NT !R, C ,,`_ \2 L - Santa Susana Field Laboratory

96
e''f L_R F`, L 5k T e ° 7e ' NT !R, C ,,`_ \2 L,, HDMSe00037354

Transcript of NT !R, C ,,`_ \2 L - Santa Susana Field Laboratory

e''f L_R F`, L 5k T e ° 7e '

NT !R, C ,,`_ \2 L,,

HDMSe00037354

[_ . .3 . I I Ph (SWM1114 8)Facility

w,,; ,Ja.sie Handling

IE<!-i918'<-

'el spril 1990Joiie 199 .N,Iay 1994iliarch 200 3April 200 5

/ 20062 .8 Summary of Analytical Results from Previous !nvestiggalionn s

Q SUlriitzair\ .ii 1- r, ra i e 4 ,niplir1` Resuli. .s

Summary of Air Dispcrsion Pathway

OPOSEO SAMI UNG,.

:Sampling Within Area I Ouni Pit - SVdM l 1 4 . 83 .1 .1 Source Area s

Disturbed Area sI .3 vliaration Pathway s

3 .1 .4 Data Gaps3 .2 Sampling Outside Area 1 Burn Pit - S\VM Ii 4

FIELD I MF1FIIODOLOGV

4.1 Exploratory, Trenching

4 I .1 Dust and Vapor Monitoring

1 1 .3 Dust Suppression

-t . 1 .2 Soil Managcrueiu and Disposal

1 .1 Post-Trenching Area Managemen

4 . 1 .5 Decontainination

4 2 Sampling I'vicihodolog y-2 . I Soil Vaporr Screcruin o

4 . :2 .2 Soil ~1 nd Sedi ;nerlt Samplin g

_ . , 14 ~dic ;act,\ I i I[LE ials Scicc[iiii +

.2 .2 1 :.:sploratorv I rench Samplin g

.. .. Hi ~_456[~i h \ m $ JILi1 A tyll . ~`Y ' 'i. .~4TD 1j Z .4 i4u

1EDt)1 a1 mh : j Pl~l` I .i a

556

61

1 6

16

HDMSeOO 037355

T.

Li, { .ull Eiie~aiLU aStt I1SIiliStCl

tiei'inca8 Ljelected in f n irOomental Ste n~i S i " rea t r oi'I1 'it, : iB P

U :- .8, RFI WorL F ai i

r. ca I Burn Pit (S A MU 4.8) Sumutarv of 1ti'tic:,t1 SIctlmts Rationale ,?I' (S~ 'Tt,It J 4-S) RFi vVork Plat i

Suoiniarl c,1' Propused Sampling, Area I Buri n

URIIN

'Pitta.

Location of the Area I Burn Pit - SWNIU 4 .8

SSPI . I=II Report Croupin`cs

it /r_rea (,S ;'f IU J. 8 )

IIistorical Soil Saniplinn Locations, ,1iea i Burn P it - SW'NIIJ

Ilisiorical Soil Samples with Elevated Concentrations of AnalyzesSSoutlirlcst Area \ ea I Burn Pit - SWMU 4 . 8

Historical Soil Samples withBlerated Concentrations of Analytes -Northeast Area, Area I Burn Pit - SWMU -l . 8

historical Soil Sampler with Elevated C'.oncentrilions tii ,-~nalytes -Thermal lreatinent IFacility, Area I Burn Pit- SWI1U 4 .8

Southeast ''rea, Area I Burn Pit - SWN1 U 4- 8

4 rani [;event, and Proposed Drainage ,``'diinent Ua:iliple [ .c':~ttiiotis ann .kern its, I Burn Pit Area

e ? . ;cations u r Its ,

jw I

~~ . Itirtorical Soil Samples with Llevated I oncciiti .~,tim e of Analyzes -

Inc .

4 . 8

HDMSe00037356

1 ai Results - AVII .

11 1 i. C t i t t Lj a

Historical Operations Doeuinc its (c1Lci f ;Ei« ; \crsiM

=1 F1!'E li)'`II t .-IK,_j VOR

L;n1ts I'M- the I,TF and A F 'a l I3unn Pit (`, fieand Rccenr Sampling Laboratory Rcport and Dam Validation Report .

Recent correspondence and biological, Cultural, and PaleontologicalIvesource Assessmew . Pathological surveying documentation .

;IPI eNi E .''iBP Area Addendum I-IASP, QAPP' .

. . . . . . . . .. . . . . . . . . . . . .. . . . . . . . . . . .. . . . . . . . .. . . . . . . . . ..

d :rt a t

t e le.. normal _ ~, TT < . .surrounding at(-,.,, to as die

~I icad Laboratot liiorn _ ,.uitial s ,_~ dndttal pro , . . . .

Ii [ ,r ~'1i ( - P IOCUSli1L ttri Luf1 , . _ 1 _ n t tEi ' / . . s'}' _I ;r t 0 01 („ =t &1 (&(MP B Rep" .- cu w ,' _) O PIt _t€ I

; Lloiiliii TI Js stlmilij-r (,i the RnVIt, of .' mil()nttiem

131'✓:Gb~!o J o tl'. . .t- ELF .,E_! J o tt n ..pro €CsE ~LiIJ f! Et 1 ) 0 0 51 0 . :

character'- A101! <7t divines 4GIIsis.. .St , ,il the on -going AS ` t swo F ,. t tl ti%(1 €

RCRA Corrective Action (R.C e / ' _ r c,E, t' n i .

Ho cod, Aerioo I' : '~,i=gym Cil ~~hF C ~~) 1S (tllC (0 lice tte i/ s'511 g 17i'L ,

l .i,l , . 1' .ttt' s.il' a .t ;i it SEt£ii Itt£r ;̀a ;€FEiS at the ' S['l,, and is 0101(1 , otiniiwa Oils SI1onritentitiCn)t! hms , It .( y (0140A) P .;6..li a ? tAwnr ()f To!". i1 .'- D bs ?:`tne r Contr ()TS(') re itlatua't mighi (1'' 0 i, P)-I) . Che 12CRAL CA process includes Our phases to achieve. site cleanupand clc O MTL Thu r i . iJude the RCRA Facility Assessment ( RCA), the RCRA FacilitylliV tt`cli :Y (ELI" j , Col.'r-l,etiVt ; )Measurer : Stu(y (t ' OS }, and Cotrecclv'e Measure s

linple, )etitatt(9 ;1 (C'is' l phases . .' reas being investigated as part of the RHY include Sold".J niis (SVVM Js) and Was of Concern (AU( s), which are units that hi v--

used, Stored, or handled vat ions hazardous materials . S\, VPIUJs and A(~C.s undergoing closureas part of the RC Ai'. prograt[i Ots,'e been grouped by location for ins estlgation and are calle d

Fb; l ,itc :s . T ht Ogled ( . of an Fit i )vestigatAn is to characterize the nature and extent o fvI]t.;tl'll ..I r;r'; stv t]'l? ,iE ;'tl is e t€( t€l )i" 1:l titl medic+, evalua te risks to potential recep tors , ga therdata for inc ocot phase oi no € C .RA CA, [lie CMS, and identify areas for additional work .

`.;aloe the eat j' ` ; 5t) t so ohariicterization has pr occeded along two parallel paths, oneNo groundwater= and the Oche t An soft and relatedsurficial media . In 1999 , DTSC 'normalizedtliis ,!pproach by identiiyird two Operable Units (OUs) (DTSC, 1999 ) . The OU : at the SSFL=re . 1) theo Surficial Media CU, Iconllir sed of soil, soil vatior, sediment, rut face water ., near-s?iriact 5tc t edsvatel, sit-, Eiot :,_, and "'eatheted bedrock ; and, 2) the Chatsworth FormationOF O'cOll 1, c€ tiipr sec of We C nlis\-vorth Formation acluifei, and both the unsaturated andSit'hotter, ',!l nu_ .tlietelt omp1 o ni) `o `molt . This di Mfr .0 'ham? hl'l Work Plan (die DraftSs'v'• jl lOot has heels prepared as a step toward the, goals M' tilt' \ F I program throughcI_ar t(tc t%:'? alai of die l atrt ire and e stmt of contanlinan oic in s u i ,ieial media at the tea I BurnPit ., .iii°c'i l `, c -uli ' ) , the i ner

l

mal Treatment Facili('i 'CC) , and surrounding area ,he raw rile' LI.Y f i ..1t' . a, at, tilt'. "A IBP Area, " slit. ow on I 1 igro r ,

11 f D t t i t [ E ?tl f+?t 1 €e_ lit s tI Vol ; ;1 :, ._,C: 'U '

Y.:dEG aeS tvvs 2i .11!~ (QUA 'Saab, aT5 a i1 u, Y ) ft 1€„it Of At kCR1_ S . ;lain (C'gdL 1

t P Area RFI investiga ,- ' i" 6.mod ifi . _Iris ,weft Work Plan ar~. needed to cl . _{'c _L c, neriis., ncl,, _ tu ggrounuv; tIn- ; idiways . When the AIPP Area RF1 __ . E ,libation is completed, allresults . i in a comprehensive RFI report,

HDMSe00037358

; ng Awa5 Oti ;_, k;izt,;g; ated description 1 li~l 1

F :e we, The Group Rt'1 i, rnolilu2 e .\ tilt a

-iz :,aion completeness, .ansport and Cate of€ <ii risk to receptors. flee AIBP Area is hielud c

_ % 'Io [Is .

1 .1 Purpose

jo 1€ At -11L u csotahc~i-,,.i-_liPC _ .morcr

it appro . . :iiiately 5 .8 in ._ J-ea And i s?,r_ 1-,i IA t id t 1c <<t ; tt;_s di

785 t . 7 i0 feet above c>te € ;,es I ;vAA (iv 3i .) <,i id _i.w

support of

Bowl Arm . 4 .-5 and AO(N )Area l l ese , air (SW NH J 4 A 6 )CTL 111 (` U i\€i1 % )Periniere 'arid ; f ~ F fl -1 .17)Area 1Bu o Ni vid -'I%€J . .5 )CTL (A no 1 NY' )

i l€c :tic€up .ly I :E i repots cutrw idy scheduled for completion in 2008, ,\ ill to suppleineiiie dt:_v two additional R1'1 reporis, including a Site -Wide Groundwater Report and a Site-W''';iide

true Runes Risk- Assesswoiii L ,,port . These supplemental reports will 1 :u, prepared a sinvesL ig thins or assessments 2lis con ipleted .

The purpose of this Draft \Vork Plan is to outline a detailed site characterization programocusing on surfical media for the AIBP Area, which will support the preparation of the RFl

Croup I B as previously described and in response to the 30 August 2006 letter to " fhe BoeingCompany (Boeing) 'trout the Department of ToKlc Substances Control (D'iSC) regarding th eA IBP Area . This Draft Work Plan will be Iinalized (Final Work Plan ) on or prior t oNovember 30, 2006, following completion of directives contained in the August 30BTSCletter including :

(iron

iA res:°iew of documents related to the A113Pwhich have been reviewed i tthe duveioplnent of this Draft Work Plan ,A list of wastes and waste types, locations from which they cans , and a listing ofwhere and how wastes were managed at the AIBP Area, based on the documentrevieoV document compilation and search .Rationale for sampling to characterize soil and sediment within the. A!BC Area ,melee inns p rocedures to screen soils and debris for radioactivity ; andRationale for sampling to rharactet - izc° sediment down gradient in the eastern andwt-stern drainage of the ",,IBP Are a

litiplo1nci 1tetitln of tllc i i€1 EI °Jorls P lan will proceed in an iterative process to prosidreharaeief izatiein ire (this di :i will addre s .ir disper l ion . groundwater and ill[ iacr eate r

pathways co osisti°iIL w 4h €i . SS FL RC CO progiain . In addition , the Final `,IoikMl address !dditi utal operational and facility information at and surrounding the

data

HDMSe00037359

or of th ;_(II Lsle ( illc ;cc;ter ; ?

'loll,) it v 'as esu 'rlt s lini in appro;alnatel !958 MY the safe disposa l

cltet~ It t l fuc_l~; lzv eoi)lhusti(1o, m osrder to minimum; potential public MOM "t"11~"(ll_,1(z reslJ. lt iron-, transport across public highways tc dispose in conventional landfill .The ;ite vas' operated by Rocketdyne Protective Services personnel until N17 1(R ck 'c11, 1981) . 11c site was closed it) 1971 due to Or pollution considerations ,and "as in i Li `r. v jib the exception of a few fire department denlunstrations an dtraining ex ercises (Rockwell, 1981) .

[he Area E Burn Pit (S\\ MU 4 .8) area surrounding the " 1'I 1~ Interim Status Facilit y(Figure 2) formerly consisted of three earthen ponds, three concrete-lined ponds, acontrol comer and two explosixes storage sheds . The six ponds ranged in s plum efrom apl)roviiniately 200 to 10,0 00 gallons (Rockwell, 1981) . Both Concrete Ponds 2and 3 were historically used for burning wastes (Groundwater Resource Consultant s[GWRCI, 1992) ,

The AMP "'as l rtmarily used for be destruction of explosive and flamilial le waste sby open ,,aiming (OiWRC, 1992) . Wastes treated at the AMP primarily includedsolvents and furls generated Fern other areas at they SSFl- (SAIC, 1994). In addition ,historical records indicate that sonic wastes from off-site locations were disposed of atthe Area I Hurl) Pit . According to Rockwe ll (1981), the following nalerirlls wer edisposed of at the AMP :

b 450,000 gall o ns of fuel s

2 1,300 gallons of process chemical s

Ell 0,924 igniter s

13,810 pour, b o 1i ;lctl 'c I))dtal s31,717 gallons (l1 organic so lvents5,121 pounds (,f e\plosivc s/ 2,93,2 ciihic fei.,,L of tul IC f Ig 21SCti

191 LLflmis of heavy ,meta l

silty

I "ۥ_'.1

W -W ratus Facilin As within and Dust the ee .uer o f dIlL c %lt k 111 ,II `tor,t1 _ I 11 Said formerly consisted of two eoiocc €, pad (I t~ri; 1 1 . ) 1 . 1-d _!;Its etc

2' ;1 t t` . N , 1990) surrounded by earthen bcfl 1 , , 1 "E^ ,) J-!1(2 ln[~ ; im

HDMSe0003736 0

I'd

'Lo utia11001 ,.if, %il, . 11ip . 1'11C i~ ; snvated on Quaternarv

ll! ri II- '_ . l . aiL `'u _ll €'OrmLttiL ll . and hcrirock rangess III dept hAIL"I( ii oi(illl'lO lll` I c,at`CL ill the I Ljdwas ?

t_i . U S

lly iII 'I''t

C idi ill the SjV1v'1(1 4 .8, . i1)e , Vh_' alltl d1L `I e'[ i(IL ' I i

'1 he`=e, respectively, _,ll d '(pci-atio lc, and (Vasa. I i LIdlalg a(teal f _0 'i [ 1 ",7

is . ._ <<~z. ~ ~i_-f ~_. . f .i ~}•~'.;'

M . iGee- . Ail UL.L , alai . LS ._ Liar

lid

r~ : Ca ta iSgo {Lt!', f,? [U ~ f"HiP, -were tL\te \C to cvaluat~. Uie i13~ril l(-i ;: ;r

ai (3 '''f C I! t , :icl! invd r . i the Area s Rwri t . .-s'!,cu[ f n its re .- n _

[nCIUC e Cl .:if : t: ;iCL4 i U 4i s MI i"ttt_C[ lo is 'I 'SC Or ,': Lt 4:.? 11St t} _'O(f'r aid ,''_Lif!- Lltit t < ., . 1 .=v

ally other dc',Cu iiciits °l f e a. ih i Punt it (t-. hoth .t d to l t,`d with die°,

took Coil Pon) .

Additiona. dueLt nWnts at-c-, under review and include aerial photographs,

reports and correseotideiicc : the -will he used to identi(s' potential historical dis ;osid

areas and to re 101 thr scope arid area of investigation required for complete f?lf

characterization odo; Areal Burin Pit - SC, MU d .g and adjacent trek . 1'h~itrus,, .ph .related to the Area IBurn Pit are also submitted to DUCT along with this Druf W orkPlan .

Historical documents reviewed in support of this I)ralt work Plan were used to createa liWiilie of wastes and waste types at the A hiW, locations front which they cattle, andwhere mid how wastes vote managed at the i\1BP . The results of the review were

used in developime the pi-elintinary proposed sampling pln, including the analytical

suites required to characterize' identified wastes, and in setting the level of personnelprotection .

l)tirilig the review, documents that contained information ahout the origination,characterization and/or iiianagemellt of wastes were identified and evaluated . ' ;'hisevaluation was used to create a list of wastes, chemicals, turd/ ortheir deconipositiaiproducts , that have the potential to be present at the Area I Burn Pit (Table I) . '1 hislist of chemicals \\ras used to develop required anal y tical methods .

11C fist of usasies, chemicals and/or their decomposition products ('Ca'ttle l ) and a list

of chemicals that We been detected (Tattle Ii) were used tai identify the suite of

analytical methods to be used for the sampling (Table lll) as well as to modify

sampling locations wlien appropriate .

E('uita of his oric"ii docutilents related to the AIBP is ur -going) . Revisions to uti s

Draft Vi ork Plan may include modifications or addition of sampling locutions anti

a .i f,In it Ikethods based on information developed from time cni going cloculticti .re vif vv . As part. of the AIBP Area RFI investigation , the historical documents v, ill Ci.con .iuiLd end SUI-MAtted prior to the completion of the Final AIBP AreaRFl `VGekPi : n .

HDMSe00037361

2.

~a?c~ uric euI iy k~80 ' ;the TTF Interim Status lachistorical act ,,ities incirwe :

.c,Lcl ,irve0r.8 ,L ions and actions h. . . :> hPen conducted a ti :`Lrra T Burn Pit (GRWC, 1992 : B(eiug . 2003) . These

1981 -19'(I,! tteopl] Catl `,u1 ,w ing, remedial l EC iat .( 1i,`:., atti It (,mils

(1990 d iI Y!"InjIII(u nd a€zl1ysi s

19 9 7 )~,,sI metallic-anomaly excavations , soil Sa andanalysi s

® 199d Soil sampling, and analysis20()}; Soil leachate and surface water sampling and a,i l .<s.2005 Soil sampling and analysis20OO Soil sampling and

These activities r re described below in more. riot ill . Fioare'," 2 1111-oilgh q inched srlt'cerdanalytical results from the samplinl( activities described below . All Acre ciucl chemicals arpresented . Only metals vsith concentrations greater than SRAM background levels are shown ;all other concO ntrations of inctals are below detection limits and ; or SRAXI hocdgiounu levels .Dioxins are presented as calculated toxic equivalents (i OS )

2 .1 13131-1982

In 1981 Rocl yell International Corporation (Rockwell) contracted [larding Lawson

Associates to conduct a radar scan to identify buried objects and disturbed soils . Numerousareas of buried debris, disturbed sails, and locali~.ed subsurface anomalies icieiitI 'led usinggeophysical Cquipnient were excavated . Approximately 1 .600 cubic yards of materials and

soils Were excavated and removed from the SWMU, of which 1,300 cubic yards were

designated as non-hazardous waste, and 300 cubic yards were designated as hazardous w a.ste .

The excavated areas are shown on Figure 2 .

twenty confirmation soil samples %,yere collected from the excavation sites, and outbackground soil sample was also collected . The samples were analyzed for a suite of organic

constituents and selected metals, and the locations are identified on Figure 2 by thedesignation "0229-11 ." 'H IC analyticatl iesults for these soil samples are summarized onFigures 3 through 6 . The work was performed under the direction and supervision of the LaosAngeles Regional Water 2uaild f t ;rstol Bra d (LARVV'QC'B), and was rep, reel to theI ARWQCI3 and the 1)115 .

In August 1 98 at the die ti ed i f Rockctd .VlIC, eleven SOil saiiiples wee collected t1 'Pcoek\3,cll `r ni arlotl': ;t ; die ,10M" . The soil samples were a?ni l zed i,()I iiiclulsyolatilc or"aanic compounds (\1`()(-s) . The anal }'kcal results for these soil samples irepresciited in `lppcnd2a C-1 h( :sVC,,cr, the exact soil sample locations ssccc not reported .

lti l'1 'i Fl_II ; 11"'90, CVJG sax 7I ;1 . from the AIB1` wee collected 2 tla CRocl~ctdvla e for chemical c n' :lvsts . iple analyses included metals . se ine s lato ,a ' Oic

compounds (SVOCs ), ail , .r ",_ -111 u t _tyttcat results foitllcs(: so :] samples are ? r :esei~t~,:~(p e however , tit-, '!21 saniph ! .cations were not Leported .

Is i lil(',

HDMSe00037362

1992) . Th ,sx .rples are prese t

t_Ct_ ~ : i :(r( .Lttta l t<. a :sa : tI f) i-'flE- I it `eophvSICal sui\'e'T tlC€J55 11 1 r LS n a

LE(_ .t~,~a; t LC1 dCl(~CI E1[I1iCd PIICt l C)l)jLCL ; . ~flt I the ;llr'f ai;'R . .ct l

oblec ts . Ilc c\ca\' ;ii n luc .ttiohs . leased oia report [halls, are shov,'ii on IL figure 2 .

perSf)Illl('I a[seil t he 10 ;WOL it granicIlt mal l' es a guide tot Caicate and rciitov u I nddi ! octal

collected at the request of Rockwell personnel during the geophysical survey exxca ;vation .

identified on Figure 2 by the designations "S L-n " and "RR-it " . The "RR" s_mlllles wer e

Plan and supporting 1-lealth and Safety Plan (GWR(', 1992) . The sample locations ar ewastes disposed of in the Area 1 burn pit, and are summarized in the Sampling and Analysi s

`'F.'CpE : ; (CF~''l C' . 1 ?9~j . '1'Iie .e ei feel analytical suite vvas nevi loped based on review o f

199_) . l'he s'ii iples ys crc aEnalyzed for metals, total petroleum hyd~ ocarbons, ~t ~'s, and

suite :'. aid soil boring locations sscre reported in the Sui ipliip will -firedvsi,i Plan (GWRC ,

including three backgroundsampics . from surface and soil boring locatio ns. The analytica lI1( "tag die surv'c} , at the dirC:ctioii of the IYI'SC, G \VRC collected 70 sod samples ,

Specific analyses requested for each of these samples were based on materials observed at theexcavations . The sample results are sulumarized o il Figures 3 through 6 and are included inAppendix I ' . Operational. structures, including the - TF siraictures (Burn Cage and Cylinde rTreatment Area) were removed in June and July 1993 .

i /tiay i99.s

pcntachloiophcuol, identified aat sample location Sl .--I in 1993 (Figure 3 ) . DTSC requeste d

based on the elevated concentration (d 1,000 milligrams per kilogram (mg/kg) of

thai new soil samples he collected its this area and analyzed for diox ins . GW RC personnelcollected four soil samples for dioxins analysis from within Earth Pond 2 of the SWMU ; thes elocations are identified o il Figure 3 by the designation "DR-n." TEQs calculated for the soilsamples range (roan 0 .117 to 1, 880 picograms /gram (pg/g) (Figure 3 and Appendix C) .

2 March 2003

the gealeral vicinity of the Area I burn Pit for perchlorate analysis (MW11, 2003 ; Hoeing ..

NikO<' :r pci-sohnel collected seven soil letachate samples and four suiiaace w ater samples f~'01-1 1

200/0 . Perchlorate vv,as not detected in the soil leachate samples, but one surface ,vate rsample coiltaiiied a perelilorate concentration of 0 .0043 mg/l ., ja,st slightly over the r eportinglimit u'' () . 10.-+ mg/L. (Figure 7) i `z,ipendix Q . The sampling v, tis periorlllcu aL tua ac :.}uesiofthe DTSC .

ll , ,`inGE ii n ci c I .z it 7 "- (, f'_ Cf' ei 'caitO ~) l . ^' p(1sol id line!acU t_ ion :- it c

r .V i_~l(2v 'nf- .ii1 .rlC z 21)0 ' I fir 4a .n 15 te I i il' ~]rili`-. On s',V(2 r Ct~., a igu enitiiedby the designation "T LI")'E ; . " '11'Q valil, calculated for ilt(~ five soil samples range from8 . 18 to -"7 .4 pg/g C1 o ~'

HDMSe0003736 3

I i . iS . . .

2~3 1 C ar'

LL :u F - .suit samples, k

2

samplnk8 _i i ; __nai-jsis outside the SWMIJ 1 .8 boundaries was to hrov i d c framework

samples , . : ; dniiiiagc it uim ni, leachaLe samples were coliec ic8, It purpose of th e

",v/( 1 ,

- tlc-li is

o -a/whi:nMeusra. ti L °h t jdr'theArea _ . i , _Santa S i%. ;ia;i t /eiC! Ct lviuto i, Vente/'a

(DfSt, 2O0(:) (9ctiside the `VVh&LJ =€ .z Louildaries, lour soil sal iples . seeco surface soi l

characteriza G i? of drainages proximal to the AIBP .

'iltc 1)0-i ;Liiiq-,lc Ic rci :iotis (Figures 7 and d) are ideiititied by th desizoalon : i Vhii,, ."T" 22 &- and ` t,i i✓ Eii" . Samples uctc cheered hum 0 .05) lest below `ground surf,1CC (ogs )(scdh lr,€ L }li plc.), ( - 0 .5 ind 0.5 - 1 . 0 feet bras; ; WMI v,"ci cnat ;:CC! IN f W CQ

biphenyl' (Of'Os) (Table All iii Appe ndpiw A ) . The analyses; were performed on the soil

polyc,yclic aromatic iiydrocarhons (PA as), dioxins, perchlorate,andpolychl)rinate d

leachate samples . The 2006 analytical remits are summarized i 11 Figures 7 and 8 and Tables

atria sailiplr--s °, lilt he essceptioli of the perchlor rte analysis, which was conducted on soil

A11I through ` 1t in <S±_ppoir.d ix 6.

is Summary of iunalvtieat Results from Previous Investigation s

coilcentiraiioins of chemicals ci the Allah' . The data and available AIBP history indicate the

Oct. Scat +.,if i ece[ t a_n-dy tidal data ied€eau; the locations -ti the most lighly-elmatul

c ;l € ,: : iiig sift rCC rrc is .

Li t ✓artu t-otia 4 area qi iikures 2 l1110 2) . l hQs calculated for dioxins i nrange to a max mum of 5,257 .e pg/g, as reported for sample TTFD-f .l entachlorophenol was detecte d at a coneentratic n of 4,000 mg/kg in the sample fruitoc.-aion S O-8 .

~aiitile 0()C iio [i lf [ -8 (Figures 3 and 8 ) . Chromiulck i111pacts . ~'~ r . oieiuiiifi€ A ii i

ainnplc colic c red Kim locations RR-8, based on a detected coacenmiatioti (,,l'860iTAg (Figure V .

enc enti ati ai . of 260 fig/L, rid i . :.,ills -sere detected at a calculated TEQ

i'ili , i acili€y )erC11101-atc \ . <, detected in soil lc icilate sample TTF _ .%4 at ,i

I u _ ., Oita .,oic,s 1 ~3CAiIal ' €'h ;, - ) i e3u .L1 Plt2 of the 0T "

(will €E "€' ;ti 3€i ;l .._ t , y 0 )

lrht aunt hy6roc ~s

1,-,, and June ''C

ea. Fifteen sub s!, :n the TTF Inteaii

sto provide L( r-t- ; !

