Thevenard Island - Department of Mines and Petroleum

Thevenard Island

Onshore Well Plug and Abandonment Program Environment Plan Summary

Document ID: ABU171001855 Revision ID: 5.0

Revision Date: 18 June 2018 Next Revision Due: 12 June 2023

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Thevenard Island Onshore Well Plug and Abandonment Program Environment Plan Summary

Document ID: ABU171001855 Revision ID: 5.0 Revision Date: 18 June 2018 Page ii Information Sensitivity: Public Uncontrolled when Printed

CONTROLLED DOCUMENT

Thevenard Island

Onshore Well Plug and Abandonment Program Environment Plan

Summary

Document Information

Document

Number ABU171001855 Revision 5.0

Document Author Shannon Dolbel Department Owner Drilling and Completions

Revision History

Rev

No. Description Date Prepared By Approved By

1.0 Issued for DMIRS acceptance 23 October 2017 Ashley Fertch Amie French

1.0 Issued for DMIRS acceptance 18 December 2017

Ashley Fertch Shannon Dolbel

2.0 Issued for DMIRS acceptance 18 June 2018 Ashley Fertch Shannon Dolbel

3.0 Issued for DMIRS acceptance 16 March 2018 Shannon Dolbel John Scott

4.0 Issued for DMIRS acceptance 28 March 2018 Shannon Dolbel John Scott

5.0 Issued for DMIRS acceptance 18 June 2018 Shannon Dolbel John Connor


Document ID: ABU171001855 Revision ID: 5.0 Revision Date: 18 June 2018 Page iii Information Sensitivity: Public Uncontrolled when Printed

Contents

1.0 Introduction .................................................................................................. 1

1.1 Overview .................................................................................................... 1

1.2 Location ..................................................................................................... 1

1.3 Scope ........................................................................................................ 2

1.4 Licence Holder and Operator Details .............................................................. 2

1.5 Stakeholder Engagement ............................................................................. 2

2.0 Description of the Activity ............................................................................... 4

2.1.1 Overview Onshore Oil Gas and Water Disposal Wells ................................ 4 2.1.2 Timing ................................................................................................ 5

2.2 Phase 1: Well-site Grooming Prior to Plug and Abandonment ............................ 5

2.3 Plug and Abandonment Activities ................................................................... 5

2.3.1 Phase 2: Temporary Reservoir Isolation and Disconnection of the Trees ..... 5 2.3.2 Phase 3: Permanent Reservoir Isolation .................................................. 5 2.3.3 Phase 4: Permanent Surface Isolation .................................................... 6

2.4 Access Track and Well-site Construction ......................................................... 6

3.0 Description of the Environment........................................................................ 7

3.1 Physical Environment ................................................................................... 7

3.2 Biological Environment ................................................................................. 7

3.3 Cultural Heritage ......................................................................................... 8

3.4 Socio-Economic Environment ........................................................................ 8

4.0 Environmental Risk Assessment Methodology .................................................... 9

5.0 Management Approach .................................................................................. 15

5.1 Operational Excellence Management System .................................................. 15

5.2 Environment Plan Review ............................................................................ 15

6.0 Chemical Disclosure ...................................................................................... 16

7.0 Acronyms and Abbreviations .......................................................................... 17

8.0 References ................................................................................................... 18

Tables

Table 1-1: Titleholder Details ...................................................................................... 2

Table 1-2: Operator Contact Details ............................................................................. 2

Table 1-3: Stakeholder Engagement Log ...................................................................... 3

Table 2-1: Well Identifiers, Types, and Locations ........................................................... 4

Table 4-1: Summary of the Potential Impacts Risks and Control Measures ....................... 10

Table 5-1: OEMS Elements Relevant to the Activity ....................................................... 15

Table 7-1: Acronyms and Abbreviations ...................................................................... 17

Figures

Figure 1-1: Location of L12, TVI-1, and the CALM Act Lease on Thevenard Island .............. 1


Document ID: ABU171001855 Revision ID: 5.0 Revision Date: 18 June 2018 Page ii Information Sensitivity: Public Uncontrolled when Printed


Document ID: ABU171001855 Revision ID: 5.0 Revision Date: 18 June 2018 Page 1 Information Sensitivity: Public Uncontrolled when Printed

1.0 Introduction

1.1 Overview

Chevron Australia Pty Ltd (CAPL) is the proponent and nominated operator of the

Thevenard Island (TVI) Joint Venture petroleum-related activities within the petroleum

titles containing the Saladin, Cowle, Yammaderry, Crest, Roller, and Skate oilfields.

Petroleum well-related activities on Thevenard Island are regulated under the Western

Australian (WA) Petroleum and Geothermal Energy Resources Act 1967 (PGERA), and

associated Petroleum and Geothermal Energy Resources (Environment)

Regulations 2012 (PGER(E)R).

The Thevenard Island oilfields and production facility have reached the end of their

economic life, and therefore CAPL has ceased production. The assets have remained in

care and maintenance mode since 2014, and will remain in this stage until all

decommissioning activities have been completed.

The next stage of decommissioning requires the 15 onshore wells (used for production,

injection, water disposal, and exploration) to be permanently plugged and abandoned.

1.2 Location

The wells associated with the EP are on Thevenard Island within Petroleum Production

Licence L12 (Figure 1-1). Thevenard Island is approximately 25 km north-west of

Onslow and 70 km south-west of Barrow Island in the Carnarvon Basin, WA. It is

approximately 5 km long, 1 km at its greatest width, and covers an area of

approximately 550 ha.

Figure 1-1: Location of L12, TVI-1, and the CALM Act Lease on Thevenard Island



1.3 Scope

Under the PGER(E)R, the scope of the EP is limited to the petroleum activity as

described in Section 2.0.

1.4 Licence Holder and Operator Details

CAPL is nominated as the operator and titleholder of the Thevenard Island petroleum

activities on behalf of the non-operating joint venture partners listed in Table 1-1.

Table 1-1: Titleholder Details

Titles Details Titleholders Operator Address

L12 Production

Licence

Chevron Australia Pty Ltd

Chevron (TAPL) Pty Ltd *

Mobil Australia Resources Company Pty Ltd *

Santos Offshore Pty Ltd *

Chevron

Australia Pty Ltd

QV1, 250 St

Georges Terrace, Perth,

WA, 6000

* Non-operating joint venture partner

In accordance with the (PGER[E]R), the contact details for CAPL (the operator) are

listed in Table 1-2.

Table 1-2: Operator Contact Details

Company Name Chevron Australia Pty Ltd

Nominated Liaison Person John Connor

Position Drilling and Completions Manager

Business Address GPO Box S1580, Perth WA 6845

Telephone Number +61 8 9216 4254

Fax Number +61 8 9216 4223

Email Address [email protected]

1.5 Stakeholder Engagement

Regular consultation with relevant stakeholders (community, State government

departments, industry operators, and contractors to CAPL) has been undertaken by

CAPL throughout the Thevenard Island Retirement Project.

CAPL’s Thevenard Island Stakeholder Consultation Plan addresses the requirements of

Regulation 17 of the (PGER(E)R) and provides a process for ensuring all stakeholders

are identified and appropriately engaged throughout the Thevenard Island

decommissioning activities.

This Stakeholder Consultation Plan also includes details regarding previous extensive

consultation undertaken with stakeholders to provide general awareness, and a forum

for providing feedback, on the Thevenard Island Retirement Project.

As discussed in the Stakeholder Consultation Plan and in accordance with

Regulation 15(11) of the (PGER(E)R), CAPL has undertaken targeted consultation with

stakeholders regarding the scope and content of the EP, as summarised in Table 1-3.

mailto:[email protected]



Table 1-3: Stakeholder Engagement Log

Stakeholder Date Summary of

Consultation Response Summary

DBCA 4 Oct 2017

Overview of the activities,

potential environmental hazards, and

control measures

Confirmation that previous feedback from DBCA is incorporated into the EP. Follow-up correspondence with DBCA to provide a full draft of the EP for review on 18 Oct 2017.

Department of Transport (DoT) (Harbour Master)

4 Oct 2017 Feedback related to existing requirements outside the development of the EP that pertain to vessel activity in the area.

Department of Water and Environmental Regulation

4 Oct 2017 Acknowledgement of correspondence, no specific feedback provided.

Mackerel Island Pty Ltd (MIPL)

4 Oct 2017 Response related to ensuring the timing of the plugging of Saladin wells is communicated to MIPL in advance

so that visitors can be made aware of the activities and potential noise when booking.

Pilbara Port Authority 4 Oct 2017 In DoT Harbour Master’s response. No further specific response provided.

DoT (Marine Pollution Branch)

13 Oct 2017 As above, with additional details pertaining to oil spill contingency plans

Response specific to the content of spill contingency plans resulting in minor administrative changes to the subsidiary document.

DBCA 8 December

2017

Requested

several minor changes regarding:

Species names, breeding times (turtles) etc.

Consideration of additional control measures for specific activities where interaction with marine

turtles and light sensitives species may occur

Several minor administrative changes

made to this plan re: species names and breeding times.

CPAL provided more specific information to the evaluation of lighting impacts, and included additional consideration of control

measures where potential interaction with marine turtles and light sensitive species had the potential to occur.



2.0 Description of the Activity

Before onshore plug and abandonment activities commence, well-site grooming may be

undertaken (Section 2.2) to remove above-ground piping and equipment from the well

site, thus enabling safe rig access (called Phase 1 activities). Access track and well-site

construction (Section 2.4) may also be required to allow rig access.

Onshore plug and abandonment activities will comprise an additional three phases:

• Phase 2: Temporary reservoir isolation and disconnection of the trees

(Section 2.3.1)

• Phase 3: Permanent reservoir isolation (Section 2.3.2)

• Phase 4: Permanent surface isolation (Section 2.3.3).

These activities will be undertaken using the wireline / slickline unit, workover rig, and

cementing unit, as well as a coiled tubing unit or rig assist snubbing unit. Logistics and

support operations may be required.

2.1.1 Overview Onshore Oil Gas and Water Disposal Wells

Four well types are associated with the EP:

• production well

• injection well

• water disposal well

• exploration well.

Table 2-1 lists the well identifiers, well types, and as-built geographic coordinates.

Table 2-1: Well Identifiers, Types, and Locations

Well Site Well Well Type Date

Drilled Easting Northing

Saladin East Saladin 5 Gas injection Nov 1988 295294 7625781

Saladin 6 Producer Dec 1988 295295 7625779

Saladin 11 Water injection Jun 1994 295295 7625812

Saladin 14 Gas-lifted producer Aug 1996 295291 7625756

Saladin South Saladin 4M Gas injection Feb 1989 294702 7625299

Saladin 12 Gas-lifted producer Jul 1996 294732 7625315


Saladin 18M Gas-lifted producer Oct 1999 294732 7625338

Saladin 19M Gas-lifted producer Sep 1999 294732 7625328


Crest Crest 6 Producer Mar 1998 294963 7626089

WDW 1 PFW disposal Apr 1994 294961 7626082

WDW 2 PFW disposal May 1994 294958 7626075

WDW 3 PFW disposal Mar 1994 294956 7626068

TVI-1 TVI-1 Exploration well Drilled and abandoned

Mar / April 1968

294458 7625351



2.1.2 Timing

The onshore plug and abandonment program is expected to commence in Q1 2018 and

run for ~10 months. Some activities covered under the EP will occur 24 hours a day.

2.2 Phase 1: Well-site Grooming Prior to Plug and Abandonment

To provide additional space at the well sites for well abandonment activities, CAPL

propose to disconnect and remove all surface piping and infrastructure from these sites.

Existing piping and infrastructure to be removed includes:

• production pipework and associated vessels, tanks, pumps, filters, valves,

instrumentation, electrical and control systems

• pipe stands, bunds, and foundations

• fences, light poles, sign posts, and bollards

• walkways, platforms, ladders, stairs, and structural steelwork

• relocation of some disused equipment and stabilisation blocks.

All production pipelines and vessels have been cleaned and flushed, and all production

plant and metering station facilities have been isolated, depressurised, and are free of

residual hydrocarbon.

No chemicals are required for these activities.

2.3 Plug and Abandonment Activities

The following subsections describe how CAPL expects the well abandonment activities to

be conducted.

2.3.1 Phase 2: Temporary Reservoir Isolation and Disconnection of

the Trees

Temporary reservoir isolation is required to enable the Christmas tree to be

disconnected. This isolation can be undertaken via the rig or the wireline unit. During

wireline operations, a wire or braided cable is lowered into the well to run tools in and

out of the wellbore. Generally, onshore wireline operations are conducted from a diesel-

powered unit (potentially self-propelled; not a rig) modified to deploy wireline cables.

However, in some instances wireline operations may be completed by a rig.

Diesel-powered coiled tubing units and/or a hydraulic workover unit (snubbing unit) and

cement mixing / pumping equipment may perform some of these operations.

Tasks associated with this activity include:

• Install Pressure Control Equipment

• Bullhead the Well

• Isolate the Reservoir

• Remove Pressure Control Equipment and Christmas Tree

2.3.2 Phase 3: Permanent Reservoir Isolation

Permanent reservoir isolation is required prior to permanent abandonment of the wells.

Tasks associated with this activity include:

• Install and Pressure Test Blow Out Preventer

• Establish Communication with the Annulus

• Install Permanent Reservoir Barrier



2.3.3 Phase 4: Permanent Surface Isolation

Permanent surface isolation is required to ensure two barriers are in place prior to

permanent abandonment of the wells. Tasks associated with this activity include:

• Set Upper Abandonment Plug

• Perforate / Cut / Punch Well Casing

• Install Surface Isolation Barrier

2.4 Access Track and Well-site Construction

Most wells covered by the EP have existing infrastructure and access tracks, but one

well (TVI-1) requires an access track, construction of a well lease, and potentially a

cellar around the wellhead. This construction is required to allow the rig (and support

equipment) to safely access the well site.

Well sites other than TVI-1 may require well-site stabilisation.



3.0 Description of the Environment

Thevenard Island is a Nature Conservation Reserve (Reserve No. 33174) vested in the

Conservation Commission, and managed by DBCA under the CALM Act. The reserve is

primarily for the protection of seabird and shorebird populations.

3.1 Physical Environment

Thevenard Island is a low, relatively flat, vegetated mid shelf cay approximately 5 km

long by 1 km wide. Thevenard Island covers an area of approximately 550 ha with an

average height above sea level of 5 m Australian Height Datum (AHD). The surrounding

shallow sea constitutes the continental shelf and comprises up to 250 m of lime

cemented sand, grit, conglomeratic and coral reef deposits of Quaternary age, overlying

Tertiary limestones of the Cape Range Group (LeProvost et al., 1987). No natural

drainage patterns exist on Thevenard and rainfall infiltrates the sandy soils and directly

recharges the shallow unconfined superficial groundwater. The unconfined groundwater

aquifer is present within the Aeolian sands between 1 and 7 m (Golder 2011).

The benthic marine environment within the Thevenard Island area is broadly

characterised by five intertidal and subtidal habitats (sandy beaches, intertidal

limestone pavement, subtidal limestone pavement, coral communities, subtidal sand).

3.2 Biological Environment

According to the DPaW Declared Rare and Priority Flora list for the Pilbara region, no

Declared Rare Flora (DRF) species are known to occur on Thevenard Island; however,

the Priority 3 flora species, Carpobrotus sp. Thevenard Island occurs on the island. To

date, 102 plant taxa have been identified on the CALM Act Lease and the DBCA Nature

Reserve. Since operations commenced, 11 environmental weed species and 20

mainland native species have been recorded as introduced to Thevenard Island (Astron

Environmental 2013). Results from weed management and monitoring programs

conducted in 2014-2015 recorded 12 weed species on the CALM Act Lease (Astron

Environmental 2015).

The DBCA advised there is an occurrence of Priority Ecological Community (PEC) #24,

previously recorded on Barrow Island. This PEC is further described as ‘Coastal dune

native tussock grassland dominated by Whiteochloa airoides (Priority 3)’ and is located

on the western side of Thevenard Island. A Priority 3 PEC is defined as a poorly known

ecological community that do not meet adequacy of survey requirements and/or are not

adequately defined.

The house mouse (Mus domesticus) and the Northern Short-tailed Mouse (Leggadina

lakedownensis) are the only two terrestrial mammal species found on Thevenard

Island.

The Northern Short-tailed Mouse was recorded in 1985 (LeProvost et al. 1987), and the

house mouse is believed to have been anthropogenically introduced to Thevenard

Island in approximately 1985 (Astron Environmental 2011).

A total of 76 bird species have been recorded during avifauna surveys on TVI between

1985 and 2013 (Astron Environmental 2013). These bird species consist of resident and

migratory bird species that utilise suitable habitats on Thevenard Island.

Five species of sea turtle occur in the waters of north-western WA, with Green Turtles

(Chelonia mydas) particularly abundant in this region (Pendoley 1997). All five species

are listed as Threatened and Migratory under the WA Wildlife Conservation Act 1950

and the Environmental Protection and Biological Conservation Act 1999.

Migrating humpback whales may be encountered in the offshore area of Thevenard

Island between September and November, however the offshore area does not contain

recognised migratory routes, known feeding, breeding or resting areas. Whale sharks



are known to pass through and potentially feed in the offshore area of Thevenard Island

while migrating to aggregation areas on the Ningaloo Coast. Dugongs are also likely to

be present in the nearshore waters around Thevenard.

3.3 Cultural Heritage

Thevenard Island is not within any Native Title area and no Aboriginal heritage places

or registered sites are within the CALM Act Lease on Thevenard Island.

3.4 Socio-Economic Environment

The Pilbara coastal region is one of WA’s largest resource development and industrial

areas. Important industries include petroleum, iron ore export, salt production, and

aquaculture. A major shipping port at Dampier facilitates exports from this region.

Major commercial fisheries operate out of Exmouth and Onslow. Exmouth also supports

a tourism industry, primarily centred on the area’s marine attractions. Recreational

fishing charters regularly visit the waters around the offshore islands of the region

during the winter tourist season, including the waters surrounding Thevenard Island.



4.0 Environmental Risk Assessment Methodology

An Environmental Risk Assessment Workshop was undertaken to evaluate impacts and

risks arising from the petroleum activities described in Section 2.0. The risk assessment

also considered emergency conditions and spill response activities.

The risk assessment was undertaken in accordance with the Chevron Australia Health,

Environment, and Safety (HES) Risk Management Process and the processes outlined in

ISO 31000:2009 Risk Management – Principles and Guidelines (SASNZ, 2009) and

Handbook 203:2012 Managing Environment-related Risk (SASNZ, 2012).

The environmental impact and risk evaluation process comprised these components:

• identification and description of the petroleum activity

• identification of particular environmental values

• identification of relevant aspects

• identification of relevant environmental hazards

• exposure evaluation

• evaluation of impacts and risk

• consequence

• control measures and as low as reasonably practicable (ALARP) evaluation

• likelihood

• quantification of the level of risk

• risk acceptance criteria

• environmental performance objectives, standards, and measurement criteria.

Table 4-1 summarises the environmental impacts, risks, and control measures in place

to manage the activity.



Table 4-1: Summary of the Potential Impacts Risks and Control Measures

Source of Environmental

Impact or Risk (Hazards)

Potential Environmental

Impacts and Risks

(Consequences) Control Measures

Light emissions generated from the activity have the potential to alter the behaviour of fauna and reduce their chances of survival

Fauna injury or death

• Where practicable, Phase 2-4 Plug and Abandonment activities scheduled

to commence outside of turtle nesting season

• Lighting mitigations:

o Where possible, lower-frequency light sources (i.e. red or orange) shall be used, and blue/white lights avoided

o Shielded, directed away from the beach and directed on the work area only

• Lighting mitigations for vessels on stand-by overnight at the jetty:

o External lights will be turned off at night

o All window coverings will be drawn

• Site induction which includes environmental measures for using lighting

• Weekly inspection undertaken from the beach to assess placement, height, and direction of light during turtle nesting season.






Impacts and Risks


All activities were identified as

having the potential to result in interactions with fauna. Specifically,

these included

• fauna strike via movement of vehicles and machinery (including sand clearing)

• entrapment from removal of well cellars

• entrapment from seawater intake

• Fauna injury or death

• Personnel access restrictions and speed restrictions on Thevenard Island (40 km/h)

• Driver certification in accordance with the Australian Business Unit (ABU) Motor Vehicle Safety Process Fauna exclusion/egress controls are in place and operational

• Any open fixed pipes are to be covered overnight to prevent fauna ingress and entrapment

• Any open-ended tubular hoses and waste pipes are to have open ends elevated by at least 200 mm to prevent fauna access

• Intake hose has a screen to prevent fauna ingress

• Site inductions which include fauna management measures, personnel access restrictions, and speed restrictions on

• During turtle nesting season (Nov–Apr):

o demarcate barge landing hardstand area

o conduct inspection prior to clearing sand from the barge landing area

o stockpile all sand removed from the barge landing area within the laydown area 2 m away from the beach

• Install concrete blocks on the outside of the barge landing ramp below Highest Astronomical Tide (HAT)

Well-site grooming, operation of plant and equipment during onshore plug and abandonment activities, and aviation logistics will generate

noise emissions.

• Behavioural disturbance of fauna

• Temporary disturbance to existing land use (tourism)

• No shift changes at midnight

• Equipment is maintained in accordance with maintenance schedule

• Stakeholder consultation with MIPL

• Site inductions






Impacts and Risks


Vegetation clearing and well-site stabilisation will result in various environmental interactions which has

the potential to cause a number of

risks.

• Introduction of Non-indigenous Species (NIS) and disturbance to flora, fauna, and ecological communities

• Fauna injury or death

• Disturbance to potential Aboriginal heritage sites

• Conditions within the CPS 7024 will be implemented to minimise the risk of the introduction and spread of weeds and disturbance to ecological communities

• Clearing activities to be undertaken during daylight hours

• Pre-inspection of area to be cleared

• Activities will be undertaken in accordance with the Aboriginal Heritage Act 1972 (WA).

• A heritage survey will be completed before clearing

• Vegetation Disturbance Certificate will be obtained before clearing activities, and will include a Vegetation Disturbance Assessment Form

Vegetation clearing has the potential to cause a fire.

• Disturbance to terrestrial flora, fauna, and ecological communities

• A fire trailer comprising a water tank, pump and hose will be present on

site.

• Fire extinguishers present (both in vehicles and on site)

• Site induction which includes smoking restrictions, Permit to Work system, and emergency response procedures

Moving personnel and mobile equipment onshore has the potential to introduce new NIS to Thevenard Island, or further spread existing

NIS.

• Introduction of NIS and disturbance to flora, fauna, and ecological communities

• Spread of existing NIS

• Site inductions which include an overview of quarantine requirements for

Thevenard Island for the onshore and nearshore environment

• Equipment quarantine checks undertaken before mobilisation to Thevenard Island, as per the Quarantine Management Plan

• Vehicle movements are restricted to existing roads and tracks within the approved CALM Act Lease and TVI-1 footprint

Handling and storage of solid waste during this onshore plug and

abandonment program, has the potential for an accidental release of solid waste to the environment.

• Injury and entanglement of

marine fauna and seabirds.

• Site induction

• All waste is appropriately segregated, labelled and contained within covered receptacles (where there is the potential for material to be wind-blown) and removed from active well leases at the end of each day/campaign as appropriate and returned to the mainland for disposal

• Emergency Response Plan in place for the Thevenard Island Onshore Well Plug and Abandonment Program which addresses cyclone preparedness

arrangements.

• Post Cyclone Inspection

• Thevenard Island Radiation Management Plan (ABU130100161)






Impacts and Risks


Operating vehicles, equipment, and

rigs within the well sites requires the use and storage of hazardous

materials, and chemicals

• contamination of groundwater and soil

• localised impacts to marine and

coastal fauna and habitats

• impacts to socioeconomic values

• All personnel have completed site inductions, which include spill response procedures and responsibilities

• Diesel fuel will be stored in a double-skinned container or secondary containment comprising 110% of the tank volume and inspected for leaks during use

• Refuelling will be undertaken in accordance with refuelling procedure / JHA, which includes these safeguards:

o Using a spill tray during refuelling

o Monitoring fuel tank levels to avoid overfilling

o Spill response equipment on site during refuelling operations

o Any spills cleaned up immediately

• The Contractor Bulk Hydrocarbon Transfer Checklist will be utilised to

ensure the diesel transfer hoses are fitted with dry break couplings and the condition of diesel transfer hoses, couplings and seals are checked prior to bunkering activities

• Response to spills in the marine environment conducted in accordance with the offshore OSCP

• Bulk liquid chemicals will be stored in an existing bunded area on

Thevenard Island

• On the well site, any liquid chemicals will be stored within secondary containment comprising 110% of tank volume

• Portable tanks, hoses, and pipes will be checked for integrity and securement of fittings before use

• During use, visual monitoring will be undertaken to identify any discharges to the environment

• Before disconnecting hoses from temporary storage tanks, spill protection will be provided underneath hose connections

• The minimum requirements for well barriers as described in CAPL’s global barrier standard are met

• Safety-critical well control equipment is maintained in accordance with the rig operator safety management system as detailed in the DMIRS-accepted rig-specific safety case revision






Impacts and Risks


• The WMP (documenting plug and abandonment design and preventive engineering controls) is accepted by DMIRS before activities commence

• The OSCP is implemented in the event of an uncontrolled release from a well

• Spill response exercises will be undertaken in accordance with the rig

operator’s emergency response exercise program

• Clean-up to be started immediately on identifying a leak/spill

• Emergency Response Plan in place for the Thevenard Island Onshore Well Plug and Abandonment Program which addresses cyclone preparedness arrangements



5.0 Management Approach

The implementation strategy in the EP identifies the systems, practices, and procedures

used to ensure the environmental impacts and risks of the activities are continuously

reduced to ALARP and the environmental performance outcomes and standards are

met. These are predominantly driven through Chevron Australia’s Operational

Excellence Management System (OEMS).

5.1 Operational Excellence Management System

The implementation strategy of the EMP was developed in line with Chevron Australia’s

OEMS. Chevron’s OEMS is aligned to ISO 14001:2004; Table 5-1lists the key

components.

Table 5-1: OEMS Elements Relevant to the Activity

OEMS Element Element Description Key Processes Relevant to the Activity

Safe Operations (OE-03)

Operate and maintain facilities to prevent injuries, illness, and incidents

• (OE-03.01.01) ABU HES Risk Management

Management of Change (OE-04)

Manage both permanent and temporary changes to prevent incidents

• (OE-04.00.01) Management of Change for Facilities and Operations – ABU Standardised OE Process

Incident Investigation (OE-09)

Investigate and identify root

causes of incidents to reduce or eliminate systemic causes to prevent future incidents

• (OE-09.00.01) Incident Investigation and Reporting – ABU Standardised OE Process

Community and Stakeholder Engagement

(OE-10)

Reach out to the community and engage in open dialogue to build trust

• (OE-10.00.01) Community and Stakeholder Engagement – ABU Standardised OE Process

Emergency Management (OE-11)

Prevention is the first priority, but be prepared to respond immediately and effectively to all emergencies involving wholly owned or operated

Chevron assets

• (OE-11.01.01) Emergency Management Process

• (ABU160500405) Thevenard Island Onshore Well Securement OSCP

Compliance Assurance (OE-12)

Verify conformance with OE

requirements in applicable company policy and government laws and regulations

• (OE-12.01.19) Compliance Assurance Audit Program ABU Standardised OE Procedure

• (OE-12.01.18) Compliance Assurance Management of Instances of Potential

Noncompliance

5.2 Environment Plan Review

Regulation 18 of the PGER(E)R requires CAPL to submit a proposed revision of the

accepted EP to the Minister:

• before commencing a new activity

• before any significant modification or change, or a new stage of an existing activity

• before, or as soon as practicable after, any significant new environmental impact or

risk occurs, or any significant increase in an existing environmental impact or risk

which occurred or is to occur.



6.0 Chemical Disclosure

To meet the DMIRS requirements regarding chemical disclosure, Appendix A details any

chemicals that will be introduced into the wells on Thevenard Island for the Plug and

Abandonment Program.



7.0 Acronyms and Abbreviations

Table 7-1 defines the acronyms and abbreviations used in this document.

Table 7-1: Acronyms and Abbreviations

Acronym/Abbreviation Definition

°C Degrees Celsius

ABU Australian Business Unit

AHD Australian Height Datum

ALARP As low as reasonably practicable

CAPL Chevron Australia Pty Ltd

DBCA WA Department of Biodiversity, Conservation and Attractions

DMIRS WA Department of Mines, Industry Regulation and Safety

DoT Department of Transport

DRF Declared Rare Flora

EP Environment Plan

HES Health, Environment, and Safety

ISO International Organization for Standardization

JHA Job Hazard Analysis

Km/h Kilometres per hour

MIPL Mackerel Island Pty Ltd

NIS Non-indigenous Species

OE Operational Excellence

OEMS Operational Excellence Management System

OSCP Oil Spill Contingency Plan

PEC Priority Ecological Community

PGERA Petroleum and Geothermal Energy Resources Act 1967

PGER(E)R Petroleum and Geothermal Energy Resources (Environment) Regulations 2012

Q1, Q2,etc. Three-month quarter of a calendar year

TVI Thevenard Island

WA Western Australia

WDW Water Disposal Well

WMP Well Management Plan



8.0 References

Document

Astron Environmental Service. 2013. Thevenard Island – Flora and

Vegetation Monitoring Report – October 2012. Unpublished report to CAPL.

Astron Environmental Services. 2015. Thevenard Island WA Oil Operations 2014-2015 Annual Weed Monitoring Report. Unpublished report to CAPL.

Astron Environmental. 2011. Thevenard Island Terrestrial Fauna Monitoring. Unpublished report to CAPL.

Golder Associates. 2011. Thevenard Island Conceptual Site Model. Perth, Western Australia (Ref 087643491-023-R-Rev3).

LeProvost, Semeniuk and Chalmer. 1987. Saladin Oilfield Development, Environmental Review and Management Program. Unpublished report to

WAPET. Report No. R114. Perth, Western Australia.

Pendoley, K.L. 1997. Sea Turtles and Management of Marine Seismic Programs Western Australia. PESA Journal, 25: 8–15.

Standards Australia/Standards New Zealand. 2009. ISO 31000:2009 Risk Management – Principles and Guidelines. Sydney, Australia/Wellington, New

Zealand.

Standards Australia/Standards New Zealand. 2012. Handbook 203:2012 Managing Environment-related Risk. Sydney, Australia/Wellington, New Zealand.



Appendix A Chemical Disclosure

To meet the DMIRS requirements regarding chemical disclosure, this Appendix details

any chemicals that will be introduced into the wells on Thevenard Island for the Plug

and Abandonment Program.

1.0 MI SWACO

1.1 System Details Inhibited P&A Fluids

OPERATOR: Chevron Australia Pty Ltd

PROJECT / WELL: Thevenard Island

SYSTEM: Inhibited P&A Fluids

TOTAL VOLUME OF SYSTEM 32 - 159 m3

1.2 Product List Details Inhibited P&A Fluids

Trade

name

Supplier Purpose Product in

system fluid

(%)

Toxicity & Ecotoxicity Info MSDS

Water N/A Base Fluid ~70 N/A N/A

SAFE-SCAV NA

MI SWACO Oxygen Scavenger 0.35

Acute Toxicity: Bisulfites may cause skin and respiratory sensitization in sulfite sensitive persons. May also cause respiratory sensitization in asthmatics. Sulfur dioxide: = 2500 ppm LC50 Inhalation (Rat) 1h

Chronic Toxicity: Repeated or prolonged contact may cause allergic reations in very susceptible

persons. EcoToxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Non-CHARMable: OCNS Group E “least potential environmental hazard”

OSPAR have defined this chemical as PLONOR.

Biodegradation/Bioaccumulation:

Not applicable - Inorganic chemical

Y

Trade

name


system fluid

(%)


CONQOR 303A

MI SWACO Corrosion Inhibitor

0.5

Acute Toxicity: = 5000 mg/kg LD50 Oral (Rat) > 2000 mg/kg LD50 Dermal

Chronic Toxicity:

May cause sensitization by skin contact Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Algae: > 100 mg/L EC50 72h Fish: >100 mg/L LC50 96h Daphnia and other aquatic invertebrates: > 100 mg/L EC50 48h Biodegradation/Bioaccumulation: Product is biodegradable. No bioaccumulation expected due to high molecular weight.

Y

DUO-TEC MI SWACO Viscosifier 1

Acute Toxicity: Glyoxal = 200mg/kg LD50 Oral (Rat) = 12700 mg/kg LD50 Dermal (Rabbit) = 2410 mg/m3 LC50 Inhalation, 3-4hrs; Chronic Toxicity: Contains Glyoxal. May produce an allergic reaction.

Contains a known or suspected mutagen. Ecotoxicity:

The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Glyoxal

= 460-680 mg/L LC50 (Leuciscusidus) 96 h = 215 mg/L LC50 (Pimephales promelas) 96h <= 348.59 mg/L EC50 (Pseudokirchneriella subcapitata) 96 h > 500 mg/L EC50 (Desmodesmus subspicatus) 96 h > 500 mg/L EC50 (Desmodesmus subspicatus) 72 h = 404 mg/L EC50 (Daphnia magna) 48h Biodegradation/Bioaccumulation:

Product components not expected to be biodegradable. Does not bioaccumulate.

Y

Trade

name


system fluid

(%)


DEFOAM A MI SWACO Defoamer 0.02

Acute Toxicity: Inhalation of vapours in high concentration may cause irritation of respiratory system. Causes serious eye injury. Prolonged contact with skin may cause redness

and irritation. Ingestion may cause stomach discomfort

2,2,4-trimethylpentane-1,3-diol = 2 g/kg LD50 Oral (Rat) = 6300μL/Kg LD50 Dermal (Rabbit) Ecotoxicity: The product components are not classified as environmentally hazardous.

However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. > 700 mg/L - LC50 (Fish) - 96h (literature data) > 100 mg/L - EC50 (Algae) - 72 h (literature data) > 100 mg/L - EC50 (Daphnia magna) - 48h (literature data) Biodegradation/Bioaccumulation:

No product level data available

Y

NUOSEPT 78 TROY CORPORATION / MI SWACO

Preservative 0.06

Acute Toxicity: > 2000 mg/kg LD50 Dermal (Rat) 1009 to 3950 mg/kg LD50 Oral (Rat- female) Chronic Toxicity: Eyes (Rabbit) - Cornea opacity - 21 days - score 59 Skin (Rabbit) - mild irritant

Skin (Mouse) - sensitizing Ecotoxicity:

10 - 100 mg/L Acute EC50 (Daphnia) 48 h 10 - 100 mg/L Acute LC50 (Fish) 96 h Biodegradation/Bioaccumulation: Product readily biodegradable. Low Potential to bioaccumulate.

Y

BENTONITE MI SWACO Viscosifier 8

Acute Toxicity: This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystalline silica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis.

Crystalline Silica = 500 mg/kg LD50 Oral (Rat) Chronic Toxicity:

Y

Trade

name


system fluid

(%)


Crystalline silica dust is listed by IARC in Group 1 as known to cause lung cancer in humans, if inhaled.

Ecotoxicity: The product components are not classified as environmentally hazardous.

However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

LC50 96 hours > 10000 mg/l Onchorhynchus mykiss (Rainbow trout) Biodegradation/Bioaccumulation:


CAUSTIC

SODA / Sodium

hydroxide

MI SWACO Additive 0.04

Acute Toxicity: 1350 mg/kg (Rabbit) LD50 Dermal (Rabbit) Ecotoxicity: The product components are not classified as environmentally hazardous.

However, this does not exclude the possibility that large or frequent spills can

have a harmful or damaging effect on the environment. 45.4 mg/L LC50 (Onchorhynchus mykiss) = 96 h Biodegregation/Bioaccumulation: Biodegradability not applicable - inorganic material Not bioaccumulating

Y

NaCl / Salt MI SWACO Additive 20

Acute Toxicity:

= 3 g/kg LD50 Oral (Rat) > 10g/kg LD50 Dermal (Rabbit) > 42 g/m3 LC50 Inhalation (Rat) 1h

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can

have a harmful or damaging effect on the environment. 5560 - 6080 mg/L LC50 (Lepomis macrochirus) = 96 h 12946 mg/L LC50 (Lepomis macrochirus) = 96 h 4747 - 7824 mg/L LC50 (Oncorhynchus mykiss) = 96 h 7050 mg/L LC50 (Pimephales promelas) = 96 h 6420 - 6700 mg/L LC50 (Pimephales promelas) = 96 h 6020 - 7070 mg/L LC50 (Pimephales promelas) = 96 h

340.7 - 469.2 mg/L EC50 (Daphnia magna) = 48 h 1000 mg/L EC50 (Daphnia magna) = 48 h

Y

Trade

name


system fluid

(%)


Biodegradation/Bioaccumulation: Degradability not applicable- Inorganic material. Does not bioaccumulate.

LIME MI SWACO pH Modifier 0.01

Acute Toxicity: = 7340 mg/kg LD50 Oral (Rat)

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. The product may affect

the acidiy in water with risk of harmful effects to aquatic organisms. 160 mg/L LC50 (Gambusia affinis) = 96 h Biodegradation/Bioaccumulation: Not applicable - Inorganic chemical

Y

SODA ASH MI SWACO pH Modifier 0.02


Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 300 mg/L LC50(Lepomis macrochirus) = 96 h 310 - 1220 mg/L LC50 (Pimephales promelas) = 96 h 242 mg/L EC50 (Nitzschia) = 120 h

265 mg/L EC50 (Daphnia magna) = 48 h Biodegradation/Bioaccumulation: Not applicable - Inorganic chemical

Y

Total ~100%

1.3 Chemical List Inhibited P&A Fluids

Chemicals within products in part 1.2 CAS Number Mass Fraction (%)

Water (Including Mix Water Supplied by Client) * - ~ 70

Glyoxal 107-22-2 < 0.01

1,3-Pentanediol, 2,2,4-trimethyl 144-19-4 < 0.1


Sodium carbonate 497-19-8 < 0.1

Bentonite 1302-78-9 ~ 8

Calcium hydroxide 1305-62-0 < 0.1

SODIUM HYDROXIDE 1310-73-2 < 0.1

Hexahydro-1,3,5-tris(2-hydroxyethyl)-sym-triazine 4719-04-4 < 0.1

2,2,4-Trimethyl-1,3-pentanediol diisobutyrate 6846-50-0 < 0.1

Sulfur dioxide 7446-09-5 < 0.01

Sodium chloride 7647-14-5 ~ 20

Ammonium hydrogensulfite 10192-30-0 ~ 1

Xanthan Gum 11138-66-2 < 1

Crystalline silica (impurity) 14808-60-7 < 1

Tripropylene glycol monobutyl ether 25265-77-4 < 1

Ethanol, 2,2'-oxybis-, reaction products with ammonia, morpholine derivs. residues 68909-77-3 < 1

2-aminoethanol 141-43-5 < 0.01

Propane-1,2-diol, propoxylated 25322-69-4 < 0.1

Total ~100.00

1.4 System Details Shale Inhibited Fluid

OPERATOR: Chevron Australia PTY LTD

PROJECT / WELL: TVI

SYSTEM: Shale Inhibited Fluid


1.5 Product List Details Shale Inhibited P&A Fluid

Trade name Supplier Purpose Product in

system

fluid (%)


Water N/A Base Fluid ~70 N/A N/A

SAFE-SCAV NA MI SWACO Oxygen Scavenger 0.35

Acute Toxicity: Bisulfites may cause skin and respiratory sensitization in sulfite sensitive persons. May also cause respiratory sensitization in asthmatics. Sulfur dioxide: = 2500 ppm LC50 Inhalation (Rat) 1h

Acute toxicity:

Acute Toxicity (Oral LD50)

> 2000 mg/kg Rat Chronic Toxicity:

Repeated or prolonged contact may cause allergic reactions in very susceptible persons. Ecotoxicity: The product components are not classified as environmentally

hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.



Y


system

fluid (%)


Biodegradation/Bioaccumulation: Not applicable - Inorganic chemical

Defoam A MI SWACO De-foaming Agent 0.02

Acute toxicity: Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system. Eye contact May cause slight irritation.

Skin contact Prolonged contact may cause redness and irritation. Ingestion Ingestion may cause stomach discomfort. Sensitization This product does not contain any components suspected to be sensitizing. Mutagenic effects This substance has no evidence of mutagenic properties. Carcinogenicity This substance has no evidence of carcinogenic

properties. Reproductive toxicity None known. Developmental toxicity Not known to cause birth defects or have a deleterious effect on a developing fetus. Routes of exposure None known. Routes of entry No route of entry noted. Specific target organ toxicity

(single exposure) Not classified Specific target organ toxicity

(repeated exposure) Not classified. Aspiration hazard No hazard from product as supplied.

2,2,4-trimethylpentane-1,3-diol –LD50 Oral = 2 g/kg ( Rat )LD50 Dermal = 6300 μL/kg ( Rabbit )

Ecotox:

Toxicity to algae This product is not considered toxic to algae. Toxicity to fish

Y


system

fluid (%)


Not considered toxic to fish. Toxicity to daphnia and other aquatic invertebrates Not considered toxic.

> 700 mg/L - LC50 (Fish) - 96h (literature data)

> 100 mg/L - EC50 (Algae) - 72 h (literature data) > 100 mg/L - EC50 (Daphnia magna) - 48h (literature data)

Biodegradation/Bioaccumulation: No Data Available

DUO-TEC MI SWACO Viscosifier 1

Acute Toxicity: Glyoxal = 200mg/kg LD50 Oral (Rat) = 12700 mg/kg LD50 Dermal (Rabbit)

= 2410 mg/m3 LC50 Inhalation, 3-4hrs; Chronic Toxicity: Contains Glyoxal. May produce an allergic reaction. Contains a known or suspected mutagen. Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that

large or frequent spills can have a harmful or damaging effect on the environment. Glyoxal

= 460-680 mg/L LC50 (Leuciscusidus) 96 h = 215 mg/L LC50 (Pimephales promelas) 96h <= 348.59 mg/L EC50 (Pseudokirchneriella subcapitata) 96 h

> 500 mg/L EC50 (Desmodesmus subspicatus) 96 h > 500 mg/L EC50 (Desmodesmus subspicatus) 72 h = 404 mg/L EC50 (Daphnia magna) 48h Biodegradation/Bioaccumulation: Product components not expected to be biodegradable. Does not bio-accumulate.

Y

Sodium Bicarbonate

MI SWACO Alkalinity <1

Acute toxicity:

=4220 mg/kg LD50 Oral (Rat) =4.74 mg/l LC50 Inhalation dust/mist (Rat)

Y


system

fluid (%)


Ecotoxicity: OSPAR have defined this chemical as PLONOR. >7000 mg/l LC 50 Fish 96 Hrs

>4000 mg/l EC 50 Daphnia 48 Hrs Biodegradation/Bioaccumulation:

No Data Available

NUOSEPT 78 TROY CORPORATION / Mi SWACO

Preservative 0.06

Acute Toxicity: > 2000 mg/kg LD50 Dermal (Rat)

1009 to 3950 mg/kg LD50 Oral (Rat- female) Chronic Toxicity: Eyes (Rabbit) - Cornea opacity - 21 days - score 59 Skin (Rabbit) - mild irritant Skin (Mouse) - sensitizing Ecotoxicity: 10 - 100 mg/L Acute EC50 (Daphnia) 48 h

10 - 100 mg/L Acute LC50 (Fish) 96 h Biodegradation/Bioaccumulation: Product readily biodegradable. Low Potential to bio-accumulate.

Y

Polypac UL MI SWACO Fluid Loss Control 1

Acute Toxicity: Inhalation of dust may cause shortness of breath, tightness of chest, a sore throat and cough

Carboxymethylcelloulose sodium salt =27000mg/kg LD50 (Rat) LD50 >2g/kg (Rabbit), > 5800mg/m3 LD50 Inhalation (Rat) 4h Eco Toxicity

Non-CHARMable: OCNS Group E “least potential environmental

hazard”


Bioaccumulation No data available

Y

DUO-VIS MI SWACO Viscosifier 0.5

Acute toxicity:

Component: Glyoxal LD50 Oral = 200 mg/kg ( Rat ) LD50

Dermal = 12700 mg/kg ( Rabbit ) LC50 Inhalation = 2410 mg/m³, 3-4 hrs Ecotoxicity:

Y


system

fluid (%)


The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on

the environment. Component: Glyoxal Toxicity to fish 460 - 680 mg/L LC50

Leuciscuidus 96 h = 215 mg/L LC50 Pimephales promelas 96 h Toxicity to algae <= 348.59 mg/L EC50 Pseudokirchneriella subcapitata 96h > 500 mg/L EC50

Desmodesmus subspicatus 96 h > 500 mg/L EC50 Desmodesmus subspicatus 72 h Toxicity to daphnia and other aquatic invertebrates = 404 mg/L EC50 Daphnia magna 48 h Biodegradation/Bioaccumulation: Readily biodegradable/Does not bio-accumulate.

Potassium chloride

MI SWACO Density and Inhibition

+ 8

Acute toxicity: Inhalation of dust in high concentration may cause irritation of respiratory system. LD50 Oral - = 2600 mg/kg ( Rat )

Ecotoxicity: The product component(s) are not classified as environmentally

hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.

Toxicity to fish 750 - 1020 mg/L LC50 (Pimephales promelas) = 96 h

1060 mg/L LC50 (Lepomis macrochirus) = 96 h

Toxicity to algae 2500 mg/L EC50 (Desmodesmus subspicatus) = 72 h

Toxicity to daphnia and other aquatic invertebrates 83 mg/L EC50 (Daphnia magna) = 48 h

825 mg/L EC50 (Daphnia magna) = 48 h

Y


system

fluid (%)


Biodegradation/Bioaccumulation: No data available

NaCl / Salt MI SWACO Additive 20

Acute Toxicity: = 3 g/kg LD50 Oral (Rat)

> 10g/kg LD50 Dermal (Rabbit) > 42 g/m3 LC50 Inhalation (Rat) 1h Ecotoxicity: The product components are not classified as environmentally

hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 5560 - 6080 mg/L LC50 (Lepomis macrochirus) 96 h 12946 mg/L LC50 (Lepomis macrochirus) 96 h 4747 - 7824 mg/L LC50 (Oncorhynchus mykiss) 96 h 7050 mg/L LC50 (Pimephales promelas) 96 h

6420 - 6700 mg/L LC50 (Pimephales promelas) 96 h 6020 - 7070 mg/L LC50 (Pimephales promelas) 96 h 340.7 - 469.2 mg/L EC50 (Daphnia magna) 48 h 1000 mg/L EC50 (Daphnia magna) 48 h Biodegradation/Bioaccumulation: Degradability not applicable- Inorganic material.

Does not bio-accumulate.

Y

SODA ASH MI SWACO pH Modifier 0.02


Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that

large or frequent spills can have a harmful or damaging effect on the environment. 300 mg/L LC50(Lepomis macrochirus) 96 h 310 - 1220 mg/L LC50 (Pimephales promelas) 96 h 242 mg/L EC50 (Nitzschia) 120 h 265 mg/L EC50 (Daphnia magna) 48 h Biodegradation/Bioaccumulation:


Y


system

fluid (%)


Total ~100%

1.6 Chemical List Shale Inhibited P&A Fluid


Water (Including Mix Water) - ~ 53

Potassium Chloride Brine 0-00-0 ~ 8

Glyoxal 107-22-2 < 0.01

2-aminoethanol 141-43-5 < 0.01

Sodium hydrogen carbonate 144-55-8 < 1

Sodium carbonate 497-19-8 < 1

Hexahydro-1,3,5-tris(2-hydroxyethyl)-sym-triazine 4719-04-4 < 0.1

Sulfur dioxide 7446-09-5 < 0.01

Sodium chloride 7647-14-5 ~ 36

Sodium carboxymethylcellulose 9004-32-4 < 1

Ammonium hydrogensulfite 10192-30-0 ~ 1

Xanthan gum 11138-66-2 < 1

Propane-1,2-diol, propoxylated 25322-69-4 < 0.1

Total 100.00

1.7 Contingency Products Details


system fluid (%)

Toxicity & Eco toxicity Info MSDS

attached

G-SEAL

(All Grades) MI SWACO Plugging Agent 1 – 14

Acute Toxicity: Inhalation of dust in high concentration may cause

irritation of respiratory system. May cause slight eye

irritation. Prolonged skin contact may cause redness and irritation.

Graphite

LD50 Oral - LD50 > 2000 mg/kg bw, Rat, OECD 423 LC50 Inhalation - LD50 > 2000 mg/m³, Rat, OECD 403 Ecotoxicity:

The product components are not classified as

environmentally hazardous. However, this does not

exclude the possibility that large or frequent spills

can have a harmful or damaging effect on the

environment.

Toxicity to fish

LC50 > 100 mg/l, 96 hour, OECD 203 Toxicity to algae EC50 > 100 mg/l, 72 hour, OECD 201 Toxicity to daphnia and other aquatic invertebrates EC50 > 100 mg/l, 48 hour, OECD 202 Biodegradation/Bioaccumulation:

Biodegradability - no product level available. Does

not bioaccumulate.

Y

CALCIUM CHLORIDE

MI SWACO Weighting Agent < 3

Acute Toxicity: = 1000 mg/kg LD50 (Rat) = 2630 mg/kg LD50 (Rat)

Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 10650 mg/L LC50 (Lepomis macrochirus) = 96 h

52 mg/L EC50 (Daphnia magna) = 48 h

Y


system fluid (%)


attached


SAFE-SCAV HSB MI SWACO H2S SCAVENGER < 0.05

Acute toxicity

This product may contain or release trace amounts of formaldehyde. The International Agency for Research on

Cancer (IARC) has classified formaldehyde as a Group 1carcinogen (limited evidence in humans, sufficient evidence in animals). Exposure to formaldehyde has been linked to adverse reproductive effects in some human and animal studies. In other

reproductive studies, however, no adverse effects were noted. (Meditext). Formaldehyde may also cause skin sensitisation (allergic reaction). Constituent (30-60%) LD50 Oral = 763 mg/kg (rat) Constituent (30-60%) LD50 Oral > 90 mg/kg (rat)

Constituent (1-5%) LD50 Oral = 1720 mg/kg (rat) Ecotoxicity

227 mg/L LC50 (Pimephales promelas) = 96 h 3684 mg/L LC50 (Brachydaniorerio) = 96 h 300 - 1000 mg/L LC50 (Lepomismacrochirus) = 96 h 114 - 196 mg/L LC50(Oncorhynchus mykiss) = 96 h 200 mg/L LC50 (Oncorhynchusmykiss) = 96 h 65 mg/L EC50 (Daphnia magna) = 48 h

Does not bioaccumulate

OCNS rating = Gold – no substitution warning

Y

MAGNESIUM OXIDE

MI SWACO pH Modifier < 0.5

Acute Toxicity: Inhalation of dust in high concentration may cause irritation of respiratory system. Dust may cause mechanical eye irritation. May irritate skin with prolonged

contact.

Acute Toxicity (Dermal LD50)

> 2 mg/kg Rabbit Ecotoxicity: The product components are not classified as environmentally hazardous. However, this does not

exclude the possibility that large or frequent spills can

have a harmful or damaging effect on the environment.

Y


system fluid (%)


attached

The product may affect the acidity (pH factor) in water with risk of harmful effects to aquatic organisms.




Circal All grades /

SAFE-CARB All grades / Omyacarb

All Grades

MI

SWACO

Lost Circulation Material

1 - 5

Toxicity

Calcium carbonate - LD50 Oral - = 6450 mg/kg ( Rat ) Crystalline silica (impurity) - LD50 Oral = 500 mg/kg ( Rat )

Ecotoxicity LC50 Fish 96 h > 10'000 mg/l LC50 Daphnia 49 h > 1000 mg/l

LC50 Algae 72 h mg/l Persistence & degradability Not readily degradable, except in acid conditions where it tends to have a neutralizing effect. Bioaccumulative potential Calcium carbonate is a naturally occurring inorganic

compound which has constituent elements that make up natural components of biological organisms. Mobility in soil

Calcium carbonate is practically insoluble except in acid conditions, and so presents a low soil mobility in most ground. Moreover it is commonly used as an effective soil conditioner and fertiliser

Y

Barite MI SWACO Weighting Agent 1 – 10

Toxicity Crystalline silica (impurity) - LD50 Oral - = 500 mg/kg ( Rat ) Chronic Toxicity May contain small amounts of respirable crystalline silica, silica is a IARC Group 1

Carcinogen

Eco Toxicity

Y


system fluid (%)


attached

Acute Fish Toxicity TLM96: 7500 mg/L (Oncorhynchus mykiss)

Biodegradation / bioaccumulation N/a given inorganic and naturally occurring

Citric Acid MI SWACO pH modifier / treating cement contamination

< 1

Toxic Dose 1 - LD 50 - 5040 mg/kg (oral-mouse)

Toxic Dose 2 - LD 50 -3000 mg/kg (oral rat)

Acute toxicity:

Acute Toxicity (Oral LD50) > 7000 mg/kg Rabbit ATE (Oral) 3000 mg/kg

Acute Fish Toxicity 96h LC50: >440-760 mg/L (Leuciscus idus)

Degradability

There are no data on the degradability of this product. Bioaccumulative potential No data available on bioaccumulation

Y

M-I-X II MI SWACO Lost Circulation

Material < 5

Acute Toxicity

Cellulose: > 2 g/kg (Dermal LD50; Rabbit) > 5 g/kg (Oral LD50; Rat) > 5800 mg/m3 (Inhalation LC50; Rat) 4 h

Silica, crystalline, quartz LD50 Oral = 500 mg/kg (rat)

Toxicity to algae This product is not considered toxic to algae. Toxicity to fish This product is not considered toxic to fish. Toxicity to daphnia and other aquatic invertebrates This product is not considered toxic to invertebrates.


Persistence and degradability

Y


system fluid (%)


attached

This product is expected to be readily biodegradable. Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

Kleen-Up MI SWACO Detergent <1

Acute Toxicity

> 2000 mg/kg LD50 Oral (Rat) > 100 mg/l LC50 (Fish) Ecotox: Skeletonema Algae – 72h EC50 mg/l – 1.7 Acartia Crustacean – 48h LC50 mg/l >1.7

Corophium (10d LC50 mg/Kg dry sediment) >2.2

Biodegradation/Bioaccumulation: OECD 306 (% in 28 days) - 61No data available on bioaccumulation

Y

SAPP MI SWACO Dispersant 2

Acute Toxicity:

= 1800 mg/kg LD50 Oral – Rat > 0.58 mg/L C50 Inhalation – Rat l Ecotoxicity: Not considered toxic to algae, fish, daphnia or other aquatic invertebrates

Non-CHARMable: OCNS Group E “least potential

environmental hazard”



Not applicable, inorganic chemical

Y

Sodium Bicarbonate

MI SWACO Alkalinity <1

Acute toxicity: 4220 mg/kg LD50 Oral (Rat)

Acute Toxicity (Inhalation LC50) 4.74 mg/l (dust/mist) Rat Ecotoxicity: OSPAR have defined this chemical as PLONOR. >7000 mg/l LC50 Fish 96 Hrs >4000 mg/l EC 50Daphnia 48 Hrs, Biodegradation/Bioaccumulation:

No Data Available

Y

Safe-Solv E MI SWACO Solvent 1 Acute toxicity Inhalation May cause irritation of respiratory tract. Vapors inhaled in high concentration have a narcotic

Y


system fluid (%)


attached

effect on the central nervous system. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. Eye contact Causes eye irritation. Skin contact May cause skin irritation and/or dermatitis.

Prolonged skin contact may defat the skin and produce dermatitis. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis

EcoToxicity: Toxicity to algae See component information below. Toxicity to fish See component information below. Toxicity to daphnia and other aquatic invertebrates See component information below.

Chemical Name Distillates, petroleum, hydrotreated light Toxicity to fish =

45 mg/L LC50 Pimephales promelas 96 h = 2.4 mg/L LC50 Oncorhynchus mykiss 96 h = 2.2 mg/L LC50 Lepomis macrochirus 96 h Toxicity to algae No information available Toxicity to daphnia and other aquatic invertebrates = 4720 mg/L LC50 Den-dronereides heteropoda 96 h Terpenes and terpenoids, sweet orange-oil Toxicity to fish

No information available Toxicity to algae No information

available Toxicity to daphnia and other aquatic invertebrates No information available Bioaccumulation: No product level data available

Chrome Free

Desco® Deflocculant

MI SWACO / Chevron Phillips Chemical

Company

Deflocculant 0.5 - 1

> 5000 mg/kg bw LD50 Oral (Rat) > 6.66 mg/L LC50 Inhalation Genotoxicity: Negative (AMES) Subchronic (oral: gavage) (Rat) NOAEL: 1000 mg/kg bw/d Reproductive/Developmental NOAEL: 1000 mg/kg bw/d

Ready biodegradability 38% after 28 days

> 100 mg/L EbC50 Algae (Desmodesmus subspicatus) 72h = 73.2 mg/L LC50 Acartia tonsa 48h

Y


system fluid (%)


attached

> 1800 mg/L LC50 Fish (Scophtalmus maximus) 96h Causticized lignite = 2970 mg/L ErL50 Skeletonema costatum 72h > 10,000 mg/L EL50 Acartia tonsa 48 h > 2970 mg/L LL50 Cyprinodon variegatus 96h:

Ferrous Sulfate 319 mg/kg bw LD50 Oral (Rat) Skin Irritant: (yes) Eye Irritant: (yes) = 45 mg/L EL50 Skeletonema costatum 72h > 190 mg/L EL50 Acartia tonsa 48h

> 6.25 mg/L LL50 Cyprinodon variegatus 96h

Total ~100

1.8 Contingency Chemical List

Chemicals within products in part 1.7 CAS Number Mass Fraction (%)*

Water (Including Mix Water Supplied by Client) * - ~ 55

Magnesium oxide 1309-48-4 < 1

Graphite 7782-42-5 ~ 1 -14

2,2',2''-(hexahydro-1,3, 5-triazine-1,3,5-triyl) triethanol 4719-04-4 ~ 1

2-aminoethanol 141-43-5 < 1

Calcium Carbonate 1317-65-3 ~ 1 -15

Barium Sulphate 7727-43-7 ~ 1 -10

Crystalline silica (impurity) 14808-60-7 < 0.1

Calcium chloride 10043-52-4 ~ 3

Citric Acid 5949-29-1 < 0.1

Ethoxylated Fatty Alcohol 78330-21-9 < 1

Sodium hydrogen carbonate 144-55-8 < 1

Chemicals within products in part 1.7 CAS Number Mass Fraction (%)*

Disodium dihydrogen diphosphate 7758-16-9 <2

Terpenes and terpenoids, sweet orange-oil 68647-72-3 < 1

Distillates, petroleum, hydrotreated light 64742-47-8 < 1.5

Cellulose Fibre 9004-34-6 <1.5

Sulfomethylated Quebracho 68201-64-9 < 1

Causticized lignite 68131-04-4 < 0.2

Ferrous Sulfate 17375-41-6 < 0.1

Crystalline Silica 14808-60-7 < 0.1

Total ~100.00

* % to be used in total system if required – note contingency materials only

2.0 Wellcem

2.1 System Details Inhibited P&A Fluids

OPERATOR: Chevron Australia PTY LTD

PROJECT / WELL: TVI

SYSTEM: Resin system


2.2 Product List Details Inhibited P&A Fluids

Trade

name


system fluid

(%)


ThermaSet Wellcem Base fluid 15

Acute toxicity:

Inhalation: Harmful by inhalation. May cause irritation of respiratory tract. Inhalation of high vapour concentrations can cause CNS depression and narcosis. Eye contact: Irritating to eyes. Skin contact. Causes skin irritation. Prolonged skin contact may defat the skin and produce dermatitis. Ingestion: HARMFUL IF SWALLOWED. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. May be fatal if swallowed and enters airways.

Vinyl toluene (ECHA): Oral LD50: (rat) 3.68 ml/kg Dermal LD50: (rabbit) >5 ml/kg Inhalation LC50: (rat – 4 h) 16.891 mg/l

Chronic Toxicity

Repeated or prolonged exposure may cause skin irritation and dermatitis, due to

defatting properties of the product. May cause damage to the liver, eyes, brain, respiratory system, central nervous system through prolonged or repeated exposure if inhaled.

Ecotoxicity

Vinyl Toluene

Algae EC50: 2.6 mg/l (Selenastrum Capricornutum) 72 h

Fish LC50: 23.4 mg/l (Pimephales rafinesque)

Y

Trade

name


system fluid

(%)


96 h Aquatic invertebrates EC50: 1.3 mg/l (Daphnia magna) 48 h


Bioaccumulation is unlikely

ThermaSet

Cleaner Wellcem

Cleaning

Fluid 10

Acute toxicity:

Based on available data, the classification criteria are not met.

Oral LD50: (rat) >5 000 mg/kg Dermal LD50: (rat) >2 000 mg/kg Inhalation LC50: (rat) 11 mg/l 4 h

Chronic Toxicity

Based on available data, classification criteria not met

Ecotoxicity

Fish LC50: 18 - 24 mg/l (fish):) (96 h)

Aquatic invertebrates EC50: 112 - 150 mg/l (Daphnia magna) (48 h)


No further relevant information available.

Y

Curing Initiator 65

Wellcem Initiator 5.3

Acute toxicity

Not classified based on available information.

Oral LD50: (rat) >5 000mg/kg Inhalation LC50: (rabbit) 24.3 mg/l (4 h) dust/mist

Chronic Toxicity

Skin corrosion/irritation: Not classified. May cause skin irritation and/or dermatitis. Serious eye damage/irritation: Causes serious eye irritation. May cause irreversible eye damage. Respiratory or skin sensitisation: May cause an allergic

skin reaction. Respiratory sensitisation: Not classified based on available information. Germ cell mutagenicity: Not classified based on available information. Dibenzoyl peroxide test – genotoxicity in vitro/in vivo – negative. Reproductive

toxicity: Not classified based on available information. Dibenzoyl peroxide test (rat) oral, fertility: No observed adverse effect level >1 000 mg/kg body weight. No effects on fertility.

Ecotoxicity

Dibenzoyl peroxide Algae EC50: 0.0711 mg/l (Pseudokirchneriella subcapitata) 72 h Fish LC50: 0.0602 mg/l (Oncorhynchus mykiss) 96 h Aquatic invertebrates EC50: 0.11 mg/l (Daphnia magna) 48 h M-Factor 10 (acute aquatic toxicity) Bacteria EC50: 35 mg/l 0.5 h

Y

Trade

name


system fluid

(%)


Bioaccumulative potential

Dibenzoyl peroxide: Partition coefficient n-octanol/water: Log pow 3.2 (20C)

Curing Initiator 40


Acute toxicity

Oral LD0: (rat) >2 000 mg/kg

Inhalation LC50: (rat – 4h) 4,9 mg/l (dust/mist)

Dermal LD0: (rat) >2 000 mg/kg

Chronic Toxicity

Skin irritation. Vapours may cause irritation to the eyes, respiratory system and the skin. May cause an allergic skin reaction. Respiratory sensitization

Ecotoxicity

Fish LC50: 1.6 mg/l (Danio rerio) (96 h)

Aquatic invertebrates EC50: 11 mg/l (Daphnia magna) (48 h)

Algae EC50: 0.8 mg/l (Pseudokirchneriella subcapitata) (72 h)

Algae NOEC: 0,72 mg/l (Pseudokirchneriella subcapitata) (72h)

M-Factor 1 (acute aquatic toxicity)

Bacteria EC50: 43 mg/l (0.5 h)

Aquatic invertebrates EC10: 0.49 mg/l (Daphnia magna) (21 d) chronic toxicity


Partition coefficient n-octanol/water: Log Pow 2.89 (25C)

Y

PergaQuick Wellcem Accelerator 2

Acute toxicity

Inhalation: Toxic if inhaled. Eye contact: Irritating to eyes. Skin contact: Toxic in contact with skin. Causes mild skin irritation. Ingestion: Toxic if swallowed.

Oral LD50: (rat) 1 767 mg/kg

Dermal LD50: (mouse) >2 000 mg/kg

Inhalation LC50: (rat – 4 h) 1.4 mg/l

Chronic Toxicity

Skin corrosion/irritation: Mild skin irritation. Serious eye damage/irritation: Slightly irritating to eyes. Germ cell mutagenicity: DNA damage on rat and mouse. Carcinogenicity: Ames test: negative result. Reproductive toxicity: No data available. STOT-single exposure: May cause damage to organs through prolonged exposure. STOT-repeated exposure: May cause damage to organs through

Y

Trade

name


system fluid

(%)


prolonged or repeated exposure – category 2. Aspiration hazard: Harmful by inhalation.

Ecotoxicity

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life with long lasting effects.

Fish LC50: 46-52 mg/l (Pimephales promelas) 96 h


No information available

Curing Initiator T


Acute toxicity

Oral toxicity: Acute toxicity estimate: > 2 000 mg/kg

Acute oral toxicity LD50: (rat) > 4 700 mg/kg

Acute inhalation toxicity LC50: (rat – 4h) >1.2 mg/l (dust/mist)

Acute dermal toxicity LD50: (rat) > 2 000 mg/kg

Repeated dose toxicity NOEL 150 mg/kg (rat, oral, 28 days)

Chronic Toxicity

Skin corrosion/irritation: (rabbit): Skin irritation. Serious eye damage/irritation: No eye irritation. Respiratory or skin sensitisation: May cause an allergic skin reaction. Germ cell mutagenicity: Not classified based on available information. In vitro: Negative, in vivo: No data available. Carcinogenicity: Not classified based on available information. Reproductive toxicity: Species: Rat, male and female Application Route: Oral Dose: 0, 75, 150, 600 milligram per kilogram General Toxicity - Parent: No observed adverse effect level: 150 mg/kg bw/day Fertility:

No observed adverse effect level Parent: 150 mg/kg bw/day h) STOT-single exposure: Not classified based on available information. i) STOT-repeated exposure: The substance or mixture is not classified as specific target organ toxicant, repeated exposure

Ecotoxicity

tert-Butyl perbenzoate

Aquatic invertebrates EC50: 4.3 mg/l (Daphnia magna) (48 h)

Algae ErC50: >100 mg/l (Pseudokirchneriella subcapitata) (72 h)

Algae NOEC: 0.58 mg/l (Pseudokirchneriella subcapitata) (72h)

.alpha.-Methylstyrene

Y

Trade

name


system fluid

(%)


Aquatic invertebrates NOEC: 0.401 mg/l (Daphnia magna) (21 d) (Chronic toxicity)

Cumene

Aquatic invertebrates EC50: >1 - 10 mg/l (Daphnia magna) (48 h)


Bioaccumulation: Bioconcentration factor (BCF): 2,57

Micromax Wellcem Filler 22

Acute toxicity

LD50 Oral Rat-female >2 000 mg/kg (fixed dose method)

Chronic Toxicity

Skin corrosion/irritation: Dust may cause mechanical irritation. Serious eye damage/irritation: Dust may cause mechanical irritation. Respiratory or skin sensitisation: Dust may cause mechanical irritation of mucous membranes. Inhalation of high concentrations of Mn vapour or Mn oxide fumes (See section 8) can result in chemical pneumonia. Reproductive toxicity: Reproductive toxicity - Mouse - Oral Paternal Effects: Testes, epididymis, sperm duct. Paternal Effects:

Prostate, seminal vessicle, Cowper's gland, accessory glands.

Ecotoxicity

Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - > 1.6 mg/l - 48h


Not relevant

Y

Glass beads Wellcem Filler 15

Acute toxicity

Inhalable dust TWA: 10 mg/m³ 8 hours

Respirable dust TWA: 4 mg/m³ 8 hours

Chronic Toxicity

Serious eye damage/irritation: Dust may cause mechanical irritation.

Ecotoxicity

On PLONAR. No Substitution warning. OCNS Group E (least concern).

Y

Aerosil 200 Wellcem Filler 5

Acute toxicity

Oral LD50: (rat) >3 300 mg/kg no deaths occured

Dermal LD50: (rabbit) 5 000 mg/kg comparable product

Y

Trade

name


system fluid

(%)


Inhalation LC0: (rat) 0,139 mg/l 4 t no deaths occurred

Chronic Toxicity

Carcinogenicity: No evidence that cancer may be caused. Germ cell mutagenicity:

No evidence of mutagenic effects

Ecotoxicity

Fish LC50: > 10 000 mg/l (Brachydanio rerio):) (96 h)

Aquatic invertebrates EC50: > 1 000 mg/l (Daphnia magna) (24 h)


Not to be expected.

EnvoSet Wellcem Base Fluid 15

Acute toxicity

Oral LD50: (rat) 5 000 mg/kg

Dermal LD50: (rabbit) 3 000 mg/kg

Chronic Toxicity

Inhalation: No known hazard by inhalation.

Eye contact: May cause slight irritation.

Skin contact. May cause allergic skin reaction.

Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

Ecotoxicity

Algae EC50: 23.6 mg/l (Phaeodactylum tricornutum) 72 h

Fish LC50: >20.3 mg/l (Cyprinodon variegatus) 96 h

Aquatic invertebrates LC50: 20.3 mg/l (Acartia tonsa) 48 h


Weighted average Log Pow for the substance is 3.92.

Y

Trade

name


system fluid

(%)


Total ~100%

2.3 Chemical List Inhibited P&A Fluids

Chemicals within products in part 2 CAS Number Mass Fraction (%)

Maleic anhydride 108-31-6 1.425

Dibenzoyl peroxide 94-36-0 2

Cumene 98-82-8 0.12

Bisphenol A 80-05-7 1.425

Methanol 67-56-1 0.1

Vinyl toluene 25013-15-4 4.7

Ethylene glycol 107-21-1 1.425

Dimethyl succinate 106-65-0 2

Polyvinyl acetate 9003-20-7 1.425

tert-Butyl perbenzoate 614-45-9 4.9

Hydrophilic amorphous fumed silica 7631-86-9, 112945- 52-5 5

Fatty acid 61788-89-4 1.425

Dimethyl adipate 627-93-0 1.2

N,N-Dimethyl-p-toluidine 99-97-8 2

Dicyclopentadiene 77-73-6 1.425

Silicon dioxide 7631-86-9 0.3

Benzoquinone 106-51-4 0.01

Isophthalic acid 121-91-5 1.425

Acetophenone 98-86-2 0.1

https://www.sigmaaldrich.com/catalog/search?term=80-05-7&interface=CAS%20No.&N=0&mode=partialmax&lang=en&region=NO&focus=product

Diethylene glycol 111-46-6 1.425

Propylene glycol 57-55-6 1.425

Isodecyl benzoate 131298-44-7 2.3

Phthalic anhydride 85-44-9 1.425

Dimethyl glutarate 1119-40-0 6.9

Water 7732-18-5 0.8

Soda lime borosilicate glass 65997-17-3 15

.alpha.-Methylstyrene 98-83-9 0.12

Polyvinylacetate 9003-20-7 1.6

tert-Butyl cumyl peroxide 3457-61-2 4.75

1,4-Butanediol Dimethacrylate 2082-81-7 9.75

Zinc stearate 557-05-1 0.1

Trimanganese tetroxide 1317-35-7 22

Total ~100.00

3.1 SYSTEM DETAILS

Operator Chevron Australia

Project Thevenard Island Onshore P&A

System BiSN Well-Lok Plugging System

Total Volume of System 0.135 – 0.55 m3 per well

3.2 PRODUCT LIST

Trade Name Supplier Purpose Product

content in system (%)

Toxicity & Ecotoxicity Information MSDS

attached

BiSN-93 BiSN Sealing Agent 80-95

Toxicity

Bismuth – LD50 Oral-rat >5,000 mg/kg

Tin – LD50 Oral-rat >700 mg/kg

Lead – LD50 N/A; LC50 N/A

Ecotoxicity

LC50 – Micropterus dolomieui 2.2 mg/L 96h

EC50 – Skeletonema costatum 7.94 mg/L 10d

Biodegradation / Bioaccumulation

Bismuth - Insoluble in hot or cold water (ToxNet, 2018)

Tin – Insoluble in water (ToxNet, 2018)

Lead – Elemental lead is not biodegradable (ToxNet, 2018)

Yes

BiSN-ETC-1 BiSN Heating Agent 5-20

Toxicity

Ferric Oxide - LD50 Oral-rat >10,000 mg/kg

Silica Sand – LD50 Rat oral >22,500 mg/kg

Sodium acid / silicate – LD50 Rat oral 1.1 – 1.6 g/kg

Ecotoxicity

Yes




attached

Aluminium Powder– L50 Pisidium casertanum >1.0 mg/L 96h

Silica Sand - PLONAR


Ferric Oxide – Insoluble in water (ToxNet, 2018)

Silica oxide (amorphous silica) – Insoluble (ToxNet, 2018)

Silicic Acid - Very slightly soluble or almost insoluble in cold water; less readily soluble in large amount of water than in small amount; anhyd dissolve with more difficulty than hydrate in water (ToxNet, 2018)

Aluminium - Insoluble in water (ToxNet, 2018)

Total Fluid 100%

3.3 CHEMICAL LIST

Chemicals within products in Part B CAS number Mass fraction (%)

Bismuth 7440-69-9 35-55

Tin 7440-31-5 8-22

Lead 7439-92-1 20-35

Ferric Oxide 1309-37-1 3-8

Aluminum Powder (uncoated) 7429-90-5 1-5

Silica Sand 14808-60-7 0-3

Sodium Silicate 6834-92-0 0-2

Total - ~100

3.4: SYSTEM DETAILS



System BiSN Well-Lok Plugging System 2


3.5: PRODUCT LIST




attached


Toxicity


Lead – LD50 N/A; LC50 N/A

Ecotoxicity

LC50 – Micropterus dolomieui 2.2 mg/L 96h

EC50 – Skeletonema costatum 7.94 mg/L 10d



Lead – Elemental lead is not biodegradable (ToxNet, 2018)

Yes


Toxicity


Silica sand – LD50 Rat oral >22,500 mg/kg


Ecotoxicity

Yes




attached





Silica sand (amorphous silica) – Insoluble (ToxNet, 2018)



Total Fluid 100%

3.6: CHEMICAL LIST


Bismuth 7440-69-9 42-63

Lead 7439-92-1 28-47



Silica Sand 14808-60-7 0-3

Sodium Silicate, sodium salt 1344-09-8 0-2

Total - ~100

3.7: SYSTEM DETAILS





3.8: PRODUCT LIST




attached


Toxicity


Tin – LD50 Oral-rat >700 mg/kg



Tin – Insoluble in water (ToxNet, 2018)

Yes


Toxicity


Silica – LD50 Rat oral >22,500 mg/kg


Ecotoxicity





Silica sand (amorphous silica) – Insoluble (ToxNet, 2018)

Yes




attached



Total Fluid 100%

3.9: CHEMICAL LIST


Bismuth 7440-69-9 45-60

Tin 7440-31-5 30-45



Silica Sand 14808-60-7 0-3


Total - ~100

3.10: SYSTEM DETAILS


Project Thevenard Island



3.11: PRODUCT LIST




attached


Toxicity

Silver – LD50 Oral-rat >5,000 mg/kg




Silver compounds - Most silver compounds are insoluble, with the exception of nitrate which is miscible(1). The oxides, sulfates, carbonates, and phosphates of silver are moderately soluble(1). These compounds are not likely to remain as solids or precipitates in the natural environment (ToxNet, 2018)

Yes


Toxicity


Silica Sand– LD50 Rat oral >22,500 mg/kg


Ecotoxicity



Yes




attached



Silica Sand (amorphous silica) – Insoluble (ToxNet, 2018)



Total Fluid 100%

3.12: CHEMICAL LIST


Bismuth 7440-69-9 80-95

Silver 7440-22-4 0.5-5



Silica Sand 14808-60-7 0-3


Total - ~100

4.0 SandAband

4.1 System Details SandAband

OPERATOR: Chevron Australia Pty Ltd

PROJECT / WELL: TVI

SYSTEM: Zonal Isolation Material: SandAband®

TOTAL VOLUME OF SYSTEM: ~20 m3/well

4.2 Product List Details


system fluid (%)


Water N/A Mix water 10.9 % N/A N/A

Silica Sand Flopetrol Well Barrier

Inert mineral particles

50.3 %

Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.

