ISHANGA LIFE SCIENCE PVT. LTD. - Gujarat Pollution ...

DRAFT ENVIRONMENTAL IMPACT ASSESSMENT

REPORT

OF

ISHANGA LIFE SCIENCE PVT. LTD.

FOR

MANUFACTURING OF PHARMA & INTERMEDIATE

PRODUCTS

NEW PROJECT

LOCATED AT:

SURVEY NO.: 310/1/2/3, MADHVAS, TAL.KALOL,

DIST. PANCHMAHAL - 389330, GUJARAT.

PREPARED BY

M/s. JYOTI OM CHEMICAL RESEARCH

CENTRE PRIVATE LIMITED

Shed No. K-1, 7705/2,3,4 GIDC ESTATE,

Ankleshwar - 393002

Phone: 9409423156, 9824150383

Website:www.jyotiom.com

Email: [email protected]

DRAFT EIA FOR M/S. ISHANGALIFESCIENCE PVT. LTD., MADHVAS, DIST: PANCHMAHAL, GUJARAT.

M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. i

TABLE OF CONTENTS

SR. NO. CONTENT PAGE

NO.

CHAPTER -1 INTRODUCTION

1.1 PURPOSE OF THE PROJECT 1

1.2 INTRODUCTION OF THE PROJECT 2

1.3 PROJECT PROPONENT 4

1.4 KEY INFORMATION OF PROJECT 5

1.4.1 IMPORTANCE AND JUSTIFICATION FOR THE NEW

PROJECT 5

1.4.2 NATURE OF THE PROJECT 5

1.4.3 SIZE AND COST OF THE PROJECT 5

1.4.4 SITE SELECTION 7

1.4.5 LOCATION OF THE PROJECT 7

1.5 SALIENT FEATURES 11

1.6 REGULATORY FRAMEWORK 12

1.7 SCOPE & OBJECTIVES OF THE EIA STUDY 12

1.8 STRUCTURE OF EIA REPORT 14

1.9 COMPLIANCE OF STANDARD AND SPECIFIC TERMS OF

REFERENCE (TOR) IN RESPECT OF INDUSTRY SECTOR 15

CHAPTER - 2 PROJECT DESCRIPTION

2.1 TYPE OF PROJECT 30

2.2 NEED FOR THE PROJECT 30

2.3 PRODUCTS AND RAW MATERIAL DETAILS 30

2.3.1 PRODUCT STORAGE & HANDLING 37

2.3.2 RAW MATERIAL STORAGE AND HANDLING 39

2.3.3 PHYSICAL & CHEMICAL PROPERTY / CHARACTERISTICS

OF HAZARDOUS RAW MATERIALS 49

2.3.4 TRANSPORTATION OF RAW MATERIALS AND FINISHED

PRODUCTS 52

2.4 MANUFACTURING PROCESS DESCRIPTION 56

2.5 DETAILS OF SOLVENT AND CHEMICAL RECOVERY

SYSTEM 93

2.6 RESOURCE REQUIREMENT 97

2.6.1 INFRASTRUCTURE FACILITIES (LAND) 97

2.6.2 DETAILS OF FUEL AND ELECTRICITY CONSUMPTION 97

2.6.2.1 BIO-COAL ANALYSIS DETAILS 98

2.6.2.2 DETAILS OF FLY ASH STORAGE, HANDLING AND

DISPOSAL 98


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2.6.3 DETAILS OF ENERGY DISTRIBUTION/UTILISATION AND

EQUIPMENTS/ MACHINERIES 98

2.6.4 UTILITIES 100

2.6.5 MAN POWER REQUIREMENT 101

2.7 WATER REQUIREMENT 102

2.8 WASTE WATER MANAGEMENT 103

2.8.1 WASTE WATER GENERATION DETAILS 103

2.8.2 PRODUCTWISE WASTE WATER GENERATION DETAILS 104

2.9 EFFLUENT TREATMENT PLANT PROCESS 108

2.9.1 SEWAGE GENERATION OR DOMESTIC WASTE WATER 113

2.10 GASEOUS EMISSION 113

2.10.1 FLUE GAS EMISSION 113

2.10.2 PROCESS EMISSION 113

2.10.3 DETAILS OF SCRUBBERS 114

2.11 HAZARDOUS WASTE GENERATION 116

2.12 PROJECT COST ESTIMATES 117

2.13 ADEQUACY OF THE EMS 118

CHAPTER - 3 BASELINE ENVIRONMENT STATUS

3.1 INTRODUCTION 119

3.2 WINDROSE 120

3.3 AIR ENVIRONMENT 122

3.3.1 AMBIENT AIR QUALITY (AAQ) 122

3.3.1.1 LOCATION OF AAQ MONITORING STATIONS 122

3.3.1.2 BASE LINE DATA 123

3.4 WATER ENVIRONMENT 126

3.5 NOISE ENVIRONMENT 133

3.5.1 RECONNAISSANCE 134

3.5.2 METHODOLOGY FOR NOISE MONITORING 134

3.5.3 NOISE MONITORING LOCATIONS 134

3.6 SOIL ENVIRONMENT 136

3.6.1 BASELINE DATA 136

3.7 LAND USE PATTERNS 137

3.8 GEOLOGICAL, BIOLOGICAL ENVIRONMENT FEATURES

OF THE AREA 139

3.8.1 PHYSIOGRAPHY 139

3.8.2 HYDROGEOLOGY 139

3.8.3 GROUNDWATER REGIME MONITORING 140

3.8.4 SEISMICITY 141


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3.8.5 ECOLOGICAL INFORMATION 142

3.8.6 FOREST 143

3.8.7 FLORA 143

3.8.8 FAUNA 146

3.9 SOCIO-ECONOMIC ENVIRONMENT 148

3.9.1 DEMOGRAPHIC DATA WITHIN THE REGION OF INTEREST 149

3.9.2 LITERACY RATE 150

3.9.3 OCCUPATIONAL STRUCTURE 152

3.10 TRAFFIC SURVEY 156

CHAPTER - 4 IDENTIFICATION AND ASSESSMENT OF IMPACTS

4.1 IDENTIFICATION OF IMPACT 157

4.1.1 IMPACT DURING CONSTRUCTION PHASE 158

4.1.2 IMPACT ON AIR ENVIRONMENT 158

4.2 PREDICTION AND ASSESSMENT OF THE IMPACT 165

4.2.1 WATER ENVIRONMENT 165

4.2.1.1 CONSTRUCTION PHASE IMPACTS 165

4.2.1.2 OPERATIONAL PHASE IMPACTS 165

4.2.2 AIR ENVIRONMENT 166


4.2.2.2 OPERATION PHASE IMPACTS 166

4.2.3 NOISE ENVIRONMENT 176



4.2.4 LAND ENVIRONMENT 176



4.2.5 ECOLOGICAL ENVIRONMENT 177



4.2.6 INFRASTRUCTURE AND SERVICES 178


4.2.7 SOCIO-ECONOMIC IMPACT 178


4.2.7.1.1 POPULATION 178

4.2.7.1.2 EMPLOYMENT 179

4.2.7.1.3 TRANSPORTATION 179


4.2.7.2.1 POPULATION 179

4.2.7.2.2 EMPLOYMENT 179

4.2.7.2.3 TRANSPORTATION 179


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4.2.7.2.4 IMPACT DUE TO FIRE ACCIDENT 179

4.2.7.2.5 IMPACT ON PUBLIC HEALTH 179

4.2.7.2.6 ACCIDENT HAZARD AND SAFETY 180

4.3 IMPACT MATRIX 180

CHAPTER – 5 ANALYSIS OF ALERNATIVES (TECHNOLOGY & SITE)


5.2 SITE ALTERNATIVE 183

5.3 TECHNOLOGY ALTERNATIVE 184

CHAPTER – 6 ENVIRONMENT MONITORING PROGRAM


6.2 OBJECTIVES OF ENVIRONMENTAL MONITORING PLAN 185

6.3 IMPLEMENTATION SCHEDULE OF MONITORING

MEASURES 185

6.4 POLLUTION MONITORING AND SURVEILLANCE SYSTEM 186

6.4.1 AMBIENT AIR QUALITY MONITORING 187

6.4.2 STACK MONITORING 187

6.4.3 NOISE MONITORING 187

6.4.4 ENVIRONMENT MONITORING PLAN 187

6.5 COST PROVISION FOR ENVIRONMENTAL MEASURES 190

6.6 IN-HOUSEMONITORING EQUIPMENT AND

CONSUMABLES 190

6.7 ENVIRONMENTAL MANAGEMENT CELL 191

CHAPTER - 7 RISK ASSESSMENT

7.1 EXECUTIVE SUMMARY 192

7.2 OBJECTIVE, PHILOSOPHY AND METHODOLOGY OF RISK

ASSESSMENT 193

7.2.1 OBJECTIVE 193

7.2.2 PHILOSOPHY 193

7.2.3 METHODOLOGY 194

7.3 INTRODUCTION OF THE UNIT 195

7.3.1 COMPANY INTRODUCTION 195

7.3.2 DETAILS OF UNITS 196

7.3.3 PROJECT SETTING 196

7.4 PRECAUTION TO BE TAKEN DURING STORAGE 198

7.4.1 FOR PESO UNDERGROUND STORAGE TANK FARM 198

7.4.2 FOR ABOVE GROUND NON PESO STORAGE TANK FARM 198

7.4.3 FOR ACID & ALKALI 199

7.4.4 HYDROGENATION PLANT 199

7.4.5 FOR DRUM STORAGE AREA 200

7.4.6 FOR WARE HOUSE SAFETY MEASURES 200


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7.4.7 BROMINE BOTTLE STORAGE & HANDLING SAFETY 200

7.5 HAZARDOUS PROPERTIES OF THE CHEMICALS,

COMPATIBILITIES AND SPECIAL HAZARD 205

7.6 TRANSPORTATION, UNLOADING AND HANDLING

PROCEDURE 214

7.6.1 FOR ACETONE, METHANOL, TOLUENE, ETHANOL 214

7.6.2 DRUMS TRANSPORTATION, UNLOADING AND

HANDLING PROCEDURE 217

7.6.3 BROMINE TRANSPORTATION, UNLOADING AND


7.6.4 SODIUM CYANIDE TRANSPORTATION, UNLOADING AND


7.7 FIRE PREVENTION & PROTECTION SYSTEM 225

7.8 DETAILS OF OCCUPATIONAL HEALTH PROGRAM 226

7.9

OCCUPATIONAL HEALTH IMPACT ON EMPLOYEES,

CONTROL MEASURES, ACTION PLAN IF ACCIDENT

OCCUR AND ITS ANTIDOTES

228

7.10 DO’S AND DON’T’S FOR STRENGTHENING HSE 244

7.11 HAZARD IDENTIFICATION 245

7.11.1 INTRODUCTION 245

7.11.2 IDENTIFICATION OF HAZARDOUS AREAS 245

7.11.3 FAILURE FREQUENCIES 246

7.11.4 EVALUATION OF PROCESS AREAS 248

7.12 RISK ASSESSMENT 249

7.12.1 EFFECTS OF RELEASES OF HAZARDOUS SUBSTANCES 249

7.13 FIRE 250

7.13.1 JET FIRE 250

7.13.2 TANK ON FIRE/ POOL FIRE 250

7.13.3 FLASH FIRE 250

7.14 EXPLOSION 251

7.14.1 LATE EXPLOSION (UVCE) 251

7.14.2 BALL FIRE / BLEVE 251

7.15 MODES OF FAILURE 251

7.16 IMPACT CRITERIA 252

7.17 DAMAGE CRITERIA FOR HEAT RADIATION 253

7.18 EXPLOSION / OVER PRESSURE 254

7.19 CONSEQUENCE ANALYSIS 255

7.19.1 CONSEQUENCE ANALYSIS 255

7.19.2 THE CATASTROPHIC/ RUPTURE FAILURE AND MAXIMUM

CREDIBLE LOSS SCENARIOS (MCLS) 255

7.19.3 CONSEQUENCE RESULTS 258


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7.20 CONCLUSION 261

7.21 RISK REDUCTION MEASURES 262

7.21.1 RECOMMENDATIONS 262

7.21.2 CONSEQUENCE CONTUORS 263

7.22 SCENARIO BASED ON SITE AND OFF SITE EMERGENCY

PLAN 285

7.22.1 POSSIBLE EMERGENCYS 285

7.22.2 POSSIBLE EMERGENCY: EARTH QUACK 310

7.22.3 POSSIBLE EMERGENCY: FLOODS 311

7.22.4 POSSIBLE EMERGENCY: CYCLONIC STORMS /

HURRICANE 313

7.22.5 POSSIBLE EMERGENCY: BOMB THREAT 314

7.22.6 POSSIBLE EMERGENCY: NDUSTRIAL UNREST 316

7.22.7 POSSIBLE EMERGENCY: LIGHTING STRIKE IN COMPANY 318

CHAPTER- 8 PROJECT BENEFITS


8.2 ECONOMIC DEVELOPMENT 319

8.3 EMPLOYMENT POTENTIAL 319

8.4 ACTION PLAN FOR BUDGETARY ALLOCATION FOR CER

ACTIVITY 320

CHAPTER- 9 ENVIRONMENTAL COST BENEFIT ANALYSIS

9.1 COST-BENEFIT ANALYSIS 321

CHAPTER- 10 ENVIRONMENT MANAGEMENT PLAN


10.2 AIM AND OBJECTIVE 322

10.3 ENVIRONMENT, HEALTH AND SAFETY (EHS) 323

10.4 ENVIRONMENTAL MANAGEMENT PLAN 323

10.4.1 ENVIRONMENTAL OBJECTIVES 324

10.4.2 IMPLEMENTATION 324

10.5 ENVIRONMENT MANAGEMENT PLAN FOR

CONSTRUCTION PHASE 325

10.5.1 BASIC ENGINEERING CONTROL MEASURES 325

10.5.2 MANAGEMENT OF AIR ENVIRONMENT 326

10.5.3 MANAGEMENT OF WATER ENVIRONMENT 327

10.5.4 MANAGEMENT OF NOISE ENVIRONMENT 328

10.5.5 MANAGEMENT OF LAND / SOIL ENVIRONMENT 328

10.5.6 MANAGEMENT OF SOLID WASTE & HAZARDOUS WASTE 329

10.5.7 MANAGEMENT OF SOCIO-ECONOMIC AND CULTURAL

ENVIRONMENT 331


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10.5.8 MANAGEMENT OF TRAFFIC CONTROL 332

10.5.9 COMPLETION OF CONSTRUCTION ACTIVITY –

RESTORATION 332

10.6 ENVIRONMENT MANAGEMENT PLAN FOR OPERATIONAL

PHASE 332

10.6.1 MANAGEMENT OF WASTE WATER ENVIRONMENT 333

10.6.1.1 EXPLORE THE POSSIBILITIES FOR ZERO LIQUID

DISCHARGE (ZLD) 333

10.6.1.2 MANAGEMENT PLAN FOR

SPILLAGES/LEAKAGES/VESSEL WASHING 333

10.6.2 MANAGEMENT OF AIR ENVIRONMENT 334

10.6.2.1 ALL EMISSIONS MANAGEMENT PLAN 334

10.6.3 MANAGEMENT OF NOISE ENVIRONMENT 336

10.6.4 MANAGEMENT OF LAND ENVIRONMENT 337

10.6.5 MANAGEMENT OF GREEN BELT DEVELOPMENT 338

10.6.5.1 ACTION PLAN FOR THE GREENBELT DEVELOPMENT 339

10.6.5.2 PLANTATION TECHNIQUE AND CARE 340

10.6.7 VEHICULAR POLLUTION CONTROL 341

10.6.8 HEALTH AND SAFETY 341

10.6.9 CLEANER PRODUCTION 342

10.7 ADDITIONAL MITIGATION MEASURES 342

10.7.1 ENERGY CONSERVATION PROGRAMME 342

10.7.2 WATER CONSERVATION PROGRAMME 343

10.7.3 MANAGEMENT OF TRAFFIC 344

10.7.4 ODOUR CONTROL MANAGEMENT PLAN 344

10.7.5 SOCIAL WELFARE MEASURES FOR FUTURE PLANNING 345

10.8 FINDINGS 346

10.9 CONCLUSION 347

CHAPTER- 11 EXECUTIVE SUMMARY& CONCLUSION


11.1.1 LOCATION 348

11.1.2 INVESTMENT 348

11.1.3 INFRASTRUCTURE FACILITIES 348

11.1.4 PRODUCT DETAILS 349

11.2 PROJECT DESCRIPTION 349

11.2.1 NEED FOR THE PROJECT 349

11.2.2 PRODUCTION AND RAW MATERIAL 349

11.2.3 RESOURCE REQUIREMENT 349

11.2.4 POLLUTION POTENTIAL SCENARIO 350

11.3 BASELINE ENVIRONMENT STATUS 351

11.3.1 STUDY AREA INCLUDED IN ENVIRONMENTAL SETTING 351


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11.3.2 CLIMATE OF THE STUDY AREA 351

11.3.3 AMBIENT AIR QUALITY 352

11.3.4 WATER QUALITY 352


11.3.6 SOIL 353

11.3.7 BIOLOGICAL ENVIRONMENT 353

11.4 IDENTIFICATION & ASSESSMENTOF IMPACT 353

11.4.1 WATER ENVIRONMENT 353

11.4.2 AIR ENVIRONMENT 353


11.4.4 LAND ENVIRONMENT 354

11.4.5 ECOLOGICAL ENVIRONMENT 355

11.4.6 INFRA STRUCTURE AND SERVICES 355

11.4.7 SOCIO-ECONOMIC IMPACT 355

11.5 ENVIRONMENT MONITORING PROGRAM 355

11.6 RISK ASSESSMENT AND DISASTER MANAGEMENT

PLAN 356

11.6.1 RISK ASSESSMENT 356

11.6.2 DISASTER MANAGEMENT PLAN 356

11.6.3 OCCUPATIONAL HEALTH AND SAFETY MANAGEMENT

SYSTEM 356

11.7 PROJECT BENEFITS 356

11.8 ENVIRONMENTAL MANAGEMENT PLAN 357

11.8.1 ENVIRONMENT MANAGEMENT CELL 357

11.8.2 ENVIRONMENT MANAGEMENT PLAN FOR UNIT 357

11.9 HEALTH & SAFETY 359

11.10 CONCLUSION 359

CHAPTER- 12 DISCLOSURE OF CONSULTANT ENGAGED

12.1 SALIENT FEATURES 360

12.2 SERVICES PROVIDED BY THE CENTRE 360

12.3 OUTSTANDING ACHIVEMENTS 361

12.4 STATUS OF NABET ACCREDITATION 362

12.5 DECLARATION BY CONSULTANT 363


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LIST OF TABLES

TABLE

NO. TABLE NAME

PAGE

NO.


1.1 LIST OF PRODUCTS 2

1.2 LIST OF DIRECTORS 4

1.3 CAPITAL COST OF PROJECT 6

1.4 PROJECT IMPLEMENTION SCHEDULE 6

1.5 DETAILS OF SIX CORNERS CO-ORDINATE OF SITE 7

1.6 SALIENT FEATURES OF THE PROJECT SITE 11

1.7 DETAILS OF NEIGHBORING INDUSTRIES AT PROJECT SITE 12

1.8 STRUCTURE OF EIA REPORT 14

1.9 GENERIC TOR IN RESPECT OF INDUSTRY SECTOR 16


2.1 LIST OF PRODUCT WISE RAW MATERIALS CONSUMPTION 30

2.2 DETAILS OF PRODUCT STORAGE 38

2.3 DETAILS OF RAW MATERIAL STORAGE 41

2.4 DETAILS OF OTHER CHEMICAL STORAGE FACILITY 48

2.5 CHARACTERISTICS OF HAZARDOUS RAW MATERIALS 49

2.6 DETAILS OF RAW MATERIAL SOURCE AND METHOD OF

TRANSPORTATION

52

2.7 DETAILS OF SOLVENTS TO BE USED AND RECOVERED 94

2.8 LAND USE BREAK UP OF TOTAL PLOT AREA 97

2.9 FUEL CONSUMPTION & ELECTICITY CONSUMPTION 98

2.10 BIO-COAL/FUEL ANALYSIS AND FLUE GAS ANALYSIS

REPORT

98

2.11 DETAILS OF PLANT AND MACHINERY ALONG WITH

ENERGY REQUIREMENT

99

2.12 DETAILS OF UTILITIES 100

2.13 MAN POWER REQUIREMENT 101

2.14 DETAILS OF WATER CONSUMPTION 102

2.15 DETAILS OF WASTE WATER GENERATION 104

2.16 PRODUCT WISE WASTE WATER GENERATION WITH

QUALITATIVE AND QUANTITATIVE ANALYSIS

105

2.17 EQUIPMENT LIST OF EFFLUENT TREATMENT PLANT 110


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TABLE

NO. TABLE NAME

PAGE

NO.

2.18 CHARACTERISTICS OF WASTEWATER BEFORE &AFTER

TREATMENT

111

2.19 EFFLUENT QUALITY AFTER R.O. 111

2.20 EFLUENT QUALITY AT MEE AND VTFD 111

2.21 CHARACTERISTICS OF HIGH COD EFFLUENT 111

2.22 DETAILS OF FLUE GAS EMISSION 113

2.23 DETAILS OF PROCESS EMISSION 113

2.24 DETAILS OF HAZARDOUS WASTE GENERATION 116

2.25 BUDGET OF ALL LOCATION FOR ENVIRONMENTAL

MANAGEMENT

117

CHAPTER – 3 BASELINE ENVIRONMENT STATUS

3.1 LIST OF NEIGHBOUR INDUSTRIES 120

3.2 METEOROLOGICAL DATA 120

3.3 DETAILS OF SAMPLING LOCATION OF AMBIENT AIR 123

3.4 AMBIENT AIR QUALITY STATUS OF STUDY AREA 124

3.5 DETAILS OF GROUND WATER SAMPLING LOCATIONS 127

3.6 WATER QUALITY PARAMETERS (GROUND WATER

SOURCES)

128

3.7 DETAILS OF SURFACE WATER SAMPLING LOCATIONS 130

3.8 WATER QUALITY PARAMETERS (SURFACE WATER

SOURCES)

131

3.9 METHOD OF ANALYSIS 133

3.10 DETAILS OF NOISE LEVEL SAMPLING LOCATIONS 135

3.11 CPCB RECOMMENDATIONS FOR COMMUNITY NOISE

EXPOSURE

135

3.12 DETAILS OF SOIL QUALITY SAMPLING LOCATIONS 136

3.13 DETAILS OF SOIL QUALITY PARAMETERS 136

3.14 LAND USE STATISTICS OF THE STUDY AREA 137

3.15 PROXIMITY TO SEA/WATER BODIES 137

3.16 LIST OF FLORA 143

3.17 LIST OF FAUNA 146

3.18 DEMOGRAPHIC DATA 149

3.19 LITERACY RATE WITHIN 10 KM RADIAL DISTANCE OF

STUDY AREA

150

3.20 OCCUPATIONAL STRUCTURE 152

3.21 DISTRIBUTION OF WORKERS 154


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TABLE

NO. TABLE NAME

PAGE

NO.

3.22 TRAFFIC SURVEY: STATE HIGHWAY (SH-87) 156

CHAPTER – 4 IDENTIFICATION AND ASSESSMENT OF IMPACTS

4.1 DETAILS OF STACKS 167

4.2 CONCENTRATION OF PM & SO2 168

4.3 CONCENTRATION OF NOx 168

4.4 CONCENTRATION OF HCl, Cl2 & NH3 169

4.5 ENVIRONMENT IMPACT MATRIX (WITH MITIGATION

MEASURES)

181

4.6 CUMULATIVE IMPACT CHART 182

CHAPTER – 6 ENVIRONMENT MONITORING PROGRAM

6.1 IMPLEMENTATION POLLUTION CONTROL MEASURES 186

6.2 ENVIORNMENT MONITORING PLAN 187

6.3 LIST OF LAB EQUIPMENTS 190

CHAPTER -7 RISK ASSESSMENT

7.1 DETAILS OF PROPOSED PROJECT 196

7.2 HAZARDOUS PROPERTIES OF THE CHEMICALS,

COMPATIBILITIES AND SPECIAL HAZARD

205

7.3

TRANSPORTATION, UNLOADING AND HANDLING

PROCEDURE FOR ACETONE, METHANOL, TOLUENE,

ETHANOL

214


PROCEDURE FOR DRUMS

217


PROCEDURE FOR BROMINE

220


PROCEDURE FOR SODIUM CYANIDE

224

7.7 FIRE PROTECTION SYSTEM 225

7.8 FIRE EXTINGUISHER TYPE 226

7.9

OCCUPATIONAL HEALTH IMPACT ON EMPLOYEES,

CONTROL MEASURES, ACTION PLAN IF ACCIDENT OCCUR

AND ITS ANTIDOTES

228

7.10 TYPICAL FAILURE FREQUENCIES 246

7.11 ESTIMATED FREQUENCIES OF VAPOUR CLOUD EXPLOSION 247

7.12 FAILURE RATES FOR PRESSURE STORAGE 248

7.13 MODES OF FAILURE 252

7.14 PRACTICAL SIGNIFICANCE OF RADIATION INTENSITY 253

7.15 PRACTICAL SIGNIFICANCE OF OVER PRESSURE 254

7.16-A

THE CATASTROPHIC/ RUPTURE FAILURE AND MAXIMUM

CREDIBLE LOSS SCENARIOS (MCLS) IDENTIFIED FOR

PLANT BASE

255

7.16-B CONSEQUENCE RESULTS 258

7.17 HEAVY SPILLAGE OF SOLVENT FROM ROAD TANKER 285

7.18 UNCONFINED POOL FIRE DUE TO HEAVY SPILLAGE FROM

ROAD TANKER UNLOADING HOSE

288

7.19 HEAVY SPILLAGE OF ACID FROM STORAGE TANK 291


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TABLE

NO. TABLE NAME

PAGE

NO.

7.20 DRUM SPILLAGE IN DRUM STORAGE AREA (SPILL

CONTROL PLAN)

293

7.21 FIRE IN DRUM STORAGE AREA 296

7.22 THIONYL CHLORIDE DRUM SPILLAGE 298

7.23 SODIUM CYANIDE 301

7.24 BROMINE BOTTLE DAMAGE SPILLAGE SCENARIO 303

7.25 HYDROGEN CYLINDER CHARGING LINE FAILURE / POINT

SOURCE RELEASE SCENARIO

305

7.26 MAJOR ELECTRICAL FIRE IN HT/LT PANEL, CABLE

TRENCH, CABLE TRAY, ELECTRICAL EQUIPMENTS

307

7.27 LEAK FROM FLANGES, VALVES, DURING TRANSFER

FROM/TO MAIN TANK.

309

7.28 POSSIBLE EMERGENCY: EARTH QUACK 310

7.29 POSSIBLE EMERGENCY: FLOODS 311

7.30 POSSIBLE EMERGENCY: CYCLONIC STORMS / HURRICANE 313

7.31 POSSIBLE EMERGENCY: BOMB THREAT 314

7.32 POSSIBLE EMERGENCY: INDUSTRIAL UNREST 317

7.33 POSSIBLE EMERGENCY: - LIGHTING STRIKE IN COMPANY 318

CHAPTER- 8 PROJECT BENEFIT

8.1 BUDGETARY ALLOCATION FOR CER ACTIVITIES 320

CHAPTER- 10 ENVIRONMENT MANAGEMENT PLAN

10.1 CONSTRUCTION PHASE DETAILS 326

10.2 DETAILS OF ALL EMISSION CONTROL MEASURES 334

10.3 DETAILS OF CONTROL MEASURES FOR NOISE POLLUTION 336

10.4 LIST OF PLANT SPECIES TO CONTROL GAS, DUST EMISSION

AND NOISE LEVEL

338

10.5 BUDGET FOR GREENBELT DEVELOPMENT 340

CHAPTER- 12 DISCLOSURE OF CONSULTANT ENGAGED

12.1 NAME OF EIA TEAM MEMBER 362


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LIST OF FIGURES

FIGURE

NO. FIGURE NAME PAGE NO.