., p . oposc;8 ht a:t

e collected witli i E td 1 4 .8 boundaries ,

setsonnel collected L _al :i125 soil and sedimen t

cility . The purpme of Ids sae pling and analysi si atioli in kcy, loc_aic;ee 0i1 development o f

. '') :;rains with a cal. a au i . iis TTBS53, located w former t c av_i

Concrete Pona .cotn~-:entration of 4-Jii ti red iia :1,,(. f ~ t7 .id, < ' ;d in Sarrip i(- S ~ : C . ,r('rlii thu; ('";~ (:cduai W t_t 350 a «1 t ; . . . .<<<_ ., I at 290 lug L' cop1-a j

E alt l lei ;1 54 g and nickel at 1,30C

h -ai rjrd 3 ( " T(L was detected at a concentra iwt)i of 15) ing/ :g

2 .9

levels are co- located at Earth Pond 3 (Figure f) .

_il ,e oIL frc iii - AS On bgs at lacatiF n SL-?h . L. I . . aine sample ,c. Ltirii t c r :ic<rI<<fti aid 1 1tydrocarhons ('7 (18 as Sicsi, i) were detected at

CSC VIM) RgI' m! - , 400 tug kg . rC .spectiv 'is' .

t'Is cs dcc_c.tcc~ 'Jiev areas o€ the A113, include m v.el a nc~',1,<attoils of dinatns,pciclilortac . VO( , ;, l-eti-iileLiiit Its drocarboits, cyanide, and inu :tals ahitve ,`SRAM

background levels ( lS' ama t s 3 - 8) . The highestcalculaied dioviii °-EQs it the AIB Pare t 1?t.rth °ortd 2 and appear to be co- located with elevated pentaclilorophenol an d

metals a,ith concetitraiions above SRAM backgrouixl levels (Figure 3) . lie higlics lperchloratc concentration detected at the AlOP was from a saimiple collected fromBurn Pit 2 (F:iguee 8) . In detected concentration of chromiuma at 860 n-rg/kga tlocation RR-8 (Figure 3 ) is ahi,vc; the SIRANI background level of 37 mg./kg . Theelevated chromium is co-located with other metals with conceniritions exceedin gSRAivi background . The elevated TFQ dioxin concentration him sample TTBS17 at

Concrete Ponds 2 and 3 appears co-located with other chemicals . including chromiu m(Figure 4) . TCP: . petroleum hydrocarbons, and metals above SRAM background

Eased on analytical results discussed above, areas with the most highly-elevatedconcentrations of dioxins, perchlorate, chromium, and other chemicals are identified ,and their extents are generally constrained by recent soil sampling . These areas ar e

indicated as sourer areas tarar;ted in this Drah \Vork Plan . Other areas, including

migrational patli\vays, data gaps, and drainage pathways , are also addressed .

Summary o1' Drainage Sampling Results

Surface water from the ATOP drains southward and ultimateiy to Outfall 001 (Figure 7) .Soil, drainage sediment, soil lcachate, and surface water samples collected by MMiWII bnwcc 12003 and I)ccenilier 20(13 indicate that dioxins '1-EQ coucentratiomw range from 8 .2 ps/g nea r

le A113P to 0 .31 pI;/g down-drainage :if the A113P, which is below the background dioxinsE) value of 0 .9S pg /g (ItiV.'11, 2005a) (Figure 7 ) . Perchlorate and PCBs were not detected

in samples down -drainage of the A1BP (Figure 7) .

Ogden ( 1999) analyzc6 two soil samples collected from I;e o; tecu the AiBP and C u tl' H ()f ;

rr:portcd as t, 1 ;tiu 0A)7 pg', which arc both below the backgrctunu ieSel 4 1) 39 lag/g _

aiid down-drainage froth Outfall 001 (Figure 7) . TEQ cant c littatit is act dioxins were

dill . V lCS. PLUS, S V OCs, c i tergcncs, Perchlorate , and formaldehyde were riot detecteu=,.atlier sampli_

HDMSe00037365

-j( : . y alum :; H 1 : .: geographic and vertica l

impacts fro Y ,1, i 1 . ADS) . Based on the ava iaulc daiu, :here was noappar ie p. itf_ i is 1i[ t h ._ ger " - =1tt_ C ( W ei isti ibutio ill soil Ee < . f~ ~.?! £)(,1'[C! metals an d

WNW % _ ;I .1Ie ` "urn conducted to c, ~_luate the potent l of airborne

t,dao ns S; _i € "H t`? i U UAS W ! .ate: .iiri E ._ .'e dispersion and Jcfe k e l cif ; 1a cLa contaminail':.

1<<};-i ( .i,Uaa[!t, o i 1 21 I(r 5h) it \Videap read disc ibuii 01 OF ran", : nigher mete s

~`-`l? i iii}'] of ~J_1L2uttt't~1li i,L has had no apparent SIguilfC izs A eci on uacl ground

uvat nelif al Ca5, ' I nd -:Stir} iaa_,L ;rI A higher resu lts with 1'lrlc i111ed soi's indicate Lh a t airborne

e ileen o",i, I,s, lih i~tciC (I tO 1~ € ~onC„ iifra~nons in samples tie~lie Life €Cs ILig {1 ~h ( :E! ta t

data sut soils . H AY ; 0)51;) . with other pathways, Or dhpersd}I i azhiaa "s from the Are aI [Barn 'it W ho addiessec in the Group II M report .

to areas witli ;L .al, . .,d"met. S .'r..'tJ

Filial 1 .FI Work Play o: it i _iclude evail3 a 1 . i and.o: potentially impacted r (,a~ ilorthwestann ,( LhLca sother areas outside o LhL .1 4 .8 bounda :a .

I.ti . DON A w k, w k 190, ti tr i •% . u . vs if Welineate the la tcl-a.E and \ n l iieal extent of prev i uaSiy-ctet(' :!__! t'11 11I!:%l and r i po ced the o iic d \.va tes disposed \\itlti l tl C` defined bot! tndaries ! ;l the.N,ri:a 4 ~L ' i f'ii - I.E _1 At, It tali ee d sampling I cati nos LOP We r<a .idnale and scope o fthe a 1 aI V P c i ~'tre ire bpoci ca Ilya aim P at characterizing- the extent of impacted soil in

knee a} scalrc_ ~t`eLI aiin( i.b .[eatte p!'tel€tlal impacts in otht°i' paon of the RIP i :_i'Ca . The

ai v_tca . s i , ~~ valua t• c` Ow ~J.n It '_iitltalla~ . sulk K chclcal impacts at the e 1 ope~~ttluua . areas of the w1M~

lair'-'est 1 1 rrav of Clielilicatls at their most likely locations at the AlH1' . The purpose- o the

ci tie I ist(~r~ca i Utacuit m revievya . The eSatended analytical stilt! .; was developed to capture the

amts anal suites ' .en is de\rl( tie f Pitied on historical and recent analytical data and tilt rUSUIt S

I lie RI analytical suite is designed to aid future RFl charactcriiation activities . The purposeof the ;t hl analytical suite: is to ev aluate the lateral and vertical extents of chemical impacts i nareas outside the main source areas .

the proposed samplin, plan serves as an ameodmeni in the ,S'i!pp/e ;ii ntal Soil Srimpliilg Fla n

(MM j Ks t l laley it Aldrich, ?005a), and draft DTSC comments (D`I'S C , X005) . from

jar the Mimi/ /IC(ilinCiii l' ci /111' (77F) ui id .Pr(a / Bw-n Tit-Solid Rune Ploia,g'C'uicm, I Init

described . AltP RI'! investigation data will be integrated into the Group I B reportin g

PIan. Ile sampling described herein represents a step in the €RF1 process previousl y

which proposed samples and exploratory trenches are included as part of this Draft work

process .

1 lie AMA T sampliiiee desc riptions are grouped into tour general categ (

Souicc area Satllpling ,

Disturhed ai(a sampling ,

a Migration pailivvay saillplirtg, an d

Data gap sairipilng .

to better clarify their respeetin objectives and analyHeal spuroaeii's . Ito pRip!tse f s! ;i l

all proposed soil sampling are presented in . Table r:1E. and are 501111 1 ari ;ee bern

sampling locations are shown on Figures 7 and 9 . Specific raiii(lnale atad aitaiv ical suites fo r

4Ida aa Cap i 1y @krs 21t - M ' , Al l

SW MU 4.8, based ii p ev'ious eon ironirenral HE ;`sngw a

Proposed sot .te : a `.iitpie !atrp CL known 0) ! :,L

documents related to I 13P . tile- sample iota! ii VC target p; 11 _ ✓ 'per-

LIL_ ea

'I . 1- i c t `epartmerit D);iiioil st f `'i ') i lvatiofS l

I FCC itc-ti€ . . ;tatiiS R ila

Fordl Nowwerr_te :AnNs __ Un 3, and

atioi t, rca ,

l I t c s _ s t tlsi's v'ill fit; : v} a1yzed using the e \tc ndcd c iv t\ deal Suitt-' in, !Ti'ltC, i s

~~ ;_~ L a~i alp areas , . ES known e lc :., .e _ of impact l`!'`ej : 9 and 9 _€b le Wy lay iitraUlttli!1 .

the Stt ;ilp)IIIg teeatious will SCI- \'e t , delineate tlti_' lateral and \,'i`ttic :tl careilt o fchemicals in soil neat the lviev, .l sf urce areas .

d, e C

1°rt'i,C'' ~l 9isturbed -area samples L rget cettn tti soil disturhaner of unknown naton. .\dithi€i the S v 'Ivt U boundary . The sample locations target the pet inle tet of lpi hoaryoperations areas, debris , and structures and include Rev AlPP features and forme rgeopli_s sical anomalies (Mgie e 9) . The proposed samples will he analyzed using th eRh analytical suite in order to evaluate the lateral and vertical extents of chemica limpacts at the perimeter of source a reas and at key operational features (Ta ble fV) .~ppro~imately ten pei-cetn of the sanlpies will he analyzed Wing Me extendedanalvtical suite .

t )i , :atEoti f atliw at<vs;

1 coposed migration pathw ay sampling Nvithin the SW[RIU boundary is designed L Oe' ;tiuate the (potential rnigratiotl of eltenlicals from known and. potential source a}tar;vvcitin the A 1131' due to erosion and sediment . mobilization along current drainagepantvv acs . The drainage pathways at the A1BP were selected based on the curren tAlPP topography, operational areas, and potential source areas . Most of thec}licrational portion of the All3P drains towards forutct Earth Pond 3, near thesoutheastern corner of the WNW boundaries . The vsestenunostportion of the AIB Pstrains to the west and soutli\vest in the `sestern tributar y' dr : intge (Figu e 9) .

t raiuage i itliway sample locations at the Al B1' are spaced evenly along the dtarinage sand 'trget drainage areas of ope r ation-al features of the relItPD (Figure 9 ) . 1 h r-m-of-,,used sa nples will be analyr,eci using the Rid analytical suite in order to e\aluat .~the ametal and vertical extents of potential the inic ._t1 idnt ;ac(s due to sea tlleiit tFiig _ du i

haa(it IV) .

3.Ie

-uta gap satkrr)in?a 'ill `l \`, dine ttiC , „1 .̀E! J boundary, butou N iuL "-

source ,.?eas and - ~iisrtt i are-s . ,:' II... c on inint ie €lat analytical data and oi, ,, n : a.C„

history are lacking ;`) . 1 t l> c,l, ., ; d sEtn;ples e ill be analyzed using tie RF+'s}-e' y tical suite in order i .r es aluatt; anti SCi-ccii ht litjt '.€ itt} rt i in areas that

HDMSe00037368

7 l !lain < < 2, %he L'aJ??1

z. -luf ll(aitil (If t!; J 4 .8 H E, andlate .

il ~,a. Valli aLii 6 _ina e of Hit Area 1 Liiil l It I ., Li i L ji 1 %`__ Li X11 E,¢ C ltE°t' h 1a W An kll(A ill and potc ilt ial (iLIrc a jtle

(3(}liui l-' ~Ls al ontg1~ d Ic11€lag pmd- [I\~„ . t_CiCr IilY . at; iLl tatC;Lli t " ~ .l d"

d; Fli ft i_f he AIBP w ill be ia s&;ssed in cirdcr to e\ alu . e impacts to tllc \\Lstcl ii No Anydrams the w e s tern AI BP . .rea, :line tllc eastern tl ifllit lr\' if aina `~.','. 7

and a W a.l in and eastern tiidutas I f arm it coi11Luence smith of the A1BBP, v,'hicl

?IitII71 f Lads i ( 3 )L Li ali 00 f 2 a )

til[_t SY NYI -..tr i<< tl(, ft_ c t]j» along, [hL LY-II,UL FV drahi'i-g e r: °I . ! :(L lf . Li' __nd. ..

also j acget locations a 'eniii!cal depoltiiti (1Il ( sand bars , banks, and inside -curves (1! cilallnels)

(Figure I -' ) . 1 at lvnpoS, .d ;;a i1 iJe', will he a naJ red us the W-1 anai ~ Y lrlb ~ kal suite , o ~ vaI u a c~ewe lateral and V er tlf mL( a' (u item ml C he111ical impacts :Fa wn dra inage Iran the AMArea due to migratio n (' "nh,11e IV)

H D M Se00037369

4m

[1L „ i i piL_nentatic n o , ' r,_I_a I;YE e -Jsi viii : !C-.eop .,,a t : .

<% u tll`€ ; ,Cc flc ~ ling il'ELtll m i ;,hoi as nLLCILd, i n undirt yip n , ,'. tc nvlrE'st nwrt u

u til s « .id allay i 1ic`,la ds ,c. :,pmcifrfed . TV wil[ ins ure that no dupUca0m Us, ;

( .`-it€',tit) -1 .S' (Haley & Ald ich, 2005a) will be included in the !Nab y: ark Plaa . Comm,

r :11 oserl e pll~ratory t, aches outlin in the Suppleir rain/ ,Soil Siwnpfrn, Plan /of i/toiiC' ri,Crl eatment FC,acliil\ OF and O 'na I Burn P'dt solid Nast 4 tail[I}cinei11 f ;i :' ; i

ir~aichrs are proposed for hail' Ponds I and 2, the former lire Ueparfnmnt De€nonstrati« n

A-en, ant! Earth fond 3 (figure 9 and TOW IN') . Trenching' within the [ 1-FwiI1 be es altiatedand melt€d u i, as appropriate, in the Final RN Work Plan . The depth of trenching will he torcdrock or the 3-nalamunl depth possiole v alt excavating equipment, and lateral extents will bes_artoled l;-N, "ihun11 held cvidcre' such i setining and debris . Site personnel are probibiteutram entering exploratory trenches that are tour feet deep or greater, as per the Site- specifichealth and Safety Plan .

Vehicular traffic, other than the excavation equipment , will be prohibited near th eactin c exploratory' trenches . It is anticipated that soils may either be directly loadedinto bins or stockpiled using the excavation equipment . Exploratory trenches will be(-,le arlti° marked and secured with fencing to prevent inappropriate entry into th etrenchin~~ areas during and after excavation field activities , as per the site -specifi cIr dtlj and SJiet\ Plan . Before the rainy season, the exploratory trenches will be

SC,-'tied creaming to EM€'s with devices such as plastic sheeting , sand bags, silt-few.l€tg toe bydt o- ri"stI ell to prC\ eti migration of iil.ipacted soils . The potential fo rincidental runoff from stockpiles v J11 be minimized by the covering of soil stockpile swith secured plastic . Surlhce water coitirols, such as tenipamary barrier ;, to prey entsu l ce water runol foot enlerilig the exeav Iioos ., wilt be inplenicntuh to coal !g t C

the Area I Burn Pit Lrosion and Sediment Control plan . 1 otenti~ l trcotcl€ hat ly f i 11 lu g"itu clean Al and locahLedrecontouri ig options according to h XiP s s ill ben o It€ated after review of Final RF1 Work Plan sampling r€ sr Its and op til a lWon DTSC . The general surface water drainage pattern s of the All; /t) toil notsign iicantl_y altered by explo aror ,~ t cnching activities .

~ .C 1`: d ccl method V, i h,-- that were .iatxlplr d. ath ,€ J-c,ud si i

excavated soil, then imported or onsite borrow soil or crushed rock may be used for fill

it is determined by NCPC'AR to he inappropriate to backfill exploratory trenches with

hotrthcrn California Permitting and Correctis,e Action llranr_h of DTSV'' (N(' )CAR) shall

approvc or reino e exploratory trench locations, observe exploratory trenches, review

analytical results, and provide approval before trench hacktilling will occur . Excavated soilstill he handled as discussed in Section 3 .1 .2 . If excavated soil is not characterized ashazardous ssaste, the soil will be used as backfill material, with concurrence by NCPCAB . I

material .

4 . J . I tSist-'li't'€nehing Area Ix tanagetiien

11

ti/ ['rt.I r r' =1ri t,y the approp . i, .i ni soi is c ;~Cavated neat iic - . .

wa, ra ;ited lea , .l .2 :01 , .'i, siorca in s, on g ii d, stockpiles or in ( .r ;_nvd ., .bias pendi is at,: c.,la .E~ct~~ri~ation and lcttt( ;\ al to approltr H,c ar,E,~,a l

LW Srvlphn or sod him, '°;!ih he cc)IllpiiseJ 'H sod frown a snow mHno ,L c}.-i ,i rI c ,ri( 1,r r tl' ;l lt) .

;'E.; Ire lurpose of waste i ri di fiirg i(r d isposal , chem ical ail-,, si ;- 5 viii is cC i

w Illeeutng representant,c sarlig ~,s of excavated material and ailllsi ns illeni . .sta crilttecl laboratory . hr_ ,.Waste will be elassihed in mC.Grdwoc a Ki cTi.Urodescribe( Li California (Code of teagulations , Title 22, Sections cc,?C l .21 to 6n2(~I . ;l .

n ily ic,?1 )esults. will i submitted to the appropriate disposal Iheibties or approviand disposal (ii , asic . moil- hazardous waste is anticipated to he transported in th einto rrpe .'allfcv Landfill ("g lass 31 in Palmdale, and hazardous waste, if cncot.!.+itered ,will he transported to the lKeitlennan Hills Facility ( Class 1, 11, 111) in Kettlcwan City .operated chemic al !\%ist, Ni _IUagcrnent, or similar peinOwd KIM. Dus tsuppression measures will he employed, as necessary, during the loading of wastetransportation 'trucks . "t rucks tlransport irlg excavation material will he spaced t.tappropriate intervals transport to the designated disposal facility and will noexceed 20 trucks per day . The trucks will be covered and will follow all Departmentor I ransportation (DOT) regulations . A qualified, fully-licensed" aril insuredtransporter or combination of transporters will be used . "I ransportation activities wi lfollow the guidelines outlined in the Transportation Plait for Interim Measures at i/i elieu / Bunt Pil - Solid it ` stc 11 'M llaelncitt (,tit (S'ii 1 U'O 4. b', Santa Susur' tu Held

lcil.>t~ ; aic;t t, Veitnrra ointiv, (ali(o itlu (Haley &, Aldrich . 2006b) .

4.1, , Dust Si .pptt_°essiu t i

!A,ppropriatc dust suppression techniques will be implemented during exploratoryircnching and potential subsequent transportation activities . Dust suppressio ntechniques include fine 5pravin~e of water on the active excavation areas . and coveringin active exploratory trenches albs stockpiles with plastic . Dust suppleSSioii_measures will be increased if visible dust is observed during trenc hing, stockpiling ,

times that excavation or soil movement occurs to monitor dust suppression

r<+Iuslerring, or transportation activities . Oversight personnel will be present at al l

procedures .

Dust a11u uIn, is

1,11C !l sl , l id V2ipot Itntni / it rr~,3grain is described in detail lit i t o

i,C 'tf and SAW Y P ho the :'ill he presentsd in the ental ltl r AM e'ltiis . ' :,.if s

<Mnd di lsi inoI :iIoring will be l~eriarCned Will upseiild and clown tvi .i%l of o l,_ ti(?Yip;

Tog " c i-',an'on ae l'dilles . Vapor monitoring for ` CC s, 1v :1l N _

iw Itiili! si'' di n ing actlt ' e excavation . On-s ite personnel in cie.. ct i':ifri Ci1C

unc /Ta iptiate personal protection equipment (PPE) IS outlined in the Fa, siw-ct'iic Tlealth and Safety Plan .

HDMSe00037371

Mu : L m I is " z.,-

each ebaess f: .o thcontainerized ;,i 1disposal .

«t iw Spee ,e Jd ._i'c r; .o trtti r Decuntainili 1i_iti!i rinse water will in La l l ectl:.d and

,ding appiobriare ` << s ( : cacr t," aii acd

primp

I,~i < .ch y V ,heSe objective : the prutposed stail sampling at the A Of still include the collectionsty <<,e and sub-surlaee stefi for we ll"'1ysis of the, Echovs-rtig parametees in accordanc e

ry ith ie ietical methods promulgated he the 11SEPA . These parameters and methods ofanalysis. W de VOCs (82b011), S\SX's (8270C), lormaldchyde (83 5A), total metak(o )I O, (,( ;2h, 747 : .',), T PH (0('1_i ., LHOA is (8290), perrhl(irate (8321 '1), iOtal antousiaeluding li tondo, chloride, suliate, nitrate and nitrite (300), pll (150 .2), PCBs (8082) ,

F. ('s in oil vapor (111-15) . OSl is (8270C, B/N only), iNDM, . (1612551) . hexavalencl .rciniuin (7199), nitroaromaties (8330A), cyanide (9012A), and total organic nitrogen andtotal K j(21dahi tiiirogcit ( .` tliiidard S, :ethods 18°' ed . Method 1500) .

The soil 'c uip;ling analytical program paraitieter Of and proposed analytical methods havcbeen ,elected to confirm the presence and i iagnitude of impacts front previously detectedchentieals and/or identify areas impacted by disposal operations at the AIBP (Tables III and_. )

Soil samples will he collected, prepared, packaged, and shipped as described in the RFl WorkPlan ;yddendeiii and the ,Addendunt Amendment (Ogden, 1996 and 2000) . Chain of custodyrecords will be prepared pursuant to the procedures detailed in the RFI Work Plan Addendum

and the Addendum Amendment (Ogden, 1996 and 2000) .

i ?. s per V i l protocols, duplicate field samples will he collected to measure the consistency andprecision of the sample collection . A target of 10% duplicate samples will be collected fromlocations distributed across the A1RP . Split samples will be collected in the identical manneras primary samples but sill be submitted to an alternate laboratory for analysis . Split sampleswill he collected at the rate of 5 %1 ofLheprimary samples . All sample locations will besurveyed using global positioning svstcm (CGS) .

l lie l'rEilo sin, sampling methodologies are divided into four subcategories :

Soil vapor screening ,Soil and sediment sampling,Explorator} treneIt sLtiuplin~_, andRadioactive material screeni n

tit 'La ~3iG "eeeirit o

i .~ 'MS Je .ra 1 'Ltpfii SC e(„ii=L iL>ii.1 i r € kfoguy Fr that

is f~ '3°" rt,'iPJrl ;,Ct2 (t ~LL`lS~i~ .,;5 it tElc 1 li ~i` o- ~Litm tLac _

SKI r :'l ;l '' i PIC_ will lie "(lees '_ . n approximn itetiphysical ai : iniu ies L ! to-'atioii vsiiere dcptl, to bedrock is 5 ice o r;tif es gill he collected :t iee_t bgs and at the top of bedrock at locations

15

HDMSe00037372

l ,ocations to be sampled and investigated during the chemical char acterizatioii, and al lsamples taken For chemical characterization will be screen usin(_, the nieihodspresented in the iii IS- approved Rodiologicrrl ,Screening Pu (educe , f1rea 1 Mn Ili ,(Boein(,' . 20005) .

HDMSe00037373

c lectec Yin a nand auger 'an shit si 0 at a . e : r at QU!r in r_ Step-o t,t 1; ci yes to 11 ! ww W ( ;i vis' :

ch s<< , debris, and 1 ec( sail .

wi 'fatllaec s< tigles will be collected at low spot, of to d Wnige ch :_nec! . A

`gin sa ul) ie Itieation s in down-drainage locations, sediment sanigles will :)c aril LL':d

015 !t ;"'g' , Jcivi'L i, _,-_ [i bgs and/or just above bedrock . At the mI1t1 -i : .~_ lt;psc . is pl clocations 'linl;les \vih he collected at 0 .05 ft bgs , between 3-5 It Ugs and/or justabov c KKK, «,Wbin diainag e, Bank samples "Al hi' collected approximately 3feet aN,, av frmn the central channel and will target fine gr iined sedinients . Banksatitl)Ies ,dill be c ;lieete~i at O . ft La`s, between 3-5 It bl-'s and/or just ~tl)ovc bedrock .additional samples will be collected at 10-foot lateral step-nuts Iioin the bank

lac t ions . ( he step - out sa_mple~, a ll b e p1 teed on hold at tie an ± lytical laboratory ,pendiiice the adjacent sample results .

f,'xpiorraiory Trench Samp(m g

Samples "Al! be collected during exploration trenching at two locations along W etrench . Bic exact locations of the samples will he guided based on visual evidence o fimpacted soil such as debris, stained soil, and disturbed soil . Samples will b ecollected at .;round surface and at the base of each exploratory trench . Samples naybe collected frciin the bucket of the etcavation equipment in order to comply with theSite:-specific heath and Safety Plan' s guidance for confined spaces and excavatio ncollapse .

.4 Rariiiiaetive° F iatet•ials screening

To I . , c ' ii .,, .,=l"H :fir' I,t nu ( J i ?S). _j Jla lty Assur t1Ce /

egUdreincilts fcr ( )ueelhA ',,SUtir mcc Project Phn", EPA 0.V R-5 ,

°<ilarch >001 :

Final RFC Wyk;1 NL . Thu -'.

ad! t~~c ~tcle the 1~~~~~ . ~c ;i ~t ;: saiitl °, ~,ly and analytica l

Addenduit . -K. . (l„ ;i Thu . .` :[ Am iris MP ir,; e,sli,ation wil be provided in thy .

Quality Assu_celcc Mom Poo (U .f H (Udti-clen, 1999 e U 2000) and the Perchlorat,- Q. . ,

Cont ai i,os /)-c) a r iami 9 ,d <a li e "Ail he cf i .si~tLu u with the SSFL site-wiu::

proCedu iS f ;) be i Ott -ac a q ue in the p\ I €uees6 _c.bau .