11.1 Information on toxicological effects:

The inhalation of quartz containing dust, in particular the fine dust fraction (respirable size), in high concentrations or over repeated or prolonged periods of time can be hazardous to health and may lead to chronic lung disease and an increased risk of lung cancer. This risk will be minimal if correct working practices

are observed and applied. According to the International Agency for Research on Cancer (IARC Monograph Volume 100C - 2012) “Crystalline silica inhaled in the form of quartz or cristobalite is carcinogenic to humans (Group 1).

Acute toxicity: Not classified. Skin corrosion/irritation: Not classified. Serious eye damage/irritation: Not classified.

Yes

Trade name Supplier Purpose Product in system fluid

(%)


Respiratory or skin sensitisation: Not classified. Germ cell mutagenicity: Not classified. Carcinogenicity: Suspected of causing cancer. Reproductive toxicity: Not classified. Specific target organ toxicity - single exposure: Not classified.

Specific target organ toxicity – repeated exposure: Not classified. Aspiration hazard: Not classified.

Additional information:

Dust may irritate respiratory system or lungs. May cause irritation in the mouth and to the mucous membranes. May cause skin irritation/eczema. Particles in the eyes may cause irritation and smarting.

Microsilica

Flopetrol

Well Barrier


12.7 %

Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable.

Biodegradation: Substance is inorganic - biodegradation is not applicable.

11.1 Information on toxicological effects

Acute toxicity: Not classified. Skin corrosion/irritation: Not classified. Serious eye damage/irritation: Not classified.

Respiratory or skin sensitisation: Not classified. Germ cell mutagenicity: Not classified. Carcinogenicity: Not classified. Reproductive toxicity: Not classified. Specific target organ toxicity - single exposure: Not classified. Specific target organ toxicity – repeated exposure: Not classified.

Aspiration hazard: Not classified.

Additional information:

Dust may irritate respiratory system or lungs. May cause irritation in the mouth and to the mucous membranes. May cause skin irritation/eczema.

Yes

Natural product. On PLONAR List.


(%)


Particles in the eyes may cause irritation and smarting.

Stone Boulders

Flopetrol Well

Barrier


21.1 %

Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.

11.1 Information on toxicological effects:

Acute toxicity: Not classified.

Skin corrosion/irritation: Not classified. Serious eye damage/irritation: Not classified. Respiratory or skin sensitisation: Not classified. Germ cell mutagenicity: Not classified.

Yes

IS FLR H10 Lamberti

Natural polymer derivative in hydro/glycolic

solution

0.9 %

8.1. Control parameters Ethylene glycol US - ACGIH (TLV) - STEL(15 min.): C 100 ppm - Notes: A4 UK - EH40/2005 (WEL) - LTE(8h): 10 ppm - Notes: Skin; Particulate

DE - TRGS 900 (MAK) - LTE(8h): 26 mg/m3, 10 ppm - STEL(15 min.): 52 mg/m3, 20 ppm - Notes: Particulate and Vapour. IT - D. 6 agosto 2012 (Valore limite) - LTE(8h): 52 mg/m3, 20 ppm - STEL(15

min.): 104 mg/m3, 40 ppm - Notes: Skin; Vapour. EU - Dir. 2000/39/CE (ILV) - LTE(8h): 52 mg/m3, 20 ppm - STEL(15 min.): 104 mg/m3, 40 ppm - Notes: Skin; Vapour. UK - EH40/2005 (WEL) - LTE(8h): 52 mg/m3, 20 ppm - STEL(15 min.): 104 mg/m3, 40 ppm - Notes: Skin; Vapour. FR - VLEP - LTE(8h): 52 mg/m3, 20 ppm - STEL(15 min.): 104 mg/m3, 40 ppm - Notes: Vapour.

DNEL Exposure Limit Values

Ethylene glycol Worker Industry: 35 mg/m3 - Worker Professional: 35 mg/m3 - General population: 7 mg/m3 - Frequency: Long Term, local effects Human Inhalation Worker Industry: 106 mg/kg - Worker Professional: 106 mg/kg - General population: 53 mg/kg - Frequency: Long Term, systemic effects Human Dermal

PNEC Exposure Limit Values Ethylene glycol

Yes

On PLONAR List

Natural Product


(%)


11.1. Information on toxicological effects Toxicological information of the mixture: a) acute toxicity:Toxicity Oral Rat LD50> 2000 mg/kg - Calculated data. b) skin corrosion/irritation:

Irritation Skin: repeated and prolonged contacts may cause slight irritation. c) serious eye damage/irritation:

Irritation Eye: repeated and prolonged contacts may cause slight irritation. i) STOT-repeated exposure:May cause damage to organs through prolonged or repeated exposure. Toxicological information of the main substances found in the mixture: Ethylene glycol

a) acute toxicity:Toxicity Oral Rat LD50= 7712 mg/kg - Literature data. Toxicity Inhalation Rat LC50 > 2.5 mg/l - Duration: 6h - Literature data. Toxicity Skin Mouse LD50> 3500 mg/kg - Literature data. Toxicity Oral: harmful. - Duration: > 90 days. - Literature data. b) skin corrosion/irritation:

Irritation Skin Rabbit: Not irritant. - Literature data.

c) serious eye damage/irritation:Irritation Eye Rabbit: Not irritant. - Duration: 24h - Literature data. d) respiratory or skin sensitisation:Guinea pig maximization test Skin Guinea pig: Not sensitizing. - Literature data. e) germ cell mutagenicity:OECD 474 Mouse: Not mutagenic. - Literature data.

i) STOT-repeated exposure:Repeated dose effects. Oral Rat NOAEL = 150 mg/kg - Duration: > 90 days. Literature data. - Notes: STOT - Kidneys.

12.1. Toxicity

Ecological information of the mixture: a) Aquatic acute toxicity:Data not available. Ecological information of the main substances found in the mixture: Ethylene glycol

a) Aquatic acute toxicity:EPA Guideline Fish LC50 = 72860 mg/l - Duration h: 96 - Notes: Literature data.


(%)


OECD 202 Daphnia magna EC50 > 100 mg/l - Duration h: 48 - Notes: Literature data. 12.2. Persistence and degradability Ecological information of the mixture: Biodegradability: Data not available.

Ecological information of the main substances found in the mixture: Ethylene glycol

Biodegradability: Readily biodegradable - Test: OECD 301 A - Duration: 10 days: 90% - Notes: Literature data. 12.3. Bioaccumulative potential Ecological information of the mixture: Bioaccumulation: Data not available.

Ecological information of the main substances found in the mixture: Ethylene glycol Bioaccumulation: Not bioaccumulative - Test: BCF - Bioconcentrantion factor 10 - Duration: 72h - Notes: Literature data. 12.4. Mobility in soil Ecological information of the mixture:

Mobility in soil: Data not available.

Ecological information of the main substances found in the mixture: Ethylene glycol Mobility in soil: Very high - Test: Koc: 1 - Notes: Calculated data (in silico). 12.5. Results of PBT and vPvB assessment vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects

None Use according to criteria of good industrial practice, avoiding product dispersion in the environment.

IS 3116 Lamberti Polymeric

solution 3.8 %

8.2. Exposure controls

Eye protection: Use close fitting safety goggles. (ref. EN 166, EN 140, EN175). Protection for skin: No special precaution must be adopted for normal use.

Protection for hands: Chemical protective gloves should not be needed when handling this material. Consistent with general hygienic practice for any material, skin contact should be

Yes


(%)


minimized. In case of prolonged contact, the use of protective gloves is recommended, providing comprehensive protection to chemicals (refer to EN 374). Respiratory protection: Use respiratory protection where ventilation is insufficient or exposure is

prolonged, e.g. (ref. EN 136, EN 140, EN 141, EN 143, EN 149, EN 405). Thermal Hazards:

None Environmental exposure controls: None Appropriate engineering controls: None

11.1. Information on toxicological effects Toxicological information of the mixture:

a) acute toxicity:Toxicity Oral Rat LD50> 2000 mg/kg - Based on components. b) skin corrosion/irritation:

Irritation Skin: repeated and prolonged contacts may cause slight irritation. c) serious eye damage/irritation:Irritation Eye: repeated and prolonged contacts may cause slight irritation.

Use according to criteria of good industrial practice, avoiding product dispersion in the environment.

12.1. Toxicity Ecological information of the mixture: a) Aquatic acute toxicity:

EC50/LC50 > 100 mg/l - aquatic species (Lamberti internal data). 12.2. Persistence and degradability

Ecological information of the mixture: Biodegradability: Readily biodegradable. - Test OECD 306: > 60% - Lamberti internal data. 12.3. Bio accumulative potential Ecological information of the mixture:

Bioaccumulation: Data not available. 12.4. Mobility in soil


(%)


Ecological information of the mixture: Mobility in soil: Data not available. 12.5. Results of PBT and vPvB assessment vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects

None Use according to criteria of good industrial practice, avoiding product dispersion in

the environment.

Total 100%

4.3 Chemical List

Chemicals within products in part 2 CAS Number

Mass

Fraction

(%)

Silicon dioxide, crystalline 14808-60-7 62.4 %

Water 7732-18-5 14.8 %

Silicon dioxide, amorphous 69012-64-2 12.7 %

Feldspar, crystalline 68476-25-5 6.4 %

Mica, crystalline 12001-26-2 2.6 %

Polycarboxylic acid 30915-61-8 0.69 %

1,2 Ethanediol (Ethylene glycol) 107-21-1 0.24 %

Hydroxyethyl cellulose, 2-Hydroxyetethyl ether cellulose 9004-62-0 0.17%

Total 100.0

5.1 System Details:

Operator:

Project / Well:

System:

Total Volume of System (m3):

Chevron

TVI

PlugCem + Tuned Spacer

15.581 m^3 (98 bbls)

5.2 Product List

Trade name Supplier Purpose Mass % of

Total Ecotoxicity Info MSDS Attached

Customer Supplied Mix Water Customer To Mix Fluids 37.8% No Hazard No

Cement - Class G Halliburton Cement 31.9%

PRODUCT CEFAS LISTED

100% PLONOR

CONSTITUENT 1 (≤100%):

LD50 Oral: >2000 mg/kg (Rat), LD50 Dermal: >2000 mg/kg, LC50 Inhalation: >1.0 mg/L (4h) (Rat)

After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000)

Static Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L

Static Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L

Static Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L

Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics

Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics

Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics


LD50 Oral: >15000 mg/kg (human)

Freshwater Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance);

Freshwater Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance);



Carcinogenicity: Classified as a human carcinogen (IARC Group 1)

Yes

Barite Halliburton Weighting Agent 17.2%


100% PLONOR


Oral LD50: >5000 mg/kg (Rat), Oral LD50: >3000 mg/kg (Mouse), Inhalation LC50: >1.1 mg/L (Rat, Aerosal, 4h) (similar substance

Freshwater Algae Toxicity 72h EC50: > 61.1 mg/L (Pseudokirchneriella subcapitata) [ECHA];

Freshwater Crustacean Toxicity 48h LC50: 14.5 mg/L (Daphnia magna) [ECHA] (similar substance);

Freshwater Fish Toxicity 96h LC50: > 3.5 mg/L (Danio rerio) [ECHA];

No Marine Data

Marine sub-chronic Crustacean Toxicity NOEC (7d) 100 mg/L (Cancer anthonyi)

Bioaccumulation Fish BCF: 1.2-74.4 (Lepomis macrochirus) [ECHA];



LD50 Oral: >15000 mg/kg (human)


Freshwater Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance);

Marine Water Algae Toxicity 72h EC50: 4717 mg/L (Skeletonema costatum)

Marine Water Crustacean Toxcity 48h LC50: 7713 mg/L (Acartia tonsa)

Marine Water Fish Toxicity 96h LC50: > 4200 mg/L (Scophthalmus maximus) [Halliburton Sponsored Study];




Yes

TUNED SPACER E+ Halliburton Mud/Cement Spacer 3.9%

PRODUCT CEFAS LISTED, 100% PLONOR

CONSTITUENT 1 (≤100%): Component is naturally occuring and not intrinsically hazardous.

Freshwater Algae Toxcity 72h EC50: 440 mg/L (Pseudokirchneriella subcapitata)

Freshwater Crustacean Toxcity 48h EC50: > 100 mg/L (Daphnia magna)

Freshwater Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio)


Oral LD50: >15000 mg/kg (Human)

Freshwater Algae Toxicity 72h EC50: 440 mg/L (Pseudokirchneriella subcapitata) (similar substance) Freshwater

Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater

Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance);

Marine Water Algae Toxicity 72h EC50: 4717 mg/L (Skeletonema costatum)

Marine Water Crustacean Toxcity 48h LC50: 7713 mg/L (Acartia tonsa)

Marine Water Fish Toxicity 96h LC50: > 4200 mg/L (Scophthalmus maximus) [Halliburton Sponsored Study];

Bioaccumulation/Biodegradation: Substance is inorganic - bioaccumulation/biodegradation is not applicable.



Oral LD50: >15000 mg/kg (Human) (Similar Substance)



Fish Toxicity 96h LC50: 5000 mg/L (Danio rerio) (similar substance) Bioaccumulation/Biodegradation:

Substance is inorganic - bioaccumulation/biodegradation is not applicable.


Oral LD50: >15000 mg/kg (Human) (Similar Substance)



Fish Toxicity 96h LC50: 5000 mg/L (Danio rerio) (similar substance) Bioaccumulation/Biodegradation:

Substance is inorganic - bioaccumulation/biodegradation is not applicable.


Oral LC50: >5000 mg/L, Inhalation LC50: > 480 mg/m3

Freshwater Algae Toxicity LC50: >600 mg/L (Scenedesmus subspicatus)

Freshwater Crustacean Toxicity 48h EC50: > 2100 mg/L (Daphnia magna);

Freshwater Fish Toxicity 48h LC50: 7300 mg/L (Oncorhynchus mykiss) [US EPA ECOTOX];

Freshwater Fish Toxicity LC50: >1000 mg/L (Danio rerio)

Marine Water Algae Toxicity 72h EC50: 301 mg/L (Skeletonema costatum) [Halliburton Funded Study];

Marine Water Crustacean Toxicity 48h LC50: 1261 mg/L (Acartia tonsa) [Halliburton Funded Study];

Bioaccumulation Log Kow: -3.45 [EPISUITE] (similar substance);

Freshwater Biodegradation 10d: 29 % [US EPA HPV Haz. Char. Doc.] (similar substance);

CONSTITUENT 6 (≤10%): Natural product

Yes

Latex 2000 Halliburton Cement expanding

Additive 2.9%


Marine Water Algae Toxicity 72h EC50: 151.688 mg/L (Skeletonema costatum) [Halliburton Funded Study];

Marine Water Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study];

Bioaccumulation Log Pow: -1.6-3.5 [Halliburton Funded Study];

Marine Water Biodegradation 28d: 6.84% [Halliburton Funded Study];

Toxicology - contains no hazardous substances in concentrations above cut-off values according to the

Yes

Versaset Halliburton Accelerator 1.6%

competent authority

CONSTITUENT 1 (≤ 100%):

Substance not expected to exhibit toxic effects in the aquatic environment due to low solubility in transformation/dissolution assays.

Freshwater Algae Toxicity 72h EC50: 0.0169 mg/L (Pseudokirchnerella subcapitata) [ECHA];

Freshwater Crustacean Toxicity 48h LC50: 2.3 mg/L (Ceriodaphnia sp.) [ECHA];

Freshwater Fish Toxicity 64hr LD50: 0.2 mg/L (Oncorhynchus mykiss) [Peer Reviewed Journal];

Bioaccumulation BCF: 215 [US ATSDR];


CONSTITUENT 2 (≤ 10%):

No Hazard

Toxicology - Sodium aluminate - LD50 Oral - >2000mg/kg (Rate) (Similar substance)

Yes

Halad-413L Halliburton Fluid Loss Additive 1.3%



Oral LD50: >2000 mg/kg (Rat)

Marine Water Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) [OSPAR];

Marine Water Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [OSPAR];

Marine Water Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [OSPAR];

Bioaccumulation Log Kow: < 3.5 [Halliburton Funded Study];

Marine Water Biodegradation 28d: 6 % [Halliburton Funded Study];


Product is naturally occuring and not intrinsically hazardous

No data available to indicate product or components present at greater than 0.1% are chronic health hazards

Yes

Gascon 469 Halliburton Cement Additive

Stabiliser 0.8%


100% PLONOR

CONSTITUENT 1 <=1%

Oral LDL: 500 mg/kg (Rabbit), Dermal LD50: 1350 mg/kg (Rabbit)

Freshwater Crustacean Toxicity 48h EC50: 40.4 mg/L (Ceriodaphnia sp.) [ECHA];

Freshwater Fish Toxicity 96h LC50: 45.4 mg/L (Oncorhynchus mykiss) Freshwater

Fish Toxicity 96h LC50: 125 mg/L (Gambusia affinis) [OECD SIDS];



CONSTITUENT 2 <=60%

Oral LD50: >10,000 mg/kg, Inhalation LC50: >0.69 mg/L (4h) (Rat)

Freshwater Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum) [IUCLID; LOLI];

Freshwater Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia) [IUCLID; LOLI];

Freshwater Fish Toxicity 96h LC50: 5000 mg/L (Brachydanio rerio) [IUCLID; LOLI];



CONSTITUENT 3 <= 100%

Product is naturally occurring and not intrinsically hazardous

Yes

DCA-22001 Halliburton Cleaner 0.6%



LD50 Oral: 1400 mg/kg (Rat), LD50 Dermal 1.78 mL/kg (Rabbit)

Freshwater Algae Toxicity EC50 (72h): 0.5 mg/L (Scenedesmus subspicatus) (Similar substance)

New Zealand CCID cites algae study (Selenastrum capricornutum) EC50=0.7 mg/L

Freshwater Crustacean Toxicity EC50 (48h): 0.5 - 1.9 mg/L (Similar substance)

New Zealand CCID cites daphnia study with EC50=0.39 mg/L from Warne, 1999.

Freshwater Fish Toxicity LC 50 (96h) 1.2 - 6.4 mg/L (Brachydanio rerio) (Similar substance)

Marine Water Algae Toxicity 72h EC50: 0.25 mg/L (Skeletonema costatum);

Marine Water Crustacean Toxicity 48h LC50: 2.27 mg/L (Acartia tonsa);

Marine Water Fish Toxicity 96h LC50: 7.8 mg/L (Scophthalmus maximus)

Not Bioaccumulative; LogPow 1.12

Readily biodegradable (100% @ 28d)


Component is naturally occuring and not intrinsically hazardous


Oral LD50: 5840 mg/kg (Rat), Dermal LD50: 12870 mg/kg (Rabbit), Inhalation LC50: 72.6 mg/L (Rat) 4h Vapor

Freshwater Algae Toxicity 72h EC50: > 1000 mg/L (Scenedesmus subspicatus) [IUCLID];

Freshwater Crustacean Toxicity 24h EC50: > 10000 mg/L (Daphnia magna) [ECHA];

Freshwater Fish Toxicity 96h LC50: 9640 mg/L (Pimephales promelas) [ECHA];

Marine Water Fish Toxicity 96h LC50: 9640 mg/L (Pimephales promelas);

Marine Water Crustacean Toxicity 48h LC50: 1400 mg/L (Crangon crangon);

Marine Water Algae Toxicity 72h EC50: >1000 mg/L (Scenedesmus subspicatus);

Bioaccumulation Log Pow: 0.15 [IUCLID]; LogKow < 4.5


Freshwater Biodegradation 14d: 83% [HSDB];

Yes

SteelSeal 100 Halliburton Loss circulation material 0.6%


Oral LD50: >5000 mg/kg (Rat)

Dermal LD50: >2000 mg/kg (Rat)

Inhalation LC50: >37.8 mg/L (Rat)

Algae toxicity EC50: >10000 mg/L (Skeletonema costatum)

Fish toxicity LC50: >10000 (Cyprinodon variegatus)

Crustacean toxicity EC50: >10000 mg/L (Acartia tonsa)

Substance is inorganic - bioaccumulation is not applicable

Substance is inorganic - biodegradation is not applicable

No data available to indicate product or components present at greater than 0.1% are chronic health hazards"

Yes

Super CBL Additive Halliburton Cement Additive 0.5% PRODUCT CEFAS LISTED Yes EC50 (72hr): 448.05mg/L (Skeletonema costatum, LC50 (48hr): 2.47 mg/L (Arcatia tonsa)

5.3 Chemical List

hazards

Chemical Name CAS Number Mass %

Customer Supplied Mix Water Not Applicable 38.0%

Portland cement 65997-15-1 30.5%

Barium Sulfate 7727-43-7 16.4%

Water in Products 7732-18-5 3.49%

Crystalline silica, quartz 14808-60-7 2.58%

Bentonite 1302-78-9 2.38%

Styrene / 1,3 Butadiene copolymer 9003-55-8 1.43%

Sodium Lignosulfonate 8061-51-6 1.30%

Sodium aluminate 1302-42-7 1.05%

Calcined Petroleum coke 64743-05-1 0.566%

Aluminum 7429-90-5 0.468%

Humic acids, sodium salts, polymers with N,N-dimethyl-2-

propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1-

propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-

473268-27-8 0.382%

Silica, amorphous - fumed 7631-86-9 0.320%

Alcohols, C12-16, ethoxylated 68551-12-2 0.238%

Polyethylene glycol (C6-C10) alkyl ether, sulfate ammonium salt 68037-05-8 0.213%

Welan gum 72121-88-1 0.198%

Isopropanol 67-63-0 0.190%

Acrylic acid polymer with sodium AMPS, sodium salt 37350-42-8 0.0809%

Rape Oil 8002-13-9 0.0772%

Crystalline silica, cristobalite 14464-46-1 0.0396%

Crystalline silica, tridymite 15468-32-3 0.0396%

Sodium dicyclohexyl sulfosuccinate 23386-52-9 0.0323%

Sorbitan, mono-9-octadecenoate, (Z) 1338-43-8 0.0246%


Sodium hydroxide 1310-73-2 0.0173%

Monopropylene glycol monooleate 1330-80-9 0.00439%

Ammonium hydroxide 1336-21-6 0.00291%

Aluminium stearate 637-12-7 0.000877%

Sorbitan, monopalmitate 26266-57-9 0.000877%

2-Bromo-2-(bromomethyl)pentanedinitrile 35691-65-7 0.000203%

FD&C Blue 1 3844-45-9 0.000203%

Total ~100%

SEM-8 Halliburton Emulsifier 0.4%


Oral LD50: >2000 mg/kg (Rat) (Similar Substance), Dermal LD50: >2000 mg/kg (Rat) (Similar Substance)

Marine Water Algae Toxicity 72h EC50: 32 mg/L (Selenastrum capricornutum) [Madsen et al., 2002] (similar substance);

Freshwater Algae Toxicity 72h ErC50: 32 mg/L (Pseudokirchneriella subcapitata) (similar substance)

Freshwater Crustacean Toxicity 96h EC50: 1.17 mg/L (Daphnia magna) [Madsen et al., 2002] (similar substance);

Freshwater Fish Toxicity 96h LC50: 1-2.5 mg/L (Salmo trutta) [Madsen et al., 2002] (similar substance);

Marine Water Algae Toxicity 72h EC50: 73.52 mg/L (Skeletonema costatum)

Marine Water Crustacean Toxicity LC50 (48h) 232.5 mg/L (Acartia tonsa)

Marine Water Fish Toxicity LC50 (96h) 350 mg/L (Scophthalmus maximus)

Not Bioaccumulative; LogPow 0.7

Marine Water Biodegradation 28d: 61% [OSPAR];


Oral LD50: 5840 mg/kg (Rat), Dermal LD50: 12870 mg/kg (Rabbit), Inhalation LC50: 72.6 mg/L (Rat) 4h Vapor

Freshwater Algae Toxicity 72h EC50: > 1000 mg/L (Scenedesmus subspicatus) [IUCLID];

Freshwater Crustacean Toxicity 24h EC50: > 10000 mg/L (Daphnia magna) [ECHA];

Freshwater Fish Toxicity 96h LC50: 9640 mg/L (Pimephales promelas) [ECHA];

Marine Water Fish Toxicity 96h LC50: 9640 mg/L (Pimephales promelas);

Marine Water Crustacean Toxicity 48h LC50: 1400 mg/L (Crangon crangon);

Marine Water Algae Toxicity 72h EC50: >1000 mg/L (Scenedesmus subspicatus);

Bioaccumulation Log Pow: 0.15 [IUCLID]; LogKow < 4.5


Freshwater Biodegradation 14d: 83% [HSDB];


No Hazard - Product is naturally occuring


Oral LD50: 600 mg/kg (Rat) (Similar Substance), Dermal LD50: >2000 mg/kg (Rat) Similar Substance

Freshwater Algae Toxicity 96h EC50: 0.7 mg/L (Selenastrum capricornutum) [CCID] (similar substance);

Freshwater Crustacean Toxicity 48h EC50: 0.2 mg/L (Daphnia magna) (similar substance);

Freshwater Crustacean Toxicity 48h EC50: 0.39 mg/L (Ceriodaphnia dubia) [CCID] (similar substance);

Freshwater Fish Toxicity 96h LC50: 1.4 mg/L (Pimephales promelas) [CCID] (similar substance);

No Marine Data

Not Bioaccumulative

Bioaccumulation BCF: 12.7-237 [ECHA] (similar substance);

Freshwater Biodegradation 28d: 72% [ECHA] (similar substance);


Yes

HR-6L Halliburton Cement Retarder 0.3%


100% PLONOR


Componenet is naturally occuring and is not intrisically hazardous


Oral LC50: >5000 mg/L, Inhalation LC50: > 480 mg/m3

Freshwater Fish Toxicity LC50: >1000 mg/L (Danio rerio)


Marine Water Crustacean Toxicity 48h LC50: 1261 mg/L (Acartia tonsa) [Halliburton Funded Study];

Bioaccumulation Log Pow: -3.45 (Calculated) [Halliburton Funded Study];

Biodgradation: No data - expected to be inherently biodegradable


Yes

SCR-100L Halliburton Cement Retarder 0.2%


PRODUCT DATA

Oral Toxicity LD50: >5000 mg/kg (Rat), Dermal LD50 : >2000 mg/kg (Rabbit)

Freshwater Fish Toxicity 96h LC50: 4900 mg/L (Oncorhynchus mykiss)

Freshwater Crustacean Toxicity 48h LC50: 2800 mg/L (Daphnia magna)

Marine Water Algae Toxicity 72h EC50: > 3300 mg/L (Skeletonema costatum) [Halliburton Funded Study];

Marine Water Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [Halliburton Funded Study];

Marine Water Fishn Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study];

Marine Water Biodegradation 28d: 14% [Halliburton Funded Study];

Product was tested using OECD 117 no peaks detected MW>700Da. Product is not expected to be bioaccumulating


Yes

NF-6 Halliburton Reduces air entrainment

into cement slurry 0.1%

PRODUCT DATA


Marine Water Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton Funded Study];

Marine Water Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study];

Marine Water Biodegradation 28d: 70% [Halliburton Funded Study];

CONSTITUENT 1 (≤10%)

Marine Algae Toxicity 72h EC50: 991.02 mg/L (Skeletonema costatum)

Marine Crustacean Toxicity 48h LC50: 2500 mg/L (Acartia tonsa);

Marine Fish Toxicity 96h LC50: >3200 mg/L (Scophthalmus maximus);

Bioaccumulation: Calculated Log Pow: 7.45

Acute Mammalian Tocixity - no data, Chronic toxicity - no known carcinogenic properties or chronic

impacts


Oral LD50: >15900 mg/kg (Mouse), Inhalation LC50: >5 mg/L (4h) (Rat)

Marine Algae Toxicity 72h EC50: 41 mg/L (Skeletonema costatum)

Marine Crustacean Toxicity 48h LC50: >10000 mg/L (Acartia tonsa);




Oral LD50: > 5000 mg/kg (Rat), Dermal LD50: >5000 mg/kg (Guinea Pig)

Marine Algae Toxicity 72h EC50: 6488.87 mg/L (Skeletonema costatum)

Marine Crustacean Toxicity 48h LC50: 5085.71 mg/L (Acartia tonsa);


Bioaccumulation: Calculated Log Pow: 22.69 (MW>700)


No Hazard Product is naturally occuring


Oral LD50: 90 mg/kg (Mouse) (Similar Substance)

Marine Algae Toxicity 72h EC50: >3200 mg/L (Skeletonema costatum)

Marine Crustacean Toxicity 48h LC50: >10000 mg/L (Acartia tonsa);



Yes

Total Fluid 100.0% No data available to indicate product or componetns present at greater than 0.1% are chronic health

5.5 Product List

Trade name Supplier Purpose Mass % of Total Ecotoxicity Info MSDS Attached

Customer Supplied Mix Water Customer To Mix Fluids 38.0% No Hazard No

Cement - Class G Halliburton Cement 24.4%


100% PLONOR CONSTITUENT

1 (≤100%):

LD50 Oral: >2000 mg/kg (Rat), LD50 Dermal: >2000 mg/kg, LC50 Inhalation: >1.0 mg/L (4h) (Rat) After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Aquatic Toxicity - Freshwater and Marine Algae:- 72 hour EC50: >1,000 mg/L Static Aquatic Toxicity -Freshwater and Marine Invertebrates:- 48 hour LC50: >1,000 mg/L Static Aquatic Toxicity- Freshwater and Marine Fish:- 96 hour LC50: >1,500 mg/L Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics CONSTITUENT

2 (≤10%):

LD50 Oral: >15000 mg/kg (human) Freshwater Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance);

Freshwater Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation:

Substance is inorganic - bioaccumulation is not applicable.

Biodegradation: Substance is inorganic - biodegradation is not applicable. Carcinogenicity: Classified as a human carcinogen (IARC Group 1)

Yes

Barite Halliburton Weighting Agent 16.9%


100% PLONOR CONSTITUENT

1 (≤100%):

Oral LD50: >5000 mg/kg (Rat), Oral LD50: >3000 mg/kg (Mouse), Inhalation LC50: >1.1 mg/L (Rat, Aerosal, 4h) (similar substance Freshwater Algae Toxicity 72h EC50: > 61.1 mg/L (Pseudokirchneriella subcapitata) [ECHA]; Freshwater Crustacean Toxicity 48h LC50: 14.5 mg/L (Daphnia magna) [ECHA] (similar substance);

Freshwater Fish Toxicity 96h LC50: > 3.5 mg/L (Danio rerio) [ECHA]; No Marine Data

Marine sub-chronic Crustacean Toxicity NOEC (7d) 100 mg/L (Cancer anthonyi)

Bioaccumulation Fish BCF: 1.2-74.4 (Lepomis macrochirus) [ECHA]; Biodegradation:

Substance is inorganic - biodegradation is not applicable. CONSTITUENT 2 (≤5%):

LD50 Oral: >15000 mg/kg (human) Freshwater Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Marine Water Algae Toxicity 72h EC50: 4717 mg/L (Skeletonema costatum) Marine Water Crustacean Toxcity 48h LC50: 7713 mg/L (Acartia tonsa) Marine Water Fish Toxicity 96h LC50: > 4200 mg/L (Scophthalmus maximus) [Halliburton Sponsored Study]; Bioaccumulation:

Substance is inorganic - bioaccumulation is not applicable.

Biodegradation: Substance is inorganic - biodegradation is not applicable. Carcinogenicity: Classified as a human carcinogen (IARC Group 1)

Yes

Pozmix A - Class C Flyash Halliburton Light weight cement additive 9.5%

CONSTITUENT 1 (≤100%): Freshwater Algae Toxicity 72h EC10: 1400-2000 mg/L (Scenedesmus subspicatus) [IUCLID]; Freshwater Crustacean Toxicity 24h EC50: 140-2000 mg/L (Daphnia magna) [IUCLID]; Freshwater Fish Toxicity 96h LC50: 120 mg/L (Poecilia reticulata) [ECHA]; Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable.

Biodegradation: Substance is inorganic - biodegradation is not applicable. CONSTITUENT 2

(≤10%):


Freshwater Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation:

Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.

Yes

TUNED SPACER E+ Halliburton Mud/Cement Spacer 3.9%

PRODUCT CEFAS LISTED, 100% PLONOR

Freshwater Algae Toxicity 72h EC50: 440 mg/L (Pseudokirchneriella subcapitata) (similar substance) Freshwater Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Marine Water Algae Toxicity 72h EC50: 4717 mg/L (Skeletonema costatum) Marine Water Crustacean Toxcity 48h LC50: 7713 mg/L (Acartia tonsa) Marine Water Fish Toxicity 96h LC50: > 4200 mg/L (Scophthalmus maximus) [Halliburton

Sponsored Study]; Bioaccumulation/Biodegradation: Substance is inorganic -

bioaccumulation/biodegradation is not applicable. Carcinogenicity: Classified as a human

carcinogen (IARC Group 1) CONSTITUENT 3 (≤1%):

Oral LD50: >15000 mg/kg (Human) (Similar Substance) Freshwater Algae Toxicity 72h EC50: 440 mg/L (Pseudokirchneriella subcapitata) (similar substance) Freshwater Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Fish Toxicity 96h LC50: 5000 mg/L (Danio rerio) (similar substance) Bioaccumulation/Biodegradation: Substance is inorganic - bioaccumulation/biodegradation is not applicable.


Oral LD50: >15000 mg/kg (Human) (Similar Substance) Freshwater Algae Toxicity 72h EC50: 440 mg/L (Pseudokirchneriella subcapitata) (similar substance) Freshwater Crustacean Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Fish Toxicity 96h LC50: 5000 mg/L (Danio rerio) (similar substance) Bioaccumulation/Biodegradation: Substance is inorganic - bioaccumulation/biodegradation is not applicable.

CONSTITUENT 5 (≤30%): Oral LC50: >5000 mg/L, Inhalation LC50: > 480 mg/m3 Freshwater Algae Toxicity LC50: >600 mg/L (Scenedesmus subspicatus) Freshwater Crustacean Toxicity 48h EC50: > 2100 mg/L (Daphnia magna); Freshwater Fish Toxicity 48h LC50: 7300 mg/L (Oncorhynchus mykiss) [US EPA ECOTOX]; Freshwater Fish Toxicity LC50: >1000 mg/L (Danio rerio) Marine Water Algae Toxicity 72h EC50: 301 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean Toxicity 48h LC50: 1261 mg/L (Acartia tonsa) [Halliburton Funded Study]; Bioaccumulation Log Kow: -3.45 [EPISUITE] (similar substance); Freshwater Biodegradation 10d: 29 % [US EPA HPV Haz. Char. Doc.] (similar substance);


Component is naturally occuring and not intrinsically hazardous.

Yes

Latex 3000 Halliburton Cement Expanding Additive 2.2%

PRODUCT CEFAS LISTED CONSTITUENT

1 (≤ 60%):

Marine Fish Toxicity LC50 96h: >1000 mg/L (Cyprinodon variegatus)

CONSTITUENT 2 (≤ 60%): No Hazard CONSTITUENT 3 (≤ 0.1%):

Freshwater Fish Toxicity 48h LC50: > 1,000 mg/L [Catalyst Partners SDS]; CONSTITUENT

4 (≤ 0.1%):

Freshwater Algae Toxicity 72 h EC50: 4.9 mg/L (Selenastrum capricornutum); Freshwater Crustacean Toxicity 48 h EC50: 4.7 mg/L (Daphnia magna); Freshwater Fish Toxicity 96 h LC50: 4.02 mg/L (Fathead minnow [Pimephales promelas]);

Source: OECD SIDS CONSTITUENT 5 (≤ 0.1%):

Freshwater Crustacean Toxicity 96h EC50: 34.8 mg/L (Daphnia magna); Marine Fish Toxicity 24 h LC50: 71.5 mg/L (Lagodon rhomboides); Bioaccumulation BCF: 13 Acute toxicity (amorphouse silica): Fish LC50 (96hr): 97,811 mg/L (fish – estimated) Crustacean EC50 (48hr): 16,552 mg/L (Daphnia magna – estimated) Chronic toxicity : No known carcinogenic properties or chronic impacts. Biodegradation / bioaccumulation: No specific studies undertaken to date.

Yes

Microbond M Halliburton Expander 1.9%

CONSTITUENT 1 (≤100%) No data was available in the IUCLID for this component, as magnesium ions are a major component of all natural waters.

Source: IUCLID 2000 – Note previously approved by DMIRS with this information.


Toxicity to Algae 72 h EC50: 5131.54 mg/L (Skeletonema Costatum) Toxicity to Crustacean 48 hr LC50: ≥10,000 mg/L (Acartia tonssa) Toxicity

to Fish 96 Hr LC50: ≥320 mg/L (Scophthalmus maximus)

Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable Biodegradation: Substance is inorganic - bioaccumulation is not applicable

Source: HESI Internal Data CONSTITUENT 3 (≤1%)

Freshwater Crustacean Toxicity 48h EC50: > 100 mg/L (Daphnia magna) [ECHA]; Freshwater

Fish Toxicity 48h LC0: 1000 mg/L (Leuciscus idus) [ECHA];

Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable. Biodegradation:

Substance is inorganic - biodegradation is not applicable

CONSTITUENT 4 (≤5%) Toxicity to Algae 72 h EC50 184.57 mg/L (Psuedokirchnerella subcapitata)(Similar Substance) Toxicity

to Fish LC50 33.884 mg/L(Clarias gariepinus)

Toxicity to Microorganisms EC50 (3h) 300.4 mg/L (activated sludge) (similar substances) Toxicity to Invertebrates EC50 (48h) 49.1 mg/L (Daphnia magna) (similar substance) Bioaccumulation: Log Kow=-0.571 BCF = 0.5 Biodegradadation: Substance is inorganic - bioaccumulation is not applicable CONSTITUENT 5 (≤5%) Invertebrates Toxicity 24h LL50: > 10000 mg/L (Daphnia magna) [Health Canada] (similar substance);

Fish Toxicity 96h LL0: 10000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation:

Substance is inorganic - bioaccumulation is not applicable. Biodegradation: Substance is inorganic - biodegradation is not applicable.

Yes

DCA-22001 Halliburton Cleaner 0.6%

PRODUCT CEFAS LISTED CONSTITUENT

1 (≤60%):

LD50 Oral: 1400 mg/kg (Rat), LD50 Dermal 1.78 mL/kg (Rabbit) Freshwater Algae Toxicity EC50 (72h): 0.5 mg/L (Scenedesmus subspicatus) (Similar substance) New Zealand CCID cites algae study (Selenastrum capricornutum) EC50=0.7 mg/L

Freshwater Crustacean Toxicity EC50 (48h): 0.5 - 1.9 mg/L (Similar substance) New

Zealand CCID cites daphnia study with EC50=0.39 mg/L from Warne, 1999.

Freshwater Fish Toxicity LC 50 (96h) 1.2 - 6.4 mg/L (Brachydanio rerio) (Similar substance) Marine Water Algae Toxicity 72h EC50: 0.25 mg/L (Skeletonema costatum); Marine

Water Crustacean Toxicity 48h LC50: 2.27 mg/L (Acartia tonsa);

Marine Water Fish Toxicity 96h LC50: 7.8 mg/L (Scophthalmus maximus) Not Bioaccumulative; LogPow 1.12 Readily

biodegradable (100% @ 28d)


Component is naturally occuring and not intrinsically hazardous CONSTITUENT

3 (≤30%):

Oral LD50: 5840 mg/kg (Rat), Dermal LD50: 12870 mg/kg (Rabbit), Inhalation LC50: 72.6 mg/L (Rat) 4h Vapor Freshwater Algae Toxicity 72h EC50: > 1000 mg/L (Scenedesmus subspicatus) [IUCLID]; Freshwater Crustacean Toxicity 24h EC50: > 10000 mg/L (Daphnia magna) [ECHA]; Freshwater Fish Toxicity 96h LC50: 9640 mg/L (Pimephales promelas) [ECHA]; Marine Water Fish Toxicity 96h LC50: 9640 mg/L (Pimephales promelas); Marine Water Crustacean Toxicity 48h LC50: 1400 mg/L (Crangon crangon); Marine Water Algae Toxicity 72h EC50: >1000 mg/L (Scenedesmus subspicatus); Bioaccumulation Log Pow: 0.15 [IUCLID]; LogKow < 4.5 Readily biodegradable (53% @ 5d) Freshwater Biodegradation 14d: 83% [HSDB];

Yes

5.4 System Details:

Operator: Chevron

Project / Well: TVI

System: PlugCem + Tuned Spacer

Total Volume of System (m3): 15.581 m^3 (98 bbls)

Gascon 469 Halliburton Cement Additive Stabiliser 0.6%

PRODUCT CEFAS LISTED 100% PLONOR CONSTITUENT 1 <=1% Oral LDL: 500 mg/kg (Rabbit), Dermal LD50: 1350 mg/kg (Rabbit) Freshwater Crustacean Toxicity 48h EC50: 40.4 mg/L (Ceriodaphnia sp.) [ECHA]; Freshwater Fish Toxicity 96h LC50: 45.4 mg/L (Oncorhynchus mykiss) Freshwater Fish Toxicity 96h LC50: 125 mg/L (Gambusia affinis) [OECD SIDS];


Substance is inorganic - biodegradation is not applicable.

CONSTITUENT 2 <=60% Oral LD50: >10,000 mg/kg, Inhalation LC50: >0.69 mg/L (4h) (Rat) Freshwater Algae Toxicity 72h EC50: 440 mg/L (Selenastrum capricornutum) [IUCLID; LOLI]; Freshwater Crustacean Toxicity 48h EC50: 7600 mg/L (Ceriodaphnia dubia) [IUCLID; LOLI];

Freshwater Fish Toxicity 96h LC50: 5000 mg/L (Brachydanio rerio) [IUCLID; LOLI];



CONSTITUENT 3 <= 100% Product is naturally occurring and not intrinsically hazardous

Yes

SteelSeal 100 Halliburton Loss circulation material 0.6%

PRODUCT CEFAS LISTED Oral LD50: >5000 mg/kg (Rat) Dermal LD50: >2000 mg/kg (Rat) Inhalation LC50: >37.8 mg/L (Rat) Algae toxicity EC50: >10000 mg/L (Skeletonema costatum) Fish toxicity LC50: >10000 (Cyprinodon variegatus) Crustacean toxicity EC50: >10000 mg/L (Acartia tonsa) Substance is inorganic - bioaccumulation is not applicable Substance is inorganic - biodegradation is not applicable No data available to indicate product or components present at greater than 0.1% are chronic health hazards"

Yes

PhenoSeal Halliburton Lost Circulation Control 0.5%

PRODUCT CEFAS LISTED Marine Water Algae Toxicity 72h EC50: 626.57 mg/L (Skeletonema costatum) [OSPAR]; Marine Water Crustacean Toxicity 48h LC50: > 10000 mg/L (Acartia tonsa) [OSPAR]; Marine Water Fish Toxicity 96h LC50: > 3200 mg/L (Scophthalmus maximus) [OSPAR]; Bioaccumulation Log Pow: -1.71 [OSPAR]; Marine Water Biodegradation 28d: 83% [OSPAR]; No data available to indicate product or components present at greater than 0.1% are chronic health hazards

Yes

WellLife 665 Halliburton Cement Enhancer 0.2%

PRODUCT CEFAS LISTED Marine Water Algae Toxicity 72h EC50: > 10000 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean Toxicity 48h LC50: > 10000 mg/L (Acartia tonsa) [Halliburton Funded Study]; Marine Water Fish Toxicity Limit Test 96h LC50t: > 10000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Bioaccumulation: The molecular weight is well in excess of 700, therefore bioaccumulation is unlikely [Halliburton Funded Study]; Biodegradation: The product showed no potential to biodegrade [Halliburton Funded Study];

Yes

WellLife 734 Halliburton Cement Enhancer 0.2%

PRODUCT CEFAS LISTED 100% PLONOR Product is an inert, man-made substance and not intrinsically hazardous. Is a fine rigid fibrous material (glass fibre), which is chemically inert. As such irritation resulting from contact with this product is by mechanical abrasion. Standard PPE is require to handle the

product to minimise direct exposure from mechanical contact. The irritation from contact with this product was not identified being from a chemical reaction. Acute Crustaceans Toxicity: TLM96: >1,000,000 ppm (Mysidopsis bahia) SPP @ 10 ppb

Yes

SCR-100L Halliburton Cement Retarder 0.2%

PRODUCT CEFAS LISTED PRODUCT DATA Oral Toxicity LD50: >5000 mg/kg (Rat), Dermal LD50 : >2000 mg/kg (Rabbit) Freshwater Fish Toxicity 96h LC50: 4900 mg/L (Oncorhynchus mykiss) Freshwater Crustacean Toxicity 48h LC50: 2800 mg/L (Daphnia magna) Marine Water Algae Toxicity 72h EC50: > 3300 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [Halliburton Funded Study]; Marine Water Fishn Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 14% [Halliburton Funded Study]; Product was tested using OECD 117 no peaks detected MW>700Da. Product is not expected to be bioaccumulating No data available to indicate product or components present at greater than 0.1% are chronic health hazards

Yes

SEM-7 Halliburton Emulsifier 0.3%

CONSTITUENT 1 (≤30%) Oral LD50: 5840 mg/kg (Rat), Dermal LD50: 12870 mg/kg (Rabbit), Inhalation LC50: 72.6 mg/L (Rat) 4h Vapor Freshwater Algae Toxicity 72h EC50: > 1000 mg/L (Scenedesmus subspicatus) [IUCLID]; Freshwater Crustacean Toxicity 24h EC50: > 10000 mg/L (Daphnia magna) [ECHA]; Freshwater Fish Toxicity 96h LC50: 9640 mg/L (Pimephales promelas) [ECHA]; Bioaccumulation Log Pow: 0.15 [IUCLID]; Freshwater Biodegradation 14d: 83% [HSDB]; CONSTITUENT 2 (≤60%) Product is naturally occuring and not intrisically hazardous CONSTITUENT 3 (≤60%) Oral LD50: 4100 mg/kg (Rat), Dermal LD50: >5000 mg/kg (Rabbit) (Similar Substance) Freshwater Algae Toxicity EC50 (72h) 27.7 mg/L (Desmodesmus subspicatus) Freshwater Crustacean Toxicity EC50 (48h) 7.4 mg/L (Daphnia magna) Freshwater Fish Toxicity LC50 (45d) 0.9 mg/L (Pimephales promelas) Biodegradation: Readily biodegradable (81% @ 28d) Bioaccumulation: Log Kow = 1.62


Oral LD50: 4100 mg/kg (Rat) (Similar Substance), Dermal LD50: >5000 mg/kg (Rabbit) (Similar Substance) Freshwater Algae Toxicity EC50 (72h) 27.7 mg/L (Desmodesmus subspicatus) (Similar Substance) Freshwater Crustacean Toxicity EC50 (48h) 7.4 mg/L (Daphnia magna) (Similar Substance) Freshwater Fish Toxicity LC50 (45d) 0.9 mg/L (Pimephales promelas) (Similar substance) Biodegradation: Readily biodegradable (81% @ 28d) (Similar Substance) Bioaccumulation: Log Kow = 1.62 (Similar Substance) CONSTITUENT 5 (≤1%) Freshwater Algae Toxicity 18d EC50: 2700 mg/L (Chlorella vulgaris) Freshwater Crustacean Toxicity 96h EC50: >100 mg/L (Daphnia magna) [OECD SIDS]; Freshwater Fish Toxicity 96h LC50: 173 mg/L (Salmo gairdneri) [OECD SIDS]; Freshwater Fish Toxicity 96h LC50: 53 mg/L (Oncorhynchus mykiss) Marine Water Crustacean Toxicity 96h EC50: 81 - 130 mg/L (Crangon crangon)

Substance is inorganic - biodegradation is not applicable. Substance is inorganic - bioaccumulation is not applicable. No data available to indicate product or componetns present at greater than 0.1% are chronic health hazards

Yes

Halad-344 Halliburton Fluid Loss Additive for high

temperature 0.1%

PRODUCT CEFAS LISTED CONSTITUENT 1 <=100% Marine Water Algae Toxicity EC50: >3300 mg/L (Skeletonema costatum [HES Interal Study] Marine Water Crustacean Toxicity EC50: > 2000 mg/L (Acartia tonsa) [ HES study] Marine Fish Toxicity LC50: >1000 mg/L (Scophthalmus maximus) [ HES study] Bioaccumulation Log Pow: <0 OECD 117 [HES Study] 0% (OECD 306) [HES Study] CONSTITUENT 2 <=5% PLONAR CONSTITUENT 3 <= 5% PLONAR CONSTITUENT 4 <=5% PLONAR Effect concentrations in the aquatic environment are attributable to a change in pH value. Oral LD50: 7340 mg/kg (Rat), Dermal LD50: >2500 mg/kg (Rabbit) Freshwater Crustacean Toxicity 48h EC50: 49.1 mg/L (Daphnia magna) [ECHA]; Freshwater Fish Toxicity 96h LC50: 50.6 mg/L (Oncorhynchus mykiss) [ECHA]; Marine Water Crustacean Toxicity 96h LC50: 158 mg/L (Crangon septemspinosa) [ECHA];



PRODUCT DATA Oral LD50: >2000 mg/kg (similar Product) Marine Water Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Bioaccumulation Log Pow: <0 [Halliburton Funded Study]; Marine Water Biodegradation 28d: 0% [Halliburton Funded Study];

Yes

NF-6 Halliburton Reduces air entrainment into

cement slurry 0.1%

PRODUCT DATA Marine Water Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton Funded Study]; Marine Water Fish Toxicity 96h LC50: > 1000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine

Water Biodegradation 28d: 70% [Halliburton Funded Study];

CONSTITUENT 1 (≤10%) Marine Algae Toxicity 72h EC50: 991.02 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: 2500 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >3200 mg/L (Scophthalmus maximus);

Bioaccumulation: Calculated Log Pow: 7.45 CONSTITUENT 2 (≤5%):

Oral LD50: >15900 mg/kg (Mouse), Inhalation LC50: >5 mg/L (4h) (Rat) Marine Algae Toxicity 72h EC50: 41 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: >10000 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >1800 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 4.28 CONSTITUENT 3 (≤5%) Oral LD50: > 5000 mg/kg (Rat), Dermal LD50: >5000 mg/kg (Guinea Pig) Marine Algae Toxicity 72h EC50: 6488.87 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: 5085.71 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >5600 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 22.69 (MW>700) CONSTITUENT 4 (≤10%) No Hazard Product is naturally occuring CONSTITUENT 5 (≤100%) Oral LD50: 90 mg/kg (Mouse) (Similar Substance) Marine Algae Toxicity 72h EC50: >3200 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: >10000 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >5600 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 7.09 No data available to indicate product or componetns present at greater than 0.1% are chronic health hazards

Yes

Total Fluid 100.0%

5.6 Chemical List

Customer Supplied Mix Water Not Applicable 38.0%

Portland cement 65997-15-1 23.2%

Barium Sulfate 7727-43-7 16.1%

Fly ash 68131-74-8 8.7%

Crystalline silica, quartz 14808-60-7 2.96%

Bentonite 1302-78-9 2.32%

Magnesium oxide 1309-48-4 1.79%

Water in Products 7732-18-5 1.63%

Functionalized Styrene Butadiene Latex 403824-26-0 1.30%

Sodium Lignosulfonate 8061-51-6 1.16%

Calcined Petroleum coke 64743-05-1 0.554%

Blend of Cellulose Paper, Phenolic Resin and Melamine Resin 9004-34-6 9003-35-4 9003-08-1

0.473%

Soda Lime Borosilicate Glass 65997-17-3 0.236%

Styrene / 1,3 Butadiene copolymer 9003-55-8 0.236%

Chemical Name CAS Number Mass %

Total ~100%


Silica, amorphous - fumed 7631-86-9 0.232%

Welan gum 72121-88-1 0.194%

Isopropanol 67-63-0 0.166%

Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-(dodecyloxy)-, ammonium salt 32612-48-9 0.132%

N,N-dimethylacrylamide copolymer with calcium AMPS 103115-52-2 0.0807%

Calcium oxide 1305-78-8 0.0670%

Acrylic acid polymer with sodium AMPS, sodium salt 37350-42-8 0.0609%

Rape Oil 8002-13-9 0.0540%

Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-(tetradecyloxy)-, ammonium salt 27731-61-9 0.0462%

Crystalline silica, cristobalite 14464-46-1 0.0387%

Crystalline silica, tridymite 15468-32-3 0.0387%

Iron oxide 1309-37-1 0.0117%

Sodium hydroxide 1310-73-2 0.00580%

Calcium hydroxide 1305-62-0 0.00474%

Lecithins 8002-43-5 0.00474%

Sodium sulfate 7757-82-6 0.00474%

Aluminum oxide 1344-28-1 0.00340%

Ammonium sulfate 7783-20-2 0.00330%

Monopropylene glycol monooleate 1330-80-9 0.00307%

4-Vinylcyclohexene 100-40-3 0.00216%

Butadiene 106-99-0 0.00216%

Styrene 100-42-5 0.00216%

Aluminium stearate 637-12-7 0.000613%

Sorbitan, monopalmitate 26266-57-9 0.000613%

2-Bromo-2-(bromomethyl)pentanedinitrile 35691-65-7 0.000153%

FD&C Blue 1 3844-45-9 0.000153%

Safety Data SheetBARITE (ALL GRADES)

SDS no. MI11207Version 10Revision date 19/Mar/2015Supersedes date 17/Nov/2014

1. Identification of the substance/preparation and of the Company/undertaking

1.1 Product identifier

Product name BARITE (ALL GRADES)Product code MI11207REACH registration name Exempt Annex V ENTRY 7.Denmark Pr. no.: 1154758

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Weighting agent.

Uses advised against Consumer use

1.3 Details of the supplier of the safety data sheet

1.4 Emergency Telephone Number

Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to (EC) No. 1272/2008

Health hazards Not classified

Environmental hazards Not classified

Physical Hazards Not classified

________________________________________________________________________________________

2.2 Label elements

SupplierM-I Australia Pty LtdABN: 67 009 214 162Level 5256 St. George TcePerthWA 6000T = +61 08 9440 2900F = +61 08 9322 3080+47 51577424

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[email protected]

________________________________________________________________________________________

BARITE (ALL GRADES) SDS no. MI11207Revision date 19/Mar/2015

Signal wordNone

Hazard statementsThis product is not classified as hazardous therefore no (H) hazard statements assigned.

Precautionary Statements - EU (§28, 1272/2008) This product is not classified as hazardous therefore has no (P) precautionary statements assigned.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

Indication of dangerNot classified

ContainsCrystalline silica (impurity)

For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16.

2.3 Other data

Not classified as PBT/vPvB by current EU criteria

Australian statement of hazardous/dangerous natureClassified as Non-Hazardous according to the criteria of NOHSC.NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.

3. Composition/information on ingredients

3.1 Substances

Component EC-No. CAS-No Weight % -range

Classification(67/548)

Classification (Reg.1272/2008)

REACHregistration

numberCrystalline silica

(impurity)238-878-4 14808-60-7 1-5 Xn; R48/20 STOT Rep. 2 - H373 Exempt

3.2 Mixtures

Not Applicable

________________________________________________________________________________________

CommentsThe product contains other ingredients which do not contribute to the overall classification.

This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystallinesilica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such as silicosis. IARC Monographs, Vol.68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form of quartz or cristobalite fromoccupational sources causes cancer in humans. IARC Classification Group I.

4. First aid measures

Page 2 / 11

4.1 First-Aid Measures

________________________________________________________________________________________


Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.

Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms occur.

Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2 Most important symptoms and effects, both acute and delayed

General advice The severity of the symptoms described will vary dependant of the concentration and thelength of exposure. If adverse symptoms develop, the casualty should be transferred tohospital as soon as possible.

Main symptoms

Inhalation Please see Section 11. Toxicological Information for further information.

Ingestion Please see Section 11. Toxicological Information for further information.

Skin contact Please see Section 11. Toxicological Information for further information.

Eye contact Please see Section 11. Toxicological Information for further information.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing mediaUse extinguishing media appropriate for surrounding material.

Extinguishing media which shall not be used for safety reasonsNone known.

5.2 Special hazards arising from the substance or mixture

________________________________________________________________________________________

Unusual fire and explosion hazardsNone known.

Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors.

5.3 Advice for firefighters

Special protective equipment for fire-fightersAs in any fire, wear self-contained breathing apparatus and full protective gear.

Page 3 / 11

Special Fire-Fighting ProceduresContainers close to fire should be removed immediately or cooled with water.

________________________________________________________________________________________


6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. See also section 8. Do not breathe dust.

6.2 Environmental precautions

The product should not be allowed to enter drains, water courses or the soil.

Environmental exposure controlsAvoid release to the environment. Local authorities should be advised if significant spillages cannot be contained.

6.3 Methods and materials for containment and cleaning up

Methods for containmentPrevent further leakage or spillage if safe to do so.

Methods for cleaning upSweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water. Avoid generating orbreathing dust. Product is slippery if wet.

6.4 Reference to other sections

See section 13 for more information.

7. Handling and storage

7.1 Precautions for safe handling

HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation. Donot breathe dust. Material becomes slippery when wet. Use caution if wet.

Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product Remove contaminated clothing.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid wet and humidconditions.

Storage class Chemical storage.

Packaging material Use specially constructed containers only

7.3 Specific end uses

See Section 1.2.

________________________________________________________________________________________

8. Exposure controls/personal protection

8.1 Control parameters

Exposure limits No biological limit allocated

Page 4 / 11

________________________________________________________________________________________


Component EU OEL Austria Australia DenmarkCrystalline silica (impurity) Not determined Not determined 0.1 mg/m3 TWA 0.1mg/m3

Component Malaysia France Germany HungaryCrystalline silica (impurity) 0.1 mg/m3 TWA 0.1 mg/m3 Not determined Not determined

Component New Zealand Italy Netherlands NorwayCrystalline silica (impurity) 0.2 mg/m3 TWA

Known or presumedhuman carcinogen

Not determined 0.075 mg/m3 0.3 mg/m3 TWA totaldust

0.1 mg/m3 TWArespirable dust

0.9 mg/m3 STEL totaldust

0.3 mg/m3 STELrespirable dust

Carcinogen

Component Poland Portugal Romania RussiaCrystalline silica (impurity) 2 mg/m3 TWA >50% free

crystalline silica totalinhalable dust

0.3 mg/m3 TWA >50%free crystalline silica

respirable dust4.0 mg/m3 TWA 2% to

50% free crystalline silicatotal inhalable dust

1.0 mg/m3 TWA 2% to50% free crystalline silica

respirable dust

0.025 mg/m3 TWArespirable fraction

Not determined 1 mg/m3 MAC3 mg/m3 STEL

1 mg/m3 TWA aerosolFibrogenic substance

Component Spain Switzerland Turkey UKCrystalline silica (impurity) 0.1 mg/m3 VLA-ED

respirable fraction0.15 mg/m3 MAK

respirableNot determined 0.3 mg/m3 STEL

calculated respirable0.1 mg/m3 TWA

respirable

________________________________________________________________________________________

8.2 Exposure controls

Page 5 / 11

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazardpresent and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemicalhazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards maybe created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection willvary from workplace to workplace and should be assessed by the user in each situation.

________________________________________________________________________________________


Engineering measures to reduce exposureEnsure adequate ventilation. Mechanical ventilation or local exhaust ventilation is required.

Personal protective equipmentEye protection It is good practice to wear goggles when handling any chemical. Tightly fitting safety

goggles.Hand protection Use protective gloves made of:, Neoprene, PVC, Nitrile, Frequent change is advisable.Respiratory protection Respirator must be worn if exposed to dust, Suitable mask with particle filter P3 (European

Norm 143).Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at

the work place.

Hygiene measures Wash hands before eating, drinking or smoking, Remove and wash contaminated clothingbefore re-use.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance PowderOdor OdorlessColor Tan - GrayOdor threshold Not applicable

Explosive properties Not ApplicableOxidizing properties None known.

9.2 Other information

Physical state Solid

Property Values Remarks pH No information availablepH @ dilutionMelting/freezing point 1580 °CBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not ApplicableFlammability Limits in Air

Upper flammability limit Not applicableLower flammability limit Not applicable

Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density 1920 - 2400 kg/m³Relative density 4.10 - 4.25 @ 20°C.Water solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________

Kinematic viscosity No information availableDynamic viscosity No information availableLog Pow

Page 6 / 11


________________________________________________________________________________________


Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available

10. Stability and reactivity

10.1 Reactivity

No specific reactivity hazards associated with this product.

10.2 Chemical stability

Stable under normal temperature conditions and recommended use.

10.3 Possibility of Hazardous Reactions

Hazardous polymerizationHazardous polymerization does not occur.

10.4 Conditions to avoid

Avoid dust formation. Avoid wet and humid conditions.

10.5 Incompatible materials

No materials to be especially mentioned.

10.6 Hazardous decomposition products

See also section 5.2.

11. Toxicological information


Acute toxicity

Product information This product contains a small quantity of quartz, crystalline silica. Prolonged and repeatedexposure to concentrations of crystalline silica exceeding the workplace exposure limit(WEL) may lead to chronic lung disease such as silicosis.

Respirable quartz <0.3% . Report number: N0600517.

Inhalation Inhalation of dust in high concentration may cause irritation of respiratory system.

Eye contact May cause slight irritation.

Skin contact Prolonged contact may cause redness and irritation.

Ingestion Ingestion may cause stomach discomfort.

Unknown acute toxicity Not Applicable.

Component LD50 Oral

________________________________________________________________________________________

LD50 Dermal LC50 InhalationCrystalline silica (impurity) = 500 mg/kg ( Rat ) No data available No data available

Page 7 / 11

________________________________________________________________________________________


Sensitization This product does not contain any components suspected to be sensitizing.

Mutagenic effects This product does not contain any known or suspected mutagens.

Carcinogenicity Crystalline silica dust is listed by IARC in Group 1 as known to cause lung cancer inhumans, if inhaled.

Reproductive toxicity This product does not contain any known or suspected reproductive hazards.

Routes of exposure Inhalation.

Routes of entry Inhalation.

Specific target organ toxicity(single exposure)

Not classified

Specific target organ toxicity(repeated exposure)

Not classified.

Target organ effects Lungs.

Aspiration hazard No hazard from product as supplied.

12. Ecological information

12.1 Toxicity

Listed on PLONOR list of OSPAR

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.

Toxicity to algaeThis product is not considered toxic to algae.

Toxicity to fishThis product is not considered toxic to fish.

Toxicity to daphnia and other aquatic invertebratesThis product is not considered toxic to invertebrates.

Component Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates

Crystalline silica (impurity) No information available No information available No information available

________________________________________________________________________________________

12.2 Persistence and degradability

Product is not biodegradable.

Page 8 / 11

12.3 Bioaccumulative potential

________________________________________________________________________________________


Does not bioaccumulate.

12.4 Mobility in soil

MobilityInsoluble in water.

12.5 Results of PBT and vPvB assessment

Not classified as PBT/vPvB by current EU criteria.

12.6 Other adverse effects.

None known.

13. Disposal considerations

13.1 Waste treatment methods

Waste from residues / unusedproducts

Dispose of in accordance with local regulations.

Contaminated packaging Empty containers should be taken for local recycling, recovery or waste disposal.

EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 01 05 07

14. Transport information

14.1 UN Number Not regulated

14.2 Proper shipping name The product is not covered by international regulation on the transport of dangerous goods

14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class Not regulatedIMDG Hazard class Not regulatedICAO Hazard class/division Not regulated

________________________________________________________________________________________

14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG Packing group Not regulated

Page 9 / 11

ICAO Packing group Not regulated

________________________________________________________________________________________


14.5 Environmental hazard No

14.6 Special precautions Not Applicable

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Germany, Water EndangeringClasses (VwVwS)

Water endangering class = nwg

Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo Poisons Schedule number allocated

New Zealand hazard classification Not classified.

HSNO approval no. Not required.

Group number Not required.

Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the EuropeanParliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.

This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.

National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].

National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].

________________________________________________________________________________________

National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].

Safe Work Australia.

Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP).

Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport byroad or rail.

Page 10 / 11

Dutch Mining Regulations: In accordance with Mining Regulations 9.2 and Chapter 4 of the Working Conditions Decree.

________________________________________________________________________________________


Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations2013 [P.U.(A) 310/2013] (CLASS Regulations)

The Industry Code of Practice on Chemical Classification and Hazard Communication 2014 [P.U. (B) 128/2014] (ICOP)International inventories

USA (TSCA) CompliesEuropean Union (EINECS and ELINCS) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies

Contact [email protected] for REACH information.

15.2 Chemical Safety Report


16. Other information

Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Anne Karin (Anka) Fosse

Supersedes date 17/Nov/2014

Revision date 19/Mar/2015

Version 10

The following sections have beenrevised:

2,, 3,, 16, Updated according to GHS/CLP.

R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation

Full text of H-Statements referred to under sections 2 and 3

________________________________________________________________________________________

This product is not classified as hazardous therefore no (H) hazard statements assigned.H373 - May cause damage to organs through prolonged or repeated exposure if inhaled

DisclaimerThe information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.

Page 11 / 11

Revision Date 06-08-2013

Revision 6

Supersedes date 21-03-2011

SDS No. 11209

SAFETY DATA SHEET

BENTONITE

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier

Product name BENTONITE

Synonyms, Trade Names API BENTONITE, OCMA BENTONITE, WYOMING BENTONITE

REACH Registration notes REACH. With respect to minerals, Article 2 § 7(b) and Annex V point 7 explicitily exempt from

registration and evaluation "minerals which occur in nature, if they are not chemically modified." This

product is exempt from registration.

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Viscosifier

1.3. Details of the supplier of the safety data sheet

M-I Australia Pty LtdSupplier

Level 5

256 St. George Tce

Perth

WA 6000

T = 08 9440 2900

Contact Person [email protected]

1.4. Emergency telephone number

(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East

and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.

SECTION 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)

Physical and Chemical Hazards Not classified.

Human health Not classified.

Environment Not classified.

Classification (67/548/EEC) Not classified.

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

Human health

This product contains a small quantity of quartz, crystalline silica. IARC Monographs, Vol 68, 1997, concludes that there is sufficient

evidence that inhaled crystalline silica in the form of quartz or crystobalite from occupational sources causes cancer in humans. IARC

classification Group 1. Because of quantity and composition, the health hazard is small.

2.2. Label elements

Label In Accordance With (EC) No. 1272/2008

No pictogram required.

Australian statement of hazardous/dangerous nature

Classified as Non-Hazardous according to the criteria of NOHSC.

NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.

2.3. Other hazards

Not Classified as PBT/vPvB by current EU criteria.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

71 /

SDS No. 11209

BENTONITE

3.1. Substances

QUARTZ, CRYSTALLINE SILICA 5-10%

CAS-No.: 14808-60-7 EC No.: 238-878-4

Classification (67/548/EEC)

Xn;R48/20.


STOT RE 2 - H373


REACH Registration notes REACH. With respect to minerals, Article 2 § 7(b) and Annex V point 7 explicitily exempt from

registration and evaluation "minerals which occur in nature, if they are not chemically modified." This

product is exempt from registration.

Composition Comments

The data shown is in accordance with the latest EC Directives. This product contains a small quantity of quartz, crystalline silica.

Prolonged and repeated exposure to concentrations of crystalline silica exceeding the workplace exposure limit (WEL) may lead to chronic

lung disease such as silicosis. Because of quantity and composition, the health hazard is small. This is a naturally occurring mineral.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures

Inhalation

Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort

continues.

Ingestion

Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention

if any discomfort continues.

Skin contact

Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after

washing.

Eye contact

Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.

Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed

General information

The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop

as described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.

4.3. Indication of any immediate medical attention and special treatment needed

Treat Symptomatically.

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media

Extinguishing media

Use fire-extinguishing media appropriate for surrounding materials.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

When heated, vapours/gases hazardous to health may be formed.

Unusual Fire & Explosion Hazards

High concentrations of dust may form explosive mixture with air.

5.3. Advice for firefighters

Special Fire Fighting Procedures

Containers close to fire should be removed immediately or cooled with water.

Protective equipment for fire-fighters

Self contained breathing apparatus and full protective clothing must be worn in case of fire.

SECTION 6: ACCIDENTAL RELEASE MEASURES

72 /

SDS No. 11209

BENTONITE

6.1. Personal precautions, protective equipment and emergency procedures

Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Do not allow to enter drains, sewers or watercourses.

6.3. Methods and material for containment and cleaning up

Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. In case of

spills, beware of slippery floors and surfaces.

6.4. Reference to other sections

For waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation. Good personal hygiene is

necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Remove contaminated clothing. Do not

eat, drink or smoke when using the product. Avoid wet and humid conditions.

7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Avoid wet and humid conditions.

Storage Class

Unspecified storage.

7.3. Specific end use(s)

The identified uses for this product are detailed in Section 1.2.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

STD STEL - 15 MinTWA - 8 HrsName Notes

0,1 mg/m3WELQUARTZ, CRYSTALLINE SILICA

WEL = Workplace Exposure Limit.

No biological limit allocated.

QUARTZ, CRYSTALLINE SILICA (CAS: 14808-60-7)

DNEL

Inhalation. Short Term Local Effects 4 mg/m³

Inhalation. Long Term Local Effects 1 mg/m³


Protective equipment

Process conditions

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and

the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated

with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such

further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace

and should be assessed by the user in each situation.

Engineering measures

Provide adequate general and local exhaust ventilation.

Respiratory equipment

No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational

exposure limit. Dust filter P3 (for especially fine dust/powder).

73 /

SDS No. 11209

BENTONITE

Hand protection

For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile. or Neoprene.

Eye protection

Wear approved chemical safety goggles where eye exposure is reasonably probable.

Other Protection

Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.

Hygiene measures

Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash hands after handling. Promptly remove

any clothing that becomes wet or contaminated.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Solid

Colour Cream to grey.

Odour Odourless.