1.1 GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT

LOCATION WITH IN 0.5 KM

8

1.2 GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT

LOCATION WITH IN 2 KM

9

1.3 GOOGLE EARTH OR SATELLITE IMAGE OF ALL SIX

CORNERS OF THE SITE

10


2.1 FLOW DIAGRAM OF SOLVENT RECOVERY SYSTEM 93

2.2 WATER BALANCE DIAGRAM 103

2.3 FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT 112

2.4 DIAGRAM OF ALKALI SCRUBBER ATTACHED WITH

REACTOR- II & REACTOR-III

114

2.5 DIAGRAM OF TWO STAGE WATER SCRUBBER 115

CHAPTER - 3 BASELINE ENVIRONMENT STATUS

3.1 (A) WIND ROSE DIAGARM FOR PERIOD OF OCTOBER-2018

TO JANUARY-2019

121

3.1 (B) WIND ROSE DIAGARM ON SATELITE IMAGE 121

3.2 WIND CLASS FREQUENCY DISRTIBUTION 122

3.3 LOCATION OF AMBIENT AIR QUALITY MONITORING

STATIONS

123

3.4 LOCATION OF GROUND WATER QUALITY

MONITORING STATIONS

127

3.5 LOCATION OF SURFACE WATER QUALITY

MONITORING STATIONS

130

3.6 LOCATION OF NOISE MONITORING STATIONS 134

3.7 LOCATION OF SOIL MONITORING STATIONS 136

3.8 LAND COVER MAP WITH VILLAGE LOCATION / LAND

USE MAP WITH STUDY AREA

138

3.9 HYDROGEOLOGICAL MAP OF PANCHMAHAL DISTRICT 140

3.10

DEPTH OF WATER LEVEL MAP OF PANCHMAHAL

DISTRICT DURING NOV-2012

141

3.11 SEISMIC ZONES IN INDIA 142

CHAPTER - 4 IDENTIFICATION AND ASSESSMENT OF IMPACTS

4.1 IMPACT NETWORK ON AIR ENVIROENMENT 159

4.2 IMPACT NETWORK ON NOISE ENVIRONMENT 160

4.3 IMPACT NETWORK ON WATER ENVIRONMENT 161

4.4 IMPACT NETWORK ON GROUND WATER

ENVIRONMENT

162

4.5 IMPACT NETWORK ON SOCIO-ECONOMIC AND 163


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. xiv

CULTURAL ENVIRONMENT

4.6 IMPACT NETWORK ON LAND ENVIRONMENT 164

4.7 ISOPLETHS OF SO2 170

4.8 ISOPLETHS OF NOX 171

4.9 ISOPLETHS OF PM 172

4.10 ISOPLETHS OF NH3 173

4.11 ISOPLETHS OF HCl 174

4.12 ISOPLETHS OF Cl2 175

CHAPTER -6 ENVIRONMENTAL MONITORING PROGRAM

6.1 FLOW DIAGRAM OF ENVIRONMENT MANAGEMENT

CELL

191

CHAPTER -7 RISK ASSESSMENT

7.1 SITE FIRE HYDRANT LAYOUT 197

7.2 DIAGRAM FOR BROMINE HANDLING 204

7.3 ACETONE 20 KL ROAD TANKER UNLOADING POINT

CATASTROPHIC RUPTURE – POOL FIRE

263

7.4 ACETONE 20 KL ROAD TANKER UNLOADING POINT

CATASTROPHIC RUPTURE – FLASH FIRE

263

7.5

ACETONE 20 KL ROAD TANKER UNLOADING POINT

CATASTROPHIC RUPTURE – LATE EXPLOSION WORTH

CASE

264

7.6

ACETONE20 KL ROAD TANKER UNLOADING POINT 25

MM LEAK – POOL FIRE

264

7.7

ACETONE 20 KL ROAD TANKER UNLOADING POINT 25

MM LEAK – JET FIRE

265

7.8


MM LEAK – FLASH FIRE

265

7.9


MM LEAK – LATE EXPLOSION WORTH CASE

266

7.10


MM HOSE FAILURE – POOL FIRE

266

7.11


MM HOSE FAILURE – JET FIRE

267

7.12


MM HOSE FAILURE – FLASH FIRE

267

7.13


MM HOSE FAILURE – LATE EXPLOSION WORTH CASE

268

7.14 METHANOL 20 KL ROAD TANKER UNLOADING POINT 268


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. xv

CATASTROPHIC FAILURE – POOL FIRE

7.15

METHANOL 20 KL ROAD TANKER UNLOADING POINT

CATASTROPHIC FAILURE – FLASH FIRE

269

7.16


CATASTROPHIC FAILURE – LATE EXPLOSION WORTH

CASE

269

7.17


25 MM LEAK – POOL FIRE

270

7.18


25 MM LEAK – JET FIRE

270

7.19


50 MM HOSE FAILURE – POOL FIRE

271

7.20

METHANOL20 KL ROAD TANKER UNLOADING POINT

50 MM HOSE FAILURE – JET FIRE

271

7.21


50 MM HOSE FAILURE – FLASH FIRE

272

7.22


50 MM HOSE FAILURE – LATE EXPLOSION WORTH

CASE

272

7.23

TOLUENE 20 KL ROAD TANKER UNLOADING POINT

CATASTROPHIC FAILURE – POOL FIRE

273

7.24


CATASTROPHIC FAILURE – FLASH FIRE

273

7.25


CATASTROPHIC FAILURE – LATE EXPLOSION WORTH

CASE

274

7.26

TOLUENE 20 KL ROAD TANKER UNLOADING POINT 25

MM LEAK – POOL FIRE

274

7.27


MM LEAK – JET FIRE

275

7.28


MM HOSE FAILURE – POOL FIRE

275

7.29


MM HOSE FAILURE – JET FIRE

276

7.30 TOLUENE 20 KL ROAD TANKER UNLOADING POINT 50 276


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. xvi

MM HOSE FAILURE – FLASH FIRE

7.31


MM HOSE FAILURE – LATE EXPLOSION WORTH CASE

277

7.32

ETHANOL 20 KL STORAGE TANK CATASTROPHIC

FAILURE – POOL FIRE

277

7.33


FAILURE – FLASH FIRE

278

7.34


FAILURE – LATE EXPLOSION WORTH CASE

278

7.35

ETHANOL 20 KL STORAGE TANK 50 MM LEAK – POOL

FIRE

279

7.36

ETHANOL 20 KL STORAGE TANK 50 MM LEAK – JET

FIRE

279

7.37

ETHANOL 20 KL STORAGE TANK 50 MM LEAK – FLASH

FIRE

280

7.38

HYDROGEN 7 M3 CYLINDER RUPTURE CATASTROPHIC

FAILURE– FIRE BALL

280

7.39


FAILURE– FLASH FIRE

281

7.40


FAILURE– LATE EXPLOSION WORTH CASE

281

7.41

HYDROGEN 7 M3 CYLINDER RUPTURE 10 MM LEAK –

JET FIRE

282

7.42


FLASH FIRE

282

7.43


LATE EXPLOSION WORTH CASE

283

7.44

BROMINE PACK OF SIX 3 KG GLASS BOTTLE IN

WOODEN CASE – MAXIMUM CONCENTRATION

FOOTPRINT

284

7.45

DRUM 80 KL STORAGE CATASTROPHIC RUPTURE –

FIRE BALL / BLEVE

284

7.46

DDRUM 80 KL STORAGE CATASTROPHIC RUPTURE –

POOL FIRE

284


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. xvii

LIST OF ANNEXURE

ANNEXURE

NO.

ANNEXURE NAME

I TOR LETTER

II-A UDYOG AADHAAR MEMORANDUM

II-B EC TO CTE ON XGN GPCB WEBSITE

III LAND DOCUMENTS (NA LETTER)

IV PLANT LAYOUT

V TOPOSHEET

VI CHARACTERISTIC OF PRODUCTS AND RAW MATERIALS

VII APPLICATION ON CGWA FOR GROUND WATER PERMISSION

VIII-A TECHNICAL OFFER FOR RO SYSTEM

VIII-B TECHNICAL OFFER FOR MEE SYSTEM

IX MEMBERSHIP CERTIFICATE FROM BEIL

X MOU FOR FLY ASH

XI LETTER FROM MADHVAS VILLAGE FOR CER ACTIVITY

XII EHS PLOICY

XIII BASE LINE MONITORING DATES & LOCATIONS

XIV-A PHOTOGRAPHS OF MONITORING

XIV-B PHOTOGRAPHS OF PROJECT SITE

XV UNDERTAKING BY PROJECT PRSOPONENT

XVI UNDERTAKING BY CONSULTANT

XVII HIGH COURT STAY ORDER


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. xviii

ABBREVIATIONS

AAQM Ambient Air Quality Monitoring

APCM Air Pollution Control Measures

API Active Pharmaceutical Ingredient

AMSL Above Mean Sea Level

BEIL Bharuch Environ Technology Limited

BGL Below Ground Level

BOD Biological Oxygen Demand

CETP Common Effluent Treatment Plant

CGWA Central Ground Water Authority

CGWB Central Ground Water Board

CH BASE Chlorhexidine Base

CH & S Community Health & Safety

CO Carbon Monoxide

COD Chemical Oxygen Demand

CPCB Central Pollution Control Board

CSR Corporate Social Responsibility

CTE Consent to Establish

CTO Consent to Operate

Db Decibels

DCM/MDC Dichloro Methane/Methylene Dichloride

DCP Dry Carbon Powder

DEM Dimethyl ether

DFO Deputy Forest Officer

DG Diesel Generator

DGVCL Dakshin Gujarat Vij Company Limited

DMP Disaster Management Plan

DMS Dimethyl Sulfide

DO Dissolve Oxygen

EHS Environmental Health and Safety

EIA Environmental Impact Assessment

EMP Environmental Management Plan

EOT Electric Overhead Travel

EPA Environmental protection Act

ESP Exchangeable Sodium Percentage

ETP Effluent Treatment Plant

FAE Functional Area Expert

FETP Final Effluent Treatment Plant

GIDC Gujarat Industrial Development Corporation

GLC Ground Level Concentration

GPS Global Positioning System

Ha Hectare

HAZOP Hazard and Operability Study

HC Hydrocarbon

HCl Hydrochloric acid

HDPE High Density Polyethylene

HP Horse Power


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. xix

HSD High Speed Diesel

H2SO4 Sulphuric Acid

IMD Indian Meteorological Department

IPA Isopropyl alcohol

IPE Isopropyl Ether

INR Indian Rupees

KG Kilo Gram

KLD Kilo Liter per Day

KVA Kilo Volt Ampere

kW Kilowatt

MCLS Maximum Credible Loss Scenarios

MEE Multiple Effect Evaporator

MIBK Methyl Isobutyl Ketone

MoEF & CC Ministry of Environment and Forest & Climate Change

MoU Memorandum of Undertaking

MS Mild Steel

MSIHC Manufacture, Storage and Import of Hazardous Chemical

MSDS Material Safety Data Sheet

MSW Municipal Solid Waste

MT Metric Tone

NA Not Applicable

NABET National Accreditation Board of Education and Training

NAAQS National Ambient Air Quality Standards

NaOH Sodium Hydroxide

NH National Highway

NH3 Ammonia

NOC No Objection Certificate

NOX Nitrogen Oxides

NECL Nandesari Environment Control Limited

OHS Occupational Health& Safety

OSHAS Occupation Health and Safety Assessment Series

PCU Passenger Car Unit

PEL Permissible Exposure Level

PESO Petroleum and Explosives Safety Organization

PHC Public Health Center

PM Particulate Matter

PP Project Proponent

PPE Personal Protective Equipments

PPMV Parts per Million by Volume

PUCC Pollution Under Control Certificate

QCI Quality Council of India

R&R Resettlement & Rehabilitation

RCC Reinforced Cement Concrete

RO Reverse Osmosis

SEAC State Expert Appraisal Committee

SEIAA State Environment Impact Assessment Authority

SS Stainless Steel

STP Sewage Treatment Plant

SH State Highway

SO2 Sulfur Dioxide


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. xx

LIST OF SYMBOLS / NOTATIONS

°C : Degree Celsius

dB(A) : Decibels(A-Weighted)

Kcal/Hr : Kilo Calorie per Hour

KVA : Kilo Volts Ampere

KLD : Kilo Liters per Day

m : meters

m/s : Meters per Second

mg/lit : Milligram/ Liters

MW : Mega Watt

µg/m3 : Microgram/cube meter of air

µs : Microgram second

NOX : Oxides of Nitrogen

PM : Particulate Matter

ppm : Parts per Million

SCM : Standard Cubic Meter

SO2 : Sulphur dioxide

Sq. km. : Square kilometer

Sq. m. : Square Meter

TPM : Ton per Month

TDS Total Dissolved Solids

TOC Total Organic Compound

ToR Terms of Reference

TPD Tone Per Day

TSDF Transportation Storage and Disposal Facility

TSS Total Suspended Solid

USEPA United States Environment Protection Agency

VECs Valued Environmental Components

VOC Volatile Organic Compound

ZLD Zero Liquid Discharge


M/S. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1

CHAPTER -1

INTRODUCTION

1.1 PURPOSE OF THE PROJECT

M/s. Ishanga Life Science Pvt. Ltd. is located at Survey No.: 310/1/2/3, Madhvas, Tal.Kalol,

Dist. Panchmahal- 389330, Gujarat. The unit will be engaged in manufacturing of Pharma &

intermediate products. Proposed production capacity will be 193 MT/Month. The proposed

products manufacture by the unit fall in the Schedule attached to the EIA Notification, i.e.

Project No. 5(f), Synthetic Organic Chemicals. As per EIA Notification dated 14th Sep, 2006,

and its amendments thereafter from time to time, the project falls under as Category ‘A’ Project.

Environment Clearance will be evaluated by the Industrial committee of MoEF and CC, New

Delhi.

The unit had applied for its TOR, in MOEF& CC, Delhi. With respect to the TOR application,

unit had submitted Form-I and prefeasibility report on dated 11th November 2018, after TOR

acceptance. After that its auto TOR granted on dated 14th December, 2018. Thus, the purpose of

EIA studies and preparation of detailed EIA/EMP report is to comply with Terms of References

(TOR) granted by MOEF& CC. The copy of TOR is attached as Annexure-I.

The purpose of this report is to:

• Establish a pre-project baseline with respect to environmental indicators.

• Identify environment related impacts

• Evaluate safety related risk factors associated with project

• Propose appropriate mitigation measures for minimizing the adverse impacts to the extent

possible

• Suggest Environment Management Plan

• Recommend Risk Management Plan

This report is also made in the overall frame work of the Environmental Impact Assessment

(EIA) Notification dated 14thSeptember 2006(and subsequent amendments to the same) issued

by the Ministry of Environment and Forests &Climate Change (MoEF& CC), by providing

required information with regards to the project as mentioned in the Terms of Reference issued

by the Industrial committee-2 of MoEF& CC, New Delhi.

This Report is prepared based on ‘General Structure of EIA’ given in Appendix III and IIIA of

mentioned EIA Notification.



1.2 INTRODUCTION OF THE PROJECT

M/s. Ishanga Life Science Pvt. Ltd. is a new unit. It will manufacture pharma& intermediate

products at Survey No.: 310/1/2/3, Madhvas, Tal. Kalol, Dist. Panchmahal- 389330, Gujarat.

The unit has proposed to manufacture 193 MT/Month. The total plot area is 6378 sq. m. The

expected cost of proposed new project will be approx. Rs. 11.65 Crores.

The proposed manufacturing plant will be equipped with appropriate production facilities.

Features justifying the location are summarized below:

• Availability of suitable and adequate land;

• Availability of all essential facilities like infrastructure, communication, medical facilities,

fuel, ground water, power, unskilled & skilled manpower, raw materials, road network.

• The proposed project will be located on non-agricultural land.

• District Panchmahal, head quarter Godhra is 36.7 km away from the location, which is

having connectivity with other parts of the country by road, rail.

In addition there are advantages of present site. They are -

• Site is very well connected by road and rail and close to Kalol city. Availability of power

facilities–MGVCL, availability of water facilities from own bore well, raw materials will be

available easily and transportation cost will be cheap, availability of TSDF site for disposal

hazardous waste.

Considering the above features, above site is selected for proposed activities. The details of list

of products are given in Table 1.1.

TABLE NO.: 1.1

LIST OF PRODUCTS

Sr.

No. Name of Products CAS No.

Capacity

MT/Month End usage

1 5-Nitrofurfural diacetate 92-55-7 3 Intermediate of

Nitrofurantoin

2 1 amino hydantoin 2827-56-57 3 Intermediate of

Nitrofurantoin

3 Phosphoryl choline chloride,

calcium salt 72556-74-2 7

Intermediate of

Citicoline

4 Citicoline (CTS) tech 33818-15-4 5 Alzheimer's disease

5 2-(4-Aminopentyl (ethyl)

amino) ethanol 69559-11-13 10

Intermediate of

hydroxy chloroquin

sulphate



Sr.


Capacity

MT/Month End usage

6 3-Quinuclidinone 3731-38-2 10 Intermediate of

solesenacin&pemilin

7

1-Ethyl-3-(3-

Dimethylaminopropyl)

Carbodimide Hydrochloride

25952-53-8 15 Intermediate for

Gliptin Series API

8 3-(1-Cyanoethyl) Benzoic

Acid 5537-71-3 15

Ketoprofen

intermediate

9

1-(p-methoxy benzyl)-

1,2,3,4,5,6,7,8,Octahydro iso

quinaline- S-octa base

30356-07-1 8

Intermediate of

Dextromethorphan

hydrobromide

10 Dextrometharphin free base 6700-34-1 8 Cough suppressant

11

Cis-2-(2,4-Dichloro phenyl)-

2-(1H-1,2,4-triazol-1-yl-

methyl)-1,3-

dioxolan-4-yl methyl methane

sulfonateCrude

67914-86-7 10 Intermediate of

Itraconazole

12

cis-2-(2,4-Dichloro phenyl)-


methyl)-1,3-dioxolan-4-yl

methyl methane sulfonate -

Pure

67914-86-7

8

Intermediate of

Itraconazole

13 Phenyl (1h pyrrole-2-

yl)methanone – tricarboxylate 136116-84 10

Intermediate of

Ketorolac

14

(-)-1-[(4-

Chlorophenyl)phenyl

methyl]-4-[(4-methylphenyl)

sulfonyl] piperazine


Levocetrizine

15 p-Chloro benzhydryl

piperazine 303-26-4 6

Intermediate of

Levocetrizine

16

2,3 pyrridineBenzyle

carboxylate Hydrate Chloro

compound


Moxyfloxacin

17 3,4-dimethoxy-2-chloro

methyl pyridine 169905-10-6 10

Intermediate of

Pentaprozole

18 pentaprozolesulphide 102625-64-9 10 use in medicines

19 Pregabalin (Racemic) 148553-50-8 8 Use for

neuropathic pain

20 11-Piperazinyl-dibenzo(b,f)

(1,4)-thiazepine 111974-74-4 8

Intermediate of

Quetiapine



Sr.


Capacity

MT/Month End usage

hydrochloride

21

11-[4-[2-(2-Hydroxy ethoxy)

ethyl]-1-piperazinyl] dibenzo

(b, f) (1, 4) thiazepine

hemifumarate


Quetiapine

22

2-[(4-(3-methoxypropoxy)-3-

methyl- 2-pyridinyl)

methyl]thio]-1H-

benzimidazole- Crude


Rabeprazole

23

2-[4-(3-methoxypropoxy)-3-

methyl-2-pyridinyl]

methyl]sulfinyl]-1H-

benzimidazole - Pure


Rabeprazole

Total ---- 193 ----

Note: At a time, not more than 6 to 8 products will be manufactured. Products will be

manufactured on campaign basis.

1.3 PROJECT PROPONENT

The directors of the company have good experience in handling the production management,

financial management and all the allied areas. One of the Managing director of the company is

Ms. Tanvi Tank, who is well educated (M. Pharm) & knowledgeable. She has more than 5years

experience in Production, Operations, Process Improvement & optimization and new product

Scale up, strong administration, Liasoning, human resource, Project management, etc. Details

regarding Directors are given in Table 1.2.

TABLE NO.: 1.2

LIST OF DIRECTORS

Sr. No. Name of Directors Residential Address Contact no.

1. Mr. Ramlal Maru 33,34-Narmada Nagar, Kanjari Road,

Halol, Dist: Panchmahal- 389350 9825033071

2. Mr. Jigar Maru 33,34-Narmada Nagar, Kanjari Road,


3. Ms. Tanvi Tank C-25/26, Uma society, Kanjari Road,


4. Ms. Avani

Bhattacharya

B-302, Surya Kiran Society, Charwada

Road, Vapi, Dist: Valsad- 396195 7715086528



1.4 KEY INFORMATION OF PROJECT

1.4.1 IMPORTANCE AND JUSTIFICATION FOR THE NEW PROJECT

The unit does contribute towards improving their quality of life since the end users of products

are industries ranging from pharma and its intermediate’s - markets that are critical to long-term

sustainability. By supplying high quality and good value products to the customers, the unit

indirectly helps people to have access to better medicines of daily use. In other words, the supply

chain management will improve which will play a significant role in the unit’s business strategy.

The products are highly influenced by the market demand and market rates.

Various products listed in Table no.1.1 are used in manufacturing of API & Pharmaceuticals

industries.

1.4.2 NATURE OF THE PROJECT

The proposed project is for pharma and intermediates products. The various categories of the

pharma intermediates like 5-Nitrofurfural diacetate, 1-amino hydantoin hydrochloride,

Phosphoryl choline chloride, calcium salt, Citicoline (CTS) tech, 2-(4-Aminopentyl (ethyl)

amino) ethanol and other products will also be manufactured.

The project will develop on principle of unit operations. The design based on requirement of unit

operations rather than based on individual products.

The site is located on non-agricultural land of Madhvas village. The expected cost of proposed

project is Rs. 11.65 Crores.

1.4.3 SIZE AND COST OF THE PROJECT

The plot is located on non- agricultural land of Madhvas village, Dist: Panchmahal. The total

plot area of the unit is 6378 sq. meter. The total green belt area is approx. 2110 sq. meter. The

expected cost of proposed new project is Rs. 11.65 Crores.

The letter of private land is attached as Annexure-III, in which described that the land is non-

agricultural land.

Udyog Aadgar memorandum is attached as Annexure-II-A.

Plant layout is attached as Annexure – IV. Toposheet of the project site and nearest habitats is

attached as Annexure-V.

New Plant and machineries, Environment Protection and safety systems, Green belt

development, provision of fire extinguishers etc. are also calculated. The following table shows

the break-up of the proposed project cost.



TABLE NO.: 1.3

CAPITAL COST OF PROJECT

Sr. No. Purpose Proposed

(Rs. In Crore)

1. Land 0.25

2. Building 2.50

3. Plant and Machinery 6.0

4. Q.A. Lab set up 0.70

5. Env. Protection & Safety 2.20

a) Effluent treatment Plant 1.25

b) Safety Equipment

(PPE, fire extinguishers, Ventilation etc.)

0.25

c) Green belt development 0.10

d) Fire 0.15

e) Air Pollution Control Measures 0.25

f) Hazardous Waste Storage Area 0.20

Total 11.65

Being a new unit, following schedule is planned, wherein the unit will start its schedule after

receiving EC & CTE simultaneously. EC to CTE apply is done on XGN website and copy of

application is attached as annexure-II-B.

TABLE NO.: 1.4

PROJECT IMPLEMENTION SCHEDULE

Project implementation schedule after getting NOC from GPCB

Sr. No. Activity Required Period

1. Civil work Immediately after getting NOC– 8 to 10 Months in

Stages

2. Procurement of machinery 2 months after getting NOC in Stages

3. Eraction & installation of machinery

Immediately after completion of activity no. 2 – 1 month

4. Trial of machinery& equipment

Within 1 month after completion of activity no. 3

5. Commercial activity 1month after completion of activity no. 4



1.4.4 SITE SELECTION

The project proponent did not consider any other alternative site for proposed new project. The

proposed plot is on private land which is considered as non- agricultural land. Land possession

documents are attached as Annexure - II.

1.4.5 LOCATION OF THE PROJECT

The project site is located at Survey No.: 310/1/2/3, Madhvas, Tal. Kalol, Dist. Panchmahal-

389330 in the state of Gujarat. It is approximately 3.87 km away from Halol – GIDC.

Halol is largely an industrial area dominated by small scale, Medium scale and large scale

industries. Communication facility available in the area is good. The nearest Domestic Airport is

Vadodara, about 38.85 Km away from the project site. A railway line of Bakrolis 3.20km away

from the project site. The project site is very well connected with the both National Highway

No.8 and State Highway No.87.

The site location map showing 2 km radial distance from project site is as given in Figure no.

1.2. The plant layout is attached as Annexure –IV.

The approximate geographical positioning of the project site is at Latitude: 22°34'29.33"N,

Longitude: 73°26'48.47"E. The unit is spread over in 6378 sq.mt. Area in Madhvas village. The

location of the project site can be identified from the satellite image or Google earth image

shown in Figure 1.1 & 1.2.

All six corners of the site Co-ordinates latitude and Longitude are given in Table 1.5 and shown

in Figure 1.3.

TABLE NO.: 1.5

DETAILS OF SIX CORNERS CO-ORDINATE OF SITE

Directions Corners Latitude Longitude

WN 1st 22°34'30.40"N 73°26'47.75"E

NE 2nd 22°34'30.48"N 73°26'49.53"E

East 3rd 22°34'29.34"N 73°26'50.98"E

East 4th 22°34'29.28"N 73°26'49.17"E

SE 5th 22°34'29.06"N 73°26'48.05"E

SW 6th 22°34'27.35"N 73°26'47.33"E



FIGURE 1.1

GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT LOCATION WITH IN 0.5 KM



FIGURE 1.2

GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT LOCATION WITH IN 2 KM



FIGURE 1.3

GOOGLE EARTH OR SATELLITE IMAGE OF ALL SIX CORNERS OF THE SITE



1.5 SALIENT FEATURES

The plant is located on a private land, which is considered as non- agricultural land. The unit will

have all essential facilities such as own bore well for water supply, and power supply from

MGVCL, hazardous waste disposal facilities etc.

The Madhvas village is falls in Kalol tehsil & it’s approximately 3.87 km away from Halol –

GIDC. Halol is largely an industrial area dominated by small scale, Medium scale and large scale

industries. The salient features of project site are given in Table 1.6.

TABLE NO.: 1.6

SALIENT FEATURES OF THE PROJECT SITE

Particulars Details Distance from project

site

Village Madhvas 2.0km

Taluka/ Tehsil Kalol 4.03 km

District Panchmahal, Head Quarter Godhra 36.7km

Approx. Geographical

positioning

Latitude: 22º34ʹ28.63ʺ N

Longitude: 73º 26ʹ 48.17ʺ E

Nearest City Vadodara 40.5 km

Nearest Town Kalol 4.03km

Nearest Highway National Highway No. 8

State Highway No. 87

33.0 km

0.75km

Nearest Railway line/

Railway station Bakrol 3.20 km

Nearest Airport/ Airbase Vadodara 38.85km

Nearest Hospital ---- 3.8km

Nearest School ---- 0.6 km

� There are no metropolitan cities.

� There are no ecological sensitive areas such as tropical forests, biosphere reserve, and

important lakes or coastal areas rich in coral formation.

� There is no national park of wild life sanctuary.

� There are no sensitive places of archaeological, historical, cultural and religious or tourist

importance.

� There is no reserved forest and protected forest within 10 km distance.

� The lists of neighboring industries are given in below table.



TABLE NO.: 1.7

DETAILS OF NEIGHBORING INDUSTRIES AT PROJECT SITE

Sr.

No

Name of

Neighboring industries Address

Direction &

distance

1. M/s. CEAT Tyre Getmuvada, PO: Chandrapura,

Tal: Halol, Dist.: Panchmahal

South

4.84km

2. M/s. Panchmahal Poly Pack Pvt.

Ltd.

