Technical Submittal NITOCOTE EN901

Technical Submittal

NITOCOTE EN901

Al Gurg Fosroc LLC P O Box 657, Dubai U.A.E. Tel : 04 2039699, Fax : 04 2859649 www.fosroc.com

CONTENTS

section 1 Submission Summary

Company Introduction

section 2 ISO Certification

Trade License

section 3 Technical Data Sheet

Method Statement section 4 Material Safety Data Sheet

Section 5 Independent Test Certification

section 6 Job references

Company Profile

SUBMISSION SUMMARY

Summary

Fosroc’s range of products offer the following key advantages :

• technology developed to match application criteria

• high durability - long service life

• full compatibility between systems

• excellent track record in Middle East conditions

In terms of this submission, points of note include the following :

• technical data sheet

• independent test certificates

• job references and approvals of previous applications

The other main benefits of choosing Fosroc include :

• products manufactured by an ISO 9002, quality-assured manufacturer

• full range of complimentary products to ensure a compatible system

• products manufactured, and fully supported, locally in the UAE

• experienced, local applicators available

• additional training available for main contractor’s supervisory staff to ensure that the correct installation techniques are observed throughout

Al Gurg Fosroc

The company was founded as a joint venture in 1975 between HE Easa Saleh Al Gurg and Fosroc International. Al Gurg Fosroc is the first construction chemicals company to establish a manufacturing base in the region, and presently serves the markets of the U. A. E., Kuwait, Bahrain, Qatar, Oman and other Fosroc companies worldwide.

Fosroc is one of the world's leading manufacturers of advanced technology products for the construction and refurbishment industries.

For over 25 years, Al Gurg Fosroc is widely recognised as the market leader in concrete repairs and protection, in particular; and has built a substantial reputation in a wide range of product fields: Admixtures - Concrete repair and protection - Joint fillers and sealants -Waterproofing - Protective coatings - Surface treatments - Waterstops - Grouts and anchors – Flooring – Electrochemical products and services.

Fosroc's success is built on a powerful combination of market knowledge, technical resource, manufacturing expertise and problem-solving capabilities. The company follows a policy of detailed product research and development providing high quality products and long-term solutions.

The company has been the first construction materials manufacturing company to introduce specification and AutoCAD services.

Al Gurg Fosroc's products are guaranteed for quality, but they must be applied correctly and consistently to benefit from a long service life. To ensure this success, Al Gurg Fosroc has introduced a Contracts and Application Department. This ensures that the technical product knowledge is transpired to the applicators and the availability of the local technical support center ensures that the correct application techniques are followed.

Al Gurg Fosroc's commitment to total quality management system had lead to ISO 9002 certification in December 1994 - the first construction chemicals company in the Gulf region to achieve this prestigious award. To keep up with the present market demands, Al Gurg Fosroc has chosen the policy of continuous improvement, which led to ISO 9001:2000 certification in July 2003.

Al Gurg Fosroc was awarded the ISO 14001 certification in 1996 making it the first construction chemicals company and the third company in any sector in the Gulf region to receive this award.

As a clear indication of continual improvement in safety, quality and environmental standards, Al Gurg Fosroc was awarded the OHSAS 18001 certification in October 2004.

Al Gurg Fosroc has a state of the art production unit, which has an output exceeding 120,000 metric tonnes per annum.

www.fosroc.com

http://www.fosroc.com/

ISO Certificate

Technical data sheet

Nitocote

EN

901

constructive solutionsFosroc Nitocote EN901

High chemical resistant protective lining

Uses

Nitocote EN901 is an Epoxy Novolac lining designed to provide

protection to concrete and steel structures in aggressive

chemical conditions. The material is particularly suitable in

wastewater treatment plants, desalination plants, food

processing plants, pump and paper mills, electric power

plants, chemical manufacturing plants, fertiliser and

insecticide plants and petroleum refineries.

Nitocote EN901 may be used with or without Fosroc Anti-slip

grains as a heavy-duty floor coating in applications such as

chemical processing and drum storage areas, loading docks

and ramps. It may also be used in conjunction with glass

fibre cloth to increase the thickness of the system or to

reinforce structures subjected to aggressive chemicals.

Advantages

Nitocote EN901 is 100% solids, no solvents

Nitocote EN901 exhibits excellent chemical resistance in

pH ranging from 1-14 at 25°C

Nitocote EN901 has excellent adhesion to properly

prepared concrete, mild steel, and other substrates

Nitocote EN901 has excellent abrasion resistance

Description

Nitocote EN901 is a solvent free, highly crosslinked, high

build epoxy-novolac-based coating. Nitocote EN901 is a two-

part material and can be applied by brush or roller. Nitocote

EN901 is grey in colour. It is formulated to be applied in one

or two coats to achieve a minimum total-dry-film thickness of

500 microns. Higher thickness can be specified.

Specification

Chemical and abrasion resistant lining

The chemical and abrasion resistant coating shall be

Nitocote EN901, a high build, two-pack epoxy-novolac system

specially designed to provide a tough and impermeable high

chemical resistant film.

