..1III.f~l3f~I * Ifd

MuTNET~~It~~ Lf2aw6 210T

1. 4 4.1D~I. fEl .1

W 4 2 : ;a1II an I

I /

'I-, ~'

L00a-130-9a 96WOMI WNUM (911 ) 1 A 6) OTUMO OWD

*1 E R ORT: Gf r.:i:j - 1: ( 1.75 : W'1rIi32 1 4W0P2. 96 .... 200T* 17 1 '?iF. 2

Ener ~y ca~J.lbrat i.on I:D~ nu m al /. A.,cJ di :1. e 'f c- c

Ho: ~.;0tjv c~~a a i o.1 . I o: 'a

1I.1 ,(-*?)0(,;J (!t

~~(*~~ Di EX ) 3 ) ~*I * 44.~ y . ) N T IF I : E: D: .!NI

P ENETARE

S U 111 1*11 f".'i F.: YUII-ICEFIIIT

G 111() 17"r+............................-+- - -f f f f f . 4............................ ...... 1,.....1 .. 1 ..-̀ ... -.-

CE-14

IA. :1. 6 (,;

R J :1. k,."

1 :1. 31

.1111 5 Z

z I III

(..!*` 2 11 5

724.0

J.

11f.. (J

:I.

:1 2 "

P8. 56~,~

34. F

65.15.

9 17

1 4I

11I 1'ý*-3

IRS'

:1.01

2J

I it

I I

F III lf II~

( IF

KB KBf~) rjF)

it

UHI,:I

:1.

@5:1.

'it

UK' K:I (B*j 17(K)

U)'?) :1.

f'II'If. I

illfill

f I

:1 -,4 '. !..

147.3

2!..'. 4, 5'

4jr 0i20("..)

44.1.5

16,

:1. 8 4,

4 1.4

.14

I~:f 41

ft:1..

fBI II

:1.1,I'll

I..t

4?

III I-,! ý'-l 'f, (:J F, !-..I I I'l1,111F: ("IF, "FIJIF: f,-):I: I-ITY

U L, 1: D F ACTIVITY ACTIVITY M wa I

r) 1'! I::(::i11~)

C i/ ... •" f' I

III

<I 278 E I.

G.6 .E0

4.S

0vs is O TEC 6 i V s - Is (~ 175 WA 3 1.OR 9 2Os:,T 2 -*" :1.7::..')

RU10

(I-- 31

-3. 823E0

4.

.. 5 2 '` I-

6.1

0t 3. 3t~ 7E + 0

Q.I .1 MM

(-M. 5 0:11.

I.R117EM5V4F)I./

No11E0

A~~~ Acivt prntd, < :: MDWF . .. ....... .... ... .... .. ... ... .. .. ... . .. ... ..... ..... ... .. ... ..... ... .... ..l~ .P ... .. ... ......: . ... .. ... ... ... .. .. .. .. .. ... ..

TOT(.5y.)(l 65. to:mI~ 2031.4 keV)~~~1A ~~s :j.~~;~: 40 ~::...

133.44 & CE14

W8.76. %' LA-14

497.0 R U$ 062 .8 R~ RUi5,-1i0655

756.7 %~ 5) $5834~.84 % MM-54

1291.60 FE-59$

145. .44*

132 50

'V

"AA'

DI 1 1

CE141-131

B A 1

1-131

28.0X 1

:1.115 5 X I-1i ý

1408 R 'K-40

04 11 8 J1.

011..; 313: S W4 M3~'4>

1 5 11-"! !K Ir, $ 6

Peak $ is > par of a1 mult~.ipt t am!.4 U MV areaii:: went-2>. :ii

Pea isI to wideiat FW 5M bu ok at' I It- 5$ It 1

X Itt Pea fails Wliisit (45 I I

0

I'

Woo wi~~Jr~fI~i I '

jo u:: ."..'::]. !:/, !: •:]. !:.. .........'.. .•.u '.-:. ..E.:,..,.-:-,-...-.:.:--- i

• ~~~~~~~~~~~~~. ..........!.•...:.:l.-t.l....•• .. • :.,( [,:, t :

p!.::''' !: ..:i , ..-. .,: : "

um:1 Ana SO" 1.k OO Yt.L~A~ ~ ri :.}

ri.!,.! u~: .j *~~ C'tVi*1'

..~ .,.~ .I .,..~, .::~ I I' '1 '~ '1

I,

~ Iki~i Ibi Irh

0 "31: 0 1`. 10

P, J

p r j:3 Ip. >;;j: :....;.. , 13:-g 96 w o P I'1JPI a mw I) n o I I m > O W0 0 .fie

0 E.' "

irT

0tI

CM. "

...."......

0 .;)

I'E' ID"

'Iv (

. 1

"3S

C. 00

0 I ý ('31

'6 "92

TOO"

I 00J

T("i (-,f)'000If

T T

ii4

q T

4 I.

(1

4.''..-

C..

~j42

'1 0

E" 1ý

(..,j ."D

6t WE I

6 1: , i*,'

00 "492

Ct 9 I C

Sf :il

I Z

.0 *1:M

oll" IF I).

I-TA) I

T 14,/

.)Af.4.ff If~)~ UIA , ".) .114. .4~ f ) ':4. *34 ). f:I 4 il 14 I'.., :Ii :D J,4 (I~ .f]f T .::I I~ J. 1-1 :jI. (I4 I

..........4... ................... .4.......

+e:HKI 11 ,11 44ff ,.i .. d U .4 i

',-,I U A cl ci :::i :i: i :i: i ii :ýij a i N n

I:-4 44 1:4e I::~oa-s ou4f.Cl4

40 a 1 0 g 96 0 V aENU WAT )11 1 y;- Ai Sf 4.,.C.M4~)(1~f' .if.'4 .1U. OWM.~,IA

Aqu aqu.. N quo e4a q t .^T ip fe j ..

w~a.MM D U a~j

j~~~~~o ~ .-ga. n 4 OTJT Aaf.W.d S

*1*

I ~ ' I if

if. I ,I,I, Ii

1•14" II X fJ~ f

M"EUT G.-N

I ~ Wf II

QI :1 0., "D T U

%1 2 : 1Z..`s% 9

Q W ME vf)u w 4 "WK 1

x v t"T ~ T

`tl:ý1.11:.~ -I 'I( a ."Vaj 04 T.sA l l I I

Tf 0~ "ej'6" (.`J

00399'.

I jI IT

00+37000"2

0 0 : ~~

T: 0H ".

T~~- 1.3 6j (-

TO69 AT 4 I

00+ ZIM

V ̀T -' i

, ""T

go -n .,:Icoi-;f:

(12)H

9S,')N21:

I.4

I 44 ~4 .4 .4 .4.

p 214:1 I 1 LI ~ i: Id 2.:IZII p~y' i:

MOTS 2X. -X. 3k- -I ]J IAI t-.) !.,3

E,31.1 111,11`10.. T tI :: v .) Ikil :t.J.::uIcIfIII

4 ~ ~ ~ ~ ~ ~ W U (fIL ). 1ff4. .'..I 4J i p:4u ~ 7 Af'U. : .~~.

* III

4I )~.,4

:ý].M(DI

33A.

uo Pa.

00+10000000"

POW$ .444 A

KiiT '..

I. ~ I.4.~.4:I

T 4nd l T 0 1.,l

a,(II('Iiw:.• Im

* 4 .4;l&.

,.~ ~j(.

O4T4 4w4Q

4.) .q

ocq4 ,

r~4~•~400a1ON 4l 96di.J MOM .2K .NU Wj.4).

4.A 0 .MIM.4fI.J SWE

4

'"T

S ) I:

f ii.'

.D

C.. (' I~

TT dT*--;-'

Tf 4'i.

60"0

"i~. 0" E

F9" E

E * 1*J''

Tl

WIi

TooJj

TOO, I

TOO"..

900

T1

CD

ZlI

(-,".3

0 1,

!T l' "T lliý*ii .' l

...................... .

'!:i.I .... .....

,"'I,.,,' ,' i

f'Tf I' "T

"T'

ý.- .) I'D D

1.41

'I

I 3

I~iIf'f.:i I ý.:I f:I) Its Z3 3 .S5 3 1Afl~~~~~~ 13i S)~ Nf ~.i j 1 '~ k31 IA0M Al 13N

-4ý --ý' --il- ý.. lllý- ... --ý' --:1-- -.1c I,- .- ý"- .... -11v .. --11. -- Js..,J. 1%1 fj A.,f7' H:Hl -ED F1 F! U FID

minodomme nommo mad B U 1 -13FT1(T 'D I -!:I 1 -1. 1--l ';ý! G. I

(A C, ":'ý f.) Vý j, V"' V" 'H"'l

d qýii -1: J.

.' -ý. "V"'? ýt' C,* .3,. 1: '1

: ii l fi3I'lI ?1Y)'Yj c.1 '%" :) ..ijI 1 .J j'.jU38 ki13N jul02 ,¾2."A:hINUH) I-1IH)t:.3I'I2

3' 06T .ým a~j paIonuuTwa~e nu

ab e ''JfI.'.3 10SiOW C 9 6 W O M ::s.t a S N U W i l )2 .~f~lI. 01. A S M R A....

bulmmns wopue',.:l

k " i t * * .) 1.: ) u .- 1 : p

aIjn 1~q go qud SOY n.

"WIT W ' is) ' n q Iand ;]Tad

quamwan slq pu jalT41~u rgo myd T Iyac

92"660

"16V'''

toKII

I.'i C" -8

'A,

(I:

0 '"I 1:

to 'V&1'1

(J

II

1(1

H ~, A.

I~II~l II

L 6 9 E

A:. "'I/ II309OG~ AlM T"02 0 MA w w nxoa w

..... ... ... ................ ... ........ 4 I'l F f ýE ' .... ... .... .. A.. .. .. ...... .. .

' i ; 10..I 1

00MU II '

.:I AS I,'

4-A q(-?)

...... ......•< <.... .j .i .,

1A 4-H 'W:0MG., 9I ";

I 1)1

r jA,

~i ~Al(.1

A ~A IIA 'A '

II.:12:1

IAIk'./.

.................... ............ +.... -.+ ... +,.` `.`+, `. .-.. ..,+..`+. .. -".+.-`+...+ .... 4............. ..........

.....I.. .,.'M K .d3lllnocl

, I. A:1 .:MO a:

:1A 131....... 3 Il4 1 a :!: Gf1 -k "J U W 4 11.1 '13

T k;.A. kA'.1 Al (1, s.~ -1: !;:c .::w., t.'' t~f 1, kiU C%.' d

E1 'allad p : 'W " IT 40 0-ONCOl~ 96) "ta' OMVP'~r! 22NUMP'P W 1;T.1 ) I: A C) 31 .;E:O 9VJ

4 1 P E G & i O R T E C 0i* 4 i V'r - : 1 (: 1 7 5 ) 443 2 4 W 0 2. 9 6: *F '. 4*-iN .' ;

02NVPI MO

Spetru

Ac-~~~~ q j;. ,:J. 3I :•. .. :

1 C I Inpu

:4:; ed L.-M r-O IM M 31 8..wf :. i

Pea rejetio level

pna seu4 sos44iit :

Sa pl 4 4 eý

Aciiysaigfco

51 0.I:

:1. f .f( a )"I 44 f fi11 )404 for of~..: :~c

30. (:4p .

:4.: 09. ek

I.OOOWE+0:/( 1: 00EM 424 'MOCIEfOO)

F44 r.:; cn t..J ci: I-- I• J(74Ba ~4ckground3 c.c~ width a bexsxt methodl (based :44..4.:]s41 pectni.41

correct ions Cc..

ci~ *:.Aýe

Peaked backgroun correction. 1 :

En rg I a i ra~ na m li I ,(, 1 3

U N :D I i F I fF~. El~ D P E A K U I.I/.1.f";;3!:;,

02 .1 510.7 IM M6.3. l.R94.3. .Fl t4'. 7 1. T..I.....3: 4

"5~~~~ D3 E. H3~ T4 I~' F* I* E( 1) ** E~ A it

CE 1 1.193 1 4.6 159.

BA :1. ~ 4 0 .6 0 .W)

II f 135 I

06 13 1209.42 64. 0';j. 1

II' 13 15 3. 796 86 1:

F, Fi 1.'.).

5e l') 34 I4..LA zii

I'l I' ("I! R. I.

(.110('I IIJ. I I.,

I 5 4' 1 .~*1

M'.30.

I j I:Ij I

0(4!'~,

3:

-..-c 0ap-In s~q go lead

G S 10 T

t-1196-N 1 MO-.1

A U3

~,6 , T *.j f 1WIII

It "OR.T"W

04009)

99-N

YET-% IT21I 1

TV I

C)Illy'I

II i

iOWE

'CI,,.64 99Z

wo 1. 1

83111/Tod ~~ ~ I a030ipuI (na 1t:: n 6"r

('iD I t ,

00+999"

*.J0W OT 9 iM.)

CJ --iý I Ii (ý, 1151., '.I. (.,

0 ("'.) -.:,i ) . I V I

TOMEc'1% >i 0 ,-

U 1:21 ITI,-. aI.-I T :i,..i C( T I 1.D F1 1---I A 01 A -*ý:I tj W 41 Fl ý.i,5

F aMed TOWIT 400aMON-00 9600= WMMI (911: ) :I:

- , Environmental, Inc.Midwest Laboratory~ an Albohny TechnoogieO Co.

700 Lzndwehr Road . Nodhbrnok. IL 60062-2310ph. (847) 5064-0700 - fax (847) 504-4517

Mr. Al PercivalFirstEnergy CorporationMail Stop 10415501 North State Route 2Oak Harbor, Ohio 43449

LABORATORY REPORT NO.: 8003-100-371DATE: 11-06-07

SAMPLES RECEIVED: 10-19-07PURCHASE ORDER NO.:

Dear Mr. Percival

Enclosed are results of the analyses for tritium and gamma-emitting isotopes in twenty-oneground water samples.


S.A. Coorlim,Quality Assurance

LZý b t o y M ag e r


Report: 8003-100-371Page 1 of 3


Sample Location MW-30D MW-37S MW-20S DBD-02 MW-33SDate Collected 10/9/2007 10/9/2007 10/9/2007 10/9/2007 10/5/2007Time Collected 10:02 12:29 14:48 12:00 9:55



H-3 < 174 1231 ± 130 189 ± 94 218 ± 95 1110 ± 127


Sample Location MW-33S MW-33D MW-31S DBD-03 MW-20DDate Collected 10/5/2007 10/5/2007 10/5/2007 10/5/2007 10/10/2007Time Collected 9:55 11:33 14:10 12:00 10:35



H-3 1230 + 130 1934 ± 150 3149 + 178 3012 ± 175 < 174



Report: 8003-100-371Page 2 of 3


Sample Location MW-23S MW-1 5S MW-15D MW-1 2S MW-12DDate Collected 10/10/2007 10/10/2007 10/7/2007 10/4/2007 10/412007Time Collected 12:50 14:12 16:52 10:48 13:38



H-3 306 ± 99 301 ± 99 442 ± 104 276 + 98 738± 115

Mn-54 < 2.4 < 3.2 < 2.8 < 2.1 < 2.3Fe-59 < 3.8 < 6.6 < 5.9 < 2.7 < 3.8Co-58 < 1.6 < 3.2 < 3.5 < 1.8 < 1.0Co-60 < 2.2 < 3.0 < 2.5 < 2.1 < 1.5Zn-65 < 3.4 < 2.2 < 3.9 < 2.4 < 2.9Zr-Nb-95 < 3.9 < 5.0 < 2.2 < 2.5 ..... < 3.3.Cs-134 < 2.3 < 2.6 < 2.7 < 2.0 < 1.9Cs-137 < 2.9 < 3.5 < 2.6 < 2.5 < 2.0Ba-La-140 < 5.1 < 7.6 < 7.8 < 6.2 < 5.4

Sample Location DBD-01 MW-31D MW-1 05A MW-30S MS01-MW-30SDate Collected 10/4/2007 10/8/2007 10/8/2007 10/8/2007 10/8/2007Time Collected 12:00 9:47 12:41 15:25 15:25

Lab Code TWW- 7181 TWW- 7182 TWW- 7183 TWW- 7184 TWW- 7185 a


H-3 769 ± 116 183 ± 94 1832 ± 147 494 ± 106 26895 ± 467

Mn-54 <1.1 < 3.3 < 4.8 < 4.0 < 2.7Fe-59 < 3.9 < 8.6 < 5.9 < 5.7 < 5.4Co-58 < 2.2 < 5.2 < 3.3 < 2.0 < 2.2Co-60 < 1.4 < 5.3 < 3.8 < 1.8 < 2.8Zn-65 < 2.1 < 7.1 < 5.0. < 1.9 < 4.3Zr-Nb-95 < 2.3 < 5.1 < 4.0 < 4.1 < 4.1Cs-134 < 1.4 < 4.2 < 1.8 < 3.8 < 3.4Cs-137 < 2:0 < 3.8 < 5.0 < 2.8 109.1 ± 9.7Ba-La-140 < 2.8 < 12.7 < 14.4 < 4.9 < 3.6

a Known spike activ Cs-137, 98.4 pCi/L.

H-3, 27,496 pCi/L.The error given is the probable counting error at the 95% confidence level.Less than (<), value is based on a 4.66 sigma counting error for the background sample.

0

Report: 8003-100-371Page 3 of 3


Sample Location MSDO1-MW-30SDate Collected 10/8/2007Time Collected 12:00

Lab Code TWW- 7186 a


H-3 26895 ± 467

Mn-54 < 3.7Fe-59 < 2.5Co-58 < 2.5Co-60 < 3.0Zn-65 < 5.1Zr-Nb-95 < 1.9Cs-i 34 < 2.9Cs-i 37 108.4 ± 8.6Ba-La-1 40 < 2.2


- .. Environmental, Inc.Midwest Laboratoryan Allegheny Terhnologies Co.

PRG-33Form LS-4 Ver. 10

0.10032g STD T-36

Counter iD:

TRITIUMLSP-2000C,.

LSP-2550TR1I/ AB Aj

LSP-2800TR D

o7Iit. & Co=ttDate: 1 O /t

BKG BKG Sample STD STD : STD DateTime Counts Time Time Counts Activity Issued

,)O0 5:f 00 c29 5-7905-_!003.78 01/18/2001

Sample ID Volume Sample Remarks(ml) Counts

277517 / tb•

C___ -7-5q

\ C- 77O ___ _

_ _ _ _ _ -7

_ _ _ __ _ _ _ _ _ _ __ i _ _ _

- , Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.PRG-33Version No. 1.0 06/17/97Programmed by Rick Lesko



Background Counts:

STRITIUM


LSP-2000CA or LSP-2800TR Reviewed and Approved by:--

Date approved: I

100

200

594


Standard Counts:

200

57905

0.188


Calculated by: Rick


Sample Coll. Vol. Sample Corr. pi/L 3.00 4.66ID. Date (ml) Counts Factor A Error TPU. Sigma Sigma

TWW- 6754 10/2/2007 13.0 425 0.997 236.752 ± 88.589 94.259 95.628 148.541TWW-6757 10/2/2007 13.0 322 0.997 46.241 + 80.240 80.487 95.628 148.541TWW- 6758 10/2/2007 13.0 310 0.997 24.045 ± 79.211 79.278 95.628 148.541TWW-6759 9/25/2007 13.0 371 0.996 137.020 + 84.406 86.439 95.731 148.701TWW-6765 10/1/2007 13.0 510 0.997 394.031 ± 94.942 109.021 95.642 148.564TWW- 6766 9/28/2007 13.0 425 0.996 236.898 ± 88.644 94.317 95.686 148.633TWW- 6767 9/28/2007 13.0 432 0.996 249.853 ± 89.183 95.437 95.686 148.633TWW- 6769 10/3/2007 13.0 420 0.997 227.469 ± 88.189 93.457 95.613 148.519TWW- 6770 10/3/2007 13.0 496 0.997 368.019 ± 93.898 106.405 95.613 148.519

ci" =Best probable result.

C-) V T. 1`1 T 4 w 9 CD 6

3, :1. cl -il f., -I.- -j'

0

J.S

to "

t l. r - ; Ji.

:v~~~) e )I.-: Pfv :i

0 0 --ý E-'.' 0'1ý1 1 :1.19 -3 4 4

L :~' :: ~ (2 C-

I:

vjf.~ ;~.:3 1h,~ 2'2- Mar 1

02

I l'* A-' I I .4. arrr 1 c4 t

:5.k P . -21. ED s J . n .. u4( .Plc l; i") .mis 1. J.2 I1-[5 c -f a r

'I. Ji. Is

:1 ( i u ( ru r- sl v' (.: 0 ". -.1. C.i I. .4 ':: *i 'f Cy 2024.

I. f.: QnfDI lC

J. I sniJ. A,'

Di c) r. -f, cV- c.02 -Tt; cs ) d: t

,fc ' ci u. r" J. n % cI (- c Iui J. A. ..:'S . Js .o

d*' I- ui .- I-u si -'c 'I. 'I.I ; c -:'.!ct J. I. c:'

ii

II,'.11

us ~ r- ::' 1; :1. *s: i (~[. F; n 1 ).Iv-:-:Is;f-:' (::-(s:l(-c-f(-YusF.: 51. . I

* :.n v rc 'ri m e~ -nt 1.Im 25 'n .m 7n:1

0 1.J. I:.-- -f-- :i .-ti o o m. r, i.j *z' 9dci

XYXu q 1 1: 1:: N I T i F, D T: F: .) F, E.j A U Irl A R. '( ***

7! 0 . 8.O*E

4:: :1. II. ~.

".53.1. 98C, F, 1-3 2:1.4J. 70 9 CEE. :1. 41. 9 -'.3 i3T ....... 14.

P :1. lid "I 7A [K.-?

X- -X- Y.

C '., HPIN HE I ENE*.'I:`GY COU1,11'." Cl"C' I. i HT..

S U lyl 11 A 1:*, y

C11,13/f: I,::, C.,.S 4.4-. 1 ......................... ..... ....... .... . .... . ........... ... ..... ....... .............. ..... . .... 4.......... .....

T. -, 1

I f-) --

F.11 J :.

iIS :1

1- EI ,I

" I .3

CIO 0I

K I 4

9 '../5 4 4

i.' 2 1::J 0?

4 0 0~**

.1*3 11".:

5.4~

C.... C..s C

9I 9 4

1. 0 8

".4 E, ~ 5

WS 9i A

3,12 1 20.

0....,, -H

C 513 0

311.

:1. "3:1 6.6C

"l 0.

:.4.,

81,

4.5

41.

:1i.,

001

0> ["ilo'isv.'

,.(1.100

0:.

Qf.') O .

8 1.

311. (I*',8

6 .

5.II'J'

//51 57!

S,~

:1. *.

I., •Jb

I. .,I.. Ž''~~ 3':1. .

.1.

I..

S 5:1 Fl

Si

II SIj

'I'I)

.5;: ~ ~ :1. ~1. ~(ti 5 P~' 14251,5;,

ORý-('EC'.'~~~~ V 4:71t'I.(:..ai

U I'l VI A R Y 0 F 14 U C L. I D ER S T 1ý4

DE ACTIVITY COUNT I NGC. 1

.X. N. * .)(. *

pCi/LITER pCiiLTTER''

i_-._1.--4 ....... 4 ..... ..

4.'

1''I I ('

T~~ :1. 11

3IS ... 1 4:,

LA-140 R

41. 980E0

:176E0

4I

c:? 498 ~>1E+00it/G 09411 1

1.'* 4 13 .1 : _

3.1.476E0f:1

K 765ME10P/xvt 0n-wapago 00 Pý. eA-i

0 All( peak fo atiit

Acivt Omite 11o -tta an l *easMd. hp,

Aw Activity'H ~' ,~ :W 74~I(371:31: ~ 33 1

****A**~ 4?~(** 13 U ' I1 P

:1.4 ..3 3 ii'6 6

Lt.i . (4 :

49.0 Xl RUI 10

A 0F I G6.

i"' k. 4 t ':1

63'.97 1-13

133. Ci.'. O

7. 11I

:1.11.5 N6

a4 :1, 4

Z 1

Peak:.4.;~.', is Part of. a i42 : ',oI

negativet'::i

O1

t OR 'TE~C .(::I: j V: -: c1 ( :175 M U 11 4WIOR .96C~f 13'-31- 'a ; :1.

110. k 5:f :1 1 :i.

p ~.:c c: I: p>' :2 2~. 3. c:* n A m e C:: Li 2; ~' I. :;' ~:I 7 fl, ~ ~

Live ti 1.me A7v98

Dea timeIDete tor GeoetC1. 2i.~ LLry. II s I.

CaI i bra io......n

I'll ed 14 Ma.R 0 10 6 & 2 IIl -xr,-2 (.'

J3'" I 1.: ., ,] a)l t f - .J

Zer of se 12.: c) C ke .v( Gai

Quadra c t i'a1;:,c: . 121E .... 07 k Y/c ta~. 5111

Peakrejetionleve

Pea serc sestvt:

Sapl sizw 1)iCAcivt scln factor

R.. . I:. :

f.*~1(:).fA:: energ of 58.~~ IL (k

LI I i I , I:I::f;.C 3: @ ~ . Tw 1::*~s

3.500

RIOmethod *::

ci [ :1. 1;:i. C i 3 * "c 12A.'l a 1:i.i. c: e t c::rX'. 1. . C LL(LLILl.< ()F. 233

B23a ckgroundi t wi:.d t: best~.. I me thod ov,: in ::~ * :~ ~l

Corr2ec :12:i.D C JA.y.0...........0

De.cay t during a2cquI.i. . i. 12 :

Pekdbakrun oreto 151

I::CommenLi its1

11 q:Iw. pL2 W2..

:1. 0L (iA .23(3;l1231'AlF U 2;i.ft (~1 Ttii AU.ii

N(:",

En:v ir :.'o ,men3t al~ I. ric.' S:3c'i. n '1 I..' 11 !,7( ", . 4 1-, :1.

Energy cal~ 1 ibrati' ': :.on nort'Fmali 1 :.zed c ii. for en c' I E53

*~~~ N I* D E'v*1 ii i*~ N T :I F I1 E 1. P E It Li U I V1 i M f) 1 *, * *M

706.96 352.181023.67 510.84 :1.:1. 2,

'0.4.84E0

POO)5. 2.060E+0!.'.5 (.*i 11 :1. " :1. "," 5 F, B 2 :1.431.37 3"M 11ýQOB

j. J. ID

)(~~~~ D~ IT N3~ T3 I~ F:~ : 3 ~~3(3:*~ ~~ I Ei Dtt P: E~ A1: It !7; U I 11 Ai R y ***** 3 .'*.:*3

riT E3 :1 :: / :1:; Eii( Cf- -+ +- - - - ,' 3 3 . 3 4 4 4 33ff-f-f- -f f 3 4 . 33- -.... I .. ." ..3 -A .... ...4- .- +

.1-3DA14

AA 40)

1-31

LA140

RU- 103.

BA 14CS-134

Cs- 1.733 "!

FT: i ..

3.3 1,4.

D, FC,3 k

733.32959171.

976 .90"'

139.91,.107.4

1211.03 C122.2

1247.00f3F:127...4111124.1

1.4~f 4 8 4

:.51. 0

:1 5 ;4

3'1 5' "

9 0~

:1 3 )""e

:.4!*.- . 1,0.

284.5

304.60

326.9

36.38 '

,.10.33

66 35

`j. N,

J4(.'A. ('.; 9'

6.7

32."

25,,

'135

T.'

01,

5.,

14.

;12

12.

:12.,

.@50

(l-1) (ij1.00-.3 )2

:.- 3 8.1 9

291-1 :1.269.'I77

2 :. I:1. -3

172.49

5 3.'i:' 43

142.38311

2453.51

9 ','1,. -3

: 1. 8 .. 0

133

:1 23

1. 2

,, .33,3..'.

. If1iia.)

,,68Mt•..i.,, 590(: .i.-.

:., 471:1. ,, ('7 U.

I. 77t..I

,,13:. 3133

&G R :E G V - I ( :1.75) WAJN13R9 1t4 WOR.96 06THF-O0 W&HO Page331 : ~y* 111 f1 .1 .1 )1110 L4. ... l n-:, S :o 1ct L A ) ruIw/ /CA

1-'K X1~. *' 'T1 C) A F" F, 1"I U (., 1 .-. 1: ) E: 1 :1'. (.~ i~i ::

(~jvj ~

.4. .~.44 ~1 4 .1444.A .A4.f .~ ~ ~~44 1 ~*4 ~i 4 )~

C.. (:3 58F

ZN-65

ZR-9

NB-95RU 10

.:I:~ J.31CS-13

<~J 4. 3263E+0

1.27 I "AIF

< t 05E0

<.

< 5994E+0

< . 1:3 I.< '7.501E+00

8.1

"201E+:1

1.~ 158E01

X, 2CC :IEE93I.)

K 054E+0':1.

1. 166E+02.

A Actvit prntd Wrt actvit (:: :9

D1H:CA-(E AC TI:VIT 58. 1 to 8026. 19 ke ) I ?.4397( F 3 i:1./.::CI9

1,i',5. 4 (:'F :1. 4

f,/497 F.08 % RU1:

621.8 %i RU-10

A R Y 0

1332 50 '

D IS

FE-5

M-60I

C FA D: Ef. I 1l ) P F'i A284..3. % ......-. 3l

4, & BE-7604,,70 % CS.--134661.,66 % CS---.37795,,8.4.% CS.-.-1. -3,4ý

11 l15.,55 S ZN].t.-651596.,18 % LA---140iI

&F -i,% z% I :.4

610.33 3 Ish 0I*

Pea is parFit: of a4 mutlU.:.L 1 Fl-0 are..... went

negative duyA :i')Y F::IiI.yvoluti (31

1i:C."o1C cw0 i:*1.1:C:*C- (K 1-,-7 ) W.i1isKa3 T-(J(,)2 9 f.-u'J.'-O T 2 0 M OM%. Page1E.n v:ir onmeta . T.J.J.c 1: c na~meo:: 7~'i4 ,f~i

I.le

1, 1" : 1 4 ::r :1. 5 TI :: ("D

e.2 --- G~ El n ::,:.I. i2 12U i.; 3 4* 1

(1to

Acquisi~~tio inomt nStr ime

12 :~$

MB I npt '

Cr a e o 14-a -R 0 W 203y :.~: 3 1I & '.,. 3K('i :1.4' 1/,:50NKi 4,3

Ze~ro ofs et '4: ,. 1.0 k:e:' ( 3 ý.J .1..

Quadraic I .**Wý

Liray il-iif.i

0

50C.)

n ~3~ energy of" 0k 1i.)

i nrg rf RR40W

06M~: / ( .. il: (1U:4*.- +T 0 4 . 32fiFX*~1

F a.c~t ion I.A.i.i:i : . 0001~%,

Peake bakron correction:i

Sttu

I Il

comms1::

!::,l. . p b(i;..•, :) :,::-.

i.i 1::Ic:: c: ii U: :1. c:~ ~i~4 (hI 44 {.:~&y ~** *~ 14 ,K1)N 0

I:,3' 1 F3I' 33:* C (. C.) X V 3 1:: 1-715 11)(1113 14 :t'1, r 33102. 96) (,-) 331 f.Nl(.`Y

I:: -I~ c-? - 3 f . i .:-- a 3 : ' k 1:f L: : i. c3 I" c 33W i I i -o z c I .c 3 I ' 3: f r '33vf:

C I- -PI :3,3.3I H ::-,1 1: ,*1 ::~iu :" 1:'1,"3" C, 0 U ".3 T SC ::;'3 1, 'i3 R. C) r2 T' C.IV I~ %~ 3~.i.33,3 I'.U.C; L. T )1::..... 13 r.. . ..' . .- +---. i. -.. +I.." .3. .3 * 3.4' 4 3 3 3 A . .... I .....I

~:1. c ('. 1

A1. 1. 383.. ':i.' :3. :3.

37,, 361. W-37' FI 21.4

:.1... Ef3 :1: 2J. '4 1

F'3 f k~3 J. 1.2 1 ~:'''. i 3* c

Y. ~ ~ 'i )(.3:3. '-X:-:: :M: If.rc~3 N.~3J )( M. '-K X. 'K M.:F:1, N 'riyl ii :l .3 Pt ~ c::3ý 3:.''

4.-A . ...... ...... 4- -.-- d... -- + .- -ý, . A,- .--- - .--- + ---- + ---- A- .... 4 ....... ý,- ---- -V- .-.. + .--. 4 ...... i ...... I-- - .... 1-1ý ..... .. ý- ...- 4 ..... .§ ....... 4 ....... ý- .- 4 ........ L .... + -.-- -le ..... .f ....... ý- ..-- + ..-.

1".-:' *3 1.'

. :1 0 3

Bf.,:1. 43

F-1U . 03

C'

26,.)2. 48

6:.0. :l3,

51 (,.' / .--21 2

99U 8 J3':1~, 0

:1 , 23:1

;"' . E

3*, 2.,

45.' 4:.3.

'' 4.i

J3. -3 ,,

C.1.81; 3.1

3)1 e ' 'I

:3 3

1.43 7'J0

, . :31.

1. 1 15 '

J. 4:4.

'3'

2.3

:1. 6:.

1.J.,

3'

17

6.,

o .:3.3

32 (1: (" L.

1it::",

0C.)

0iP (". C.

21 C). G':. ' 4.

"3 5 3l*-ý 3.1

:3 "3') 3

33

,J C.%-4 7'7

(3,?) 82

36-'e' 1

3 :1.9.,

t'! 2 "1

/ 6','1 '

1 .l J. .'3 I

:1. 3 , D'

.1. :, E'..

7 4.:

'3', .:~. :i. :3. '32 3"i ~Y'. 3:3 '3;,: O u t

OFO:r'Fc3 C F ' :::.:: V - I ~ ( 175) ~ I~ :i:3 14WO2.96 cc-:CT- '2007 1j4. iY00:i 2 S

*~*x*:. ("I R. 6; 0ii i ' F H U C L :1 1) 6 :I:H S ) F . F

2 SiGM(3Mg.*•,• "*€ .)m,.s(*

p j. /I :I: Tliý:R : i" /II. T"i-, I p i/LT[K F

*4...JrI r i- 4 --t... .)....ý,.4 ... ..... ....I....e .i....3 -- --A ... m...m.-+ - -+ -+ -+ -f -+ -+ .-1 ....4 4 ... ).. 4. "..- 4- . . 1... ) .. .. 14. . m.......

534)

IIilkl-.."

Zk'j 3 "7

RU6 :1. 0:1. 0 6

:I: J. 31

S. 7340E+01

0-1. '2)3: '2 F:: 0-.

314 .1 E+00 i I

I2,. .3424mI."D IW'

3813E+0313

EN2875E+1-& 734011+0i::*3r~ 1.

3.ii 4. W'

D !* 3 V 2 14-. Y

6~~~~~~~~~~~~~~~~~1...-rF . n) rb: 6 t: 2 5 .:.eIsoV ) 0.. 6 .mfm26m 6 . :3/ .TOTAIFc :I ACIVIT 59.9'2 to: 2024A. . kOY ) I. @666 6: f3 1;C:

******* 3 b 3 i b

21. 4 &n

75.7 Xi

834.8 &'

13 LJ V 4

L Am 1RU-103

RU-106

I IR - 9 5

MN-5

r" F'. y , 1) :1 1-

7% 7 &' I' B-95 '

109.E & FE-59

C " :., 3.) : I::'E P

:1.46.8 % I

(,*.:1.(.-'..). -'1 RU J 0 3

M 0. 77 ....

11"1 '3 1. 2

J. 59 .', :1 1 -1 4

Peak is pat f ai''~~n', m l iple ma th3mra e---

negatim~~~ duigdcupaui

CJR.(:3 iý:mCv V - '.i :( 175) EVW1: 14WOR. 03-NOV-2007 1.1092 Pag

ii 1

f & , it ,

star time

Liv I Il',

Rea tim

3: 7.24

I 11 11%,"

\\n Ad

MCB inut .3I

.- :...... ..-.. . .. ........... .... ... , :.

: ' "... . ..

Li r r Fi , I.

Owlysil paamte

Pea rjc to le l

Sa pl Size.:;.

Actiity calng fcto

II. I.

1. C) *3~~3:i*~IC) C~

r~~;j x2 ý,,-J 1

Adiioa sytmai ep

Frcto LU M; CiCC'I

Bakgoud idh tstnsth d aed xispc.um.

Decay ~ ~ .. duin cqiito

Peke bakron corr ctio Y PT

bkgw. ::c

ii hr. V r: o ::: t.: :i. C:

(2fl CLI.fliiii :1.

0EGM ORTEC G V - I ( 175) WAN32 14WO2.96F: i -r% (:-ý vm ) t: :1, 11 cý "'3 1:'ý c. I., -i -u !-1-1 ). -1 1-1-1 c.s 7' A

Energy calibTation normalized differemovi 2336

*w~wwM**M*:; L)

1: 1 1 T. 1 E 1

P E A KEFFICIENCY

W 14REVA CL;~~~~ II D:: :1ý: i

51 :11 B. C10. 1.25E0 23.48 :hQQ2 BI-214 iF:

111 -A T' v k. c.... c

*I~~~* D4~ Eii N4 T4 I F4 4f E4 D.))~ PI E A: K: to:

(LLII. CUI.I TF ROvID~ 39M:i~ C:: WII(F CNr::. AiREA

U ~ :; 01P

J: I

i.0

c 134~

M-54

12

I .. ' .* (1-

12 5. 16'

:.21. 6

1 1M.10

19 11 11 2

53.5

4M

2~

529

* "* /I'~I:*~r* *iI 11111 ~C;

I IC

f 'I{ '''I

f i~ IF'' fl~*3 iii'

ii

31311 , I

I II

1)11" .~ I..

I f'~ ~

I. Ii. * . I

I I, I I fi III I I 1

III 1 1

I ~I I

II' I I.,

II '' ' I

If

III 4

III I I

II , I

Ill IIll 31.' I

~

.1. I,.

1.1 5 11

:1.. . 4'i)

2l

0.,

0

(*ý". V - I ( 175) WAN32 14W02.96 03-NOV-2007 M19H25Flivirom m ital ly-tc-, Sý'p'ec't-f-ufý1-1 ý1-1'.-m-i-l*:-'.'ýl

NK**m 1; U P1 rl A R Y OF NUCLIDEE.,

hRM I -.- E:

Xi_

~?I. f <

ZR-9

NB.9

RU-103

S.. .~,..,..t.%. .. ~ .......

21.947 O5,.275B It

3. 29 1+91

. 1533E+01

2. 016E4@

1. 78@E+1.

''''I f 1:1

1.94GEa0

21. 1092+0:1

it2150E+ f'

i. 731E+0:1

TO AR AC::lTIVIT (.. 59.9 to 20~:24 .2 MY):' 11 ~ f,~ h 1

11Thrf4. DECAhYEDi ACI VITY 0 59. to 2024::i'~:~.21 k= FE ý ' 3 .:. 1 ki R

-'0 1. 1' (

I ". )911' f..' '5 11 5.50

Z4-1 117 .24 i

K-0IPm 1

iD . f. < .ý

DIM 750 72' hR-

L3 A I - 14 t-

A ek fls Oemiiio ltesIM

1ý ak iden ifie , bu:: f~f-:'Ii.

EGM ORTE Gt V.LT -:: 1.~:C 175) WFyi m9 05NV20 M.: 209 Pa.:1.

Starttime

Live time:~

Rea tc::ime I, ~i. ~i:~Y.c(8

Detector: sysel:,

in

Pea k Jrej.iec-t: i.on level1

Siiamp•::le S~i, z:

fov aneeryo

3. 50(-*:-..!.OOOOE+06/( ~ ~ 1,00MW M00MO

RIS meho

.diioa sytmai erar 1.0000

Fract~)Iion LWO . 00!i

Peaked: I I

S at Comments

J,.: '. CC C C

r*1.,.ýC, ORIDC* C- V . I3 (:'~'~;'.C 175)i~ W 3 TW0 .9 05-M -200 1I.1 Page

Energy calibration normal dif .1", -f, v, (::- .ý274(,f

Ui 11 C:) D E< N Cl I A K il lyl Ct F:'y." *:Y

121 .2 609.i l 2ilEl -w'h 34. ~ 20..I'.T 83. 92 E 0 .:j.p:p :~'.3 4,,~ ... '.9,3 D~u:l.::i:

C~~~~~~~: . C.'. C-, C v. . . -- C C C. . ..... 'C C. u

[i~~~iC D E W T I Fi IICCC C.C( 1lCtlT)

CE144 269 1335 19%,

TI.31i "'130. C 0i 365.1 2 78.

C:,. U - -11 t, 1,1 :. IRU 10 1 '. 2C C-1

2 ~ -3C C-.-

2 4: T, ? 1 ~:;

C;C* 1 'CC. , C3 I'l A

15, 002 163.84 1 '5~. f.

rCC~~~ 2C 1 C'C'

13 FC.00 170 33 ! 1

CJC . C.1 GI 8 1.

C' 'CCC I~

.00C( 11 I'.82.1

D. -'C 4 :4. ' ~'C:c'C'. : .L

SEG&. OR)E G Vf~' -- . 1: ( 175 WAN3 14W02.9 05-MO-200 10%1 Page

A F" 0 F, I,-! ýJ C ý11 I :I:'FIIIE OF' COUNT TIME CORRECTED

11) Fý ACTIVITY ACTIVTTY

E r1i V-1' 13 C-11 Il !::, I Ei:2 SIGM(-'t

.X ( .*ýY

BE-I*;K -

111. 1 A-

:1 .J.C-134

C i / I TEI:',

64. 984@EIl

I . .5 K- 4ti'i0

4.51810

p /LITElK'.

3.443E+0* L:1.

E- 9 4@E+ :1.

TOTALfd M~ DECAYEDF ACTIVITY (c 60~i.1 to 204. W-,,V) p:1 C~l,4i /. p0 J1..

13))lff~t J 01 41 Pi R Y 0 F , Dl :I: F"' ' K , Ki:1ý` "

133.54 ~ ~ ~ ~ ( CE14 154 C-4 8.0 1 .3

49.0 RU10 53.2 B-4 0.0XC -3

2 .8 RU1'' 63 .9 X d ''- 13 241

*65 .7 ND-9 79.8 & C 14 1.7

109.5 FE5 11 5.5 % ZN6 117.2 ,* a

133 .5 %F 00-6 146 .8 % Si 9 . Ir,

Pea is par of a53.1 muti.e am! Who ap' wen

negai v dur.~-s.ct~ingI

. I -ea is tooc wi de at~ --."- U.F I.:. S.cS5-{. . rr I1S.% ';i.~ -. ~ijiI Peak ~~ 2i ~ c, :::.v: I S .33t:S'22.jyi;. ~ i ~'

610.33 t ITT 10

84 11i1-+i(iA' 7,1 F Ei.

T 14 1,0 2 ý, 9 :1.2

10::2,

Dea ti me .1.11

Da e t: / eo e r :i.; (3

Detector systemMCB I input 4

Cal i bratio-t-iFil a 1-1-1Createdn 14-MaT-2007 M56M 1 r 15::10H31.

Nfl33. 5 1 J. ii--i 171B

Zero off~;set -. 10keq Ga

Quadratic

Anlyi paramete.

55ti I::c --,.f.

.ea reec in eel& .00111

1. :i.

~~::l~x'fE +j~ 0: i

7i 1

Ad itoa sytmai err. 1.:0i0017+0

Backgroun widhN es meho

Corec ions~IDeca durin acquisition•:i •:,'• "i

Peaked-,,:: bacg;.UM ,:i•.O'" :.'"M.'',,:. .M:i f. i ; :!'" Y F:

Comments:

-I

..,1 nd o 1-11 u 1ý11 I I'[ i -F .. I N(O)

LEG& ORE G:iI~ Y: - I7 ( 175)~~gI' ~* WAN3 14O29 :12-(T3(22:T 15: 7I3423 37 Pape~~1:Envi pon:1 3 imen'ta I . nc. : i3: 33m ,33~33 ~? 37, ~ i:

En: ~erg calJ i.brati on no ma i -zed:3 3cT 3 ~ .: ij.4F . 3.: : 1.. 0(l'0

'C*(*33'~3U. ~ N I3 D. E3 3N T. Ir 3 F I E 1) [:,[r 1 /1 ,' U l.' II p 1:. * ~ .x .3 )(.3 -)(.

W17 .00 608:. 51.-.-*.13342., . 036E+04 2'3...3 4:1. I.. x (H)' '14.

NUI:1: i21) 1ý.g 3. PEAK i CENTRI.,:. BA13 )e3CKGROUND.I'. NET AR iEA I N TIEN'iSI.TY ii2Ei :i4.El~i~ (2iY 22: O~iV8 (2t..if8 C:. / 1122: 8. :I: G Il'll PtI.,e

.- 31

B : I.

31.4

RU- 10

33 1: 3

269* >.7

2839 ,2)

64 3 3 ,

311 33 R

656.'333

729.071>

1 '1 31

31 R .I

3''o

23,21<3., 2

28. R.)

36.3; 30

I -111 , 7 11" ...

53.330

3,I

J-3 3 ',-

:1. /,, 1. (,

1L:. 30!i ,

4::•,,

M',

1W3

:1.36.

133,

2.,

2.3

a.,

-3 H

53

2i

3(IJ If."(:

(320

@0:

(3o) :1

6, 8) 1 3. 0

.. .I ... .. iI .i ,

213.' 33(Ji. 9i •, . 2•

:1. -2:: 7:.i••

J :. 0-

8'3'

:I. ":I 33,,, .,•: :

,', •.I 3 i'')

z1 . 583',13 .-j'

9'>

a

E~r~c~oI:~r (.:::: 3 U - I :3 175 WAN3 14W02.~:: 96 10-OCT...2f;,(1 10 3 17;. :

1H '. r n3 P-:3wTt:~.. :al ~ 1 31-.lef u r ta~rn3.-:; 4' t.58 7 ,.A , 0

S~ U m m~ A. R,: Y .C - 3'. F.1 (2I U I C" . L@ . H ýTI1:1 F'W (:)I::' CO::: TIME CO RE TE ;i :owvc i::' UAi;ER:TAIN~Y

A: I :'ll F

2 IG.-*.3• .33 *€ 3' -

:3. ..'l :.Ci. :i. Ei : :,/I. .i E :

f f f - f f f f + f f f f - -+ + +- - - - - -3.......'+-43. ......... 3.3I33........ .... ......... 3 .... .... ........ .....

CC C" (33 )

N ' K? ..

-31

(.33 - 1 3 4 <

CB-137BA-140LA-140

I.E-141 <3::EJ..14439: K

1. ;-"?IHk+ 'l

1.2707E+01p3

1!.-. -4 2;7: F: 4-:0 :1*..'

5. 0315E+0031

1.1

..203'130E+01: .

:..98311. E+0 (1:1.

H". U .Ir 1 II 3

....0 D~lý: CIA1 Y :1:Y'9:, ACc:'IT ;9:tl3h 202"i: Y1 , &:'1. 3I@ @9I: :[TER.:3/I..:

I1.3 111 111

333, LA-140

49.0 X3~ R Ii jj62 .8 &33 RU-0I I

756.2 & R-0S34.04X AN35

1216 ' & FE-59I

1 .45. 44 & 3.E-4136 .4 %~'3 1-3

63 .9 % 1-131

:1332.50 %' CO 60

Fý. 1) hi: 1 F, F

R8 .3 % 3-1 '

K ý. J(. ýI*). -j(- -XI . *.3.)*

4*8 .. 1 (.'i 2 'x, L.A: 1 . 43;

Colo 33, X, I U1

4.3 ,,v(3*33

81.7 A CO5

faile on '.33 (.33 qI''1 u 3 it3,- .C. t;J )- L

Sv 0 :, U C Iiý II. .i.i C-3 V T: WAN3 14 O2 9 13-OCTŽ :1.

0 C.:"'T~ 200',"ii 11 :; .49~ (111%3''N

~0~'

Stat t . . ime~Fcc~ .o

Lvtime

7 .

NCB I Input :1.

Calibatio

VJJ.

t F. . .:i c 1. i'.? 0"',` k nc:t 2i~i

I ti~l I I ~ Ii ~l'-Ctf~~ 2.

Anlyi parameters

Sto channe 4048for

0501 keU/MannXI.

, :1, :. I:

(:if "'5 :1. '.3 1.!. e V2026,,

3. 5 0aG/ C I

2. 8571E+05

Ad ito a sysem t It'..' 1.00I~O

Fr.Iiacti on ii~'I I t :l: Ft Sa:' 1..0rSi;:r:I0 1C3SS..eF

Backroun widt betmho o,

f7 a~ df u~ rs J. n quiJ:J

Pekdbakrun -reto

Y '.

is.t: 1 5

EG&G ORTEC 0 V I ( 175) 4MI13E 141002.96 13-OCT 2007r u I'll -1-1 .4-L I-,, :; :1.*,ý";."O (.ý'.!ý.f."I)-,:Iý

2

Energ c al 1ib~rat o no: 1.~ r mai zed.:.:~@ic c;iync:c fi3.0 (") .109:

y~~~~ Ny 1:~ D E~ 14 T 1 17i 1r~2 E: 0 Pi E .Ai Ki 3 U: 41 PI A ~ R ~ Y

ii ;iViii IT. FR.: ci..i BIKO N NET COREAQ 3 w*FFICIENC .r irY~k k r~u

706.18351.*783 1,08.

85.215.

15. 1. 0 E-,0

4:1.6.32. -3-; 1.

L"MM PB-R141. (.,24 TL-2082,, Y-.']: 2 14

a a -f c o t; (....',d

I D F: FIEW CENTROIDF: I E: :f) P : A: ,

NE II .1Ii

U M 1*11 A R y X., -X I'.,(- K.X. )(. M.

INTENSITY MICERT RMI

CE-14

CE-141

BA1.;:?LA14.

:i.3

1-.l* :1-. 4`

LA140

Z :1,1

S1. -11 'JtHr .1i .1,,'!'`

1 . .

CO

s Pak

D i

( 0608 0

If 1.1 1. .

1 0

4,I.! Q) 0

151 3. 50.1 .'

A. i 6'" C

:1 C,6 .

143. 91.1

I9. 3(,-'j53& 2

'C.? 0

3Ca

2i t ,3 I

i'i W-

8i..,. 0)833.8

38

511.

24..

2 .

*14

P4.

2)

:1.4

Ci?(i"

( 00

(I 2

(IDL'

.7.

102.0

3I~I U) Fl

.

A.i~iI *''

.

I.:11 31)

.

ii

III

I Ii

I'

fill

cŽ ~ c: If ~::I I. *I:; I' ci

SEG&. OR:: B Vn -- I (3 175) W::.' 1410c:3:'.n2 .96 10 3 page ~~

["IF N'3; :: :y:'.J. 1 F * Ur 1'~~ 1::~3: :: 1)D EE333 3h : 1T : SI"!F .E

4.3...................~3......3.........I I.......................3.4.4.~.3.3. 3 .*. 444.

B3 ' A;3

K-403

33 ,,

ZR-95 i

333W'4

:.34

BA-14

LA-14PCE- 141

.:.; 11 3ý) .. 43 '1, 33[

.3'. 43'38E+00

.3 0 :I. 3E+0i)

:3. 0113[E+013

4..

3.0560E+0

5094+0:1

",7 I~ j E-3*. .

2. 44(.33 3133

ON 5420E+3(3p3

(;j.734. (-?) Q).

. 0',789EM.

< p i ---, (:I . 3

A; Ac iv t prited I3..3 < 33

r' O'3 in.. r ~ ~ 1:,.. y:~ . 3:F (:, F, D~ :I: ;,H; 2.1 F.. , :3 ) 3. ý 1) .3, Ii A>, 11"3333f3: .3.~ S d: 3..