PO: Madhvas, Tal: Kalol,

Dist.: Panchmahal

NE

0.27 Km

3. M/s. Avdhut Steel Pvt. Ltd. Survey No.: 230/1, Madhvas, Tal:

Kalol, Dist.: Panchmahal

SE

0.76 Km

4. M/s. Hero Moto Corp. Ltd. Sathrotha Road, Maghasar,

Tal: Kalol, Dist.: Panchmahal

ESE

1.66 Km

5. M/s. Safari Industries (India) Ltd. Abhetwa, Halol- 389350,

Dist.: Panchmahal

SSE

6.66 Km

1.6 REGULATORY FRAMEWORK

Based on the scope of work and general guidelines, study area of 10 km around the site has been

taken as the spatial frame for the impact assessment. Temporal frame of assessment has been

chosen to reflect the impacts in two distinct phases of the project namely:

1) Construction phase

2) Operation phase

This report is also made in the overall frame work of the Environmental Impact Assessment

(EIA) Notification dated 14th September 2006 (and subsequent amendments to the same) issued

by the Ministry of Environment and Forests and Climate Change (MoEF-CC). The unit requires

taking Environmental clearance from Industrial Committee of MoEF-CC, Delhi.

1.7 SCOPE & OBJECTIVES OF THE EIA STUDY

This EIA Report is prepared to comply with the requirements of the Industrial committee,

MoEF-CC as per the guideline for the Clearance. The objectives of this EIA are:

• To describe the Project and associated works together with the requirements for carrying

out the Project.



• To identify and describe the elements of the community and environment likely to be

affected by the Project, and / or likely to cause impacts upon the Project, including both

the natural and man-made environment;

• To identify and quantify emission sources and determine the severity of impacts on

sensitive receivers and potential affected uses;

• To recognize and quantify any environmental impacts associated with the Project and

recommend appropriate mitigation measures;

• To study landscape and visual quality in the Study Area so as to evaluate the landscape

and visual impacts of the Project;

• To propose mitigation measures to minimise pollution, environmental disturbance and

nuisance during construction and operation of the project;

• To identify, predict and evaluate the residual (that is, after practicable mitigation)

environmental impacts and cumulative effects expected to arise during the construction

and operation phases of the Project in relation to the sensitive receivers and potential

affected uses;

• To identify, assess and specify methods, measures and standards, to be included in the

detailed design, construction and operation of the project which are necessary to mitigate

these impacts and reduce them to allowable levels within established standards /

guidelines;

• To investigate the extent of side-effects of mitigation measures that may lead to other

forms of impacts;

• To identify constraints associated with the mitigation measures recommended in this

EIA;

• To identify any additional studies necessary to fulfil the objectives to the requirements of

this EIA Study.

1.8 STRUCTURE OF EIA REPORT

The generic structure of the EIA report, as per the guideline provided by MoEF& CC is

illustrated in the following tabulated format.



TABLE NO.: 1.8

STRUCTURE OF EIA REPORT

Sr. No. EIA Structure Contents

1. Introduction • Purpose of the report and regulatory frame work

• Identification of the project and project proponent

• Key Information of project

• Regulatory Frame work

• Scope & Objective of EIA study

• Structure of EIA report

• Terms of reference & Its Compliance

2. Project Description • Condensed description of those aspects of the project

(based on project feasibility study), likely to cause

environmental effects. Description contains the details of

the following:

• Type of project

• Need for the project

• Location details showing general location, specific

location, project boundary & project site layout)

• Technology and process description

• Project description. Including drawings showing project

layout, components of project etc. Schematic

representations of the feasibility drawings which give

information important for EIA purpose

• Description of mitigation measures incorporated into the

project to meet environmental standards,

3. Description of the

Environment

• Study area, period, components & methodology

• Establishment of baseline for valued environmental

components, as identified in the scope

• Base maps of all environmental components

4. Anticipated

Environmental

Impacts &

Mitigation Measures

• Details of Investigated Environmental impacts due to

project location, possible accidents, project design, project

construction, regular operations, final decommissioning or

rehabilitation of a completed project

• Measures for minimizing and / or offsetting adverse

impacts identified

• Irreversible and Irretrievable commitments of

environmental components

• Assessment of significance of impacts (Criteria for

determining significance, Assigning significance)

• Mitigation measures



Sr. No. EIA Structure Contents

5. Analysis of

alternatives

(technology & site)

• Need for alternatives with respect to technology and site

selection, give details of each alternative, summary of

adverse impact of each alternative and propose mitigation

measures for each alternative.

6. Environmental

Monitoring Program

• Technical aspects of environmental monitoring for the

effectiveness of mitigation measures (incl. Measurement

methodologies, frequency, location, data analysis,

reporting schedules, emergency procedures, budget &

procurement schedules)

7. Additional Study: Risk

Assessment &

Disaster Management

Plan

• Hazard Identification

• Risk Assessment & control/prevention Measures

• Disaster Management

8. Project Benefits • Detail of the Socioeconomic & other tangible benefits of

the project

9. Environmental Cost

Benefit Analysis

• Environmental cost benefit analysis to be carried out if

required.

10. Environment

Management Plan

• Description of the administrative aspects of ensuring

that mitigation measures are implemented and their

effectiveness monitored, after approval of the EIA. The

Chapter consist of:

• Mitigation measures for impacts

• Pollution Prevention Plan

• Greenbelt Development Plan

• Mangrove Management Plan

• Dredging management Plan

• Waste management plan

• Environment Management Cell

• Budgetary Provisions for EMS

11. Summary &

Conclusion

• Description of brief of EIA report

12. Disclosure of

Consultant Engaged

• Detail of the EIA Consultant



1.9 COMPLIANCE OF STANDARD AND SPECIFIC TERMS OF REFERENCE

(TOR) IN RESPECT OF INDUSTRY SECTOR.

As per TOR letter issued by the MoEF-CC, Delhi as received vide ref no. IA-J-11011/320/2018-

IA-II (I) dated: - 14th December 2018, has been duly addressed. The copy of TOR is attached as

Annexure-I. Point wise summary of compliance is given below table.

TABLE NO.: 1.9

STANDARD AND SPECIFIC TOR IN RESPECT OF INDUSTRY SECTOR

Sr.

No.

TOR Points Compliance

(Reference in EIA report)

1. Executive Summary Details are covered in Chapter 11 of the

EIA Report.

2. Introduction

i Details of the EIA Consultant including

NABET accreditation

M/s. Jyoti Om Chemical Research Centre

Pvt. Limited, Ankleshwar. Details as

covered in Chapter 12 of the EIA Report.

High court stay order is attached as

Annexure XVII.

ii. Information about the project proponent Details are covered in chapter 1, section

1.3, pg. no. 4 of the EIA Report.

iii. Importance and benefits of the project Details are covered in chapter 1 under

section 1.4.1, pg. no. 5 of the EIA Report.

3. Project Description

i Cost of project and time of completion Details are covered in chapter 1 under

section 1.4.3; Table no.: 1.3 & 1.4; pg.

no. 6 of the EIA Report.

ii Products with capacities for the

proposed project.

Details are covered in chapter 1 under

section 1.2; Table No.:1.1; pg. no. 2 to 4

of the EIA Report.

iii. If expansion project, details of existing

products with capacities and whether

adequate land is available for expansion,

reference of earlier EC if any

Not Applicable,

Project is new & applying for EC, first

time.

iv. List of raw materials required and their � List of product wise raw materials are



Sr.

No.



source along with mode of

transportation.

covered in chapter-2 under section

2.3, table no 2.1 from page no. 30 to

37 of the EIA Report.

� Detail of source along with mode of

transportation is covered in chapter 2

under section 2.3.4 from page no 52 to


v. Other chemicals and materials required

with quantities and storage capacities.


section 2.3.3, table 2.5 pg. no. 48 of the

EIA Report.

vi. Details of Emission, effluents, hazardous

waste generation and their management.

� Details of Emission are covered in

chapter 2 under section 2.10; table no.:

2.22 & 2.23, pg. no. 113.

� Details of effluents are covered in

chapter 2 under section 2.8.1; table

no.: 2.15, pg. no. 103 to 107.

� Details of hazardous waste generation

& their management are covered in

chapter 2 under section 2.11, table

2.24, pg. 116 to 117 of the EIA

Report.

vii. Requirement of water, power, with

source of supply, status of approval,

water balance diagram, man-power

requirement (regular and contract).

� Details of water requirement are

covered in chapter 2 under section

2.7, pg. no. 102.

� Details of power and its source are

covered under section 2.6.2, table 2.9,

pg. no. 97 to 98.

� Status of approval – CGWA

application is made, attached as

Annexure VII.

� Water balance diagram in Fig 2.2 pg.



Sr.

No.



no. 103.

� Manpower details covered under

section 2.6.5, table 2.13, pg. no. 101.

viii. Process description along with major

equipments and machineries, process

flow sheet (quantities) from raw material

to products to be provided

� Details for Process description are


2.4, pg. no. 56 to 92.

� Details of major equipments and

machineries are covered in chapter 2

under section 2.6.3, table 2.11 pg. no.

98 to 100 of the EIA Report.

ix.

Hazard identification and details of

proposed safety systems.

� Details are covered in chapter 7, Risk

Assessment, of the EIA Report.

� Details of proposed safety system is


6.4.4 from page no 187 to 189 of the

EIA Report.

x. Expansion/modernization proposals:

a. Copy of all the Environmental

Clearance(s) including Amendments

thereto obtained for the project from

MOEF/SEIAA shall be attached as an

Annexure. A certified copy of the latest

Monitoring Report of the Regional

Office of the Ministry of Environment

and Forests as per circular dated 30th

May, 2012 on the status of compliance

of conditions stipulated in all the

existing environmental clearances

including Amendments shall be

provided. In addition, status of

compliance of Consent to Operate for

the ongoing existing operation of the

project from SPCB shall be attached

with the EIA-EMP report.

Not Applicable. This is the first EC

Application.

b. In case the existing project has not

obtained environmental clearance,

Not Applicable,

Project is new & applying for EC, first



Sr.

No.



reasons for not taking EC under the

provisions of the EIA Notification 1994

and/or EIA Notification 2006 shall be

provided. Copies of Consent to

Establish/No Objection Certificate and

Consent to Operate (in case of units

operating prior to EIA Notification

2006, CTE and CTO of FY 2005-2006)

obtained from the SPCB shall be

submitted. Further, compliance report to

the conditions of consents from the

SPCB shall be submitted.

time.

4. Site Details

i. Location of the project site covering

village, Taluka/ Tehsil, District and

State, Justification for selecting the site,

whether other sites were considered.

� Project site location details are


1.4.4 & 1.5, pg. no.7 to 11 of the EIA

report.

� Justification for selecting site is


1.4.4 pg. no.7 of the EIA report.

ii. A toposheet of the study area of radius

of 10km and site location on

1:50,000/1:25,000 scale on an A3/A2

sheet. (including all eco-sensitive areas

and environmentally sensitive places)

Toposheet of the study area of radius of

10 km and site location on 1:50,000 scale

is attached as Annexure-V of the EIA

report.

iii. Details w.r.t. option analysis for

selection of site.


section 5.2 pg. no. 183 to 184 of the EIA

Report.

iv. Co-ordinates (lat-long) of all four

corners of the site.

Details are covered in chapter 1, under

section 1.4.5, table 1.5 pg. no. 7 of the

EIA Report.

v. Google map-Earth downloaded of the

project site.


section 1.4.5, Figure 1.1, 1.2 & 1.3 pg. no.

8 to10 of the EIA Report.

vi.

Layout maps indicating existing unit as

well as proposed unit indicating storage

area, plant area, greenbelt area, utilities

etc. If located within an Industrial

area/Estate/Complex, layout of

Industrial Area indicating location of

unit within the Industrial area/Estate.

This project is new project.

Layout is attached as Annexure-IV of the

EIA report.



Sr.

No.



vii.

Photographs of the proposed and

existing (if applicable) plant site. If

existing, show photographs of

plantation/greenbelt, in particular.

Photographs of proposed site are attached

as Annexure XIV-B of the EIA report.

viii. Landuse break-up of total land of the

project site (identified and acquired),

Government/private - agricultural,

forest, wasteland, water bodies,

settlements, etc shall be included. (not

required for industrial area)


section 3.7, pg. no. 137 to 138 of the EIA

Report.

ix. A list of major industries with name and

type within study area shall be

incorporated. Land use details of the

study area

Details are covered in chapter 3, table 3.1

pg. no. 69 of the EIA Report.

x. Geological features and Geo-

hydrological status of the study area

shall be included.


section 3.8.1 to 3.8.4, pg. no. 139 to 142

of the EIA Report.

xi. Details of Drainage of the project upto

5km radius of study area. If the site is

within 1 km radius of any major river,

peak and lean season river discharge as

well as flood occurrence frequency

based on peak rainfall data of the past 30

years.

Details of Flood Level of the project site

and maximum Flood Level of the river

shall also be provided. (mega green field

projects)

Not applicable.

xii. Status of acquisition of land. If

acquisition is not complete, stage of the

acquisition process and expected time of

complete possession of the land.

Land is already allocated as private non-

agricultural land. Land documents (NA

letter) is attached as Annexure-III.

xiii. R&R details in respect of land in line

with state Government policy.

Not applicable.

5. Forest and wildlife related issues (if applicable):

i. Permission and approval for the use of

forest land (forestry clearance), if any,

and recommendations of the State Forest

Department. (if applicable)

Not applicable.

Our site is on private land which is

allocated as non-agricultural land.

ii. Landuse map based on High resolution

satellite imagery (GPS) of the proposed

Not applicable.




Sr.

No.



site delineating the forestland (in case of

projects involving forest land more than

40 ha)


iii. Status of Application submitted for

obtaining the stage I forestry clearance

along with latest status shall be

submitted.

Not applicable.



iv. The projects to be located within 10 km

of the National Parks, Sanctuaries,

Biosphere Reserves, Migratory

Corridors of Wild Animals, the project

proponent shall submit the map duly

authenticated by Chief Wildlife Warden

showing these features vis-à-vis the

project location and there

commendations or comments of the

Chief Wildlife Warden-thereon

Not applicable.



v. Wildlife Conservation Plan duly

authenticated by the Chief Wildlife

Warden of the State Government for

conservation of Schedule I fauna, if any

exists in the study area.

Not applicable.



vi. Copy of application submitted for

clearance under the Wildlife (Protection)

Act, 1972, to the Standing Committee of

the National Board for Wildlife.

Not applicable.



6. Environmental Status

i. Determination of atmospheric inversion

level at the project site and site-specific

micro-meteorological data using

temperature, relative humidity, hourly

wind speed and direction and rainfall.



Report.

ii. AAQ data (except monsoon) at 8

locations for PM10, PM2.5, SO2, NOX,

CO and other parameters relevant to the

project shall be collected. The

monitoring stations shall be based CPCB

guidelines and take into account the pre-

dominant wind direction, population

zone and sensitive receptors including

reserved forests.



Report.



Sr.

No.



iii. Raw data of all AAQ measurement for

12 weeks of all stations as per frequency

given in the NAAQM Notification of

Nov. 2009 along with – min., max.,

average and 98% values for each of the

AAQ parameters from data of all AAQ

stations should be provided as an

annexure to the EIA Report.

� Details are covered in chapter 3 under

section 3.3, pg. no. 122 to 126 of the

EIA Report.

� Location wise monitoring details are

attached as Annexure-XIII and

photographs of monitoring are

attached as Annexure-XIV-A of the

EIA Report.

iv. Surface water quality of nearby River

(100m upstream and downstream of

discharge point) and other surface drains

at eight locations as per CPCB/ MoEF&

CC guidelines.


Section 3.4, Table 3.7 & 3.8, pg. no. 130

to 133 of the EIA Report.

v. Whether the site falls near to polluted

stretch of river identified by the

CPCB/MoEF & CC, if yes give details.

No, polluted stretch of river identified by

the CPCB/MoEF & CC.

vi. Ground water monitoring at minimum at

8 locations shall be included.


Section 3.4, Table 3.5 & 3.6, pg. no. 126

to 129 of the EIA Report.

vii. Noise levels monitoring at 8 locations

within the study area.



Report.

viii. Soil Characteristic as per CPCB

guidelines.

Details are covered in chapter 3, section

3.6 pg. no. 135 to 137 of the EIA Report.

ix. Traffic study of the area, type of

vehicles, frequency of vehicles for

transportation of materials, additional

traffic due to proposed project, parking

arrangement etc.


section 3.10 pg. no. 156 of the EIA

Report.

x. Detailed description of flora and fauna

(terrestrial and aquatic) existing in the

study area shall be given with special

reference to rare, endemic and

endangered species. If Schedule-I fauna

are found within the study area, a

Wildlife Conservation Plan shall be

prepared and furnished.


section 3.8.7 & 3.8.8, pg. no. 143 to 148

of the EIA Report.

xi. Socio-economic status of the study area. Details are covered in chapter 3 under

section 3.9, pg. no. 148 to155 of the EIA

Report.



Sr.

No.



7. Impact and Environment Management Plan

i. Assessment of ground level

concentration of pollutants from the

stack emission based on site-specific

meteorological features. In case the

project is located on a hilly terrain, the

AQIP Modeling shall be done using

inputs of the specific terrain

characteristics for determining the

potential impacts of the project on the

AAQ. Cumulative impact of all sources

of emissions (including transportation)

on the AAQ of the area shall be

assessed. Details of the model used and

the input data used for modeling shall

also be provided. The air quality

contours shall be plotted on a location

map showing the location of project site,

habitation nearby, sensitive receptors, if

any.


section 4.2 & 4.3, pg. no. 165 to 182.

ii. Water Quality modeling – in case of

discharge in water body.

Not applicable, as unit will achieve zero

liquid discharge.

iii. Impact of the transport of the raw

materials and end products on the

surrounding environment shall be

assessed and provided. In this regard,

options for transport of raw materials

and finished products and wastes (large

quantities) by rail or rail-cum road

transport or conveyor-cum-rail transport

shall be examined.


section 4.2.6 pg. no. 178 of the EIA

Report.

iv. A note on treatment of wastewater from

different plant operations, extent

recycled and reused for different

purposes shall be included. Complete

scheme of effluent treatment.

Characteristics of untreated and treated

effluent to meet the prescribed standards

of discharge under E(P) Rules.


section 2.8 & 2.9, pg. no. 103 to 111

of the EIA Report.

� Unit will achieve zero liquid

discharge.

� The project proponent, Zero Liquid

Discharge will be ensured and no

waste/treated water will be

discharged outside the premises.

v. Details of stack emission and action plan � Details of stack emission are covered



Sr.

No.



for control of emissions to meet

standards.

in chapter 2 under section 2.10, pg.

no. 113 to 115 of the EIA Report.

� Details action plan for control of

emissions & measures for fugitive

emission control are covered in

chapter 10 under section 10.6.2.1, pg.

no. 334 to 336 of the EIA Report.

vi. Measures for fugitive emission control.

vii. Details of hazardous waste generation

and their storage, utilization and

management. Copies of MOU regarding

utilization of solid and hazardous waste

in cement plant shall also be included.

EMP shall include the concept of waste

minimization, recycle/reuse/recover

techniques, Energy conservation, and

natural resource conservation.

� Details of hazardous waste generation

are covered in chapter 2 under section

2.11 pg. no. 116 to 117 of the EIA

Report.

� Membership certificates of TSDF site

& solid waste are attached as

Annexure- IX & X of the EIA Report.

� Details of EMP of waste

minimization recycle/ reuse/ recover

techniques are covered in chapter 10

under section 10.5.6 pg. no. 329 to


viii. Proper utilization of fly ash shall be

ensured as per Fly Ash Notification,

2009. A detailed plan of action shall be

provided.


section 2.6.2.2, pg. no. 98 of the EIA

Report.

� MOU with Bricks manufacturer is

attached as annexure-X of the EIA

Report.

ix. Action plan for the green belt

development plan in 33 % area i.e. land

with not less than 1,500 trees per ha.

Giving details of species, width of

plantation, planning schedule etc. shall

be included. The green belt shall be

around the project boundary and a

scheme for greening of the roads used

for the project shall also be incorporated.


section 10.6.5, pg. no. 338 to 340 of the

EIA Report.

x. Action plan for rainwater harvesting

measures at plant site shall be submitted

to harvest rainwater from the roof tops

and storm water drains to recharge the

ground water and also to use for the

various activities at the project site to

conserve fresh water and reduce the

� Details of rain water harvesting are


10.7.6, pg. no. 345 to 346.

� Details of water conservation program

are covered in chapter 10 under

section 10.7.2, pg. no. 343 to 344.



Sr.

No.



water requirement from other sources.

xi. Total capital cost and recurring

cost/annum for environmental pollution

control measures shall be included.


section 2.12, pg. no. 117 of the EIA

Report.

xii. Action plan for post-project

environmental monitoring shall be

submitted.


section 6.4.4, pg. no. 187 to 189 of the

EIA Report.

xiii. Onsite and Offsite Disaster (natural and

Man-made) Preparedness and

Emergency Management Plan including

Risk Assessment and damage control.

Disaster management plan should be

linked with District Disaster

Management Plan.


section 7.12 & 7.22, pg. no. 249 to 309 of

the EIA Report.

8. Occupational health

i. Plan and fund allocation to ensure the

occupational health & safety of all

contract and casual workers

� Details of occupational health program


7.8 & 7.9, pg. no. 226 to 243 of the

EIA Report.

� Details of Fund allocation are covered

in chapter 2 under section 2.12, pg.

no. 117 of the EIA Report.

ii. Details of exposure specific health status

evaluation of worker. If the workers’

health is being evaluated by pre

designed format, chest x rays, Audio

metry, Spiro metry, Vision testing (Far

& Near vision, color vision and any

other ocular defect) ECG, during pre-

placement and periodical examinations

give the details of the same. Details

regarding last month analyzed data of

above mentioned parameters as per age,

sex, duration of exposure and

department wise.

� This is a new project.

� Hence, at the time of recruitment, unit

will hire the employees & workers

after doing Pre medical examination

and arrange periodically medical

checkup.



Sr.

No.



iii. Details of existing Occupational &

Safety Hazards. What are the exposure

levels of hazards and whether they are

within Permissible Exposure level

(PEL). If these are not within PEL, what

measures the company has adopted to

keep them within PEL so that health of

the workers can be preserved.

Not applicable. This is a new project.

iv. Annual report of health status of workers

with special reference to Occupational

Health and Safety.

� Not applicable. This is a new project.

� Hence, at the time of recruitment, unit

will hire the employees & workers

after doing Pre medical examination

and arrange periodically medical

checkup.

9. Corporate Environment Policy

i. Does the company have a well laid

down Environment Policy approved by

its Board of Directors? If so, it may be

detailed in the EIA report.

The copy of safety policy attached as

Annexure- XII.

ii. Does the Environment Policy prescribe

for standard operating process /

procedures to bring into focus any

infringement / deviation / violation of

the environmental or forest norms /

conditions? If so, it may be detailed in

the EIA.

The copy of safety policy attached as

Annexure- XII.

iii. What is the hierarchical system or

Administrative order of the company to

deal with the environmental issues and

for ensuring compliance with the

environmental clearance conditions?



Report.



Sr.

No.



Details of this system may be given.

iv. Does the company have system of

reporting of non-compliances /

violations of environmental norms to the

Board of Directors of the company and /

or shareholders or stakeholders at large?

This reporting mechanism shall be

detailed in the EIA report



Report.

10. Details regarding infrastructure facilities

such as sanitation, fuel, restroom etc. to

be provided to the labour force during

construction as well as to the casual

workers including truck drivers during

operation phase.

Details as given in Chapter 10, section

10.5.7, pg. no. 331 of the EIA Report.

11. Enterprise Social Commitment (ESC)

i. Adequate funds (at least 2.5 % of the

project cost) shall be earmarked towards

the Enterprise Social Commitment based

on Public Hearing issues and item-wise

details along with time bound action

plan shall be included. Socio-economic

development activities need to be

elaborated upon.

� The unit is green field project. So, unit

will fund allocation for the CER

2.23% of capital investment as per

new Office Memorandum - F. No: 22-

65/2017-IA.III, MoEF &CC on Dated:

1st May, 2018.

� The total cost of the proposed project

(Rs.1165 Lakhs) over a period of five

years towards CER activity. So, as per

the proposed project cost Rs. 26 Lakhs

used in the CER activities.

12. Any litigation pending against the

project and/or any direction/order passed

by any Court of Law against the project,

if so, details thereof shall also be

included. Has the unit received any

notice under the Section 5 of

Environment (Protection) Act, 1986 or

� No litigation pending against the

project.

� Not applicable. This is a new project.



Sr.

No.



relevant Sections of Air and Water Acts?

If so, details thereof and

compliance/ATR to the notice(s) and

present status of the case.

13. A tabular chart with index for point wise

compliance of above TORs.

� Instruction followed.

� Incorporated in Chapter 1 under

section 1.9 on page no 16 to 29 of the

EIA Report.

PART- B : SPECIFIC TERMS OF REFERENCE FOR SYNTHETIC ORGANIC

CHEMICALS INDUSTTRY

1.

Details on solvents to be used, measures

for solvent recovery and for emissions

control.


section 2.5, page no 93 to 96 of the EIA

Report.

2.

Details of process emissions from the

proposed unit and its arrangement to

control.

Details of process emissions are covered

in chapter 2 under section 2.10.2, page no

113.

3.

Ambient air quality data should include

VOC, other process-specific pollutants*

like NH3*, chlorine*, HCl*, HBr*,

H2S*, HF*,etc.,(*-as applicable)


section 3.3, page no. 122 to 126 of the

EIA Report.

4. Work zone monitoring arrangements for

hazardous chemicals.

� This is a new project.

� Unit will periodically arrange work

zone monitoring for hazardous

chemicals.

5. Detailed effluent treatment scheme

including segregation of effluent streams

for units adopting 'Zero' liquid

discharge.


section 2.8, page no 108 to 112 of the

EIA Report.

6. Action plan for odour control to be

submitted.

Detail of action plan for odour control is


10.7.4, page no 344 of the EIA Report.

7. A copy of the Memorandum of

Understanding signed with cement

MOU signed with Bricks manufacturers

are attached as Annexure- X.



Sr.

No.



manufacturers indicating clearly that

they co-process organic solid /

hazardous waste generated.

8. Authorization/Membership for the

disposal of liquid effluent in CETP and

solid/hazardous waste in TSDF, if any.

Membership certificate of TSDF is

attached as Annexure- IX.

9. Action plan for utilization of

MEE/dryers salts.


section 10.5.6, page no 329 to 330 of the

EIA Report.

10. Material Safety Data Sheet for all the

Chemicals are being used/will be used.

Material Safety Data Sheet for all the

Chemicals are provided in soft copy.(CD)

11. Authorization/Membership for the

disposal of solid/hazardous waste in

TSDF.

Membership certificate of TSDF is

attached as Annexure- IX.

12. Details of incinerator if to be installed. Not Applicable.

13. Risk assessment for storage and

handling of hazardous chemicals /

solvents. Action plan for handling &

safety system to be incorporated.

� Details of risk assessment for Storage

and handling of hazardous chemical


7.19 to 7.21, page no. 255 to 284.

� Details of action plan for handling &

safety system are covered in chapter 7

under section 7.6, page no. 214 to

224.

14. Arrangements for ensuring health and

safety of workers engaged in handling of

toxic materials.


section 7.9 on page no. 228 to 243.

DRAFT EIA FOR M/S. ISHANGA LIFE SCIENCE PVT. LTD., MADHVAS, DIST: PANCHMAHAL, GUJARAT.

M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 30

CHAPTER – 2

PROJECT DESCRIPTION

2.1 TYPE OF PROJECT


Dist. Panchmahal- 389330, Gujarat. The unit will be engaging in manufacturing of Pharma &

intermediate products. Proposed production capacity will be 193 MT/Month. The proposed

products manufacture by the unit fall in the Schedule attached to the EIA Notification, i.e.

Project No. 5(f), Synthetic Organic Chemicals. As per EIA Notification dated 14th September,

2006, and its amendments thereafter from time to time, the project falls under as Category ‘A’

Project. Environment Clearance will be evaluated by the Industrial committee-2 of MoEF & CC,

New Delhi.