Solubility Insoluble in water

Melting point (°C) > 450°C (842°F)

Relative density 2.3 - 2.6 s.g @ 20°C

Bulk Density 750 - 950 kg/m3

pH-Value, Conc. Solution 9 - 10

Solubility Value (G/100G

H2O@20°C)

< 0.9 mg/l

Decomposition temperature (°C) > 500°C (932°F)

9.2. Other information

Not relevant

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

There are no known reactivity hazards associated with this product.

10.2. Chemical stability


10.3. Possibility of hazardous reactions

Not known.

10.4. Conditions to avoid

Avoid wet and humid conditions.

10.5. Incompatible materials

Materials To Avoid

Not known.

10.6. Hazardous decomposition products


SECTION 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Aspiration hazard:

Not anticipated to present an aspiration hazard based on chemical structure.

Inhalation

Dust may irritate respiratory system or lungs.

74 /

SDS No. 11209

BENTONITE

Ingestion

May cause discomfort if swallowed.

Skin contact

Prolonged and frequent contact may cause redness and irritation.

Eye contact


Route of entry

No route of entry noted.

Target Organs

No specific target organs noted

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity

Contact M-I SWACO's QHSE Department for ecological information at [email protected]. OSPAR have defined this chemical as

PLONOR.

12.1. Toxicity

Acute Toxicity - Fish

LC50 96 hours > 10000 mg/l Onchorhynchus mykiss (Rainbow trout)

12.2. Persistence and degradability

Degradability

The product solely consists of inorganic compounds which are not biodegradable.

12.3. Bioaccumulative potential


The product does not contain any substances expected to be bioaccumulating.

12.4. Mobility in soil

Mobility:

The product is insoluble in water.

12.5. Results of PBT and vPvB assessment


12.6. Other adverse effects

None known.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.

Waste Class

The definitive European Waste code for this product will depend upon the final use that is made of this material. EWC-code: 01 04 09

SECTION 14: TRANSPORT INFORMATION

General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,

ADR/RID). and (ADG).

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

75 /

SDS No. 11209

BENTONITE

Not applicable.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally Hazardous Substance/Marine Pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

Not applicable. Please contact [email protected] for info regarding transport in Bulk.

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Uk Regulatory References

Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)

Workplace Exposure Limits EH40.

EU Legislation

Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,

Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive

1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive

76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.

Water hazard classification

WGK 0

Australian Standard for the Uniform Scheduling of Drugs and Poisons

No Poisons Schedule number allocated.

Australian Regulations

National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)]. National Occupational

Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances [NOHSC:1008 (2004) 3rd Edition]. National

Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in the occupational Environment

[NOHSC:1003 (1995)]. Safe Work Australia. Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). ADG Code – Australian

Dangerous Goods Code.

15.2. Chemical Safety Assessment

International Chemical Inventories

Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:

Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New

Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).

SECTION 16: OTHER INFORMATION

Information Sources

Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals

Bureau - ESIS (European Chemical Substances Information).

Revision Comments

The following sections have been revised: 1, 9, 15, 16.

Issued By Sandra McWilliam


Revision 6


SDS No. 11209

Safety Data Sheet Status Approved.

Date 06-08-2013

Signature Sandra McWilliam

Signature 2 Sarah Malone

76 /

SDS No. 11209

BENTONITE

Risk Phrases In Full

Harmful: danger of serious damage to health by prolonged exposure through inhalation.R48/20

Not classified.NC

Hazard Statements In Full

May cause damage to organs <<Organs>> through prolonged or repeated exposure.H373

Disclaimer

MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from

sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.

We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this

information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or

situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this

product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any

nature with respect to this product or to the data herein is made or incurred hereunder.

77 /

Safety Data SheetCALCIUM CHLORIDE (ALL GRADES)

SDS no. MI10432Version 5Revision date 01/Apr/2014Supersedes date 15/Nov/2010



Product name CALCIUM CHLORIDE (ALL GRADES)Product code MI10432Molecular weight 111Norway Pr. no. 46238Denmark Pr. no.: 988590


Recommended Use Weighting agent.








Health hazardsSerious eye damage/eye irritation Category 2


Physical Hazards

________________________________________________________________________________________

Not classified


Page 1 / 11

[email protected]

________________________________________________________________________________________

CALCIUM CHLORIDE (ALL GRADES) SDS no. MI10432Revision date 01/Apr/2014

2.2 Label elements

Signal wordWARNING

Hazard statementsH319 - Causes serious eye irritation

Precautionary Statements - EU (§28, 1272/2008) P280 - Wear protective gloves/protective clothing and eye/face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/ attentionP501 - Dispose of contents/container in accordance with local regulations.

Indication of dangerXi - Irritant

ContainsCalcium chloride


2.3 Other data


Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.


3.1 Substances




REACHregistration

numberCalcium chloride 233-140-8 10043-52-4 60-100 Xi; R36 Eye Irrit. 2 (H319) 01-2119494219-28-x

xxx

________________________________________________________________________________________

3.2 Mixtures

Page 2 / 11

________________________________________________________________________________________





Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention if irritation occurs.





Main symptoms










________________________________________________________________________________________



Unusual fire and explosion hazardsContact with metals may evolve flammable hydrogen gas.

Hazardous combustion productsFire or high temperatures create:, Chlorine, May release hydrogen gas (explosive) on contact with metals.

Page 3 / 11


________________________________________________________________________________________






Use personal protective equipment. See also section 8.



Environmental exposure controlsAvoid release to the environment.



Methods for cleaning upSweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.





HandlingAvoid contact with skin and eyes. Avoid dust formation.

Hygiene measuresUse good work and personal hygiene practices to avoid exposure When using do not smoke, eat or drink. Wash hands beforeeating, drinking or smoking Remove contaminated clothing.



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moistureAvoid contact with: Strong oxidizing agents Strong acids.


________________________________________________________________________________________



See Section 1.2.

Page 4 / 11


________________________________________________________________________________________



Exposure limits NUI = Nuisance dust, TWA 4mg/m3 Respirable Dust, 10mg/m3 Total Dust.No biological limit allocated

Component EU OEL Austria Australia DenmarkCalcium chloride Not determined Not determined Not determined Not determined

Component Malaysia France Germany HungaryCalcium chloride Not determined Not determined Not determined Not determined

Component New Zealand Italy Netherlands NorwayCalcium chloride Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaCalcium chloride Not determined Not determined Not determined 2 mg/m³ MAC (aerosol)

Component Spain Switzerland Turkey UKCalcium chloride Not determined Not determined Not determined Not determined

Derived No Effect Level (DNEL)

Short term exposure local effectsCalcium chlorideInhalation 10 mg/m³

Long term exposure local effectsCalcium chlorideInhalation 5 mg/m³


________________________________________________________________________________________


Engineering measures to reduce exposureEnsure adequate ventilation.

Personal protective equipment

Page 5 / 11

Eye protection It is good practice to wear goggles when handling any chemical. Tightly fitting safetygoggles.

________________________________________________________________________________________


Hand protection Repeated or prolonged contact:, Use protective gloves made of:, Nitrile, Neoprene gloves,Rubber gloves.

Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Half mask with a particle filter P2(European Norm EN 143 = former DIN 3181).

Skin and body protection Wear suitable protective clothing, Provide eyewash station.




Appearance Powder DustOdor OdorlessColor Off-whiteOdor threshold Not applicable


9.2 Other information Pour point No information availableMolecular weight 111VOC content(%) NoneDensity No information available


Property Values Remarks pH Not applicablepH @ dilution 7 - 10 5% solMelting/freezing point 772 °CBoiling point/range > 1600 °CFlash point No information availableEvaporation rate (BuAc =1)Flammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density No information availableRelative density 2.1 g/cm³ @ 20°C.Water solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________

Kinematic viscosityDynamic viscosity No information availableLog Pow

Page 6 / 11

Not determined

________________________________________________________________________________________



10.1 Reactivity







Avoid contact with water and moist air - product is hygroscopic.


Metals. Strong oxidizing agents. Strong acids.


May release hydrogen gas (explosive) on contact with metals. See also section 5.2.



Acute toxicity

Inhalation Inhalation of dust may cause shortness of breath, tightness of the chest, a sore throat andcough.

Eye contact Causes serious eye irritation.




Component LD50 Oral LD50 Dermal LC50 InhalationCalcium chloride = 1000 mg/kg ( Rat ) = 2630 mg/kg ( Rat ) No data available


________________________________________________________________________________________

Mutagenic effects This substance has no evidence of mutagenic properties.

Carcinogenicity This substance has no evidence of carcinogenic properties.

Page 7 / 11

________________________________________________________________________________________


Reproductive toxicity None known.

Routes of exposure Eye contact.

Routes of entry No route of entry noted.


Not classified


Not classified.



12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Listed on PLONOR list of OSPAR

Toxicity to algaeSee component information below.

Toxicity to fishSee component information below.

Toxicity to daphnia and other aquatic invertebratesSee component information below.


Calcium chloride 10650 mg/L LC50 (Lepomismacrochirus) = 96 h

No information available 2,400 mg/L EC50 (Daphnia magna)= 48 h


Not Applicable - Inorganic chemical.



________________________________________________________________________________________


MobilitySoluble in water.

Page 8 / 11


________________________________________________________________________________________




None known.






EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 06 03 14 - solid salts and solutions other than those mentioned in 06 0311 and 06 03 13 Waste Code: 7091 Inorganic salts and other solids.


The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,ADR/RID/ADG).


14.2 Proper shipping name Not regulated


14.4 Packing group ADR/RID/ADN/ADG Packing group Not regulatedIMDG Packing group Not regulatedICAO Packing group Not regulated


________________________________________________________________________________________

14.6 Special precautions


Page 9 / 11

________________________________________________________________________________________





Water endangering class = 1













USA (TSCA) CompliesEuropean Union (EINECS and ELINCS) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) Complies

________________________________________________________________________________________

Korean (KECL) CompliesNew Zealand (NZIoC) Complies


Page 10 / 11


________________________________________________________________________________________




Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals)

Supersedes date 15/Nov/2010

Revision date 01/Apr/2014

Version 5

The following sections have beenrevised

This SDS have been made in a new database and therefore a new layout. No changes withregard to classification have been made, Updated according to GHS/CLP.

________________________________________________________________________________________


H319 - Causes serious eye irritation

DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.

Page 11 / 11

Revision Date 27.05.2013

Revision 5

Supersedes date 26.05.2008

SDS No. 11233

SAFETY DATA SHEET

SODIUM HYDROXIDE SOLID



Product name SODIUM HYDROXIDE SOLID

Synonyms, Trade Names CAUSTIC SODA, SODIUM HYDROXIDE PRILLS


Identified uses pH modifier.



Level 5

256 St. George Tce

Perth

WA 6000

T = 08 9440 2900


M-I SWACOManufacturer

A Schlumberger Company

Woodlands Drive

Kirkhill Industrial Estate

Dyce, Aberdeen AB21 0GW

Scotland UK

T=+44(0)1224-246600

F=+11(0)1224-246699







Physical and Chemical Hazards Met. Corr. 1 - H290

Human health Skin Corr. 1A - H314


Classification (67/548/EEC) C;R35.


2.2. Label elements

Contains SODIUM HYDROXIDE


Signal Word Danger

81 /

SDS No. 11233


Hazard Statements

H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

Precautionary Statements

P260 Do not breathe dust.

P280 Wear protective clothing, gloves, eye and face protection.

P301+330+331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

P501 Dispose of contents/container in accordance with local regulations.

Supplementary Precautionary Statements

P234 Keep only in original container.

P264 Wash contaminated skin thoroughly after handling.

P321 Specific treatment (see medical advice on this label).

P303+361+353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated

clothing. Rinse skin with water/shower.

P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a position

comfortable for breathing.

P310 Immediately call a POISON CENTER or doctor/physician.

P363 Wash contaminated clothing before reuse.

P390 Absorb spillage to prevent material damage.

P405 Store locked up.

P406 Store in corrosive resistant/… container with a resistant inner liner.


Classified as Hazardous according to the criteria of NOHSC.

HAZARDOUS SUBSTANCE. DANGEROUS GOODS.

2.3. Other hazards



3.1. Substances

SODIUM HYDROXIDE 60-100%

CAS-No.: 1310-73-2 EC No.: 215-185-5


C;R35


Met. Corr. 1 - H290

Skin Corr. 1A - H314



The data shown is in accordance with the latest EC Directives.



General information

Seek medical attention for all burns, regardless how minor they may seem.

Inhalation

Move the exposed person to fresh air at once. Provide fresh air, warmth and rest, preferably in a comfortable upright sitting position. If

respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort continues.

Ingestion

Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. If vomiting occurs,

keep head low so that stomach content doesn't get into the lungs. Get medical attention immediately!

Skin contact

Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention immediately!

Eye contact


Continue to rinse for at least 15 minutes. Get medical attention immediately. Continue to rinse.

82 /

SDS No. 11233



General information







Extinguishing media

Water spray, foam, dry powder or carbon dioxide.

Unsuitable extinguishing media

Do not use water jet as an extinguisher, as this will spread the fire.



When heated, toxic and corrosive vapours/gases may be formed.



Specific hazards

Australian Hazchem code - 2W












Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. This

material and its container must be disposed of as hazardous waste.





Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation. Never add water directly to this

product - may cause vigorous reaction/boiling. Always dilute by carefully pouring the product into the water. Good personal hygiene is


eat, drink or smoke when using the product.


Store in locked, well ventilated room and isolated from acids. Unsuitable containers: metals.

Storage Class

Corrosive storage.



83 /

SDS No. 11233


Usage Description

Do not add water directly to the product. It may cause a violent reaction.




WEL 2 mg/m3SODIUM HYDROXIDE



SODIUM HYDROXIDE (CAS: 1310-73-2)

DNEL

Inhalation. Long Term Local Effects 1 mg/m3



Process conditions









Use respiratory equipment with particle filter, type P2.

Hand protection

Use protective gloves made of: Impermeable material. Butyl rubber. Polyvinyl chloride (PVC). Neoprene.

Eye protection

Wear tight-fitting goggles or face shield.

Other Protection


Hygiene measures

Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash hands after handling. Use appropriate

skin cream to prevent drying of skin. Promptly remove any clothing that becomes wet or contaminated.

Skin protection

Wear apron or protective clothing in case of contact.



Appearance Pellets

Colour White.

Odour Odourless.

Solubility Completely soluble in water

Initial boiling point and boiling range

(°C)

1390°C 760 mm Hg

Melting point (°C) 318°C

Relative density 2.13 g/cm3 @ 25°C

Bulk Density 1.1 - 1.25 g/cm3

Vapour pressure 3.5 h Pa @ 800°C

pH-Value, Diluted Solution 14.0 @ 5%

84 /

SDS No. 11233



H2O@20°C)

50.0


Mol. Weight 49.99 g/mol


10.1. Reactivity





Not known.


Water, moisture. Do not add water directly to the product. It may cause a violent reaction.


Materials To Avoid

Avoid contact with: Acids. Metals.


When heated, toxic and corrosive vapours/gases may be formed.



Toxicological information

Causes severe skin burns and eye damage.

Acute toxicity:


1350 mg/kg Rabbit

Aspiration hazard:


Inhalation


Ingestion

Corrosive. Even small amounts may cause serious damage. May irritate and cause stomach pain, vomiting and diarrhoea.

Skin contact

Causes severe burns.

Eye contact

Risk of serious damage to eyes.


Ecotoxicity

Contact M-I SWACO's QHSE Department for ecological information at [email protected]. The product may affect the acidity

(pH-factor) in water with risk of harmful effects to aquatic organisms.

12.1. Toxicity

85 /

SDS No. 11233


Acute Toxicity - Fish

LC50 96 hours 45.4 mg/l Onchorhynchus mykiss (Rainbow trout)


Degradability

There are no data on the degradability of this product.





Mobility:

Completely soluble in water


This product does not contain any PBT or vPvB substances.


None known.



Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements. This material

and its container must be disposed of as hazardous waste.

Waste Class



14.1. UN number

UN No. (ADR/RID/ADN) 1823

UN No. (IMDG) 1823

UN No. (ICAO) 1823


Proper Shipping Name SODIUM HYDROXIDE, SOLID


ADR/RID/ADN Class 8

ADR/RID/ADN Class Class 8: Corrosive substances.

IMDG Class 8

ICAO Class/Division 8

Transport Labels

CORROSIVE

8

14.4. Packing group

ADR/RID/ADN Packing group II

IMDG Packing group II

ICAO Packing group II

86 /

SDS No. 11233




No.


EMS F-A, S-B

Emergency Action Code 2W

Hazard No. (ADR) 80

Hazchem code (ADG) Australian Hazchem code - 2W


Not applicable. Ship Types are stored in 14.0 General to assign search all phrases






EU Legislation






WGK 1


Schedule Number 6.













Information Sources



Revision Comments

Updated according to CLP. Compiled or revised by Sarah Malone

Revision Date 27.05.2013

Revision 5

Supersedes date 26.05.2008

SDS No. 11233



Causes severe burns.R35


Causes severe skin burns and eye damage.H314

May be corrosive to metals.H290

87 /

SDS No. 11233


Disclaimer








88 /

SAFETY DATA SHEET

Chrome Free Desco® Deflocculant Version 1.6 Revision Date 2016-03-11

SDS Number:100000013725 1/11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product information

Product Name : Chrome Free Desco® Deflocculant Material : 1016808

Use : Drilling Mud Additive Company : Chevron Phillips Chemical Company LP

Drilling Specialties Company LLC 10001 Six Pines Drive The Woodlands, TX 77380

Local : Chevron Phillips Chemicals Australia Pte Ltd

Suite 409 685 Burke Road Camberwell, Victoria Australia 3124 Hours of Operation: 9:00 a.m. - 5:00 p.m. SDS Requests: 61 3 8080 5700 Technical Information: 61 3 8080 5700 Responsible Party: Product Safety Group Email:[email protected]

Emergency telephone:

Health: 866.442.9628 (North America) 1.832.813.4984 (International) 61 3 8080 5700 (Australia) Transport: CHEMTREC 800.424.9300 or 703.527.3887(int'l) Asia: +800 CHEMCALL (+800 2436 2255) China:+86-21-22157316 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600

Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected]

SAFETY DATA SHEET


SDS Number:100000013725 2/11

Website : www.CPChem.com

SECTION 2: Hazards identification

Classification of the substance or mixture Model Work Health and Safety Regulations 2011, Model Code of Practice for the Labelling of Workplace Hazardous Chemicals (2011), Guidance on the Classification of Hazardous Chemicals under the WHS Regulations (2012) (GHS 2009)

Classification

: Carcinogenicity, Category 1A

Labeling

Symbol(s) :

Signal Word : Danger

Hazard Statements : H350: May cause cancer.

Precautionary Statements : Prevention: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P281: Use personal protective equipment as required. Response: P308 + P313: IF exposed or concerned: Get medical advice/ attention. Storage: P405: Store locked up. Disposal: P501: Dispose of contents/ container to an approved waste disposal plant.

SECTION 3: Composition/information on ingredients

Synonyms : Drilling Mud Deflocculant

Molecular formula : Mixture

Chemical Name CAS-No. / EINECS-No. Concentration [wt%]

Sulfomethylated Quebracho 68201-64-9 60 - 80 Ferrous Sulfate 17375-41-6 5 - 9 Crystalline Silica 14808-60-7 0.1 - 1

SECTION 4: First aid measures

SAFETY DATA SHEET


SDS Number:100000013725 3/11

General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attendance.

If inhaled : If unconscious place in recovery position and seek medical

advice. If symptoms persist, call a physician. In case of eye contact : Flush eyes with water as a precaution. Remove contact

lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear. Never give anything by mouth to

an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital.

SECTION 5: Firefighting measures

Flash point : Not applicable Autoignition temperature : No data available


: High volume water jet.

Specific hazards during fire fighting

: Risks of ignition followed by flame propagation or secondary explosions can be caused by the accumulation of dust, e.g. on floors and ledges.

Special protective equipment for fire-fighters

: Wear self-contained breathing apparatus for firefighting if necessary.

Further information : Standard procedure for chemical fires. Use extinguishing

measures that are appropriate to local circumstances and the surrounding environment.

Fire and explosion protection

: Avoid dust formation. Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.

Hazardous decomposition products

: Iron Oxides. Sulfur oxides.

SECTION 6: Accidental release measures

Personal precautions : Use personal protective equipment. Avoid dust formation.

Avoid breathing dust. Environmental precautions : Prevent product from entering drains. Prevent further leakage

or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up : Pick up and arrange disposal without creating dust. Clean up

promptly by sweeping or vacuum. Keep in suitable, closed containers for disposal.

SAFETY DATA SHEET


SDS Number:100000013725 4/11

Additional advice : Dust deposits should not be allowed to accumulate on

surfaces, as these may form an explosive mixture if they are released into the atmosphere in sufficient concentration. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).

SECTION 7: Handling and storage

Handling

Advice on safe handling : Avoid formation of respirable particles. Do not breathe

vapors/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary, but may not by themselves be sufficient.

Advice on protection against fire and explosion

: Avoid dust formation. Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Provide appropriate exhaust ventilation at places where dust is formed.

Storage

Requirements for storage areas and containers

: Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.

SECTION 8: Exposure controls/personal protection

Ingredients with workplace control parameters

AU Ingredients Basis Value Control parameters Note Ferrous Sulfate AU OEL TWA 1 mg/m3

Crystalline Silica AU OEL TWA 0.1 mg/m3 (respirable dust)


Adequate ventilation to control airborned concentrations below the exposure guidelines/limits. Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.


Respiratory protection : Wear a supplied-air NIOSH approved respirator unless

ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under

SAFETY DATA SHEET


SDS Number:100000013725 5/11

normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.

Hand protection : The suitability for a specific workplace should be discussed

with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eye protection : Eye wash bottle with pure water. Safety glasses. Skin and body protection : Choose body protection in relation to its type, to the

concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.

Hygiene measures : When using do not eat or drink. When using do not smoke.

Wash hands before breaks and at the end of workday.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance

Form : Powder Physical state : Solid Color : Fine reddish-brown with small white specks Odor : Odorless Odor Threshold : Not applicable

Safety data

Flash point : Not applicable

Lower explosion limit : Not applicable

Upper explosion limit : Not applicable

Oxidizing properties : No

Autoignition temperature : No data available

Thermal decomposition : No data available

Molecular formula : Mixture

Molecular weight : Not applicable

SAFETY DATA SHEET


SDS Number:100000013725 6/11

pH : Not applicable

Pour point : No data available

Boiling point/boiling range : Not applicable

Vapor pressure : Not applicable

Relative density : Not applicable

Density : 1.60 g/cm3

Water solubility : Partly soluble

Partition coefficient: n-octanol/water

: No data available

Viscosity, kinematic : Not applicable

Relative vapor density : Not applicable

Evaporation rate : Not applicable

SECTION 10: Stability and reactivity

Chemical stability : This material is considered stable under normal ambient and

anticipated storage and handling conditions of temperature and pressure.

Possibility of hazardous reactions

Conditions to avoid : Generation of Dusts. Materials to avoid : May react with oxygen and strong oxidizing agents, such as

chlorates, nitrates, peroxides, etc. Thermal decomposition : No data available

Hazardous decomposition products

: Iron Oxides Sulfur oxides

Other data : No decomposition if stored and applied as directed.

SECTION 11: Toxicological information

Chrome Free Desco® Deflocculant Acute oral toxicity : Acute toxicity estimate: 3,544 mg/kg

Method: Calculation method

Chrome Free Desco® Deflocculant

SAFETY DATA SHEET


SDS Number:100000013725 7/11

Acute inhalation toxicity : LC50: unknown Chrome Free Desco® Deflocculant Acute dermal toxicity : LD50: unknown Chrome Free Desco® Deflocculant Skin irritation : May irritate skin. Chrome Free Desco® Deflocculant Eye irritation : May irritate eyes. Repeated dose toxicity

Sulfomethylated Quebracho : Species: Rat, male Sex: male Application Route: oral gavage Dose: 100, 300, 1000 mg/kg Exposure time: 32 d Number of exposures: Daily NOEL: 1,000 mg/kg Method: OECD Guideline 422 No adverse effects expected

Species: Rat, female Sex: female Application Route: oral gavage Dose: 100, 300, 1000 mg/kg Exposure time: 39 - 47 d Number of exposures: Daily NOEL: 1,000 mg/kg Method: OECD Guideline 422 No adverse effects expected

Reproductive toxicity

Sulfomethylated Quebracho : Species: Rat Sex: male Application Route: oral gavage Dose: 100, 300, 1000 mg/kg Exposure time: 32 d Number of exposures: Daily Method: OECD Guideline 422 NOAEL Parent: 1,000 mg/kg NOAEL F1: 1,000 mg/kg Fertility and developmental toxicity tests did not reveal any effect on reproduction.

Species: Rat Sex: female Application Route: oral gavage Dose: 100, 300, 1000 mg/kg Exposure time: 39 - 47 d Number of exposures: Daily Method: OECD Guideline 422 NOAEL Parent: 1,000 mg/kg NOAEL F1: 1,000 mg/kg Fertility and developmental toxicity tests did not reveal any effect on reproduction.

SAFETY DATA SHEET


SDS Number:100000013725 8/11

Chrome Free Desco® Deflocculant Aspiration toxicity : No aspiration toxicity classification. CMR effects

Crystalline Silica : Carcinogenicity: Human carcinogen.

Chrome Free Desco® Deflocculant Further information : No data available.

SECTION 12: Ecological information

Toxicity to fish Sulfomethylated Quebracho : LL50: > 1,800 mg/l

Exposure time: 96 h Species: Scophthalmus maximus (Flatfish, Flounder) Method: OECD Test Guideline 203

Ferrous Sulfate LL50: > 6.25 mg/l Exposure time: 96 h Species: Cyprinodon variegatus (sheepshead minnow) Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates Sulfomethylated Quebracho : EL50: 73.2 mg/l

Exposure time: 48 h Species: Acartia tonsa (Marine Copepod) Method: ISO TC147/SC5/WG2

Ferrous Sulfate LC50: 190 mg/l Exposure time: 48 h Species: Acartia tonsa (Marine Copepod)

Toxicity to algae Sulfomethylated Quebracho : ErC50: > 100 mg/l

Exposure time: 72 h Species: Desmodesmus subspicatus (green algae) Method: OECD Test Guideline 201

EbC50: 79 mg/l Exposure time: 72 h Species: Desmodesmus subspicatus (green algae) Method: OECD Test Guideline 201

Ferrous Sulfate EL50: 45 mg/l Exposure time: 72 h Species: Skeletonema costatum (Marine Algae)

Elimination information (persistence and degradability) Biodegradability : Not applicable

SAFETY DATA SHEET


SDS Number:100000013725 9/11

Ecotoxicology Assessment

Acute aquatic toxicity Sulfomethylated Quebracho : Harmful to aquatic life.

Chronic aquatic toxicity Sulfomethylated Quebracho : Harmful to aquatic life with long lasting effects.

Additional ecological information

: Harmful to aquatic life with long lasting effects.

SECTION 13: Disposal considerations

The information in this SDS pertains only to the product as shipped.

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.

Product : Do not dispose of waste into sewer. Do not contaminate

ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product.

Do not re-use empty containers.

SECTION 14: Transport information

The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition). Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading.

US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE))

SAFETY DATA SHEET


SDS Number:100000013725 10/11

NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))


ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)


Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

SECTION 15: Regulatory information

National legislation

Standard for the Uniform Scheduling of Medicines and Poisons

: Schedule 6

Notification status Europe REACH : On the inventory, or in compliance with the inventory United States of America TSCA : On the inventory, or in compliance with the inventory Canada DSL : On the inventory, or in compliance with the inventory Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : Not in compliance with the inventory Korea KECI : On the inventory, or in compliance with the inventory Philippines PICCS : Not in compliance with the inventory China IECSC : On the inventory, or in compliance with the inventory

SECTION 16: Other information

Further information

Legacy SDS Number : 59420

Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this SDS pertains only to the product as shipped.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the

SAFETY DATA SHEET


SDS Number:100000013725 11/11

specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of

Government Industrial Hygienists LD50 Lethal Dose 50%

AICS Australia, Inventory of Chemical Substances

LOAEL Lowest Observed Adverse Effect Level

DSL Canada, Domestic Substances List

NFPA National Fire Protection Agency

NDSL Canada, Non-Domestic Substances List

NIOSH National Institute for Occupational Safety & Health

CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of

Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect

Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure

Scenario Tool OSHA Occupational Safety & Health

Administration EOSCA European Oilfield Specialty

Chemicals Association PEL Permissible Exposure Limit

EINECS European Inventory of Existing Chemical Substances

PICCS Philippines Inventory of Commercial Chemical Substances

MAK Germany Maximum Concentration Values

PRNT Presumed Not Toxic

GHS Globally Harmonized System RCRA Resource Conservation Recovery Act

>= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and

Reauthorization Act. IARC International Agency for Research

on Cancer TLV Threshold Limit Value

IECSC Inventory of Existing Chemical Substances in China

TWA Time Weighted Average

ENCS Japan, Inventory of Existing and New Chemical Substances

TSCA Toxic Substance Control Act

KECI Korea, Existing Chemical Inventory

UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological Materials

<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System

LC50 Lethal Concentration 50%

Revision Date 28-Feb-13

Revision 6

Supersedes date 14-Mar-08

SDS No. 11350

SAFETY DATA SHEET

CITRIC ACID



Product name CITRIC ACID


Identified uses Oil well drilling fluid additive. pH modifier.



Level 5

256 St. George Tce

Perth

WA 6000

T = 08 9440 2900




Woodlands Drive



Scotland UK

T=+44(0)1224-246600

F=+11(0)1224-246699








Human health Eye Irrit. 2 - H319


Classification (1999/45/EEC) Xi;R36.


2.2. Label elements

Contains CITRIC ACID MONOHYDRATE


Signal Word Warning

Hazard Statements

H319 Causes serious eye irritation.

71 /

SDS No. 11350

CITRIC ACID


P337+313 If eye irritation persists: Get medical advice/attention.


P280 Wear protective gloves/protective clothing/eye protection/face protection.

P264 Wash contaminated skin thoroughly after handling.





HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.

2.3. Other hazards



3.2. Mixtures

CITRIC ACID MONOHYDRATE 60-100%

CAS-No.: 5949-29-1 EC No.:


Xi;R36.


Eye Irrit. 2 - H319






Inhalation


continues.

Ingestion

Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort

continues.

Skin contact


washing.

Eye contact


Continue to rinse for at least 15 minutes and get medical attention.


General information







Extinguishing media



72 /

SDS No. 11350

CITRIC ACID


Fire or high temperatures create: Irritating gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).














Avoid generation and spreading of dust. Remove spillage with vacuum cleaner. If not possible, collect spillage with shovel, broom or the

like. Flush with plenty of water to clean spillage area. Do not let washing down water contaminate ponds or waterways.









Store in tightly closed original container in a dry, cool and well-ventilated place. Store separated from: Alkalis. Oxidising material.

Storage Class

Chemical storage.





Ingredient Comments

NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.




Process conditions






73 /

SDS No. 11350

CITRIC ACID




No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air

contamination exists. Wear mask supplied with: Dust filter P2 (for fine dust).

Hand protection

For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber. Polyvinyl chloride (PVC).

Eye protection

Wear approved safety goggles.

Other Protection


Hygiene measures





Appearance Crystals or crystalline

Colour White.

Odour Odourless.

Solubility Soluble in water.


Relative density 1.542g/cm3 @ 20°C

Bulk Density 900 kg/m3

pH-Value, Diluted Solution 1.6 @ 100g/l


H2O@20°C)

60

Auto Ignition Temperature (°C) 1010°C


Not relevant


10.1. Reactivity

Violent reaction with: Strong alkalis. Strong oxidising agents.




Not known.


None known.


Materials To Avoid

Strong alkalis. Strong oxidising agents.


Fire or high temperatures create: Irritating gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).



Toxic Dose 1 - LD 50

5040 mg/kg (oral-mouse)

74 /

SDS No. 11350

CITRIC ACID

Toxic Dose 2 - LD 50

3000 mg/kg (oral rat)

Acute toxicity:


> 7000 mg/kg Rabbit

ATE (Oral)

3000 mg/kg

Aspiration hazard:


Inhalation


Ingestion

May irritate and cause stomach pain, vomiting and diarrhoea.

Skin contact

Skin irritation is not anticipated when used normally.

Eye contact

Causes serious eye irritation. Particles in the eyes may cause irritation and smarting.

Route of entry


Target Organs



Ecotoxicity

Contact M-I SWACO's QHSE Department for ecological information at [email protected].

12.1. Toxicity

Acute Fish Toxicity

Not considered toxic to fish.

LC 50, 96 Hrs, Fish mg/l 440 - 760


Degradability




No data available on bioaccumulation.


Mobility:

The product is soluble in water.


This product does not contain any PBT or vPvB substances.


None known.




75 /

SDS No. 11350

CITRIC ACID

Waste Class

EWC-code: 06 01 06. 7134. Organic acids.




14.1. UN number

Not applicable.


Not applicable.


Not applicable.

14.4. Packing group

Not applicable.



No.


Not applicable.








EU Legislation






WGK 1















76 /

SDS No. 11350

CITRIC ACID

Information Sources



Revision Comments

General revision.

Issued By Sarah Malone

Revision Date 28-Feb-13

Revision 6

Supersedes date 14-Mar-08

SDS No. 11350

Signature Laura McDonald

Signature 2 Sandra McWilliam


Irritating to eyes.R36


Causes serious eye irritation.H319

Disclaimer








77 /

SDS no. MI10031Version 10Revision date 10-Mar-2015Supersedes date 31-Jan-2012

Safety Data SheetCONQOR* 303A



Product name CONQOR* 303AProduct code MI10031


Recommended Use Corrosion inhibitor




Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600Netherlands National Poisons Information Center (NL): +31 30 274 88 88 (NB: this service is only

available to health professionals)




Health hazardsSkin corrosion/irritation Category 2Serious eye damage/eye irritation Category 1Skin sensitization Category 1



2.2 Label elements


[email protected]

________________________________________________________________________________________

Page 1 / 12

________________________________________________________________________________________

CONQOR* 303A SDS no. MI10031Revision date 10-Mar-2015

Signal wordDANGER

Hazard statementsH315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damage

Precautionary Statements - EU (§28, 1272/2008) P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP280 - Wear protective gloves/ protective clothing/ eye protection/ face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/ physicianP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP333 + P313 - If skin irritation or rash occurs: Get medical advice/ attention

Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP272 - Contaminated work clothing should not be allowed out of the workplaceP362 - Take off contaminated clothing and wash before reuseP501 - Dispose of contents/container in accordance with local regulations.



R-code(s)R38, R41, R43

ContainsEthanol, 2,2''-oxybis-, reaction products with ammonia, morpholine derivs. residues


2.3 Other data




3.1 Substances

Not Applicable

________________________________________________________________________________________

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________________________________________________________________________________________


3.2 Mixtures




REACHregistration

numberEthanol, 2,2''-oxybis-,reaction products withammonia, morpholine

derivs. residues

272-712-1 68909-77-3 30-60 Xi; R38, R41, R43 Skin Irrit.2(H315)Skin Sens. 1B(H317)Eye Dam. 1(H318)

01-2119537286-35-xxxx






Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention if irritation persists.

Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contactlenses, if present, after the first five minutes, then continue rinsing eye. Seek medicalattention at once.



Main symptoms









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Suitable extinguishing media

________________________________________________________________________________________


Water Fog, Alcohol Foam, CO2, Dry Chemical.















Methods for containmentPrevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.

Methods for cleaning upAbsorb with earth, sand or other non-combustible material and transfer to containers for later disposal. After cleaning, flush awaytraces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use. Persons susceptible to allergic reactions should not handle this product.

Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands beforeeating, drinking or smoking Remove contaminated clothing.

________________________________________________________________________________________

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________________________________________________________________________________________



Technical measures/precautions Ensure adequate ventilation.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid: Acids NitritesStore at room temperature.


Packaging material Use specially constructed containers only.


See Section 1.2.



Exposure limits Contains no substances with occupational exposure limit valuesNo biological limit allocated

Component EU OEL Austria Australia DenmarkEthanol, 2,2''-oxybis-, reaction products with

ammonia, morpholine derivs. residuesNot determined Not determined Not determined Not determined

Component Malaysia France Germany HungaryEthanol, 2,2''-oxybis-, reaction products with


Component New Zealand Italy Netherlands NorwayEthanol, 2,2''-oxybis-, reaction products with

ammonia, morpholine derivs. residuesNot Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaEthanol, 2,2''-oxybis-, reaction products with


Component Spain Switzerland Turkey UKEthanol, 2,2''-oxybis-, reaction products with



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Short term exposure systemic effects

________________________________________________________________________________________


Ethanol, 2,2''-oxybis-, reaction products with ammonia, morpholine derivs. residuesDermal 12.5 mg/kg

Inhalation 29.4 mg/m³

Long term exposure systemic effects

Ethanol, 2,2''-oxybis-, reaction products with ammonia, morpholine derivs. residuesDermal 12.5 mg/kg

Inhalation 29.4 mg/m³

Predicted No Effect Concentration (PNEC)Ethanol, 2,2''-oxybis-, reaction products with ammonia, morpholine derivs. residuesFresh water 0.12 mg/L

Sea water 0.012 mg/L

Fresh water sediment 0.636 mg/kgSea sediment 0.0636 mg/kgSoil 0.0566 mg/kg

Impact on sewage treatment 1000 mg/L

Intermittent release 12 mg/L



Engineering measures to reduce exposureEnsure adequate ventilation. Local exhaust ventilation.


goggles.Hand protection Use protective gloves made of:, Rubber, Neoprene, PVC, Be aware that liquid may

penetrate the gloves. Frequent change is advisable.Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient

ventilation wear suitable respiratory equipment, Use respirator with organic vapor protection(A, brown), At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.

Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available atthe work place.



________________________________________________________________________________________

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________________________________________________________________________________________


Appearance No information availableOdor SlightColor Dark AmberOdor threshold Not applicable


9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information available


10.1 Reactivity







Store at room temperature.


Physical state Liquid

Property Values Remarks pH Approximately 11.5pH @ dilutionMelting/freezing point No information availableBoiling point/range > 100 °CFlash point > 100 °C Closed cupEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.03 - 1.05 @ 20 °CBulk density No information availableRelative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availableLog Pow No information available

________________________________________________________________________________________

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________________________________________________________________________________________


Acids. Do not add nitrites or other nitrosating agents to this product. May cause formation of nitrosamine.





Acute toxicity

Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.

Eye contact Causes serious eye damage.

Skin contact Causes skin irritation. May cause an allergic skin reaction.



LD50 Oral 5000 mg/kg (based on components)LD50 Dermal > 2000 mg/kg (based on components)

Component LD50 Oral LD50 Dermal LC50 InhalationEthanol, 2,2''-oxybis-, reaction products with

ammonia, morpholine derivs. residues= 1500 mg/kg ( Rat ) No data available No data available

Sensitization May cause sensitization by skin contact.


Carcinogenicity This product does not contain any known or suspected carcinogens.


Routes of exposure Skin contact. Eye contact.

Routes of entry None known.


Not classified


Not classified.



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________________________________________________________________________________________


12.1 Toxicity


Toxicity to algaeEC50 72h : > 100 mg/l.

Toxicity to fishLC50 96h : > 100 mg/l.

Toxicity to daphnia and other aquatic invertebratesEC50 48h : > 100 mg/l.


Ethanol, 2,2''-oxybis-, reactionproducts with ammonia, morpholine

derivs. residues

No information available No information available No information available


Product is biodegradable.


No bioaccumulation expected due to high molecular weight.


MobilityThe product is water soluble, and may spread in water systems.




None known.



Waste from residues / unused Dispose of in accordance with local regulations.

________________________________________________________________________________________

Page 9 / 12

________________________________________________________________________________________


products










Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.






New Zealand hazard classification Irritant

HSNO approval no. HSR003599

Group number 6.4A, 9.1C

________________________________________________________________________________________

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Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European

________________________________________________________________________________________


Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning theRegistration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European ChemicalsAgency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.







ADG Code – Australian Dangerous Goods Code.

International inventories

USA (TSCA) CompliesEuropean Union (EINECS and ELINCS) CompliesCanada (DSL) CompliesPhilippines (PICCS) Does not ComplyJapan (ENCS) Does not ComplyChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) Does not ComplyNew Zealand (NZIoC) Complies






Supersedes date 31-Jan-2012

Revision date 10-Mar-2015

Version 10


Updated according to GHS/CLP, This SDS has been made in a new database andtherefore a new layout. There have been changes with regard to classification.

________________________________________________________________________________________

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Text of R phrases mentioned in Section 3R38 - Irritating to skin

________________________________________________________________________________________


R41 - Risk of serious damage to eyesR43 - May cause sensitization by skin contact


H315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damage

*A mark of M-I L.L.C., a Schlumberger Company


________________________________________________________________________________________

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Safety Data SheetDEFOAM†-A

SDS no. MI10199Version 6Revision date 07/Apr/2015Supersedes date 13/Sep/2010



Product name DEFOAM†-AProduct code MI10199


Recommended Use Defoamer











________________________________________________________________________________________

2.2 Label elements

SupplierM-I Australia Pty LtdLevel 5256 St. George TerracePerthWA 6000T= 08 9440 2900

Page 1 / 11

[email protected]

________________________________________________________________________________________

DEFOAM†-A SDS no. MI10199Revision date 07/Apr/2015

Signal wordWARNING


Precautionary Statements - EU (§28, 1272/2008) P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/protective clothing and eye/face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/ attentionP501 - Dispose of contents/container in accordance with local regulations.



R-code(s)Xi; R36

Contains

2,2,4-trimethylpentane-1,3-diol


2.3 Other data




3.1 Substances

________________________________________________________________________________________

Not Applicable

3.2 Mixtures

Page 2 / 11

________________________________________________________________________________________





REACHregistration

number2,2,4-trimethylpentane

-1,3-diol205-619-1 144-19-4 10 - 30 Xi; R36 Eye Irrit. 2 (H319) No data available







Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.



Main symptoms







________________________________________________________________________________________



Suitable extinguishing mediaDry chemical, CO 2, water spray or regular foam.


Page 3 / 11


________________________________________________________________________________________




















HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors orspray mist. Avoid spills and splashing during use.

________________________________________________________________________________________

Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands and facebefore breaks and immediately after handling the product. Remove contaminated clothing.



Storage precautions

Page 4 / 11

Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid contact with:Strong oxidizing agents

________________________________________________________________________________________





See Section 1.2.



Exposure limits Contains no substances with occupational exposure limit valuesNo biological limit allocated

Component EU OEL Austria Australia Denmark2,2,4-trimethylpentane-1,3-diol Not determined Not determined Not determined Not determined

Component Finland France Germany Hungary2,2,4-trimethylpentane-1,3-diol Not determined Not determined Not determined Not determined

Component New Zealand Italy Netherlands Norway2,2,4-trimethylpentane-1,3-diol Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania Russia2,2,4-trimethylpentane-1,3-diol Not determined Not determined Not determined Not determined

Component Spain Switzerland Turkey UK2,2,4-trimethylpentane-1,3-diol Not determined Not determined Not determined Not determined

________________________________________________________________________________________




Page 5 / 11


________________________________________________________________________________________


Eye protection It is good practice to wear goggles when handling any chemical. Tightly fitting safetygoggles.

Hand protection Use protective gloves made of:, Nitrile, Neoprene, Be aware that liquid may penetrate thegloves. Frequent change is advisable.

Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Use respirator with organic vapor protection(A, brown), At work in confined or poorly ventilated spaces, respiratory protection with airsupply must be used.





Appearance No information availableOdor SlightColor ColorlessOdor threshold Not applicable


9.2 Other information Pour point No information available


Property Values Remarks pH No information availablepH @ dilutionMelting/freezing point -50 °C / -58 °FBoiling point/range 225 °C / 437 °FFlash point 120 °C / 248 °F Closed cupEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density No information availableRelative density 0.95 sg @ 20°C.Water solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________


Page 6 / 11

Not determined

________________________________________________________________________________________


Molecular weight No information availableVOC content(%) NoneDensity No information available


10.1 Reactivity







None known.


Strong oxidizing agents.





Acute toxicity

Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system.





Component LD50 Oral LD50 Dermal LC50 Inhalation2,2,4-trimethylpentane-1,3-diol = 2 g/kg ( Rat ) = 6300 µL/kg ( Rabbit ) No data available

________________________________________________________________________________________



Page 7 / 11


________________________________________________________________________________________






Not classified


Not classified.



12.1 Toxicity






2,2,4-trimethylpentane-1,3-diol No information available No information available No information available


No product level data available.



________________________________________________________________________________________


Page 8 / 11


________________________________________________________________________________________





None known.











14.3 Hazard class(es) ADR/RID/ADN Hazard class Not regulatedIMDG Hazard class Not regulatedICAO Hazard class/division Not regulated

14.4 Packing group ADR/RID/ADN Packing Group Not regulatedIMDG Packing group Not regulatedICAO Packing group Not regulated


________________________________________________________________________________________


Page 9 / 11

________________________________________________________________________________________








New Zealand hazard classification Classified

HSNO approval no. HSR002503

Group number 6.3A










USA (TSCA) CompliesEuropean Union (EINECS and ELINCS) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) CompliesChina (IECSC) Complies

________________________________________________________________________________________

Australia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies

Page 10 / 11


________________________________________________________________________________________





Prepared by GRC-Chemicals (Global Regulatory Compliance - Chemicals) , Sarah Malone

Supersedes date 13/Sep/2010


Version 6



Text of R phrases mentioned in Section 2 and 3R36 - Irritating to eyes



________________________________________________________________________________________

†A mark of M-I L.L.C.


Page 11 / 11

Safety Data SheetDUO-TEC†

SDS no. MI10800Version 2Revision date 12/Aug/2014Supersedes date 05/Apr/2014



Product name DUO-TEC†

Product code MI10800


Recommended Use Viscosifier.











________________________________________________________________________________________

2.2 Label elements

Signal wordNone



Page 1 / 12

[email protected]

________________________________________________________________________________________

DUO-TEC† SDS no. MI10800Revision date 12/Aug/2014

EU specific hazard statementsEUH208 - Contains ( Glyoxal ). May produce an allergic reaction




Contains

Glyoxal


2.3 Other data




3.1 Substances

Not Applicable

3.2 Mixtures




REACHregistration

numberGlyoxal 203-474-9 107-22-2 <1 Xn; R20, Muta

cat.3 68Xi; R36/37/38, 43

Acute Tox. 4 (H332)Skin Irrit. 2 (H315)Eye Irrit. 2 (H319)

Skin Sens. 1B (H317)Muta. 2 (H341)

STOT SE 3 (H335)

No data available

________________________________________________________________________________________




Inhalation

Page 2 / 12

If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.

________________________________________________________________________________________







Main symptoms









Suitable extinguishing mediaWater Fog, Alcohol Foam, CO2, Dry Chemical.



Unusual fire and explosion hazardsDust may form explosive mixture in air.

Hazardous combustion productsFire or high temperatures create:, Carbon oxides (COx).


________________________________________________________________________________________




Page 3 / 12


________________________________________________________________________________________


Use personal protective equipment. See also section 8. If spilled, take caution, as material can cause surfaces to become veryslippery.






Methods for cleaning upSweep up and shovel into suitable containers for disposal. Prevent dust cloud. After cleaning, flush away traces with water.






Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands beforeeating, drinking or smoking. Remove contaminated clothing.


Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Keepaway from heat, sparks, and flame.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid contact with:Strong oxidizing agents Protect from moisture




See Section 1.2.



________________________________________________________________________________________


Page 4 / 12

________________________________________________________________________________________


Component EU OEL Austria Australia DenmarkGlyoxal Not determined Not determined Not determined 0.2 ppm Ceiling

0.5 mg/m3 Ceiling

Component Finland France Germany HungaryGlyoxal Not determined Not determined Not determined Not determined

Component New Zealand Italy Netherlands NorwayGlyoxal Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaGlyoxal Not determined 0.1 mg/m3 TWA

inhalable fraction,aerosol and vapor

Not determined Not determined

Component Spain Switzerland Turkey UKGlyoxal 0.1 mg/m3 VLA-ED it is

prohibited the partial orcomplete

commercialization or useof this substance as a

phytosanitary o biocidecompound inhalablefraction and vapor

Not determined Not determined Not determined


Long term exposure local effectsGlyoxalInhalation 0.04 mg/m³


GlyoxalDermal 10.8 mg/kgInhalation 5.29 mg/m³

Predicted No Effect Concentration (PNEC)GlyoxalFresh water 0.319 mg/lSea water 0.0319 mg/lFresh water sediment 0.685 mg/lSea sediment 0.0685 mg/lSoil 4.06 mg/l

________________________________________________________________________________________

Impact on sewage treatment 4.1 mg/lIntermittent release 1.1 mg/l

Page 5 / 12


________________________________________________________________________________________





goggles.Hand protection Repeated or prolonged contact:, Use protective gloves made of:, Butyl, Neoprene, Nitrile.Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient

ventilation wear suitable respiratory equipment, Half mask with a particle filter P2(European Norm EN 143 = former DIN 3181).





Appearance Powder DustOdor MildColor Cream - TanOdor threshold Not applicable


Property Values Remarks pH Not applicablepH @ dilution 7 @ 1% sol.Melting/freezing pointBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1)Flammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.5 20 °CBulk density 50 lb/ft³ (800 kg/m³)Relative density No information availableWater solubility Soluble in water

________________________________________________________________________________________

Solubility in other solvents No information availableAutoignition temperature > 200 °CDecomposition temperature

Page 6 / 12


________________________________________________________________________________________





10.1 Reactivity







Heat, flames and sparks. Protect from moisture.







Acute toxicity





________________________________________________________________________________________


Page 7 / 12

Not determined

________________________________________________________________________________________


Component LD50 Oral LD50 Dermal LC50 InhalationGlyoxal = 3300 mg/kg ( Rat ) No data available = 2410 mg/m³, 3-4 hrs

Sensitization Repeated or prolonged contact may cause allergic reactions in very susceptible persons.

Mutagenic effects Contains no ingredients above reportable quantities listed as a mutagenic.



Routes of exposure None known.



Not classified


Not classified.



12.1 Toxicity





Component Toxicity to fish Toxicity to algae

________________________________________________________________________________________

Toxicity to daphnia and otheraquatic invertebrates

Glyoxal 215 mg/L LC50 (Pimephalespromelas) = 96 h

460 - 680 mg/L LC50 (Leuciscusidus) = 96 h

500 mg/L EC50 (Desmodesmussubspicatus) = 72 h348.59 mg/L EC50

(Pseudokirchneriella subcapitata) =96 h

500 mg/L EC50 (Desmodesmussubspicatus) = 96 h

404 mg/L EC50 (Daphnia magna) =48 h


Page 8 / 12

The product contains substances which are not expected to be biodegradable.

________________________________________________________________________________________









None known.






EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 07 01 99.





14.3 Hazard class(es)

________________________________________________________________________________________

ADR/RID/ADN Hazard class Not regulatedIMDG Hazard class Not regulatedICAO Hazard class/division Not regulated

Page 9 / 12

14.4 Packing group

________________________________________________________________________________________


ADR/RID/ADN Packing Group Not regulatedIMDG Packing group Not regulatedICAO Packing group Not regulated















________________________________________________________________________________________





Page 10 / 12


________________________________________________________________________________________










Supersedes date 05/Apr/2014

Revision date 12/Aug/2014

Version 2


2. Hazards Identification, 3. Composition/information on Ingredients, 11. Toxicologicalinformation, Section 16: Other information, Updated according to GHS/CLP.

Text of R phrases mentioned in Section 2 and 3R20 - Harmful by inhalationR43 - May cause sensitization by skin contactR68 - Possible risks of irreversible effects.

R36/37/38 - Irritating to eyes, respiratory system and skin


This product is not classified as hazardous therefore no (H) hazard statements assigned.

________________________________________________________________________________________

H332 - Harmful if inhaledH315 - Causes skin irritationH319 - Causes serious eye irritationH317 - May cause an allergic skin reactionH341 - Suspected of causing genetic defects if inhaledH335 - May cause respiratory irritationEUH208 - Contains ( Glyoxal ). May produce an allergic reaction

Page 11 / 12


________________________________________________________________________________________



________________________________________________________________________________________

Page 12 / 12

Safety Data SheetDUO-VIS†

SDS no. MI10216Version 8Revision date 08/Aug/2014Supersedes date 06/May/2014



Product name DUO-VIS†



Recommended Use Viscosifier.











________________________________________________________________________________________

2.2 Label elements

Signal wordNone



Page 1 / 11

[email protected]

________________________________________________________________________________________

DUO-VIS† SDS no. MI10216Revision date 08/Aug/2014

EU specific hazard statementsEUH208 - Contains ( Glyoxal ). May produce an allergic reaction




Contains

Glyoxal


2.3 Other data



3.1 Substances

Not Applicable

3.2 Mixtures




REACHregistration

numberGlyoxal 203-474-9 107-22-2 <1 Xn; R20, Muta

cat.3 68Xi; R36/37/38, 43

Acute Tox. 4 (H332)Skin Irrit. 2 (H315)Eye Irrit. 2 (H319)

Skin Sens. 1B (H317)Muta. 2 (H341)

STOT SE 3 (H335)

No data available



________________________________________________________________________________________



Ingestion

Page 2 / 11

Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.

________________________________________________________________________________________






Main symptoms
















________________________________________________________________________________________




Page 3 / 11

Use personal protective equipment. See also section 8. If spilled, take caution, as material can cause surfaces to become veryslippery.

________________________________________________________________________________________







Methods for cleaning upSweep up and shovel into suitable containers for disposal. Prevent dust cloud. After cleaning, flush away traces with water.





HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.

Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands beforeeating, drinking or smoking. Remove contaminated clothing.


Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Keepaway from heat, sparks, and flame.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid contact with:Strong oxidizing agents Protect from moisture




See Section 1.2.



________________________________________________________________________________________

Page 4 / 11

________________________________________________________________________________________


Component EU OEL Austria Australia DenmarkGlyoxal Not determined Not determined Not determined 0.2 ppm Ceiling

0.5 mg/m3 Ceiling

Component Finland France Germany HungaryGlyoxal Not determined Not determined Not determined Not determined

Component New Zealand Italy Netherlands NorwayGlyoxal Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaGlyoxal Not determined 0.1 mg/m3 TWA

inhalable fraction,aerosol and vapor


Component Spain Switzerland Turkey UKGlyoxal 0.1 mg/m3 VLA-ED it is

prohibited the partial orcomplete

commercialization or useof this substance as a

phytosanitary o biocidecompound inhalablefraction and vapor



Long term exposure local effectsGlyoxalInhalation 0.04 mg/m³


GlyoxalDermal 10.8 mg/kgInhalation 5.29 mg/m³

Predicted No Effect Concentration (PNEC)GlyoxalFresh water 0.319 mg/lSea water 0.0319 mg/lFresh water sediment 0.685 mg/lSea sediment 0.0685 mg/lSoil 4.06 mg/lImpact on sewage treatment

________________________________________________________________________________________

4.1 mg/lIntermittent release 1.1 mg/l


Page 5 / 11


________________________________________________________________________________________




goggles.Hand protection Repeated or prolonged contact:, Use protective gloves made of:, Butyl, Neoprene, Nitrile.Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient






Appearance Powder DustOdor MildColor Cream - TanOdor threshold Not applicable



Property Values Remarks pH Not applicablepH @ dilution 7 @ 1% sol.Melting/freezing pointBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1)Flammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.5 20 °CBulk density 50 lb/ft³ (800 kg/m³)Relative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature > 200 °CDecomposition temperature No information available

________________________________________________________________________________________


Page 6 / 11

Not determined

________________________________________________________________________________________




10.1 Reactivity







Heat, flames and sparks. Protect from moisture.







Acute toxicity





Unknown acute toxicity .

Component LD50 Oral LD50 Dermal LC50 InhalationGlyoxal

________________________________________________________________________________________

= 3300 mg/kg ( Rat ) No data available = 2410 mg/m³, 3-4 hrs

Sensitization Repeated or prolonged contact may cause allergic reactions in very susceptible persons.

Page 7 / 11

Mutagenic effects Contains no ingredients above reportable quantities listed as a mutagenic.

________________________________________________________________________________________







Not classified


Not classified.



12.1 Toxicity






Glyoxal 215 mg/L LC50 (Pimephalespromelas) = 96 h

460 - 680 mg/L LC50 (Leuciscusidus) = 96 h

500 mg/L EC50 (Desmodesmussubspicatus) = 72 h348.59 mg/L EC50

(Pseudokirchneriella subcapitata) =96 h



________________________________________________________________________________________


The product contains substances which are not expected to be biodegradable.



Page 8 / 11

________________________________________________________________________________________







None known.












14.4 Packing group ADR/RID/ADN Packing Group Not regulated

________________________________________________________________________________________

IMDG Packing group Not regulatedICAO Packing group Not regulated

Page 9 / 11

14.5 Environmental hazard

________________________________________________________________________________________


No
















Prepared by

________________________________________________________________________________________

Global Regulatory Compliance - Chemicals (GRC - Chemicals)

Supersedes date 06/May/2014

Revision date 08/Aug/2014

Page 10 / 11

Version 8

________________________________________________________________________________________



2. Hazards Identification, 3. Composition/information on Ingredients, 11. Toxicologicalinformation, Section 16: Other information.

Text of R phrases mentioned in Section 2 and 3Not classifiedR20 - Harmful by inhalationR43 - May cause sensitization by skin contactR68 - Possible risks of irreversible effects.

R36/37/38 - Irritating to eyes, respiratory system and skin


This product is not classified as hazardous therefore no (H) hazard statements assigned.H332 - Harmful if inhaledH315 - Causes skin irritationH319 - Causes serious eye irritationH317 - May cause an allergic skin reactionH341 - Suspected of causing genetic defects if inhaledH335 - May cause respiratory irritationEUH208 - Contains ( Glyoxal ). May produce an allergic reaction

________________________________________________________________________________________



Page 11 / 11

SDS no. PID686Version 8Revision date 15-Jun-2017Supersedes date 01-Aug-2014

Safety Data SheetG-SEAL*



Product name G-SEAL*

Product code PID686Synonyms G-SEAL* FINEDenmark Pr. no: 1203433


Recommended Use Plugging agent.




Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600Denmark Poison Control Hotline (DK): +45 82 12 12 12Germany +49 69 222 25285Norway Poison information centre: +47 22 59 13 00

2. Hazards Identification


Classification according to Regulation (EC) No. 1272/2008 [CLP]





[email protected]

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

G-SEAL* SDS no. PID686Revision date 15-Jun-2017

2.2 Label elements

Signal wordNone



ContainsGraphite

2.3 Other hazards




3.1 Substances

Chemical Name EC No CAS No Weight-% Regulation (EC) No1272/2008

REACHregistration

numberGraphite 231-955-3 7782-42-5 60-100 Not classified 01-2119486977-1

2-xxxx

3.2 Mixtures

Not applicable


4.1 First aid measures



Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Eye Contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses. Getmedical attention if any discomfort continues.



Symptoms










Extinguishing media which must not be used for safety reasonsNone known.



Hazardous combustion productsFire or high temperatures create: Carbon oxides (COx).






Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Use personal protective equipment. See also section 8.

_____________________________________________________________________________________________

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_____________________________________________________________________________________________




6.3 Methods and material for containment and cleaning up

Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading.






HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Keep away from heat and sources of ignition.




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away fromopen flames, hot surfaces and sources of ignition. Protect from moisture Avoid contact with:Oxidizing agents


Packaging materials Use specially constructed containers only.


See Section 1.2.




Chemical Name EU OEL Austria Australia DenmarkGraphite Not determined 10 mg/m3 STEL alveolar

dust with <1% Quartz,respirable fraction

3mg/m3TWArespirabledust

2.5 mg/m3 TWA

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_____________________________________________________________________________________________


5 mg/m3 TWA alveolardust with <1% Quartz,

respirable fractionChemical Name Malaysia France Germany Hungary

Graphite 2 mg/m3 TWA 2 mg/m3TWA 1.5 mg/m3 TWA4 mg/m3 TWA

Not determined

Chemical Name New Zealand Italy Netherlands NorwayGraphite 3 mg/m3 TWA Not determined Not determined 5 mg/m3 TWA total dust

2 mg/m3 TWA respirabledust

10 mg/m3 TWA totaldust


10 mg/m3 STEL totaldust

4 mg/m3 STELrespirable dust

15 mg/m3 STEL totaldust

8 mg/m3 STELrespirable dust

Chemical Name Poland Portugal Romania RussiaGraphite 4.0 mg/m3 TWA NDS

natural1.0 mg/m3 TWA NDS

natural6.0 mg/m3 TWA NDS

synthetic

2 mg/m3 TWA all formsexcept Graphite fibers

respirable fraction

2mg/m3TWAdust,respirable fraction

Not determined

Chemical Name Spain Switzerland Turkey UKGraphite 2 mg/m3 TWA VLA-ED 2.5 mg/m3 TWA MAK

natural5 mg/m3 TWA MAK

natural

Not determined 30 mg/m3 STELcalculated inhalable

dust12 mg/m3 STEL

calculated respirabledust

10 mg/m3 TWAinhalable dust




Engineering ControlsEnsure adequate ventilation.

Personal protective equipmentEye protection Use eye protection according to EN 166, designed to protect against powders and dusts.

Tightly fitting safety goggles. Safety glasses with side-shields.Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Use

protective gloves made of: Neoprene Nitrile Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment, Suitable mask with

particle filter P3 (European Norm 143), At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used, No personal respiratory protectiveequipment normally required.


_____________________________________________________________________________________________

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_____________________________________________________________________________________________





Appearance Powder DustOdor OdorlessColor Gray - BlackOdor threshold Not applicable

Explosive properties Suspended dust may present a dust explosion hazardOxidizing properties None known.


CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.



Property Values Remarks pH No information availablepH @ dilutionMelting / freezing point 3652 °C / 6605.6 °FBoiling point/range 4827 °C / 8720.6 °FFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 2.19 - 2.26 20 °CBulk density No information availableRelative density No information availableWater solubility Insoluble in waterSolubility in other solvents No information availableAutoignition temperature > 500 °C / 932 °FDecomposition temperature > 400 °C / 752°FKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


10.1 Reactivity

Dust may form explosive mixture in air.






Keep away from open flames, hot surfaces and sources of ignition. Avoid dust formation. Protect from moisture.


Oxidizing agents.


See Section 5.2.



Acute toxicity


Eye contact Dust may cause mechanical irritation.



Unknown acute toxicity Not applicable.

Toxicology data for the componentsChemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Graphite LD50 > 2000 mg/kg bw, Rat,OECD 423

No data available LD50 > 2000 mg/m³, Rat,OECD 403




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_____________________________________________________________________________________________





Specific target organ toxicity -Single exposure

Not classified

Specific target organ toxicity -Repeated exposure

Not classified.

Aspiration hazard Not applicable.


12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.Listed on PLONOR list of OSPAR




Chemical Name Toxicity to fish Toxicity to algae Toxicity to daphnia and otheraquatic invertebrates

Graphite LC50 > 100 mg/l, 96 hour, OECD203

EC50 > 100 mg/l, 72 hour, OECD201

EC50 > 100 mg/l, 48 hour, OECD202






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_____________________________________________________________________________________________






None known.






EWC Waste Disposal No According to the European Waste Catalog, Waste Codes are not product specific, butapplication specific Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 01 05 99 - wastes not otherwise specified


14.1. UN number Not regulated

14.2. UN proper shipping name The product is not covered by international regulation on the transport of dangerous goods





_____________________________________________________________________________________________

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_____________________________________________________________________________________________


Not applicable

14.7 Transport in bulk according to Annex I/II of MARPOL 73/78 and the IBC CodePlease contact [email protected] for info regarding transport in Bulk.




Water endangering class = Nwg

Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated






National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)].National Occupational Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances[NOHSC:1008 (2004) 3rd Edition].National Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in theoccupational Environment [NOHSC:1003 (1995)].



Not classified as dangerous goods in accordance with the Australian Code for the Transport of Dangerous Goods byRoad and Rail (ADG).




USA (TSCA) CompliesEuropean Union (EINECS and ELINCS) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) Does not Comply

_____________________________________________________________________________________________

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_____________________________________________________________________________________________


China (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies





Supersedes date 01-Aug-2014

Revision date 15-Jun-2017

Version 8

This SDS has been revised in thefollowing section(s)

All sections Product Code change No changes with regard to classification have beenmade.



*A mark of M-I L.L.C., a Schlumberger Company


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Safety Data SheetKLEEN UP†

SDS no. MI10834Version 3Revision date 17/Feb/2015Supersedes date 21/Feb/2011



Product name KLEEN UP†



Recommended Use Detergent

Uses advised against None known.










________________________________________________________________________________________

2.2 Label elements


Page 1 / 11

[email protected]

________________________________________________________________________________________

KLEEN UP† SDS no. MI10834Revision date 17/Feb/2015

Signal wordDANGER

Hazard statementsH318 - Causes serious eye damage

Precautionary Statements - EU (§28, 1272/2008) P280 - Wear protective gloves/ protective clothing/ eye protection/ face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/ physician



R-code(s)R41

Contains

Alcohols, C11-14-iso-, C13-rich, ethoxylated


2.3 Other data




3.1 Substances

Not Applicable

3.2 Mixtures

________________________________________________________________________________________




Page 2 / 11

REACHregistration

number

________________________________________________________________________________________


Alcohols, C11-14-iso-,C13-rich, ethoxylated

78330-21-9 10-30 Xn; R22Xi; R41

Acute Tox. 4 (H302)Eye Dam. 1 (H318)

Polymer exempt







Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contactlenses, if present, after the first five minutes, then continue rinsing eye. Seek medicalattention at once.



Main symptoms








________________________________________________________________________________________





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________________________________________________________________________________________




















Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Wash thoroughly after handling. Do not eat, drink or smokewhen using this product. Remove contaminated clothing.


Technical measures/precautions

________________________________________________________________________________________

Ensure adequate ventilation.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Do not freeze


Page 4 / 11


________________________________________________________________________________________



See Section 1.2.



Exposure limits Contains no substances with occupational exposure limit values No biological limit allocated

Component EU OEL Austria Australia DenmarkAlcohols, C11-14-iso-, C13-rich, ethoxylated Not determined Not determined Not determined Not determined

Component Finland France Germany HungaryAlcohols, C11-14-iso-, C13-rich, ethoxylated Not determined Not determined Not determined Not determined

Component New Zealand Italy Netherlands NorwayAlcohols, C11-14-iso-, C13-rich, ethoxylated Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaAlcohols, C11-14-iso-, C13-rich, ethoxylated Not determined Not determined Not determined Not determined

Component Spain Switzerland Turkey UKAlcohols, C11-14-iso-, C13-rich, ethoxylated Not determined Not determined Not determined Not determined



________________________________________________________________________________________



goggles.

Page 5 / 11

Hand protection Use protective gloves made of:, Neoprene, PVC, Be aware that liquid may penetrate thegloves. Frequent change is advisable.

________________________________________________________________________________________


Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Use respirator with organic vapor protection(A, brown).





Appearance No information availableOdor slight amineColor Clear YellowOdor threshold Not applicable


9.2 Other information Pour point </= 0°CMolecular weight No information availableVOC content(%) No information availableDensity No information available



Property Values Remarks pH 6.5 - 8.5pH @ dilutionMelting/freezing pointBoiling point/range ~ 100 °CFlash point > 100 °C PMCCEvaporation rate (BuAc =1)Flammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.02 s.g @ 20 °CBulk density No information availableRelative density No information availableWater solubility Miscible with water.Solubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________


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Not determined

________________________________________________________________________________________


10.1 Reactivity







Do not freeze.







Acute toxicity

Inhalation May cause irritation.




Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity.

Component LD50 Oral LD50 Dermal LC50 InhalationAlcohols, C11-14-iso-, C13-rich, ethoxylated No data available No data available No data available



Carcinogenicity

________________________________________________________________________________________

This product does not contain any known or suspected carcinogens.

Page 7 / 11

________________________________________________________________________________________




Routes of entry Skin absorption.


Not classified


Not classified.



12.1 Toxicity






Alcohols, C11-14-iso-, C13-rich,ethoxylated






________________________________________________________________________________________


MobilityThe product is miscible with water. May spread in water systems.


Page 8 / 11


________________________________________________________________________________________



None known.






EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 07 01 04 Waste Code: 7152 Organic waste without halogen.








________________________________________________________________________________________



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________________________________________________________________________________________



















Prepared by

________________________________________________________________________________________

Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sarah Malone

Supersedes date 21/Feb/2011

Revision date 17/Feb/2015

Page 10 / 11

Version 3

________________________________________________________________________________________



This SDS has been made in a new database and therefore a new layout. There have beenchanges with regard to classification, Updated according to GHS/CLP.

Text of R phrases mentioned in Section 2 and 3R22 - Harmful if swallowedR41 - Risk of serious damage to eyes


H318 - Causes serious eye damageH302 - Harmful if swallowed

________________________________________________________________________________________



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Safety Data SheetLIME

SDS no. MI10290Version 7Revision date 09/Jul/2015Supersedes date 15/Apr/2013



Product name LIMEProduct code MI10290Synonyms CALCIUM HYDROXIDE, HYDRATKALKNorway Pr. no. 46235Denmark Pr. no.: 342757


Recommended Use pH modifier








Health hazardsSkin corrosion/irritation Category 2Serious eye damage/eye irritation Category 1Specific target organ toxicity(single exposure)

Category 3

________________________________________________________________________________________



Page 1 / 12

[email protected]

________________________________________________________________________________________

LIME SDS no. MI10290Revision date 09/Jul/2015


2.2 Label elements

Signal wordDANGER

Hazard statementsH315 - Causes skin irritationH318 - Causes serious eye damageH335 - May cause respiratory irritation

Precautionary Statements - EU (§28, 1272/2008) P261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP280 - Wear protective gloves/ protective clothing/ eye protection/ face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/ physicianP501 - Dispose of contents/container in accordance with local regulations.

Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathingP332 + P313 - If skin irritation occurs: Get medical advice/ attentionP362 - Take off contaminated clothing and wash before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closed

ContainsCalcium hydroxide

2.3 Other data


________________________________________________________________________________________



3.1 Substances

Page 2 / 12

________________________________________________________________________________________





REACHregistration

numberCalcium hydroxide 215-137-3 1305-62-0 60-100 Xi; R37/38

Xi; R41Eye Dam. 1 (H318) Skin Irrit. 2 (H315)STOT SE 3 (H335)

01-2119475151-45-xxxx

3.2 Mixtures

Not Applicable






Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses.Continue to rinse for at least 15 minutes. Get immediate medical attention.



Main symptoms






________________________________________________________________________________________




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Suitable extinguishing mediaAlcohol Foam, CO2, Dry Chemical.

________________________________________________________________________________________


Extinguishing media which shall not be used for safety reasonsWater.














Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.

Methods for cleaning upAvoid dust formation. Sweep up and shovel into suitable containers for disposal. After cleaning, flush away traces with water.




________________________________________________________________________________________



Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product. Washhands and face before breaks and immediately after handling the product Remove contaminated clothing.


Page 4 / 12


________________________________________________________________________________________


Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moistureAvoid contact with: Acids




See Section 1.2.




Component EU OEL Austria Australia DenmarkCalcium hydroxide Not determined Not determined 5 mg/m3 TWA 5 mg/m3 TWA

Component Malaysia France Germany HungaryCalcium hydroxide 5 mg/m3 TWA 5 mg/m3 1 mg/m3 TWA Not determined

Component New Zealand Italy Netherlands NorwayCalcium hydroxide 5 mg/m3 TWA Not determined 5 mg/m3 5 mg/m3 TWA

10 mg/m3 STEL

Component Poland Portugal Romania RussiaCalcium hydroxide 2 mg/m3 TWA NDS 5 mg/m3 TWA indicative

limit value5 mg/m3 TWA 2 mg/m3 MAC

Skin

Component Spain Switzerland Turkey UKCalcium hydroxide 5 mg/m3 TWA VLA-ED 5 mg/m3 TWA MAK 5 mg/m3 TWA 15 mg/m3 STEL

calculated5 mg/m3 TWA


Short term exposure local effects

________________________________________________________________________________________

Calcium hydroxideInhalation 4 mg/m³

Long term exposure local effectsCalcium hydroxide

Page 5 / 12

Inhalation 1 mg/m³

________________________________________________________________________________________


Predicted No Effect Concentration (PNEC)Calcium hydroxideFresh water 0.49 mg/LSea water 0.32 mg/LSoil 1080 mg/kgImpact on sewage treatment 3 mg/LIntermittent release 0.49 mg/L




Personal protective equipmentEye protection It is good practice to wear Safety Glasses with Side-shields when handling any chemical.Hand protection Use protective gloves made of:, Nitrile, Frequent change is advisable.Respiratory protection Half mask with a particle filter P2 (European Norm EN 143 = former DIN 3181), At work in

confined or poorly ventilated spaces, respiratory protection with air supply must be used.Skin and body protection Wear suitable protective clothing, Eye wash and emergency shower must be available at

the work place.