.4.4 133 .~.54.1 4 % 3 CE 14s3 .33: :; : 3 14 .4 &: CE 14 28:: 3 &: 1-13:'3. 3 0 ~ 4 P4.8 4 3 & B 14 03287 % 3 LA14 364.48' % 3 1-131 477.61 &... BE-7 48MORI:3 %H LA'3 140

Al ' e"i 11i' 0 R'L' 1~ 537.3 S S 4 61 . 3 RU I~3 1.*.- -. 21. ~ i:"4

63,9. %4 1-3::.33...3 % ( Ca 3'33 724.13 % 3:Zl!-9531: ''36 7P4 Z' R3 -333

76 .7 % NB-93 795,8 % C 134 8 .7 % O588-3 4 . 8, -1 y 1-1 4:1 IE 91 1 .5 % ZN 6 113.R %~~' C::::-611 I 1 .6

1332.50 CO-6 146 ,8 % K34 15 6 1 % LA''-140 A '' '; :::3Žj3 ' ' '

F. a.d ,,.' id n i e , bu fist pe k f i

3 ~ ~~~ k, ,, J. y. !-- J. q 13 .1 L .1: ;3. I:':4n J. r: a 3 4 :: .:.33I

oil EBRO ORTEC G V -- 11 ( 1705) WCM13E 14WOR. 96 :1.,*i."!,ý!.'.*.iý*.*-.-".,.ý:iý;.,ý',' IDiEnvironmental Inc Ard.

Specrum ilenmei;C:\Qer\1702.n:.

i0

Start3 time :1.

Real ti.me

Dead c time. ic'c 13':'' v'>:1.

1.

Cal i :3 " I:: i. 3

Cre ted 14.-R 0 IMMx &Is 2(.-' -. II .-: r: --2('.0

ci~ Offset.:: (".3 .1.

LibraryFile~i

I i l f 1-.r lei

Pea reeto ee

Peak ~ ~ ' searc :en i.iit

SapeSie.

2 I. 1i 1:

120foran nery~o 58131:':kek'14 fo'r an en3ergI~y Wl 2026:'.061,M)'3~.?

.'3'.

Detectio li i m *'ii I. !-.Iui o:'''''" d. S&I(VWI'.'IRI S method'Li~~' "''c'' 'c1 2j13F' ' s

Additioa sytmai error I ,, 00EM

Fract ion 1 3 it: .000i';I 33.:l::3ccl c :sc;x

D 'cayV c 3l 1 i s qui. xsi oI' t c:,'

Y E .i ̀

31:'

YESI

cx 3 'I.:f.:~~~..3'3,::: 'I::.2VI~3'? i. 3 2132~s [~J3~3

bk g I w. p bc:

Randat" summing

gEGR. ORTE CA - Qo --1 I ( 175 WA3 14:-: 96 MOT00 10125R:12 . 73 .

2

Ene*:'~rgy: ca i r t o normal P 1k i zed 001 ::: ; j-45 :~34-41. ~4 --*~1

U4- ~ - -i i 4 4 4-1i4 3 3 3 4:D E 1 T IF E 14sE4)K4U 7 '.* I

479.17

!.5-6 , i ! .ý7

.7.770.42

9 28 1 .j',9

9.21

:4.1. 1 84 11 9 6

608.9

i21'.5 2I.-,1

1,5'7,, 81

:1.*--,4135

I I B..

94.

1. 'V8 E f..'

:1. 1. 585E+04

4. 444E+04-8

1.. 9 ;.

12.3............................... .......14.32

I. (--''3`

1.847

:496R. 01j4

FPB-'14

EAT 152

AC-22 18

X)

X)

I.)I)

s2: ;:i:n,

31-:-. U 3 (.*. ' L : *1) L -3:- I:41-4 CENTRO:) -- I- i F- 1k :: ATILT!

.1-3

I: .iJ 1. (.) .

R.1RU- 10

CB-137

R[' '

270.53 I

293. QM4

")5. 93

1 i'.' ? 2' i.

:1 2 2

144.80

364.92

476 4-'i

48. U'..:-

5 3 6. M

.62

27.,.

.1")

8.3

21.

1 1 / II ý 14 8 :,Ii 1. 4-' ,j

I ~ ~ 8 111 i9'I 1~' -

0 1,.13 1.- 4. ' -- . --

.005 14.60- 570i ,ii!0' 4 I '',%-

YJ4;:iI84F.J D41 (4 I

.005I:I 112 8 , I.61

ri~ ~ I~. :i 175 WAM ni fl4:AlWiO t 2'.;~ 96A 13-OUP ic 77~3. i

Nucl~~i fe.

FIF 51.

Chane Enerp Ba~ckgTC round Net~2 are2:199 :1 ) 1. 0 . 2Q

IJ 6

2658.6 13995M

01.

0:1. :4

9 0 " 31

---,9 5

282., 8

I:: I*U~l

f~ )

..1.1.

~ ii

~ (~I~

3. ~ ~m ~

U 7 7 , Y 0 F:, . ['l U :... I 1 ) F I H .)(. N. .I(- K )(-

pCiiLITER p:i/ ITE.

IF FA "I <' 4. P5 0 4.944+0.

Ki i- 4~iI CD .i85 E *3 1.5 4E 0 1. 2i8'ii$).*-.

VH-54~~ ~ ~ ~ < .74I00 40W

FE5 7 '.3469E:+00I 8.04E0

EM-58 < 8523E+00 A" 2858MC O -6 0 < (.*.'1.'... 13 . H5,1*1,

$3... %i ~ :1P.I.1473E+01 1.18• 33E 01. f,,:;rY I*. $n fA . 3___ I.4:v..9.4359 E 0 I. . 05 1 EI4 +0 ' ''1.~'

V ~ *~~ZF ~iI V:</( 484E0 z" 36E 00 6''~ . . I

EG:*&G (JFT:CFW(4)3--*I ( 171~5) WAN3'*l~r2 14 W 0 2, 9 , :1*'1

1291.60 X FE5 325' C 1

'; -Peak ~

@ - Pea is too wid at IW5M but (to M I

$ - I Pea idnie, bu fis pea cY thi IVA Iil. 1

file on or mor quaifia ion tests,,:r *

+ -Pea acivt hihe than coutn u -I-- c. -f- Y ~~.- Pea acivt lowe tha contn uncertainty ran

analys0

1 1:. (c:: Ci t: 7' (A: riI --,a111 .:1.

C' (."

TWIJtA.~!.7~ .

~~~~~~~3~~,ý,1 ::e'z L.Ij ::1 . 3ý3 \U & ;\ ' 431 svý ()-l10

A' C I UJ.s J. 1'..'J i Y): j f3 LC)i Y`3.1 k 1a

Str time::12-TWC c:;2K-R0 CI? :14 3::

.77

:15

1:3 c~ 1: c*~ c I:; c:Y c:; ~:; C c*~ in

FJ. T~~ ).-[-A 3 V 4 Ie

Zero offset -1.980 kev; GainQuadratic 1. L'.!.01iý:

. 501 ket)/Marn-w].

I hPea reecio lee

Peak J.3:I:lv;i:; 1 3 I'~rSamlevv lL s iz:;:I J1.c133

Activity s.1i(51 caing facto.

R :. 1 i I•

:1.20 for of

4t1. CI 2 ( 1. (I. l...,c -.4I ' :ý3i:c 4 - i).30.000%

A d d J, J. 0 Y~ I a I :1. >31 0cc r -(.3 D0 E .7

1 J. I 3II @ IJ.iBakron 311 1111 c bes: :c~ct; 33(5iJ-iCt I).hc;'c

Dea wiqaqusto Y E

N(.'I lii *.

I..c:~133 33355)

1',AI 1k. U111 :, kAH13113 .1, 1 1.H I U.P

Enrg cal~+ ib i :ra tionv normal izedi ci .f feremng :1.0000

* (** f* .f *:** U N 1:i~:r :i) E7

N T 1 i F I E, D~ P3 Iii (" K3~(.3~f S,33 U( IyI .f A

PEAK ................................................ICIENCY...............ECTE

COUIITSý ff')RA 2 IGMA ko)::LG ID

0105 ~i*. 80 'i . 3515 6.3E0 57 8 Sh CM P i.i.t214cic

R13..3 2*. : 3. .T..13 09:2.3..3.. 11 4iu : '. :i 9.'~ r 1.0 0E 0 3 5I 1- -4 BIYI1 f:3 i (1 3:3 3333~( f..i.*(3 3.:3 )3

NW. ~E::FY3<cr~ uo ~ x~c~ :ou1 areaii::3 :1 i 13 iCRT iiIi~

I fD Ei Ni Ti I V'; I Ei 1) ID I :fI3: K. U~~ '\1 I'("3111: A Et3i 1A01 3~r T B AC G O N NE ARE .A 11 T E 3-- S1.( 'V j 1,1I'ý1" , I:1HT

I ~ ~ ~ ~ ~ ~ ~ ~ ~ I31 % iIP':.~.h"I i '.)3

CE 14 271.6 13 .1' 18 . :1.I 0 001 4

1- 131 5 7 I 2. '33' 1 (i.,,,-

BA 14i14 3 3330 . 61 5 5 9 :1.~ (?) 6-I~f ". 37.*: " ~ ."f'VI''J 'A

B l**.-.-/ :1 0 6 , 11

RU-1033 1122 12 110 3 3.6 4- 8 *1,:1.84 1

1:.. .3 1 CI . 2 3 33 (71 003t 1314 8.

C -34; 4 13' -3 . I'31i 3* ::

p ~ N 9.3. .33-.3 :1.. 4'.

oil EMS ORTEC 0 V - I ( 175) WAN3R [email protected] 12-OCT-RO07 104105 Page

Environmental We

S U F 1 1 %I (ll i::OF COUN{Th T1. 1iti c.::r ;: : n;:' I.I. ::;

,)" : *..**:

..-.. -.-.. -. ....-...-..... -.-. -.-.. - . .. . .. . . -- . . . - --.-..-.....4-.. .. ..... ....... . ... ........ ...

11111 1 .

I..I

z 1 ."

CS-13

C l , :. 3

Cili :. 6

S. 326E0

2.:1

2.:

Q 68E01

XMM1

-4. 91 t f@

1 r~rni.. ~ i i: ~ j' * . :. ' ?c 2(.', :1. I..~V4 0.. 0 1-fER .. 4 I

TOTAL DECAYED ACTIVIT 3'.). ( 1 to 2026. :1 kV)+ : 0. 10000 OlE /I0 I TF:1.

133.5Iif444 1

497.0

62 .8 %/lI

756.7 If,

830 .1

129.60

S (1 .I'

I A 1 6'I .

f.",~ ~ ~ ~ F-.y 01

4. /. 8 I131

284.3 % 1-3:1

477 . (..,1 1-7

604 .70 % CS13

1061.66

795.84 1.1113.55 4

JA64.81

he 8 ~ , (jý " I' . 1

610.3 % RU I WI

I J.dentiied, ut~ firs pea W M

EvM OR. E GD V I; (. 175)i WN P 14O29 06OC-R0 W49:3 Page 7 ~ 1@0

*IA 6, 5 ' i,5,, 1- 1 1::

nV:

Acquisition informatio-nStart timeLive timeReal timeDead time

06Ot20 1140..1:135113T."%

MDI Inpu .4I~

Calbra ion I t'

Zevoxd . . . 1 ofse .-.13 ke/ G a in U 1 .500 keV/channe:l.

Ac ivt scaing fato

RI. Ii.

l'in.-fC allP&'i :'*~iin : ~

30 00OX7:1.i'

I J. I. '..c i' 4n~r~ I. ,

Ba k ro n width bes method :r~~1: 4i14':I Kln..n~C'~Ir

Correction,.;-,correct YE-i 3.

.0M: Me 't /

0PI 1-.) s o f.. o -[--I tý..- -f.. I-, a l

.... ..... .

* i E r v 6 O R E G V Ii (. 1 7 5 W A N 3 R 1 4 O R 9 0 6 O T 2 0 1 0 4 9 : 3 P a pe:~ i 4 7 ~ i (~2::

En rg cal. ibra ~t1: io ~n vmc Cfli zedI i :cx ic .ff ~~st~c :i. ,, . 0

U~ Ni 1: D E:1 T:cF E 1) P .E u1 Ki S U 1I 1 A R YPEAK lC~lEN (:3 3.: BA:CK.~GI;ROUND~s3 NET AREAf '.Eir FFI:i::C iN:*.-`C UNCA'~l::ii:- F I:hj.-~ IN 3I:~cl

476.68

676.59;

703.6712B 58

1589~4.3

1351.8

609.31

376.217.186.

S&

23.6I*~ 5 ~ Iý 1- ii:,0

45.4~37.:~ 913 ;1. :q'.3~ 4

1- B1 2: *~~1.4f- C(--2.

I)

11pa fail shap tests.,

I D E N T I F I E D P E A 1-1NUCA-1 DE PEAK CENTROID BACKGROUND NET AREA

FJ-,IIH:R.GY (:."OUNTS

13 ii 11 VI ("I R Y .. s sisi s*s s

.5 4 4 4 5 5 5 5 5 5 4 4 5

OE 14CE-I 14

RU 10

(:1 1: fi : . .1

I 1 31CS-137

5IS-134

C;0

L. A, 1.

(1) 1fý

(-' 1 1 (1-)

I' :1.220.62

1245.0

: 1. '- , ,.*~1321.4

2347 *I.13

25 f.'' ý 11 8V".

2 92

60i

135.146.41

49. M.)

£" -3*" , " -3 .

26'.

117.6

11 -4 ,I' 1

132.

44,

I (3

-1111

:19.

III,

4,,

0 0f

Will '.

0 ''?)

(.7 (ý'Cd4 1 1. '

16R. 19

:1~*, 5

2. 8

:1. 0,'3&ý'

01. 0' 0

MY.%1'J

0 0

517ki3

lii:C`j(&G OR-Hýý:C*1, C.3 V - I ( 175) WON3R 14WO2.96 W6-0C'T--2(.7j(?)7 IDageE -,-I v J. re. -.-I I .-I I I -I ý.*Z" I' I L.- :1, 1 1.1c !'.3 p c I.; -C, u 1-1-1 1*1,:1.f)-1**,ý :: 4*,7!.,..,.;68 " (41.) 1

-0.1 - -),iiO ape

*:~: ~ 13 tJ j I 1* A) R. Y .: 0 F Al J C.: L.: )I D v. E S N 13 A V! P L E.2 SI('311()

pCiiLITER pCi/LITER

.S

I.4.4.S.A.4.............I.4 'S

C "I ) 5

CM-60 '

FU 106

SC) :..

.40CE141(~

CE144

<) .3 9187E+01

it5.9943E+02

< (f

< ~ ~ I4 Q' .30 ifr J,

< !...,; 6 0 (.*l If I.-

< ? !'.'5 9 97 -1 I

<~~ :1,0440E+01

<~ ~ 2.52B(<i

<'l 6.0710

< 11"76211+0< ~ *3~. ~F

2 .3S Fý .", 0

< 4.634+0

1.24E0

45:.2815E+01fJ a

7 ,*3 irý+-,)(ýj

5 ' 6:1. 4 *1Ii '

1.90EW

& 725E0Q~~~; 4447E+00I

& 99E+.1

4,. (? t 3I. 1

I. (66f+0

it All peaks for activity hadActivity omitted from total

omitted from total arld all

A Activity printed, but <....... .... .I ................. ........ .... ........ .............. ....... ......... .... ........ FZ Y .... .... .... I~ ~ .............. ................... ................ ....... ................ ...3 ITI

TOTAL CICT14JITY 59.9 to 2024. 1 keV) !.`.-5.

TC)TrA. DECAYED ACTIUITY ( 59. 9 to 2024. 1 keV) 5.

********* ýý'; L) 1*11 I'll () V11. `( C) 1:7 1) 1 ýH*; C: (1 R 1) IH: D V, li:: A1133.054 of CE-144 145.44 & CE-141 284.30 R 1 1,31.328.76 % LA-140 364.48 % 1-13:1. 477.61 R BE-7497.08 & WOW 537.32 % BA-140 604.70 % CS-134

621.84 % RU-106 636.97 % 1-131 6161.66 & C "I f.. ý) :1. '3-,'ý756.7p & ZR-95 765.79 X NB-95 795.84 9 Cfýý*.,--l '.ýi5,1834.84 % MN-54 1099.25 % FE-59 1115.55 & ZN (.*,5

1291-60 % FE-59 1332.50 & CG (""10 1.5,ý.';?6. 18 1 (.4 :1. z:,, Q)

! - Peak is part of a multiplet wwl this area went.:

'1 4/ IX B(4 :. 4 (

1 a', .*4. 11 4 C;C.. CVj

E cuI 0 "H:~rEC:: V3 T, ( 1.75) WA 3 1:.'~4fZIO:. 96. 1. 1-OCl T J h :1. f<:('.*7: .44E I V . f, C) .1.fl C. 1- t '.. Z.-O.5p c:U I -1. i: .,I) ~ (~@1

:1.

ý1.. :;:

il*. 13C F IA n : .1D. ... m :: \. i;e '\.1

(1(0

IO.f.. (t:,I)-) m I. 3 ~ ~7 1 . :.

Start C :: F C ( ti e ':i l:r *'::

(:"1

MCB I Input '3

f.2reated.:ec . 1L. i3 141. 4RO 31. .1. & 1.4 'w. @17 .4 53 4ITICJ H2433 IC:lW i 1

Zer offse F:W ke, G1 I VF 3ai:.nQuad.rat1; ic.....2F(7I:e ha 1. ne.V "2

.500 keWchannel

I 1. i 11CC.1.2C- for' ;f) a n e': o~ff ,Ti3o*,

I ~ ~ ~ ~ 44 fo' no- (eeg M;i P024.r09ke. V j ~iCKPea reeto lwe 000

Peak searc

Sapl S ~ize:;C~~I:~ 3. 5@fCf:: :

I)ActS.iv. ity ::. .h sca ing.:l factorCi; m ~ ::'I.O O E 1 '3 aeci f) 4 . ) V.,::.I..

corretio.

Peake backround coreto

Statulii.YE,:G,Y ENO

pb(::-

R,-Wid CA-11 "HJAIM-1-1 J. n

0EGRG O F:RTEC 0:-I: ( .175 WAN32~~:r 14W '.:9 :1- t .r ... 1?007

Energy calibration normalized difference::

3,33344333U N4~4~ 1: .l) E4 Al T 1 F'. I Ei ))

EFFICIENCY.2 ,xI I (;-v-'*V

Y 34 *:444:34:3

:1217. 70

2.38,:.13p294.7

6.4(

St .. 4'.762E+03 @

67 4X"~I.548E+03'

42.,9457.0:1

32:j.96

1..1.74 PB..21~4

1.191I PB24

I.)

1) 1 (,. ic a k . a i4 ::v'' : .i. :: i

*;4~~ ~ DC E3.333333 N33 T3 I3..~***~: c~ F i I E :1 r.: E A. 1*11 I'll (.11 R YINTENSITY WART FWHIYI(:.'*'I'ýý.*,'/.".i-.,'F:(:'..* 2 S 1 (.-3 I'll ("t 1.!.eV

'3~ 4.............+

1-131

Bii e

.A14

Cs 13

-ellI 3,

.1 (1'

10 '3.39

:1. 9. 42

122. 68I

1 ' 0

:1 4 1l 8

0,3

1.

1 :;e'' 11 ;3

,310 1.," '(A

-.1 5 0;2

13 I I) 5 5

I "1. -.31.

"!'.3.

40,

48..

-3

4.3

12.,

21,

89.

(21

21121

~::l(~J:I.

~:ilŽ3 :1.(k:If3~;I(3 (2~

(23(21 I.

(301.~

riII

I.IA (:j

12I (A (A

(<3 143

121

(21,1(21

(21 (21 (A

:1.

404

1. -17

I 8

I' Ii 3 3

:1.3 4 4

/ I')

'I I. ('I.81

('I 3

(JI~4 '3

111.3'

:1..3 .3,

I.,. '3 11131.. i 3)

33~ 3'3.

('.3

1(1(3

33 33

I ('II I"

3.',. .,; I.

4(13:3 4 :31 3

:1. ,,

I :3..:. 0:r: I ~ .33, j. 3.3 *(',3:3..33 C1333'1'' 33f3 V ~ 3 ct:35l3::I

OR:c ~ i:._ G~ V -:~ I~:: 2 (' :175 WAm :4 2 96 11:..... 4j ,,9.3. :0:o@ 1En, J. ~ : I~ t;.- 1. :: r~ p: c-.; Ain i rum :: 3,17' (9 ný :1.

I'll I'll (.", R IT, 0 F N U C*..* I :I:TIME OF COUNT TIME CORRECTED

WWCLIDE ACTIVITY ACTIVITY

p IiCi/LITER

UNCRTANT

:1. .INC`;

* '* * *-.X.

†---ý .. 4...... .. . . . . . . ..+. . . . . . . .+- +- _ _ + .4.4. ..+ -+ +_.- .+-.4-.4 . ... ..It . 4.....I .4...+-- +---4 ..... .ý--+-- 4 .....)

CO0

(I'I)

.U 10/:1: :1. 3 .

5206E+01(2

1.2647W.

< 1.58361 1+0

2.

3.34:1. 4E+00

z" I I r I'I(2)

EN 4785E'0:1.

2 .81 2 + :1.t. 5270E m+004001E-o

z"89E+:1

.OTA DECAYED ACIVT 59. 9 to 2024. :j keV I.,; :[TER.

:1.33. 54 %' CE-14l4 14 .44

622 .71.8 X' I (10 1 '.9

83.8 %I MN5 111.5 K

:1 ., % '.' C O I (L... I'.. " %

DIS~CARDIH1.

CE14 28I 4.3 X,

1-131 ,4 477.61 %

ZNi6 1 +4.

I 1 3

C J.

3~~~~ ri." 8 4 'IAI4

61.3 W40II3

C O'' '

PeakAni 1 is ato a mutpe .0: Wn,.: arreaa wen~tiI

ne a ive 4 t iij~

Peak Iis too wide

Pe ......k~ fail so isi fi I it it ,iie:st, 1 .tt::.KI;:4:.:~

EGAB ORTEC (3 V -- 1 0 175) WnN32 14WO2. 96 2007 :U.*.'.';ýf.*.-`.2;::1.8f-':*-'i--i,,2:i,-r--c:)-,--ii-i-ie-t--i-t-.ý..-L]. Tric- 5',"500 . (*-1-,--, 1.

de.;

TWO 3. 5 LITE:R2!.-'.*.,'--.-!'-'ý[ý:1::,ý..-20(ý'-)*;7 :1.2i:(-.,J(,)

1 0

Sp~c 1:trum :.J.~YI 1: .37 fiF

Start time 09-Oct-2007 W45436Live time 1300:1.Real time 13 0 0!.-*.'jDead time .03711DetectoT/Geometry ID,,i-, 5 f,.'!f

D)etecto System 0(;

CaI i br ti I

Cratd 19Mr20 11:09M

Analysis~ I paamterel-.

Pea serhsnitvt~

. 50(ý.

a-1- cvf 6 5,, 9:1. V.

.3 i '

3. 50E

+(7

1.00 00IiiO

: *t 0

Y Ei C'-

Comments

. R O OR TEC2 (6 V I ( :175) WANh.3RF :1: 4W02 ~.9 09 0(.*."..c.:i::. 1. 2 4 3 I' I:.'"'J r ov. m' (.n)3303 L.3: :34'04F 1333 !.*.57300 1 5~ .

2.

Energy calibration normalizeml differennneg I.. 000E

34 ~ ~ 11 13444443444 D F : N V 1 : E:: 1) P4

PEAK CENTRID::~ B CKMU 1,11.i5; 7 AF'Ji.wi I'2 c.Tl:CTEN

13 U l'~l Iil A4 F;" ' 34 4

... 4.........3................................ I... 4.+.4..3....4.,.4. 3.4....3,. 3.4...3 ........A.4.....3.......,..1...'.,. . . . .... I`.•.•.•..•-•,. .. •.•........•....• .... ....

1. 2:1.'*,-",. 4 8 ."*[ 11 ("..) 8 -3-9. 28 B1 214 D)

'0~ 4314

34~~~ ~~ D3 E4 N4 T444:4*c +43 4 i C I F I EI '.0 1:1, lis: 1'.I [H; U I'l 4444443444.43 ("IR.

f-f-f -f- f-f-f-f- + - + -f- + -f-f - f-f-f- f-f- + -f -f- f-f- +---+ -... 11 1 1, ..... .I'. .... 4 ...... ..... ..

CE-1~ ]44

B:1

F*:U... J.0*3

RU1065:

H B 6

K 0

...J. 40

9 r.5 'I'l

'9 2.1 0I

: J 4 . 9i

1.272. 5*',)1'323.7

: '.6 5. '.

:31 'I' (`

'I3 6.,41 i'"

(53 61. -43

8:12,, 2,1-

835.3

1 :. *f

f:1. -326

:1 X" II 2~ -'3

651.

31

21-

1.2,

:L5.

1 ~

91,

.3"''J1

00:.

.0:1.0033:3:1.

0:: 1.33~

I, A 5 ('"ý

374 1?,

f.'O

.. '

4

4 8:1

2,j M.

2., 232

:... ... .. .. .. ....

EGRG ORTEC G V 11 ( 175) WAN3R 14WOR.96 09-OCT-2007 W2018 Page

Sr U MC MI A~ R It 0i F 11 C ..L r I D) !i: 5~ :1 11.

T1IvE IF ()I:' COUNT.JF :i TIME13 COR:J:;RECTE UN .. hi(CERTAINTYC FNUCLID ACTIV.. A1F i ~~ CTr.IVITY COUNT IN

S 4 (*- 'l , I F

pC i/L.'I.'TER :.,CiiLITER pCi/LIT(R

+_ +_ +_+_ +_ +_+ _+_+_ + _+_+ _+_ +_+_+_ + _+_+_+ -+-..I.

I,I4 -!-.*;-5

R.U

Clii :1. .4A

-,% 2.%[K--(3:I(

3 7 ) 1..4 3 ii: + 00

C':: 3! 5 1:: E+00

.3 9 **5 :. Iii:

*i. 11 ! 9 0lvi ':

I.5 6 E 0

7.84881.100

5,, 22-.,*1*,71'- (1

41 21. Iii: f-0 (a

224:1E+:1.n

:1.02 1E0 3'3 . :01.

TOTA (.f :L . ~ ' AC IVIT ( 635,, I.9 t:: 203:1.4 k'::' ) (3,*-, (ý''.ý(i..O (-' 013 Jl~: 311.3.,, @ 13:' :*4 :i. /I 1:1, i: F

D33r1!I...1):31:::'3AYE ACTVIT (3 65. to :. 203.:1. .4 kV e : 0.0000000Eu:II2±00 ;1Kj:I..F,,

"]ý U I 'll 'ITI P, R Y 0 1 :I : R. 1, (* 1 D ) 1 F: j,

10 " '' ' .J.

II)b .'I J II'3

Pea ispr fa'liltad W ;ae el.

negai veII. .~

411,18B ORTEH! G V 11 ( 175) WAN32 14WO2.96 11 C) C". 'T -.. E*-1(.'.-'JO1 71C',9'3 .

:1

T > W IlA 3" 51 1 TY ThrA\ I./:F,1:1

~0~'

Liv time 770:~1.4

De(:tectov/Y ,GeometArQ;y Is X);

M::f':t.* w 14- 2t.-2007 10 36: 49 I-*Ia& 2U1 H 1."

Zev ofst -198 e; Gi.501 key/channel

!'I ai .1.) a.[-- al y s :i U s.

Peak1 ii . i

Peak i

I..8 foxf" anr ,.,e'".y o:'f 58, .`j 1..e4(.48 for an e e,.y of 2-'}6 0 .:e

;I. ,, 080 01i+.)6/( I1.8 0 ti+ (}:• , 5 (?0i>.-8R:; •.'. 8571EI I+>05

De ec io I. :t ciI met::i cWRIS method ~

I I c.~cc I ~il ~r ' .00 00O.O

.I I~~~~~ J. 11-d l:c. Ic5t *~. IBackgroundc .:idthuL: bes method:j

D d. J. . :1) .1. c t:: icPeake baci(1lckground cic corre a:,ction c

I.'

I Ii]

Ciii cc ci-ii

IF. nd ':~ in ~. U 144144 :4. n El 4'.4 C)I "

EGs&G (RTE" 0l V I: ( 1.75~,) Wi:IN3R~: 1:4 W(O) .9 l : (:IX::IP-'2007 :4. S Pagei:'

Energy q ca~ibrI:'at:i.on i norminal ; ~ : ize dif:.fe~'c~ r ene ., 05:.

*x:~~4**'4 U NPEAK 4: '.N( ' ::4.4 I4

I D E N T I F I E DBACKGROUND MET AREA

C,-,(AJ1%1*f!ii3 COUNT!ii),

P Ii: A 1/EFFCINC

S:1 U. 11W 11Af"Y '4*4'144

.1.4.4....A.4.4.+.1.1.4~-.I.4.4.+.I.4.1.4.~.4.4.4~.4.4.4.4.4.4.4.

IOR3.65 510.83IR19.90 609. M,.,j

98.k4..,

.138~ . 1.4200

69 .97E03

39.99 1. 774 TL-20,1-.",36-1 .!.*.5ll-,.; 1-8-47 I)

P.ILC :1 a l af*.' 14. ci C:A, CENTRO, i: I. :+D: :

44 *.44.*i4~.4j * * -.4j 44 1, I1 ) 41 H F: 4 (IRC E I D lEiA It

NET AREA. 13 .U V14 Vc14:( A `( i 4: '13

4.A.4.4.4................4.4.4.4.1.4.4.4..4.4.........4.4.4..4.4.4.4.4.4.4..4.F. C. 3 174f. 424;'4

4 .1.. 1. 4 0.1

J: 41

BA-i 1 40i4CS-14

Z 1:

C *i 1. i

lii C.,

.6,~'

6'462 1241

J, 12. 4.

1.4!.j 0

2 41 0I

2 '.'? 3 0 .7

13P 9Q43146.48: :4:

P83 02.

304.76 1::

W9 71,

(--,

477.54,)IA

48.00b

X1,'

2I 1,'.

8 1 1.

t4 *. i 4 4.'4: 4 0 (1,

III4r 1

0' 43

2971,240,

83.107.,

54'70 1,

22 .,

.3

45 ,

I64

4291,

:4.

1 3 .

I.,

0.1

4',

19.('

.0024

.l

0 ~l

:.34.4,

I 4

287. 1,,*.ý

)48

:1. 48. 8

F'~4 . 1

: '. 2 473.0

12

76M-,

3) 4::. a 4.: .~. •:4 ::~ ::: '2)44,.' I::: 4. I;; ~: c4

*M G : ORcE; GD U ( - I. ( 1.75:;) Wrd.32 1441112 . 96, Page@ 1.~ ~~ I:En ir nm n a I(-.1..C:rn .

*X. M': -ý X. ý U 171 11 A R "l 0 : F I N I U C ... :I D Eýj3 :: F l(

'4..... 43.3.'. 3S~3 443544. .443444 44

I.., <

FE-5 <i

O-58

F./U1. 03FM106 <'

1I '.-1 <

CS 13 <'

o i ..l C s .1 3 7L <

BA- 140 <LA-140 <3

.3. 415E0

3.8122M:I:I

3 ... , ' 4: . .. 3(23.

2. 1 2871. **

41. 1656E+01s(

4' 1960E+0:1r.

i.? .314 9 I 0 E +I'. 876711+00'

-3 j. 3 .I Irj )

3.884311+0

1.1

3..

9 .4"ýi O -.)i:--,'J.)

TOTA DECAYE ACTIVITY~3: ( 58,. 1. to; 220~2 6,I. I..<''.. 0.2 2ru232'32 2 FU3 :' .i ITi::.

621.8

756.72 &

83.8 %

Ui I' I'

I (3 4(,'I,

RU- 106ZR -9i I 1'

I'll I

(" R Y 1: D 1: 'I.H

109. W M-59

1332.50 CO-60

6. 1.661'-

795~ *.8'4

111 .5

:146.8I~i 13( '

ZN(.,

1 3 .-x .-if 3K4 ). -x. )(.-

304. 84 B . -.

2 4. J . Z

1 :1. 42

Peak is part of a multiplet mW W" area wen-(-.-.negative duping deconvolution.Fleak J.,.iý ),w.i*f-f,,(:)i/-).Peak is too wide al-, III 1ý 1:jul-, FIA1.111.Peak fail....;.., test'.

$ Peak identified, but first peak of W.s nucli&-,ýfailed one or q u ali H. c a o -I--, 1.,ests.

lEG& ORTF1EC: G V. I ( 1.75) WANh32 1: 4U@8 .9 (.' ..Gt 2'!007i.I;,;:li V: .I--, v i ro :1. 1-1 t:.: .' (*D.3: , 13 3~~l3~: .. /:

I.

a ill 1 c i. I;:1 r

- I1,,o1

Ac-u 1.J ct; 15333 1 . U3±:rl' 13 @

Dead time . 31.'

M CB.. .I n p u -':: 3 '

( ~ ~ ir I I I :.331

Zer oi331ffse t -.. 1.1.0 ke;:Y G in 3 ,.500 kc'Y.c.ha-Q..uadra.~t:ic I: 2!.*-ý 1H .0~7 k). c~,/ C.'II'-A1" 3 :Y) :1. "

Peak rejec,3 tionlee

Sa pl Size::3

Acivt scain factor:1

2. 1: i:b

404 for w) enegy

!.'J 9 .. 9 0 (...? Y2024.09k&

3. 500I..OOOOE+06/( I.OOOOE+00* .......... '."l .50O ........ 3

A 3ditional sytemti rry 1.0000OU

Fract.3 i on wL i .Jt 3 5333: 333t' :31 (l::i-&l 333 :3f3331:333

corrections '33 3: . i:': 3: I.

Peake backgroun 33::I.i correction:3

W E;I .. tpbc.33333331:

I. ORE Bi V~. -. ~i Ivc (3 175 WM3 14O .96nn. n 37 :.

Energly calibration normal i :1. 00 0

IH 1.11H!:'" .-I D E11T I F" CI.Ei1)

P E A K 13 Ui A~ l(

SI:

* ***::* X..(

:1021.2 51 .5 9 . 177. 1.81 t7E 04 i': .. 2 0 1. 'I 'T..**

1217.98~~~~~~~~~~ 60.8P. 5 .41+33.4 1W? I24

I D E N T IF.: iI3Li. E

Pi E A.

NET: AREAii.f

13U11V ():14 f~.Y *~*i

INTESIT tkf::FIW

O E-I141

LA140

I.-.i3

7 I

KA-1 40

RU-10DA-140

CS-13

tl...I

0.'6. 0

R9. 84'

.'D

ii 4i

6396 Octf-3 1 ..) ';

1209.42I 220l .68

1. 4.¼ (*.*ii1..... .......... .'

2

3 1. (!"'J

:13.44:1.46.8 . 4

604L. 7 ,'

72.3'. .1 -J

( 3 2j

'53 -'3 1)

53.1

54.

26

-34

3i3OR

7

'II

ii

iiII(I

II

I I

I,

I I.

0,.

LiCi',

00.5:1.

00:i1.

sOO(l

0 3.

I A."?I

209. :.4

1IR ms

,,8.0 . ' 7 i.346.41,

6. 5 4:1.00

405.'96

319.39

:1 2

158I. MR

I FI

1,1 *1

I ~*/Ic~

iii(ii'J(3~,

I )ii(A-

j,1i1

i~iI 1

1.iiII~l'liii)

'1'1

I j( I

I i(.II~I'

'I.

I iL~IL'i'

~II

II'

:o .-&('- ORI:C.4X~ (3 V~:~:rc - t I r75.AN R 1 WO . 6 1 OC *1cK1Q7 15t33:I5

13 11 11 11 A R Y 0 F, 1`1 U C I 1 1) F: 113 :1: NT11"IE 0F'

DE ACTIVITY ACTIVITY CXWKHJN(".1

.::, *4

~ :i: ~9 4' 9 .9() (. (

J.3 :/1-. :1: 'T F*:•"R: I 3:i. C . .I. TE~~' p C :L ..,: I... I 'f' Ei: F',.'.

4 ... l.. .1--+._A, .... . . .-- 1'..,-.-4...... + . . . . . . . . . ..+4.......................

K - 4i

RU I (")-I

1 1 :1.

71. 79 1 OE +

J.:11. 4

2 :.'i ,; I .. Fr + ("..) 0r~r

5. 705E+00

:1,.5 3 E 0

2 . 3E: + (..

440

2.244 :11i:1,0

:1.3539E.. 0.:414

Ni 6160E+00,

A c ii tyr printed, a(U. fL.r :i. Vi < 11DA.

TOTAL.~~ ~ ~ ~ ~ ACIVT 39. 9 to 2R.1kV .1:y './ UT:

T O T A:.. K H C E A C I V T (. 5 9 .) 9 o 0 2 . 1 9 k e V ) r (D . 9 j:) C J / 1 1/ T .,.:f: R ':

J. '3 -. 3.5 4 ( I r i: 1I/1 f Ii -, 5. 4 4 & CE 4 28 .3 % 1-

3R8.7 X LA 10 36.8X;-, 476 &B-

970 &'l RU10 1573 &I A10 64.0%C-3

5I *: .7.45 5. .

117.24~ Xf CO-60:

IW EG&G ORTEC G V I ( 175) WME: 14WOR.96 11-OCT-RO07 13H45MFK-nvi I p c- r u. 1-1-i i-,-, e :;

:1.

TWW 6'*";'(.'.-'-3 -'.3" "'5 1 T 'T IH: R.,

(0

Str t'~:ime

Live time.Rea time

I-Oct-RO07

.1311

M 1.1 I nu

13 0 i e i n.3~31' N~3IT'*':

Zer offset '

Quadratic

An ly i - I:).e -ii

I c-I;op :33~33 1

PeakPea serc sestii

Sa pl Sizes4 i.*~3 ~ 144 '~

F:: .i. si. 47) 343

for4 aAI0' . n*3 ... 3~ .4.

Aditiona sstemti erup 17 fl00000EM3,;:Fvaction~~I. Limi 00,1,

Bakron with bst, meho (based323 on spcr

Correct3.. ion

Decay du in .,( 3! 43:::t3 I. P& :.SM OY

Peke background3cs:~l..1 correc: si.

yI -1-:'33

IfE'41C_: •.)YESi~ii

Comments: rI:

33~w 3 33

I ":' u

.1 ý L I ý-,

LIE-ý 0 1)) (-ý! G) C: C1 f, C.., C: ý: .1. 0 11

R,-.-xn d of-1) MA) I .. I !;I

I " I

0EG&Gr:c:l: ORT: 0 V - :I ( 175) ,r:~~I * WAN3 14OR9 :1. 1.1:'':: .. 2 7 M U PageI~jc

Energ calj.~ .,ib ~rat ion rvinrr 3. i. e d i ffern

*:~~~ D( E( NC T~ 1:*- * : i ) (: I~~ (ii ~ [: If iS( C:: E ~NT kG3J X

F E 1) 1:BACK3GROUND~iiix

Es () 1K

NET AREAl(

I'lli I' (.11 ' R Y ' *' X***4 );**4

I 4 1 ('A A.. .'............................y~*'c."*. I; *~f I (* 7

CE-144

LA- 14J: 1 -'31t

Pl.) 3.(")-3RU- 10('

: -1,-'3

CS- 13

z 111 . ,1*5

K (f),

D) Peak

EGG 15

9 1

:.* * /f.? .;44

1322.22'

:I., 44?' O 'f

J .,

i.t.? 5

flt

4* ½

145. 62285I.9B

306.95

327 /.79

486. M.?

610.3362.6

21

6ItI0., 1 1I-.J!,,

11

651,

106.

It I..

75,.

(201

III.91

IiI)

if,

I.21.:1.U

:1(5..

':4,,

:1. 3.C I

C,

ifIf

Il.

0:.4

0035):1,

J. (I".'

.31 1'.-;

98.\ A13

:1. 2 . 0 -3

449r. 94s

0.81

:.1., "7!59s,-

177

,,9I.5

:1. :1.27:1..

2.,, (5,"5.C5)

J. 400.s21.

:1., '•:'j;.. •

:1. ,, . "i(: ..

U 111 ivi A F", Y 0 F, I-1 U C11 L, ITIIIE CIF TlIlKý:

1--lUCI JA)F: ( 4 C'.'T I V I T Y ACTTVITY

CMU: TM13I...

C Ii (3

I T : , i: 1:;..' c:, ý i./L.1 ""ITlER Q U:,C: i.,". t: ER :.... .. .C . . . . . . . . . . . . . . . . . . . . . .

<5 2lF: 0 6

F:C-3&1G ORTE'C", C-) V T ( 175) WAI-4,32 T 4 W 0 P. 9

T <

Pf . .:4 ED

'1, 4 C-)C I,:, .A1

<I~~

:1. 11 8 -31. 9 E: 0

4 G' ""'1 1::. Q'I 01:5 Z11 0 (".3 1::* 0 0

Fill

4.It:, " "ý' 4 F, +

'31 0 3 E, 0

jf 811:147.

81. 0 .1 1.00

9'. 01

U ~ ~ ~ ~ ~ ~ ~ ~ ~~'9 9.: .. ~ (r:'i~ :~ .U K K~ t~o 2024A., :1. (Ill 0. @000000OE 400 j:) 1.."L.:1

*~~Uf ~ `3~ U IrlIl

"'Y2 I, '/ 1I "1,

I I'3 4 8 4 I'il- -4

F'11: C

I !..J 79

D'~ 't *I'

-~ r 1. 4(?).

' It i I "1

CI (1F , 1:

J.1. 1.

6.J.IC1

I I

( II t

'II'5~1

r ~ ~ : i1.03

1~'4 0 F IA 4 Y

0. 7 j.?, 58J..~.

part.- c'-f ...A th i-,

J. L.-c-o but; ol-,-. td-, F101-11"'L.

1::! 1 - J.

C. ',' t, f J. d t-, -f -i i:.-. t. p o! a I.,-. c) f 1--i i --:i -riu c 1

J. 1 f.-:i c) -f, 1-11 c.) v- (.-I k. -itt 'I. J. -f J. t: J. c) -1.1 t... c-l

ý I - A I I-t-.: J, ,,, J. A.; V-I i 1-11--, (-..! f' -L.- I c- a ýý k -1, -1 -(' J. v i I k. k v -j

t; i v i T.: T c.-) vj r t., I. -ii-t r) c' c) u n t: i I. c- I:--ý v., -t -A c

1D I.t&. ;Dij J... t..:.j. C:1 a 1. 7c u '. J.- viot; c-1. c., i.."? c.-n-lou gh t' c) -t-, I

j

EGM (::T:;. 6c V~ -: I (J 175) V~i.. WME 14WOR.96 :11 CT 7 1.4: R3 Page :..~

Fi n vi I;; al~ 1-ie1-1cU tA1.

'3 ~ * I; in:.-OC.1 12~ .r :: 3 ,,f:0V

ii,'"9

J.-- o-,217 17ic [.

Start'7 tim 11c:-R0 11:4509 ~y ::

I.

Calibratio-i-)F'i :1.

CreatedN 19-Mar-RO07 1009NO.)

Zero (2 I V I ('3ai:I,9131F-'-,--(ý'-.'1!."-; 1-:ý V/ c., I--, a

Library~2 Fie--

AnalysisI pr mei~': t U :1,11:

Pea rejection* level~(4

Sapl Size

Aciity scatin.facto

2.1 i1:-..~Y 500

7404 fo an energ.ti( t 7 'y o:7E0 1.4k

3.500I.OOOOE+06/( I.OOOOE+00-.',(, *~3.

7:1. *4* U~c, 1J o 1. i :1.1, 1,, 1. 1 0J

RIS me r2thod:i :c .: .f:l.2LI:(J~:t~f

Correct i on---.i--..1"o

Peaked background correction

St tu

F-1H'ti

YI i 5,bknw pbc t~iI:

0 1", 1.:: ý' -, I', i -,-, ý T -1-: -r- -,-I ... 'I '"', !.Id i

(:)R-f*liH'..* C-3 U I ( 175) WAN3R 14WOR. 96 11 0C.-IT 2EAT7 lh,.l:l0:f.3,*3 2

'riF:F f : ~.i.'~ a :. : i ci r"ma 11.'' ize i :i. f" f erenceNi :1.00

1<.~ N.i'i~)III: D): NT) F: Ii Er 2) P E A KEFFICIENCY

UNCER y FTW*W: *"F L.**II 'cY::t

:1. 018. !".51 Qj . -3 :1.21. ,Fj'2'.571E+04 34. W 1. 491

ii ~ .~s.y" I c A D E N T. ' I:.(~

*1 ,1 1.) Dri': 1:ir l* i 'jENF' T ROt I 0 iC*,l-.li`,l~ lKi~l liý: 1.1 Fii tý :

F: I 1 D1 E: () Ill :tt; LI "I i'~i ri '( * ii: ~L ~F:** :'L* * iL. *** '* *

`• .,..,.• .,.`,..,`'•.`.• ,,`,``, ``,• `•. ......`,,,A,.,• .•....`,•```.,``. .`.,,`.• .``• `•• •• .. ,• `,`.. A . .....•.} .••} -•• ,,`,... `,`,.•• ,,• `••• ...

1.0. :1. .

fIJ..f 6Jlf

.1 ý 1.4

F1 0 t* . 6.

I.FI ' : 1 3

25 2:: .3

.3 ' J.i tI

2 9"1.8 9 ~i

8 0 ':i..

1. '3 '

FIS

Fl A

F, I4

1.4 ,j :

4A,,

9'1,f.'!. 1 ,

4,,

i.4i.

(.I:

19.

:12.

1.00:1.

0IC.') t; I

C-?) 03 29

CJQ"1 C.'J

C.ACAC.

C~i A 0I

.i'?'

4 8I

A1) 0F 0

:1, -."0.

F 1 4)

8 A

'flooli

EGM ORTEC 13 V -- 3: ( 175) WAN32 14WO2.96 It-OCT-2007 IMM33Environmental Inc,

S U 01 11 A R Y 0 F 11 LJ 0 L ITINF: OF, COUNT TINF: (:*"ý:)I:ý.,I:ýEý:(:""TIli:l)

(.11 T1 V1 "(* Y ACTIVITY

'I~ ~ Ei S: Ii Ni~ *'

2 cii:

B Er

K - 4

I. I'58(

C 0-

ZR-95

I.. 1 1.4

CE-14:1.CE-11 44i

4. 194+1

B. 51E0

.3.. 1610E+00~

7 '.

4.' 125E+0

11" 664E0

*3.3462E+0

-4-00iI V 'l

4.7779E I r00

. 7813E+0

3'.

*1 V *E+0 .

3.4096E+0:1.

p :,f7:.4. (-D 0

3.. ~

8.2175E+00

pCJ. /LITE

< ~ 1'11.(.

A. Aciiypine,1D.

... ...... ... ... :...... . f -... ... ... ... ... .... ... ...... ... .. ......... .. .. ..... . . 4T ....J .... .... -..'i@ Ž) i .@ :)..... .... .I .... ... ... .... ..I........ .. ...

TOTAL ~:y~: :::i ACTVIT 65.9yl*C to 2031.4 .4.) 0.000000MO p , icCici ci*LITEF cl. l

K*** /**13 .5 %3

3P. 6

49.0 S

621.84 %~

756.7 & h

RU- 103'iR II liiI I ii

IN-5FE-5

01 R145.44

D I

I I.41-3:.'

BA-140V

i* 2

-4-'` .6 1

1104.70

111 .5

1)

/

I -' , 1 Ii

K-40

301'.64 4.4 8 2 A :1

61 .3 f7 I 1. R:..::

& ~

Pekispr of a multiplet .m WAY area went.:

negai ve1 .~ ii4C d r ngc i.IIIU ' : 4.i;

EG&G' ORE G. V -. I~ (: 175 WA3 1; r i.9 10vOCT in 71642705fl n :1

1, W~ :: 1") :~1

~3 c':: t ~~ 1. . ~ ~ 2 "fJ; c \ 00i 9,,f

~o1(0

' :c ; . -1-1 f:

Start1Live time~mc~*:~* i

800,3)

I', I C; f...'i ',*.,.; T )..I p u l., :1.

Cre~t edN 1')*** *i.r- f~200 M ON:.f~9 29 ~ 19 ' ~ .:.

I J.

.Ze Irocl. ofse 6.79 keI 0~~~! .. y.J!:i.xnc

Peak serc senitiit

Sampl S............ tfI~~Acivit scln facto[r*:

n:T ~~ ene y (:.f~ T: ~for'~ TY ~vc ' C ~I.'21: :'.

~~3'.IY~~~ffai~~~~iE::~R r8:;/ : .. F F+ L* O!..,. ii 'I U I

Aditcional~ 11':: systematic erup 1.0 @o 0(1 f:E.'

I J.i I .I.' 1,:c iLi~ i:-;; m t'cc c..::i o (~:::ft.

J1 -. -. ,-1

Peaked b ckgouI-

Ii

it

iiI L 1ii ~

.1C omment--...-.. f~

kJA2V.' .)II IA kW , I k.. k.A I I ., .. ,.1..1"1.,

EGS ORTE Gn. V~ 1A 175 WA. 1 9 11OT-07 UiPg

Environmna Inci~ p f.- m .. ~ i 4~@ 1 C.2?& 1 E :

Enrg calibr m Uationt. normalizedn n 7 ~ 9,,

2::

.33.33u N4**~: ~*44 .I ~ ~ ~ .D NT F I E

F, Iii: ("I KEFFICIENCY

.A , lii:f! - A R )

U~ M 71AF"' Y ., A*.44A.3.

~~~~~~:1. 2:1. C 3 C -* - 5:,1 9A :. ri~..4

1D; -:: fxA -.i -. . ~ x; p :

are d ; 3 gx ci (:.j .1.1 v o:iu l.; (,,'d

.~~~4~ D~( E3 N T~3 I~.': F3 I* E~1

D: P:i i ::: E A "H: U 3171 11'1 P, R 3 43Y A ~*3 1 3 3.~4

keV, .A. ... .. +... . ................... 3. -. -. ....... ...... .. 14 I .... 4. +-+

.1 1

Y.' (. I -- :1 A

.37

5*A. 5. 0A '1. 42

Al." ' J1 'i3

60.31

65 61

ii5 .'3

975.95

99.) 11

:1 i. 2 , (.,

1,321~i., A'i1

2l 0

:1.4

A! 9I

2 0Ii

I ý-.*!. 00l

C7. 3 I, f1

30.4

328.9

-3 A', 1 1

604.7

92i-3,.,6 A

7i 4. 1

:1 -, .-,*...I .

9f (..

I /1 1

3A1

12.

2.

4.

2.1.

0iF".1

00:.

1) (1.,100

6e:1

1.15. :1.8

Zil

5.37:17. ("' -,,

47.'?-.2:.]{!2 8

I A Al7.8

4:7. 6 5 .3

1;55'. 2..7

'1 2

3344ii58.A i2

AS i/il1

S(ii. 2, (')!•

68.]hi-

1., '35

:1.. ') X

21. C1)45

:1 .. -1

i[J 'A-

I! A~ :30 43.' 1

* G& (:ITT:C: G V I ( 175) : W(:d..1P 14W@2. 96 :.:.:1 2 .11

S;'**cR 03 F" N t.)j: 0I C' I. 1 1) E. 1 3 1 HT r:Hv 0::: OF* TINEH (::*(:)221",i:("IEi:c TE I.J NC:::.r t F.F :1: II-I i::. ~:> I.

*ir~ ~ * .i~ **jC~

pCiiLITER pCi!LITER

K-4

Z N -I: 6.-

z -9!".,

NB(RU- 103

9. 37 11X4.(.) I

2 2 (-?) .ý. 0Yp

3.6349MO

6 1.278+01

2,, 4(J3-eIH:-00it, EABR@F4 "01

I... ~ ~ ~ t 203..j1 £2 ~: (¼1,.4 I.eV ) 0~.0000OWf OEt pCi/ITER3TTLDECAYE ACIVT 65 : 3~ os.9 to 20.31. ,4 kV V) 0.,000000@E+00 (2:1 /. 1:TERI:

********* 9 U m I'll (.') ['11. y (::I F, -.(:) :I: ýHlý (:." Al [". 1) r'i: 1) ID IH:133.54 & CE-144 145.44 % CE-141 284.30 % 1-131

% LA-140 364.48 % 1-131 477.61 % BE-7497.08 9 RU-1021 537.3R % BA-140 604.70 % CS-134621.84 % RU-106 636.97 & 1-131 661.66 X CS-137756.72 & ZR-95 765.79 % NB-95 795.84 % M3,-1-34834.84 % MN-54 1099.25 % FE-59 1115.55 %1291.60 % FE-59 1.332.50 & M-60 1460.81 X K-40

Peak is Part of a multiplet and WA; area weal.-;negative

Peak is too wide at FW2511, bmt ohn axt FWHMPeak test.,

$ Peak identified, but first peak of Who nucHd(-.-,,failed one or more testm

30 .8 B'I ' 1 :487 LA140

610 33 1%-

I"2 ZI: 1

11 2' 4' (.