Properties

Solid content : 100%

Finish : Gloss

Colour : Grey

Specific gravity : 1.35

Pot life : 45 min. @ 23°C

20 min. @ 35°C

Tack-free time : 4 hours @ 23°C

2 hours @ 35°C

Overcoating time : <16 hours @ 23°C

<10 hours @ 35°C

Full cure : 7 days @ 23°C

5 days@ 35°C

Tensile strength : 30 N/mm2

(ASTM D638)Flexural strength : 30 N/mm2

(ASTM C580)Compressive strength : 85 N/mm2

(ASTM C579)Hardness : >70 Shore D

(ASTM D2240)Abrasion resistance : <0.10 mg/cycle

(1 kg, CS10 Wheels)(ASTM D4060)Service temperature : <60°C

Reaction to fire(ASTM E84/UL 723) : ‘Class A’ ( For flame spread

Index (FSI) and Smokedevelopment Index (SDI))

Chemical resistance

The fully cured coating is resistant to the splash/spillage of

the following chemicals

Acetic Acid 25% Hydrochloric acid 35%

Ammonium Hydroxide * Hydrofluric acid 25%

Benzene Jet fuel

Benzoyl chloride Isopropanol

Benzyl alcohol Ethylene glycol monoethyl ether

Bleach (Sodium hypochlorite) Kerosene

Boric Acid * Lactic acid 20%

Brake Fluid Methyl isobutyl ketone

Brine 10% Mineral spirit

Car oil Nicotinic acid *

Carbon tetrachloride Nitric acid 30%

Castor Oil Phenol 50% in IPA

Deionised water Phosphoric acid 85%

Diesel fuel Potassium hydroxide *

Diethanolamine 88% Propylene glycol

Ethylene glycol Sea water

Hydrogen peroxide 20% sol Skydrol

Fatty acids Sodium hydroxide *

Formaldehyde 37% Sulphuric acid *

Gasoline Tartaric acid 50%

Sewage Citric acid 50%

Hexamine 25% Toulene

Hexane Vegetable oils

Hydraoine 35% Xylene

* Any concentration in water

The local Fosroc office should be consulted for resistance to specific chemicals and conditions or

when long term exposure is required.

Nitocote EN901 - Page 2 of 4

Fosroc Nitocote EN901

Instructions for use

Preparation of concrete surfaces

All surfaces, which are to receive the lining, must be at least 28

days old and have a moisture content of less than 5%. These

surfaces shall be dry, sound and free form debris and loose

material. The substrate must be free from contamination such

as oil, grease, wax, dirt or any other form of foreign matter

which might affect adhesion.

All blow holes and imperfections should be filled with

Nitomortar FC*†.

Preparation of steel surfaces

All surfaces should be grit blasted to meet the requirements of

BS4232, First Quality.

The lining work should be programmed so that newly cleaned

steel is coated as soon as possible before the formation of

rust or scale.

Priming

Nitocote EN901 is designed to be used without primer.

However, if the condition of the concrete substrate requires

priming, Nitoprime 25* can be used.

Mixing

It is imperative that the resin be thoroughly mixed with the

hardener in the exact ratios to ensure optimum performance.

Therefore, the entire contents of the hardener can should be

added to the base container and mixed until a uniform colour

and consistency are obtained, taking particular care to scrape

the sides and bottom of the container. It is recommended that

mechanical mixing be employed using a Jiffy mixer on a slow

speed electric drill.

Application

Once mixed, Nitocote EN901 should be immediately applied

to the prepared surface ensuring a continuous coating of

uniform thickness is obtained.

Stiff nylon brush or short nap roller is recommended for such

application. Faster rate of application is possible using airless

spray equipment.

Re-coating

To re-coat, it is imperative that the second coat be applied

within the specified over-coating time.

Use of glass fibre reinforcement

Nitocote EN901 may be used in conjunction with glass fibre

cloth to increase the thickness of the system or, where

necessary, bridge fine cracks in the substrate. The cloth should

be laid directly on the first coat whilst wet and should be

pressed in and smoothed out with a split washer roller. A

second coat should then be applied within the specified over-

coating time.

Use of Fosroc Anti-slip grains

Nitocote EN901 can be used in conjunction with Fosroc Antislip

Grains*† to provide a heavy-duty slip-resistant flooring system.

The first coat will be applied as described above with a

minimum film thickness of 200 microns. The base coat should

now be dressed with the chosen Fosroc Antislip Grains.

The recommended procedure is to completely blind the base

coat i.e. apply excess dressing aggregate to completely

obliterate the base coat.

When the base coat has reached initial cure, the excess Antislip

Grains should be vacuum-cleaned from the surface.

The top coat can then be applied. Care should be taken to

ensure that a continuous film is achieved and the surface is

completely sealed.

Cleaning

Nitocote EN901 should be removed from tools and equipment

with Fosroc Solvent 102* immediately after use. Cured material

can only be removed mechanically.

Limitations

- Substrate, ambient and product temperature must remain

above 15°C during application and curing. Minimum

material/container temperature for spray application is

20°C. Avoid moisture contamination.

- Nitoflor EN901should not be applied on to surfaces known

to, or likely to suffer from, rising dampness, potential osmosis

problems or have a relative humidity greater than 75% as

measured in accordance with BS 8203 Appendix A, or by a

Hammond concrete/mortar moisture tester type COCO.

- Application should not be undertaken if the temperature is

below 5°C, or is 5°C and falling, nor when the prevailing

relative humidity exceeds 90%.

- Nitocote EN901 may not be colour stable when in contact

with some chemicals or direct sunlight. The colour change

will not affect the performance of the protective system

either on concrete or steel.

Nitocote EN901 - Page 3 of 4


Technical support

Fosroc offers a comprehensive technical support service to

specifiers, end users and contractors. It is also able to offer on-

site technical assistance, an AutoCAD facility and dedicated

specification assistance in locations all over the world.

Estimating

SupplyNitocote EN901 : 4 litre packs

Nitoprime 25 : 1 & 4 litre packs

Fosroc Solvent 102 : 4 litre cans

CoverageNitocote EN901 : 0.5 litre /m2 @ 500 microns

Nitoprime 25 : 4.0 - 5.0 m2 per litre

Note: The coverage figure is theoretical - due to wastage

factors and the variety and nature of substrates, practical

coverage figures may be substantially reduced.

Storage

When stored in dry air conditioned stores at temperatures

between 15-30°C, in the original, unopened containers Nitocote

EN901 will have a shelf life of 12 months.

If stored at high temperatures the shelf life will be reduced. Air

conditioned storage at high ambient temperatures is

recommended.