Appearance PowderOdor OdorlessColor White - Off-whiteOdor threshold Not applicable


Property Values Remarks pH 12.4pH @ dilutionMelting/freezing point > 450 °C / > 842 °FBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not ApplicableFlammability Limits in Air

Upper flammability limit

________________________________________________________________________________________

Not applicableLower flammability limit Not applicable

Vapor pressure

Page 6 / 12


________________________________________________________________________________________



9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) NoneDensity No information availableParticle Size (Micron) < 500


10.1 Reactivity

Exothermic reaction with:. Acids.






Avoid dust formation. Protect from moisture.


Acids. Water.





Acute toxicity

Inhalation May cause respiratory irritation.


Vapor density No information availableSpecific gravity 2.24 @ 20 °CBulk density 400 kg/m³Relative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________


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Not determined

________________________________________________________________________________________


Skin contact Causes skin irritation.



Component LD50 Oral LD50 Dermal LC50 InhalationCalcium hydroxide = 7340 mg/kg ( Rat ) No data available No data available





Routes of exposure Skin contact. Inhalation. Eye contact.



Category 3


Not classified.

Target organ effects Respiratory system.



________________________________________________________________________________________

12.1 Toxicity

The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. The product may affect the acidity (pH-factor) inwater with risk of harmful effects to aquatic organisms.




Page 8 / 12


________________________________________________________________________________________



Calcium hydroxide 160 mg/L LC50 (Gambusia affinis) =96 h

No information available No information available










None known.





Contaminated packaging

________________________________________________________________________________________

Empty containers should be taken for local recycling, recovery or waste disposal.

EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 06 03 14 - solid salts and solutions other than those mentioned in 06 0311 and 06 03 13 Waste Code: 7132 Inorganic bases.


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________________________________________________________________________________________















________________________________________________________________________________________





Page 10 / 12


________________________________________________________________________________________












Supersedes date 15/Apr/2013

Revision date 09/Jul/2015

Version 7


All sections, Updated according to GHS/CLP, No changes with regard to classification havebeen made.

Text of R phrases mentioned in Section 3R41 - Risk of serious damage to eyes

________________________________________________________________________________________

R37/38 - Irritating to respiratory system and skin


H315 - Causes skin irritationH318 - Causes serious eye damageH335 - May cause respiratory irritation

Page 11 / 12

________________________________________________________________________________________



________________________________________________________________________________________

Page 12 / 12


Revision 5


SDS No. 11193

SAFETY DATA SHEET

MAGNESIUM OXIDE



Product name MAGNESIUM OXIDE

REACH Registration notes This product is exempt from REACH registration according to EC Regulation 1907/2006 Article 2 § 7 b

and Annex V, point 7.


Identified uses pH modifier.



Level 5

256 St. George Tce

Perth

WA 6000

T = 08 9440 2900













2.2. Label elements






2.3. Other hazards



3.1. Substances

71 /

SDS No. 11193

MAGNESIUM OXIDE

MAGNESIUM OXIDE 60-100%

CAS-No.: 1309-48-4 EC No.: 215-171-9


Not classified.


Not classified.


REACH Registration notes This product is exempt from REACH registration according to EC Regulation 1907/2006 Article 2 § 7 b

and Annex V, point 7.





Inhalation


continues.

Ingestion


continues.

Skin contact


washing.

Eye contact




General information







Extinguishing media















72 /

SDS No. 11193

MAGNESIUM OXIDE




Remove sources of ignition. Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the

area with water.









Store in tightly closed original container in a dry, cool and well-ventilated place. Avoid contact with: Water, moisture. Interhalogens

Aluminium. Magnesium. Powder. Avoid contact with acids. Oxidising materials.

Storage Class

Chemical storage.






10 mg/m3WELMAGNESIUM OXIDE as Mg





Process conditions









Respiratory protection must be used if air contamination exceeds acceptable level. Dust filter P2 (for fine dust).

Hand protection

For prolonged or repeated skin contact use suitable protective gloves. Rubber or plastic.

Eye protection


Other Protection


73 /

SDS No. 11193

MAGNESIUM OXIDE

Hygiene measures





Appearance Solid

Colour White.

Odour Odourless.

Solubility Insoluble in water


(°C)

3600°C


Relative density 3.58 - 3.65 g/cm3

pH-Value, Conc. Solution 10.3 @ 20°C


H2O@20°C)

0.006 g/l


Not relevant


10.1. Reactivity





Avoid contact with: Interhalogens


Avoid contact with: Water, moisture.


Materials To Avoid

Avoid contact with acids. Oxidising materials. Aluminium. Magnesium. Powder.





Acute toxicity:


> 2 mg/kg Rabbit

Aspiration hazard:


Inhalation


Ingestion


74 /

SDS No. 11193

MAGNESIUM OXIDE

Skin contact


Eye contact


Route of entry


Target Organs



Ecotoxicity


PLONOR.

12.1. Toxicity

Acute Fish Toxicity

Not considered toxic to fish.


Degradability






Mobility:

The product is insoluble in water.




None known.




Waste Class





14.1. UN number

Not applicable.


Not applicable.


Not applicable.

75 /

SDS No. 11193

MAGNESIUM OXIDE

14.4. Packing group

Not applicable.



No.


Not applicable.








EU Legislation






WGK 1











This product is exempt from REACH registration according to EC Regulation 1907/2006 Article 2 § 7 b and Annex V, point 7. Contact

[email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:




Information Sources



Revision Comments

The following sections have been revised: 11

Issued By Sandra McWilliam


Revision 5


SDS No. 11193

Safety Data Sheet Status Approved.

Date 12-09-2013


Signature 2 Sarah Malone

76 /

SDS No. 11193

MAGNESIUM OXIDE


Not classified.NC

Disclaimer








77 /

MATERIAL SAFETY DATA SHEET

MSDS No. 10038 Trade Name M-I-X† II Revision date 24/Sep/2013

1. Chemical product and company identification

Trade Name M-I-X† II

Chemical Family CelluloseUse of thesubstance/preparation

Oil well drilling fluid additive. Lost circulation material.

Supplied by M-I PRODUCTION TECHNOLOGIESA Business Unit of M-I L.L.C.P.O. Box 42842Houston, TX 77242www.miswaco.slb.com

Telephone Number 281-561-1511Emergency Telephone (24 hr.) 281-561-1600Prepared by Chemical Regulatory Compliance (CRC):

Version 9

HMIS health rating

4=Severe, 3=Serious, 2=Moderate, 1=Slight, 0=Minimal Hazard. *Chronic effects - See Section 11. See Section 8 forPersonal Protective Equipment recommendations.


Emergency Overview: CAUTION. Long term inhalation of particulates may cause lung damage. Containscrystalline silica which may cause cancer. Cancer hazard. May cause mechanicalirritation of eyes, skin and respiratory tract.

Canadian Classification

Potential Health EffectsAcute Effects

Eye contact May cause mechanical irritation.Skin contact Long term contact can cause skin dryness. May cause mechanical irritation.Inhalation May cause mechanical irritation.Ingestion May cause gastric distress, nausea and vomiting if ingested.

Chronic toxicity: See Section 11 - Toxicological Information.Principle routes of exposure Dermal (skin) contact. Eyes. Inhalation.Target Organs/MedicalConditions Aggravated byOverexposure

Eyes. Skin. Respiratory system.

Health 1* Flammability 1 Physical hazard 0 PPE E

UN PIN No Not regulated. WHMIS HazardClass

D2A

Physical state Solid Color Tan Odor Mild (or faint)

M-I-X† IIMSDS No. 10038 Revision date 24/Sep/2013 Page 2 / 7


Component CAS-No Weight % - range CommentsCellulose 9004-34-6 60 - 100 No comments.Silica, crystalline, quartz 14808-60-7 1 - 5 No comments.

Composition Comments Component LD50 and LC50 values are provided in Section 11, if available.


Eye contact Promptly wash eyes with lots of water while lifting eye lids. Look for and removecontact lenses. Continue to rinse for at least 15 minutes. Get medical attention ifany discomfort continues.

Skin contact Wash skin thoroughly with soap and water. Remove contaminated clothing andlaunder before reuse. Get medical attention if any discomfort continues.

Inhalation Move person to fresh air. If breathing is difficult, give oxygen. If not breathing, giveartificial respiration. Get medical attention.

Ingestion Dilute with 2 - 3 glasses of water or milk, if conscious. If signs of irritation ortoxicity occur seek medical attention. Never give anything by mouth to anunconscious person.

General notes Persons seeking medical attention should carry a copy of this MSDS with them.Notes to physician Treat symptomatically.

5. Fire fighting measures

Flammable properties

Flash Point Not DeterminedFlammability Limits in AirLower No information availableUpper No information availableAutoignition Temperature °F (°C) N/DExplosion data - sensitivity to mechanical impact N/AExplosion data - sensitivity to static discharge If applicable, information is provided in Section 5 Special

Fire-Fighting Procedures, Other Flammable Properties andSection 6 Spill Procedures.

Flammability Class NAExtinguishing Media Use extinguishing media appropriate for surrounding fire.

Protection Of Fire-Fighters

Special Fire-Fighting Procedures Evacuate area and fight fire from a safe distance. Water spray may be used tokeep fire-exposed containers cool. Do not enter fire area without proper personal protective equipment, includingNIOSH/MSHA approved self-contained breathing apparatus. Keep water run off out of sewers and waterways.

Hazardous combustion products Oxides of: Carbon.

Conditions of Flammability Products are classified as flammable/combustible based on flash point as defined in theHealth Canada Controlled Products Regulations, U.S. Occupational Health and Safety Administration HazardCommunication Standard and transportation regulations. See Sections 1, 2, 5, 14 and 15 for flammable/combustibleclassification information. Flammable/combustible materials may ignite and burn if exposed to a flame or othersources of ignition.


Other Flammable Properties Palleted bags of some fine cellulosic materials have been reported to smolder undercertain conditions. See Section 7 Handling and Storage. Particulate may accumulate static electricity. Dusts atsufficient concentrations can form explosive mixtures with air.


Personal precautions Use personal protective equipment identified in Section 8.

Spill procedures Evacuate the spill area with the exception of the spill response team. Containspilled material. Avoid the generation of dust. Sweep, vacuum, or shovel andplace into closable container for disposal. Wet product may create a slippinghazard. Do not allow spilled material to enter sewers, storm drains or surfacewaters.

Environmental precautions Waste must be disposed of in accordance with federal, state and local laws.


Handling Put on appropriate personal protective equipment. Use only in a well ventilatedarea. Avoid contact with skin and eyes. Avoid generating or breathing dust.Product is slippery if wet. Wash thoroughly after handling.

Storage Store in a well-ventilated place. Keep container tightly closed. Follow safewarehousing practices regarding palletizing, banding, shrink-wrapping and/orstacking.


Exposure Limits (TLV & PEL - 8H TWA):

Component CAS-No Weight % -range

ACGIH TLV OSHA PEL Other Notes

Cellulose 9004-34-6 60 - 100 10 mg/m3 15 mg/m3

(Total); 5mg/m3

(Respirable)

10 mg/m3 TWA(total dust); 5mg/m3 TWA(respirable

dust)

None

Silica, crystalline,quartz

14808-60-7 1 - 5 0.025 mg/m3 see Table Z-3 50 mg/m3 IDLH(NIOSH)

(R)

Engineering Controls Use appropriate engineering controls such as, exhaust ventilation and process enclosure, toensure air contamination and keep workers exposure below the applicable limits.

Personal Protection Equipment

All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemicalhazard present and the risk of exposure to those hazards. The PPE recommendations below are based on anassessment of the chemical hazards associated with this product. Where this product is used in a mixture with otherproducts or fluids, additional hazards may be created and as such further assessment of risk may be required. Therisk of exposure and need of respiratory protection will vary from workplace to workplace and should be assessed bythe user in each situation.

Eye/Face Protection Dust resistant safety goggles.


Skin Protection Nitrile. Wear appropriate clothing to prevent repeated or prolonged skin contact.Chemical resistant gloves recommended for prolonged or repeated contact. Useprotective gloves made of: Neoprene.

Respiratory Protection All respiratory protection equipment should be used within a comprehensiverespiratory protection program that meets the requirements of 29 CFR 1910.134(U.S. OSHA Respiratory Protection Standard) or local equivalent.

If exposed to airborne particles of this product use at least a NIOSH-approved N95half-mask disposable or re-useable particulate respirator. In work environmentscontaining oil mist/aerosol use at least a NIOSH-approved P95 half-maskdisposable or re-useable particulate respirator.

General Hygiene Considerations Work clothes should be washed separately at the end of each work day.Disposable clothing should be discarded, if contaminated with product.


Color TanOdor Mild (or faint)Physical state SolidpH Not DeterminedSpecific Gravity (H2O = 1) 1.4 - 1.65 at 68 F (20 C)Density (lb/gal) Not DeterminedSolubility (water) InsolubleMelting/freezing point Not DeterminedBoiling point/range Not DeterminedPour point Not DeterminedViscosity Not DeterminedVapor pressure 0 mmHg @ 20°CVapor Density (Air=1) NAEvaporation rate 0Octanol/Water PartitionCoefficient

Not Determined

Odor Threshold(s) Not DeterminedVOCs (lbs/gallon) Not Determined


Chemical stability StableConditions to avoid Keep away from heat, sparks and flame See Section 7 also.Materials to avoid Oxidizing agentsConditions of Reactivity See Conditions and Materials to Avoid, if applicable.Hazardous decompositionproducts

For thermal decomposition products, see Section 5.

Hazardous polymerization Will not occur


Acute Exposure Effects, Irritation and Sensitization See Section 2.Chronic, Carcinogenicity, Reproductive Toxicity, Teratogenicity, Embryotoxicity, Mutagenicity Effects SeeComponent Toxicological Summary and Product Toxicological Information, if available.Synergistic Products/Effects N/D

Component Toxicological Data Any adverse component toxicological effects and acute toxicity values (LD50s,LC50s) are listed below. If no effects or acute values are listed for components, no such data were identified.


Component Target organ effects LD50 / LC50Cellulose eyes,respiratory system,skin > 2 g/kg (Dermal LD50; Rabbit)

> 5 g/kg (Oral LD50; Rat)> 5800 mg/m3 (Inhalation LC50; Rat) 4 h

Silica, crystalline, quartz eyes,respiratory system = 500 mg/kg (Oral LD50; Rat)

Component IARC Group 1 or 2 ACGIH - Carcinogens OSHA listed carcinogens NTPCellulose N/A N/A N/A N/ASilica, crystalline, quartz Group 1; Monograph 100C

[in preparation]Group 1; Monograph 68

[1997]Monograph 100C [in

preparation] (listed underCrystalline silica inhaled in

the form of quartz orcristobalite from

occupational sources);Monograph 68 [1997]

A2 Suspected HumanCarcinogen

Present Listed

Component Component Toxicological SummaryCellulose Long term inhalation exposure to this particulate may cause a benign pneumoconiosis (irritation

caused by dust inhalation which may lead to fibrosis (formation of fibrous tissue)). (NIOSH,HazardText)

Silica, crystalline, quartz Crystalline silica is the most widely occurring of all minerals. The most common form of silica is sand.The International Agency for Research on Cancer (IARC) has designated crystalline silica in the formof quartz or cristobalite a Group 1 (carcinogenic to humans). This designation was based on anincreased risk of lung cancer among crystalline silica exposed workers. IARC did note thatcarcinogenicity of crystalline silica in humans was not detected in all industrial circumstances studied.Further, carcinogenicity of crystalline silica may be dependent on inherent characteristics of thecrystalline silica or external factors affecting its biological activity or distribution of polymorphs. (IARCVol. 68, 1997, p. 41).The National Toxicology Program (NTP) classifies crystalline silica as "reasonably anticipated to causecancer in humans" (6th Annual Report on Carcinogens, 1991). Long term inhalation of crystalline silicacan also result in the lung disease, silicosis. Symptoms of this disease include coughing andshortness of breath. (NJ HSFS, January 1996)

Product Toxicological Information Long term inhalation of particulate can cause irritation, inflammation and/orpermanent injury to the lungs. Illnesses such as pneumoconiosis ("dusty lung"), pulmonary fibrosis, chronic bronchitis,emphysema and bronchial asthma may develop.


Ecotoxicology No data available.

Product Ecotoxicity Data Contact M-I Environmental Affairs Department for available product ecotoxicitydata.

Biodegration N/DBioaccumulation N/D

Component ecotoxicity data are listed below. If no data are listed, none were found in the company review.


Waste Classification N/D


Waste Management Under U.S. Environmental Protection Agency (EPA) Resource Conservation andRecovery Act ( RCRA), it is the responsibility of the user to determine at the timeof disposal, whether the product meets RCRA criteria for the hazardous waste.This is because product uses, transformations, mixtures, processes, etc., mayrender the resulting materials hazardous. Empty containers retain residues. Alllabeled precautions must be observed.

Disposal Method Recover and reclaim or recycle, if practical. Should this product become a waste,dispose of in a permitted industrial landfill. Ensure that the containers are emptyby the RCRA criteria prior to disposal in a permitted industrial landfill.


DOTProper Shipping Description Not regulated for transportation by DOT, TDG, IMDG,

ICAO/IATA.Canada TDG Shipping Description Not regulated.UN PIN No Not regulated.IMDG shipping description. Not regulated.ICAO/IATA Shipping Description Not regulated.


U.S. Federal and State Regulations

SARA 311/312 HazardCatagories

Delayed (chronic) health hazard.

SARA 302/304, 313, CERCLA RQ, California Proposition 65Note: If no components are listed below, this product is not subject to the referenced SARA and CERCLA regulationsand is not known to contain a Proposition 65 listed chemical at a level that is expected to pose a significant risk underanticipated use conditions.

Component SARA 302 / TPQs SARA 313 CERCLA RQ

Cellulose N/A N/A N/A

Silica, crystalline, quartz N/A N/A N/A

State Comments Proposition 65: This product contains chemical(s) considered by the State of California's SafeDrinking Water and Toxic Enforcement Act of 1986 to cause cancer and/or reproductive toxicity. See table underU.S. Federal and State Regulations for the specific chemicals.

Silica, crystalline, quartzCalifornia Proposition 65 carcinogen


U.S. TSCA - Components are listed or exempt from listing.China Inventory - Components are listed or exempt from listing.European Union EINECS/ELINCS - Components are listed or exempt from listing.Korea TCCL ECL - Components are listed or exempt from listing.U.S. TSCA - No components are subject to TSCA 12(b) export notification requirements.Australia AICS - Components are listed or exempt from listing.Canada DSL - Components are listed or exempt from listing.New Zealand - Components are listed or exempt from listing.Philippine PICCS - Components are listed or exempt from listing.Japan METI ENCS - Components are listed or exempt from listing.


Canadian Classification

This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all theinformation required by the CPR.

WHMIS Hazard Class D2A

16. Other informationThe following sections have been revised 1, 2, 6, 8, 9, 16.

N/A - Not Applicable, N/D - Not Determined.


DisclaimerThe information and recommendations contained herein are based upon tests believed to be reliable. However, Schlumberger does not guaranteetheir accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED ORIMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR APARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. Schlumberger assumes no responsibility forresults obtained or for incidental or consequential damages, including lost profits arising from the use of these data. No warranty againstinfringement of any patent, copyright or trademark is made or implied.

Safety Data SheetPOLYPAC* (All Grades)

SDS no. 141381Version 2Revision date 05/Feb/2016Supersedes date 21/Mar/2014



Product name POLYPAC* (All Grades)Product code 141381Synonyms POLYPAC* ELV, R, UL & POLYPAC* SUPREME R, ULREACH registration name ExemptDenmark Pr. no.: 920684


Recommended Use Fluid loss reducer. Viscosifier.











________________________________________________________________________________________

2.2 Label elements


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[email protected]

________________________________________________________________________________________

POLYPAC* (All Grades) SDS no. 141381Revision date 05/Feb/2016

Signal wordNone



ContainsPolyanionic cellulose

2.3 Other data




3.1 Substances




REACHregistration

numberPolyanionic cellulose Listed Proprietary 60-100 - Not classified Exempt

3.2 Mixtures

Not Applicable



Inhalation

________________________________________________________________________________________

If inhaled, remove from area to fresh air. Get medical attention if respiratory irritationdevelops or if breathing becomes difficult.


Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists.

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Eye contact Promptly wash eyes with lots of water while lifting eye lids. Remove contact lenses. Getmedical attention if any discomfort continues.

________________________________________________________________________________________




Main symptoms













Hazardous combustion productsFire or high temperatures create:, Carbon oxides (COx), Sodium oxides.





________________________________________________________________________________________





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________________________________________________________________________________________



Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.






HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Keep away from heat and sources of ignition.

Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Do not eat, drink or smoke when using this product. Washhands and face before breaks and immediately after handling the product Remove contaminated clothing.


Technical measures/precautions Ensure adequate ventilation. Keep airborne concentrations below exposure limits. Takeprecautionary measures against static discharges.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moistureStrong oxidizing agents


Packaging material Use specially constructed containers only.


See Section 1.2.




Component EU OEL Austria Australia DenmarkPolyanionic cellulose Not determined Not determined Not determined Not determined

Component Malaysia France Germany HungaryPolyanionic cellulose Not determined Not determined Not determined Not determined

________________________________________________________________________________________

Component New Zealand Italy Netherlands NorwayPolyanionic cellulose Not Determined Not determined

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________________________________________________________________________________________


Component Poland Portugal Romania RussiaPolyanionic cellulose Not determined Not determined Not determined 10 mg/m3 MAC

Component Spain Switzerland Turkey UKPolyanionic cellulose Not determined Not determined Not determined Not determined




Personal protective equipmentEye protection Safety glasses with side-shields. Tightly fitting safety goggles.Hand protection Repeated or prolonged contact:, Use protective gloves made of:, Nitrile, Neoprene gloves,

Frequent change is advisable.Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient

ventilation wear suitable respiratory equipment, Half mask with a particle filter P2(European Norm EN 143 = former DIN 3181), At work in confined or poorly ventilatedspaces, respiratory protection with air supply must be used.




________________________________________________________________________________________


Appearance Granules PowderOdor OdorlessColor White

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________________________________________________________________________________________


Odor threshold Not applicable




10.1 Reactivity







Avoid contact with water and moist air - product is hygroscopic.




Property Values Remarks pH Not applicablepH @ dilution 6.5 - 8 @ 1% solutionMelting/freezing point No information availableBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.5 - 1.6 @ 25 °CBulk density 400 - 800 kg/m³Relative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature > 230°C / 446°F

________________________________________________________________________________________


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Not determined

________________________________________________________________________________________


See Section 5.2.



Acute toxicity


Eye contact Dust may cause mechanical irritation.




Component LD50 Oral LD50 Dermal LC50 InhalationPolyanionic cellulose = 27000 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) > 5800 mg/m3 ( Rat ) 4 h








Not classified


Not classified.

Aspiration hazard Not Applicable.

________________________________________________________________________________________


12.1 Toxicity

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The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment.Listed on PLONOR list of OSPAR

________________________________________________________________________________________






Polyanionic cellulose No information available No information available No information available










None known.


________________________________________________________________________________________





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________________________________________________________________________________________
















________________________________________________________________________________________



Group number

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Not required.

________________________________________________________________________________________


















________________________________________________________________________________________

Supersedes date 21/Mar/2014


Version

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2

________________________________________________________________________________________



All sections, No changes with regard to classification have been made.



________________________________________________________________________________________

*A mark of M-I L.L.C.


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Safety Data SheetPOTASSIUM CHLORIDE

SDS no. MI10857Version 5Revision date 20/Jun/2015Supersedes date 26/Feb/2013



Product name POTASSIUM CHLORIDEProduct code MI10857Synonyms Potassium Chloride 88-99%Denmark Pr. no.: 336939


Recommended Use Completion fluid additive. Drilling fluid additive.











________________________________________________________________________________________

2.2 Label elements


Page 1 / 11

[email protected]

________________________________________________________________________________________

POTASSIUM CHLORIDE SDS no. MI10857Revision date 20/Jun/2015

Signal wordNone



ContainsPotassium chloride

2.3 Other data




3.1 Substances




REACHregistration

numberPotassium chloride 231-211-8 7447-40-7 60-100 - Not classified 01-2119539416-36-x

xxx

3.2 Mixtures

Not Applicable



________________________________________________________________________________________



Skin contact

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Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Get medical attention immediately if symptoms occur.

________________________________________________________________________________________





Main symptoms













Hazardous combustion productsFire or high temperatures create:, Chlorides.





________________________________________________________________________________________




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________________________________________________________________________________________










HandlingHandle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid dust formation.Wash thoroughly after handling.

Hygiene measuresUse good work and personal hygiene practices to avoid exposure. When using do not smoke, eat or drink. Wash hands beforeeating, drinking or smoking Remove contaminated clothing.


Technical measures/precautions Ensure adequate ventilation. Provide appropriate exhaust ventilation at places where dustis formed. Keep airborne concentrations below exposure limits.

Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid contact with:Strong oxidizing agents Strong acids. Strong alkalies. Protect from moisture




See Section 1.2.




Component EU OEL Austria Australia DenmarkPotassium chloride Not determined Not determined Not determined Not determined

________________________________________________________________________________________

Component Malaysia France Germany HungaryPotassium chloride Not determined Not determined

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________________________________________________________________________________________


Component New Zealand Italy Netherlands NorwayPotassium chloride Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaPotassium chloride Not determined Not determined Not determined 5 mg/m3 MAC

Component Spain Switzerland Turkey UKPotassium chloride Not determined Not determined Not determined Not determined


Short term exposure systemic effectsPotassium chlorideDermal 910 mg/kgInhalation 5320 mg/m³


Potassium chlorideDermal 303 mg/kgInhalation 1064 mg/m³

Predicted No Effect Concentration (PNEC)Potassium chlorideFresh water 0.1 mg/lSea water 0.1 mg/lImpact on sewage treatment 10 mg/LIntermittent release 10 mg/L




Personal protective equipmentEye protection

________________________________________________________________________________________

Safety glasses with side-shields.Hand protection Use protective gloves made of:, Rubber gloves, Frequent change is advisable.Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient

ventilation wear suitable respiratory equipment, Half mask with a particle filter P2(European Norm EN 143 = former DIN 3181), At work in confined or poorly ventilatedspaces, respiratory protection with air supply must be used.

Page 5 / 11


________________________________________________________________________________________





Appearance DustOdor OdorlessColor White - Light pinkOdor threshold Not applicable




10.1 Reactivity


Physical state Solid powder

Property Values Remarks pH Not applicablepH @ dilution ~7 @ 1%Melting/freezing point 768-773 °C / 1414-1423 °FBoiling point/range 1406-1413 °C / 2562-2575 °FFlash point No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density No information availableRelative density 1.98 @ 20°C.Water solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________


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________________________________________________________________________________________







Avoid dust formation. Protect from moisture.


Strong oxidizing agents. Strong acids. Strong alkalies.





Acute toxicity






Component LD50 Oral LD50 Dermal LC50 InhalationPotassium chloride = 2600 mg/kg ( Rat ) No data available No data available




________________________________________________________________________________________



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________________________________________________________________________________________



Not classified


Not classified.



12.1 Toxicity







Potassium chloride 750 - 1020 mg/L LC50 (Pimephalespromelas) = 96 h

1060 mg/L LC50 (Lepomismacrochirus) = 96 h








________________________________________________________________________________________





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________________________________________________________________________________________



None known.














________________________________________________________________________________________

Not Applicable



Page 9 / 11

________________________________________________________________________________________




Hazardous to water/Class 1


Potassium chlorideSchedule 4















USA (TSCA) CompliesEuropean Union (EINECS and ELINCS) CompliesCanada (DSL) CompliesPhilippines (PICCS) Complies

________________________________________________________________________________________

Japan (ENCS) CompliesChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) Complies

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New Zealand (NZIoC) Complies

________________________________________________________________________________________







Supersedes date 26/Feb/2013

Revision date 20/Jun/2015

Version 5



________________________________________________________________________________________




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Safety Data SheetSAFE-CARB† (All Grades)

SDS no. MI11713Version 7Revision date 02/Apr/2014Supersedes date 11/Jan/2011



Product name SAFE-CARB† (All Grades)Product code MI11713Synonyms SAFE-CARB 2, 10, 20, 25, 40, 250, 500, 600, 750, 1400 and 2500.REACH registration name ExemptDenmark Pr. no.: 2175905


Recommended Use Lost circulation material. Weighting agent. Bridging material.











________________________________________________________________________________________

2.2 Label elements


Page 1 / 11

[email protected]

________________________________________________________________________________________

SAFE-CARB† (All Grades) SDS no. MI11713Revision date 02/Apr/2014

Signal wordNone





ContainsCalcium carbonate

Crystalline silica (impurity)


2.3 Other data




3.1 Substances




REACHregistration

numberCalcium carbonate 207-439-9 471-34-1 60-100 - Not classified No data available

Crystalline silica(impurity)

238-878-4 14808-60-7 <1 Xn; R48/20 STOT Rep. 2 - H373 Exempt

3.2 Mixtures

Not Applicable

________________________________________________________________________________________

CommentsNaturally occuring mineral. This product contains a small quantity of quartz, crystalline silica. Prolonged and repeated exposure toconcentrations of crystalline silica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease such assilicosis. IARC Monographs, Vol. 68, 1997, concludes that there is sufficient evidence that inhaled crystalline silica in the form ofquartz or cristobalite from occupational sources causes cancer in humans. IARC Classification Group I.


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________________________________________________________________________________________









Main symptoms












________________________________________________________________________________________





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________________________________________________________________________________________
















Hygiene measuresHandle in accordance with good industrial hygiene and safety practice When using do not smoke, eat or drink. Wash hands beforeeating, drinking or smoking Remove contaminated clothing.



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moisture




See Section 1.2.


________________________________________________________________________________________



Page 4 / 11

________________________________________________________________________________________


Component EU OEL Austria Australia DenmarkCalcium carbonate Not determined Not determined 10 mg/m3 TWA

(containing no asbestosand <1% crystalline

silica, inspirable dust)

Not determined

Crystalline silica (impurity) Not determined Not determined 0.1 mg/m3 TWA 0.1mg/m3

Component Malaysia France Germany HungaryCalcium carbonate Not determined 10 mg/m3 Not determined Not determined

Crystalline silica (impurity) 0.1 mg/m3 TWA 0.1 mg/m3 Not determined Not determined

Component New Zealand Italy Netherlands NorwayCalcium carbonate Not Determined Not determined Not determined Not determined

Crystalline silica (impurity) 0.2 mg/m3 TWAKnown or presumedhuman carcinogen

Not determined 0.075 mg/m3 0.3 mg/m3 TWA totaldust

0.1 mg/m3 TWArespirable dust

0.9 mg/m3 STEL totaldust

0.3 mg/m3 STELrespirable dust

Carcinogen

Component Poland Portugal Romania RussiaCalcium carbonate 10 mg/m3 TWA <2% free

crystalline silica totalinhalable dust

10 mg/m3 TWAparticulate matter

containing no Asbestosand < 1% Crystalline

silica


Crystalline silica (impurity) 2 mg/m3 TWA >50% freecrystalline silica total

inhalable dust0.3 mg/m3 TWA >50%free crystalline silica

respirable dust4.0 mg/m3 TWA 2% to

50% free crystalline silicatotal inhalable dust

1.0 mg/m3 TWA 2% to50% free crystalline silica

respirable dust

0.025 mg/m3 TWArespirable fraction

Not determined 1 mg/m3 MAC3 mg/m3 STEL

1 mg/m3 TWA aerosolFibrogenic substance

Component Spain Switzerland Turkey UKCalcium carbonate 10 mg/m3 VLA-ED Not determined Not determined Not determined

Crystalline silica (impurity) 0.1 mg/m3 VLA-EDrespirable fraction

0.15 mg/m3 MAKrespirable

Not determined 0.3 mg/m3 STELcalculated respirable

0.1 mg/m3 TWArespirable

________________________________________________________________________________________

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________________________________________________________________________________________




Engineering measures to reduce exposureEnsure adequate ventilation.


goggles.Hand protection Repeated or prolonged contact:, Use protective gloves made of:, Nitrile, Neoprene.Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient

ventilation wear suitable respiratory equipment, Suitable mask with particle filter P3(European Norm 143).





Appearance Powder DustOdor OdorlessColor WhiteOdor threshold Not applicable


Property Values Remarks pH Not applicablepH @ dilution 8.5 - 9.5 @ 100 g/lMelting/freezing pointBoiling point/range No information availableFlash point No information availableEvaporation rate (BuAc =1)Flammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 2.7 - 2.8 @ 20 °CBulk density No information available

________________________________________________________________________________________

Relative density No information availableWater solubility Insoluble in waterSolubility in other solvents

Page 6 / 11


________________________________________________________________________________________





10.1 Reactivity







Protect from moisture.







Acute toxicity






Autoignition temperature No information availableDecomposition temperature 825 °C

________________________________________________________________________________________


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Not determined

________________________________________________________________________________________


Component LD50 Oral LD50 Dermal LC50 InhalationCalcium carbonate = 6450 mg/kg ( Rat ) No data available No data available

Crystalline silica (impurity) = 500 mg/kg ( Rat ) No data available No data available








Not classified


Not classified.



12.1 Toxicity



Toxicity to fishNot considered toxic to fish.

Toxicity to daphnia and other aquatic invertebratesNot considered toxic.


Calcium carbonate No information available No information available No information availableCrystalline silica (impurity) No information available No information available No information available

________________________________________________________________________________________


Page 8 / 11


________________________________________________________________________________________









None known.






EWC Waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 06 03 99 - wastes not otherwise specified.





14.3 Hazard class(es)

________________________________________________________________________________________

ADR/RID/ADN/ADG Hazard class Not regulatedIMDG Hazard class Not regulatedICAO Hazard class/division Not regulated

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14.4 Packing group

________________________________________________________________________________________


ADR/RID/ADN/ADG Packing group Not regulatedIMDG Packing group Not regulatedICAO Packing group Not regulated







Water endangering class = nwg








________________________________________________________________________________________





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________________________________________________________________________________________










Supersedes date 11/Jan/2011


Version 7



Text of R phrases mentioned in Section 3

R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation


This product is not classified as hazardous therefore no (H) hazard statements assigned.H373 - May cause damage to organs through prolonged or repeated exposure if inhaled

________________________________________________________________________________________



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Safety Data SheetSAFE-SCAV† HSB

SDS no. MI12673AUZVersion 2Revision date 15/May/2014Supersedes date 15/May/2014



Product name SAFE-SCAV† HSBProduct code MI12673AUZ


Recommended Use Hydrogen Sulphide Scavenger.

Uses advised against None known.







Health hazardsAcute oral toxicity Category 4Acute inhalation toxicity - vapor Category 2Skin sensitization Category 1Specific target organ toxicity (repeated exposure) Category 1



________________________________________________________________________________________

2.2 Label elements


Page 1 / 12

[email protected]

________________________________________________________________________________________

SAFE-SCAV† HSB SDS no. MI12673AUZRevision date 15/May/2014

Signal wordDANGER

Hazard statementsH302 - Harmful if swallowedH317 - May cause an allergic skin reactionH330 - Fatal if inhaledH372 - Causes damage to organs through prolonged or repeated exposure if inhaled

Precautionary Statements - EU (§28, 1272/2008) P260 - Do not breathe dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/protective clothing and eye/face protectionP301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physicianP304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathingP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP310 - Immediately call a POISON CENTER or doctor/ physician

Supplementary precautionary statements P271 - Use only outdoors or in a well-ventilated areaP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP261 - Avoid breathing dust/ fume/ gas/ mist/ vapors/ sprayP363 - Wash contaminated clothing before reuseP501 - Dispose of contents/container in accordance with local regulations.

Indication of dangerT - ToxicXn - HarmfulXi - Irritant

R-code(s)R-23, R-22, R-43, R-48/23

Contains

Hexahydro-1,3,5-tris(2-hydroxyethyl)-sym-triazine


2.3 Other data

________________________________________________________________________________________


Australian statement of hazardous/dangerous natureClassified as Hazardous according to the criteria of NOHSC.HAZARDOUS SUBSTANCE. DANGEROUS GOODS.


Page 2 / 12

3.1 Substances

________________________________________________________________________________________


Not Applicable

3.2 Mixtures




REACHregistration

numberHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-tria

zine

225-208-0 4719-04-4 30-60 Xi; R43Xn; R22

T; R23, R48/23

Acute Tox. 4 (H302)Acute Tox. 2 (H330)Skin Sens. 1 (H317)STOT RE 1 (H372)

01-2119529226-41-xxxx




Inhalation Move the exposed person to fresh air at once. Seek medical attention at once.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention at once.

Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Seek medical attention.




Main symptoms




Eye contact

________________________________________________________________________________________

Please see Section 11. Toxicological Information for further information.




Page 3 / 12


________________________________________________________________________________________


Suitable extinguishing mediaWater spray, Water Fog, Alcohol Foam, CO2, Dry Chemical.




Hazardous combustion productsFire or high temperatures create:, Carbon oxides (COx), Nitrogen oxides (NOx).




Hazchem code ADG2X










________________________________________________________________________________________





Page 4 / 12


________________________________________________________________________________________




Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid contact with:Strong oxidizing agents Acids Keep at -5 - 40°C



See Section 1.2.



Component EU OEL Austria Australia DenmarkHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-tri

azineNot determined Not determined Not determined Not determined

Component Malaysia France Germany HungaryHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-tri


Component New Zealand Italy Netherlands NorwayHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-tri

azineNot Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-tri


Component Spain Switzerland Turkey UKHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-tri


________________________________________________________________________________________


Long term exposure local effectsHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-triazineInhalation

Page 5 / 12

0.2 mg/m³


________________________________________________________________________________________


Predicted No Effect Concentration (PNEC)Hexahydro-1,3,5-tris(2-hydroxyethyl)-sym-triazineFresh water 0.0066 mg/lSea water 0.00066 mg/lFresh water sediment 0.0304 mg/kgSea sediment 0.00304 mg/kgSoil 0.00219 mg/kgImpact on sewage treatment 5.5 mg/lIntermittent release 0.066 mg/l



Engineering measures to reduce exposureEnsure adequate ventilation. Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist intowork environment.


goggles.Hand protection Use protective gloves made of:, Nitrile, Neoprene, Be aware that liquid may penetrate the

gloves. Frequent change is advisable.Respiratory protection Use respirator with organic vapor protection (A, brown), If there are conditions in which this

triazine containing product produces a vapor, a chemical respirator with A1 + Formaldehydeand P2 particulate pre-filter combination would be required.





Appearance Aqueous solutionOdor AmineColor AmberOdor threshold Not applicable


Property Values Remarks pH No information availablepH @ dilutionMelting/freezing point < -20 °C / <-4 °F

________________________________________________________________________________________

Boiling point/range No information availableFlash point > 101 °C / > 213.8 °F Closed cupEvaporation rate (BuAc =1)

Page 6 / 12

________________________________________________________________________________________





10.1 Reactivity







Keep at temperatures above -5 and < 40°C.


Strong oxidizing agents. Acids.





Acute toxicity

Flammability (solid, gas) Not ApplicableFlammability Limits in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity No information availableBulk density No information availableRelative density 1.065 - 1.135 @ 16°C.Water solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________

Kinematic viscosity <10 cSt @ 38 °CDynamic viscosity No information availableLog Pow

Page 7 / 12

Not determined

________________________________________________________________________________________


Product information This product may contain or release trace amounts of formaldehyde. The InternationalAgency for Research on Cancer (IARC) has classified formaldehyde as a Group1carcinogen (limited evidence in humans, sufficient evidence in animals). Exposure toformaldehyde has been linked to adverse reproductive effects in some human and animalstudies. In other reproductive studies, however, no adverse effects were noted. (Meditext).Formaldehyde may also cause skin sensitisation (allergic reaction).

Inhalation Fatal if inhaled. Causes damage to organs through prolonged or repeated exposure.

Eye contact Contact with eyes may cause irritation.

Skin contact May cause an allergic skin reaction. May be absorbed through the skin in harmful amounts.

Ingestion Harmful if swallowed.

Unknown acute toxicity .

Component LD50 Oral LD50 Dermal LC50 InhalationHexahydro-1,3,5-tris(2-hydroxyethyl)-sym-triazine = 763 mg/kg ( Rat ) > 2 g/kg ( Rat ) = 0.371mg/L (dust/mist) Rat =

4h

Sensitization May cause sensitization by skin contact.




Routes of exposure Inhalation. Ingestion. Skin contact.

Routes of entry Inhalation. Ingestion. Skin contact.


Not classified


Category 1.


________________________________________________________________________________________


12.1 Toxicity


Page 8 / 12


________________________________________________________________________________________





Hexahydro-1,3,5-tris(2-hydroxyethyl)-sym-triazine


Percent unknown aquatic toxicity 57% of the mixture consists of components(s) of unknown hazards to the aquaticenvironment





Log Pow-1.5 - 0.2






None known.

________________________________________________________________________________________



Page 9 / 12



________________________________________________________________________________________





14.1 UN Number

UN/ID No. (ADR/RID/ADN/ADG) 2810UN No. (IMDG) 2810UN No. (ICAO) 2810

14.2 Proper shipping name TOXIC LIQUID, ORGANIC, N.O.S. (2, 2', 2"-(hexahydro-1, 3, 5-triazine -1, 3, 5-triyl) triethanol)

14.3 Hazard class(es) ADR/RID/ADN/ADG Hazard class 6.1IMDG Hazard class Class 6.1: Toxic substances.ICAO Hazard class/division 6.1

14.4 Packing group ADR/RID/ADN/ADG Packing group IIIMDG Packing group IIICAO Packing group II


14.6 Special precautions Hazard identification no (ADR) 60EmS (IMDG) F-A, S-AEmergency action code 2XTunnel restriction code (D/E)Hazchem code ADG 2X

________________________________________________________________________________________



Page 10 / 12


________________________________________________________________________________________




















________________________________________________________________________________________


Supersedes date 15/May/2014

Revision date

Page 11 / 12

15/May/2014

________________________________________________________________________________________


Version 2



Text of R phrases mentioned in Section 3R23 - Toxic by inhalationR22 - Harmful if swallowedR43 - May cause sensitization by skin contactR34 - Causes burns

R20/21/22 - Harmful by inhalation, in contact with skin and if swallowedR48/23 - Toxic: danger of serious damage to health by prolonged exposure through inhalation


H302 - Harmful if swallowedH317 - May cause an allergic skin reactionH330 - Fatal if inhaledH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH312 - Harmful in contact with skinH332 - Harmful if inhaledH314 - Causes severe skin burns and eye damage

________________________________________________________________________________________



Page 12 / 12


Revision 7


SDS No. 11326

SAFETY DATA SHEET

SAFE-SCAV* NA



Product name SAFE-SCAV* NA


Identified uses Oxygen Scavenger



Level 5

256 St. George Tce

Perth

WA 6000

T = 08 9440 2900




Woodlands Drive



Scotland UK

T=+44(0)1224-246600

F=+11(0)1224-246699








Human health EUH031;Eye Irrit. 2 - H319


Classification (67/548/EEC) Xi;R36. R31.


2.2. Label elements


Signal Word Warning

Hazard Statements

H319 Causes serious eye irritation.

71 /

SDS No. 11326

SAFE-SCAV* NA




P313 Get medical advice/attention.


P280 Wear protective gloves/protective clothing/eye protection/face protection.

Supplemental label information

EUH031 Contact with acids liberates toxic gas.



HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.

2.3. Other hazards



3.1. Substances

AMMONIUM BISULPHITE 30-60%

CAS-No.: 10192-30-0 EC No.: 233-469-7


Xi;R36.

R31.


EUH031

Eye Irrit. 2 - H319

WATER 30-60%

CAS-No.: 7732-18-5 EC No.: 231-791-2


Not classified.


Not classified.






Inhalation


continues.

Ingestion


continues.

Skin contact


washing.

Eye contact




General information




72 /

SDS No. 11326

SAFE-SCAV* NA




Extinguishing media





Specific hazards

Fire or high temperatures create: Oxides of: Sulphur. Ammonia or amines. and Nitrous gases (NOx).












Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel

into dry containers. Cover and move the containers. Flush the area with water.





This product slowly releases sulphur dioxide in contact with air. Ventilate well, avoid breathing vapours. Use approved respirator if air

contamination is above accepted level. Avoid spilling, skin and eye contact. Good personal hygiene is necessary. Wash hands and

contaminated areas with water and soap before leaving the work site. Remove contaminated clothing. Do not eat, drink or smoke when

using the product.


Store in a cool and well-ventilated place. Store in closed original container at temperatures between 5°C and 30°C.






1 ppm 2.6 mg/m3WEL 1 ppm 2.6 mg/m3SULPHUR DIOXIDE


Ingredient Comments

Exposure Limit noted above is for decomposition product Sulphur Dioxide.

NOHSC (Australia) - SULFUR DIOXIDE, TWA: 2ppm or 5.2mg/m3 and STEL 5ppm or 13mg/m3.


73 /

SDS No. 11326

SAFE-SCAV* NA



Process conditions









Respiratory protection must be used if air contamination exceeds acceptable level. Use respiratory equipment with gas filter, type K.

Hand protection

Use protective gloves made of: Butyl rubber. Neoprene. or Nitrile.

Eye protection


Other Protection


Hygiene measures





Appearance Liquid

Colour Colourless to pale yellow.

Odour Pungent. Sulphur.

Solubility Miscible with water


(°C)

105°C

Relative density 1.27 - 1.39 @ 20°C

Vapour density (air=1) <1

Vapour pressure 18 mmHg 20°C

pH-Value, Conc. Solution 4.5 - 5.5 @ 20°C

Flash point (°C) N/A


Not relevant


10.1. Reactivity

Reacts violently with strong oxidising substances. Reaction with: Acids.




Generates toxic gas in contact with acid.


Avoid exposing to heat and contact with strong oxidising substances. Avoid contact with acids.

74 /

SDS No. 11326

SAFE-SCAV* NA


Materials To Avoid

Strong oxidising substances. Strong acids. Strong alkalis.


Sulphurous gases (SOx). Nitrous gases (NOx).



Other Health Effects

Bisulfites may cause skin sensitization in sulfite sensitive persons. Bisulfites may also cause respiratory sensitization in asthmatics and

sulfite sensitive persons.

Acute toxicity:


> 2000 mg/kg Rat

Aspiration hazard:


Inhalation

Gas or vapour may irritate respiratory system.

Ingestion

May irritate and cause stomach pain, vomiting and diarrhoea.

Skin contact

Irritating and may cause redness and pain.

Eye contact

Irritating to eyes. Spray and vapour in the eyes may cause irritation and smarting.

Route of entry


Target Organs



Ecotoxicity

Contact M-I SWACO's QHSE Department for ecological information at [email protected].

12.1. Toxicity

Acute Fish Toxicity

Do not empty into river: may cause impoverishment of oxygen and ammonia increase.


Degradability

The product is biodegradable.





Mobility:

Mobile.

75 /

SDS No. 11326

SAFE-SCAV* NA




None known.







14.1. UN number

Not applicable.


Not applicable.


Not applicable.

14.4. Packing group

Not applicable.



No.


Not applicable.


Not applicable.






EU Legislation






WGK 3



76 /

SDS No. 11326

SAFE-SCAV* NA













Abbreviations and acronyms used in the safety data sheet

*a mark of M-I L.L.C.

General information

HMIS Health - 3 HMIS Flammability - 0 HMIS Physical Hazard - 1

Information Sources



Revision Comments

Classification updated. Compiled or Revised by Ewan MacLeod

Issued By Bill Cameron


Revision 7


SDS No. 11326


Contact with acids liberates toxic gas.R31

Irritating to eyes.R36


Causes serious eye irritation.H319

Contact with acids liberates toxic gas.EUH031

Disclaimer








77 /

Safety Data SheetSAFE-SOLV† E

SDS no. MI10641Version 6Revision date 10/Jun/2015Supersedes date 04/Mar/2013



Product name SAFE-SOLV† EProduct code MI10641


Recommended Use Drilling fluid additive.




Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600Netherlands National Poisons Information Center (NL): +31 30 274 88 88 (NB: this service is only





Health hazardsAspiration toxicity Category 1Skin corrosion/irritation Category 2


Physical Hazards

________________________________________________________________________________________

Not classified


Page 1 / 12

[email protected]

________________________________________________________________________________________

SAFE-SOLV† E SDS no. MI10641Revision date 10/Jun/2015

2.2 Label elements

Signal wordDANGER

Hazard statementsH304 - May be fatal if swallowed and enters airwaysH315 - Causes skin irritationEU specific hazard statementsEUH066 - Repeated exposure may cause skin dryness or cracking

Precautionary Statements - EU (§28, 1272/2008) P280 - Wear protective gloves/ protective clothing/ eye protection/ face protectionP301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomitingP301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physicianP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/ attentionP501 - Dispose of contents/container in accordance with local regulations.

Supplementary precautionary statements P264 - Wash face, hands and any exposed skin thoroughly after handlingP362 - Take off contaminated clothing and wash before reuse

Contains

Hydrocarbons, C11-C14, n-alkanes, isoalkanes, cyclics, < 2% aromatics

Terpenes and Terpenoids, sweet orange oil

2.3 Other data




3.1 Substances

________________________________________________________________________________________

Not Applicable

3.2 Mixtures

Page 2 / 12

________________________________________________________________________________________





REACHregistration

numberHydrocarbons,

C11-C14, n-alkanes,isoalkanes, cyclics, <

2% aromatics

926-141-6 * 60-100 Xn; R65, R66 Asp. Tox. 1 (H304)EUH066

01-2119456620-43-xxxx

Terpenes andTerpenoids, sweet

orange oil

232-433-8 8028-48-6 10-30 F;R10Xn;R65Xi;R38R52/53

Flam. Liq. 3 (H226)Asp Tox. 1 (H304)

Skin Irrit. 2 (H315)

01-2119493353-35-xxxx

CommentsTerpenes and Terpenoids, sweet orange oil can also use CAS 68647-72-3.*Substances which have an EC Number that begins with the number "9" is a Provisional List Number. The list numbers publishedby ECHA do not have any legal significance. The EC substance definition and related classification & labelling has been developedin the framework of the Regulation (EC) No 1907/2006 (REACH). For information about the related CAS number see section 15 ofthis SDS.



Inhalation Move the exposed person to fresh air at once. If breathing has stopped, begin artificialrespiration. Seek medical attention at once.

Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Seek medical attention.

Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes andshoes. Seek medical attention.




Main symptoms




Eye contact

________________________________________________________________________________________

Please see Section 11. Toxicological Information for further information.




Page 3 / 12


________________________________________________________________________________________


Suitable extinguishing mediaWater spray, dry chemical, carbon dioxide (CO2), or foam.

Extinguishing media which shall not be used for safety reasonsDo not use a solid water stream as it may scatter and spread fire.

















________________________________________________________________________________________




Page 4 / 12


________________________________________________________________________________________


Hygiene measuresUse good work and personal hygiene practices to avoid exposure Wash hands and face before breaks and immediately afterhandling the product When using do not smoke, eat or drink. Remove contaminated clothing.



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid heat, flamesand other sources of ignition. Avoid contact with: Strong oxidizing agents Strong acids.Strong bases




See Section 1.2.



Exposure limits Oil mist (mineral) workplace exposure limits are currently under review by legislativeauthorities. This workplace exposure limit (WEL) standard is applicable to highly refinedmineral oils and is provided as a guidance limit only LT. EXP = 5mg/m3 and ST. EXP =10mg/m3.No biological limit allocated

Component EU OEL Austria Australia DenmarkHydrocarbons, C11-C14, n-alkanes,isoalkanes, cyclics, < 2% aromatics

Not determined Not determined Not determined Not determined

Terpenes and Terpenoids, sweet orange oil Not determined Not determined Not determined Not determined

Component Malaysia France Germany HungaryHydrocarbons, C11-C14, n-alkanes,isoalkanes, cyclics, < 2% aromatics



Component New Zealand Italy Netherlands NorwayHydrocarbons, C11-C14, n-alkanes,isoalkanes, cyclics, < 2% aromatics

Not Determined Not determined Not determined Not determined

Terpenes and Terpenoids, sweet orange oil Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaHydrocarbons, C11-C14, n-alkanes,isoalkanes, cyclics, < 2% aromatics


Terpenes and Terpenoids, sweet orange oil Not determined

________________________________________________________________________________________


Component Spain Switzerland

Page 5 / 12

Turkey UK

________________________________________________________________________________________


Hydrocarbons, C11-C14, n-alkanes,isoalkanes, cyclics, < 2% aromatics





Engineering measures to reduce exposureEnsure adequate ventilation. Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist intowork environment.


goggles.Hand protection Use protective gloves made of:, Nitrile, Neoprene, Be aware that liquid may penetrate the

gloves. Frequent change is advisable.Respiratory protection In case of inadequate ventilation wear respiratory protection, Use respirator with organic

vapor protection (A, brown), At work in confined or poorly ventilated spaces, respiratoryprotection with air supply must be used.





Appearance No information availableOdor SweetColor ColorlessOdor threshold Not applicable


Property Values

________________________________________________________________________________________

Remarks pH No information availablepH @ dilutionMelting/freezing point

Page 6 / 12

< -20 °C / -4 °F

________________________________________________________________________________________


Explosive properties No information availableOxidizing properties No information available

9.2 Other information Pour point No information availableMolecular weight No information availableVOC content(%) No information availableDensity No information available


10.1 Reactivity





Hazardous polymerizationNot known.


Avoid heat, flames and other sources of ignition.


Strong oxidizing agents. Strong acids. Strong bases.





Boiling point/range 173 °C / 343.4 °FFlash point 65 °C / 149 °FEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not ApplicableFlammability Limits in Air

Upper flammability limit 5Lower flammability limit 0.7

Vapor pressure ~2 mmHg @ 20 °CVapor density No information availableSpecific gravity No information availableBulk density No information availableRelative density 0.81 sg @ 20°C.Water solubility Insoluble in waterSolubility in other solvents Soluble organic solventsAutoignition temperature 230 °C / 446 °FDecomposition temperature No information available

________________________________________________________________________________________

Kinematic viscosity <20.5 mm2/s @ 40 °CDynamic viscosity No information availableLog Pow

Page 7 / 12


________________________________________________________________________________________


Acute toxicity

Inhalation Inhalation of vapors in high concentration may cause irritation of respiratory system. Maycause additional affects as listed under "Ingestion".

Eye contact May cause irritation.

Skin contact Causes skin irritation. Prolonged contact may cause redness and irritation. Repeatedexposure may cause skin dryness or cracking.

Ingestion May be fatal if swallowed and enters airways. Ingestion may cause gastrointestinalirritation, nausea, vomiting and diarrhea.


Component LD50 Oral LD50 Dermal LC50 InhalationHydrocarbons, C11-C14, n-alkanes, isoalkanes,

cyclics, < 2% aromaticsNo data available No data available No data available

Terpenes and Terpenoids, sweet orange oil = 4400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) No data available





Routes of exposure Ingestion. Skin contact. Inhalation.

Routes of entry Ingestion. Inhalation.


Not classified


Not classified.

Aspiration hazard May be fatal if swallowed and enters airways.

________________________________________________________________________________________


12.1 Toxicity


Page 8 / 12


________________________________________________________________________________________





Hydrocarbons, C11-C14, n-alkanes,isoalkanes, cyclics, < 2% aromatics


Terpenes and Terpenoids, sweetorange oil

> 124 mg/L LC50 (Scophthalmus) =96 h

> 450 mg/L EC50 (Skeletonema) =72 h

> 100 mg/L LC50 (Acartia) = 48 h










None known.


________________________________________________________________________________________





Page 9 / 12


________________________________________________________________________________________














________________________________________________________________________________________




Page 10 / 12


________________________________________________________________________________________





ADG Code – Australian Dangerous Goods Code.Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport byroad or rail.



USA (TSCA) CompliesEuropean Union (EINECS and ELINCS) CompliesCanada (DSL) CompliesPhilippines (PICCS) CompliesJapan (ENCS) Does not ComplyChina (IECSC) CompliesAustralia (AICS) CompliesKorean (KECL) CompliesNew Zealand (NZIoC) Complies


CAS Number 64742-47-8 can be used to identify the substance given a list number in section 3 in areas not subject to the REACHregulation.




Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sandra McWilliam


Revision date 10/Jun/2015

Version 6



________________________________________________________________________________________

Text of R phrases mentioned in Section 3R10 - FlammableR38 - Irritating to skinR65 - Harmful: may cause lung damage if swallowedR66 - Repeated exposure may cause skin dryness or cracking

R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

Page 11 / 12


________________________________________________________________________________________


H304 - May be fatal if swallowed and enters airwaysH315 - Causes skin irritationH226 - Flammable liquid and vaporEUH066 - Repeated exposure may cause skin dryness or cracking

________________________________________________________________________________________



Page 12 / 12

SDS no. PID1436Version 2Revision date 06-Jul-2017Supersedes date 11-Jun-2014

Safety Data SheetSAPP



Product name SAPPProduct code PID1436Molecular weight 222.15Denmark Pr. no: 2212219


Recommended Use SAPP dispersant. Thinner.




Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600Denmark Poison Control Hotline (DK): +45 82 12 12 12Netherlands National Poisons Information Center (NL): +31 30 274 88 88 (NB: this service is only









[email protected]

_____________________________________________________________________________________________

Page 1 / 11

_____________________________________________________________________________________________

SAPP SDS no. PID1436Revision date 06-Jul-2017

2.2 Label elements

Signal wordWARNING


Precautionary Statements - EU (§28, 1272/2008) P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/protective clothing/eye protection/face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attentionP501 - Dispose of contents/container in accordance with local, regional, national, and international regulations as applicable

ContainsDisodium dihydrogen diphosphate

2.3 Other hazards




3.1 Substances

Chemical Name EC No CAS No Weight-% Regulation (EC) No1272/2008

REACHregistration

numberDisodium dihydrogen

diphosphate231-835-0 7758-16-9 60-100 Eye Irrit. 2 (H319) 01-2119489793-1

9-xxxx

3.2 Mixtures

Not applicable

_____________________________________________________________________________________________

Page 2 / 11

_____________________________________________________________________________________________



4.1 First aid measures



Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.

Eye Contact Remove contact lenses, if worn. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.



Symptoms













Hazardous combustion productsFire or high temperatures create: Oxides of phosphorus.

_____________________________________________________________________________________________

Page 3 / 11


_____________________________________________________________________________________________











Methods for containmentCover powder spill with plastic sheet or tarp to minimize spreading. Prevent further leakage or spillage if safe to do so.










Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid excessive heatfor prolonged periods of time. Protect from moisture Avoid contact with: Strong alkalies.




See Section 1.2.

_____________________________________________________________________________________________

Page 4 / 11


_____________________________________________________________________________________________




Chemical Name EU OEL Austria Australia DenmarkDisodium dihydrogen diphosphate Not determined Not determined Not determined Not determined

Chemical Name Malaysia France Germany HungaryDisodium dihydrogen diphosphate Not determined Not determined Not determined Not determined

Chemical Name New Zealand Italy Netherlands NorwayDisodium dihydrogen diphosphate Not determined Not determined Not determined Not determined

Chemical Name Poland Portugal Romania RussiaDisodium dihydrogen diphosphate Not determined Not determined Not determined Not determined

Chemical Name Spain Switzerland Turkey UKDisodium dihydrogen diphosphate Not determined Not determined Not determined Not determined


Long term exposure systemic effectsDisodium dihydrogen diphosphateInhalation 2.79 mg/m³

Predicted No Effect Concentration (PNEC)Disodium dihydrogen diphosphateFresh water 0.05 mg/lSea water 0.05 mg/lImpact on sewage treatment 50 mg/l



Engineering ControlsEnsure adequate ventilation.


Tightly fitting safety goggles. Safety glasses with side-shields.Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Repeated or

prolonged contact Use protective gloves made of: Nitrile Neoprene PVC Frequent change isadvisable

Respiratory protection No personal respiratory protective equipment normally required, In case of insufficientventilation wear suitable respiratory equipment, Half mask with a particle filter P2 (EuropeanNorm EN 143 = former DIN 3181), At work in confined or poorly ventilated spaces,respiratory protection with air supply must be used.



_____________________________________________________________________________________________

Page 5 / 11

_____________________________________________________________________________________________




Appearance Crystalline PowderOdor OdorlessColor WhiteOdor threshold Not applicable

Explosive properties Not applicableOxidizing properties None known.

9.2 Other information Pour point No information availableMolecular weight 222.15VOC content(%) NoneDensity No information available

CommentsThe data listed above are typical physical and chemical properties and should not be construed as product specification.


10.1 Reactivity



Property Values Remarks pH No information availablepH @ dilution 4.0 - 5.0 @ 10 g/lMelting / freezing point No information availableBoiling point/range No information availableFlash point n/a No information availableEvaporation rate (BuAc =1) No information availableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure No information availableVapor density No information availableSpecific gravity 1.8 - 1.9 sg 20 °CBulk density 1000-1200 kg/m³Relative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information availableKinematic viscosity No information availableDynamic viscosity No information availablelog Pow No information available

_____________________________________________________________________________________________

Page 6 / 11

_____________________________________________________________________________________________







Protect from moisture. Avoid excessive heat for prolonged periods of time.


Strong alkalies.


See Section 5.2.



Acute toxicity



Skin contact Prolonged skin contact may cause skin irritation.



Toxicology data for the componentsChemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Disodium dihydrogen diphosphate = 1800 mg/kg (Rat) No data available > 0.58 mg/L ( Rat ) 4 h





_____________________________________________________________________________________________

Page 7 / 11

_____________________________________________________________________________________________





Not classified


Not classified.



12.1 Toxicity






Disodium dihydrogen diphosphate No information available No information available No information available








_____________________________________________________________________________________________

Page 8 / 11

_____________________________________________________________________________________________




None known.






EWC Waste Disposal No According to the European Waste Catalog, Waste Codes are not product specific, butapplication specific Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 01 04 10 – dusty and powdery wastes other than those mentioned in 0104 07, EWC waste disposal No: 7091 Inorganic salts and other solids.







14.6 Special precautions Not applicable

_____________________________________________________________________________________________

Page 9 / 11


_____________________________________________________________________________________________




Australian Standard for the Uniform Scheduling of Drugs and PoisonsNo poisons schedule number allocated















_____________________________________________________________________________________________

Page 10 / 11

_____________________________________________________________________________________________


Supersedes date 11-Jun-2014

Revision date 06-Jul-2017

Version 2


All sections Product Code change No changes with regard to classification have beenmade.




_____________________________________________________________________________________________

Page 11 / 11

SDS no. M003Version 4Revision date 10-Apr-2017Supersedes date 09-May-2014

Safety Data SheetSoda Ash M3



Product name Soda Ash M3Product code M003Norway Pr. no. 52700Denmark Pr. no: 1309326


Recommended Use Buffer in oilfield applications




Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 595 3518Denmark Poison Control Hotline (DK): +45 82 12 12 12Germany Poison Center Berlin (DE): +49 030 30686 790Italy Centro Antiveleni Ospedale Niguarda Milan: +39 02 6610 1029Norway Poison information centre: +47 22 59 13 00




Health hazardsSerious eye damage/eye irritation Category 2A



SupplierSchlumberger Oilfield Australia Pty LtdABN: 74 002 459 225ACN: 002 459 225256 St. Georges Terrace, Perth WA 6000+47 5157 7424

[email protected]

_____________________________________________________________________________________________

Page 1 / 11

_____________________________________________________________________________________________

Soda Ash M3 SDS no. M003Revision date 10-Apr-2017

2.2 Label elements

Signal wordWARNING


Precautionary Statements - EU (§28, 1272/2008) P264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/protective clothing and eye/face protectionP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/ attentionP501 - Dispose of contents/containers in accordance with local regulations

ContainsSodium carbonate

2.3 Other hazards




3.1 Substances

Chemical Name EC No CAS No Weight-% Classificationaccording to67/548/EEC

Regulation (EC) No1272/2008

REACHregistration

numberSodium carbonate 207-838-8 497-19-8 60-100 Xi; R36 Eye Irrit. 2 (H319) 01-2119485498-19-X

XXX

3.2 Mixtures

Not applicable

_____________________________________________________________________________________________

Page 2 / 11

_____________________________________________________________________________________________






Skin contact Wash off immediately with soap and plenty of water while removing all contaminatedclothes and shoes. Get medical attention immediately if symptoms occur.

Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.Continue to rinse for at least 15 minutes. Seek medical attention.



Main symptoms













Hazardous combustion productsThermal decomposition can lead to release of irritating gases and vapors


_____________________________________________________________________________________________

Page 3 / 11

Special protective equipment for fire-fighters

_____________________________________________________________________________________________


As in any fire, wear self-contained breathing apparatus and full protective gear.




Use personal protective equipment. See also section 8. Avoid dust formation.





Methods for containmentPrevent further leakage or spillage if safe to do so. Cover powder spill with plastic sheet or tarp to minimize spreading and keeppowder dry.







Hygiene measuresUse good work and personal hygiene practices to avoid exposure. Wash hands and face before breaks and immediately afterhandling the product Remove contaminated clothing. Do not eat, drink or smoke when using this product.



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Protect from moistureAvoid contact with water and moist air - product is hygroscopic. Store away fromincompatibles, Powdered aluminum Strong acids.




See Section 1.2.

_____________________________________________________________________________________________

Page 4 / 11


_____________________________________________________________________________________________



Chemical Name EU OEL Austria Australia DenmarkSodium carbonate Not determined Not determined Not determined Not determinedChemical Name Malaysia France Germany Hungary

Sodium carbonate Not determined Not determined Not determined Not determinedChemical Name New Zealand Italy Netherlands Norway

Sodium carbonate Not determined Not determined Not determined Not determinedChemical Name Poland Portugal Romania Russia

Sodium carbonate Not determined Not determined 3mg/m3STEL1mg/m3TWA

Skin

Chemical Name Spain Switzerland Turkey UKSodium carbonate Not determined Not determined Not determined Not determined

NotesNo biological limit allocated


Long term exposure local effectsSodium carbonateInhalation 10 mg/m³



Engineering measures to reduce exposureEnsure adequate ventilation. Provide appropriate exhaust ventilation at places where dust is formed.


Tightly fitting safety goggles.Hand protection Wear gloves according to EN 374 to protect against skin effects from powders Impervious

gloves made of: Nitrile PVA Frequent change is advisableRespiratory protection In case of insufficient ventilation wear suitable respiratory equipment, Half mask with a

particle filter P2 (European Norm EN 143 = former DIN 3181), At work in confined or poorlyventilated spaces, respiratory protection with air supply must be used.

Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash andemergency shower must be available at the work place.

Hygiene measures Wash hands before breaks and immediately after handling the product, Remove and washcontaminated clothing before re-use.


_____________________________________________________________________________________________

Page 5 / 11


_____________________________________________________________________________________________


Appearance PowderOdor OdorlessColor WhiteOdor threshold Not applicable

Explosive properties Not applicableOxidizing properties None known.



10.1 Reactivity

Decomposes by reaction with strong acids.






Protect from moisture. Avoid contact with water and moist air - product is hygroscopic.



Property Values Remarks pH 11pH @ dilutionMelting / freezing point 851 °C / 1564 °FBoiling point/range Not applicableFlash point Not applicableEvaporation rate (BuAc =1) Not applicableFlammability (solid, gas) Not applicableFlammability Limit in Air


Vapor pressure Not applicableVapor density Not applicableSpecific gravity 2.5 @20 °CBulk density No information availableRelative density 2.53 @ 20°C.Water solubility 212.5g/L @ 20 °CSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature >400°C/ 752°F

Kinematic viscosity No information availableDynamic viscosity No information availablelog Pow Not determined

_____________________________________________________________________________________________

Page 6 / 11

_____________________________________________________________________________________________


Powdered aluminum. Strong acids.


See Section 5.2.



Acute toxicity


Eye contact Causes serious eye irritation. May cause pain, redness, discomfort.

Skin contact May cause skin irritation and/or dermatitis.



Chemical Name LD50 Oral LD50 Dermal LC50 InhalationSodium carbonate = 4090 mg/kg ( Rat ) No data available = 2300 mg/m3 ( Rat ) 2 h





Routes of exposure Skin contact. Eye contact. Inhalation.



Not classified


Not classified.



_____________________________________________________________________________________________

Page 7 / 11

12.1 Toxicity

_____________________________________________________________________________________________


The product component(s) are not classified as environmentally hazardous. However, this does not exclude the possibility thatlarge or frequent spills can have a harmful or damaging effect on the environment. Large amounts will affect pH and harm aquaticorganisms





Sodium carbonate 310 - 1220 mg/L LC50 Pimephalespromelas 96 h = 300 mg/L LC50

Lepomis macrochirus 96 h

= 242 mg/L EC50 Nitzschia 120 h = 265 mg/L EC50 Daphnia magna48 h










None known.



Waste from residues / unused Dispose of in accordance with local regulations.

_____________________________________________________________________________________________

Page 8 / 11

_____________________________________________________________________________________________


products


EWC Waste Disposal No According to the European Waste Catalog, Waste Codes are not product specific, butapplication specific Waste codes should be assigned by the user based on the applicationfor which the product was used. The following Waste Codes are only suggestions: EWCwaste disposal No: 16 03 04 - inorganic wastes other than those mentioned in 16 03 03







14.6 Special precautions Not applicable







_____________________________________________________________________________________________

Page 9 / 11


_____________________________________________________________________________________________












Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Muriel Martin Beurel

Supersedes date 09-May-2014

Revision date 10-Apr-2017

Version 4


All sections No changes with regard to classification have been made.

Text of R phrases mentioned in Section 3R36 - Irritating to eyes



_____________________________________________________________________________________________

Page 10 / 11

Disclaimer

_____________________________________________________________________________________________


The information contained herein is considered in good faith as reliable of the date issued and is based upon onmeasurements, tests or data derived from supplier’s own study or furnished by others. In providing this SDSinformation, Supplier makes no express or implied warranties as to the information or product; merchantability or fitnessof purpose; any express or implied warranty; or non-infringement of intellectual property rights; and supplier assumes noresponsibility for any direct, special or consequential damages, results obtained, or the activities of others. To themaximum extent permitted by law, supplier’s warranty obligations and buyer’s sole remedies are as stated in separateagreement between the parties.

_____________________________________________________________________________________________

Page 11 / 11


Revision 6


SDS No. 11368

SAFETY DATA SHEET

SODIUM BICARBONATE



Product name SODIUM BICARBONATE


Identified uses Drilling fluid additive



Level 5

256 St. George Tce

Perth

WA 6000

T = 08 9440 2900




Woodlands Drive



Scotland UK

T=+44(0)1224-246600

F=+11(0)1224-246699












2.2. Label elements






2.3. Other hazards



71 /

SDS No. 11368

SODIUM BICARBONATE

3.1. Substances

SODIUM BICARBONATE 60-100%

CAS-No.: 144-55-8 EC No.: 205-633-8


Not classified.


Not classified.






Inhalation


continues.

Ingestion


continues.

Skin contact


washing.

Eye contact




General information







Extinguishing media



Do not use water jet as an extinguisher, as this will spread the fire.













72 /

SDS No. 11368

SODIUM BICARBONATE

Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of dust and contact with skin and eyes. Avoid

spreading dust.




Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.





Avoid handling which leads to dust formation. Avoid inhalation of dust and contact with skin and eyes. Good personal hygiene is


eat, drink or smoke when using the product. Avoid Water, moisture, acids and heating.


Store in tightly closed original container in a dry, cool and well-ventilated place. Avoid Contact with acids.

Storage Class

Chemical storage.





Ingredient Comments

NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.




Process conditions









No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air

contamination exists. Dust filter P2 (for fine dust).

Hand protection

For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber. PVC gloves are recommended.

Eye protection

Use tight fitting goggles if dust is generated.

Other Protection


Hygiene measures



73 /

SDS No. 11368

SODIUM BICARBONATE



Appearance Solid

Colour White.

Odour Odourless.

Solubility Soluble in water.


Relative density 2.21 - 2.23 s.g @ 20°C

Bulk Density 500 - 1150 kg/m3

pH-Value, Diluted Solution 8.1 - 8.4 @ 50g/l


H2O@20°C)

95 @ 20°C

Decomposition temperature (°C) > 60°C


Not relevant


10.1. Reactivity





Not relevant


Avoid contact with: Moisture. Avoid heat.


Materials To Avoid

Avoid contact with acids.





Acute toxicity:


4220 mg/kg Rat

Acute Toxicity (Inhalation LC50)

4.74 mg/l (dust/mist) Rat

Aspiration hazard:


Inhalation


Ingestion


74 /

SDS No. 11368

SODIUM BICARBONATE

Skin contact


Eye contact


Route of entry


Target Organs



Ecotoxicity


PLONOR.

12.1. Toxicity

LC 50, 96 Hrs, Fish mg/l >7000

EC 50, 48 Hrs, Daphnia, mg/l >4000


Degradability




No data available on bioaccumulation.


Mobility:

The product is soluble in water.




None known.