4 . .. :; ac.::t.: i. .'I P * hi he than counti...j. - n-ig ~ :. v:y

-p c:~i. ate ivitya owe nth~an:.c cc; 1 ti ccig na. ji

:1. .I cic aF a a 11 c an a a :1. i fc pc;:i :i a Pc n I i c t:.ccc *.. c~,.:~s .: ~ peak~o ~ ci a LIi: r c i.ie cn-,-~j

EGM ORTEC 0 V ~~~I ( 7)WA E 1W..6 110':1.

i..'N,307 J.0::0','Y 01,11E,

A1 A)1si I.-J, (:).[-) i I~[ fo-1-11-1 conStart time ILive timeReal timeDead timeDetectoT/Geometry IDs

73:1.

M 0 Ni 0:.

I.) CC' -2: I:

Calibratio.nY~:.7 T . 'lr.~'J 7 I. 5

Cratd :2MrR071N 4

Zero offse

':1 .2r . 1:

-1.980 kevq Gain

.120E-07 keV/channe JA2

.501 ket)/cManne].

Sample cr Sizei:Activit sicaln fato

2. 1 :i 1:.

4048 ifor' i~ * of ~: i*, 0' 0, 6 kT e. V

I.OOOOE+06/q2 I.OO+0*MOE

j. 'C 1A.;[1JA.

AddiciitionalC .sytmtc err :1.00000OO @ @Frcti o L r i m: ;it::c 0. 0i c: rC:0A IJ~cU~fL 1 .J'

Backgoundwidt N bst m

Coret.n

De a ) u ::(3 cI-rLic"Ylýý:S

YEiiIT)

.02

Comet

.>k l2j. A.f-i I;; (-i

EGt&G ui:T.j: V 1. : 1'',M WAN3~2: 14WOE .96 1.-OCT 2007 21 @P ~li::.v r . i ovII .1.1 t; al :. in c:p II 1 0r

Energy c~al i.br:lat: i.on normafli z i 1 :edi 0ii E! .i8ec : 0

* A * I...............+.I.I...........I...................... ......I,..4... 4..... ..1 .4.........A...3.)---4 .... 4

I i I E D, P5 E A K.~ S *1Ill ("I iY: t rrY

14 4A :1. :1 (".)02 248.a? i 656s11 '.~

I 1 A3 9~.. 11 9A, 1.. 1.i :1 -1' 1, 52l

DA 14 Al13.30 3 05.j 2(-'.V.' 0 1 2,,1 0(;,lf'.3 105. 38 15 i1

LA 14 i5 .8 32 .5 112 11 . 0(,1 *.4,-*Z, 5 'A J

j ."?8 497. 92i 371 21. ("..FK)13 , (ll3.A -. 1 0A :(. (,'j ,, 5.I.I BE 536 9(. 43. 2. 0()1.1 4

RU 10 1 f "(.) t'.fi (...1 :1.f4 0 :1

it :ll 7I~i~ i.3 2I Z'k. 1-' 8:.I~l.'

IH:CVW 01:*-,-HýH' C-3 V I ( 175) WAN3R 14WO2. 96 11-OCT-2007 15=050liý: -I--, VJ. r a

I'l I'l A R Y C) , 14 U C" J: 1) : ý`; I: N1S C P, ,. X ,)(. * *

C, J. / L. IT E R p CA / L I T E R JR. /L I TER

K-4

CC._I... .

C'.O(1f`

Z*NHz F1 I"...;

S.:f~ 4757E 4f01

4. 1095:.yi.0.

6. 3 u 51 fI.'K+0(

3.354E+0

::.S4757E+0i:1.

In571M..

31.

2. :1." 4313~-L

1.1065E+:1,(

A~~i Acivt p.ne. u (:i:~J--y<MA

X. A.M ) ( )( -X. ý,*1 I'l I 'l

1 54 C. .: 1 4", 4

I1 PiI I :1 I C

I~ h 4 C,` E 1.1. 28 .3 %

53. IE BI 4 it84.0

" : *j. 9 1''6

133 .5 % (:(: 1 .4 0 X

r.3c

i A .-:,

& I A~ (P. 43i 0h

~ CC) 5 ' I')

Pea is part o.fa mliple wo Wn area iwh :

neatv du in dmNA:'4:' utio'n ','

J..I. to -.At bu . o'l'2'4 F34: 1- 1,1 .

EGRG ORTEC G V I ( 175) WMM32 14WO2.96 I!-OCT-2007 102W46 Page I1.

2 t-*; -tu S :j. I::,- - *cu-) 'e :1 J. ::i 4i'.-?..A 1

(C

Liv time.Real t ime

7: 5

7 5 V-.

Cetedu 3.4 1HLi.R @73 1........ & ~ .(i2

IV3112 ;3 Gce one try MI .

0

III ~ I a J.I- .1!1 .i :1. J

1 J.brar' I ,d h

Analys~is paraetr

2 .1i1-

12 ,f ' i.i C3 )jT

4048c f ~ or o f i.,,ý(. 4.

I.OOE06Ii.001709 .5OV;O

2.871+0

Ti iwiý ~i -i-it

I I '. ~I 1.00000OOrcoOO

Pe ke ba iI.ckgroundI cic c: C ec: 1: i

SI.atu

IC iJ

Commnt

.2pK: 2 A. f:

1 ci 3E 333 333 :i. 31 3:~ ii (:1NO.I

S & o;0 (.u:: f v :.I: ( 1;*ý; :3.; :1J:\ I4W4@25 s.96 11-OCTc 210'p7 . 1

E-". Y .: .-n ' v i l r 3 a n 3 I; a 1 1Iv --c:p :1; t. 3. 33:' 3 /h :.(::.

4. ...... .f ...U . .. .~ ..... .1 ..3 : . .. .. . .. .::j:...3 4 --1..fl .4 .f 4 .... j4....4... . ....-- 4 . ... ..F

121.1 6093~. 1:3 3 1. IR6. 1 ,i.6.42E+04 27 " (".1 ZI :1. ':. 9r 11 :r:i 2:1.4

D - r' a:; . l C .' :C ) V: 0 :1. k.i:ec

3~~~~ D~ E~ N~ T1 3~~ 3 'h . ~ 131: I F I: E1 D~ :13 P

[IiU( J:~ r (if: PEA31 K CENTRiID BAC~ rwKGROU) NDE 1/

IN EN IT ITCiT i1 0l(i '' .J ..- 31 3 *3 1 C 3

1 1.33' (11.) 0 ( 2 333t1. .(.*,o:.5

I-, (ii 27I -'3,3 '?- ";' 233( 2.(

1-3. 792 6. 70( (3F9. 13 00 17.4 .5710

LA-14 974.2 4"f' 8'3 7. M', S9. f23:1F 2 ii2

1. 03 '34- 114 . 1.41. .535 , 33A~

:1. 3 6 0 -H!" 8.3. 8 S 3;:3f;:325- 3V3

'i 13 : '1 3 2) (,- 9. 34 (:314 ,, '",

F'.)1 . -3 :1 c'? 0 .r' 5' 0 0. 0.I).: 0''0RU. 10 :1 ' ' 'j . :13.3 91. 8~3' .(31( 3 ~

.1: .. s.,- / 3 . ~ 22, 8,:((~3 I 3 8~ 4:.3

1,1- 5 6. (-3 -3 .'002 1

F ..: -34 10S,19. 2 Q)0 3

2 9', 2:1 -'1 131LA333 1403~3 3 9 .60 1595. 5 2' . 5(3:1. 125' . , I3

-.--A I::~41~ a' 4'f C :c k3,~~c . At:.: :

0E:M ORE 0.:I VI:.. I K3 175)i:~ WTI'32 :i 4hj4WO.9(- :11.U ;r4r; ~ '4

E'-. -I- v i r ~ c Y (-n. -t. a I. pe fl,:: II 1U.u i : '*.-'71,Ai

8 (D: F~: H:: U:LJHr :i: 1'iu 1::J~f1: ::: J :1) . 1: n1.1* * * I( -*

p:ti• i./"i. [TTERJ :C:i./ 'I E:..'

I ...4 .. .,.... ... .. ...4... .4 f... 1 ... ...f... .ý -... ..... 'If... 4 ...I .. 1 .... ... 4 4 F 4 . 4 . 1 4 . -1 144 . .. 14 .... ..... 4--- ,-Ar-- -- ...

K - I .*,

(:,'() 58I

C 0 - I.,')

R.. U - I'

CI .3 13-1

B(. 1. 4

CE 1 :.

1 ' .. 2 i.. J.4.(0f

'3 1413E02.5717E+00I (I.'.

6.2342E+0.2.1499E+00

8.858B~IO

6:. ,r' 0.' .:L',I~ i--..I(,f * .'Jf)

:1.90E0

2 1 (.)7 F66 .,,. 0~

A, 1060W.

Pc:.1: :'J Va luej: .v. ::c, :'~ 1* .42U:.v~ : / I

A Activity < 11.,01`1

ITTA ACT(iI. U:F:r .IV ITY 60.1 to',:: 202:4.4 .k y ) :,@f Ij @I: 'nt C:i/l.::T']fAL, DECA) fYEID ACTIVIT.. .Y (~ 60. 1. to:: 2264.4 Vc ) ), 6666+6 i:. / I.FR

"i- U 11 11, R. Y 1) 1 'E' (I' A .'D i )

:1~...'i. 4 l(:,`F 16, A" F : 1 4 :1* . 8I '3 0 II, :1

I 1'I .: 3~1454.4 It It 477.61 B:

1i )::14 -1031i 4 '4: c i44~.:.4 i ~..t ~,:)V U

-A~* 44. 4 )(- I . 4. ) .4 IX (. 4 '- )(-)4

83 ,,~4. 4 & )' 10KA f

0higher than COUnting LOWIWtaint)" range,,

9 E,:C-386 ORTEC G k? -- I ( 175) WAME 14WOR.96 11-OUT ..... 20(,D7 PapeEK-o v J. 3: -1 -.1 f.: : ".' ý"' 1: ) ý--. -.. (: .. ' L: -(' k. k I -I -i -i -'i a i -, i E--ý :: 61, 7 (.*,'7 2 ýý (*,'t',--i :1.

1,

"1 1 " , , . .. " H1 :200".,i~i•l:' ";2 (Y; 1::. 1 ]5 f;A!lyl`.-

(1 q

(.c -tJ a-11J. - Ifjostart :1

Li e i...Rea tim.

-I ~ :1

Creaedu 4'IMar-200h~7 M2. & 15-Nar.-2@(:7 WHOM

if .fit.

Fwa sewi Sastvt;

Acivt scaling factor

2. 1. i1 I.)

4048 for an energy of& 1. 0 1. .-. e Y

2024. 36kebi

3.50, ý

N IMOOE+00

~1.000000LMOAddit: ional*i sytematic Ii C' 0 1.000000017+0Frcto Li i : .1 000'x" 1.

CorrctinshC~C

bkg2!. 4 121.

<I Io 1 -11 s ý.k I-, 11,1.1 J. I I NOI

0li::.36.6 o1RTIi:(:r v' -r <1. 175 WAN432 1W296 :ti* C* 2iiT 3 15-~ 41-53~En -vi r1 con y-, on I T'.::: 4 ,.. n n i : .7 7 ,

21'

Energy ca .:.lb rat o normal~: Y;~ .:. ~'1 : 3 44ecn :1. . 000

44444444.44:444U4 14~. 1 F: E N i T :FI E0 1 Ii: P ' I.3 LJ '4' 44.4 A:" R4 y 4444

. . .......... ......... .............................. .... ........................-. 4........ .. +....+.... ....

702'3' 3 35:1. ,!.'.; , 1.9,, :L ,, :1. :1..@ )E+04 30., :10 I 368 CE-10... 41021.721 51"' 0:.9,, 4 65. 163. 1.861E+0. ,, 11 2. 51 TI

D e l:. '";., i .... h .':p :., "'•,,s s ,

1) 1)ff E N T I F I E D cP E A.C: j.3 U 'l Il A~ r-,' Y 44.444.43444444

111.1'T, E1-.4 S T -1 Y UH *I.ý::,.: Ftl'1.7

4.-..--.-.....÷.-.% .. -....,....+ -... . .. -. .. .. .. . .. -'. .. 4...-. ..... ... 4.. ...--....- 4.-..."-".................................4.......4.......................4................4..........

BA' :1 -4 0

LA 140

4. . 0 43

CS- 13

z 9'' 15

655.24

99.4.83I

:1. 2' 244

614 .

144.60

.04.89,

327.7363.5~'4

6I 3 7. 1 I.

"4 , .45

:1 4438.

98I'.

91,

:17

3',.

14.

31

4,.

2i

'4

:1. 0.

It.

44..

F: @2

42:442.)?

4•) 4.~4 /~ :1.

F~ F'C*) F)iS~

(4] 424 4~)

(43 42'I 4.44

:14.;:) 444

4. f*4(4'I11)11

4,4,4'

~.ir~i4)1 ii)

44)444

:1.

:1.4•)

F)FLI.I•4 ~:1 '1,

4.~i)

2 41.

:1. 1`3 1. .

: 1.0 1. 4 .. 4*.

.8

1 44.

14.4 '

4I 4'e 21

Iff2.). W

9, 0

2.

85 Vi.

27, 4':'

00:1.,

ORTFJ:', V I ( J."75) WAN3E 146102.96 11-OCT

IJJ ~ ~ "3 U' 1y ilj (::-r>1 R Y, (:. F :,~ f . ' ~ aiJ'(i 1"1 1::' L E

pC i /L IT El:,,' p :iLITF !

*44-:**, ~44*:4 ~444 ~ *~*44*4*

CO5

( :(3 (1.

Z N

z -% .-9 .ND-15

1. 9922E+1'

.3 i 5 9 : 0 0~

421:.22E0

2.3582E+01.

f .106- 5G2E ( ff

1- 344+0-

1. 1210.3 ~ );

It. . 6:3,A02

UNDfJ

IYIDA p r .1. 1 -11., *,ý dA Activity pTinted,

......... .... ............... ........ .......... ............. ........ ... .... .... .... .... lyl 0 Y .... .... .... .. I ............. ........... ....... .....................

6(-ý). :1. to 2024. 4 keV) 0,. pf:ý'J. /1 :1: 1, IH: F,TORM. DECAYED ACTIVITY ( 60. 1 to 20R4. 4 keV) 0. OOOOOOOE+00 142 /L I TEI:,*,'

U 17 I'll .3.3

636. 9

01' ýi - F'.. 1) [

I I I .t 284.3

1-3 477.6a h

BA- 140 604.70

1-3 66 66NB91 795.84

FE-59 .115.5CO-6 I 4)60~.8 1

I)

V

F, F A2 1K

1-13

,II r

I ('t' 14

(11- 1C(3 1~ (I I) Ii)1561 %f LA14

Peki Par Of a~ n.'U.jt........ an sae et.

neatv dur '1III~*iiC) -I I

:c-&c'M8 k FC*J:,.TI.: (* V -* I: ( 175 WANR:~~~ 14:: 9 06-O~C'T-2007 1¶50031 Pagi~eFi n Vi .r O rge 1. taln 1.-1 ic , : ru 5."-49, 3 ,. ri-1. :1. 0

T L4,J~'~.i:

F'J.J. 1-1

~0~

Rea time/ 3I c'~

06-et-0071:1.44034

~121

Caibration

:19hr20 11:90 & rMr20 1N45.i*

11C.3 42,3in NMiiJ ,' I.1I iI:.J.cl wj.-te J.- Ii -i 1 .1 Fci : '*1B* . o Ž .3 :

Zero'~: offse~t:~ r:.7 ke).3v;~ 1, V 1-1 -1-1 n

STarI C.. I-

Pea reeto lee

Peakl ntn :-,nn'v I*Sampl Siz::

2. 1 i b

12.) for of 6, 9 **' * :1. 1. -...

3-31

Additoa sysemti erar 1.00 II000IO:'f :OO

:1 m 1 :i. ;).. Li i : :. 000%j~Z.~ p:

FcPeaked'1'

b s' r n C h- T.,S r:: -I-- J

Yf E

CommentsI I~~) :.3(~~

0M..::

ivy ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~~~: :1. 0' E4r i-S: ec: "l 1.~u 543.~n r::.

Evierily :1. .. CDC"JOC)

ii~~~~~~~~~ K; `3) U~. ;::;I; Irl Ax Fj Yi p : :. \ ~ 44.44.44.44

(2t..I(.1pIi ~ ~ ~ItIIE ARE.11 C',"I' EKC SD).J Us $:. P'.n E C. T Et.4 Ii ~; ~~y tts.DL

121. 6 j x 1ý 1, 6~1 0 f.*' 7 0iI)J.,,99:1. :1 ,2.il4 92 E 4

J1. J. '4', 2 8-, [:., 04 '4.3.33 1., 8_391::'B.2..pj4

'.?3, ':'4 l1. '. XL' :1. 3K I

4:4.3'. 14. 4 4~4 d CI 'C~ ii v it.'. 13: ci

.44.4.1 144 T F, T' 44: *i) 1,:, V* A V, :~ ... ~ y x~ Iv; x Y '**. 4.4 ' 444 W 4.p.?

J.- .... ..-rl.. e ...... + ..+ . .4.... .. . ... f ..... .. A ....... )...... ..

I A 1. 41 :1. '3

t:I': 1. 40

0i.3I.

FkIt 1 0 1...,

1:I: ......i5

CO

C. 4

I'D

5i C.) 44

.4

9 8j 9~J..

CA

1I 4 4ý 8 /

:1. 1 ,5 .3 1

J.14 G.2 l(

I I.

258,-3. .4JO

:1.t4 4

0 ..c ,

4 ',' 41

6(D .4 "'1, 0

O l"11 -

,C'.. 07

41

8 :' I I'

F 2'

.44

.1.0

9 1.511I)"

0'

J.

0 C.) 0

0: 1.

.001.

D1.

G-! (.73 J.4

(D0:1.

0(511.) '..

(". CD

:1 '33'' C.4!*.* C.) 4 0

21. 9. 8

529:1.

2' 1.08

24.1 44

t, 1,.(.) . - 1'l

6ý7., 84

2 2. i:*! 4'

1. 0

(-D (D 0

01, 0~'.

1.:1. 22. :

71 :

Dll

f" 0 0

2 ,:

0 ................................

C G&G EC:II: E C - v y ( :V/5 1A: A if:I'l '1'4 ,, (.: j 1E .9 ;* C.-j0(:OC :1. 5:1 !::' C:iC1- r* o)f nm e~ 1 1,1C.p*:? :- t f- II n fl5fW /4 :: 1.

3.

.y.~ U~ I'l II l (.1 F1, YT C F, U C,: L...I S (11 lyl F, 1 1"::.,

2 ý.3*1.*Glyl('i

p(-1i! L.TTF.R p .J .. /LT *:i:

ý- I- ..) . A. ..-- .4. 1- .-1 . ) . I'. -. -1 ...... 4 ..... .. I- -.-. T. ..-- + -..- .4 ....... I ..... 4. -- .1. ...- 4 ....... ..... .. ý-.- J, ...- 14. t ....... ý- .- -1 ....... ..... .4 ....... ý- .... .4- .... .." ...... 4. ---. -4 ....... ý- I... -§ ..... .. ý- .- 4. .- .§-

1I 4

C'i 0 8

Nii K3 IR~~ U (-Ki

T 3:1.

Cf :1. 4 :1.

:7:41. 4.:3 r Fr. I

2. (I /

!.59 1:2 8r~ E. E

4 -E

:i-I...) 7 ,7,A 1.4.C

1. 4:1.

71 4'1. Ar 1-* r,. + QJI.?:r

4*,',`8'.I.~I:*..0

8 1 J .

T0T131.. ~ ~ ~ ~ ~ ~ t 0) ""~3I:3)n: ~ ~~( (~ j. .1. ,, 4 1- V ~ 0 F, flj3 Ffj'..ra~ f:.

3C3I~~~~~4bIC~1 F,'34 F, . ** C ~ ) 3~ (.4 1,1%

1. PI 14'? 4.jfr .1' 30 4I*' 1 . C.A.(

1~ 5lsr 51 :fcc':o. . i:

J. . 0 . 1 . :1." :" 3 c~ .1. 0 ' 8 :1. 1: 1 s :s s

3 14 BA 1. 'Ile

0. '.3 RU :1

0, .i' 58i

S

EG&G ORTEC 0 U I ( 175) WAME 14WOE.96 WAXMT007r Q V1 Ill e c 1., r k.t 1-11 1-, a s ý.'Y'76-79.

:1

1WIA :i". Ii T TEF

o vlý-. : ;i:.r"Ii-..0 *. 1.s"1 lI132, ::~~ /0"

Dei~tecto syte

MI 5 ipu

Cal .ibraio-

Activ;ity sclig ato

f`or jVI'l (:...-f :H-.*.-'jI.ý.eV4048 for jai energy of 2024.36keV

30.000%

3. 5M."iI.OOOOE+06/( 1-

F'ractio: Lits

Bcigon wii~t idc ths bes meho (base on spec It~;trum).

I Dea duin acusto

D x c" -y d f'J.n c:: -oll' ci o . -

Peake ý: : :~:i ifvc I..i ci cfm V r x: 1.:

!..l*iYiENE)

3:;.

k.1 L", C)I I I G. T. 11 U1 ' . .' O e L ; j ~ (: ' C ' T 3 2 3 I. -I: II t .( .. 1 -. 11 n ! 1I

EGOOTE -- I3 (m 175) WAN3 1 HfO.::' -C 1 :647Pg

Envr onmentall:3I: Inc.,':: 3 ;: r~~ ; 1s( . 1 ? ra

Energy :3 ca..lbat'I: ion~s' C nrmal s . i.z ed di f f (.- reI- 1. t.'10

PEAK4(43 ~s CENTROUID1DENTIFIEDBACKGROLIND NET AREA

P EA P

EFIIW

13i~ U 11 11 1) * 3 cY ******

58356

MR.7 853

1217 W

29.2 :1..31.

:4.

151.

17.1. ,475E+0)4

4 Ž I

320

2. 2,34:1- TM3 PB-21.4

2. IE24 BF-214D)

T i~~ '.::v. V.. c:1. LAt ~:.s (:~:. :; )~ 1:,b ** : a I

I D E N Tl 1ŽN1~F 1E )

BA: 3 ( l 0 i'. I ML J11 *ýi'

S U I'l I 'l R. ( Y x.T -x -x, )(. -.- 5 .3s -)..3~ N3s. .3 M. -X- *3 X*3

f. +3 3 . 3.+3 .- -f -f f f- -+-f f-+-f -+- f f - f 3 a14-011-131

1-31 L

f.4:1 .

1,1% 1 5 3

655.213

(730 5.0

952 59

:1 fI.. -4 5 " 0

2 2I(ij 0

23 5 0:

6 ' 3.

36.5.03

47~s ("1*i1' 8

485. 84

.4.

1. 1 1. 2

J.5

: 3 4 0

51.

91,

613

:10,

Z.-

0.3

00:1.

Qi3,4 11,

0:.

2I .3 is1

( .('i, . , 0(

..

C'5 539

.82.

3 G.f

.K)

7,3

583:.

W

0a5s33 C : 1:s:::::,ý ': ol

0R"f'F:C V J: :I: Z., W 0 9 :1. -'3 0 C.' T M"'.107o rw)) C.-ý I--,

.~~. L4i 41. 1114~ A.. FR r Y 0 F N U C L.. I D) E~ 13 1 ]-,R~ S¶~IGM

A.* A.~

FI: 59

z I- .61*,.*

:1 .13 :1.

o B134

< 2 8308E+ I

0~r 0

9 :.()F (' .;

<1 i:

< (

ON4 222:*j'41Ž11+01.

EN.4' 5163 (,''

1. 158E+:1.it 809+01

T0.L to 20 4. ke) pi Ci "I I C r I i

TWAL.~~~~~~~~~~ XAMYE ACIIY 6.1to R2.4kV j '-F:

'3

621.8 9

834.8 X

1, 91. 0C

S U MI'I

RU- 10P."1

MR-54

FF". "'J J.IJ

I~~ ~ C0.~:.~C

1115 55 4 C10 I 0

a7 J44 3 . l::I I-. ci w :* J. d : a F 4C; , 1 b ..3: (3..I; I:FIAJ I- -I Y

. ......... ....... ":'.-...

- .. Envirbnmental, Inc.Midwest Laboratoryan Allegneny Technoiogies Co.

PRC-33Form LS-4 Va-. 10

ThJTRLN4

Counter ID.

LSP-2000C-A 1

LSP-2-350TRI/AB _

LSP-2800TR

!nit. & Count Date: P i (' / i / < /C 70.10032g STD T-36

BKG BKG Sample STD STD STD Date

Time Counts Time Time Counts ActivitP Issued

POg1 0 0 0o75? 1002.78 010/18/2001

Sample ED Volume Sample Remarks

(ml) Counts

C -756G- G s 7___ _. _ _ _,67 qC• 6

.... 61-0 CD0

I _

C7v f -I j 71]9TZ 6 Y- o7C~ ___ ______ ____

______________________________ ' _________________ _________ -___- _____T1 2 _ _ _ __. p.• ./q~

Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.PRG-33Version No. 1.0 06/17/97

Programmed by Rick Lesko



Background Counts:


For any sample counted on the LSP-2550TRI/AB,LSP-2000CA or LSP-2800TR Reviewed and Approved by t A

Date approved: I , I Y I

100

200

1081

Standard Count Time (mmn.):

Standard Counts:

200

60733

0.195


Calculated by: Rick


Sample Coll. Vol. Sample Corr. pA i/L 3.00 4.66ID. Date (ml) Counts Factor Activity Error TP.U. Sigma Sigma

TWW-6760 9/25/2007 13.0 543 0.996 4.447 ± 101.463 101.464 124.075 192.729TWW-6761 9/25/2007 13.0 734 0.996 344.227 112.750 122.082 124.075 192.729TWW-6762 9/25/2007 13.0 758 0.996 386.922 114.089 125.639 124.075 192.729TWW-6763 10/1/2007 13.0 819 0.997 494.981 - 117.316 135.258 123.960 192.552TWW-6764 10/1/2007 13.0 744 0.997 361.683 ± 113.205 123.430 123.960 192.552TWW-6768 9/28/2007 13.0 494 0.997 -82.683 ± 98.313 98.954 124.017 192.640

__ =Best probable result.

- . . Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.


Sample Count Time (rmin.):


Background Counts:


For any sample counted on the LSP-2550TRI/AB,

LSP-2000CA or LSP-2800TR

Date approved:

100

200

1081


Standard Counts:

200

60733

0.195


Calculated by: Rick


pCi/LSample Coll. Vol. Sample Corr. c + TU. 3.00 4.66

ID. Date (ml) Counts Factor Actvity Error Sigma Sigma

TWW- 6835TWW- 6836TWW- 6837TWW- 6749TWW- 6750TWW- 6751TWW- 6755TWW- 6756

10/5/200710/5/200710/5/20079/27/20079/27/20079/24/200710/2/200710/2/2007

13.013.013.013.013.013.013.013.0

483441535762569588657569

0.9980.9980.9980.9970.9970.9960.9980.998

-102.133 ± 97.498-176.734 ± 94.741

-9.769 ± 100.807393.916 ± 114.27550.685 ± 103.04084.513 ± 104.248

207.025 ± 108.22450.646 ± 102.961

98.48397.742

100.816126.210103.270104.880111.827103.191

123.884123.884123.884124.036124.036124.094123.941123.941

192.433t" 192.433c3 192.433

192.670192.670192.759192.522

• 192.522

=Blest probable result.

Environmental, inc.Mildwest Laboratoryan Aileaheny Technolopies Co.

PRC-33]Form S Ver. 10

TRITU7-NmLýSP-29000C0A"ýZ

LS?50OflIIABJ

LSPI-28007R COUf~J~

ri~it. & CounttDate: Z C- I I /I ,!-/ 070.10032- STDI T-36

- Environmental, Inc.Midwest Laboratoryan Allegheny Technologies Co.

PRG-33

Version No. 1.0 06/17/97Programmed by Rick Lesko


For any sample counted on the LSP-2550TRI/AB,LSP-2000CA or LSP-2800TR Reviewed and Anoroved bv:



Background Counts:

100

300

1146

Standard Count Time (ruin.):

Standard Counts:

100

Date aooroved: -

Date Counted:

Calculated by:

Date Calculated:

28457

0.185

11/5/2007

11/6/2007Counter Efficiency:

pCi/L

Sample Coll. Vol. Sample Corr. Activity Error T.P.U. 3.00 4.66

ID. Date (ml Counts Factor Sigma Si m

TWW-6761 9/25/2007 13.0 632 0.994 472.475 ± 104.156 122.382 110.813 172.130TWW- 6762 9/25/2007 13.0 610 0.994 430.898 ± 102.636 118.188 110.813 172.130TWW-6763 10/1/2007 13.0 839 0.995 862.889 ± 117.390 165.988 110.711 171.971TWW-6764 10/1/2007 13.0 598 0.995 407.842 ± 101.704 115.846 110.711 171.971TWW-6836 10/5/2007 13.0 330 0.995 -98.124 ± 80.708 81.804 110.643 • 171.866TWW-6749 9/27/2007 13.0 582 0.994 • 377.864 ± 100.638 112.999 110.779 172.077TWW-6755 10/2/2007 13.0 460 0.995 147.254 ± 91.505 93.671 110.694 171.945

=BCst probable result.

S.Q

ERM has over 100 officesAcross the followingcountries worldwide

*ArgentinaAustraliaAzerbaijanBelgiumBrazilCanadaChileChinaFranceGermanyHong KongHungaryIndiaIndonesiaIrelandItalyJapanKazakhstanKorea

MalaysiaMexicoThe NetherlandsPeruPolandPortugalPuerto RicoRussiaSingaporeSouth AfricaSpainSwedenTaiwanThailandUKUSVietnamVenezuela

ERM's Boston Office

399 Boylston Street, 61h FloorBoston, MA 02116(617) 646-7800(617) 267-6447 (fax)

ERMERM consulting services worldwide www.erm.com

Oavis-Besse Nuclear Power SlalionFirstEner5501 Noh Stae Rout 2Oak Harbor, Ohio 43449.9760

September 18, 1998

State Fire Marshall OfficeMr. Charles Zepp6606 Tussing RoadReynoldsburg, Ohio 43065-9009

Dear Mr. Zepp,

Subject: Underground Storage Tank Overfill Release Report; Incident Number 6281145-00

The attached 'Twenty-Day' report is submitted to the Ohio State Fire Marshall's Office in accordancewith Code of Federal Regulations (CFR) Title 40, Subchapter I, Part 280, Subpart F-Release Responseand Corrective Actions for Underground Storage Tank (UST) Systems Containing Petroleum orHazardous Substances, Section 280.62, paragraph (b).

The report is submitted in response to an August 21, 1998 notification provided to the State FireMarshall's Office of an overfill release of ajproxrimately, 50 gallons of diesel fuel from a registeredUST at the Davis-Besse Nuclear Power Station. The UST is unique in that the tank is actually anabove ground tank, however, it is registered as a UST because the tank is totally enclosed in an earthenbunker for missile shielding protection. The UST is part of an emergency generator system at anuclear power generation facility regulated by the Nuclear Regulatory Commission under 10 CFR Part50.

The written report is the twenty-day follow-up report required after a release confirmation from a USTin accordance with 40 CFR 280.60 (b). The initial response and reporting requirement in accordancewith 40 CFR Part 280 was confirmed by the Duty Officer(s) of the Ohio State Fire Marshall's officeupon the verbal release notification. The report is included as Attachment 1, Twenty-Day WrittenRelease Notification.

Additional correspondence from your office dated September 1, 1998, was received by the Davis-Besse Nuclear Power Station on September 9, 1998. The release response cited in the September 1,1998 correspondence was for a %suspected release', as defined in accordance with OAC 1301:7-9-13(B)(3), however, the release was a confirmed 'release' under actions of petroleum product transferspecifically defined in OAC 1301:7-9-13(B)(2)(b). Furthermore, the release was from an emergencygenerator system at a nuclear power generation facility regulated by the Nuclear RegulatoryCommission under 10 CFR 50. Due to the nature of the release and the tank system, the Davis-BesseNuclear Power Station does not agree to perform the activities referenced in OAC 1301:7-9-13 (D) and(E). However, excavated soil from the UST upon remnediation or closure will be managed as

SPage 2

petroleum contaminated soil (PCS) unless laboratory analysis indicates otherwise, and a "SoilDisposal/Treatment Notification Form" will be provided to your office for PCS disposal activities.Reference Attachment 2, Response to September 1, 1998 Correspondence, for information addressingthe supplemental request for actions.

The only remaining documents required in this matter are the twenty-day letter included as Attachment

I, and an agreement to provide the proper documentation to your office upon PCS disposal activities.

Per your request on September 15, 1998, a photograph of the tank bunker is enclosed-

Should you be in need of any further information, please contact Mr. Greg W. Gillespie,Superintendent-Chemistry at (419) 321-7268.

Sincerely yours,

C mes H. LashPlant ManagerDavis-Besse Nuclear Power Station

KNM/bkk

Attacmunents

cc: Lowell Johannsen, Carroll Township Fire DepartmentD. F. Petersen, Ottawa County Local Emergency Planning Committee

ATTACHMENT 1TWENTY-DAY WRITTEN RELEASE NOTIFICATION

This report is submitted to the Ohio State Fire Marshall's Office in accordance with 40 CFR, Part 280- Technical Standards and Corrective Action Requirements for Owners and Operators of UndergroundStorage Tanks (UST), Subpart F-Release Response and Corrective Actions for UST SystemsContaining Petroleum or Hazardous Substances.

The written report is the twenty-day follow-up report required after a release confirmation from a USTin accordance with 40 CFR 280.62(b). The initial response and reporting requirement in accordancewith 40 CFR Part 280 was confirmed by the Duty Officer(s) of the Ohio State Fire Marshall's officeupon the verbal release notification of an overfill spill of approximately fifty gallons of diesel fuel.The notification was provided to the State Fire Marshall's Office on August 21, 1998, in response to anoverfill spill from a registered UST at the Davis-Besse Nuclear Power Station, Oak Harbor, Ohio.

This tank is part of an emergency generator system at a nuclear power generation facility regulated bythe Nuclear Regulatory Commission under 10 CFR 50. Typically, USTs are underground storagetanks, however, this particular tank is a forty thousand gallon aboveground tank which is registeredwith the Bureau of Underground Storage Tank Regulators because it is completely enclosed in anabove ground earthen bunker. The earthen bunker is for missile shielding protection requirements ofthe emergency generator system.

The release was an overfill as defined in accordance with OAC rule 1301:7-9-13(B)(2)(b). Althoughthe release was not into any nearby surface water nor released into the environment, the notificationwas made in accordance with Ohio Administrative Code (OAC) 1301:7-9-13(C) because the releasewas greater than twenty-five gallons and due to the nature of the security and integrity requirements ofthe tank and earthen bunker, removal and clean up of the soil in the spill area would not occur withintwenty-four hours.

In accordance with requirements of the twenty-day report, the following initial response actions wereperformed in accordance with requirements of Part 280.61, paragraph (a), (b), and (c), respectively:

(I) The release notification was provided to the implementing agency (State Fire Marshall Officeand Local Fire Department) within twenty-four hours of the release confirmation.

(2) The release originated from an inadvertent overfill spill occurring during transfer of fuel intothe tank during performance of a High Level Alarm calibration activity. Once the overfillcondition was identified/the pumping of fuel into the tank was immediately terminated. Theoverfill resulted in fuel spillage from a vent pipe into an overfill drum stationed under the ventpipe, and on the top of the tank bunker. The spill area was contained to the stone overlay andearthen bunker on the top and a small portion of one side of the bunker. Site emergencyprocedures for spills were immediately activated. The spill area was immediately investigatedfor spill assessment and extent of release. Visual inspections verified the release was a soleresult of the overfill and no further release threat to the environment existed from the tank. Noevidence of runoff to any other ground or water system was identified during the initial visualinspections and assessments.

S(3) The overfill product drum was appropriately closed and the work was terminated. No runoff to

any other ground, groundwater or storm water system was evident, and no other free product,fire explosion, or vapor hazard was present.

The following initial abatement measures and site checks were performed in accordance with Part280.62 (a):

(1) The initial assessment and incident initiator of manual overfill verified that product removalfrom the UST was not a requirement necessary to prevent further release to the environment.Additionally, periodic tank integrity testing has verified tank tightness. No other threat ofrelease was probable or identified.

(2) The type of soil surrounding the tank back-fill is clay substrate prohibiting the threat ofmigration into the ground or ground water. Visual inspections of the storm system area drainand out-fall verified that the fuel overfill was not released or migrating into surrounding soils orground water, therefore, actions for further prevention of migration were not applicable.

(3) In accordance with physical characteristics as described in response to paragraph (2) above, noadditional fire and safety hazards posed by free product migration exists, therefore, monitoringand mitigation are not applicable.

(4) The drum of overfill fuel generated from the vent spill has been removed and properly disposedin accordance with station and local requirements. The top layer of contaminated compactedstone overlay of the earthen bunker which is not removed (due to tank shielding integrity) willbe bioremediated and managed in place and properly managed at site closure in accordancewith the applicable state and local requirements.

(5) and (6) In accordance with the incident description in Part 280.62 (a), the location and amountof the release is confirmed. Noadditional measurements or free product removal activitieswere required.

The initial site characterization information as required in Part 280.63 (a), is provided as follows:(1) The nature and estimated quantity of the release was approximately fifty gallons of Number

Two Fuel Oil originating from an inadvertent overfill during a High Level Alarm calibrationactivity. Once the overfill condition was identified, the pumping of fuel into the tank wasterminated. The overfill resulted in fuel spillage from a vent pipe into an overfill drumstationed under the vent pipe, and onto the top of the tank bunker. The spill area was containedto the stone overlay and earthen bunker on the top and a small portion of one side of thebunker.

(2) The climatological conditions were clear and fair at the time of the release and are notconsidered a factor in the release occurrence. The site meteorological data indicated a windspeed and direction of 5.65 miles per hour from the SSW (219 degrees) with 0.00 inchesprecipitation. The Davis-Besse Annual Environmental Operating Report (ABOR) wasconsulted to determine the following land and use characteristics of the area: soil conditions,water quality, and surrounding population. The Davis-Besse Nuclear Power Station site ismainly comprised of back-filled clay substrate with a small portion previously used forfarmland. The surrounding area is mainly farmland or marsh and is sparsely populated. Asreported in the AEOR for the facility, the 1990 census indicates the population for incorporatedcormnunities within a 10 mile radius of the site are: Port Clinton, 10 miles southeast,population 7,106; Oak Harbor, 7 miles south, population 2,637; and Rocky Ridge, 7 milessouthwest, population 425. The type of soil underlying the site back-fill is clay substrate which

southwest, population 425. The type of soil underlying the site back-fill is clay substrate whichprohibits the threat of migration into the ground outside of the site by runoff other than storm orsewer systems. The on-site storm sewer run-off for this area drains to an on-site holding pondand is routinely monitored. Site investigations verified no run-off to surrounding lands orground or water systems occurred as a result of this release, and no subsurface or local wellsare potentially affected by this release.

(3) and (4) Not applicable, reference response provided to Part 280.62 (a) (5) and (6).

Part 280.64, Free product removal activities are not applicable, reference response provided to Part280.62 (a) (5) and (6).

Part 280.65, Investigations for soil and groundwater cleanup, gre not applicable. Because the bunker ismissile shield for an emergency system at a nuclear power generating facility, no borings were taken ofthe earthen bunker. Initial assessments performed at the time of the overfill, and re-verificationinspections performed prior to initiating the required 24 hour notification to the State Fire Marshall,validated that the spill area, ground and surface water storm runoff systems had no evidence ofaboveground release, noi did a threat of release into surrounding soils and groundwater exist.

Part 280.66, Corrective action plan, and Part 280.67, Public participation, are currently not applicable.Responses to these sections are not part of this report.

In accordance with 40 CFR 280.62, the report is due September 21, 1998, or twenty working days afterthe incident occurred.

ATTACHMENT 2 SRESPONSE TO SEPTEMBER 1, 1998 CORRESPONDENCE

On September 9, 1998, the Davis-Besse Nuclear Power Station received correspondence from your officedated September 1, 1998 requesting response actions supplemental to the twenty-day report submittal inaccordance with 40 CFR 280.62 required by the Duty Officer(s) at the time of notification: The responsecited in the correspondence dated September 1, 1998 was for a 'suspected release', as defined inaccordance with OAC 1301: 7-9-13(B)(3), which required tightness testing results within 10 days of theincident and site check results within 60 days of the incident in accordance with OAC 1301:7-9-13 (D).Actually, the release was a confirmed 'release' under actions specifically defined in accordance withOAC 1301:7-9-13(B)(2)(b). Furthermore, the release was from an emergency generator system at aNuclear Power Station regulated by the Nuclear Regulatory Commission (NRC) under 10 CFR 50. Dueto the nature of the spill and the maintenance and integrity requirements for the system, the Davis-BesseNuclear Power Station does not agree to perform the activities referenced in OAC 1301:7-9-13 (D) and(E). However, a site assessment was performed in conjunction with the requested twenty-day writtenreport in accordance with 40 CFR 280 (F) and is included in this correspondence (reference AttachmentI).

In addition to the written release response requested August 21, 1998, the following information is alsoprovided for actions requested in your correspondence datedSeptember 1, 1998.

(1) Regarding the tightness test referenced in OAC 1301: 7-9-13 (D) (1), due to the nature of the tanksystem, periodic integrity testing of the tank system includes tightness testing, .and.u.rent testing.._results verify the tank is of sound integrity. In addition, the cause of the release was visually andpositively identified as an overfill spill in accordance specified activities listed in 1301: 7-9-13(B)(2)(b) and was not a function of the tank integrity, therefore, additional tank tightness testingwas not warranted.

(2) Regarding drinking water well analysis referenced in OAC 1301:7-9-13(D) (2), in consideration ofthe nature and extent of the release, visual inspections and assessments performed at the time ofthe release, and the physical characterizations and distance of the release site in relation to anysurrounding property drinking water wells, more than sufficient evidence is provided todemonstrate that the release will not impact a drinking water well on a nearby property.

(3) Regarding the site check in accordance with OAC 1301:7-9-13(D) (3), the nature and functionalrequirements of the tank system and inherent bunker shielding requirements prohibit borings onthe tank earthen bunker. Additionally, site investigations and the nature and extent of the releasedemonstrated that migration of the spill did not occur.

(4) Regarding action levels referenced in OAC 1301:7-9-13 (E)' (3), as described in response (3)above, no borings were performed, therefore, comparisons with the action levels based upon SiteFeature Scoring System (SFSS) were not performed. The SFSS work sheet is not included,however, the SFSS is estimated as 70 based upon scoring system in section 1301:7-9-13(D) (3).Site details as listed in response to 40 CFR 280.63 (a) of Attachment I detail the sitecharacteristics.

(5) Ihe UST is part of an emergency generator system at a nuclear power generating facility regulatedby the United States Nuclear Regulatory Commission, and is exempt from OAC 1301:7-9-07 (E).

(6) Excavated soils will be managed as petroleum contaminated soils (PCS) unless laboratory analysisindicates otherwise, and the soil will be properly disposed in accordance with state and localregulations. A Soil Disposal/Treatment Notification form will be submitted to your~office asrequired for PCS disposal activities.

S

i!e~4-Y j4ZoVaJ~S

-~ ie~~sr iJ

,14 1S c'6/'ýeS4.~.,.

~ ,'~,

CENTERIORENER~GY

300 Madison AvenueToledo% OH 43652-0001419-249-2300

Louis F. SlorzVice President-NuclearDavis-Besse

RAOG 94-09

February 22, 1994

Timothy 0. HickinEmergency Response Unit SupervisorEmergency Response SectionDivision of Emergency and Remedial ResponseOhio Environmental Protection Agency1800 Watermark DriveP.O. Box 1049Columbusy OH- 43266-0149 ........

Subject: Submittal of Information Regarding Spill of GasolineIdentification Number 01-62-0180

Dear Mr. Hickin:

In accordance with Section 3750.06(D) of the Ohio Revised Code and Rule3750-25-25(A)(2) of the Ohio Administrative Code, enclosed is theinformation on the onsite release of unleaded gasoline at the Davis-BesseNuclear Power Station reported on January 18, 1994; spill eventidentification number 01-62-0180.

Should you be in need of any further Information, please contactMr. W. T. O'Connor, Manager - Regulatory Affairs at (419) 249-2366.

Sincerely yours,

JCS/lkg

Attachments

5-S

cc: M. Gerber, Ohio Environmental Protection AgencyLocal Emergency Planning Committee (Ottawa County)

0Operating Companies:Cleveland Electifc IllurninotingToledo Edison


TOLEDO EDISON RESPONSE TO OHIO EPA SPILL EVENTIDENTIFICATION NUMBER 01-62-0180

JANUARY 18, 1994DAVIS-BESSE NUCLEAR POWER STATION

1. Reporting and Event Summary

Question:

a) Time, date and duration of release or discharge.b) Time and date of discovery of the release or discharge.c) Indicate the Ohio EPA spill number and the National Response Center case

number.d) Provide an event summary.

Response:

a) The actual time, date and duration of the release is unknown. Therelease most likely occurred between approximately 0300 hours on

-....- January-16,-1994,- (the-last recorded-vehicle refueling) and.1130 hours-January 17, 1994 (the first recorded observation of pump malfunction).

b) The actual time and date of discovery of the release of gasoline wasapproximately 1800 hours on January 18, 1994.

c) The Ohio Environmental Protection Agency Spill Response Number is01-62-0180. The National Response Center Number is 217385.

d) On Monday, January 17, 1994, approximately 1300 gallons of gasoline werefound missing from the above ground gasoline storage tank at ServiceBuilding 4. The gasoline is used to service site vehicles; pool cars,snow plows, etc. On the morning of January 17, the gasoline pumpappeared to be malfunctioning. Gasoline was pumped from the tank andabout eight gallons were pumped and the flow stopped. The storage tanklevel was checked and measured approximately 100 gallons. Themeasurement of the tank on Friday, January 14, indicated approximately1470 gallons with 88 gallons being dispensed over the weekend. The lastgasoline was pumped from the tank on January 16, 1994, at 0300 hours.

Industrial Safety and Environmental were notified of the missinggasoline. The site was checked for indications of a gasoline spill.There was no evidence of gasoline in the concrete dike surrounding thetank, or of any amounts around the gasoline pump or inside the pumphousing, or in any of the areas' storm water outfalls (i.e., marsh orponds). No gasoline odors were present. Security was notified forpotential theft investigation.

On January 18, 1994, the tank and underground piping to the gasoline pumpwere pressure tested with no evidence of any leaks. The gasoline tankwas partially filled and the pump was tested by pumping gasoline throughthe pump. When the pump was stopped, gasoline was observed to besiphoning through the gasoline pump fire safety valve's atmospheric vent.This leak path was established when a diaphragm failed in the fire safetyvalve. This confirmed that the gasoline had been released to theenvironment, not stolen as was previously suspected. It is suspectedthat the fire safety valve's diaphragm failed due to the extremely cold


weather on January 16, 1994, and at 0300 hours, when the pump was lastused, gasoline siphoned through the atmospheric vent until the pump'ssuction was uncovered (100-gallon tank level).

At 1800 hours on January 18, 1994, notifications were made in thefollowing sequence: the National Response Center, the State EmergencyResponse Center, and the Ottawa County Sheriff's Department as requiredfor the local fire department and local emergency planning committeenotifications.

At approximately 2120 hours on January 18, 1994, the OEPA Division ofEmergency and Remedial Response representative arrived onsite andinspected the spill area.

Collection activities to date have recovered approximately 500 gallons ofgasoline and determined how far the gasoline has spread. The gasoline iscontained in the porous fill underneath the Service Building 4 parkinglot and poses no environmental concerns as it has not entered the marsharea, and is confined within Toledo Edison's property. The leak has beenisolated and repaired. See Attachment 2 for a sketch of the incidentscene .-- - ...

2. Location

Question:

a) Location of the facility from which the release or discharge occurred.b) Location of the release or discharge.c) Longitude and latitude

Response:

a) Toledo Edison CompanyDavis-Besse Nuclear Power Station5501 North State Route 2Oak Harbor, Ohio 43449

b) Ottawa CountyCarroll TownshipOak Harbor (nearest village)

c) The longitude and latitude of the Davis-Besse Nuclear Power Station is410 36' N, 830 05' W. Attachment 1 contains a map showing thesite location. The release was not transportation related.

01


3. Product Release

Question:

a) Chemical name (common name or technical name) and Chemical AbstractsService (CAS) registry number of the substance involved in the dischargeor release.

Response:

a) The material released was Gasoline, BP Super Unleaded (No CAS Number isavailable because the product is a mixture). The Material Safety DataSheet (MSDS) is attached (Attachment 5). The material is not anextremely hazardous substance. The estimated release quantity wasapproximately 1300 gallons.

4. Environmental Impact

Question:

a) Identify the environmental medium or media impacted an~dthe extent of_the impact.

Response:

a) The gasoline was released into the soil underneath the gasoline pump.The estimated area of contaminated subsurface soil is 2500 square feet.There appears to be a zone of gasoline-contaminated soil approximately

.six inches wide. This zone is approximately three feet below the groundjust above the clay substrate. The spill is 400 feet from the nearestwaterway, no navigable waterways have been or are anticipated to beaffected.

Collection activities to date have recovered approximately 500 gallonsof the gasoline and determined how far the gasoline has spread. Thegasoline is contained in the porous fill underneath the Service Building4 parking lot and poses no environmental concerns as it did not enterthe marsh area and was confined within Toledo Edison's property.Additionally, the soil beneath the porous fill material is composed of aclay substrate which Is very dense and has prevented the gasoline frommigrating deeper. Area storm water drains have been isolated to preventthe potential of the gasoline from being released off site.

5. Monitoring and Detection

Question:

a) If the release or discharge was monitored, indicate the method ofdetection and concentrations.


Response:

a) As described in Section l.d., Event Summary, the gasoline leak isthought to have occurred during the weekend of January 15 and 16, 1994.The release path to the ground is not a monitored pathway and wasunnoticed by site personnel. For event detection specifies, refer toSection 1.d., Event Summary.

6. Mitigation and Containment Action

Question:

a) Amount recovered or neutralized.

b) Describe any actions taken to reduce the impact of the release ordischarge.

c) Actions taken to respond and contain the release or discharge.

Response:

a) To date, approximately 500 gallons of gasoline have been recovered fromthe gasoline recovery sumps that were dug to collect the gasoline, andstorm water oil interceptors. These low collection points are beingmonitored and the material is being collected throughout the remediationprocess.

b),Weather conditions (-IOF) predicted a low probability of migration atc) the time of the release. The storm water line oil interceptors were

pumped out for initial recovery. Recovery sumps were dug to recoveradditional bulk gasoline which may be present and to determine how farthe gasoline had spread. Attachment 2 contains a sketch of the incidentscene. Approximately 500 gallons of gasoline has been recovered todate. Gasoline recovered from the recovery sumps has slowed. Theremaining gasoline appears to be contained in the porous fill beneaththe parking lot. Additionally, the storm water lines have been pluggedto prevent any gasoline from leaving the site from this pathway. Furtherremediation activities to remove the residual gasoline contaminationfrom the soil are currently being evaluated.