Precautions

Health and safety

Nitocote EN901 and Fosroc Solvent 102 should not come in

contact with skin and eyes, or be swallowed. Ensure adequate

ventilation and avoid inhalation of vapour. If working in confined

areas, then suitable respiratory equipment must be worn.

Some people are sensitive to resins and solvents. Wear

suitable protective clothing, gloves and eye/face protection.

Barrier creams provide additional skin protection. Should

accidental skin contact occur, remove immediately with a resin-

removing cream, followed by soap and water. Do not use

solvent. In case of contact with eyes, rinse immediately with

plenty of clean water and seek medical advice. If swallowed,

seek medical attention immediately - do not induce vomiting.

Fire

Fosroc Solvent 102 is flammable. Keep away from sources of

ignition. No smoking. In the event of fire, extinguish with CO2

or foam. Do not use a water jet.

Flash pointsFosroc Solvent 102 : 33°C

For further information, refer to the Product Material Safety

Data Sheet.

UAE/0418/12/H


Al Gurg Fosroc LLCPost Box 657, Dubai

United Arab Emirates

www.fosroc.com

Important noteFosroc products are guaranteed against defective materials and manufacture and are sold subject to its standard Conditions for

the Supply of Goods and Service. All Fosroc datasheets are updated on a regular basis. It is the user’s responsibility toobtain the latest version.

Head Officetelephone: (+9714) 2039699 fax: (+9714) 2859649 email: [email protected]

Regional officesAbu Dhabi, Al Gurg Fosroc telephone: 673 1779 fax: 673 1449 email: [email protected]

Bahrain, YBA Kanoo telephone: 17738200 fax: 17732828 email: [email protected]

Kuwait, Boodai telephone: 4817618 fax: 4832124 email: [email protected]

Oman, Al Amana telephone: 24815080 fax: 24817554 email: [email protected]

Qatar, Tadmur telephone: 4432365 fax: 4419517 email: [email protected]

* Denotes the trademark of Fosroc International Limited

† See separate data sheet

Additional Information

Fosroc manufactures a wide range of complementary

products which include :

waterproofing membranes & waterstops

joint sealants & filler boards

cementitious & epoxy grouts

specialised flooring materials

Fosroc additionally offers a comprehensive package of

products specifically designed for the repair and

refurbishment of damaged concrete. Fosroc’s ‘Systematic

Approach’ to concrete repair features the following :

hand-placed repair mortars

spray grade repair mortars

fluid micro-concretes

chemically resistant epoxy mortars

anti-carbonation/anti-chloride protective coatings

chemical and abrasion resistant coatings

For further information on any of the above, please consult

your local Fosroc office - as below.

Method statement

telephone: fax: email:

(+9714) 2039699 (+9714) 2859649 [email protected]

Registered Office: 215 Community, Street No. 13, Nad Al Hamar Road, Al Ramool Industrial Estate, Rashidiya, Dubai

Al Gurg Fosroc

LLC

Post Box 657, Dubai

United Arab Emirates

www.fosroc.com

constructive solutions Method statement

Nitocote EN901

Section A : General Comments Comments High temperature working It is suggested that, for temperatures above 35°C, the following guidelines are adopted as

good working practice: (i) Store unmixed materials in a cool (preferably temperature controlled - not above 25°C)

environment, avoiding exposure to direct sunlight.

(ii) Keep equipment cool, arranging shade protection if necessary. It is especially important to keep cool those surfaces of the equipment, which will come into direct contact with the material itself.

(iii) Try to avoid application during the hottest times of the day, arrange temporary shading as necessary.

(iv) Make sufficient material, plant and labour available to ensure that application is a continuous process.

Equipment

It is suggested that the following list of equipment is adopted as a minimum requirement.

Protective clothing : Protective overalls : Good quality gloves, goggles and face mask

Preparation equipment : Stiff wire brush

: Proprietary blasting equipment

Mixing equipment : 1 KW slow speed heavy duty drill, 400/500 rpm

: Fosroc mixing paddle MR3

Application equipment : Stiff Nylon Brush or Roller

: Airless spray equipment Application - points of note Fosroc operates a policy to encourage the use, where possible, of approved or licensed applicators. This ensures that repairs are completed satisfactorily so that the long-term performance of the materials is assured. For contractors who wish to apply the materials themselves Fosroc is also able to offer technical assistance and training, either on-site or at its Training Centre in Dubai

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constructive solutions

Section B : Application Method 1.0 Overcoating Any application of Nitocote EN901, which has become damaged, can be readily overcoated. 1.1 The existing surface should be well abraded, using a stiff wire brush, or similar, to

ensure that a good mechanical bond will be achieved between the two layers. 1.2 Overcoating works can then proceed as for new work. 1.3 Consult Data sheet for Overcoating times.

2.0 Preparation

Following the preparation, care should be taken to ensure that any exposed blowholes are filled with Nitomortar FC or Nitomortar FC (B).

2.1 Concrete Surfaces

2.1.1 All surfaces must be smooth, sound and free from debris, loose or flaking material, areas of standing water, oil grease and organic growth.

2.1.2 New concrete surfaces must be fully cured, laitance free and free from any traces of shuttering, release oils and curing compounds.

2.1.3 Light blasting is recommended as an effective method of surface preparation and provide suitable key for Nitocote EN901.

2.1.4 All steel surfaces should be grit blasted to meet the requirements of BS4232, First Quality.

2.1.5 For Steel surfaces, the lining work should be programmed so that newly cleaned steel is coated as soon as possible before the formation of rust or scale.

2.2 Steel Surfaces 2.2.1 All surfaces should be grit blasted to meet the requirements of BS4232, First Quality. 2.2.2 The lining work should be programmed so that newly cleaned steel is coated as soon

as possible before the formation of rust or scale. 3.0 Priming 3.1 For sound, untreated, good quality and non-porous substrates, priming is not required. 3.2 Porous substrates should be primed with Nitoprime 25/ Nitocote Primer Sealer.