Waste Class

The definitive European Waste code for this product will depend upon the final use that is made of this material. EWC-code: 06 03 14 7132.

Inorganic bases.




14.1. UN number

Not applicable.


Not applicable.


Not applicable.

75 /

SDS No. 11368

SODIUM BICARBONATE

14.4. Packing group

Not applicable.



No.


Not applicable.


Not applicable.






EU Legislation






WGK 1















Information Sources



Revision Comments

General revision. Compiled or revised by Sarah Malone

Issued By Sarah Malone


Revision 6


SDS No. 11368

Signature Sarah Malone

Signature 2 Nina Ovrehus


Not classified.NC

76 /

SDS No. 11368

SODIUM BICARBONATE

Disclaimer








77 /

Safety Data SheetSODIUM CHLORIDE POWDER (SALT PVD or GRANULAR SALT)

SDS no. MI11332Version 8Revision date 06/Feb/2015Supersedes date 26/Mar/2014



Product name SODIUM CHLORIDE POWDER (SALT PVD or GRANULAR SALT)Product code MI11332Synonyms Sodium chloride, NaClMolecular weight 58.44 g/molREACH registration name ExemptDenmark Pr. no. 701625


Recommended Use Additive in oilfield applications




Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600Denmark Poison Control Hotline (DK): +45 82 12 12 12Norway Poison information centre: +47 22 59 13 00







________________________________________________________________________________________

2.2 Label elements


Page 1 / 11

[email protected]

________________________________________________________________________________________

SODIUM CHLORIDE POWDER (SALTPVD or GRANULAR SALT)

SDS no. MI11332Revision date 06/Feb/2015

Signal wordNot applicable





ContainsSodium chloride


2.3 Other data




3.1 Substances




REACHregistration

numberSodium chloride 231-598-3 7647-14-5 60-100 - Not classified No data available

3.2 Mixtures

Not Applicable


________________________________________________________________________________________



Ingestion

Page 2 / 11

Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouthto an unconscious person. Get medical attention if symptoms occur.

________________________________________________________________________________________







Main symptoms












Unusual fire and explosion hazardsNone.

Hazardous combustion productsFire or high temperatures create:, Chlorine, chlorine oxides, hydrogen chloride.



________________________________________________________________________________________





Page 3 / 11


________________________________________________________________________________________













Hygiene measuresHandle in accordance with good industrial hygiene and safety practice. When using do not smoke, eat or drink. Wash hands andface before breaks and immediately after handling the product.



Storage precautions Keep containers tightly closed in a dry, cool and well-ventilated place. Avoid contact with:Strong acids. Oxidizing agents Metals



Packaging materials to be avoided Metal


See Section 1.2.




________________________________________________________________________________________

Component EU OEL Austria Australia DenmarkSodium chloride Not determined Not determined

Page 4 / 11


________________________________________________________________________________________



Component Finland France Germany HungarySodium chloride Not determined Not determined Not determined Not determined

Component New Zealand Italy Netherlands NorwaySodium chloride Not Determined Not determined Not determined Not determined

Component Poland Portugal Romania RussiaSodium chloride Not determined Not determined Not determined 5 mg/m3 MAC

Component Spain Switzerland Turkey UKSodium chloride Not determined Not determined Not determined Not determined





goggles.Hand protection Use protective gloves made of:, Rubber or plastic gloves, Be aware that liquid may

penetrate the gloves. Frequent change is advisable.Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient


Skin and body protection

________________________________________________________________________________________

Wear suitable protective clothing, Eye wash and emergency shower must be available atthe work place.


Page 5 / 11


________________________________________________________________________________________




Appearance CrystallineOdor OdorlessColor WhiteOdor threshold Not applicable


9.2 Other information Pour point No information availableMolecular weight 58.44 g/molVOC content(%) NoneDensity 2.1615 g/cm²


10.1 Reactivity







Avoid dust formation.

Physical state Solid powder

Property Values Remarks pH No information availablepH @ dilution 7 @1%Melting/freezing point 801 °CBoiling point/range 1461 °CFlash point No information availableEvaporation rate (BuAc =1)Flammability (solid, gas) Not ApplicableFlammability Limits in Air Not applicable


Vapor pressure 1 mmHg @ 865 °CVapor density No information availableSpecific gravity No information availableBulk density 800 - 1600 kg/m³Relative density No information availableWater solubility Soluble in waterSolubility in other solvents No information availableAutoignition temperature No information availableDecomposition temperature No information available

________________________________________________________________________________________


Page 6 / 11

Not determined

________________________________________________________________________________________




Strong acids. Oxidizing agents. Metals.





Acute toxicity





Component LD50 Oral LD50 Dermal LC50 InhalationSodium chloride = 3 g/kg ( Rat ) > 10 g/kg ( Rabbit ) > 42 g/m3 ( Rat ) 1 h





Routes of exposure Inhalation. Eye contact.



Not classified


Not classified.

Aspiration hazard

________________________________________________________________________________________

No hazard from product as supplied.


Page 7 / 11

12.1 Toxicity

________________________________________________________________________________________








Sodium chloride 5560 - 6080 mg/L LC50 (Lepomismacrochirus) = 96 h

12946 mg/L LC50 (Lepomismacrochirus) = 96 h

4747 - 7824 mg/L LC50(Oncorhynchus mykiss) = 96 h7050 mg/L LC50 (Pimephales

promelas) = 96 h6420 - 6700 mg/L LC50

(Pimephales promelas) = 96 h6020 - 7070 mg/L LC50

(Pimephales promelas) = 96 h

No information available 340.7 - 469.2 mg/L EC50 (Daphniamagna) = 48 h

1000 mg/L EC50 (Daphnia magna)= 48 h









________________________________________________________________________________________


None known.

Page 8 / 11

________________________________________________________________________________________



















________________________________________________________________________________________





Page 9 / 11

________________________________________________________________________________________


















Prepared by Global Regulatory Compliance - Chemicals (GRC - Chemicals) , Sarah Malone


________________________________________________________________________________________


Version 8


Page 10 / 11


________________________________________________________________________________________



Text of R phrases mentioned in Section 2 and 3Not classified


________________________________________________________________________________________

This product is not classified as hazardous therefore no (H) hazard statements assigned.Not classified


Page 11 / 11

SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016

Trade name: Accelerator NL-65-100, PergaQuick A-100 Page 1 of 10

According to Commission Regulation (EU) 2015/830

SDS Revision: 19.07.2016 Version: 3.2


1.1. Product identifier Trade name: Accelerator NL-65-100, PergaQuick A-100

Chemical name: N,N-Dimethyl-p-toluidine CAS: 99-97-8

1.2. Relevant identified uses of the substance or mixture and uses advised against Auxiliaries for the Thermoset Industry; component in ThermaSet® UPR

1.3. Details of the supplier of the safety data sheet Company: Wellcem

Orstadvegen 108 N-4353 Klepp Stasjon Norway

Phone number: +47 52 98 65 00 Email: [email protected]

1.4. Emergency telephone number 24-7 Emergency Advice: +44 (0) 203 394 9859 (English language) The National Poisons Information Centre (Norway): +47 22 59 13 00 (Norwegian language)


2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Acute toxicity (inhalation) category 2 H330 Acute toxicity (oral) category 3 H301 Acute toxicity (dermal) category 3 H311 Target organ, repeated exposure category 2 H373 Aquatic environment, chronic category 3 H412

2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Signal word: Danger Contains: N,N-Dimethyl-p-toluidine

Hazard Statements H301 Toxic if swallowed H311 Toxic in contact with skin H330 Fatal if inhaled H373 May cause damage to organs through prolonged or repeated exposure

Importer Name: Chevron Australia Pty LtdAddress: 250 St Georges Terrace, Perth, WA, 6000, AustraliaTelephone: 08 9216 4000Fax: 08 9216 4444

Emergency contact number available during office hours only: 0427 495 187


SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016

Trade name: Accelerator NL-65-100, PergaQuick A-100

Page 2 of 10

H412 Harmful to aquatic life with long lasting effects Precautionary Statements PREVENTION P260 Do not breathe vapours P264 Wash hands and contaminated skin thoroughly after handling P270 Do not eat, drink or smoke when using this product P271 Use only outdoors or in a well-ventilated area P273 Avoid release to the environment P280 Wear protective gloves, eye/face protection and protective clothing P284 Wear respiratory protection

RESPONSE P301+P330 IF SWALLOWED: Rinse mouth P302+P352 IF ON SKIN: Wash with plenty of soap and water P304+P340 IF INHALED:

Remove victim to fresh air and keep at rest in a position comfortable for breathing P310 Immediately call a POISON CENTER or doctor/physician P320 Specific treatment is urgent P361 Take off immediately all contaminated clothing

STORAGE P403+P233 Store in a well-ventilated place. Keep container tightly closed

DISPOSAL P501 Dispose of contents and container according to local regulation

2.3. Other hazards PBT – and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. N,N-Dimethyl-p-toluidine is classified as STOT RE2 and it can be concluded that the substance is classified as poisonous according to REACH Annex XIII criteria. No further data available.


3.1. Substances

Component EC # REACH # CAS #

% by weight CLP classification

N,N-Dimethyl-p-toluidine

202-805-4 90 - 100 Acute Tox. 3; H301 Acute Tox. 3; H311 STOT RE 2; H373 Acute Tox. 2; H330 Aquatic Chronic 3; H412

01-2119937766-23 01-2119956633-31

99-97-8

For full text of H-statements: see section 2.2 or 16.

SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016


Page 3 of 10


4.1. Description of first aid measures General: Immediate medical attention is required.

Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Symptoms of poisoning may appear several hours later.

Inhalation: If breathed in, move person into fresh air.

Call a physician or poison control centre immediately. Remove to fresh air. Keep patient warm and at rest. If unconscious place in recovery position and seek medical advice. Keep respiratory tract clear.

Skin Contact: Take off contaminated clothing and shoes immediately.

Rinse immediately with plenty of water. Take victim immediately to hospital.

Eye Contact: Rinse with plenty of water.

Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

Ingestion: Clean mouth with water and drink afterwards plenty of water.

DO NOT induce vomiting unless instructions from medical personnel. Call a physician immediately. Never give anything by mouth to an unconscious person. Take victim immediately to hospital.

4.2. Most important symptoms and effects, both acute and delayed The symptoms and effects are as expected from the hazards as shown in section 2. No specific product related symptoms are known.

4.3. Indication of any immediate medical attention and special treatment needed Other information: Treat symptomatically


5.1. Extinguishing media Suitable extinguishing media: Water spray, Carbon dioxide (CO2), Dry chemical, Alcohol resistant foam

Unsuitable extinguishing media: High volume water jet

5.2. Special hazards arising from the substance or mixture Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases flammable. Water spray may be ineffective unless used by experienced firefighters. Do not allow run-off from fire fighting to enter drains or water courses.

SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016


Page 4 of 10

Dangerous decomposition products: Combustion creates carbon oxides and nitrogen oxides (NOx).

5.3. Advice for firefighters In the event of fire, wear self-contained breathing apparatus. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored separately in closed containments. Cool unopened containers with waterspray.


6.1. Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Avoid direct contact with the product. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8.

6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. If the product contaminates rivers and lakes or drains inform respective authorities.

6.3. Methods and material for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust) for disposal. Keep in clean, suitable, closed containers for disposal.

6.4. Reference to other sections For personal protection see section 8. See section 12 for environmental information. See section 13 regarding disposal.



Use personal protection equipment, see section 8. Handling: Smoking, eating and drinking should be prohibited in the application area. Do not pipet by mouth. Provide sufficient air exchange and/or exhaust in work rooms. Apply effective local ventilation. Avoid inhalation of vapour or mist. Avoid contact with skin, eyes and clothing. Avoid direct contact with the product. Avoid incompatible substances (see Section 10).

General Hygiene Considerations: Wash hands before eating, drinking or smoking. Keep work clothing separate and do not bring them home.

Fire and explosion: Keep away from heat. Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge.

7.2. Conditions for safe storage, including any incompatibilities Should not be stored together with foodstuffs, beverages, and animal feed. Containers must be kept upright to prevent leakage.

SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016


Page 5 of 10

Store in cool and well-ventilated place. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Store in accordance with local / national regulations.

7.3. Specific end use(s) Use only as specified by producer, see section 1.2 .


8.1. Control parameters Exposure Limits: N,N-Dimethyl-p-toluidine is not listed in the UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011). Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006

Substance name End Use Exposure routes Potential health effects Value

N,N-Dimethyl-p-toluidine

Workers Skin contact Long-term systemic effects

1,19 mg/kg

Workers Inhalation Long-term systemic effects

1,35 mg/m3

Consumers Inhalation Long-term systemic effects

0,34 mg/m3

Consumers Skin contact Long-term systemic effects

0,29 mg/kg

Consumers Ingestion Long-term systemic effects

2,37 mg/kg

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006 Substance name Environmental Compartment Value

N,N-Dimethyl-p-toluidine Fresh water 0,153 mg/l

Marine water 0,0153 mg/l

Intermittent water 0,153 mg/l

Sewage treatment plant 4,29 mg/l

Fresh water sediment 45,38 mg/kg dry weight

Marine sediment 45,38 mg/kg dry weight

Soil 18,68 mg/kg dry weight

8.2. Exposure controls Engineering controls: Use effective general ventilation and local exhaust ventilation at the

workstation.

General: Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Smoking, consumption of food and beverages, as well as storage of tobacco, food and beverages are not recommended in the workplace. Wash exposed areas of the body before breaks and after finishing work. Remove clothing soiled by the product immediately. Water for rinsing of eyes and skin must be available. Store and wash work clothes separately. Avoid contact with skin and eyes.

Eye protection: Safety glasses with side-shields conforming to EN166. Tightly fitting safety

goggles (EN166) should be used if splashes are likely to occur. Ensure that eyewash stations and safety showers are close to the workstation location.

Skin protection: Impervious clothing for protection against chemicals.

SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016


Page 6 of 10

Hand protection: Use protective gloves that are inspected before use. Gloves must comply with requirements in EN 374.

Prolonged use (break through time 480 min) Minimum layer thickness: 0.47 mm Material: Butyl Type: Butyl 0897 (KCL) Short term use (break through time 30 min) Minimum layer thickness: 0.2 mm Material: Nitrile Type: Nitrile 0743 (KCL)

Data source: KCL GmbH, e-mail [email protected], phone +49 6659 87300 This recommendation is advisory only and must be evaluated by responsible chemist familiar with the specific situation of anticipated use. It should not be construed as offering an approval for any specific use scenario.

Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion.

Respiratory protection: Avoid breathing vapours. Use a full-face combination filter ABEK (EN14387) when handling the product. If there is no ventilation on premises use supplied-air respirator with full face mask. Use only approved and tested equipment / components according to standard CEN (EU).

Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained.


9.1. Information on basic physical and chemical properties a) Appearance: yellow liquid b) Odour: characteristic c) Odour threshold: No information available d) pH: alkaline e) Melting/freezing point: -25°C f) Initial boiling point/range: 211°C g) Flash point: 83°C Method: closed cup h) Evaporation rate: No information available i) Flammability (solid/gas): No information available j) Upper/lower flammability Upper: 7% (V)

or explosive limits: Lower: 1.2% (V) k) Vapour pressure: 0.1 hPa (20°C) l) Vapour density: 4.7 at 20°C (Air=1) m) Relative density: 0.935 (20°C) n) Solubility (water): at 20 °C immiscible


SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016


Page 7 of 10

o) Partition coefficient n-Octanol/Water (log Pow): 2.81

p) Auto-ignition temperature: 300°C q) Decomposition temperature: No information available r) Viscosity: 2 mPas (20°C) s) Explosive properties: Not explosive t) Oxidising properties: Not classified as oxidising

9.2. Other information This safety datasheet only contains information relating to safety and does not replace any product information or product specification.


10.1. Reactivity Stable under normal conditions.

10.2. Chemical stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use.

10.4. Conditions to avoid Avoid heat, flames and sparks.

10.5. Incompatible materials Avoid contact with (organic) peroxides, unless under controlled processing. Avoid acids, acid chlorides and acid anhydrides.

10.6. Hazardous decomposition products Carbon oxides, nitrogen oxides (NOx)


11.1. Information on toxicological effects a) Acute toxicity:

Inhalation: Toxic if inhaled. Eye contact: Irritating to eyes. Skin contact. Toxic in contact with skin. Causes mild skin irritation. Ingestion: Toxic if swallowed.

Oral LD50: (rat) 1 767 mg/kg Dermal LD50: (mouse) >2 000 mg/kg Inhalation LC50: (rat – 4 h) 1.4 mg/l

b) Skin corrosion/irritation: Mild skin irritation c) Serious eye damage/irritation: Slightly irritating to eyes d) Respiratory or skin sensitisation: No data available

SAFETY DATA SHEET

Date: 04.11.14 Doc no: 407994 Rev.:3.2 19.07.2016


Page 8 of 10

e) Germ cell mutagenicity: DNA damage on rat and mouse f) Carcinogenicity: Ames test: negative result g) Reproductive toxicity: No data available h) STOT-single exposure: May cause damage to organs through prolonged

exposure. i) STOT-repeated exposure: May cause damage to organs through prolonged

or repeated exposure – category 2. j) Aspiration hazard: Harmful by inhalation.


An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Harmful to aquatic life with long lasting effects.

12.1. Toxicity N,N-Dimethyl-p-toluidine

Fish LC50: 46-52 mg/l (Pimephales promelas) 96 h

12.2. Persistence and degradability No information available

12.3. Bioaccumulative potential No information available

12.4. Mobility in soil No information available

12.5. Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

12.6. Other adverse effects Harmful to aquatic life with long lasting effects.


13.1. Waste treatment methods Waste from residues/unused products The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Hazardous waste Dispose of contents/container in accordance with local regulation.

Contaminated packaging: Disposal in accordance with local regulations. Do not flush residue into sewage or other waterpipes. EWC code: Code example 16 05 06 / 16 05 08; The waste code is intended as a guide. The user must select the appropriate code according to usage.

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Page 9 of 10


14.1. UN number ADR/RID/IMDG/IMO/IATA: UN2810

14.2. UN proper shipping name ADR/RID/IMDG/IMO: TOXIC LIQUID, ORGANIC, N.O.S. (N,N-Dimethyl-p-toluidine) IATA: Toxic liquid, organic, n.o.s. (N,N-Dimethyl-p-toluidine)

14.3. Transport hazard class(es) ADR/RID/IMDG/IMO/IATA: 6.1

14.4. Packing group ADR/RID Packing group: II Classification code: T1 Hazard id (Kemler no.): 60 Tunnel restriction code: D/E Labels: 6.1 LQ: 100 ml

IMDG/IMO Packing group: II Labels: 6.1 EmS number: F-A, S-A

IATA Packing instruction: 622 (cargo) Packing instruction: 654 (passenger) Packing instruction: Y641 (LQ) Packing group: II Labels: 6.1

14.5. Environmental hazards ADR/RID: no IMDG/IMO: Marine pollutant: no IATA: no

14.6. Special precautions for user See sections: 6, 7 and 8

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Not classified


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture European Parliament and Council Regulation (EC) No. 1907/2006 of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency and amending Directive 1999/45 / EC and repealing Council Regulation (EEC) No. 793/93 and Commission Regulation (EC) No. 1488/94 and Council Directive 76/769 / EEC and Commission Directive 91/155 / EEC, 93/67 / EC, 93/105 / EC and 2000/21 / EC, as amended. Commission Regulation (EU) 2015/830 of 25 May 2015 amending Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).

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Page 10 of 10

15.2. Chemical safety assessment not carried out Additional information: People under the age of 18 should not be exposed to this product.


Relevant H-statements referred to under sections 2 and 3 H301 Toxic if swallowed H311 Toxic in contact with skin H330 Fatal if inhaled H373 May cause damage to organs through prolonged or repeated exposure H412 Harmful to aquatic life with long lasting effects Changes

- Amended according to Commission Regulation (EU) 2015/830, Annex II.

Legal Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet

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Date: 04.11.14 Doc no: 364820 Rev.:2.2 20.12.2016

Trade name: Curing Initiator 40 / CI40 / TBPB / Norox TBPB / TRIGONOX C Page 1 of 11




1.1. Product identifier Trade name: Curing Initiator 40 / CI40 / TBPB / Norox TBPB

tert-butylperbenzoate / TRIGONOX CChemical name: tert-Butyl perbenzoate PR-no.: 2304754 (DK)

1.2. Relevant identified uses of the substance or mixture and uses advised against Initiator for curing UPR (Unsaturated Polymer Resin)






2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Organic peroxides, Type C H242 Acute toxicity, Cat. 4 H332 Skin irritation, Cat. 2 H315 Skin sensitisation, Cat. 1 H317 Acute aquatic toxicity, Cat. 1 H400 Chronic aquatic toxicity, Cat. 3 H412


Signal word Danger

Hazard Statements H242 Heating may cause a fire. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life.




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H412 Harmful to aquatic life with long lasting effects. Precautionary Statements PREVENTION P220 Keep/Store away from clothing/ strong acids, bases, heavy metal salts and other reducing substances /combustible materials P233 Keep container tightly closed P235 Keep cool P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray P262 Do not get in eyes, on skin, or on clothing P273 Avoid release to the environment P280 Wear protective gloves/ protective clothing/ eye protection/ face protection

RESPONSE P333 + P313 If skin irritation or rash occurs: Get medical advice/attention P362 + P364 Take off contaminated clothing and wash it before reuse DISPOSAL P501 Dispose of contents/ container to an approved waste disposal plant Hazardous components which must be listed on the label: tert-Butyl peroxybenzoate (CAS 614-45-9)

2.3. Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.


3.1. Substances Organic peroxide liquid

Substance CAS # % by weight

EC #

REACH #

tert-Butyl perbenzoate 614-45-9 99 - 100

210-382-2

01-2119513317-46-0003


REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). Status: Not applicable


4.1. Description of first aid measures General: Move out of dangerous area. Show this safety data sheet to the doctor in

attendance. Do not leave the victim unattended. Symptoms of poisoning may appear several hours later. Call a physician immediately.

First aiders: First Aid responders should pay attention to self-protection and use the recommended protective clothing.

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Eye Contact: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash contaminated clothing before re-use. If on skin, rinse well with water. If on clothes, remove clothes. If symptoms persist, call a physician.

Ingestion: Keep respiratory tract clear. Call a physician immediately. Rinse mouth thoroughly with water and drink afterwards plenty of water.

Inhalation: Call a physician or poison control centre immediately. If unconscious place in recovery position and seek medical advice. Keep respiratory tract clear. If breathed in, move person into fresh air.

4.2. Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Harmful if inhaled.

4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician: Treat symptomatically and supportively.


5.1. Extinguishing media Carbon dioxide (CO2), Dry chemical, Alcohol resistant foam, Water spray

Extinguishing media which must not be used for safety reasons: Do not use high volume water jet as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture Contact with incompatible materials or exposure to temperatures exceeding SADT may result in a self-accelerating de-composition reaction with release of flammable vapours which may auto-ignite. Flash back possible over considerable distance. The product burns violently. Vapours may form explosive mixtures with air. The product will float on water and can be reignited on surface water. Cool closed containers exposed to fire with water spray. Fire will produce smoke containing hazardous combustion products (see section 8.1).

5.3. Advice for firefighters Special protective equipment for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. Specific extinguishing methods Do not use a solid water stream as it may scatter and spread fire. Remove undamaged containers from fire area if it is safe to do so. Use water spray to cool unopened containers. Further information Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.



Use personal protective equipment.


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Remove all sources of ignition.

Follow safe handling advice and personal protective equipment recommendations.

Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.

Never return spills in original containers for re-use.

Treat recovered material as described in the section 13.


Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.

If the product contaminates rivers and lakes or drains inform respective authorities.


Contact with incompatible substances can cause decomposition at or below SADT.

Clear spills immediately.

Suppress (knock down) gases/vapours/mists with a water spray jet.

To clean the floor and all objects contaminated by this material, use plenty of water.

Soak up with inert absorbent material.

Isolate waste and do not reuse.

Non-sparking tools should be used.

Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.

6.4. Reference to other sections For personal protection see section 8. See section 12 regarding environmental information. See section 13 for disposal information.



Do not swallow.

Do not breathe vapours/dust.

Avoid exposure - obtain special instructions before use.

Avoid contact with skin and eyes.

Avoid formation of aerosol.

Take precautionary measures against static discharges.

Never return any product to the container from which it was originally removed.

Provide sufficient air exchange and/or exhaust in work rooms.

Avoid confinement.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Smoking, eating and drinking should be prohibited in the application area.

Wash thoroughly after handling.

For personal protection see section 8.

Protect from contamination.

Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

General Hygiene Considerations

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Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product. Protection against fire and explosion Avoid shock and friction. Keep away from heat and sources of ignition. Use only explosion-proof equipment. Keep away from combustible material.

7.2. Conditions for safe storage, including any incompatibilities Avoid impurities (e.g. rust, dust, ash), risk of decomposition. Electrical installations / working materials must comply with the technological safety standards. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from strong acids, bases, heavy metal salts and other reducing substances. Recommended storage temperature is between 10 - 30 °C. Avoid temperatures below

10C. No decomposition if stored normally.

7.3. Specific end use(s) For further information, consult for technical guidelines.


8.1. Control parameters Exposure Limits Contains no substances with occupational exposure limit values. Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Substance name End Use Exposure routes

Potential health effects Value

tert-Butylperbenzoat


4 mg/m3


6.25 mg/kg bw/day

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Substance name Environmental compartment Value

tert-Butylperbenzoat Fresh water 0.0088 mg/l

Marine water 0.0009 mg/l

Intermittent use/release 0.008 mg/l

Sewage treatment plant 0.6 mg/l

Fresh water sediment 0.24 mg/kg

Soil 0.043 mg/kg

Marine sediment 0.024 mg/kg

8.2. Exposure controls Engineering controls: Local ventilation may be required during certain operations. General: Avoid contact with skin, eyes and clothing. Smoking, consumption of food

or liquid, and storage of tobacco, food or liquid, are not allowed in the workroom. Whenever you take a break in using this product and when you have finished using it, all exposed areas of the body must be washed. Always wash hands, forearms and face. Clothing that has been

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contaminated with the product must be removed immediately. Make sure that eyewash and emergency showers are clearly marked and are close to the workstation location. Store and wash work clothing separately.


Eye protection: Tightly fitting safety glasses conforming to EN166. Also wear face protection

if there is a splash hazard. Ensure that eyewash stations and safety showers are close to the workstation location.

Skin protection: Impervious clothing that gives chemical protection.


Short use (break through time 30 min) Minimum layer thickness: 0.11 mm Material: Nitrile Type: Nitrile 0740 (KCL) Prolonged use (break through time >=480 min) Minimum layer thickness: 0.47 mm Material: Butyl II Type: Butyl II 0897 (KCL)

Data source: KCL GmbH, e-mail [email protected] This recommendation is advisory only and must be evaluated by responsible chemist familiar with the specific situation of anticipated use. It should not be construed as offering an approval for any specific use scenario.


Respiratory protection: In the case of dust or aerosol formation use respirator with an approved filter. Use full mask with combination filter type ABEK (EN141) when handling the product. Only use tested and approved equipment/component according to standards (CEN(EU)).




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9.1. Information on basic physical and chemical properties a) Appearance: light yellow liquid b) Odour: ester-like c) Odour threshold: no data available d) pH: no data available

e) Melting/freezing point: 10C f) Initial boiling point/range: Decomposition: Decomposes below the boiling point.

g) Flash point: 100C ISO3679 h) Evaporation rate: no data available i) Flammability (solid/gas): not applicable j) Upper/lower flammability no data available

or explosive limits: no data available

k) Vapour pressure: 0.00003 hPa at 20C l) Vapour density: no data available m) Relative density: 1.04 g/cm3 (20°C) n) Solubility (water): completely miscible in alcohol and phthalates o) Partition coefficient

n-Octanol/Water (log Pow): 3.0 (25C) p) Auto-ignition temperature: no data available

q) Decomposition temperature: Decomposes below the boiling point. SADT: 60C r) Viscosity: Dynamic: 8 mPas (20°C), kinematic: no data available s) Explosive properties: not explosive t) Oxidising properties: The substance or mixture is not classified as oxidizing.

Organic peroxide

9.2. Other information Refractive index: 1.499 at 20 °C


10.1. Reactivity Stable under recommended storage conditions.


10.3. Possibility of hazardous reactions Vapours may form explosive mixture with air.

SADT - 60C (Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size will undergo a self-accelerating decomposition reaction.)

10.4. Conditions to avoid Protect from contamination. Contact with incompatible substances can cause decomposition at or below SADT. Heat, flames and sparks. Avoid confinement.

10.5. Incompatible materials Accelerators, strong acids and bases, heavy metals and heavy metal salts, reducing agents.

10.6. Hazardous decomposition products Irritant, caustic, flammable, noxious/toxic gases and vapours can develop in the case of fire and decomposition. Potential decomposition products: Benzene (CAS 71-43-2), tert-Butanol (CAS 75-65-0), Acetone (CAS 67-64-1), Benzene (CAS 71-43-2), Isohexane (CAS 107-83-5).

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Harmful if inhaled. Produkt: Acute inhalation toxicity Components: tert-Butylperbenzoat

LC50: (rat – 4h) 4,9 mg/l (dust/mist) Oral LD0: (rat) >2 000 mg/kg Inhalation LC50: (rat – 4h) 4,9 mg/l (dust/mist) Dermal LD0: (rat) >2 000 mg/kg

b) Skin corrosion/irritation:

Causes skin irritation. Remarks: May cause skin irritation and/or dermatitis. Tert-Butylperbenzoat-test: Skin irritation.

c) Serious eye damage/irritation: Not classified based on available information. Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin. Tert-Butylperbenzoat-test: No eye irritation.

d) Respiratory or skin sensitisation: May cause an allergic skin reaction. Respiratory sensitization. Not classified based on available information. Remarks: Causes sensitisation. Tert-Butylperbenzoat-test: Probability or evidence of high skin sensitisation rate in humans.

e) Germ cell mutagenicity: Not classified based on available information. Tert-Butylperbenzoat-test: In vitro: Positive, in vivo: Negative

f) Carcinogenicity: Not classified based on available information. g) Reproductive toxicity: Not classified based on available information.

Tert-Butylperbenzoat-test: Fertility: (rat, oral 300 mg/kg): No observed adverse effect level. Foetal development: (rat, oral 300 mg/kg): No observed adverse effect level:.

h) STOT-single exposure: Not classified based on available information. i) STOT-repeated exposure: Not classified based on available information. j) Aspirasjonsfare: Not classified based on available information.

Further information: No data available.


12.1. Toxicity tert-Butyl perbenzoate:

Fish LC50: 1.6 mg/l (Danio rerio) (96 h) Aquatic invertebrates EC50: 11 mg/l (Daphnia magna) (48 h)

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Algae EC50: 0.8 mg/l (Pseudokirchneriella subcapitata) (72 h) Algae NOEC: 0,72 mg/l (Pseudokirchneriella subcapitata) (72h) M-Factor 1 (acute aquatic toxicity) Bacteria EC50: 43 mg/l (0.5 h) Aquatic invertebrates EC10: 0.49 mg/l (Daphnia magna) (21 d) chronic toxicity

12.2. Persistence and degradability tert-Butyl perbenzoate:: Readily biodegradable

12.3. Bioaccumulative potential tert-Butyl perbenzoate:: Partition coefficient n-octanol/water: Log Pow 2.89

(25C) 12.4. Mobility in soil No information available 12.5. Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6. Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life. Harmful to aquatic life with long lasting effects.


13.1. Waste treatment methods Waste from residues/unused products: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of wastes in an approved waste disposal facility.

Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. Dispose of in accordance with local regulations. EWC-code: suggestion: 16 09 03 (peroxides)


14.1. UN number ADN/ADR/RID/IMDG/IMO/IATA: UN3103

14.2. UN proper shipping name ADN/ADR/RID/IMDG: ORGANIC PEROXIDE TYPE C, LIQUID (tert-BUTYL

PEROXYBENZOATE) IATA: Organic peroxide type C, liquid

(tert-Butyl peroxybenzoate) 14.3. Transport hazard class(es) ADN/ADR/RID/IMDG/IATA: 5.2 14.4. Packing group

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ADN/ADR Packing group: Not assigned by regulation Classification Code: P1 Labels: 5.2 Tunnel restriction code: (D) Limited quantity: LQ14 RID Packing group: Not assigned by regulation Classification Code: P1 Hazard Identification Number: 539 Labels: 5.2 Limited quantity: LQ14 IMDG-Code Packing group: Not assigned by regulation Labels: 5.2 EmS Code: F-J, S-R IATA-DGR Packing instruction (cargo aircraft): 570 Packing instruction (passenger aircraft): 570 Packing group: Not assigned by regulation Labels: Organic Peroxides, Keep Away From Heat

14.5. Environmental hazards ADN/ADR/RID (Environmentally hazardous): yes IMDG (Marine pollutant): yes

14.6. Special precautions for user not applicable

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable for product as supplied.


15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Pressure Equipment (Amendment) Regulations 2011. Chemicals (Hazard Information and Packaging for Supply) Regulations 2009. Control of Substances Hazardous to Health Regulations 2002 (as amended). Merchant Shipping (Dangerous Goods and Marine Pollutants) Regulations 1997. Reporting of Injuries, Diseases and Dangerous Occurrences Regulations 1995 (as amended). Personal Protective Equipment Regulations 2002. Personal Protective Equipment at Work Regulations 1992. Hazardous Waste (England and Wales) Regulations 2005(as amended). EC regulation 1907/2006 (REACH) Directive 2000/532/EC and Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006.

Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and import of dangerous chemicals.

: Not applicable

REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).

: Not applicable

Regulation (EC) No 1005/2009 on substances that deplete the ozone layer.

: Not applicable

Regulation (EC) No 850/2004 on persistent organic pollutants. : Not applicable

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Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. Quantity 1 Quantity 2 P6b SELF-REACTIVE

SUBSTANCES AND MIXTURES and ORGANIC PEROXIDES

50 t 200 t

E1 ENVIRONMENTAL HAZARDS

100 t 200 t

15.2. Chemical safety assessment Information not available Additional information: People under the age of 18 should not be exposed to this product.


Relevant H-statements referred to under sections 2 and 3 H242 Heating may cause a fire. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H332 Harmful if inhaled. H400 Very toxic to aquatic life. H412 Harmful to aquatic life with long lasting effects. Changes

- General update of the document.



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Date: 04.11.14 Doc no: 468099 Rev.:3.2 12.12.2016

Trade name: Curing Initiator 65 / CI65 / Benox L-40LV Page 1 of 11




1.1. Product identifier Trade name: Curing Initiator 65 / CI65 / Benox L-40LV

Chemical family: Dibenzoyl peroxide PR-no.: 2304762 (DK)







2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Self-reactive organic peroxides, Type E H242 Eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Acute aquatic toxicity, Category 1 H400


Signal word Warning Contains: Dibenzoyl peroxide

Hazard Statements H242 Heating may cause a fire H317 May cause an allergic skin reaction H319 Causes serious eye irritation H400 Very toxic to aquatic life




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Precautionary Statements PREVENTION P220 Keep/Store away from clothing/ strong acids, bases, heavy metal salts and other reducing substances /combustible materials P233 Keep container tightly closed P235 Keep cool P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray P262 Do not get in eyes, on skin, or on clothing P273 Avoid release to the environment P280 Wear protective gloves/ protective clothing/ eye protection/ face protection

RESPONSE P363 Wash contaminated clothing before reuse P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes Remove contact lenses, if present and easy to do. Continue rinsing P333 + P313 If skin irritation or rash occurs: Get medical advice/attention P337 + P313 If eye irritation persists: Get medical advice/ attention P362 + P364 Take off contaminated clothing and wash it before reuse DISPOSAL P501 Dispose of contents/ container to an approved waste disposal plant Hazardous components which must be listed on the label: Dibenzoyl peroxide (CAS-No. 94-36-0)



3.2. Mixtures Organic peroxide liquid mixture

Substance CAS # % by weight CLP Substance Classification

EC #

REACH #

Dibenzoyl peroxide 94-36-0 40 - <45 Org. Peroxide B; H241 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Acute 1; H400

202-327-6

01-2119511472-50



4.1. Description of first aid measures General: Move out of dangerous area. Show this safety data sheet to the doctor in

attendance. Do not leave the victim unattended. Call a physician immediately. First aiders: First Aid responders should pay attention to self-protection and use the

recommended protective clothing. Eye Contact: In the case of contact with eyes, rinse immediately with plenty of water and seek

medical advice. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

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Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash contaminated clothing before re-use. If on skin, rinse well with water. If on clothes, remove clothes. If symptoms persist, call a physician.

Ingestion: Keep respiratory tract clear. Call a physician immediately. Rinse mouth thoroughly with water.

Inhalation: If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. If breathed in, move person into fresh air.

4.2. Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye irritation.




Extinguishing media which must not be used for safety reasons: Do not use high volume water jet as it may scatter and spread fire. 5.2. Special hazards arising from the substance or mixture Contact with incompatible materials or exposure to temperatures exceeding SADT may result in a self-accelerating de-composition reaction with release of flammable vapours which may auto-ignite. Flash back possible over considerable distance. Vapours may form explosive mixtures with air. The product will float on water and can be reignited on surface water. Cool closed containers exposed to fire with water spray.

5.3. Advice for firefighters Special protective equipment for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. Specific extinguishing methods Do not use a solid water stream as it may scatter and spread fire. Remove undamaged containers from fire area if it is safe to do so. Use water spray to cool unopened containers. Further information Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.







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Contact with incompatible substances can cause decomposition at or below SADT.

Clear spills immediately. Suppress (knock down) gases/vapours/mists with a water spray jet.

To clean the floor and all objects contaminated by this material, use plenty of water.

Soak up with inert absorbent material.



Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable.

6.4. Reference to other sections For personal protection see section 8.



Do not swallow.

Do not breathe vapours/dust.

Avoid contact with skin and eyes.


Take precautionary measures against static discharges.

Never return any product to the container from which it was originally removed.

Provide sufficient air exchange and/or exhaust in work rooms.

Avoid confinement.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.


Wash thoroughly after handling.


Protect from contamination.

General Hygiene Considerations Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product. Protection against fire and explosion Keep away from heat and sources of ignition. Use only explosion-proof equipment. Keep away from combustible material.

7.2. Conditions for safe storage, including any incompatibilities Avoid impurities (e.g. rust, dust, ash), risk of decomposition. Electrical installations / working materials must comply with the technological safety standards. Containers which are opened must

SAFETY DATA SHEET

Date: 04.11.14 Doc no: 468099 Rev.:3.2 12.12.2016


be carefully resealed and kept upright to prevent leakage. Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from strong acids, bases, heavy metal salts and other reducing substances. Recommended storage temperature is between 0 - 30 °C. No decomposition if stored normally.

7.3. Specific end use(s) For further information, refer to the product technical data sheet.


8.1. Control parameters Exposure Limits TWA (time-weighted average), STEL (Short Term Exposure Limit)

Components CAS no. Control parameters

dibenzoyl peroxide 94-36-0 TWA: 5 mg/m³ 8 hours

Zinc stearate 557-05-1 TWA inhalable dust: 10 mg/m³ 8 hours TWA respirable dust: 4 mg/m³ 8 hours STEL inhalable dust: 20 mg/m³ 15 minutes

UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011). Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used. For the purposes of these limits, respirable dust and inhalable dust are those fractions of airborne dust which will be collected when sampling is undertaken in accordance with the methods described in MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust, The COSHH definition of a substance hazardous to health includes dust of any kind when present at a concentration in air equal to or greater than 10 mg/m³ 8-hour TWA of inhalable dust or 4 mg/m³ 8-hour TWA of respirable dust. This means that any dust will be subject to COSHH if people are exposed above these levels. Some dusts have been assigned specific WELs and exposure to these must comply with the appropriate limit. Most industrial dusts contain particles of a wide range of sizes. The behaviour, deposition and fate of any particular particle after entry into the human respiratory system and the body response that it elicits, depend on the nature and size of the particle. HSE distinguishes two size fractions for limit-setting purposes termed 'inhalable' and 'respirable'., Inhalable dust approximates to the fraction of airborne material that enters the nose and mouth during breathing and is therefore available for deposition in the respiratory tract. Respirable dust approximates to the fraction that penetrates to the gas exchange region of the lung. Fuller definitions and explanatory material are given in MDHS14/3. Where dusts contain components that have their own assigned WEL, all the relevant limits should be complied with.

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Substance name End Use Exposure routes Potential health effects Value

Dibenzoyl peroxide


11.75 mg/m3


6.6 mg/kg bw/day



Dibenzoyl peroxide Fresh water 0.000602 mg/l

Marine water < 0.0001 mg/l

Intermittent use/release 0.000602 mg/l


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Fresh water sediment 0.338 mg/kg

Soil 0.0758 mg/kg

Oral 6.67 mg/kg

8.2. Exposure controls Engineering controls: Use general ventilation to maintain airborne concentrations to levels that

are below regulatory and recommended occupational exposure limits. Local ventilation may be required during certain operations.

Hygiene measures: General information/ Hygiene measures: Smoking, consumption of food or liquid, and storage of tobacco, food or liquid, are not allowed in the workroom. Whenever you take a break in using this product and when you have finished using it, all exposed areas of the body must be washed. Always wash hands, forearms and face. Make sure that eyewash and emergency showers are clearly marked and are close to the workstation location. Store and wash work clothing separately. Avoid contact with eyes and skin.


Eye protection: Safety glasses with side-shields conforming to EN166. Tightly fitting safety

goggles (EN166) should be used if splashes are likely to occur. Ensure that eyewash stations and safety showers are close to the workstation location.

Skin protection: Impervious clothing.


Short use (break through time 480 min) Minimum layer thickness: 0.11 mm Material: Nitrile II Type: Nitrile II 0743 (KCL) Prolonged use (break through time 480 min) Minimum layer thickness: 0.47 mm Material: Butyl II Type: Butyl II 0897 (KCL)


Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated


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gloves after use in accordance with applicable laws and good laboratory practices. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion.

Respiratory protection: In the case of dust or aerosol formation use respirator with an approved filter.

Recommended filter type: Type ABEK (EN141)



9.1. Information on basic physical and chemical properties a) Appearance: white suspension b) Odour: characteristic c) Odour threshold: not available d) pH: n/a e) Melting/freezing point: not available f) Initial boiling point/range: Decomposition: Decomposes below the boiling point. g) Flash point: n/a h) Evaporation rate: n/a i) Flammability (solid/gas): does not ignite j) Upper/lower flammability n/a

or explosive limits: n/a k) Vapour pressure: n/a l) Vapour density: not available m) Relative density: 1.2 g/cm3 (25°C) n) Solubility (water): Insoluble o) Partition coefficient

n-Octanol/Water (log Pow): No information available p) Auto-ignition temperature: No information available

q) Decomposition temperature: Decomposes below the boiling point. SADT: 50C r) Viscosity: Dynamic: 1 mPas , kinematic: n/a s) Explosive properties: not explosive t) Oxidising properties: not classified


SADT - 50C (Self Accelerating Decomposition Temperature. Lowest temperature at which the tested package size will undergo a self-accelerating decomposition reaction.)


10.1. Reactivity Stable under recommended storage conditions.


10.3. Possibility of hazardous reactions Vapours may form explosive mixture with air.


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Protect from contamination. Contact with incompatible substances can cause decomposition at or below SADT. Heat, flames and sparks. Avoid confinement.

10.5. Incompatible materials Accelerators, strong acids and bases, heavy metals and heavy metal salts, reducing agents.

10.6. Hazardous decomposition products No information available


11.1. Information on toxicological effects a) Acute toxicity: Not classified based on available information. Components: Dibenzoyl peroxide: Oral LD50: (rat) >5 000mg/kg Inhalation LC50: (rabbit) 24.3 mg/l (4 h) dust/mist

b) Skin corrosion/irritation: Not classified. May cause skin irritation and/or

dermatitis c) Serious eye damage/irritation: Causes serious eye irritation. May cause irreversible

eye damage d) Respiratory or skin sensitisation: May cause an allergic skin reaction. Respiratory

sensitisation: Not classified based on available information

e) Germ cell mutagenicity: Not classified based on available information. Dibenzoyl peroxide test – genotoxicity in vitro/in vivo - negative

f) Carcinogenicity: Not classified based on available information. Dibenzoyl peroxide test- negative

g) Reproductive toxicity: Not classified based on available information. Dibenzoyl peroxide test (rat) oral, fertility: No observed adverse effect level >1 000 mg/kg body weight. No effects on fertility.

h) STOT-single exposure: Not classified based on available information. i) STOT-repeated exposure: Not classified based on available information.

Dibenzoyl peroxide test: (rat), NOAL 1 000 mg/kg (oral) (28 d)

j) Aspiration hazard: Not classified based on available information.


12.1. Toxicity Dibenzoyl peroxide

Algae EC50: 0.0711 mg/l (Pseudokirchneriella subcapitata) 72 h Fish LC50: 0.0602 mg/l (Oncorhynchus mykiss) 96 h Aquatic invertebrates EC50: 0.11 mg/l (Daphnia magna) 48 h M-Factor 10 (acute aquatic toxicity) Bacteria EC50: 35 mg/l 0.5 h

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12.2. Persistence and degradability Dibenzoyl peroxide: biodegradable


Dibenzoyl peroxide: Partition coefficient n-octanol/water: Log pow 3.2 (20C) 12.4. Mobility in soil No information available 12.5. Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6. Other adverse effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life.


13.1. Waste treatment methods Waste from residues/unused products: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of wastes in an approved waste disposal facility.

Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. Dispose of in accordance with local regulations. EWC-code: option: 08 04 09


14.1. UN number ADN/ADR/RID/IMDG/IMO/IATA: UN3107

14.2. UN proper shipping name ADN/ADR/RID/IMDG/IMO: ORGANIC PEROXIDE TYPE E, LIQUID (DIBENZOYL PEROXIDE) IATA: Organic peroxide type E, liquid (Dibenzoyl peroxide) 14.3. Transport hazard class(es) ADN/ADR/RID/IMDG/IMO/IATA: 5.2 14.4. Packing group ADN/ADR/RID/IMDG/IMO/IATA: Packing group: Not assigned by regulation ADN/ADR/RID: Classification code: P1 ADN/ADR/IMDG: Labels: 5.2 RID: Hazard ID: 539 ADR: Tunnel restriction code: (D) IMDG: EmS Code: F-J, S-R IATA: Packing instruction (cargo): 570 IATA: Packing instruction (passenger): 570

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IATA: Packing group: Not assigned by regulation IATA: Labels: Organic Peroxides, Keep Away From Heat

14.5. Environmental hazards AND/ADR/RID: Environmentally hazardous: yes IMDG/IMO: Marine pollutant: yes





Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and import of dangerous chemicals.

: Not applicable

REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).

: Not applicable

Regulation (EC) No 1005/2009 on substances that deplete the ozone layer.

: Not applicable

Regulation (EC) No 850/2004 on persistent organic pollutants.

: Not applicable



50 t 200 t


100 t 200 t

15.2. Chemical safety assessment Information not available Additional information: People under the age of 18 should not be exposed to this product.


Relevant H-statements referred to under sections 2 and 3 H242 Heating may cause a fire H317 May cause an allergic skin reaction

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H319 Causes serious eye irritation H400 Very toxic to aquatic life Changes




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Trade name: Curing Initiator T / CIT / TRIGONOX T / TBCP Page 1 of 14




1.1. Product identifier Trade name: Curing Initiator T / CIT / TRIGONOX T / TBCP /

tert-butyl cumyl peroxide Chemical name: tert-butyl cumyl peroxide PR-no.: 2482200 (DK)







2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Org. Perox. Type E H242 Aquatic Chronic 2 H411 Skin Irri. 2 H315 Skin Sens. 1 H317 Eye Irrit. 2 H319


Signal word Warning

Hazard Statements H242 Heating may cause a fire. H315 Causes skin irritation. H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects.




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Precautionary Statements PREVENTION P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.

No smoking. P220 Keep away from dirt, rust, chemicals in particular concentrated acids, alkalis and

accelerators (e. g. heavy metal compounds and amines). P234 Keep only in original container. P243 Take precautionary measures against static discharge. P264 Wash thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P362 Take off contaminated clothing. P410 Protect from sunlight. P411+P235 Store at temperatures not exceeding +40°C. Keep cool. P420 Do not mix with peroxide-accelerators or reducing agents.

RESPONSE P302+352 IF ON SKIN: Wash with plenty of water. DISPOSAL P501 Dispose of contents/ container to an approved waste disposal plant Hazardous components which must be listed on the label: tert-Butyl cumyl peroxide (CAS 3457-61-2)



3.1. Substances Organic peroxide liquid


EC #

REACH #

tert-Butyl cumyl peroxide

3457-61-2 90 - 100 Org. Perox. E; H242 Skin Irrit. 2; H315 Skin Sens. 1; H317 Aquatic Chronic 2; H411

222-389-8

01-2119969063-35

.alpha.-Methylstyrene 98-83-9 5 - 10 Flam. Liq. 3; H226 Eye Irrit. 2; H319 STOT SE 3; H335 Aquatic Chronic 2; H411

Acetophenone 98-86-2 1 - 3 Acute Tox. 4; H302 Eye Irrit. 2; H319

Cumene 98-82-8 0.25 Flam. Liq. 3; H226 STOT SE 3; H335 Asp. Tox. 1; H304 Aquatic Chronic 2; H411

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Note: Sk

Remarks: tert-Butyl cumyl peroxide, neat For full text of H-statements: see section 2.2 or 16.



4.1. Description of first aid measures General: Move out of dangerous area. Consult a physician. Show this safety data sheet to the

doctor in attendance. Eye Contact: Rinse immediately with plenty of water. Remove contact lenses. Protect unharmed

eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. Skin Contact: Immediately flush skin with plenty of water and soap for at least 15 minutes while

removing contaminated clothing and shoes. If symptoms persist, call a physician. Wash contaminated clothing before re-use.

Ingestion: Rinse mouth thoroughly with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Obtain medical attention.

Inhalation: Move person into fresh air. Call a physician after significant exposure.

4.2. Most important symptoms and effects, both acute and delayed The symptoms and effects are as expected from the hazards as shown in section 2. Inhalation: Inhalation of aerosols may cause irritation to mucous membranes.

Thermal decomposition can lead to release of irritating gases and vapours.

Skin: Causes skin irritation. May cause an allergic skin reaction. Eyes: May cause eye irritation. Ingestion: May be harmful if swallowed.




Extinguishing media which must not be used for safety reasons: Do not use high volume water jet as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture CAUTION: re-ignition may occur. Supports combustion. Do not use a solid water stream as it may scatter and spread fire. Water spray may be ineffective unless used by experienced firefighters. Heating may cause decomposition with release of toxic fumes. Do not allow run-off from fire-fighting to enter drains or water courses. Fire will produce smoke containing hazardous combustion products (see section 10).

5.3. Advice for firefighters Special protective equipment for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Use personal protective equipment. Do not inhale explosion gases or combustion gases. Specific extinguishing methods

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Do not use a solid water stream as it may scatter and spread fire. Remove undamaged containers from fire area if it is safe to do so. Use water spray to cool unopened containers. Further information Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.













Keep wetted with water.

Clear spills immediately.

Soak up with inert absorbent material and dispose of as hazardous waste.


Confinement must be avoided.




6.4. Reference to other sections For personal protection see section 8. See section 12 regarding environmental information. See section 13 for disposal information.




Persons with a history of skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.


Open drum carefully as content may be under pressure.

Dispose of rinse water in accordance with local and national regulations.

Avoid contact with skin, eyes and clothing.

General Hygiene Considerations Keep away from food and drink. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product.

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Protection against fire and explosion

Use explosion protected equipment.


Keep away from sources of ignition - No smoking.

No sparking tools should be used.

Keep away from reducing agents (e.g. amines), acids, alkalies and heavy metal compounds (e.g. accelerators, driers, metal soaps).

Do not cut or weld on or near this container even when empty.

Take measures to prevent the build up of electrostatic charge.

Keep away from combustible material.

It is recommended to use electrical equipment of temperature group T3. However, autoignition can never be excluded.

7.2. Conditions for safe storage, including any incompatibilities No smoking. Electrical installations / working materials must comply with the technological safety standards. Keep only in original container. Store away from other materials. Protect from heat and direct sunlight. Store at temperatures below +40 °C. No decomposition if stored normally.




Component CAS no. Workplace Control Parameters* Reference*


98-83-9 TWA: 50 ppm (246 mg/m³) STEL: 100 ppm (491 mg/m³)

Cumene 98-82-8 TWA: 25 ppm (125 mg/m³) STEL: 50 ppm (250 mg/m³)

Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity.

*UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011) Occupational exposure limits of decomposition products

Component CAS no. Workplace Control Parameters* Reference*

Acetone 67-64-1 TWA: 500 ppm (1210 mg/m³) STEL: 1500 ppm (3620 mg/m³)

*UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011) Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

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2.64 mg/m3


3 mg/kg



246 mg/m3

Workers Inhalation Acute local effects 492 mg/m3


38 mg/kg

Consumers Inhalation Long-term systemic effects

41 mg/m3

Consumers Skin contact Long-term systemic effects

11.4 mg/kg bw/day

Consumers Ingestion Long-term systemic effects

11.4 mg/kg



tert-Butyl cumyl peroxide Fresh water 43 mg/l


Intermittent water 0.043 mg/l

Sewage treatment plant 10 mg/l

Fresh water sediment 8.73 mg/kg dry weight

Marine Sediment 0.873 mg/kg dry weight

Soil 1.72 mg/kg mg/kg dry weight

.alpha.-Methylstyrene Fresh water 0.008 mg/l


Intermittent water 0.01645 mg/l


Fresh water sediment 0.583 mg/kg dry weight

Marine Sediment 0.0583 mg/kg dry weight

Soil 0.112 mg/kg dry weight


or liquid, and storage of tobacco, food or liquid, are not allowed in the workroom. Whenever you take a break in using this product and when you have finished using it, all exposed areas of the body must be washed. Always wash hands, forearms and face. Clothing that has been contaminated with the product must be removed immediately. Make sure that eyewash and emergency showers are clearly marked and are close to the workstation location. Store and wash work clothing separately.

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Eye protection: Tightly fitting safety glasses conforming to EN166. Also wear face protection

if there is a splash hazard. Ensure that eyewash stations and safety showers are close to the workstation location.

Skin protection: Impervious clothing that gives chemical protection.


Break through time >=480 min Minimum layer thickness: 0.4 mm Material: Nitrile Type: Nitrile 0730 (KCL) Break through time >=480 min Minimum layer thickness: 0.47 mm Material: Butyl II Type: Butyl II 0897 (KCL)

Data source: KCL GmbH, e-mail [email protected] This recommendation is advisory only and must be evaluated by responsible chemist familiar with the specific situation of anticipated use. It should not be construed as offering an approval for any specific use scenario.


Respiratory protection: In the case of dust or aerosol formation use respirator with an approved filter. Use full mask with combination filter type ABEK (EN141) when handling the product. Only use tested and approved equipment/component according to standards (CEN(EU)).

Environmental exposure controls Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained (contamination to rivers, lakes or drains).


9.1. Information on basic physical and chemical properties a) Appearance: Clear colourless liquid


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b) Odour: Faint c) Odour threshold: no data available d) pH: Neutral

e) Melting/freezing point: 0 - 16C f) Initial boiling point/range: Decomposition: Decomposes below the boiling point.

g) Flash point: 82C (closed cup) h) Evaporation rate: no data available i) Flammability (solid/gas): Decomposition products may be flammable j) Upper/lower flammability no data available

or explosive limits: no data available

k) Vapour pressure: 0.1 hPa at 20C l) Vapour density: no data available m) Relative density: 0.940 g/cm3 (20°C) n) Solubility (water): Immiscible at 20°C o) Partition coefficient

n-Octanol/Water (log Pow): 4.4 (20C) p) Auto-ignition temperature: test method not applicable

q) Decomposition temperature: Decomposes below the boiling point. SADT: 80C r) Viscosity: Dynamic: 4 mPas (20°C), kinematic: 4.26 m2/s (20°C) s) Explosive properties: not explosive t) Oxidising properties: The substance or mixture is not classified as oxidizing.

9.2. Other information Active oxygen content: 7.3 % Organic peroxides: 94 – 96 %





SADT - 80C (Self accelerating decomposition temperature) is the lowest temperature at which self-accelerating decomposition may occur with a substance in the packaging as used in transport. A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by thermal decomposition at and above the SADT. Contact with incompatible substances can cause decomposition below the SADT.

10.4. Conditions to avoid A high degree of confinement must be avoided. Heat, flames and sparks.

10.5. Incompatible materials Contact with incompatible materials will result in hazardous decomposition. For queries regarding the suitability of other materials please contact the supplier. Do not mix with peroxide accelerators, unless under controlled processing. Use only stainless steel 316, PP, polyethylene or glass-lined equipment. Acids and bases. Iron. Copper. Reducing agents. Heavy metals. Rust.


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Potential decomposition products: Acetone (CAS 67-64-1), 2-Phenylisopropanol (CAS 617-94-7), Acetophenone ( CAS 98-86-2), Carbon oxides.


Hazard summary Inhalation: Inhalation of aerosols may cause irritation to mucous membranes.

Thermal decomposition can lead to release of irritating gases and vapours.

Skin: Causes skin irritation. May cause an allergic skin reaction. Eyes: May cause eye irritation. Ingestion: May be harmful if swallowed. Toxicology Assessment No further information available. 11.1. Information on toxicological effects Test result Acute oral toxicity: Acute toxicity estimate: > 2 000 mg/kg

Component:


a) Acute toxicity:

Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Repeated dose toxicity

LD50: (rat) > 4 700 mg/kg LC50: (rat – 4h) >1.2 mg/l (dust/mist) LD50: (rat) > 2 000 mg/kg NOEL 150 mg/kg (rat, oral, 28 days)


(rabbit): Skin irritation.

c) Serious eye damage/irritation: No eye irritation. d) Respiratory or skin sensitisation: May cause an allergic skin reaction. e) Germ cell mutagenicity: Not classified based on available information.

In vitro: Negative, in vivo: No data available f) Carcinogenicity: Not classified based on available information. g) Reproductive toxicity: Species: Rat, male and female

Application Route: Oral Dose: 0, 75, 150, 600 milligram per kilogram General Toxicity - Parent: No observed adverse effect level: 150 mg/kg bw/day Fertility: No observed adverse effect level Parent: 150 mg/kg bw/day

h) STOT-single exposure: Not classified based on available information. i) STOT-repeated exposure: The substance or mixture is not classified as

specific target organ toxicant, repeated exposure.

j) Aspiration hazard: Not classified based on available information.

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Component:

.alpha.-Methylstyrene Eye irritation: Irritating to eyes STOT- single exposure: Inhalation, respiratory system. The substance or

mixture is classified as specific target organ toxicant, single exposure, category 3 with respiratory tract irritation.

Aspiration toxicity: No aspiration toxicity classification. Component:

Acetophenone Acute oral toxicity: LD50 301 – 2 000 mg/kg Component: Cumene Acute oral toxicity: LD50 (rat) >2 000 mg/kg STOT- Single exposure: Inhalation. May cause respiratory irritation. Aspiration toxicity: May be fatal if swallowed and enters airways. Further information: No data available.


Ecotoxicology assessment Chronic aquatic toxicity: Toxic to aquatic life with long lasting effects. Additional ecological information: An environmental hazard cannot be excluded in the event of

unprofessional handling or disposal. Toxic to aquatic life with long lasting effects.

12.1. Toxicity Ecotoxicology assessment tert-Butyl perbenzoate Acute aquatic toxicity: Toxic to aquatic life. Chronic aquatic toxicity: Toxic to aquatic life with long lasting effects. .alpha.-Methylstyrene Acute aquatic toxicity: Toxic to aquatic life. Chronic aquatic toxicity: Toxic to aquatic life with long lasting effects. Test results tert-Butyl perbenzoate

Aquatic invertebrates EC50: 4.3 mg/l (Daphnia magna) (48 h) Algae ErC50: >100 mg/l (Pseudokirchneriella subcapitata) (72 h) Algae NOEC: 0.58 mg/l (Pseudokirchneriella subcapitata) (72h)

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Bacteria NOEC: 100 mg/l (58 d) .alpha.-Methylstyrene

Aquatic invertebrates NOEC: 0.401 mg/l (Daphnia magna) (21 d) (Chronic toxicity) Cumene

Aquatic invertebrates EC50: >1 - 10 mg/l (Daphnia magna) (48 h)

12.2. Persistence and degradability No information tert-Butyl cumyl peroxide Not readily biodegradable Cumene Not readily biodegradable

12.3. Bioaccumulative potential No information available. tert-Butyl cumyl peroxide Bioaccumulation: Bioconcentration factor (BCF): 2,57 Cumene Bioaccumulation: No data available 12.4. Mobility in soil No information available 12.5. Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6. Other adverse effects No information available


13.1. Waste treatment methods Waste from residues/unused products: The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Hazardous waste. Dispose of wastes in an approved waste disposal facility.

Contaminated packaging: Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. Dispose of in accordance with local regulations. Follow all warnings even after the container is emptied.

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EWC-code: suggestion: 16 09 03 (peroxides)


14.1. UN number ADR/RID/IMDG-Code/IATA-DGR: UN3107

14.2. UN proper shipping name ADN/ADR/IMDG: ORGANIC PEROXIDE TYPE E, LIQUID

(tert-Butyl cumyl peroxide) RID: ORGANIC PEROXIDE TYPE E, LIQUID

(tert-Butyl cumyl peroxide) IMDG-Code: ORGANIC PEROXIDE TYPE E, LIQUID

(tert-Butyl cumyl peroxide) IATA-DGR: Organic peroxide type E, liquid

(tert-Butyl cumyl peroxide)

14.3. Transport hazard class(es) ADR/RID/IMDG-Code: 5.2 IATA-DGR: 5.2 (HEAT) 14.4. Packing group ADR Packing group: Not assigned by regulation Classification Code: P1 Labels: 5.2 Tunnel restriction code: (D) RID Packing group: Not assigned by regulation Classification Code: P1 Hazard Identification Number: 539 Labels: 5.2 IMDG-Code Packing group: Not assigned by regulation Labels: 5.2 EmS Code: F-J, S-R IATA-DGR Packing instruction (cargo aircraft): 570 Packing instruction (passenger aircraft): 570 Packing group: Not assigned by regulation Labels: 5.2 (HEAT)

14.5. Environmental hazards ADR/RID/IMDG-Code (Environmentally hazardous): yes IMDG (Marine pollutant): yes (tert-Butyl cumyl peroxide)


14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

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Not applicable for product as supplied.





50 t 200 t


200 t 500 t

REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) EU. REACH - Annex XVII: Banned and/or restricted:

Cumene

15.2. Chemical safety assessment tert-Butyl cumyl peroxide: A Chemical Safety Assessment has been carried out for this

substance. Cumene: No information available. Additional information: People under the age of 18 should not be exposed to this product.


Relevant H-statements referred to under sections 2 and 3 H242 Heating may cause a fire. H315 Causes skin irritation. H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects.

H226 Flammable liquid and vapour H335 May cause respiratory irritation H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways

Changes


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SAFETY DATA SHEET

Date: 25.01.2017 Doc no: 611159 Rev.:1.0 25.01.2017

Trade name: EnvoSet® Page 1 of 8




1.1. Product identifier Trade name: EnvoSet®

Chemical family: Polyester Resin

1.2. Relevant identified uses of the substance or mixture and uses advised against Restore & maintain integrity of oil & gas wells






2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin. Sens. 1B H317


Signal word Warning

Hazard Statements H317 May cause an allergic skin reaction

Precautionary Statements PREVENTION P280 Wear protective gloves/protective clothing/eye protection/face protection

RESPONSE P302 + P352 IF ON SKIN: Wash with plenty of soap and water P333 + P313 If skin irritation or rash occurs: Get medical advice/attention2.3. Other hazards see sections 7 and 8




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3.2. Mixtures Liquid unsaturated polymer resin

Component CAS # EC # % by weight EC CLP Classification REACH #

1,4-Butanediol Dimethacrylate

2082-81-7 218-218-1 55 - 65 Skin. Sens. 1B (H317)

01-2119967415-30



4.1. Description of first aid measures Eye Contact: Immediately flush eyes for at least 15 minutes. Get medical attention. Skin Contact: Wash off with warm water and soap. Remove contaminated clothing and shoes.

If skin irritation persists, call a doctor. Wash contaminated clothing before re-use. Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person.

Get immediate medical advice/attention. Inhalation: In case of unconsciousness bring patient into stable side position for transport.

Remove to fresh air. Keep patient warm and at rest. If breathing is laboured, administer oxygen. If not breathing, give artificial respiration. Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed May cause allergic skin reaction.

4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician: Treat symptomatically.


5.1. Extinguishing media Carbon dioxide (CO2), Foam, Dry chemical, Alcohol resistant foam, Water spray

Extinguishing media which must not be used for safety reasons: Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases flammable. Combustion may produce carbon monoxide, carbon dioxide, irritating or toxic vapours and gases. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

5.3. Advice for firefighters Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and protective suit.

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6.1. Personal precautions, protective equipment and emergency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Avoid contact with skin and eyes. Use personal protective equipment as required. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. All equipment used when handling the product must be grounded.

6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains. Soak up with inert absorbent material and dispose of as hazardous waste.

6.3. Methods and material for containment and cleaning up Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use clean non-sparking tools to collect absorbed material.

6.4. Reference to other sections See section 12 for more information


7.1. Precautions for safe handling Do not breathe vapour or mist. Avoid contact with skin, eyes or clothing. Take off contaminated clothing and wash it before reuse. Ensure adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion-proof equipment. Consult your supplier of promoters and catalysts for additional instructions on proper mixing and usage. Empty containers may retain product residue (liquid and/or vapour). Do not pressurize, cut, weld, braze, solder, drill, grind, or expose these containers to heat, flame, sparks, static electricity, or other sources of ignition as the container may explode and may cause injury or death. Empty drums should be completely drained and properly bunged. Empty drums should be promptly returned to a drum reconditioner or properly disposed. Do not use compressed air for filling, discharging or handling. Wash hands before breaks and immediately after handling the product.

General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Protect from direct sunlight. Store away from incompatible materials. Keep containers tightly closed in a cool, well-ventilated place. To ensure maximum stability and maintain optimum resin properties, resins should be stored in closed containers at temperatures below 25°C.



8.1. Control parameters Exposure Limits 1,4-Butanediol Dimethacrylate not listed in the UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011)

Biological occupational exposure limits

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This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific regulatory bodies.

8.2. Exposure controls Engineering controls: Use general ventilation to maintain airborne concentrations to low levels.

Local ventilation may be required during certain operations. Use explosion-proof electrical equipment.

Hygiene measures: General information/ Hygiene measures: Smoking, consumption of food or liquid, and storage of tobacco, food or liquid, are not allowed in the workroom. Whenever you take a break in using this product and when you have finished using it always wash hands. Make sure that eyewash and emergency showers are clearly marked. Store and wash work clothing separately. Avoid contact with eyes and skin.


Eye protection: Safety glasses with side-shields conforming to EN166. Face shield if risk

assessment instructs. Tightly fitting safety goggles (EN166) should be used if splashes are likely to occur. Ensure that eyewash stations and safety showers are close to the workstation location.



65% CAS 2082-81-7:

Prolonged use (break through time 480 min) Minimum layer thickness: 0.7 mm Material: Viton Type: Viton 0890 (KCL) Short term use (break through time 240 min) Minimum layer thickness: 0.4 mm Material: Nitrile Type: Nitrile 0730, 0732, 0733 (KCL)


Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory


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practices. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion.

Respiratory protection: None required if hazards have been assessed and airborne concentrations are maintained below the exposure limits listed in section 8.1. Wear an approved air-purifying respirator with organic vapour cartridges and particulate filters where airborne concentrations may exceed exposure limits in section 8.1 and/or there is exposure to dust or mists due to sanding, grinding, cutting, or spraying. Use an approved positive-pressure air-supplied respirator with emergency escape provisions if there is any potential for an uncontrolled release, airborne concentrations are not known, or any other circumstances where air-purifying respirators may not provide adequate protection.

Recommended Filter type: Type A (EN141) and Type P3 (EN143)



9.1. Information on basic physical and chemical properties a) Appearance: yellow liquid b) Odour: pungent c) Odour threshold: not available d) pH: n/a e) Melting/freezing point: -23°C f) Initial boiling point/range: not available g) Flash point: >110°C (seta closed cup) h) Evaporation rate: not available i) Flammability (solid/gas): No information available j) Upper/lower flammability Upper: not available

or explosive limits: Lower: not available k) Vapour pressure: not available l) Vapour density: not available m) Relative density: 1.06 – 1.1 (23°C) n) Solubility (water): Insoluble (water) o) Partition coefficient

n-Octanol/Water (log Pow): No information available p) Auto-ignition temperature: not available q) Decomposition temperature: not available r) Viscosity: 150 - 250 mPas (23°C) Cone & Plate s) Explosive properties: not available t) Oxidising properties: not available

9.2. Other information No information available

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10.1. Reactivity Unstable upon depletion of inhibitor.

10.2. Chemical stability Stable under normal conditions. Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions Polymerisation can occur. Hazardous polymerization will occur if contaminated with peroxides, metal salts and polymerization catalysts. Hazardous polymerization may occur upon depletion of inhibitor - may cause heat and pressure build-up in closed containers. Product will undergo hazardous polymerization at temperatures above 65°C (150°F).

10.4. Conditions to avoid Heat, flames and sparks. Contamination by those materials referred to under section 10.5 incompatible materials. Unstable upon depletion of inhibitor. Elevated temperatures.

10.5. Incompatible materials Strong oxidising agents. Strong reducing agents.

10.6. Hazardous decomposition products Hydrocarbons. Carbon monoxide. Carbon dioxide (CO2). Thermal decomposition can lead to release of irritating and toxic gases and vapours.



Inhalation: No known hazard by inhalation. Eye contact: May cause slight irritation. Skin contact. May cause allergic skin reaction. Ingestion: Ingestion may cause gastrointestinal irritation, nausea,

vomiting and diarrhoea. 1,4-Butanediol Dimethacrylate: Oral LD50: (rat) 5 000 mg/kg Dermal LD50: (rabbit) 3 000 mg/kg

b) Skin corrosion/irritation: No information available. c) Serious eye damage/irritation: No information available. d) Respiratory or skin sensitisation: May cause an allergic skin reaction. e) Germ cell mutagenicity: No information available. f) Carcinogenicity: No information available. g) Reproductive toxicity: No information available. h) STOT-single exposure: Inhalation - May cause respiratory irritation. i) STOT-repeated exposure: No information available. j) Aspiration hazard: No information available. Target organ(s): Skin Numerical measures of toxicity - Product Information Unknown acute toxicity: 39.4 % of the mixture consists of ingredient(s) of unknown toxicity.

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The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 10 029 mg/kg ATEmix (dermal) 3 009 mg/kg


12.1. Toxicity Algae EC50: 23.6 mg/l (Phaeodactylum tricornutum) 72 h Fish LC50: >20.3 mg/l (Cyprinodon variegatus) 96 h Aquatic invertebrates LC50: 20.3 mg/l (Acartia tonsa) 48 h


12.3. Bioaccumulative potential Weighted average Log Pow for the substance is 3.92.

12.4. Mobility in soil No information available

12.5. Results of PBT and vPvB assessment No information available

12.6. Other adverse effects No information available


13.1. Waste treatment methods Waste from residues/unused products: This material and its container must be disposed of as hazardous waste. Dispose of contents/containers in accordance with local regulations. Can be incinerated, when in compliance with local regulations.

Contaminated packaging should be taken for local recycling, recovery or waste disposal. EWC code: 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES

07 02 00 Wastes from MFSU of plastics, synthetic rubber and man-made fibres 07 02 99 Wastes not otherwise specified


14.1. UN number

ADR/RID/IMDG/IMO/IATA: Not regulated

14.2. UN proper shipping name Not regulated


ADR/RID: - IMDG/IMO: - IATA: -

14.4. Packing group

ADR/RID Classification code: -

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Packing group/Labels: - Hazard id (Kemler no.): - Tunnel restriction code: -

IMDG/IMO Packing group/Labels: - EmS number: -

IATA Packaging: - Labels: -

14.5. Environmental hazards ADR/RID/IMDG/IMO/IATA: Environmental hazard: none IMDG/IMO: Marine pollutant: no

14.6. Special precautions for user see sections: 6, 7 and 8

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code No information available





Classification procedure: Skin sensitisation calculation method

Relevant H-statements referred to under sections 2 and 3 H317 - May cause an allergic skin reaction Changes

- New SDS



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Date: 04.11.14 Doc no: 364828 Rev.:2.2 29.12.2016

Trade name: Glass Beads / Glass Spheres Page 1 of 8




1.1. Product identifier Trade name: Glass Beads / Glass Spheres Chemical name: soda lime glass / glass oxide PR-no.: 2304746 (DK)

1.2. Relevant identified uses of the substance or mixture and uses advised against Filler/ weight material to adjust specific gravity of the UPR (Unsaturated Polymer Resin).