7. Preventive Actions

Question:

a) Provide plans to prevent a recurrence of the release or discharge.

Response:

a) The pump and above ground storage tank were taken out of service. Thegasoline pump will be repaired and redesigned to ensure that any futurepump failure would be captured in secondary containment.

I

I

0


8. Health Risks

Question:

a) Describe any known or anticipated acute or chronic health risksassociated with the release or discharge.

b) Advice regarding medical attention necessary for individuals exposed tothe substance released or discharged.

Response:

a) No known or anticipated acute or chronic health risks are associatedyith the release as long as the plume is contained in the soil substrateand completely removed or remediated, and there is no migration intowaterways or exposure to cleanup personnel.

b) N/A

9.

Question:

a) Indicate any air, water or other permit numbers which may be pertinentto this incident.

Response:

a) The National Pollutant Discharge Elimination System (NPDES) permitnumber for the Davis-Besse Nuclear Power Station is 21B00011*ED. Thegasoline was contained to the Davis-Besse site. The gasoline did notenter into the "waters of the state" and posed no environmentalconcerns.

Question:

a) Provide a chronological summary of the incident. Include a chronology

of communications with the state and local government agencies.

Response:

10.

a) Chronological Review

Date Time Event

January 17, 1994 -1130 Measured tank level and noticed -1300gallons of gasoline missing.


Date Time Event

January 17, 1994 ~1200

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

January 18, 1994

-~1000

-1730

-1830

-1903

-1918

-'1948

-1955

-2010

Environmental and Safety personnelresponded to scene and commencedinvestigation. No evidence of spillageon ground or in marsh area, or siteponds. Pump housing inspected and noindication of gasoline. No gasolinepresent in concrete dike surrounding thetank. Theft of gasoline was suspected.

Piping between tank and pump pressuretested. No indications of leak in pipe.Still no indication of gasoline spill atscene.

Refilled tank and tested pump.Identified leak from fire safety valvein gasoline pump. Leak immediatelyIsolated and capped, pump and tank weretagged-out toprevent- use and furtherrelease.

Notified plant management of gasolineleak and spill. Commenced notificationof regulatory agencies. Commencedproduct recovery. Recovered -300gallons of gasoline from oilseparators.

Notified National Response Center (PettyOfficer Floyd) of the release ofgasoline. No release to "waters of theState" occurred.

Notified Ohio EPA.

Ohio EPA Night Duty officer (Tom Buchan)called and gasoline release informationprovided.

Ohio EPA, Division of EmergencyResponse, Emergency Response Coordinator(Mike Gerber) called to get releasedetails. Indicated he would come onsiteto investigate.

Ottawa County Sheriff (Deputy Sauvey)was notified of gasoline release.Ottawa County Sheriff is point ofcontact for Ottawa County EmergencyManagement Agency (EMA) for localfire department and LEPC (localemergency planning committee).


Date Time Event

January 18, 1994 -2120 Division of Emergency Response,Emergency Response Coordinator (MikeGerber) arrived onsite for releaseinvestigation. !

11.

12.

Question:

a) Provide manifest, bills of lading, laboratory analyses which weregenerated which are germane to the incident.

Response:

a) See Attachments 3 and 4 for sample results and manifests.

Question:--~-

a) Describe any extenuating circumstances which caused the discharge.

Response:

a) The cause of the failure of the gasoline pump fire protection valvediaphragm is believed to be the severe cold weather conditions thatoccurred during the weekend of January 15 and 16, 1994.

!I

_ ----8

~2 N

S::

I

***.%~ -'

!

ý NM I,

-I0

tdj

Z4.133 00=0

b uQO

LAKE

57A.* q,.

£,~ ~

A96A

ARE OF STUD-

poli / A/D2~', 1>. ~~ -~P

643>.*

CDd* - . -

ALL L~VAION. ARE ERA~ TO .6.L~..Al~7OSM/

r? 0Map Reproduced from Updated Safety Analyi Report Volume 3

RAOC 94-09Attachment 2

oDqhV TO M

-1

0I< SOLSrAINDC

- rollbumy)

RXR8

PC)Mirmdko bid on &wmvot$U moftatPlb Mly. kua44difawfolovt9ole Mof

(in owets)

MAINI'Ma?~ GWREFACILITY

SDNRI&MICHIGAN DEPARTMENT

OF NATURAL RESOURCES

,ltigfa as amaenoeo i31o ACt IJO. JA.RAOG 94-09 t19.Attachment 3 Failure to tile Is P•ilshable under/ -.,aOe 299.548 MCL osecti.¢on 10 of

DO NOT WRITE IN THIS SPACE Act 136. PA. 1969.

ATr . DIS. LI REJ. 0I PR.LIPlease punt or

1-tForm Approved. OMB No. 2050.0039 Ex5 Ies 9-30-94

. Page I Informalion in 'he shaded areasf S not required by Federalof / law.

3. Generator's Name-and Mailing Address

-OL po EPwo7 -'.1 ,&^ 4 1-- sv -P "'k6 .

4. Generator's Phone( 7-q I -

A. State Manifest Document Number

MI 307.8050.B..State Generator's I D - -. ..

S-, ";• .:' 73 4,.,:•'-.. U'r~',;V -- :'' .:,;'-..• " "

0. transporter 1 Company Name

CO(IS/ al44f a (flA'Th c tw. A

6. US EPA It Number

D.ETranspoorter's Phone /~~Zv.~-

NE

0

7. Transporter 2 Company Name 8. US EPA ID Number E.State Transporter's ID

I ( I ( I I I I I- - I [ Transporter's Phone9. Designated Facility Name and Site Address 10. US EPA ID Number G. State Facility's ID

a7/ 1" 0 1! P rL/c A VG. 8.Facility's hone, --

1I. US DOT Description (including Proper Shipping Name, Hazard Class, and 12.Containers 13. 14. I. WasteHM ID NUMBER). No. Type Quantity U NIH

a. UK.-nlc 1(4ACL (A Nri 0.ZE-2¢ ~ ~ ~ ~ ~ ~ ~~ i , ,,qq.•':;001 -r-r 0i/1 • 1010o1) "I

b.

C.I..-' "

___ __ __ ___ _. L. I..L JJ I - ".I I

J.:_? ýAddltlonal Desc" ptlons forMatedals Usted Above, . . K, HandIlpO •pdep4 ...Waqs a el ..--C'C5i W A - .. .m-bI ,,i

_ _ _ _ _ _ _...... bl I

• ~d//

lb. bpecial Handling Instructions and Additional Information ' 'p•tlr-,• F -I ItFX ' ý fpWz ro 6 CA.FotPAA +05 4P46L.9- 1-t Yrt5&-

16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this conslgnment are fully and accurately described above byproper shipping name and are classified, packed, marked, and labeled, and are In all respects In proper condition for transport by highwayaccording to applicable Inlemaltonal aM national govenmvent regulations.

If I am a large quantity generator. I certify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determinedto be economically practicable and that I have selected the practicable method of treatment. storage, or .disposal currently ava,.able to me. whtii.h minimizes thepresent and future threat to human health end the environment: OR; if lam a small quantity generator. I have made a good ith effort to minimize my wastegeneration and select the best waste management method that is available to me and that I can afford.

C3£'3aC3C

2C

C

Printed/Typed Name Signature _ Month Da Y.

Si-(r -f V\ i D •ateT 17. Transporier 1 Acknowledgement of Receipt of Materials Date

A Printed N a Sign M D a"*" .. l

o 18. Transportef 2 Acknowledgement or Receipt of Materials " Date..

T Printed/Typed Name signature Month Day' Year

19. Discrepancy Indication Space) " '

Ac

1 20. Facility Owner or Operator: Certification of receipt of hazardous materials covered by this manifest except as noted inItem I9.

Printed/Typed Name Signature Mono) Day Yea'

IFýl 1EPA Form 8700-22 (Rev. 9188) To he mnaled by Michigan ONR

G "-.iio, Itr Box 30038

PH 5110RHe. i0192

I1 please print or type. (friNM creslged Wa us.en ea #R (2jpkChj yPrewrdrr.) Pane A00e,. MV ~ W ie 205.0. ~&.2. Page I IInformation in hethade ern

.

.. .. . ..... If=', .. i . ... . .

UNiHt-U..1 HALA.U.US_ 1. Generato's US EPA ID No. Manifest

I..1

7 .1*~

'I

WA),- It MANIFEST CHDOO0720508 . ( " of j is no r•t (Ia..byFeT,3. Generator's Name and Maiting Address A. State Manifest Document Number

A(.K H ;ARBOR, 0H. 8. State Generator's ID ...4344V

4.Generate'sPhon"( 419 ) 419i ' , " "

5. Transporter I Company Name 8. US EPA 10 Number Ci Atiknspý'ei Id ~ .'

RESEARCH OIL COMPANY I GH0004178612 ..... ...... ( N7. Transporter 2 Company Name 8. US EPA t0 Numnber spre_. . .. . . . . . . . • -- • :' -• . : •9. Designated Facility Name and Site Address t0. US EPA I Number G:Sft('aclty'a"ID r. .. II,.RESEARCH O3IL CO. .. '. .••.' '.'- ..•:•'." ; ..' .2655 TRANSPORT RD. ,,-• "-. ;,-,.".,;. mit,,-.,• '--"-:-.:,

CLEVELAND k H. Facilnt'a Phor,•.e- . " V ,

I OH4115041787.. .......... 1(216) 623_8383 ;._"12.•• Continer 1.4.It. US DOT Description (Including Proper Shipping Name, Hazard Class, and ID Number) 12. 3,ontaUne3

HM Type Total Ouantity WVO 'Waste No.'

a. N ast* CoI b'.stible Liquid. n.o.s.Irs ,bitu iti bi e L i'oq d 't LIN 19 9 .. P.11 1

d. V.

lions Ioe aledej Lsted Above ~ .HntlgCdelot OM W Wstes 4sb-~.tEGN~~R RESONS V18O-b9~95 ERij.:.s. ,T~EIN 5JY.M........................_ I..

. . . . . . . .. __ __ ___"_ __ __ __,_ __

.4.;ý -W:.: "YT; : . ".F '-- ..

G

I!AT0R

15. Special Handling Instructions and Additional Ino allon l-'U# V _.I4s L R -L .- IUSE GLUVES & GOGGLESZ PUMP TANK NEED 60' OF HOSE CALL 419-321-7149 AND STEVE WILL MEET V-tlU TO LOIAD ARVEA

ACCEPT .S (a)S 001E 485 TALL SPILLS MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER AT (WO0) 424-8802, 24 HOURS PER DAY. • /'.•/"

16. GENERATOR'S CERTIFICATION: I hereby declaie that the contents of tis consignment are fully and accurately described above by proper ship•ing name and areclassified, packed, marked, and labeled, and are In at respt in proper condition for transport by highway according to applicable international and national govemmenlreguataions.

I I am a Large quantity generator, I conify that I have a program in place to reduce the volume and toxicity of waste generated to the degree I have determined to beecororicatly practicable and that I have selected the practicable method of treatment, storage, or disposal currently available to me which mlnimizes the present andfuture threat to human heaqlh and the envronment; OR if I an a arait quantity generator, I have made a good faith effort to minimIze my waste generation and Selectthe best waste management method that is available to me and that I can elflord.

Printed/typed Name Signature Month Day Year

T 17, Trantporer I Ackorwtedgement or Receipt Of Materials Date

A Piecufy Signa , Month Day Year

1a . Ti1ns a!er 2 Acknwle ýefien or Raeeceri of Materials .at.

T PrintedlTyped Name Signature Month Day yearER

1 9. Discrepancy Indication Space

Ac

I 20. Facility Owner or Operator: Certificalion of receipt of hazardous materials covered by this manilest except as noted in item 19.

T DatePrintedlTyped Name Signalure Month Oar Yea'Mot I I


1II

J. ()Please print or type. (F•ns deo0etdlo A uV Mn Re (I 21schi) •~pf,'frj Fom A•enrv•d O9AB -.. -V,00" Ei,. 3

[.N U HA"AR 5I-ju I. Generator's US EPA ID No. Manifest 2. Page I I lnomation in the shaded areas

WASTE. MANIFEST (0Hn07? .",- 7 •, Is not reqsired by Federal law

3 Genefator's Name and Mailing Address A. Stale Maifti5 Document Number

- ," : :" • .. a. t. ±., r: ' : - . i-:-.: ,-•,;" *; , r. *H .

OAK HARBOEiR, OH. a. State Generatlors to4344? . r'Z

4.Generator's Phone( 419 ) 321---14-0. ,5. Transporter I Company Name 6. US EPA If) Number -St:te'T-sot'a.to • os -.

RESEARCH OIL COMPANY CHDO04178612 .......- .7. Transpote?-o Company Name 8 US EPA 10 Number 715Staterno,"aO.-1.E'..:'..

-. . . .ail Na. . & APi~rebso -iphone *.

9. Designated Facilit Name and Site Address 10. US EPA I0 Number G(3State Facility's IDt

RESEARCH OIL CO.2655 TRANSPORT RD. :"

CLEVELAND H. Fadlilys Phone.

OH 44115 I OH00,4178612 ...... (216)623-8,38312. ontaners14.1t. US DOT Description (Including Propei Shipping Name, Hazard Class. and ID 12 Containers 13. Unit

HM No. Type Total Quantity WUVot Waste No.a. ffl',ýte Flammable. Liwidt n,o.t- Iroptains rxioline)

1. UN1993. FGIII. R0(0018,)0101 TT :

E

E

T

J.AddfIorW-E'- -WýI!alerlats;Listed Above:- -, "--. ' ... :K....- "' and(Ing Codes (orWastes Lsted Above

emer eý&•r,[esponse, #I -a00-969-9252 ERG#27 "A? TIM ''?9

i ~~~~~ ~-TM OUT%•"-",-' .... ,-15. Special Handling Instructions and Additional Informalki0 Pf.• VERBL REL#

I ISqF OL.OVES &. 6OGGLES. pLiflp t;:-nl: ni-e:e -1W,` o• hos-e contaect Steve" Chino t9 ,19-321--!149

AC•:*IEPT a) 038

AL PLSMS ERPRE OTH AINLRSOS ETRA (0 242 4HUSPRDY

- I4

i 16. GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignment are fulq and accurately desribed above by propee shipping name and areclassified. packed, marked, end labeled, and are In all respects In proper concdion for transport by highway according to applicable international and nationat governmentregutations.If l am a large quanlty generaor. I certify that I have a progtam in place to reduce the volume and toxicity of waste generated to the degree I have determined to beeconomically practicable and that I have selected the practicable method oi treatment. storage, or disposa currently available to me which minimizes the present andfuture threat to human heatth and the environment; OR. if I am a small quantity generator. I have made a good laith effort to minImIze my waste generation and selectthe best waste management method that is available to me and thai I can atlord.

PrintedfTyped Name - Signature Month Day Year

T 17. Transiporler I Ackonwledgement or Receipt of Materials . Date

' ,ntLnmffy 'Signaturs"j) - Month Day Year

t 8.'ffarsporl&'; AhA'otedgemen or Reept o Materials .. . " Dale

T PrIntedfTyped Name Signature Month Day Year

R ! {19. Discrepancy tndication Space

A lrft - Corr - 'd,4/ I"-,x; A'.. .. . ,-. .,-_.Y

L

T

20. Facilty Owner of Operator: Cerititcation Of receipt of hazardous materats covered by this manifest except as noted in Item 19.lr

Pfrnted/Typed NameISignaitae

DateMonth Day yearI i I


RAOG 94-09Attachment 4'

JONES & HENRY LABORATORIES, INC./ 2567 TRACY ROAD, NORTHWOOD, OHIO 43619/(419) 666-0411

February 1, 1994

Toledo EdisonDavis Besse Nuclear Pwr. Sta.300 Madison Ave. MS 3360Toledo, Ohio 43652ATTN: Mr. Steve Chimo

Dear: Mr- Chimo:

Below are the results of analysis of 3 samples received for examinationon January 28, 1994:

Sample I.D_ AC16141 Location code: TEDDBMProject account code: 285LocaEion Descr-ipti-on: North fnhtercept6-r . . .Sample collector: RR Sample collection date: 01/28/94Lab submittal date: 01/28/94 Time: 16:32------------------------------------ :----------------------------------------

.TEST UNITS TEST DETECTION*PARAMETER RESULT LIMIT

HYDROCARBONS (gasoline) by GC mg/L <5 (trace) 5

.Multicomponent analysis: BTXBENZENE ug/L 210 5.0ETHYLBENZENE ug/L 69 5.0TOLUENE ug/L 550 .5.0o-XYLENE ug/L 130 5.0rn+p-XYLENE ug/L 280 5.0

Sample I_D_ AC16142 Location code: TEDDEMProject account code: 285Location Description: North catch basinSample collector: RR Sample collection date: 01/28/94Lab submittal date: 01/28/94 Time: 16:32




Multicomponent analysis: BTXBENZENE ug/L 4.9 1.0ETHYLBENZENE ug/L 6.0 1.0TOLUENE ug/L 20 LOo-XYLENE ug/L 10 1.0j+ •>-XYLENE ug/L 21 1.0

Page: 2February 1, 1994

Sample I-D- AC16143 Location code: TEDDBMProject account code: 285Location Description: South interceptorSample collector: RR Sample collection date: 01/28/94Lab submittal date: 01/28/94 Time: 16:32------------------------------------------------------------------------

TEST UNITS TEST DETECTIONPARAMETER RESULT LIMIT------------------------------------------------------------------------


Multicomponent-analysis: BTXBENZENE ug/L Not detected 1.0ETHYLBENZENE ug/L Not detected 10TOLUENE ug/L Not detected 1.0'o-XYLENE ug/L Not detected 1.0mn+p-XYLENE ug/L Not detected 1.0

---------------------------------------------------------------

Please advise should you have questions concerning these data.

Respectfully submitted,

Fred W. DoeringPresident

2478 1994.01-18 15536 #10S P.02/03FW)H I BP 0 1 L TECH REqEpRCH=%NMMM -

To

RAOG 94-09-Attachment 5.

MATERIAL SAFETY DATA SHEETBP OIL

24-HOUR EMERGNCY ASSISTANCE_ GENERAL ASSISTANCE NFPA FIRE HAZARD SYMBOL

BP Ameiica (1i Ohio): 800-362-6059 216-441-8124 A 4 .W(Outside Ohio): 800-321..642 .

CHEMTREC Assist: 800-424-4300

MSDS Numiber> 104a

MANUFACORERISUPPLIER: BP OH CompanyADDRESS: 200 Public Square. Cleveland, OH 44114-2375

° " ~ ~~~............. . .1...

TRADE NAME;

GASOLINE, HP SUPER UNLEADED

CAS NUMBER.SYONYIM(s): -

CHEMICAL FAMILY:

MOLECULAR FORMULJMOLECULAR WFjGHT:

PRODUCT CODE.

MIXTURE

eASounE; MOTOR FUELHYDROCARBON

U MIXTUREMIXTUREP 1630

I

'HIERARCHY: 040.040

, -w-r,0,wx.g

HEALYMnAai.orL OP. rATa :i 31aSVL1 orn W-

ALxASTh:nON HAZARD TIf SwAL~w9--CAN Ew=ti LUNGS MW a&usn DmhfGEVAPORS 1aW BE-HAmmUMMAY BE IRRZTATnG TO nhE SIM=, EIES AND RESPXPATORY TRACTLOMQ-TSRIU EfPOSflR% TO VAPORS HAS CA-USED CAICER In SOUS LABORATORY A)IWLS

FLAMMABILITY DAHQZRItxxP= wzNwi"sz L1=U0 AND VAPORS

VAPO )fl CAUSE 9=AS4 P•ER

RRACTVITY • STA

ýýopyTight @ 1980. National Ptae Protectlon Assoc., MA 02269.rhis reprinted material is not the complete And official position of the NFPA on the referenced svuquect, which is repiýsented3nly by the standard in its entirety.

FROM I BP OIL. TECH4 RESSPAM4 TO 2478 1994.01-18 15337 fie P.03/09

INGEST10M:2RODERPA2!E W=XC-. MM=a~ q3:4l LDE~o -3.0-30 0MR. Ajiat:1.0 ±ntoQ 1utAn~ oMaY (MfpnQimownOt~ia. MCY CAXnS' Vaztro0i~t*tizDel dj1gtuwbvanoe S~tCCM limy :Wd1Qda 17,LIatioa,Mus1ed, vomizting mnd diarrhien. may Oa~to% hagmiu1 central nnOXO1.Ud wsytoa 6ffoatS., EffactutflaY Li28lude OX=L t4ati, supborii. heada~ohe, di~zziness, drowg~ieuoa, blurred Triglonifativuex, tr.amorg, oowhvulujong, loan of oriooi~0~ o~,~ezpi t~omr azrret aMd doatlix.

SKIN:P* C CAIrc~c~~ U=Q-T0XX. R~abbit d6=Al =a50 >5 ln1/kg. BL3!1EX~ XE IAMIH. ~61t6Pr4~ Or

P1-oaffa cottact m~ rosal iL diatatti74, rednaga, itcbihgr, 3inflazw~ti.pn ioZacking1 ai~P906ible, PO-otnda infactioz. HighI prouv~a a~ici 1injectionsa ara 2SD=CrUS IEDIC2LX*RM=S Xa~uzy may not appq,= arieyosqu at firstly vjLtWA± a faw hoaixa' hosuue will.h-ACOMG SWol14,~ discolored and aztxaxs3ly painful (ao~ Notaot tc 3?yp±il eauction) .

EYE;MAY ca 1 ew Slighit tranoidIit± i~ritý.tivi.

INf1ALATMON: '

MYF c~auza xespix2ntoxy t=;.et irx~itatiLoji. 1Exzposu±~ 2=sy cause CQtLral Iaoxvoun nyto=OYtS1 mwa s~mi~llo to Ch1ajiifa IXiqata~ Unidoa~ ~goataLon* (a** Zzzgaatioo n sutAtn) . 2ky ~a-IoCAUfAQ aflGSR1± aM4 LX~egidler heakit r1V~b. Relpai~td or p~o3.onged W~omz~xe i~y cwaxaobeIbAVioral chanages.

i

SPEG1ALTPXID EEFE.Cr:Yh Cuo 4Varua 1±Vax and k.idZwy affacot liasad. on tastx Wi1thbr~~ Is A

Dxauc 09X4,0 capo OA.14lift bas1een fouvA to b .gax.i1nogpszi to lal=Ato7xy akn4=1lVhen giveA by 4 "1,~a fZ4,8 a~styo mtaoiiyi~y u.Vbei'~~oo ~ah*70 Y'ifilded Conflicting resulta.

MW U daet&Ts13d that t1~o* Isu lijmitied ervidonon Car the coxinog.-nAoity of gasoeunii inioX~e~r1=uta2. anima1.g aud SinV49quata eydfnoe for the C~cdinoglaniity of gApoJAino inhxumans. (X2Ec* Class--2B) -

WUNfl00- 7Tho uxe og .vx hydjsooux2bn fuel liA an axea. without adagumtiA voxtntilaion mayMOnrgt in hnZa~r4*Uf levala Of combrigbln prodacot eand iadequata ox-rgan 1&va1s. TU= ba.0daQtoxmLd.u t~jt 04001ine ang-ize arbaait is pogaikay~ caxaiiuoffni to humans25. 1t. E4

Whin prodact dr'aw lua b~gfzQnqt. ]Uwzana $A O=c;LuOnEcjr to lab~ory' ani-Ina vhan givoxibY 1=1ato or by inh~latiori. Thera is ah assoaiatioLo blatw~oa occupatdonal. 02:yOSIm tobanzone and iu~mazk lostcoinia. Carcna~tenia detiariftnntioa: XARiC--Ruo=aa nd Animl~aftufficidht "Videnca of darac3 oganicluy, (IMC Claan--.); EIp-ftown caxcijaogaa;

AActuta b4=0a poisaning cauaes csantrl a*vouz systieka deQuroooion. Oho gouoIWCfacts btih hwnNtaoloatic stywtan caivaing blood diftordera includtIngif O1Land

p~'nytgi~n k. ttagunic and dlastogonlc J.u mamma11an and non-um=Aliah taiat oysteuwIWP~o4uctlvs toxicanlt: only at doneB that wce maternallyl toxic, based oA 4aoto With~

ND -No Data 1049/Page 2of8NA -Not Appricable

FFWH cBP OIL- TECH RF-1ZDI TO " F~t'1IB OL ELH ESP ~ TO2478 13%4.01-10 I1S38 #10S P.04/09

INGE$TION:DO ITOT XkMfUCP9 VOX~XTXa= A=AUSE 011 DAMO)M OF ASPL& lATflf raQ17If ýi3Mr 'LOOS. (et; 'Mmne.Oltemed~ica:l attVezntic. Xf gpon~t'zeoug Vomitding occura, zMon1t~or folr bremthiug diifficulIty.

SMI CONTACT-;R&I 0oohtinM4nates clothiusg l± &-1tatoy. Wau2I. £J04 ct Contact thoroughlY WithI 90XV b~dWatur. Cat wdical attention if iwit~tiotz yersista. High prgazlura Sld 3.njactions u=SMZOU WflIMAZ W~IE~IS Got- 1jmioata zaadicaJ. atteitftnt0k

*EYE C 0 TAC~T:Fluab imodia".y With larget BanUnts of WAter for ait leasit 15 Mi~lzL90. Eyelid" ahould baheld awvay froza tha aya~b.2 to erwure thortixgh rinfring. Caet ma~ioal attontiOn If4=4Statiton xvenult.

INI{ALAT[ONN:RO46VQ fttOCte'l Poll Xxc ~om uce of axpoaunre MEI not breathina, oeanfliw *Pon aifrv 'andozin_4.fu~ carvvdio. Gzota raotl~ita~te ion CP) itenin 4rabnri IIf fiiOXY911 itu a Lopzk "ta~ uim itatodi cal- ato~ion br.hn-i tfa L~K~4

VhfTtO~i =a ft- imVot-tanti Vlak to Mageso !S- thea axtont of- aopfration 09- th* Prauctin~to tbe l~ingn sino vA Aor chemical ~n~1m~o21±tjU can rapidly FPxog0wVto Gj4xrfailugal 'asping,'congbIing, and 6ho~ing ax* r 3 tei~tve evide48 of ugjrttn yaffuggoated that aLU XAh1Aw*u a gpected og wwiOZJO2 ahfaion haiav bas1 Uina cheat:X-zayP. * Iwdlata hospitalizatlion x~iotad 23a conosidered for na~yuptomatio cb.Lld~r= Witt anabnoxmaj couat x-ray, obt=W~e or b&eToxid patients, iiitantional or inavolv 1=g-azt;ionx, andP~ti~ualt 'With aibnoz=a 49hat x-:rayn witsh olinlicaliy significant V±lMoxwazy 4it'eavo.

10 Ganoiu ±tentina1 flyj~taens iar iujoually mltuor And pathological ahaxngea of -tho llla= andkiuar wo ruported to be unfc==ol iu acita inoxivitions. DaconaixiAtion (induced

al-a~slz oxý Uevagre) i-a qanray eia. ;tnd shovidI ba 00311dere'd on the weli- of deachindividual cazs; of cooxpa taie usuil pracaution of ani on.dotraollea.l tube nBhould baoonsideed Ptior to lav*06..

%ld-ocxbos ay ±nocruwa~ the 0ansitivity of bao Pyoe riwum to catedbeliminev;eloatzooardigralphic moninom boy~be 1ndioated And careiul coný± oration a21ou14 be givento tho Selection o01 ch4l~aoa

Xcu~to centr;Axxu2 ii~wa yeaem signa ind aymptaon =ny r~ault from lerge Itigeotiona oraspiatin-idx~e4 ypoxia.

MM7~LhkTION ).HL13x G6azojun is one ýf thte solvents Uneld brZ chemicaa siibstanoe abqaeira.whefse pbatient M~AYr Present with 4tcute- and/or chronic cantral nervoýua system sig-ns orPYmp1toms. They uay aAxQ proee-I wtI~h arrythmias.

Tn canaf of akin Injaction, condider promit dabri4oamvrt of the irouad to minfimiza ziedrosgif4*d tissus lo~a.

*ND.No Data' 10 49/page3CV8NA Not APPr~cable

FTWM 113P OrL T1FjU4 REnEPRCH TO F~ lP I TD- SRC-f TO2478 1994,131-18 JS138 ffI0s P.O5/0s

EYE PROTETOMN:Avoid GYe contg~ct wi~th tia material'. wear sOfaty 91ftnean or chellic&l !709-9100 P=ovj.&afaaotlities £11 the woxk zmca for edLýýately fl-qshing the dyes.

SKIN PROTECTIN:Avoid aknld cobat Xf akLin contaot is antioai~atud, protectiva clothingi inciuxinfflwazw~icau gloves, should ho worn. Wash bAdn if they comia in aoiitct with tb~iA =ita&rLal.Use good paruoun3. bygiene. daez xagiu&xly alotmied work clothing. showazirng and c~ningInto atraat clothing a~zor 1(O2X is desirable. Product apilt an clotbing' niy rvimlt Luda1~ad~ evaporationcm en4 a-us sq~keit fire "zazIed. Wdat cnnt~mjnated Clothilng -eP;Vrt*1Y.

If 91othing i La o be lAund~zr4 by iqromoJio eilsee iiPJqxm laundorer of proZ Porocladurdau.

RE9SPIRATORY PR;OTECTION:xf 0=POffu=Q limits ate exOQcoloI or it frritAtion ia o3xporisnaed, tiZOSR appr~ovdreapiratt ry Proet@(ion abould be wrorn-. Ventilation and otMxa foxtw of *ng1zaatinoQOOtZV20 a~XO ften the preferred nm6ann for contxro~Jl;xg chemical ea~poauxr. Xairatpxy

Protection Ina~ be nnee4e f or n -toutjina oýC .=Q;geaao situatSionz. _

fp.-.,

JOIUNG POINT: 26.670- 226.'700 Cl 00 -440 Pi)

SPECIFIC GRAVITY; 0.720;- 0.740 G 160 P'MELTING ( pIT.' V% %VOLATUt:h( 100.aoo e 4A~ P IVAPOR PRES$URE 79060og I = el 100 1'

.EVAPORAYIO ' RATE (WATER=1): >-3VAPOR DEMMrY (A]R=I): a.200 AS VAPOR~VlsGosftYý- tiD

% SOLU8IL1T IN WATEFL- Nm -,

QCTANOLJWATEFI PARTITION COEMFC4Ea4T., ND

POUR POINT;-~PH: qAPPEARANCEIO DOR: cr-M -LXQUID W=~ 2L STaoDM R OCABOt ODOR.

.!

NEEMFLASH POENT! -37.000 a (-3s p) C i

I FIAMMABIUlY LITS IN AIR(% BY VOL)LOWER: 1.400-FLAIWMAOLMlT UMMT IN AIR (%/ BY VOL) UIPPER! 7.600

BASIO FIREFIGHTINGc PROCEDUREý):

WAtur M&Y be izaeff agbAva but stxeld be used~ to caae iyceia.,aab7 oml fpi~o~ r oaxpollediid cotaiesobt;tx

and to 'zvQtect P6170onnal. Xf LQAa Or sPill hA0 not ignitod, 'rennilmts arenan usewaet"Prky to cliap=4 Qae u or vapor A= to proect~ peraomine athemplting to stop a led%~. us*'WatOX t6 4iJ.i~tO OPillo a~d to IlUskn th6M a~ay froU OOU~eca of Ignition. Do not f1uzu * downpublic sawarx or ot~her drajlpago Myetoen. EX-Poned firefighitern meat wear HSMA/I0S~App2r6Ve4 poa:Ltiva Preanura selt-contain~ed broAtbing 5aPPAratun WWIt ftll faca miaek an~d fu.1l

protective Clothinug.

ND - No DataNA ý Not AUpaable

1049/Page 4 of 8

0t|

FROH ISP OIL TECH RESEARCH TO 1 2478 1994.01-18 jSS39 #10S P.06/09

. UNUSUAL FIRE AND EXPLOSION HAZARDS;

Daunarous when uxposud to hbat or Clagu. VApOrZ norm flammable or explosivO mtXturen withair at roemn te•no-raturs. Vapor or gas may apread to distant ignition UouaCeU and fla•hback. Vapors may concintrate in confied areas. Runoff tO '0sWer may vause fire orexplosiorn hazard- contahiers may explode in heat of firse. Xrritating or toxic substancesmay be emitted upon, t:erwl decoMposition.

STABILITYINCOOMPATIUILTY:atabla Under anOMal .conditions of use. Avoid contact with strong oxid-1tus.

HAZAflDOUS READ-U1ONS1DECOMPOS1fJON PRODUCTS:CombUit±±on may produce CO, C02 end reactive hydroocrbonS.

SPILL OR RELEASE TO THE ENVIRONMENT:Xf your facility or operation baa an bo0l or Hazardous Substance ConGtieUgayklan', activate its proceures.

-- Ta Sxe4inte steps to atop and contain thea pii1. Caution s hould beaxeXciedA regarding "reasonn1 safety and eXpQgare to the spilled material.

-- 3or techu~ical advise and ek*istance rolate4 to ahemlos coutact ca~flTS(BoVJA2A-S3003 and your lo0"l f ire doptlrtmeat.

-- totify the National Response Ceater, if raqzired. Also notilfy ap7icpriateabatell and local. rogUl~tory Aa~'ncien, the LEMO and tbil SM10. 'Contact the

'local Coast Guard if the relemse is into a watOerly.

. mergency Acton:Keep unneceseazy peopl. Awy; Liolate hazard area and deonlyqntr 9 . Stay k1Ud .eep oat8f low are". (Xlso Pee Pqrounal Protcotion Xntormtaton section.) Isolare for 1/2 Mile in411 .d1irctiozs if tank, :ail car or tank truck is involved Sn fire.

Spil or Leak Procedure:Shut off ignition sources; no flares, gmoZiug or Zames iz hazard area. Stop leak. if youcan do it W•ithout rink.. Water svpra may reduce vapvor but it may not prevant ignition inclosed spaces-. Small Spills: Take up with. sand orother nonuccbustible absorbentmaterial and place into containera for later disposal. Larg6 SDills: Dike- far ahead of'Iquid spill; for lator dlsponal. *. '

Noliffcataon:clean Water A't (oil spills),:Any spinl or rslease, or subtataatial threat oX release, of thin z•aterial to navigablewater (virtually any stirgAae wxter) sufficient to gause a visible sheen upon the watermust be reportaid inealiately to the National RUsponse Cent•e (200/A24-8802)# as requiredby U7.S. PederaL Law. Failure to report may result in substantial civil and oriminalpenaltios. Also *ontact the Coast GcArd and appropriate state -and loal regulatoryagoncias.

CERCLA/SARX (Chemic&I Spills) .

The reportable quantity for thins material id 333 A poutrd(u).

ND = No Data . 1049/Page 5 of 8NA - Not Appficable

FROM1 9381 CIL TECH RESE1PRCH- -to 2478 1994,01-18 j~s40 if10S P.07/09

%1xis material contai~ns onia 021 =OrQ1 Conahtjetszlt ragalatad ng ha~ardougu ýU]b tnces tUnderVLS.. Federal I-kw. Aby BPill or other~ r.loaaO or osibst~ntial th~reat of release,. of thxiooAtorial to the a~ir, w.ater or land (unless OuF-lrely contadjad iin the workpli~ca) eqia2. toor J- oxcooo of the reportable qua~tity- much be reD0fttd immediately to th*o Netioflal3AQgpornu Ceutor (800/424-83802). Aloe contact Apropriate atatot andz local rga3lntotyJlganldOe. Co,~tACLt ha coast Guard if apilj~d ýti4 navi1gabla. watorways under theirJu~rindlition. Fai:luX6 to 3:ePort may roault in Raboautintal ciVil and crim.LnAJ 'penalties-.

*Calcula~tod on tbA basis foIr Whichaveaq bazatdoun coOroxiefl providaug t-balowest Value for:

RQ/ 1± nixtiuzes

WASTE DISPOSAL:TLhig aubsta~~ade 1w~n, dislcarded 01- dipCAo, ig not apaificually Xist*4 A0 a hasamdoniuwaste in Fedealmi regu),~tjonal however it could be obracteriStically hazardous Le it: ;L0

* CdlS dated toxic, coxgSu.ye, 1gajtabla, or toactijj accoxin to Fedornl dafinitioue (40CPR~ 261). Addlie21uI3.y, it could be dosignated- A'A lintadofls According~ to atateregulAhioio. Tihi~s subxtta~nog cou.1A also becoome A hazardouo Waste if It it, -i-Ad With Orc~naa In cont~ct with a hkzardo~ij waste. Cheek 40 CPR 261 to det-mina. whether it ia ZthaWardou.5 Vests. Xg it is: a. baaxdouz 'waste, raonl*.tions at: 40 ca1n 262, 2 1ý, 264, 260. an4

*270 *pPly. chemical addition~s, processing or othexwiaa Altaring this materinaL may nakethe wastea managexeut- infor±matiorx presented in this msPCs incomiplete, inAnourireoOrOtherwie naprpite -

UhG tZI.LU~portatioai, storage, tX-eAtment, and daposal of thia mWa~td =ntowial 82¶Ult beconucted in acmliatice Idifth all applicabla Rdowal, a tata, =nd local reg ilnt;Lonx

SARA TMTE IQ INFOR~MATION;I4.stad~ balow axv the Mxaxd. categorla. ft t~ke gVnorfun4 .Aw~1edments AndR~uthorizat4bna2&t (SAM~) Secticm 317.131.2 (40 CP 270) 1Immefitre 9=W!rd X -Delayed Hazard:~ Y~r Flra Hard. X Pressure Hazard, - . Reacttvity Hazard: -

ThU PXndalOt COntainsO the f-olewing toxic~ abminial(a) nubjeot to the raportingrTeqnix~unlalF of the Stpa2rund Aondm ants and ReauthOriZation- AXt (SAXR&)sedF-1.ou 313 (40 CW'R 372):

Com~ponent: CAS Nwefler . Maximum %Tolugns 108-88-~3-. 12-0D0Xylene 1=3-20-7 i2_000B&nzene 71-43-s *ool,2,4-Thmenhyfl~b61zene .95-63-6 .3.000

Eftljbeniene 100-41-4 2.000* Cyclohexane 110-82-7 1.000

*ADDITONAL ENVIRONMENTAL REGULATORY INFORMATION;Olin material containse a ubtshunc% lisetd as a Iiazaxdotip aix'- polluta~t vmder U.S. Fedeala

zvilatWne See 40 cxR Part 61 for restrictions which may applky to ±ta use.

*Thin mmnAmta~ia co22tain.5 a =inixt~uxa o ubatanees, name of which axe listed an t-oxicPOX1Mtazits Pursuax~t to 40 ClER 122.21, A~etidix D, Tables XX/Ifl/V. A.ny qusuruali~t-rOdwiction. of tliSx oubutauca into the facility'a process streninz, xtoxtawter ansi/onW*At&W5~tme2 otild )Zaaqlt in. the Y$,olati.ou of U.S. Padaral yAW. raottitiagg rMut k1otify the

VEAan soon. A~r they know, or ha.'r. roaaon to believe, that ally activity has ocaurred, Orwill occur, Vhiebt Would reae41t im'ehe dischaxue of a taxia poll~utant whlich iA 21otzeamlated in the facilityss ITrnmS permit. Notification lavela are '2ono2x±bod I2 40 CFR12 2 .42(at) (1) and 122.42 (a) (2). Refer to spill 0ection for a44itiona. -rogu2lAtOXYxequf~rexnents -

NO = No DataNA -Not App~cable

1049/Page 6 of 8

FROH :8W DIL TECH WRES-fRCH TO t 2478 19S4,01-ia IS:41 #185 P.88/es

TherQ bay be Seaoifia regUlations at the local, ragional o0 gtate level t•at pertain tothis lnaterival.

Thii %roduot contains ingred3ent (a) known to the state ot California to Caro0 oancer,birth defects or other reproductive harm.

conbans s•sns. " Conaot OSl standard 1.910.1025. Initial air Wnijtorng should beconducted to deteoxine if exposures are above .- p1pm action lmit o= I pm mL. If8xpoduXOU are &bov~o1 OSHA requirements apply for trailnIf.Sr medical surveflianca,p xrsonal/provec6tiVe aqwiment, regulated areas, eta.

The tolloving CanAdian Workplace Hazardo'tu X'torlulu Information System {EHaIS) catntrorionapply to thits Drodtce:CampressedGss - Nammtable/Combustible x ozidizer - Acutely Toxic -

Other Toxic Effects X SbHazardous - Corrosive - Dangerously Reactive

- FtAt4DUNGlSTORAGit:Store gasoline only in approved, claarly labeled containeru. Uever store in glano orUnapproV9d plastic containers.

stoe ?tb~t~bty aloedcontainara in cool, dxy, isolAted, weit-ventdilAto4 area away =-oakhbat, souras o' lgltion aud ,InqoomatibLas. Ground lines and eqdipmant usaed uring"

* tralnsfe to reQ~ j- tUhe possibility o- atatia nparc-iniviatod fire or axplosion.

U86 good t'C94q hy~iQne Lflactices. Wasn ha-ds bofore aativg,' dzinkIna, smokipl, orusing to53.et'facilities. .. Remove~ c~taxibate4 clothing and clean before reuse. Ohowerafter work using uoap and water. to not siphon this product by mouth. Use only as amtor fuel. - Do not use for clUe•ing, pressure appliance fuel, or* a••y other use. Do notstore, in uAlablcO contaianers. rep out of reach, of children.

* EMPTY CONTAINERS;En~tty coatAaie!rB may contai toxic, flmmwtblefconbustible or explonire r.4jiauo or vap~ror.DO not .cut, gri=&, drill, Veld,. riuse o4 diopooe containers unleas a4oquate precautlona

tnaen etgainst those haeardd."

• ~ ~ ~ ~ ~ ~ ~ 1 1 WO pill__ _. . .. K-..... . ....... -- -...............

D.O.T, PROPER SHIPPING NAME (49 CFOi 172.101):

D.O.T. HAZARD CLA.SS (49 COl 172.101):UN/NA CODE (49 CF- 1724-01):PACKINQ GROUP (40 CFI 172.1011;BILL OF LADING DE8CRIPTION (49-CFR 172-202):D.O.T. LABEL.S IREQ, IRV,(4 CFR 172.101):D.o.T. PLACAfDS REQUIRED (49 COR 172.04):

IAlSODrIf; 3, UN1203, PC X1

3

UN 1203

XrGASOL*NK1 5, UN 1203, PG 11PLA~nOML LIQUID

!I

ND = No Data"NA - Not Applicable

1049/Page 7 ot 8oIII

FRW 9 BP 0 1 L TEcH m-,WZý FRI A OL ~c-dREEfRC-( TO2478 1994.01.-16B 15942 #ie e f.es/osTO 9

.~' .. '. ~. 4

. CO•O-NENT I CAiS U10 - 1% 1 ZVQSU1E L1X=rS - RF

8009-61-9 99.99-100 200 ppm (690 =9/m3) TLjVi 500 Vppm(J.'480 mg/m3) S¶P.P (Ac-GIU200 ppm (900 mgIld3) PELi; 500 PVM(1,500 zMfJU) STME (0m.)

CGaspli.1l my cont~iu teha following:

T611~AI~a108-68-3 10-12 1.00 rpm (077 ,Mog11) 2Wt. Igo pm4(565 knUIM3) 9T (ACG3X)

1.00 ppm (375 mg/H3) PMt; 1-50 12pm(590 mg'/X3) STMT. .(OSEWl00 pp= (375 inr/H3) 104kou~r TL¶'7A150 pma (!;Go mlwl3 S¶EL (=%O=H

1yai*:330-20--7 10-12 l00 ppm (43~ =/l ) IM)TLV1 S 150 p(651 mq/3) STFlL (AlCQIH)100 rpm (435 yma/M1i3 PElL: X.9 p

I ppm PVlL; Sppsm BIlL (QBH&

±,2~-ey~ewor~z95-63'-6 U-3 25 )ppm (123 M91113) TT47 (ACQOaW

3.~bf~~ 00-41-4 0-2 i.00 ppm C43d iwjI1m) MV: ' 125 pm

(S43 naM/173) STPL CX8P:=)*

1ohZ~zo 10-8-70-1L 300 ppm (1,030 wg/l3) TiV (Ac=Q)300 ppm (1,050 mg/193) PEL (09EC)

Re~xn~i&.t cowponerms iot xdetaltnined b.xc~dogx andIorbazaerdoum colnponento preac=~at Inao than 1.014 (04.:L* f~ox

REVISION DATE, 17-apr.1992 REPLACES SHEET DATED: 21-lan-1991COMPLE~TED BY: SP OIL HSEQ DEPARTMENT

1101108 The hlurrnadio6 preeained herein Is based on datx *x1dued IQ bu 2=r;a1 va of hgAt IFV~wmfan tl oft Ma%4 G~fWt V~at& Shut4 Hevr, no wnmnd or tap(mOeflaGofl .oprs oiimpflad. s ~made~ ~ IN aoumcy or datUef~w~q na an d fetVW=l2w~60c\ nor

is any auffi-orba1n given or knrodi prc. ny patntid lawngun wlihout a ibmso. inaddodI50mo roaponsibWMy cmn be asrumed by vendor for any duagse or kijuy rest4fing horn hbbnonr uso, bmm any

ND - No DataNA - Not AWpicable

1049/Page 8 of 8

Davis-Besse Nuclear Power Station5501 North State Route 2t Oak Harbor, Ohio 43449-9760

RAOG 07-0005

January 29, 2007

Mr. Andy Gall, Environmental SpecialistDivision of Surface WaterOhio Environmental Protection AgencyNorthwest District Office347 North Dunbridge -Bowling Green, Ohio 43402

Dear Mr. Gall:

Subject: Submittal of 2006 Annual Sludge Disposal Report

Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear Power StationSewage Treatment Facility for the 2006 calendar year. This report is submitted in accordancewith the requirements of the National Pollutant Discharge Elimination System (NPDES) PermitS #21B00011 *ID.

If you have any questions on this matter, please contact Mr. Patrick J. McCloskey, Manager -

Site Chemistry, at (419) 321-7274.

Sincerely yours,

Vito A. Kaminskas

SMC/

Attachments

cc: Ohio EPA Central Office, Division of Surface Water

RAOG 07-0005Attachment IPage 1 of I

2006 ANNUAL SLUDGE DISPOSAL REPORTfor the DAVIS-BESSE SEWAGE TREATMENT FACILITY

NPDES Permit #

Reporting Period:

Sludge disposed of:

Disposal Method:

Analysis Summary:

Problems Encountered/Complaints Received:

21B0001 1*ID

January 1 through December 31, 2006

129,700 gallons

Transported to Sandusky, Ohio Sewage TreatmentPlant for additional sludge processing

None

None

"S

I'0

Davis-Besse Nuclear Power Station5501 North State Route 2

FOak Harbor, Ohio 43449-9760

January 18, 2008

L-08-0008

Mr. Rick Zuzik, Environmental SpecialistDivision of Surface WaterOhio Environmental Protection AgencyNorthwest District Office347 North DunbridgeBowling Green, Ohio 43402

SUBJECT:Submittal of the 2007 Annual Sludge Disposal Report for Davis-Besse Nuclear PowerStation

Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear PowerStation Sewage Treatment Facility for the 2007 calendar year. This report is submittedin accordance with the requirements of the National Pollutant Discharge EliminationSystem (NPDES) Permit Number 21B00011*ID.

There are no regulatory commitments contained in this letter. If there are any questions or ifadditional information is required, please contact Mr. Patrick J. McCloskey, Manager-SiteChemistry, at (419) 321-7274.

Sincerely,

Vito A. Kaminskas

Director - Site OperationsDavis-Besse Nuclear Power Station

TSC/SMC

EnclosureA. Annual Sludge Disposal Report for the Davis-Besse Sewage Treatment Facility

cc: Ohio E P A Central Office, Division of Surface Water

Enclosure AL-08-0008Page 1 of 1

2007 ANNUAL SLUDGE DISPOSAL REPORT for theDAVIS-BESSE SEWAGE TREATMENT FACILITY

6

NPDES Permit #

Reporting Period:

Sludge disposed of:

Disposal Method:

Analysis Summary:

Problem Encounter/Complaints Received:

2IB00011 *ID

January 1 through December 31, 2007

67,400 gallons

Transported to Sandusky, Ohio Sewage Treatment Plantfor additional sludge processing

None 6

None

6

-FENOC 5501 North State Route 2

FirstEnergy Nuclear Operating Company Oak Harbor, Ohio 43449

Barty S. Allen 419-321-7676Vice President - Nuclear Fax: 419-321-7582

January 23, 2009

L-09-006

Mr. Andrew Gall, Sewage Sludge CoordinatorOhio Environmental Protection AgencyNorthwest District Office347 North DunbridgeBowling Green, Ohio 43402

SUBJECT:Submittal of the 2008 Annual Sludge Disposal Report for Davis-Besse Nuclear PowerStation

Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear PowerStation Sewage Treatment Facility for the 2008 calendar year. This report is submittedin accordance with the requirements of the National Pollutant Discharge EliminationSystem (NPDES) Permit Number 21B0001 1 *ID.

There are no regulatory commitments contained in this letter. If there are any questionsor if additional information is required, please contact Ms. Polly M. Boissoneault,Manager-Site Chemistry, at (419) 321-8549.

Sincerely,

Barry S. Allen

TSC/SMC

EnclosureSewage Sludge Disposal Report 2008 for the Davis-Besse Sewage Treatment Facility(Ohio EPA Form 4229 - Two Applicable Pages)

cc: Ohio E P A Central Office, Division of Surface Water

Division of Surface WaterAnnual Sewage Sludge Report 2008

Facility name: Davis-Besse Nuclear Power Station

Ohio NPDES permit #: 21B00011*ID County: Ottawa

Mailing address: 5501 North State Route 2

city: Oak Harbor State: OH zip: 43449

El Mark box with an "X" if no sewage sludge has been removed from the facility for the year 2008 and proceedto instruction item No. 1, located on Page 8.

Certification StatementA responsible individual* shall affix their signature to the following Certification Statement:

"1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision inaccordance with a system designed to assure that qualified personnel properly gather and evaluate the informationsubmitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsiblefor gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, andcomplete. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations".

5. /W ,/Z5-07Signature i"

Barry S. AllenPrinted Name

Site Vice President, Davis-Besse NuclearTitle

Date

1.419.321.7676Telephone

* Title 40 of the Code of Federal Regulations, Part 122.22 signatory requirements:For a corporation by a corporate officer or their duly authorized representative.For a partnership or sole proprietorship by a general partner or the proprietor or their duly authorizedrepresentative.For a municipality, State, Federal, or other public agency by either a principal executive officer or ranking electedofficial or their duly authorized representative.

Were you inspected by U.S. EPA last year? YES__ NO X Date (if yes) / /

Required to be attached if sewage sludge has been removed from the facility:

o Pathogen Reduction and Vector Attraction Reduction monitoring results

" Priority pollutant analysis, if performed during 2008.

" Summary of nuisance complaints received and corrective actions taken

Ohio EPA 4229 (11/08) Page 1 of 10

Printed on Recycled Paper

Click to clear all entered information (on all pages of this form) LEAR

O C**EFA Division of Surface WaterAnnual Sewage Sludge Report 2008


Ohio NPDES permit #: 21B0001 1 *ID County: Ottawa

Table 3 - Stations 585, 586, 587, 588, and 589 Sewage Sludge Use or Disposal

70316 80991Sewage Sludge Weight Volume

(dry tons) (gallons)

Incineration (Station 585)

Landfill (Station 586)

Other (Station 587)

Transferred to Another NPDESFacility (Station 588) 109,200

PPG Lime Lakes (Station 589)

. Ohio EPA 4229 (11/08)Printed on Recycled PaperPage 4 of 10

FENOC Davis-Besse Nuclear Power Station"• ' - • 501 N. State Route 2

FirstEnergy Nuclear Operating Company Oak Harbor. Ohio 43449

Januar 21, 2010L-10-0D9

Mr. Andrew Gall, Sewage Sludge CoordinatorOhio, Environmental Protection AgencyNorthwest District Office347 North DunbridgeBowling Green, Ohio 43402

SUBJECTSubmittal of the 2009 Annual Sludge Disposal Report for the Davis-Besse NuclearPower Station

Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear PowerStation Sewage Treatment Facility for the 2009 calendar year. This report is submittedin accordance with the requirements of the National Pollutant Discharge EliminationSystem (NPDES) Permit #21B00011*'ID.