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3.3 Mix the entire contents of the hardener can into the base container and mix until homogeneous.

3.4 Apply the primer to form a thin coating of continuous film on the substrate. During

application, ensure that the primer is brushed into the substrate with a stiff brush or roller and is not over applied causing “puddling”.

3.5 The primer should be left to achieve tack-free condition prior to application of Nitocote

EN901. Incase the substrate is excessively porous; a second coat of the primer may be applied.

4.0 Mixing

4.1 The contents of the base can should be stirred thoroughly to disperse any settlement.

4.2 The entire contents of the hardener can should be added to the base container and

mixed thoroughly until a uniform consistency is obtained, taking particular care to

scrape the sides and bottom of the container. It is recommended that mechanical

mixing be employed, using a Fosroc mixing paddle (MR3) on a heavy duty, slow

speed electric drill. 5.0 Application

Whilst Nitocote EN901 can be applied to damp surfaces; running water must be excluded from the work area during both application and curing of the product. Where excessive seepage or leaking occurs, consult the local Fosroc office for recommendations.

5.1 Hand application

5.1.1 Nitocote EN901 should be applied in two coats. The thoroughly mixed material should

be applied with a suitable brush or roller.

5.1.2 Nitocote EN901 must be firmly applied and be well scrubbed into the surface,

ensuring a uniform coating with a wet film thickness of between 250 and 500 microns

for horizontal application. For vertical application, ensure the wet film thickness is a

maximum of 350 microns per coat to avoid sagging. An exception is when using

Antislip grains, the first coat should be applied at a wet film thickness of 200 microns

to avoid the Antislip grains sinking too deep into the coating. Subsequent coats are

then applied at the normal thickness.

5.2 Spray application

5.2.1 Faster rates of application are possible using suitable airless spray equipment.

Consult the local Fosroc office prior to application for technical advice.

5.3 Glass Fibre reinforcement

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5.3.1 Immediately upon completion of the first coat, lay the glass fibre reinforcement directly

on the wet substrate.

5.3.2 The second coat should be applied over the reinforcement within the overcoating time

specified in the data sheet.

5.4 Anti-slip finish

5.4.1 Immediately upon application of the first coat, seed the coating with Fosroc Antislip

Grain No. 1200. Ensure complete blinding of the coating with the anti-slip grains.

5.4.2 After 12-14 hours from application, vacuum clean the substrate to remove the excess

grains.

5.4.3 Apply the second coat ensuring that a continuous film is achieved and the surface is

completely sealed.

6.0 Cleaning

6.1 Tools and equipment should be cleaned with Solvent 102 immediately after use. Section C : Approval and variations

This method statement is offered by Fosroc as a „standard proposal‟ for the application of Nitocote EN901. It remains the responsibility of the Engineer to determine the correct method for any given application.

Where alternative methods are to be used, these must be submitted to Fosroc for approval, in writing, prior to commencement of any work. Fosroc will not accept responsibility or liability for variations to the above method statement under any other condition.

Revision date: 23/10/2016 Revision: 3 Supersedes date: 24/12/2013

SAFETY DATA SHEETNITOCOTE EN901 BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOCOTE EN901 BASE

Product number 1748048AE1

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Base component of two-part high build epoxy novolac coating.

1.3. Details of the supplier of the safety data sheet

Supplier Al Gurg Fosroc LLCPO Box 657DubaiUnited Arab Emirates+ 971 4 2858606

1.4. Emergency telephone number

Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Skin Sens. 1 - H317

Environmental hazards Aquatic Chronic 2 - H411

Human health May irritate eyes. Prolonged skin contact may cause redness and irritation.

Environmental The product is not expected to be hazardous to the environment.

2.2. Label elements

Pictogram

Signal word Warning

Hazard statements H315 Causes skin irritation.H317 May cause an allergic skin reaction.H411 Toxic to aquatic life with long lasting effects.

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NITOCOTE EN901 BASE

Precautionary statements P202 Do not handle until all safety precautions have been read and understood.P233 Keep container tightly closed.P301+P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell.P402+P404 Store in a dry place. Store in a closed container.P501 Dispose of contents/ container in accordance with national regulations.

Contains BISPHENOL F - EPOXY RESIN ADDUCT, PHENOL FORMALDEHYDE NOVOLAC -EPICHLOROHYDRIN ADDUCT

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

BISPHENOL F - EPOXY RESIN ADDUCT 30-60%

CAS number: —

ClassificationSkin Irrit. 2 - H315Skin Sens. 1B - H317Aquatic Chronic 2 - H411

MICA POWDER 30-60%

CAS number: 12001-26-2

ClassificationNot Classified

Classification (67/548/EEC or 1999/45/EC)-

PHENOL FORMALDEHYDE NOVOLAC -EPICHLOROHYDRIN ADDUCT

10-30%

CAS number: —

ClassificationSkin Sens. 1B - H317Aquatic Chronic 2 - H411

TITANIUM DIOXIDE 5-10%

CAS number: 13463-67-7 EC number: 236-675-5



CARBON BLACK PIGMENT <1%




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NITOCOTE EN901 BASE

SILICA FUME <1%

CAS number: 112945-52-5



XYLENE <1%

CAS number: 1330-20-7 EC number: 215-535-7 REACH registration number: 01-2119488216-32-0000

ClassificationFlam. Liq. 3 - H226Acute Tox. 4 - H312Acute Tox. 4 - H332Skin Irrit. 2 - H315

ETHYLBENZENE <1%


ClassificationFlam. Liq. 2 - H225Acute Tox. 4 - H332STOT RE 2 - H373Asp. Tox. 1 - H304

ISO-BUTANOL <1%


ClassificationFlam. Liq. 3 - H226Skin Irrit. 2 - H315Eye Dam. 1 - H318STOT SE 3 - H335, H336

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable forbreathing. Keep affected person under observation. Get medical attention. Show this SafetyData Sheet to the medical personnel.