2.1. Classification of the substance or mixture This material is exempt from hazard classification according to Regulation (EC) No. 1272/2008, as amended, on classification, labelling, and packaging of substances and mixtures.


Not applicable

Signal word -

2.3. Other hazards None under normal conditions. No experimental study on the product is available. The information given is based on our knowledge of the components and the classification of the product is determined by calculation.


3.1. Substances


EC #

REACH #

Glass 65997-17-3 100

266-046-0

-





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4.1. Description of first aid measures General: If you feel unwell, seek medical advice (show the label where possible) Eye Contact: Rinse with eyewash solution or clean water, holding the eyelids apart, for at least 15

minutes. Remove contact lenses if easy to do. Obtain medical attention if pain, blinking or redness persists.

Skin Contact: Wash affected skin with plenty of soap and water. If symptoms occur obtain medical attention.

Ingestion: Rinse mouth. No significant signs or symptoms indicative of any adverse health hazard are expected to occur as a result of ingestion. Get medical advice/attention if you feel unwell.

Inhalation: Temporary discomfort to upper respiratory tract may occur due to inhalation of high dust levels. In case of accident by inhalation: remove casualty to fresh air and keep at rest. If symptoms develop, obtain medical attention.

4.2. Most important symptoms and effects, both acute and delayed Not expected to present a significant hazard under anticipated conditions of normal use. Dust may cause mechanical irritation.



5.1. Extinguishing media Non-combustible. Use a fire fighting agent suitable for surrounding fire. Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Extinguishing media which must not be used for safety reasons: Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture Fire hazard : Not determined. Not combustible. Explosion hazard : None under normal conditions. Reactivity in case of fire : Fume, mist. Hazardous decomposition products in case of fire : On burning: release of harmful/irritant

gases/vapours.

5.3. Advice for firefighters Special protective equipment for fire-fighters: Do not enter fire area without proper protective equipment, including respiratory protection. Do not approach fire except upwind and only with proper skin and respiratory protection (supplied air only).

Specific extinguishing methods Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment.

Further information Do not breathe fumes. Keep upwind. Avoid static electricity discharges.

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Dust formation: consult the information on the powder! Wear suitable protective clothing. Concerning personal protective equipment to use, see section 8. 6.1. Personal precautions, protective equipment and emergency procedures Avoid breathing dust. Protective equipment : Dust cloud production: dust-tight suit. Respiratory

protection. Emergency procedures : Evacuate unnecessary personnel. Measures in case of dust release : Knock down/dilute dust cloud with water spray

6.2. Environmental precautions Prevent product from entering drains.


For containment use dust binding agents. Collect all waste in suitable and labelled containers and dispose according to local legislation. Do not use compressed air for pumping over spills.

Clean up on land; sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials.


In storage and working areas, avoid spilling as this will make floors very slippery.

6.4. Reference to other sections For personal protection see section 8. See section 13 for disposal information.



Do not raise dust.

Do not breathe dust.

Use only in well ventilated areas.

Keep product in closed bag, away from humidity.

Take precautionary measures against static discharge.

Both local exhaust and good general room ventilation must be provided not only to control exposure but also to prevent formation of flammable mixtures.

Do not eat, drink or smoke when using this product.

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

Provide good ventilation in process area to prevent formation of vapour.

Handle in accordance with good industrial hygiene and safety procedures.

Handle at temperatures above +10C.

General Hygiene Considerations Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.


Use explosion-proof electrical, Ventilation, lighting. Use explosion-proof equipment.

Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.

Protect from moisture. Keep container closed when not in use.

Incompatible with strong bases, strong acids, oxidizing substances, oxidizing agents.

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Store for maximum 12 months.

Store at 25 (10 – 50) C

No flames, no sparks. Eliminate all sources of ignition. Protect from heat and direct sunlight.

Do not store together with food.

Store away from heat. Store in a well-ventilated place.

Keep only in original container. 7.3. Specific end use(s) For further information, consult for technical guidelines.



Components* CAS no. Control parameters*

Inhalable dust - TWA: 10 mg/m³ 8 hours

Respirable dust - TWA: 4 mg/m³ 8 hours *UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011). In the event that dust and/or fine particles are generated with this product, it is prudent to minimize prolonged inhalation exposure to these forms not to exceed the occupational exposure limit.


or liquid, and storage of tobacco, food or liquid, are not allowed in the workroom. Whenever you take a break in using this product and when you have finished using it, all exposed areas of the body must be washed. Always wash hands, forearms and face. Clothing that has been contaminated with the product must be removed immediately. Make sure that eyewash and emergency showers are clearly marked and are close to the workstation location. Store and wash work clothing separately.


Eye protection: Tightly fitting safety glasses conforming to EN166. Ensure that eyewash

stations and safety showers are close to the workstation location.

Skin protection: Impervious clothing that gives dust protection (with hood).

Hand protection: In case of repeated or prolonged contact wear gloves. Use protective gloves that are inspected before use. Gloves must comply with requirements in EN 388.

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Respiratory protection: Dust mask with filter type P3. Only use tested and approved equipment/component according to standards (CEN(EU)).

If heating the product wear self-contained breathing apparatus.

Environmental exposure controls Prevent spreading in sewers. Assure that emissions are compliant with all applicable air pollution control regulations. Refer to all applicable national, international and local regulations or provisions. Handle in accordance with good industrial hygiene and safety practice. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.


9.1. Information on basic physical and chemical properties a) Appearance: solid white powder b) Odour: odourless c) Odour threshold: not applicable d) pH: not applicable

e) Melting/freezing point: > +1 350 C f) Initial boiling point/range: not applicable

g) Flash point: not determined h) Evaporation rate: no data available i) Flammability (solid/gas): not determined j) Upper/lower flammability not determined

or explosive limits: not determined k) Vapour pressure: not applicable l) Vapour density: no data available m) Relative density: 0.1 -2.5 n) Solubility (water): not determined (soluble in hydrofluoric acid) o) Partition coefficient

n-Octanol/Water (log Pow): no data available p) Auto-ignition temperature: not determined q) Decomposition temperature: no data available r) Viscosity: no data available s) Explosive properties: not explosive t) Oxidising properties: no data available

9.2. Other information Critical temperature: 550 - 650 °C


10.1. Reactivity Stable under normal conditions

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10.2. Chemical stability Stable at room temperature and without humidity

10.3. Possibility of hazardous reactions None under normal conditions.

10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures.

10.5. Incompatible materials Strong acids. Strong bases.

10.6. Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide



Not classified, based on available data.



c) Serious eye damage/irritation:

Not classified, based on available data. Dust may cause mechanical irritation.

d) Respiratory or skin sensitisation:


e) Germ cell mutagenicity:


f) Carcinogenicity:


g) Reproductive toxicity:


h) STOT-single exposure:


i) STOT-repeated exposure:


j) Aspirasjonsfare: Not classified, based on available data. Further information: Dust may cause mechanical irritation. No experimental study on the product is available. The information given is based on our knowledge of the components and the classification of the product is determined by calculation.


12.1. Toxicity No experimental study on the product is available. The information given is based on our knowledge of the components and the classification of the product is determined by calculation. Not expected to present a significant hazard to air or water under anticipated conditions of normal use.

12.2. Persistence and degradability Not established.

12.3. Bioaccumulative potential Not established.

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12.4. Mobility in soil Not determined.

12.5. Results of PBT and vPvB assessment No additional information available

12.6. Other adverse effects This material has not been tested for environmental effects. Avoid release to the environment.


Waste treatment methods

Disposal must be done according to official regulations.

Collect all waste in suitable and labelled containers and dispose according to local legislation.

Do not discharge into drains or the environment.

Dispose of contents/container in a safe manner in accordance with local/national regulations.

Handle uncleaned empty containers as full ones. Empty containers should be taken for recycling, recovery or waste in accordance with local regulation.

Avoid release to the environment. Discharge together with other inert waste.


14.1. UN number ADN/ADR/RID/IMDG/IMO/IATA: not applicable

14.2. UN proper shipping name ADN/ADR/RID/IMDG: not applicable IATA: not applicable 14.3. Transport hazard class(es) ADN/ADR/RID/IMDG/IATA: not applicable 14.4. Packing group ADN/ADR Packing group: not applicable Classification Code: not applicable Labels: not applicable Tunnel restriction code: not applicable Limited quantity: not applicable RID Packing group: not applicable Classification Code: not applicable Hazard Identification Number: not applicable Labels: not applicable Limited quantity: not applicable IMDG-Code Packing group: not applicable Labels: not applicable

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EmS Code: not applicable IATA-DGR Packing instruction (cargo aircraft): not applicable Packing instruction (passenger aircraft): not applicable Packing group: not applicable Labels: not applicable

14.5. Environmental hazards ADN/ADR/RID (Environmentally hazardous): not applicable IMDG (Marine pollutant): not applicable





Glass is not on the REACH Annex XIV List (authorization list). Glass is not on the REACH Candidate List of Substances of Very High Concern for Authorisation (Article 59). Glass is not included on REACH Annex XVII restrictions list. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to take all precautions required in handling the product. The product is intended for professional use.

15.2. Chemical safety assessment No chemical safety assessment has been carried out. This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP].


Changes - General update of the document.



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Trade name: Heavy Weight Material / Micromax Page 1 of 9




1.1. Product identifier Trade name: Heavy Weight Material / Micromax Chemical name: Trimanganese tetroxide, Manganese tetraoxide, Mn3O4 PR-no.: 2417417 (DK)

1.2. Relevant identified uses of the substance or mixture and uses advised against Filler/ weight material to adjust specific gravity of the UPR (Unsaturated Polymer Resin).






2.1. Classification of the substance or mixture This material is exempt from hazard classification according to Regulation (EC) No. 1272/2008, as amended, on classification, labelling, and packaging of substances and mixtures.


Not applicable

Signal word -

2.3. Other hazards Long term inhalation (years) of dust from manganese oxides might cause adverse health effects. (See section 11). This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.


3.1. Substances


EC #

REACH #

Trimanganese tetroxide 1317-35-7 100

215-266-5

01-2119448167-35-0001




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4.1. Description of first aid measures General: If you feel unwell, seek medical advice (show the label where possible). Eye Contact: Rinse with eyewash solution or clean water, holding the eyelids apart. Remove

contact lenses if easy to do. Obtain medical attention if pain, blinking or redness persists.

Skin Contact: Wash affected skin with plenty of mild soap and water. If symptoms occur obtain medical attention.

Ingestion: Rinse mouth. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell.

Inhalation: Temporary discomfort to upper respiratory tract may occur due to inhalation of high dust levels. In case of accident by inhalation: remove casualty to fresh air and keep at rest. If symptoms develop, obtain medical attention. If not breathing, give artificial respiration.

4.2. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in section 11. Dust may cause mechanical irritation.



5.1. Extinguishing media Non-combustible. Use a fire fighting agent suitable for surrounding fire. Alcohol-resistant foam. Dry powder. Carbon dioxide. Water spray.

Extinguishing media which must not be used for safety reasons: Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture Manganese/manganese oxides Fire hazard : Not combustible. Explosion hazard : None; is formed under surplus of oxygen (O2). 5.3. Advice for firefighters Special protective equipment for fire-fighters: Do not enter fire area without proper protective equipment, including respiratory protection. Do not approach fire except upwind and only with proper skin and respiratory protection (supplied air only).

Specific extinguishing methods Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment.

Further information None

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Dust formation: consult the information on the powder! Wear suitable protective clothing. Concerning personal protective equipment to use, see section 8. 6.1. Personal precautions, protective equipment and emergency procedures Avoid dust formation. Avoid breathing dust, vapours, mist or gas.

6.2. Environmental precautions Prevent product from entering drains.


For containment use dust binding agents. Collect all waste in suitable and labelled containers and dispose according to local legislation.

Clean up on land; sweep or shovel into suitable closed containers. Minimize generation of dust.


6.4. Reference to other sections For personal protection see section 8. See section 13 for disposal information.



Do not raise dust.

Do not breathe dust.

Use only in well ventilated areas.

Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.

Provide good ventilation in process area to prevent formation of vapour.

Handle in accordance with good industrial hygiene and safety procedures.


Store in a dry, well ventilated place.

Protect from moisture. Keep container closed when not in use.

Keep away from hydrochloric acid (HCl).

Store at above 5C (do not freeze)




Components* CAS no. Control parameters*

Manganese and its inorganic compounds (as Mn)

- TWA: 0.5 mg/m³ 8 hours

Inhalable dust - TWA: 10 mg/m³ 8 hours

Respirable dust - TWA: 4 mg/m³ 8 hours

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*UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011). Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used.

In the event that dust and/or fine particles are generated with this product, it is prudent to minimize prolonged inhalation exposure to these forms not to exceed the occupational exposure limit.


or liquid, and storage of tobacco, food or liquid, are not allowed in the workroom. Whenever you take a break in using this product and when you have finished using it, all exposed areas of the body should be washed. Always wash hands, forearms and face. Make sure that eyewash and emergency showers are clearly marked and are close to the workstation location. Store and wash work clothing separately.


Eye protection: Tightly fitting safety glasses conforming to EN166. Ensure that eyewash

stations and safety showers are close to the workstation location.

Skin protection: Impervious clothing that gives dust protection (with hood) recommended.

Hand protection: Handle with gloves. Use protective gloves that are inspected before use. Gloves must comply with requirements in EN 388 and EN 374.

Full contact Minimum layer thickness: 0.11 mm Material: Nitrile Type: Nitrile 0740 (KCL)


Respiratory protection: Dust mask with filter type P3. Only use tested and approved equipment/component according to standards (CEN(EU)).

Environmental exposure controls Prevent spreading into drains. Assure that emissions are compliant with all applicable air pollution control regulations. Refer to all applicable national, international and local regulations or provisions.

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Handle in accordance with good industrial hygiene and safety practice. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Target value and limit value for PM10 and PM2.5 (Directive 2008/50/EC)

PM Averaging Period Limit Value/Target Value By Date

PM10 One Day LV: 50 µg/m3 * 01.01.2005

PM10 Calendar Year LV: 40 µg/m3 01.01.2005

PM2.5 Calendar Year TV: 25 µg/m3 01.01.2010

PM2.5 Calendar Year LV: 25 µg/m3 01.01.2015

* Not to be exceeded more than 35 times a calendar year


9.1. Information on basic physical and chemical properties a) Appearance: solid reddish brown powder b) Odour: odourless c) Odour threshold: not applicable d) pH: 7 - 10; 5g product in 50 ml distilled water

e) Melting/freezing point: 1 550 – 1 650 C f) Initial boiling point/range: not applicable

g) Flash point: not determined h) Evaporation rate: no data available i) Flammability (solid/gas): not determined j) Upper/lower flammability not determined

or explosive limits: not determined k) Vapour pressure: not applicable l) Vapour density: no data available m) Relative density: 4.8 (water=1) n) Solubility (water): Insoluble/slightly soluble in water/organic solvent o) Partition coefficient

n-Octanol/Water (log Pow): no data available p) Auto-ignition temperature: no data available q) Decomposition temperature: no data available r) Viscosity: no data available s) Explosive properties: no data available t) Oxidising properties: no data available


Powder with particle diameter 3-100 m, of which 90 % has a particle diameter < 5 m. Dust forms agglomerates.



10.2. Chemical stability Stable at recommended storage conditions and without humidity.


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Concentrated hydrochloric acid (HCl). Reacts violently with hydrogen peroxide (H2O2).

10.4. Conditions to avoid None. The substance is a stable manganese oxide.

10.5. Incompatible materials Concentrated hydrochloric acid (HCl). Strong oxidizing agents. Reacts violently with hydrogen peroxide (H2O2).

10.6. Hazardous decomposition products Concentrated hydrochloric acid reacts with the substance forming toxic chlorine gas (Cl2) under certain conditions.


The product does not meet the criteria for hazard classification according to Directive 67/548/EEC (DSD) and Regulation (EC) No1272/2008 (CLP). 11.1. Information on toxicological effects

a) Acute toxicity:

LD50 Oral Rat-female >2 000 mg/kg (fixed dose method)


Dust may cause mechanical irritation.

c) Serious eye damage/irritation:

Dust may cause mechanical irritation.

d) Respiratory or skin sensitisation:

Dust may cause mechanical irritation of mucous membranes. Inhalation of high concentrations of Mn vapour or Mn oxide fumes (See section 8) can result in chemical pneumonia.

e) Germ cell mutagenicity:

No data available.

f) Carcinogenicity:

No data available.

g) Reproductive toxicity:

Reproductive toxicity - Mouse - Oral Paternal Effects: Testes, epididymis, sperm duct. Paternal Effects: Prostate, seminal vessicle, Cowper's gland, accessory glands.

h) STOT-single exposure:

No data available.

i) STOT-repeated exposure:

No data available.

j) Aspirasjonsfare: No data available. Further information: Dust may cause mechanical irritation. RTECS: OP0895000 Men exposed to manganese dusts showed a decrease in fertility. Chronic manganese poisoning primarily involves the central nervous system. Early symptoms include languor, sleepiness and weakness in the legs. A stolid mask-like appearance of the face, emotional disturbances such as uncontrollable laughter and a spastic gait with tendency to fall in walking are findings in more advanced cases. High incidence of pneumonia has been found in workers exposed to the dust or fume of some manganese compounds.

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Chronic effects Manganese is an essential trace metal in all living organisms. Long-term inhalation (years) of Manganese oxides may cause chronic manganese intoxication (manganism) affecting the central nervous system (CNS), and lead to extensive disablement, that cannot be cured. Fumes/dust of MnO2 (tetravalent manganese (Mn[IV])) is classified as harmful to health. The substance contains divalent and trivalent manganese (Mn[II] and Mn[III]). Mn[IV] has not been detected in the product.


12.1. Toxicity No data available Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - > 1.6 mg/l -

48h

12.2. Persistence and degradability Not relevant for inorganic substances.

12.3. Bioaccumulative potential Not relevant.

12.4. Mobility in soil The product is not mobile under normal environmental conditions.


12.6. Other adverse effects No data available


Waste treatment methods

Disposal must be done according to official regulations.

Collect all waste in suitable and labelled containers and dispose according to local legislation.

Do not discharge into drains or the environment.

Dispose of contents/container in a safe manner in accordance with local/national regulations.

Handle uncleaned empty containers as full ones. Empty containers should be taken for recycling, recovery or waste in accordance with local regulation.

Avoid release to the environment.


14.1. UN number ADN/ADR/RID/IMDG/IMO/IATA: not applicable

14.2. UN proper shipping name ADN/ADR/RID/IMDG: not applicable IATA: not applicable 14.3. Transport hazard class(es) ADN/ADR/RID/IMDG/IATA: not applicable

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14.4. Packing group ADN/ADR Packing group: not applicable Classification Code: not applicable Labels: not applicable Tunnel restriction code: not applicable Limited quantity: not applicable RID Packing group: not applicable Classification Code: not applicable Hazard Identification Number: not applicable Labels: not applicable Limited quantity: not applicable IMDG-Code Packing group: not applicable Labels: not applicable EmS Code: not applicable IATA-DGR Packing instruction (cargo aircraft): not applicable Packing instruction (passenger aircraft): not applicable Packing group: not applicable Labels: not applicable

14.5. Environmental hazards ADN/ADR/RID (Environmentally hazardous): no IMDG (Marine pollutant): no





The substance is not on the REACH Annex XIV List (authorization list). The substance is not on the REACH Candidate List of Substances of Very High Concern for Authorisation (Article 59). The substance is not included on REACH Annex XVII restrictions list. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to take all precautions required in handling the product. The product is intended for professional use.

15.2. Chemical safety assessment

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A chemical safety assessment (CSA) has been carried out for the substance in accordance with Regulation (EC) 1907/2006 (REACH).


Changes - General update of the document.



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Trade name: ThermaSet® Cleaner v2 Page 1 of 8




1.1. Product identifier Trade name: ThermaSet® Cleaner v2

PR-no.: 2304770 (DK)

1.2. Relevant identified uses of the substance or mixture and uses advised against Detergent / cleaning fluid for UPR (Unsaturated Polymer Resin).






2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified


Signal word -



3.2. Mixture


EC #

REACH #

Reaction mass of dimethyl adipate and dimethyl glutarate and dimethyl succinate

>99 Not classified

906-170-0

01-2119475445-32-x

Methanol 67-56-1 <0.2 Flam. Liq. 2; H225 Acute Tox. 3; H301 200-659-6




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01-2119433307-44-X Acute Tox. 3; H311 Acute Tox. 3; H331 STOT SE 1; H370



4.1. Description of first aid measures General: In all case of doubt, or when symptoms persist, seek medical advice. Show this safety

data sheet to the doctor in attendance. Inhalation: Exposed to a large quantity can give inconvenience. Let the affected person rest in a

well ventilated room.

Skin Contact: Wash off with plenty of water and soap. Rinse afterwards with plenty of water. Eye Contact: Rinse immediately with plenty of water while lifting the eye lids. Remove contact

lenses if easy to do. Continue to rinse for at least 15 minutes. Contact physician if persistent irritation or other symptoms occur.

Ingestion: Never give anything by mouth to an unconscious person. Clean mouth with water. Seek medical advice/attention if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed No relevant information available.

4.3. Indication of any immediate medical attention and special treatment needed Symptomatic treatment.


5.1. Extinguishing media Adapt fire-extinguishing measures to surroundings.

Appropriate extinguishing media: Water spray, foam, CO2, dry powder. Extinguishing media which must not be used for safety reasons: Do not use full-force water jet in order to avoid dispersal and spread of the fire.

5.2. Special hazards arising from the substance or mixture Carbon monoxide.


PPE: Self-contained respirator / breathing apparatus (DIN EN 133).

Water used to extinguish fire should not enter drainage systems, soil or stretches of water.

Ensure there are sufficient retaining facilities for extinguishing water.


6.1. Personal precautions, protective equipment and emergency procedures Avoid breathing vapours, mist or gas.



Do not let product enter drains.


Discharge into the environment must be avoided.

6.3. Methods and material for containment and cleaning up Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,

sawdust).

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Keep in suitable, closed containers for disposal.

6.4. Reference to other sections See section 8 for personal protection. See section 13 for disposal.


7.1. Precautions for safe handling Use personal protective equipment listed in section 8.

7.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed at a dry and well-ventilated place.

Store in cool place.

7.3. Specific end use(s) Cleaning agent.


8.1. Control parameters Exposure Limits

TWA (time-weighted average), STEL (Short Term Exposure Limit)

Components CAS no. Control parameters

Methanol 67-56-1 TWA: 266 mg/m³ - 200 ppm 8 hours STEL: 333 mg/m³ - 250 ppm 15 min IOELV skin; 260 mg/m³ - 200 ppm Long term

*UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011), Directive 2006/15/EC - indicative occupational exposure limit values (IOELV) Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:




Workers Inhalation Long-term

8.3 mg/m3

Consumers Inhalation Long-term

5 mg/m3




Fresh water 0.018 mg/l


Fresh water sediment 0.16 mg/kg dwt

8.2. Exposure controls General: Handle in accordance with good industrial hygiene and safety practice.

Wash hands before breaks and at the end of workday.

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Personal Protective Equipment:

Eye protection: Safety glasses with side-shields conforming to EN166. Ensure that eyewash

station is close to the workstation location.

Skin protection: Working overall with long sleeves. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection: Respiratory protection not required. For nuisance exposures use type ABEK (EU EN 14387) respirator cartridges. Use respirators and components tested and approved under standards CEN (EU).


Prolonged use (break through time 480 min) Minimum layer thickness: 0.47 mm Material: Butyl II Type: Butyl II 0897 (KCL) Short term use (break through time 60 min) Minimum layer thickness: 0.4 mm Material: Nitrile Type: Nitrile 0730, 0732, 0733 (KCL)

Data source: KCL GmbH, e-mail [email protected]. This recommendation is advisory only and must be evaluated by responsible chemist familiar with the specific situation of anticipated use. It should not be construed as offering an approval for any specific use scenario.




9.1. Information on basic physical and chemical properties a) Appearance: clear fluid b) Odour: type specific c) Odour threshold: not applicable


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d) pH: not determined e) Melting/freezing point: not determined f) Initial boiling point/range: not determined

g) Flash point: > 100C h) Evaporation rate: not determined i) Flammability (solid/gas): not determined j) Upper/lower flammability not determined

or explosive limits: not determined k) Vapour pressure: not determined l) Vapour density: not determined m) Relative density: 1.09 g/cm3 (20°C) n) Solubility (water): slightly soluble in water o) Partition coefficient

n-Octanol/Water (log Pow): not determined p) Auto-ignition temperature: not applicable q) Decomposition temperature: not determined r) Viscosity: not determined s) Explosive properties: not explosive t) Oxidising properties: not determined

9.2. Other information No further relevant information available.


10.1. Reactivity Stable under recommended storage and handling conditions.

10.2. Chemical stability Stable under recommended storage and handling conditions.


10.4. Conditions to avoid No further relevant information available.

10.5. Incompatible materials No further relevant information available.

10.6. Hazardous decomposition products Carbon monoxide


11.1. Information on toxicological effects Acute toxicity: Based on available data, the classification criteria are not met. a) Acute toxicity: Oral LD50: (rat) >5 000 mg/kg Dermal LD50: (rat) >2 000 mg/kg Inhalation LC50: (rat) 11 mg/l 4 h

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b) Skin corrosion/irritation: Based on available data, classification criteria not met

c) Serious eye damage/irritation: Based on available data, classification criteria not met

d) Respiratory or skin sensitisation: Based on available data, classification criteria not met

e) Germ cell mutagenicity: Based on available data, classification criteria not met

f) Carcinogenicity: Based on available data, classification criteria not met

g) Reproductive toxicity: Based on available data, classification criteria not met

h) STOT-single exposure: Based on available data, classification criteria not met

i) STOT-repeated exposure: Based on available data, classification criteria not met

j) Aspiration hazard: Based on available data, classification criteria not met

Ingestion of large amounts may cause gastrointestinal disturbances.


12.1. Toxicity

Fish LC50: 18 - 24 mg/l (fish):) (96 h) Aquatic invertebrates EC50: 112 - 150 mg/l (Daphnia magna) (48 h)

12.2. Persistence and degradability Easily biodegradable.

12.3. Bioaccumulative potential No further relevant information available.

12.4. Mobility in soil Slightly water soluble. No further relevant information available.


12.6. Other adverse effects Water hazard class (D) (Self-assessment): Slightly hazardous for water. Do not allow product to reach ground water, water course or sewage system.


13.1. Waste treatment methods Must not be disposed together with household garbage. Do not allow product to reach sewage system.

Unclean packaging should be rinsed before handing over to local recycling facilities. EWC code: suggestion: 07 06 01 - aqueous washing liquids and mother liquors

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14.1. UN number ADR/ADN/IMDG/IATA: Not classified

14.2. UN proper shipping name ADR/ADN/IMDG/IATA: Not classified

14.3. Transport hazard class(es) ADR/ADN/IMDG/IATA: Not classified

14.4. Packing group ADR/ADN/IMDG/IATA: Not classified

14.5. Environmental hazards ADR/ADN/IMDG/IATA: Not classified IMDG/IMO: Marine pollutant: no

14.6. Special precautions for user Avoid contact with eyes and skin. See sections: 6, 7 and 8




The substance is not on the REACH Annex XIV List (authorization list). The substance is not on the REACH Candidate List of Substances of Very High Concern for Authorisation (Article 59). The substance is not included on REACH Annex XVII restrictions list.

15.2. Chemical safety assessment For this product a chemical safety assessment was not carried out.


Methanol: H225 Highly Flammable liquid and vapour. H301 Toxic if swallowed. H311 Toxic in contact with skin H331 Toxic if inhaled. H370 Causes damage to organs. Changes


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Trade name: ThermaSet® Page 1 of 9




1.1. Product identifier Trade name: ThermaSet®

SAP ID(s): 195593, 195594, 197094 Chemical family: Polyester Resin PR-no.: 2304826 (DK)

1.2. Relevant identified uses of the substance or mixture and uses advised against Restore & maintain integrity of oil & gas wells






2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Liq. 3 H226 Asp. Tox. 1 H304 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Acute Tox. 4 H332


Signal word Danger Contains: Vinyl Toluene

Hazard Statements H226 Flammable liquid and vapour H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H319 Causes serious eye irritation H332 Harmful if inhaled




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50% of the mixture consists of ingredient(s) of unknown toxicity. 100% of the mixture consists of components(s) of unknown hazards to the aquatic environment. Precautionary Statements PREVENTION P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking P260 Do not breathe mist/vapours/spray P280 Wear protective gloves/protective clothing/eye protection/face protection

RESPONSE P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician P331 Do NOT induce vomiting P302 + P352 IF ON SKIN: wash with plenty of soap and water P304 + P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for

breathing P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction

2.3. Other hazards see sections 7 and 8


3.2. Mixtures Liquid unsaturated polymer resin

Component CAS # EC # % by weight EC CLP Classification REACH #

Vinyl toluene

25013-15-4 246-562-2 48 - 52 Flam. Liq. 3 (H226) Skin Irrit. 2 (H315) Acute Tox. 4 (H332) Eye Irrit. 2 (H319) Asp.Tox. 1 (H304)

01-21196222074-50



4.1. Description of first aid measures Eye Contact: Immediately flush eyes for at least 15 minutes. Get medical attention. Skin Contact: Wash off with warm water and soap. Remove contaminated clothing and shoes.

If skin irritation persists, call a doctor. Wash contaminated clothing before re-use. Ingestion: Do NOT induce vomiting. Aspiration Hazard. Never give anything by mouth

to an unconscious person. Get immediate medical advice/attention. Inhalation: In case of unconsciousness bring patient into stable side position for transport.

Remove to fresh air. Keep patient warm and at rest. If breathing is laboured, administer oxygen. If not breathing, give artificial respiration. Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed Irritating to eyes, respiratory system and skin. Harmful by inhalation, in contact with skin and if swallowed.


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Notes to Physician: Treat symptomatically.



Extinguishing media which must not be used for safety reasons: Do not use a solid water stream as it may scatter and spread fire 5.2. Special hazards arising from the substance or mixture Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases flammable. Vapours may form explosive mixture with air. Vapours may travel to areas away from work site before igniting/flashing back to vapour source. Combustion may produce carbon monoxide, carbon dioxide, irritating or toxic vapours and gases. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

5.3. Advice for firefighters Special protective equipment for fire-fighters: Wear self-contained breathing apparatus and protective suit.


6.1. Personal precautions, protective equipment and emergency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Avoid contact with skin and eyes. Use personal protective equipment as required. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. All equipment used when handling the product must be grounded.

6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not allow material to contaminate ground water system. Prevent product from entering drains.

6.3. Methods and material for containment and cleaning up A vapour suppressing foam may be used to reduce vapours. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use clean non-sparking tools to collect absorbed material.

6.4. Reference to other sections See section 12 for more information


7.1. Precautions for safe handling Do not breathe vapour or mist. Avoid contact with eyes, skin and clothing. Take off contaminated clothing and wash before re-use. Ensure adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion-proof equipment. Consult your supplier of promoters and catalysts for additional instructions on proper mixing and usage. Empty containers may retain product residue (liquid and/or vapour). Do not pressurize, cut, weld, braze, solder, drill,

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grind, or expose these containers to heat, flame, sparks, static electricity, or other sources of ignition as the container may explode and may cause injury or death. Empty drums should be completely drained and properly bunged. Empty drums should be promptly returned to a drum reconditioner or properly disposed. Do not use compressed air for filling, discharging or handling.

General Hygiene Considerations: Wash hands before eating, drinking or smoking.

7.2. Conditions for safe storage, including any incompatibilities Keep away from heat and sources of ignition. No smoking. Protect from direct sunlight. Store away from incompatible materials. Keep containers tightly closed in a cool, well-ventilated place. To ensure maximum stability and maintain optimum resin properties, resins should be stored in closed containers at temperatures below 25°C.



8.1. Control parameters Exposure Limits Vinyl toluene not listed in the UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011)

Component CAS no. Workplace Control Parameters Country

Vinyl toluene 25013-15-4 TWA: 50 ppm (240 mg/m³) STEL: 75 ppm (300 mg/m³)

Norway

TWA: 100 ppm (480 mg/ m³) NIOSH REL/OSHA PEL

USA

25 ppm (120 mg/m³) Denmark

TWA: 50 (mg/m³ vapour) STEL: 150 (mg/m³ vapour)

Russia

TWA (time-weighted average), STEL (Short Term Exposure Limit) Biological occupational exposure limits

8.2. Exposure controls Engineering controls: Use general ventilation to maintain airborne concentrations to levels that

are below regulatory and recommended occupational exposure limits. Local ventilation may be required during certain operations.

Hygiene measures: General information/ Hygiene measures: Smoking, consumption of food or liquid, and storage of tobacco, food or liquid, are not allowed in the workroom. Whenever you take a break in using this product and when you have finished using it, all exposed areas of the body must be washed. Always wash hands, forearms and face. Make sure that eyewash and emergency showers are clearly marked. Store and wash work clothing separately. Avoid contact with eyes and skin.


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Eye protection: Safety glasses with side-shields conforming to EN166. Tightly fitting safety goggles (EN166) should be used if splashes are likely to occur. Ensure that eyewash stations and safety showers are close to the workstation location.



Prolonged use (break through time 480 min) Minimum layer thickness: 0.7 mm Material: Viton Type: Viton 0890 (KCL) Short term use (break through time 51 min) Minimum layer thickness: 0.4 mm Material: Nitrile Type: Nitrile 0730, 0732, 0733 (KCL)



Respiratory protection: None required if hazards have been assessed and airborne concentrations are maintained below the exposure limits listed in section 8.1 . Wear an approved air-purifying respirator with organic vapour cartridges and particulate filters where airborne concentrations may exceed exposure limits in section 8.1 and/or there is exposure to dust or mists due to sanding, grinding, cutting, or spraying. Use an approved positive-pressure air-supplied respirator with emergency escape provisions if there is any potential for an uncontrolled release, airborne concentrations are not known, or any other circumstances where air-purifying respirators may not provide adequate protection.

Recommended Filter type: Type A (EN141)



9.1. Information on basic physical and chemical properties a) Appearance: yellow liquid b) Odour: aromatic c) Odour threshold: 240 mg/m3 (vinyl toluene)


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d) pH: n/a e) Melting/freezing point: -77°C (vinyl toluene) f) Initial boiling point/range: 168°C (vinyl toluene) g) Flash point: 53°C ISO 1523 h) Evaporation rate: < 1.0 (BuAc=1) (vinyl toluene) i) Flammability (solid/gas): No information available j) Upper/lower flammability Upper: 6.1% (vinyl toluene)

or explosive limits: Lower: 1.9% (vinyl toluene) k) Vapour pressure: 2 hPa (20°C) (vinyl toluene) l) Vapour density: 4.08 (Air=1) (vinyl toluene) m) Relative density: 1.017 ±0.003 (23°C) n) Solubility (water): Insoluble (water) o) Partition coefficient

n-Octanol/Water (log Pow): No information available(vinyl toluene) p) Auto-ignition temperature: 489 - 515°C (vinyl toluene) q) Decomposition temperature: not classified r) Viscosity: 20 - 40 mPas (23°C) Cone & Plate s) Explosive properties: not classified t) Oxidising properties: not classified

9.2. Other information No information available


10.1. Reactivity Unstable upon depletion of inhibitor.

10.2. Chemical stability Stable under normal conditions. Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions Polymerisation can occur. Hazardous polymerization will occur if contaminated with peroxides, metal salts and polymerization catalysts. Hazardous polymerization may occur upon depletion of inhibitor - may cause heat and pressure build-up in closed containers. Product will undergo hazardous polymerization at temperatures above 65°C (150°F).

10.4. Conditions to avoid Heat, flames and sparks. Contamination by those materials referred to under section 10.5 incompatible materials. Unstable upon depletion of inhibitor. Elevated temperatures.

10.5. Incompatible materials Strong acids. Strong oxidising agents. Metal salts. Polymerization initiators. Copper. Copper alloys. Brass.

10.6. Hazardous decomposition products Hydrocarbons. Carbon monoxide. Carbon dioxide (CO2). Thermal decomposition can lead to release of irritating and toxic gases and vapours.



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a) Acute toxicity: Inhalation: Harmful by inhalation. May cause irritation of

respiratory tract. Inhalation of high vapour concentrations can cause CNS depression and narcosis.

Eye contact: Irritating to eyes. Skin contact. Causes skin irritation. Prolonged skin contact may defat

the skin and produce dermatitis. Ingestion: HARMFUL IF SWALLOWED. Ingestion may cause

gastrointestinal irritation, nausea, vomiting and diarrhoea. May be fatal if swallowed and enters airways.

Vinyl toluene (ECHA): Oral LD50: (rat) 3.68 ml/kg Dermal LD50: (rabbit) >5 ml/kg Inhalation LC50: (rat – 4 h) 16.891 mg/l

b) Skin corrosion/irritation: Irritating skin c) Serious eye damage/irritation: Irritating eyes d) Respiratory or skin sensitisation: Not sensitizing e) Germ cell mutagenicity: No data available f) Carcinogenicity: No data available g) Reproductive toxicity: No data available h) STOT-single exposure: No data available i) STOT-repeated exposure: Repeated or prolonged exposure may cause skin

irritation and dermatitis, due to defatting properties of the product. May cause damage to the liver, eyes, brain, respiratory system, central nervous system through prolonged or repeated exposure if inhaled.

j) Aspiration hazard: Harmful by inhalation. Target organ(s): Kidney, Liver, Central Nervous System (CNS), Respiratory system Numerical measures of toxicity - Product Information Unknown acute toxicity: 50% of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (inhalation-vapour) 11 mg/l


12.1. Toxicity Vinyl Toluene

Algae EC50: 2.6 mg/l (Selenastrum Capricornutum) 72 h Fish LC50: 23.4 mg/l (Pimephales rafinesque) 96 h Aquatic invertebrates EC50: 1.3 mg/l (Daphnia magna) 48 h


12.3. Bioaccumulative potential Bioaccumulation is unlikely

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Vinyl Toluene log Kow 3.36 Bioconcentration factor (BCF) 32 - 35 goldfish 12.4. Mobility in soil No information available 12.5. Results of PBT and vPvB assessment No information available 12.6. Other adverse effects No information available


13.1. Waste treatment methods Waste from residues/unused products: This material and its container must be disposed of as hazardous waste. Dispose of contents/containers in accordance with local regulations. Can be incinerated, when in compliance with local regulations.

Contaminated packaging should be taken for local recycling, recovery or waste disposal. EWC code: 07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES

07 02 00 Wastes from MFSU of plastics, synthetic rubber and man-made fibres 07 02 99 Wastes not otherwise specified


14.1. UN number

ADR/RID/IMDG/IMO/IATA: UN1866

14.2. UN proper shipping name RESIN SOLUTION Flammable (Vinyl toluene)


ADR/RID: 3 IMDG/IMO: CLASS 3 IATA: 3

14.4. Packing group

ADR/RID Classification code: F1 Packing group/Labels: III Hazard id (Kemler no.): 30 Tunnel restriction code: D/E

IMDG/IMO Packing group/Labels: PG III EmS number: F-E,S-E

IATA Packaging: 355; 366 Labels: III


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ADR/RID/IMDG/IMO/IATA: Environmental hazard: none IMDG/IMO: Marine pollutant: no







Classification procedure: Acute toxicity - Inhalation (Vapours) calculation method Skin corrosion/irritation calculation method Serious eye damage/eye irritation calculation method Flammable liquid on basis of test data

Relevant H-statements referred to under sections 2 and 3 H226 - Flammable liquid and vapour H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H332 - Harmful if inhaled Changes

- Amended according to Commission Regulation (EU) 2015/830.



SAFETY DATA SHEET

Date: 04.11.14 Doc no: 364836 Rev.:2.2 16.12.2016

Trade name: Viscosifier / Orisil 200 / Aerosil 200 Page 1 of 6




1.1. Product identifier Trade name: Viscosifier / Orisil 200 / Aerosil 200Chemical name: Silicon dioxide, Hydrophilic amorphous fumed silica PR-no.: 2304797 (DK)

1.2. Relevant identified uses of the substance or mixture and uses advised against Viscosifier to keep weight material suspended in UPR (Unsaturated Polymer Resin)






2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified


Signal word -



3.1. Substance

Chemical name CAS # Concentration %

CLP classification

EC #

REACH #

Silicon dioxide 7631-86-9, 112945-52-5

100 Not classified

231-545-4

01-2119379499-16-0109





SAFETY DATA SHEET

Date: 04.11.14 Doc no: 364836 Rev.:2.2 16.12.2016



4.1. Description of first aid measures General: In all case of doubt, or when symptoms persist, seek medical advice. Eye Contact: Possible discomfort is due to foreign substance effect. Rinse thoroughly with plenty

of water keeping eyelid open. Obtain medical advice if any pain or redness persists. Skin Contact: Wash off with plenty of water and soap. Ingestion: Clean mouth with water and drink afterwards plenty of water. After absorbing large

amounts of substance and in case of discomfort seek medical attention. Inhalation: Exposed to a large quantity can give inconvenience. Let the affected person rest in a

well ventilated room.

4.2. Most important symptoms and effects, both acute and delayed No known symptoms or dangers.

4.3. Indication of any immediate medical attention and special treatment needed First aid, decontamination, treatment of symptoms.


5.1. Extinguishing media Water spray, foam, CO2, dry powder. Adapt fire-extinguishing measures to surroundings.

Extinguishing media which must not be used for safety reasons: Do not use full-force water jet in order to avoid dispersal and spread of the fire.

5.2. Special hazards arising from the substance or mixture The product is stable if stored and handled as prescribed /indicated.

5.3. Advice for firefighters Self-contained respirator / breathing apparatus (DIN EN 133). Water used to extinguish fire should not enter drainage systems, soil or stretches of water. Ensure there are sufficient retaining facilities for water used to extinguish fire


6.1. Personal precautions, protective equipment and emergency procedures Avoid generation and breathing of dust. Avoid contact with skin and eyes. If the formation of dust is beyond the occupational exposure limit values, approved and suitable respiratory protection and safety goggles must be used. Danger of slippery surfaces combined with water.

6.2. Environmental precautions This product is not classified as dangerous to the environment, but avoid spillage to ground or to water systems.

6.3. Methods and material for containment and cleaning up Sweep up or vacuum up spillage and collect in suitable container for disposal.

6.4. Reference to other sections See section 7 for handling and storage. See section 8 for personal protection. See section 13 for disposal.



SAFETY DATA SHEET

Date: 04.11.14 Doc no: 364836 Rev.:2.2 16.12.2016


Keep container tightly closed and at a well ventilated place. Carry out filling operations only at stations with exhaust ventilation facilities. Prevent formation of dust. Use personal protection equipment if the concentration of dust increases beyond the exposure limit values.

7.2. Conditions for safe storage, including any incompatibilities Keep container tightly closed at a well-ventilated place. Take precautionary measures against static discharges. Keep in a dry place.

7.3. Specific end use(s) Use only as specified by producer, see section 1.2.


8.1. Control parameters Exposure Limits

Component CAS no. Workplace Control Parameters Country

Silicon dioxide, Silica, amorphous

112945-52-5, 7631-86-9

TWA: 6 mg/m³ - inhalable dust TWA: 2.4 mg/m³ - respirable dust

UK*

TWA (time-weighted average), STEL (Short Term Exposure Limit) *UK Health and Safety Executive (HSE), EH40 Workplace exposure limits (second edition, published 2011)

8.2. Exposure controls General: Avoid dust formation. Ensure good ventilation. Protect respiratory tracts,

eyes and hands at high concentration of dust or at prolonged exposure. Do not eat, drink or smoke during work. Wash face and/or hands before break and end of work. To ensure ideal skin protection: use super fatted soaps and skin cream for skin care. Wash contaminated clothing before re-use.

Eye protection: Safety glasses with side-shields conforming to EN166. If dust occurs use

basket-shaped glasses. Ensure that eyewash station is close to the workstation location.

Skin protection: Working overall with long sleeves.

Hand protection: Wear protective gloves made of the following materials: material, rubber, leather. The material thickness and rupture time data do not apply to non -solute solids / dusts.

Respiratory protection: Approved and suitable respiratory protective mask must be used if the concentration exceeds the exposure limit values, according to EN 149: use filter FFP2 or FFP3.


SAFETY DATA SHEET

Date: 04.11.14 Doc no: 364836 Rev.:2.2 16.12.2016



9.1. Information on basic physical and chemical properties a) Appearance: Solid white powder b) Odour: odourless c) Odour threshold: not applicable

d) pH: 3.5 – 5.5 (100g/l at 20C) e) Melting/freezing point: ca. 1 700°C f) Initial boiling point/range: ca. 2 230°C g) Flash point: not applicable h) Evaporation rate: not applicable i) Flammability (solid/gas): not applicable j) Upper/lower flammability not applicable

or explosive limits: not applicable k) Vapour pressure: not applicable l) Vapour density: not applicable m) Relative density: 2.2 g/cm3 (20°C) n) Solubility (water): > 1 mg/l o) Partition coefficient

n-Octanol/Water (log Pow): not applicable p) Auto-ignition temperature: not applicable

q) Decomposition temperature: > 2 000C r) Viscosity: not relevant, solid s) Explosive properties: not explosive t) Oxidising properties: not oxidizing

9.2. Other information Tapped density: ca 50 g/l Method: DIN/ISO 787/11


10.1. Reactivity The product is stable if stored and handled as advised.


10.3. Possibility of hazardous reactions No hazardous reactions are known if properly handled and stored.

10.4. Conditions to avoid No dangerous reaction known under conditions of normal use.

10.5. Incompatible materials No further relevant information available.

10.6. Hazardous decomposition products None known. Stable under normal conditions. Product will not undergo hazardous polymerization.



SAFETY DATA SHEET

Date: 04.11.14 Doc no: 364836 Rev.:2.2 16.12.2016


a) Acute toxicity: Oral LD50: (rat) >3 300 mg/kg no deaths occured Dermal LD50: (rabbit) 5 000 mg/kg comparable product Inhalation LC0: (rat) 0,139 mg/l 4 t no deaths occurred

b) Skin corrosion/irritation: Not irritating (rabbit) c) Serious eye damage/irritation: Not irritating (rabbit) d) Respiratory or skin sensitisation: Not known e) Germ cell mutagenicity: No evidence of mutagenic effects f) Carcinogenicity: No evidence that cancer may be caused. g) Reproductive toxicity: No evidence of reproduction toxic properties h) STOT-single exposure: Not classified i) STOT-repeated exposure: Not classified j) Aspiration hazard: Not classified


12.1. Toxicity No ecotoxicological data is available for this product.

Fish LC50: > 10 000 mg/l (Brachydanio rerio):) (96 h) Aquatic invertebrates EC50: > 1 000 mg/l (Daphnia magna) (24 h)

12.2. Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.

12.3. Bioaccumulative potential Not to be expected.

12.4. Mobility in soil No remarkable mobility in soil is to be expected.

12.5. Results of PBT and vPvB assessment Not a PBT, vPvB substance as per the criteria of the REACH Regulation.

12.6. Other adverse effects Not classified.


13.1. Waste treatment methods Can be disposed of with domestic refuse in accordance with the necessary technical regulations following consultation with waste disposal expert(s) and the responsible authorities.

Unclean packaging should be rinsed before handing over to local recycling facilities. EWC code: No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer. The waste key number must be determined as per the European Waste Types List (decision on EU WasteTypes List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.


SAFETY DATA SHEET

Date: 04.11.14 Doc no: 364836 Rev.:2.2 16.12.2016


14.1. UN number ADR/RID/IMDG/IMO/IATA: Not classified

14.2. UN proper shipping name Not classified

14.3. Transport hazard class(es) ADR/RID/IMDG/IMO/IATA: Not classified

14.4. Packing group ADR/RID/IMDG/IMO/IATA: Not classified

14.5. Environmental hazards ADR/RID/IMDG/IMO/IATA: Not classified IMDG/IMO: Marine pollutant: no





15.2. Chemical safety assessment No exposure or risk assessment is required for this product since it is not classified for health or environmental risks.


Changes

- Amended according to Commission Regulation (EU) 2015/830.



1 | P a g e SDS – BiSN-93 Rev 0

BiSN

Safety Data Sheet – BiSN 93

1 Product & Company Information Product Name: BiSN 93

Synonyms: N/A

SDS Number: SDS – BiSN-93 Rev 0 (Revision Date: 02/06/2018)

Product Use: Formation of plugs in oil and gas wells

Manufacturer: BiSN 4539 Brittmoore Rd, Houston, TX 77041

Contact information: (832) 919-7500 (Day Only)

2 Hazard(s) Identification Classification of the mixture:

Irritant – Acute toxicity (oral, dermal, inhalation), Category 4 Health hazard – Reproductive toxicity, category 1A Specific target organ toxicity following repeated exposure, category 2 Environmentally Damaging – Acute hazards to the aquatic environment, category 1 Chronic hazards to the aquatic environment, category 1

Hazard Statement(s)

Harmful if swallowed

Causes skin irritation

May cause an allergic skin reaction

May cause respiratory irritation

Harmful if inhaled

May damage fertility or the unborn child

May cause damage to organs through prolonged or repeated exposure

Very toxic to aquatic life

Very toxic to aquatic life with long lasting effects

Precautionary Statement(s)

Avoid breathing dust/fume/gas/mist/vapours/spray

Do not eat, drink or smoke when using this product

Importer Name: Chevron Australia Pty Ltd Address: 250 St Georges Terrace, Perth, WA, 6000, Australia Telephone: 08 9216 4000Fax: 08 9216 4444



Avoid release to the environment

Wear protective gloves/protective clothing/eye protection/face protection

Take off contaminated clothing and wash before reuse

Use only outdoors or in a well-ventilated area


IF Swallowed get medical attention/advice if you do not feel well

IF ON SKIN: Wash with plenty of soap and water

IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing

IF IN EYES: Rinse continuously with water for several minutes (15 Minutes.)

IF EXPOSED or CONCERNED get medical attention/advice

Potential Health Effects:

Eye Contact: Contact with dust from alloy or fumes may cause irritation. Severe eye damage may result from hot molten metal being splashed into the eyes. Wear safety glasses and face shield when working with molten metal. Dusts are irritating to eyes.

Ingestion: May be harmful. Ingestion of alloy in any form may cause headache, nausea, abdominal pain, fatigue and pain in the legs, arms and joints.

Inhalation: Inhalation of fume or dust may cause local irritation to the respiratory system. Inhalation of fume or dust may cause headache, nausea, abdominal pain, fatigue and pain in the legs, arms and joints. Inhalation of fumes can cause metal fume fever.

Skin Contact: Normal handling should not cause any adverse health effects. May cause skin irritation. Hot molten metal may cause burns to the skin. Wear protective equipment when handling molten metal.

Chronic: BISMUTH: May cause kidney damage.

3 Composition/Information on Ingredients

Components CAS Registry # %wt

Bismuth 7440-69-9 N/A*

Tin 7440-31-5 N/A*

Lead 7439-92-1 N/A*

*Percentage of composition has been withheld as a trade secret.


4 First Aid Measures Eye Contact: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Seek medical

attention if irritation persists.

Ingestion: If patient is conscious, ONLY induce vomiting as directed by trained personnel. NEVER give anything by mouth to an unconscious person. Seek medical attention immediately.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration or oxygen by trained personnel. Seek immediate medical attention.

Skin Contact: Remove to fresh air. Rinse/flush exposed skin gently using soap and water for 15-20 minutes. Seek medical advice if discomfort or irritations persists.

Most important symptoms and effects, both acute and delayed:

Irritation, Nausea, Headache, Shortness of breath.

5 Fire Fighting Measures Flash Point: Not Established

Method: Not Established

Auto Ignition Temperature:

Not Established

Flammable Limits:

Limits are not established. Massive metal is not flammable; however, dust or powder may be flammable.

Extinguishing Media:

Use extinguishers appropriate for the surrounding fire conditions. Do not add water to molten metal.

Special Fire Fighting:

Firefighters must wear NIOSH approved self-contained breathing apparatus and full protective clothing.

Special Hazards:

Lead oxides. Combustion products may include carbon oxides or other toxic vapours. Thermal decomposition can lead to release of irritating gases and vapours.

6 Accidental Release Measures Spill or Leak Procedures:

Contain spill if molten, cool to allow metal to solidify.

If a solid metal, wear gloves, pick up and return to process.

If dust, wear recommended personal protective equipment including respiratory protection.


DO NOT SWEEP. Use a vacuum, place in barrels and return to process if applicable. Use proper ventilation. Otherwise, dispose of following all Federal, State and Local regulations.

Environmental Precautions:

Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization. Should not be released into environment.

7 Handling and Storage Handling: Use protective gloves when handling as solid at ambient temperature.

If working with molten metals, or exposed to fume or dust, use appropriate personal protective equipment.

Storage Precautions:

Store product in a cool, dry area away from incompatible materials.

8 Exposure Controls/Personal Protection

Engineering Controls

Exhaust ventilation is recommended to control any air contaminants. Control concentration of all components so that their exposure levels are not exceeded. Use ventilation for example especially during heating, grinding, cutting, sanding, melting and any other types of work where exposure is possible.

Personal Protection

Eyes: Chemical safety glasses/goggles and face shield with molten metal. Safety glasses.

Respirator: An authority approved or compliant marked air-purifying respirator with a fume/dust chemical cartridge is recommended under certain circumstances where airborne concentrations are expected to be elevated. Additional respiratory protection may be required based on the work performed and the area in which the work is performed.

Skin: Gloves-leather or impervious (vinyl) type. Heat resistant gloves if handling hot metal. Safety type boots. Personal protective equipment is recommended when working with molten metal to avoid burns.

Other: Lab coat, safety shower and eye-wash fountain in work area. Avoid the use of contact lenses in high fume areas. Follow OSHA guidelines for lead and cadmium workers.

Work/Hygienic:

Maintain good housekeeping. Clean up spills immediately. Good personal hygiene is essential. Avoid eating, smoking or drinking in the work area. Wash hands thoroughly with soap and water immediately upon leaving the work area.


9 Physical and Chemical Properties Appearance: Silver-grey solid metal Boiling Point: Not applicable

Odor: Odorless Melting Point: 93 oC (199.4 F)

Specific Gravity: N/A pH: Not applicable

Vapor Pressure: Not applicable Solubility in Water: Insoluble

Vapor Density: (air=1) Not applicable Flash Point: Not applicable

10 Stability and Reactivity General: Stable

Conditions to Avoid:

Not established

Incompatible Materials:

Avoid contact with mineral acids

Hazardous Decomposition /Combustion:

Harmful organic fumes and toxic oxide fumes may form at elevated temperatures.

Hazardous Polymerization:

Will not occur.

Carcinogenicity: IARC: 2B: Possibly carcinogenic to humans (Lead); NTP: Reasonably anticipated to be a human carcinogen (Lead)

Reproductive Toxicity:

Reproductive toxicity – rat – Inhalation Effects on Newborn: Biochemical and metabolic. Reproductive toxicity – rat – Oral Effects on Newborn: Behavioral.

11 Toxicological Information Tin - LD50 oral - rat > 700mg/kg

Bismuth - LD50 oral - rat > 5,000mg/kg

Lead – LD50-not available

12 Ecological Information An environmental hazard cannot be excluded in the event of handling or disposing of metal mixtures in an inappropriate manner. Recycle when possible.

Ecotoxicity – LC50- Micropterus dolomieui: 2.2 mg/l – 96.0 h


EC50- Skeletonema costatum: 7.94 mg/l – 10 d

13 Disposal Considerations Waste Disposal Method: Scrap metal alloy usually has value. Contact us about recycling. Otherwise, dispose of in accordance with all Federal, State and Local environmental regulations.

14 Transport Information Transport in accordance with applicable regulations and requirements.

Not regulated under US DOT (United States Department of Transportation).

Not hazardous under shipping regulations (ground/sea/air).

15 Regulatory Information PROPER SHIPPING NAME..................................................................... Not a regulated product in ingot form. TRANSPORT CANADA AND U.S. DOT CLASSIFICATION.................... Not Applicable

TRANSPORT CANADA AND U.S. DOT PIN ........................................... Not Applicable

MARINE POLLUTANT.............................................................................. No

IMO CLASSIFICATION ............................................................................ Not Regulated

16 Other Information

PREPARATION INFORMATION:

Rev Revision Description Written By: Approved By: Date

0 First Issue Denna Gatewood Lance Underwood 09/13/2017

DISCLAIMER:

BiSN. believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because BiSN has no continuing control over such changes; those handling, storing, or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored, used, or disposed of, and that the same is done in accordance with federal, state, and local law. BiSN makes no warranty, expressed or implied, including (without limitation) warranties with respect to the completeness or continuing accuracy of the information contained herein, or with respect to fitness for any particular use.


BiSN



Synonyms: N/A



Manufacturer: BiSN 4539 Brittmoore Rd, Houston, TX 77041

Contact information: (832) 919-7500 (Day Only)

2 Hazard(s) Identification Classification of the mixture:

Irritant – Acute toxicity (oral, dermal, inhalation), Category 4 Health hazard – Reproductive toxicity, category 1A Specific target organ toxicity following repeated exposure, category 2 Environmentally Damaging – Acute hazards to the aquatic environment, category 1 Chronic hazards to the aquatic environment, category 1

Hazard Statement(s)





Harmful if inhaled

May damage fertility or the unborn child

May cause damage to organs through prolonged or repeated exposure

Very toxic to aquatic life

Very toxic to aquatic life with long lasting effects


Avoid breathing dust/fume/gas/mist/vapours/spray


Importer Name: Chevron Australia Pty Ltd Address: 250 St Georges Terrace, Perth, WA, 6000, AustraliaTelephone: 08 9216 4000Fax: 08 9216 4444






Use only outdoors or in a well-ventilated area


IF Swallowed get medical attention/advice if you do not feel well




IF EXPOSED or CONCERNED get medical attention/advice






Chronic: BISMUTH: May cause kidney damage.




Lead 7439-92-1 N/A*







Skin Contact: Remove to fresh air. Rinse/flush exposed skin gently using soap and water for 15-20 minutes. Seek medical advice if discomfort or irritations persists.

Most important symptoms and effects, both acute and delayed:

Irritation, Nausea, Headache, Shortness of breath.




Not Established

Flammable Limits:

Limits are not established. Massive metal is not flammable; however, dust or powder may be flammable.





Special Hazards:

Lead oxides. Combustion products may include carbon oxides or other toxic vapours. Thermal decomposition can lead to release of irritating gases and vapours.






Environmental Precautions:

Prevent from reaching drains, sewer or waterway. Collect contaminated soil for characterization. Should not be released into environment.









Personal Protection





Work/Hygienic:


9 Physical and Chemical Properties Appearance: Silver-grey solid metal Boiling Point: Not applicable








Not established






Will not occur.

Carcinogenicity: IARC: 2B: Possibly carcinogenic to humans (Lead); NTP: Reasonably anticipated to be a human carcinogen (Lead)

Reproductive Toxicity:

Reproductive toxicity – rat – Inhalation Effects on Newborn: Biochemical and metabolic. Reproductive toxicity – rat – Oral Effects on Newborn: Behavioral.

11 Toxicological Information Bismuth - LD50 oral - rat > 5,000mg/kg

Lead – LD50-not available


Ecotoxicity – LC50- Micropterus dolomieui: 2.2 mg/l – 96.0 h

EC50- Skeletonema costatum: 7.94 mg/l – 10 d






15 Regulatory Information PROPER SHIPPING NAME..................................................................... Not a regulated product in ingot form. TRANSPORT CANADA AND U.S. DOT CLASSIFICATION.................... Not Applicable

TRANSPORT CANADA AND U.S. DOT PIN ........................................... Not Applicable

MARINE POLLUTANT.............................................................................. No

IMO CLASSIFICATION ............................................................................ Not Regulated

16 Other Information

PREPARATION INFORMATION:

Rev Revision Description Written By: Approved By: Date

0 First Issue Denna Gatewood Lance Underwood 09/13/2017

DISCLAIMER:



BiSN



Synonyms: N/A



Manufacturer: BiSN Oil Tools, LLC 4539 Brittmoore Rd, Houston, TX 77041

Contact information: (832) 919-7500

2 Hazard(s) Identification Hazard Statement(s)





Harmful if inhaled


Avoid breathing dust/fume/gas/mist/vapors/spray





IF Swallowed Get Medical Attention/Advice if you do not feel well












Chronic: SILVER: Chronic skin contact or ingestion of silver dust, salts or fume can result in a condition known as Argyria, a condition with bluish pigmentation of the skin and eyes.

BISMUTH: May cause kidney damage.




Tin 7440-31-5 N/A*






Skin Contact: Remove to fresh air. If not breathing, give artificial respiration or oxygen by trained personnel. Seek immediate medical attention.





Not Established

Flammable Limits:

Limits are not established. Massive metal is not flammable; however dust or powder may be flammable.


















Personal Protection





Work/Hygienic:


9 Physical and Chemical Properties Appearance: Silver-gray solid metal Boiling Point: Not applicable








Not established






Will not occur.

11 Toxicological Information Tin - LD50 oral - rat > 700mg/kg







15 Regulatory Information


16 Other Information Created Date: 5/3/2017

Prepared by: S. Bedouet

Revised by: N/A

Approved by: D. Gatewood

The information and recommendations contained herein are, to the best of BiSN Oil Tools, LLC knowledge and belief, accurate and reliable as of the date issued. BiSN Oil Tools does not warrant or guarantee their accuracy or reliability, and BiSN Oil Tools shall not be liable for any loss or damage arising out of the user thereof. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container.


BiSN Oil Tools



Synonyms: N/A



Manufacturer: BiSN Oil Tools, LLC 4539 Brittmoore Rd, Houston, TX 77041

Contact information: (832) 919-7500

2 Hazard(s) Identification Hazard Statement(s)





Harmful if inhaled


Avoid breathing dust/fume/gas/mist/vapors/spray





IF Swallowed Get Medical Attention/Advice if you do not feel well












Chronic: SILVER: Chronic skin contact or ingestion of silver dust, salts or fume can result in a condition known as Argyria, a condition with bluish pigmentation of the skin and eyes.

BISMUTH: May cause kidney damage.




Silver 7440-22-4 N/A*






Skin Contact: Remove to fresh air. If not breathing, give artificial respiration or oxygen by trained personnel. Seek immediate medical attention.





Not Established

Flammable Limits:

Limits are not established. Massive metal is not flammable; however dust or powder may be flammable.


















Personal Protection





Work/Hygienic:


9 Physical and Chemical Properties Appearance: Silver-gray solid metal Boiling Point: Not applicable

Odor: Odorless Melting Point: 262.5 oC (504 F)







Not established






Will not occur.

11 Toxicological Information Silver - LD50 oral - rat > 5,000 mg/kg







15 Regulatory Information


16 Other Information Created Date: 3/13/2017

Prepared by: M. Price

Revised by: N/A

Approved by: S. Bedouet

The information and recommendations contained herein are, to the best of BiSN Oil Tools, LLC knowledge and belief, accurate and reliable as of the date issued. BiSN Oil Tools does not warrant or guarantee their accuracy or reliability, and BiSN Oil Tools shall not be liable for any loss or damage arising out of the user thereof. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container.

SAFETY DATA SHEET

PAGE 1 OF 9 SDS – BiSN ETC-1 Rev 2

Exothermic Composition-1

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Exothermic Composition-1

SYNONYMS: Thermite reaction, Thermite powder, Alumino-thermic reaction,

MANUFACTURER: BiSN

ADDRESS: 4539 Brittmoore Rd., Houston, TX 77041

EMERGENCY PHONE: (832) 919-7500 – Day Only

CHEMICAL NAME: ETC-1

CHEMICAL FAMILY: Metals

PRODUCT USE: Sealing applications in oil field wells

PREPARED BY: BiSN


EMERGENCY OVERVIEW:

WARNING! May be harmful if inhaled. May irritate the eyes, skin, and respiratory tract. Molten material may

cause thermal burns. Molten steel is hazardous.

MATERIAL DESCRIPTION:

Mixture of silver, black, brown, red, and gray granules with no odor.

CAUTION! Combustible Solid

SECTION 2 NOTES:

This material is not considered hazardous by the OSHA Hazard Communications Standard, if properly used.


INGREDIENT CAS NO. % WT

Ferric Oxide 1309-37-1 proprietary

Aluminum Powder (uncoated) 7429-90-5 proprietary

Silica Oxide 14808-60-7 proprietary

Silicic acid, sodium salt 1344-09-8 proprietary

Water 7732-18-5 proprietary

SECTION 3 NOTES:

This section covers ingredients contained in the product as shipped. The product shipped will consist mostly of

solid pieces of metal with some dust present. Some elements may not be present in some shipments.

Weight percentages are considered trade secrets, and thus, are not disclosed.



SAFETY DATA SHEET




POTENTIAL HEALTH EFFECTS

EYE CONTACT:

Dust or particulates may cause irritation including pain, tearing, and redness. Scratching of the cornea

can occur if eye is rubbed. Fumes may be irritating. Contact with the heated material will cause thermal

burns.

SKIN CONTACT:

Dust or particulates may cause irritation due to abrasion. Some components in this product are capable

of causing an allergic reaction, possibly resulting in itching and skin eruptions. Diseases of the skin, such

as eczema, may be aggravated by exposure. Contact with heated material will cause thermal burns.

INGESTION:

Not expected to be acutely toxic via ingestion based on the physical and chemical properties of the

product. Swallowing excessive amounts of dust may cause irritation, nausea, and diarrhea.

INHALATION:

Dust may cause irritation of the nose, throat, and lungs. Excessive inhalation of metallic fumes and dust

may result in metal fume fever, an influenza-like illness. It is characterized by a sweet or metallic taste in

the mouth, accompanied by dryness and irritation of the throat. Other symptoms include coughing,

shortness of breath, pulmonary edema, general malaise, weakness, fatigue, muscle and joint pain,

blurred vision, fever and chills. Typically, symptoms will last 12 - 48 hours. Disorders of the respiratory

system including asthma, bronchitis, and emphysema may be aggravated by exposure.

FIRST AID TREATMENT

EYE CONTACT:

In case of overexposure to dust or fumes, immediately flush eye with plenty of water for at least

15 minutes; occasionally lifting the eyelids. Get medical attention if irritation persists. Thermal

burns should be treated as medical emergencies.

SKIN CONTACT:

In case of overexposure to dust or particulates, wash with soap and plenty of water. Get medical

attention if irritation develops or persists. If thermal burn occurs, seek immediate medical attention.

INGESTION:

Not considered an ingestion hazard. However, if excessive amounts of dust or particulates are

swallowed, treat symptomatically and supportively. Get medical attention.

INHALATION:

In case of overexposure to dust or fumes, move to fresh air. Get immediate medical attention if any

symptoms listed above (Potential Health Effects) develop.

NOTES TO PHYSICIANS OR FIRST AID PROVIDERS:

Inhalation of metal fume or metal oxides may produce an acute febrile state, with cough, chills, weakness, and

general malaise. Nausea, vomiting, muscle cramps, and remarkable leukocytosis can develop. Treatment is

SAFETY DATA SHEET



symptomatic, and condition is self-limited in 24 – 48 hours. Chronic exposure to dusts may result in

pneumoconiosis of mixed type.

SECTION 5: FIRE-FIGHTING MEASURES

FLAMMABLE LIMITS: Not available.

FLASH POINT: Not available.

AUTOIGNITION TEMPERATURE: > 1830oF / 999oC

NFPA HAZARD CLASSIFICATION

HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0

OTHER: Use No Water.

Note: NFPA classifications are 0 - 4, with 4 as the most severe.

HMIS HAZARD CLASSIFICATION

HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0

PROTECTION: Safety glasses, gloves, dust respirator recommended. Note: HMIS

classifications are 0 - 4, with 4 as the most severe.

EXTINGUISHING MEDIA:

Do NOT use water, carbon dioxide, or foam. Metal dust fires need to be smothered with sand or inert dry powder.

Use a dry chemical or dry silica sand to extinguish fire. Contact professional fire fighters. If impossible to

extinguish, withdrawal from area, protect surroundings, and allow fire to burn itself out.

SPECIAL FIRE FIGHTING PROCEDURES:

Fire fighters should wear full firefighting turn-out gear and respiratory protection (self-contained breathing

apparatus). Combustible solid. Material is not sensitive to mechanical impact or static discharge.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

After ignition, the chemical reaction cannot be halted. May burn rapidly with flare burning effect. Molten slag and

steel are produced – stay clear when reaction takes place. Reaction can reach over 4500oF / 2500oC.

HAZARDOUS DECOMPOSITION PRODUCTS:

When heated to decomposition, acid fumes are emitted. Do NOT use water or foam, as generation of explosive

hydrogen may result. Chemical reaction with carbon dioxide may produce flammable and explosive methane.


HMIS

HEALTH 1

FLAMMABILITY 1

REACTIVITY 0

PPE E

1

1

0

W

SAFETY DATA SHEET



ACCIDENTAL RELEASE MEASURES:

Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Sweep up spill and place in

sealed bag or container for disposal. Wash spill area after pick up is complete.

SECTION 6 NOTES:

Use proper personal protective equipment as indicated in Section 8.


HANDLING:

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate

ventilation. Avoid contact with eyes, skin, and clothing. Minimize dust generation and accumulation. Avoid

inhalation and ingestion.

STORAGE:

Store in a cool, dry, well ventilated and locked storeroom away from incompatible materials. Store in general

storage area with other items. No specific storage hazards.

OTHER PRECAUTIONS:

DO NOT USE material that got wet for well sealing operations. Wet ETC-1 that is ignited will react violently.


INGREDIENT ACGIH TLV TWA OSHA PEL NIOSH

Iron Oxide 5 mg / m3 15 mg / m3 (total)

5 mg / m3 (resp)

<10 mg / m3

Aluminum 1 mg / m3 15 mg / m3 (total)

5 mg / m3 (resp)

10 mg / m3 (total)

5 mg / m3 (resp)

Silica Oxide 0.025 mg / m3 12.7 mg / m3 (total)

4.25 mg / m3 (resp)

0.05 mg / m3 (total)

Silicic acid, Sodium

Salt

No occupational exposure limit assigned. An exposure limit of 2 mg/m^3 (15

min TWA) is recommended by analogy with sodium Hydroxide (UK EH40)

NOTE:

No permissible exposure limits (PEL) or threshold limit values (TLV) exist for ETC-1. The above listing is a

summary of elements used in BiSN product. Various grades of ETC-1 will contain different combinations of the

elements and/or trace materials.

VENTILATION :

Use local exhaust ventilation, or other engineering controls, to keep airborne levels below the recommended

exposure limits.

SAFETY DATA SHEET



RESPIRATORY PROTECTION:

Use a NIOSH/MSHA approved respirator with a dust cartridge if exposure limits are exceeded, or if irritation or

other symptoms are experienced.

EYE PROTECTION:

Safety glasses should be used when handling the powder.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (cont.)

SKIN PROTECTION:

Wear appropriate protective clothing, shoes, and gloves to prevent skin exposure.

SECTION 8 NOTES:

Information concerning hazardous exposure limits has been compiled from sources considered to be reliable and

is accurate and reputable to the best of our knowledge and belief but is not guaranteed to be so.


APPEARANCE: Granular mixture/Solid blocks, gray in color

ODOR: Odorless

PHYSICAL STATE:

Solid/granular powder

pH AS SUPPLIED: Not Applicable

BOILING POINT: Not Applicable

MELTING POINT: > 1220oF / 660oC

FREEZING POINT: Not Applicable

VAPOR PRESSURE (mmHg): Not Applicable

VAPOR DENSITY (AIR = 1): Not Applicable

SPECIFIC GRAVITY (H2O = 1): > 1 g/mL @ 20oC

EVAPORATION RATE: Not Applicable

SOLUBILITY IN WATER: Insoluble

WEIGHT PERCENT SOLIDS: 100% Solids

PERCENT VOLATILE: Not Available

MOLECULAR WEIGHT: Not Available

VISCOSITY: Not Applicable


STABILITY: STABLE UNSTABLE

CONDITIONS TO AVOID (STABILITY): Does not spontaneously ignite.

INCOMPATIBILITY (MATERIAL TO AVOID): Reacts with acids and caustic solutions to produce

hydrogen.

SAFETY DATA SHEET



HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Can produce hydrogen when exposed to caustic

solutions or acid.

HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS TO AVOID (POLYMERIZATION): Not applicable.

SECTION 10 NOTES:

Avoid heat and moisture. Shelf life is indefinite if stored properly.

SAFETY DATA SHEET




ACUTE SYMPTOMS / SIGNS OF EXPOSURE:

EYES: Redness, tearing, itching, burning, conjunctivitis.

SKIN: Redness, itching

INGESTION: Irritation and burning sensation of mouth and throat, nausea, vomiting, and

abdominal pain.

INHALATION:

Irritation of mucous membranes, coughing, wheezing, shortness of breath.

CHRONIC EFFECTS:

None expected.