* There are no regulatory commitments contained in this letter. If there are any questionsor if additional information is required, please contact Mr. Stephen M. Chimo, AdvancedNuclear Specialist, at (419) 321-7149.

Sincerely yours,

Polly M. BoissoneaultManager, Site Chemistry

KAS/SMC



. JDivision of Surface WaterAnnual Sewage Sludge Report 2009


Ohio NPDES permit#: 21B0001 1 *ID County: Ottawa

Mailing-address: 5501 North State Route 2

city: Oak Harbor State: OH zip: 43449

El Mark box with an "X" if no sewage sludge has been removed from the facility for the year 2009.

If no sewage sludge .was removed during 2009, on what date was sewage sludge last removed from the facility?

Date I I

If sewage sludge has never been removed from the facility, mark this box Li

Certification StatementA responsible individual* shall affix their signature to the following Certification Statement:

"I certify under penalty of law that this document and all attachments were prepared under my direction or supervision inaccordance with a system designed to assure that qualified personnel properly gather and evaluate the informationsubmitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsiblefor gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, andcomplete.. I am aware that there are significant penalties for submitting false information, including the possibility of fineand imprisonment for knowing violations".

signaturej .Date

Polly M. Boissoneault 1419.321.8549Printed Name Telephone

Manager, Site ChemistryTitle

Title 40 of the Code of Federal Regulations, Part 122.22 signatory requirements:For a corporation by a corporate officer or their duly authorized representative.For a partnership or sole proprietorship by a general partner or the proprietor or their duly authorizedrepresentative.For a municipality, State, Federal, or other public agency by either a principal executive officer or ranking electedofficial or their duly authorized representative.

Required to be attached if sewage sludge has been land applied/distributed:o Pathogen Reduction and Vector Attraction Reduction monitoring resultso Summary of complaints received and corrective actions takeno Copies of all certification statements required by ruleOhio EPA 4229 (8/09) Page 1 of10

Printed on Recycled Paper

Click to clear all entered information (on all pages of this form) CLEAR

O~E~ Division of Surface WaterAnnual Sewage Sludge Report 2009

Facility name:.. Davis-Besse Nuclear Power Stat% Ohio EPA NPDES # 21B00011 *ID

Table 3 - Sewage Sludge Disposal (Alternatives to Land Appl cation)

Sewage Sludge Fee WeightDry Tons

DMR Reporting Code 51129

Incineration

Landfill

PPG Lime Lakes

If sent to landfill

Name of licensed receiving landfill:

Sewage Sludge Weight Sewage Sludge VolumeDry Tons Gallons

,,_ _ DMR Reporting Code 70316 DMR Reporting Code 80991

Transferred to Another NPDESPermit Holder 30,000

If transferred to another NPDES Permit Holder

Name of receiving NPDES Permit Holder:

Sandusky Waste Water Treatment Plant

Receiving Facility's Ohio NPDES Permit Number:

2PFOOOO*MD

If receiving facility is out of state, receiving facility's USEPA NDPES Number:

Ohio EPA 4229 (8109)Printed on Recycled Paper

Page 4 of 10

FENOC Davis-Besse Nuclear Power Station"• 5501 NV. State Roule 2

FiratEnergy Nuclear Operating Company Oak Harbor, Ohio 43449

January 25, 2011

L-11-009'

Mr. Andrew Gall, Sewage Sludge CoordinatorOhio Environmental Protection AgencyNorthwest District Office347 North DunbridgeBowling Green, Ohio 43402

SUBJECTSubmittal of the 2010 Annual Sludge Disposal Report for the Davis-Besse NuclearPower Station

Enclosed is the Annual Sludge Disposal Report for the Davis-Besse Nuclear PowerStation Sewage Treatment Facility for the 2010 calendar year. This report is submittedin accordance with the requirements of the National Pollutant Discharge EliminationSystem (NPDES) Permit #211B0001 IID.

There are no regulatory commitments contained in this letter. If there are any questionsor if additional information is required, please contact Mr. Stephen M. Chimo, SeniorNuclear Specialist, at (419) 321-7149.

Sincerely yours,

Polly M. Boissoneault

Manager, Site Chemistry

SMC/KAS



PoetoEnvironmentalj Protection Agency


General Information

Facility name:Davis-Besse Nuclear Power StationOhio NPDES permit No: 21B300011*ID) -[onyOtw

Mailing address:5501 North State Route 2

City:Oak Harbor State:Ohio Zip:43449

DI Mark box with an "X" if no sewage sludge has been removed from the facility for the year 2010.

If no sewage sludge was removed from the facility during 2010, on what date wassewage sludge last removed from the facility?

Date: / I

El Mark box with an "X" if sewage sludge has never been removed from the facility.

Certification Statement

"I certify under penalty of law that this document and all attachments were prepared undermy direction or supervision in accordance with a system designed to assure that qualifiedpersonnel properly gather and evaluate the information submitted. Based on my inquiry ofthe person or persons who manage the system, or those persons directly responsible forgathering the information, the information submitted is, to the best of my knowledge andbelief, true, accurate, and complete. I am aware that there are significant penalties forsubmitting false information, including the possibility of fine and imprisonment for knowingviolations".

Sig Date

Polly M. Boissoneault 1.419.321.8549

Printed Name Telephone

Manager, Site Chemistry

TitleForm 1

EPA 4229 (10/10) Page 1 of 7


Stations 585, 586, 588, and 589 - Sewage Sludge Disposal

Facility name:Davis-Besse Nuclear Power Station Ohio NPDES permit #:21100011*ID

Table 3 - Sewage Sludge Disposal MethodsSewage Sludge Fee Sewage Sludge Weight Sewage Sludge Volume

Disposal Method Weight (Dry Tons) (Dry Tons) (Gallons)DMR Reporting Code DMR Reporting Code DMR Reporting Code

51129 70316 80991

Incineration (Station 585)

Landfill (Station 586)

Transferred to Another NPDES 35,400Permit Holder (Station 588)

PPG Lime Lakes (Station 589)

If the facility is reporting with Station 586, provide the following information:

Name of licensed receiving landfill:

If the facility is reporting with Station 588, provide the following information:Sandusky Waste Water Treatment Plant

Name of receiving NPDES permittee:

2PFOOOO*MDReceiving permittee's Ohio NPDESPermit #:

If receiving permittee is located outside theState of Ohio, the receiving permittee'sUSEPA NPDES Permit #:

Form 4

Page 4 of 7. EPA 4229 (10/10)

S.

0,

Flrst~ner 6 othMinSAM.on Ohio 44308

1-800-646-0400

October 21, 2010

L-10-a287

Mr. Rick ZuzikDivision of Surface WaterNorthwest District OfficeOhio Environmental Protection Agency347 North Dunbridge RoadBowling Green, Ohio 43402

Dear Mr. Rick Zuzik:

Re: National Pollutant Discharge Elimination System Permit Renewal ApplicationDavis-Besse Nuclear Power Station, EPA ID No. OH0003786 Permit No. 21B0001 lID

Enclosed are two copies of completed Form 1, Form 2C, and Form 2F applications forFirstEnergy Nuclear Generation Corp. (a subsidiary of FirstEnergy Corp.) Davis-Besse NuclearPower Station's National Pollutant Discharge Elimination System (NPDES) permit renewal.These forms are submitted 180 days prior to expiration of the existing permit in accordance withOAC-3745-33-04. Also enclosed is check number 1374125 for $200.00 for payment of theapplication fee.

The following are additional items pertinent to the application and/or permit renewal:

1. Samples for Storm Water Outfalls 002 and 006 have been collected and analyzed, withthe results reported on Form 2F. The collection of the Outfall 005 sarnple has notoccurred to date due to no flow conditions during the sampling event. Results for Outfall005 will be reported on Form 2F Item VII when available.

2. The asbestos monitoring results have been below detection at Outfall 004 sincequarterly sampling was initiated in September 2006. Therefore, it is requested that themonitoring for asbestos be removed from the renewal permit, and also, that thecorresponding Item 0 in Part II, Other Requirements, be removed. It is also requestedthat the metals monitoring requirement at Outfall 004 be removed.

3. Presently the pathway for the discharge of Outfall 004 is to the State Route 2 ditch,which is then pumped into the Navarre Marsh Pool #1, along with other local area stormwater run-off. It is requested that the facility have the option to discharge Outfall 004 tothe Navarre Marsh Pool #1. when flooding or pump maintenance is occurring to alleviatehigh water levels on neighboring properties.

Mr. Rick Zuzik Davis-Besse Nuclear Power StationPage 2 of 2 L-10-287October 21, 2010

4. Sampling has indicated that dissolved oxygen is not an issue at Outfall 001. Therefore,

it is requested that further sampling of dissolved oxygen be removed from the permit.

If you have any questions, please contact me at (330) 384-4643.

Sincerely,

Scott F. BrownSenior Engineer

Enclosure A:USEPA Form I for the Davis-Besse Nuclear Power Station NPDES Permit Renewal

Enclosure B:USEPA Form 2C for the Davis-Besse Nuclear Power Station NPDES Permit Renewal

Enclosure C:USEPA Form 2F for the Davis-Besse Nuclear Power Station NPDES Permit Renewal

By UPS Groundcc w/enc: SMChimo

MJJirousekKASadieDJWeber

U:ACorp\EnvXEnv.OH\AII EnvXNPDES.K~mXDav~s Besse\Davis Besse CO*ver Lelter Ftnal.doa

1374125FirstEnergyVOID IF rOT CASUMD WI1 90 DAYS

Check NO. 1374125

PAY TO TREASURER STATE OF OHIOTHE OHIO EPA

ORDE.ROF PO BOX 1049

COLUMBUS, OH 43216-1049

JPMorgan Cbase Bank, Syracuse, NY 13206

CHECK DATE

¶10Ij15oioIEXACTLY ********200

rir st~hergy Corp.

50-937

213

AMOUNT

1* *****200.00

)OLLARS 00 CENTS

1191371,4125sil ,:(32 L3093 791. 60 L a ?,4,8al"

VENDOR ITO. 0140008749 DOC NO. 2000254364

PO NO INVOICE / RCPT # DATE DOCUMENT # VENDOR INV AMT

0H0003786 10/14/2010 1902212003 200,00

FirstEnergy NHclear - Davis-Besse NPDES Renewal

REV-IEW INVOICE ACTIVITY AT 11TrPS://WWW.GPU.COM/APVWB. FOR ACCESS CALL 814-539-3200

DISCOUNT

0.00

NET AMOUNT

200.00

Hf)

L-10-287Enclosure A

US EPA Form I

for the


NPDES Permit Renewal

(3 pages follow)

Please type. Do not complete by hand.FORM LAS. ENwtL4ON TA[ PROIEGTMON A YENPCy

GENERAL INFORMATION1RE P A ConsoPdaredPerýmis ram OH0003786GENERAL tReod d•i o iml loo" erc siarig)0 0

tA5t. rTV.S If a preprinted label has been provided, affixL EPA .D. NUMBER It In the designated space. Review the Inform-

allen carefulty; It any of It Is Incorect, cross

7 - through It and enter the correct data in thell. FACILITY NAME O oEPA does not appropriate fill-In below. Also, If any of

Ohio EPtprovide labets, the preprinted data Is absent (the area to the

V. FACILITY Enter this information in items 1, III, V left oflho ael space 11sis thet Inormatlon

MAILING ADDRESS that should appear), please provide It in the

and V1. proper fil-In area(s) below. It the label Iscomplele and correct, you need not completeltems I, II1, V, and VI (except V1-B which

VI. FACILITY mustbeconpletedregardless). Complet allLOCATION Items If no label has been provided. Refer to

the Instructions fo, detailed item descsip-lions and for the legal authortzallons underwhich this data Is collected.

INSTRUCTIONS: Complete A through G to determine whether you need to submit any permit application forms to tha EPA. If you answer 'yes" to anyquestions, you must submit this form and the supplemental form listed in the parenthesis following the queslion. Mark "X' In the box In the third columnIf the supplemental form Is attached. It you answer "no' to each question, you need not submit any of these forms. You may answer "no" If your activityis excluded from permit iequlcrements; see Section C of the Instructions. See also, Section D of the Instructions for deflnrt(ons of bold-faced terms.

t.tARK 'X k'ARi( "X'SPECIFIC QUESTIONS MARK SPECIFIC QUESTIONS

YES NO I T ", FORM

A. Is this lacitity a publicly owned treatment works B. Does or will this facitity (either oxisting orpr'oposed)which results In a discharge to'waters of the U.S.? ' Include a concentrated animal feeding operation or(FORM 2A) aquatic anlantil production facility whtch results In

discharge to waters of the U.S.? (FORM 2B)

C. Is this a facility which currently results In discharges D. Is this a proposed tacllky (other than those desc'bedinto waters of the U.S. other than those described in A or 8 abovelwhlch will result In a discharge toAor B above? (FORM 2C) X waters of the U.S.? (FORM 2D)

E. Is this a facility which does not discharge process F. Is thIs a laclllty which o'ischarges stormwaterwastoewter? (FORM 2E) X associated with Industrial activity? (FORM X X

G. Do you generate sewage sludge that Is ultimately regulated byPart 503? Do you generate sewage sludge that Is sent toanother facility for treatment or blending? Do you process or ,derive material from sewage sludge that Is disposed In amanner subject to Part 503? (FORM 2S)

I NAME OF FACILITY "

Davis-Besse Nuclear Power S.tationIV. FACILITY CONTACT

Chlmno, Stephen, Senior Nuclear Specialist (419) 321t -7149V .FACILITY MAILINGADDRESS

A. ST REET "OR P.O. sOX

5501 N. State Route 2

a. crf Y OR TOM 0. STATE , ZIP CODE

Oak Harbor OH 43449V1. FACILITY LOCATION15

A.. STREET, eeUTI! NO. OR 0OTHER S PECIFIC IDENTI FIER•

5501 N. State Route 2

S. COU||Frt HAJE

Ottawac. CRY on TOWN a .TY E.W11 z•co ",ý.U 0'0•o

Oak Harbor OH 43449 I 62

EPA Form 3510-1 (Rev. for Ohio EPA usa 2108) CONTINUE ON REVERSE

Click to clear all entered Information (on both pages of this form).LE

TCONTINUED FROM "[HE FRONT

VIL SIC CODES (4-digat, in order..olprfofty) .P. M RST B, SECOND

• t•'pti~l)4911 .. . _ '°:

0. THIIAD D. FOURTH

Vill. OPERATOR INFORt A-nch NONE.. .

A. MU•E B. Is the name listed InItem VIII-A also theowner?

FirstEnergy Nuclear Operating Company owner? [•-Dyes NNO

0. STATUS OF OPERATOR fwlh, .lnA, r O•&' .r.) PHONE gr od' A ID

F = FEDERAL M.PUBLIC (otherthanfederalor, fate) olf)S = STATE 0= OTHER (spec6f) (800) 633 - 4766P = PRIVATE P

E. STREET OR P.O. BOX

76 South Main Street -

F. C I•YOR TOWN l . .STAfE I. Ozip COD'E IX INDIAN LAND- F~Is facisla ity located on Indian lands?.A kron O H44 08Y . O- ]N ,,

x. EXISTING ENVIRONM.ENTAL PERMITS 111 M 1 ;A NPDES D.~aac PSO Jur[•r todiionfto ,rpy d " s]

21BOO01 I *ID

1R.UIO C dr[od•J.lo ~ds E. OTHER fioafl,6)

0362000091BOOl Auxiliary Boiler

C. RCfA (lds m e) F. OTHER fUpetfir)

0HD00 0720508~

Attach to this application a topographical map of the area extending to at leas[ one mile beyond property boundaries, The map must showthe outline of the facilily, the location of each of Its existing and proposed Intake and discharge structures, each of its hazardous wastetreatment, .storage, or disposal faclilties, and each well where It Injects Ilulds underground. Include all springs, rivers, and other surfacewater bodies In the map area. See Instructions for precise requirements.

XII. NATURE OF BUSINESS (provide abrief de~scrfptlon)

The Davis-Besse Nuclear Power Station is a 908 (net) megawatt steam electric facility that generates electric power.

XIII. CERTIFICATION .(see lnsirictions)

I certify underpenally of law that I have personally examined and am famtmtlar with the Information submitted In this application and allattachments and that, based on my inquIry of those persons Immediately responsible for obtaining the Information contained In theapplication, I belive that the Information Is true, accurate, and complete. I am aware that there are significant penalties for submiflingfalse •nformatlon, Including the possibility of fine and Imprisonment,

A. NAE OFFICIAL TreE (.piop.,) I.SIaNATURe C. DATE SIONED

Barry S. Allen, Site V.P.- D.B. Nuclear 0 I /Y / 6

COMMENTS FOR OFFICIAL USE ONLY

EPA Form 3510-1 (Rev. for Ohio EPA use 2106)

la dl,-o v

8441'7T3C y'.7

FIrst nrgy Nuclear Operatn CopanyDavis-Besse Nuclear Power Station

: " •" I, ........................... ............ " . 1.' :" .. :."':: ......... ....

Refrece '~s SGS gmpohpic Maps

-. Lacmmne; Ohio;.Quidranglt,.Photo Revised 1980

S-- . .... , E Scale:,I = 2000,

35'

...' .K 601

%Tr:WLrlTxv rt E , 002

,....V

- - ~ ~ V

-'-

- *.:.

WI.N ,. ' . •

4

L-10-287Enclosure B

U.S EPA Form 20

for the



(69 pages follow)

EPA I.D. NUMBER (copyftem Pten I of Form )

0H10003786 I

Form Approved.OMB No. 2040-0086.Approval expires 3-31-98.Please print or type In the unshaded areas only.

FORM U.S. ENVIRONMENTAL PROTECTION AGENCY

I FA EXISTING MANUFACTURING, COMMERCIAL, MINING AND SILVICULTURE OPERATIONSPOESConhsofdate dPeriN/ts Program

1. OUTFALL LOCATION,

A. OUTFALL NUMBER B. LATITUDE C. LONGITUDE(list) 1. DER. I MIN. 3. SEC. L DEC 2. PMI. 3. SEC. "D. RECEIVING WATER (nmne)-

001 41 36 S 83' 4 10 Lake Erie

002 41 35 35 83 5 20 Pool 3-Navarre-Toussaint River

003 41 35 45 83 5 0 Pool 2-Navarre-Lake Erie

004 41 36 2 83 5 40 Pool 1-ditch-Navarre-Lake Erie

041 35 58 83 5 3 Internal to 001

1. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIESA. Attach a line drawing showing the water flow Ihrough the facility. Indicate sources of intake water, operalions contributing wastewater to the effluent, and treatment units

labeled to correspond to the more detailed descriptions In Item B. Construct a water balance on the line drawing by showing average Ifows between Intakes. operations,treatment units, and outfalls. If a water balance cannot be determined (e.g., for ceraeln mining acliilles), provide a pictorial description of thd nature and amount of anysources of water and any collection or treatment measures.

B. For each outfall, provide a description of: (1) All operations contributing Wastewater to the effluent, including process wastewater, sanitary wastewater, cooling water,and storm water runoff; (2) The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets Ifnecessary.

1. OUT- 2. OPERATION(S) CONTRIBUTING FLOW 3. TREATMENT

FALL b. AVERAGE FLOW " b. UST CODES FROMNO. (/lan) a. OPERATION (list) (ircdude urtni) a. DESCRIPTION TABLE 2C-1

Cooling 7o-er elo'wdow, aritary and E33. vaporation

G.eondary heat ex.chanSr.. Katen DOtinfectiOn tCheor-ne)

tztmt make up demin bldg ourp, se2 I50 E-hcuane

flow, dl]Utton flow, radwaste systen Discharge to suxrace Water A

Area runoff, Station draing, sedicanataon (Settlng)1002 0._______-

C-ecutaden ontor ynea" d-rain tan.y Figoation H

during ehutdont tiinýention (Chlorinet 2

Daicharge to Surface Water4-- 4-A

Sc0eee S r.nh 0.22 Screeaneng

SedtiNaetatinn Isettliaa 2

004 Circulating Water ayaten drain 0.0o a9d Disinfection (Chlorina)

Discharge to Surface ater-A

Saniary Canreacter ac Sedinentation lSettitevi601 Sntr -- e 0.02 .togalng 1-u

Activated sludge 3-A

Stabill-•ioe Ponde 3.0

OFFICIAL USE ONLY (rift.

EPA Form 3510.2C (8-90)

tent guhlsdlnes j.b-cotegorlej)

PAGE 1014 -CONTINUE ON REVERSE

PAGE 1 0f 4 -CONTINUE ON REVERSE

EPA I.D. NUMBER (copyfrom ftem I ofForn 1)

OH0003786Form Approved.OMB No. 2040-0086.Approval expires 3-31-98.Please print or type In the unshaded areas only.

FORM U.S. ENVIRONMENTAL PROTECTION AGENCY

2C EXISTING MANUFACTURING, COMMERCIAL, MINIOIG AND SILVICULTURE OPERATIONSNPDES Consorldialed'Permtls Program

I. OUTFALL LOCATION

For each outfall, list the latitude and longliude of its location to the nearest 15 seconds and the name of the receiving water.A. OUTFALL NUMBER B. LATITUDE C. LONGITUDE

(list) 1. DEG. 2. MIN. 3. SEC. 1. DEG. 2.MaN. 13. SE0;. D. RECEMNG WATER (onme)

602 41 35 59 83 5 5 Internal to 001

801 41 36 4 83 4 12 Intake from Lake Erie

II. FLOWS. SOURCES OF POLLUTION. AND TREATMENT TECHNOLOGIESi. .....a ...a . ..n orw, n w n a am 10 reu-lr aur. .. r..ca.e surces.or...a.e ........ r..ron...n.n...n.wasrewa.. 10....r.......... ..... .. ..... ............. aun.. . . n.. unasIA. Att1ach a line dr~awig shonowg trhe water flow thiroug th~e facility, indicate sources of Intake water, operations controutung wastewater to the effuent, and treatmlent units

labeled to correspond to the more detalied descriptions In Item 8, Construct a water balance on the line drawing by showing average flows between Intakes, operations,treatment units, and outlfalls. If a water balance cannot be determined (e.g,. for certaln ,mInIng activities), provide a pictorial description of the nature and amount of anysources of water end any collection or treatment measures.

B. For each outfall, provide a descripon of: (1) All operations contributing wastewalter to the effluent, Including process wastewater, sanitary wastewater, cooling water,and storm water nrnoff; (2) The average flow contrIbuted by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets ifnecessary.

1. OUT-FALL

NO. (s,3r)

2. OPERATION(S) CONTRIBUTING FLOW I 3. TREATMENT

a. OPERATION (i13t)4 . - -4

602Reneflrate Wactawate., Water Tntmt

W-I~l-'tor, Station drain.,

Screen W. h

b. LIST CODES FROMa. DESCRIPTION TABLE 2C-1

Platat iens-Ht

Sedimenrtation (Setting)1-

Neut•alizat•on 2-K

+ -4

-4 I

OdFFICIAL USE ONLY (rffluenrt gldhllnesrub.-oregortrs)

EPA Form 3510O-2C (8-90) PAGE 1 of 4 CONTIINUE Ott REVERSE

CONTINUED FROM THE FRONT

C. Except for storm runoff, leaks, or spils, are any of the discharges described In Items II-A or B Intermltlent or seasonal?

17 YES (coniptere rhe follou'ing roble) ] NO (go ro S&cnon i10)

3. FREOUENCY 4. FLOW

a. DAYS PER I... TOTAL VOLUME2. OPERATION(s) WEEK b. MONTHS & FLCWRATE {sagd) (sp., c.tlth wur,)

1.OUTFALL CONTRIBUTING FLOW (spe•df PERYEAR J. LONGTERM 2. MAXIMUM, 1, LONG TERM 2. MAXIMUM C. DURATIONNUMBER (fi•t) fIts,) usee) (sPr'.4s1wMge) AVERAGE DAILY AVERAGE DAILY (i'seg,)

002 Circulating water system drain 1 0.71 7004 circulating water eystem drain I 0.86 7

Il.PODUCTION

A. Does an effluent guideline limitation promulgated by EPA under SectIon 304 of the Clean WaterAct apply to your facility?

W] YES (co,,,piere lrtem 1i/1) 0..] NO (go io Section IV)

B. Are the limitations In the applicable effluent guideline expressed In terms of production (or other measure of operation)?

[] YES (compfre lient 111-C) 1] NO (go to SrctI;on l)

C. If you answered 'yes' to Item Ill-B, list the quantity which represents an actual measurement of your level of production, expressed In the terms and units used In theapplicable effluenl guideline. and Indicate the affected outfallA.

1. AVERAGE DAILY PRODUCTION

a. QUANTITY PER DAY b. UNITS OF MEASURE c. OPERATION, PRODUCT, MATERIAL, ETC.2. AFFECTED OUTFALLS

(Ilist orafoll iutsstarr)

IV. IMPROVEMENTSA. Are you novw required by any Federal, State or local authority to meet any Implementation schedule for the construction, upgrading or operations of wastewaler

treatment equipment or pbacllces or any other environmental programs which may affect the discharges descn'bed In this application? ThIs includes, but is not limited to,permit conditlons, admlnlsirative or enforcement orders, enforcement compliance schedule leterm, stipulations, court orders, and grant or loan conditions.

[] YES (com,,plete ltefotlorrlng table) [] NO (xo ta Iterm -B)

1. IDENTIFICATION OF CONDITION. 2. AFFECTED OUTFALLS 4. FINAL COMPLIANCE DATEAGREEMENT, ETC. 3. BRIEF DESCRIPTION OF PROJECT

a. NO. b. SOURCE OF DISCHARGE a. REQUIRED i PROJECTED

B. OPTIONAL: You may attach additional sheets describing any additional waler pollut~cn control programs (or other environmental projects which may affect yourdischarges) you now have underway or which you plan. Indicate whether each program Is now underway or planned, and indicate your actual or planned schedules forconstruction.

E] MARK X IF DESýCRIPTION OF ADDITIONAL CONTSOL PROGRAMS IS ATTACHED

EPA Form 3510-20 (8.90) PAGE 2 of 4 CONTINUE ON PAGE 3EPA Form 3510-2C (8-90) PAGE 2 of 4 CONTINUE ON PAGE 3

I

EPA I.D. NUMBER (copyfrom Item Iof Farmu 1)

0 H0 003786ICONTINUED FROM PAGE 2

V. INTAKE AND EFFLUENT CHARACTERISTICS -

AB, & C: See InstfUctIons before proceeding - Complete one s"ol tables for each outfall - Annotate the outfall number In the space provided.NOTE: Tables V-A. V-B. and V.C are Included on separale sheeats numbered V-1 throuoh V-9.

D. Use the space below to list any of the pollutants listed In Table 2c-3 of the Instnctions, which you know or have reason to belilev Is discharged or may be dischargedfrom any outfall. For every polutant you lIst, briefly describe the reasons you believe It to be present and report any analytical data in your possession,

I. POLLUTANT 2. SOURCE 1. POLLUTANT 2. SOURCE

VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS

Is any pollutant hIsted In Item V-C a substance or a component of a substance which you currently use or manufacture as an intermedlate or final product or byproduct?[i YES (tirall a'ch pot/aw•ats below) 17 NO (go 0o Iter W-B)

EPA Form 35t0-2C (8-90) PAGE 3 of 4 CONTINUE ON REVERSE


VII. BIOLOGICAL TOXICITY TESTING DATA

Do you have any knowledge or reason to believe that any biological tesa for acute or chronic toxIcity has been made on any of your discharges or on a receiving water In'relation to your discharge within the last 3 years?

[] YES (Identif th teit(s) nd ddsc,ibe, their purposes belto) [] NO (go to Section WJL

VIill.CONTRACT ANALYSIS INFORMATION--

Were any of the analyses reported In Item V performed by a contract laboratory or consulting firm?

"7] YES (list the rCaere. ea e£s, ondrirleplrhone nrmrber of endppoelrorrts onalyzed by. [El NO (go to Serion LR)each such lbortoretory orfim] below)

C. TELEPHONE D. POLLUTANTS ANALYZEDXe NAME B.ADDRESS (are code & no.) W(lOs)

EA Group 7118 Industrial Park Blvd 440-951-3514 OrganicsPhenolsCyanide

L, -CERTIFICATION

I cerfify under penaiay of law that this document and all attachments were prepared under my cr~ectlon or supervisWon In accordance with a system designed to assure thatquafilled personnel propedy gather and evaluate the Information submitted. Based on my Inquiy of the person or persons who manage the system or those personsdirectly responsible for gathering the Information, the Infotmation subritted Is, to the best of my knowledge and betleý true, accurate. and complete. I am aware that thereare significant penaites for rubmitting false Information, Including the possib/tly of fine and ImprIsonment for knowing violations.

AL NAMAE & OFFICIAL TITLE (type orprint) i B. PHONE NO. (area role & no.)

Barry S. Allen, Site V.P.- D.B. Nuclear (419) 321-7676

C. SIGN D0. DATE SIGNED

EPA Form 3 5 0O-24/(8-90) PAGE 4 of 4

Davis-Besse Nue. Power Station

Unit No. 1

Ottawa CountyOak Harbor, Ohio

Intalke Crib

Intake

00 MGGD

NMI~ 602 0.22• M0Lake Erie

Outfal ,501Wast t Station

Effluent..... (Outf 00)

Toussoint River

9.PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this Information EPA I.0. NUMBER (oa.J'from Item I I)Form 1)on,separate sheets (use the Same format) inStead of completing these pages. ]000 0003786SEE INSTRUCTIONS.

V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C) - ".-'.. "

PART A -You must provide the results of at least one analysis for every pollutant in this table. Complete one table for eahloutFalL See instructions for additional Oetedil,

3. UNITS 4. INTAKE2- EFFLUENT (sp Mo•n•, .bfak) Copttonal)

.b. MAXIMUM 30 DAYVALUE c. LONG TERM AVRG. VALUE a. LONG TERMa. MAXIMUM DAILY VALUE ial able) NO. OF a. ONCEN- AVERAGEVALUE . NO."(1) " / (1)" A.NALSE TRAIO b. MASS EN- (1)b.N.F

1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (21 MASS (1) CONCENTRATION (21 MASS ANALYSES TRATI MA SS MASS CONCENTRAT1ON I2) MASS ANALYSES

a. Biochemicgl Oxygen 4.5 663.4 M5/1I kg/day xDemand (30D)

b. Chemical Oxygen

Demand (COD) 20.8 3066.6 1 mg/i kg/day

0. Total Organic Carbon 5.73 844.8 1 mg/l kg/day(TOC) 5.73_8__.8__

d. Total SuspendedSolds (7"$s) I 5m/1 k9/day x

e. Ammonia (as N) e0.1 -- 1 Mg/i kg/day

VALUE VALUE VALUE VALUEf. Flow 38.9 24 mgd kg/dayg. Temperature VALUE VALUE VALUE VALUE(,iner)

h. Temperature VALUE VALUE VALUE VALUF(smme) 25.4 4 "C

MINIMUM 8.20 MAXIMUM . MINIMUM MAXIMUM . ..... .LpN8.0 .27. '~~I STANDARDOUNITS

PART B- Mork "X" in column 2-a for each pollutant you know or have reason to belicve is present Mark"X In column 2-b for each pollutant you believe to be absent If you mark column.2a for any potlutant'which'is limited eitherdirectly, or lindirectly but expressly, in an effluent limitations guldeline, you must provide the results of at least one analysis for that pollutant For other pollutants for whlch you mark column 20. you must providet.ntltntitwh, I•tn e•? n svmLn.ssftinn ,nf hoir r•-tunr'r I, unirr di~ch.-rrrt. fmnltP nne" tabe for Ar.•r~hOrt,'at S'ep tire |rve;trum~ors for rrdditinnsl, derails and reaulrirnentr_

2, MARKX" 3. EFFLUENT 4.,UNITS S. INTAKE (aploral1. POLLUTANT b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE

AND 80.MAXIMUM DAILY VALUE W-M614dlI.O a.COe)N VALUE .OFCAS NO. BELIEVED SELIEVED - (. I d. NO. OF a. CONCEN- (t) b. NO. OF(Irf-,ailable) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES

a. Bromide X 0.389 57.4-(24959-67-9) 1 Mg/1 kg/dy .

b. Chlorine. Total .<0t0s - Mg/i kg/dyResidual "

c-Color X 10 -- 1 Units

d. Fecal Coltorr )X 19.5 -- 4 perlO0ml

(.-Fluoride 0.252 36.6 1 mg/i kg/dy(698"4M.) X __262_38.

r.Nitrate-Mt1.te 277.2 mg/i kg/dy(as• M _Ls X•2 9/ •EPA Form 3510-2C (8-90) PAGE V-1 CONTINUE ON REVERSE

ITEM V-3 CONTINUED FROM FRONT2, MARK=X 3. EFFLUENT 4. UNITS 5. INTAKE (optlonol)

1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERMAND a. b. a. MAXIMUM DAILY VALUE (,'afoifoblh) vai-l able) AVERAGE VALUE

GAS NO. BELIEVED BELIEVED (1) (1) (1) ri. NO. OF a. CONCEN- (1) b. NO. OF(ir'•,ailoblC) PRESENT ABSNNT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES

C. Nitrogen.Total Organic (as <0.2 I- -mg/i kg/dy x

h-rOil and <5.0 -- 4 mg/i kg/dyGreaseI. Phosphonu . ,(as P). ToW 0.136 20.1 1ag/1 kg/dy(77W-14-0).

.1 Radloactivity

(1) Alpha, Total

(2) Bota. Total

(3) Radium,Total

(4) Radium 226.Total

Ik. Sulfate(.30.) 49.6 7312.6 mg/1 kg/dy(14808-79-8)

L x <i0 -- 1 mg/i kg/dy

m. Sulfilto(aS <15 -- 1 mg/i kg/dy(14265-45-3) x _ ____

n. Surfactants x 0.006 0.885 1 mg/1 kg/dy

o. Aluminum.Total342 5 41 Ug/1 kg/du x(7429-0-5)

p. Barium, Total 447(7440-30-3) x 41 6.04 1 ug/i kg/dyq. Boron, Total(7440-42-8) x <75 -- 1 ug/1 kg/dy

r. CobalLt Total(744D4-4.4) x - <1.0 -- I g k/l

a. It X 397 58.5 . ug/1 kg/dy x

t Magnesium.Toal 17024 2509.9 1 ug/i kg/dy

u. Motybdonum,Total <2.0 -- . ug/l kg/dy(7439-S,-7) xv. Manganese,Total X 1B 2.7 1 Ug/i. kg/dy

•.i.ot'a- X <•. 0 -- 2. ug/2. kg/dyv.T"in, Total(7440-31-5) ______ <4.0__ _____ I___ ______ kci /

x. Titanlum,Total 8 X 3.0 0.44 1 uS/1 kg/dy('7440-32-6)

EPA Form 3510-2C (8-90) PAGE V-2 CONTINUE ON PAGE V-3

0.

0.

EPA I.D. NUMBER (copyfro,/;h-m I ofF,-r 1) OUTFALL NUMBER

OH0003786 001CONTINUED FROM PAGE 3 OF FORM 2-CPART C - if you are a primary industry and this outfall contains process wastewater, refer to Table 2-2 in the instructions to determine which of the GC/MS fractions you must testYor. Mark "Xý in column 2-a for all such GC/MS

fractions that apply to your industry and for ALL toxic metals, cyanides, and total phendlls. If you are not required to mark column 2-a (secondary industries, nonprocess wastewateroufalls, and nonrequired GC/MSYtsctions). mark "X' in column 2-b for each pollutant you know or have reason to believe Is present Mark "X7 in column 2-c for each pollutant you believe is absent. If you mark column 2a for any poautant. you mustprovide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant you must provide the results of at least one analysis for that pollutant if you know or have reason to believe It wilt bedischarged In concentrations of 10 ppb or greater. If you mark column 2b for acrolein. acrylonltr2e. 2,4 dinlfrophenol, or 2-rmethyl-". 6 dinitrophenol. you must provide the results of at least one anaeysia for each of thesepollutants which you know or have reason to believe that you discharge In concentrations of 1 aD ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis orbriefly describe the reasons the pollutant Is expected to be discharged. Note that there are 7 pages to this part'. please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions foradditional details and requirements.

2. MARK"X 3. EFFLUENT I 4. UNiTS I 5. INTAKE (aorlanali4. UNITS 1 5. INTAKE (oprlonaý

I. POLLUTANT b. MAXIMUM 30 DAYVALUE c.LONG TERM AVRG. a. LONG TERMAND b. c a. MAXIMUM DAILY VALUE (1favailable) VALUE (If aailable) AVERAGE VALUE

CAS NUMBER TES'LNG BELUEVED BELIEVED . i) Ii) (1) d. NO. OF a. CONCEN- (t) b. NO. OF(if avilable) D REQUIRED PRESENT ABSENT CONCENTRATION 2) MASS CONCENTRATION (2) MASS CONCENTRATION 12) MASS ANALYSE TRATION b. S CONCENTRATION (2)2) MASS ANALYSES

METALS, CYANIDE. AND TOTAL PHENOLS

1M.Antimony.Total <8.0 -- 2- ,g/ kg/day(7440-36i-0) --8.0__ _____gda

M" Arsenic Total <10 -- ug/1 kg/day(7440-38-2) _ I3M. Beryllurn, Total < .0 --(7440-41-7) <1 Ug/. kg/day4M. Cadmium, Total <I0 -- 1 Ug/1 kg/day(744N.43-9) , • ...... 0.......Ik

5M. Chromium, <1. 0 1 ug/ kg/da.rTotal (7440-47-3)SM. Copper. Total0(744D-50-8) X 6.0 O.88 i uS/ k9/day x7M. Lead. Total 7(7439-92-1) 7.0 1.03 1 ug/1 kg/day x

SM. Mercury. Total 02 1(7439-97-6) 0.2 - ug/1 kg/day

9M.ke.Tota ... K <40 -- o t./a kg/d(7440-02-0) X__ <4___ .___ 0__ US/)-k9/__

'IOM. Selenium, 28 4.1 1 u9/. kg/dayTotal (7782-49-2) 2. I/ /I1IM. Silver. Total ...0.. .(7440-22-4) X </. k -"/: g9/day

12M. Thallium,Total (7440-28-0) 27 2.9813M. Zinc, Total 9.0 1.337440-65-6) X ug/1 kg/day14M. Cyanide,Total (57-12-5) X <0.005 -4 m9/1 k/day1SM. PhenoLs,Total <504Xgi k/aDIOXIN2,3.7.8-Teira- DESCRIBE RESULTSchlorodibenz(-P-Doxain (11764-01-6)

EPA Form 3510-20 (8-90). PAGEV-3 CON71NUE ON REVERSE

CONTINUED FROM THE FRONT2- MARK *X" 3. EFFLUENT 4. UNITS 5. INTAKE (opod ' I'

1. POLLUTANT b. MAXIMUM 30 DAY VALUE Q. LONG TERM AVRG. a. LONG TERMAND . b. c, a. MAXIMUM DAILY VALUE (Wf-cJlabic) VALUE (W-fa110abfe) AVERAGE VALUE

CAS NUMBER TESTING BEUEVED 3F_,,./50 ( I (1) I "1) d. NO. OF a. CONCEN- (1) b. NO. OF(/f.avolablo) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION 12) MASS CONCENTRA1ION 12) MASS ANALYSES TRATION b. MASS ANALYSES

GCIMS FRACTION -VOLATILE COMPOUNDS

(1.0 702-)x <25 -- 2 ug/h kg/day

2V. Acylonibile2(107-13-1) x <25 -ug/l kg/dy

3V. Benzon¢(71-43-2) x <5.0 -- 3 ug/! kg/day

4V. Sla (Chor-".,.o-vM Elher <5.0 -.- ug/l kg/day(542-88-1) ........ ..... _

5V. Bromoforn ugh kg/day(75-25.2) <5.0

WV. CarbonTobochlodo <5.0 -- 2 ug/1 kg/day(56-23-5)7V. Chlorobenzene <5.0 -- 2 ug/2 kg/day(10-9C0.7) xBV. Chlorodi-bromomeIIha~ <5.0 -- 1 ug/l kg/day

9V. Chloroothane(75-00-3) x <5 . 0 2. ug/I kg/day

0V. 2-Chloro-eWnyl Ether <5o 2. ug/2 kg/cay(110o-75")11v.Chiooformi67-66-3) x -r<5.0 -- 2 ug/1 kg/day

12V. Dichloro-bromomethane <5.0 -- 2 ug/h kg/day(75-27-4) x13V. Dichloro-drnuoromethane <5.0 -- 2 ug/1 kg/day(7&-71-8)x <

14V. 1,1-0D1cloro-ethane (75-34-3) x <5.0 -- 2 ug/! kg/day

15V. 1 ,.2-Dlcloro-ethane (107.0&2) x <5.0 -- .ug/1 kg/day

i6v.1 6V.<5.0 -- 1 ug/2 kg/dayethylene (75-35-4) _ <5_0_a.____________i7V. 1.2-Dlchloro-

propane (78-87-S) X <5.0 -- 2. ug/)l kg/day

ISV. 1.3-Dichloro-propylen¢ <5.0 -- 1 ug/2. kg/day(542-75) -19v. Ethylbcnzene <5.0 -(100-41-4) x < ug/2 kg/day20V. MethylBromide (74-83-9)

21V. Methyl <5.0 I- ug'2/l kg/dayChlordde (74-87-31 ..0..-

EPA Form 3510-2C (8-90) PAGE V-.4 CONTINUE ON PAGE V-5

0.

0:ONTINUED FROM PAGE V.-4

0.

1 2- MARK X° I 3. EFFLUENT 4. UNITS 5. INTAKE (opijono) .1. POLLUTANT b. MAXIMUM 30 DAYVALUE .. LONG TERM AVRG. a. LONG TERM

AND a. b . n. a.MAXIMUM DAILY VALUE (If , allobte) VALUE (If'-pJablbe) AVERAGE VALUE..S.UM B..... ..... . .B U S Y O ( ) d N O , O F a . C O N C E N - " i) b . N O .O FCAS NUMBER "RSUIRNG BPRIVEDS ASEET EMNT(RATION SE TRATION .NCENT ALY(i•'tl~l) REQUIRED PRE:SENT ABSENT ICONCEN(ITýAO (2 AS OO 2) MASS CONCENTA( N(•MS INLSS RTO b. MASS (ONC)TPTION/ ANALY2E

GC/MS FRACTION -VOLATILE COMPOUNDS (canthnned)ZZ.MethyleneMloie Xe < S. 0 1 ug/1 kg/day

Chlo14e (7Z5-09-2) ___________

23V. 1,1.2.2-TetChloethane . <5.0 1 ug/I kg/day24V/. TetrachlOro- %ethylene (2I-.8-4)' <5.0 1 ug/1 kg/dayetJhylene (127.-18-4) ___

25V. Toluene <5. 0 1 Ug/l kg/day(108-88-3) x

26V. 1.2-Trans-Dl0chloroethylene x <5.0 1 Ug/! kg/day

27V. 1.1.1.TtChIoro-ethane ('71-5-6)_ x <5.0 1 Ug/h kg/day

8. 1.2-TacHoro- x A <5.0 1 ug/1 kg/dayZBVr1h~le.r.0-15 <5. 0 1 ug/1 kg/day29V Trc"'0orO-

30V. Trichloto-fluAete <5.0 I ug/l kg/day31NW. Vinyl Chldore * <s. 01 Ug/1 k/

(75ý0 1-4) k g / ....

GC(MS FRACTION -ACID COMPOUNDS

IA. 2-Chlorophenol X <10 1 ri/i kg/day

2A. 2-4-DIcbilo•. 2 ug/l kg/dayphenmol (120-83-2) <10

3A. 2.4-Dlmethyl-phenol (105-67-9) <10 1 ug/1 kg/dy

4A. 4,6-DnlUo-O-lCre301(534-52-1). <50 1 ug/1 kg/day

5A.X2,4Dfrmitrc- 6 <50 1 ug/ kg/dayp h e n o l (5 1- 2 S8 -5 ) . ....

6A. 2-Nitrophenol <10 1 ug/1 kg/day(88-75-5)

7A._4-Nitrophenol \ <50(1000-2-7) X <50 I ug/1 kg/day

8A. P-.ChorO-M-Cro) (5S-30-7) <i0 1 ug/1 kg/day

9A. Penachleto- X <50 1 ug/1 kg/dayphenol (87..88-S)

10A.Phenol X <1 0 1 ughl kg/day

X <10 1 ug/1 kg/day

ph.nol (88-05-2) .....

EPA Form 351 C-2C (8-90) PAGE V-5 CONTINUE ON REVERSE

CONTINUED FROM THE FRONT2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (opfiol)

1. POLLUTANT b. MAXIMUM 30 DAYVALUE c. LONG TERM AVRG. a. LONG TERMAND ). b. I. . MAXIMUM DAILY VALUE (if-,iliaJble) - VALUE (Qf-,-1abkc) AVERAGEVALUECAS NUMBER TESTING BEUEVED BELIEVED - I ' f (1) d. NO. OF a. CONCEN) b. NO. OF

({fivc/1iabf) REQUIRED PRESENT ASENT CONCENTRATION I CONCENTRAT ION (2) MASS - CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES

GO/MS FRACTION - BASE/NEUTRAL COMPOUNDS

19B. Acoaphtliere

2B. Aconaph-tylena

39. AAttvaoenc(120-12-7)49. acnzlIdInc(92-87-5) _ _

SE. Eenzo (0)Anthracerie(565.553)_ _

65t. Oen7c (al)Pyrenc (50-32-S) ____ ____

TB. S,4E8etzo-fluorantlelie(205.90.2) _______ ____________

8B. Eerizo (rfi,)perylene 11.426B. eenzo (k)Fluoraethene(207-08-9) ____

108. 8i (-Ci/ecihoxy) Methane

1113. Ble (2-C/i/ore-

(111-44-4) _____ __________________ _____________

129. Eis (2.chlaoplsoprepylEither (102-80-1) ___ ___ ___ _____________

138. 9SS (2-Edn'I.

149. 4-EromophenylPhenyl Ethier1(101-55-3) 1_______ ____

158. Buryl BeneylPhlhalate (85-68.7)

16S. 2-Chloro-naphthalene

178. 4-Chloro-phenyl Phenyl Ether(7005.72-3) ____________

I188. Chrysene(218-01-9)

Antttracene(53-7".)208. 1 .Z-0chloro-bertzcrte (95.50-1) _______ ____ _______

219B. 1 .3.OI1cAOf.benzene (541.73-1) ____________________________

EPA Form 3510-2C (8-90) PAGE V-6 - CONTINIJE ON PAGE V-7'

0

0CONTINUED FROM PAGE V-6

0.

2- MARKX. . 3. EFFLUENT 4. UNITS 5. INTAKE (ophaowo)1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. o. LONG TERM

AND 0. b, C, a. MAXIMUM DAILY VALUE • (Ifailoie) VALUE (If il able) AVERAGE VALUEGAS NUMBER TEsTnNG BESUEVED SEUSEVED (1) )1) d. NO. OF a. CONCEN- (1) b. NO. OF

(iý/aflable) REQUIRED PRESENT ASSENT CONCENTRAION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CON -•.nON cz MASS ANALYSES

GCJMS FRACTION - BASEINEUTRAL COMPOUNDS (cowidae-)

226. 1,4-OIOhlI~otbenzene (10S-46-7)

23B. 3,3,-Dlchloro.-benzJdine (91-94-1)

248. OlethylPhthalato (84-66-2) _

25B. DimrethylPhtholate(131-11.3)

26B. DI-N-ButylPhthalate (84-74-2)

276.2,4-Olnltro-toluene (121:-14.-2)

286. 2.6-DInltro-toluene (606&20-2)298. Dl--Octyl

Phthlatro (117-84-0)

30& 1.2-Dlphenyl-hydrazine (as AmO-benzene) (122-66-7)

318. •l"uoranthene(206-44-0)

32B. Fluoreno(8r-73.7)_____ __

331. Hexachloro-benzene (118-74-1)

346. Hexachloro-butadiene (87-68-3)

35B. H etachioer-cyclopentadleno(77-47-4)

36B HeXachloro-ethane (67-72-1)

37B. Indeno(l2.3-cd) Pyrone(193-39-S).

386. I3ophorone'Ct8-39-1) ____

39S. Naphthalene9(1-20.3)

403. Nitrobonzene(98-95-3)41B. N-Nltio-oodlmethylamrrno(62-75-9) ______

42B. N-Nitrosodi-N-PropyIamlne(621-64-7)

EPA Form 3510-2C (8-20) PAGE V4-7CONTINUE ON REVERSE

CONTINUED FROM THE FRONTI

2. MARKWX" 3. EIFLUENT 4. UNITS I 5. INTAKE (o:kt,,,aII4. UN 1 5. INTAKE (-tknol)

1. POLLUTANT F b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a: LONG TERMAND . b. r- a. MAXIMUM C)/JLY VALUF.. (IfowIL~ble) VALUE (Ifm~alloUL) AVE.RAGE.VALU I-CAS NUMBER TESTING BELIEVED BELIEVED (1) (1) (1) d. NO. OF a. CONCEN- (2) b. NO. OF

(I4frovaIh!z) REQUIRED PRESENT ABSENT CONCENTRATION 1 (2) MASS C2) MASS OON.0BNTRATIDN (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS IANALYSE

GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (confinued)

4313. N-Nltro-sodliphenylarflifl226-30-6) ________

' 448. Phanathrene

45B. Pyrene(12-00-0)__ _ _ _ _ _ _ __ __ _ _

46B. 1.2.4-TtI-chloroben-nol(120-a2-1) ___ ______ ___ ______ ____

GC/MS FRACTION - PESTICIDES__________

I P. A~drin(:309-00-2) ___ _____

2P. a-BHC(210-84.6)

3P. ý-BHC,(3139-8-5-7)

4P. y-8HC

5?.&8BHC(3196-86) ________ ___ ____

GOP. Chlordanle(57-74-9) ____________ ____

7?. 4.4!-DDT(50-2&-2)

SP'. 4.4'-DOE(72-55-9) ______ _______ ______

9OP. 4.4'-DDD)(72-S4-8)

1lOP. DiIdnidi

li.m-EflosU26(115-29-7) __ ___________ ____

12P. ý-Endosulfan(115-29:-7) ____ ____________ ___________

13P. EndosulfanSulfate(1031-07-M)_______

14P. Edrifti(72-20-8) ____ ____ ____ _____________ ____ ______________

15?P. Enddr%(7421-83-4A(742-93-416P. Heptochlor

I 78-44-8)__________ ___ __


0i

0 0.