The production capacity of all products is given in Chapter 1, Table 1.1. The list of raw materials

required for each product is provided in Table 2.1.

2.2 NEED FOR THE PROJECT

Any investment decision is done based on techno economic viability of the project. The project

has to be technically feasible and financially viable in nature. The products manufacture by the

unit find application in manufacture of Pharma and intermediates products as well as they find

application as coating material to the tablets. The market for them is ever increasing.

In recent year, market demand for Organic Chemicals (Bulk drugs & Intermediates) has become

increasingly diverse and specialized, meaning that we must be able to offer customers a diverse

range of derivatives techniques. Keeping in mind this trend, demand for Bulk drugs &

Intermediates based products are increasing.

2.3 PRODUCTS AND RAW MATERIAL DETAILS

The list of name of proposed raw materials with consumption quantity in MT/Month for each

product is provided in below Table 2.1.

TABLE NO.: 2.1

LIST OF PRODUCT WISE RAW MATERIALS CONSUMPTION

Products Name and

Quantity Name of Raw materials CAS No.

Quantity

MT/MT MT/Month

5-Nitrofurfural

diacetate

2-furaldehyde diacetate 13529-27-6 2.029 6.09

Pyridine 110-86-1 0.294 0.88

Acetic anhydride 108-24-7 5.882 17.65



Products Name and


Quantity

MT/MT MT/Month

3.00 MT/Month Sulfuric Acid 7664-93-9 2.941 8.82

Nitric acid 7697-37-2 2.941 8.82

Acetic acid 64-19-7 2.059 6.18

Sodium Hydroxide 1310-73-2 0.588 1.76

Total 16.735 50.21

1 amino hydantoin

Hydrochloride

3.0 MT/Month

Hydrazine Hydrate 10217-52-4 1.250 3.75

Urea 57-13-6 1.125 3.38

Acetone 67-64-1 1.05 3.15

2-Propanone semicarbazone 110-20-3 0.813 2.44

Sodium Methoxide 124-41-4 0.375 1.13

Methyl Chloroacetate 96-34-4 0.438 1.31

Propanonesemiaminohydrant

oin

2827-56-7 0.750 2.25

Hcl 7647-01-0 0.188 0.56

Total 5.988 17.96

Phosphoryl choline

chloride, calcium

salt

7.0 MT/Month

Choline Chloride 67-48-1 1.111 7.78

Phosporyl chloride 4826-71-5 1.444 10.11

Calcium Chloride 10043-52-4 0.556 3.89

Calcium Carbonate 1317-65-3 1.111 7.78

Methanol 67-56-1 0.133 0.93

Total 4.356 30.49

Citicoline(CTS)tech

5.0 MT/Month

CytidineMonophospahte

(CMP )

67-63-6 1.429 7.14

Methanol 67-56-1 1.286 6.43

Morpholine 110-91-8 1.143 5.71

DCC (N,N'-

Dicyclohexylcarbodiimide)

538-75-0 1.857 9.29

Phosphorul Choline chloride 4826-71-5 3.571 17.86

MethanolicHcl 7647-01-0 1.429 7.14

IPA 67-63-0 0.643 3.21

Activated Carbon 7440-44-0 0.114 0.57


Ethanol 64-17-5 0.400 2.00

Total 12.014 60.07

2-(4-aminopentyl

(ethyl) amino)

ethanol

10.0 MT/Month

5 Chloro 2 pentanone 5891-21-4 0.909 9.09

Xylene 1330-20-7 0.545 5.45

N-Ethyl ethanol amine 110-73-6 1.136 11.36

Orgno Copper Catalyst 7440-58-8 0.045 0.45

Raney Nickel 12003-78-0 0.364 3.64

Methanol 67-56-1 0.545 5.45

Methanolic Ammonia 1336-21-6 0.909 9.09

Hydrogen Gas 1333-74-0 1.818 18.18

Total 6.273 62.73



Products Name and


Quantity

MT/MT MT/Month

3-Quinuclidinone

10.0 MT/Month

Ethyl Piperidine Carboxylate 1126-09-6 1.429 14.29

Toluene (Fresh) 108-88-3 1.143 11.43

Ethyl Chloro acetate 105-39-5 3.071 30.71

Potassium Tert- Butoxide 865-47-4 1.571 15.71

Hcl Acid solution 7647-01-0 1.429 14.29

Sulfuric Acid 7664-93-9 0.714 7.14

Sodium hydroxide 1310-73-2 1.786 17.86

Chloroform (Fresh) 67-66-3 2.171 21.71

IPA Hcl 70849-64-8 0.043 0.43

Total 13.357 133.57

1-ethyl-3-(3-

dimethylaminoprop

yl) carbodimide.

hydrochloride

15.0 MT/Month

Ethylisothiocynate 542-85-8 0.732 10.98

Chloroform (Fresh) 67-66-3 0.546 8.20

N,N Dimethyl-1,3-Propane

diamine 109-55-7 0.927 13.90

Calcium Carbonate 1317-65-3 0.537 8.05

Potassium Hydroxide 1310-58-3 0.463 6.95

Acetonitrile (Fresh) 75-05-8 0.854 12.80

Hcl (Gas) 7647-01-0 0.244 3.66

Total 4.302 64.54

3-(1-cyanoethyl)

benzoic acid

15.0 MT/Month

Benzoic Acid 65-85-0 1.111 16.67

Formaldehyde 50-00-0 2.000 30.00

Methanol (Fresh) 67-56-1 0.48 7.2

Dichloromethane (Fresh) 75-09-2 0.111 1.67

Aluminium Chloride 7446-70-0 0.778 11.67

Sulfuric Acid 7664-93-9 10.000 150.00

Sodium Cyanide 143-33-9 0.667 10.00

Di Methyl Carbonate 616-38-6 1.667 25.00

Total 16.813 252.2

1-(p-methoxy

benzyl)-1,2,3,4,5,6,

7,8,Octahydro

isoquinaline- S-octa

base

8.0 MT/Month

4-[4-[4-(4-methoxy phenyl)-

1- acetic acid

3399-73-3 1.754 14.04

Cyclohexane Ethylamine 104-01-8 1.754 14.04

Cyclohexynyl ether 78917-92-7 1.316 10.53

Toluene (Fresh) 108-88-3 1.081 8.65

Phosphorus oxychloride 10025-87-3 1.088 8.70

Caustic Flakes 1310-73-2 1.088 8.70

D-Mandalic acid 611-71-2 0.965 7.72

Acetone (Fresh) 67-64-1 0.526 4.21

Total 9.572 76.58

Dextrometharphin

free base

8.0 MT/Month

Ethyl Formate 109-94-4 1.854 14.83

Toluene Fresh 108-88-3 1.420 11.36

HCl 7647-01-0 2.000 16.00

Phosporic acid 7664-38-2 8.780 70.24

Phosporouspentaoxide 1314-56-3 3.805 30.44



Products Name and


Quantity

MT/MT MT/Month

Methanol Fresh 67-56-1 1.073 8.59

C.S flakes 1310-73-2 1.707 13.66

Formaldehyde 50-00-0 0.585 4.68

Total 21.224 169.80

cis-2-(2,4-

Dichlorophenyl)-2-

(1H-1,2,4-triazol-1-

ylmethyl)-1,3-

dioxolan-4-ylmethyl

methane sulphonate

10.0 MT/Month

4-[4-[4-(4-methoxy phenyl)-

1-piperazinyl]phenyl]-3H-

1,2,4-triazol-3-one

74853-07-9 1.667 16.67

Dimethyl sulfoxide 67-68-5 6.667 66.67

2-Bromo butane 78-76-2 1.667 16.67

Potassium hydroxide 1310-58-3 0.889 8.89

Hydrobromic acid 10035-10-6 5.000 50.00

Glacial acetic acid 70384-51-9 10.000 100.00

Sodium carbonate 497-19-8 0.444 4.44

Dimethylformamide 68-12-2 6.889 68.89

Activated carbon 7440-44-0 0.222 2.22

cis-[(2-bromomethyl)-2-(2,4-

dichlorophynyl)-1,3-

dioxolan-4-yl methyl]

benzoate

61397-56-6 2.222 22.22

Toluene Fresh 108-88-3 0.133 1.33

1,2,4-Triazole 288-88-0 0.778 7.78

Potassium carbonate 584-08-7 1.556 15.56


Palladium 5% 7740-05-03 0.111 1.11

MDC Fresh 75-09-2 0.778 7.78

Triethyl amine 121-44-8 0.667 6.67

Methane sulfonyl chloride 124-63-0 0.333 3.33

Ammonia solution 7664-41-7 1.111 11.11

Total 41.80 418.00

cis-2-(2,4-

Dichlorophenyl)-2-

(1H-1,2,4-triazol-1-

ylmethyl)-1,3-

dioxolan-4-ylmethyl

methane sulphonate

(Pure)

8.0 MT/Month

Toluene Fresh 108-88-3 0.800 6.40


Methanol 67-56-1 0.111 0.89

Tetrabutylammonium

bromide 311-28-4 0.11 0.89


Total 1.36 10.84

Morpholine 110-91-8 2.600 26.00

Benzyl chloride 100-44-7 4.000 40.00

C.S lye 1310-73-2. 7.200 72.00

Toluene 108-88-3 0.940 9.40

Pocl3 10025-87-3 5.000 50.00

Pyrrole 109-97-7 11.600 116.00

Megnesium oxide 1309-48-4 3.200 32.00



Products Name and


Quantity

MT/MT MT/Month

Phenyl (1h pyrrole-

2-yl)methanone –

tricarboxylate

(Crude)

10.0 MT/Month

Dimethyl Malenate 108-59-8 6.400 64.00

Ethyl chloroformate 541-41-3 5.200 52.00

Sulpuric acid 7664-93-9 4.000 40.00

Megnesium acetate 142-72-3 3.320 33.20

Actic anhydride 108-24-7 6.060 60.60

Glacial acetic acid 64-19-7 1.800 18.00

Ethyl acetate 141-78-6 1.464 14.64

EDC 25952-53-8 16.000 160.00


TBAB 1643-19-2 0.200 2.00


Total 83.18 831.84

(-)-1-[(4-Chloro

phenyl)phenylmethy

l]-4-[(4-methyl

phenyl)sulfonyl]

piperazine

6.0 MT/Month

Parachlorobenzophenon 134-85-0 2.778 16.67

Ammonia formate 540-69-2 4.444 26.67

Toluene 108-88-3 1.178 7.07

CS flakes 1310-73-2 5.067 30.40

MDC 75-09-2 1.144 6.87

HCl 75-09-2 3.222 19.33

L+tartaric acid 526-83-0 1.967 11.80

Methanol 67-56-1 1.133 6.80

Bis 2 chloro ethylene

hydrochloride

821-48-7 1.211 7.27

PTSC 98-59-9 1.000 6.00

Soda ash 497-19-9 0.894 5.37

Diiso propyl ethyl amine 36340-89-3 1.556 9.33

Hydrobromic acid 10035-10-6 0.604 3.63

Hydrobenzoic acid 99-96-7 1.000 6.00

Hyflow 61790-53-2 0.222 1.33

Carbon 7440-44-0 0.111 0.67

Total 27.53 165.19

p-Chlorobenz

hydryl piperazine

6.0 MT/Month

2-chloro ethanol 107-07-3 0.369 2.21

Triethyl amine 121-44-8 0.531 3.19

Toluene Fresh 108-88-3 0.538 3.23

DMF 68-12-2 2.688 16.13

CS flakes 1310-73-2 0.538 3.23

MDC (Fresh) 75-09-2 1.035 6.21

Sodium mono chloro acetate 3926-62-3 0.563 3.38

Acetone Fresh 67-64-1 0.963 5.78

HCl 7647-01-0 0.750 4.50

Total 7.975 47.84


2,3 pyrridnedicarboxylic acid 89-00-9 5.000 25.00

Acedic anhydride 108-24-7 22.500 112.50

Benzyl amine 100-46-9 6.825 34.13

Methanol 67-56-1 0.900 4.50



Products Name and


Quantity

MT/MT MT/Month

carboxylate Hydrate

Chloro compound

5.0 MT/Month

Toluene 108-88-3 1.775 8.88

Palladium Carbon 7740-05-03 0.300 1.50

Nitrogen gas 7727-37-9 1.750 8.75

Ethyl acetate 141-78-6 0.425 2.13

D-tartaric acid 147-71-7 1.000 5.00

THF 109-99-9 15.000 75.00

Aluminum Chloride 7446-70-0 3.000 15.00

Total 58.48 292.38

3,4-dimethoxy-2-

chloro methyl

pyridine

10.0 MT/Month

Maltol 118-71-8 1.000 10.00

Potassium carbonate 584-08-7. 1.100 11.00

Acetone 67-64-1 0.630 6.30

Dimethyl sulphide 75-18-3 1.000 10.00

Liquor Ammonia 1336-21-6 2.300 23.00

Chloroform 67-66-3 0.160 1.60

Phosphorous Oxychloride 10025-87-3 1.300 13.00


MDC 75-09-2 4.100 41.00

Acetic acid 64-19-7. 1.200 12.00

Hydrogen peroxide 7722-84-1 1.000 10.00

Sodium tungaste 13472-45-2 0.030 0.30


Methanol 67-56-1. 0.800 8.00

Sodium sulpahte 7757-82-6. 0.250 2.50


Soda ash 497-19-8 0.500 5.00

Thionyl chloride 7719-09-7 0.800 8.00

Total 21.92 219.20

PentaprozoleSulphi

de

10.0 MT/Month

Maltol 118-71-8 1.429 14.29


Acetone 67-64-1 0.900 9.00

Dimethyl sulphide 75-18-3 1.429 14.29

Liquor Ammonia 1336-21-6 3.286 32.86

Chloroform 67-66-3 0.229 2.29

Phosphorous Oxychloride 10025-87-3 1.857 18.57


MDC 75-09-2 1.486 14.86

Acetic acid 64-19-7 2.429 24.29

Hydrogen peroxide 7722-84-1 1.357 13.57

Sodium tungaste 13472-45-2 0.043 0.43


Methanol 67-56-1 0.486 4.86

Sodium sulpahte 7757-82-6 0.357 3.57


Soda ash 497-19-8 0.714 7.14



Products Name and


Quantity

MT/MT MT/Month

Thionyl chloride 7719-09-7 1.143 11.43

5-(Difluoromethoxy)-2-

mercaptobenzimidazole

97963-62-7 1.443 14.43

Total 28.23 282.29

Preparation of

Pregabalin

(Racemic)

8.0 MT/Month

Isovelaraldehyde 590-86-3 4.500 36.00

Ethyl Cyano acetate 105-56-6 6.100 48.80

Di ethyl Malonate 105-53-3 15.900 127.20

Di n Propyl amine 142-84-7 0.574 4.59

HCl CP 7647-01-0 42.900 343.20


Liquor Ammonia 1336-21-6 14.200 113.60

N- Hexane Fresh 110-54-3.. 0.400 3.20

Toluene Fresh 108-88-3. 1.100 8.80

Chloroform Fresh 67-66-3 4.560 36.48

R-(+) ∞ Phenyl ethyl amine 3886-69-9. 2.475 19.80

Methanol 67-56-1. 0.160 1.28

NaoH flakes 1310-73-2 2.000 16.00

Bromine 7726-95-6 1.320 10.56

MDC 75-09-2 0.480 3.84

IPA 67-63-0 0.270 2.16

Total 102.865 822.92

11-Piperazinyl-

dibenzo(b,f) (1,4)-

thiazepine

hydrochloride

8.0 MT/Month

2-Aminodiphenyl suphide: 1134-94-7 0.625 5.00

Phenychoroformate: 1885-14-9 0.625 5.00

Sodium bi carbonate 144-55-8 0.375 3.00

n- Heptane Fresh 142-82-5 0.113 0.90

Toluene Fresh 08-88-3. 0.500 4.00

Sodium suphate 7757-82-6 0.875 7.00

Hcl 7647-01-0 4.750 38.00

Poly phosphoric acid 8017-16-1 3.125 25.00

Acetone Fresh 67-64-1 0.275 2.20

POCl3 10025-87-3 4.125 33.00

N, N-Dimethylaniline 121-69-7 0.250 2.00

Piperazine 110-85-0 0.750 6.00

IPA 67-63-0 0.045 0.36

Total 16.433 131.46

11-[4-[2-(2-Hydroxy

ethoxy) ethyl]-1-

piperazinyl] dibenzo

(b, f) (1,4) thiazepine

hemifumarate

8.0 MT/Month

Sodium carbonate 497-19-8 0.500 4.00

Toluene 108-88-3 0.600 4.80

Methanol 67-56-1 0.190 1.52

N-methypyrroidinone 872-50-4 1.400 11.20

2-Choroethoxy ethanol 628-89-7 0.700 5.60

Fumaric acid 110-17-8 0.400 3.20

Sodium Iodide 7681-82-5 0.100 0.80

Total 3.890 31.12

2,3-Dimethyl-4-nitropyridine 37699-43-7 0.909 9.09



Products Name and


Quantity

MT/MT MT/Month

2-[[(4-(3-methoxy

propoxy)-3-methyl-

2-pyridinyl)methyl]

thio]-1H

benzimidazole

10.0 MT/Month

N-oxide

Iso Propyl alcohol 67-63-0 0.364 3.64

Iso Propyl HCL 51639-49-7 0.109 1.09

3-Methoxy Propanol 1589-49-7 0.636 6.36

Methylene Di Chloride Fresh 75-09-2 0.164 1.64


TBAB 1643-19-2 0.000 0.00

Sodium sulphate 7757-82-6 0.455 4.55

Toluene Fresh 108-88-3. 0.291 2.91

Acetone Fresh 67-64-1 0.073 0.73

Sulfuric Acid 7664-93-9 1.091 10.91

Carbon 7440-44-0 0.182 1.82

Hcl 7647-01-0 2.182 21.82

Thionyl Chloride 7719-09-7 0.545 5.45

2-mercapto benzimidazole 583-39-1 1.091 10.91

Total 9.727 97.27

2-[[[4-(3-methoxy

propoxy)-3-methyl-

2-pyridinyl] methyl]

sulfinyl] -1H-

benzimidazole

10.0 MT/Month

Sodium Hypochorite 7681-52-9 7.778 77.78

MDC Fresh 75-09-2 0.400 4.00

Acetonitrile Fresh 75-05-8 0.222 2.22

Triethyamine 121-44-8 0.111 1.11


IPE 108-20-3 0.333 3.33

Ammonium Suphate 7783-20-2 0.889 8.89

Sodium Suphate 7757-82-6 0.222 2.22

Total 10.067 100.67

2.3.1 PRODUCT STORAGE &HANDLING

The monthly production quantity is given in Table 2.2. Products will be stored in Fibre Drums,

HDPE Bags, Carboys & Cans. They will be odourless and not volatile. The quality of products will

be checked properly and stored in the close shed with due consideration of compatibility of

chemicals.

The storage area are designed in such a way that the floor level is 150 mm above the maximum

floor level with 2.5 mm thickness of HDPE geo membrane and two layers of RCC in storage is

proposed.

Details of Products Storage and handling are given in Table 2.2.



TABLE NO.: 2.2

DETAILS OF PRODUCT STORAGE

Sr.

No Name of products State Storage

Max storage

capacity at

site (MT)

MOC

1. 5-Nitrofurfural diacetate solid Intermediate

storage area 1.0

25 Kg Fibre

Drum

2. 1 amino hydantoin solid Intermediate

storage area 1.0

25 Kg Fibre

Drum

3. Phosphoryl choline

chloride, calcium salt solid

Intermediate

storage area 1.5

25 Kg HDPE

bags

4. Citicoline (CTS) tech solid Intermediate

storage area 1.0

25 Kg HDPE

bags

5. 2-(4-Aminopentyl (ethyl)

amino) ethanol Liquid

Intermediate

storage area 0.6

50Kg

HDPEcarboy

6. 3-Quinuclidinone solid Intermediate

storage area 0.6

50 Kg HDPE

bags

7.

1-Ethyl-3-(3-Dimethyl

aminopropyl) Carbodimide

Hydrochloride

solid Intermediate

storage area 0.6

50 Kg HDPE

bags

8. 3-(1-Cyanoethyl) Benzoic

Acid solid

Intermediate

storage area 0.6

50 Kg HDPE

bags

9.

1-(p-methoxy benzyl)-

1,2,3,4,5,6,7,8,Octahydro

isoquinaline- S-octa base

Liquid Intermediate

storage area 1.6 50 Kg HDPE Can

10. Dextrometharphin free base Liquid Intermediate

storage area 1.6 50 Kg HDPE Can

11.

Cis-2-(2,4-Dichloro phenyl)

-2-(1H-1,2,4-triazol-1-yl-

methyl)-1,3- dioxolan-4-yl

methyl methane sulfonate

solid Intermediate

storage area 1.5

50 Kg HDPE

bags

12.

cis-2-(2,4-Dichloro phenyl)-


methyl)-1,3-dioxolan-4-yl

methyl methane sulfonate -

Crude

solid Intermediate

storage area 1.6

50 Kg HDPE

bags

13.

Phenyl (1h pyrrole-

2yl)methanone –

tricarboxylate crude

solid Intermediate

storage area 1.5

50 Kg HDPE

bags

14.

(-)-1-[(4-Chlorophenyl)

phenylmethyl]-4-[(4-methyl

phenyl) sulfonyl] piperazine

solid Intermediate

storage area 1.2

50 Kg HDPE

bags

15. p-Chloro benzhydryl

piperazine solid

Intermediate

storage area 1.2

50 Kg HDPE

bags



Sr.

No Name of products State Storage

Max storage

capacity at

site (MT)

MOC

16. 2,3 pyrridineBenzyle


compound

solid Intermediate

storage area 1.0

50 Kg HDPE

bags

17. 3,4-dimethoxy-2-chloro

methyl pyridine solid

Intermediate

storage area 1.5

50 Kg HDPE

bags

18. Pentaprozole sulphide solid Intermediate

storage area 1.5

50 Kg HDPE

bags

19. Pregabalin (Racemic) solid Intermediate

storage area 1.2

50 Kg HDPE

bags

20. 11-Piperazinyl-dibenzo(b,f)

(1,4)-thiazepine

hydrochloride

solid Intermediate

storage area 1.2

50 Kg HDPE

bags

21.

11-[4-[2-(2-Hydroxyethoxy)

ethyl]-1-piperazinyl]

dibenzo (b, f) (1, 4)

thiazepine hemifumarate

solid Intermediate

storage area 1.2

50 Kg HDPE

bags

22.

2-[(4-(3-methoxypropoxy)

-3-methyl- 2-pyridinyl)

methyl]thio]-1H

benzimidazole

solid Intermediate

storage area 1.5

50 Kg HDPE

bags

23.

2-[4-(3-methoxypropoxy)-

3-methyl-2 pyridinyl]

methyl]sulfinyl]-1H-

benzimidazole

solid Intermediate

storage area 1.5 50Kg HDPE bags

Note: At a time, not more than 6 to 8 products will be manufactured. Products will be

manufactured on campaign basis.

2.3.2 RAW MATERIAL STORAGE AND HANDLING

The raw materials with monthly consumption quantity are given in Table 2.3. Raw materials will

be stored in Fibre drums, HDPE bags/ Carboys/ Cans, MS Barrels, Plastic bags and Tank. The

quality of raw materials will be checked properly and stored in the closed shed, storage area as

per characteristic of raw materials.

The storage area are designed in such a way that the floor level is 150 mm above the maximum

flood level with 2.5 mm thickness of HDPE geo membrane and two layers of RCC in storage is

proposed.

Hazardous flammable substances are separately stored in (solvent) storage shed within premises.

Chemicals like Iso propyl alcohol, Liquor Ammonia, Methanoletc will be stored in drums with



all precautionary process instrumentation and safety appliances. Close handling system for

chemicals are provided. Flame arrester cum breather valve and flame proof fittings will be

provided. Solvent transfer will be done by pumps. Reactor and solvent handling pumps will have

mechanical seal with flame proof electrical fitting. The solvent storage area will be restricted for

unauthorized persons. Proper earthing will be provided in all electrical equipment whenever

solvent handling will be done. Also Jumpers & Flange guards will be provided in piping. Flame

arresters will be provided on tank farm and the solvent transfer through pumps.

Unit will following the rules and guidelines under Manufacture, Storage and Import of

Hazardous Chemicals (MSIHC) Rules, 1989 as amended time to time. All transportation of

Hazardous Chemicals shall be as per the Motor Vehicle Act (MVA), 1989.

Details of quantity of Raw Material Storage are given in Table 2.3.