Ingestion Never give anything by mouth to an unconscious person. Do not induce vomiting. Rinsemouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Washskin thoroughly with soap and water. Get medical attention if any discomfort continues.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15minutes. Continue to rinse for at least 15 minutes. Get medical attention if any discomfortcontinues.

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NITOCOTE EN901 BASE

4.2. Most important symptoms and effects, both acute and delayed

Skin contact Irritating to skin. May cause sensitisation by skin contact.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards Not known.

5.3. Advice for firefighters

Protective actions duringfirefighting

Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protectiveclothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions For personal protection, see Section 8.

6.2. Environmental precautions

Environmental precautions Avoid release to the environment.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place intocontainers. Flush contaminated area with plenty of water. Avoid the spillage or runoff enteringdrains, sewers or watercourses. For waste disposal, see Section 13.

6.4. Reference to other sections

Reference to other sections For waste disposal, see section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Avoid contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parametersOccupational exposure limitsMICA POWDER

Long-term exposure limit (8-hour TWA): WEL 0,8 mg/m³

TITANIUM DIOXIDE

Long-term exposure limit (8-hour TWA): WEL 4 mg/m³

CARBON BLACK PIGMENT

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NITOCOTE EN901 BASE

Long-term exposure limit (8-hour TWA): WEL 3,5 mg/m³Short-term exposure limit (15-minute): WEL 7 mg/m³

SILICA FUME

Long-term exposure limit (8-hour TWA): TLV - Threshold Limit Value 2.4 mg/m3 Resp. Dust

XYLENE

Long-term exposure limit (8-hour TWA): WEL 50 ppm 220 mg/m³Short-term exposure limit (15-minute): WEL 100 ppm 441 mg/m³Sk

ETHYLBENZENE

Long-term exposure limit (8-hour TWA): WEL 100 ppm 441 mg/m³Short-term exposure limit (15-minute): WEL 125 ppm 552 mg/m³Sk

ISO-BUTANOL

Long-term exposure limit (8-hour TWA): WEL 50 ppm 154 mg/m³Short-term exposure limit (15-minute): WEL 75 ppm 231 mg/m³WEL = Workplace Exposure LimitSk = Can be absorbed through the skin.

TITANIUM DIOXIDE (CAS: 13463-67-7)

DNEL Industry - Inhalation; Long term local effects: 10 mg/m³Consumer - Oral; Long term systemic effects: 700 mg/kg/day

PNEC - Fresh water; >1 mg/l- Sediment (Freshwater); >=1000 mg/kg- Marine water; 0.127 mg/l- Sediment (Marinewater); >= 100 mg/kg- Soil; 100 mg/kg- STP; 100 mg/kg

XYLENE (CAS: 1330-20-7)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³Workers - Inhalation; Short term systemic effects: 289 mg/m³Workers - Dermal; Long term systemic effects: 180 mg/kg/day

PNEC - Fresh water; 0.327 mg/l- Marine water; 0.327 mg/l- STP; 6.58 mg/l

ETHYLBENZENE (CAS: 100-41-4)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³Workers - Dermal; Long term systemic effects: 180 mg/kg bw/day

PNEC - Fresh water; 0.1 mg/l- Marine water; 0.01 mg/l

ISO-BUTANOL (CAS: 78-83-1)

DNEL Workers - Inhalation; Long term local effects: 310 mg/m³


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NITOCOTE EN901 BASE

8.2. Exposure controls

Protective equipment

Appropriate engineeringcontrols

Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupationalexposure limits for the product or ingredients.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. The following protection should be worn: Chemical splash goggles orface shield.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn ifa risk assessment indicates skin contact is possible. It is recommended that gloves are madeof the following material: Polyvinyl chloride (PVC). Rubber (natural, latex).

Other skin and bodyprotection

Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene measures Do not smoke in work area. Wash hands at the end of each work shift and before eating,smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly removeany clothing that becomes contaminated. Use appropriate skin cream to prevent drying ofskin. When using do not eat, drink or smoke.

Respiratory protection No specific recommendations. Respiratory protection may be required if excessive airbornecontamination occurs.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.

Colour Grey.

Odour Mild.

Odour threshold Not available.

pH No information available.

Melting point Not applicable.

Initial boiling point and range >200°C @

Flash point >150 deg C°C

Evaporation rate Not available.

Evaporation factor Not available.

Flammability (solid, gas) Not applicable.

Upper/lower flammability orexplosive limits

Not applicable.

Other flammability Not applicable.

Vapour pressure 2.3 kPa(water）

Vapour density Not available.

Relative density 1.54 @ 20 deg C°C

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NITOCOTE EN901 BASE

Bulk density Not applicable.

Solubility(ies) Insoluble in water.

Partition coefficient Not available.

Auto-ignition temperature Not available.

Decomposition Temperature Not available.

Viscosity Not determined.

Explosive properties Not applicable.

Explosive under the influenceof a flame

Not considered to be explosive.

Oxidising properties Not available.

9.2. Other information

Other information No information required.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity Stable at normal temperatures and pressure.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

Hazardous polymerization will not occur.

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Not available.

10.6. Hazardous decomposition products

Hazardous decompositionproducts

Does not decompose when used and stored as recommended. Fire creates: Carbonmonoxide (CO). Carbon dioxide (CO2).

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Inhalation Gas or vapour in high concentrations may irritate the respiratory system. Symptoms followingoverexposure may include the following: Coughing.

Ingestion May cause discomfort if swallowed.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact Vapour or spray in the eyes may cause irritation and smarting.

Toxicological information on ingredients.

TITANIUM DIOXIDE

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NITOCOTE EN901 BASE

Acute toxicity - oral

Acute toxicity oral (LD₅₀mg/kg)

5,000.0

Species Rat

Acute toxicity - inhalation

Acute toxicity inhalation(LC₅₀ dust/mist mg/l)

6.82

Species Rat

ATE inhalation(dusts/mists mg/l)

6.82

Skin corrosion/irritation

Animal data Not irritating.