The > 9'i' W01 he prepared i€l ccor'lance with applicable MI P2 1Z .ee4ou 9 and U EPAfederal 9uiciaalcc iite luding :

"I"F 2_ Huiclanec for Qu ahty Assurance Project ldcns IPA Q ,,V6-5, E ehruery 1998 ,2. k' gion IA Requitellientsfor Quality Assurance Project Fleas` P90 ./03 . 1

ugust 200

6 .

lie field a,L&00i 'I n e 1%~ ;t . ,i,, d ',11owiiigDTSC approval of u eWork Plan atki Sur P , nT 'r, l ii ifi}; Nye 4:ihw i .o o , if Wa rranted . Sampling ac [i\ W ac(

aa,ticipated Lt, [C:`•_1L Eze i. -w o t clghL wcelc5 ii} complete , and L ..(?ECiilil I ~l( 1~~'

alli ll'Ii L ,t1 '1 1[8 . I'illltl`Jv'11;1~̀ t' iiiThIeUnil of le \S'()1k described in 111e F h il it P11 Work Plain a ;! 6

53t1[1,1C 1tiCUIIC" IS will he condo 1Cd It}(Ir,"Inu die cniiiplctio11 Uf field aCtivitlss ai l

1 ~i I~4 valid jlf,r 1l a', ill k Lr1'b cq ', .I ;-c ; it iit ,lil n11 cri eigli i \`'Cek.s with normal tlld i?cii ,L!(!C€ _fil LS c,d

3_il11t1Cti . .` I :(Lt ;il , (l? ti a Lt' +'iz , ;( i! S :111ililig, LIS 1'CC1t?irod, and surveying l3 [' L:Yi _ilil! -flit

arSLO itI S <li ,~~_ c (o one to twu week' tillilV' i~. CABs ~ cl ;a, i: L

C :1c11picLi€lil of data repulti ., a id da .iua,uii .; lfic results he dossii cured iii she GroupRFI Repot-I .

7, L ;i'.ia'E1 :

1 F i .hitv ' c 'urance Proj t :l Plan ,`(/ 'i i r e .

l t'{It/fl ;oiC .ddei'Eiiu i . .,ai iiu SiC .laoo C_'Id €.abo ~e 'do- (tf Yr C€) wuyl t E hiTcit?I ,

/, Draft. i~' : c tool 200: .

2 . W l_'.tc_iny, L oinpau (0aein ) . IM . `barn!>lttlf i (il I ttl- /707 it er 1101 lk 'bu'f f

illy (1,~3ia roi pi Marij . 1 3 Mm ih r 21(03 .

he 1 3«csm- Company (Boeing), 2006 . 1:ftJioI1t(~o u! 22 i '£'iii I~FE)C'C'40 1

Bu171 11o . I Attgust 2006 .

tmcnt of To is Suhstanoes C onitol (I)"I5k') . 20W . f)raft fetter 1101 deie()epar

mf ntS for the"C omCompany re :to Ar- The Boeingt Leno x1) (' ,,HailsI (T! 1) andt1- a il yc tattnen tul~lfleluent~tl Soil Sampling Plan for the 1 hcrmal pt e~~ ,w v E L•tua f~jc1rl

Laboratory (SSI k ), Ventura County . CEliifornta . Un(lated, uoo .I Turn Pit - Sclko AV'astc Nianagetncnt 1-nlt Q VV RI(l) .

i .ciicr iruin James M . Pappas, 1 )15C, to Arthur J . Lenox, l'he Boeingnet~til I tiett"1bermauest for Emeiiin Measures Work Plan 01") , Mh,"1?~ cyre :Coiiipan

, F d Area I Burn Pit - Solid Waste [Management Cnit (S\VNIB) . (AD 093aili ntyac 1 ;4, - 17 1<tnuyna

2006 .

.365 435, Santa Susana Field Laboratory . Ventura County , ~ a of t

' %hlerrrur ( rrc<rtntc~rrt rlpetations Plcml,1990i (1 NICON)\ aie ,s oeONLNI( .

Ro( o'ell Iracrnational Corporatioll, Scuno Sttsanta Field Laboratory -rhea 1, lilerrnu l

Trcatnu>nt J"aeilit\_ 23 Niiav 1990 .

(1oundss'ater IZcsources Consultants, Inc ., 1992 . Sampling and ,, lrirlysis Plan, 4rea I'ii on,l .eSanta Snsana Field l,aboratorv, Rockc'tdvne 1)t Facili tt-d T" ynlcn, eulhernu

Rock-well 1111e1natiorlal Corporation , Ventura County, Cali/ornio . 08 Janu.iry 1992 .

linArea I Thermal 7reatrriemt (Inn, June 1993 Santa Susan('1993 Soil Scmnp. ., .

nturaVi eon ,Field halroratorv, Rocketdvne Division Rockwell 1nieriai(anal Corpora t

Corirrty, California . 16 August 1993 .

Maley & Aldrich, Inc ., 2(IOSa . Supplerneilial Soil S(my)ling Plan for the 111errnal),mc Cmit (SGJtul 1l/fatiagermclid Worn A

7'reannenr Facility (7H°) cold .Area / Burn Pit So

-1 .8 . February 2005 .

f( . 2005b . Results of April 20115 Dint /tr Soil Samples, I TF, Santa Srlscrr10 Field

Laboratory . June 2005 .

2016- Revis ed lnieiirn S lecisitres Woik 4lau (or tlic Aiet I Burin 1'ii - c;lid, .

lttrrc'-I1'aste Munat)enleal too (SWUM2 4 .5, Sulin Swware! Yield I a/) rrcuor_r, e r

C`t~nrlt)~, Calijol-ni ( r . Jun c 2006 .

11)061 . hYlif(spsrr((?rfcir [/1/ir /11 101011111 ttt!' Area I do; ii '4' 2oIia

t 1, v n rn` Q(1t'VL') 4 .2, 5o.11 Susa,lu l 0 ! _` rv r y3 1110

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L l S O ( J ([ AT AREA I Btu -,

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1 #-81 Blasting Cap s2 (C2H4)4B2H2

4 (CH3)2NP(CH3)2 -----.~------

59

(CH3)2PH(CH3 )2PH/CH3PH2

7 (CH3)3 P8

---------(CH3NBH) 3

9 (Me2 ) NBCL2) 2

10 (PF2)3 N

11 (PF2N) n12 1 of 13 was CC/DOT 3A480-chlorin e13 1,3-Diphenphinophosphine14 1,3-diphosphino propan e15 i ,4-diphosphino butane16 -1 0

17 10% fluorine

18--- ------

20% nitroglycerine , 80% methylene chlorid e

19 30% methylene chloride solutio n

20 4 bottles unknown liqui d

21 49 RDX pellets (SSME )

22 49-75 gram RDX pellets (SSME )23 5% TEA/TEB can s24 5% TEA B25 5% TEAB/RP- 126 50% propyl nitrate'50% isopropyl alcoho l27 6 samples of FT M28 75% C2H5OH / 25% AZDN E29 a plasticizer (TEGDN )30 AB-1

31 Acetic Aci d

32 aceton e

33 Acetone , Contaminated34 acetone , ethanol, isopropanol , NG, TMETN , DANPE , Al, Mg, Cr, S i35 acetone , ETOH , ETAC, NC, CAB , DANPE , NO, RDX , AP, RDX , A1203, Cr203 , MgO, Al , Mg, Cr ,

paper towels, plastic containers

36 acetonitril e37 acetylen e38 aci d39 Acid- cleanin g40 Acids

41-----------acids/misc acid s

42 additional ampoules from Vanowen . See Appendix A ta b

43 AFN25 --------------

444546

- -Alcoho lalcohol sAlkali metal s

Propric,i, ;i ;

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4 7 Alkaline Cleane r48 Alkaline powde r4 9

50

aluminiu mAluminum

----- -____~.- -

51 Aluminum Ghlorid e52 aluminum oxid e

53 aluminum powder

54 Aluminum powder 54 g i n+ Freon TF55 Alumnium turnings 33 gm saturated with sulfur - base cutting oil + Freon T F56 amatol/HN D57 ammoni a58 Ammonia cylinders (small )

59 Ammonia Perchlorate60 ammonium - - -

61 ammonium nitrate/PET N62 ammonium perchloate ( oxidizers ),63 ammonium perchlorate

64 ampoules of unknowns from Vanowe n65 Amyl nitrate66 anhydrous ammoni a67 AP nitrate esters68 AP , GAP, TMETN , N-100, C, NMA .69 approximately 60 cubic yards of loosely packed empty steel drums and misc . scrap metals formally hazardou s

materials

70 aqua ammoni a

71 Aqueous Ammoni a72 argo n

73 Argon Ga s

74 asbestos75 AZDNE/MeCl276 B5H8Et

77 B5H8 178 B5H9

79 Barium chlorid e80 Bas Cyi's

81 bases

82 BC1 283 Benzaldehyde

84 benzene

85 --- ----benzene on sawdust ------ -

86 benzene/MBDA recovery87 Benzene-HC L

88 Benzene - Hydrochloric Acid Mixture89 Bermite Carbides90 binders91 Bis Ethyl 2 Chloroforma l

92 bis ( 2,2-difluoramino-5,5 ,5-fl uorodinitropentyl ) formal (SYFO)

"f opt 0 ar y

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93 Bis(2,2-ditlou roomino-5,5,5-fluorodinitropen tyl)formil (SYFO)94 Bis(fluorodinitroethoxy) 2,2-bis(difluoramino) propane (S 'EP )95 Bis(fluorodinitroethoxy)-2-isopropanol (SECQH )96 bis(fluorodintitroethoxy) 2,2-bis(difluoroamino) propane (S YEP )97 bis(fluorodintitroetho''y)2- propanol (SECOH )98 Black Powder -

99 Blasting cap s100 blue green cylinder-!Ink so wn (F2 )

101 boranes

102 boric oxid e103 Boro l104 Boron 90%

--------- -------105

-boron amorphou s

106 Boron Fue l

107 Boron hydrid e108 Boron trifluorid e109 Bottle s

110 Breathing ai r111 Bromide pentaflouride serial RS021 5112 Bromin e113 Bromine pentafluorid e

114 Bromine pentafluoride general chemical serial R-5 9115 Bromine triflourid e116 Bromine trifluorid e117 BTU NG compoun d118 Butadien e119 Butadiene polymate120 butadiene polyme r

121 butadienes122 butaiene polymer, R-4 5123 butanetriol trinitrate124 C2H5BCI 2125 C2H5PH2126 CAB, NC, CMP, CONPALT, T METH, DEGDN, TEGDN, NG, EC PVAC, TEGDA, PEG, R-45, GAP, GAPA ,

ATEC, NDPA, RDX, AP, KP, ?RH2, TAGNI . K2SQ4, C, CU0202, Al, Mg, B, acetone, toluene, ETOH, ETA C

127 Cal-1 2

128 CAL- 3

129 Calcium chlorid e

130 Calcium hydrid e131 Carbon Tetrachlorid e132 cartridge NA5-28088- 1133 cartridge NA5-28124134 cartridge NA5-28124T 1135 Caustic Soda136 Caustid Potas h

137

138

CCI 4

Cesiu m

F-roi,H-tar,,Haley L .Idnch, Inc.

G \Pi .ijecis\26472 \TTF\RFI WP Addend or ;- i 6 ; `_OG,.1 Jnii t LisiLo L sposed(3o rieals xis OCLUL i ''00 6

HDMSe00037379

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139140

CF2CI,-'CF31

- - - _ -141 _ - ------ - -ICF3SF 5142 CH3HP(CH2)3PHCH 3143 CH3MgBr in THF: 3-100 gm bottle s14 CH3PCI2 - - ---

145 CH3SiC13146 Chem Solven t147 Chemicals, unknow n148 chlorin e

149 Chlorine & 02 ga s150 chlorine gas151 Chlorine Pentafluorid e152 chlorine pentafluoride (compound A )153 Chlorine Trifluorid e

154 Chlorine trifluorind e155 Chlorine trifluorin e

156 ChlorineTrifluorid e157 chloriofor m158 Chlorobutadiene159 Chloroform160 Chloropropane161 Chromic acid162 cleaning materials and swabs163 CMP, N-100,DANPE, CMP, NC, NG, PCOE, S-RP, CAB ATEC, GAPA, R-45, DD1, DOA,PEC, CMGA, DX,

NDPA, ZrH2, Si, HMX, B, KCIO3, NaHCO3, DATH, S, yellow dye, Al ;_am. Iodate, OECHCURANZ, LV2 ,K2Cr202, hexachloroethane, acetone, toluene, ethanol, ethyl acetate .

164 CO165 C02166 Comp A .167 Comp A . fluid168 Comp C-4

------- ----169 Comp ; A170 composite solid propellant grai n171 composition Alpicric aci d172 composition B! RD X173 composition Cl tetryl174 composition Dl torpex175 Compound A

176 Compound A cylinder (1 empty )

177 compress gas cylinde r178 - ----- - --Compressed air

179 Conax valves

180 Contaminated Hydrasin s181 Contaminated UDM H

182 corrosive s183 Crude CH3SF 5

PropueiaiyHaley & Aldrich, Inc .G :\Projocts`126472\TTF\RFI WP Addend for A1BP\20060922UniqueListofDs os uClic ;nieals . ;.Is October 200 6

HDMSe00037380

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VENTUFth CcU ' ielli'.

184 U F cylinders185 CTF-Ign ite r186 cupric chlorid e187 cyclonite188 Cyclo-tetramethylene-Nita mmii~ .

i89 cyclotrimethlyenp-- ------

190 cyclotrimethylene tr inilr <rnin c

191 Cylinders

192 DATB

193 Daworals sodiu m194 DCFO/CH3C N

195 Decaborane

196 Decon . Flui d197 Decon . Soln .198 DEGD N199 Delt a200 desiccator with unknown contents + ca p

201 Detonating primers 2 Gr Long 8258 470640- 3202 Deuterium cylinders (small )

203 DHSG ignition , TEB canisters204 diazidylnitramino pentan e205 diboran e206 dibutylphhalat e207 dictylphthalat e208 Diesel fuel oi l209 diethyl ether/benzene/magnesium boro hydride diammoniate (MBDA) residues . 4 -1-L bo tt le s210 Diethylcyclohexan e

211 diethylene glycol dinitrale212 Diethylene Triamin e

213 difluoride ga s214 Dimazine215 Dimethyl mercu ry216 dinitrotoluene217 dioctylothalate218 diotyphthalat e219 Dioxane

220 dioxin

221 DPA-HPE-NFPA

222 D ry nitroge n

223 dynamite `- -

224 Elec . Lighters225 Electric igniter s226 Electric squib b227 Electric squibb ignitor s228 Electrolyte229 Electrolyte Solution n

230 electrolytic solutio n

PropuelaryHaley & AlduLh, Inc.

G\Projecs\26472\TTF\RFIWP Addend forA1G,', 0060922UniqueListofDisposedChemicals,xls GbLube "O f

HDMSe00037381

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19~D OF AT AREA I BURN PI T

231 Empt y232 empty TEB caniste r233 energe tic binders ii;, 300m1 ruU ~ . uoddo r f lasks234 epichlorohydri n235

236

. . . . 237

Epoxy

Et2BC lErg p H --- _ --- --- -- ----- -

238 EtBBr2

239 Ethane cylinders (large) ---240 etheno l241 Ethe r

242 Ether Squibb s243 ether/benzene/MBD A

244 Ethyl deka boran e245 ethyl nitrate

246 Ethylamine

247 ethylene diamine248 ethylene diamine (drain back )249 Ethylene Oxid e250 Ethylenediamine251 EtNH2252 EtP H253 EtPH 2254 Explosive A+ B

255 Explosive wastes256 Explosives257 explosives A& B

258 Explosives bolt s259 F2 gas

260 F2 gas generator pellets ( NF4/BF4 /KF/AI )261 F2 seial FL2540262 FDNE - -

263 FDNE/ alchoho l

264 FDNE /MeC12/C2H5O H265 Ferrocen e266 FI empty cylinder

267 A (empty)

268 flammable rags

269 Flare mi x270 flares smok e271 Floro x272 Flourine allied chem . 29-23041 1

27 3

27 4- -

flourine ga sFluorid e

275 Fluoride-matheson serial TH54 2276

277

Fluorine

Fluorine Gas

Proauk r

Haley & ~ldrici~, Inc.G :\Projecls'126 :72\T1 Fl-,F1 \ /P Addend for A1BP\200601,221irnIqu~2 _J .s a Lisposedci,ei-,iicals .xls Daub ?U3 .

HDMSe00037382

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VENT L'I',-1 J,'N t vl\I J

?7 8

2 7 9

Flushing oi lformaldehyde

280 Formic Aci d28 1282

aeonFreon + acio -

283 Freon NT O

284 Freon T F- ---- ----- -

285 Fue l286 Fuels; Cont

287 Gap 30%, AP and C 70 %288 GAP 30%, Ap/C 70 % . Mix 3-21- 1289 GAP 30 %, Ap/C 70% . Mix 3-21-1,2290 GAP 30 %, Ap/C 70 % . Mix 3-21-2291 GAP, -100, DANPE , GAPA , AP, Mg , Cr, NIX, IBC, CiMP, OATH , TMETN , DADNH, HMDi, acetone, ethy l

acetate, ethanol

292 GAP , N-100, DANPE, HMX, GAPA , TMETN , NC,CMP , DATH, DADNH , paper towels , plastic tubes an dbeakers, Ailasol yellow dye.

293 GAP, N 100 , TMETN, DBTDL , DANPE , CMP ; R-45 DD1 , PS555; GAP,, NC; NG, R-18 ; IDP, HD1 , CAB ; DOA ,PEG, CMGA , ,P, MNA, C, TPB , Si02, Al, Cu0202 , Si, NOPA , KCI03 NaHCO3 , S, yellow dye,, BaCrO312 ,hezachloroethane , Fe, Mg , Fe203 , Mo, B, 1205 , RDX, ZrH2, ATEC, E

-m_GAP/ DANPE 30 % AP/AL/Mg/Cr 70%. Paper towels , plastic containers .

295 gas cylinders296 Gases, unknow n297 Gasolin e298 gasoline soaked sawdus t299 GDNFE

300 GDNFE/alcohol

301 GDNFE/MeC12/alcoho l

302 Gear oi l

303 Glycerine304 glycidyl azide polyme r305 Glycidyl Fluorodinitroethoxide (GDNFE )306 glycidylazide polyme r307 glycidylazide polymer azide308 glycidylazide polymers309 GM lab cylinders310 green C02311 green K bottl e312 gunpowde r313 HBX/TNT314 HCL

315 . ..Heptane - - -II

316 . . . . hexane ---- ---. .~

317 Hexane s

318 Hexanitrostilben e

319 hexpger, ~ ~----

320 H F

plopn Aar yHaley & /,Idi I iInc

G \Projects\3( ,- iz\TTF\RFI WF A .o, ,it' 006Ob22Uniq ; :!_ i iofD sposetlChemiculs .;a~ October 200 6

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322 Hi-Cal- 3323 Hivelite s

324 HMX - - 1

325 HMX scra p

326 HMX-Nitrocellulusc

327 HN B

328 HII F

329 HN S330 HX31 0

331 Hybaline332 Hybaline - Cal- 3333 Hybaline A and RP L

334 Hybaline and R P335 Hybaline- Cal-3336 Hybaline s337 Hybalines RP- 1

338 hybrid motor grades339 Hybrid motor grain s340 hydrailic oi l341 Hydraulic oi l342 Hydraulic Oil, Contaminate d343 Hydrazine344 Hydrazine + cap345 Hydrazine 90%, EDA 10%

346 Hydrazine and admixtures sample s347 Hydrazine and water (drain back )348 Hydrazine Nitrate

--------349 Hydrazine, non-returnable drums350 Hydrazine, returnable drum s351 Hydrazine, warehouse drums352 Hydrazine/ HMX Propellant Mixture353 hydrazine-admixtures and lab chem354 Hydrazinefluoride (N2F4) ICC3AA226 5355 Hydrazines

- --356 - -Hydrocarbo n357 Hydrocarbon s358 hydrocarbons EB-4 0

359 Hydrochloric Acid-360 Hydrofluoric Acic! - - - - -

361 hydroge n

362 hydrogen argo n

363 hydrogen bromid e364 hydrogen chlorid e/helium365 Hydrogen cylinders (large)

366 Hydrogen cylinders (small) - --- ---~--_._

367 Hydrogen fluorid e

1 ialey ,~" P,Idiich, Inc :r .' .P . ul ;;cis\26472\TTF\RFI WF ,',uueow iur /' . i r 26060"2GUniyu LtsioiL spusedCherru~als S 200 6

H D M Se00037384

Page 9 of 1 9LI_ ! 7 -0 OF _ J PIT

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3() H Hydrogen fluoride RC4463

36

Hydrogen gas

370 hydrogen silfid e371 Hydro gen Sulfid e

372 Hydrogen sulfu r

373 Hy drolic Oi l

374 nydroxy terminated polybutnolictic.,

375 hydroxy terminated polybytadien e

376 Hypergol igniter s377 hypergol TE A

3/8 hypergol TEA/TEB/RP-1 residu e379 Hypergol TE B380 Hyrazin e

381 Hyrazine 75%, Ethanol 21 %, water 4382 --- Hyrazine and admixtures

383 Hyrdrazin e384 Igniter Class C

-385

--- ---------Igniter ST4530001 RE00 1

386 Igniters

387 Ignitors388 Inhibited - Red Fuming Nitric Aci d389 Initiator NA5 -26528-3390 Initiator R595 0391 IRFN A

392 IRFNA ( obsolete spec)393 IRFNA, NTO

394 iron carbonyls + caps . 3-1 pt . can s

395 Isopropy alcoho l396 isopropyl alchoho i

397 Isopropyl alcoho l398 Isopropyl Alcohol /NTO mixture399 Isopropyl Butan e400 JP-4401 JP-4 (kersosene base )402 K bottle403 K-Bottle unkown ( liq gas )404 K- Bottle unkown empty

405 KCIo4, Ap, ZrH2 G 0% NC, NG 40"//,j . /acetone , etoh, eta c.,.:.._~ ~.-406: . . . . .. Kerosene

- --407

------------Ketones

408 Lab chemicals and/or fuel sampler409 Lab cylinde r410 lab cylinders unknown411 Lab silver cylinde r412 Lab , Samples ( Fuels )413 Lach ry matory414 Lack rymatory

opi :iaryNUley & Alunch . I ;c _

PP Piu~ec'cs\26,,7`, TF,RFI U1.r Pnde~1~ for , !3P,20060PP2 .1nic, .!_iSio DSOUSE ~c'i tiacr_l ., h ociobo .- "Too

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..__ ..------------ ------ ------- ----Laquer Thinne r

418 large TEB bottl e419 Leaded Paint (189 g~ i I r s )420 Leaded paint s

421 Licthi h422 LiH -- ----- - ----- - - ----

----------423 liquid waste nitrate esters424

-- - -liquified petroleum gas

425 Lithiu m426 Lithium chloride427 Lithium hybri d428 Lithium hydrid e429 Lithium meta l430 Lube Oil , Contaminated431 Lube oil-heav y432 Lube oil ligh t

433 magnesium434 magnesium powde r435 Magnesium /telfon flare mi x436 magnisiu m437 Mathan e438 MBDA residues

-439 Me Allyl P H440 Me Isopropyl phosphin e441 Me N-Propylphosphine442 Me2ETp

443 Me2PH444 Me4P 2

445 Me - D3 Iodid e446 MeEtPBH 2447 MePH

448 meson ,. oxid e449 mercury450 Mercu ry salts

451 metal additives (aluminum )

452 metal and /or metal oxides (Al, Bacon , Zirconium, magnesium

453 metal oxides

-454 --- --metals- -- -- - -

455-- - -- -----

Metals Alkali-- -

456- -- --- -

Methan e457 Methane cylinders (large )

458 methane ethan e

459 Methano l460 Methanol - benzene curric chloride-Al0 3461 Methanol - Cupric Chloride - Aluminu m

4'roprietarvHaley & SIdrich, fn c

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462 Methanol Cup i . Chlol kJe ".L. I I Ch .oride Mixture463 Methanol -HC L

464

465

methyl acet I ne popadi&-,,'-.

Methyl alchoho l

466 Methyl alcoho l

467 Methyl-borate metho ito l468 Methyl-B-Trimethyl Borazin c

469 methylene chlorid e470 methyl-hydrazin e471 Metriol-tri -nitrate472 MHF-5473 MHF-5 Samples ---

474 MIPB

475 M I PP - ---

476 Misc Acids

477 Misc ampoules from VanOwen . See Appendix A tab .478 misc binders (FEFO/ R-18, NG/R-18, TMETN/R-18, PGDNFE/EA-AA )479 misc lab chemicals

480 misc samples of AB-1, QMB - 3, and MBDA481 misc small vials of TN M482 misc solid propellant scrap s483 Misc solid propellant waste484 Misc . Contaminated fuel s485 misc . contaminated fuels .486 Misc. flamables

487 misc . junk

488 misc: lab chemical s

489 Misc . Lab Chemicals ( Various Size & Type )490 Misc . phenols491 Misc . small cylinder s492 Misc . Waste chem493 mix oxide s494 Mixed oxides495 Mixed TABH/HMX (dry )

496 Mixed TABN/HMX (dry )

497 MM H

498 MMH 70 ml + Freon T F499 Mono - Methyl -Hydrazin e

500 Muriati c

51:)1--_ Muriatic aci d502 Muriatic Acid s503 Mydyne

504 Mydyne (drain back )505 N butyl alcoho l

506 N2 gas generator pellets (NaN3 based )507 N2H4? ca p

508 NAK

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G \Piu Jcts\26472\TTI-\R"~ I' Advert 2r ; .̀1BP\20GS0 2Ui~iqi ~Listuil"I n)scciC,h ll .ical .: . .:is CicCc'oe ?00

Page 12 of 1 9LIS I )F LI E; i P.io D`UKi ski

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509 NAKA B359 slurry . Acetone/ethano l/ isopropanol / NG/TMETN/DANPE . Trace amounds Al, Mg, Cr, Si; .510 NAKA B372 s lurry : KCI4/AP.ZrH2 60 0/,, LA CING 4 0 0/,s .511 NAKA propellants512 NAKA p ropel lents

-- - -X13 NAKAroph ----pyrophoric waste/;'apes 1514 NAKA scrapshMpe s

515 NAKA slurr y

516 NAKA soli d

517 NAKA waste - pyro scrap , Kim wipes

518 Napal m

519 Naphthalene520 Napthalen e

521 NC522 NC RDX etc523 NC , NG, R-18 , RDPA; HO1, ZrH2 , Si, AP, GAP , GAPA, N-100 , KCLO3 , NaHCO3 , S, Yellow dye, CAPEe ,

plastic containers .

524NC/CAB/DANPE / DINA/CMP 25 `io, [IDS 75% . PEG/NG 50%, RDX/ A1203/Cr2O3 50% .GAP / TMETN/ GAPA/ TEGDN!DANPE 50 '1% , Atlasol yellow dye 50% .

525 N-Dimethyl-B-Trimethyl Borazin e

526 Neutralized Acid527 Nitrate Aga r528 Nitric & Hydrofluoric Acid Mixture529 Nitric Aci d530 Nitric and Hydrofluoric Acid Mixtur e531 Nitric oxid e532 nitro compounds in 30% methylene chloride solutio n533 Nitrocellose

534 nitrocellulos e

535 nitrocellulose RD X

536 nitrocellulose ,537 Nitroexthan e538 nitrogen tetroxid e539 Nitrogen Tetroxide (contaminated )540 nitrogen trifluoride541 Nitrogen trifluoside542 Nitrogentetroxid e543 nitroglyceri n544 nitroglycerin e545 Nitroguandin e

546 nitrogycerin ~{I547 nitromethane poured onto sawdust : 1-500 gram bottle

548 nitromethane poured onto sawdust : 2-500 gram bottle J549

INitrostarch

550 Nitrosyl chlorid e551 nitrous oxide552 NONA

553 notrocullulos e

P r op IieiaryHaley 8 Akiildl, l i(-. :',Project- 1 `,~ ;FI VJ P io -i r X00609Is (-% 200 6

HDMSe00037388

L L OF it __ raw F 1,iL P

1CLIi~IC ~,`.~ ci iLLD L .L:-, ATORY

v b l U R- J I I J F!'i' ! P.