TABLE NO.: 2.3

DETAILS OF RAW MATERIAL STORAGE

Name of Raw Materials Quantity

(MT/M) State Storage Area

Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

1,2,4-Triazole 7.00 Solid RCC - Ventilated Storage Area 50 Kg 1.4 HDPE Carboy

2,3 pyrridnedicarboxylic acid 6.40 Solid RCC - Ventilated Storage Area 50 Kg 1.2 Fibre Drum

2,3-Dimethyl-4-nitropyridine N-

oxide 8.40 Solid RCC - Ventilated Storage Area 50 Kg 1.6 HDPE Carboy

2-Aminodiphenyl suphide 4.70 Solid RCC - Ventilated Storage Area 25 Kg 1 Fibre Drum

2-Bromo butane 11.10 Liquid RCC - Ventilated Storage Area 35 Kg 0.21 HDPE Canester

2-chloro ethanol 2.60 Liquid RCC - Ventilated Storage Area 50 Kg 0.5 HDPE Canester

2-Choroethoxy ethanol 6.79 Liquid RCC - Ventilated Storage Area 200 Kg 2 HDPE Drum

2-furaldehyde diacetate 61.20 Solid RCC - Ventilated Storage Area 25 Kg 10 Fibre Drum

2-mercapto benzimidazole 11.40 Solid RCC - Ventilated Storage Area 50 Kg 2 Fibre Drum

2-Propanone semicarbazone 4.10 Solid RCC - Ventilated Storage Area 50 Kg 0.8 Fibre Drum/HDPE

carboy

3-Methoxy Propanol 5.46 Liquid RCC - Ventilated Storage Area 200 Kg 4 MS Barrel

4-[4-[4-(4-methoxy phenyl)-1-

acetic acid 7.00 Solid RCC - Ventilated Storage Area 50 Kg 1.4 HDPE Carboy


piperazinyl]phenyl]-3H-1,2,4-

triazol-3-one

11.10 Solid RCC - Ventilated Storage Area 50 Kg 2.0 HDPE Carboy

5 Chloro 2 pentanone 18.20 Liquid RCC - Ventilated Storage Area 200 Kg 3.6 HDPE Barrel





Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

5-(Difluoromethoxy)-2-mercapto

benzimidazole 10.91 Solid RCC - Ventilated Storage Area 50 Kg 1.9 Fibre Drum

Acetic anhydride 293.73 Liquid Acid Storage area 50 Kg 4 HDPE Carboy

Acetic acid 45.11 Liquid Acid Storage area 30 Kg 4.2 HDPE Carboy

Acetone 88 Liquid Tank Farm Area 20 KL 10 Tank

Aceto nitrile 185.15 Liquid Solvent Storage Area 150 Kg 9 MS Barrel

Carbon 12.71 Solid Carbon room 25 Kg 0.10 Plastic Bag

Aluminium Chloride 28.81 Solid RCC - Ventilated Storage Area 25 Kg 0.200 Plastic Bag

Ammonia solution 11.11 Liquid RCC - Ventilated Storage Area 50 Lt 1.1 HDPE Can

Ammonium Sulphate 8.89 Solid RCC - Ventilated Storage Area 50 Kg 1.9 Plastic Bag

Benzoic Acid 16.67 Solid RCC - Ventilated Storage Area 50 Kg 3 Plastic Bag

Benzyl amine 39 Liquid RCC - Ventilated Storage Area 35 Kg 0.77 HDPE Canester

Benzyl chloride 44.44 Liquid RCC - Ventilated Storage Area 220 Kg 1.76 HDPE Barrel

Bis 2 chloro ethylene hydrochloride 7.69 Solid RCC - Ventilated Storage Area 50 Kg 1.4 Fibre Drum

Bromine 8.12 Liquid Acid Storage area

Pack of six

3 Kg glass

bottle in

wooden

case

0.51 Glass bottle in

wooden case

CS flakes 217.61 Solid RCC - Ventilated Storage Area 50 Kg 3.6 HDPE Bags

Calcium Carbonate 15.83 Solid RCC - Ventilated Storage Area 50 Kg 2.2 HDPE Bags

Calcium Chloride 3.89 Solid RCC - Ventilated Storage Area 50 Kg 1.00 HDPE Bags

Chloroform 472.61 Liquid Solvent Storage Area 275 Kg 5.5 HDPE Barrel





Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

Choline Chloride 7.78 Solid RCC - Ventilated Storage Area 25 Kg 1.4 HDPE Carboy


dichlorophynyl)-1,3-dioxolan-4-yl

methyl] benzoate

22.22 Solid RCC - Ventilated Storage Area 2.5 Kg 4.0 HDPE bag

Cyclohexynyl ether 10.53 Liquid RCC - Ventilated Storage Area 180 Kg 0.9 MS Barrel

Cyclohexane Ethylamine 14.04 Liquid RCC - Ventilated Storage Area 35 Kg 1.4 HDPE Canester

CytidineMonophospahte (CMP ) 7.14 Solid RCC - Ventilated Storage Area 50 Kg 1 Fibre Drum

DCC (N,N'-

Dicyclohexylcarbodiimide) 9.29 Solid RCC - Ventilated Storage Area 25 Kg 2.00 HDPE Carboy

Di chloro methane 1.67 Liquid Solvent Storage Area 200 L 1 HDPE Drum

Di ethyl Malonate 97.85 Liquid RCC - Ventilated Storage Area 210 Kg 2.10 MS Barrel

Di Methyl Carbonate 25 Liquid RCC - Ventilated Storage Area 170 Kg 5.1 MS Barrel

Di N Propyl amine 3.53 Liquid RCC - Ventilated Storage Area 50 Kg 2 HDPE Canester

Di iso propyl ethyl amine 9.88 Liquid RCC - Ventilated Storage Area 50 Kg 2 HDPE Barrel

Di methyl Malenate(320L) 71.11 Liquid RCC - Ventilated Storage Area 200 L 2 MS Barrel

Dimethyl sulfoxide 111.11 Liquid RCC - Ventilated Storage Area 200 L 5 MS Barrel

Dimethyl sulphide 24.29 Liquid RCC - Ventilated Storage Area 250 Kg 3 HDPE Barrel

Dimethylformamide (DMF) 84.46 Liquid RCC - Ventilated Storage Area 200 Kg 9 MS/HDPE Barrels

D-Mandalic acid 7.72 Solid RCC - Ventilated Storage Area 25 Kg 1.5 Plastic bags/Fibre

drum

D-tartaric acid 5.71 Solid RCC - Ventilated Storage Area 25 Kg 1 HDPE bags





Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

EDC 177.78 Liquid RCC - Ventilated Storage Area 200 Kg 10.0 HDPE Barrel

Ethanol 50 Liquid Solvent Tank Farm Area 5 KL 5 Tank

Ethyl acetate 161.11 Liquid Solvent Storage Area 210 Kg 10.5 MS/ HDPE Barrel

Ethyl Chloro acetate 30.71 Liquid Solvent Storage Area 200 Kg 10.0 HDPE Drums

Ethyl chloroformate 57.78 Liquid RCC - Ventilated Storage Area 200 L 10.0 MS Barrel

Ethyl Cyano acetate 37.54 Liquid RCC - Ventilated Storage Area 200 Kg 2.0 HDPE Barrel

Ethyl Formate 14.83 Liquid RCC - Ventilated Storage Area 50 Kg 1.5 HDPE Carboy

Ethyl Piperidine Carboxylate 14.29 Liquid RCC - Ventilated Storage Area 200 Kg 2.0 HDPE Drums

Ethyl isothiocynate 10.98 Liquid RCC - Ventilated Storage Area 50 Kg 2.2 HDPE Carboys

Formaldehyde 34.68 Liquid RCC - Ventilated Storage Area 50 Kg 5.0 HDPE Carboys

Fumaric acid 3.2 Solid RCC - Ventilated Storage Area 25 Kg 0.5 Plastic Bag

Glacial acetic acid 120 Liquid Acid Storage area 30 Kg 4.5 HDPE Carboys

HCl 385.3 Liquid Acid Storage area 50 Kg 10.0 HDPE Tank

Hydrazine Hydrate 3.75 Liquid RCC - Ventilated Storage Area 200 Kg 2.0 HDPE Barrel

Hydrobenzoic acid 6.35 Solid RCC - Ventilated Storage Area 25 Kg 1.5 Fibre drum/Woven

Bag

Hydrobromic acid 53.84 Liquid RCC - Ventilated Storage Area 300 Kg 4.5 HDPE Drum

Hydrogen Gas 18.18 Gas Gas Cylinder Shed 60 Kg

Cylinder 0.9 Cylinders

Hydrogen peroxide 23.57 Liquid RCC - Ventilated Storage Area 50 Kg 0.1 HDPE Carboys





Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

Hyflow 1.41 Solid RCC - Ventilated Storage Area 50 Kg 0.3 Paper Bag

IPA Hcl 7.14 Liquid Acid Storage area 50 Lt 0.2 HDPE carboys

IPE 3.33 Liquid RCC - Ventilated Storage Area 200 Kg 1.0 MS Barrel

IPA 120.52 Liquid Solvent Storage Area 10 KL 10 MS Tank

Isovelaraldehyde 27.69 Liquid RCC - Ventilated Storage Area 150 Kg 1.5 HDPE Barrel

L+tartaric acid 12.49 Solid RCC - Ventilated Storage Area 25 Kg 2.0 HDPE Bags

Maltol 24.29 Solid RCC - Ventilated Storage Area 25 Kg 1.4 Plastic Bag

MDC 765.24 Liquid Solvent Storage Area 10KL 10.0 MS Tank

Megnesium acetate 36.89 Solid RCC - Ventilated Storage Area 50 Kg 1.8 HDPE Bags

Megnesium oxide (160Kg) 35.56 Solid RCC - Ventilated Storage Area 50 Kg 1.6 Plastic bag

Methane sulfonyl chloride 3.56 Liquid RCC - Ventilated Storage Area 250 Kg 1.3 HDPE Drums

Methanol 624.04 Liquid Solvent Tank Farm Area 20 KL 20.0 Tank

Methanolic Ammonia 152.33 Liquid RCC - Ventilated Storage Area 150 Kg 4.5 HDPE Barrel

MethanolicHcl 7.14 Liquid Acid Storage area 200 Lt 1.8 HDPE Drum

Methyl Chloroacetate 1.31 Liquid RCC - Ventilated Storage Area 200 Kg 0.6 HDPE Barrel

Morpholine 34.6 Liquid RCC - Ventilated Storage Area 50 Kg/150

Kg 2.0

MS Barrel/HDPE

Carboys

n- Heptane 6.4 Liquid Solvent Storage Area 200 Kg 4.0 MS barrel

N- Hexane 16.62 Liquid Solvent Storage Area 200 Lt 2.0 MS Barrel

N, N-Dimethylaniline 1.88 Liquid RCC - Ventilated Storage Area 200 Kg 0.6 HDPE Barrels

N,N Dimethyl-1,3-Propanediamine 13.9 Liquid RCC - Ventilated Storage Area 150 Kg 15.0 Steel Barrel

N-Ethyl ethanol amine 11.36 Liquid RCC - Ventilated Storage Area 200 Kg 2.0 HDPE Drum





Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

Nitric acid 8.82 Liquid Acid Storage area 50 Kg 0.5 HDPE Carboy

Nitrogen gas 10 Gas Gas Cylinder Shed 60 Kg

Cylinder 0.9 Cylinders

N-methypyrroidinone 11.2 Liquid RCC - Ventilated Storage Area 200 Kg 1.4 HDPE Drum

Orgno Copper Catalyst 0.45 Solid RCC - Ventilated Storage Area 25 Kg 0.15 PP Bags

Palladium Carbon 2.82 Solid RCC - Ventilated Storage Area 25 Kg 0.20 Plastic Bag

Parachlorobenzophenon 17.65 Solid RCC - Ventilated Storage Area 25 Kg 1.00

high pressure

cardboard drum

lined with PE bag

Phenylchoroformate 4.97 Liquid RCC - Ventilated Storage Area 200 Kg 1.00 MS Barrel

Phosphorul Choline chloride 27.97 Solid RCC - Ventilated Storage Area 25 Kg 2 Fibre Drum

Phosporic acid 70.24 Liquid RCC - Ventilated Storage Area 50 Kg 3.0 HDPE carboys

Phosporouspentaoxide 30.44 Solid RCC - Ventilated Storage Area 100 Kg 3.0 HDPE carboys

Piperazine 5.87 Solid RCC - Ventilated Storage Area 25 Kg 0.8 Plastic bag/Fibre

drum

Phosphorus oxychloride (POCl3) 99.78 Liquid Acid Storage area 250 Kg 1.0 HDPE Carboys

Poly phosphoric acid 26.67 Liquid Acid Storage area 40 Kg 1.2 HDPE Carboys

Potassium carbonate 154.02 Solid RCC - Ventilated Storage Area 50 Kg 1.8 Plastic Bag

Potassium hydroxide 15.28 Solid RCC - Ventilated Storage Area 50 Kg 1.5 Plastic Bags

Potassium Tert- Butoxide 15.71 Solid RCC - Ventilated Storage Area 50 Kg 1.1 HDPE Bags

Propanone semi amino hydrantoin 2.25 Solid RCC - Ventilated Storage Area 25 Kg 1 Fibre Drum





Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

PTSC 6.35 Solid RCC - Ventilated Storage Area 50 Kg 2.0 Fibre Drum

Pyridine 1.76 Liquid RCC - Ventilated Storage Area 200 Kg 0.2 HDPE Barrel

Pyrrole 128.89 Liquid RCC - Ventilated Storage Area 35 Kg 1.05 HDPE Carboys

R-(+) ∞ Phenyl ethyl amine 15.23 Liquid RCC - Ventilated Storage Area 150 Kg 1.5 HM HDPE Drum

Raney Nickel 3.64 Solid RCC - Ventilated Storage Area 200 Kg 0.4 Barrel

Sodium bi carbonate 2.77 Solid RCC - Ventilated Storage Area 50 Kg 1.0 HDPE Bags

Sodium carbonate 26.71 Solid RCC - Ventilated Storage Area 50 Kg 3.0 HDPE Bags

Sodium Cyanide 10 Solid RCC - Ventilated Storage Area 50 Kg 1.0 MS Drum

Sodium Hypochorite 77.78 Solid RCC - Ventilated Storage Area 50 Kg 2.0 HDPE Carboys

Sodium Iodide 0.8 Solid RCC - Ventilated Storage Area 25 Kg 0.200 Plastic Bag/HDPE

Carboys

Sodium Methoxide 1.13 Solid RCC - Ventilated Storage Area 100 Kg 1.000 MS Drum

Sodium mono chloro acetate 3.38 Solid RCC - Ventilated Storage Area 50 Kg 1.0 Plastic Bag with

liner

Sodium sulpahte 20.31 Solid RCC - Ventilated Storage Area 50 Kg 1.6 Plastic bag

Sodium tungaste 0.73 Solid RCC - Ventilated Storage Area 50 Kg 0.1 HDPE Carboys

Sulfuric Acid 221.31 Liquid Acid Storage area 5KL 10 MS Tank

TBAB 1.78 Solid RCC - Ventilated Storage Area 50 Kg 0.5 HDPE bags

Tetra butyl ammonium bromide 0.94 Solid RCC - Ventilated Storage Area 50 Kg 0.5 HDPE bags

THF 85.71 Liquid Solvent Storage Area 180 Kg 1.8 MS Barrel

Thionyl chloride 24.88 Liquid Solvent Storage Area 250 Kg 2.0 HDPE Drums

Toluene 204.03 Liquid Solvent Tank Farm Area 20 KL 20 Tank





Capacity

of

Bag/Tank

Max storage

capacity at

site (MT)

Storage Mode

with MOC

Triethyl amine 10.63 Liquid RCC - Ventilated Storage Area 200 Kg 0.8 MS Barrels

Urea 3.38 Solid RCC - Ventilated Storage Area 50 Kg 2.0 HDPE Bag

Xylene 9.09 Liquid Solvent Storage Area 180 Kg 6.0 MS Barrel

Note: Production will be carried out on campaign basis. Not more than 50 MT solid raw materials will be stored at a time.

Details of other chemical use in ETP to be stored are given in Table 2.4.

TABLE NO.: 2.4

DETAILS OF OTHER CHEMICAL STORAGE FACILITY

Name of Chemicals State

No. of containers & size

No. of

containers MT

Material of construction

of storage

Lime Solid 300 Bags 15 MT HDPE Bags of 50 Kgs.

Alum Liquid 1 Tank 20 MT HDPE Tank

Poly Electrolyte Liquid 4 carboys 0.2 MT 50 kg carboys

As per the Manufacture, Storage and Import of Hazardous Chemical Rules, 1989 issued by the Ministry of Environment and Forests and

Climate Change (MoEF & CC), Govt. of India, the listed chemicals in table 2.4 are falling in this schedule. However, there storage quantity at a

time being very low, they do not fall under the threshold quantities mentioned in the MSIHC Rules, 1989 and its amendment thereafter.



2.3.3 Physical & Chemical Property / Characteristics of Hazardous Raw Materials:

The Characteristics of hazardous raw materials are as given in Table 2.5.

TABLE NO.: 2.5

CHARACTERISTICS OF HAZARDOUS RAW MATERIALS

Sr.

No

Name of Raw

material

Physic

al State

M.P 0C

B.P 0C

F.P 0C

LEL/UEL

%

TLV

ppm or

mg/m3

LD50mg/kg

LC50mg/l

Sp.

Gravity

(water=1)

Vapour

Density

(air =1)

CAS No.

1. 2-Bromo butane Liquid 112 91 21 2.6-6.6 ---- NA 1.257 4.7 78-76-2

2.

5-(Difluoro

methoxy)-2-mer

captobenzimidaz

ole

solid 243 360.9±

50.0

172.1±

30.1 NA NA NA NA NA 97963-62-7

3. Acetic

anhydride Liquid -73 140 48.9 2.7 - 10.3 10 ppm 630 mg/kg 1.083 3.5 108-24-7

4. Acetic acid Liquid 16.6 118 43-

44.5 5 - 16 25 mg/m3 3310 mg/kg 1.05 2.07 64-19-7

5. Acetone Liquid -94.3 56.2 <-20 2.6 - 12.8 -- 5800 mg/kg 0.792 2 67-64-1

6. Aceto nitrile Liquid -45 81.1 5.5 4.4 - 16 5 mg/m3 400 mg/kg 0.8 1.4 75-05-8

7. Ammonia Liquid -- 100 -- 16 - 25 25 ppm 350 mg/kg 0.88 0.6 7664-41-7

8. Bromine Liquid -7.2 58.78 -- -- 0.7 mg/m3 1700 mg/kg 3.12 5.51 7726-95-6

9. Dimethylforma

mide (DMF) Liquid -61 153 58 2.2 - 15.2 -- >3200 mg/kg 0.94 2.5 68-12-2

10. Ethyl acetate Liquid -83 77 -4.4 2.2 - 11 400 ppm 10170 mg/kg 0.9 3 141-78-6

11. Ethyl

isothiocynate Liquid

−6 °C

(lit.)

130-

132 °C 24 °C --

NA

LD50

of 2000

0.995 g/m

L at 3.01 542-85-8



Sr.

No

Name of Raw

material

Physic

al State

M.P 0C

B.P 0C

F.P 0C

LEL/UEL

%

TLV

ppm or

mg/m3

LD50mg/kg

LC50mg/l

Sp.

Gravity

(water=1)

Vapour

Density

(air =1)

CAS No.

(lit.) mg/kg -5000

mg/kg

25 °C(lit.)

12. Formaldehyde Liquid 0 °C /

32 °F

90 –

100°C

(lit.)

> 60

°C 7 - 73 0.37 mg/m³ 500 mg/kg

1.08 to

1.0975 0.62 to 1.04 50-00-0

13. Hydrogen Gas Gas -

259°C

-252.8

°C

NA

???

4.0% -

75.0%

Simple

asphyxiant

> 15000

ppm/1h 0.069 21.1°C 1333-74-0

14. IPA Liquid -88.5 82 11.7 2.3 - 12.7 -- 5000 mg/kg 0.78 2.07 67-63-0

15. Maltol Solid

160 –

164

C°

284,7

°C at

1013

hPa

> 93.3

°C -- 10 mg/m3 1.410 mg/kg

1.348g/cm

3 3.8 118-71-8

16. Methanol Fresh Liquid -97.8 63.9-65 11-12 5.5 - 36.5 200 ppm >1187-2769

mg/kg 0.79 1.1 67-56-1

17. Morpholine Liquid -7 - -5

°C

126,0 -

130,0

°C

31 °C 1.8 - 10.8 20 ppm 1.900 mg/kg 0.996

g/cm3 3.01 110-91-8

18. Palladium

Carbon Solid >3500 -- -- -- -- -- -- -- 7740-05-03

19. Sodium Cyanide Solid 563.7

°C 1497°C

1500°

C -- 5 mg/m3 4.7 mg/kg 1.6 1.7 143-33-9

20. Sodium tungaste Solid 698°C 5660 °C 32.00

°F -- 1 mg/m3 1.453 mg/kg

3.23

g/cm3

Not

applicable 13472-45-2

21. Sulfuric Acid Liquid 3 °C 288 °C

Not

applic

able

-- 1 mg/m3. 2.140 mg/kg 1.80 3.39 7664-93-9

22. THF Liquid 108,4 65,0 - -17,0 1.8 – 11.8 590 mg/m3 1.650 mg/kg 0.89 2.5 109-99-9



Sr.

No

Name of Raw

material

Physic

al State

M.P 0C

B.P 0C

F.P 0C

LEL/UEL

%

TLV

ppm or

mg/m3

LD50mg/kg

LC50mg/l

Sp.

Gravity

(water=1)

Vapour

Density

(air =1)

CAS No.

4 °C 67,0 °C °C g/cm3

23. Thionyl chloride Liquid -105 79 -- -- -- 270 mg/kg 1.64 4.1 7719-09-7

24. Toluene Liquid -95 110.6 4.4 1.3 - 7.0 100 ppm 636 mg/kg 0.87 3.2 108-88-3

25. Triethyl amine Liquid -115 89-90 -6.7 1.2 - 8 3 ppm 460 mg/kg 0.73 --- 121-44-8

It will be purchased on campaign basis, only 6-8 products will be manufactured at a time in a day.



2.3.4 TRANSPORTATION OF RAW MATERIALS AND FINISHED PRODUCTS

The raw materials and finished goods are transported through tankers and trucks. There is well

developed road structure in Madhvas region as well as within premises also. No additional road

infrastructure will be required for transportation.

The number of trucks per day for raw material and finished product transportation will be

approx. 4 to 8 tanker/trucks. The raw material source will be standard manufacturer or supplier.

Indicative list along with mode of transportation is included in Table 2.6.

TABLE NO.: 2.6

DETAILS OF RAW MATERIAL SOURCE AND METHOD OF TRANSPORTATION

Sr.

No. Name of Raw Material State Source

Mode of

transportation

1. 1,2,4-Triazole Solid Local Supplier Truck

2. 2,3 pyrridnedicarboxylic acid Solid Local Supplier Truck

3. 2,3-Dimethyl-4-nitropyridine N-

oxide Solid

Local Supplier Truck

4. 2-Aminodiphenyl suphide Solid Local Supplier Truck

5. 2-Bromo butane Liquid Local Supplier Truck

6. 2-chloro ethanol Liquid Local Supplier Truck

7. 2-Choroethoxy ethanol Liquid Local Supplier Truck

8. 2-furaldehyde diacetate Solid Local Supplier Truck

9. 2-mercapto benzimidazole Solid Local Supplier Truck

10. 2-Propanone semicarbazone Solid Local Supplier Truck

11. 3-Methoxy Propanol Liquid Local Supplier Truck

12. 4-[4-[4-(4-methoxy phenyl)-1-

acetic acid Solid


13.


piperazinyl]phenyl]-3H-1,2,4-

triazol-3-one

Solid Local Supplier Truck

14. 5 Chloro 2 pentanone Liquid Local Supplier Truck

15. 5-(Difluoromethoxy)-2-

mercaptobenzimidazole Solid


16. Acidic anhydride Liquid Local Supplier Truck

17. Acetic acid Liquid Local Supplier Truck

18. Acetone (Fresh) Liquid Local Supplier Truck

19. Aceto nitrile (Fresh) Liquid Local Supplier Truck

20. Carbon Solid Local Supplier Truck

21. Aluminum Chloride Solid Local Supplier Truck

22. Ammonia solution Liquid Local Supplier Truck

23. Ammonium Suphate Solid Local Supplier Truck

24. Benzoic Acid Solid Local Supplier Truck



Sr.


Mode of

transportation

25. Benzyl amine Liquid Local Supplier Truck

26. Benzyl chloride Liquid Local Supplier Truck

27. Bis 2 chloro ethylene hydrochloride Solid Local Supplier Truck

28. Bromine Liquid Local Supplier Truck

29. CS flakes Solid Local Supplier Truck

30. Calcium Carbonate Solid Local Supplier Truck

31. Calcium Chloride Solid Local Supplier Truck

32. Chloroform Liquid Local Supplier Truck

33. Choline Chloride Solid Local Supplier Truck

34.


dichlorophynyl)-1,3-dioxolan-4-yl

methyl] benzoate

Solid


35. Cyclohexynyl ether Liquid Local Supplier Truck

36. Cyclohexane Ethylamine Liquid Local Supplier Truck

37. CytidineMonophospahte (CMP ) Solid Local Supplier Truck

38. DCC (N,N'-

Dicyclohexylcarbodiimide) Solid


39. Di ethyl Malonate Liquid Local Supplier Truck

40. Di Methyl Carbonate Liquid Local Supplier Truck

41. Di N Propyl amine Liquid Local Supplier Truck

42. Di iso propyl ethyl amine Liquid Local Supplier Truck

43. Di methyl Malenate(320L) Liquid Local Supplier Truck

44. Dimethyl sulfoxide Liquid Local Supplier Truck

45. Dimethyl sulphide Liquid Local Supplier Truck

46. Dimethylformamide (DMF) Liquid Local Supplier Truck

47. D-Mandalic acid Solid Local Supplier Truck

48. D-tartaric acid Solid Local Supplier Truck

49. EDC Liquid Local Supplier Truck

50. Ethanol Liquid Local Supplier Truck

60. Ethyl acetate Liquid Local Supplier Truck

61. Ethyl Chloro acetate Liquid Local Supplier Truck

62. Ethyl chloroformate (260Kg) Liquid Local Supplier Truck

63. Ethyl Cyano acetate Liquid Local Supplier Truck

64. Ethyl Formate Liquid Local Supplier Truck

65. Ethyl Piperidine Carboxylate Liquid Local Supplier Truck

66. Ethyl isothiocynate Liquid Local Supplier Truck

67. Formaldehyde Liquid Local Supplier Truck

68. Fumaric acid Solid Local Supplier Truck

69. Glacial acetic acid Liquid Local Supplier Truck

70. HCl Liquid Local Supplier Truck

71. Hydrazine Hydrate Liquid Local Supplier Truck

72. Hydrobenzoic acid Solid Local Supplier Truck



Sr.


Mode of

transportation

73. Hydrobromic acid Liquid Local Supplier Truck

74. Hydrogen Gas Gas Local Supplier Truck

75. Hydrogen peroxide Liquid Local Supplier Truck

76. Hyflow Solid Local Supplier Truck

77. IPA Hcl Liquid Local Supplier Truck

78. IPE Liquid Local Supplier Truck

79. Iso Propyl alcohol (IPA) Liquid Local Supplier Truck

80. Isovelaraldehyde Liquid Local Supplier Truck

81. L+tartaric acid Solid Local Supplier Truck

82. Maltol Solid Local Supplier Truck

83. MDC Fresh Liquid Local Supplier Truck

84. Megnesium acetate Solid Local Supplier Truck

85. Megnesium oxide (160Kg) Solid Local Supplier Truck

86. Methane sulfonyl chloride Liquid Local Supplier Truck

87. Methanol Fresh Liquid Local Supplier Truck

88. Methanolic Ammonia Liquid Local Supplier Truck

89. MethanolicHcl Liquid Local Supplier Truck

90. Methyl Chloroacetate Liquid Local Supplier Truck

91. Morpholine Liquid Local Supplier Truck

92. n- Heptane Fresh Liquid Local Supplier Truck

93. N- Hexane Fresh Liquid Local Supplier Truck

94. N, N-Dimethylaniline Liquid Local Supplier Truck

95. N,N Dimethyl-1,3-Propanediamine Liquid Local Supplier Truck

96. N-Ethyl ethanol amine Liquid Local Supplier Truck

97. Nitric acid Liquid Local Supplier Truck

98. Nitrogen gas Gas Local Supplier Truck

99. N-methypyrroidinone Liquid Local Supplier Truck

100. Orgno Copper Catalyst Solid Local Supplier Truck

101. Palladium Carbon Solid Local Supplier Truck

102. Parachlorobenzophenon Solid Local Supplier Truck

103. Phenylchoroformate Liquid Local Supplier Truck

104. Phosphorul Choline chloride Solid Local Supplier Truck

105. Phosporic acid Liquid Local Supplier Truck

106. Phosporouspentaoxide Solid Local Supplier Truck

107. Piperazine Solid Local Supplier Truck

108. Phosphorus oxychloride (POCl3) Liquid Local Supplier Truck

109. Poly phosphoric acid Liquid Local Supplier Truck

110. Potassium carbonate Solid Local Supplier Truck

111. Potassium hydroxide Solid Local Supplier Truck

112. Potassium Tert- Butoxide Solid Local Supplier Truck

113. Propanone semi amino hydrantoin Solid Local Supplier Truck



Sr.


Mode of

transportation

114. PTSC Solid Local Supplier Truck

115. Pyridine Liquid Local Supplier Truck

116. Pyrrole Liquid Local Supplier Truck

117. R-(+) ∞ Phenyl ethyl amine Liquid Local Supplier Truck

118. Raney Nickel Solid Local Supplier Truck

119. Sodium bi carbonate Solid Local Supplier Truck

120. Sodium Cyanide Solid Local Supplier Truck

121. Sodium Hypochorite Solid Local Supplier Truck

122. Sodium Iodide Solid Local Supplier Truck

123. Sodium Methoxide Solid Local Supplier Truck

124. Sodium mono chloro acetate Solid Local Supplier Truck

125. Sodium sulpahte Solid Local Supplier Truck

126. Sodium tungaste Solid Local Supplier Truck

127. Sulfuric Acid Liquid Local Supplier Truck

128. TBAB Solid Local Supplier Truck

129. Tetra butyl ammonium bromide Solid Local Supplier Truck

130. THF Liquid Local Supplier Truck

131. Thionyl chloride Liquid Local Supplier Truck

132. Toluene Fresh Liquid Local Supplier Truck

133. Triethyl amine Liquid Local Supplier Truck

134. Urea Solid Local Supplier Truck

135. Xylene (Fresh) Liquid Local Supplier Truck



2.4 PROCESS DESCRIPTION

2.4.1 MANUFACTURING PROCESS

1) 5-NITROFURFURAL DIACETATE

Process:

Acetic anhydride and Sulphuric acid is treated with Nitric acid gives 5-NLTA which on

Hydrolysis gives 5-Nitrofurfural diacetate.

Chemical Reaction:

Material Balance & Flow Diagram:



2) 1-AMINO HYDANTOIN HYDROCHLORIDE

Process:

Hydrazine Hydrate is treated with Urea in presence of Methanol gives 2-PSB which on

cyclization with Methyl Chloro acetate gives PSAH.

PSAH further treated with HCl to give final product 1-Amino hydantoin hydrochloride.