EPA .D. NUMBER (copyfroi,- lIofFon,, 1) OUTFALL NUMBER

0H0003786 001CONTINUED FROM PAGE V-8

2. MARKIX" 3. EFFLUENT 4. UNITS 5. INTAKE (Wpik.no,)1. POLLUTANT J .MAXIMUM 30 DAY VALUE Q. LONG TERM AVRG. a. LONG TERM

AND a. a. . MAXJMUM DAILY VALUE (If available) VALUE ((f availablc) AVERAGE VALUECAS NUMBER TESTING BEUEVED BELIEVED (1)d. NO. OF a. CONCEN- b. NO. OF

lab) RQUIRE RE ABSENT CONCENTRATON (2) MASS CONC RATION (2 MASS CONCENTRATION ( 2) A Y TRATON b. MASSI CONCENTRATION (Z) MASS ANALYSES

GCJMS FRAcTION - PESTICIDES (eotI) _ _

17P. HeptachiorEpoxlda(1024-57-3)

18P. PCB-1242(53469-21-,9)

1 9P. PCB-1 254(11097-89-1)20P. P C.3-A221

(11104-28-2)

21P. PCB-1232n(11141-16-5)

22P. PCB-1248(12872-29-2)

23P. PCB-1260(11096-82-5)

24P. PCB-1016(12874-11-2) _______

25P. Toxaphene(8001-35-2)

EPA Form 3510-2C (Eý-90) PAGE V-9

PLEASEPRINTOR TYPE NTHEUNSHADEDAREbAS.ONLY. YmaXIou DrtsmeraY oVfthisLInf-atLonn EPAVI.. VNUMBER (ca..LNomGt TEoMFarm])on separate sheeM (use the Lame forat instead of completing theLe paogesSEE( NSTRUaTIONS. •. a. C•NE-NO 0

V. LNTAKE AND EFFLUENT CHARACTERISTNCS (conA1nued from page 3 of Form 2-CN) ONTAAL YSES

PART A-You must provide the results of at least one analysls for every pollutant in thi table. Cornplete one table for e.ach outlaJI. See instbutdans for additional detalls. "

3. UNITS 4. INTAKE

a. Bloc, hemical Oxcygen <30-1 m/i k/ yDemand (SOD)EFFLUENT

1 l (000-1yb. Chemical Oxygen 22.7 3. I mg/i kg/day

Demand (COD)b.Deman I (Oxyge 22.7 33.7 1 rag/1 kg/day

c. Total Organic Carbon 474 704 1 Mg/i kg/day(Too .4 70 /l k/ y

Id. Total SuspendedSolids (7" n 15 22.3 1 mg/i kg/day x

e. Ammonia (asaM 0.3 0.45 1 mg/i kg/day

VALUE VALUE VALUE VALUEf. Row 0.392 24 Uog/ kg/day

S. Temperature VALUE VALUE VALUE VALUE(wi i ,) -0

h. Temperature M VALUE3D VLVRG. VAE a. LN E A GVALUE

(245,5.) 234 mg" kgd

MINIMUM MAXIMUM IM]INMUM IMAXIMUM L YT

.pH 7 STANDARD UNITS

7. C.lor..... . .. kg/d..

PARTSB- Mark X" in column 2.-a for each pollutant you know or have reason to believe is present. Mark "X" in column 2-b for each pollutant you believe to be absent, If you mark col~mn 2a for any pollutant "qhlch is limited eitherdirectly. or indirectly but expressly, in an effluent Ilmitations guideline, you must provide the resuits of at least one analysis for that pollutant For other pollutants for which you mark coiumnn 2a, you must providequantitative data or an explanation of their Presenc~e in your dftcharge. Complete one table for each outfall. See the instruct~ons,.for additional details and requirements. .,

1. 2. MARKX" 3. EFFLUENT 4. UNITS 5. INTAKE (optional)1.PCLTN b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE I15LN TR VRAE ..AND a. b. a. MAXIMUM DAILYVALUE 6(anm~leb (i,/-nollabte) VALUE

CAS'NO. SELIED BELIEVED 1 1)( d. NO. OF a. CONCEN- 0i) b. NO. OF.(Jfmv fbble) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TPATION to, MASS CONCEN-fRATrION • MS ANALYSES

a. Br4mide(2495"7.9) X <X0. 03 01 1 Mg/1 kg/dy

b. Chlorine, TotNIl 0 mg/i kg/dyResdual <00 I-4 m/ •d

c.Color X 5 1 unlits kg/dy

d. Fecal Colfom X 147.8 -- 4 perlO Orl kg/dy

e Fluoride 0.21. 0.31! 1 .mg/1 kg/dyf. Nl~trat-Nlitr i 1

(as v)I 0.36 0.53 1 kg/dy

EPA Form 3510-2C (8-90) PAGE V-1 CONTINUE ON REVERSE

0

0.ITEM V-6 CONTINUED FROM FRONT

2, MARK1X' 3. EFFLUENT r 4. UNITS 5. INTAKE (oprion'l)i. POLLUTANT B 8b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM

AND a. b, a. MAXIMUM DAILY VALUE (ifrailabir) Qvtobk) AVERAGE VALUECAS NO. BE 0 EIEVED(1) d. NO. OF a. CONCEN- - b. NO. OF

(fovaI/c) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES

Tota Organlc (x 0.39 0.5B 1 rmg/! kqrdy x

In. Oil and "

Grease x <5.0 -- 4 mg/i kg/dy

L Phosphorus(as P).Tolal 0.06 0.08 1 mg/i kg/dy x

1. Radioactivity

(1) Alpha, Total

(2) Beta. Total

(4) Radium,Total(4) Radium 226,

k. Sulfate(-.so) 76.8 114.1 1 mrg/i kg/dy(14-80&7"4) 7. 1x4.1. Sulfide(= S X <10 I mg/i kg/dy

m. Sulfite(-s SO,) X <15 -- I mg/i kg/dy(14265-45-3) x

n. Surfuctants x 0.005 0.0 07 1 mg/1 kg/dy x

o. Aluminum,Total 275 041 ug/1 kg/dtz x(7429-90-5) 2

p. Barium. Total 34.,(7440-39-3) 7v 3 0 0.04 1 ug/, kg/dy_q. Boron, Total(744D-42-8 <75 -- 1 ug/i kg/dyr. Cobalt, Total Ig/i kg/dy,(7440-48-4) <1.0 -- _u . /

S Iro 9n, Total 278 0.41 1 ug/1 kg/dy x

L Magno.sium,T n2713 18.89 1 ug/i kg/dy

(743-9-95-4) 1

LL Molybdenium.Total X <2.0 -- 1 ug/i kg/dy(7439-98-7) x

Manganese, X2 .Total X 6 0.04 1 ug/1 kg/dy1(743&).-s

x. Tiotai(7440-31-5)] X 6 0.01 1 ug/ 1, kg/dy

-Total 1.0 .C 0 1 ug/1 kg/dy x(744D-32-6) ...

EPA Form 3510-2C (8-90) PAG EV-2 CONTINUE ON PAGE V-3

EPA LD. NUMBER (cop),fromf q 1 efFortn 1) OUTFALL NUMBER

0H0003786 002I'CONTINUED FROM PAGE 3 OF FORM 2-C

PART C - If you are a primary industry and this ouffall contains process wastewater, refer to Table 2c-2 In the Instructions to detenrine which of the GCIMS fractions you must test for. Mark 'X" in column 2-a for all such GC/MSfractions that apply to your industry and for ALL toxic metals. cyanides, and total phenols. If you are not required to mark column 2-a (secondary lndustnies. nonproco•, wasewater ou'fa//s. and nonrequired GC/MS

fractions), mark *X" in column 2-b for each pollutant you know or have reason to believe Is present. Mark X in column 2-c for each pollutant you believe is absent If you mark column 2a for any pollutant, you mustprovide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe It Will bedischarged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein. acrylonitrile, 2,4 dinitrophenol, or 2-methyl-4. 6 dinitophenol, you must provide the results of st least one analysis for each of thesepollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis orbriefly deScribe the reasons the pollutant Is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table(a/l 7 pages) for each outfalL See Instructions foradditional details and requirements.

2- MARK-X" 3. EFFLUENT I 4. UNITS 5. INTAKE rno'lonai)4. UNIT$

I. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAND a. b. • a. MAXIMUM DAILY VALUE (ifuailoblc) VALUE (QovoiI able) AVERAGEVALUE

GAS NUMBER TESTING BELUEVED BELIEVED (1) 11 I d. NO. OF a. CONCEN- bii I. NO. OF(fcvallabln) REQUIREC PRESENT ABSENT CONCENTRATION 1 12) MASS CONCENTRATION 1 (2) MASS CONCENTRATION 121 MASS ANALYSES TRATION b. MASS CONCINTRATION 121 MASS NALYSES

NAFTAI 51 rtVANI[%I:: ANt' TflTAI PHFNrII 5;

IM. Antimony, Total .8.1 1 kG/dyC7440-36-0) IIIIIII

2M.ANacalc. Total x<a:0 -.- 1 g kg/day(7440-36-2) _5___1_1_

3-M. Bcnyrium, Total '-X <1.0 1 Ug/1 k9/day(7440.41-7) 1" -

4M. Cadmium, Total X <i0 1 ,ug/1 kg/day(7 D-43,-9)

SM. Chromiun. <1. 0 1 ug!1 kg/ dayTotal (7440-47-3) .6M. Copper. Total X4.0 1 u9/1 kg/day(7439.SO-9l-_) <_._ __--_ _ __ /_ k _/7M. Lead. To~al X 5.0 0.01 1 ug/l kg/day x.

OK. Mercuy. Total <0.2 -- 1 'ug/1 kg/day(7430-97-6)SM. Nickel, Total <4. 0 -- 1' ug9/ kg/day(7440-02-0) X

1DM. Selenium, 17 0.03 x Ug/1 k9/dayTotal (7782-4.-2) X 0 . I11 M. Sliver, Total <>. 0 -- 1 Ug/1 kg/day(7440-22-4) X__0 __Ik_

12M. Thallium, 1 kg/day XTotal=7440-280) 17 0.03 ug/113M. Zinc. Total 1 ug/2 kg/day X(7440-66-6) X14 0.02

14M. Cyanide.Total (57-12-5) X <0. 05 -- . mgl kg/day

SMt Phenols. <.0 -- 4 Ug/1 kg/dayTotal...,

DIOXIN2.3.7,8-Tetra-. DESCRIBE RESULTSchllrodibenzo-P-Doioan (1764-01-6


0

0.CONTINUED FROM THE FRONT

2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (opflonci"1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND a. b. e. a. MAXI MUM DAILY VALUE (if-0J1ob1c) VALUE (i, avllao&,) AVERAGE VALUECAS NUMBER TESTING BEUVEDVBEEUEVED " e1 e1 d. NO. OF a. CONCEN- ý ' b. NO. OF

(f av&Aolbf) REQUIRED .PRESENT ABETCONCENTRA'iON (2) MASS CONcENTRAION (2) MASS CONCENTRATION (2) M AA LYS E TRTON b. MASS ICONCENTRATION (21 MASS NALYSE

GC/MS FRACTION-VOLATILE COMPOUNDS

iV. Accrolel5(107-02-8) 1 1 g/ kg/dy

2V.Aryionlotrile(107-13-1) x<2 -- 1 ug/h kg/day

3V. Benzene(71-43-2) x <5.0 -- 1 ug/l ks/day

4V. 8Et (Chibe.-.cihy EthV <5.0 -- 1 Ug/1 kg/day(542$88-1) x

SV, Bromofoarn 075-25-2) <5.0 -- 1 ug/1 kg/day

5V. CarbonTeO-achlorlde %Ttahrie<S.D0 -- 1 ug/1 kg/day(55-2:3-5) _____

TV. Chlorobenazene(IO8Sg-7/ <5.0 1-l ug/1 kg/day

8v. Chlorodl-bromomethale 105.0 -- '1 0 u/1 kg/day(124-48-)

9V. Chloroetr]ano(75-00-3) x <5.0 - -_ug/1 kg/day

ioV. 2-Chloro-(y11 (.lEO.)r x5.0 -- 1 ug/1 kg/day(110-75-8) ....... ....______________________ _______ _____

11V. Chloroform(67-_6-3) x <5.0 -- 1 ug/1 kg/day

12V. Dichloro-bromomethane <5.0 -- 1 Ug/l kg/day(75-27-4)13V. Dichioro-diuoromthane <5.0 -- 1 u0/1 kg/day(75-71-8) x ______ ug/_______

14V. I1,-Dlchlor-/ethane (75-34-3) /N. 0S-D 1 U0/1 kg/day

15V, 1.2-Dlchioro-ethane (107-0452) x <5.0 -a- ug/1 kg/day

16V. 1.1-DIohloro-oiiylene (75-35-4) x <5, 0 -1 ug/ ky/d'ay

17V. 1,2-DI¢.,hioro-ppne (78-87-5)- <5.0 -- 1 ug/I kg/day

18V. 13-Dicrhloro- .g /

propylenre <5.0 -- 1 ug/1 kg/day(542-75-6) -19V. Ethyibg nr, nt

I 0 tý41-4) x <5 .0 -- 1 ug/1 kg/day

2OV. MethylBromlde (74-83-4) __ 5.0 , j

21V. Methyl 0 1 ug/I kg/dayChloride (74-87-3) 50 -

EPA Form 351 Q-2C ("0) PAGE V.-4 CONTINUE ON PAGE V-5

cONwNUED FROM PAGEV.-42. MARKX" 3. EFFLUENT 4. UNITS 5. INTAKE (opilon.a)

1. POLLUTANT b. MAXIMUM 30 DAY VALUE c LONG TERM AVRG. a. LONG TERMAND a. b. -a. MAXIMUM DAILY VALUE -c•labtle) VALUE (if ovall•ai) AVERAGE VALUE

CAS NUMBER TESiING BEUEVED BEUEV*ED (1) (i){(1) a. CONCEN- b. NO. OF(ifavafiable) REQUIRED PRESENT ABSENT CONCENTRATION 2) MASS I CONCENTRATION 1 (2) MASSI CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATIONI (2 MA-S NALYSES

GO/MS FRACTION -VOLATILE COMPOUNDS (coniwtid) -

ethylene <5.0 -- ug/1 kg/dayChlorda (75&09-2)

23V. 1.1 a2-.2thane <5.0 -- 1 ug/! kg/day

24V. Tetrachloro-ethylene (127-18-4) - 1 uql) kg/day

25V.Toluene 5 I(i OE-8&3) <5.0 -- 1 Ug/ kg/day26V. 1,2-Trans-Oichitoethylene <5.0 -- 1 us/I kg/day(156-60-5) 1 x _____

27V. 1,1.1-Trichlorc- kgd"ethane (71•55-) .\ <5.0 -- 1 uS/I kg/day

28V. 1.1.2.Trtchloro- <5.0 -- 1 U/ kg/dayethane (79-00-5) I

25V Tfthloro. <5.0 -- 1 ug/l kg/dayethylene (79-01-6) x30V. Trichloro.lluommethznI ' < 5. -- 1 ug/1 kg/day31V.\Aiyl Chliolde <5.0 -- "1 U/. k/ayC75-01-4)

GC/MS FRACTION-ACID COMPOUNDS

IA. 2-Chlorophenol. .k/9-Z-h7-8 x <10 -- I ug/1 kg/day.?A_ 2.4-Dichloro-phenol (12043.2) x <10 :L ug/1 kg/day

3A. 2.4-DimethyF- <10 -- 1 uq/1 kg/dayphenol (105-67-9) x4A.S-OInitro- X <50 -- 1 ug/1 kg/dayCresol (534-52-1)

12.5) <50 -- 1 ug/1 kg/dayphenol (51-2.8-5)

6A. 2-Nrophnol --1 1 ug/h kg/day(88-75-5) I7A. 4-Nltrophenol so - gh kg/day(100-02-7) x <S_- 1_____/a8A. P-Chloro-M-D/esol (55-50-7)

A. Pent<chloro- -- 1 ug/1 kg/dayphenol (87-86-5) x10A. Phenol <10 ug/1 kg/day(1 08-95t2) _____

I___ ___________________ _____

il(2.4,8-95T-l2 o <10 -- 1 uS/1 kg/dayphenol (88-05-2) ______________

EPA Form 3510-ZC (8-90) PAGE V-5 CONTINUE ON REVERSE

0

0CONTINUED FROM THE FRONT

2. MARK "X" 3. EFFLUENT 4. UNITS 5: INTAKE (op lono71)1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LO.WG TERM AVRG. a. LONG TERM

AND 0. b. c. a. MAXIMUM DAILY VALUE (fm'la, l•e) VALUE (/fooi bb)ý AVERAGE VALUECAS NUMBER TESTING BELIEVED BELlEVED ( I (I) (1). -- d. NO. OF a. CONCEN- b. NO. OF

(/.#vo,.blc) REQUIRED PRESENT ASENT CONCENTRATION (21 MASS CONCENTRATION (2 MASS CONCENTRArTON I2IMASS ANALYSES TRATiON b. MASS CONCENTRATION 1) MASS ANALYSES

GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS

(83_32_9)B cnptea-Ig/ k/,y

2B. Acenahylen -- 1 u'l k'day(208-96-8) x __0 -- ! ug/ k/ay31nhr)cene x <10 1 ag/ 1 kg/day

48. Benzidine(92-87-5) x <SO 0 -- _ I kg /clay5s. Benzo ()A(,lllacene X <10 -- 1 ug/ kg/day158..55-3) ____ _______

6P. Senezo (o-) x <iD -- 1 ug/ kg/dayFPyrone (50.-32A878. 3,4-Benzo-

'uoznlhne - <10 . . 1 ug/1 kg/day

88. Benzo (< x _10 1 ug kPeryle (191-24-Z) -lkg/day

98. Benzo (k)Fluolnthone <10 -- 1 ug/1 kg/day(207-08-9) _108. Els (3-C<ho,o-ahowy) Methane <10 a. 1 lg/l kg/day1111-91•-I) ,,.- g/ g/a118. BEl (2-Chloro-r,"kI) Ether <0 -- 1 ug/1 k/day

12B. BIS (2-C•hlomoprpyo <10 -u/1 kg/dalyEther (102-80-1) A139. BIa 12.&h,/-hery) Phthamtae " <10 -- 1 uday(1"7-81-T) g148. 4-1-omophenylPhonyl Ether <10 -- ug/l k/day(101-55-3) . kIa .

15B., BtylBenzyl <10 -- 1 ug/ kg/dayPhthalate (85-68-7)

168. 2-Chloro-naphthalenre <10 -- 1 ug/1 kg/day1(91-589-TI ________ _____ ______

17B, 4-Chlor o-

phonyl Phonyl Ether <10 - - 1 ug/ kg/day(7005-72-3) 11118B. Chrysene <10 -- e ug/1 kg/day(211-9) kg/day198. Diberzo (-.h),

Anzecene (0<10 -- 1 ug/1 kg/day(53-70-.3)208. 1.2-C)ichloro- 1 g l k / a

benzene(5-50-) <10 -- 1 ug/( kg/dayePA.Forn 3 510-27(-9) PAG< V---ONTINUE/O PAGE V-


CON-flNUED FROM PAGE V-62. MARK1X" 3. EFFLUENT 4. UNITS 5. INTAKE (opliono

1. 'POLLUTANT Eb. MAXIMUM 30 DAY VALUE I. LONG TERM AVRG. a. LONG TERMAND a. b. I C. a. MAXIMUM DAILYVAI UE (!J-alaabk)j VALUE (/ oj,67blabe) OF a. COFE "AVEzRAGEVALUE b. NO. OFCAS NUMBER TESTING BELIEVED BEUEvE. (1) O. O a. CONCEN..('• NI 2. NO.OEF

(ifavalablc) REQUIRED PRESENT ABSENT CONCENTRATION 1 (21 MASS CONCENTRATION 1 (21 MASS. CONCENTRATON (2) MASS ANALYSES TRATION b. MASS NCENT

GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (conlmr4d)

22B. ,4- r-Dchloro 10 -1 ug/! kg/daybenzene (108-46-7) <10 1 1238. 3.3-DichlorO- NybenZldOn* (91-94-1) <20 - - 1 U/ kg/day248. D1ethyiPhihalSte (&4-6r-2) <10 1 ugS/ kg/day

258. DimethylPhthalate <10 -- I ug/ kg/day(131 -11-3) .

26B. OI-N-ButyI x .0 ug/l ks/dayPhthalate (84-74-Z)

278. .4-Oilntro-toluene (121-14-2) <10 -- 1 ug/ kg/day

28. .,E-Olnitro-touueCiC (806-•0-2) x <10 I ug/! kg/day

298. DIN-Ocryl 0PhthaIOe (117-84-0) <10 - ug/I kg/day30B. 1.2-Dlphenyl-hydrazlne (OsAZD- <50 -- ks/daybenzene) (122-W7) xg

31B. Ruoranthene(206-44-0) x <10 -- ug/l kg/day

328. Fluorene N(8&-73-7) 1<0 - -1 ug/1 kg/day

338. HexachlorO-benzene (118-74-1) <10 -- 1 u9/1 kg/day

34a. Hexachloro- <0U/1 k/abutadleno (87- __-3) . <10 -- 1 Ug/ kg/day35a. HIma chloro-cydopentacuene r <10 -- 1 ug/l kg/day(77-47-4) .. .. .. . . .. .

368 Hexa=&Ioro- <11 ug/1 kg/dayethane (67-72-1) <O-1__<_378. IndenO(1.z3-51) Pyrone x <10 -- 1 ug/l kg/day

388. Isophorone .<10 ug/ kg/day('78-59-1) - I -1 US' s/a

39 Naph enekg/day(91-20-3) I <I0 -- 1 _/__k_/__

408, Nitrobcnzene(98-97-2) x0 CIO I u_/l k/day

41 8, N-Nltro-soolmethylamn-fe <10 -- 1 Ug/l kg//day(82-7&09142B. N-Nltrosodl-N-Propylamne <10 -- 1 ug/1 kg/day(621-14 ... . ...


W

0 0.pCONTINUED FROM THE FRONT

2. MARK X" I 3. EFFLUENT 4. UNITS 1 5. INTA.KE (optiomat)1. POLLUTANT ' I b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. I a. LONG TERM

AND I , a. MAXIMUM DAILY VALUE I f W.'oiible) VALUE (0f, OF a.bleE) AVERAGEVALUECAS NUMBER TFSTI1NG BELI8VED BUEVED (1) I (1) (1) ' d. NO. OF a. CONCEN- (1) b. NO. OF

(i availal"e) REUIRBO PRESENT' ABSENT CONCENTRATION I (2) MASS CONCENTRAT ON I (2) MASS CONCENTRATION MA ANALYSES TRATION b. MASS CONCENTRATION (2) A PALYS

GO/MS FRACTION - SASS/NEUTRAL COMPOUNDS (conlimied) ___________________

438. N.N~trc-sodlPhenylallllfl <10 2. Ug/ kg/day(88-30-81443.- phonanthIreno

1 45 , nox2.1 u g / 1 k g / d a y

2P9. Pyeoa

43P. 1.,-TB-

(319-65-7)

4P. a-EHO(319-84-9) _ _

6P. Ch-ordsC

(58-74-9)

7P. 4.4-DO)T(50-29-3) ______

8P. 44-ODE(72-5-5-9) ________

9P. 4.4'-00

10p. 0licdrIn(80-57_1)___________

1 IP.ct-Enosulfafl(115.29.>7) _ ___

12P. p-Enbosu~fan(11 5-2sl),___ ______ ____

13P. Encdosuk1On

(1031-07-6) ___________ ____ ______

14P. Endenf(72-20-8) _________

iSP, EndrinAldehyda(7421.93-4) ____ ___________ ____

(76-44-8) _ __

EPA Form 3510-2C (8-9 0) PAGE V-8 CONTINUE ON PAGE V-9

EPA Form 3510-2C (8-90) PAGE V-9

0

- 0

PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this Information EPA I.D. NUMBER (copyftom h.n / qfFa.r/ )on separate sheets (use the same forma) instead of completing these pages. OH0003786SEE INSTRUCTIONS.

V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 o Fnorm 2-C)OUTFALL NO.

03

PART A-You must provide the results of at least one analysis for every pollutant In this table. Complete one table for each outfaIll. See lstructions for additional detal.s.

3. UNITS 4. INTAKE2. EFFLUENT (SpzciIý ltlank) (opuo-eea)

b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE ' a. LONG TERMa. MAXIMUM DAILY VALUE (If-01a 10bc) (Wif eiot ) AVERAGEVALUE

1) (I) d. NO. OF a. CONCEN- () b. NO. OF1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION 121 MASS ANALYSES TRATION b. MASS CONCENTRATION 12) MASS ANALYSES

a. BlochemicaJ Oxygen 6 5.04 1 m9//1 kg/day xDemand (BOD)

b. Chemical Oxygen 24.6 20.7 1 t/1 kg/dayDemand (COD)

r- Total Organic Carbon(TOrP 4.26 3.58 1 mg/1 kg/day

d. Total SuspendedSolids (TSS) 16 13.5 1 mg/i kg/day x

c. Ammonia (as N) 0.144 0.120 1 mg/i kg/day

VALUE VALUE VALUE 24.... / VALUEf. Flew D. 222 24 mgd I kg/day

g. Temperature VALUE VALUE VALUE VALUE(w•n•er) C

h. Temperature VALUE' VALUE VALUE VALUE(a,,me,) 22.9 4 C

L. PH 1 .91 8.14 4MX U 4 1111'5

PART B- Mark *X In coIumn 2-a for each pollutant you know or have reason to believe is present. Mark *X" in column 2-b for each pollutant you believe to be absent If you mark column 2a for any pollutant which is limited eitherdirecty. or indirectly but expressly, in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant For other pollutants for which you mark column 2a, you must providequantitative data oran explanation of their presence in your discharge. Complete one table for each outfall. Seethe instructions for additional details and requirements.

2. MARKX* 3.EFFLUENT 4. UNITS S. INTAKE Cop.o ..1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE

AND a. b. a. MAXIMUM DAILY VALUE (if a0ailable) (iailable) VALUECAS NO. BUEVED BELIEVED (1) (1) d. NO. OF a. CONCEN b. NO. OF'

(Ifoval/lable) PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (1) MASS ANALYSES

a. Bromide(24959-67-9) X <0. 03 -1 Mg/ kg/dy

b. ChloIneTo .alResidual

c. polor

d. Fecal Coliforme. Fluoride

(16984-48") X 0.200 0.170 1 mg/i kg/dyý.Nsltret.mtrite X 0.631 .531 2. tog/I kg/dy xEPA. oe 351 -(-SO PAG v....CON..INU...ON..REVER..EEPA Form 3510-2C (8-90) PAGE V-1 CONTINUE ON REVERSE

ITEM V-8 CONTINUED FROM FRONT2..MARK " 3. EFFLUENT ...._4. UNITS S. INTAKE (opoliona•)

1. POLLUTANT ' ...... b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG, VALUE a. LONG TERMAND a. b. a. MAXIMUM DAILY VALUE (ffo,,lloble) (QfoiLea.) . AVERAGEVALUE

CAS NO. BELIEVED BELIEVED (1) (1) (1) d. NO. OF a. CONCEN- (1 b. NO. OF

o'•zvoblo) PRESENT ABSENT CO..NC.ENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b.MASS CONCENTRATION (2 MASS ANALYSES

a. Nitrogen.Total Organic (os

h. OIl endGreaseL Phosphorus(as P). TotalC1723-1 4-0)

J. Radloactvity

(1) Alpha, Total

(2) Beta. Total

(3) Radium,Total


%. Sulfate(14.6) 30279 1 mg/i kg/dy

L Sulfide(*S)m. Sufite

(142&--45-3)

n. Surfactannt

o. AJumInum,Total(7429-90-5)p. Barium. Total(7440-39-3)q. Boron. Total(7440-42-8)r. Cobalt, Total(7440-48-4) ____

s. Iron. Total(743M9-69-) ___

I Magnesium.Totala7439-95-4)u. Molybdenum,Total(7439-98-7)v. Manganese,Total(7439-9-) __-s,,___

w. Th. ToalC7440-31-5)x. TntanIum,

(744D-32-6)

EPA Form 3510-2C (840) PAGE V-2 CONTINUE ON PAGE v-3

EPA I.D. NUMBER (copyframole I of Form 1) - OUTFALL NUMBER

OH0003786 1 003 LCONT]NUED FROM PAGE 3 OF FORM 2.-CPART C - If you are a pimary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark -X- In column 2-a for all such GC/MS

fractions that apply to your industry and for ALL foxlc metals, cyanides. and total phenols. If you are not required to mark column 2-a (secondary industries. ronproce.• vaoeswater outf al, and rronreqtred GC/MSfractions), mard "X In column 2-b for each pollutant you know or have reason to believe is present Mark WX in column 2-c for each pollutant you believe Is absent If you mnark column 28 for any pollutant, you mustprovide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe It will bedischarged In concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitrie, 2.4 dinltrophenol. or 2-methyl-4. 6 dlnitrophenol. you must provide the results of at least one analysis for each of thesepollutants which you know or have reason to believe that you dlscharge In concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either Submit at least one analysis orbriefly describe the reasons the pollutant Is expected to be ischarged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each ouffall. See instructions foradditlonal details and reoufrernents.

2. MARK WX' 3. EFFLUENT 1 4. UNITS 1 5. INTAKE (optriol)1. POLLUTANT b..MAXIMUM30DAYVALUE c. LONG TERM AVRG. a. LONG TERM

AND a. b. a. MAXJMUM DAILY VALUE . AMM VALUE (tifvic) AVERAGEVALUVECAS NUMBER TESTING BELEVED IBLIeVED (1) MS dI N NO. OF a. CONCEN- b b. NO. OF

(t(owabalab) REQUIRED PRESENT ASSENT I CONCENTRAIoNi 121 MASS tCONCENTRATION I2) MASSI CONCENTRATION 1 21 mASS ANALYSES TRATION b. MASS CON 'RATION 1(21) MSS JANALYSES

METALS. CYANIDE. AND TOTAL PHENOLS

I M. Antimony, Total(7440-36-0)

2M. Arsenic. Total(7440--2) ,

3M. Beryllium, Total(7440-41-7)

1M. Cadmlum, Total(7440-43.9)

SM, Chromrium.Total (744047-.,3)

6M. Copper, Total(7440-50-8)

7M. Lead, Total(743"Z52i) ____

aM. Mercury, Total(743"..7--S)9M. Nickel. Total(7440-02-0)1DM. Selenium.

Total (7782-49-2)

I I M. Silver, Total(7440-22-4)

12M. Thallum,Total (7440-28-0)

13M. Zinc, Total(T440-66-6)

14M. Cyanide.Total (57-1 2-5)

iSM. Phenols.TotalDIOXIN

2.3.7.8-Tet-r - DESCRIBE RESULTSchlonodi..en.o-P-Dioxin 11784"1-6)

EPA Form• 3s1-2C (a-9) PAGE V-3 CONTINUE ON REVERSE

ICIM11NI IFr FROM TI-E~ FRONTCONTINUED FROM THE FRONT

2. MARK X" 3. EFFLUENT I 4. UN)TS I 5. INTAE (oolionrat) 11 4. UN S 1 5. INTAKE abnaO

1. POLLUTANT b. ,MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAND e. b. , . MAXIMUM DAILY VALUE (,fl ~ble) VALUE (Wfoal/able) AVERAGE VALUE

CASNNUMBER TESTING BEUEVED B(E\EE 1) (d) . . . l. NO. OF a. CONCEN- ba. NO OF(i~f ,vailabe) R8CUIRE- PRESENT ABSENT CONCSNTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION 3) MS ANALYSES TRATION '. MASS CONCENTRATION I)FMASS ANALYSES

Gu/ms FRACTION -VOLATILE COMPOUNDS

lV. Accrolcln(107.02-a)

2V. Acryloleett~(107-13-1) ____________ ____

3V. Berzon*(71-43-2) _________ ____

4v. alaS (Cbforo,mcikyO Ether

5V. Brrnioforrm(75-25-2) __ ____ ___

6V, CarbonTetrachloride

7V - Chlorobenzole,(108-90-7) ____ ____

5V. Chlorodil-brornomnethamo(I12A48-41)

RV. Chloroolarlo(75-00.3) ___________

I OV. 2-Chloro-ethyvlnyl Ether1010-7-5-8) ______ ___

I IV. Chloroform(87-85-3)

12V. Dicliloro-bromomnethone(75-Z7-4) ____

l3Vi Olcirloro-d turoehane(7&-71-8) __ ________ __ ___

14V. 1.1-DIChIc~rO-ethane (7$,34-S) _ __

Isv. 1.2.D1chlorO.ethrane (107-06-2) ___

isv. 1 .i-DIchIoro-ethylene (75.35.4) _________ _______

17V. 1 .2.0ithlpro_propane (78-87-5)18V. 1.5-DiohlorO-propylene(542-75-6)

i9V. Ethylberrefle(100-41-4)

20V. MethylBromide (74-83-9) ____

21V. MethylChloride (473 ____________________________________

EPA Form 351 D-2C (8-90)PAGE V-4 CONTINUE ON PAGE V-5

CONTINUED FROM PAGE V-4

2. MARKX'X 3. EFFLUENT 4. UNITS 5. INTAKE (oplionol)1. POLLUTANT' b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. -. LONG TERM

AND a. b. c a. MAXIMUM DAILY VALUE (I. a'oobkI VALUE (afovoilobtc) AVERAGE VALUECAS NUMBER TESTING BFUEVEO BELIEVED (1) i I (1) d. NO. OF a. CONCEN- (II b. NO. OF

(If avalaMek) REQUIREDý PRESENT ABSENT CONCENTRATION _(2) MASS CONCENTRRATION (2) MASS CONCETrRAT1ON 1(2 MASS ANALYSESý TRATION b. MASS CONCENTRA'lON (21 MASS ANALYSES

GCJMS FRACTION -VOLAIlLE COMPOUNDS (conrh-ed)

22V. MethyleneChlorde (75409-2) .......

23v. 1.1.22-Tetracnloroehane

24V. Teb-•chlora-othyleno (127-18-4) " _

25V. Toluene(105-05-3) __ ________ ____

29V. 1.-Trans-DCahloroethyleno(15s.60- ......

27V. 11,i.-Trichloro-ethJane (71-55-6)

28V. 1,1.2-Trdchloro-ethane (7S-00-5)Z9V TrIchloro-ethylene (79-01-6)30V. Trichloro-fluorometh nn(7.,-69-4) , __

31V. Vinyl Chltrode(75-01-4)

GCIMS FRACTION - ACID COMPOUNDS

1A. 2-Chlorophenol(95-57-8)

2A, 2.4-DichWro-phenol (120-83-2)3A. 2,4.Dimethyl-

phenol (105-67-9)

4A. 4,6-DInlto-O-Cresol (534-52.1)5A 2,4-Dlnitro.phenol (51-28.5)

SA. 2.Nitrophenol(M8875-5) ......

7A .4-Nltrophenol(1 00-02-7)1A. P-Chleorc-M-CrLsol (59-50-7)

9A. PentLchloro-phenol (87-86-5)

10A. Phenol(108-95-2)

11 A. 2.4,6-Trchloro-phenol (588.5-2)

EPA Form 351 0-2C (-0 PAG EV.-5 CONTINUE ON REVERSE

CONTINUED FROM THE FRONT2- MARKIX" 3. EFFLUENT 4. UNITS 5. INTAKE ({pdow) ,

4.POLLUTANT b. MAXIMUM 30 DAY VALUE c LONG TERM AVRG. a. LONG TERMAND 1. a. MAXIM UM DAILY VALUE (i~~iolJVALUE {IOr--,aJble) AVE RAG EVALUE

CAS NUMBER TESTING BEU`VEDV ELIUEVEB (1) "). I d. NO. OF a. CONCEN- (1) b. NO. OF(J(avlkabh4) REQUIREDJ PRESENT ABSENT CONCENTRATION C2) MASS CONCENTRATION (2) MASS CONCENTRATION I (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES

GC(MS FRACTION - BASE/NEUTRAL COMPOUNDS .....

' S. Acenaphthone(58-32.9) ____ ____

218. AcenaphryIen e(208""8-8) ,

38.Ant•mcene(12012.)1____ _______

48. Benzidine(02-87-5)58. Senzo (W)Anthrcane

Ba. Bermo (a)Pyrene (50-32)8)

7B. 3,4-Benzo-fluoranthene(205-99-2)

88. Benzo (gl/)Porylene (191-24-2)

9B. Berzo (k),luoranthene

(207.08-9)

10B. BIs (2-Chdoro-(flhoxy) Methane(11 1-91-1) ___________

418 . Bls (2..Chfawo-

'hy/) Ether(111-44-4)128. BLs (p.ChforoL•sopopyo

thner (1 02-80-1)

138. Bis(2EbJ],-Ay) Phthalate(117-81-7)

14B. 4-BromophenylPhenyl Ether'(101-55-3) _________

15S8. Butyl BenwyiPhthalate (85.68-7)

165. 27-Chloro-naphthalene(91-58.7) ___ ____

179. 4-Chloro.phenyl Phenyl Ether(7005&72-3)

183. Chrysene(21"18.0.) ______

19B. Dibenzo (,J.,)Anthracene(53-70-3)

20B. 1.2-Dichloro-bensene (9.50)D-1)

21B. 1.3-0-ch•or0-benzene (541-73-1)


CONTINUED FROM PAGE V-.6

2- MARK X 3. EFFLUENT I 4. UNITR I _ INTAKR (a,I,,,,,,I4. UNITS 5 1 NTAKE fppflonaA

1. POLLUTANT I /b. MAXIMUM 30 DAY VALUE I. .LONG TERM AVRG. a. LONG TERMAND b. a. MAXIMUM DAILY VALUE (Ifroallabfc) VALUE (if oal/dbte) AVERAGE VALUECAS NUMBER TESTING 8UEvSD BELEVED ) (1) (1) d. NO. OF a CONCEN- (1) b. NO. OF

(4Iývf•lb) REQU-IRED RES-NT ABSENT CONCENTRATION 1(2) MASS CONCENPTRATION (2) MASS CONCEN'TRATION (2) MASS ANALYSES "TRATION t b. MASS CONCTRATION M SS NALYSE

GD/MR FRACTION -- BASE/NEUTRAL COMPOUNDS Icotd,('

228.1lA-Olchloro-benzen~e (1 06-4&-7) ____________

236. 3.3-Dichloof-beraldine (91-94-1)

248- OleIIhylPhthalate (84-66-2)

259. OlsethytPhthalate

268. 0t-N-ButylPhthalate (84-74-2) ___

276. 2,4-Drlnltro-toluen~e (121.14-2) _______

286. ZS-Olnltro-toluene (606-20-2) 1_______ ____

208. Dl-N-OctylPhthalato (117-84-0) ____ _______ ____ __________ _______

308. I.2-DlpheA*hydrazine (as AzO-benzene) (12-67 _______

318B. Fluoronthene(20&-44_0) ___ _______

328. Fluorerta

338. Hmxchloro-benzene (118-74-1) ____________

34B. Hexochloro-hutadlene (87-68-3) ____

356. Hexachloro-cyclopentadlonc(77-47-4)

368 Hexachlorc-ethane (67-72-1)'378. Indeno(1.2,3-cd) Pyrenc(1983-39-5) _______ _____

388. Isophorco1e(78-58-1) ___ ____

39B6- Naphihaleile(91-20_3) _______ _______

40B. Nltrobonznefl

41 B. N-NItro-sodimethylarnirdl

428. N-Nitrosodi-N-Propylamine1(621-64-7) _ _ _ ________ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ________ ____


CONTINUED FROM THE FRONT2. MARK "X 3. EFFLUENT 4. UNITS 5. INTAKE (oprioni)_•

1. POLLUTANT b. MAXIMUM 30 DAY VALUE ¢. LONG TERM AVRG. a. LONG TERMAND a. b. a . MAXIMUM DAILY VALUE (ifmoab/c) VALUE ( oval•abhc) AVERAGE VALUE

CAS NUMBER TES-ING BEUIEVED BEUEVED (1) 1 (1) ". NO. OF o. CONCEN- (1) 1 b. NO. OF..f ovalable) REQUIRED PRESENT ABSENT CDNCENTRATI0N (2) MASS CONCENTR ON ,2)MSS ENTRANTRATION (2)MASS ANALYSES TRATION b. MASS CONCENTRATION r2) MAS ANALYSES

GC-MS FRACTION - aSE/NEUTRAL COMPOUNDS (connimed)

438. N-NIl(O-s.dsphcen~amlnc(86-30-6) .... :

44B. Phananthrtefe

45B. Pyrene(129-00-0)

468" 1.24-.Tr6.

GC/MS FRACTION - PESTICIDES

I P. A/orn "'(309-00-2)

2P. ,-SHC(319-84-6)

3P. "H,-BHC(3198-85-7) _______

4P. 7-BHC(58-8g-9)

5P.6-BHC(311;-86-8)

6P. Chlordoane(57-74-9)

7P. 4.4'-DDT(50-29-3)8P. 4.4'-0E)(72-5,5-9) _ __ _

OP. 4.4'-DDO

(60-57-1)

11 P. -Eiosulforn

12P. ),-E.ndosulfan(1 10-29-7) I I I13P. End•osutlanSulfate(1031-07-8)

14P. Ezndrin(72-2U-8)

15P. EndrinAldehyde(7421-934)

16P. Heptacl/or(76-44-B)


EPA I.D. NUMBER (copyfrom Item I o/Form n)

OH0003786

OUTFALL NUMBER

003CONTINUED FROM PAGE V-8

2. MARK 3. EFFLUENT 4. UNITS 5. INTAKE (opiono,2. MOLLTAN *X b. MAXIMU 3. EAYFVLUENT . LONG TERM AVRG. a.LONG TERM

b. o. c a. MAXIMUM DAILY VALUE (if-, avible) VALUE (I ova/labLe) AVERAGE VALUECAS NUMBER TESTING BEUEVED IEUEVED (1) (1) d. NO. OF a. CONCEN- b. NO. OF((o,.llable) REQUIRED PRESENT 1 ABSENT N RAON (2) MASS CONCENTRATION (2) MASS OCNTRATION (21mAss JANALYSES TRATION b. MASS CONCENTRATION (2 M ALYSESICONCEN~r.T• {''MS OCNTRATGON N2) MASS CONCENTRATION PAL MASS

GC/MS FRACTION - PESTICIDES (conThnr.d)

17P. HepItenlor(1024-5T-3)- C -

18P. PCB-1242(534S9-21-9)

19P. PCB-1 254(11097-65-1)

20P. PCS-l 221(11'04-28-2)

21P. PCB-1232(11141-16&5)

22P. PCB,-1248(12672-29g,.6)

23P. PCB-1260

24P. PC.-1016(12874-11.2) " 1

25P.Toxaphent I(E001-35-2)


PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (copyfmnlim o Form/)on separate sheets (use the same format) Instead of completing these pages. OE0 0 03 786SEE INSTRUCTIONS.

V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 2-C))UTFALL NO.

D4

PART A -You must provide the results of at least one analysis for every pollutant In this table. Complete one table for each outfall. See instructions for additional details.

3. UNITS 4. INTAKE2. EFFLUENT (spect! (yfbLk) (opional0

b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERMa. MAXIMUM. DAILY VALUE (if vi1abd) (a. COell hEN) AVERAGE VALUE

(1) (1) d. NO. OF a. CONCEN- (1) b. NO. OF1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2)1 ASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSES

0. Blochemical Oxygen 5.4 .102 1 rat/1 k2./dayDemand (DOD)

b. Chemlcal Oxygen 24.6 0.47 1 mg/i kg/dayDemand (COD)

c. Total Organic Carbon 5.67 0.11. 1 mg/i kg/day(TO C)

d. Total SuspendedSolids (TSS) 68 1.3 1 mg/1 kg/day

e. Ammonla ("A) <0.1 -- I mg/ kg/day

VALUE VALUE VALUE VALUE

f. Flow 0.005 24 mgd kg/dayg. Temperature VALUE VALUE VALUE VALUE(win,,) "

h. Temperature VALUE VALUE VALUE . VALUE(Swn.er) 22.2 4

MINIMUM MAXiMUM MINIMUM MAXIMUMLpH 7.65 ? 4 STANDARD UNITS

PART B- Mark 'X" In column 2-a for each pollutnlt you know or have reason to believe is present. Mark I"C in column 2-b for each pollutant you believe to be absent. If you mark column 2a'for any pollutant which is limited eith&directly, or indirectly but expressly, in an effluent limahtions guideline, you must provide the results of at least one analysis for that pollutant For other poliutarts for which you mark column 23, you must providea uantitalive data or an explanation of their oresenne in you r isn~horae lCemnlete one lable for each ouftfatL Ree the in tiutons fnr ordditimnnl 4etoiln •n riuo•_monin

-. 2. MARK -A, 3. EFFLUENT 1 4. UNITS S. INTAKE (..ioptofk',;)_1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE

AND b. a. MAXIMUM DAILY VALUE fIf,,aila5le,) (If avilabl,) VALUECAS NO. BIBIEVED BELIEVED (1) (1)(1d. NO. OF a. CONCEN- V b. NO. OF

PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (22) MASS ANALYSES

a. romide(24o59-57-9) X <0.03 -- 1 tg/i kg/dyI•OiuoneTolal <O.OS -- 4 mg/i kg/dy

c. Color X 20 -- 1 Units kg/dy

d. Fecal Collform X 102.5 -- 4 perlO Ol kg/dy

e. Fluoride6,- 0.396 0. 0n0 1 mg/i kg/dy

f.Virato-Nalmte X 0.154 .003 1 mg/i kg/dy x(as M

EPA Form 3510-2C (8-90) PAG E V'-1 -CONTI NU EON REVERSE

ITEM V-B CONTINUED FROM FRONT

2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (opijonol)1. POLLUTANT b. MAXJMUM 30 DAY VALUE C. LONG TERM AVRG. VALUE a. LONG TERM

AND b. a. MAX)MUM DAILYVALUE ( ,ble) (/.(, )AVERAGEVALUE:CA$ NO. BEUEVED BE1IEVED (1) (1) d. NO. OF a. CONCEN-. b NO. OF

(Ofoildable) PRESENT ABSENT 0ONCENTRATON () MASS CONCENTRATION () MASS CONCENTRATION 12) MASS ANALYSES TRATION b. MASS CONCENTRATION 12) MASS ANALYSES

g .N l -ro g e lwen , \

Total Organic (as 0.95 0.02tO

h. on andGraeX <-5.0 -- mg/1. kq/dyGre.asoL Phosphorus(asP.Tol0.06 0.01 mg/i kg/dy x.(77Z3-14-0) / ,..

J. Rsdioecllvity _

(I) Alpha, To•al

(2) Beta. Total

(3) Radium.Total


k. Sulfate(ISO,) 356.6 6.76/(14808-7.) . mg/ kg/dy

I. Suffide(= )x <10 _m_"/_ _ kg"/dy

m. u1fitle* sq.) is1 - gl Sd(142565-45-3) x Mg/i kg/dy

n. Suactants x 0.01.3 0.0. mg/, kq/dy

o. AlumInum.TotalT429-9a) / 2246 0.043 1 ug/ kg/du

p. Barium. Total '.

(7440-39-i) 2 94 0.002 1 Ug/. kg/dy

q. Boron, Total(7440-42-8) x 262 0.005 1 ug/2. kg/dy

r. CObaL. Total

(7440.4864) x <1.0 -- 1 ug/1 kg/dy3.. 1 (on, Total17439-&9-q x 2485 0.047 -ug/3 kg/dy

t. Magnesium,( 20650 0.391. 2 ug/1 kg/dy

0u. Mogybdenum/

TX <2.0 -- ug/i kg/dy,. Mznganose,

Total 4119 .002 2. ug/l kg/dy

w. n, Total(744D-31-5) x <4, -- u9/1 k9/dy

EATorm 35tanium,0- ' P

(7A4u,0- I g- k/d

EPA Form 3510-2C (840) PAGE V4-2 CONTINUE ON PAGE V-3

EPA I.D. NUMBER (copvfrom lIcm 1 of Formi) OUTFALL NUMBER

0H0003786 004CONTINUED FROM PAGE 3 OF FORM 2-C

PART C - if you are a primary industy and this outtafl contains process wastewater, refer to Table 2c-2 in the instructions to determine which of me GC/MS fractions you must test for. Mark X& in column 2-a for all such GC/MSfractions that apply to your industry ard.for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondaryindusdes. nonprocess wastewater oulfats, and nonrequlred GC/MSfracdons), mark *X" in column 2-b for each pollutant you know or have reason to believe is present. Mark "XC in column 2-c for each pollutant you belIeve Is absent If you mark column 2a for any pollutant, you mustprovide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant If you know or have reason to believe It wtl bedischarged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein. acryloritrile, 2,4 dinitrophenol, or 2-methyl-4. 6 dinitrophenol, you must provide the results of at least one analysis for each of thesepollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis orbriefly desCribe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table (all 7 pages) for each outfall. See InstructJons foradditional details and requirements.

2. MARK"X" 3. EFFLUENT 4. UNITS 1 5. INTAK<E fopfibnal

1. POLLUTANT ---7' b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAAVER-- VALULEAND a.T b. . a. MAXI MUM DAJLY VALUE (if'obk) VALUE (ifIatalebtc) d. NOA OF L. CONCEN- "U E bNO. OF

CAS NUMBER [IT1,1NG SELIEVED aEUsveo 1 I d (1) '0' • b(ffovo/ob~.) jRECUIRED PRESENT ABSENT CON.CENTRATON 12) MASS CONCENTRATION1 121 MASS CONC-NTRATION 121 MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS LYSES

METALS, CYANIDE, AND TOTAL PHENOLS

'1M. Antimony, Total X <8.0 -- 1 . g/i kg/day(7440-36-0) _____________

2M. A.•enlcToW•2M.3Nea. X <<10 -- 1 ug/ kg/day(7440-38-2) ___

3M. Beryllum, Total <i.0 -- 1 ug/1 kg/day(74.40-41-7) X <. U/1_ga

4M. Cadmium, Total <1.o -- 1 ug/ kg/day(7440-43-9) <.0g__

5M. Chromium. 4 3.0 0.00 1 ug/1 kg/dayTotal (7440-47-3) X 3.0 001____

6M. Copper, Total(744D.50-a)o . <4.0 - - I U9/1 kg/day X

7M.Lead, Total 17 0.0003 1 ug/1 kg/day(7439.92-1) X

8M. Mercury.Total <0.2 -- 1 ug/T kg/day(7439-97-6) X 0_2_I_____

9M. Mckel, Total 5 0.00 1 Ug/1 kg/day(7440-02-0) X10M. Selnium, \1TOMa lni82-4m-2) X 55 .001 1 ug/1 kg/day

11M. Silver, Total 2 0.00 1 ug/) kg/day(74-40-22-4)

12M. Thallium,Total (7440-28-0) X 33 0. 0006 1 ug/l k9/day

13M. Zinc, Total 201 uq/1 kg/day(7440-66-6) 21 0.000/14M. Cyanide, c 0.005 -- 4 Tg/1 kg/dayTotal (57-12-5) X15M. Phenols. $< -- 4 ug/ kg/dayTotal <5.04k;da

DIOXIN

2,3.7,B-Tesps.- DESCRIBE RESULTSchlrorodlberizo-P-0-ovin, (1764-01-6)

EPA Form 3510--2C (8-90) PAGE V- CONTINUE ON REVERSE


____-- - -2. MARK'X 3. EFFLUENT 4. UNITS 5. INTAKE (cpfionOI)1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM.

AND 3. b. . a. MAXIMUM DAILY VALUE (if'ifa'bl.) VALUE (eftabic) AVERAGE VALUECAS NUMBER a. TF.NG ý ELU•VED BELIEED fl• I.v; I(1) • d. NO. OF a. CONCEN- i, Ib NO, OF

, llle) REQUIREj PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION I (2) MASS CONCENIRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION.1 (2)IMASS IANALYSESGC/MS FRACTION -VOLATILE COMPOUNDS

IV. Ac.roLeln(107-02_8) x 25 . ugI2 kg/day

2V. Acrylonitrile(107-13-1) X <25 -- 1 ugI k/day3V. BGenzno u.J 2.(71-43-2) x <5.0 -- ug/ kg/day4v. Bl1 (Ch/ror-m-4) Ether <S.0 -- ug/l kg/day(542-88-i) x

5V. Brrnofor X <. -- 1 ug/l kg/day(75-25.2) x____

GV. Carbon

(5&23-5) x < 5.0 -- 1 lg/l kg/day

7V. Chlorobenzere 5k(1 O-0-7) x <5.0 I ug// kg/day

BV. Chlorodl-bromomethane <5.0 -- 2 ug/l kg/day

1(124-48-1) _____

DV. Chloroethane(75-00-3) X <5.0 ug/l kg/clay

1OV. 2-Chloro.llvylhnh1 Ether <5.0 -- 1 ugl kg/day(110-75-8) .