554 N-1 0555 N O cont. hardware ~~556 NTOcontaining ha rdw< rc557 NTO cylinder s

558 NTO/ Alcohol mixtur e559 N-trimethly borazol o

560 N-trimethyl borazal e561 I!-Tiimethyl-B-Methyl boranzine

562 Oi l563 Oil Waste564 Oil, wast e565 oil/ oil waste566 organic binder (HTPB )567 oxidizer dust568 oxidizers - - -

569 oxidizers (ammonium nitrate )570 oxyge n

571 Oxygen + nitrogen ---

572 Oxygen cylinders -

573 Oxygen cylinders (MT )574 Oxygen DiFluorid e575 Oxygen Difluoride Gas576 Oxygen difluorin e577 Oxygen Gas578 oxygen/nitroge n579 Oxygen-nitrogen580 Pain t581 paint thinner582 Paint finne r583 paper

584 paper towel s585 paper towels contaminated with binde r586 paper towels contaminated with small amounts of oxidize r587 paper towels contaminated with small amounts of plasticizer s588 paper, plastic containers589 Para Xylene

590 partially decomposed metallic materials all empty ,-- -

591 PCB s592 PEG/NG 50°/,, RD`X/Al203/Cr2O3 50%, paper towels, plastic containers

593 PEG/NG 50% %, RDX/MgO 50%, paper towels, plastic containers594 pentaborane595 Pentaborane + unknow n

596 pentaborane . 2 ampoule s597 Penteborane & Acetone598 Penteborane & RP- 1599 perchlorate

600 Perchloric Aci d

Pl opial„r, ,

JHaley & Aldrich, n cG :yPLcjectsv264i2VI TF\RFI \NI- , uen(l LC ' ,'ibl ,26060922UniqueListofDisposed 0 I , . i-iii ;uls Is , ciuu : ; i 200 6

HDMSe00037389

I?5T OF NTFCU VV/ . ;,

IOLIi G S L

-Ii U RNPIT

601 ( oc rchloroeil lyl c : r e602 Permangante Li

-603- -PGDN E

604 PGDN-FEF O

605 PH __-_-------

606 PH 2

607 PH2(CH2)3PH2 --f

608 PH2(CH2)4PH2 _ `. - - - - ----

609 phenol s610 Phenyl phosphin e

611 Phosphoric Aci d612 phosphorous

613 phosphorous oxychlorid e614 Phosphorus

615 Phosphorus Oxychlorid e

616 Pipe residu e

617 Piperna l

618 plasticizer (triethyleneglycol dinitrate , TEGDN) m619

- _plasticizers

620 Plastisol Nitrocellulose 4621, Plating Solution -

.

622 PN C

623 Polyme r624 Polymer soap oi l

625 Polymer Waste626 polymer/polymer waste

627 potassiu m

628 Potassium Bromid e629

--------------- -potassium cyanid e

630 potassium perchlorate631 Potassium permangant e632 Potasssium Cyanide633 PPNF - Nitrocellulose634 Propane

635 propane/ai r636 Propellant hybri d

637 propellant scraps, wipe s

638 Propellant, soli d

639- - ---------- -

Propellant, solid s640 Propellant s641 propellants and Pyrotechnics642 PS5555 , GAPA, N-100, AP , GAP, NAHCO3 , S, KOC04 , yellow dye, RDX, CMP , Si, R-45 DDI,-Cu?, DANP E

paper, plastic containers .

643 Pyradin e644 pyridin e645 Pyroforic liquids

646 Pyrophoric Aluminu m

P opi efaryHaley Aldrich, I i sG ~,,'io}ectsOu {r'~I ;FI VIP Auuciu fur . UF ,20060922UniqueListofDisposedChemicals .xis October ?OOi'

HDMSeOO037390

IO1= I-) , ;-I,/IE l - I) e /P,STE DISP r` ~ED OF AT AREA I BURN PI T

BOLING S! i F D I

VENTURA COUN C,= .1 C ,H', II ,

647 Pyrophoric Ignite r

648 Pyrophoric Invite r649 Pyrotechnic ignite r650 Pyrotechnic Ingite r651 pyrotechnic misc . types

652 Quarz Voo l653 R -45, DD1, AP, Cu0202, `J, ~~i Cl'jiD CAP, N-100, GAPA , KC104 , ATLASOL yellow dye , KClo3 , NaHCO3, 5

paper , plastic containers

654 R-45 , DD1, GAP , GAPA, N - 100, R-18 , HMD1 , NC, NG, PS555 , DANPE, AP, KCI04 , KCIO3 , RDX, NaHC03 ,S, Si, PMF, Al, Cu020 2

655 R - 45, DD1 IDP, s, KCIO3 , ATLASOL yellow , NC, ba(N03)2 , NaHCO3, GAP , N-1C0, AP ; TEMETN , MNA, C ,TPB, R- 18, 1IMD1, Mo, B , DD1, 1205 , DNPE , RDX, CMP , ATEC, DAT H

656 R - 45, DDi . AP, Cu0202, Al, Si, GAP, N-100, yellow dye, GAPA, TMETN , CMP, DANPE , ethyl alcohol ,acetone , toluen e

657 R - 45, DDi , AP, Cu02O2 , Al, Si, GAP , N-100, yellow dye, GAPA, TMETN , CMP, DANPE , paper towels , plasti ccontainers

658 Ram set charges-- ----- -- -

659 RDX

660 RDX- Nitrocellulos e661 Red Fume Nitric Aci d662 --- Red Fuming HN03663 Red Fuming Nitric Acid664 Redfume nitric aci d665 resi n666 REX-1 7667 Rifle shells668 RJ- 1669 RJ-1 fuel -

670 rocket fL10 1671 Rosin Flu x

672 RP- 1673 RP-1 (kerosene base )674 RP- 1, Contaminate d675 RP-1' TEA TE B676 rubber binder (HTPB-hydroxy terminated polybutadiene )677 Scrap gun propellan t678 scrap solid propellant679 shop waste

-

680 Silicate of sod a681 SKL-4-DX E682 Slurry: CAB, NC . CMP , BNPA/ I, TMETN , DECDN, T EGDN, NC, ED,PVAC, TEGDA, PEG, R -45, GAP, GAPA ,

ATEC, NDi'A, RDX, AP, KP, Zi H?, TAGN, K2SO4, C, Cu0202, Al, Mg Cr, B, actone, toluene , ETCH, ETAC .

683 small B , GM cylinder s684 small cylinders ,685

- -Small cylinders (MT)

686 small GM cylinders687 small green C0 2

1-Cupi,u Lii yHoley ~. Aldrich .C ~.l'i ~iects~ I F\RFI WH : .udariu ) r A`BP\20060922UniqueListofDisposedChemicals .xis CCLohcr 2000

HOMSe0003739I

P-) 4-1, - PIT) S'~/V i

30CI JG -IF[ [I L'

VENTUW . (UU ~i i Ll,_L1FGE J '

688 !small green smoke pe llet689 Small unknown cylinders

690691

Small unknown cylinders (MT ,small white canister 30psi N2

------------------

692 Smoke flare s

603 Smoke grenade me[ .694 Smoke mi x

695696697698

Smoke powde r

Soda ashmm

sodium --

sodium arsenite

-

699 sodium azide1

700701

Sodium fluorideSodium Hydroxide

702 sodium nitrate703 Sodium nitrite

704 sodium phosphate

705 Sodium Waste706 Sodium, waste707 Soldering Flu x708 solid gun propellant scra p709 solid oxidizers (hexogen )710 solid propellant scra p711 solid propellant scraps plus misc ampolues from VanOwen . See Appendix A tab .712 Solid propellants

713 Solid Propellants & Heptane

714 Solids, unknow n

715 Solvent

716 Solvent waste

717 solvent/solvent wast e718 solvents719 spent fuels720 spent halogenated solvents721 squib 101513 -722 Squib 19-403189 - -i

723 Squib valve 19-403211 , P/N 19 21 3

724 stenciled fluorine

725 stoddard solven t726 strong oxidize r s

727 Sulfur dioxid e728 Sulfuric Aci d729 Sulfuric trioxide

- --730 - ------ -sulfas dioxid e731 Sulphuric Aci d732

733

734

IAB N

TAE

TAG N

Haley C. FvIdrlcil, In c

G :\Proj ectsV"'u' I>\T1 FR I VNP dd-n for Al UN, 20060922UniqueListofDisposedChemicals .xls October 2006

HDMSe00037392

l( t- ;Ui ii 1 ,

1 1E[ ~IV! ! r` '

BOEI I`i l

r . , i AREA I BURN PI T

(3 5----TAGN in ET,

73 5

737

TAGN in IP A

TAMA- - ---- ---- -- --

738 TATS739 t-BuBCl2740 TCE

741 TEA

7,112 TEA and TFAB ignitors

743 TEA B

744 TEA cylinders

745 TEA, RP- 1746 TEA/TE B747 TEA/TEB drums with RP 1748 TEA/TEB/RP- 1749 TEA/TEB/RP-1 .+ ca p750 TEA/TEB/RP-1 + cap . 4-1 gallon can s751 TEA K

752 TEAB igniter s

753 TEAB, RP- 1

754 TEAB+RP- 1

755 TEB

756 TEB caniste r757 TEB in caniste r758 TEB+TEAB759 TEB+TEAB igniters760 Tetra isobutylene761 Tetrafluoran e762 tetrafluorohydrazin e

763 Tetraisobutylene764 Tetramethylene phosphin e

765 Thiophosgene C12CS`

766 Titanium767 titanium tetrachlorid e768 titanium trichloride769 TMETN/GAP 30 %, AP, CP, C 70% . Mix 3-22-1,2,3 .(-/0 TMETN/GAP 30 °T, AP, CP, C 70% . Mix 3-22- 1771 TMETN/GAP 30 %, AP, CP, C 70% . Mix 3-22-2772 TMETN/GAP 30 %, AP, CP, C 70% . Mix 3-22- 3773 TN N

77 .1 TIN T

(75 toluene

776

777

Toxic gases

triaminoguanidine nitrate

778 Tributylamine779 Tributylborane780 Trichloroethene18-i Ti ichloroethylen e

! ~"V F P_ Ge~~~_I i ) Df 20060522UniqL LisoDisposedChE ni als ;;! October 2006

HDMSe00037393

I_I I 01 I_)V1., ~. iVf HIV ILL) II _ F'lJ 'i ) ..%i ' i L; lip C "

782 T ietl,lybo rori

783 ---Triethyl Aluminiu m

784 Triethyl Aluminium Ee : 3ne785 Triethyl Aluminu m786 Triethyl Al uminum Boran e

787 Trieth ylalu mi nu m788 trieth ylaluminum/triethylboran yl~ .l~i~r (NEP1 /TEB Ib )789 Triethylaluminum/triethylboro n790 Triethylamine

791 Triethylboran e792 Triethylboro n

793 triethylboron (PIG) cylinder ( TEB volume 141b; NEAT, TEA/ TEB 14 lb )794 triethylboron cylinder (TEB volume 69 .5 Ibs )795 Triethylboron-RPI Mixture

796 triethyleneglycol dinitrate797 Triethylene-Glycol - Dinitrat e798 trietyleneglycol dinitrate799 Trifluoroacetic anahydrid e

800 Trigger Assembly 1617 - 170-01801 Trigger Assembly ST2840002 RES00 5802 Trigger Assembly ST2840002 RES007803 trimethioltrinitrate804 Trimethyl boran e

805 Trimethyl boro n806 Trimethyl -borate-CH30 H807 Trimethyl - Borate-Methano l808 trimethylolethane trinitrate .809 trinitramine810 Tri-o -cresyl borat e811 TTTT

812 Turbine spinner grain s

813 TVOP A814 UDM H815 UDMH +ca p816 UDMH 90%, water 10 %

817 UDMH and water ( drain back )818 Ukown empt y819 Unidentiifed Fuel s

820 unknow n

821 Unknown (AA2015 propane/air)

822-

Unknown ( large cylinrlr?r)- - -- -823 ----

unknown ampoule--

824 - ~.- -Unknown cylinde r825 ' Unknown cylinder (MT)826 Unknown cylinders827 unknown quantity/content s

828 unknown quantity/contents . "Arm

! upneiar;aley & Aldrich Inc .

GI lolects\26472\TTF\RFl WP Addend for AlBP\20066922Ul,lyu . .l is~()i i)I~ ;rescdChemicals .xls October 2006

HDMSe00037394

LIS ( it J '~ Vim, . u u

F

829 unknown clu iy , orients Compcr, _830 Unknown RIP C4-9208831 Unknown RP-'A2 0832 unknown substances

833 Unknown type/quantity834 unknown vial

835 Unkown cylidners

836 Unkown Cylinder837 Unsymetrical-Dimethyl -Hydrazin e838 US Navy MP060 7839 Valve Assembly NA5-260180-1 D840 Versamid 14 0841 Very small unknovdn cylinders (M T )

----- ----842 --------VM-P Napth a

843 waste acid

844 Waste Oi l845 Waste Polyme rs

846 I l- - ----Water purifier pof Ymetrics 7149631520

847 water with <5% binders848 White Fuming Nitric Aci d849 White K bottl e850 wood851 xylene852 Zero ga s853--- zirconium hydride powde r854 zirconium nitrocellulose855 zirconium powde r

I --' fOp, i Ciaty

I IL,Ic 414011 -i I cG:\Projects\26-J21Ti G I Vv' „d ricr < o ,`, i !P\20060u 22 U Ii CILI eLW suiDlsposedChen .icals ;,Is 2006

HDMSe00037395

"sn Page 1of 5S DETECTED I ! i ~ONMENTAL SAMPLES ., , I J(i_ .^, bURl ; P1 I

AIBP 3Wia ,-i .3, - JUBOEIN ; Lo ;

VEN1 Uf uLJi, i ALIT t~~ . :1 ,

ANIONS

ANIOI l

VOCVOC

ANALYSIS GROUP AN ALYTE CAS NUMB E RANIONS Bicarbonate (as C C03)

Carbonate (as Ca~03 ;Chlorid e

ANIOl IS Fluorid eANIONS Nitrate

ANIONS SulfateGEN MIN Cation /Anion BalanceGEN MIN Total Dissolved SolidsVOC 1 71-55-6VOC 1,1,2,2-Tetrachloroethane 79-34-5VOC_-- 1 ;1 2 - Trichloroethane -~ 79-00-5 IVOC

.-. --- - ---

1,1-Dichlo roethane. ._...

----_-75-34-3

VOC -- -1, 1 Dichloroethene 75-35-4

VOC 1,2,4-Trichlorobenzene 120-82- 1VOC 1,2 -Dibromo - 3-chloropropane ( DBCP) 96-12-8VOC 1 , 2-Dibromoethane 106-93-4VOC 1,2-Dichlorobenzene 95-50- 1VOC 1,2 Dichloroethane 107-06-2VOC 1, 2-DichloroetheneVOC 1 , 2-Dichloropropane 78-87-5VOC 1 , 3-Dichlorobenzene 541-73- 1

11 ,4-Dichlorobenzene 106-46-72-Butanone 78-93-3

VOC 2-Hexanone 591-78-6VOC 4-Methyl - 2-pentanone 108-10- 1VOC Acetone 67-64- 1VOC Benzene 71-43-2VOC Bromodichloromethane 75-27-4VOC Bromoform 75-25-2VOC Bromomethane 74-83-9VOG Carbon disulfide 75-15-0VOC Carbon tetrachloride 56-23-5VOCVO C

ChlorobenzeneChloroethane

108-90-775-00-3

VOC Chloroform 67-66-3VOC Chloromethane 74-87-3VOC cis-1,2-Dichloroethene 1 56-59-2VOC cis- 1,3-Dichloropropene 10061-01-5VOC Cyclohexane 110-82-7VOC Dibromochloromethane 124-48-1VOC 11-DichloroethaneVOC trans - l,2-Dichloroethene

Dichlorodifluoromethane (CFC-12 )-12) 75-71-8VOC DichloromethaneVOC Ethylbenzene 100 41 -4VOC !sopropano lVOC

---- lsopropylbenzene 98-82 8VOC- M eth Y ceta te 79-20-9

Pr~>!~ric'rani

Haley C, Q,Idrich Inr, .

G :'.Po} '!,TTF\RFI WF 6-.udcctid orA1 BP\20060922 TargetAnalyteList T02 .xlsUc obe " OO o

HDMSe00037396

Page 2of 5

l`,I

BOE :

VEN i

SVOC 3 ;3' DichlorobenzidineSVOC 3-Nitroaniline

L? L,= .GRATORY

ANAL SIS GROUP IRI! .L ; E G S NUiv BE PVOC f,) iethyl cyclohexane 108-87- 2VOCE 4-Methyl-2-penta noneVOC

_Methyl te rt butyl ether i f C.-_- . - 1634-04- 4

VOL- -_-----------~--

Methylene chloride------ -. .. 75-09-2VOC Styrene

.100-42- 5

VOC-

Tetrachloroethene 127-18-4VOC Toluene 108-88-3VOi trans-1,3-Dichloropropene 10061-02-6VOC TrichloroethaneVOC Trichloroethene 79-01-6VOC Trichlorofluoromethane (CFC-1 1) 75-69-4VOC 1,1,2-Trichlorotrifluoroethan eVOC Trifluorotrichloroethanc (Freon 113) 76-13- 1VOC Vinyl chloride 75-01-4VOC 1,4-Dioxan eVOC Xylenes, Tota lSVOC 2 ;2'-oxybis(1-Chloroprop ane) (bis(2-chloroisopropyl) ether) 108-60- 1SVOC 2,4,5-Trichlorophenol 95-95-4

2,4,6-Trichlorophenol 88-06-2SVOC 2,4-Dichlorophenol 120-83- 2SVOC 2,4-Dimethylphenol 105-67- 9SVOC 2,4-Dinitrophenol 51-28-5SVOC 2,4-Dinitrotoluene 121-14-2SVOC 2,6-Dinitrotoluene 606-20-2SVOC 2-Chloronaphthalene 91-58-7SVOC 2-Chlorophenol 95-57-8SVOC 2-Methylnaphthalene 91-57-6SVOC 2-Methylphenol 95-48-7SVOC --- 2-Nitroaniline 88-74-4SVOC 2-Nitrophenol 88-75-5SVOC 4-Nitrophenol

91-94- 199-09-2

SVOC 4,6-Dinitro-2-methylphenol 534-52-1SVOC 4-Bromophenyl phenyl ether 101-55-3SVOC 2-Bromopheno lSVOC 4 Chloro-3-methylphenol 59-50-7SVOG 4-Chloroaniline 106-47-8SVOC 4-Chlorophenyl phenyl ether 7005-72-3SVOC 4-Methylphenol 106-44-5SVOC 4-Nitroaniline 100-01-6SVOC 4-Nitrophenol 100-02- 7SVOC Acenaphthene 83-32-9SVOC Acenaphthylene 208-96-8SVOC Acetophenone 98-86-2SVOC Anthracene 120-12-7SVOC Atrazine 1912-24-9SVOC Benzaldehyde -- - 100-52-7

ProprietaryHaley & Aldrich, Iu:G :\Projects' 6 1-'1 \ VP :aUoenu Ion %, 'UP\20060922 _TargetAnalyteList_T02 .xls

I

OCi.6Uel 00 6

HDMSe00037397

TABLE I I

CHEMICALS DETEC" LD I J 'VIRG. .'E /i~ ,I ,K LA LSURit PITAIGI' (VIi~.J F.. ~~ I -I< h

- ;-

ANALY~ 5 ~,I .CU ; !A TL I CAS NUMBERSVOC Benzo ( a)an thracene 56-55-3SVOC Benzo ( a)pyrene ----- 50-32-8SVOC Benzo ( b)fluoranthene 205-99-2SVOC Benzo ( g,h,i)pe ry lene 191-24-2SVOC Benzo (k)fluoranthene 207-08-9

SVOC Biphenyl 92-52-4SVOC bis( 2-Chloroethoxy) rnethane 111-91- 1SVOC bis ( 2-Chloroethyl)ether 111-44- 4SVOC bis(2-Ethylhexyl )phthalate 117-81-7SVOC Butyl benzylphthalate 85-68-7SVOC Butoxycellosolv eSVOC Caprola ctam 105-60-2SVOC Carbazole 86-74-8SVOC 2-Chloropheno lSVOC Ch rysene 218-01 -9SVOC Di - n-butylphthalate 84-74-2SVOC Di - n-octylphthalate 117-84-0SVOC Dibenz(a,h)anthracene 53-70-3SVOC Dibenzofuran 132-64-9SVOC Diethyl phthalate 84-66-2SVOC 2,4-Dimethylpheno l

SVOC Dimethyl phthalate 131-11- 3SVOC Fluoranthene 206-44-0SVOC Fluorene 86-73-7SVOC Hexachlorobenzene 118-74- 1SVOC Hexachlorobutadiene 87-68-3SVOC Hexachlorocyclopentadiene 77-47-4SVOC Hexachloroethane 67-72- 1

SVOC Indeno ( 1,2,3-cd )pyrene 193-39-5SVOC lsophorone 78-59- 1SVOC N-Nitrosodi - n-propylamine 621-64-7SVOC N-Nitrosodiphenylamine 86-30-6SVOC Naphthalene 91-20-3SVOC Nitrobenzene 98-95-3SVOC Pentachlorophenol 87-86-5SVOC Phenanthrene 85-01-8SVOC Phenol 108-95-2SVOC Pyrene 129-00-0SVOC Tetrachloroph eno l

SVOC 1 , 2,6-Tribromop heno lPCB Aroclor-1016 (PCB-1016 ) 12674-11-2PCB Aroclor-1221 (PCB- 1221)

.11104-28- 2

PCB Aroclor-1232 (PCB-1232 ) 11141-16-5PCB Aroclor-1242 (PCB-1242 ) 53469-21-9PCB Aroclor-1248 (PCB-1248 ) 12672-29-6PCB f1'roclor-1254 (PCB-1254) 11097-69- 1PCB Aroclor -1260 (PCB-1260) 11096-82-5

METAL Aluminum 7429-90-5

3of 5

I'ropriu a yHaley & Aldrich, Inc. -0ciobc, 2006

G ;\Projects\26472\TTF\RFI VVP F1uu-~nu iu<<•iBP\20060922 TaigeiF:nalyteLlat T02 .xls

HDMSe00037398

CHEi' A-SS DF EC T iE ✓ ikONNiAIBP , W .i 1BOEIj 1G ,/ _i i . Imo' Et

VENTUR;, ;C~UilTY . C;ALIFORivsi A

ANALYSI S GROUP ANALYTE AS NUMBER IMETAL Antimony 7440-36-0METAL Arsenic 7440-38-2METAL Barium 7440-39-3METAL Beryllium 7440-41-7METAL BoronMETAL Cadmium 7440-43-9METAL Calcium 7440-70-2METAL Chromium Total 7440-47-3METAL Chromium, Hexavalen tMETAL Cobalt 7440-48-4METAL Copper 7440-50-8METAL Iron 7439-89-6METAL Lead 7439-92- 1METAI Lithium

METAL Magnesium 7439-95-4METAL Manganese 7439-96-5METAL Mercury

-7439-97- 6

METAL ---- Molybdenu mMETAL Nickel 7440-02-0METAL Phosphoru sMETAL Potassium 7440-09- 7METAL Selenium 7782-49-2METAL Silic aMETAL Silicon (as (Si02) 7440-21-8METAL Silver 7440-22-4METAL Sodium 7440-23-5METAL Strontiu mMETAL Thallium 7440-28-0METAL Ti nMETAL Titaniu mMETAL _ Vanadium 7440-62-2METAL Zinc 7440-66-6METAL CyanideSemiquantitative (TIC) Unknown Akipat eSemiquantitative (TIC) Molecular Sulfu rSemiquantitative (TIC) Unknown Hydrocarbo nTPH C6-C12 (Gasoline )TPH C07-C24 (Heavy Oil )TPH C07-C28 (Diesel Range )TPH C10-C24 (Diesel Range )TPH C12-C2 8TPH C16-C2 8TPH Diese lPERCHLORATE PerchloratepH pH

HYDRAZINE HydrazineMERCAPTANS Mercaptan sDIOXIN 1 ;2,3,4,6,7,8-HpCD D

lop ietary

Gctobe 1000Hale, ~.Idr .ch, nc .G .AProjects\264 2 \TTF\RFI WPAodei 1 ,f fc getG\~ I, o!_is~_T02,;Is

HDMSe00037399

z. i cv h! I AREA I BUt. ; l ?1 1

Ai IALYS ROUP ANALYTE CI .S NUMBE RDIOXIN 1,2,x , ,FI,7,8~HpCDF -DIOXIN 1,2,3,4, 7 ,S,O-HpCD FDIOXIN 1 ,2 3 ,4, 7,8 HxCD D

DIOXIN 12,3,4 /,8 -HxCD FDIOXI NDIOXIN

1, 2 3,6,7 .8 - HXCD D1 , 2 3 6 7,8 HxCD F

DIOXIN 1,2,3,7,8 ,9-HxODDDIOXIN f,2 3,7,8 , 9-HxCD FDIOXIN 1,2,3,7,8-PeCD DDIOXIN 1,2,3,7,8-PeCDF --- -DIOXIN 2,3,4,6,7 ;8-HxCD F

DIOXIN 2,3,4,7,8-PeCDFDIOXIN 2,3,7,8- T( fRDIOXIN 2 ,3,7 ;8-TCD FDIOXIN OCD DDIOXIN OCDFDIOXIN TODD TEQ (ND 0 )DIOXIN Total HpODDDIOXIN Total HpCD FDIOXIN Total HxCD D

DIOXIN Total HxCDFDIOXIN Total PeCD DDIOXIN Total PeCD FDIOXIN Total TODDDIOXIN Total TCD F

IPr<,,,ne1L, ,Uc:cobe 2000Halc, ~Idreh, hi(c ,

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HDMSe00037400

VENTURA COUN i ^.Lf ~) ; ;~if A

Parameters for Anal .O y ` ,nalytleat Cc•tEt F € Rational eTarget Compound List t < Ia ii )rganic EPA Method (a. h I I1, :mrical deti- .:tion of',iC in co ,fimdwate 1 'c ;ilti i cCooipounds (TCL t 1€'s) 1 richiort u . er~ci . .ni c[o~u~ , ~ .[c' i l[, ~ rsal V:<<..~ at

aruci I ompounu e .ist ut ., ictattle EPAM~-ihou S .)JC 1116wi ic,!1 d('icclioil )i phth~ll .uc_ r . H. .I i., ills disp~[,a . ; iOr ani . otnpouuu~) (fC1'-'OCs) plaslieiiei ti dud the poie![tial lot tlic t01 1.l oo of i'nxtucts t o

Incomplc« ` 'oirhu bolt (n€('~) frog tin hiii ii11 <;i a . that

could include 1)01'at[inaiic hydrocaibuns i e Ir(AlLo la )pyrene .