SENSITIZATION:

None expected.

TOXICITY TO ANIMALS: ETC-1: LD 50 [oral, rat]: Not applicable

LC 50 [rat]: Not applicable

LD 50 [dermal, rabbit]: Not applicable

SECTION 11 NOTES:

Material has not been found to be a carcinogen nor produce genetic, reproductive, or developmental effects.


ECOTOXICITY (AQUATIC AND TERRESTIAL): Ecological impact has not been determined.


WASTE DISPOSAL METHOD:

Check with all applicable local, regional, and national laws and regulations. Local regulations may be more

stringent than regional or national regulation.

RCRA HAZARD CLASS:

None listed.

SAFETY DATA SHEET




U.S. DEPARTMENT OF TRANSPORTATION

PROPER SHIPPING NAME: ETC-1

HAZARD CLASS: NOT APPLICABLE

ID NUMBER: NOT APPLICABLE

PACKING GROUP: NOT APPLICABLE

LABEL STATEMENT:

WATER TRANSPORTATION

NOT APPLICABLE





LABEL STATEMENTS:

AIR TRANSPORTATION

NOT APPLICABLE





LABEL STATEMENTS:

NOT APPLICABLE

CANADA TDG: Not regulated.


U.S. FEDERAL REGULATIONS

EPCRA Section 302 – Extremely Hazardous Substances:

None listed.

CERCLA - Hazardous Substances:

None listed.

EPCRA Section 313 – Toxic Chemicals:

CAS # 7429-90-5, Aluminum, is on the list as a fume or dust.

CAA 112(r) - Regulated Chemicals for Accidental Release Prevention:

None listed.

EPA TSCA Section 8(b) – Chemical Inventory:

CAS # 7429-90-5, Aluminum, is on the list.

CAS # 1309-37-1, Iron Oxide, is on the list.

SAFETY DATA SHEET



STATE REGULATIONS:

New Jersey Right to Know Hazardous Substance List:

CAS # 1309-37-1, Iron Oxide, is on the list.

CAS # 14808-60-7, Silica - Quartz, is on the list.

California Proposition 65 List of Chemicals:

Crystalline silica is on the list.

INTERNATIONAL REGULATIONS:

The product has been classified in accordance with the hazard criteria of the Controlled Products Regulations.

The Safety Data Sheet contains all the information required by the Controlled Products Regulations.


PREPARATION INFORMATION: Rev Revision Description Written By: Approved By: Date

2 Removed and Updated CAS numbers Billy Clark Denna Gatewood 06/08/2018

1 Added revision log and footer update Denna Gatewood Billy Clark 02/02/2018

0 First Issue Billy Clark Denna Gatewood 09/13/2017

DISCLAIMER:


1083 KLEIMANN LN – COLUMBUS, TX – 78934 - (979) 732-8210 SDS SE1

Page 1 of 9

SAFETY DATA SHEET (Complies with OSHA 29 CFR 1910.1200)

SECTION I: PRODUCT IDENTIFICATION

Sand Express Emergency Telephone Number 1083 Kleimann Lane (979) 732-8210 Columbus, TX 78934

SDS SE1 Revision: Aug-15

ProductsProduct Name Product # BLAST SAND COARSE - BULK BP83991C BLAST SAND MEDIUM - BULK BP83991M BLAST SAND FINE - BULK BP83991F OFFSHORE BLASTING SAND COARSE -4000# NR83991C OFFSHORE BLASTING SAND MEDIUM -4000# NR83991M OFFSHORE BLASTING SAND FINE - 4000# NR83991F 100# BLASTING SAND #3 COARSE 10091003 100# BLASTING SAND #4 MEDIUM 10091004 100# BLASTING SAND #5 FINE 10091005 100# BLASTING SAND #3/4 10091034 100# BLASTING SAND #4/5 19001045 80# BLASTING SAND #3 COARSE 8091003 80# BLASTING SAND #4 MEDIUM 8091003 80# BLASTING SAND #5 FINE 8091003 50# BLAST SAND - COARSE 509100C / 1009100C 50# BLAST SAND - MEDIUM 509100M / 1009100M 50# BLAST SAND - FINE 509100F / 1009100F

PRODUCT USE: AGGREGATES FOR USE IN SAND BLASTING

SECTION II - HAZARD IDENTIFICATION

Hazard-determining components of labeling: Silica 2.1 Classification of the substance or mixture Carcinogen – Category 1A Specific Target Organ Toxicity Single Exposure – Category 3 Specific Target Organ Toxicity Repeat Exposure – Category 1 Eye Irritant – Category 2B

2.2a Signal word DANGER!




Page 2 of 9

2.2b Hazard Statements May cause cancer through chronic inhalation May cause respiratory irritation Causes damage to lungs through prolonged or repeated inhalation Causes eye irritation if particles or dust get in eye 2.2c Pictograms

2.2d Precautionary statements Do not handle until all safety precautions have been read and understood. Wear protective gloves, eye protection, and protective clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Do not breathe dust. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately seek medical advice or attention if symptoms are significant or persist. Dispose of contents/containers in accordance with all regulations. 2.3 Additional Information 2.3a HNOC – Hazards not otherwise classified: Not applicable 2.3b Unknown Acute Toxicity: None 2.3c WHMIS Classification Class D2A – Chronic Toxic Effects – Carcinogen Class D2B – Eye Irritant


Page 3 of 9

2.3d Label Elements According To WHMIS Hazard Symbols

Signal Word DANGER!

SECTION III - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

Hazardous Components CAS No. % by Weight Sand, Silica, Quartz 14808-60-7 100

SECTION IV – FIRST AID MEASURES

4.1 Description of the first-aid measures General information: After inhalation: Remove person to fresh air and keep comfortable for breathing. After skin contact: Rinse skin with water. After eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. After swallowing: If conscious, have the victim drink plenty of water and call a physician immediately. Never give anything by mouth to an unconscious person. 4.2 Most important symptoms/effects, acute and delayed Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged or repeated inhalation. This product contains crystalline silica. Prolonged or repeated inhalation of respirable silica from this product can cause silicosis. Skin contact: Causes mechanical skin irritation. Eye Contact: Causes eye irritation if particles or dust get in eye. Ingestion: Ingestion of large quantities may cause discomfort and/or distress, nausea or vomiting. 4.3 Indication of immediate medical attention and special treatment needed: Immediately seek medical advice or attention if symptoms are significant or persist.

SECTION V - FIRE FIGHTING MEASURES

5.1 Flammability of the Product: Non-flammable and non-combustible 5.2 Suitable extinguishing agents: Treat for surrounding material 5.3 Special hazards arising from the substance or mixture: None 5.3a Products of Combustion: None


Page 4 of 9

5.3b Explosion Hazards in Presence of Various Substances: Non-explosive in presence of shocks

SECTION VI – ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures: Wear personal protective equipment (See section VIII). Keep unprotected persons away. 6.2 Methods and material for containment and cleaning up: Do not allow to enter sewers/ surface or ground water. Dispose of unwanted materials and containers properly in accordance with all regulations.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE

7.1 Handling Precautions for safe handling: Wear NIOSH-certified, type CE, blasting airline respirator with positive pressure blasting helmet for all people in the vicinity of blasting operations. The respirator must cover the wearer’s head, neck and shoulders. Comply with OSHA Respiratory Protection standard. Do not breathe dust. Wear eye/face protection. Wear protective gloves/clothing. Additional required equipment includes, but is not limited to: hearing protection, long leather gloves, aprons and safety boots. Do not eat, drink, or smoke when using this product. Dust remains in the air after blasting is completed; therefore, continue all safety precautions until the area is clean and ventilated. Prevent inhalation of dust from contaminated clothing and equipment. Wash contaminated clothing before reuse. Wash contacted hands, skin and hair thoroughly after handling. 7.2 Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep out of the reach of children.

SECTION VIII – EXPOSURE CONTROL MEASURES / PERSONAL PROTECTION

8.1 Components with limit values that require monitoring at the workplace: Hazardous Components CAS No. PEL (OSHA) TLV (ACGIH) mg/M3 mg/M3 Silica Sand, crystalline 14808-60-7 0.1 0.025 (resp) 8.2 Exposure Controls Use ventilation adequate to keep exposures below recommended exposure limits. Perform routine cleanup using wet methods or HEPA filtered vacuuming to minimize the accumulation of dust. Do not use compressed air to clean as this will create dust in the air. Clean and decontaminate equipment on the worksite. Schedule blasting when the least number of workers are at the site. Avoid blasting in windy conditions to prevent the spread of airborne dust.


Page 5 of 9

8.3 General protective and hygienic measures Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Provide accommodations for end-of-shift showers and change areas with separate storage facilities for street clothes, protective clothing and equipment. Keep contaminated clothing and equipment out of the clean change area. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. 8.3a Personal protective equipment Workers who are blasting or exposed to the dust remaining in the air from blasting operations must wear NIOSH-certified, type CE, blasting airline respirator with positive pressure blasting helmet for all people in the vicinity of blasting operations. The respirator must cover the wearer’s head, neck and shoulders. Comply with OSHA Respiratory Protection standard. Wear eye/face protection. Wear protective gloves/clothing. Additional required equipment includes, but is not limited to: hearing protection, long leather gloves, aprons and safety boots. Workers in the area who are not exposed to the dust from blasting (for example, pouring bags of media into a hopper) must wear a NIOSH N-95 particulate respirator, eye protection, and protective gloves/clothing when handling product.

SECTION IX - PHYSICAL/CHEMICAL CHARACTERISTICS

General Information Appearance Form: Granular Solid Color: Varies Odor: None pH-value at 20°C (68 °F): Not applicable Boiling point/Boiling range: Not applicable Flash point: Not applicable Auto igniting: Product is not self-igniting Vapor pressure at 21°C (70°F) Not applicable Density at 25°C (77 °F): 2.5-2.8

Solubility in / Miscibility with Water: Insoluble VOC content: 0 g/L VOC

SECTION X – STABILITY AND REACTIVITY

10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability


Page 6 of 9

Stable under normal storage conditions. Keep in dry storage. 10.3 Possibility of hazardous reaction No dangerous reaction known under conditions of normal use. 10.4 Thermal decomposition / conditions to be avoided No decomposition if used according to specifications. 10.5 Incompatible materials Contact of silica with powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, or oxygen difluoride may cause fires 10.6 Hazardous Decomposition or By-products Silica will dissolve in Hydrofluoric Acid and produce a corrosive gas – silicon tetrafluoride.

SECTION XI – TOXICOLOGICAL INFORMATION

11.1 Exposure Routes: Inhalation, skin contact, eye contact, or ingestion. 11.2 Symptoms related to physical/chemical/toxicological characteristics:

Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged or repeated exposure. This product contains crystalline silica. Prolonged or repeated inhalation of respirable silica from this product can cause silicosis. Skin contact: May cause mechanical skin irritation. Eye Contact: Causes eye irritation if particles or dust gets in eye. Ingestion: Ingestion of large quantities may cause discomfort and/or distress.

11.3 Delayed, immediate and chronic effects of short-term and long-term exposure Short Term

Skin Corrosion/Irritation: Not applicable Serious Eye Damage/Irritation: Causes eye irritation if particles or dust gets in eye Respiratory Sensitization: Not applicable Skin Sensitization: Not applicable Specific Target Organ Toxicity-Single Exposure: (Category 3) May cause respiratory irritation Aspiration Hazard: Not applicable

Long Term Carcinogenicity: May cause cancer through chronic inhalation. Germ Cell Mutagenicity: Not applicable Reproductive Toxicity: Not applicable Specific Target Organ Toxicity- Repeated Exposure: (Category 1) Causes damage to lungs through prolonged/repeated exposure Synergistic/Antagonistic Effects: Not applicable

SECTION XII – ECOLOGICAL INFORMATION

12.1 Ecotoxicity No further relevant information available.


Page 7 of 9

12.2 Persistence and degradability No further relevant information available. 12.3 Bioaccumulative potential: No further relevant information available. 12.4 Mobility in soil No further relevant information available. 12.5 Other Adverse Effects No further relevant information available.

SECTION XIII – DISPOSAL CONSIDERATIONS

13.1 Waste Disposal Method The packaging and material may be land filled; however, material should be covered to minimize generation of airborne dust. This product is not classified as a hazardous waste under the authority of the RCRA (40CFR 261) or CERCLA (40CFR 117&302). Disposal must be made in accordance with local, state and federal regulations. 13.2 Other disposal considerations Uncleaned packaging Recommendation: Disposal must be made in accordance with local, state and federal regulations. Recommended cleansing agent: Water, if necessary with cleansing agents.

SECTION XIV – TRANSPORT INFORMATION

DOT (U.S.) TDG (Canada) UN-Number Not Regulated Not Regulated UN proper shipping name Not Regulated Not Regulated Transport Hazard Class(es) Not Regulated Not Regulated Packing Group (if applicable) Not Regulated Not Regulated 14.1 Environmental hazards: Not applicable 14.2 Transport in bulk according to Annex II of Marpol 73/78 and the IBC Code Not applicable 14.3 Special precautions for user Do not handle until all safety precautions have been read and understood.

SECTION XV – OTHER REGULATORY INFORMATION

15.1 Safety, Health and Environmental Regulations/Legislations specific for the chemical


Page 8 of 9

Canada WHMIS Classification: Considered to be a D2A and D2B hazardous material under the Hazardous Products Act as defined by the Controlled Products Regulations and subject to the requirements of Health Canada’s Workplace Hazardous Material Information (WHMIS). This document complies with the WHMIS requirements of the Hazardous Products Act (HPA) and the CPR.

15.2 US Federal Information

SARA 302/311/312/313 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, 311, 312 or 313. RCRA: Crystalline silica (quartz) is not classified as a hazardous waste under the Resource Conservation and Recovery Act, or its regulations, 40 CFR §261 et seq. CERCLA: Crystalline silica (quartz) is not classified as a hazardous substance under regulations of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), 40 CFR §302. Emergency Planning and Community Right to Know Act (SARA Title III): Crystalline silica (quartz) is not an extremely hazardous substance under Section 302 and is not a toxic chemical subject to the requirements of Section 313. FDA: Silica is included in the list of substances that may be included in coatings used in food contact surfaces, 21 CFR §175.300(b)(3)(xxvi). NTP: Respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational settings, is classified as Known to be a Human Carcinogen. OSHA Carcinogen: Crystalline silica (quartz) is not listed.

15.3 State Right to Know Laws

California Prop. 65 Components WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Inhalation Reference Exposure Level (REL): California established a chronic REL of 3 µg for silica (crystalline, respirable). A chronic REL is an airborne level of a substance at or below which no adverse health effects are anticipated in individuals indefinitely exposed to the substance at that level. Massachusetts Toxic Use Reduction Act: Silica, crystalline (respirable size, <10 microns) is “toxic” for purposes of the Massachusetts Toxic Use Reduction Act.

15.4 Global Inventories

DSL All components of this product are on the Canadian DSL list. TSCA No.: Crystalline silica (quartz) appears on the EPA TSCA inventory under the CAS No. 14808-60-7. All constituents are listed in the TSCA inventory.


Page 9 of 9

15.5 NFPA Ratings

SECTION XVI – OTHER INFORMATION

Last Updated: August 21, 2015 NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products.

End of SDS

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Safety data sheet IS 3116

Safety Data Sheet dated 18/10/2016, version 1 Printing date: 20/10/2016

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

Trade name: IS 3116 MSDS code: F006260 Chemical description: Polymeric solution.

1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Industrial uses. 1.3. Details of the supplier of the safety data sheet

Supplier: LAMBERTI S.p.A. - Via Piave 18 - 21041 Albizzate (VA) Tel.: +39 0331 715 111 - Fax.: +39 0331 775 577 - e-mail: [email protected]

Competent person responsible for the safety data sheet: [email protected]

1.4. Emergency telephone number LAMBERTI S.p.A. - Tel. : +39 0331 715 111 - 24h

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP)

The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects:

No other hazards

2.2. Label elements Hazard pictograms:

None Hazard statements:

None Precautionary statements:

None Special Provisions:

None Special provisions according to Annex XVII of REACH and subsequent amendments:

None 2.3. Other hazards

vPvB Substances: None - PBT Substances: None Other Hazards:

No other hazards

SECTION 3: Composition/information on ingredients 3.1. Substances

N.A. 3.2. Mixtures

Hazardous components within the meaning of the CLP regulation and related classification: No ingredients to be listed.

SECTION 4: First aid measures 4.1. Description of first aid measures

Importer Name: Chevron Australia Pty LtdAddress: 250 St Georges Terrace, Perth, WA, 6000, AustraliaTelephone: 08 9216 4000Fax: 08 9216 4444Emergency contact number available during office hours only: 0427 495 187

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In case of skin contact:

Wash with plenty of water and soap. In case of eyes contact:

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion:

Do not under any circumstances induce vomiting. Seek immediately medical advice. In case of Inhalation:

Remove casualty to fresh air and keep warm and at rest. 4.2. Most important symptoms and effects, both acute and delayed

Not known. 4.3. Indication of any immediate medical attention and special treatment needed

Treatment: Not known.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: Not known.

5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases.

5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8.

6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.

6.3. Methods and material for containment and cleaning up Suitable material for taking up: absorbing material, organic, sand Wash with plenty of water.

6.4. Reference to other sections See also section 8 and 13

SECTION 7: Handling and storage 7.1. Precautions for safe handling

Avoid contact with skin and eyes, inhalation of vapours and mists. Do not eat or drink while working. See also section 8 for recommended protective equipment.

7.2. Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None. Instructions as regards storage premises:

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Adequate ventilation in working area. Packaging suggested: Plastic drums.

7.3. Specific end use(s) None in particular

SECTION 8: Exposure controls/personal protection 8.1. Control parameters No occupational exposure limit available DNEL Exposure Limit Values N.D. PNEC Exposure Limit Values N.D. 8.2. Exposure controls Eye protection:

Use close fitting safety goggles. (ref. EN 166, EN 140, EN175). Protection for skin:

No special precaution must be adopted for normal use. Protection for hands:

Chemical protective gloves should not be needed when handling this material. Consistent with general hygienic practice for any material, skin contact should be minimized. In case of prolonged contact, the use of protective gloves is recommended , providing comprehensive protection to chemicals (refer to EN 374).

Respiratory protection: Use respiratory protection where ventilation is insufficient or exposure is prolonged, e.g. (ref. EN 136, EN 140, EN 141, EN 143, EN 149, EN 405).

Thermal Hazards: None

Environmental exposure controls: None

Appropriate engineering controls: None

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties

Appearance and colour: Liquid (20 °C) Odour: Slight. Odour threshold: N.D. pH: 9.0 - 11.0 (as supplied) Melting point / freezing point: N.D. Initial boiling point and boiling range: N.A. Solid/gas flammability: N.D. Upper/lower flammability or explosive limits: N.D. Vapour density: N.D. Flash point: > 100 °C Evaporation rate: N.D. Vapour pressure: N.D. Relative density: 1.23 - 1.30 Solubility in water: Soluble Solubility in oil: N.D. Partition coefficient (n-octanol/water): N.D. Auto-ignition temperature: N.D. Decomposition temperature: N.D. Viscosity: N.D. Explosive properties: N.D.

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Oxidizing properties: N.D.

9.2. Other information Miscibility: N.D. Fat Solubility: N.D. Conductivity: N.D. Substance Groups relevant properties N.D.

SECTION 10: Stability and reactivity 10.1. Reactivity

Stable under normal conditions 10.2. Chemical stability

Stable under normal conditions 10.3. Possibility of hazardous reactions

Stable under normal conditions 10.4. Conditions to avoid

Stable under normal conditions. 10.5. Incompatible materials

Not known. 10.6. Hazardous decomposition products

Not known.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the mixture:

a) acute toxicity: Toxicity Oral Rat LD50> 2000 mg/kg - Based on components.

b) skin corrosion/irritation: Irritation Skin : repeated and prolonged contacts may cause slight irritation.

c) serious eye damage/irritation: Irritation Eye : repeated and prolonged contacts may cause slight irritation.

Other : N.D. If not differently specified, the information required in Regulation (EU)2015/830 listed below must be considered as N.D.: a) acute toxicity; b) skin corrosion/irritation; c) serious eye damage/irritation; d) respiratory or skin sensitisation; e) germ cell mutagenicity; f) carcinogenicity; g) reproductive toxicity; h) STOT-single exposure; i) STOT-repeated exposure; j) aspiration hazard.

SECTION 12: Ecological information 12.1. Toxicity

Ecological information of the mixture: a) Aquatic acute toxicity:

EC50/LC50 > 100 mg/l - aquatic species (Lamberti internal data). 12.2. Persistence and degradability

Ecological information of the mixture: Biodegradability: Readily biodegradable. - Test OECD 306: > 60% - Lamberti internal data.

12.3. Bioaccumulative potential Ecological information of the mixture:

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Bioaccumulation: Data not available.

12.4. Mobility in soil Ecological information of the mixture:

Mobility in soil: Data not available. 12.5. Results of PBT and vPvB assessment

vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects


SECTION 13: Disposal considerations 13.1. Waste treatment methods

If possible recover the product in accordance with local regulation.

SECTION 14: Transport information 14.1. UN number

N.A. 14.2. UN proper shipping name

Proper Shipping Name: N.A. 14.3. Transport hazard class(es)

Road (ADR): N.A. Air (ICAO/IATA): N.A. Sea (IMO/IMDG): N.A.

14.4. Packing group N.A.

14.5. Environmental hazards N.A.

14.6. Special precautions for user N.A.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N.D.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE. Regulation (CE) n. 1907/2006 (REACH). For non-EU Countries, the Material Safety Data Sheet it is prepared following the main principles of Globally Harmonized System of Classification and Labelling of Chemicals (GHS) which are adopted worldwide. 15.2. Chemical safety assessment

No

SECTION 16: Other information N.A. = Not Applicable N.D. = No Data available This safety data sheet has been completely updated in compliance to Regulation 2015/830. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources:

TOXNET - Databases on toxicology, hazardous chemicals, environmental health, and toxic releases;

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NIOSH - Registry of toxic effects of chemical substances (1983) - Occupational Health Guidelines for Chemical Hazards (1995) - Pocket Guide to Chemical Hazards (on line) OECD - eChemPortal: The Global Portal to Information on Chemical Substances; CESIO - Human Health and Environmental classification of AE, AES, AS and various surfactant families. M.Sittig-Handbook of toxic and Hazardous Chemicals and Carcinogens- III Ed. E.R. Plunkett - Handbook of Industrial Toxicology - III Ed. 1991. Samson Chem. Pub.-Chemical Safety Sheet working safely with hazardous chemical. SAX'S Dangerous Properties of Industrial Materials. VIII (1993) ACGIH - "TLVs and BEIs" - latest edition

The product must be stored, handled and used according to criteria of good industrial practice and to regulations in force. This leaflet is offered for your consideration and guidance only. This leaflet complements the Technical Data Sheet but does not replace it. The information herein contained is given to the best of our knowledge at the time of issue. Due to the several ways in which the product may be used and the possible interaction with variables not depending on or unknown to the supplier, we also cannot accept any liability whatsoever for any loss or damage however arising from the handling and use of our products. ADR: European Agreement concerning the International Carriage of

Dangerous Goods by Road. CAS: Chemical Abstracts Service (division of the American Chemical

Society). CLP: Classification, Labeling, Packaging. DNEL: Derived No Effect Level. EINECS: European Inventory of Existing Commercial Chemical Substances. GefStoffVO: Ordinance on Hazardous Substances, Germany. GHS: Globally Harmonized System of Classification and Labeling of

Chemicals. IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the "International Air Transport

Association" (IATA). ICAO: International Civil Aviation Organization. ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"

(ICAO). IMDG: International Maritime Code for Dangerous Goods. INCI: International Nomenclature of Cosmetic Ingredients. KSt: Explosion coefficient. LC50: Lethal concentration, for 50 percent of test population. LD50: Lethal dose, for 50 percent of test population. LTE: Long-term exposure. PNEC: Predicted No Effect Concentration. REACH: Registration Evaluation and Authorization of Chemicals. RID: Regulation Concerning the International Transport of Dangerous Goods

by Rail. STE: Short-term exposure. STEL: Short Term Exposure limit. STOT: Specific Target Organ Toxicity. SVHC: Candidate List of Substances of Very High Concerns. TLV: Threshold Limiting Value. TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day.

(ACGIH Standard). WGK: German Water Hazard Class.

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Safety data sheet IS FLR H 10

Safety Data Sheet dated 18/10/2016, version 1

Printing date: 20/10/2016

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier Trade name: IS FLR H 10 MSDS code: F006736 Chemical description: Product based on polymer in hydro-glycolic solution.

1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: Industrial uses. 1.3. Details of the supplier of the safety data sheet

Supplier: LAMBERTI S.p.A. - Via Piave 18 - 21041 Albizzate (VA) Tel.: +39 0331 715 111 - Fax.: +39 0331 775 577 - e-mail: [email protected]

Competent person responsible for the safety data sheet: [email protected]

1.4. Emergency telephone number LAMBERTI S.p.A. - Tel. : +39 0331 715 111 - 24h

SECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP)

Warning, STOT RE 2, May cause damage to organs through prolonged or repeated exposure.

Adverse physicochemical, human health and environmental effects: No other hazards

2.2. Label elements Hazard pictograms:

Warning Hazard statements:

H373 May cause damage to organs through prolonged or repeated exposure. Precautionary statements:

P260 Do not breathe dust/fume/gas/mist/vapours/spray. P314 Get medical advice/attention if you feel unwell. P501 Dispose of contents/container in accordance with applicable regulations.

Special Provisions: None

Contents Ethylene glycol

Special provisions according to Annex XVII of REACH and subsequent amendments: None

2.3. Other hazards vPvB Substances: None - PBT Substances: None

Other Hazards: No other hazards



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SECTION 3: Composition/information on ingredients 3.1. Substances

N.A. 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: >= 10% - < 25% Ethylene glycol

REACH No.: 01-2119456816-28-XXXX, Index number: 603-027-00-1, CAS: 107-21-1, EC: 203-473-3

3.1/4/Oral Acute Tox. 4 H302 3.9/2 STOT RE 2 H373

SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact:

Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. Wash with plenty of water and soap. Remove contaminated clothing immediately and dispose of safely.

In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

In case of Ingestion: Do not under any circumstances induce vomiting. Seek immediately medical advice.

In case of Inhalation: Remove casualty to fresh air and keep warm and at rest.

4.2. Most important symptoms and effects, both acute and delayed Not known.

4.3. Indication of any immediate medical attention and special treatment needed In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment: Not known.

SECTION 5: Firefighting measures 5.1. Extinguishing media

Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: Not known.

5.2. Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases.

5.3. Advice for firefighters Use suitable breathing apparatus . Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures

Wear personal protection equipment. Remove persons to safety.

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See protective measures under point 7 and 8.

6.2. Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.

6.3. Methods and material for containment and cleaning up Suitable material for taking up: absorbing material, organic, sand Wash with plenty of water.

6.4. Reference to other sections See also section 8 and 13

SECTION 7: Handling and storage 7.1. Precautions for safe handling

Avoid contact with skin and eyes, inhalation of vapours and mists. Do not use empty container before they have been cleaned. Before making transfer operations, assure that there are not any incompatible material residuals in the containers. Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment.

7.2. Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: None. Instructions as regards storage premises: Adequate ventilation in working area. Packaging suggested: Plastic drums.

7.3. Specific end use(s) None in particular

SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ethylene glycol US - ACGIH (TLV) - STEL(15 min.): C 100 ppm - Notes: A4 UK - EH40/2005 (WEL) - LTE(8h): 10 ppm - Notes: Skin; Particulate DE - TRGS 900 (MAK) - LTE(8h): 26 mg/m3, 10 ppm - STEL(15 min.): 52 mg/m3, 20 ppm -

Notes: Particulate and Vapour. IT - D. 6 agosto 2012 (Valore limite) - LTE(8h): 52 mg/m3, 20 ppm - STEL(15 min.): 104

mg/m3, 40 ppm - Notes: Skin; Vapour. EU - Dir. 2000/39/CE (ILV) - LTE(8h): 52 mg/m3, 20 ppm - STEL(15 min.): 104 mg/m3, 40 ppm

- Notes: Skin; Vapour. UK - EH40/2005 (WEL) - LTE(8h): 52 mg/m3, 20 ppm - STEL(15 min.): 104 mg/m3, 40 ppm -

Notes: Skin; Vapour. FR - VLEP - LTE(8h): 52 mg/m3, 20 ppm - STEL(15 min.): 104 mg/m3, 40 ppm - Notes:

Vapour. DNEL Exposure Limit Values Ethylene glycol

Worker Industry: 35 mg/m3 - Worker Professional: 35 mg/m3 - General population: 7 mg/m3 - Frequency: Long Term, local effects Human Inhalation Worker Industry: 106 mg/kg - Worker Professional: 106 mg/kg - General population: 53 mg/kg - Frequency: Long Term, systemic effects Human Dermal

PNEC Exposure Limit Values Ethylene glycol

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Fresh Water 10 mg/l Marine water 1 mg/l Intermittent release 10 mg/l STP 199.5 mg/l Freshwater sediments 37 mg/kg Marine water sediments 3.7 mg/kg Soil (agricultural) 1.53 mg/kg

8.2. Exposure controls Eye protection:

Use close fitting safety goggles. (ref. EN 166, EN 140, EN175). Protection for skin:

Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton. (ref. EN 340).

Protection for hands: Chemical-resistant protective gloves (EN 374). When prolonged or frequently repeated contact may occur, a glove is recommended to prevent contact. Examples of preferred glove barrier materials include: Neoprene. Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyvinyl chloride ("PVC" or "vinyl"). As general indication we suggest as suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) and suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness). This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances-mixtures.

Respiratory protection: Use adequate protective respiratory equipment. (ref. EN 136, EN 140, EN 141, EN 143, EN 149, EN 405).

Thermal Hazards: None

Environmental exposure controls: None

Appropriate engineering controls: None

SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties

Appearance and colour: Liquid (20 °C) Odour: Slight. Odour threshold: N.D. pH: 7.0 - 9.0 (as supplied) Melting point / freezing point: N.D. Initial boiling point and boiling range: N.A. Solid/gas flammability: N.D. Upper/lower flammability or explosive limits: N.D. Vapour density: N.D. Flash point: > 100 °C Evaporation rate: N.D. Vapour pressure: N.D. Relative density: 1.04 - 1.07 Solubility in water: Soluble. Solubility in oil: N.D. Partition coefficient (n-octanol/water): N.D. Auto-ignition temperature: N.D. Decomposition temperature: N.D. Viscosity: > 20.5 cSt @ 40 °C Explosive properties: N.D.

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Oxidizing properties: N.D.

9.2. Other information Miscibility: N.D. Fat Solubility: N.D. Conductivity: N.D. Substance Groups relevant properties N.D.

SECTION 10: Stability and reactivity 10.1. Reactivity

Stable under normal conditions 10.2. Chemical stability

Stable under normal conditions 10.3. Possibility of hazardous reactions

Stable under normal conditions 10.4. Conditions to avoid

Stable under normal conditions. 10.5. Incompatible materials

Not known. 10.6. Hazardous decomposition products

Not known.

SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the mixture:

a) acute toxicity: Toxicity Oral Rat LD50> 2000 mg/kg - Calculated data.

b) skin corrosion/irritation: Irritation Skin : repeated and prolonged contacts may cause slight irritation.

c) serious eye damage/irritation: Irritation Eye : repeated and prolonged contacts may cause slight irritation.

i) STOT-repeated exposure: May cause damage to organs through prolonged or repeated exposure.

Toxicological information of the main substances found in the mixture: Ethylene glycol a) acute toxicity:

Toxicity Oral Rat LD50= 7712 mg/kg - Literature data. Toxicity Inhalation Rat LC50 > 2.5 mg/l - Duration: 6h - Literature data. Toxicity Skin Mouse LD50> 3500 mg/kg - Literature data. Toxicity Oral : harmful. - Duration: > 90 days. - Literature data.

b) skin corrosion/irritation: Irritation Skin Rabbit : Not irritant. - Literature data.

c) serious eye damage/irritation: Irritation Eye Rabbit : Not irritant. - Duration: 24h - Literature data.

d) respiratory or skin sensitisation: Guinea pig maximization test Skin Guinea pig : Not sensitizing. - Literature data.

e) germ cell mutagenicity: OECD 474 Mouse : Not mutagenic. - Literature data.

i) STOT-repeated exposure: Repeated dose effects. Oral Rat NOAEL = 150 mg/kg - Duration: > 90 days. Literature data. - Notes: STOT - Kidneys.

Other : N.D. If not differently specified, the information required in Regulation (EU)2015/830 listed below must be considered as N.D.: a) acute toxicity; b) skin corrosion/irritation;

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c) serious eye damage/irritation; d) respiratory or skin sensitisation; e) germ cell mutagenicity; f) carcinogenicity; g) reproductive toxicity; h) STOT-single exposure; i) STOT-repeated exposure; j) aspiration hazard.

SECTION 12: Ecological information 12.1. Toxicity

Ecological information of the mixture: a) Aquatic acute toxicity:

Data not available. Ecological information of the main substances found in the mixture: Ethylene glycol a) Aquatic acute toxicity:

EPA Guideline Fish LC50 = 72860 mg/l - Duration h: 96 - Notes: Literature data. OECD 202 Daphnia magna EC50 > 100 mg/l - Duration h: 48 - Notes: Literature data.

12.2. Persistence and degradability Ecological information of the mixture:

Biodegradability: Data not available. Ecological information of the main substances found in the mixture: Ethylene glycol

Biodegradability: Readily biodegradable - Test: OECD 301 A - Duration: 10 days: 90% - Notes: Literature data.

12.3. Bioaccumulative potential Ecological information of the mixture:

Bioaccumulation: Data not available. Ecological information of the main substances found in the mixture: Ethylene glycol

Bioaccumulation: Not bioaccumulative - Test: BCF - Bioconcentrantion factor 10 - Duration: 72h - Notes: Literature data.

12.4. Mobility in soil Ecological information of the mixture:

Mobility in soil: Data not available. Ecological information of the main substances found in the mixture: Ethylene glycol

Mobility in soil: Very high - Test: Koc: 1 - Notes: Calculated data (in silico). 12.5. Results of PBT and vPvB assessment

vPvB Substances: None - PBT Substances: None 12.6. Other adverse effects


SECTION 13: Disposal considerations 13.1. Waste treatment methods

If possible recover the product, otherwise dispose of in authorized landfill or incineration in accordance with local regulation.

SECTION 14: Transport information 14.1. UN number

N.A. 14.2. UN proper shipping name

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Proper Shipping Name: N.A.

14.3. Transport hazard class(es) Road (ADR): N.A. Air (ICAO/IATA): N.A. Sea (IMO/IMDG): N.A.

14.4. Packing group N.A.

14.5. Environmental hazards N.A.

14.6. Special precautions for user N.A.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N.A.

SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE. Regulation (CE) n. 1907/2006 (REACH). For non-EU Countries, the Material Safety Data Sheet it is prepared following the main principles of Globally Harmonized System of Classification and Labelling of Chemicals (GHS) which are adopted worldwide. 15.2. Chemical safety assessment

No

SECTION 16: Other information N.A. = Not Applicable N.D. = No Data available Full text of phrases referred to in Section 3:

H302 Harmful if swallowed. H373 May cause damage to organs through prolonged or repeated exposure.

This safety data sheet has been completely updated in compliance to Regulation 2015/830. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources:

TOXNET - Databases on toxicology, hazardous chemicals, environmental health, and toxic releases; NIOSH - Registry of toxic effects of chemical substances (1983) - Occupational Health Guidelines for Chemical Hazards (1995) - Pocket Guide to Chemical Hazards (on line) OECD - eChemPortal: The Global Portal to Information on Chemical Substances; CESIO - Human Health and Environmental classification of AE, AES, AS and various surfactant families. M.Sittig-Handbook of toxic and Hazardous Chemicals and Carcinogens- III Ed. E.R. Plunkett - Handbook of Industrial Toxicology - III Ed. 1991. Samson Chem. Pub.-Chemical Safety Sheet working safely with hazardous chemical. SAX'S Dangerous Properties of Industrial Materials. VIII (1993) ACGIH - "TLVs and BEIs" - latest edition

The product must be stored, handled and used according to criteria of good industrial practice and to regulations in force. This leaflet is offered for your consideration and guidance only. This leaflet complements the Technical Data Sheet but does not replace it. The information herein contained is given to the best of our knowledge at the time of issue. Due to the several ways in which the product may be used and the possible interaction with variables not depending on or unknown to the supplier, we also cannot accept any liability whatsoever for any loss or damage however arising from the handling and use of our products.

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ADR: European Agreement concerning the International Carriage of

Dangerous Goods by Road. CAS: Chemical Abstracts Service (division of the American Chemical

Society). CLP: Classification, Labeling, Packaging. DNEL: Derived No Effect Level. EINECS: European Inventory of Existing Commercial Chemical Substances. GefStoffVO: Ordinance on Hazardous Substances, Germany. GHS: Globally Harmonized System of Classification and Labeling of

Chemicals. IATA: International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the "International Air Transport

Association" (IATA). ICAO: International Civil Aviation Organization. ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"

(ICAO). IMDG: International Maritime Code for Dangerous Goods. INCI: International Nomenclature of Cosmetic Ingredients. KSt: Explosion coefficient. LC50: Lethal concentration, for 50 percent of test population. LD50: Lethal dose, for 50 percent of test population. LTE: Long-term exposure. PNEC: Predicted No Effect Concentration. REACH: Registration Evaluation and Authorization of Chemicals. RID: Regulation Concerning the International Transport of Dangerous Goods

by Rail. STE: Short-term exposure. STEL: Short Term Exposure limit. STOT: Specific Target Organ Toxicity. SVHC: Candidate List of Substances of Very High Concerns. TLV: Threshold Limiting Value. TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day.

(ACGIH Standard). WGK: German Water Hazard Class.

SAFETY DATA SHEET

BARITERevision Date: 22-Jan-2018 Revision Number: 50

1. Product Identifier & Identity for the Chemical

Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goodsaccording to the criteria of ADG.

1.1. Product Identifier Product Name BARITE

Other means of Identification Synonyms NoneHazardous Material Number: HM000105

Recommended use of the chemical and restrictions on use Recommended Use Weight AdditiveUses advised against No information available

Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.

15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300

E-mail Address [email protected]

Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012

Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100

2. Hazard Identification


Classification of the hazardous chemical Carcinogenicity Category 2 - H351Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373

Label elements, including precautionary statements

Hazard Pictograms

_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________BARITE Revision Date: 22-Jan-2018

Signal Word WARNING

Hazard Statements: H351 - Suspected of causing cancer if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled


Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required

Response P314 - Get medical attention/advice if you feel unwellP308 + P313 - IF exposed or concerned: Get medical advice/attention

Storage P405 - Store locked upDisposal P501 - Dispose of contents/container in accordance with

local/regional/national/international regulations

ContainsSubstances CAS NumberCrystalline silica, quartz 14808-60-7

Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

For the full text of the H-phrases mentioned in this Section, see Section 16

3. Composition/information on Ingredients

Substances CAS Number PERCENT (w/w) GHS Classification -Australia

Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 2 (H351)STOT RE 1 (H372)


Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory

irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15

minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Symptoms caused by exposure Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.

Medical Attention and Special Treatment Notes to Physician Treat symptomatically

_____________________________________________________________________________________________Page 2 / 8


5. Fire Fighting Measures

Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireNone anticipated

Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.

6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated withcontaminating substances and use appropriate methods for collection, storage and disposal.


7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits.Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery whenwet.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Use goodhousekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuse emptycontainer.Other GuidelinesNo information available

8. Exposure Controls/Personal Protection

Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWACrystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3

Appropriate engineering controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures

below applicable exposure limits.

_____________________________________________________________________________________________Page 3 / 8


Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the

selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.

Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, orequivalent respirator when using this product.

Hand Protection Normal work gloves.Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered

before reuse. Use precautionary measures to avoid creating dust when removing orlaundering clothing.

Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available

9. Physical and Chemical Properties


Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 4.23Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information Molecular Weight 233.4VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials None known.10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).

Physical State: Solid Color Pink to tan to grayOdor: Odorless Odor Threshold: No information available

_____________________________________________________________________________________________Page 4 / 8


11. Toxicological Information

Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.

Symptoms related to exposure Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation

Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No data available No data available

Immediate, delayed and chronic health effects from exposure Inhalation Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.

Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).

Eye Contact May cause mechanical irritation to eye.Skin Contact None known.Ingestion None known.

Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause aprogressive, disabling, and sometimes-fatal lung disease called silicosis.Symptoms include cough, shortness of breath, wheezing, non-specific chestillness, and reduced pulmonary function. This disease is exacerbated by smoking.Individuals with silicosis are predisposed to develop tuberculosis.

Exposure LevelsNo data available

Interactive effects Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not beexposed to quartz dust.

Data limitationsNo data available

Substances CAS Number Skin corrosion/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the skin

Substances CAS Number Serious eye damage/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the eye

Substances CAS Number Skin SensitizationCrystalline silica, quartz 14808-60-7 No information available.

Substances CAS Number Respiratory SensitizationCrystalline silica, quartz 14808-60-7 No information available

Substances CAS Number Mutagenic EffectsCrystalline silica, quartz 14808-60-7 Not regarded as mutagenic.

Substances CAS Number Carcinogenic Effects

_____________________________________________________________________________________________Page 5 / 8


Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure.

Substances CAS Number Reproductive toxicityCrystalline silica, quartz 14808-60-7 No information available

Substances CAS Number STOT - single exposureCrystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposureCrystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)

Substances CAS Number Aspiration hazardCrystalline silica, quartz 14808-60-7 Not applicable

12. Ecological Information

Ecotoxicity

Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to

MicroorganismsToxicity to Invertebrates

Crystalline silica,quartz

14808-60-7 EC50 (72 h) =440 mg/L(Selenastrum

capricornutum)(similarsubstance)

LL0 (96 h) =10000 mg/L(Danio rerio)(similar

substance)

No information available LL50 (24 h) >10000 mg/L(Daphnia magna)(similar

substance)

12.2. Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.Substances CAS Number Persistence and DegradabilityCrystalline silica, quartz 14808-60-7 The methods for determining biodegradability are

not applicable to inorganic substances.

12.3. Bioaccumulative potential Does not bioaccumulate.Substances CAS Number Log Pow

Crystalline silica, quartz 14808-60-7 No information available


Substances CAS Number MobilityCrystalline silica, quartz 14808-60-7 No information available

12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors

13. Disposal Considerations

Safe handling and disposal methods Follow all applicable community, national or regional regulations regarding waste management methods.

Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.

_____________________________________________________________________________________________Page 6 / 8

Environmental regulationsNot applicable


14. Transport Information

Transportation Information Australia ADG

UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

Special precautions during transport None

HazChem Code None Allocated

15. Regulatory Information

Safety, health and environmental regulations specific for the product

International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or

assessment certificate.New Zealand Inventory ofChemicals

All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.

EINECS (European Inventory ofExisting Chemical Substances)

This product, and all its components, complies with EINECS

US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)

All components listed on inventory or are exempt.

Poisons Schedule number None Allocated

International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply


Date of preparation or review

Revision Date: 22-Jan-2018

_____________________________________________________________________________________________Page 7 / 8


Revision NoteSDS sections updated:2

Full text of H-Statements referred to under sections 2 and 3H351 - Suspected of causing cancer if inhaledH372 - Causes damage to organs through prolonged or repeated exposureH373 - May cause damage to organs through prolonged or repeated exposure if inhaled

Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.

For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.

Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID

Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.


_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

CEMENT - CLASS GRevision Date: 21-Jun-2016 Revision Number: 31



1.1. Product Identifier Product Name CEMENT - CLASS G


Recommended use of the chemical and restrictions on use Recommended Use CementUses advised against No information available


15 Marriott RoadJandakotWA 6164Australia

ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300


Emergency phone number + 61 1 800 686 951




Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318Skin Sensitization Category 1 - H317Carcinogenicity Category 2 - H351Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373

_____________________________________________________________________________________________Page 1 / 9


_____________________________________________________________________________________________CEMENT - CLASS G Revision Date: 21-Jun-2016

Hazard pictograms

Signal Word Danger

Hazard Statements: H315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritationH351 - Suspected of causing cancer if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled


Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP272 - Contaminated work clothing should not be allowed out of the workplaceP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required

Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP333 + P313 - If skin irritation or rash occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathingP312 - Call a POISON CENTER/doctor/physician if you feel unwellP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell

Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closedP405 - Store locked up

Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations

ContainsSubstances CAS NumberPortland cement 65997-15-1Crystalline silica, quartz 14808-60-7




Substances CAS Number PERCENT (w/w) GHS Classification -

_____________________________________________________________________________________________Page 2 / 9


AustraliaPortland cement 65997-15-1 60 - 100% Skin Irrit. 2 (H315)

Eye Corr. 1 (H318)Skin Sens. 1 (H317)STOT SE 3 (H335)




irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.Skin In case of contact, immediately flush skin with plenty of soap and water for at least

30 minutes and remove contaminated clothing, shoes and leather goodsimmediately. Get medical attention immediately.

Ingestion Under normal conditions, first aid procedures are not required.

Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Maycause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer.Crystalline silica has also been associated with scleroderma and kidney disease.



Suitable extinguishing equipment Suitable Extinguishing MediaNone - does not burn.Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireNot applicable



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation. Evacuate all persons from the area.



_____________________________________________________________________________________________Page 3 / 9



7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may become airbornewithout a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keepexposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator whenusing this product. Material is slippery when wet. Wash hands after use. Launder contaminated clothing before reuse.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool well ventilated area. Keep container closed when not in use. Store locked up. Store in a cool, dry location. Use goodhousekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product has a shelf lifeof 24 months.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAPortland cement 65997-15-1 TWA: 10 mg/m3 TWA: 1 mg/m3

Crystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3






Hand Protection Impervious rubber gloves.Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered


Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: 12.4Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data available

Physical State: Solid Color GrayOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 9



Vapor Density No data availableSpecific Gravity 3.14Water Solubility No data availableSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data available


10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid Keep away from any contact with water.10.5. Incompatible materials Hydrofluoric acid.

10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. Maycause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer.Crystalline silica has also been associated with scleroderma and kidney disease.

Numerical measures of toxicity



Portland cement 65997-15-1 > 2000 mg/kg (Rat) > 2000 mg/kg > 1 mg/L (Rat) 4h

Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No information available No data available

Immediate, delayed and chronic health effects from exposure Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is

carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (IARC, Group 2A).

Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).Causes moderate respiratory irritation.

Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation. Can dry skin. May cause alkali burns with confined contact. May

_____________________________________________________________________________________________Page 5 / 9


cause an allergic skin reaction.Ingestion Causes burns of the mouth, throat and stomach.


Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.




Substances CAS Number Skin corrosion/irritationPortland cement 65997-15-1 Irritating to skin. (Rabbit)Crystalline silica, quartz 14808-60-7 Non-irritating to the skin

Substances CAS Number Serious eye damage/irritationPortland cement 65997-15-1 Corrosive to eyesCrystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible. No information available

Substances CAS Number Skin SensitizationPortland cement 65997-15-1 May cause sensitization by skin contactCrystalline silica, quartz 14808-60-7 No information available.

Substances CAS Number Respiratory SensitizationPortland cement 65997-15-1 No information availableCrystalline silica, quartz 14808-60-7 No information available

Substances CAS Number Mutagenic EffectsPortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.

Substances CAS Number Carcinogenic EffectsPortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The

IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity of

_____________________________________________________________________________________________Page 6 / 9


crystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.

Substances CAS Number Reproductive toxicityPortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 No information available

Substances CAS Number STOT - single exposurePortland cement 65997-15-1 May cause respiratory irritation.Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposurePortland cement 65997-15-1 No data of sufficient quality are available.Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)

Substances CAS Number Aspiration hazardPortland cement 65997-15-1 Not applicableCrystalline silica, quartz 14808-60-7 Not applicable


Ecotoxicity Product Ecotoxicity DataNo data available



Portland cement 65997-15-1 No information available No information available No information available No information available



capricornutum)

LL0 (96 h) =10000 mg/L(Danio rerio)

No information available LL50 (24 h) >10000 mg/L(Daphnia magna)


Substances CAS Number Persistence and DegradabilityPortland cement 65997-15-1 The methods for determining biodegradability are

not applicable to inorganic substances.Crystalline silica, quartz 14808-60-7 The methods for determining biodegradability are



Substances CAS Number Log Pow

Portland cement 65997-15-1 No information available



Substances CAS Number MobilityPortland cement 65997-15-1 No information availableCrystalline silica, quartz 14808-60-7 No information available



_____________________________________________________________________________________________Page 7 / 9

Safe handling and disposal methods


Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewagefacility.




Transportation Information UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable













International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStolkhom Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply



Revision Date: 21-Jun-2016

Revision NoteSDS sections updated: 2

_____________________________________________________________________________________________Page 8 / 9



H315 - Causes skin irritationH317 - May cause an allergic skin reactionH318 - Causes serious eye damageH335 - May cause respiratory irritationH351 - Suspected of causing cancer if inhaledH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled







_____________________________________________________________________________________________Page 9 / 9

SAFETY DATA SHEET

DCA-22001Revision Date: 09-Feb-2018 Revision Number: 9


Statement of Hazardous Nature Hazardous according to the criteria of the 3rd Revised Edition of the Globally HarmonisedSystem of Classification and Labelling of Chemicals (GHS), Dangerous Goods according tothe criteria of ADG.

1.1. Product Identifier Product Name DCA-22001


Recommended use of the chemical and restrictions on use Recommended Use CleanerUses advised against No information available








Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318Specific Target Organ Toxicity - (Single Exposure) Category 3 - H336Acute Aquatic Toxicity Category 1 - H400


Hazard Pictograms

Flammable liquids. Category 2 - H225

_____________________________________________________________________________________________Page 1 / 9

_____________________________________________________________________________________________DCA-22001 Revision Date: 09-Feb-2018

Signal Word DANGER

Hazard Statements: H225 - Highly flammable liquid and vaporH315 - Causes skin irritationH318 - Causes serious eye damageH336 - May cause drowsiness or dizzinessH400 - Very toxic to aquatic life


Prevention P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.No smoking.P233 - Keep container tightly closedP240 - Ground and bond container and receiving equipment.P241 - Use explosion-proof electrical/ventilating/lighting/equipmentP242 - Use only non-sparking toolsP243 - Take action to prevent static discharges.P261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP271 - Use only outdoors or in a well-ventilated areaP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protection

Response P302 + P352 - IF ON SKIN: Wash with plenty of water.P332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathingP312 - Call a POISON CENTER/doctor/physician if you feel unwellP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP370 + P378 - In case of fire: Use water spray for extinctionP391 - Collect spillage

Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closedP403 + P235 - Store in a well-ventilated place. Keep coolP405 - Store locked up


ContainsSubstances CAS NumberAlcohols, C12-16, ethoxylated 68551-12-2Isopropanol 67-63-0

Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).

_____________________________________________________________________________________________Page 2 / 9





Alcohols, C12-16, ethoxylated 68551-12-2 30 - 60% Acute Tox. 4 (H302)Skin Irrit. 2 (H315)Eye Corr. 1 (H318)Aquatic Acute 1 (H400)Aquatic Chronic 3 (H412)

Isopropanol 67-63-0 10 - 30% Eye Irrit. 2 (H319)STOT SE 3 (H336)Flam. Liq. 2 (H225)


Description of necessary first aid measures Inhalation If inhaled, move victim to fresh air and seek medical attention.Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.Skin In case of contact, immediately flush skin with plenty of soap and water for at least

15 minutes. Get medical attention. Remove contaminated clothing and launderbefore reuse.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medicalattention.

Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. May cause headache, dizziness, andother central nervous system effects.



Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireMay be ignited by heat, sparks or flames Use water spray to cool fire exposed surfaces. Closed containers may explode in fire.Decomposition in fire may produce harmful gases.




_____________________________________________________________________________________________Page 3 / 9

Use appropriate protective equipment. Remove sources of ignition. Wear self-contained breathing apparatus in enclosed areas.


Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequate ventilation. Evacuate all persons from thearea.


6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Remove ignition sources and work with non-sparking tools. Contain spill with sand or otherinert materials. Scoop up and remove.


7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequateventilation. Wash hands after use. Launder contaminated clothing before reuse. Ground and bond containers when transferringfrom one container to another.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Store between 40.5F (4.7 C) and 120.5 F (49 C). Product has a shelf life of 24 months.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAAlcohols, C12-16, ethoxylated 68551-12-2 Not applicable Not applicableIsopropanol 67-63-0 TWA: 400 ppm

TWA: 983 mg/m3

STEL: 500 ppmSTEL: 1230 mg/m3

TWA: 200 ppmSTEL: 400 ppm

Appropriate engineering controls Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas without

good cross ventilation.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Organic vapor respirator.

Hand Protection Impervious rubber gloves.Skin Protection Rubber apron.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls No information available

_____________________________________________________________________________________________Page 4 / 9




Property Values Remarks/ - Method pH: 6.5 - 7.5Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range 80 °C / 176 °FFlash Point 21.1 °C / 70 °F PMCCEvaporation rate No data availableVapor Pressure 33 mmHg @ 20 CVapor Density No data availableSpecific Gravity 0.96Water Solubility Miscible with waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid Keep away from heat, sparks and flame.10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May cause headache, dizziness, andother central nervous system effects.



Alcohols, C12-16,ethoxylated

68551-12-2 1600 mg/kg No data available No data available

Isopropanol 67-63-0 5840 mg/kg-bw (rat) 12870 mg/kg-bw (rabbit) 72.6 mg/L (Rat, 4h, vapor)

Physical State: Liquid Color Colorless to AmberOdor: Alcohol Odor Threshold:

_____________________________________________________________________________________________Page 5 / 9



Immediate, delayed and chronic health effects from exposure Inhalation May cause respiratory irritation. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,giddiness and unconsciousness.

Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation.Ingestion Irritation of the mouth, throat, and stomach. May cause abdominal pain, vomiting, nausea,

and diarrhea. May cause headache, dizziness, nausea, vomiting, gastrointestinal irritationand central nervous system depression.

Chronic Effects/Carcinogenicity May contain ethylene oxide in the headspace of the drum. Ethylene oxide is acancer and reproductive hazard.


Interactive effects Skin disorders. Eye ailments.


Substances CAS Number Skin corrosion/irritationAlcohols, C12-16,ethoxylated

68551-12-2 Causes skin irritation.

Isopropanol 67-63-0 Non-irritating to the skin (Rabbit)

Substances CAS Number Serious eye damage/irritationAlcohols, C12-16,ethoxylated

68551-12-2 Causes severe eye irritation which may damage tissue.

Isopropanol 67-63-0 Causes moderate eye irritation (Rabbit)

Substances CAS Number Skin SensitizationAlcohols, C12-16,ethoxylated

68551-12-2 Did not cause sensitization on laboratory animals

Isopropanol 67-63-0 Did not cause sensitization on laboratory animals (guinea pig)

Substances CAS Number Respiratory SensitizationAlcohols, C12-16,ethoxylated

68551-12-2 No information available

Isopropanol 67-63-0 No information available

Substances CAS Number Mutagenic EffectsAlcohols, C12-16,ethoxylated

68551-12-2 Not regarded as mutagenic.

Isopropanol 67-63-0 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

Substances CAS Number Carcinogenic EffectsAlcohols, C12-16,ethoxylated

68551-12-2 Not regarded as carcinogenic.

Isopropanol 67-63-0 Did not show carcinogenic effects in animal experiments

Substances CAS Number Reproductive toxicityAlcohols, C12-16,ethoxylated

68551-12-2 Not regarded as a reproductive and developmental toxicant.

Isopropanol 67-63-0 Animal testing did not show any effects on fertility.

Substances CAS Number STOT - single exposureAlcohols, C12-16,ethoxylated

68551-12-2 No significant toxicity observed in animal studies at concentration requiring classification.

Isopropanol 67-63-0 May cause headache, dizziness, and other central nervous system effects.

_____________________________________________________________________________________________Page 6 / 9


Substances CAS Number STOT - repeated exposureAlcohols, C12-16,ethoxylated

68551-12-2 No significant toxicity observed in animal studies at concentration requiring classification.

Isopropanol 67-63-0 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)

Substances CAS Number Aspiration hazardAlcohols, C12-16,ethoxylated

68551-12-2 Not applicable

Isopropanol 67-63-0 Not applicable


Ecotoxicity Product Ecotoxicity DataVery toxic to aquatic organisms.



Alcohols, C12-16,ethoxylated

68551-12-2 EC50 0.7 mg/L(Selenastrum

capricornutum)

No information available No information available 0.39 mg/L (DaphniaMagna)

Isopropanol 67-63-0 EC50 (72h) > 1000 mg/L(Desmodesmus

subspicatus)EC50 (7d) 1800 mg/L

(meanextinctionvalue)(Scenedesmus

quadricauda)

LC50 (96h) 9640 mg/L(Pimephales promelas)LC50 (7d) 7060 mg/L(Poecilia reticulata)

TT (16h) 1050 mg/L(Pseudomonas putida)

EC50 (48 h)=2285 mg/L(Daphnia sp.)

EC50 (24h) > 10,000mg/L (Daphnia magna)


Substances CAS Number Persistence and DegradabilityAlcohols, C12-16, ethoxylated 68551-12-2 No information availableIsopropanol 67-63-0 Readily biodegradable (53% @ 5d)



Alcohols, C12-16, ethoxylated 68551-12-2 No information available

Isopropanol 67-63-0 Not Bioaccumulative; LogPow < 4.5


Substances CAS Number MobilityAlcohols, C12-16, ethoxylated 68551-12-2 No information availableIsopropanol 67-63-0 No information available



Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approvedincinerator according to federal, state, and local regulations.

Disposal of any contaminated packaging Follow all applicable national or local regulations.

_____________________________________________________________________________________________Page 7 / 9





UN Number UN1993UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol)Transport Hazard Class(es): 3,Packing Group: IIIEnvironmental Hazards: Marine Pollutant (Contains Ethoxylated Alcohol)

IMDG/IMO UN Number UN1219UN proper shipping name: Isopropanol MixtureTransport Hazard Class(es): 3Packing Group: IIEnvironmental Hazards: Marine Pollutant (Contains Ethoxylated Alcohols)EMS: EmS F-E, S-E

IATA/ICAO UN Number UN1219UN proper shipping name: Isopropanol MixtureTransport Hazard Class(es): 3Packing Group: IIEnvironmental Hazards: Marine Pollutant (Contains Ethoxylated Alcohol)


HazChem Code 3Y







This product does not comply with EINECS



Poisons Schedule number S5



_____________________________________________________________________________________________Page 8 / 9



Revision Date: 09-Feb-2018


Full text of H-Statements referred to under sections 2 and 3H225 - Highly flammable liquid and vaporH302 - Harmful if swallowedH315 - Causes skin irritationH318 - Causes serious eye damageH319 - Causes serious eye irritationH336 - May cause drowsiness or dizzinessH400 - Very toxic to aquatic lifeH412 - Harmful to aquatic life with long lasting effects




Key literature references and sources for datawww.ChemADVISOR.com/



_____________________________________________________________________________________________Page 9 / 9

MATERIAL SAFETY DATA SHEETProduct Trade Name: GASCON 469

Revision Date: 26-Mar-2014

None

Halliburton Australia Pty. Ltd.15 Marriott RoadJandakotWA 6164Australia

ACN Number: 009 000 775Telephone Number: 61 (08) 9455 8300Fax Number: 61 (08) 9455 5300

Product Emergency TelephoneAustralia: 08-64244950Papua New Guinea: 05 1 281 575 5000NewZealand: 06-7559274

Fire, Police & Ambulance - Emergency TelephoneAustralia: 000Papua New Guinea: 000New Zealand: 111

Statement of Hazardous Nature

Application: Cement Additive

Synonyms: None

Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goodsaccording to the criteria of ADG.

Prepared By Chemical ComplianceTelephone: 1-580-251-4335e-mail: [email protected]

Chemical Family: Blend

3. HAZARDS IDENTIFICATION

UN Number: None

Identification of Substance or Preparation

Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goodsaccording to the criteria of ADG.

Dangerous Goods Class: None

Hazard Overview May cause mild eye irritation. May cause mild skin irritation.

Subsidiary Risk: None

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THECOMPANY/UNDERTAKING

Manufacturer/Supplier

Hazchem Code:

GASCON 469

None

Product Trade Name:

Page 1 of 6

GASCON 469

Poisons Schedule:

Classification None.

Risk Phrases None

Safety PhrasesS24/25 Avoid contact with skin and eyes.

HSNO Classification 6.3B Mildly irritating to the skin

2. COMPOSITION/INFORMATION ON INGREDIENTS

Substance CAS Number Percent Australia NOHSCNew ZealandWES

ACGIH TLV-TWA

Contains no hazardoussubstances

Mixture 60 - 100% Not determined Not determined Not applicable

Non-hazardous Substance to Total of 100%

4. FIRST AID MEASURES

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratoryirritation develops or if breathing becomes difficult.

Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, or suspected contact, immediately flush eyes with plenty ofwater for at least 15 minutes and get medical attention immediately after flushing.

Ingestion Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seekmedical attention. Never give anything by mouth to an unconscious person.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Suitable Extinguishing MediaAll standard fire fighting media

Unsuitable Extinguishing MediaNone known

Special Exposure Hazards Not applicable.

Special Protective Equipmentfor Fire-Fighters

Not applicable.

6. ACCIDENTAL RELEASE MEASURES

Personal PrecautionaryMeasures

Use Appropriate protective equipment.

Environmental PrecautionaryMeasures

None known.

Procedure forCleaning/Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inertmaterials. Scoop up and remove.

GASCON 469Page 2 of 6

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapours.

Storage Information Store in a cool well ventilated area. Keep from excessive heat. Keep fromfreezing. Keep container closed when not in use. Store in non-rusting containers.Product has a shelf life of 12 months

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.

Respiratory Protection Dust/mist respirator. (N95,P2/P3)

Hand Protection Impervious rubber gloves.

Skin Protection Normal work coveralls.

Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.

Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: LiquidColour: TransparentOdour: OdourlesspH: 10Specific Gravity @ 20 C (Water=1): 1.1Density @ 20 C (kg/l): 1.098Bulk Density @ 20 C (kg/l): Not DeterminedBoiling Point/Range (C): 100Freezing Point/Range (C): Not DeterminedPour Point/Range (C): Not DeterminedFlash Point/Range (C): Not DeterminedFlash Point Method: Not DeterminedAutoignition Temperature (C): Not DeterminedFlammability Limits in Air - Lower (g/m3): Not DeterminedFlammability Limits in Air - Lower (%): Not DeterminedFlammability Limits in Air - Upper (g/m3): Not DeterminedFlammability Limits in Air - Upper (%): Not DeterminedVapour Pressure @ 20 C (mmHg): Not DeterminedVapour Density (Air=1): Not DeterminedPercent Volatiles: 80Evaporation Rate (Butyl Acetate = 1): Not determined.Solubility in Water (g/100ml): 10Solubility in Solvents (g/100ml): Not DeterminedVOCs (g/l): Not DeterminedViscosity, Dynamic @ 20 C(centipoise):

Not Determined

Viscosity, Kinematic @ 20 C(centistokes):

Not Determined

Partition Coefficient/n-Octanol/Water: Not DeterminedMolecular Weight (g/mole): Not DeterminedDecomposition Temperature (C): Not Determined

10. STABILITY AND REACTIVITY


Stability Data: Stable

Hazardous Polymerisation: Will Not Occur

Conditions to Avoid None anticipated

Incompatibility (Materials toAvoid)

Strong oxidisers. Strong acids.

Hazardous DecompositionProducts

None known.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Sympotoms related to exposure Acute Toxicity

Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% are chronichealth hazards.

Toxicology data for the components Substance CAS Number LD50 Oral LD50 Dermal LC50 Inhalation

Contains no hazardoussubstances

Mixture No data available No data available No data available

12. ECOLOGICAL INFORMATION

Ecotoxicological Information

Ecotoxicity Product Acute Fish Toxicity: Not determinedAcute Crustaceans Toxicity: Not determinedAcute Algae Toxicity: Not determined

Ecotoxicity Substance Substance CAS Number Toxicity to Algae Toxicity to Fish Toxicity to


Contains nohazardous substances

Mixture No information available No information available No information available No information available

12.2 Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.

12.3 Bioaccumulative potential Does not bioaccumulate

12.4 Mobility in soil No information available


12.5 Results of PBT and vPvB assessment No information available.

12.6 Other adverse effects

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state and local regulations.Incineration recommended in approved incinerator according to federal, state, andlocal regulations. Substance should NOT be deposited into a sewage facility.

Contaminated Packaging Follow all applicable national or local regulations. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, ortreating packaging to remove residual contents, or treating packaging to makesure the residual contents are no longer hazardous, or by disposing of packaginginto commercial waste collection.

14. TRANSPORT INFORMATION

Land Transportation

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

Chemical Inventories

Australian AICS Inventory All components listed.New Zealand Inventory ofChemicals

All components listed.

US TSCA Inventory All components listed.EINECS Inventory All components are listed on the inventory.

Classification Not DeterminedRisk Phrases Not determined

Safety PhrasesS24/25 Avoid contact with skin and eyes.

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS:Not applicable


Contact

Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100

New Zealand National Poisons Centre0800 764 766

Additional Information For additional information on the use of this product, contact your local Halliburtonrepresentative.

For questions about the Material Safety Data Sheet for this or other Halliburtonproducts, contact Product Stewardship at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as toaccuracy or completeness. The information is obtained from various sourcesincluding the manufacturer and other third party sources. The information may notbe valid under all conditions nor if this material is used in combination with othermaterials or in any process. Final determination of suitability of any material is thesole responsibility of the user.

***END OF MSDS***


SAFETY DATA SHEET

HALAD® 344 CEMENT ADDITIVERevision Date: 07-Mar-2016 Revision Number: 34


Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.

1.1. Product Identifier Product Name HALAD® 344 CEMENT ADDITIVE

Other means of Identification Synonyms NoneProduct Code: HM000816

Recommended use of the chemical and restrictions on use Recommended Use Fluid Loss Additive

Uses advised against No information available









Classification of the hazardous chemical Not classified


Hazard pictograms

_____________________________________________________________________________________________Page 1 / 7

_____________________________________________________________________________________________HALAD® 344 CEMENT ADDITIVE Revision Date: 07-Mar-2016

Signal Word Not Hazardous

Hazard Statements Not Classified


Prevention NoneResponse NoneStorage NoneDisposal None

ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority

NA





Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority

NA 60 - 100% Not Applicable



irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Symptoms caused by exposure No significant hazards expected.




Specific hazards arising from the chemical

_____________________________________________________________________________________________Page 2 / 7

Special exposure hazards in a fireDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in high


concentrations. Good housekeeping practices are required to minimize this potential.



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.


6.3. Methods and material for containment and cleaning up Scoop up and remove.


7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool, dry location. Store away from oxidizers. Keep container closed when not in use. Product has a shelf life of 60months.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority

NA Not applicable Not applicable

Appropriate engineering controls Engineering Controls Use in a well ventilated area.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)

Hand Protection None known.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.

_____________________________________________________________________________________________Page 3 / 7


Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range -8 °CMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.37Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information Molecular Weight > 600VOC Content (%) No data available


10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials None known.10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide. Oxides of sulfur.



Symptoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.



Physical State: Powder Color White to off whiteOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 7




Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority

NA No data available No data available No data available

Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact Non-irritating to rabbit's eyeSkin Contact Not irritating to skin in rabbits.Ingestion No adverse health effects are expected from swallowing.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.


Interactive effects None known.






Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority

NA No information available No information available No information available No information available

12.2. Persistence and degradability Not readily biodegradableSubstances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority

NA No information available


_____________________________________________________________________________________________Page 5 / 7




Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority



Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority




Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Substance should NOT be deposited into a sewagefacility.




Transportation Information UN Number Not restrictedUN proper shipping name Not restrictedTransport Hazard Class(es) Not applicablePacking Group: Not applicableEnvironmental Hazards Not applicable







All components are listed on the AICS or are subject to a relevant exemption, permit, orassessment certificate.


This product does not comply with EINECS



_____________________________________________________________________________________________Page 6 / 7

Poisons Schedule number


None Allocated




Revision Date: 07-Mar-2016


Full text of H-Statements referred to under sections 2 and 3None







_____________________________________________________________________________________________Page 7 / 7

MATERIAL SAFETY DATA SHEET

Product Trade Name: HALAD® 413L CEMENT ADDITIVERevision Date: 02-May-20131. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING

Statement of Hazardous Nature Non-Hazardous according to the criteria of NOHSC, Non-Dangerous Goodsaccording to the criteria of ADG.

Manufacturer/Supplier Halliburton Australia Pty. Ltd.15 Marriott RoadJandakotWA 6164Australia


Product Emergency TelephoneAustralia: 08-64244950Papua New Guinea: 05 1 281 575 5000NewZealand: 06-7559274


Identification of Substance or Preparation

Product Trade Name: HALAD® 413L CEMENT ADDITIVESynonyms: NoneChemical Family: PolymerUN Number: NoneDangerous Goods Class: NoneSubsidiary Risk: NoneHazchem Code: NonePoisons Schedule: NoneApplication: Fluid Loss Additive

Prepared By Chemical ComplianceTelephone: 1-580-251-4335e-mail: [email protected]

2. COMPOSITION/INFORMATION ON INGREDIENTS

Substance CAS Number Percent AustraliaNOHSC

New ZealandWES

ACGIH TLV-TWA

Acrylic polymer Proprietary 10 - 30% Not determined Not determined Not applicable

HALAD® 413L CEMENT ADDITIVEPage 1 of 6

Non-hazardous Substance to Total of 100%

3. HAZARDS IDENTIFICATION

Hazard Overview No significant hazards expected.

Risk Phrases None

HSNO Classification Non-hazardous

4. FIRST AID MEASURES


Skin Wash with soap and water. Get medical attention if irritation persists.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutesand get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Notes to Physician Not Applicable

5. FIRE FIGHTING MEASURES

Suitable Extinguishing Media All standard fire fighting media

Unsuitable Extinguishing Media None known

Special Exposure Hazards Decomposition in fire may produce toxic gases.

Special Protective Equipment forFire-Fighters

Full protective clothing and approved self-contained breathing apparatus required forfire fighting personnel.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautionary MeasuresUse Appropriate protective equipment.

Environmental PrecautionaryMeasures

None known.

Procedure forCleaning/Absorption

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials.Scoop up and remove.

7. HANDLING AND STORAGE

Handling Precautions Avoid contact with eyes, skin, or clothing.

Storage Information Store away from oxidisers. Product has a shelf life of 24 months

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls Use in a well ventilated area.


Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, EuropeanStandard EN 149, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, shouldbe performed by an Industrial Hygienist or other qualified professional.

Not normally needed. But if significant exposures are possible then the followingrespirator is recommended. Dust/mist respirator. (N95,P2/P3)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: LiquidColour: Brown-blackOdour: SweetpH: 7.5Specific Gravity @ 20 C (Water=1): 1.1Density @ 20 C (kg/l): 1.098Bulk Density @ 20 C (kg/l): Not DeterminedBoiling Point/Range (C): Not DeterminedFreezing Point/Range (C): Not DeterminedPour Point/Range (C): Not DeterminedFlash Point/Range (C): Not DeterminedFlash Point Method: Not DeterminedAutoignition Temperature (C): Not DeterminedFlammability Limits in Air - Lower (g/m3): Not DeterminedFlammability Limits in Air - Lower (%): Not DeterminedFlammability Limits in Air - Upper (g/m3): Not DeterminedFlammability Limits in Air - Upper (%): Not DeterminedVapour Pressure @ 20 C (mmHg): Not DeterminedVapour Density (Air=1): Not DeterminedPercent Volatiles: Not DeterminedEvaporation Rate (Butyl Acetate = 1): Not determined.Solubility in Water (g/100ml): MiscibleSolubility in Solvents (g/100ml): Not DeterminedVOCs (g/l): Not DeterminedViscosity, Dynamic @ 20 C(centipoise):

Not Determined

Viscosity, Kinematic @ 20 C(centistokes):

Not Determined

Partition Coefficient/n-Octanol/Water: Not DeterminedMolecular Weight (g/mole): Not DeterminedDecomposition Temperature (C): Not Determined

10. STABILITY AND REACTIVITY

Stability Data: Stable

Hazardous Polymerisation: Will Not Occur

Conditions to Avoid None anticipated


Incompatibility (Materials toAvoid)

Strong oxidisers.

Hazardous DecompositionProducts

Oxides of nitrogen. Carbon monoxide and carbon dioxide.

Additional Guidelines Not Applicable

11. TOXICOLOGICAL INFORMATION

Principle Route of Exposure Eye or skin contact, inhalation.

Sympotoms related to exposureInhalation None known.

Skin Contact None known.

Eye Contact None known.

Ingestion None known

Aggravated Medical Conditions None known.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 1% arechronic health hazards.

Other Information None known.