Skin sensitisation

Skin sensitisation Local Lymph Node Assay (LLNA) - Mouse: Not sensitising.

Specific target organ toxicity - single exposure

STOT - single exposure Not classified as a specific target organ toxicant after a single exposure.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure.

Aspiration hazard

Aspiration hazard Based on available data the classification criteria are not met.

XYLENE

Acute toxicity - dermal

ATE dermal (mg/kg) 1,100.0

Carcinogenicity

IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans.

ETHYLBENZENE

Carcinogenicity

IARC carcinogenicity IARC Group 2B Possibly carcinogenic to humans.

SECTION 12: Ecological Information

Ecotoxicity Very toxic to aquatic life with long lasting effects.

12.1. Toxicity

Toxicity Not relevant.

Ecological information on ingredients.

TITANIUM DIOXIDE

Acute toxicity - fish LC₅₀, 96 hours: >10000 mg/l mg/l, Fish

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NITOCOTE EN901 BASE

Acute toxicity - aquaticinvertebrates

EC₅₀, 48 hours: >100 mg/l mg/l, Daphnia magna

CARBON BLACK PIGMENT

Acute toxicity - fish LC₅₀, 96 hours: >1000 mg/l, Fish

SILICA FUME

Acute toxicity - fish LC₅₀, 96 hours: >10000 mg/l, Fish


EC₅₀, 48 hours: >10000 mg/l, Daphnia magna

XYLENE

Toxicity Not considered toxic to fish.

12.2. Persistence and degradability

Persistence and degradability Not available.


XYLENE

Persistence anddegradability

The product is biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential Not available.

Partition coefficient Not available.


TITANIUM DIOXIDE

Bioaccumulative potential The product is not bioaccumulating.

12.4. Mobility in soil

Mobility Not available.


XYLENE

Mobility The product is insoluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvBassessment

This substance is not classified as PBT or vPvB according to current EU criteria.

12.6. Other adverse effects

Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

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NITOCOTE EN901 BASE

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of thelocal Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number

UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name

Proper shipping name(ADR/RID)

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINSBISPHENOL F - EPOXY RESIN ADDUCT, PHENOL FORMALDEHYDE NOVOLAC -EPICHLOROHYDRIN ADDUCT)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINSBISPHENOL F - EPOXY RESIN ADDUCT, PHENOL FORMALDEHYDE NOVOLAC -EPICHLOROHYDRIN ADDUCT)

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINSBISPHENOL F - EPOXY RESIN ADDUCT, PHENOL FORMALDEHYDE NOVOLAC -EPICHLOROHYDRIN ADDUCT)

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINSBISPHENOL F - EPOXY RESIN ADDUCT, PHENOL FORMALDEHYDE NOVOLAC -EPICHLOROHYDRIN ADDUCT)

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ADN packing group III

ICAO packing group III

14.5. Environmental hazards

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NITOCOTE EN901 BASE

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number(ADR/RID)

90

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009No. 716).Occupational Safety and Health (Classification, Labelling and Safety Data Sheet ofHazardous Chemicals) Regulations 2013 (CLASS Regulations)

Guidance Workplace Exposure Limits EH40.CHIP for everyone HSG228.Approved Classification and Labelling Guide (Sixth edition) L131.Safety Data Sheets for Substances and Preparations.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information The user must be instructed in the proper work procedure and be familiar with the contents ofthese instructions.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 23/10/2016

Revision 3

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NITOCOTE EN901 BASE

Hazard statements in full H225 Highly flammable liquid and vapour.H226 Flammable liquid and vapour.H304 May be fatal if swallowed and enters airways.H312 Harmful in contact with skin.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H332 Harmful if inhaled.H335 May cause respiratory irritation.H336 May cause drowsiness or dizziness.H373 May cause damage to organs (Hearing organs) through prolonged or repeatedexposure.H411 Toxic to aquatic life with long lasting effects.

Supersedes date 24/12/2013

The information on this data sheet represents our current data and is reliable provided that the product is used under theprescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidanceliterature. Any other use of the product which involves using the product in combination with any other product or any otherprocess is the responsibility of the user.

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SAFETY DATA SHEETNITOCOTE EN901 HARDENER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOCOTE EN901 HARDENER

Product number 1748064AE1

1.2. Relevant identified uses of the substance or mixture and uses advised against1.3. Details of the supplier of the safety data sheet

Supplier Al Gurg Fosroc LLCPO Box 657DubaiUnited Arab Emirates+ 971 4 2858606

1.4. Emergency telephone number

Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4

SECTION 2: Hazards identification

2.1. Classification of the substance or mixtureClassification (EC 1272/2008)Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens.1 - H317 STOT RE 2 - H373

Environmental hazards Aquatic Chronic 3 - H412

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H302+H312 Harmful if swallowed or in contact with skin.H314 Causes severe skin burns and eye damage.H317 May cause an allergic skin reaction.H373 May cause damage to organs through prolonged or repeated exposure.H412 Harmful to aquatic life with long lasting effects.

Precautionary statements P233 Keep container tightly closed.P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.P304+P312 IF INHALED: Call a POISON CENTER/ doctor if you feel unwell.P402+P404 Store in a dry place. Store in a closed container.P501 Dispose of contents/ container in accordance with national regulations.