I'(r) [ naldehyde

IEPA Mc shod 831 AA Historical de :;ct.c, . ; and the documt ited disposal of

formaldehyde in the A1BP .Polychlorinated dibenzo - l : dioxins and EPA Method 8290 Historical detection of dioxin s/iur : ns it, site soils and sedimen tCol~chlonnated dibe :izu p iurans and the piitential I'm the loru[atiu[t in I't's It din the burning o f(P('I)t),PCDFs) wastes that could include polychl<<rin . ted hiphenyl (PCBs)

compoundsTarget , tnalyte List (71W,) Metals plus on, EPA Method 6010B , Historical detection (i .e . chromium) and the documentedtitanium , strontium , boron and zirconium 6020 disposal of metal containing wastes in the A1BP .

Perchlorate EPA Method Historical detection of perchlorate in soil leachate in the ASB P314/8321M area Outfall .

PCBs EPA Method 8082 Documented disposal ofPCBs containing wastes in the A1BP.

Nitroso-dimethyl amine (NDMA) EPA Method 1625C The documented disposal of Unsymmetrical Dimethy lHydrazine (UDMH) in the A1BP area . UDMH rapidl ydecomposes to NDMA upon contact with soil pore moisture .

Nitroaromatics ( Nitrobenzene , EPA Method 8330A The documented use of energetic compounds to detonate wasteTrinitrotoluene (TNT), dintrotoluene , materials for disposal in the A1BP area .Total Anions (i .e . chloride, fluoride , EPA Method 300 The documented disposal of reagent grade acids including :sulfate , nitrate and nitrite) Hydrochloric acid (HC1), Sulfu ri c acid (H2S04), Hydrofluoric

acid (HF ), and Nitric acid (HNO3 )

Total Cyanide (CN) EPA Method 9012A Historical detection of CN in soils within the A1BP .Soil pH Levels EPA Method 150 .2 The documented disposal of reagent grade acids and bases in

the A1BP .Total Ammonia (NH3), 'I otail Kjeldahl Std Methods 18th The documented disposal of organic amines includingNitrogen (TKN) and'lotal (iiganic Edition Method 4500 Tetraethylamine (TLA) and other organic compound sNitrogen (TON) containing forms of nit, o ai . (~uiiine, .+ inides and ammoniu m

salt,;)

Total Petroleum Hydrocarbons 0,11h E .0 l Iethod 801 the documented use of petroleum distillates t5 :.cccteratca ioi`ilic disposal of o aster in the A1BP .

C: .%` . ' 1r! t'I t - 5vv _ i,i,'J,'Y OF ANALYTICAL METHOL ., G; l& !3P`.~!h'U ~,~ F

But : ' G 5 _v:l, ; ;Lt - L ,, .)1,ATORY

Page 1 of 6TI .LiL 111 a d; P SCC PLING5

I BUF I " 'I f' "I ~duivH J 4 . 8u 1~ ; Sf N I 1 I_~) ,~ .BORATORY

:wended

~;E?° FIGURES) - bc~ c : , . Approach. ..op dp,odrg Sarn ° use,. r._ .` ,runi cr+ t ~ ' . Ir,, a Samples

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TBD (68) Focused I rregular Grid Vapor 68 VOCs Collect and analyze soil vapor sampl ;s at 3 f, tgs at Source areas, disturbed ens, 68geophysical anomolies and at locations where depth 'e a gapbedrock is 5 feet or less . Collect and analyze soil vap o rsamples at 3 feet and at top ofbedro d al location swere depth to bedrock is greater than 5 fee t

Ii Pond t 1 3

TBD (Z) SW corner of SWMU 4 . 8 - one proposed Soil 4 Extended PFl Suite Collect samples at ground su face and at base of ewe Source area 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4exploratory irench exploratory trench . HOLD sample -At base of trench if

no fi eld evidence of soil impacts .

TBD (5 ) SW corner of SWMU 4 .8 Soil 10 ExtendedRFl Suite Collect samples at 0 . 5 ft bgs, between 3-5 ft bgs , Source area 10 10 10 10 1 0 1) 10 10 10 10 10 10 10 10 10 10 1 0and/or just above bedroc k

TBD (3 ) SW corner of SWMU 4 .8 Soil 6 RFI Suite Collect samples at ground surface and 3 .5 -4 .0 ft bgs Disturbed area G 6 6 6 f 5, 6 6 6on containment ber m

-- _ 1

ri Earth pond 2TBD (2) SW corner of SWMU 4 .8 one proposed Soil

-4 Exlendcd RFi Suite ailed samples at ground surface ar id at base of eac ource area 4 -1 4 4 1 -1 4 4 4 4 4 4 4

exploratory trench i ,ploratory trench HOLD sample atbase of tienc ;' i fno field evidence of soil impacts .

TBD (9 ) SW corner of SWMU 4 .6 Soil 18 Extended RFI Suite Collect samples at 0 . 5 It bgs , between 3-5 ft bgs, Source area 18 18 18 18 18 18 18 18 18 18 18 18 18 1 9~ 18 18 1 8and/or just above bedrock

TBD (2) SW corner of SWMU d .8 Soil 6 RFI Suite Collect samples at ground sui face and 3 .5-4 .0 ft bgs Disturbed area 6 6 6 6 6 6 6 6 6 6oil containment b rm

Foy n . , Espiosiva Shopsa_ ~>

-TBI (3) East of Eai lh Ponds I and 3 Soil E • tended RFI Sui C, tsar t b- s between .-5 It is Scarce are aad or just the bedrock

- -F c r ni Jemanstrufiu,- - -

TBD (4) Former Fire Demonstration At and Soil 8 Extended RFl Suite Collect samples at ground su rfa( and at base of eac 6ouice area 8 8 8 e 8 8 8 8 8 8 8 8 8 8Sample Location RR-S - hvo Imposed exploratory trench HOLD sample al )L-s- of trench i fexplorato ry trenches no field evidence of soil impacts thet a

TBD (4) Former -ire Demonsti auon Area and Soil 8 Extended RFI Suite Collect samples at 0 .5 ft bgs, between 7-5 ft bgs . Source area 8 8 8 8 8 8 8 8 8 8 9 8 3 8 8 8Sao pia Location PP 3 alony Maas of n 1'o just above bedroc knioposed e,plci aioiy t enches

HalG-APrcji ITFIlMWP\IMP Final12006100E H AI

H D M Se00037402

Page?_ of 6SUMN I P. i uhAREA 1Blll,l 'I ~~tVrhJ r 8

BOEING °F . >l1,_;r,I ;', t FL[ L-,~ ~!t> t lFFNYIIG~gI (,I ~,iV ~'?' .li n

{ J ofGI E F ~ ~ ~ CI

CIOx

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Ai ara;: ; s atC ) P 4 x 8

E ocasa c f I _ BSS y) I'~ Number Proposec9 Ain j Approach Sampl ingo o

(see Figure Samples a a c 1v E

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BD (4) ormer (1982) excavations I 3, W of 1 TF Soil 12 Fite .awd RN Sane Colleai aamples,af 0;5It bgs, between3-5ft bgs, and Source area 12 12 12 12 12 12 t 2 12 12 12 13 12 1 2just above bedroc k

TBD (7) Former ( 1982) excavation 4, W of TTF, and Soil 21 Extended RFI Suite Collect samples at 0.5 ft bgs, between 3-5 ft bgs, and Source area 21 21 21 21 21 21 21 21 21 21 21 2t 21 21 21 21includinggeophysical anomaly just above bedroc k

1ED (3) Perimeter of former (1982) excavation 4, V I Soil 9 RFI Suite Collect samples at 0 .5 ft bgs, betweei 3-5 ft bgs, and Disturbed area 9 9 9 9 9 9 9 9 9 9of TTF j ust above bedroc k

EBD (1) Former ( 1982) excavation 5, NE of Soil 2 Extended El i Suite Collect samples at 0 5 it bgs, between 3-5 ft bgs, and Source area 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2Concrete Pad 2 just above bedroc k

inTBD (1) With formerconcrete pond, NE of Bur nPit 1

Soil 2 Extended RFI Suite Collect samples at 0 .5 ft bgs, between b-5 ft bg sand /or just above bedrock

Source area 2 2 2 2 2 2 2 7 2 2 2 2 2 2 2 2

Gontro sett#er (removed ]TBD (1) At former Control Center Soil 2 Extended RFI Suite Collect samples at 0 . 5 ft bgs ,between 3-5 ft bgs, Source area 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

andlor just above bedroc k

BM r, P i i i - - -

TBD ( 1 ) Wi9lsn toms Burn P i t 1 Soil 3 Extended RFI Suite Collect samples at 0 .Sit bgs, between 3-5 i t bgs Source area 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3and/or just above bedrock

- ------ ---- - - -

lF interim St-i ;.is Facility

TBD (1) Within Burn Pit 2 Soil 3 F tended RFI Suite Collect samples at U .5 ft bgs , between 3-5 $ bgs, Source area 3 3 9 3 3 3 3 3 3 3 3 3 3 3and/or just above bedrock

TBD (3) W, S, and E perimeter of Burn Pit 2 Soil 9 Extended RFI Suite Collect samples at 0 .5 ft bgs, between 3-5 ft bgs, Source area 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9 9and/or just above bedrock

TBD (4) Noi them and southern containment berms Soil 8 RFI Suite Collect samples at ground surface and 3 .5-4 .0 ft bgs Disturbed area 5 8 8 8 8 8 8 8 8 8of Burn Pit 2 on containment berm

TBD (1) SW perimeter of Burn Pit 2 berm Soil 3 RF1 Suite Collect samples at 0.5 ft bgs, between 3-5 ft bgs, Disturbed area 3 3 3 3 3 3 3 3 3and/or just above bedroc k

TBD (1) At former Concrete Pad 2 Soil 2 Extended RFI Suite Collect samples at 0 .5 ft bgs, between 3-5 ft bgs S^ri ce area 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2and/or ustabove bedroc k

TBD (2) Within col iainmenf m bet i of former Soil 6 Extended RFI Suite Collect samples at 0.5 ft bgs, between 3-5 ft bgs, Source area 6 6 6 6 6 6 6 6 6 6 6 6 6 6 b 6 6Concrete Pad and/or just above bedroc k

TBD (5) Perimeter of ici i er Concrete Pad 2 and Soil 10 RFI Suite Collect samples at 0 3 bgs, behveen 3-5 ft bgs, Disturbed area 10 10 10 10 10 10 10 10 10 1 0contauurrel,i bo n includin0 S geophysical andlorjust above bedieci,

°

enomalie ,BD (2) Containment berm of former Concrete Pad Soil 4 RFI Suite Collect samples at ground surface and 3 .540 ft bgs Disturbed area 4 4 4 4 4 4 1 4 4

2 on containment berm .

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V. ~ I i n t ~ I , ,AI . 7RivlA Extende dI F Suite

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t 'pprox i ma:~ '_1 umber a '

Samplesmy o, , ,i Proop, ~ ~~ Sob piing Approach SamF€i~e C rr~ra . c o

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T,13 D (2) -Within the former concrete ponds Soil 4 Extended PH Sun e Collect samples at (l : ; ; 4 bgs, betwee 3'- :) it bgs, Source area 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4

and/or just above bedIuc kTBD (5) Around and between the former concrete Soil 10 RF! Suite Collect samples at 0 .5 ft bgs, between 3-5 ft bgs, Disturbed area 10 10 __ 10 10 10 10 10 10 10 1 0

Ponds and/or just above becircick,- -~-- - - --- - -bat it] I ortu ~

- _ -- - - _ -- -- -

TED (4) Within former Ear th Pond 3 - two propose Soil 8 Extended Rt I Suit.. Collect samples at ground surface and at base of eac eurce area P 8 B B 8 8 -8 B B 8 8 8 8 8 8exploratory trenches exploratory trench . HOLD sample at base of trench i f

no field evidence of soil impacts them .TBD (4) Parameter of former Earth Pond ? Soil 8 REI Suite Collect samples at 0 .5 ft bgs, between 3-5 ft bgs, and Disturbed area 3 8 8 8 8 8 8 8 8 8

- - -- - lu st above be drock

1 4I31ed Geu tt u al AnomP Ys: :TBD (1) W of Earth Pond 2 Soil 4 RFISuite Collect samples at 0.5 ft bgs , between 3-5 ft bgs , Disturbed area t 4 4 d 4 4 4 4

and/or just above bedroc k

TBD (3 ) N of Former Fire Demonstration Area Soil 6 RFI Suite Collect samples at 0 . 5 ft bgs, between 3-5 ft bgs, Disturbed area 6 6 6 6 6 6 6 6 6 6and/or just above bedroc k

TBD (1) S of TTF, just N of southern SWMU 4 .8 Soil 2 RFISuite Collect samples at 0 .5 ft bgs , between 3-5 ft bgs, Disturbed area 2 ? 2 2 2 2 2 2 2 2boundary and/or just above bedroc k

TBD (1) NE of Concrete Pond 3 Soil 2 RFI Suite Collect samples at 0.5 ft bgs, between 3- 5 fft bgs Disturbed area 2 2 2 2 2 2 2 2 2 2and/or just above bedroc k

TBU (1) NE side of Earth Pond 3 Soil 2 RFI Suite Collect samples at 0.5 ft bgs, between 3-5 ft bgs, Disturbed area 2 2 2 2 2 2 2 2 2 2and/or just above bedrock

TBD (1) Between Earth Pond 3 and Perimeter Pon Soil 2 RFI Suite Collect samples at 05 ft bgs, between 3-5 ft bgs Disturbed area 2 2 2 2 2 2 2 2 2 2and/or just above bedrock

TBD (1) SE side of Burn Pit 2 Soil 2 RFI Suite Collect samples at 0 .5 ftbgs, between 3-5 ft bgs, Disturbed area 2 2 2 2 2 2 2 2- _- >-- and/or just above bedroc k

I BE (3) Three oeophysrcal anomalies on S side of Soil 6 RFI Suite Collect samples at 0 .5 ft bps, between 3-5 ft bps Disturbed area 6 6 6 6 6 6 6 6 6 6Earth Pond 3 and/or ust above bedror l

Wnr Mi ti P t hesLerr. gra on a waysI LI✓ (3) SW and S of Earth Pond 2, respectively Soil I 4 -Cl=1 Suite Collect samples at Ob It bgs, between 3-5 it bgs, llgralion pathway 4 4 4 4 4 4 4 4 ¢

and/or just above bedroc k

I RD (J) Along southwesternSWMI 14 .8 boundary Soil 6 RFI Suite Collect samples at 0,5 ft bas, het.recr 5 ft bgs, 11gialion palhvv,, 6 6 6 6 6 6 6 G 6and eas', of arih Pond 2 and/or just 4 on bear oc

l- T -

Erstei :- 11ryaratig nPathways iS ~,a of former (198x) . ., :cavationS 13 Soil 'FI Suit Collect mplas Z11 0,5Itogs, betvv~rn 3-5 ft bgs ; iv uiauon path~~ay 3 3 a a

and.'ci ust abo v e bedtec r

i a ich, Inc

P`I i J -'ROPOSED SAMPLIN GI „I't II r PRE .r . >WMU4 . 8

I r - 3 / I i ,t ISLD LABO F

GlProjects\26472tT -I i'Jlt.l',rP111vSP_fL ,,I',z:006 i00_-HA S3FL tl~ . : .'('t I

Page 4 of 6

Pi LJ o _[ `,nl~u i P

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j .: Sampleso

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TBD (1) SVV of former ( 1982) excavation 4 Soil 3 RFI Su e Collect samples at 0 .5 ft bgs, between 3-5 ftbg Migration pathway 3 3 3 3 3 _ 3 3and/or ustabovebed ioc k

TED (1)_

-In minor drainage E of Concrete Pad 2 Soil 2 RFI ` Banc Collect samples at 0 .5 ft bgs , between 3-5 ft bgs Migration pathway 2 2 2 2 2 2 2 2 2_ _-_ and/or just above bedroc k

TBD (4) Along minor drainage leading from Concrete Soil 8 RFI Suite Collectsamples at 05 ft bgs, between 3-5 ft bgs, Migration pathway 8 8 8 8 3 8 8 8 8Pad 2 to the SE, towards SE come - of and/or just above bedroc kSWMU 4 . 8

TBD (1) SW of former nitrogen tetroxide tank Soil 2 RFI Suite Collect samples. of 0 .5 ft bgs,, between 3-5 ft bgs, Migration pathway 2 2 2 2 2 2 2 2 2 2and/or just above bedrock

TBD (1) In minor drainage E of former Control Soil 2 RFI Suite Collect samples at 0 .5 ft bgs , between 3-5 ft bgs, Migration pathway 2 2 2 2 2 2 2 2 2 2Center and/or ustabove bedrock

TBD O 2 Along minor drainage E of Earth Pond 3, Soil 4 RFISuite Collect samples at 0 .5 ft bgs, between 3-5 ftbgs, Migration pathway 4 4 4 4 4- 4 4 4 4 4draining towards the E side of Earth Pond and/or just above bedrock

TED (2) Along minor drainage SE of Concrete Pon Soil 4 RFI Suite Collect samples at 0,5 ft bgs, between 3-5 ft bgs, Migration pathway 4 3i 4 4 4 4 4 4 43, draining towards the SE and/or just above bedroc k

_ 1 VNStfrptadfdGdilAr 3

TED (2) NE of Earth Pond 1 Soil 4 RFI Suite Collect samples at 0 . 5 ft bgs, between 3 -5 ft bgs, Day pop ! 4 a. _ 4and/or just above bedroc k

TBD 1O No th-central SWMU 4 .8 boundary~ Soil 2 RFI Suite -Collect samples at 05 ft bgs, between 3-5 ft bgs, Data gap - _- -2 - 2 2 2 2 2 ? 2 ? jand/or just above bedroc k

Eastern Data GapN,l yTBD (1) Between Concrete Pad 1 and former (1982) Soil 2 R-I Suite Collect samples at 0 .5 ft bqs, between 3 5 ft bqs Data gap 2 2 2 2 2 2

excavations 1-3 and/or ust above bedroc kTBD (1) Concrete Pad 1 Soil 2 RF LSuite Collect samples at 0 .5 ft bgs, between 3-5 It bgs, Data gap ' 2 2 2 -- 2 -__ 2 2

and/or ist above bedroc kTBD (1) N of Concrete Pond (removed), NE or Bu Soil 2 RFI Suite Collect samples at 0 .5 ft bgs, between 3-5 ft bgs, Data gap 2 2 2 2 2 2 2 2 2 2

Pit 1 ardlor ust above bedrec kTBD (1) Former nitrogen tetroxide tank at NE cor n

of SWMU 4 .8r Soil 2 RFI Suite Collect samples at 0 .5 ft bgs, between 3-5 ft logs ,

and/or just above bedreckData gap 2 2 2 2 2 2 2 2 2

TBD (1) NE of Control Center (removed) Soil 2 RFI Suite Collect samples at 0 .5 ft bqs, between 3-5 ft bgs, DptM gep 2 2 2 2 2 L 2 2and/or lust above bedrec k

TBD (1) N of Control Center (removed Soil 2 RFI Suite Collect samples of 0 5 ft bgs, between 3-5 ft bgs; Dot-i gap 2 2 . 2 2 2 2 2 2 2and/or ust ,bore beuioc k

TSD l°)- s t e r n ;

Y ~sf e rnnlost drain 'J\/ o` ion /

Hummocksbecunau,

Scii

~I . . L it o L_€ . .__ I, by _u . 0

and,'o, jest o hedrox ,C : .ithin c ninagcDcwn-draniage sample 4 i

TBD (3) South of Northwest I i mmoct . Kith of e tc n nevi, 6 RFI Suite Collect samples at 0 .05 ft bgs, between 3-5 ft bgs Down-drainage sample b 6 6 6 6 6 6Earth Pond 1 Sal and/or just ;hove Led ock within drainag e

G\P,ojscc '2,,12iT lr~! .wI'1lfdlk ' In k"U0b 100=H, i SSN Fat e. IF

HDMSe00037405

E~Landed Su

PE! Sit

Page :5 of 6' )POSED SAMPLING

I,F E / SWM U=ILLD I ;,B0fATCR Y

V ,.,i OR N

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3ampling App . o~i,

!

ac,Aiono . ,- FI SURE 9) . . . w„r . •„ ;V ~cai Suite Proposed Sampling Approach nl ..re Saml ~ ]l! L~' 11 11 L

E ro c7

U -A

0 7i r_a

TBU (3) 5W at Earth Pond 2 Sedrnlcnt, I 9 Rn1 Suite Collect samples at 0 .05 It bgs, between 3-5 ft bgs Down drainage sample 9-13 9-13 9-13 9-13 9-13 9-13 9-1 9-13 9-13 9-1 3Soil and/or just above bedrock, within drainage, and a t

drainage banks Collect additional samples at 10 f tstep-outs of bank locations and HOLD, pending ,drainage result s

RD NE of Outfal 011 at SE corner of SWMU Sediment, 9-13 RFI Suite Collect samples at 0 .05 it bgs, between 3-5 it bgs Down drainage sample y- i3 9-13 9-13 9-13 9-1" 9-13 9-13 9-13 9-13 9-1 34 .8 Soil and/or just above bedrock, within drainage, and a t

drainage banks . Collect additional samples at 10 f istep-outs of bank locations and HOLD, pendin gdrainage results .

s uttee a_ t7r (P f ::TBD (1)

___ __South of south-central SWMU 4 .8 Sediment, 2 RFI Suite Collectsamples at 0.05 ft bgs, between 3-5 ft bgs Down drainage sample 2 2 2 2 2 2 2 2 22boundary Soil and/or just above bedrock

_ _

TED (3) SW of SWMU 4 .8, in western drainage Sediment, 9-13 RR Suite Collect samples at 0.05 ft logs, between 3-5 ft bgs Down-drainage sample 9-13 9-13 9-13 9-13 9-13 9 13 9-13 9-13 9.13 9-1 3Soil and/or just above bedrock, within drainage, and a t

drainage banks . Collect additional samples at 10 ftstep-outs of bank locations and HOLD, pendin gdrainage result s

TBD (5) Along eastern drainage, SS of SWMU %' .8 Sediment, 13-17 RFI Suite At single sample locations, collect samples at 0 .05 ft Down-drainage sample 13-17 13- 13-1713-17 13- 1 J -17 13-17 13-17 13- 13 -Soil bgs, between 3-5 It bgs and/or just above bedrock q 17 17 17 1 7

the multiple sample location, collect samples at Q .C 5bgs, between 3-5 It bgs and/or just above bedrock ,within drainage, and at rlrainaga hanks Collec tadditional samples at 10 It step-outs of bank locauu n

and HOLD, pending drainage results .

T B D (?l Along drainage S of confluence of E and Sediment, 4 RFI Suite Collect samples at 0 .05 it bgs, between 3-5 it bgs Down-drainage sample 1 4 4 4 4 4 4 4 4 4wa„iuges near SWMU 4 .8 Soil and/or just above bedroc k

BD (C) Approximately 900 ft NE of Outiall 001 Sediment, 9-13 RFISuite Collect samples at 0,05 ft bgs, between 3-5 ft bgs Down-drainage sample 9-13 9-13 9-13 9-13 9-13 9-13 9-13 9-13 9-13 9-1 3(Sample location BCBSO7SO1) Soil and/or lust above bedrock, withir ci r mage, and a t

drainage bunt's Collect additional samples at 10 f tstep-outs of Lank locations and HOLD . pendin gdrainage r : :anlts .

TEt7 (1) Nppro ,imately 350ft E of Outfall 001 Sediment, 4 RFI Suite Collect samples at 0 .05 ft bgs, between 3-5 ft bgs Down-drainage sample 4 4 4 4 4 4 4 4 4 4Soil andAor just above b dtocf;

215-225 samp ling tunncations APprox number of souP lei , i" 433 Totals 6b 345 3 -ach 130 130 130 130 130 130 130

G\Projesi JITTI iL VJi',lklr' Lna112UU 1 ((U'--1n1 SSt1 M IU Is

F

Jclobe. -006

HDMSe00037406

K)TE ;-? AND ABBREVIA r .1iag

1 . The proposed samplin , isle " (,ii dhis taLMe ar Ih o wr i on Figures 7 ,i5 ( t

pH (150 2 ), -'L. ,i'uu ( :':30111.j, dioxins l2- Hs (da/J'4, NUM! . (I >2 ii ;l j

EPA lvieihoc Noj[ibers / )C ( G 5, (;2008}, SvOCs (82/uC), i .,r n< Io coyd ( ~3"I P.), ni roger c nnix ur ris (965 ,SM4JC0), ii i, is ;65105 . 0020 I (FE) /411A), cy l lic e (30121;}. (80 i'. ;, pcrcialoi ,tc. (0321 f } . ili c (; 'i

Nitrogen tolnls includliiq i0iiraiE -, (50! 046 EPA Method 0056) cod NiuOO s, Total Organic Nitroge nand Total Kjelrlahl Nitrogen St 500 ( S-aecfard Methods 18th en . Method 4500 ).

Samples collected for Sc' .avaleni chromium will be held pending the total chico lot resuhs . Hexavalent chromiu m

PotoniiS iivdrotlilc fili" Sots will he cMlaludie0 by a'la^lyzing f n i11tusud llClh)/I'oll .ie (lNDMA) .

PCBs well be I~M ld and an Flyzod in samilles containing elevated oil - range 1St (= 1000 Illg/kg) .

will be wnon samples containing elevated total chromium above `.he background concentration .

`J~ rlch, ho.cibC26'IL ', t rr\ilvi vvP\Ilvi Vii Einaivduu,.

AREA IV AREA III AREA it

UNDEVELOPED LAN D

ai Jwrt Pit (SWMU 4 .8) Boundary

AREA I

STALE IN FEET

400

vtNfUr

J, I he ona nal " , of this fig ar indatles'asand sad:, n ,,tr. copy

of it ire -hould not be used becacse it may not,,, , aitsent the mformallon presented

°1N RFIWORKPLA N,Ni SUSANA FIELD LABORATOR Y

t t 0Th CALIFORNI A

OCTGEEI? . IA FIGURE 1 A

H D MSe0003740 8

Legend

UNDEVELOPED LAND

UNDEVELOPEDLAND

(BOEING )

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ProF Orrdyo Fill 335 1

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AREA IIIleased to DOE)

8515 SIP

SNA AAREA I

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CBS V

Area I

Bum Pir

RI Pond

C'L III

Perimeter Pon d

69

UNDEVELOPED LAND

(BOEING)

IFIFr

CIL

Bowl

BOEINGAREA I

nma I Landfil l

AP7Fo /11111113 5

crayon

V a

BI

- in

MAP COORDINATES IN

STATEPLANE,NAD 2r ZONEV

Le end

Leachfields by Owner NPUES D .,d a ya , on tDOE ;ounu .. WO .-BOEIN G

5 . Eees hyOwne r

DOF sroandwater 'ell,

NArPr

HOEING

HMSA, SNAPv

Pslol R,o0

n Q RMHF

O !°~O 801 0

L- h nem

~~

8132 SR E

e a s a v

Area IV B 6 '1

h1,9 L ..ch'icln

3393

OC Y

e l .n r,~n

[192 9

SE D,,,, Slorag e

~ p 0 0Landfill WarJiol`e ECL l SilvelnnlyM l l Cl oli

duildin' 5(

Lin

J o ~\

oFSOF Le Ch Feldh"`9.ampnlrnc A

Report Grou p

Number Area Nam e

NortheasternSoutheastern

North CentralCentralSouthern Cenha lBurro Flat s

Northea+ Aea IV

North Are . IVWestern Area IV

Western Ponds

Notes:

1. Property ownership labeled for administrative areas2 DOE has leased and used several buildings In Area N .as snuwn9 All NASA [each fields located at RFI sites

Base Map Legend

HaP' V'Il,y

SSIL gn : y

Pun i

a .Ides

A,I Ang

del

F1

SSFL RFI Report Grouping s

SANTA SUSANA FIELD LABORATORY

FIGUREMWH I B

HDMSe00037409

)-03

RS-07'

Please Note . The original version of this figure includescolorized features and shading A black and white copyof the figure should not be used because it may notaccurately represent the information presented .