11V. Chloroforrt(67-6.3) x <5.0 -- 1 ug/ kg/day12V. Dlchloro-bromomethane <5.0 -- 1 ugh/1 kg/day

275 - 4-) .. .. . . ..13V. Dichloro-

(75-1-ethane ,- <5.0 - ug/l kg/day

14V. I,1 i-D•chloro- X <5.0 -- 1 ug/1 kg/dayethane (75-34-3)

16V. 2ne-87.hloro- <5. -- ug/1 kg/day,ethane (107,06-2) ____ ______ ___

16V. 1 .1-DiOlhloro - \-gethylene (7<.35-4) x Ug/1 kg/day

7V.1<. -- 1 ug/1 kg/daypropane (78-87-5) gl g/a

18V. 1,2-DlchIoro-prpyee < <5.0 - u/ kg/day

1 SVEthtyIbernze < 5. 0 -- 1 ug/ 1 kg/day(100.41-4)

2oV. Methyl X 1 ug/1 kg/dayBromide (74-W-9) <5.0

21V.CMethyl ( <5. I US/ I kg//dayChordde('74..87.43) SC -

EPA Form 3510-2C (8-90) PAGE V-4CONTINUE ON PAGE V-5

CONTINUED FROM PAGE V-4I. MARKIX 3. EFFLUENT 4. UNITS 5. INTAKE (optional)

1. POLLUTANT . b. MAMIMUM10 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAND a. a. -,AXIMUM DAILY VALUE (aifblblc) VALUE W.vallo•bl) AVERAGEVALUE

CAS NUMBER TESTING BELIEVED BELUEVE (1D .... (1) I d. NO. OF a. CONCEN- (1) b. NO. OF(OfovoilobJc) REQUIRED PRESENT ASSENT CONCENTRATION (2) MASS CONCENTRATION (21 MASS CONCENTRATION I t21 MASS ANALYSES TRATION b. MASS CONCENTRATION (21 MASS JANALYSES

GC/MS FRACTI ON - VOLATILE COMPOUN(DS (conmted)

22V. Methlylene <50 A ug/ I kg/dayOhloride (75.-05-2) x

23V. 1.122-l"etrchloroethane x <5.0 1 u1 kg/day

24V. Tetrachloro- <5 0 Uq/1 kg/dayethylene (127-18-4) g

25V. Toluene <5.0 1 ug/1 kg/day(080"e.3) ____________

26V. 1,2-Trans.,.DichloroethyIene x ug/l kg/day(15B-o•....M7V. 1.1.1-TrIchloro- <5. 0 1 ug/1 kglday

otharl (71-55-6) j xg1 k/a28V. 1.1 2-Trichloro- <5.1 0ugg/ kg/dayethane •(9-0-S__5_

29V Tnrihloro-<5.0 Ug/1 kg/dayethylene (78-0116)

30V. Trtchioro-fluoom5-9n4 <5.01 ug/1 kg/day(7,1-69-4) .,31V. VInyl ChloridX <5.0 ug/1 kg/day(75-01-4) _ ___

GCIMS FRACTION -ACID COMPOUNDS'A. 2-Chloroplronol X1 ug/h kg/day(95-57-8)

2k 2.4-DIchIlro- 1<0 1 ug/1 kg/dayphenol (120-83-2) x I

3k 2,4-Dimethyl- <10 1 ug/ kg/dayphenol (105-7-6)

4A. 4,-olimtro-O- . " <5 ugh kg/dayCresol (534-52-1) _

5A 2.4-Ditro. <50 1 ug/ kg/dayPhenol (51-28-5) -

6A. 2-Nltrophenol <10 uq/1 kg/day(88-75-5) x

7A. 4-Nitrophenol(100-02-7) x <50 1 u/1 kg/day

8k P-Chlro-M- ' <10 1 ug/1 kg/dayCresol (59-50-7) x , I

SA. Pentachloro- x <50 1 F/I kg/dlayphenol (B7-86-5)

IOA Phenol .<I 1 ug/l kg/dayaI(108-95-2) x

11Ak 2,4,.Trlchoro" <10 1 ug/1 kg/dayphenol (85-05-2) 1 ---

EPA rorm 3510-2C (8-90) PAGE V-5 CONTINUE ON REVERSE

CONTINUED FROM THE FRONTI -..... ----. ,,-..- ----.- -~ --

2-, MAR•K X'--.. 3. EFFLU.NT 4. UNITS -5. INTAKE IeeIeaM. I4. UNITS I S. INTAKE (opno-h

1. POLLUTANT I -b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAND a. IR b. CR A . MAXIMUM DA)LY VALUE5 (CNTATIOI() M NAIA E T MASS CONAERAT 1 MAS ASCAS NUMBER TESTING BELIEVED SEUEVEJ/ O ) .. 1 d, NO. Fa CONCEN- .AV VALE O. OF

(;fer al01 b06c) REQUIRED PRESENT ' ABSEN T MASS 'R1T)N-.-M I -.CNETAIN MMASICONCENTRA'nON 1(2) MASS CONCENTPRAT oN ý2) MASS ANAYE aTRATIOIN b. rV•SCNETA N()MASS AN.A.YSES

GCIMS FRACTION - BASEINEUTRAL COMPOUNDS18. A~ena ph81eimo(83-32-0) ____ ________

2B. Acenaphtylen f(208.96-8)

3B. Anthracene

48. Benrldlnc(92-87_S)5B. Berzmo (a)AnllhraCene(56-55-3)

8B. Bearzo (a)Pyrene (50-32-8)78. 3,4-8enz=.-

nuoran0'ene(20,5-90-2)88. Benzo (w4i)Peryiene (191-24-2)9B. Bonzo (k)FluorantheneZ207-08-9)109. 813 (0-C(Uore-t'.,y) Methane

(111.91-1) ,.,118. Bs (2-Chloro-eiI7,J athcr(l11-44-4)128. B1s (2-ChlomlsoproyAEther (102-80-1)13B. gis (2-Ethvi-ho)I) Phthalate(117-91-7)

14B. 4-BromophenylPmenyl Ether

158. Butyl BenzylPhthal3te (85-68-7) .....

168. 2-Chloro-.naphtholenf

178. 4-Chloro-phenyl Phenyl Ether(7005-72-3)188. Chrysene(218-01-9) _____________________

19B. Dlbonzo (a.h)Anhac.ene(53-70-3) I___________________

208. 1.2-DIchloro-benzone (95-50-1)

benizene (541-73-1) ____

EPA Form 3510-2C (8--90) PAGE V-6 CONTINU E ON PAGE V-7

CONTINUED FROM PAGEV-62. MARK X" 3. EFFLUENT 4. UNITS 5. INTAKE (ophonO

1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. N a. LONG TERMAND a. b. C. a. MAXIMUM DAILY VALUE (if-allabWe) VALUE (1(,ailoble.) AVERAGE VALUECAS NUMBER TETN SEUEVEO BEUJEVED (1) () (1) j .NO F(1) -b. a NO- OF

(Iffailabl) REQUIRED PRESENT ABSENT CONCENTRATION CONCONTRATSS CONCENTRATION (2) MASS ANALYSES TRAI'ON b. CONCENTRA]iON (2) MASS ANALYSES

GCMS FRACTION - BASE/NEUTRAL COMPOUNDS (cowniicd)

228. 1.4-Dichloro-beraene (1 06r4-7) ,,

23B. 3.3-Dicrhloro-bergJdlne (91-94-1)

248,. OethylPhthadate (84-66-2)

25.B DimethylPhtnalato(131 -11-3)

26B. DI-N-ButyIPhthalate (84-74-2)

27B. 2.4--Dinivo.toluene (121-14-2)

28B. 2.6-Olnbt-o-toluene (E06-20-2)

29S. DI'-N-OctylPhthalate (1 17-84-0)

308. 1.2-Olphenyl-hydrazIne (as Azo-benz-ene) (122-88-7)

313. Fluoranthane(206-44-0) ____ __________________

328. Fluoreno(86-73-7)33B. Hexactrlorc-benzene (118-74-)1)

348. Hexachloro-buladlotne (87-68-3)

358. Hexachloro-cyclopentadioone(77-47-4)

3B Hexachloro-etthane (57-72-1)

37B.nlndeno(1,2,3-co) Pyrene(193-39-5)

388. IsophoronL(78-59-1)

39B. Naphthalene(91-20.3) __ __ ____ ________ ___ ___ _ ___

403. Nltrobonzene(984(5-,3)

41B. N-Nltro-3odlmcthylarmne(62-7&-9) .........

42B. N-Nltrosodi-N-Propylamlne(621-64-7) . .

EPA Form 3510-2C (8-90) PAGE V-7CONIMNUE ON REVERSE

CONTINUED FROM THE FRONT2. MARKX 3. EFFLUENT 4. UNITS 5. INTAKE (ouono/

1. POLLUTANT lb. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAND a. b. c a. MAXIMUM DAILY VALUE . (W-a106labl) VALUE (.f available) AVERAGEVALUE

CAS NUMBER TESTING BEUEVED BELIEVED (1) d. NO.OF a. CONCE('N- 1) b. NO. OF(Wodl.abl&) REQUIRED PRESENT ABSENT CONCENTRATION 1(2) MASS |CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 12) MAS ANALYSES

GC/MS FRACTION- BASE/NEUTRAL COMPOUNDS (conhmed)

439. N-Nit-rosoaiphenylbmln(86-30-6)

1448. Phen3nthrene(8.0-01.8) _______

458. Pyrene(120-00-0) _______

468. 1,2.4-Td-c.hloroben en(120.-82-1) _


1P. A/drtn(30o900-2)

2P. -- BHC(31 90.) ___ __ __

3P. "-EHC(319-8.5-7)

4P. 7-EHC(S8-8-09)

5P. 6-BHC(319-8G-8)

SP. Chlordane(57-74-G)7P. 4,4-DOT(50-.7-3)8P. 4.4-DOE'(7_2-55-9)

9P. 4.4'-ODD"('72.S4-8) __ _ __ _

loP. Dieldrin(60-.57-1)

1 1 P. a-Enosulfan(I158-2S-7)12P. 1 -End°'ulfan

(115-2-S-7) ____

13P. EndosulfanSulfate(1031-07-8)

14P. Endrln(72.2M-B)15P. EndrInAldehyde(7421-93-4)16P. Heptachlor(76-44..8)....

EPA Form 3510-2C (8-90) PAG E V-8 CONTINUE ON PAGE V-9)

EPA .D. NUMBER (copyfron.mll I ofFom 1) OUTFALL NUMBER

CR0003785 004CONTINUED FROM PAGE V-8

S 2.' MARK "X 3. EFFLUE'NT' 4. UNITS 5. INT3AKE (opIlonoJ)i. POLLUTANT b. MAXJMUM 30 DAY'VALUE c. LONG TERM AVRG. -. LONG TERM

AND 'L b. c. a. MAXIMUM-DAILY VALUE ("ifva//bde) VALUE (I,)"vl/able) AVERAGE VALUECAS NUMBER TESliNG BEUEVEO SEuEVED (1) (1) d. NO. OF 2. CONCEN (1) b. NO. OF

(I fveihabi) REQUIRED PRESENT ABSENT CONCENSATION R 2) MASS CDNATION TION ( I2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. •S CONCENTRATION 12) MASS ANALYSES

GC/MS FRACTION - PESTICIDES (conu,,rd)

17P. HeptachlorEpoxdde(1024-57-3)18P. PCB-1242(53469-21-9)

19P. PCB-1254(11097-69-1)

20P. PCB-1221(11104-28-2)

ziP. PC D-1232(11141-16.5)

22P. PCB-1248(12672-29,.6_

Z3P. PCB-1 260(11096-82-5)

24P. PCB-1016(12674-1-2)

25P. Toxmphene

EPA Form 3510,-2C (8-90) PAGE V-9

0

0PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (copvlfrom 1cm, I OfForm'l)on separate sheets (use the same formao) Instead of completing these pages. 0H0C03786SEE INSTRUCTIONS. I .... . I I

V. INTAKE AND EFFLUENT CHARACTERISTICS (continued(rfromepage'3ofForm 2-C)OUTFALL NO.601.. .

PART A -You must.provide the results of at least one analysis for every pollutant in thls table, Complete one table for each ouffall. See instructions for additional details.

3. UNITS 4. INTAKE2. EFFLUENT (sab5 f blak) (Opdioa))

b. MAXIMUM $0 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERMa. MAXIMUM DAILYVALUE (Q/maailable) (If avmilable) AVERAGE VALUE

(I) (t) 'd. NO. OF a. CONCEN- (1) b. NO. OF1. POLLUTANT DONCENTRATlON (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS ANALYSES TRAT1ON b. MASS CONCENTRA71ON C2Z MASS ANALYSES

a. BiochemIcal Oxygen 8.6 0 .98 1 mg/L kg/dayDemand (BOD)

b. Chemical Oxygen 45.5 5.17 1 mg/i kg/dayDemand (COD)

c. Total Organic Carbon 9.52 1.08 1 mg/i kg/day(TO. 95 101_____

d. Total SuspendedSolids (TSS) 10 1. 14 1 Tg/1 kg/day X

e. Ammonla (as N) 6.70 0.76 1 mg/i kg/day

VALUE VALUE VALUE V VALUEf. Flow 0.03 24 mgd k/ay

g. Temperature VALUE VALUE VALUE VALUE(winier)

h. Temperture VALUE VALUE VALUE VALUE(•c)24.3 4 "

MINIMUM MAXIMUM MINIMUM MAXIMUM .. ... 'L PH i.3 76 STANDARD UNITS

PART B- Mark"X" in column 2-a for each pollutant you know or have reason to believe s present. Mark W("in column 2-b for each pollutant you believe to be absent If you mark columrn 2a for any pollutant which Is limited eitherdirectly, or indirectly but expressly, in an effluent limitation, guideline, you must provide the resuats of at least one analysis for that pollutant For other pollutants for which you mark column 2a., you must providequantitative data or an explanation of their presence in your discharge. Complete oee tablefor each outfall. See the Instructions for additional details and requirements.

2. MARK"X" 3. EFFLUENT 4. UNITS S. INTAKE (opil) I1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE

AND b. a. MAXIMUM DAJLY VALUE (f-.4aallable) A(Uelabl)ECAS NO. BELIEVED BEUEVED () .1) (1) W. NO. OF a. CONCEN- M b. NO. OF

(f/ar'ollobl) PR-ESENr ABSENT CONCENTRATION 12) MASS CONCENTRATION 12) MASS CONCENTRATION RATION b. MASS CONCENTRATION 121 MASS ANALYSES

a. Bromide x <0.03 -- 1 mg/l kg/dy(24959-67-9)

b. Chlorine, Total <0 . 05 4Residual <0X Mel 4 mg/ kg/dy

c. Color 15 -- 1 units kg/dy

d. Focal Collfp.om X 25.8 -- 4 perl00ml kg/dy

e. Fluoride(16984-4-B) 0.233 0.026 1 1 mg/1 kg/dyf. Nitra-Niite 0.25 0.02 mg/i kg/dy x

(sN)025 0.2

EPA Forrn 3510-2C (8-90) PAGE V-1 cownmuE ON REVERSE

ITEM V-S CONTINUED FROM FRONT

2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE [oplaonal)1. POLLUTANT b" . MAX1MUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM

AND b.' a. MAXIMUM DAILYVALUE (Q'o, alkblc) (•,fa-Robc) AVERAGEVALUECAS NO. BELIEVED BEUEVED (1) 0() d. NO. OF a. CONCEN- () b. NO. OF

(!fýodablc) PRESENT ASSENT CONCENTRATION (2) MASS CONCENTRATION 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 12) MASS ANALYSES0. Nitrogen,Total Organic (as 1.3 0.15 1 mg/1 kg/dy

h. Oil and 5-Sr¢==/ -,. <5.0 - 4ag"/i kg '/dyGrease

I. Phosphorus1(as P).Total 8.15 0.93 I mg/! kg/dy(7723-14-0) X

. Radoactivity

(1) Alpha, Total

(2) Beto, Total

(3) Radlum,Total(4) Radium 226.

Total

k. Sulfate(-SO.) X 63.3 7.20 1 mg/1 kg/dy(14808-79-8)

</I. Sulfide(_sS) x -. <0~ 2I mg/i kg/dy

m. Su)lte12 S6•t!-) <15 -- 1 mg/i kg/dy('14265-45-3)

n. Surfactant x 0.006 .0007 1- mg/i kg/dy

o. Auaminum.Total x 192 0.02 1 Ug/i kg/du x1920.0.02

p. Barium, Total(7440.39.3) x20 0.05 1 tag/ I kg/dy X

q. Boron, Total(7440-42-6) X 78 0.01 2- ug/i kg/dy .r. Cobat, Toted <1.0 -- 1 Ug/i kg/dy(7440-48-4) _____s,. Iron, Total(7439-8s.-T) X 232 0.03 1 ug/1 kg/dy x

L. Magnesium.Total 16404 1.8651 1 aug/1 kg/dy(7439.95-4)U. Molybdenumr.Total <2.0 -- 1 ug/1 kg/dy(7439-8-7)

v. Manganese,Total X 127 0.01 2. ug/i kg/dy(7439-96-5)

(7440-31-,5) X <4 -- 1 ug/ I kg/dyw.Tin.anium,

STotauml II I l-/ Y.9/d(7440-32 x)TaL•.-2.6 X i--1 tgi kg/dy x


0CONTINUE ON PAGE V-3

0

I EPA I.D. NUMBER (opýyfromfiem 1 ofFamnn) OUTFALL NUMBER

OH0003786 601ICONTINUED FROM PAGE 3 OF FORM 2-C

PART C - If you are a primary Industry and this outfall contains process wastewater. refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X In column 2-a for all such GC/MSfractions that apply to your industry and for'ALLtoxic metals, cyanides, and toal phenols. If you are no, rejulred to mark column 2-a (secondaq lndustrdes, nonprocess wastewateroutfalls, and nonrequiied GC1MSfractions), marx' X' in column 2-b for each pollutant you know or have reason to believe Is present Mark "X" In column 2-c for each pollutant you beliove Is absent. If you mark column 2z for any potutant. you mustprovide the resvlts of at least one analysis for that pollutanrt If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant W you know or have reason to believe It will bedischarged in concentrations of 10 ppb or greater. If you mark column 2b for acroteln. acrylonitrlle. 2,4 dlnitrophenol, or2-methyl-4, 6 dinitrophenol. you must provide the results of at~least one anarlysIs for each of thesepollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either submit at least one analysis orbriefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfalL See instructions foradditional details and requirements.

2. MARK "X" 3. EFFLUENT 4. UNITS I s. INTAKE (atioinatl

1. POLLUTANT BEUEVE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAND P U TN a. MAXIMUM DAILY VALUE (iovolebl VALUE (if'aveiabio) AVERAGE VALUE bCAS NUMBER. TESTING U EVEeLtEaD Ci (1) I (1) d. NO. OF a. CONCEN- b. NO. OF(tfevailabo/) REDUIRED PRESENT ;ABSNT CONCENTRATION 1 (2) MASS CONCENTRATION 1N I(2 MASS ANALYSES TRATION b. MASS CONCENTRAT)ON 121 MSS ANALYSEE

METALS, CYANIDE. AND TOTAL PHENOLS

1 M. Antimony, Total I0.0 0 O 1 ugl kg/dayC7440-3"-0)

3M. Arsenli. Total X 0.0kd(7440-38-2) 12 0 .g/0 k/day3M. Beryllum. Total <I. 0 -" ug/. kg/day(7440-41-7)

4M. Cerlalum, Total <10 -- 1 tg/i kg /dayC74.40-43-9) ______

5M. Chrormum,Total (7440-47-3) A < - - 2 Uo/. kg/day

SM. Copper, Total e a. Ug/i kg/day X(7440-50-9) __<___0_--__ u_/__kS/day

7M. Lead. Total X9 .001 2I g/ I kg/day(7439-92-1) 9

aM. Mercury, Total .ce.2 -- I kg/day(7439-97-6)

9M. NIckel, Total X uq/1 kg/day(744C-02-0)

tOM. Selenium. 33 0.004 1 Ug/1 kg/dayToal (7782-40-2)

/

IIM. Sliver, Total < 1 I 2g/I kg/day(7440-22-4) <--_/ k d12MTo haliurn,7 29 0.004 1 ug/l kg/day

13M. Zinc. Total 0001C7440-66-6) 2.2. . 1 tog/1 kg/day no14M. Cyanide.Total (57-12-5) X <0.005 -- 4 mg/l kg/day

IBM. Phenols, .Total 0

DIOXIN

2.37ro-TeTlran DESCRIBE RESULTSchlorodibenzo-P[Dioxin 1174-0-S

EPA Form 3510-2C (8-90) PAGE V-3 CONTIN UE ON REVERSE


2. MARK"X" 3. EFLUENT 4. UNITS 5. INTAKk (oet/onal1. POLLUTANT b. MAXIMUM 30 DAY VALUE r. LONG TERM AVRG. a. LONGTERM

AND b ý. MAXIMUM DAILY VALUE (if oalvla/e) VALUE (i.. ova/lb/e) AVERAGE VALUEGAS NUMOER TESTING BEUEVED BELIEVED (1) '2) (1) (1) NO. OP a. CONCEN- b. NO. OF(ifawoloMe RE2UIRED PRESENT ASSENT CONCENTRATIONJ (2) MASS 1CONCEN(TIRAT1ION (2) MASS , CCNCENTAIN(}MS ANLSSTAIN b AS OC.1fAIN )mS AAYE

((fovot/oblo) REDUIRED PRESENT ABSENT CONCENTF1AI1ON RI MASS CONCENTRATION (2) MASS ANALYSES TRXflON 5. MASS CONCENTRATION 12) MASS ANALYSESGC/MS FRACTION-VOLATILE COMPOUNDS

IV. Accrotelrr(107.02-8) _______

2V. Acrylonitrille(107.13.1)

3V. Benzene(71-43-2) ____

4V. BIs (hor/or-oýejhy/) Ether(542-88-1)

5V. Bromoronn(75-25-2)

6V. CarbonTetrachloride(56-23-5)7V. Chlortberaene(108-90-7) ____

Sy. Chlorodl-bromometharte,

OV. Ch~eetlo~r(75.00.3) ______ ____ ______

I CV. 2-Otrloro-cthyinI4 Either

lIV. ChrloroformOE(67-6ý6-3) ____ ____

I2V. DIchloro-bromomethaefl

13V. DIcirlorp-dllluoromathofle

14V. I.1.D~chlrl~o-ethane C751-34-3) _____ ________________________

ISV. 1 ,2.DIrhI~r0-ethnare (107.06-2) ______

I SV. 1 .1-D1chlrIoO-ethylene (75-35-4) _____ __

17V. 1 .2.D1chIl=-propane (7&.87-5) ______

18Vy. I ,3-DkNOto-propytene

_(542-75-6)

19V. Ethylbarsone(100-41-4)

20V. MethylBromIcie (74-63ý-9) ___ ____

21V. MethylChloride (7A-87-3). El l]_ ______________


0 0,


2. MARK "X" 3. EFFLUENT 4. UNITS S. INTAKE (opJon..) .SPOLLUTANTD b. MAYJMUA 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND b. C.a. MAXIMUM DAILY VALUE Qrfaraoblk) vALUE (a.al CS/) A RGE VALUECAS UMBR T~rIG BUEVD uu~vuý.. VLUEQ(ýllale)AVERAGE VALUE

CAS NUMBER le TESTING BESEVEN BALBEVED . (1) CL1(1 ) NO. OF a. CONCEN- M (1) b. NO. OF(IoIa/,k) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (21 MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION r MASS NALYSFS

GO/MS FRACTION-VOLATILE COMPOUNDS (camnied)

22V. Methylen[Chodde (75-09-2)23V. 1.1.2.2-TeaOc.lormetnann

24V.Tnetamehioto.-thyleno (1 27-18..-4)

25V. Toluene(108-88-3)2EV. 1,2-Trans-DIchloroethylern,

27V. 1,1.1-TrIoNora-ethane (71-55-6)28V. 1.1 2-Trichloro-ethano (79-00-5)

29V T-chloro-ethylene (79-01-.6)

30V. TrItchao--fluoromethane

31V. Vinyl ChloridIe(75-01-4)

GO/MS FRACTION- ACID COMPOUNDS

1Ak 2-ChIoropherilo195&57-8)

3A 2,4A. Dchioro-phenol (120-83-ý)

3A. 2,4Dimethyl-phienol (105--7-9)

4A. 4.•-Dinlt"o-O-Crasol (534-52-1)

5. 2,4-Dinitfo-phenol (51-28-5)

6A. 2-Nitroph cool(88-75-5) _ ___

7A. 4-Nltrophanol(100-02-7)

B.k P-Chloro-M-Cresol (59-50-7)

9A. Pentachloro-.Phenol (87-•86-.5)

10M Phenolr (108-9&.2) 1 j ....

ikA 2,4,S-Trichloro-ipnenol (88-05-o)

EPA Form 3510-2C (B-90) PAGE V-5 . CONTINUE ON REVERSE


2. MARK X" 3. EFFLUENT 4. UNITS S. INTAKE (oprnoW)i. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND a. b. , .MAXIMUM DAILY VALUE (if-ai/ble) VALUE (,f•amlcblc) AVERAGE VALUECAS NUMBER TESTING BELIEVED 0EUEVED ( (1) d. NO. OF a. CONCEN- b. NO. OF

TESID BELIEVEDIMU BEAILYE VALU (1)noibc VAUtjaoJbc VRG AU(ifavo•ilblc) REQUIRED PRESENT ABSENT CONCENTRATION (2Z MASS CONCENTRATION (12 MASS CONCENTRATiON (2) MASS ANALYSES TRATION bCON) MASS NALYSES

oO/MS FRACMION- EASE/NEUTRAL COMPOUNDS

1B. Acenaphthono(B3-32-B) _

28. Acenaphtylene(20"s-8-) ___ ____

38. Anthra_.e.e(120-12-7)_.......4B. Bert.idlne(92-87-5) ......

,B. Bsnzo (q)Anthracene(56.55-3) _____

6B. Boenzo (o)Pymne (50-32-8)

78. 3,4-Berizo-,fluoranthene(205-99-2)

3B. Benzo (ghi)perylene (191-24-2) ,.99. Benno (A-)Fluormnthc e(207-08-9)108. sts (2-C/rio,-/,ho•y) Methane

(111-91-1)

11 B. B~s (?-Chtorvo-,e.y,) Ether(111-44-4)

128. Bis (2-Ckbo'olsop.otpyd/)Ether(102-80-1)

13S, Bis (2-Et.hv-hu3't) Phthalate(1 IT-81-7)

148. 4-Bromopheny!phenyl Ether(1 01-65-3) ____ _________

158, Butyl BentzylPhthalate (85-M8-7)

16B. 2-Chloro-naphtholono(91-58-7)171. 4-Chforo-phenyl Phenyl Ether(7005-72-3)188. Chrysene(218.-Cl-9) ____ ___

198. O0benzo (ah)Anthracene953-70-3) ......

208. 1,2-Dichloro-benzene (95-50-1)

218. 1.3-DI-chloro-benzene (541-73-1) _____________

EPA Form 3510-20 (B-90) PAGE V-6 CON11NUE ON PAGE V-7

0

SCONTINUED FROM PAGE V-6

2. MARKW I" 3. EFFLUENT 1 4. UNITS 1 5. INTAKE (ovdofl)I. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND a b . a. MAXJMUM DAILY VALUE (ifamsilable) VALUE (zavla•bLc) AVERAGE VALUECAS NUMBER TESING BELIEVEO BEL!EVED (1') (1) (1 d. NO. OF a. CONCEN- b. NO. OF

...... ECUIRED PRESENT ABSENT COOCENTRATION1 NCENTRA'ION (2) MASS CONCENTRTION 12) MASS ANALYSES TRATION b. MASS CONCEITRAION 12) ,S ALYSES(I'~olbl) I EURE REET BET OCETJ•IN (2) MASS CONTA1....TRT MS

GCDMS FRACTION- BASE/N ELTRAL COMPOUNDS (conitinc-a)

22B. 1 ,4-ihD oro-benzene (106-46-71

238. 3,3-DIchloro-benrz1dino (91-94-1)

248. DlethylPhthalate (84.66-2)

25B. OIlmethylPhtholate(131-11-3)

268. Di-N-EutylPhthalate (84-74-Z)

278. 2.4-Dinitro-toluone (121-14-2)

288. 2.6-DInIto-toluene (606-20-2)

298. DI-N-OclyPhlhalate (117.4-0)

308.1 2-.Ophenyt-hydrazine (as Azo-benzene) (022-58-7)

31B. Fluoranthene(206-44-C)32B. Fluorene(848-73-71 .... _

33B. Hexac=rtoro-benzene (118-74-1)

348. Hexachloro-butadlene (87-68-3)

358. Hexachloro-cyclopentadlene(7747-4)36B Hexachltoro-ethane (67.72-1)

378. Indeno(1,2,3-.cd Pyrene

388. Isophorone

39B. N•phthalene(91-20-3)40B. Nltrobenzene(98.95.3)

41B. N-Nitro-sodlrnethylamine(62-75-9)

22. N-Nirosop -N-Propylarnlno4(S21-64-7)

EPA Form 3610-2C (8-90) PAG EV-7 CONTINUE ON REVERSE


2..MARK "X* 3, EFFLUENT 4. UNITS 5:. INTAKE (opt/onrn)1. POLLUTANT b. MAXIMUM 30 DAY VALUE a. LONG TERM AVRG. a. LONG TERM

AND b. a. MAXIMUM DAILY VALUE (ifm-allab/e) VALUE (Qf tvaIdabtc) AVERAGE VALUECAS NUMBER TESTING BEUEVSD ]BELIEVE0 ) (1) d. NO. OF a. CONCEN- b. NO. OF,f.vi~~bli) REQUIRED PRESENT ABSENT CONCENTTION. (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCEMTRATION (2)MASS ANALYSES

GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS (ýo,,imvd)

43B. N-Nttro-sodliphenylamine

448. Phenanthrone

458. Pyrene(129-00.0) • _468.1.2,4-Tn-cnlorobenzene(120.82-1)


IP. Aldrdn(309-00-2)

2P. a-BHC(319-84-6)

3P. 1"-EHN(319 -6-57)

4P. y.BHC(58-89-B)

5P. 5-HC(319-86-8)

SP. Chlordane(57-74-9)

7P. 4.4'-DT(50-29-3)

8P. ,4.-DDEC72-5-5-9) ___ ______ _ ____

9P. 4.4'-DoD(72-54-8)

1OP. Dleldn"in(80-57.1)"____

11P. a-Enosulfan

(11 S-29-7)12?. p-E~n~osu95n

13P. ErndsulfznSulrate(1 c31-07-8)

14P. Eddndn(72-20-8)

15P. EndrinAldehyde(7421-•3-4)1OP. Hept~chlor('7E-44-E)

EPA Form 3510-2.C (S-90) PAG E V--8 CONTINUE ON PAGE V-9

0.

EPA I.D. NUMBER (copyfrom 1mmn I! oFormn 1) OUTFALL NUMBER


I -2. MARKX "X 3. EFFLUENT 4. UNITS 1 5. INTAKE (opitowli2. MARK'X* I

1. POLLUTANT I b. MAXIMUM 30 DAY VALUE _ LONG TERM AVRG.AND a. b. . a. MAXIMUM DAILY VALUE (i/failable) VALUE (ftvoltable)

CAS NUMBER TESTING BELIEVED BEUE:VED (1) ̀ (2) MAS (1) i 12) S (ITRATION 1

(2)1MASS(0ffvaJlcb) REQUIRED PRESENT ABSENT CONCENTRATION CONCENTRATION CONCEN

a. LONG TERMAVERAGE VALUE

d. NO. OF a. CONCEN- AV " b. NO. OFANALYSES TRATION b. MASS CONCENTRATION ,2 MASS NALYSES

GU/MS FRACTION - PESTICIDES (contlnc4

17P. HeplachlorEpodde11024,,7-3)18P. PCB-1242(53469-21,,-s)

19P. PCS-12-4(11097-69-1)

20P. P45-1221

21 P. p CB-1 232(11141 -1 6-9)

22P. PCB-1248(12672-2M-)

23P. PCB-1260(I1 ,0 9 -8 2 -5 )

24P. PCS-1016(12674-11-2)

25P. Toxaphen¢(6001-35-2)

EPA Form 3510-2C (8-90) PAG E V-9

PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this informatIon EPA I.D. NUMBER (copv/fom/ J,•eIJofForm 1)on separate sheets (use the same fornat) Instead of completing these pages. OR0 000378"SEE INSTRUCTIONS.I .I

V. INTAKE AND EFFLUENT CHARACTERISTICS (contlnuedfrom page 3 of Form 2-C))-UTFALL NO.02

PART A -You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each ouffaiL See instructions for additiohal details.

3. UNITS 4. INTAKE2. EFFLUENT (ap~cifyiJ b/on/r (op0lonni)

b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERMa. MAXIMUM DAILY VALUE (if uoooblr) (d. Nvaiaable) AVERAGE VALUE

(1. (1) d. NO. OF a. CONCEN- ( I. b. NO. OF1. POLLUTANT CONCENTRATION (2) MASS CONCENTRATION (2) MASS (1) CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSESa. Biochemical Oxygen 45 241 tgi k/a

Demand (BOD) 4.5 2.4 - mg/1 kg/dey X

b. ChemicaJ OxygenDemand (COD) <20 -- I M9/1 kg/cay

r. Total Organic Carbon(cTOr 2.89 1.53 1 m9g/ kg/day X

d. Total SuspendedSollds.() 8 4.2 1 mg/i kg/day X

e.Am'monia(asN) <0. , -- I Mg/i kg/day

VALUE VALUE VALUE VALUEf.Flow 0.14 24 mgd kg/day

. T.emperature VALUE VALUE VALUE VALUE(winte,) _

h. Temperature VALUE VALUE VALUE VALUE(smmr) 2 .5C

MINIMUM MAXIMUM MINIMUM MAXIMU7.. 8.3 4 STANDARD UNITS

PART B- Mark "X* in column 2-a for each pollutant you know or have reason to believe is present. Mark "X' in column'2-b for each pollutant you believe to be absent. If yoau mark column 2a for any pollutant which is limited. etherdirectly, or indirectly but expressly, in an effluent limitations guidefine, you must provide the results of at least one analysis for that pollutant For other pollutants for.which you mark column 2a. you must providequantitative data or an explanation of their presence In your discharge. Complete one table for each ouffall. See the instructlons for additonal details'and requirements.

2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (optlo•el)1. POLLUTANT b. MAXIMUM 30 DAY VALUE r. LONG TERM AVRG. VALUE a. LONG TERM AVERAGE

AND . a. MAXIMUM DAILY VALUE (iJvel/•bte) (If ovailab/l) VALUECAS NO. BBELIEV ELIDEEVED ( li (1) d. NO. OF a. CONCEN- b. NO. OF

(ffmalable) PRESENT ASSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSESa. Bromide X <0.03 -- 1 mg/1 kg/dy(24959.6T-D) Xb. Chlorne. TotalResidual / <0.05 -- 4 mg/lI kg/dy

c- Color X5 -- I Units kg/dy

d. Fecal Coliform X8 4 perlO ml kg/dye. FluorideS69u4-48-8) X 0.41 0.22 1 mg/i kg/dy

(trate.Hlaito X 3.29 2.75 1 mg/l kg/dy(as N) x______

EPA Form 3510-20 (8-S2) PAGEV-1 CONTI'NUE ON REVERSE

S!

0 S

ITEM V-S CONTINUED FROM FRONT

S2. MARK•.X 3. EFFLUENT 4. UNITS 5, INTAKE (optional)1, POLLUTANT b. MAXIMUM 30 DAY VALUE c- LONG TERM AVRG. VALUE a. LONG TERM

AND b. a. MAXIMUM DAILY VALUE (If ava[able) (I, alable) AVERAGE VALUECAS NO. BELIEVED BELVED d. NO. OF a. CONCEN- b. ND. OF

(•[~avla~ibi) PRESENT ABSENT CONCENTRATION 12) MASS CONCENTRATION 12) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES

TO= Organic (n <0.2a 1 mg/i kg/dy xh, Oil Dnd

Grease<S. -- 4 mg/i kg/dy

1. Phosphorus g

7T23-.14-0) I )g/1 kg/dy x

J. Radloactlvliy

(1) Alpha, Total

(2) Beta, Total

C3) Radium,Total.

(4) Radium 226,TotalY-¢ SulfateI= SO,) -7) x 366.7 194.6 1 mg/ kg/dy(• SOul ide

I.Sulfide X <' -- 1 mg/i kg/dy

m. Sulflite(-, SO.,) X <15 -- 1 mg/i kg/dy(14265-45-3) -

n. Surfacants x <0.005 -- 1 mg/i kg/dy x

o. Aluminum,Total V1 g/ k/d(7429-93.5) x 347 0.18 1 ug/1 kgldu

p. Barium. Total 72(7440-39-372 0.04 1 ug/1 kg/dy

q. Boron, Total(7440-42-8) x 118 0.06 1 ug/I kg/dy

r. Cobalt, Total(7440-48-4). . <. 0 -- I uY/1 kg/dy

s. Iron, Total Xk4i o 3• u/ sd3-89-) 441 0.23 1 Ug/1 kg/dy

t. MagnesJum.Total X 15550 8.251 1 ug/i kg/dy

U. Molybdenum,Tota7 x <2.0 -- 1 ug/1 kg/dyi 743•9-97)

V. Manganese,Total X 13 0.01 1 ug/l kg/dy(7439-96-5)

w."nn, Totan

TotaX <1.0 -- 1 ug/1 kg/dy x(7440-32-6) _U__ _ .EPA Form 3510-2C (S-90) PAGE V-2 CONTINUE ON PAGE V-3

EPA LD. NUMBER (cop"from'n fle.m of'Form J) OUTFALL NUMBER

OH0003786 602 ICIONTINUED FROM PAGE 3 OF FORM 2-C

PART C - if you are a primary industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GCIMS fractions you must test for. Mark "X" in column 2-a for all such GO/MSfractions that apply to your industry and for ALL toxic metals, cyanides. and total phenols. If you are not required to mark column 2-a (secondary Industries. nonprocess wastewater ouffalls, and nonrequked GO/MSfractons). mark X in column 2-b for each pollutant you know or have Mason to believe is present Mark 'X* in column 2-c for each pollutant you believe is absent If you mark column 2a for any pollutant, you mustprovide the results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you Must provide the results of at least one analysis for that pollutant if you know or have reason to belleve it will bedischarged In concentrations ot 10 ppb or greater. If you mark column 2b for acrolein. ZCrylonitrile, 2,4 dinitrophenol, or 2-melhyl-4, 6 dinltrophenol, you must provide the results of at least one analysis for each of thesepollutnts which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b. you must either submit at least one analysis orbriefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See Instructions foradditional details and requirements..

2. MARK'X 3. EFFLUENT 4. UNITS 5. INTAKE (oprionar)1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

CAS NUMBFR TESTING BELIEVED UELIEVEDLJ ) i' I) d. NO. OF a. CONCEN- b.b. NO. OPAND QUIREDc a.EEN MAXIMUM DNTATILVAU baelk-VLE (lfo'ailo AENRAGEVAU(ffovoallable) REQUIRED PRESENT ABSENT CONCENTRATION )21 MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES

METALS, CYANIDE. AND TOTAL PHENOLS .......

1M.Anllmony,Total <B.0 I ugh kg/day(7440.3M.) ____ ___

2M. Arsenic. Total 10 1 1X < 0 -- i ug/ kg/day174.4D-38-21 __ __

3M. Beryllium. Tot2s cn.0 -1 ug/I kg/day(7440-41-7) X <:_.. 0 -- ___/__"/_

4M. Cadmium. Total <1. 0 3. ugh kg/day(7440-43-9) ____I __I

5M. Chtrornum, X -<1 .0 - 1 us/i kg/dayTota (7440.47-3)SlM. copper. Total lX <4.0 1 ug/. kg/day(7440-50-a)_______

7M. Lead,Total 1 0.01 I ug/ 1 kg/day(7439-92-1)

SM. Mercury, Tots <0.2 -- 1g/ kg/day(743-0-97-il)SM. Nickel TotalX <4.0 1- 1 ug/1 kg/day(7440-02-0) , X

IOM. seleium. 55 0.03 1 ug/1 kg/dayTotal 17782-49-2) _

IIM. Silver, Total 1 00 1g(7440-22-4) / 1 0.00 clay

12M. Thallu.M, 35 0.02 1 Ug/i kg/dayTotal (7440-28-0) . I

13M. Zinc, Tctal 14 0.01 1 ug/1 kg/day(7440-,6-6) X

14M. Cyanid. <0.005 -- 4 mg/i kg/dayTotal (57-12-5) X _ . III

5M. Phenol$, <5. -- 4 ug/i kg/dayTotal

DIOXIN

2,3.7,8-Tetra- DESCRIBE RESULTSolrorodlbenzo-P-Dioxin (17 4 -1-6") TEPA Form 3510-20 (8-90) PAGE V-3 CONTINUE ON REVERSE

S.

SCONTINUED FROM THE FRONT

2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (optional)1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND . b. C a. MAXIMUM DAILY VALUE (QfEavilabl.) VALUE (Qfaviablc) AVERAGE VALUECAS NUMBER TESTING BELIEVED BEUEVED i) () ' d. NO. OF a. CONCEN- (1)b NO. OF

Qtfvcllabte) RECUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATnCN (2),MASS CONCENTRATIONI (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 12) MASS ANALYSES

GC/MS FRACTION -VOLATILE COMPOUNDS

IV. ACCroiefl <25 g/i 1Ig kg/day(107-02.8)

2V. Acrylonrwle(107-1 3-1) x<25 -- 1 ug/l kg/'day3V. Benze n(71-43-2) X <5.0 -- 1 ug/l kg/day4V. SI (Chro,--mh•il) ELher <5.0 ~- 1 ug/ kg/day(542-88-1) ____ ____

SV. Bromoform(75-25-2) x 5,- ug/l kg/day

6V. Caroon . <.. .

Tetrmchlodde <-C -- / g/day(56-23-5)7V. Chlorobenzene(10860-7) <5.0 -- gBV. Chlorodl-bromromethaie, <5.0 -g/l kg/day

SV. Chlimathnan(0.3) <5.0 -- 1 ug/l kg/day(75-00-3) ________ ___

10V. 2-Chioo-etylnyllEther <5.D -- 1 ug/l kg/day( 110-75-8)

1 IV. Chloroform(67-66-3) x <5.0 -- 1 ug/ kg/day12V. OlchlorO-bromomethae x <5.0 -- 1 ug/l kg/day,( .DL,27 -.)1duoromehoone <5.0 -~ ug/1 kg/day

14V. 1,1-Dlchloro- <5.0 -- 1 ug/ kg/dayethone (75-34-3) x _s_0___________

15JV. 1,2-D1Ieoro- x ugh kg/dayethane (10706-2) - 0 _____1_/_

16V. .1.-Ichloto- > <5.0 -- 1 ug/l kg/dayethylene (75-3&4)

17V. 1.2-Dichloro-"prooane (78-B7-5) .' <5.0 -- 1 ug/! kg/day

18V. 1.3-DIchloro-propylane <5.0 "- 1 ug/1 kg/day(542-75-6) x

1EV. Ehtylbenzene <5.0 -- 1 ugl1 kg/ay(100-41_4)

20V. Methyl <5 kg/daBronide (74-83-9) < I21V. Methyl <5.0 -- 1 kg/laChlodde (74-87.-3) < I I k

EPA Form 3510-2C (8-9 0) PAGE V.-4 CONTINUE ON PAGE V-5

CONnNUED FROM PAGE V-2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (optroncl)

1. POLLUTANT .b. MAXIIhUM 30 DAY. VALUE o. LONG TERM AVRG. a. LONG TERMAND a. b. a a. MAXIMUM DAlLY VALUE (0failablc) VALUE (•favailabh) AVERAGE VALUE

CAS NUMBER TESTING BZUEVED SEUEVED (.) (1) (1) d. NO. OF a. CONCEN- b. NO.rflr~lble) REQUIRED PRESENT IASENT CONCENTRATION 213M MASS I CONCENTRATION (2 MASS CONCENpTsRATIN a"I MASS ANALYSES TRATION b. MASS OF•rra" P A ANALYSES

.a-~~~~.IMS NC.--TON ------.--,,-,-,J--.

GC/MS FRACTION -VOLATILE COMPOUNDS (conifimie

Z2V. Methylnle <5.0 1 ug/ kg/dayChloride (75-09-2) ... .23V. 1.1,2.2-T(avl)Ioroeane <5.0 1 ug/l kg /day

24V. T eirachioro- <5.0 1 ug/ kg/dayethylene (127-1 8-4)

25V. Tokleme <5.- 0 1 ug/1 -kg/day(108-88-3) x

26V. 1.2-Ttafl-DlChloroethyl•en <5.0 1 g/l kg/day(156.6"- - x ...... I.27V. 1.1.1-iTichlo <5.0 I ug/l kg/dayethane (715-55-6) x___ L_______

28V . 1.1 2 .T r tch lo rXge <5.0 3. ug/ kg/day

29V Tfchlos)- X <5.0 u/1 k/yethylene (7901-r) 1 uga /Iy

30V. Tdchloro.-fluorometane\/ X <5. 0 1 ucr/1 kcr/dav(7.1.rQ-A) I -. I31V.VIrnyl Chlorie c<5.0 12 ug/1. kg/day

GC/MS FRACTION -ACID COMPOUNDS

1 A. 2-ChlotoPhanol(95-57-8 I<10 1 ug/1 kg/day

2A. 2,4.Dlochloro- <10 1 ug/l kg/dayphenol (120-83-2) _101_____

3A. 2.4.Dileth)4- X <20 1 ug/2 kg/dayphenol (105-87-9) x - _1______

4A. 4,68-InltrO-0<Cresol (534-52-1) <50 ug/2 kg/day

&k<50 1 ug/i kg/dayphenol (51-28-5) x <50 u9/1 k9/day

6A. 2-NittophenolMk X N l<10 1 ug/1 kg/day

7A. 4-Ntrophenol <50 2 ug/I kg/day(10o.-o2-7)8.Phl _r"-M- X <50 1 u9/1 kg/day

ctesol (59-50.7) _-.

9X Penc Or u- k/dayphenol (87-8- <

2 -C

kd

IOA. Phonol.(1 08-95-2) .1. ug/. kg/day

1 IA. 2,4.8-Trlchloo- <10 1phenol (88-05-2) . . .g/1 kg/dy

EPA Form 3510-20 (8-90) PAGE V-6 CONTINUE ON REVERSE

49


S

2. MARK X" 3. EFFLUENT 4. UNITS 5. INTAKE (opionl)1.POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

CrAS NUMBER TESTNG EUQEIVED BEUEVED C RION MS T 1 2 C T 1) 0 FA R.ACON bEN . O ION b. NO. OFW - 110, h',cl) R E• R D ASESE RT / ýFN CONCENlT)RATION / t2) MASS ICONCENTRATION (2) MASS CONCF.NlT)RA 'TI.ON 1(2) MAS S •[•- SE (Q,"O b A S CN CENTR AT ON {* 2) MASS {kA.AUYSES

GC/MS FRACTION - BASEINEUTRAL COMPOUNDS . .... _ _

I B.Ac(n)phtheneo X C I'O// k-/a/y1 ______

(83-32-9) X_____ =128. Acenaphtylene(20B-96-8) .</1 lkg/day

381R A nth n I -- I I .. . .. I I I I48. -8e.z ... 2, <50 -- 1 ug/h kg/day4,3. 8enzidine

1 19 1 k(92.974) L I_ -- _ _0

5B. Benzo (a)Anthracenc X <10 -- 1 ug/l kg/day(56-55-3) 0 -- kg/da

6E8. e.•o (,) <10 -- 1 Ug/h kg'/day88. Senzo (V)I' <10 -- lg/iL kg/day

Pyrein (50-32-2)TB. 3,B-enzo-flumranthene X <1O -- 1 ug/l kg/day(2O5-gS-2)x

8. Benzo ( lhhPeryene (191-242) x <10 -- 1 ug/1 kg/day98. ranthy ne1 <)0 -- 1 ug/L kg/day

(2 708-9)x

(111-91-1)_

1 2s. Bal (2- x <10 -- I ug/! kg/day

138. Bis (2-Eukl4.

hO Phtholate <10 I g/. kg/day

(111744-7)

148. 4-,Bromo(h2e.yPhenyl Ether (<I -- 1 ug/l kg/day

(101-55-3) _ _153. Butyl -sBenz

1836. 2.-Chloro-flo; Phthaltene <0i -- 1 ug/l , kg/day(91158-7) x17B. 4-Chioro-

phenyl Phenyl Ether 10 ug/ k(1001-•7-3) x_<____ _/__115B. ChByl en ___ X <10 - uSg/ kg/day

198. Dlberzo (r.,)Anthalcene <I0 -- 1 ug/l kg/day

1(91-5&-7) ______

bhen IPhnri (Eth0e1 <10 1-1 ugJ kg/dlayC700,.•o-3) x _

216.Choro- <10 -- 1 ug/l kg/day1 ber9ane (ad-73-1)2E8. 1.o-Drcho o- 1-0 PAGE VOI NP V



2. MARK "X" . 3. EFFLUENT T 4. UNITS 5. INTAKE (optpoa,)"1. POLLUTANT b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. a. LONG TERM

AND . b. . a. MAXIMUM DAILY VALUE (if'a,.iloble) VALUE Qfowj"ibl/) AVERAGE VALUECAS NUMEER *IES11NG BEUEVED BELIEVED (1) (1) (11 d. NO. OF a CONCEN- (1) b.TNO.MOP

((fccvlloa!b) REQUIRED PRESENT" ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATION 12) MASS 1ANALYSES TRATION b. MASS CONCENTRATION (2) MASS NALYSES

GC/MS FRACTION - EASENEUTRAL COMPOUNDS (contilm4'

223.1.4-Dichoro- <10 -- 1 ug/1 kgdaybenzene (I06.4S4) 6-x-.7 )0 _____

23B. 3.3-Dichloro- <20 Fbenzldlfne (91-94-1) <20 -- L1 ug/ kg/day248. DoetylPhthalate (84-86.-2) x <10 - 1 ug/1 kg/day

258. DimethyIPhthalato .(13111-) x <10 -- ug/ kg/day

26B. 01-N-Butyl <10 -- a ug/I kg/dayPhlhafate (84-74-2) x

278. 2,4-.01nltro 1toluefne (121-14.2) 10 -- 1 dg/1 kg/ day

288. 2.6-DInltro- 1 ytoluene (606-20.2) <i0 -- 1 Ug/1 kg/day298. DI-N-OctylPhthalatc (117-84-0) x<1 -- 1 ug/1 kg/day

308. 1.2-Olphenyl-hydrazine (asAzO- <50 -- 1 Ug/1 kg/day

benzene) (122-68-7)

31B. Ruoranthene(20644-0) x <1 0 -- 1 ug/1 kg/day32,8. Plu or'ene

-- <10 -- 1 ug/1 kg/day

33B. HNnachloro- Xbenzene (118.74-1) <10 -- _U/ kg/day

346. Hexachloro--butaiiene (8788-36) x <10 -- 1 ug/l kg/day

358. Hexachloro-cyclopontadleno <10 -- 1 ug/1 kg/dayCr7-47-4) x _

368 Hexachloro- <10 1 u1/1 kg/dayethane (67-72-1)' <378. Indono(1, Z3-c Pyrene <10 -- 1 ug/i kg/day(193-.3.5) , ..

388. IsophoroneX(785.1) <10 -- I ug/_ _ kq/da

396. Naphthalene(91-20-3) x <10 -- 1 ug/1 kg/day

413 . Nitrobenzene94B95Nb) < -- 1 ug/h kg/day

41B. N-Nizro-sod-me-hylamnan <10 -- 1 ug/l kg/dayý2-75-9) x____ ___ _______ _____________

426. N-Nltro•od&-N-Propylamlno <10 -" 1 Ug/1 kg/day(621-64-7)0

EPA Fon'n 3510-2C (8-90) PAGE V-7 CONTINUE ON REVERSE

S.1


(

2. MARK,)X" 3. EFFLUENT 4. UNITS 5. INTAKE (opaon•a)1. POLLUTANT b. MAXIMUM 30 DAYVALUE, c. LONG TERM AVRG. a. LONG TERM

AND a. b. c. a. MAXIMUM DAILY VALUE (If v-alab/k) VALUE (tfavailable) OF AVERAGE VALUECAS NUMBER TESTINS BEUEVED BELIEVED (1) [() (11 d. . OF a. CONCEN- b1) - NO. OF

(if oaable) REOuiRED PRESENT ABSENT CONCENTRATION 121MASS CONCENTRATION 12)MASS. CONCENTRATIONý () p LYSES ON b. MASS CONOCTRATION (2) MASS ANALYSES(ifa~aifabl..... ... .... A• L r-SESMSýGC/MS FRACTION - BASEINEUTRAL COMPOUNDS (c:ioviea)

_38 N-11Nltro-socilprleylail Ix I <10 uglh Ikg/&ay I448-. PheanhronC 10 -- 1 ug/l kg/day(65-.01-8) x _______ _____ _____

45B. Pyrene(I 29-00-0) x <10 -- 1 ug/1 kg/day468.1.2.4-Tr-chlorobenzene X <10 -- . ug/1 kg/day(120-82-1)


1 P. Aldrnn(309-00-2)

2P. a-BHC121 9-84.8) _____

3P. Pý-BHC(31 9-85-7)

4P. y-BHC(5&-89-9)

SP. ,-BHC(319-B"-B)

6P. Chlordane(57.74-9)

7P. 4,4-.DT "(50-29-3)

SP. 4.4!-DDE(72-55-9) _

9P. 4,4-ODDO(7Z-54B)

lOP. Olelddn

11P.a-Enosuc*an(1•15-29-7)

12P. 1-Endosulfan(115-29-7) 1 1 1 _

13P. EndosulfanSulfate(1031-07-.8) .______

14P. Endrin(72-20-8)

15P. EhdinAldehyde(7421-93-4) _

16P. Heptachlor(7-)44-8)

EPA Form 3510-2C (5-90) PAGE V-8 CONTI N U E ON PAGE V-9

EPA 1.0. NUMBER (copyfrom Iti I of 1orm 1) OUTFALL NUMBER


2- MARK'X" 3. EFFLUENT 4. UNITS S. INTAKE (opljoo)1. POLLUTANT b. MAXIMUM 30 DAY VALUE c.LONG TERM AVRG. a. LONG TERM

AND Z. a MAXIMUM DAILY VALUE (ifallable) VALUE Q(afolvblc) AVERAGE VALUECAS NUMBER TESING BEUEV'ED BELIEVED (1) (1) I d. NO. OF a. CONCEN- (1) b. NO. OF

(),fo.-a1Icb/e) RECUIREl PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATIONt (2) MASS CONCENTRATION MASS ANALYSES TRATION tb. MASS CONCE NTRATION 12 MASS ANALYES

GCJMS FRACTION - PESTICIDES (conrlnua

17P. HeptachlorEpOxIde(1024-57-3)

1ISP. PC8-1242(5349.21 -9)

19P. PC0-1254(11097-69-1)

TOP. PCf-1221(11104-28-2)

21P, P01-1232(111 41-16-5) ___

22P. PCSB-248(12672-2&-s)

23P. PCE-1260

24P. PCB-101S(12674-11-2)

25P. Togaphornc(8001.35-2) ____________ ____ ___


S

0 SPLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information EPA I.D. NUMBER (ceolfram Iieam I ofForm I)on separate sheets (use the same foimat) Instead of completing these pages. 'R0 003786SEE INSTRUCTIONS.