Chemical Reaction:




3) PHOSPHORYL CHOLINE CHLORIDE, CALCIUM SALT.

Process:

Choline chloride is reacted with Phosphorous oxychloride to give Phosphroryl choline chloride,

which subjected to hydrolysis and converted to Calcium salt to give the desired product

Phosphoryl Choline chloride, Calcium salt.

Chemical Reaction:


4) CITICOLINE INTERMEDIATE– 1 (CTS TECH)

Process:

CytidineMonophospahte (CMP) dissolved in Methanol in presence of DicyclohexyCarbodamide

(DCC) and then condensed with Phosporyl Choline chloride at ambient temperature. After

completion of reaction the reaction mass is filtered and final product is purified in Methanol.



Chemical reaction:

Cytidine 5'-monophosphate Morpholine

(5'-CMP-morpholidate)

(5'-CMP)

OP

ON N

OH OH

OH

O

OH

O

NH2

NHO + DCC

Methanol

OP

ON N

OH OH

N

O

OH

O

NH2

O

(CPCC)

N+

O

P

CH3

CH3

CH3 Ca

O

O

O

Cl-

Methanol

HCl

OP

ON N

OH OH

O

O

OH

O

NH2

PN+

OCH3

CH3

CH3 O-

O

IPA

DIPA + Oxalic acid

Water

Activated Carbon

Sodium hydroxide

Formic acid

Methanol + IPA

OP

ON N

OH OH

O

O

ONa

O

NH2

PN+

OCH3

CH3

CH3 O-

O

Citicoline Sodium Crude / Citicoline sodium Tech

Purification

Water

Formic acid

Sodium hydroxide

Methanol + IPA

OP

ON N

OH OH

O

O

ONa

O

NH2

PN+

OCH3

CH3

CH3 O-

O

Citicoline Acid Crude

Citicoline Sodium - API

Material balance & flow diagram:



5) 2-(4-AMINOPENTYL (ETHYL) AMINO) ETHANOL

Process:

5-Chloro-2-pentanone is treated with N-ethyl ethanol amine and organo-copper catalyst in

xylene. Reaction mass was refluxed till completion of reaction followed by distillation of xylene.

Obtained intermediate residue was treated with methanolic ammonia and raney nickel in

methanol. After separation of catalyst, distilled methanol to get 2-(4-aminopentyl (ethyl) amino)

ethanol.

Chemical Reaction:

CH3

Cl

O

+ CH3 NHOH

CH3

N

OHCH3

O

CH3

N

OHCH3

NH2

Xylene

Cu

Raney Nickel

Methanol + NH 3

Molecular Formula = C5H9ClO

Formula Weight = 120.57

5-chloropentan-2-one 2-(ethylam ino)ethanol

Molecular Formula= C4H

11NO

Formula Weight = 89.13 5-[ethyl(2-hydroxyethyl)am ino]pentan-2-one

Molecular Formula = C9H

19NO

2


2-[(4-am inopentyl)(ethyl)am ino]ethanol

Molecular Formula = C9H

22N

2O

Formula Weight = 174.28 Material balance & flow diagram:



6) 3- QUINUCLIDINONE

Process:

Ethyl Piperidine 4-carboxylate has been treated with ethylchloro acetate in toluene solvent in

presence of potassium carbonate as base. Reaction mass was refluxed for completion of reaction.

Reaction mass was quenched with water. Organic layer was washed with water and toluene layer

was subjected to next reaction Insitu.

To above toluene layer charged potassium tert-butoxide and refluxed till completion of reactions.

After this charge hydrochloric acid in to reaction mass and product was extracted in water. This

acidic aqueous layer was refluxed for 24 hrs and finally product extracted in chloroform at basic

pH. Distilled chloroform and IPA.HCl was added in to it. Filter precipitated product and dried

under vacuum.

Chemical Reaction:




7) 1-ETHYL-3-(3-DIMETHYLAMINOPROPYL) CARBODIMIDE HYDROCHLORIDE

(EDC. HCl)

Process:

Ethyl isothiocynate treated with N,N-Dimethyl-1,3-propanediamine in presence of sodium

hypochlorite, potassium hydroxide in calcium carbonate treatment in chloroform as solvent, after

completion of reaction, reaction mass is quenched with water and isolated product 1-ethyl-3-(3-

dimethylaminopropyl) carbodimide.

Further,1-ethyl-3-(3-dimethylaminopropyl) carbodimide further treated with anhydrous

hydrochloric acid in acetonitrile solvent to give 1-ethyl-3-(3-dimethylaminopropyl) carbodimide

hydrochloride.

Chemical Reaction:

CH3 N S + NH2 N

CH3

CH3

CH3 N N N

CH3

CH3

N-[3-(dimethylamino)propyl]-N'-ethylcarbodiimide

N,N-dimethylpropane-1,3-diamineIsothiocyanatoethane

CH3 N N N

CH3

CH3

HCl

N-[3-(dimethylamino)propyl]-N'-ethylcarbodiimide.hydrochloride (EDC.HCl)

Molecular Formula = C8H17N3






Molecular Formula = C3H5NS


NaOCl, Chloroform

HCl




8) 3-(1-CYANOETHYL) BENZOIC ACID

Process:

Benzoic acid is treated with formaldehyde in presence of aluminium chloride in dichloromethane

followed by esterification reaction with methanol in sulphuric acid gives methyl 3-

(chloromethyl) benzoate which on further treated with sodium cyanide in methanol gives methyl

3-(cyanomethyl)benzoate.

Methyl 3-(cyanomethyl) benzoate further methylated with dimethyl carbonate in water gives 3-

(1-cyanoethyl) benzoic acid.

Chemical reaction:




9) 1-(P-METHOXY BENZYL)-1,2,3,4,5,6,7,8,OCTAHYDRO ISOQUINALINE- S-OCTA

BASE

Stage-I: 1-(p-methoxy benzyl)-1,2,3,4,5,6,7,8,Octahydro isoquinaline.

Process:Cyclohexenylethylamine reacts with P-methoxyphenylacetic acid in Toluene gives N-

(2-(Cyclohexen-1-yl)ethyl) -p-methoxyphenylacetamide.

Chemical Reaction:

Stage-II: 1-(p-methoxy benzyl)-1,2,3,4,5,6,7,8,OctahydroisoquinalineMandelate

Process: N-(2-(Cyclohexen-1-yl)ethyl)-p-methoxyphenylacetamide reacts with

Phosphorusoxychloride in Toluene gives 1-(P-methoxybenzyl)-3,4,5,6,7,8,

hexahydroisoquinoline.

Chemical Reaction:

Stage-III: 1-(p-methoxy benzyl)-1,2,3,4,5,6,7,8,Octahydroisoquinaline- S-octa base

Process: 1-(P-methoxy benzyl)3,4,5,6,7,8, hexa hydroisoquinoline reacts with Sodium

borohydride in water gives 1-(P- methoxy benzyl)1,2,3,4,5,6,7,8, octahydroisoquinoline.,8, octa

hydro.

Chemical Reaction:



Material Balance:

10) DEXTROMETHARPHINFREE BASE –CRUDE

Stage-I: (p-methoxybenzyl)-2-formyl-1,2,3,4,5,6,7,8, Octahydroisoquinaline

Process: D-1-(P-methoxybenzyl)1,2,3,4,5,6,7,8, octahydroisoquinolineMandalate reacts with

Caustic lye in water gives D-1-(P-methoxybenzyl)1,2,3,4,5,6,7 isoquinoline (S-Octabase).

Chemical Reaction:

Stage-II: 3--methoxy-N-formylmorphian

Process: Formulation of S-Octabase with Methyl formate in presence of Sodium methoxide and

Toluene followed by neutralization with formic acid give Stage-II compound.

Chemical Reaction:



Stage-III: 3- methoxymorphian-Deformylation

Process:yclization of stage-II compound in presence of Phosphoric acid give Stage-III.

Chemical Reaction:

Stage-IV

Process:High vacuum distillation of Stage-IV give pure compound i.e. Stage-V.

Chemical Reaction:

Stage-V :Dextrometharphin free base -Crude

Process: N-methylation of Stage-IV with formaldehyde and formic acid in presence of Toluene

followed by crystallization in Acetone gives Stage-V i.e. Dextromethorphan base.

Chemical Reaction:



Material Balance:

11) CIS-2-(2,4-DICHLORO PHENYL)-2-(1H-1,2,4-TRIAZOL-1-YL-METHYL)-1,3-

DIOXOLAN-4-YL METHYL METHANE SULFONATE (CRUDE)

Stage- I

Process:

2,4-Dihydro-4-[4-[4-(4-methoxyphenyl)-1-piperazinyl]phenyl]-3H-1,2,4-triazol-3-one is reacted

with 2-bromo butane to give 2,4-Dihydro-4-[4-[4-(4-methoxyphenyl)-1-piperazinyl]phenyl]-2-

(1-methylpropyl)-3H-1,2,4-triazol-3-one.

N N

N

N

N

O

N N

N

N

N

O

H3CO H

3CO

H

Stage – II: 2,4-Dihydro-4-[4-[4-(4-methoxyphenyl)-1-piperazinyl]phenyl]-2-(1-methylpropyl)-

3H-1,2,4-triazol-3-one is reacted with hydro bromic acid to give 2,4-Dihydro-4-[4-[4-(4-

hydroxyphenyl)-1-piperazinyl]phenyl]-2-(1-methylpropyl)-3H-1,2,4-triazol-3-one.

N N

N

N

N

O

OH N N

N

N

N

O

H3CO

Stage – III:cis-(2-Bromo methyl)-2-(2,4-dichloro phenyl)-1,3-dioxolan-4-yl methyl benzoate is

reacted with 1H-1,2,4-triazole and the resultant is hydrolised with sodium hydroxide to give cis-

2-(2,4-dichloro phenyl)-2-(1H-1,2,4-triazol-1-yl-methyl)-1,3-dioxolan-4-yl methanol.



Cl

Cl

O

OCH

2COOC

6H

5

H

Br

Cl

Cl

O

O

NN

N

CH2OH

H Stage–IV: cis-2-(2,4-Dichloro phenyl)-2-(1H-1,2,4-triazol-1-yl-methyl)-1,3-dioxolan-4-yl

methanol is reacted with methane sulfonyl chloride to give cis-2-(2,4-Dichloro phenyl)-2-(1H-

1,2,4-triazol-1-yl-methyl)-1,3-dioxolan-4-yl methyl methane sulfonate (Crude).

Cl

Cl

O

O

NN

N

CH2OSO

2CH

3

H

Cl

Cl

O

O

NN

N

CH2OH

H

Material Balance:



12) CIS-2-(2,4-DICHLORO PHENYL)-2-(1H-1,2,4-TRIAZOL-1-YL-METHYL)-1,3-

DIOXOLAN-4-YL METHYL METHANE SULFONATE (PURE)

Stage- I:2,4-Dihydro-4-[4-[4-(4-methoxyphenyl)-1-piperazinyl]phenyl]-3H-1,2,4-triazol-3-one

is reacted with 2-bromo butane to give 2,4-Dihydro-4-[4-[4-(4-methoxyphenyl)-1-

piperazinyl]phenyl]-2-(1-methylpropyl)-3H-1,2,4-triazol-3-one.

N N

N

N

N

O

N N

N

N

N

O

H3CO H

3CO

H

Stage – II: 2,4-Dihydro-4-[4-[4-(4-methoxyphenyl)-1-piperazinyl]phenyl]-2-(1-methylpropyl)-

3H-1,2,4-triazol-3-one is reacted with hydro bromic acid to give 2,4-Dihydro-4-[4-[4-(4-

hydroxyphenyl)-1-piperazinyl]phenyl]-2-(1-methylpropyl)-3H-1,2,4-triazol-3-one.

N N

N

N

N

O

OH N N

N

N

N

O

H3CO

Stage – III:cis-(2-Bromo methyl)-2-(2,4-dichloro phenyl)-1,3-dioxolan-4-yl methyl benzoate is

reacted with 1H-1,2,4-triazole and the resultant is hydrolised with sodium hydroxide to give cis-

2-(2,4-dichloro phenyl)-2-(1H-1,2,4-triazol-1-yl-methyl)-1,3-dioxolan-4-yl methanol.

C l

C l

O

OC H

2C O O C

6H

5

H

B r

C l

C l

O

O

NN

N

C H2O H

H Stage–IV: cis-2-(2,4-Dichloro phenyl)-2-(1H-1,2,4-triazol-1-yl-methyl)-1,3-dioxolan-4-yl

methanol is reacted with methane sulfonyl chloride to give cis-2-(2,4-Dichloro phenyl)-2-(1H-

1,2,4-triazol-1-yl-methyl)-1,3-dioxolan-4-yl methyl methane sulfonate.

Cl

Cl

O

O

NN

N

CH2OSO2CH3

H

Cl

Cl

O

O

NN

N

CH2OH

H

Stage – V: 4-[4-[4-(4-Hydroxyphenyl)-1-piperazinyl]phenyl]-2,4-dihydro- 2-(1methylpropyl)

-3H-1,2,4-triazole-3-one is reacted with cis-2-(2,4-dichlorophenyl)-2-(1H-1,2,4-triazol-1-yl-

methyl)-1,3-dioxolan-4-yl methyl methane sulfonate and sodium hydroxide, in toluene and

methanol to give Itraconazole (Pure).

CH3

CH3OH N NN

O

NN

Cl

Cl

O

O

NN

N

CH2OSO

2CH

3

H

+



Material Balance:



13) PHENYL (1H PYRROLE-2-2YL) METHANONE- TRICARBOXYLATE (CRUDE)

Stage – I: Marpholine phenyl methanone

Process: Morpholine reacted with Benzoyl chloride In presence of Toluene gives Marpholine

phenyl methanone

Chemical Reaction:

Material Balance:

Stage-II:Phenyl (1h pyrrole-2-yl)methanone.

Process: Marpholine phenyl methanone reacted with pocl3 and pyrrole after that quenching in

Ice water isolated product gives Phenyl (1h pyrrole-2-yl)methanone.

Chemical Reaction:

Material Balance:

Stage- III:Magnesium oxide and dimethyl Malenate reacted with Ethyl Choloroformate and

Sulfuric acid in presence of Toluene gives Triethyl methane tricarboxylate.



Material Balance:

Stage- IV: Phenyl (1h pyrrole-2-yl) methanone – tricarboxylate.

Process: Triethyl methane tricarboxylate and Phenyl (1h pyrrole-2-yl) methanone in presence of

magnesium acetate and acetic anhydride in presence of ethyl acetate gives Phenyl (1h pyrrole-2-

yl) methanone – tricarboxylate.

Chemical Reaction:

Material Balance:

Stage- V: Phenyl (1h pyrrole-2-yl) methanone – tricarboxylate.

Process: Phenyl (1h pyrrole-2-yl) methanone – tricarboxylate reacted with potassium carbonate

in presence of ethyl acetate by using TBAB catalyst Gives Phenyl (1h pyrrole-2-yl) methanone –

tricarboxylate crude.

Chemical Reaction:



Material Balance:

Stage-VI:Phenyl(1h-pyrrole-2-yl)methanone–tricarboxylate-Ketrolactrimethamin-crude

Phenyl (1h pyrrole-2-yl)methanone – tricarboxylate reacted with Triethl amine in presence of

Acetone Gives Phenyl (1h pyrrole-2-yl)methanone – tricarboxylate -Ketrolactrimethamin -crude

.

Chemical Reaction:

Material Balance:



14)(-)-1-[(4-CHLOROPHENYL)PHENYLMETHYL]-4-[(4METHYLPHENYL)SULFONYL]

PIPERAZINE

Stage-1: Reaction of p-Chloro benzophenone (PCBP) with Ammonium formate in toluene

followed by workup gives racemic (±)-(4-Chlorophenyl) phenylmethyl amine (Stage-I

Intermediate).

Chemical Reaction:

Stage-II: Treatment of Stage-I intermediate with L(+)-Tartaric acid in methanol provides the

required isomer as its tartaric acid salt, which on hydrolysis with aq. sodium hydroxide gives

Levorotatory (-)-(4-Chlorophenyl) phenylmethyl amine (Stage-II intermediate) as an oily liquid.

Chemical Reaction:

Stage-III: Treatment of N,N-Bis (2-chloroethyl)amine hydrochloride with p-Toluene Sulphonyl

chloride in Methylene dichloride and followed by workup yields N,N-bis(2-Chloroethyl)-4-

methyl benzene sulfonamide (Stage-III intermediate)

Chemical Reaction:



Stage-IV:Condensation of Levorotatory (-)-(4-Chlorophenyl) phenyl methyl amine (Stage-II

intermediate) with N,N-bis(2-Chloroethyl)-4-methyl benzene sulfonamide (Stage-III

intermediate) in presence of Disopropyl ethylamine (DIEPA) and followed by further workup

yields (-)-1-[(4-Chlorophenyl)phenylmethyl]-4-[(4-methylphenyl)sulfonyl] piperazine (Stage-IV

intermediate).

Chemical Reaction:

Material Balance:



15) (-) P-CHLORO BENZHYDRYL PIPERAZINE

Stage-1 :Reaction of p-Chloro benzophenone (PCBP) with Ammonium formate in toluene

followed by workup gives racemic (±)-(4-Chlorophenyl) phenylmethyl amine (Stage-I

Intermediate).

Chemical Reaction:

Stage-II: Treatment of Stage-I intermediate with L(+)-Tartaric acid in methanol provides the

required isomer as its tartaric acid salt, which on hydrolysis with aq. sodium hydroxide gives

Levorotatory (-)-(4-Chlorophenyl) phenylmethyl amine (Stage-II intermediate) as an oily liquid.

Chemical Reaction:

Stage-III: Treatment of N,N-Bis (2-chloroethyl) amine hydrochloride with p-Toluene

Sulphonyl chloride in Methylene dichloride and followed by workup yields N,N-bis(2-

Chloroethyl)-4-methyl benzene sulfonamide (Stage-III intermediate).

Chemical Reaction:

Stage-IV: Condensation of Levorotatory (-)-(4-Chlorophenyl) phenyl methyl amine (Stage-II

intermediate) with N,N-bis(2-Chloroethyl)-4-methyl benzene sulfonamide (Stage-III

intermediate) in presence of Disopropyl ethylamine (DIEPA) and followed by further workup



yields (-)-1-[(4-Chlorophenyl)phenylmethyl]-4-[(4-methylphenyl)sulfonyl] piperazine (Stage-IV

intermediate).

Chemical Reaction:

Stage-V: Treatment of Stage-IV intermediate with HBr in acetic acid in presence of p Hydroxy

benzoic acid (catalyst) followed by workup gives (-) p-Chloro benzhydryl piperazine (Stage-V).

Chemical Reaction:

Material Balance:



16) 2,3PYRRIDINE BENZYLE CARBOXYLATE HYDRATE CHLOROCOMPOUND

Process:

Stage-I: 2,3 pyrridineBenzyle carboxylate

2,3pyrridinedicarboxylic acid reacted acetic anhydride and benzyl amine In presence of

Methanol and toluene gives 2,3 pyrridineBenzyle carboxylate.

Stage-II: 2,3 pyrridineBenzyle carboxylate hydrate

2,3pyrridine Benzyl carbaxylate reacted with Palladium carbon catalyst in presence of

ethyacetate gives 2,3 pyrridineBenzyle carboxylate hydrate.

Stage-III :2,3 pyrridineBenzyle carboxylate Hydrate Tartrate salt

2,3 pyrridineBenzyle carboxylate hydrate reacted with tartaric acid inpresence of Water gives

2,3 pyrridineBenzyle carboxylate tartrate salt.

Stage- IV: 2,3 pyrridineBenzyle carboxylate Hydrate Chloro compound

2,3 pyrridineBenzyle carboxylate tartrate salt reacted with Alluminium chloride inpresence of

Water and toluene gives 2,3 pyrridineBenzyle carboxylate chlorcompound.

Stage-V: 2,3 pyrridineBenzyle carboxylate Hydrate Chloro compound

2,3 pyrridineBenzyle carboxylate clorocompound reacted with Hydrogenation reduction

inpresence of Water and Methanol gives Nonane compound.



Chemical Reaction:



Material Balance:



17) 3,4-DIMETHOXY-2-CHLORO METHYL PYRIDINE

Stage-I: Maltol is reacts with Dimethyl sulphate in presence of acetone to get 3-methoxy 2-

methyl-4-pyron.

Stage-II: 3-methoxy n-methyl-4-pyron reacts with liquor ammonia solution and ammonia

acetate is used as a catalyst crystallized by the acetone 3-methoxy 2-methyl-4-pyridone.

Stage-III: 3-methoxy 2-methyl-4-pyridone reacts with phosphorous oxychloride in presence of

MDC to get 4-chloro 3-methoxy 2-methyl-4-pyridone.

Stage-IV: 4-chloro 3-methoxy 2-methyl-4-pyridone reacts with hydrogen peroxide in presence

of acetic acid sodium tungastate is under as a catalyst 4-chloro 3-methoxy 2-methyl-4-pyridone-

n-oxide.

Stage-V: 4-chloro 3-methoxy 2-methyl-4-pyridone-n-oxide reacts with methanol in presence of

sodium hydroxide to get 3,4-diethoxy-2-methyl-4-pyridone-n-oxide.

Stage-VI: 3,4-diethoxy-2-methyl-4-pyridone-n-oxide reacts with acetic anhydride and further

reacts with sodium hydroxide in presne of water to get 3,4-dimethoxy-2-hydroxy methyl

pyridine.

Stage-VII: 3,4-dimethoxy-2-hydroxy methyl pyridine reacts with thionyl chloride in presence of

MDC 3,4-dimethoxy-2-chloro methyl pyridine- pantoprazole chloro.

Chemical Reaction:



Material Balance:

18) PENTAPROZOLE SULPHIDE

Stage-I: Maltol is reacts with Dimethyl sulphate in presence of acetone to get 3-methoxy 2-

methyl-4-pyron.

Stage-II: 3-methoxy n-methyl-4-pyron reacts with liquor ammonia solution and ammonia

acetate is used as a catalyst crystallized by the acetone 3-methoxy 2-methyl-4-pyridone.

Stage-III: 3-methoxy 2-methyl-4-pyridone reacts with phosphorous oxychloride in presence of

MDC to get 4-chloro 3-methoxy 2-methyl-4-pyridone.

Stage-IV: 4-chloro 3-methoxy 2-methyl-4-pyridone reacts with hydrogen peroxide in presence

of acetic acid sodium tunga state is under as a catalyst 4-chloro 3-methoxy 2-methyl-4-pyridone-

n-oxide.

Stage-V: 4-chloro 3-methoxy 2-methyl-4-pyridone-n-oxide reacts with methanol in presence of

sodium hydroxide to get 3,4-diethoxy-2-methyl-4-pyridone-n-oxide.

Stage-VI: 3,4-diethoxy-2-methyl-4-pyridone-n-oxide reacts with acetic anhydride and further

reacts with sodium hydroxide in presne of water to get 3,4-dimethoxy-2-hydroxy methyl

pyridine.

Stage-VII: 3,4-dimethoxy-2-hydroxy methyl pyridine reacts with thionyl chloride in presence of

MDC 3,4-dimethoxy-2-chloro methyl pyridine-pantoprazole chloro.



Stage-VIII: 5-(Difluoromethoxy)-2-mercapto benzimidazole and 2-chloromethyl-3,4-

dimethoxy-pyridine hydrochloride are condensed in the presence of sodium hydroxide and in

methanol to give 5-(Difluoromethoxy)-2-[[(3,4-dimethoxy-2-pyridinyl)-2-methyl] thiol]-1H-

benzimidazole to get pentaprozole sulphide.

Chemical Reaction:

Material Balance:



19) PREGABALIN (RACEMIC)

Stage-I: Isovelaraldehyde is reacts with Ethyl cyan Acetate in presence of Toluene to get 2-

Carboxy-5-methyl hex-2-exotic acid ethyl ester.

Stage-II: 2-Carboxy-5-methyl hex-2-exotic acid ethyl ester reacts with R-Phenyl |Ethyl amine in

presence of Chloroform to get 2-Carboxyethyl-3-cyano-5-methyl hexanoic acid ethyl ester.

Stage-III: 2-Carboxyethyl-3-cyano-5-methyl hexanoic acid ethyl ester reacts with Bromine in

presence of MDC to get Pregabalin (Racemic).

Chemical Reaction:

Stage-I : Preparation of 2-Carboxy-5-methyl hex-2-exotic acid ethyl ester

Stage-II :Preparation of 2-Carboxyethyl-3-cyano-5-methyl hexanoic acid ethyl ester

Stage-III : Preparation of Pregabalin (Racemic)

Stage-IV : Preparation of Pregabalin



Material Balance:

20) 11-PIPERAZINYL-DIBENZO(B,F) (1,4)-THIAZEPINE HYDROCHLORIDE

Process:

Stage – I:2-Amino diphenyl sulphide is reacted with Phenylchloroformate in presence of

Toluene gives Phenyl-2-(phenyl thio) phenyl carbamate (QUE-1).

Stage – II: Phenyl-2-(phenyl thio) phenyl carbamate (QUE-1) is reactes with Poly

phosphouricacid in presence of Acetone to give Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one

(QUE-1I).

Stage – III: Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one (QUE-1I)is reacted with Pocl3 in

presence of Piperazine to give 11-Piperazinyl-dibenzo(b,f) (1,4)-thiazepine hydrochloride.

Chemical Reaction:

Preparation of Phenyl -2- (-phenylthio)phrnylcarbamate (QUE-1)

NH2

S

NHCOOPh

S

2-Aminodiphenyl sulphide

+ C6H5-O-C-Cl

O

Na2CO3

Phenyl-2-(phenylthio)phenyl carbamate

Preparation of Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one (QUE-1I)



S

NO

Polyphosphoric acid

Dibenzo [b,f][1,4]thiazepine-11(10-H)one

HNHCOOPh

S


Preparation of 11-Piperazinyl-dibenzo(b,f) (1,4)-thiazepine hydrochloride (QUE-III HCl):

Material Balance:

Stage-I: Preparation of Phenyl-2-(phenyl thio) phenyl carbamate (QUE-1):

Stage-II: Preparation of Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one (QUE-1I)

Stage-III: Preparation of 11-Piperazinyl-dibenzo(b,f) (1,4)-thiazepine hydrochloride(QUE-III)



21) 11-[4-[2-(2-HYDROXY ETHOXY) ETHYL]-1-PIPERAZINYL] DIBENZO (B, F) (1, 4)

THIAZEPINE HEMIFUMARATE

Process:

Stage – I:2-Amino diphenyl sulphide is reacted with Phenylchloroformate in presence of

Toluene gives Phenyl-2-(phenyl thio) phenyl carbamate (QUE-1).

Stage – II: Phenyl-2-(phenyl thio) phenyl carbamate (QUE-1) is reactes with Poly

phosphouricacid in presence of Acetone to give Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one

(QUE-1I).

Stage – III: Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one (QUE-1I)is reacted with Pocl3 in

presence of Piperazine to give 11-Piperazinyl-dibenzo(b,f) (1,4)-thiazepine hydrochloride.

Stage – IV: 11-Piperazinyl-dibenzo(b,f) (1,4)-thiazepine hydrochloride is reacts with N-methyl

pyrrolidinone in presence of 2-chloro ethoxy ethanol 11-[4-[2-(2-Hydroxy ethoxy) ethyl]-1-

piperazinyl] dibenzo (b, f) (1, 4) thiazepine hemifumarate (QUE-IV).