AIBP SWMU 48 RFI WORKPLA NBOEING SANTA SUSANA FIELD LABORATORYVENTURA COUNTY , CALIFORNIA

HISTORICAL SOIL SAMPLING LOCATIONSAREA I BURN PIT - SWMU 4 . 8

SCALE : AS SHOWNOCTOBER 2006' FIGURE 2

SL-40-0.5 It bis

Boron ~~ . 15 mgikgCadmium 13 mgikgCopper 54 mg/kgSilver 1 .1 mg/kgCyanide 0.1 mg/kgPetroleum hydrocarbons 25 mg kgFuel hydrocarbons (C16-C28) 490 mg/k gPentachlorophenol 4000 mg/k g

2-2 .5 It bi sCadmium 8 .5 mg/k gMercury 0.15 mg/k gCyanide 0.12 mg k gPentachlorophenol 0 23

mg/kg

0 .5 it blsSL-1

mtnm 1 .3 mg/rugI, -Ty 0.2 mg/kgI du,lewu hydluuarbons 13 mg/kg

Di n-butyl enthalate ( 122 mgikg

SL-20-0,5 It hi s

CadmiumChromiumCyanide

21 mgikg68 mg/k g

062 mg/k g

0.0.5 ftblsSL- 3

CadmiumCopperLeadPetroleum hydrerarbone

~Di.6-tiotyl nfrthalate

3 .3 mgikg47 mgikg98 mgrkg11 mg/kg

U 2 mgikg

rr ,TTFD-3

S0-0 .5 ft bl sDioxins and Furana2378-TCDDTEOi 2049 .9 pgfg

TTFD-4

@_0-0 .5 ft bl s1 Dioxins and °urans(2,3,/

8-TCDD TEQ 179.5 /g

T-FD-

Legend

FIGURE LOCUSAREA I BURN PIT

onitonngWel l

.,I nwortnFuln alt, l.Cr ,ra:ava 22,

aoo 40 0

SCJ. ,: FEET

0229-7

SL- 1

SL 2

RR- 1

0 TTF-)-0

SL-30229-5

IP, 0229-6

RR-1-0 .0 5 It bls

CadmiumChromium

6.2 mg/kg43 mg/kg

TTFD-6 (DTSC)

10.0 (ft bl s

) ioxinsand Furans. . . . .A-TCDDTEC 3:99 . pc/n

TTFD- 1.)0-0 r fl bls .

G loxln< and Furansi 9 TCDD I EQ) 5251A pg/gI

DR- 1@ 0-0 5 It bl sDioxinsandFurans1278-TCDDTEQ) 1780:45 pglgDR 2

DR-2DR- 3DR-4

DR-40 C-0 .5 it hisDioxins and Furans(23 7,8-TCDD TED) 2136 .96 pg/g

@0.05itbl s

Dioxins and Furan s)2,3(78TCDDTED) 27 .86 pgi g

DR-32-2;5 It Ibi s

Dioxins and Furans(2.3 ,7 8-TCDD TEO) 0 .19 pg/g

yea o' Belled Detn s

r -reiel 1962)

Mere

r Iby ICF Kaiser (1993 )

L~ll .il ,li",ttr~ I~Ornsrds

Sri .mple I D(aq 0 0 ' - rplh r Feet bls bCuvlbnr• rawCopper 23 mgleg Analyl, Couwntabon Unite

1902 Total Equivalen t

0 pg19` A TEO value of zero is reponer - .el ,due to OCDO detect ion in boty . t r d,, at,,samples

F

TTFD•5(DTSC )

0-0 .5 ft blsDioxinsand Furan s2,37,8-TCDD TEQ ) 8.18 pglg

SotlSa :r ;. . _li:de Jby erdmg +sonAssociate ' 111-a2 )

So jam , Ie-ledb y: . . . . .GWRC, 1993-1994

Sot Sampl olr 'I n yHaley & A ldnch/DTSL 201. .

Ld .Len'i'r.r I

TTFD-2@0 -0.5 If bls

Dioxins and Furans(2,3,7,8-TCDD TEQ) 290 .2 1

SL-6w 0-u .5 it blsCadmium 22. mg/kuFluoroe 10 m Ik c

SLb11' 05

SL- 7@ 0-05ftblsCadmium 1 ...4 ..,mg/kg

W

SCALE IN FEET

Q 0 .0-5Tt rls

Ca) 0-0 .5 ft bl sBoron 120 mgikgCadmium 71 mg/kgChromium 860 mgikgCopper 41 mgikgLead 92 mgikgNickel ;4 mgikgMercury o4 mgikgFluoride 10 mg/kgt'etroleunl t 0.0421bu lls 5 m Ik g

Cadmium b 18 mg/kgDI n-but ahthalate 2 m Ik

SL- 8

Note: Only detectedanalytesabovebackgroundareshown - ------on map, all other analytes are below detection limits and/o rbackground levels .

Note: Perchlorate analyses performed on leachate samples ("TTLS#" )that are co - located with soil matrix samples ("ITBSII). Only `TTBS' IDsshown here

IPAPetroleumhyem,a, FI P,Fuel hydrocarbons ( '1Metals (EPA Methoc 1Mercury (EPA With, '410)

Sele tun/ (EPA 1,1'I I 4 irlCyanide (EPA .. cling 9010

Lithiu mFluoride

i )

,5oll sampes 4e,,lecleuby 1914) .Dioxins and Furans EPA'' t 8280)

991-1962)•n1 ,filer -lI ~gl .vu"netho

PA Method SW-846 )F e _PA Method SW-846 1F iII die sN

ialdelryd e

Soil samples collected by I lo ley & AIdrichlDTSC (2005) . : :Dioxins and Furans (EPA Method 8290 )

Pease Note The gnaiversioa fthsrgureeludescbloneedfeatures and shad.h.) A black and wire Coylyof the figure should not be used because it may ne'.

accurately represent the information presented

AIBP SWMU 4 .1' FFl WORKPLANBOEING SANTt7 LUSANA FIELD LABOR' TORYVENTURA COUNTY CALIFORNIA

I IISTORICAL SOIL SAMPLES WITHELEVATED CONCENTRATIONS OFANALYTES - SOUTHWEST AREAAREA I BURN PIT - SWMU4 . 8'tUAI' ~,5 titi Ak

BEl- J06

SL-320-0-0.OftoleBoronCadmiumCoppe rCyanide poi mglxgFuel hydrocarbons lC1 6-C33j 10n,9A 9Petroleum hydrocarbon, 12 mgrk gFl uoride

225 It bi s

Cadmium ft mghg

Meth ne Chloride p 008 mg/kg .4-4h5 It bi s

Cadmium 57 mgrkgMethylene CFldnde 0008 rii /k

6.6:5 it hi sCadmium 6 mglk gMethylene Chloride 0008 rn 4i

6-85 ft hisCadmium 6 .2 mglkgMethylene Chlori de 0.008 m Ile

10-10 .511 it sCaamum 64 mg/k gMethylene Chloride 0,01 m 11,12

12-12.56 hi sCadmium 6A mg/k9Mercury 0.93mglk gCyanide . .. .071 mglkgMethylene Chloride 0.01 mgikgAcetone 0'04 mi

arbor Disulfide 0006 1ngk 3

Fre r 113 0008 mg/kgQS

N03

0ro0

00

Legend

Chatsworth r mrmation Monitoi,ng Wch

Shallow MOnharbn9 Nel l

Property Pa 4odw y L n e

Streams

T it Intern, Status r-aali:y

(Area addressed in tit, Interim Status

Facility Closure) . .. .

DLl '

00 .51 bisPerioleum hydrocarbons 10 mglkgCadm um i .6 mg r

0229-12

(36Ch7GK (1 1? .0 fT b $

L-32

SL-12

SL-33

L-34 - l3 SL-35SSL-37 I SL-38

aot Luril t ns (98 1

',react oblimerI I,-1611

L,,:avatlon Perimeter ; 1'18 :)

[,proximate Location wlrei e1,nomalies Identified by CF Kaiserwere Exhumed

0229-929-1 0

n

Pornoeum hydrocarbons . 18 mg/kg

Baro nCadmium 11kcjCyanide mglkg

Petroleum hydrocarbons 41 mglkgSilver 0,95 mg/kgCadmium 77 Mg/kgCyanide .4 mpiko

4-45 It bla

Petroleum hydrocarbon

Me rcu ryNickelCadmiumCyan deMethylene Chl rFreon 113

m"'qg11 .ckg

SL 19

0229-30229-4

5L20@0-0511 OnCadmiu m

S L-18@ 0-0511bis ..Cadmium . . .

SL-40

SL-22noon bin

r,

idm u

pier gdrggam

rs .rr:~ 9rkg

~erce fN,

SL-22

SL-23SL-23

r 00.5It b15Cadmium 82 mg/kgPetroleum hydrocarbons 6 mglkg I

deem hydro-re 34 g/kgsari 220 glkg

9 glkg

Chrbm cm '.99 mglkg

Malybdenrm 5e mglkg

Nckel 350 mipku

C rim . . . 0e mhg0.ebllblslbphtsample) ._ .

P im hydeoaiMns 5 9

I rardca,bonilc1O-C24It mgt

043 mglkgno morxa+3 . inglxg,2 gikg

mgrk g

9k g

Wkg9l99Akp

SL-2 6

h k

Pelre`ram hydrocarbons 13 mg/kg

1 lei hwlrocarbons (01 2Cs)

6 mum

Boron

Cad, rn

Chromium

CopperMal","Cyanide

Lead

x,m

N rLPi

SilverzniMesa

20 m0:hg350 mglk0

13 inglkg

10 mgk g

290 . mg/k g54 mglkg

05 mg/g84 mgk g54 mglkg1

300 mglkg

4,8 mi260 mg/kg0,27 mi

SL-24

I rimer Concrete Ponds/Pads

993)

Soil Sample Collect edby 'l arding LawsorAss00ates (1981 1G.Ll

ir6l u05)

-r a Gwn Rit SdvVJ 0, [t0uudeiy'

caul en PoOA

Soil IDp 6-C Depth in Feei bis Be ow land surface

Copp. rig AnalyleCOncentratlon Unit s

TEO- Iotal Equivalen t

0 pgig' ATEQ value of zero is reported invalidation datadue to OCDD detection in both soil and blanksamples.

J =7 20

fay.. iS( ALE IN FEET

SL-25

SL-25

SL-26

10- 45 It bisPetroleum hydrocarbons 13 mglkg

Fuel hydroca rbons (CI O

C24 as0/ceci) y ,glkgBoron 10 mglkgCadmiu mChromium mglkg

Molybdenum 54 mglkg

Nickel ICU mg/kg

Cyanide nglkp

Trichloroahlrn O L, 1 .1 n/ku

Analyses Performed . . . . . .

Note : Only detected analytes above background are shown

on map ; all other analytes are below detection limits and/o rbackg round levels .

soil samples colledte l l 1VOCs (EPA Method 8240 )SVOCs (EPA Method 8270Petroleum hydrocarbons (E f 2 -418Fuel hydrocarbons (EPA M-,a 8C1Metals (EPA Method 601 0Mercury (EPA Methc' 7-Selenium (EPA Method iCyanide (EPA Method 901LithiumFluoride

Note: Perchlorate analyscs pertonned onleacnate samples i"rTLS#' )that are c o-located with soil matri x samples ("TTBS#') Cnly TTBS" IDsshown here.

So il samp les colected I- II, 1 cVOCs(EPA Method SW-840)PAti(EPA Method SW 04C'Phenols (EPA Method SW 846)Phthalate sMetals . . . . .FormaldehydeHydiazinesMercaptan s

Sod sari plan utieded by NhDiems ai,d Brans (EPA Idetho .

Soil samples collected by I airy drirhll /05)L r r in sand uurans (EPA t i-dlod )C

SL-27 SL-2710 .05 it blsMercury 052 mglkyCadmium 97 miChromium 48 inglikoN,ket a_ :--

40.5 it oil (Splh Semple)Petroleum hydrocarbons 2 1

Bor

on

Chromium:

CopperNickel

Cyanide

GALE- -S H )NIP;

uCTOr3L P

Pleas 20 ig /a - sic ollhsfguren -'ud

co1o, wile h e c back and twrecopi

olme rgui' be us cause a ma ycuratelyi e nhe if-at- p re sente d

c dP SWMU4.8 RFI WORKPLA NC' -)EINC SANT ',USANA FIELD I ,,GORATORY : : .' .Nl URA 0 11Tr ;CALIFORNIA . --- ---

HISTORICAL SOIL SAMPLES WITHELEVATED CONCENTRATIONS O FANALYTES - NORTHEAST ARE AAREA I BURN PIT - SWMU 4 8

FIGURE 4

FIGURE LOCUSAREA I BURN PI T

0 200 400

SCALE IN FEE T

Analyses Performed

Note Only detected analytes a bove background are shown on map ; allother analytes are below detection limits andlor background levels .

-~pIns (looted by Harding La -1.oa 1 1Method BW846)

f (EPA Method S00-846(. ..

r rdi(EPA Method SW846)PtltsalatesMetals

Formaldehyde

Hydrazine.,:

Mercap2ans

16.Cted ty CWRC :1933;k' .th, 18210 1

P Iola I EI t Mc11 4418

Fuel a il~p ;, M I Kl 801,

Metals (EFA M t I 0 crMartyry r :PA M 1 174 )

Selen ci EPA M x 7470)Cyanide AP/, Mathad C7 010) .Lithium

Fluorida

,a nph~s c1Il Ord ly GWRC (1994(Dmoinsand FUa le'A MI hod 8280)

L SOlsamplescollected Ly cal y s a ur cn LTSC (2005)Dioxins and Forams (EPA Mettad 8290)

SL-103 I

RR-3

0229-12

SL-1 8

SL-12 0-0 5 it hisS43 6

Boron 14 mg/k0Cadman 11. .:mg/kgoat 59-.Ingrkg

F 11, _arbons

741 25 mg/kg

7

us(Bedrock @ 1 3 0 f ( (

/0

SL37

S g bus

SL-32

SL-36

! Bedrock @ 6 . 0 ft bls~

543 3

50 5. .059 h isBoron 14 mglkgCadmium 7_a mgikg

Copper 30 rmglkg

Cairo 140 mglk gan,:o, 015 mNkA2-2 .5 9 his

CadmiumAcetone. ----

CarbonDisul4de

Freon 113

1kg

Meth )eon Chlonde

4-4.5 ft his

Cadmium 47Mercury . .. . a co n>g>kg

dyanlde 0 15 ,glkg

Acetone C 0` m,kgCarbon Disulfide 0 A6 mg/kg

Freonal3 0006 mglkgMethylene Chloride 001 m d, g

SL-3

SL-31

Cadmum

/S[--33SL-34 SL-35

SL-37

Boron 79 m : 1Cadmium 17 m 1

Nickel

Zinc

0229-20

0229-160229-14

0229-90229-10

SL-38

36 6.059 maSL-36

Boto,CadmiumBenzene

0229-3n 0229-4

it q

-05 b0

Flaade

SL-39

SI A£ = SL -4224 m a

SL 1 0229-1 1SL•1 7

0.0511 hi s

oat aa.mh rocarbons9 .9 maikg

27 realka SL-43o-05nms

SL-"

I mgrkg

9 mg/kg

16 mg/kg

75 mg/k g

u 0354m

SL-40SL-22

SL-23

B kd 5 ft bu s3 I'llroc @o . Cadmium 8 3 mglkgFluoride 79 mglkg

S L 41 Cyanide 021 mglkgSL41 1,11-Trtchl0rdethane 00074 mg/kg

00 0-C5 It bus (5 2-251tbinCadm um Beryllium 16 mglkgCopper Cadmium 9 3 mglkgBenzene

Copper 32 mglkgZinc

120 mg/kg

05It Ni

SL44Mercu ry 36 mg/k g0

Cadmmms

3 . mglkg Petroleuia hydrocalbors 11 mg/k gNickel 37 mglkg Fluonda 7 a mglk gP-1111 I vtln rnrh hi 21 Y-u l Cyanide o'/ mill/k g

Acetone 003mg/k g

Melhylem Ch-me 0406 mg/kg

SL-44Freon71a 0036 m ikSL-13 0229 -15 0229-19

0229-1 30229-170229-1 8

0229-21

aU)

17

050U050

rT

C?

ry

n

r3

Legend

Property Boundary Line - . .

Streams

inter rill Status Facility

A 'r1 =nn~d[ l s(1Sa1 1

1 It ;admvnt .1341,

Pion Po rider 1982)Applox!mate ocationwhereAnomalies Identified by ICF Kaiser (1993)here Exhumed

Cadm um 2. mglkgPetroleum h " rocam001 59 t1i lkg RR-7

Pta f 1 slgrn loft I'b' tS re u :udcscolo nized feature . and shading K black a id hit, mpyof the figurm. should not be used Ia aausr. iLtray /accurately represent the information presented

Soil Sample GuL-1L(i

by Hardng a .leon

1ussodates 19/1 '4n

3@ O -C P bus Leptn lr Eect t , land ui`uu,Copper 33 mglkg Analyte ignxntratlon Units

Sol art plr r,ulleued .,yCVJRf: 1%3-1904 .

Sod bampleGollected oye Haley & AldnCh(OTSC (2005)

To Thor Cor ifetaPonds/Pads

n ., 25

SCALE IN FEET . . . .

50-40

AIB'PWMt A oORKPLAtd3 10 FINC , fir V tl -1FLO a(tJPATORYVENTURA,. .~UN,\LIFCRNI A

HISTORICAL SOIL SAMPLING WITHELEVATED CONCENTRATIONS OFANALYTES, THERMAL TREATMENTFACILITY, AREA I BURN PIT'',LE AS SHOVJNcr, OBER2006 FIGURE 5

SL-2 812 1-1,11 Ibi sPetroleum hydrocarbons 11 mgrk gBoron 1

Vg/kg .

Cadmium pi mg/k gCopper ;& mgrkgCyanide 1714 mgrk gTric hloroethene 0b035_ ..tug/k g

2 .2,5 ft bi sBoron 18 mg/k gCadmiu mChromium i mg/k gCopper 3ti mg/k gNick==-I 73 mg/kgMercury 4 mg/kgCyanide ---- 0 4 mg/kgTdchlo roeinene 0052 ;,g/kg

4-45 ft asPetroleum hydrocarbons 6500 mg/kgFuel hydrocarbons (C7-C2 8as diesel) 4400 mgkgCarbon tetrachloride t 2 ,,O q1 ;4-Dlahbrobenzene 82 nigikg11-Dlchloroethene ? 1 mgMg

1 Tnchlo roethane 110 mg/kg :2-0mhlombenzene (UOC) 15 mg/kg

12- Dlchlorobenzene (SVOC) 4' rog/k 11,3 Dchlorobenzene 1 a riglb yF,ean t? mglknr

Tebacllorodhene d8 nun'rq

Toluene o Oa mgrkgTnc8lorontnenc 190 mgrkgBoron / nlglCy : .Cadmium . 3 t mgk 9Cyanid, r 12 144 1- S

SL-90-0 5 ft bI s

Cadmium 2 .2 m /km 0-0 .5 ft bls (Split Sample )Cadmium 10.6 m Ikg_

a L.w Mcnroang Wei.I

N r -1y Bcandaiy Lirc

SI Warn s

i F tI' r l-tatr I rty

I . 1 Stah a

k - dhy r.iiSure)

SL 9

nI'w rth!oI -4onMonito ringWell

Analyses Performed

Note : Only detected analytes above background are shownon map( all other analytes are below detection limits and/or

background levels : . . . . . .

Note : Perchlorate analyses pertormed on leachate samples("TTLS4") that are co-located with soil matrix sample s("TTBS#") . Only "TTBS" IDs shown here.

Sod samples collected oy Hard t g Lawson associates (1981`̀VCC5 ( EPA Method SW 846 )

PAH I _PA Method SW-846Phl (EPA Method SW 846(PhthalatesMetalsFormaldehyd eHydrazinesMercaptans

Soil samples Ilr~ 11/ - FPC l963) . . .VOCs (EP r Methor fl74C)SVOCs (EPA Method 8270)Petroleum hydrocarbons (E PA Method 4Fuel hydrocarbons (EPA Method 8015 )Metals (EPA Method 6010)Mer cury ( EPA Method 7470)Selenium (EPA Method 7470)Cyanide ( EPA Method 9010)LithiumFluorid e

Soli Saint, s nlecler hr t 1,

Dioxins air1 Furars (L M

So at ( ,lle(t,c by la Idnch/D rS( [005)Dioxins and rurans r EPA Method 8290)

SL-1 0

0-0 .5 ft hi sPetroleum hydrocarbon s

(Cadmium1a rig/kg

23makg

SL-1 4

@ 00.5 it bi sCadmium 7 mgrk g

Tr, sron ofthis rig mecf shabn A buck d -as c.,

of the routeshoL s useu because d may notat information presented

f Boned Gebns

;I Sed meri t

date Luc4llonwitiles Identified by CIFlimed

-crr ;onrrele 1,1/4 . 'ads

0229-1 2

SL-10

RR-3

SL-14

0229-2 1

SL-1 50-0 .5 it bt s

Cadmium 75m Ik

0229-1 8

Phosphorus 110 mg/kg

1 ;11-Tnchloroethane 1 log kg

1,1-Dichloroethane 2 mgrkg

Naphthalene 2 mgrkgDibutyl Phthalate 1 mgrkgHydrazines 0.4 mg/kgMercaDtarrs 2 rnolku

0229-21 rna 2ftbis1-hrophorus m0/k9

SL-1 60-0 5 Rbig

Cadmium 9.5 mgrkgDI n butyl Phthalate 022 mg/k g

SL-32 Soil D@005 Us Depth Inl ce nl :- 3elow land surfaceCopper 33 mg/kg Asalyte ConciII ion Units

TED = Total Equivalent

SL 2 1

So l aatnph l oheGed byGWRO 1993 199 4

Soil uamp byHaley & Alan ..:,. . ,

FRa r 1i", Fa (y81,10 4 d ) 3aur

0229-90229-1 0

022.9-11S( 17

0229-20

0229-160229-1 4

0229-13 0229-150229-1 9

0229-170229-1 8

SL-16

SL-4 2

SL-3 9

SL-43

n SL-4 0Bedrock 01 3 5 ft bi s

SL-41

SL-44R R ;7/

0229-1 5~2llpls11Dichloroethane 10 mgrkg

1 1 Dichloroethene 2 mg/kgTnchlorootheno 5 mg/kgChrysene 2 mg/kg

Phusplloiua 160 mg/kgI71-(,hr yt Phthalxe 1 mg/kgMcrwptans 6 mg/k g

0229-1 9@ 3 ftbl sI'ho51p homs 330 mg/kg

SL-22

SL-2 1

RR-4

SL-24

- SL-2 5

0229-2 0

@3 ffbl sPhosphorus 260 mg/kgHydrazines ---- 34 mg/kg1 1-Dichloroethane - i r1 g/kgAcenaphthene 1 mg/k g

- n°glknChrysen eFtrarene ---- 1 rr tkgPyrene 1 mg/kg

Toluene 2 nlglkg

Diethyl Phttalate I mgrkg

RR-6

'SL 28 0229-1 SL-2 90229 2

RD-03

[3ecrock qn 5 0 ft U s

Bedrock a 4 5 ft Us]

0.@ 05 it bl sCadmium

SL-3 0SL-30

L sHOWFrOCTOBEP 2006

FIGURE LOCUSAREA I BURN PIT

' C-LE t, FLL 1

12 mg/kg

arc

SL-2 95 it bi sor 'rydrocarbons 16 mgrkg

Cadmium 97 mg 1kg

---_-----_ RJ;Q~- I

Bedrock 5 .0 ft bi s

lBF SNMU'18RFI WORKPLANROL', -l ANA FIELD I ABoHA I ORYVENTU JNi CALIFORNI A

HISTORICAL SOIL SAMPLES WITHELEVATED CONCENTRATIONS OFANALYTES SOUTHEAST AREAAREA I BURN PIT SWMU 4 .8

FIGURE 6

Please Note : The original version of this figure includescolorized features and shading . A black and white copyof the figure should not be used because it may notaccurately represent the information presented .

AIBP SWMU 4 .8 RFI WORKPLA NBOEING SANTA SUSANA FIELD LABORATORYVENTURA COUNTY, CALIFORNIA

R ECENT (2006)AND RESULTSAREA I BURN PIT

SCALE:AS SHOWNOCTOBER 2006

SWMU 4.8

FIGURE 8

HDMSe00037416

7 j

t-03

pRiS-07

Please Note : The original version of this figure includes

colorized features and shading . A black and white copyof the figure should not be used because it may not

accurately represent the information presented .

AIBP SWMU 4 .8 RFI WORKPLANBOEING SANTA SUSANA FIELD LABORATORYVENTURA COUNTY, CALIFORNIA

PROPOSED SAMPLING LOCATIONSAREA I BURN PIT - SWMU4 . 8

SCALE : AS SHOWN FIGURE 9OCTOBER 2006

Pa s to :<BURN PIT (SWMU 4 .8) ANrAJ'(' iCAt `-7 ESIJI TS

p

'IO UNS IN SOI SAMPLES, APRi . . 200 5AIBP SWMI_! ; F WORK PLANBOEING FIELD LABORVENTURA SI4UFORNIA

P.-DR Y

.~'ola Ic~e,~1` ~~ E -rTFD-1 0°0.5 SF T! FD-2 0 0 .5 SB_TTFD-3 0-0.5 4 0 C.5 SE' f1FD ' _ SB TT ,.;v1 04/14/05 0 .". M 4 /05 04/14/05 C5 ^ ^/05, a.

0411 r°rimc d

' -. :-, ~..

9290Primccv8290

Pr ;mart'$%oG

iGi%

0c,tVi

8_0 :1Prlm~ ,8

Div1/. L IVI7:. 0.11111%';. ~)17p, S i ,3t'

3 Hpr D 9180 t 67800 903 ,8-HpUDF 901

'569 B 4900 00 10 14 Ja',8,9-HpC©I . ' 0 48.1 B 4 34.4 E 3 . .1 J

1 0 U,8-HxCDD 3500 135 1030 68.3 2 .3 . :.

2,P J-DF 735 22.56 20' r, 18 4 B 40„ 7280 207 2420.

180. U

852 277 .5 ? .B 240 ..' 19 .3 J,B l9I D a ;nr 1690 119 052.2 5.0' 3

~ . .Fi`_~ 48 . ~ 28 .3 1

8 4.64 S B 0 .73 Ui 1080 27.6 B

6 .69293 ! 204 8

5 .861 .8 U

4 J3 2 596 ."I .85 2C 1

.0,47 i_I

U0 .35 U

7.06 1 . 4 J 1 .1 COiv, 2 5 C C819000' 95 00 453000 65200 1100.