V. INTAKE AND EFFLUENT CHARACTERISTICS (continuedfroom page 3 of Form 2-C)OUTFALL NO.,01.

PART A -You must provide the result5 of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details.

3. UNITS 4. INTAKE2. EFFLUENT (Specfy 0fblan"k) (op1iono)

b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a.LONGTERMa. MAXIMUM DAILY VALUE (iQf'-ilablb) (Wcvaileblc) AVERAGE VALUE

(1) Idl t. NO. OF a. CONCEN- Ill b. NO. OF1. POLLUTANT CONCENTRATION 121 MASS CONCENTRATION (21 MASS (1,) CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION C21 MASS ANALYSES

a. Biochemical Oxygen 8-7 1 Tog/i kg/dayDemand (BOD)

b. Chemical OxygenDemand (COD) <20 1 Mg/1 kg/day

r. Total Organic Carbon(TOn 4.06 Mg/1 kg/day

d. Total Suspended 17..Solids ( &9') 17 1img/i kg/day

e. Anmonia ( AN) <0.1 I mg/1 kg/day

VALUE VALUE VALUEf. Fow 40 Mgd kg/day

g,Ternperature VALUE VALUE VALUE VALUE

h. Temperature VALUE VALUE VALUE VALUE(swmncr- 2 2.4 ,"

63L pH 8M1 M 4 STANDARD UNITS

PART B - Mark "X" in column 2-a for each polluant you know or have reason to believe as present. Mark X" in column 2-b for each pollutant you believe to be absent If you mark column 2a for any pollutant wN6icl i1 limited eitherdirectly, or indirectly but expressly, in an effluent lim'itaftons gudeldne, you must provIde the resuts of at least one analysis for that pollutant For other pollutants for wh'ch you mark column 2z, you must providequantitative data or an explanation of their presence in your discharge. Complete one tablefor eack, outrfall. See the Instructions for additional details and requirements.

2. MARK X" 3. EFFLUENT __4. UNITS 5. INTAKE (opilol)1. POLLUTANT b. MAXIMUM 30 DAY VALUE o. LONG TERM AVRG. VALUE a, LONG TERM AVERAGE

AND a. b. a. MAXIMUM DAILY VALUE (falable (ifavalLable) VALUECAS NO. BEUEVED BELIEVED CL) NO. OF a. CONCEN-. b. NO. OFCONCENTRATION PREEN ASSES (O1)RTQ 2)MS OC-T•IN ()MS

( llab)CONCENTRATION ) MASS CONCENTRATION 121 MASS CONCENTRATION (2 M ANALYSES TRATION b. MASS CONCENTRATION (2) MASS ANALYSESa. Bromide(2495--9) <0.03 1 mg/i kg/dy

b. Chlorine, Totla <0.0S 4 mg/l kg/dyResidual IiI

c. Co"or X 10 1 units kg/dy

d. Fecal Coliform X .3 4 perlOOtl kg/dy

e. Fluoride(1t698"8-8) 0.198 1 rag/! kg/dy

f. NItrate-Nitritre 1.23 1 g/i kg/dy1(asm I

EPA Form 3510-20 (8-90) PAGE V'-1 CONTINUE ON REVERSE

ITEM V-B CONTINUED FROM FRONT

2. MARK "X" 3. EFFLUENT 4. UNITS 5. INTAKE (oprioralO1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. VALUE a. LONG TERM

AND b. a. MAXIMUM DAILY VALUE (•a-,aitablb) (f/7aitable) AVERAGEVALUECAS NO. SEUEVED BELIEVED (1) d() (1) d. NO. OF a. CONCEN- (1) b. NO. OF

(1fao cllable) PRESENT ABSENT CONCSNTRATION 12) MASS CONCENTRATION C2) MASS cONcENTRATION (2) MASS ANALYSES TRATO b. M .ONCENTRATION (2) MASS ANALYSES

g. Nitrogen.Total OrganIc (a 0.5 1 mg/i kg/dy

m x I

I. ODI and <5.0 4 mg/i kg/dyGrooso1. Phosphorus(as P). Total 0.078 1 mg/i kg/dy7723-14-1)

J. Radloadvlty

;(1) Alpha, Total

(2) Beto, Total

(2) Radlum.Total

(4) Radlumn 226,Tot

k. Sulfate(Ay SO,) 'V 31.8 1 mg/1 kg/dy(I (4808-7M-) ... ,....l.I d 45 <79.0/\ mg/i kg/dyLSuXllde <10 1 mg/1 kg/dy(a S) ____

to. Sulfito(as SOJ) <i5 I mg/i kg/dy(14265-45-3) x

n. Surfacants X 0.000 1. mg/i kg/dyo. Adutnlnurm,

308 1 ug/i kg/du

p. Barium, Total/

d(7440-39-3) x 29 1 Ug/_ kg/dy

c. Boron. Total(7440424-) X <75 1 ug/l k/dyr. Cobalt Toal.(7440-48-4) x <1. 0 1 ug/l kg/dy

s. Iron. Total 374 !. Ug/1 kg/dy(7449-S-6_)

_t. Magnesium.Total x 11854 ! U/' kg/dy(7439-9 -4g)uL Motybdenum.Total X <2.0 1 ug/i kg/dy(7439-98-7) .

v. Mangono•s.Total ~ Y-(7439-9T-o ) x 14 1 Ug/1 kg/dy

w. Tin.Ttal X <4 1 Ug/I kg/dy[ýITin, Ton,x. Thtan~um.

aTotal 3 1 Utg/i kg/dy'.40..32-6) .-


S S

0 0

EPA I.D. NUMBER (cop.fromlitem I oqfFonn J) OUTFALL NUMBER

OH0003786 801CONTINUED FROM PAGE 3 OF FORM 2-CPART C - if you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GCJMS fractions you must lest for. Mark 'X' in column 2-a for all such GC/MS

fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary indutstes, nonprocess wastewater outfalls, and nonrequired GCIMSfractions), mark WX In column 2-b for each pollutant you know or have reason to believe is present Mark "X) in column 2-c for each pollutant you believe Is absent. If you mark column 2a for any pollutant, you mustprovide tie results of at least one analysis for that pollutant If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe It will bedischarged In concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acrylonitae, 2,4 dinitrophenol, or 2-methyl-4, 6 dlnltrophenol, you must provide the results of at least one analysis for each of thesepollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis orbriefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part: please review each carefully. Complete one table (all 7 pages) for each outfat.. See Instructions foradditional details and requirements.

2. MARKX .. 3.EFFLUENT 4. UNITS 5. INTAKE (opiloni)"

1. POLLUTANT Ib. MAXIMUM 30 DAY VALUE c0. LONG TERM AVRG. a. LONS TERMAND . . . a.MAXIMUJM DAILY VALUE (ff-, alea1) VALUE [ivai/abfc) AVERAGEVLU

CAS NUMBER TESTING BELIEVED BELIEVED ' d. NO. OF a. CONCEN- b. NO. OF(if.ovallable) REQUIRED PRESENT ABSENT CONCENTRATION (2ý MASS CONCENT)RATION (2) MASS CONCENTRATION (2) MASS ANALYSES TRATION b. MASS CONCENTRATION 121 MASS ANALYSES

METALS, CYANIDE, AND TOTAL PHENOLS

1 M. Antimony. Total 1< 0 1 Ug/! kg/day(7440-36-0)

2M. Arsenli. Total(7440-13-2) 1 ug/ kg/day3M. Beryllium, Total(7440-41-7) X <1.0 ug/l kg/day'

4M. Cadmium, Total <1. 0 t Ug/i kg/day(7440-43-9) .

5M. Chromium.Total (7440-47-3) X1 ug/9/ kg/day

EM. Copper, Total(7440-50-) X1 ug/i kg/day7M. Load. Total 7 1 ug/1 kg/day(7439-92-1) g8M. Mercury, Total 1 Ua/i kg/day(7439-97-q) X _ <0. 2_ 1_ ________cla

SM. Nlckcl, Total <4.0 1 ug/1' kg/day(7440-02-0)

I0M. Sclenlum., 17 1 tg/i kg/dayToWl (7782-40-2) X

IIM. Silvor, Total 1 ug/ kg/day(744 o-22-4) X ....

12M. Thallium, 1 ta/i kg/dayTotal (7440-28-) _ X_ _. _ _ _u_/l_ _g/d-

13M. Zinc, Total 12 ug/h kg/day(7440-66-6)14M. Cyanldc, 4m i gdTotal (57-12-5) X <0. 005 4 mg/l kg/day

15M. Phenols, 4 tg/i kg/dayTotal 0 g k/a

DIOXIN2,3.7,8-

Teua- DESCRIBE RESULTS

chlorodl•enzo-P-Dioxcin (1764-01-6.)

EPA Form 3510-2C (8.-90) PAG EV-3 CONTINUE ON REVERSE

CONTINUED FROM THE FRONT2. MARK"X" 3. EFFLUENT 4. U NITS 5. INTAKE (apponoo)

1. POLLUTANT ]b. MAIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERMAND a. b. m a. MAXIMUM DAILY VALUE *(if/,iloabl) VALUE (.f avolable) AVERAGE VALUE

CASNUMBER TESnNG BELIEVED BELEVED -1 (1I d. NO. OF a. CONCEN- .. NO. OF((avallabl) REQuIREO, PRESENT ABSENT CONCENTRATION (2) MASS MASS CONCENTRTION 12) MASS ANALYSES TRATION b. MASS CONCETiON (2I MASS ANALYSES

GC/MS FRACTION -VOLATILE COMPOUNDS

lvA~~n<25 ug/2 kg/day(107-02-8) ...........

2V. Acrylonit rl"c(107-13-1) X <25 ug!/1 kg/day(0-7.13-Il , ___5.0__1__/lk/_a

3V. Benzene(71-43-2) x <5.0 I ug/h kg/day

4V. BIs (Cklaoro--tkv. E_.er <5.0 I ug/h kg/day(542-88-1)

5v. Bromoform <so 1 ug/ kg/day(75-25-2) x <5.0 ug/__ ______

6V. CarbonTeatramhlodde A <50 1 ug/ kg/day(58-2z3-5) .....__ __

7V. Chlorobenzene x <5 0 1 ug/ kg/day(108-60-7) __

BV. Chlorodl-bromome.thae <5.0 ug/l k9/day(124-48-1)

OV. Chloroethane(75-00-3) X <5.0 ug/l )sg/day

1oV. 2-Chloro-ihylrvnyt Ethmer A <5.0 1 ug/ kg/day

(110-7"-) ____ _______

1IV. Chlorolorm(67-66-3) x <5.0 1 ug/l kg/day

12V. DIchI.oro-bromometheno A <5.0 I ug/l kg/day(75-27-4)13V. Dlchloro-dmuorome8hane <5.0I 1 ug/l kg/day(75-7T-8) -.-

14V. 1.1-Dlchloro- <5.0 1 ug/l kg/daythane (75-34-3) x <0_k/l

15V. 1.2-0lohloro-5

ethylene (75-35.4) x <5.0 1 ug/1 kg/day1'7V. 1,1-D1¢hloro- <5.0 I ug/l kg/day

propane (78-87-5) xI1SV. 1.3-DilchIoro-propylone <5.0 1 ug/1 kg/day(542-75-q)

(100-41-4) X <. sl k/a20V.MEtylb <5.0 1 ug/1 kg/day

BromIdCle (74-83-9) _ _V "21V. Methyl I ug/1 k9/dayChlode (7"7-3) X << L5.00 u_ k

EPA Form 3510-2C (8-90) PAGE V.-4 CONTINUE ON PAGE V-5

S 0.

0 0-"CONTINUED FROM PAGE V-4

2. MARK'X" 3. EFFLUENT 4. UNITS 5. INTAKE (qpuional)i, POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND b. a. MAXIMUM DAILY VALUE (Ifevailable) VALUE ('waloable) AVERAGE VALUEGAS NUMBER TESTING 8EUEVED BEUEVED (1) (1) (1) d. NO. OF a. CONCEN- b. NO. OF

((ffaltoble) REQUIRED PRESENT ASSENT CONCENTRATION 1 (2) MASS CONCENTRATION (2) MASS CONCENTRATION (2) MASS AZLYSES TRA71ON b. ASS CONCENTRATION MSS NALYSES

GCIMS FRACTION -VOLATILE COMPOUNDS (conimird)

Chlojde C75-09-2) _________________________ __ ____I

23V. 1.1.22,2- I-T2v ttahLy~¶Jalen <5 1 u9/1 k/a

Teb-chloethne 50 1 9/1 kg/day

24V. ToatmcNloro- 1<5 0 1 ug/1 kg/dayehy•leno (127-18-4) " ,,,.25V. Toluene 50 1 ug/h kg/day(108-88-3)2-v. "1,2-Ti•zs-

icdoroethylene x 15- 0 1 ugl/ kg/day(155-60-5) .... .....27V. 1,.11-Trichloro-kepane (71-55-6) x <s. 0 ug/I ks/day

28.%'. 1.1 2-TrIchloro- 1 ug.g/ aeinane (78-00-5) x <5. 0 _u9/1 k/day29V T(chlorO- i28'!• (co- <5.0 1 ug/1 kg/day

3-v. Trichloro-fltJoromethane <5.0 1 ug/ kg/day(75-684 __________ _______31V. Vinyl (ýnjoddo31Vr0.A4) x <5. 0 1 ug/1 kg/day

GC/MS FRACTION-ACID COMPOUNDS

57_<10 1 ug/1 kg/day

(9 -5 - 1 .... I . .

1 A .2 -C h lo r o p h e n o l X < 10

1 u S/ k g/ d a y

phb1OAS.28.4. -S)h•X 1 1 Ug/1 kg/day

)neno[ x10561-9

ZA. 2.-Oihoroph-re'.ij k /a. -1 ug/l kg/day"ne•ol (1ý2:-"z-2I)

-Dnt- 1 x <50 ug/1 kg/dayhcesoI (53-52-1) ,.. _______

pheno OI5l-2IO(O- 1 ug/1 kg/day

6A. 2-8,11trophonol(sA-7- XP<n 1 Ug/1 kg/day7A. 4-tNitrophenol

(100-2-7) x <)0 ug/l ks/day

8A. 2-Chiaro- 1 ug/1 kg/dayCrosol (5S,.G•7) ...../I g/da091r, PelcIr"X <50 I u9/1 kg/dcay

Phen ol (180-05-)EPA Fh mn 35<- C 1D uP/A kV/SN R

IA. 1,-1rlhoo-X 'I0 1 us/l kg/day


CONTINUED FROM THE FRONT2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (aptionadj

I. POLLUTANT [b. MAXIMUM 30 DAY VALUE C. LONG TERM AVRG. '. LONG TERMAND a . c.. MAXIMUM DAILY VALUE (fafloablt) VALUE (I6,(mvlable) AVERAGE VALUE

CAS NUMBER TESTING SEUEVLD BEUOVED (1) (d.N.OF a.CONCEN- b. NO. OF

GC/MS FRACTION - BASEfNEUTRAL COMPOUNDS

I B. ACerwphthene11(83-32-9) x -O0 1 us/1 Ik/day,2B. Acenaphrlene <10 -- 1 Ug/ kg/day(20C896-8)38. Anthracene

(12<12-7) x <10 -- 1 ug/ kg/day4s. serzJdlne,(9-8-. xes~n <50 I- ugh)I kg/day

5B. Benzo (a)Anthracaeru(5th56.3x <10' -- 1 ug/I kg/day

68. Benrzo ()x <10 -- 1 ug/l kg/dayPyrene (50-32-8) I uN. I ___ ___

78. 3,4-Benzco-nluoranlhene <10 -- 1 ug/ kg/day(205.99-2) x I _______ ____

83. Baezo 10h1kPeryiene (191-24-2) x <-0 - 1 Uq/I kg/day

98. Senzo (k)Fluoranthene <10 - - 1 ug/1 kg/day(207-08-9) x ug/ 1 kg/d

108. Bis (2..lrlrec./hax) Methane1

5-9-) Me~x <10 -- 1 ug/1 kg/day

11 . Bis (2.Chl/ro.v/*,h) Ether <10 -- 1 ug/l kg/day(1 11-4") __ 1 g I k/a

12B. Bis (2-hLV/,o,'lseopmfepl) V < 10 - - 1 ug / 1 k / day

Ether (10240-1) x 10_____

13B. Bis (2.-EIIkr-heayO Phthlate <10 -- 1 ug/1 kg/day(11741-7) _______

148.4-BromophenyiPhenyt Ether <10 -- 1 Ug/ kg/day(101-55-3)158. Butyl BonzylPhthsatle (85-68-7) x <10 --_ ! /I ks/day

1 88. 2-Chloro-naphthalene <10 -- 1 ug/1 kg/day(91-.58-7) x_____ <10___ _____ _______

17s. 4.-Chlora-phenyl Phenyt Ether <10 -- 1 ug/l kg/day(7006-72.0) - <10_________

I 8B. Chrysene <10(218-01-9) x 0 -- l ug/I kg/day

198. Dlbenzo (,h))<10 -- 1 ug/1 kg/day

20be.ene (95-5D-ir•) <0 -- 1 ug/1 kg/day

218. 1.3-D,-nhloro-bernzene (541-73-1) x <10 L ug/I kg/day

EPA Form 3510-2C (a-90) P•AG E V-6 CONTINUE ON PAGE V-7


2. MARK"X" 3. EFFLUENT 4. UNITS 5. INTAKE (opdlonJ)1. POLLUTANT b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND a. a. MAXIMUM DAILY VALUE ((l[aailable) VALUE (QfavailabLe) AVERAGE VALUECAS NUMBER TESTING BELIEVEDBEUEVED (1) I (I) d. NO. OF a. CONCEN- (1) b. NO. OF

(If Joa~oltlaý) REQUIRED PRESENT ABSENT CONCENTRATION (2) MASS CONCENTRATION (2) MASS CONCENTRATiON (2) MASS JANALYSES TRATION b. MASS CONCETRrATION (2) MASS ANALYSES

GCIMS FRACTION - BAS2JNEUTRAL COMPOUNDS (contiwael)22. .-DaXoa <10 -- 1 ug/ kg/day22.3. 4.3-01chloro-benzene (106-46-7) 20 ug/. kg/dy

238. 3.3-Olchloro- <2 -1 ug/). kg/day'

24B. Dletyl dPhthela•e (a4-66-2) <10 -- I kg/day

258. DimehtlylPhthaloto <10 -- ! ug/l kg/day(131 -11-3) .

268. DI-N-But14 <10 -1 ug/ kg/da•yPhthalate (84-74-2) x 0 I I

2713. 2,4-D)litro- 10 1g US1 g/dlaytolue tc (121-14-2) x<0 --

28a. 2.6-oCltfo- <10 1 ug/) kg/daytoluene (606-20-2) X <_0 -- 1 US/1 ks/day

298. D•-N-Octyt gPhithalate (117-84-0) <10 -- 1 ug/) kg/day

30B. 1 .2-Dlphenyl-hydrazInc (asAzo- > <s0 - 1 ug/2 kg/daybenzene) (122-66-7)

319. Fluoranthene(20-6"00) x <10 -- 1 ug/ kg/day

22. Fluorene 0(66-73-7) <10 -- 1 UI/1 kg/day

338, Hexoachlorc- 1benzenE (118-74-1) <10 -- 1 Ug/1 kg/day348. Hexacr.hcloro.butadleno (87-68-3) x <10 -- 1 ug/L kg/day

359. Hexochloro-cyclopontadtlne <10 -- 1 ugh/ kg/day(77-47.-4) .

368 Hexachloro- kehane (97-72-1) <101 ug/l kglday

37B. Indeno(1.2,3-cd Pyrono <10 -- 1 ug/l kg/day(193-39-5)

388. lsophorono1(7-59-1) X < I ug/l kg/day

39B. Naphthlene <10 ugh kg/day(91-20-3) ' I -

40B. Nitrobenzene X(98-95-3) <I0 -- Ug/_ kg/day

41a. N-Nitry-sodlmethylanlne <10 -- 1 Ug/1 kg/day(62-75.6) x42B. N-Nltrosool-N.Propylmhtne X <10 -- 1 ugll kg/day(621-64-7) ( P

EPA Form 3510-2C (8-90) PAG E V-7 CONTINUE ON REVERSE


2. MARK"X " 3. EFFLUENT ....... 4. UNITS S. INTAKE (optiona)'

1. POLLUTANT b. MAXIMUM 30 DAY VALUE r. LONG TERM AVRG. ' a. LONG TERM

AND ab. I a. MAXIMUM DAILY VALUE (If aoailable) VALUE [fava/lable) AVERAGE VALUECAS NUMBEER TESTiNG BEEIEVED BEIUEVED (1) 1 ((1) 1) d. NO. OF a. CONCEN- () b. NO, OF

(/avaitZabl) REQUIRED PRESENT j ABSENT CONCENTEATION (2) MASS CONCENTRATION (2) MASS CONCEN(TRATION (21 MAS ANALYSES TRATION b. MASS CONCENTRATION I (2) MASS JANALYSES

GC/MS FRACTION - BASE'NEUTRAL COMPOUNDS (con,•M=d)

438. N-Nitro- 1spe.n <10 -- ug/1 kg/day

448. Phananthrenfe <10 1g/ kg/day

458. P5yrt- <10 ug/l kg/day(129-00-0) <10 -- 2 ug/ kg/day_

468. 1,2.4-TII-ahlomoberiet' <10(120-82-1) <2.0 -- k9. ug/

GO/MS FRACTION - PESTICIDES

IP.Aiddn(309-00-2) ....

2P. a-BHC(319-84-8) __ ____

3P. .- NHOC(319-85-7) _ __

4P. 7-BHC(58-89-9)

SP. -8-HC(319-8"-) ______

sP. Chlordan1e(57-74-9)

7P. 4,4"-DDT(50-29-3)8P. 4.4"-0DD(72-55-9)

SP. 4,4"-DD(732--8)

lopP. Dieldrin(80-51-1) ____

11P. a.Enosu~tan(I 15-29-7)

12P. A-Erdosu fan(I 1I -29-7)

13P. EndosulfanSulfate(1031-07-8)

14P. Endrn(72-20-8)

1 5P. EnrdrinAidehyde(7421-93.4)

16P. Heptachlor(78-4-4-8) __________ ____


0-

0 0 0I

EPA I.D. NUMBER (copyfrom Item I ofFonm 1) O UTFALL NUMBER

0H0003786 801II•ONTINUPD FROIM PAG•P V-S

2. MARK X 3. EFFLUENT 4. UNITS 5. INTAKE (optional)1. POLLUTANT' b. MAXIMUM 30 DAY VALUE c. LONG TERM AVRG. a. LONG TERM

AND a. b. . a. MAXIM U M DAILY VALU E (0f viZlable) VALUE (If available) AVERAGE VALUECAS NUMBER TESTING .EUEVFD BEUEVED (1) d. NO. OF a. CONCEN- b. NO. OF(2 avalrable) REDUIRED PRESENT AESENT CONCNTRATION (2) MASS CONCNTRATION (2) MASS CONCENTRATION 2)MASS ANALYSES TRATON . MASS CCNCERA'rl0,r" i)SS ANALYSES

GCIMS FRACTION - PESTICIDES (condlnue.4

1TP. Heptachlr''

(1024-57-3)

loP. P08-1242(53469-21_9)

TSP. PCB.- 254(11097-69-1)

20P. PCB-1221(11104.-28-2)

21P. PC8-1232(11141-16-6)

22P'. PCE.-124,(12672-29-6)"_

23P. PCB-1260(1109r-82-5)

24P. PC0-1016(12674-11-2)

o;-5.-Toxaphcn.(6001-35-2) j____________-FPA Form 3510-2C (6w90) PAGE V-9

L-10-287Enclosure C

US EPA Form 2F

for the



(13 pages follow)

PAID(Number(copy fromlem I ofForfm 1)O0HO003786 'I Form Approved. OMB No. 2040-0086

Approv'al explires 5-31-92Please orint or Wooe In the unshaded areas only.

NPDES

U.S. Environmental Protection Agency

Washington, DC 20460

Application for Permit to Discharge Storm WaterDischarges Associated with Industrial Activity

Paperwork Reduction Act NoticePublic reporting burden for this application Is estimated to average 28.6 hours per applicaton, Including time for reviewing Instructions, searching existing data sources,gathering end maintaining the data needed. and completing and reviewing the colection of Information, Send comments regarding the burden estimate, any other aspectof this cogection of Information, or suggestions for Improving this form, Including suggestions which may Increase or reduce this burden to: Chiel. Information PolicyBranch, PM-223, U.S. Environmental Piotection Agency. 1200 Pennsylvania Avenue, NW, Washington, DC 20460, or Director, Office of Information and RegulatoryAffairs, Oftice of Management and Budget, Washington, DQ 20503.

I. Outfall LocationFor each outfall. list the latitude and lonoitude of Its location to the nearest 15 seconds and the name of the receiving water.

A. Outfall Number D. Receiving Water(ist) B. Latitude C. Longitude (name)

002 41 35 35 83 5 20 iPool 3 Navarre Marsh to Toussaint River

005 41 35 5 83 4 55 Pool 3 of Navarre Harsh ftTtITP)

006 41 3S 50 83 5 5 Pool 1 of Navarre Marsh to Lake Erie IP&SG)

IL. ImprovementsA. Are you now required by any Federal, State, or local authority to meat any Implementation schedule for the conslnrction, upgrading or operation of wastewater

treatment equipment or practices or any other environmental programs which may affect the discharges described In this application? This Includes, but Is not limitedto, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, end grant or loan conditions.

2. Afected Outfalls 4. Finat1. Identification of Condiltons, Compliance DateAgreements, Etc. number source of discharge 3. Brief Descdpti'on of Progeci a. req. b. proj.

B: You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program Is now under way or planned, and Indicate your actual or planned schedules for construction.

11. Site Drainage Map

Attach a site map showing topography (or Indicating the outine of drainage areas served by the outfales(s) covered In the appirrcation it a topographic mapis unavailable)depicting the facility Including: each of Its Intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainagearea of each storm water outfall, each known past or present areas used for outdoor storage of disposal of significant materials, each existing structural control measureto reduce pollutants In storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each ofits hazardous waste treatmont, storage or disposal units (Including each area not required to have a RORA permit which Is used for accumulating hazardous wasteunder 40 CFR 262.34); each wen where fluids from the facility are Injected underground; springs, and other surface water bodies which received storm water dischargesfrom the facility.

EPA Form 3510-2F (1-92) Page 1 of 3 Continue on Page 2

I

Continued from the Front

[IV. Narrative Description of Pollutant Sources .A. For eads cuffell, potde an estimale d the area (include unIts) of imperious surfaces nctuinag paved areas and buiIdng roofs) drained to the oatl, and en e.Wimate of the total surface area

drained by the outfall.

Outran Area of Imp•ivious Surface TotalAra Drahed Oueat Area of Imperlious Surface Total Area OrainedNWuber (proVire Urs) (pronMe units) Nuanber proide un.ts) ,(rovide unis

002 - 617,245 sq. ft. 5,120,478 sq.ft005 88,000 sq. ft. 91,735 sq. ft.006 87,063 sq. ft. 155,886 sq. ft.

B. Provide a narrative description of significant materials that are currently or In the past three years have been treated, stored or disposed In a manner to allow exposureto storm water-, method of treatment, storage, or disposal; past and present materials management practices employed to mintmlze contact by those matertals withstorm waste runoff; materials loading and access areas, and the location, manner, and frequency In which pesticides, herbicides, soft conditioners, and fertilizers areapplied.

See Attachment A

C. For each outfall. provide the location and a description of existing structural and nonstrucdural control measures to reduce pollutants In storm water runoff; and adescription of the treatment the siorm water receives, Including the schedule and type of maintenance for control and treatment measures and the ultimate disposalof any solid or fluid wastes other than by discharge.

Outtiall List Codes fromNumbes Treatment Table 2F-1

002 Flotation/Sedimentation/Stabilization Pond L-H-Flotation1-U-Sedimentation3-O-Stabilizatlon

005 Discharge to Surfane Water 4-A-Discharge006 Flotation/Sediaentstion 1-H-Flotation

1-U-Sedimentation

V. Nonstornwater Discharges

A. I certify under penally of law hat the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges, and that allnonstormyeater discharged from these outfall(s) are identified In etiher an accompanying Form 2C or From 2E application for the outfall.

Name and official Tidea (type or pn'nt) "S~nature , Date Signed

B. Provide a description ot the method used, the date of any testIng, and the onsite drainage points that were directly observed during a test.Ouctfall 002 has been evaluated for the presence of non-atorm water discharges based on observation of the outfall during dryweather conditions and examination of piping and site diagrams. No unidentified non-storm water sources were found for the WRTP(005) or P&SG (006) outfalls.

f1l. Significant Leaks or Spills

Provide existing Iaformation regarding the history of significant leaks or spills of toxic or hazardous pellutants at the facility In the last three years, Including theappro•rd'ato date and location of the spill or leak and the type and amount of material released.

rhere have been no significant leaks or spills of any toxic or hazardous pollutants at the Davis ensee Plantin the last threerears.

EPA Form 3510-2F (1.92) Page 2 of 3 Continue on Page 3

Conflnued from Page 2EPA 10 Number (copy from Item I of Form 1)

OH0003766 I-

VlI. Discharge Information - I ý . -

A, B, C, & D: See Instructions before proceeding. Complete one set of tables for each oulfall. Annotate the outfall number In the space provided.

Table VII-A, V1t-B; VIl-C are Included on separate sheets numbers VII-1 and VWl-2.

E. Potential discharges not covered by analysts - Is any toxIc pollutant listed In table 2F-2, 2F-3, or 2F-4. a substance or a component of a substance whIch you

currently use or manufacture as an Intermediate or final product or byproduct?

[] Yes (list all such pollutants below) D- No (go to Section DO

VIII. Biological Toxicity Testing DataDo you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water Inrelation to your discharge within the last 3 years?

'[:] Yes (list ell such pollutants below) [] No (go to Section IX)

IX, Contract Analysis Information ý iIOR 1; !!1,'1:

Were any of the analyses reported In Item VII performed by a contract laboratory or consulting firm?

El Yes (fist the name, address, end telephone number of, and pollulants No (go to Section X)analyzed by, each such laboratory orfimn below)

A. Name B. Address C. Area Code & Phone No. 0. Pollutants Analyzed

X. Certification

I certify underpenally of law that this document and all attachments were prepared under my drectlon or supervision In accordance wnlh a system designed to assurethat qualified personnel property gather and evaluate the Information submitted. Based on my Inquiry of the person or-persons who manage fhe system or those personsdirectly responsible for gathering the Information, the Informaifon submitted Is, to the best of my knowledge and befie!, true, accurate, end complete. 7 am aware that

A. Name & Official Title (Type Of MnO ""B. Area Code and Phone No.

Bar S. Ale, Sit V.P.- D.B. Nuclear1•/ ••1C'. Signature, 0 . Date Signed

EPA Fr3502(1.92) Page 3 of 3

IoEPA ID Number (copy from Rlem 1 of Formn )10HO003786-SW Outfall 002

Form Approved. OMB No. 2040-0086Approval expkies 56-31-92

VII. Discharge Information (Continued from page 3 of Form 2F)

PartA - You must provide the msulls of at least one analysis for every pollutant In this table. Complete one tab!e for each oulfall. See Instructions for additional details.

Maximum Values Arerage Values(enclude units) 17nclude units) Number

Pollutant GiabSample Grob Sample ofend Taken Durng Taken During Slorm

CAS Number First 20 Flow-Waelghted First 20 Floiv-Welghted Events(if avallable) Minutes Composite Minutes Composite Sampled Sources of Pollutants

Oi and Grease <s eq/! NA /A

Biological OxygenDemand (BOD5) 3.3 rrig/i

Chemical OxygenDemand (COD) 11.3 9'/1

Total SuspendedSolids (TFS) 12 mg/l

Total Nitrogen <0.20 rrg/ I

Total Phosphorus <0.05 mg/I I

pH blnlnmum 7.97 M3XImum 7. 97 Minimum Maximum I

Pad B - List each pollutant that Is limited In an effluent guideline which the facility Is subject to or any pollutant listed in the facllily's NPDES permit for Its processwastewaler (if the facility Is operating under an existing NPDES permit). Complete one table far each outfall. See the Instructions for additional delails andrequirements.

Maximum Values Average Values(Include unils) (nctu do units) Number

Pollutant Grab Sample Grab Sample ofand Taken During Taken During Storm

GAS Number First 20 Flow-Welghted First 20 Flow-Weighted Events(if avaMlable) Minutes Composite Minutes Composite Seampled Sources of Pollutanls

Dies, Oxygen 7.6 ppm I

TRC <0.0os g/i

Fluoride 0.4 mg/l

Aluminum 538 ug9/

Arsenic <10 u9/l

Barium 78 u9/i

Boron 112 ug/l

Copper <3 Ug/i

Iron 471 ug/_

Silver <5 ug/l

AmnmOnia <0.2 mg/l

T•N <0.2

EPA Form 35`10-21' (1-92) Page VAi-1 Continue on Reverse

I

I EPA IO Number (copy [rom /loe I of Form 1) IPH0003786-SW Outfall 006 1

Form Approved. OMB No. 2040-0086Approval expires 5-31-92

Vii. Discharge Information (Continued from pago 3 of Form 2F)

Part A -You must provide the results of at least one analysis for every ootlutantIn this table. Complete one table for each outfall. See Instructions for additional details.

Maximum Values " Average Values(laclude units) Jinclude units) Number

Pollutant Grab Sample Grab Sample ofand Taken During Taken During Storm

CAS Number First 20 Flow-Weighted First 20 Flow-Weighted Events(if available) Minutas Composite Minutes Composite Sampled Sources of Polutants

Oil and Grease <5 Mg/1 N/A I

Biological Oxygen 9 ag/S..Demand (3005) 1.9 f/I

Chemical Oxygen .' mg/lDemand (COD) 54 a/ATotal SuspendedSolids (SS) I57 ra/i

Total Nitrogen 0.45 ag/I I

Total Phosphorus 0.27 mrg/i

pH Minimum 7.02 Maximum 7.02 Minimum Maximum

Part 8 - List each pollulant that Is limited In an effluent guldeline which the facliuty Is subject to or any pollutant listed in the faclity's NPDES permit for Its processwastewaler (it the facility Is operating under an existing NPDES permit). Complete one table for each outfall. See the Instructions for additional details andIrequirements.

Maximum Values Average Valuesflnc/udo units) (include units) Number

Pollutant Grab Sample Grab Sample orand Taken During Taken During Steorm

CAS Number First 20 FloW-Welghted First 20 Flow-Welghted Events(if available) Minutes Composite Minutes Composite Sampled Sources of Pofulants

Dies. Oxygen 4.5 ppm 1

IRC 0.1 mrg/

Fluoride 0.8 rg/I

Alumrnum 1377 ug/l

Arsenic <10 ug/l

Bax. um 98 ug/l

Boron 77 ug/l

Copper 14 ug/_

Iron 14706 ug/l

Silver <1 ug/l

,nrreonia 0.8 mag/l

TE o - 1.2 Pog/l

EPA Form 3510-217 (1-92) Page VIH- Continue on Reverse

DAVIS-BESSE NUCLEAR POWER STATION

23 ?AA$9cKjdyAAlQt. UtE Jm(J1(ALL

OVA OdIM'SIt AW4LX cAk~fI ~M. j-I SU1CEN UtEIIHIM dMIAd

i-NpWIEW&alOLDawwS2. $MICE WILDIW4 -Z

W?? WASM1 UflR nWWf~d KW31

'SC USLDIC SrOWE TAW. (DIKEID)DIESE OIL.C W SIOdSSC lAXC W3XD)

W "_ DJ..flED 6zrS um4 (lIKmnFu I~I l I~L D4 dlS

S1U V.535K No RUM= M135.104.95 OF JTFAL . 5

STMd VATSS (OITFALLIII (MI8 -431 W= t ITM MADWC PLAY

MM11 -~1AM 831F~AL IUT 13881 - KEIIS1TgJTd. PAMWd & S&G1CC J

ATTACHMENT ADavis-Besse Nuclear Power Station

EPA I.D.#: OH0003786

The following significant materials have been stored on-site within the last three years within thedescribed stormwater discharge areas:

1. Outfall 002 (Training Center Pond Discharge)

a. Chemnical Waste Storage Areas (CWSA)

The CWSA is an enclosed structure with a curbed concrete pad to contain anypotential leaks. The pad is divided into three separate sections as follows: 1)hazardous waste, 2) waste oil and non-hazardous wastes, and 3) chemicalidentification. In the event of a large quantity leak, the flapper gates for thedrainage ditch behind the facility can be closed to isolate the spill. Also, theCWSA is inspected on a weekly basis.

b. Chemical Waste Accumulation Areas (CWAA)

There are two CWAAs In this stormwater discharge area. These two CWAAs areonly for diesel fuel. They each consist of two 55-gallon drums contained In thewater-tight plastic storage containers.

c. Sodium Hypochlorite (NaOCI) Tank

The NaOCI tank, which Is located at the site water treatment plant, has amaximum capacity of 7,500 gallons and contains a 15% solution. This tank hasa dike structure designed to contain 115% of the tank capacity.

d. Sodium Bromide (NaBr) Tank

The NaBr tank, located at the Water Treatment Plant, has a 4,500 galloncapacity and contains a 43% solution. This tank has a dike structure designed tocontain 110% of the tank capacity.

Page .1 of 3

ATTACHMENT ADavis-Besse Nuclear Power Station

EPA I.D.#: OH0003786

e, Oil Containment

Oil Containment consists of the following:

an I apacty Physical CotrolsTank. Eqim n (g. ... ..

Diesel Oil Storage Tank 100,000 DikedEmergency Diesel Generator 26000 each Collected in an Oil(EDG) Day Tanks I- InterceptorEmergency Diesel Generator 2-40,000 each None- Underground(EDG) Fuel Oil Storage Tanks IMiscellaneous Diesel Generator 750 Retaining CurbDay Tank I 5 _eaIningCurbCollected in RoomTurbine-Generator (T-G) LubeColceinRmTanks 2-14,000 each Sump and in an Oil

TanksIi 6terceptor

Main Feed Pump Turbine (MFPT) Collected In MFPTLube Oil Tanks 2-1,200 Accumulation PitMFPT Used Oil Tank 2,800 Collected in MFPT

Accumulation PitDrains to a 54,600

Main Transformer 24,000 Gallon CollectionTank

Spare Main Transformer 24,000 DikedStation Blackout Generator DieselFuel Storage Tank 1,627 Diked

Auxiliary Transformer 4,600 Drains to a 54,600gallon collection tank

Startup Transformer "10,700 Drains to a 54,600gallon collection tank

Spare Startup Transformer 16,500 DikedBus Tie AC and BD Transformers 2-1,926 each Drains to a 54,600

gallon collection tank

Lubricating Oil Drum Storage 22 55-gallon Retaining CurbRoom drumsWaste Oil Storage Tank 2,000 None-UndergroundEmergency Response Facility 8,000 None-UndergroundDiesel Generator Day Tank

There are five oil interceptors which service plant drains and sumps entering the Outfall002 Discharge System. Those storage tanks or equipment whose containments are notdirectly associated with the interceptors, would ultimately be serviced by an interceptorvia adjacent plant floor and service drains. The underground storage tanks listed are notserviced by oil interceptors.

Page 2 of 3

AT-ACHMENT RDavis-Besse Nuclear Power Station

EPA I.D.#: OH0003786

2. Wastewater Treatment Plant (WWTP) Outfall

Sodium Bisulfite (NaHS04) Tank

The NaHSO4 tank, that is located near the station collection box, has a 900 galloncapacity and contains a 40% solution.

3. Construction Parking and Service Building (P&SB) Outfall

a. Diesel Fire Pump*Day Tank

This tank has a 350 gallon maximum capacity and a retaining curb, which willcontain any oil accumulations.

b. Diesel Fuel Storage Tank and Gasoline Storage Tank

Used to service fleet vehicles, the diesel fuel storage tank has a 1,000 galloncapacity, and the gasoline tank has a 2,000 gallon capacity. They share thesame concrete dike, which Is designed to contain 115% of the total capacity.

c. Chemical Waste Accumulation Area (CWAA)

This outfall area has one accumulation area for automotive oils and antifreeze.This CWAA is a self-contained unit designed with a spill pan underneath.

4. General Information

In addition to the spill control methods mentioned above, the Site Spill Prevention Controland Countermeasure Plan, and Chemical Control Program are the primary directives forthe control of significant materials. Many personnel on site are HAZWOPER qualified tothe technician level, which requires extensive training on spill prevention and mitigation.Also, in the event of a spill, spill kits are located at the designated areas throughout thesite for easy access; these kits contain absorbent booms, pads, and personnel protectiveequipment.

No pesticides, soil conditioners, or fertilizers are applied to any of these outfall areas.

Page 3 of 3

I

= Page 1

DIVISION OF SURFACE WATER

Antidegradation Addendum

In accordance with Ohio Administrative Code 3745-1-05 (Antidegradation), additionalinformation may be required to complete your application for a permit to install orNPDES permit, For any application thrat may result in an increase in the level ofpollutants being discharged (NPDES and/or PTI)or for which there might be activitytaking place within a stream bed, the processing of the permit(s) may be required togo through procedures as outlined in the antidegradation rule. The rule outlinesprocedures for public notification and participation as well as procedures pertainingto the levels of review necessary. The levels of review necessary depend on the-degradation being considered/requested. The rule also outlines exclusions fromportions of the application and review requirements and waivers that the Director maygrant as specified in Section 3745-1-05(D) of the rule. Please complete the followingquestions. The answers provided will allow the Ohio EPA to determine if additionalinformation is needed. All projects that require both an NPDES and PTI should submitboth applications simultaneously to avoid going through the antidegradatibn processseparately for each permit

A. Applicant: Davis-Besse Nuclear Power Station

Facility Owner: FirstEnergy Nuclear Generation Corp.

Facility Location (city and county): Oak Harbor, Ottawa

Application or Plans Prepared By: Scott F. Brown

Project Name: Davis-Besse NPDES Permit Renewal

NPDES Permit Number (if applicable): 21B00011

B. Antidegradation Applicability

Is the application for? (check as many as apply):

Application with no direct surface water discharge (Projects that donot meet the applicability section of 3745-1-05(B)I, i.e., on-sitedisposal, extensions of sanitary sewers, spray irrigation, indirectdischarger to POTW, etc.). (Complete Section E)

X Renewal NPDES application or PTI application with no requestedincrease in loading of currently permitted pollutants. (CompleteSection E, Do not complete Sections C or D).

PTI and NPDES application for a new wastewater treatment works thatwill discharge to a surface water. (Complete Sections C and E)

An expansion/modification of an existing wastewater treatment worksdischarging to a surface water that will result in any of thefollowing (PTI and NPDES):(Complete Sections C and E)

addition of any pollutant not currently in the discharge, oran increase in mass or concentration of any pollutantcurrently in the discharge, oran increase in any current pollutant limitation in terms ofmass or concentration.

Click to clear all entered Information (on all 4 pages of this form)

PTI that involves placement of fill or installation of any portionof a sewerage system (i.e., sanitary sewers, pump stations, WWTP,etc,)within 150 feet of a stream bed. Please provide informationrequested on the stream evaluation addendum (i.e., number of streamcrossings, fill placement, etc.) and complete Section E.

Initial NPDES permit for an existing treatment works with awastewater discharge prior to October 1, 1996. (Complete Sections Dand E)

Renewal NPDES permit or modification to an effective NPDES permitthat will result in any of the following: (Complete Sections C and E)

a new permit limitation for a pollutant that previously had nolimitation, oran increase in any mass or concentration limitation of anypollutant that currently has a limitation.

C. Antidegradation Information

1. Does the PTI and/or NPDES permit application meet an exclusion as outlinedby OAC 3745-1-05(D)(1) of the Antidegradation rule?

Yes (Complete Question C.2)

No (Complete Questions C.3 and C.4)

2. For projects that w6uld be eligible for exclusions provide the followinginformation:

a. Provide justification for the exclusion.

b. Identify the substances to be discharged, including the amount ofregulated pollutants to be discharged in terms of mass andconcentration.

c. A description of any cons truction work, fill or other structures tooccur or be placed in or near a stream bed.

3. Are you requesting a waiver as outlined by OAC 3745-1-05(D) (2-7) of theAntidegradation rule?

No

Yes

If you wish to pursue one of the waivers, please identify the waiver andsubmit the necessary information to support the request. Depending on thewaiver requested, the information required under question C.4 may berequired to complete the application.

4. For all projects that do not qualify for an exclusion a report mustaccompany this application evaluating the preferred design alternative,non-degradation alternatives, minimal degradation alternatives, andmitigative techniques/measures for the design and operation of theactivity. The information outlined below should be addressed in thisreport. If a waiver is requested, this section is still required.

a. Describe the availability, cost effectiveness and technicalfeasibility of connecting to existing central or regional sewagecollection and treatment facilities, including long range plans for

sewer service outlined in state or local water quality managementplanning documents and applicable facility planning documents.

b. List and describe all government and/or privately sponsoredconservation projects that may have been or will be specificallytargeted to improve water quality or enhance recreationalopportunities on the affected water resource.

c. Provide a brief description below of all treatment/disposalalternatives evaluated for this application and their respectiveoperational and maintenance needs. (If additional space is neededplease attach additional sheets to the end of this addendum).

Preferred design alternative:

Non-degradation alternative(s):

Minimal degradation alternative(s):

Mitigative technique/measure(s):

At a minimum, the following information must be included in the report foreach alternative evaluated.

d. Outline of the treatment/disposal system evaluated, including thecosts associated with the equipment, installation, and continuedoperation and maintenance.

e. Identify the substances to be discharged, including the amount ofregulated pollutants to be discharged in terms of mass andconcentration.

f. Describe the reliability of the treatment/disposal system, includingbut not limited to the possibility of recurring operation andmaintenance difficulties that would lead to increased degradation.

g. Describe any impacts to human health and the overall quality andvalue of the water resource.

h. Describe and provide an estimate of the important social andeconomic benefits to be realized through this proposed project.Include the number and types of jobs created and tax revenuesgenerated.

* i. Describe environmental benefits to be realized through this proposedproject.

j. Describe and provide an estimate of the social and economicbenefits that may be lost as a result of this project. Include theimpacts on commercial and recreational use of the water resource.

)

k. Describe the environmental benefits lost as a result of thisproject. Include the impact on the aquatic life, wildlife,threatened or endangered species.

1. A description of any construction work, fill or other structures tooccur or be placed in or near a stream bed.

m. Provide any other information that may be useful in evaluating thisapplication.

D. Discharge Information

1. For treatment/disposal systems constructed pursuant to a previously issuedOhio EPA PTI, provide the following information:

PTI NumberPTI Issuance DateInitial Date of Discharge

2. Has the appropriate NPDES permit application form been submitted including

representative effluent data?

Yes (go to E)

No (see below)

If no, submit the information as applicable under a OR b as follows:

a. For entities discharging process wastewater attach a completed2C form.

*b. For entities discharging wastewater of domestic origin attach theresults of at least one chemical analysis of the wastestream for allpollutants for which authorization to discharge is being requestedand a measurement of the daily volume (gallons per day) ofwastewaters being discharged.

E. Based on my inquiry of the person or persons who manage the system or thosepersons directly responsible for gathering the information, the information is,to the best of my knowledge and belief, true, accurate and complete.

This section must be signedby the same responsible person who signed theaccompanying permit application oir certification as per 40 CFR 122.22.

Signature _______________

Date /dLa-If d/

h;revtsed.,a'Jue 30, 1997

I

View/Print Label1. Print the label: Select the print icon in your PDF Reader window to print the label below.

2.'Fold the printed label at the dotted line. Place the label in a UPS Shioing Pouch. If you donot have a pouch, affix the folded label using clear plastic shipping tape over the entire label.

3. GETTING YOUR SHIPMENT TO UPS

Customers without a Daily Pickup

o Take this package to any location of The UPS Store®, UPS Drop Box, UPS CustomerCenter, UPS Alliances (Office Depot® or Staples®) or Authorized Shipping Outlet nearyou or visit www.ups.com/content/us/en/index.jsx and select Drop Off.

o Air shipments (including Worldwide Express and Expedited) can be picked up or droppedoff. To schedule a pickup, or to find a drop-off location, select the Pickup or Drop-off iconfrom the UPS tool bar.

Customers with a Daily Pickup

o Your driver will pickup your shipment(s) as usual.

FOLD HERE

!

Binder 2 of 2, Davis-Besse Nuclear Power Station, Unit No. 1 ...

Documents

Transcript of Binder 2 of 2, Davis-Besse Nuclear Power Station, Unit No. 1 ...