Contains BENZYL ALCOHOL, HYDROGENATED FORMALDEHYDE-BENZENEAMINE POLYMER

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NITOCOTE EN901 HARDENER

2.3. Other hazards

No other information available

SECTION 3: Composition/information on ingredients

3.2. Mixtures

BENZYL ALCOHOL 30-60%

CAS number: 100-51-6 EC number: 202-859-9 REACH registration number: 01-2119492630-38-xxxx

ClassificationAcute Tox. 4 - H302Acute Tox. 4 - H312Acute Tox. 4 - H332Eye Irrit. 2 - H319

HYDROGENATED FORMALDEHYDE-BENZENEAMINEPOLYMER

30-60%

CAS number: 135108-88-2

ClassificationAcute Tox. 4 - H302Acute Tox. 4 - H312Skin Corr. 1B - H314Eye Dam. 1 - H318Skin Sens. 1 - H317STOT RE 2 - H373Aquatic Chronic 3 - H412

4,4'-METHYLENEBISCYCLOHEXYLAMINE 1-5%

CAS number: 1761-71-3

ClassificationAcute Tox. 4 - H302Skin Corr. 1A - H314Eye Dam. 1 - H318Skin Sens. 1 - H317STOT RE 2 - H373Aquatic Chronic 2 - H411

2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 1-5%


ClassificationAcute Tox. 4 - H302Skin Irrit. 2 - H315Eye Irrit. 2 - H319

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

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4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Rinse nose and mouth with water. Never giveanything by mouth to an unconscious person. Do not induce vomiting. Keep affected personwarm and at rest. Get medical attention immediately.

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Do notinduce vomiting. Rinse mouth thoroughly with water. Move affected person to fresh air andkeep warm and at rest in a position comfortable for breathing. Get medical attentionimmediately.

Skin contact Remove affected person from source of contamination. Rinse immediately with plenty ofwater. Get medical attention promptly if symptoms occur after washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses and openeyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact This product is corrosive.

Eye contact Causes serious eye damage.

4.3. Indication of any immediate medical attention and special treatment needed

Notes for the doctor Symptom treatment. Depending on the patient's situation and the specific circumstances ofthe accident, the treatment may be different. In all potential cases of poisoning, on-siteemergency treatment is essential. When you go to a doctor, show the label on the containerand SDS.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Specific hazards No unusual fire or explosion hazards noted.

5.3. Advice for firefighters

Protective actions duringfirefighting

Do not inhale explosion and/or combustion gases. During fire-fighting respirator withindependent air-supply and airtight garment is required.Do not allow contaminated extinguishing water to enter the soil, ground-water or surfacewaters.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Keep unauthorized persons away. Persons not wearing protective equipment should beexcluded from area of spill until clean-up has been completed. Provide appropriate protectiveequipment and ventilation equipment.

6.2. Environmental precautions

Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmfulto the environment if released in large quantities.

6.3. Methods and material for containment and cleaning up

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Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots,clothing or apron, as appropriate. Stop leak if possible without risk. Absorb in vermiculite, drysand or earth and place into containers. Avoid contamination of ponds or watercourses withwashing down water.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid breathing vapours. Ensure adequate ventilation. Maintain good standards of personalhygiene. Avoid skin and eye contact. Do not eat, drink or smoke whilst using this product.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Corrosive storage.

7.3. Specific end use(s)

Specific end use(s) Hardener component of two part high build epoxy novolac coating

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

BENZYL ALCOHOL (CAS: 100-51-6)

DNEL Workers - Inhalation; Short term systemic effects: 110 mg/m³Workers - Inhalation; Long term systemic effects: 22 mg/m³Workers - Dermal; Short term systemic effects: 40 mg/kg bw/dayWorkers - Dermal; Long term systemic effects: 8 mg/kg bw/day

PNEC - Fresh water; 1 mg/l- Marine water; 0.1 mg/l- STP; 39 mg/l

4,4'-METHYLENEBISCYCLOHEXYLAMINE (CAS: 1761-71-3)

DNEL Industry - Dermal; Long term systemic effects: 0.1 mg/kg/dayIndustry - Inhalation; Long term systemic effects: 1 mg/m³

PNEC - Soil; 0.072 mg/kg- Sediment (Marinewater); 0.039 mg/kg- Sediment (Freshwater); 0.39 mg/kg- STP; 80 mg/l- Marine water; 0.8 µg/l- Fresh water; 8 µg/l

Bis(dimethylaminomethyl)phenol (CAS: 71074-89-0)


8.2. Exposure controls

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Protective equipment

Appropriate engineeringcontrols

Provide adequate general and local exhaust ventilation.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicateseye contact is possible. The following protection should be worn: Chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Nitrile rubber. Viton rubber (fluororubber). Polyvinylidene chloride/polyethylene (PVDC/PE).

Other skin and bodyprotection

Wear appropriate clothing to prevent skin contamination. Provide eyewash station.

Hygiene measures Wash hands at the end of each work shift and before eating, smoking and using the toilet.Wash promptly with soap and water if skin becomes contaminated. Promptly remove anyclothing that becomes wet or contaminated.

Respiratory protection No specific recommendations. Respiratory protection must be used if the airbornecontamination exceeds the recommended occupational exposure limit.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Liquid.

Colour Amber.

Odour Amine.

Odour threshold No information available.

pH No information available.

Melting point Not available.

Initial boiling point and range No specific test data are available.

Flash point No information available.

Evaporation rate No information available.

Evaporation factor No specific test data are available.

Flammability (solid, gas) No information available.

Upper/lower flammability orexplosive limits

No information available.

Other flammability No specific test data are available.

Vapour pressure No specific test data are available.

Vapour density No information available.

Relative density 0.965 @ 25 deg C @ °C

Bulk density Not available.

Solubility(ies) Slightly soluble in water.

Partition coefficient No specific test data are available.

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Auto-ignition temperature No information available.

Decomposition Temperature No specific test data are available.

Viscosity 1P-3P @ 25 C

Explosive properties No information available.

Explosive under the influenceof a flame

Not considered to be explosive.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information No additional information.

SECTION 10: Stability and reactivity

10.1. Reactivity

Reactivity Stable at normal temperatures and pressure.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardousreactions

Will not polymerise.