160029100 E 2 130 0 14700 -`, 903 B 42 3

7« HpCDD 258000 17300 iS' 120000 8850 B 280 41 0Tot ;?! HpCDF 505008 2630 00 21500 0. 1280E 65Total E IxCDD 3990 (-; 1850 14800 934 36 t ~Total HxC !- 23000 8143 2, 7770 510 J . H' 32TotatucCUii= 4216 1 sir 1200 77, .5 C -

)ml = C':, 5970 d,O 198 J,E 1460J,8 117,10 i7 7013 340 3 4. :. 87 .7 8 .20 0 ;.7 U.

r ,, c' 1270 87 . 266 J 5

0!,5 : T'° 5257. . 290 .2' 2049 .9 '~ .

See last page of Table Al for notes and abbreviations .Haley & Aldrich, Inc .G :AProjects\264727TF\IM WP\IMWP_Finai\2006-1007--4 AI-SSFL7/14

October 2006

AREA. ;3URN €= )NMU 4 . 8) SUMMARY OF R7OF%„- SOIL SAMPLE ANALYSIS, 200 6htEF:! WORK r LAe11I

geT01 c

BOEiN - SF, 1 ->!,r A.ivfl? -'EL, !ABORATOI ?

~ I ~ S (t

T T E TTSS19S0 ', TTf3S20S 'i I RS22S0 SS23S01 , SCE TT'-,SS,j 5S0'l' TTLcs' % .,C TTLS19S01" : TLS20S0'i FTL :%50' ' T _S2c,;0 - 1?t" 02/21 /06 02/23/06 02/23 /06 2/2 /0C 02/2'/06 0 / x/0 .5

Primary PrimaE Primal`„ Prima ry i rv ; oFru rR . ~ ~~,

iaiyses 60105 3 'flD. 60'113 5C'i 06 60'.0!_ 61 016020 602, 6020 16 60 71 6020 6020 6020

7471A = <1 7t 1 , 7A71 A0 M r . 3 140D. 314 .0 MOD . 314 0 MOD . 4.^ MOD16 .

82700.

(Fa, c- of I - z` i or Goias and abbreviations .hairy c 1c c 1, i, ~r, .G :\PrvicctG\26A°\ i 'F\1 ,, WP\ iuol+r, F na€\2006-1002 -HAI-SSFC . M4xx .TA2 .® .xls

October 2006

AF 'BURN PIT (SWMI SI-1N MA L r)P E:C E!,1 COL _ SAMPLE ANALYSIS, 2006iris Nv/Iv+~(_ . 4.6F. VVC ;. ~

F ORN V

~+~, .n deg . .-

plf

TTSS26St ; .2IS . TTSS26SO. .'T! S26SO i ° 0- TTLS26S0 1

%/2 06, yr/ :' /06 02/24/0 6

e✓ r ._ Primary

TTSS29SOI TTSS3USC'`T LS29SC' > JSO' i CDS31S10

02/F~/C!0 ^?/~~/06 02/24/06

Primary -ri iary ri nary' P im~•.~ y

6016 (~ft97E602 (. 30207471A314 .0 IV? I L

See last page of Table .-'Il is .,)iFs nd abbreviations .Haiev A Aldrich `nc .

oec~s \2647~ - d i„~ WFOM\ ? Final\2006 - 1 0oy-iAl SSFL .M4 c.TA2 .®:x15

6010E 60 6

6020 6020 8270( 3111 : 61)7471 A 7Z _ ,l"314.0 MOD. 314.C w1OD .

October 2006

-'01Mi_ 1 4 .8' SUiv'MMMAiaY OP 9ECENT SOIL SAMPLE ANA! .°' SIS, 2006Page 3

VEI_U i, CX, ._, =r f .

UBS/i 330 : Jr," -I- 'I BS4' S62 a . 3.lT -Ti-S4 10 TTLS44S02'' may. 0" ; T I BS45S01 T-1 f=s

Sample ;r ; 05/25/06 05/25/06 05/25/06 05/25/06 05/25!0(: 'c 15 /0 €Sample. iv0 ., Primary Primary Primary rs i 'aF r . Primary

;alyses Per C 60108 6010B 60102 6010,x' 6C10 "rC Ci 602C 6020 6020 6020 6020 6u 0

' 14.0 MOD .7471A314 .0 MOD . MOD .

747 i/ . 7471, .

6 ; : 16'13 16'21 16'x' :'8270(0 SI'/ 8270(0 2CM 8270C SIM 8270 ; SIk 3200 !./!

-,n015 MOL 801 :j M 01), 8015 MOD . 8015 MOD . 801 ~/i00 .

See fay , :)aa oi /`.I I o Holes Rnc abbreviations .

l'rF\H,,!! VVP\ifvfiPIF_ Fiiiai\2006-1002-HAi-SSFL.M4xx .TAe .D .xlsOctober 2006

~~ .

;F r I BUR /SWivid.d - 6 SUNAMARY OP RECENT SOIL SAMPLE ANALYSIS, 2006Page 4

" ,3ANA. ~1F 'OALIFO R :

3O 1C F

,ample i 1eryEntE.r TTRS47SG TTBS48S01 -rTSS49S0~ --C' o~

SamnIN ~a . 5/2 /C0, 05/25/COc 05/25/0 0 05/25/06 ,005/2 x/06 05/26/05 05/26/06 05/ 2' 6/0Prii-c;arv rirn„', P mric,~~j y Sol ; ~ ; > nmary

"S eS F ~IIJ„ )?~ 601nr.~ 6C`OF 0 60'i 3 '60 602" 747'x 600 0,

L 0'-

7471A 1613 7„

1 5 i

Se^'ast r, cue c iHa~e« _?,. Aldncl ~, ~r~c .

1' iornoes c =.i}breviations .

ojEcf . 26.T ~\IM WP\ IMWF rinal\2006-1002-HAP SSFL. M4xx . TA2.D .xisOcio~, 200 ;

to w! C.,ilvhAj-'RY OF P SOIL SAMPLE ANALYSIS, 2006WVC ,

Div ! FQP, TORY

Page

Sams Idc ri ; '; .- TTBS57D C', TTBS5 1 .' C ; 9!'62S01 TTBS63S0', T i BS65S01 .56v'S0 TTBS(, , ` 00

Sample!') = '[- 10512610€ Ohl"610 05/2 /0 r 05/30/06 05/30/0 6c 6 6 ,05!? f06/13 /06 6!1'. /

oamni win Primary Split Primary rimer % dr Pri t

/-iisalyses ararmed 6010 60

6020 60

7P % 747', ;161 3

See last page of I ani ,i no _;i orevia ti ons .Haley & Alcrlc.!), `n r: .G :AProject \2r.~ . SNP\iMWP Final\2006-1002 -HAI-SSFL .M4xx .TA2 .D.xls

0 ; 0 60 10P _ o p 6c . c 60604.77 6020 6020 602C 60 .

, 74r'lA1613 1613 1b .. !? 1613

8260B 82600

October 2006

er )Pr' f + VUs111 ! . iil~~~/ ^F RECENT SOIL SAMPLE ANlk ", 1' . 20061 /- V\ s r

BOEINGVENTL i ' A (-.

amr'! c TB . T 680 -r ,DS68S02 TTBS69S0 ' T Tt1S70S01 TTSS70S07 'rTSS70S03 1

051 0/n,, C ,/.30/06, 05/30/06 ,Sample tas i ~ l5/30/; 05/30/06 05/30/06 05/3C/05 05/30/0' ,06/' .~l00. 0 6 3/00 n6 11 3106 06l'[ tSample Type. Primary mar'. ^ hi mary Primary Primary ~~.it+fePr'

alyses Perro ,,iec 60 10 60 6010'1 0 iC, 60105 6C 1Q? 606020 602 6020 ~~0?.C 6020 5C2 0 6C?0 ^07471,' l4 ~- , -I ~

7474rr,% 7i,1613 1111 1613

8s26C 82605 200

os~ gage of t err- 7otes and abbreviations .Hulev & Aldrich ,G•\i- ojects\26?PV- =\li", VVPV'MWP Final\2006-10024.AI-SSFh .!VIi,, .,, .1A2 .D .xls

October 200

TABAREA - '~n 1ill . .81 SUMMARY OF RECENT SOIL SAMPLE ANALYSIS, 2006AIBP Sw(vi'_ wC. ~l r id'DOEIN ? SAI, . C A SORATORYv/PlTL~ft r ~~iil _

6 ; d der R: 74S01 TTSS; a ;

Sample Date 05//O C 05/31/0 6

Sample Type +Prima ~~ F ~E yid Split

Analyses Pe ` s .f613 10'1 161 3

Se ; last page ref ~. or notes and abbreviations .EI~f Aldrich-'uri c

i-,ts\26, % \ -OH AMP\IMWP Final\2006-1002• ; IAF ,,Fi_,M4xx .TA2 . D .xls

C, i F ~ T'S0 TTBS77SO2

0513 '1/0( 05/311 10c 0513'1/0.

-Primary, Primany nma, v

"i 71 I6'0 1613

Page ,

7T9778S01

05/31/06

October 2006

-VVMU 4 .8) SL " NAI cF .; OF RECENT SOIL SAJViF'LE ANA LYSi .:: . 2006

L_ .. i ; .?r F2AT0R

j ° ldeni-

Sample Date !5/31/0 05/31/0E 06/02/06 061x2/0 6

Sample Ty i,~. Prirna r , `'rim ary F rin ; ~

26C' 8260

ee last page c oteE and abbreviations .aley A~irkTh:AProjects \26-'7 \ \!iv Vvf-UMWP Final\2006-1002 -HAI-SSFL .M4xx.TA2 .D .xIs

October 2006

_ VIAT ION S

sample .

Ac" 're samci

.,* pir

- located leachate sample for perchorate analysis .

-nethod 6010B for aluminum and bore,- .

iethod 602 `~ 'meta l

-+ethod 7/ ant .nerc .- n

0 MOD. = E ,r 1 roc " 4,u MOD modified for perchiorate .

E`" tl o 1613 for dioxins

8270 SIM ehod 8270C SIM for polycyclic aromatic hydrocarbons ( PAHs) .

8015 MOD. me hod 8015 MOD modified for total petroleum hydrocarbons (TPHs ; .

8260B - cF " ne?hod 82608 for volatile organic compounds (VOCs) .

Nriey fi ^ddrich . Inc .

C ~rol ta~'64 =\In WP\IIMWP Final\2006-1002-HA(-SSFL .M4xx.TA2.D .xisOctober 2006

WMU 4 .5 A . : ' c ' :.' RESIT S FOR RECENT SOIL SAMPLING•MFLES , 200-:

;,v'/i\ f . . ~' ' WORK FLAR[)!_ /" SUSAN/A. FIE L7 '_ \HOR.p ORY"„ ., p 1I TYY, CAL" C . C ,

Samo identifier TTBS15S01 TTBS17S01 TTBS19S01 TTBS22S01 TTBS23S01 TTBS24 ,0' t T TTSample Date 02/21 /06 02/23/06 02/23/06" 02/25/06 02/23/06 6 / n0,SampleType Primary Prima ry Prim-n! Primary ap/Laboratory DMA DMA 3kil DMA

Sao ,

vV-

Aluminum /' 0000 ~.r

17006

7Iron 'P

Antimoo 17F,ArsenicBariun 7£,

Bervlli im.ac ; .• 0.

/" 3 Sur

LearMolybdenumNickel eia/I; 2Selenium 1655Silver L ._ ; .7 5

jailiun . .40

5000 250°0 100!? 5000 I coou :2000i<< 1 6_` 9.5 4.8 U J

0 .040 1 0. 36 UJ 0.._ 36 U J C . :: : 0.37 UJ C .19 UJ

26C' 0 8 6 710.6G 0.~ O

160 19 J8.5 16

69 ar l~ °,43 4.6 1 24 13 41 8 52. 29 0 .47 2 3.6 1.5 0.4 0.35

62 660 56 49 190 .31 J JJ 9

.1 6.9

'1 .2_9j 1 . 3 UJ 1 - - i 1 .3 U 0 .21 UCr 1 0.07 ? 0, 7 0.13 n r; 3 , 10 : ; 7 0,0271 0 .3~.. 0.2 0.13 0.18 0. ' C 0.27

r30 27 60 24 27 27 22130 46 66 160 57

0.064 4.080 0'.1 u.' 0.05 . 0.0053 I 606 'J .I 0 30

See last page ofTF,oie ;~., I oi notes and abbreviations .Haley & Aldrich, In !G :AProjects\26472\i I-F\C vFffl FMWP Final\2006-1002-HAI-SSFL.3V/[ti x 4\ ." .7 .xls

October 2006

r '0 rni4 4 .81' ~, .. Y -ICAL RESULTSA'!6 'LES, 20C.

FOR RECE~i- SOIL SAMPI_ryF .

AIE, SWIMBOEING

V /C!RK PLAIN_ . ~ MNA FIELD LASOFI4I ' -

VENTURA r ~',S_ " ORNIA

Sample EderSampl _' DES, -Sairnl~ •r/i~ :=

T-R.-?8SCf02/24 /C 6

D ivi e'e_

TTBS29SO02/24/06PrimaryDMA

TTBS305: C

0212410- GFri ~,ry

TTSS33S0 '02/24/06Primary

_°54006 /" 2/0 C= rlr .~.r~,

F3S43S02 '25/,25/0 6

rimarv

T I'~a~.SO TB "

_x 20000 10000 15000 16000 100001300

613000 `C00 C0004 .°'t . 6 .5 UJ 6.6UJ 2.3 J .mg/i

18000 16000 9 :v _7 ~Cil '~,~/ mg/key 0.1 U . .! 0 .092 U f OOH . i. ;, r 0 .092 UJ Cr . ' 0

3 .' 3 .0' 5 . 6cr .~

f 65

o ~F 0.68 J . 0,0 .0e. 0 .099 (}," C1F 5 1:3 1

mg/E 4 .mg / k^ 5 . 8 .5 9,2 E, 7 .c 5 . b 8mg/k(! 34 4 .7 5.8 5 .5 2 E C 4 .8

.5Ivloivu a/I< 0,45 0 .44 O E 0 44 40' J0 0 3. . . . 7 J 2 7P c' :s n/ : /9 7 .6 i0 10 10 7 .5

.7 2

=; .552 0.21 U 0 .721, v 2~ .' 0 .76 U 0.35 J 0 .22 J 0.231.

022 U0 .03E O .0''.5 0 .05 .1 0 .055 0,05 J 0 .04 J 0.0 ~2 i 0 .08 .i0 O . 2 C O .i 0.2E 0 . 2 0 .29 J 0 .21 0

1i Ems ., _ C~/~:.._ 26 28 25 2

3 45 36 3 7 -her mg /kg 0.09 X0.0078 0 .0033 0 .0055 0 0 0,0 0 0032 U, _ . . 7 . 0 13 0 .329

See Ias- pane of Table AM for notes and abbreviations .H F, !ev `, o,r-i-, I"C,G :\Pro"cts\26='1i ' .t ~ \IM WP\I MWP Final\2006-1002-HAI-SSFL . M4xx.TA3 .D .xis

October 2006

F . Ur/n ; l! 4 .3 ;8 ti r 1= i" S FOR REGF 3 -AIVIPL~Ir -SAMPLES, 200'..AL. RFi WORK PLASOE S°JSANA FIELD L ABOR ,-` T 0 ..`, ;VE :7, , , . . CALIFORNIA

Ss rn TTBS44S03* TTBS45S01 * TTSS45S02 TTBS45SO3 * TTBS46SO1* TTSS4 7;3!D ;49Sr 05/25/06 05/25/06 05/25/06 05/25/06 05/25/06 05/25/06tai o ,a Pnmar;/ Pr "f'ar' Primary Primary Pruner : Primar

y I_d'_ n U y'Dlv/, Diyd/ . DM/ . DMA : IVIt', DMAsp,

Leve ,

ng/kg 20000 13000 13000 13000 9300 --- 9000 120Emg/kg 9. 1.7J 19 13 1C 1.6 35Jmg/kg 15000 1800C 17000 13000 1 553 ;_ UGC'mg/kg 0.09 J 0. 0.'t5 JFu' rng /kr 2.C 3. 6 C, .

42 60 62/. 0 0.48

io 05.5 0 .39J 0 0 . .- . 60;

Un r !' 9.°.. 56 i , qe 17

4 7.4 6.3z~ 7. 9 .3

. 0. 6 5. 5c,/.c 17 ? 3.54 5. 4.6 6.1 .1 X3.48 . 0 .26 m 0.56 ! 1 9

mg/: 2f, C 14 9 .2 4.5 10 1.5 8.9 17ma), 3.655 0 . 112 1.1 0 .3-7 ,.i 0.38 -1 0.22 0.31 . 0.21 2 0.25 J 026 Jv;. 0.79 0 .010 0 i 0.041' 0.0 0.05 0 . 021 i.! 0 .053 J t', J91 J3.46 01.2'! _f 0.22 0. L 02 0.26Jr.~a 6 115 2.

2C 22mg/. s 9 57 3 5 25 aRmg /kg 0.028 G

1: t00-0082 J OA072 O .u'I S

5c las page of T:?.nle Alit for notes and abbreviations .

L'si'roieets\26-i7 \T\lfvi WP\ IMWP FInSI\2006-1002-HAI-SSFL .M4xx .TA3.D.xisOctober 2006

~1U Ivi+. - - ~i

'iv '..i0PL= , 209 2t_ J

,AL RESULTS =0P RECL \: 3AMPLIIt'C`,.

33 . WOR , a DL1 1iOE `'--- 3AI i S_ $ANA FIELD " BORATOR`:'

VENTURA COUNTY, CALIFORf+i !

identifie

Levelsaminum c/ 20000

7

.1 ~r

40Mc! ; 1 .

acmiu,

chlomru .mCobalt

Copper

mg/i. ,mgl 6mg/k .Inc; .

Lead 3 /Molybdenu mNickel

me/' : /n,Gl/ i ; : 5

Seler~~ . mg/i„ 0 .65 5mg/kp. J . / 0

i .!i mg/k. 0 .46I q ..

.crVi~I (:1 0.03 0_. g . _._ .07 .! J 12_ j 0.012 ,1

lae page of Table Al II for notes and abbreviations,Haic-y & Aldrich, Inc .G :3Frojects\26472\TTF\lM WP\IMWP Final\2006-1002-HAI-SSFL . M4xx .TA3 .D .xis

TTBS49S01* TTBS52SO1* TTBS53SO1* TTPS54S01* TTBSS' C - ITBS57D01* TTBS! 005/25/06 0512610E 05/26/06 05/26/06 05/26/06 05/26/06 05/2et .Spllt Primary Pri+ er! Priri.n y '"'rlrr ..i y Cup hl .DMA DMA DM3. Dill LAM A

116(t0< r 1000 14000 25000 17000 19000 700 :.19.5 15 10 0 .

17000 19000 39000 24000 20001 . 1 L 0.19 J 0.42 J 0 .0 ;3 U 32 ~.?

3 .6 56f 58 7F0 0.49 3.5-. 0.44 ~.5 5 6

0.24 J 0.13 J (r. ~:,, 706 J20 /3 47 2_i 2'c'4.9 6 6 17 1 SaJ 10.`11 25 1- 9.3 9.7 25'i00

10 .. 12 28 5.C 5.4 5.''1 .3'j 0.83 J 3.4 0.6 0.52 J C. zi..a 0.11 U21.6 18 69 56 23 2r 3zi 170.54 U 0.22 U 0.22 0 . . .?, +. 0.22 I ; 0.22 I 0. U 0.520 .54 U 0.78 1 2.2 0.065 J 0 .06-4 6 0 .57 U 0.07 ..?1 .1 L! 0.24 J 0.15 0•' U 0.21 1.1 U 1 932. 23 28 6C 42 50.1 _

t90 46 9336

643

Page 4 of 7

October 2006

A ii= 1,V viJ '._ ',LYTIO SIJLTS FOR REOE`°!-" SOIL SAMPL_II'*iC -M _Al l✓ `H1V \ \/0)R, ~

BUFQ k ~\r A FIEL_' ; ".RUTAT~1~'VENTU':,!,

Sample Lei

~amirl /I_ ; :

Lar'r~6>

acKfY :"~}~l9JC

Levels

TTBS63S01 * TTBS65S01* TTRS66RC I TTBS67S01 * TT"-I67 .>( 3S68S01' 7--05/30/0 605/30 /0F 05 /30/06 05/2:0/06 05 /30/06 05/1-0/06 35/30/06 0PramE Primary Prin,crv / Primar, : Ir. -'r- aryDIVr.. DMA L. h ail/ -. JrVi'~

. ,mg

/kg.. 20000 1800c,

Lc- mg/kg 18

mg/kg v' 2600Emp/k, 0 0.

-- - 9/k_ 4 .820 .52

ads . 0.21'

rig/kg 9.6mg/kg 0.86 Jmg/kg -.; 33mg/kc 135;; 0.2 Lmg/ .: - 3 0.

/k 5

9800 14000 -15000-- _15060 , 30006.7 8.r- 11 8.8 .437000 20002 21000 20000 20000a() n 0.X33 .1 C .0

38 77

0.4 0.41

0 .045 J 0.2 r - 0.

16 305.3 7. .- 35.6

3 .90.33 J

1 20 .21 U0 .024 ,9

26 202u 14 1., 9 16 92. 1.6 0.86 J 1 .5 0 .53 J5C 35 43 22 31 213 . 2', 0.221 0.22 U 0.21U 0.23 U0 .28 0.28 J 0.32 J 0. 1. .J 0.054

it, J 0 .19 J 0 .1 - J 0 . ` s ! 0 .206 32 32 3 3"38 71 7= 71-0 .0032 0 .09 0 .0 9

See last page o, -r-ble Aili for notes and abbreviations .Haley & Afdrir I, it

G :AProjecis\2Eui-. ?\ i if\livi WP\IMWP Final\2006-1002-HAI-SSFLM4xx,TA3 .D .xis

of 7

ctobe : 2(CC ;.''

(SWIM .; ' "L MCAL RESULTS FOR RE°. ENT SOIL SAMP Lii2.!Vdr~t, o

i E- A LS Iift -, " w r ~.

Ipa el , SWMI. r30E

TTt3S7OS01 * TT 3S70 '.;C2 TTBS70S03 * TTSS71SO i T;S80SO I05/30/06 05/30/022 05/30/06 05/30/06 05/21/06

j :z Primary Primary PrimaryDMA DfviI..

SR S, I

I It I 2001" 17000 18000 25000 15000 --Boron 1A 12 1 6Iron 27;+00 27000 39COC 2 ~J ? C

0 .i3< 0 .072 J 0 . 2 .6 . 3

Cl0 ., . ._ 0. 11 9 J

2 .̂ 2 268 . 12 '. 2. 81[29 14 24 31Leac:' rnc!/i ; 34 11 1 17 20

Molybdenum rro /i< 5.3 0.49 J 0 . 6 0.88 0.98 J 1 . 729 25 2/., 23 27 7. 9Seleniur : /' 0.655 0 .20 0 .35 0 .58 ,' U.?'_' 0.29 J0 .79 0 .09 2 . . 0 .092 J 0 .20 v i

C .2 i 0 .28J 0.8 0. :.1 44 5 2 3 206,

59 8 3 8C 0 .03 0.02 0.1 L 819 ,

c last page of T AM for notes and abbreviation: .I ,,, Aldrich, in .

0:\Projects\26472\" I -I"ice\IM WP\IMWP Finai \2006-1002-HAl-SSFL .M4xx . TA3 .D.xisOctober 2006

AI''' . ABBREVIA -I,O'\I

Primary

f I ine, California .

mg/ :~ = ~'ii per kilogram .

k,

available ; no SRAM promulgated .

stirnated value (compound was detecte d in method blank) .

- !Mated vatuC:.

N .. z etected .

Esti~ gated not C6LCCL .

rrs,i . s a invalidated for this sampi n

Sample ;,ot analyzed for particular constituent .

Standardized Risk Assessment Methodology ( MWH, 2005) .

TTBS49S0'i _ ? tvzed for pH using EPA method 9045C at 7 .14 pH units on 05/26/06 .

_ alyzed by EPA method 7471A .noion, and iron were analyzed by EPA method 60 OF .

"ice metals were analyzed by EPA method 6020 for prima : ; samples, any b', ~ != A method 6010B fot sully asmoles .yu . greater than SRAM background levels plotted on Figure E, .

G :\Proiects \ 26=,7 2 '1\7,7 IM WP\IMWP-Final\2006-1002-HAI-SSFL .M4xx.TA3 .D .xis

Pdc c

cto3er 2006

Page 1 of 1

o} i

I

-o r5Su

LSt7SC'i . ;.aty 02/23/06 3 i d. .0 fl3 . DMATTLS19S01 Prins ary 02/23/06 31 Z . 0 flOD . D ITTLS20SO Primary 02 /23/06 314.0 MOD DMA.TTLS,22` 1-i t , s ai 02/2 .s/0' 3 :E4 .G vIOL . Df0r :TTLS233 6~by a2/G3r« , .0 lvi0G, ufvi ;`,TTLS24so ;ary 02/23/C(- '360 3 I4 .0 MOD . DMATTLS2SSOi i k iruary 02 /23/06 ?, .i 314.0 MOD . DMATTLS2US0'i E i na y U2123 1 0C 0 .05 1 314.0 MOD . DMA-I-Q _ S-1 S01 3/? .PD VIOD< DiIA •=F € LS28S01 Fd 3E ; 02/2/ /06 3 4 .0 MOD .

.

DMALS29S01 3k S 02/24/06 314 .0 MOD . DM1 '

€ ftS3050 1-i E-343501 *

ra yI `rimaiy

02/24/0605/25/06 If

1~ .0MOD .4 1314 .0 MOD .

DMADMA

TLS43S02* Prirroary 05 /25/06 314 .0 MOD DMATTLS44SO1* a z~ :v 05/25/06 3 1 4€ .0 MOD . DMATTLS44SO2* 05/25/06 314 .0NMOD . DM ATTLS44S03* f ~irrso ;; 05/25/06 314.0 MOD DM A

NOTES AND ° .P RF"EV"IP i Is-)NJ = Estimated vaiue .U Not detected .ug 11 = micrograms per Titer .314 .0 MOD . E;'. . csethc:l Zvi 3e6® E,.. o v ' pert€iio -: .Perchlorate analyses were peG :` ;rmeu o,', cI leachate samples :* = Data is unvalidated for this arsipi :

H a . ,.

G .̀\'- oj(Oct jti

HDMSe00037436

-\i 2 F ~V ~ti~L 1 . 9T9 FOR RECENT S

- SAMPLES, 200 6A,3~7 ; /V .rvi . F1 WORK PLANBOEIIe .8/ A V.a FIELD LABORAVENTUF,; CA'_1FORNIA

OIL SAlinP ' iJJ C

TORY

iT , , TTBS1'7501 TT S 0 -20S 1 TTBS24SOI 7 r9F25S0" TTBS26S6 301

02123/W_ 02/23/06 i 2/ /7F 02/23/06 1Prirnnar :' .' rn, r'% Primary Primary

1613 161 3C u'i Div!/r'' 33 DMA

_I U

DD 895 55 . 3I ;DF 10 8.29 CT 0 3091j, OF 1 .053

'.05,

.01 . .