Chemical Reaction:

Preparation of Phenyl -2- (-phenylthio)phrnylcarbamate (QUE-1)

NH2

S

NHCOOPh

S

2-Aminodiphenyl sulphide

+ C6H5-O-C-Cl

O

Na2CO3

Phenyl-2-(phenylthio)phenyl carbamate Preparation of Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one (QUE-1I)

S

NO

Polyphosphoric acid

Dibenzo [b,f][1,4]thiazepine-11(10-H)one

HNHCOOPh

S


Preparation of 11-Piperazinyl-dibenzo(b,f) (1,4)-thiazepine hydrochloride (QUE-III HCl):



Preparation of 11-[4-[2-(2-Hydroxy ethoxy) ethyl]-1-piperazinyl] dibenzo (b, f) (1, 4) thiazepine

hemifumarate (QUE-IV).:

Material Balance:

Stage-I: Preparation of Phenyl-2-(phenyl thio) phenyl carbamate (QUE-1):

Stage-II: Preparation of Dibenzo (b, f) (1,4) thiazepine-11 (10H)-one (QUE-1I)

Stage-III: Preparation of 11-Piperazinyl-dibenzo (b,f) (1,4)-thiazepine hydrochloride(QUE-III)

Stage- IV: Preparation of 11-[4-[2-(2-Hydroxy ethoxy) ethyl]-1-piperazinyl] dibenzo (b, f) (1, 4)

thiazepine hemifumarate (QUE-IV)



22)2-[(4-(3-METHOXYPROPOXY)-3-METHYL- 2-PYRIDINYL) METHYL]THIO]-1H-

BENZIMIDAZOLE

Stage – I: 2,3-Dimethyl-4-nitropyridine-N-oxide is reacted with dry HCl and isopropyl alcohol

to give 4-chloro-2,3-dimethylpyridine-N-oxide hydrochloride.

Chemical Reaction:

Stage – II: 4-Chloro-2,3-dimethylpyridine-N-oxide hydrochloride is condensed with 3-

methoxy-1-propanol and rearranged with acetic anhydride and is hydrolyzed with sodium

hydroxide and is neutralized with dry HCl to give 2-hydroxymethyl-4-(3-methoxypropoxy)-3-

methylpyridine hydrochloride.

Chemical Reaction:

Stage – III: 2-Hydroxymethyl-4-(3-methoxypropoxy)-3-methylpyridine hydrochloride is

reacted with thionyl chloride to give 2-chloromethyl-4-(3-methoxypropoxy)-3-methylpyridine

hydrochloride.

Chemical Reaction:



Stage – IV: 2-Chloromethyl-4-(3-methoxypropoxy)-3-methylpyridine hydrochloride is

condensed with 2-mercapto-1H-benzimidazole to give 2-[[(4-(3-methoxypropoxy)-3-methyl- 2-

pyridinyl)methyl] thio]-1H-benzimidazole.

Chemical Reaction:

Material Balance:

23)2-[4-(3-METHOXYPROPOXY)-3-METHYL-2-PYRIDINYL]METHYL]SULFINYL]-

1H-BENZIMIDAZOLE

Process:

Stage – I: 2,3-Dimethyl-4-nitropyridine-N-oxide is reacted with dry HCl and isopropyl alcohol

to give 4-chloro-2,3-dimethylpyridine-N-oxide hydrochloride.



Chemical Reaction:

Stage – II: 4-Chloro-2,3-dimethylpyridine-N-oxide hydrochloride is condensed with 3-

methoxy-1-propanol and rearranged with acetic anhydride and is hydrolyzed with sodium

hydroxide and is neutralized with dry HCl to give 2-hydroxymethyl-4-(3-methoxypropoxy)-3-

methylpyridine hydrochloride.

Chemical Reaction:

Stage – III: 2-Hydroxymethyl-4-(3-methoxypropoxy)-3-methylpyridine hydrochloride is

reacted with thionyl chloride to give 2-chloromethyl-4-(3-methoxypropoxy)-3-methylpyridine

hydrochloride.

Chemical Reaction:

Stage – IV: 2-Chloromethyl-4-(3-methoxypropoxy)-3-methylpyridine hydrochloride is

condensed with 2-mercapto-1H-benzimidazole to give 2-[[(4-(3-methoxypropoxy)-3-methyl- 2-

pyridinyl)methyl] thio]-1H-benzimidazole.

Chemical Reaction:

Stage–V: 2-[[(4-(3-Methoxypropoxy)-3-methyl-2-pyridinyl)-2-methyl]thio]-1H-benzimidazole

oxidized to give 2-[[[4-(3-methoxypropoxy)-3-methyl-2-pyridinyl]methyl]sulfinyl]-1H-

benzimidazole

Chemical Reaction:



Material Balance:



2.5 DETAILS OF SOLVENT AND CHEMICAL RECOVERY SYSTEM

The unit shall provide an efficient solvent recovery system, chilled water circulation jacketed

condenser, chilled water traps, etc. installed on the vent to arrest any escape of vapors from the

reaction and distillation unit. The reactors will be connected to water condenser system. The

receiver will also be jacketed with circulation of water. The recovered solvents will then be

stored and reused back in process. Proper planning and maintenance will enable unit to have an

efficient solvent recovery from the system.

There will be totally closed system, so no solvent loss is expected in atmosphere except minor

handling loss. There will be 2%-5% solvent loss in terms of residue or volatile COD in effluent.

Reuse of solvent is technically feasible because, recovered solvent will be refluxed in same kettle

and in same product.

FIGURE 2.1

FLOWDIAGRAM OF SOLVENT RECOVERY SYSTEM



TABLE: 2.7

DETAILS OF SOLVENTS TO BE USED AND RECOVERED

Sr.

No. Name of Products Name of Solvent used

Total Solvent

quantity in

MT/ Month

Fresh Solvent

quantity in

MT/ Month

Solvent Recovered

quantity in

MT/ Month

Recovery

percentage

1 1 amino hydantoin Hydrochloride

(3.0 MT/Month) Acetone 45 3.15 41.85 93

2. Phosphoryl choline chloride, calcium salt

(7.0 MT/Month) Methanol 23 0.93 22.07 96

3. Citicoline (CTS) tech (5.0 MT/Month)

Methanol 160.7 6.43 154.27 96

IPA 73.2 3.21 69.99 96

Ethanol 50 2 48 96

4. 2-(4-aminopentyl (ethyl) amino) ethanol

(10.0 MT/Month)

Xylene 181.8 5.45 176.35 97

Methanol 136.4 5.45 130.95 96

5.

3-Quinuclidinone

(10.0 MT/Month)

Toluene 282.8 11.43 271.37 96

Chloroform 558.8 21.71 537.09 96

IPA Hcl 7.3 0.43 6.87 94

6. 1-ethyl-3-(3-dimethylaminopropyl)

carbodimide. hydrochloride

Chloroform 216.4 8.2 208.2 96

Acetonitrile 182.9 12.8 170.1 93

7. 3-(1-cyanoethyl) benzoic acid

(15.0 MT/Month)

Methanol 180 7.2 172.8 96

Dichloromethane 308.8 1.67 307.13 99

8.

1-(p-methoxy benzyl)-1,2,3,4,5,6,7,8,

Octahydroisoquinaline- S-octa base

(8.0 MT/Month)

Toluene 216.1 8.65 207.45 96

Acetone 84.2 4.21 79.99 95

9.

Dextrometharphin free base

(8.0 MT/Month)

Toluene 282 11.36 270.64 96

Methanol 154.5 8.59 145.91 94

10.

cis-2-(2,4-Dichlorophenyl)-2-(1H-1,2,4-

triazol-1-ylmethyl)-1,3-dioxolan-4-

ylmethyl methane sulphonate

(10.0 MT/Month)

Toluene 31.7 1.33 30.37 96

MDC 120.3 7.78 112.52 94



Sr.


Total Solvent

quantity in

MT/ Month

Fresh Solvent

quantity in

MT/ Month

Solvent Recovered

quantity in

MT/ Month

Recovery

percentage

11.

cis-2-(2,4-Dichlorophenyl)-2-(1H-1,2,4-

triazol-1-ylmethyl)-1,3-dioxolan-4-

ylmethyl methanesulphonate (Pure)

(8.0 MT/Month)

Toluene 196.7 6.4 190.3 97

Methanol 23.2 0.89 22.31 96

12.

Phenyl (1h pyrrole-2-yl)methanone –

tricarboxylate (Crude)

(10.0 MT/Month)

Toluene 292.6 9.4 283.2 97

Ethyl acetate 500.2 14.64 485.56 97

13.

(-)-1-[(4-Chlorophenyl)phenylmethyl]-4-

[(4-methylphenyl)sulfonyl] piperazine

(6.0 MT/Month)

Toluene 186.6 7.07 179.53 96

MDC 197.3 6.87 190.43 97

Methanol 153.9 6.8 147.1 96

14. p-Chloro benzhydryl piperazine

(6.0 MT/Month)

Toluene 170 3.23 166.77 98

MDC 206.9 6.21 200.69 97

Acetone 82.5 5.78 76.72 93

15.

2,3 pyrridineBenzyle carboxylate Hydrate

Chloro compound

(5.0 MT/Month)

Methanol 175.5 4.5 171 97

Toluene 348.7 8.88 339.82 97

Ethyl acetate 137.9 2.13 135.77 98

16. 3,4-dimethoxy-2-chloro methyl pyridine

(10.0 MT/Month)

Acetone 92.1 6.3 85.8 93

Chloroform 62.8 1.6 61.2 97

MDC 437.5 41 396.5 91

Methanol 152.3 8 144.3 95

17. Pentaprozole Sulphide

(10.0 MT/Month)

Acetone 137.7 9 128.7 93

Chloroform 62.3 2.29 60.01 96

MDC 275 14.86 260.14 95

Methanol 122.9 4.86 118.04 96

18. Preparation of Pregabalin (Racemic) N- Hexane 85 3.2 81.8 96



Sr.


Total Solvent

quantity in

MT/ Month

Fresh Solvent

quantity in

MT/ Month

Solvent Recovered

quantity in

MT/ Month

Recovery

percentage

(8.0 MT/Month) Toluene 174.2 8.8 165.4 95

Chloroform 520.4 36.48 483.92 93

Methanol 24.9 1.28 23.62 95

MDC 84.4 3.84 80.56 95

IPA 37.2 2.16 35.04 94

19.

11-Piperazinyl-dibenzo(b,f) (1,4)-

thiazepine hydrochloride

(8.0 MT/Month)

n- Heptane 31.9 0.9 31 97

Toluene 100 4 96 96

Acetone 33.9 2.2 31.7 94

IPA 8.4 0.36 8.04 96

20

11-[4-[2-(2-Hydroxy ethoxy) ethyl]-1-

piperazinyl] dibenzo (b, f) (1,4) thiazepine

hemifumarate

(8.0 MT/Month)

Toluene 142 4.8 137.2 97

Methanol 37.3 1.52 35.78 96

21

2-[[(4-(3-methoxypropoxy)-3-methyl- 2-

pyridinyl)methyl]thio]-1H-benzimidazole

(10.0 MT/Month)

Iso Propyl HCL 49.6 1.09 48.51 98

Methylene Di Chloride 61 1.64 59.36 97

Toluene 98.9 2.91 95.99 97

Acetone 14.7 0.73 13.97 95

22

2-[[[4-(3-methoxypropoxy)-3-methyl-2-

pyridinyl] methyl] sulfinyl] -1H-

benzimidazole – Pure

(10.0 MT/Month)

MDC 173.4 4 169.4 98

Acetonitrile 40.5 2.22 38.28 95

Note* - Solvent will be procured on need based. At a time not more than 6-8 products will be manufactured in the premises. Solvent recovery is in the range

of 91 to 99 %. The remaining solvent is going in form of distillation residue and/or getting absorbed in water scrubber or carbon tower. There will be no loss

in the air.



2.6 RESOURCE REQUIREMENT

2.6.1 INFRASTRUCTURE FACILITIES (LAND)

The site plant is locatedat Survey No.: 310/1/2/3, Madhvas, Tal. Kalol, Dist. Panchmahal-

389330, Gujarat. Land document is attached as Annexure - II.The total plot area of the unit is

6378 sq. m. The green belt area is 2110 sq. m.(33%).The plant layout is attached as Annexure –

III.

Details of breakup of plot area are covered under following Table2.8.

TABLE NO.: 2.8

LAND USE BREAK UP OF TOTAL PLOT AREA

Sr. No. Particular Land Area (sq.m.) Land Area (%)

1. Security Cabin 12.0 0.19 %

2. Rest Room 7.5 0.12 %

3. ADM/QC/QA 170.0 2.67 %

4. Ware House 330.0 5.17 %

5. Explosive yard 360.0 5.64 %

6. ETP area 228.0 3.57 %

7. Utility 182.0 2.85 %

8. Cooling tower 16.0 0.25 %

9. Transformer 17.5 0.27 %

9. HT Panel 12.5 0.20 %

10. PCC Room 30.0 0.47 %

11. Maintenance room 17.5 0.27 %

12. DG set area 36.0 0.56 %

13. Boiler Fuel storage 48.5 0.76 %

14. Chimney 6.25 0.10 %

15. Boiler Room 77.0 1.21 %

16. Plant-01 825.0 12.94 %

17. Solvent Recovery Plant 77.0 1.21 %

18. Tank Farm 126.0 1.98 %

19. Green belt Area 2110.0 33.0%

20. Open Area 1689.25 26.57%

Total 6378.0 100%

2.6.2 DETAILS OF FUEL AND ELECTRICITY CONSUMPTION

The energy requirement in terms of power and fuel for proposed unit is shown in following

Table 2.9.



TABLE NO.: 2.9

FUEL CONSUMPTION & ELECTICITY CONSUMPTION

2.6.2.1 BIO-COAL ANALYSIS DETAILS

The unit will be used the bio-coal in boiler. The Fuel analysis and Flue gas analysis report are

given in below Table 2.10.

TABLE: 2.10

BIO-COAL/FUEL ANALYSIS AND FLUE GAS ANALYSIS REPORT

Sr. No. Name of Sample Bio-Coal

Parameter Name Test Result

1 Gross Calorific Value 4000 Kcal.

2 Ash Content 3 - 5 %

3 Moisture 10%

2.6.2.2 DETAILS OF FLY ASH STORAGE, HANDLING AND DISPOSAL:

The fly ash generated from Boiler having capacity 3 TPH will be collected by Bag filter and

Multi cyclone separator. Fly ash will be generated in 250 KG/Day (90MT/Annum) quantity

which will be very less quantity. Hence, no need to sprinkles the water. It will be stored in HDPE

bags and send to Bricks/ Tiles/ Blocks manufacturer. MOU with Bricks manufacturer is attached

as annexure-X. Unit will be follow management of fly ash as per Fly Ash Notification, 2009.

2.6.3 DETAILS OF ENERGY DISTRIBUTION/UTILISATION AND EQUIPMENTS/

MACHINERIES

Details of energy distribution are given in below Table 2.11.

Sr. No. Particulars Requirement Remark Source

1.

Bio-coal

(Coal-in case of non-

availability of bio-coal

during monsoon)

7.0

MT/day

3 ton boiler considered

at 40% load Local

2. Saw dust 4.5 MT/day Alternate fuel for

Boiler Local

3. Electricity 500 KVA On peak load MGVCL

4. Diesel 80 Lit/Hr Use for DG set in

emergency case Local



TABLE: 2.11

DETAILS OF PLANT AND MACHINERY ALONG WITH ENERGY REQUIREMENT

Sr. No. Name of Equipment Connected Energy in KVA

1. Centrifuge 11.2

2. Centrifuge 11.2

3. Centrifuge 11.2

4. Centrifuge 11.2

5. CF ML Pump 2.23

6. CF ML Pump 2.23

7. CF ML Pump 2.23

8. CF ML Pump 2.23

9. Agitated nutch filter 7.5

10. Agitated nutch filter 7.5

11. ANF ML Pump 2.23

12. ANF ML Pump 2.23

13. Vacuum Tray Dryer 5.5

14. Transfer Pump 2.23

15. Transfer pump 2.23

16. Reactor 11.2

17. Reactor 11.2

18. Reactor 11.2

19. Reactor 11.2

20 Reactor 11.2

21 Reactor 7.5

22 Reactor 11.2

23 Reactor 11.2

24 Reactor 7.5

25 Reactor 7.5

26 Reactor 11.2

27 Reactor 7.5

28 Reactor 11.2

29 Reactor 11.2

30 Reactor 11.2

31 Reactor 11.2

32 Reactor 11.2

33 Reactor 7.5

34 Reactor 7.5

35 Reactor 7.5

36 Reactor 7.5

37 Reactor 7.5

38 Reactor 7.5



Sr. No. Name of Equipment Connected Energy in KVA

39 Reactor 7.5

40 Reactor 7.5

41 Reactor 7.5

42 Reactor 7.5

43 Reactor 7.5

44 Reactor 7.5

45 Rota cone Vacuum Dryer 11.2

46 Vacuum Tray Dryer 5.5

47 Multi mill 2.2

48 Shifter 2.2

49 Cooling Tower 7.5

50 Cooling Tower Pump 15



53 Hot Water Pump 5.5

54 Hot Water Pump 5.5

55 Ejector Cooling Tower 3.7

56 CT Circulation Pump 5.5

57 Ejector Pump 7.5

58 Ejector Pump 7.5

59 Ejector Pump 7.5

60 Dry Vacuum Pump 7.5

61 Other 27.46

Total 500 KVA

2.6.4 UTILITIES

The utilities to be installed will be Boiler, Cooling tower, Compressor and Chilling plant. Details

of utilities are given in below Table 2.12.

TABLE NO.: 2.12

DETAILS OF UTILITIES

Sr. No. Name of the Utilities Capacity MOC

1. Steam Boiler 3000 KG/HR CS

2. Soft Water Plant 3 CMH FRP

3. Chilling Plant 100 TR CS

4. Primary Pump 60 CMH CS

5. Primary Pump 60 CMH CS

6 Secondary Pump 100 CMH CS




8 Brine Plant 60 TR CS

9 Primary Pump 50 CMH CS

10 Primary Pump 50 CMH CS



13 Cooling Tower 250 TR FRP

14 Chilled Water Condensing Pump 90 CMH CS

15 Chilled Water Condensing Pump 90 CMH CS

16 Chilled Brine Condensing Pump 70 CMH CS

17 Chilled Brine Condensing Pump 70 CMH CS

18 Nitrogen Plant 50 NM3/HR CS

19 Air Compressor 150 CFM CS

20 Ro Plant 3 CMH --

21 Fire Hydrant Pump 100 CMH CS

22 Joky Pump 20 CMH CS

23 Raw Water Pump 20 CMH CS

24 Raw Water Pump 20 CMH CS

2.6.5 MANPOWER

The manpower required for the project as well as during the construction/ commissioning

activities will be employed from the local area. Details of existing and proposed man power

requirement are given in below Table 2.13.

TABLE NO.: 2.13

MAN POWER REQUIREMENT

Phase of project Type of worker No. of workers (Total)

During construction Contractual 20

During commissioning Contractual 35

Total During construction 55

During operations

Managerial 7

Skilled 25

Un-skilled 70

Total During operations 102

Note: - Preference will be given to the local people for employment as per education

qualification.



2.7 WATER REQUIREMENT

Water consumption is primarily for processing, washing, boiler, cooling, RO plant, gardening

and domestic purpose. The fresh water requirement for domestic and industrial purpose will be

met through bore well. Effluent will be treated in ETP and RO & recycle back in the unit. Unit

will achieve zero liquid discharge.

Average daily fresh water consumption of the unit will be approx.77.0 KL/day and recovered

water consumption is 145.0 KL/day. So, total water consumption will be 222.0 KL/day (145.0

KL/day of recycled water + 77.0 KL/day of fresh water). Stream wise bifurcation of water

consumption is given in Table 2.14.

TABLE NO.: 2.14

DETAILS OF WATER CONSUMPTION

Category Water Consumption (KLD) Remarks

(A) Domestic 20.0 20.0 KLD Fresh

(B) Gardening 10.0 10.0 KLD Fresh

(C) Industrial

i. Process 85.0 85.0 KLD Recycle

ii. Boiler 30.0 30.0 KLD Fresh

iii. Cooling 40.0 17.0 KLD Fresh + 23.0 KLD Recycle

iv. Washing 27.0 27.0 KLD Recycle

v. Others 10.0 10.0 KLD Recycle - For Scrubber

Industrial Total 192.0 47.0 KLD Fresh + 145.0 KLD Recycle

Total (A+ B +C) 222.0 77.0 KLD Fresh + 145.0 KLD Recycle



FIGURE: 2.2

WATERBALANCE DIAGRAM

2.8 WASTE WATER MANAGEMENT

The details of waste water generation are given in below Table 2.15.

2.8.1 WASTE WATER GENERATION DETAILS

Domestic effluent (15.0 KLD) will be disposed in soak pit system.

Total industrial effluent generation will be 162.0 KL/Day. It will be treated in Effluent treatment

plant, RO Plant &MEE. After that it will be reused in the unit. Out of 162 KLD Industrial

effluent, 7.0 KLD solvent stripper will be sent to co-processing. Unit will achieve zero liquid

discharge. The project proponent, Zero Liquid Discharge will be ensured and no waste/treated water will

be discharged outside the premises. The details of waste water generation are given in below Table

2.15.



TABLE NO.: 2.15

DETAILS OF WASTE WATER GENERATION

2.8.2 PRODUCT WISE WASTE WATER GENERATION DETAILS

Unit will be manufacturing total 23 products. But at a time, 6-8 products will be manufactured.

Products will be manufactured on campaign basis. The details of product wise waste water

generation with qualitative and quantitative analysis of each waste stream are given in below

Table 2.16.

Category Wastewater

generation(KLD) Remarks

(A) Domestic 15.0 To soak pit

(B) Industrial

i. Process 120.0 Send to ETP for treatment

ii. Boiler 3.0 Send to ETP for treatment

iii. Cooling 2.0 Send to ETP for treatment

iv. Washing 27.0 Send to ETP for treatment

v. Others 10.0 Send to ETP for treatment

Total Industrial

waste water 162.0

Effluent will be treated in ETP, RO and

MEE. Recycle back in the unit. Unit will

achieve zero liquid discharge.

Total (A + B) 177.0 ------



TABLE NO.: 2.16

DETAILS OF PRODUCT WISE WASTE WATER GENERATION WITH QUALITATIVE AND QUANTITATIVE ANALYSIS

Sr.

No. Name of Products

Product

Quantity

Effluent

generation Analysis of Important parameter

TPM KL/Day pH COD in

mg/L

COD in

KG/Day

BOD in

mg/L

BOD in

KG/Day

TSS in

mg/L

TSS in

KG/Day

TDS in

mg/L

TDS in

KG/Day

1 5-Nitrofurfural diacetate 3 3.45 5.8 1800 6.21 1900 6.56 565 1.95 925 3.19

2 1 amino hydantoin

Hydrochloride 3 1.37 6.5 1775 2.43 1550 2.12 425 0.58 680 0.93

3 Phosphoryl choline chloride,

calcium salt 7 1.12 7.2 1895 2.12 1450 1.62 375 0.42 625 0.70

4 Citicoline (CTS) tech 5 4.443 6.9 1800 8.00 1545 6.86 425 1.89 780 3.47

5 2-(4-Aminopentyl (Ethyl)

Amino) Ethanol 10 0

0.00

0.00

0.00

0.00

6 3-Quinuclidinone 10 4.2 7.4 1700 7.14 1350 5.67 550 2.31 725 3.05

7

1-Ethyl-3-(3-Dimethylamino

propyl) Carbodimide.

Hydrochloride

15 3.4 6.5 1850 6.29 1425 4.85 375 1.28 640 2.18

8 3-(1-cyanoethyl) benzoic acid 15 12 7.1 1900 22.80 1785 21.42 560 6.72 850 10.20

9

1-(p-methoxy benzyl)-1,2,3,4,5,

6,7,8,Octahydro isoquinaline-

S-octa base

8 5.185 5.2 2500 12.96 1800 9.33 550 2.85 880 4.56

10 Dextrometharphin free base 8 8.013 8.9 2600 20.83 1900 15.22 450 3.61 900 7.21

11

cis-2-(2,4-Dichloro phenyl)-2-

(1H-1,2,4-triazol-1-yl-methyl)-

1,3- dioxolan-4-yl methyl

10 11.159 9.2 2200 24.55 1750 19.53 300 3.35 650 7.25



Sr.


Product

Quantity

Effluent



mg/L

COD in

KG/Day

BOD in

mg/L

BOD in

KG/Day

TSS in

mg/L

TSS in

KG/Day

TDS in

mg/L

TDS in

KG/Day

methane sulfonate - Crude

12

cis-2-(2,4-Dichloro phenyl)-2-

(1H-1,2,4-triazol-1-yl-methyl)-

1,3-dioxolan-4-yl methyl

methane sulfonate-Pure

8 1.435 8.5 2600 3.73 1800 2.58 475 0.68 775 1.11

13 Phenyl (1h pyrrole-2-yl)Methan

one -tricarboxylate crude 10 11.972 8.2 3000 35.92 1950 23.35 525 6.29 785 9.40

14

(-)-1-[(4-Chlorophenyl)phenyl

methyl]-4-[(4-methylphenyl)

sulfonyl] piperazine

6 11.74 8.8 2800 32.87 1850 21.72 600 7.04 550 6.46

15 p-Chloro benzhydryl piperazine 6 2.07 8.4 2900 6.00 1750 3.62 550 1.14 685 1.42

16



compound

5 4.132 7.7 2200 9.09 1600 6.61 425 1.76 575 2.38

17 3,4-dimethoxy-2-chloro methyl

pyridine 10 1.876 7.8 1800 3.38 1550 2.91 375 0.70 650 1.22

18 pentaprozole sulphide 10 1.195 8.3 1600 1.91 1800 2.15 425 0.51 600 0.72

19 Pregabalin (Racemic) 8 1.571 8.1 2100 3.30 1950 3.06 575 0.90 675 1.06

20 11-Piperazinyl-dibenzo(b,f)

(1,4)-thiazepine hydrochloride 8 5.946 7.2 1800 10.70 1800 10.70 475 2.82 625 3.72

21

11-[4-[2-(2-Hydroxy ethoxy)

ethyl]-1-piperazinyl] dibenzo

(b, f) (1, 4) thiazepine

hemifumarate

8 1.573 6.8 1550 2.44 1450 2.28 480 0.76 700 1.10



Sr.


Product

Quantity

Effluent



mg/L

COD in

KG/Day

BOD in

mg/L

BOD in

KG/Day

TSS in

mg/L

TSS in

KG/Day

TDS in

mg/L

TDS in

KG/Day

22

2-[[(4-(3-methoxypropoxy)-3-

methyl- 2-pyridinyl)methyl]

thio]-1H-benzimidazole

10 2.889 5.9 1880 5.43 1700 4.91 690 1.99 875 2.53

23

2-[[[4-(3-methoxypropoxy)-3-

methyl-2-pyridinyl]methyl]

sulfinyl]-1H-benzimidazole

10 1.751 7.7 1850 3.24 1650 2.89 675 1.18 800 1.40

Note* - At a time not more than 6-8 products will be manufactured in the premises.



2.9 EFFLUENT TREATMENT PLANT PROCESS

OIL & GREASE TRAP: The combined effluent from the plant is come by gravity in to the oil

& Grease trap unit where the oil & grease is separated & cleared effluent goes to the

Equalization cum Neutralization tank by gravity.

EQUALIZATION TANK: The effluent from the oil & grease trap is collected in the

Equalization tank for equalizing the hydraulic and organic load. This is achieved by running the

blower continuously. Provision for neutralization is made herewith help of lime solution

depending on the pH of the effluent. The neutralizing agents will be dosed from the dosing tank.

The pH is to be intermittently checked with the help of pH papers till a pH value of 7.0 is

achieved. The equalized and neutralized effluent will be pumped through Effluent transfer

pumps to Flash Mixer tank for chemical treatment process.

FLASH MIXER: From the equalization tank the neutralized effluent is pumped to the flash

mixer tank, where the polyelectrolyte & poly Aluminium Chloride sol. is added .Here the

agitator provided for the fast mixing of the Effluent & dosing chemicals. Then effluent overflows

to next stage that is Primary Clariflocculator (PCF).

PRIMARY CLARIFLOCCULATOR TANK: The effluent comes to the PCF tank from the

flash mixer by gravity. In the primary settling tank effluent along with the chemical Sludge

(Flocks) flow to the tank for settlement of the sludge for good Quality of the supernatant &

increasing the retention time the tube settler Media is provided in the PCF. The settled sludge

Pumped to the sludge sump. The overflow effluent goes to the next stage for Biological

treatment.