10.4. Conditions to avoid

Conditions to avoid The following materials may react violently with the product: Strong oxidising agents.

10.5. Incompatible materials

Materials to avoid Oxidant, strong acid and alkali.

10.6. Hazardous decomposition products

Hazardous decompositionproducts

Ammonia or amines.

SECTION 11: Toxicological information

11.1. Information on toxicological effectsAcute toxicity - oralATE oral (mg/kg) 504.2

Acute toxicity - dermalATE dermal (mg/kg) 1,569.56

Acute toxicity - inhalationATE inhalation (dusts/mistsmg/l)

8.64

Inhalation May cause respiratory system irritation. May cause sensitisation by inhalation. May causerespiratory allergy.

Ingestion Causes burns. May cause chemical burns in mouth and throat. May cause stomach pain orvomiting.

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Skin contact May cause allergic contact eczema. Product has a defatting effect on skin. May cause allergiccontact eczema. May cause sensitisation by skin contact. Causes burns. Harmful in contactwith skin.

Eye contact Severe irritation, burning and tearing. Causes burns.

Toxicological information on ingredients.

BENZYL ALCOHOL


Acute toxicity oral (LD₅₀mg/kg)

1,620.0

Species Rat

ATE oral (mg/kg) 500.0


Acute toxicity dermal (LD₅₀mg/kg)

2,000.0

Species Rabbit


Acute toxicity - inhalation

Acute toxicity inhalation(LC₅₀ dust/mist mg/l)

4.178

Species Rat

ATE inhalation(dusts/mists mg/l)

4.178

HYDROGENATED FORMALDEHYDE-BENZENEAMINE POLYMER



4,4'-METHYLENEBISCYCLOHEXYLAMINE


Notes (oral LD₅₀) LD₅₀ 625 mg/kg, Oral, Rat


Notes (dermal LD₅₀) LD₅₀ 2110 mg/kg, Dermal, Rabbit

2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL


ATE oral (mg/kg) 500.0

SECTION 12: Ecological Information

Ecotoxicity Dangerous for the environment. May cause long-term adverse effects in the aquaticenvironment.

12.1. Toxicity

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BENZYL ALCOHOL

Acute toxicity - fish LC₅₀, 96 hours: 460 mg/l, Pimephales promelas (Fat-head Minnow)


EC₈₀, 48 hours: 230 mg/l, Daphnia magna

Acute toxicity - aquaticplants

EC₅₀, 72 hours: 770 mg/l, Pseudokirchneriella subcapitata

4,4'-METHYLENEBISCYCLOHEXYLAMINE

Acute toxicity - fish LC₅₀, 96 hours: 46 - 100 mg/l, Leuciscus idus (Golden orfe)


EC₅₀, 48 hours: 6.84 mg/l, Daphnia magna

Acute toxicity - aquaticplants

EC₅₀, 72 hours: 140 - 200 mg/l, Algae

2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL

Acute toxicity - fish LC₅₀, 96 hours: 718 mg/l, Fish

12.2. Persistence and degradability12.3. Bioaccumulative potential

Partition coefficient No specific test data are available.

12.4. Mobility in soil

Mobility Not available.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvBassessment

Assessment not carried out but this product is believed not to be a PBT nor a vPvB.

12.6. Other adverse effects

Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of thelocal Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number

UN No. (ADR/RID) 1760

UN No. (IMDG) 1760

UN No. (ICAO) 1760

UN No. (ADN) 1760

14.2. UN proper shipping name

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Proper shipping name(ADR/RID)

CORROSIVE LIQUID, N.O.S. (CONTAINS HYDROGENATED FORMALDEHYDE-BENZENEAMINE POLYMER, 4,4'-METHYLENEBISCYCLOHEXYLAMINE)

Proper shipping name (IMDG) CORROSIVE LIQUID, N.O.S. (CONTAINS HYDROGENATED FORMALDEHYDE-BENZENEAMINE POLYMER, 4,4'-METHYLENEBISCYCLOHEXYLAMINE)

Proper shipping name (ICAO) CORROSIVE LIQUID, N.O.S. (CONTAINS HYDROGENATED FORMALDEHYDE-BENZENEAMINE POLYMER, 4,4'-METHYLENEBISCYCLOHEXYLAMINE)

Proper shipping name (ADN) CORROSIVE LIQUID, N.O.S. (CONTAINS HYDROGENATED FORMALDEHYDE-BENZENEAMINE POLYMER, 4,4'-METHYLENEBISCYCLOHEXYLAMINE)

14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID classification code C9

ADR/RID label 8

IMDG class 8

ICAO class/division 8

ADN class 8

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ADN packing group II

ICAO packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutantNo.

14.6. Special precautions for user

EmS F-A, S-B

ADR transport category 2

Hazard Identification Number(ADR/RID)

80

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport in bulk according toAnnex II of MARPOL 73/78and the IBC Code

Not applicable.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009No. 716).Control of Substances Hazardous to Health Regulations 2002 (as amended).

Guidance Workplace Exposure Limits EH40.Introduction to Local Exhaust Ventilation HS(G)37.CHIP for everyone HSG228.Approved Classification and Labelling Guide (Sixth edition) L131.

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information The user must be instructed in the proper work procedure and be familiar with the contents ofthese instructions.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 27/02/2013

Revision 2

Hazard statements in full H302 Harmful if swallowed.H312 Harmful in contact with skin.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.H319 Causes serious eye irritation.H332 Harmful if inhaled.H373 May cause damage to organs through prolonged or repeated exposure.H411 Toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.

Supersedes date 27/02/2013

SDS number 11156

The information on this data sheet represents our current data and is reliable provided that the product is used under theprescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidanceliterature. Any other use of the product which involves using the product in combination with any other product or any otherprocess is the responsibility of the user.

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Test report

Job reference

Approvals

Technical Submittal NITOCOTE EN901

Documents

Transcript of Technical Submittal NITOCOTE EN901