234 , . ";L7C~' 10 0.73J' 3 .14 C .13 ..i 0 .76 07 ~1,2,34 8.i- = 3 .0 26.2 06 !0 2 8E~

. . . 1y, ~? 6 _~ 37 7 2.38 6 .23 0 ~5, i,l 2 .9? .. 0 . 7 U3 C ;25 . 09 21 .8 0 .05 u 0,03 s!

25 . ; 7 i-7 4 .89 0 .13 1. 0 .1 61 ,

er 0 '90 .644 J 3 .29 0 .08 U 0 . 05 U n 70 1 J

1 . 0 .65 J 7 0 .07 13 0 .58 0 .08 U 4.Oo 1 .28 J/ ,! 11 20 . 2 .95 9 .84 0 .11 U .7~. a .1 U 5 . 3 7 7 3 0 .43 J1_ J 25' .3 0 .06 2 .03 0 .031 , 33 13 .6'i 0 09 1

0 . 0 .7 0 .0 :' 0 .13 U'J 095 .42 0,991. 2.17 x .09 ' 0

6907 5(1{ 148 224, 360 5 - 1t4a~.9~ E . 5rJ- 11 .9 3 .25 21 7ate 1 ? 72Q I I 1 tl e ; 6

.0 .6 81 . 3 0 .2,3 1910 ,cueT

9"

165 0.15 L, 24 .3 0 .09 t 315 7 ;otal H) 3,

T t l H C38 26 . .5 11'17 0.1,: 0 .17 E' 19 a7 . 8o a x _ i

tT l P2 / 21 .5 3: 0 .03 1' 2 6, .' 0 .04 U 84 . 32 . 4o a e DD

T7 .29 C r~ O C 0.08 L' 7.79

.otal PeL )F 3 7 32 . . 22 0 09 C~ 7 9Total 110 ~. .` 0.0' 5 .3

.0 .0H> LTotal i ` 4480,0 9

60.03 GJ .3L

C-PP- s' of is /-`.V for notes anc abbreviationsNaey is !"ldrich, !n ,

G :\Proiects\26" -\1M WP\IMWF_Final\2006-1002 -HAI-SSFL .M4xx .-P,5 .G .VIsOctober 2006

ARE, I '- _ I!- ;I"f HT (SWM (ANALY` IC.; : 0SU TC 'O 7L .0 ENT SOIL SA.(\, iF I\i(=DIOXINS !''AIBP SWI'vii I 1 !O i L%\7J.BOEING 0? I 3A5ii- F IELD LABORATORY

Page 2 ,

;fA.I IFORNI A

anlole ldentttSV3S01 TTBS43SO2* TTBS,'4S01 * TTBS44SO , TTBS44SO3* TTBS49SO 'i-' T-1 7~ S Z,. 930'. T-i ~S52 ; Nr(,+jle Ba-i : 05/25/0 (. 05/25/06

Primary05/25/06

Prima-v,

05/25/ 06PrimEErv

05/25/06Primary

06/20/06 `0 0510° ' ??6/06'

164 1613 1613 160 1613DIVM/ DMA DMA D?1i A D MI an "

)Ol6-1 O

0 .~ 5 .08 16'!0.00: 1 .23 0 .08 _ 14 . 60 .07 0 .13 L' 0 .06

lo ,m 0,0 -, ..I 0 .08 0,04 !..r 90.0~ ..- r, 0 . 50.09 0 .07 0 .5 101 . .00.00 a3 0.42

_.

0M, 0 .0? '_' 0 .58 0 .0 52 :

...0 .09 0 .05 0 .17 1 ?0 1. ( ! . 0 . 10 .09 °._ 0 .06 0 .13 0 .04 !_! 3 .06 ( 0 .56 6 /20 .0_ M4, !. .i 0 .08 0 .03 0 .05 0? 0 .26 0 U

.7?e0.07 t_ 0 .0 0 .68 0 .03 'U 0.06 .! 0 .84 0 .5U

.

0 .6 .0.08 l 1 .01 0 .0 0 .06 `J 0 .78 0 .9St .0.05 U 0 .05 !0 0.05 I_, 0 .16U 0 .! i

IC .2 : 0 .29 ' 0 .2U 0 .73 0 .30 3%G63 0 . 9 1 .35 1890 1400 3641 -i

X04 :- 1 .4 0'.10 0 .29 41 .4 40.

0 9 18 .8 0 .37 0 .52 497 290 1230c) LE;! 7DF 0 .2 0 .~ ..'.G 2 .8 0 .07 0 0 .11 59 .6 77 1 30 .0 i_I 4 .08 0 .05 I.U 0 .09 U 32 12),

Ote 0.08 0 .05 I_- 9 .39 0.03!1 0 .07 U 20.0 .0E 1 .62 0.0'-1 0.060 3.55 0 2? .t'

0 .26 0 .1)6 14 .4 0.0° 0 .17 10 .6 46 .., =iI .. 90 . l5 U 0 .25 0 .05 U 0 .05 U 0 .26- 0=i 6 .2 ,

0 v 4 .780 .0 0 .0°

z : (!agc o, f -\i Fo :-totes and abbreviation :-, .F -iey Aldric h

C .\Projects126 r 9\ FUivt WP\IMWP_ Final\2006- 1002-HAI-SSFL .M4xx .TA5 .©.;ciSOctober ,200j,

A P

SIC. _ SAMPLES, 200 0IFt ;= yli N i ;., ?Fl WORK PLAti

, r'' 31JSANA FIELD LASOSO/ T ;., , CALIFORNIA

TT8q5_ TTSS5457' T T 8~57D01 `r8S57S0 T SS57S01* TTRS62SC '105126/ 05/26/06 05/2E/0€ /5/26/00 05/26 /06 00030/00, Ooi ui

San,iole TyAnalysis IVeir,od

Primar, /X 6'0

Prim!;1613

Split1613

Primar,, ,

_a,bora to ry iDivii D \.r!`, DMA C>lM11 C?M.11 DiV P:omoound ( P9/g) '

6 <,8 HpCC 1130 5) F . 7 21 .8 Y, 3 . 6sic 2.070 0 .16 0 0.830 0 8

7 Q, 0 . : 0 . 250 .20

0 .,? '0 .35

0.77 U0

..4 U

OF0 0 ,

i 331 0.6 "0.18 5 . .. . ~ ~ 9 0 .0, .0 .47 0C '

~ , I 2 0 `; 0 .1 U 0.09 U 3 .57 i. 0 .06 U r .̀ 0 0 718 .65 _ 0 .~ 0 .17 0 .16 0 .9 0 .06 U

. _0 04

9,19 O . 0 .18 0 .21 0.5 U 0 .05 U.

0 .05 Ui5 0 . 0 .19 0 .27 0 .51 U 0 08 U 0 03 U19 .9 ? .-? 0 .35 0 .36 0.51 U

.G . i2

_ .0 .04 Ui .5 ;_ 0 .08 U 0 .09 0 .1 U 0 .45 U 004 L! 0 .05 U

35 ,i 03 4 0.72 0 .77 0 .34 U 0 .1 7I"i 2.20 695 255 357 130 50.9 67 C

6 .36 8.93 2 .7 U 1.35. 799 OHS240"

I

p0 ,

2Z69 . 47 .5

95 .5 2F G_

5 .71 8 . P, 7

`. .

0 .66 0R,

.1 ,25

.0 .08

;6C€ 2 .

0 .453 .1€ 0 . 0 .'_0 .89 1 .06 0 . 0 .1 6

L;s na ;,c ;6= i~r for notes and abbreviation:Haley & Aidri6,, Ir cG :\Projects\26:',727/ TOM WP\IMWP Final\2006-1002- HAI-SSFL. M4xx.TA5 .D .xls October 2006

I8L1-.

°

PC(,,--

\i ! i F0' RECENT SOIL SAMF_ ,I rDIOXINS 'vIPL= 2006AIBP SVVi\, vSOEINi /3'3 ' LABOR C °\IENIT10- A :-. CALIFORNi'"

ee ❑ := TTBS66S01* TTSE67F0 TTBS67DO1* TTSE6330 1 ' TTBS68SO2* TTBS69S01 TTSS7JSC05/30/0 05/30/00. 05/30/06 05/30/00. 05/30/06 05/30i0 b 05/30/0(:`Priinafy Dup Primary Trims-r, rir iar;

n~r2' Vie 1612 c _ 161 3DMA DMi4,

1 6"~rvir

r ; F

i

I5. 0

3 36 .,- 20.- 78

? . 3 .03 r. 0 .97 C 22.32 0, ®

0 5 .28 2 37 1 . 608 d ':9 2, - 0 .7 0 . i

,j 0 4 .37 1 . . : 0 .47ao 5 .93 0 .58.

0.! 0 .;5 0 .15 u 0-°iii. .65 U 1 .311 0 .69 U 0 .56 U 0 .26.

0.2 U 0.11 U2 .58 2 .52` 0 .08 1 .04 32 4 .G I 0.254 0 7,8-I-~, .. 4.49 1 .33 6 .47 0 .2E 0 . 4c 4 .6 ~. .76 1 . /2 1 .68 0.65 0 43 0 . 60 .2E C .25 0 . :3 0 .13!J 0 .091- 0 .0S L' 0,0-° U3, 5 3 .46

116Z n,57 0.6,_,

2C 1 ; . 1736 J CF I

52 .x; 17 54.8 24,4- 5 .0' 0 . 93400 400 364 38, 54 . 3 1

8 58.0. . .

93 . : 6= . 79 .3 3 U, 7 :J

100 50 '=1 54 26 C ., 5 .'.1 :; .i' 18 .4 6.26 2.3 5

Lc l p 'i 50.7 6 .3 36 .68 2 .01 1 .28 3 U .VC)

5 m . 50 .5 16 .7 71 6 .762 ~ .is f .64 8 .6 3 .98 8 0 .55

See lase ua o, "V for notes and abbreviations .Haley & Aldrich, Ins. .G:\Project, `06-' r.\fivi WP\IMWP Final\2006-1002-HAI-SSFL .M4xx .TA5 .D.xls October 2006

AF` P F (S\l0n0:ESULTS f 1 !5 'flI' ; .91AMFLIN G

SOIL SAMPLES, 9- 009Al'. 4' .. 4 .8 RFI WORK F La, :IBOFI ` SAr'TA SUSANA FIE3 !. -'BQRATORYVEiNmTI • ; U :TV, CALIFORNI ;

Sd r ~ ;, . .Samp iSa'~

i1S1 \iic,

TTf3S71 SO105/30/0 6

I✓ ri =,! . F iiary5

D JIV / E,

C J ; . ..C.0 0. .. ..

Li 0 '0L0 0 ,

100z~0.28

90.0 ' 0.46iE . 10.0•.` 0.,.

U .Cfd

r l

E3 .Oti ~

9 .1=0 .00

- 5.

9

S, Iasi page of !'abl

Haley & Aldrich, Inc .

qV for notes and abbreviation :- .

1

TTBS73S0 1 ' TTBS74S01 * TT7;7QTD 01105/31 /06 05/31/00

15'4 2'2NA

1159

' . 0.280

3,07 U C 233 .08 0, 20 0s0.12 0. 0.830.14 L' 0. l2 0.130.05 ' . G.% 0.080.07 U 0 .i 0 .1 U0 .07 G, 0.420.07 L' 0.50 0.55

0.05 ._; 0.11 L0 .22. 0. '9 0.346 .20 2_.!44 19323.0 4 2C.81 .27 6 . '1 .1'ir0.21 7.80.49 5.890.05 U ^.1 2.020.11 4.0 6.450.04 U 0.r t: 0.6A0.46 3. 80 .07 0 .93

G :\Projects\26472 \TTF\IM WP\IMWP Final\2006-1002-HAI-SSFL . M4xx ,TA5.D.xls

TTB ;7 SC

05/3 ., /0~Primacy

DMA

0 .240 .50p 0 .

^7 i

3 6

0 .59)

0 .050 .04 U0.071.10 .050 .04 i_'0 .191,9 8

.. .nC" . 1

0 .4:

0 .48

C' .'! L004

2 '.

04 _

Pac r,,i-

0 .11 U0 . IT ~'n .

0 .3

0 .7 :0 .11

0 .413858 .';

I ;.

5

4

7

October 2006

` dr _'. Nivl[ 7 . 1I77

SAMPLING

3/- N3A F1 EL'--) Ef, 1 R,( .ALIFOF !

arr'~ _

n=_iVS,-: iv/ie33,o d

6, .,8-BHpCDD9C .3DF

T.)F

0! l ;i/'r; i ;

~ hU ivi'-

TTBS77SO2 *05/31/06Priman i16 "D[ IIP

TTRS7RSO1 *05/31/06

1 0~i .A111"i

TTBS79S 005/3'i/f0'Primary16

81 2

OMI

T?'3c7oc0 •

05/-' ' 3

P o rn or

Ark Art ,.

143L 2 593 30001 15993 (" ..t `i R1^ ..

C, . c 2 .236

1C 5 .9'i2 .l E 1 .44

63.=. 1 .6C ?=6 r 4 . 4% . . . , _! 0 .12 U 0 .42 s .9L 0 .5 1

0 .20 3 .27 16 .3 0 .6 U0.00 0.62 2~. 0 .66 u

g 0

. C 2 .97 1 .840.', 1 .74 2. ? 1 .84

1 . 0 .29 0 . :93 0 .13 U(1 7 0.72 1 .1 948800 66~ 6160 23503 1500101 : 100 30 40 . 88540 16- 1750 50 472,58G 1~ 170 96C 62 . 9

683 1f, . 141 6N. 43 . 5339 62 .3 28, 31 . 941,3 r 15 .1 3 .9 5

34 .3 60 27 . 62 .27 ~ .` 0 .0 8

18 .7 19 . 716 .85 78 .29 4 .8 '

See 'c dole rio aobrey'iation s

o9ects\ .G i2`, 11NI WP\IMWP Final\2006-1002 1-IAI-SSFL .M4xx .TA5.D .xisOctober 2006

DMA Del : /jai 2"! 4 cal of Irvine, California .

Cornpc! rrra:~~~ sample .

I` air cafe sample .

_ Sc .W: sample,

p9ia _ picogram /grE,,

J Estimated vai c .

_ Not detecte6 .

J I = Estimated non detect.

= Data is unvalirsated for this sample .

= May 200 =ar" ;les were reported in ng/kg, which are equivalent to p c

Haley & Aldrich, inc .

G :\Projects\26472\--1 F\Ifvi V1'P\IMWP Final\2006-1002-HAC-SSFL .M4xx.TA5 .D .xls October 2006

TABL'-AREA I BL2r\l "-f (SVvI\rU 4 .8) ANALYTICAL RESULTS FOR RECENT SOIL SAMPLINGPOLYCYCLIC /iA ~(_; `'YDROCARBONS IN Soil_. SAviPL0 , 200iAIBP SWMU 4 . 9 PLANBOEING SANS `I 4. 9 . MELD LABORATORYVENTURA -IPORNIA

SampU lrlentlfier TTB 2= 1C TTBS25SOSample , eats 02/23/0 ?

E!l :ter! n" Prima ;"!8 .. .27O(` .SiiV~

Benzo (a)I?Yre'Benzo ( b)f(uor ~r, D,-;Benzo (g,h,l)p€ -'-

Ienzo (+c)r"!c o

.̂! n 3d)pyrene

C

00==.- •

.02 i U 0.02 ._C .J_-A 2.021 U 0.0 .2

0.02 10 .021 I. 0.0 ~a0 .02 0 . 0?_2I

. 2 '._ 0 .02' 0 .0042 lJ

.022 0 .0211 C; &.0C ! J0.022 0 0.021 u 0.022 IJ'7.022U 0.021 U 0.022 U

C._ 0.021 U 0.022 UC .C22 Lk 0 .021 UJ 0 .022 UJ0 13023 0.021 U 0. 0025 J0 .022 0.021 U 0 .022 i_

0.022 JJ 0 .021 U. . 0.022 UJ0.022 0 .021 1-; 0.022 I.,.'O .C . .=: 0.0 _ . . i 0.022I._0 .022 0 .0043 .. 0.022 U

Sea +ast page of e. A\/i for notes and abbreviations .Haiev & Aldrich, In'- . .G:\Project,\26'72\! ; P\IM WP\IMWP FinaI\2006-1002-HAI-SSFL . 4xx .TA6.D .xls

TTBS435C TTBS43SU2. B;05/^_ .5 0C 05i'?5.0C-

82(0 .:an\ ,i ;n ~ ivDMA . -.

0 .022 U O2 P Ci

0.022 0 C . ., -C0 .02 %0.02 0 . 0V . 0

.2? 0 . . . 0' -0.0,

0 . ;)" ^0.0 0.022 U 0 .022 0 '

0 .022 U 0,022 U0 .0 22 U 0 .022 U 0.022 U0.022 0 .022 U 0.022 U0.022 U 0.022 U 0 .0221 10.00®4 ,I 0 .022 U n n 20 .022 U 0.022 10.022 U 0 .022 !J0 .022 U 0 .022 0 .?0 .022 U 0 .022 _ 0 20 .0038 J 0 .022 l'

I

October 2006

A"EFP UL'( . G' .RATI HYDROCARRON~ !r` : Oil . SAMPLES, 2006

F' WORK PLA N'SA f\IA FIELD LABORATOR'-r

IIALIFORNIA

AnaIvEJ~ Mein odLaook c ;

Compound g/K g);MethyinaphthaieneMethyInapl tip : `eneej'iaphthen &

", : :enaphthyie rAnthracenehcnzo(a)an ian7o(a )p\r,e~rzo(b)ffuo a renzo (g,h,i) r .,

Henzo ( k)fluorai- :-!e[ 'e, ry . ene

'ibenzo ( a,h)anthraceneF r " . eneFluoi ~ rIndeno d ) pyrene

Naph ie!1,:

See last page of T ,I ^ V or no

a TTBS,? 4S0 : .05/25/00Pnn pa n

2270C `SI ,D121 A:

0.022 t ;0 .022 U0.022 U0.022 LI0 .022 i. i

0 .02:1 'u0 .022 I0.022 U0.022 U0 .022 U0.022 U0.022 U0 .0066 J0 .022 U0.022 U

es andHaley & Aldrich,

abbreviations .

TTBS44SO3*®5/25/06Primar,

8270C . .S i iv(Div,At

0 .022 i.'0 .0220 .0220.022k,

0 .322002, .. ;

0 .022 I..0 .022 t :

0 .022 U

0.022 U0.022 U

0.022 U0.022 U0 .022 C

0 .0220 .022 L0 .022 L'0 .022!-;

G :\Projects \26i12\'" i"-%Iivi WP\IMW =`_Final \2006 - 1002-HAI-SSFL .M4xx . TA6 .D .xl s

3`\VivIU 4 .8) ANALYTICAL :FSULTS FOR RECENT Sol` aA. APLINGS

Page

October 2006

Estimated value .

Not detected .

Estimated no,- ; d c^' .

Data is unvalidated for this sample.

Projects\26 72 V' ; =\I1 WP \lMWP_Final\2006 - 1002-HAI-SSFL . vi4x ;( . "C .1--.xls October 2 0 (

NOTES A: - F`~I a=~~ ~

DMA Lei fv ai Analyt;~;ai of Irvine, Califnrri

Selected ion monitoring .

4.8 ; ~.- + .. .: ~ . , L1LTS FOR ECF o~f AMPi~1Py' :

TG 4 HYDROCA = : AMPLES, 2006Al i' . VV <i _BOEING SI I

Pi f WORK PLA TSt `SANA FIELD LAPC)I?<<\ Tr ^

VENTURA C() 0ALIFORNI ,

S~anol ld 1801 * TTBS43S02* TTBS,i:S0 _ TTR, _Ti0

`l/21/0( 05/25 /0' 05/25/0x; 05 ,Primary Primary irin,a Pvie-6 1~) 8Q ~5 ~1iin~i . 8015MOC 8015 ; .? 80 . 10x .

r

DMA A L

g ;k g)(GaC08--l " live Rr o ange} F .4. _

C05--C30 ( Extractable Fuel -lydrocarbons ) 5. L :C12_ "14 ( Kerosene Ranu_ 5. L`C,5-x :2.0 (Diesel Range' . . 5 .4 (:'

0 -030 (Lubricant Oil Range 04 U 5 .4 U

Del !via iclytical of Irvine, Califon i-) .rO- el y = i'nmE ', sample .

MOD . = EPA method 8015 MOD modified for total petroleum hyd rocarbons (TPHs),rilg/ko = milligram/kiloor~ ~--:

Not detected .Data is unvalidated c, c sample .

Haley & Aldrich i,, nG :AProjects \264r2\ i c=\Iivi vNNP\1MWP Final \2006-1002-HAI-SSFL . M4xx . TA7 .D .xls

5 .4 U5i4 i_!

October 2006

/Al ".I I' `

IE 6v,!iiH'OEl6 ,i !

VENTURA LO!, !

Sample IdentifierSample Dat eSample TypeAnalysis Metho dLaboratoryCompound (ug/kg )

,12-Tetrachioroethane- I Uchloroethane

letrachidroethane2-Trichloroethan e

2 E richlorotrifluoroethan eI LilchloroethaneI-Dichloroethen e

Dichloropropen e2 Tri chlorobenzenc

.,2 ,3 Trichloropropanei 7, 2 I richlorobenzene

2 - -1" rimethylbenzen c1,2 DibFort lo-3-chloropro., )e1,2-Dibromoethane

.~ Dichlorobenzen ei , ^-Dichloroethane1,2-Dichloropropene

6, 5-Tri methyl benzene1,3-Dichiorobenzene0-Dichloropropane1,4-Dichlorobenzene2,2-Dichloropropene2-Butanon e2-Chloro-1,1 , I lrifluGro)i, .art e2-Chlorotoluene2-Hexanone4-Chlorotoluene4-Isopropyltoluene4-Methyl-2-pentanoneAceton eBenzene

Bromochioromethan eBromodichioromethaneBromoform

Bromomethan eCarbon disulfideCarbon tetrachlorid eChlorobenzen eChloroethan eChloroformChloromcii; ¢, eChlorotrifluorocthenecis- 1,2-Dichlovnathen e

cis-1,3-DichloropropeneDibromochloromethaneDibromomethan eDichlorodifluorom cEthylbenzeneIHekachlorob ., ie,sopro ; ut3 ..rl

Xylene

I' IC hyi :ort-bi dyl emu ;Metay(Cne chlor ;de

ivionobromobens-Naphthalenen-Butyibenzen en-Propylbenzer; eo-Xylen esec=Butylbs

TTBS85S03* TTBS86SI36/02/06 06/5,2/0(.Primary Primary32608 2260x;Dfvtf .

I_' S FOR RECErv I2006

4.6 U1 .8 U1 .8 U

LS ~I 1 .8 U UGU 4.615 ;_715

1 .8 UG U = U

: .515 : .51111 731

.6 L! ,-c,U 5.7U33 8 LI ?.3

± .o LI 3U . UIS'L. 1 3U 2.3 U

1 .8 U 2.3 U"; .6 U 1.8 U 2.3 U1 .8U 1.8 U 2.3 U. .8 0 1.8 U 2.3 LIc U 1.8 U 2 U6 12 1.8 U 2.3 15

9 . 1U 9.2 U U513 12 46 Li 5 / I_I611 ' .6 "I 1_ U9 U 9.2 U 1 U

615 615 5.7 f,1. .i2 11 6 F 7.S l i

U 6.6 15 5.7 U7 9.2 ''._

U 2; '121u _ 4.6 U 52 15

.2 LI 1 . 8 U 2 .5 U

% .G=U 4.615 Js--6 15 4.6 5.7 LIG LI c L€ 5. 7 1J

6 ' 5.7 L

J I 6 '1 5.7 ui . U 2.5124.6 U 5., u

451 46U 57 U1 .13 1 1.8 0 2.3 U1 .6 i_€ 1.8U 2.3 U1, 'J 1.8U 2.3 1

1 .8 U4.615 5 .i

6

5.6 U2.3 U2.3 U2.3 U7.4

23U5 .6 U

I I 1I

56U2_ .3 U5 .6 U2.3 U2 .3 U2 .3 U2.3 U2.3U2.3 U2 .3U2 .~, IJ

2 .3 U

I,, LI

56 LI

S .6 U

u 't ~I

.6 U2.3 U

5 .6 U

5 .6 U

2.3 U

5 .6 LI

5 .6 U

5 .u 'U

5 .6 LI

6.3 U

5.6 U

2.3 U

5.6 U

56 U

2 .3 U2 .3 U21 1523

Li5 . 8

2 . U

LI

. .sU' :J U3 U 5.71_2 5.6 U315, 22 123 U 2.5 ~ 2.3 15

5%,,

1-1 8865S01" TTBS68801 fi8S685303 TTBS69S01° TB. ;0 106/13/06 OG/ V0,, ),3/ 13/06 06/13/06 36/ '06Primary Prlrrrv I . n1Dnr Prima ry82608 >60R 82608 82608

DMA A, Divi,tk n i

2.1 U

2 .i U2 .1 U2 .1 U2 .1 U

1 J

10U

52 U

5.2 U10 U52 I

2 .1 6.'5 .2 L!10 U2.1 U5 .2 U2 .1 U5 .2 U

52 155 .2U

5 .2 U2.1 U5.2 U2.1 U5.2 U52 U21 U2 .I U

rl

4.9 U 9 U 4 L2U -2U 2 U215 215

4.9U 4.91,' 9 J2 U 712 ,3

E .~ U 4.9 U 5 U

s .9 ..3 U9.9u 9.3U oci i

'U 215 ?U.9 15 9 U 1A Uu 2IJ

2U 21520 ' U2 U2U 2U2 0 2 1j

2 UU 2 U

9-8 € : 9.9 U49 Iu 49 LIU 4.9

9 .8 Uj :9 U2J 215.915 « .9 1 593'' 90 1.

J 2LIJ9L 4915 9215 2U 2Li

% C L[ 4 .9 U,1 .9U 4.9U 915

II 4.9U ~ .9 U° LI 4.9 U . 9 L-

11 .915 4.915 X3 121-1 215 2

427' 49U 49 U215 215 2

2 15 2 U 21t

-(-)ElVENTU F

SampleIdi ., erSample D<Sample i y pAnalysis ivie.i c, dLaborator,.Compound ug/kq )Styrene L -

test buiylbenzene^er?chloroethene

trans 'i,2-D Grdoroe one ; .g Jtrap ,l,3--Dichloioprq ;. ,~, .o UTrichloroetheno 350Trichlorofluoiometha e C UVinyl acetate I ;Vinyl chlorid e2-Chloroatho vii ,/€ -Lifer : .9 U

NO) E 'J . b 3BREv r i .

BS86S03` TTBS63S01 - TBBS65SC wS6t3~ i--2S68S02` TTBS69S01 "06/02/06 06/93106 06/13106 06/13106 06/13/06Primary Primary Primary Primary Primary8260B _c08 82608 826C~ 8260

8DMADMA i r)M" CU

4 .6 U1,8 U9 U

DMA = Del Mar Analyticci of Irving . Caliiorn/a .=,1 ,,a1y i'rimary sample .?!g/i<e = -nicrugrant/kilograms .o _ Uoi detected .

- Data is unvalidated for this sample .

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HDMSe00037449