Toxicity Tests

Oral Toxicity: LD50: > 5000 mg/kg (Rat)

Dermal Toxicity: LD50: > 2000 mg/kg (Rabbit)

Inhalation Toxicity: Not determined

Primary Irritation Effect: Draize Rating (Skin): 0.09/8.0 (Rabbit) Practically Non-irritating

Carcinogenicity: Not determined

Genotoxicity: Not determined

Reproductive/DevelopmentalToxicity:

Not determined

12. ECOLOGICAL INFORMATION

Mobility (Water/Soil/Air) Not determined

Persistence/Degradability Slowly biodegradable

Bio-accumulation Not Determined

Ecotoxicological Information

Acute Fish Toxicity: Not determinedAcute Crustaceans Toxicity:Not determinedAcute Algae Toxicity: Not determined

Chemical Fate Information Not determined


Other Information Not applicable

13. DISPOSAL CONSIDERATIONS

Disposal Method Disposal should be made in accordance with federal, state and local regulations.

Contaminated Packaging Follow all applicable national or local regulations.

14. TRANSPORT INFORMATION

Land Transportation

ADR Not restricted

Air Transportation

ICAO/IATA Not restricted

Sea Transportation

IMDG Not restricted

Other Shipping Information

Labels: None

15. REGULATORY INFORMATION

Chemical Inventories

Australian AICS Inventory Product contains one or more components not listed on inventory.New Zealand Inventory ofChemicals


US TSCA Inventory All components listed.EINECS Inventory One or more components not listed on the inventory.

Classification Not Determined

Risk Phrases None

Safety Phrases None

16. OTHER INFORMATION

The following sections have been revised since the last issue of this MSDS:Not applicable


Contact


New Zealand National Poisons Centre0800 764 766

Additional Information For additional information on the use of this product, contact your local Halliburtonrepresentative.

For questions about the Material Safety Data Sheet for this or other Halliburtonproducts, contact Product Stewardship at 1-580-251-4335.

Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracyor completeness. The information is obtained from various sources including themanufacturer and other third party sources. The information may not be valid underall conditions nor if this material is used in combination with other materials or in anyprocess. Final determination of suitability of any material is the sole responsibility ofthe user.

***END OF MSDS***


SAFETY DATA SHEET

HR-6L



1.1. Product Identifier Product Name HR-6L

Other means of Identification Synonyms: NoneProduct Code: HM000901

Recommended use of the chemical and restrictions on use Recommended Use Cement RetarderUses Advised Against No information available




E-Mail address: [email protected]







Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8

Revision Date: 29-Jan-2015 Revision Number: 13

_____________________________________________________________________________________________



Prevention None

Response None

Storage None

Disposal None


NA

Other hazards which do not result in classification None known

Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16

Classification Not ClassifiedRisk Phrases None








minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Under normal conditions, first aid procedures are not required.





_____________________________________________________________________________________________Page 2 / 8

HR-6L Revision Date: 24-Feb-2015

_____________________________________________________________________________________________Specific hazards arising from the chemical Special Exposure HazardsDecomposition in fire may produce harmful gases.

Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.


6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.


7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep container closed when not in use.Other GuidelinesNo information available





Personal protective equipment (PPE) Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available



_____________________________________________________________________________________________Page 3 / 8

Revision Date: 24-Feb-2015HR-6L

_____________________________________________________________________________________________

Property Values Remarks/ - Method pH: 9.5Freezing Point/Range No data availableMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point > 98 °C / > 210 °F PMCCEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.21Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data availableLiquid Density 10.08 lbs/gal


10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong oxidizers.10.6. Hazardous Decomposition Products Oxides of sulfur. Carbon monoxide and carbon dioxide.



Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.






_____________________________________________________________________________________________Page 4 / 8

Odor Threshold: No information availablePhysical State: Liquid Color: Dark brown

HR-6L

Odor: Molasses


_____________________________________________________________________________________________

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact None known.Ingestion None known.





Substances CAS Number Skin corrosion/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable.

Substances CAS Number Eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable.

Substances CAS Number Skin SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Respiratory SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Mutagenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Reproductive toxicityContains no hazardoussubstances inconcentrations above cut-off

NA Not applicable

_____________________________________________________________________________________________Page 5 / 8


_____________________________________________________________________________________________values according to thecompetent authority

Substances CAS Number STOT - single exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number STOT - repeated exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Aspiration hazardContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable








Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority










_____________________________________________________________________________________________Page 6 / 8


_____________________________________________________________________________________________


Safe handling and disposal methods This product is not regarded as hazardous waste. Dispose in accordance with local regulations.




Transportation Information UN Number: Not restrictedUN Proper Shipping Name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable





International Inventories Australian AICS Inventory All components listed on inventory or are exempt.New Zealand Inventory ofChemicals


EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.Canadian DSL Inventory All components listed on inventory or are exempt.




Revision Date: 29-Jan-2015


Full text of R-phrases referred to under Sections 2 and 3None



_____________________________________________________________________________________________Page 7 / 8


_____________________________________________________________________________________________For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.

Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day




_____________________________________________________________________________________________Page 8 / 8


SAFETY DATA SHEET

LATEX 2000Revision Date: 20-Jun-2016 Revision Number: 17



1.1. Product Identifier Product Name LATEX 2000


Recommended use of the chemical and restrictions on use Recommended Use AdditiveUses advised against No information available











Hazard pictograms


_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________LATEX 2000 Revision Date: 20-Jun-2016

Hazard Statements: Not Classified




NA










minutes and get medical attention if irritation persists.Skin Wash with soap and water.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.






Special protective equipment and precautions for fire fighters

_____________________________________________________________________________________________Page 2 / 8

Special protective equipment for firefighters


Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool well ventilated area. Keep container closed when not in use. Product has a shelf life of 24 months.Other GuidelinesNo information available








Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.

Hand Protection Normal work gloves.Skin Protection Rubber apron.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls No information available

_____________________________________________________________________________________________Page 3 / 8




Property Values Remarks/ - Method pH: 8.5-10Freezing Point / Range 0 °CMelting Point / Range No data availableBoiling Point / Range 100 °C / 212 °FFlash Point No data availableEvaporation rate < 1Vapor Pressure 17Vapor Density < 1Specific Gravity 1Water Solubility DispersibleSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information Molecular Weight > 600 g/moleVOC Content (%) 46-48Liquid Density 8.33 lbs/gallon


10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Styrene. 1,3-Butadiene.







Contains no hazardoussubstances inconcentrations above


Physical State: Liquid Color Milky whiteOdor: Ammonia Odor Threshold:

_____________________________________________________________________________________________Page 4 / 8



cut-off values accordingto the competentauthority

Immediate, delayed and chronic health effects from exposure Inhalation Vapors given off by heated product may be harmful.Eye Contact May cause mild eye irritation.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.



Interactive effects Lung disorders.




Substances CAS Number Serious eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority










Substances CAS Number Reproductive toxicity

_____________________________________________________________________________________________Page 5 / 8


Contains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority







NA

















_____________________________________________________________________________________________Page 6 / 8



Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors


Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.





















_____________________________________________________________________________________________Page 7 / 8










_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

LATEX 3000Revision Date: 17-Feb-2016 Revision Number: 15



1.1. Product Identifier Product Name LATEX 3000

Other means of Identification Synonyms NoneProduct Code: HM006737

Recommended use of the chemical and restrictions on use Recommended Use Fluid Loss Additive

Uses advised against No information available











Hazard pictograms

_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________LATEX 3000 Revision Date: 17-Feb-2016




Prevention None

Response None

Storage None

Disposal None


NA











minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent

aspiration. Rinse mouth. Never give anything by mouth to an unconscious person.




Suitable extinguishing equipment

_____________________________________________________________________________________________Page 2 / 8

Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.



Specific hazards arising from the chemical Special exposure hazards in a fireUse water spray to cool fire exposed surfaces. Closed containers may explode in fire. Decomposition in fire may produce harmfulgases.



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Avoid breathing mist. Ensure adequate ventilation. Material isslippery underfoot. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool well ventilated area. Keep container closed when not in use.Other GuidelinesNo information available




Appropriate engineering controls Engineering Controls Trace amounts of monomers may be released during use of this material. Use in a well

ventilated area. Local exhaust ventilation should be used in areas without good crossventilation.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN

_____________________________________________________________________________________________Page 3 / 8


149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Not normally necessary.

Hand Protection None known.Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: 6.0 - 7.5Freezing Point / Range 0 °CMelting Point / Range No data availableBoiling Point / Range 100 °C / 212 °FFlash Point No data availableEvaporation rate < 1Vapor Pressure 17Vapor Density <1Specific Gravity 1.03Water Solubility Miscible with waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information Molecular Weight > 600VOC Content (%) 46-48 (0.0003 lbs/gal)Liquid Density 8.61 lbs/gal


10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products 1,3-Butadiene. Styrene.


Information on routes of exposure Principle Route of Exposure Eye and skin contact.

Physical State: Liquid Color Milky whiteOdor: Mild Odor Threshold:

_____________________________________________________________________________________________Page 4 / 8









Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation Not a likely route of exposure.Eye Contact May cause mild eye irritation.Skin Contact Prolonged or repeated contact may cause slight skin irritation.Ingestion No adverse health effects are expected from swallowing.











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Transportation Information UN Number Not restrictedUN proper shipping name Not restrictedTransport Hazard Class(es) Not applicablePacking Group: Not applicableEnvironmental Hazards Not applicable





International Inventories Australian AICS Inventory Product contains one or more components not listed on inventory.New Zealand Inventory ofChemicals


EINECS (European Inventory of This product, and all its components, complies with EINECS

_____________________________________________________________________________________________Page 6 / 8


Existing Chemical Substances)US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)

Product contains one or more components not listed on the inventory.













_____________________________________________________________________________________________Page 7 / 8




_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

MICROBOND MRevision Date: 09-Feb-2016 Revision Number: 28



1.1. Product Identifier Product Name MICROBOND M


Recommended use of the chemical and restrictions on use Recommended Use Cement AdditiveUses Advised Against No information available









Classification of the hazardous chemical Serious Eye Damage / Eye Irritation Category 1 - H318Carcinogenicity Category 2 - H351Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373


Hazard Pictograms

_____________________________________________________________________________________________Page 1 / 9

_____________________________________________________________________________________________MICROBOND M Revision Date: 09-Feb-2016

Signal Word Danger

Hazard Statements H318 - Causes serious eye damageH351 - Suspected of causing cancerH373 - May cause damage to organs through prolonged or repeated exposure


Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/eye protection/face protection

Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell

Storage P405 - Store locked up


ContainsSubstances CAS NumberCalcium oxide 1305-78-8Crystalline silica, quartz 14808-60-7



Classification Xn - Harmful.

Risk Phrases R41 Risk of serious damage to eyes.R45 May cause cancer.R48/20 Harmful: danger of serious damage to health by prolonged exposurethrough inhalation.



Calcium oxide 1305-78-8 1 - 5% Skin Irrit. 2 (H315)Eye Corr. 1 (H318)STOT SE 3 (H335)

Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 2 (H351)

_____________________________________________________________________________________________Page 2 / 9


STOT RE 1 (H372)



irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Under normal conditions, first aid procedures are not required.

Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Breathing crystalline silica can cause lung disease, includingsilicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.




Specific hazards arising from the chemical Special Exposure HazardsNot applicable.







7.1. Precautions for Safe Handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits.Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery whenwet.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

_____________________________________________________________________________________________Page 3 / 9


7.2. Conditions for safe storage, including any incompatibilities Storage InformationUse good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuseempty container.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWACalcium oxide 1305-78-8 TWA: 2 mg/m3 TWA: 2 mg/m3









Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls No information available



Property Values Remarks/ - Method pH: 10.5Freezing Point/Range No data availableMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 3.6Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

Physical State: Solid Color: Light to medium brownOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 9





10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Hydrofluoric acid.

10.6. Hazardous Decomposition Products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Breathing crystalline silica can cause lung disease, includingsilicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.




Calcium oxide 1305-78-8 > 2000 mg/kg (Rat) > 2500 mg/kg No data available

Crystalline silica, quartz 14808-60-7 >15,000 mg/kg (Human) No data available No data available



Breathing silica dust may cause irritation of the nose, throat, and respiratory passages.Breathing silica dust may not cause noticeable injury or illness even though permanent lungdamage may be occurring. Inhalation of dust may also have serious chronic health effects(See "Chronic Effects/Carcinogenicity" subsection below).

Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact May cause mild skin irritation.Ingestion None known.


Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic to

_____________________________________________________________________________________________Page 5 / 9


humans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.




Substances CAS Number Skin corrosion/irritationCalcium oxide 1305-78-8 Extremely corrosive and destructive to tissueCrystalline silica, quartz 14808-60-7 Non-irritating to the skin

Substances CAS Number Eye damage/irritationCalcium oxide 1305-78-8 Causes eye burns. (Rabbit)Crystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible.

Substances CAS Number Skin SensitizationCalcium oxide 1305-78-8 Patch test on human volunteers did not demonstrate sensitization propertiesCrystalline silica, quartz 14808-60-7 No information available.

Substances CAS Number Respiratory SensitizationCalcium oxide 1305-78-8 No information availableCrystalline silica, quartz 14808-60-7 No information available

Substances CAS Number Mutagenic EffectsCalcium oxide 1305-78-8 In vitro tests did not show mutagenic effects.Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.

Substances CAS Number Carcinogenic EffectsCalcium oxide 1305-78-8 Did not show carcinogenic effects in animal experiments (similar substances)Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The

IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.

Substances CAS Number Reproductive toxicityCalcium oxide 1305-78-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal

experiments.Crystalline silica, quartz 14808-60-7 No information available

Substances CAS Number STOT - single exposureCalcium oxide 1305-78-8 May cause respiratory irritation.Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.

_____________________________________________________________________________________________Page 6 / 9


Substances CAS Number STOT - repeated exposureCalcium oxide 1305-78-8 None under normal use conditionsCrystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)

Substances CAS Number Aspiration hazardCalcium oxide 1305-78-8 Not applicableCrystalline silica, quartz 14808-60-7 Not applicable





Calcium oxide 1305-78-8 EC50 (72h) 184.57 mg/L(Pseudokirchnerellasubcapitata) (similar

substance)

LC50 33.884 mg/L(Clarias gariepinus)

LC50 (96h) 1070 mg/L(Cyprinus carpio)

NOEC (46d) 100 mg/L(Tilapia nilotica)

EC50 (3h) 300.4 mg/L(activated sludge) (similar

substances)

EC50 (48h) 49.1 mg/L(Daphnia magna) (similar

substance)LC50 (96h) 158 mg/L

(Crangon septemspinosa)(similar substance)

NOEC (14d) 32 mg/L(Crangon septemspinosa)

(similar substance)LC50 (14d) 53.1 mg/L



14808-60-7 No information available LL0 (96h) 10,000 mg/L(Danio rerio) (similar

substance)

No information available LL50 (24h) > 10,000 mg/L(Daphnia magna) (similar

substance)


Substances CAS Number Persistence and DegradabilityCalcium oxide 1305-78-8 The methods for determining biodegradability are





Calcium oxide 1305-78-8 Log Kow = -0.571BCF = 0.5



Substances CAS Number MobilityCalcium oxide 1305-78-8 No information availableCrystalline silica, quartz 14808-60-7 No information available



Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.

_____________________________________________________________________________________________Page 7 / 9



















Revision Note

Full text of R-phrases referred to under Sections 2 and 3R41 Risk of serious damage to eyes.R45 May cause cancer.R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

_____________________________________________________________________________________________Page 8 / 9

Full text of H-Statements referred to under sections 2 and 3H315 - Causes skin irritationH318 - Causes serious eye damage


H335 - May cause respiratory irritationH351 - Suspected of causing cancer if inhaledH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled







_____________________________________________________________________________________________Page 9 / 9

SAFETY DATA SHEET

NF-6Revision Date: 16-Aug-2016 Revision Number: 28



1.1. Product Identifier Product Name NF-6


Recommended use of the chemical and restrictions on use Recommended Use DefoamerUses advised against No information available










Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016





NA











attention.




Suitable extinguishing equipment Suitable Extinguishing MediaCarbon dioxide, dry chemical, foam.Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireUse water spray to cool fire exposed surfaces. Decomposition in fire may produce harmful gases.

_____________________________________________________________________________________________Page 2 / 8

Special protective equipment and precautions for fire fighters


Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.






7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep container closed when not in use.Other GuidelinesNo information available




Appropriate engineering controls Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used in

areas without good cross ventilation.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Organic vapor respirator with a dust/mist filter. (A2P2/P3)

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact(recommended: protection index 6, corresponding to > 480 minutes permeation time as perEN 374): Polyvinylchloride gloves. (>= 0.7 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerably shorter

_____________________________________________________________________________________________Page 3 / 8


than the permeation time determined in accordance with EN 374 as a result of the manyinfluencing factors (e.g. temperature). If signs of wear and tear are noticed then the glovesshould be replaced. Manufacturer's directions for use should be observed because of greatdiversity of types.

Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range 182 °C / 360 °FFlash Point > 170 °C / > 340 °FEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 0.93Water Solubility DispersibleSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 385 °C / 725 °FDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data availableLiquid Density 7.70 lbs/gal


10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Hydrocarbons. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/Effects

Physical State: Liquid Color YellowOdor: Mild Odor Threshold:

_____________________________________________________________________________________________Page 4 / 8



No significant hazards expected.






Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause mild respiratory irritation.Eye Contact None known.Skin Contact None known.Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.






Ecotoxicity Product Ecotoxicity Data






_____________________________________________________________________________________________Page 5 / 8













Safe handling and disposal methods Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT bedeposited into a sewage facility.








_____________________________________________________________________________________________Page 6 / 8

Special precautions during transport


None















Revision Date: 16-Aug-2016





Key abreviations or acronyms used

_____________________________________________________________________________________________Page 7 / 8

bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per million


STEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDCosmetic Ingredient Review



_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

PhenoSealRevision Date: 14-Feb-2017 Revision Number: 13



1.1. Product Identifier Product Name PhenoSeal


Recommended use of the chemical and restrictions on use Recommended Use Lost Circulation MaterialUses advised against No information available

Supplier's name, address and phone number Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.









Hazard Pictograms



_____________________________________________________________________________________________Page 1 / 7

_____________________________________________________________________________________________PhenoSeal Revision Date: 14-Feb-2017




NA

















_____________________________________________________________________________________________Page 2 / 7



6.1. Personal precautions, protective equipment and emergency procedures Avoid creating and breathing dust.




7.1. Precautions for safe handling Handling PrecautionsAvoid creating or inhaling dust.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a dry location. Product has a shelf life of 60 months.Other GuidelinesNo information available




Appropriate engineering controls Engineering Controls None known.



Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Safety glasses.Other Precautions None known.Environmental Exposure Controls No information available



Property Values Remarks/ - Method

Physical State: Flake Color VariableOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 3 / 7



pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.3Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data availableBulk Density 29 lbs/ft3 @ 20 C


10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Carbon monoxide and carbon dioxide.









Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact May cause mechanical irritation to eye.Skin Contact None known.

_____________________________________________________________________________________________Page 4 / 7


Ingestion None known.






Ecotoxicity
















_____________________________________________________________________________________________Page 5 / 7























_____________________________________________________________________________________________Page 6 / 7

International Agreements


Montreal Protocol - Ozone Depleting Substances: Does not applyStockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply












_____________________________________________________________________________________________Page 7 / 7

SAFETY DATA SHEET

POZMIX® ARevision Date: 21-Jun-2016 Revision Number: 20



1.1. Product Identifier Product Name POZMIX® A


Recommended use of the chemical and restrictions on use Recommended Use Cement AdditiveUses advised against No information available









Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318Carcinogenicity Category 2 - H351Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373


Hazard pictograms

_____________________________________________________________________________________________Page 1 / 10

_____________________________________________________________________________________________POZMIX® A Revision Date: 21-Jun-2016

Signal Word Danger

Hazard Statements: H315 - Causes skin irritationH318 - Causes serious eye damageH351 - Suspected of causing cancer if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled


Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP264 - Wash face, hands and any exposed skin thoroughly after handlingP280 - Wear protective gloves/eye protection/face protectionP281 - Use personal protective equipment as required

Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell



ContainsSubstances CAS NumberCalcium oxide 1305-78-8Crystalline silica, quartz 14808-60-7Crystalline silica, cristobalite 14464-46-1





Calcium oxide 1305-78-8 10 - 30% Skin Irrit. 2 (H315)Eye Corr. 1 (H318)STOT SE 3 (H335)


Crystalline silica, cristobalite 14464-46-1 1 - 5% Carc. 2 (H351)STOT RE 1 (H372)

_____________________________________________________________________________________________Page 2 / 10





minutes. Remove contact lenses after the first 5 minutes and continue washing.Seek immediate medical attention/advice. Suitable emergency eye wash facilityshould be immediately available

Skin In case of contact, immediately flush skin with plenty of soap and water for at least30 minutes and remove contaminated clothing, shoes and leather goodsimmediately. Get medical attention immediately.


Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. Breathing crystalline silica can causelung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma andkidney disease.



Suitable extinguishing equipment Suitable Extinguishing MediaNone - does not burn.Extinguishing media which must not be used for safety reasonsNone known.









_____________________________________________________________________________________________Page 3 / 10

Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits.Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery when


wet.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool, dry location. Store in a well ventilated area. Store locked up. Use good housekeeping in storage and work areas toprevent accumulation of dust. Close container when not in use. Product has a shelf life of 36 months.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWACalcium oxide 1305-78-8 TWA: 2 mg/m3 TWA: 2 mg/m3


Crystalline silica, cristobalite 14464-46-1 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3





Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.

Hand Protection Use gloves which are suitable for the chemicals present in this product as well as otherenvironmental factors in the workplace.

Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain jacket,pants or coverall, as appropriate, to prevent skin contact.

Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls No information available



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 2.3Water Solubility Insoluble in water

Physical State: Solid Color Gray to blackOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 10



Solubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Hydrofluoric acid.

10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C).



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. Breathing crystalline silica can causelung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma andkidney disease.




Calcium oxide 1305-78-8 > 2000 mg/kg (Rat) > 2500 mg/kg No data available


Crystalline silica,cristobalite

14464-46-1 >15,000 mg/kg (Human) No data available No data available




Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes moderate skin irritation.Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.

_____________________________________________________________________________________________Page 5 / 10



Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidencethat breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.




Substances CAS Number Skin corrosion/irritationCalcium oxide 1305-78-8 Extremely corrosive and destructive to tissueCrystalline silica, quartz 14808-60-7 Non-irritating to the skinCrystalline silica, cristobalite 14464-46-1 Non-irritating to the skin

Substances CAS Number Serious eye damage/irritationCalcium oxide 1305-78-8 Causes eye burns (Rabbit)Crystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible. No information availableCrystalline silica, cristobalite 14464-46-1 Mechanical irritation of the eyes is possible.

Substances CAS Number Skin SensitizationCalcium oxide 1305-78-8 Patch test on human volunteers did not demonstrate sensitization propertiesCrystalline silica, quartz 14808-60-7 No information available.Crystalline silica, cristobalite 14464-46-1 No information available

Substances CAS Number Respiratory SensitizationCalcium oxide 1305-78-8 No information availableCrystalline silica, quartz 14808-60-7 No information availableCrystalline silica, cristobalite 14464-46-1 No information available

Substances CAS Number Mutagenic EffectsCalcium oxide 1305-78-8 In vitro tests did not show mutagenic effects.Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic.Crystalline silica, cristobalite 14464-46-1 Not regarded as mutagenic.

Substances CAS Number Carcinogenic Effects

_____________________________________________________________________________________________Page 6 / 10


Calcium oxide 1305-78-8 Did not show carcinogenic effects in animal experiments (similar substances)Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The


Crystalline silica, cristobalite 14464-46-1 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.

Substances CAS Number Reproductive toxicityCalcium oxide 1305-78-8 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal

experiments.Crystalline silica, quartz 14808-60-7 No information availableCrystalline silica, cristobalite 14464-46-1 No information available

Substances CAS Number STOT - single exposureCalcium oxide 1305-78-8 May cause respiratory irritation.Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.Crystalline silica, cristobalite 14464-46-1 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposureCalcium oxide 1305-78-8 None under normal use conditionsCrystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)Crystalline silica, cristobalite 14464-46-1 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)

Substances CAS Number Aspiration hazardCalcium oxide 1305-78-8 Not applicableCrystalline silica, quartz 14808-60-7 Not applicableCrystalline silica, cristobalite 14464-46-1 Not applicable





Calcium oxide 1305-78-8 EC50 (72h) 184.57 mg/L(Pseudokirchnerellasubcapitata) (similar

substance)

LC50 33.884 mg/L(Clarias gariepinus)

LC50 (96h) 1070 mg/L(Cyprinus carpio)

NOEC (46d) 100 mg/L(Tilapia nilotica)

EC50 (3h) 300.4 mg/L(activated sludge) (similar

substances)

EC50 (48h) 49.1 mg/L(Daphnia magna) (similar

substance)LC50 (96h) 158 mg/L


NOEC (14d) 32 mg/L(Crangon septemspinosa)

(similar substance)LC50 (14d) 53.1 mg/L




capricornutum)





substance)


substance)


Substances CAS Number Persistence and DegradabilityCalcium oxide 1305-78-8 The methods for determining biodegradability are

_____________________________________________________________________________________________Page 7 / 10



not applicable to inorganic substances.Crystalline silica, cristobalite 14464-46-1 The methods for determining biodegradability are




Calcium oxide 1305-78-8 Log Kow = -0.571BCF = 0.5


Crystalline silica, cristobalite 14464-46-1 No information available


Substances CAS Number MobilityCalcium oxide 1305-78-8 No information availableCrystalline silica, quartz 14808-60-7 No information availableCrystalline silica, cristobalite 14464-46-1 No information available













assessment certificate.

_____________________________________________________________________________________________Page 8 / 10


New Zealand Inventory ofChemicals












Full text of H-Statements referred to under sections 2 and 3H315 - Causes skin irritationH318 - Causes serious eye damageH335 - May cause respiratory irritationH351 - Suspected of causing cancer if inhaledH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled




_____________________________________________________________________________________________Page 9 / 10

bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day





_____________________________________________________________________________________________Page 10 / 10

SAFETY DATA SHEET

SCR-100L



1.1. Product Identifier Product Name SCR-100L


Recommended use of the chemical and restrictions on use Recommended Use RetarderUses Advised Against No information available











Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8

Revision Date: 21-Sep-2015 Revision Number: 32

_____________________________________________________________________________________________



Prevention None

Response None

Storage None

Disposal None


NA










irritation develops or if breathing becomes difficult.Eyes Immediately flush eyes with large amounts of water for at least 15 minutes. Get

immediate medical attention.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.




Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasons

_____________________________________________________________________________________________Page 2 / 8

Revision Date: 21-Sep-2015SCR-100L

_____________________________________________________________________________________________None known.

Specific hazards arising from the chemical Special Exposure HazardsDecomposition in fire may produce harmful gases.







7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a dry location. Keep container closed when not in use.Other GuidelinesNo information available





Personal protective equipment (PPE) Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator

is recommended:Dust/mist respirator. (N95, P2/P3)

Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system

_____________________________________________________________________________________________Page 3 / 8

SCR-100L Revision Date: 21-Sep-2015

_____________________________________________________________________________________________



Property Values Remarks/ - Method pH: 3 - 4 (28%)Freezing Point/Range -4 °CMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point > 93 °C / > 200 °F PMCCEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.16Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 520 °CDecomposition Temperature No data availableViscosity 15-30 cP @ 25°CExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) ~60%Liquid Density 9.66


10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong oxidizers.10.6. Hazardous Decomposition Products Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.







Contains no hazardoussubstances in


_____________________________________________________________________________________________Page 4 / 8

Odor Threshold: No information availablePhysical State: Liquid

Revision Date: 21-Sep-2015

Color: BlueOdor: Odorless

SCR-100L

_____________________________________________________________________________________________concentrations abovecut-off values accordingto the competentauthority

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact May cause mild skin irritation.Ingestion Irritation of the mouth, throat, and stomach.



Interactive effects Skin disorders.



NA Not applicable.

Substances CAS Number Eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable.


NA Not applicable


NA Not applicable


NA Not applicable


NA Not applicable

_____________________________________________________________________________________________Page 5 / 8


_____________________________________________________________________________________________Substances CAS Number Reproductive toxicityContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable


NA Not applicable


NA Not applicable


NA Not applicable

















_____________________________________________________________________________________________Page 6 / 8


_____________________________________________________________________________________________12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors


Safe handling and disposal methods Bury in a licensed landfill or burn in an approved incinerator according to federal, state, and local regulations. Substance shouldNOT be deposited into a sewage facility.


















_____________________________________________________________________________________________Page 7 / 8


_____________________________________________________________________________________________








_____________________________________________________________________________________________Page 8 / 8


SAFETY DATA SHEET

SEM-7 EMULSIFIERRevision Date: 18-Apr-2017 Revision Number: 21



1.1. Product Identifier Product Name SEM-7 EMULSIFIER


Recommended use of the chemical and restrictions on use Recommended Use EmulsifierUses advised against No information available








Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318Acute Aquatic Toxicity Category 2 - H401Chronic Aquatic Toxicity Category 3 - H412


Hazard Pictograms

Flammable liquids. Category 3 - H226

_____________________________________________________________________________________________Page 1 / 10

_____________________________________________________________________________________________SEM-7 EMULSIFIER Revision Date: 18-Apr-2017

Signal Word DANGER

Hazard Statements: H226 - Flammable liquid and vaporH315 - Causes skin irritationH318 - Causes serious eye damageH401 - Toxic to aquatic lifeH412 - Harmful to aquatic life with long lasting effects


Prevention P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.No smoking.P233 - Keep container tightly closedP240 - Ground and bond container and receiving equipment.P241 - Use explosion-proof electrical/ventilating/lighting/equipmentP242 - Use only non-sparking toolsP243 - Take action to prevent static discharges.P264 - Wash face, hands and any exposed skin thoroughly after handlingP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protection

Response P302 + P352 - IF ON SKIN: Wash with plenty of water.P332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP391 - Collect spillageP370 + P378 - In case of fire: Use water spray for extinction

Storage P403 + P235 - Store in a well-ventilated place. Keep coolDisposal P501 - Dispose of contents/container in accordance with


ContainsSubstances CAS NumberPoly(oxy-1,2-ethanediyl), alpha-sulfo-omega-(dodecyloxy)-,ammonium salt

32612-48-9

Poly(oxy-1,2-ethanediyl), alpha-sulfo-omega-(tetradecyloxy)-,ammonium salt

27731-61-9

Isopropanol 67-63-0



_____________________________________________________________________________________________Page 2 / 10




Poly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 30 - 60% Skin Irrit. 2 (H315)Eye Corr. 1 (H318)Aquatic Acute 2 (H401)Aquatic Chronic 3 (H412)

Poly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(tetradecyloxy)-, ammonium salt

27731-61-9 10 - 30% Acute Tox. 4 (H302)Skin Irrit. 2 (H315)Eye Irrit. 2 (H319)Aquatic Acute 2 (H401)Aquatic Chronic 3 (H412)

Isopropanol 67-63-0 10 - 30% Eye Irrit. 2 (H319)STOT SE 3 (H336)Flam. Liq. 2 (H225)


Description of necessary first aid measures Inhalation If inhaled, move victim to fresh air and seek medical attention.Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of

water for at least 15 minutes and get medical attention immediately after flushing.Skin In case of contact, immediately flush skin with plenty of soap and water for at least



Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. May be harmful if swallowed.




Specific hazards arising from the chemical Special exposure hazards in a fireMay be ignited by heat, sparks or flames Use water spray to cool fire exposed surfaces. Closed containers may explode in fire.Decomposition in fire may produce harmful gases.



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Wear self-contained breathing apparatus in enclosed areas.


_____________________________________________________________________________________________Page 3 / 10

Prevent from entering sewers, waterways, or low areas.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing beforereuse.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Store in a cool wellventilated area. Store locked up.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 Not applicable Not applicable



Isopropanol 67-63-0 TWA: 400 ppmTWA: 983 mg/m3

STEL: 500 ppmSTEL: 1230 mg/m3

TWA: 200 ppmSTEL: 400 ppm





Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Organic vapor respirator.

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact(recommended: protection index 6, corresponding to > 480 minutes permeation time as perEN 374): Nitrile gloves. (>= 0.4 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerably shorterthan the permeation time determined in accordance with EN 374 as a result of the manyinfluencing factors (e.g. temperature). If signs of wear and tear are noticed then the glovesshould be replaced. Manufacturer's directions for use should be observed because of greatdiversity of types.

_____________________________________________________________________________________________Page 4 / 10


Skin Protection Rubber apron.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls No information available



Property Values Remarks/ - Method pH: 7-8Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point 23.3 °C / 74 °F PMCCEvaporation rate No data availableVapor Pressure 89Vapor Density No data availableSpecific Gravity 1Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/waterAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid Keep away from heat, sparks and flame.10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May be harmful if swallowed.


Physical State: Liquid Color Clear light yellowOdor: Alcohol Odor Threshold: No information available

_____________________________________________________________________________________________Page 5 / 10




32612-48-9 4100 mg/kg (Rat) > 5000 mg/kg (Rabbit) (similarsubstance)

No data available

Poly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(tetradecyloxy)-, ammoniumsalt

27731-61-9 No data available No data available No data available

Isopropanol 67-63-0 5840 mg/kg-bw (rat) 12870 mg/kg-bw (rabbit) 72.6 mg/L (Rat, 4h, vapor)

Immediate, delayed and chronic health effects from exposure Inhalation May cause respiratory irritation. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,giddiness and unconsciousness.

Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation.Ingestion Harmful if swallowed. Irritation of the mouth, throat, and stomach. May cause abdominal

pain, vomiting, nausea, and diarrhea.





Substances CAS Number Skin corrosion/irritationPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 Causes moderate skin irritation. (Rabbit)


27731-61-9 May cause severe skin irritation. (similar substances)

Isopropanol 67-63-0 Non-irritating to the skin (Rabbit)

Substances CAS Number Serious eye damage/irritationPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 Causes moderate eye irritation


27731-61-9 Causes moderate eye irritation (similar substances)

Isopropanol 67-63-0 Causes moderate eye irritation (Rabbit)

Substances CAS Number Skin SensitizationPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)


27731-61-9 Patch test on human volunteers did not demonstrate sensitization properties (similar substances)

Isopropanol 67-63-0 Did not cause sensitization on laboratory animals (guinea pig)

Substances CAS Number Respiratory SensitizationPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt


Poly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(tetradec


_____________________________________________________________________________________________Page 6 / 10


yloxy)-, ammonium saltIsopropanol 67-63-0 No information available

Substances CAS Number Mutagenic EffectsPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects. (similarsubstances)


27731-61-9 In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects. (similarsubstances)

Isopropanol 67-63-0 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

Substances CAS Number Carcinogenic EffectsPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 Did not show carcinogenic effects in animal experiments (similar substances)



Isopropanol 67-63-0 Did not show carcinogenic effects in animal experiments

Substances CAS Number Reproductive toxicityPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 Animal testing did not show any effects on fertility. (similar substances)


27731-61-9 Animal testing did not show any effects on fertility. (similar substances)

Isopropanol 67-63-0 Animal testing did not show any effects on fertility.

Substances CAS Number STOT - single exposurePoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt




Isopropanol 67-63-0 May cause headache, dizziness, and other central nervous system effects.

Substances CAS Number STOT - repeated exposurePoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)



Isopropanol 67-63-0 No significant toxicity observed in animal studies at concentration requiring classification. (similarsubstances)

Substances CAS Number Aspiration hazardPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt




Isopropanol 67-63-0 Not applicable


Ecotoxicity



Poly(oxy-1,2-ethanediy 32612-48-9 EC50 (72h) 27.7 mg/L LC50 (45d) 0.9 mg/L No information available EC50 (48h) 7.4 mg/L

_____________________________________________________________________________________________Page 7 / 10


l),alpha-sulfo-omega-(dodecyloxy)-, ammoniumsalt

(Desmodesmussubspicatus)

NOEC (72h) 0.95 mg/L(Desmodesmus

subspicatus)

(Pimephales promelas)NOEC (45d) 1 mg/L

(Pimephales promelas)

(Daphnia magna)NOED (21d) 0.27 mg/L

(Daphnia magna)

Poly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(tetradecyloxy)-,ammonium salt

27731-61-9 No information available No information available No information available No information available

Isopropanol 67-63-0 EC50 (72h) > 1000 mg/L(Desmodesmus

subspicatus)EC50 (7d) 1800 mg/L

(Scenedesmusquadricauda)

LC50 (96h) 9640 mg/L(Pimephales promelas)LC50 (7d) 7060 mg/L(Poecilia reticulata)

TT (16h) 1050 mg/L(Pseudomonas putida)

EC50 (48h) 13,299 mg/L(Daphnia magna)

EC50 (24h) > 10,000mg/L (Daphnia magna)

12.2. Persistence and degradability Readily biodegradableSubstances CAS Number Persistence and DegradabilityPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt

32612-48-9 Readily biodegradable (81% @ 28d)



Isopropanol 67-63-0 Readily biodegradable (53% @ 5d)

12.3. Bioaccumulative potential Does not bioaccumulate.Substances CAS Number Log Pow


32612-48-9 Log Kow = 1.62



Isopropanol 67-63-0 0.05


Substances CAS Number MobilityPoly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, ammonium salt




Isopropanol 67-63-0 No information available







_____________________________________________________________________________________________Page 8 / 10

Transportation Information


Australia ADG UN Number UN1993UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol)Transport Hazard Class(es): 3Packing Group: IIIEnvironmental Hazards: Not applicable

IMDG/IMO UN Number UN1993UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol)Transport Hazard Class(es): 3Packing Group: IIIEnvironmental Hazards: Not applicableEMS: EmS F-E, S-E

IATA/ICAO UN Number UN1993UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol)Transport Hazard Class(es): 3Packing Group: IIIEnvironmental Hazards: Not applicable


HazChem Code •3Y














Revision Date: 18-Apr-2017

Revision Note

_____________________________________________________________________________________________Page 9 / 10

SDS sections updated:2


Full text of H-Statements referred to under sections 2 and 3H225 - Highly flammable liquid and vaporH226 - Flammable liquid and vaporH315 - Causes skin irritationH318 - Causes serious eye damageH319 - Causes serious eye irritationH336 - May cause drowsiness or dizzinessH401 - Toxic to aquatic lifeH412 - Harmful to aquatic life with long lasting effects







_____________________________________________________________________________________________Page 10 / 10

SAFETY DATA SHEET

SEM-8™ EMULSIFIERRevision Date: 21-Apr-2017 Revision Number: 46



1.1. Product Identifier Product Name SEM-8™ EMULSIFIER


Recommended use of the chemical and restrictions on use Recommended Use EmulsifierUses advised against No information available








Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315Serious Eye Damage/Irritation Category 1 - H318Acute Aquatic Toxicity Category 2 - H401Chronic Aquatic Toxicity Category 3 - H412


Hazard Pictograms

Flammable liquids. Category 3 - (H226)

_____________________________________________________________________________________________Page 1 / 9

_____________________________________________________________________________________________SEM-8™ EMULSIFIER Revision Date: 21-Apr-2017

Signal Word DANGER

Hazard Statements: H226 - Flammable liquid and vaporH315 - Causes skin irritationH318 - Causes serious eye damageH401 - Toxic to aquatic lifeH412 - Harmful to aquatic life with long lasting effects


Prevention P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.No smoking.P233 - Keep container tightly closedP240 - Ground and bond container and receiving equipment.P241 - Use explosion-proof electrical/ventilating/lighting/equipmentP242 - Use only non-sparking toolsP243 - Take action to prevent static discharges.P264 - Wash face, hands and any exposed skin thoroughly after handlingP273 - Avoid release to the environmentP280 - Wear protective gloves/protective clothing/eye protection/face protectionP280 - Wear protective glovesP280 - Wear eye protection/face protection

Response P302 + P352 - IF ON SKIN: Wash with plenty of water.P332 + P313 - If skin irritation occurs: Get medical advice/attentionP362 + P364 - Take off contaminated clothing and wash before reuseP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP310 - Immediately call a POISON CENTER or doctor/physicianP370 + P378 - In case of fire: Use water spray for extinctionP391 - Collect spillageP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water [or shower].

Storage P403 + P235 - Store in a well-ventilated place. Keep coolDisposal P501 - Dispose of contents/container in accordance with


ContainsSubstances CAS NumberPolyethylene glycol (C6-C10) alkyl ether, sulfate ammonium salt 68037-05-8



_____________________________________________________________________________________________Page 2 / 9




Polyethylene glycol (C6-C10) alkyl ether, sulfateammonium salt

68037-05-8 60 - 100% Skin Irrit. 2 (H315)Eye Corr. 1 (H318)Aquatic Acute 2 (H401)Aquatic Chronic 3 (H412)Flam. Liq. 3 (H226)


Description of necessary first aid measures Inhalation If inhaled, move victim to fresh air and seek medical attention.Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek

prompt medical attention.Skin Wash with soap and water. Get medical attention if irritation persists. Remove

contaminated clothing and launder before reuse.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.

Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. May be harmful if swallowed.




Specific hazards arising from the chemical Special exposure hazards in a fireUse water spray to cool fire exposed surfaces. Closed containers may explode in fire. Decomposition in fire may produce harmfulgases. Vapors are heavier than air and may accumulate in low areas. Vapors may travel along the ground to be ignited at distantlocations.



6.1. Personal precautions, protective equipment and emergency procedures Remove sources of ignition. Use appropriate protective equipment. Wear self-contained breathing apparatus in enclosed areas.Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequate ventilation.



_____________________________________________________________________________________________Page 3 / 9



7.1. Precautions for safe handling Handling PrecautionsRemove sources of ignition. Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Washhands after use. Launder contaminated clothing before reuse. Ground and bond containers when transferring from one container toanother. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep from heat, sparks, and open flames. Keep container closed when not in use. Store in a drylocation. Store in a cool well ventilated area. Product has a shelf life of 36 months.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAPolyethylene glycol (C6-C10) alkyl ether, sulfateammonium salt






Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Organic vapor respirator.In high concentrations, supplied air respirator or a self-contained breathing apparatus.


Skin Protection Rubber apron.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls No information available


_____________________________________________________________________________________________Page 4 / 9



Property Values Remarks/ - Method pH: 7.0-8.5 @ 5%Freezing Point / Range -29 °CMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point 33.9 °C / 93 °F Seta closed cupEvaporation rate < 1 (BuAc = 1)Vapor Pressure 15.7 mmHg @ 20CVapor Density < 1 (Air=1)Specific Gravity 1.054Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid Keep away from heat, sparks and flame.10.5. Incompatible materials Strong oxidizers. Strong alkalis.10.6. Hazardous decomposition products Oxides of nitrogen. Oxides of sulfur. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes skin irritation. May be harmful if swallowed.



Polyethylene glycol(C6-C10) alkyl ether,sulfate ammonium salt

68037-05-8 4100 mg/kg (Rat) (Similarsubstance)

>5000 mg/kg (Rabbit (Similarsubstance)

No data available

Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause respiratory irritation. May cause central nervous system depression including

headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech,

Physical State: Liquid Color Clear light yellowOdor: Alcohol Odor Threshold:

_____________________________________________________________________________________________Page 5 / 9



giddiness and unconsciousness.Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes skin irritation. May cause skin defatting with prolonged exposure.Ingestion May be harmful if swallowed. Irritation of the mouth, throat, and stomach. May cause

abdominal pain, vomiting, nausea, and diarrhea. May cause central nervous systemdepression including headache, dizziness, drowsiness, muscular weakness, incoordination,slowed reaction time, fatigue blurred vision, slurred speech, giddiness, tremors andconvulsions. May affect the heart and cardiovascular system.





Substances CAS Number Skin corrosion/irritationPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt

68037-05-8 Causes moderate skin irritation. (Rabbit) (similar substances)

Substances CAS Number Serious eye damage/irritationPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt

68037-05-8 Causes severe eye irritation (Rabbit) (similar substances)

Substances CAS Number Skin SensitizationPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt

68037-05-8 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)

Substances CAS Number Respiratory SensitizationPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt


Substances CAS Number Mutagenic EffectsPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt

68037-05-8 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similarsubstances)

Substances CAS Number Carcinogenic EffectsPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt


Substances CAS Number Reproductive toxicityPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt

68037-05-8 Did not show teratogenic effects in animal experiments. (similar substances)

Substances CAS Number STOT - single exposurePolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt


Substances CAS Number STOT - repeated exposurePolyethylene glycol(C6-C10) alkyl ether, sulfate


_____________________________________________________________________________________________Page 6 / 9


ammonium salt

Substances CAS Number Aspiration hazardPolyethylene glycol(C6-C10) alkyl ether, sulfateammonium salt

68037-05-8 Not applicable


Ecotoxicity



Polyethylene glycol(C6-C10) alkyl ether,sulfate ammonium salt

68037-05-8 EC50 (72h) 73.52 mg/L(Skeletonema costatum)

ErC50 (72h) 32 mg/L(Selenstrum

capriconutum) (similarsubstance)

NOErC (72h) 9 mg/L(Selenastrum

capricornutum)NOEC (72h) 32 mg/L

(Skeletonema costatum)

LC50 (96h) 1 - 2.5 mg/L(Salmo trutta) (similar

substance)LC50 (96h) 7.8 mg/L

(Scophthalmus maximus)LC50 (96h) 350 mg/L

(Scophthalmus maximus)NOEC (30d) 0.88 mg/L(Pimephales promelas)

(similar substance)

No information available EC50 (48h) 1.17 mg/L(Daphnia magna) (similar

substance)LC50 (96h) 232.5 mg/L

(Acartia tonsa)NOEC (21d) 0.37 mg/L

(Daphnia magna) (similarsubstance)


Substances CAS Number Persistence and DegradabilityPolyethylene glycol (C6-C10) alkyl ether, sulfateammonium salt




Polyethylene glycol (C6-C10) alkyl ether, sulfateammonium salt



Substances CAS Number MobilityPolyethylene glycol (C6-C10) alkyl ether, sulfateammonium salt




Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Incineration recommended in approvedincinerator according to federal, state, and local regulations. Substance should NOT be deposited into a sewage facility.



_____________________________________________________________________________________________Page 7 / 9




UN Number UN1993UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol)Transport Hazard Class(es): 3Packing Group: IIIEnvironmental Hazards: Not applicable

IMDG/IMO UN Number UN1993UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol)Transport Hazard Class(es): 3Packing Group: IIIEnvironmental Hazards: Not applicableEMS: EmS F-E, S-E

IATA/ICAO UN Number UN1993UN proper shipping name: Flammable Liquid, N.O.S. (Contains Isopropanol)Transport Hazard Class(es): 3Packing Group: IIIEnvironmental Hazards: Not applicable


HazChem Code •3Y














Revision Date: 21-Apr-2017

_____________________________________________________________________________________________Page 8 / 9


Revision Note

Full text of H-Statements referred to under sections 2 and 3H225 - Highly flammable liquid and vaporH226 - Flammable liquid and vaporH302 - Harmful if swallowedH315 - Causes skin irritationH318 - Causes serious eye damageH319 - Causes serious eye irritationH336 - May cause drowsiness or dizzinessH400 - Very toxic to aquatic lifeH401 - Toxic to aquatic lifeH412 - Harmful to aquatic life with long lasting effects




Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDHERAOSHA



_____________________________________________________________________________________________Page 9 / 9

SAFETY DATA SHEET

STEELSEAL® 100



1.1. Product Identifier Product Name STEELSEAL® 100


Recommended use of the chemical and restrictions on use Recommended Use Loss Circulation MaterialUses Advised Against No information available




Product Emergency TelephoneAustralia: + 61 1 800 686 951Papua New Guinea: + 61 1 800 686 951NewZealand: +64 800 451719







_____________________________________________________________________________________________Page 1 / 7

Revision Number: 21Revision Date: 30-Sep-2015

_____________________________________________________________________________________________Classification of the hazardous chemical Not classified


Hazard Pictograms




Prevention None

Response None

Storage None

Disposal None


NA












attention.


Medical Attention and Special Treatment

_____________________________________________________________________________________________Page 2 / 7

Revision Date: 30-Sep-2015STEELSEAL® 100

_____________________________________________________________________________________________Notes to Physician Treat symptomatically



Specific hazards arising from the chemical Special Exposure HazardsCombustible dust when in finely divided and highly suspended state.



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin,eyes and clothing.




7.1. Precautions for Safe Handling Handling PrecautionsAvoid creating or inhaling dust. Avoid dust accumulations. Wet activated carbon removes oxygen from air causing a severe hazardto workers inside carbon vessels and enclosed or confined spaces. Before entering such an area, sampling and dark proceduresfor low oxygen levels should be taken to ensure ample oxygen availability. Ensure adequate ventilation. Avoid contact with eyes,skin, or clothing. Wash hands after use. Launder contaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a dry location. Keep from heat, sparks, and open flames. Product has a shelf life of 60 months.Other GuidelinesNo information available




Appropriate engineering controls Engineering Controls A well ventilated area to control dust levels.

_____________________________________________________________________________________________Page 3 / 7

Revision Date: 30-Sep-2015STEELSEAL® 100

_____________________________________________________________________________________________

Personal protective equipment (PPE) Respiratory Protection Not normally needed. But if significant exposures are possible then the following respirator

is recommended:Dust/mist respirator. (N95, P2/P3)




Property Values Remarks/ - Method pH: No data availableFreezing Point/Range No data availableMelting Point/Range No data availableBoiling Point/Range 4200 °C / 7592 °FFlash Point > 356 °C / > 673 °F

lower flammability limit 0.07-0.12 oz./ft3Evaporation rate No data availableVapor Pressure 1Vapor Density 0.4Specific Gravity 1.75Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong acids. Strong alkalis.10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.



_____________________________________________________________________________________________Page 4 / 7

Color: Dark gray

STEELSEAL® 100

Odor: Odorless


Odor Threshold: No information availablePhysical State: Solid

_____________________________________________________________________________________________Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.






Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mechanical irritation to eye.Skin Contact Prolonged or repeated contact may cause slight skin irritation.Ingestion May cause mild gastric distress.



Interactive effects Skin disorders.









_____________________________________________________________________________________________Page 5 / 7

STEELSEAL® 100 Revision Date: 30-Sep-2015

_____________________________________________________________________________________________



12.3. Bioaccumulative potential Does not bioaccumulateSubstances CAS Number Log Pow



















EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.

_____________________________________________________________________________________________Page 6 / 7


_____________________________________________________________________________________________Canadian DSL Inventory All components listed on inventory or are exempt.














_____________________________________________________________________________________________Page 7 / 7


SAFETY DATA SHEET

SUPER CBL ADDITIVERevision Date: 18-Jul-2017 Revision Number: 26



1.1. Product Identifier Product Name SUPER CBL ADDITIVE


Recommended use of the chemical and restrictions on use Recommended Use AdditiveUses advised against No information available








Classification of the hazardous chemical


Hazard Pictograms

Substances/mixtures which, in contact with water, emit flammable gases.

_____________________________________________________________________________________________Page 1 / 8

Category 2 - H261

_____________________________________________________________________________________________SUPER CBL ADDITIVE Revision Date: 18-Jul-2017

Signal Word DANGER

Hazard Statements: H261 - In contact with water releases flammable gas


Prevention P223 - Do not allow contact with water.P231 + P232 - Handle and store contents under inert gas. Protect from moisture.P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response P335 + P334 - Brush off loose particles from skin. Immerse in cool water/wrap in wetbandagesP370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam forextinction

Storage P402 + P404 - Store in a dry place. Store in a closed containerDisposal P501 - Dispose of contents/container in accordance with


ContainsSubstances CAS NumberAluminum 7429-90-5





Aluminum 7429-90-5 60 - 100% Flam. Sol. 1 (H228)Pyr. Sol. 1 (H250)Water-react. 2 (H261)







_____________________________________________________________________________________________Page 2 / 8



Suitable extinguishing equipment Suitable Extinguishing MediaSand.Extinguishing media which must not be used for safety reasonsDo NOT use water or carbon dioxide or other liquids on aluminum fires.

Specific hazards arising from the chemical Special exposure hazards in a fireCombustible dust when in finely divided and highly suspended state. Avoid stirring burning aluminum. Shut off electricity. Isolatematerial. Ring sand or class D extinguishing material around fire to contain.



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin,eyes and clothing. Evacuate all persons from the area.

6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. Consult local authorities.

6.3. Methods and material for containment and cleaning up Remove ignition sources and work with non-sparking tools. Scoop up and remove.


7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid creating or inhaling dust. Avoid contact with eyes, skin, or clothing. Ensure adequateventilation. Wash hands after use. Launder contaminated clothing before reuse.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a well ventilated area. Store away from oxidizers. Keep container closed when not in use. Store locked up. Store awayfrom acids. Store away from alkalis. Store away from water. Store in a cool, dry location. Product has a shelf life of 9 monthsOther GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAAluminum 7429-90-5 TWA: 10 mg/m3

TWA: 5 mg/m3TWA: 1 mg/m3



_____________________________________________________________________________________________Page 3 / 8



Respiratory Protection Dust/mist respirator. (N95, P2/P3)Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point > 176 °C Closed cup

Lower flammability limit 0.04Evaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 2.7Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 650 °C / 1202 °FDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions May react with water with some release of energy but not violently10.4. Conditions to avoid Keep away from any contact with water.10.5. Incompatible materials Contact with water. Strong acids. Strong alkalis. Strong oxidizers. Halogenated compounds.10.6. Hazardous decomposition products Flammable hydrogen gas. Metal oxides.



Symptoms related to exposure

Physical State: Solid Color SilverOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 8



Most Important Symptoms/EffectsNo significant hazards expected.



Aluminum 7429-90-5 > 5000 mg/kg (Rat) (Similarsubstance)

> 5000 mg/kg (Rabbit) (Similarsubstance)

> 2.3 mg/L (Rat, 4 h, dust)(Similar substance)

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mechanical irritation to eye.Skin Contact Not irritating to skin in rabbits.Ingestion Irritation of the mouth, throat, and stomach.



Interactive effects Lung disorders.


Substances CAS Number Skin corrosion/irritationAluminum 7429-90-5 Non-irritating to the skin (Rabbit) (similar substances)

Substances CAS Number Serious eye damage/irritationAluminum 7429-90-5 Non-irritating to the eye (Rabbit) (similar substances)

Substances CAS Number Skin SensitizationAluminum 7429-90-5 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)

Substances CAS Number Respiratory SensitizationAluminum 7429-90-5 Did not cause sensitization on laboratory animals (mouse) (similar substances)

Substances CAS Number Mutagenic EffectsAluminum 7429-90-5 In vivo tests did not show mutagenic effects. (similar substances)

Substances CAS Number Carcinogenic EffectsAluminum 7429-90-5 Did not show carcinogenic or teratogenic effects in animal experiments

Substances CAS Number Reproductive toxicityAluminum 7429-90-5 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal

experiments.

Substances CAS Number STOT - single exposureAluminum 7429-90-5 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposureAluminum 7429-90-5 No significant toxicity observed in animal studies at concentration requiring classification. (similar

substances)

Substances CAS Number Aspiration hazardAluminum 7429-90-5 Not applicable

_____________________________________________________________________________________________Page 5 / 8



Ecotoxicity



Aluminum 7429-90-5 EC50(72h): 448.05 mg/L(Skeletonema costatum)

Limit Test: > 1 mg/L(Scophthalmus maximus)

No information available LC50(48h): 2.47 mg/L(Arcatia tonsa)

12.2. Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.Substances CAS Number Persistence and DegradabilityAluminum 7429-90-5 The methods for determining biodegradability are




Aluminum 7429-90-5 No information available


Substances CAS Number MobilityAluminum 7429-90-5 No information available










IATA/ICAO

_____________________________________________________________________________________________Page 6 / 8


















Revision Date: 18-Jul-2017


Full text of H-Statements referred to under sections 2 and 3H228 - Flammable solidH250 - Catches fire spontaneously if exposed to airH261 - In contact with water releases flammable gases




_____________________________________________________________________________________________Page 7 / 8

bw – body weightCAS – Chemical Abstracts Service


EC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day




_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

TUNED SPACER E+Revision Date: 23-Jun-2016 Revision Number: 33



1.1. Product Identifier Product Name TUNED SPACER E+


Recommended use of the chemical and restrictions on use Recommended Use Cement SpacerUses advised against No information available









Classification of the hazardous chemical Carcinogenicity Category 2 - H351Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373


Hazard pictograms

_____________________________________________________________________________________________Page 1 / 9

_____________________________________________________________________________________________TUNED SPACER E+ Revision Date: 23-Jun-2016

Signal Word Warning

Hazard Statements: H351 - Suspected of causing cancer if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled


Prevention P201 - Obtain special instructions before useP202 - Do not handle until all safety precautions have been read and understoodP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP281 - Use personal protective equipment as required

Response P308 + P313 - IF exposed or concerned: Get medical advice/attentionP314 - Get medical attention/advice if you feel unwell



ContainsSubstances CAS NumberCrystalline silica, quartz 14808-60-7Crystalline silica, cristobalite 14464-46-1Crystalline silica, tridymite 15468-32-3






Crystalline silica, cristobalite 14464-46-1 0.1 - 1% Carc. 2 (H351)STOT RE 1 (H372)

Crystalline silica, tridymite 15468-32-3 0.1 - 1% Carc. 2 (H351)STOT RE 1 (H372)





_____________________________________________________________________________________________Page 2 / 9


Symptoms caused by exposure Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.




Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.




6.2. Environmental precautions None known.



7.1. Precautions for safe handling Handling PrecautionsThis product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathingdust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits.Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery whenwet.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationUse good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Do not reuseempty container.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWA

_____________________________________________________________________________________________Page 3 / 9



Crystalline silica, cristobalite 14464-46-1 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3

Crystalline silica, tridymite 15468-32-3 TWA: 0.1 mg/m3 TWA: 0.05 mg/m3








Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.88 - 2.05Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions

Physical State: Solid Color White to light strawOdor: Odorless Odor Threshold:

_____________________________________________________________________________________________Page 4 / 9



Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of sulfur. Carbon monoxide and carbon dioxide. Amorphous silica may transform at elevated temperatures to tridymite (870C) or cristobalite (1470 C).



Symptoms related to exposure Most Important Symptoms/EffectsBreathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has alsobeen associated with scleroderma and kidney disease.







Crystalline silica,tridymite





Eye Contact May cause mechanical irritation to eye.Skin Contact None known.Ingestion None known.


Cancer Status: The International Agency for Research on Cancer (IARC) hasdetermined that crystalline silica inhaled in the form of quartz or cristobalite fromoccupational sources can cause lung cancer in humans (Group 1 - carcinogenic tohumans) and has determined that there is sufficient evidence in experimentalanimals for the carcinogenicity of tridymite (Group 2A - possible carcinogen tohumans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres(June 1997) in conjunction with the use of these minerals. The National ToxicologyProgram classifies respirable crystalline silica as "Known to be a humancarcinogen". Refer to the 9th Report on Carcinogens (2000). The AmericanConference of Governmental Industrial Hygienists (ACGIH) classifies crystallinesilica, quartz, as a suspected human carcinogen (A2). There is some evidence

_____________________________________________________________________________________________Page 5 / 9


that breathing respirable crystalline silica or the disease silicosis is associated withan increased incidence of significant disease endpoints such as scleroderma (animmune system disorder manifested by scarring of the lungs, skin, and otherinternal organs) and kidney disease.




Substances CAS Number Skin corrosion/irritationCrystalline silica, quartz 14808-60-7 Non-irritating to the skinCrystalline silica, cristobalite 14464-46-1 Non-irritating to the skinCrystalline silica, tridymite 15468-32-3 Non-irritating to the skin

Substances CAS Number Serious eye damage/irritationCrystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible. No information availableCrystalline silica, cristobalite 14464-46-1 Mechanical irritation of the eyes is possible.Crystalline silica, tridymite 15468-32-3 Mechanical irritation of the eyes is possible.

Substances CAS Number Skin SensitizationCrystalline silica, quartz 14808-60-7 No information available.Crystalline silica, cristobalite 14464-46-1 No information availableCrystalline silica, tridymite 15468-32-3 No information available

Substances CAS Number Respiratory SensitizationCrystalline silica, quartz 14808-60-7 No information availableCrystalline silica, cristobalite 14464-46-1 No information availableCrystalline silica, tridymite 15468-32-3 No information available

Substances CAS Number Mutagenic EffectsCrystalline silica, quartz 14808-60-7 Not regarded as mutagenic.Crystalline silica, cristobalite 14464-46-1 Not regarded as mutagenic.Crystalline silica, tridymite 15468-32-3 Not regarded as mutagenic.

Substances CAS Number Carcinogenic EffectsCrystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The


Crystalline silica, cristobalite 14464-46-1 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.

Crystalline silica, tridymite 15468-32-3 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. TheIARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity ofcrystalline silica with repeated respiratory exposure. Based on available scientific evidence, thissubstance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary tolung injury.

Substances CAS Number Reproductive toxicityCrystalline silica, quartz 14808-60-7 No information availableCrystalline silica, cristobalite 14464-46-1 No information availableCrystalline silica, tridymite 15468-32-3 No information available

_____________________________________________________________________________________________Page 6 / 9


Substances CAS Number STOT - single exposureCrystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification.Crystalline silica, cristobalite 14464-46-1 No significant toxicity observed in animal studies at concentration requiring classification.Crystalline silica, tridymite 15468-32-3 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number STOT - repeated exposureCrystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)Crystalline silica, cristobalite 14464-46-1 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)Crystalline silica, tridymite 15468-32-3 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs)

Substances CAS Number Aspiration hazardCrystalline silica, quartz 14808-60-7 Not applicableCrystalline silica, cristobalite 14464-46-1 Not applicableCrystalline silica, tridymite 15468-32-3 Not applicable







capricornutum)





substance)


substance)Crystalline silica,tridymite

15468-32-3 No information available LL0 (96h) 10,000mg/L(Danio rerio) (similar

substance)


substance)

12.2. Persistence and degradability Expected to be readily biodegradableSubstances CAS Number Persistence and DegradabilityCrystalline silica, quartz 14808-60-7 The methods for determining biodegradability are

not applicable to inorganic substances.Crystalline silica, cristobalite 14464-46-1 The methods for determining biodegradability are

not applicable to inorganic substances.Crystalline silica, tridymite 15468-32-3 The methods for determining biodegradability are





Crystalline silica, cristobalite 14464-46-1 No information available

Crystalline silica, tridymite 15468-32-3 No information available


Substances CAS Number MobilityCrystalline silica, quartz 14808-60-7 No information availableCrystalline silica, cristobalite 14464-46-1 No information availableCrystalline silica, tridymite 15468-32-3 No information available


_____________________________________________________________________________________________Page 7 / 9

























_____________________________________________________________________________________________Page 8 / 9



H351 - Suspected of causing cancer if inhaledH372 - Causes damage to organs through prolonged or repeated exposure if inhaledH373 - May cause damage to organs through prolonged or repeated exposure if inhaled







_____________________________________________________________________________________________Page 9 / 9

SAFETY DATA SHEET

VERSASETRevision Date: 22-Jun-2016 Revision Number: 19



1.1. Product Identifier Product Name VERSASET


Recommended use of the chemical and restrictions on use Recommended Use Cement AdditiveUses advised against No information available









Classification of the hazardous chemical Skin Corrosion/Irritation Category 1 - H314Serious Eye Damage/Irritation Category 1 - H318


Hazard pictograms

Substances/mixtures corrosive to metal

_____________________________________________________________________________________________Page 1 / 8

Category 1 - H290

_____________________________________________________________________________________________VERSASET Revision Date: 22-Jun-2016

Signal Word Danger

Hazard Statements: H290 - May be corrosive to metalsH314 - Causes severe skin burns and eye damageH318 - Causes serious eye damage


Prevention P103 - Read label before useP234 - Keep only in original containerP260 - Do not breathe dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves/protective clothing/eye protection/face protection

Response P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomitingP303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing.Rinse skin with water/showerP363 - Wash contaminated clothing before reuseP304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathingP310 - Immediately call a POISON CENTER or doctor/physicianP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP390 - Absorb spillage to prevent material damage

Storage P405 - Store locked upP406 - Store in corrosive resistant container with a resistant inner liner.


ContainsSubstances CAS NumberSodium aluminate 1302-42-7





Sodium aluminate 1302-42-7 60 - 100% Skin Corr. 1A (H314)Eye Corr. 1 (H318)Met. Corr. 1 (H290)


Description of necessary first aid measures Inhalation If inhaled, move victim to fresh air and seek medical attention.Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of

_____________________________________________________________________________________________Page 2 / 8


water for at least 15 minutes and get medical attention immediately after flushing.Skin In case of contact, immediately flush skin with plenty of soap and water for at least



Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction.





Special protective equipment and precautions for fire fighters Special protective equipment for firefightersNot applicable


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Avoid contact with skin, eyes and clothing. Ensureadequate ventilation.


6.3. Methods and material for containment and cleaning up Scoop up and remove. Do NOT spread spilled product with water.


7.1. Precautions for safe handling Handling PrecautionsUse appropriate protective equipment. Avoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequateventilation. Wash hands after use. Launder contaminated clothing before reuse.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from acids. Store in a dry location. Product has a shelf life of 24 months.Other GuidelinesNo information available


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Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWASodium aluminate 1302-42-7 Not applicable 2 mg/m3

Appropriate engineering controls Engineering Controls Use in a well ventilated area. Localized ventilation should be used to control dust levels.



Respiratory Protection Not normally needed. But if significant exposures are possible then the following respiratoris recommended:Dust/mist respirator. (N95, P2/P3)


Skin Protection Normal work coveralls.Eye Protection Dust proof goggles.Other Precautions Eyewash fountains and safety showers must be easily accessible.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: 11.5Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 2.3Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information Molecular Weight 82VOC Content (%) No data available

Physical State: Solid Color WhiteOdor: Odorless Odor Threshold:

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10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Amphoteric metals such as aluminum, magnesium, lead, tin, or zinc.10.6. Hazardous decomposition products None known.



Symptoms related to exposure Most Important Symptoms/EffectsCauses severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction.




Sodium aluminate 1302-42-7 > 2000 mg/kg (Rat) (Similarsubstance)

> 5000 mg/kg (Rabbit) (Similarsubstance)

> 5 mg/L air (Rat, aerosol, 4hr)(Similar substance)

Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause respiratory irritation.Eye Contact Causes severe eye irritation which may damage tissue.Skin Contact Causes severe skin irritation with tissue destruction.Ingestion Causes burns of the mouth, throat and stomach.





Substances CAS Number Skin corrosion/irritationSodium aluminate 1302-42-7 Causes severe skin irritation with tissue destruction. (similar substances)

Substances CAS Number Serious eye damage/irritationSodium aluminate 1302-42-7 Causes severe eye irritation which may damage tissue. (similar substances)

Substances CAS Number Skin SensitizationSodium aluminate 1302-42-7 Did not cause sensitization on laboratory animals (guinea pig) (similar substances)

Substances CAS Number Respiratory SensitizationSodium aluminate 1302-42-7 No information available

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Substances CAS Number Mutagenic EffectsSodium aluminate 1302-42-7 No data of sufficient quality are available.

Substances CAS Number Carcinogenic EffectsSodium aluminate 1302-42-7 Did not show carcinogenic effects in animal experiments (similar substances)

Substances CAS Number Reproductive toxicitySodium aluminate 1302-42-7 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal

experiments. (similar substances)

Substances CAS Number STOT - single exposureSodium aluminate 1302-42-7 No significant toxicity observed in animal studies at concentration requiring classification. (similar

substances)

Substances CAS Number STOT - repeated exposureSodium aluminate 1302-42-7 No significant toxicity observed in animal studies at concentration requiring classification. (similar

substances)

Substances CAS Number Aspiration hazardSodium aluminate 1302-42-7 Not applicable





Sodium aluminate 1302-42-7 No information available No information available EC50(3h): > 100 mg/L(activated sludge,domestic sewage)


12.2. Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.Substances CAS Number Persistence and DegradabilitySodium aluminate 1302-42-7 The methods for determining biodegradability are




Sodium aluminate 1302-42-7 No information available


Substances CAS Number MobilitySodium aluminate 1302-42-7 No information available



Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations. Bury in a licensed landfill according to federal,state, and local regulations.

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Disposal of any contaminated packaging Dispose of container according to national or local regulations. Do NOT reuse container. Contaminated packaging may bedisposed of by: rendering packaging incapable of containing any substance, or treating packaging to remove residual contents, ortreating packaging to make sure the residual contents are no longer hazardous, or by disposing of packaging into commercialwaste collection.



Transportation Information UN Number Not restrictedUN proper shipping name: Not restricted by surface modes.Transport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable


HazChem Code 2X










Poisons Schedule number S6






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Full text of H-Statements referred to under sections 2 and 3H290 - May be corrosive to metalsH314 - Causes severe skin burns and eye damage


H318 - Causes serious eye damage







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SAFETY DATA SHEET

WellLife™ 665



1.1. Product Identifier Product Name WellLife™ 665


Recommended use of the chemical and restrictions on use Recommended Use Cement AdditiveUses Advised Against No information available











Hazard Pictograms


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Revision Date: 30-Sep-2015 Revision Number: 24

_____________________________________________________________________________________________



Prevention None

Response None

Storage None

Disposal None


NA

Other hazards which do not result in classification Dust can form an explosive mixture in airThis substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).








Description of necessary first aid measures Inhalation Move person to fresh air.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15

minutes and get medical attention if irritation persists.Skin Wash with soap and water.Ingestion Under normal conditions, first aid procedures are not required.

Symptoms caused by exposure May cause mild eye irritation. May cause mild skin irritation.




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WellLife™ 665 Revision Date: 30-Sep-2015

_____________________________________________________________________________________________Specific hazards arising from the chemical Special Exposure HazardsDecomposition in fire may produce harmful gases. Organic dust in the presence of an ignition source can be explosive in highconcentrations. Good housekeeping practices are required to minimize this potential.







7.1. Precautions for Safe Handling Handling PrecautionsAvoid creating or inhaling dust. Avoid dust accumulations. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Store in a cool, dry location.Other GuidelinesNo information available





Personal protective equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)


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Revision Date: 30-Sep-2015WellLife™ 665

_____________________________________________________________________________________________



Property Values Remarks/ - Method pH: No data availableFreezing Point/Range No data availableMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point 236 °C / 457 °F Cleveland Open Cup (COC)Evaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None known.10.5. Incompatible Materials Strong oxidizers.10.6. Hazardous Decomposition Products Carbon monoxide and carbon dioxide.



Sympotoms related to exposure Most Important Symptoms/EffectsMay cause mild eye irritation. May cause mild skin irritation.




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Odor: Odorless


Odor Threshold: No information availablePhysical State: Powder Color: Off white

WellLife™ 665

_____________________________________________________________________________________________Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority


Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact May cause mild eye irritation.Skin Contact Prolonged or repeated contact may cause slight skin irritation.Ingestion None known.
















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_____________________________________________________________________________________________Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority






















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_____________________________________________________________________________________________











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SAFETY DATA SHEET

WellLife™ 734



1.1. Product Identifier Product Name WellLife™ 734


Recommended use of the chemical and restrictions on use Recommended Use Cement EnhancerUses Advised Against No information available




Product Emergency TelephoneAustralia: + 61 1 800 686 951Papua New Guinea: + 61 1 800 686 951NewZealand: +64 800 451719







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Revision Number: 18Revision Date: 30-Sep-2015

_____________________________________________________________________________________________Classification of the hazardous chemical Not classified


Hazard Pictograms




Prevention None

Response None

Storage None

Disposal None


NA









Description of necessary first aid measures Inhalation Under normal conditions, first aid procedures are not required.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15

minutes and get medical attention if irritation persists.Skin Under normal conditions, first aid procedures are not required.Ingestion Under normal conditions, first aid procedures are not required.



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_____________________________________________________________________________________________



Specific hazards arising from the chemical Special Exposure HazardsNot applicable.







7.1. Precautions for Safe Handling Handling PrecautionsMaterial is slippery underfoot. Keep floors clean of spills. Avoid creating or inhaling dust. Avoid dust accumulations. Ensureadequate ventilation. Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing beforereuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a dry location. Product has a shelf life of 60 months.Other GuidelinesNo information available




Appropriate engineering controls Engineering Controls None known.

Personal protective equipment (PPE) Respiratory Protection Not normally necessary.

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_____________________________________________________________________________________________




Property Values Remarks/ - Method pH: No data availableFreezing Point/Range 1200 °CMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 2.6Water Solubility Insoluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials None known.10.6. Hazardous Decomposition Products None known.




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Odor: Odorless


Odor Threshold: No information availablePhysical State: Solid Color: White to Variable

WellLife™ 734

_____________________________________________________________________________________________Numerical measures of toxicity





Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact May cause mechanical irritation to eye.Skin Contact None known.Ingestion None known.












Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according to


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_____________________________________________________________________________________________the competent authority






















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_____________________________________________________________________________________________Poisons Schedule number None Allocated













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Thevenard Island - Department of Mines and Petroleum

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