SLUDGE SUMP: The sludge from the primary treatment collected in the sludge sump. The

sludge pumped to the filter press for the dewatering of the sludge. After dewatering the sludge

the sludge is packed in bags & stored in hazardous waste storage room.

ACTIVETED SLUDGE TREATMENT: Secondary treatment envisages biological

degradation of effluents. As the Organic load is very high, the treatment will be given in stages.

The units are as follows:

• Aeration Tank-1 with Floating Aerator.

• Secondary clarifier -1

• Aeration Tank-2 With Floating aerator.

• Secondary clarifier-2

• Sludge Drying Beds



AERATION TANK-1: Being Aerobic system, oxygen is supplied through Floating aerators.

The Biomass is in the form of sludge. The mixed liquor developed in the Aeration Tank help in

the degradation of organics. The effluent along with sludge flows to the secondary clarifier-1 for

settlement of the biomass. The settled bio-sludge will be pumped back to the Aeration Tank to

maintain the required concentrations of MLSS in the Aeration tank.

AERATION TANK-2 / SETTLING TANK-2 : The over flow from the secondary clarifier -1

flow to the Aeration Tank-2 for further degradation of effluents. The mixed liquor flows to the

Secondary clarifier-2 for settling of the solids. The settled bio-sludge is pumped back to the

Aeration tank-2 maintain the required concentration of MLSS in the Tank.

SLUDGE DRYING BEDS: The excess sludge is drained to the sludge drying beds. The dried

sludge from the sludge drying Beds is sent to GPCB approved TSDF site.

TREATED SUMP: The overflow from the secondary clrifier-2, which is treated effluent, is

pumped to Ro feed tank through filters to remove TSS.

TERTIARY TREATMENT: Tertiary treatment consists of following:

• Sand filter.

• PHE

• High pressure pumps.

• RO plant.

This is Polishing process. The effluent is pumped through high- pressure pumps to sand filter and

PHE to maintain turbidity and temperature and is suitably fed to RO Plant which is generating

Permeate which is reused and reject which is treated in MEE. The condensate of MEE enters

ETP feed and the sludge produced is sent to GPCB approved TSDF site.

Details of ETP equipment are given in Table 2.17 and characteristics of wastewater before

treatment & after treatment are given in Table 2.18.

TABLE NO.:2.17

EQUIPMENT LIST OF EFFLUENT TREATMENT PLANT

Sr. No Equipments Capacity Purpose Remarks

1 Oil & Grease Trap 20.0 m3 To remove oil & grease RCC Tank

2

Equalization &

Neutralization Tank (2

Nos)

60 m3

To Collect, equalize &

neutralize the organic load RCC Tank

3 Flash Mixer 2.0 m3 For fast mixing of the effluent

& coagulant chemicals RCC Tank

4 Primary Clarifier 20 m3 For slow mixing & flocks

formation RCC Tank

5 Sludge Sump 20 m3 For collection of the sludge RCC Tank



Sr. No Equipments Capacity Purpose Remarks

6 Aeration tank-1 400m3 To achieve Biological

Degradation of Organic matter RCC Tank

7 Secondary Clarifier-1 20.0 m3 To settle effluent for removing

suspended solids RCC Tank

8 Aeration Tank-2 200 m3 To achieve further degradation

of effluents RCC Tank

9 Secondary Settling

Tank-2 20 m3

To settle effluent for removing

suspended solids. RCC Tank

10 Treated water collection

sump 50 m3 To collect the treated effluent RCC Tank

11 Sludge Drying Bed 40 m3 For dewatering sludge. Brickwork

12 RO Feed Tank 10 m3 To collect the treated effluent RCC Tank

14 Lime Dosing Tank 1000 lit To prepare the lime sol. HDPE

15 HCL Dosing tank 1000 lit To store the HCl HDPE

16 Polyelectrolyte Dosing

Tank 200 lit

To prepare the Polyelectrolyte

Sol HDPE

17 Poly Aluminum

Chloride Dosing Tank 1000 lit

To prepare the Poly Aluminium

Chloride Sol HDPE

18 Floating Aerators for

Stage-1 25 HP

To supply oxygen for biomass

to get proper degradation -

19 Floating Aeration for

Stage-2 25 HP

To Supply oxygen for biomass

to get further degradation -

20 Sludge return pumps 4.5 - 8

L/S

To pump the sludge to aeration

tank to maintain MLSS -

21 High Pressure Pumps 8 m3/hr

To pump the treated effluent to

Pressure Sand Filter &

Activated Carbon Filter.

-

22 Sand Filter 2 m3 To remove TSS and turbidity. -

23 Blower for Eq. Tank 7.5 HP To achieve the proper mixing of

effluent -

24 Reverse Osmosis 100 KLD To achieve High TDS treatment

of effluent -

25 Multiple Effective

Evaporator 50 KLD

To achieve further treatment of

effluent -

TABLE NO.: 2.18

CHARACTERISTICS OF WASTEWATER BEFORE &AFTER TREATMENT

Sr. No. Parameters Before Treatment After Treatment

1 pH 3.9-8 6.8-7.5

2 Colour in Hazen <1200 10-20

3 T.S.S in mg/L < 150 < 50

4 T.D.S. in mg/L < 5000 6000-7000

5 B.O.D. in mg/L < 1500 < 150



6 C.O.D. in mg/L < 10000 < 2000

TABLE NO.: 2.19

EFFLUENT QUALITY AT R.O.

Sr. No. Parameters Before Treatment Permeate Reject

1 pH 6.8-7.5 6.8-7.5 6.8-7.5

2 Colour in Hazen 10-20 5-10 <100

3 T.S.S in mg/L < 50 < 15 <100

4 T.D.S. in mg/L 6000-7000 <450 <12000

5 B.O.D. in mg/L < 150 < 30 <600

6 C.O.D. in mg/L < 2000 < 100 <3000

TABLE NO.: 2.20

EFFLUENT QUALITY AT MEE AND ATFD

Sr. No. Parameters Inlet quality to MEE MEE

Condensate

ATFD

Condensate

1. pH 6.8-7.5 8.0-8.5 7.0-7.5

2. T.S.S in mg/L <100 <50 <150

3. T.D.S. in mg/L <12000 200-300 30000-40000

4. C.O.D. in mg/L <3000 <50 7000-8000

TABLE NO.: 2.21

CHARACTERISTICS OF HIGH COD EFFLUENT

Sr. No. Parameters Before Treatment After MEE Stripper MEE Stripper

1 pH 2-6 6-7.5 6-7.5

2 Colour <1200 <1000 10-20

3 T.S.S in mg/L < 150 <150 <20

4 T.D.S. in mg/L 5000-25000 5000-25000 200-300

5 B.O.D. in mg/L 4000-6000 < 150 30000-50000

6 C.O.D. in mg/L 10000-25000 < 2000 100000-

150000



Details of ETP flow diagram are given in Figure 2.3.

FIGURE2.3

FLOW DIAGRAM OF EFFLUENT TREATMENT PLANT



2.9.1 SEWAGE GENERATION OR DOMESTIC WASTE WATER

The sewage generation will be 15.0 KL/Day, which will be sent to soak pit/septic tank.

2.10 GASEOUS EMISSION

The source of air pollution will be in a form of flue gas emission and process emission.To

control the emission of pollutants from these sources stacks will be installed of appropriate

height and diameter.

2.10.1 FLUE GAS EMISSION

The sources of flue gas emission is from 3 TPH Boiler. 1 No. of D.G. setof 600 KVA capacity

will be installed which will be used only in-case of emergencies /power failure.

Details of stack height, fuel consumption, air pollution control system etc. are shown in below

Table 2.22.

TABLE NO.: 2.22

DETAILS OF FLUE GAS EMISSION

Stack

No.

Stack Attached

to

Fuel

Consumption

Stack

Height

(m)

APCM Parameter Permissible

Limit

1. Boiler (3 TPH)

Bio-coal-

7.0 MT/Day

Or

Saw dust-

4.5 MT/Day

11.0

Multi

cyclone

separator &

bag filter

Particulate

Matter

SO2

NOx

150

mg/Nm3

100 ppm

50 ppm 2.

D. G. Set

(Cap.-600 KVA)

(Stand by)

Diesel

80 Lit/hr. 9.0

Adequate

stack height

Note: DG set will be run only in case of electricity failure.

2.10.2 PROCESS EMISSION

For Process emission, 3 nos. of Scrubbers will be attached to the Reactors. There will be one 2

stage water scrubber and 2 nos. of Alkali scrubbers which will be installed as APCM. The

process emissions are as given in the Table 2.23-A.

TABLE NO.: 2.23-A

DETAILS OF PROCESS EMISSION

Stack

No.

Stack Attached

to

Stack

Height (m) APCM Parameter

Permissible

Limit

1. Reactor- I 11.0 2 Stage water scrubber Ammonia 175 mg/ Nm3

2. Reactor - II 11.0 Alkali scrubber Chlorine 9.0 mg/ Nm3

3. Reactor – III 11.0 Alkali scrubber HCl

NOx

20.0 mg/ Nm3

50 ppm



2.10.3 DETAILS OF SCRUBBERS

1. Alkali scrubber attached to Reactor-II for Chlorine gas

The scrubbing system consists of a scrubber (packed column absorber), an exhaust blower and

scrubbing media circulation via pump. The excess chlorine vapors coming from the plant is

enters the Alkali scrubber where they are absorbed in caustic solution. Thus, the air leaving from

the scrubber is clean. The solution which is recycled in scrubber and after recycling several times

effluent from scrubber is subjected to effluent treatment plant completely. Thus, the air leaving

from the Alkali scrubber is clean.

2. Alkali scrubber attached to Reactor-III for HCl and NOx gas

The scrubbing system consists of a scrubber (packed column absorber), an exhaust blower and

scrubbing media circulation via pump. The excess HCl and NOx vapors coming from the plant is

enters in the Alkali scrubber where they are absorbed in caustic solution. Thus, the air leaving

from the scrubber is clean. The solution which is recycled in scrubber and after recycling several

times effluent from scrubber is subjected to effluent treatment plant completely. Thus, the air

leaving from the Alkali scrubber is clean.

Flow diagram of alkali scrubber for each plant is given below figure.

FIGURE 2.4

DIAGRAM OF ALKALI SCRUBBER ATTACHED WITH REACTOR- II & REACTOR-III

3. Two stage water scrubber attached to Reactor-I for Ammonia

Ammonia gas is generated from reactor- I through inlet line and send to the Primary scrubber

and Secondary scrubber are shown in the below figure.



Primary water scrubber: Un-reacted ammonia gas coming from the plant reactor is scrubbed in

primary water scrubber. Here, most of gas is scrubbed through re-circulation of water and un-

reacted gas goes to secondary water scrubber.

Secondary water scrubber: Unreached gas coming from the primary scrubber. Again un-

reacted gas is scrubbed through re-circulation water and the air leaving from the scrubber is

clean. Hence, no adverse impact in air environment.

FIGURE 2.5

DIAGRAM OF TWO STAGE WATER SCRUBBER

2.10.3.1 ADEQUACY OF APCM:

The APCM systems proposed by the unit are more than adequate. For water soluble NH3, and

Cl2, HCl & NOx alkali scrubbers are provided. For Ammonia two stage water scrubber are

provided. Calculations are given in the Table 2.23.B. The designing is done considering all

products are running at the time based on maximum worst case scenario. Looking towards

number of reactors, it is unlikely that such a situation will ever arise. Adsorbed solution will go

as effluent at ETP. However, for designing purposed the quantity is shown as going to scrubber.

Thus the air pollution management seems to be adequate.

TABLE: 2.23-B

QUANTITY OF AIR POLLUTANTS COMING OUT OF REACTOR

Sr.

No.

Name of

Product

Air

Pollutant APCM

Quantity of air

pollutant

Ton/Ton before

APCM

Quantity of air

pollutant Ton/Ton

after APCM

1. Reactor- I Excess

NH3

Two stage water

scrubber 2.3 0.03

2. Reactor - II Excess Cl2 Alkali scrubber 0.2 NIL

3. Reactor – III HCl

NOx Alkali scrubber 2.6 0.04



2.11 HAZARDOUS WASTE GENERATION

The following type of hazardous waste will be generated from the operational activities.

The collection, treatment and disposal of hazardous waste will be as per Hazardous

waste (Management and Handling) Rules 2016, and hence no adverse impact on land

environment is envisaged. It will be stored separately in dry & covered place with RCC platform.

There will be provision of separate storage area of 75.0 sq.m. Hazardous waste will be stored in

proper storage room and handed over to authorized vendor for final disposal. Details of

Hazardous Waste generation, storage and disposal facility are shown in Table 2.24.

TABLE NO.: 2.24

DETAILS OF HAZARDOUS WASTE GENERATION

Sr.

No.

Type of

Wastes

Categ

ory

Source of

Generation

Quantity

MTA Mode of disposal

1 ETP Sludge 34.3 Effluent Treatment 7115

Collection, Storage within premises,

Transportation and Disposal at TSDF

site.

2 Used Oil 5.1

Maintenance &

used lubricant oil

generated from

maintenance

activities

0.400

Collection and Storage within

premises & Disposal by selling to

registered re-processor.

3

Discarded

Containers/

Bags/Liners

33.3 Packing Materials 240

Collection, Storage and

Decontamination within premises &

Disposal by selling to authorized re-

cycler.

4 Process Residue 28.1

Mfg. Product from-

sr. no. 6, 15, 16, 17,

18, 20, 21, 22, 23

8415

Collection, Storage, Transportation

and Selling to authorize recycler/ co-

processing /Cement Industries.

5 Spent Carbon 28.3

Mfg. Product from-

sr. no. 4, 11, 12, 13,

14, 15, 22, 23

25 Collection, Storage, transportation and

send for co-processing /Cement

Industries. ETP 24

6 Spent catalyst 28.2

Mfg. Product from-

sr. no. 4, 11, 12, 13,

14, 15, 22, 23

1650


Transportation for regeneration to

authorized units/ co-processing.

7 Scrubber

solution ---

Mfg. Process to

Scrubbers 3000

Collection, Storage and send to in

house ETP for treatment.

8. Stripper solvent 28.6 Effluent Treatment 2520

Collection, storage and send to co-

processing for solvent recovery

having under Rule: 9 permission.

9 MEE Salt 37.3 MEE 3600


Transportation and Disposal at TSDF

site.



2.12 PROJECT COST ESTIMATES

A Budget allocation for project and effective Environmental Monitoring Plan (EMP) is proposed

in Table 2.25.

TABLE NO.: 2.25

BUDGET OF ALL LOCATION FOR ENVIRONMENTAL MANAGEMENT

CONSTRUCTION PHASE

Sr.

No Pollution Control Measures Cost (Lacs)

1. Dust suppression during construction 10.0

2. Solid waste management facility 15.0

3. Environment Monitoring

(Monitoring charges for air, water, noise ) 5.0

4. Occupational Health

(Includes cost of medical check-up, PPE & first aid kit and

PPE, first aid facility, safe drinking water plant & sanitation

measures)

1.0

TOTAL 31.0

OPERATION PHASE

Sr.

No Pollution Control Measures

Approximate

Capital Cost

(Rs. In Lacs)

Approximate Recurring

cost per Annum

(Rs. In Lacs)

1. Air Pollution Control 25 15

2. Safety Equipment (PPE, Ventilation,etc.) 25 3

3. Hazardous waste management 20 615

4. ETP Plant 125 165

4. Fire 15 5

5. Green belt development 10 2

TOTAL 220 807

10 Membranes --- RO Plant 2 Collection, Storage, transportation and

send for co-processing / TSDF site.

NON-HAZARDOUS WASTE

11 Fly ash -- From boiler fuel 90

Collection, Storage, transportation and

send to Bricks/ Tiles/ Blocks

manufacturer.

MOU with Bricks manufacturer is

attached as annexure-X.



2.13 ADEQUACY OF THE EMS

AIR:

For flue gas emission from vent of attached to Boiler having capacity 3 TPH and D. G. set

having capacity 600 KVA. To control the emission, adequate stack height will be provided.

For Process emission, 3 nos. of Reactors will be installed with 2 stage water scrubber and 2 nos.

of Alkali scrubbers which will be installed as APCM.

WATER:

The water will supply from Own Bore well.

Total water consumption will be 222.0 KL/Day (77.0 KLD Fresh + 145.0 KLD Recycle). Total

wastewater generation will be 177.0 KL/Day. From this waste water generation quantity, 15.0

KL/Day of sewage effluent will be disposed to soak pit and 162.0 KL/Day industrial Effluent

will be treated in ETP, RO followed by MEE system & recycle back in the unit. Unit will


HAZARDOUS WASTE:

In hazardous waste generation, ETP sludge (7115 MT/Annum), used oil (0.400 KL/Annum),

discarded containers/bags/liners (240 MT/Annum), Process residue (8415 MT/Annum) and spent

carbon (49 MT/Annum), spent catalyst (1650 MT/Annum), Stripper solvents (2520 MT/Annum),

MEE salt (3600 MT/Annum), RO membranes (2 MT/Annum) & fly ash (90 MT/Annum).

Mode of disposal, ETP sludge /MEE salt will be disposed to TSDF site. Used oil will sell to

registered re-processor. Discarded containers/ bags/liners will be disposed by selling to authorize

re-cycler. Process residue and spent carbon will be send for authorize recycler/ co-processing

/Cement Industries. Spent catalyst will be regeneration to authorized units/ co-processing.

Scrubber solution will be send to ETP for treatment. Stripper solvent will be send for solvent

recovery/ co-processing/ solvent recovery under rule-9 permission. Membranes will be send for

co- processing site. Fly ash will be sent to bricks manufacturer.

CONCLUSION:

The environment management plan given by M/s. Ishanga Life science Pvt. Ltd. for air, water

and hazardous waste is adequate as per the worst-case scenario.



CHAPTER – 3

BASELINE ENVIRONMENT STATUS

3.1 INTRODUCTION

It is essential to monitor the environment quality prevailing in the surrounding area before

implementation of the any project for assessing the environmental impacts. The Environment

status within the study area could be used for identification of significant environmental issues

to be addressed in the impact assessment study.

The impact from proposed industrial project on its surrounding environment will be mainly

regulated by,

• The nature of the pollutants

• Their quantities discharged to the environment

• Existing environment quality

• Assimilative capacity of the surrounding environment

• Topography and terrain of the project site

In order to identify and establish the extent of likely impacts, it is necessary to gather

information on environmental quality relating to various components of the environment.

Primary data were collected for baseline collection. Secondary data were also gathered for

remaining information like meteorological data, Socio-economic data, Ecological data and

Land use data. For the purpose of collection of primary data, study area was selected within 10

km radius taking project site as a center which also included towns and villages.

The main factor of local, sub-regional and regional meteorology that influence the air quality in

area of the proposed project are diurnal and seasonal wind pattern and wind direction,

humidity, temperature etc.

Madhvas is a developing industrial center having the advantage of close proximity to Kalol.

Due to SH-87, Madhvas is well connected by road to rest parts of the country. Communication

facility available in the area is good. Water will be supplied from own borewell.

At present there are some neighbour industries located in this area. Lists of industries are given

in Table 3.1.



TABLE: 3.1

LIST OF NEIGHBOUR INDUSTRIES

Sr. No. Industries Distance from Site Direction

1 M/s. CEAT Tyre

Getmuvada,

PO: Chandrapura, Tal: Halol,

Dist.: Panchmahal

South

4.84 km

2 M/s. Panchmahal

Steel

GIDC Industrial Estate, Kalol, Dist.:

Panchmahal, Gujarat 389330

NE

6.7 Km

3 M/s. Avdhut Steel

Pvt. Ltd.

Survey No.: 230/1, Madhvas, Tal: Kalol,

Dist.: Panchmahal

SE

0.76 Km

4 M/s. Hero Moto

Corp. Ltd.

Halol Bypass Rd,

Dhara Nagar, Kanjari Part, Halol, Dist:

Panchmahal

East

2.67 Km

5

M/s. Safari

Industries (India)

Ltd.

Abhetwa, Halol- 389350,

Dist.: Panchmahal

SSE

6.66 Km

3.2 WINDROSE

Based on the meteorological data like hourly wind speed, hourly wind direction, hourly

temperature, humidity and monthly rainfall of Halol station, wind rose have been prepared for

the winter season period between October 2018 to January 2019. The wind rose diagram

prepared from same data is shown at Figure 3.1(A), Figure 3.1(B) Figure 3.2.

TABLE: 3.2

METEOROLOGICAL DATA

(Data from Indian Meteorological Department, Halol)

Month

Temp. (°C) Relative

Humidity

(%)

Wind Speed

km/hr

Rainfall

mm Min. Max. Average

Oct-18 26 36 32 36% 6.4 0.0

Nov-18 23 35 29 32% 7.1 0.0

Dec-18 18 29 24 32% 9.8 0.0

Jan- 19 19 31 25 29% 8.4 0.0



FIGURE: 3.1(A)

WIND ROSE DIAGARM FOR PERIOD OF OCTOBER-2018 TO JANUARY-2019

FIGURE: 3.1(B)

WIND ROSE DIAGARM ON SATELITE IMAGE

It was observed that wind is blowing mainly towards the WSW direction from NEE. Average

wind speed was 3.5 m/s with calm winds recorded to be 0.51%.

N

N



FIGURE: 3.2

WIND CLASS FREQUENCY DISRTIBUTION

3.3. AIR ENVIRONMENT

3.3.1 AMBIENT AIR QUALITY (AAQ)

The basic objective of collection of baseline data for air environment is to identify project

specific air pollutants being released into atmosphere, which will have significant impact on air

environment of immediate locality of the project site. For assessment of the baseline data it is

important to specify the study area in respect of the location of the project. It was decided to

the study ambient air quality at 9 locations including with project site in the different directions

in probable impact zone including the project site.

3.3.1.1 LOCATION OF AAQ MONITORING STATIONS

Ambient Air Quality stations were chooses considering the various factors like the most

prevailing wind direction, pockets of habitation, available infrastructure facilities like power

supply, accessibility etc. The location of AAQ monitoring stations are shown in Figure 3.3 and

Table 3.3.



TABLE: 3.3

DETAILS OF SAMPLING LOCATION OF AMBIENT AIR

Sr.

No. Sampling locations

Sample

ID

Distance & Direction

w.r.t project site Type of Area

1. Project Site A1 ------ Residential Area

2. Alindra A2 1.44 km, NNE Residential Area

3. Varsada A3 8.93 km, ESE Residential Area

4. Halol A4 8.42 km, SSE Residential Area

5. Kanjari A5 6.86 km, SSW Residential Area

6. Khakharia A6 5.63 km, WSW Residential Area

7. Tulsipura A7 7.84 km, West Residential Area

8. Boru A8 4.02 km, NNW Residential Area

9. Kalol A9 4.16 km, NNE Residential Area

FIGURE: 3.3

LOCATION OF AMBIENT AIR QUALITY MONITORING STATIONS

3.3.1.2 BASE LINE DATA

The ambient air quality monitoring was carried out during period of 15th Oct, 2018 to 15th Jan,

2019. Location wise monitoring details are attached as Annexure-XIII and photographs of

monitoring are attached as Annexure-XIV-A. The frequency of monitoring was twice in a

week for a period of 12 weeks to assess the existing the sub regional air quality status. All the

sampling locations were monitored for PM10, PM2.5, SO2, NOX, VOC, HCl, Cl2, NH3 & CO on

N



24 hr basis to enable the comparison with ambient air quality standards prescribed by the

CPCB.

Based on the data obtained through ambient air quality survey statement showing maximum,

minimum average concentration values of different monitoring location in the study area have

been computed and presented at Table 3.4.

TABLE: 3.4

AMBIENT AIR QUALITY STATUS OF STUDY AREA

Location Min. Value Max. Value Avg. Value 98 Percentile

PM10 (Permissible Limit (CPCB standard) : 100 µg/m3)

Project Site (A1) 70 78 74 78

Alindra(A2) 72 74 73 74

Varsada (A3) 70 74 72 74

Halol (A4) 74 82 78 82

Kanjari (A5) 73 77 75 77

Khakharia (A6) 70 76 73 76

Tulsipura (A7) 69 75 72 75

Boru (A8) 70 76 73 76

Kalol (A9) 74 80 77 80

PM2.5 (Permissible Limit (CPCB standard) : 60 µg/m3)


Alindra(A2) 39 45 42 45

Varsada (A3) 40 46 43 46

Halol (A4) 43 49 46 49

Kanjari (A5) 40 48 44 48

Khakharia (A6) 41 45 43 45

Tulsipura (A7) 40 44 42 44

Boru (A8) 39 47 43 47

Kalol (A9) 42 48 45 48

SO2 µg/m3(Permissible Limit (CPCB standard):80 µg/m3)


Alindra(A2) 10 18 14 18

Varsada (A3) 14 16 15 16

Halol (A4) 22 28 25 28

Kanjari (A5) 11 13 12 13

Khakharia (A6) 14 18 16 18

Tulsipura (A7) 12 14 13 14

Boru (A8) 10 18 14 18

Kalol (A9) 20 26 23 26

NOx (Permissible Limit(CPCB standard): 80 µg/m3)


Alindra(A2) 10 14 12 14

Varsada (A3) 11 15 13 15

Halol (A4) 16 20 18 20




Kanjari (A5) 10 12 11 12

Khakharia (A6) 12 16 14 16

Tulsipura (A7) 10 14 12 14

Boru (A8) 11 15 13 15

Kalol (A9) 15 19 17 19

VOC (Permissible Limit(CPCB standard): NS)

Project Site (A1) 0.8 1.0 0.9 1.0

Alindra(A2) 0.3 0.5 0.4 0.5

Varsada (A3) 0.5 0.5 0.5 0.5

Halol (A4) 0.7 1.1 0.9 1.1

Kanjari (A5) 0.4 0.8 0.6 0.8

Khakharia (A6) 0.3 0.7 0.5 0.7

Tulsipura (A7) 0.2 0.6 0.4 0.6

Boru (A8) 0.3 0.7 0.5 0.7

Kalol (A9) 0.6 1.0 0.8 1.0

HCl (Permissible Limit(CPCB standard): 400 µg/m3)

Project Site (A1) BDL BDL BDL BDL

Alindra(A2) BDL BDL BDL BDL

Varsada (A3) BDL BDL BDL BDL

Halol (A4) BDL BDL BDL BDL

Kanjari (A5) BDL BDL BDL BDL

Khakharia (A6) BDL BDL BDL BDL

Tulsipura (A7) BDL BDL BDL BDL

Boru (A8) BDL BDL BDL BDL

Kalol (A9) BDL BDL BDL BDL

Cl2 (Permissible Limit(CPCB standard): NS)

Project Site (A1) BDL BDL BDL BDL

Alindra(A2) BDL BDL BDL BDL

Varsada (A3) BDL BDL BDL BDL

Halol (A4) BDL BDL BDL BDL

Kanjari (A5) BDL BDL BDL BDL

Khakharia (A6) BDL BDL BDL BDL

Tulsipura (A7) BDL BDL BDL BDL

Boru (A8) BDL BDL BDL BDL

Kalol (A9) BDL BDL BDL BDL

NH3 (Permissible Limit(CPCB standard): 400 µg/m3)

Project Site (A1) 0.7 1.5 1.1 1.5

Alindra(A2) 0.5 1.1 0.8 1.1

Varsada (A3) 0.7 1.1 0.9 1.1

Halol (A4) 7.4 7.8 7.6 7.8

Kanjari (A5) 2.1 2.7 2.4 2.7

Khakharia (A6) 3.0 3.4 3.2 3.4

Tulsipura (A7) 0.6 1 0.8 1

Boru (A8) 0.5 0.9 0.7 0.9

Kalol (A9) 0.8 1.2 1.0 1.2




CO (Permissible Limit(CPCB standard): 2 mg/m3)

Project Site (A1) 1.1 1.9 1.5 1.9

Alindra(A2) 1 1.6 1.3 1.6

Varsada (A3) 1.3 1.5 1.4 1.5

Halol (A4) 0.8 1.6 1.2 1.6

Kanjari (A5) 1 1.4 1.2 1.4

Khakharia (A6) 0.9 1.7 1.3 1.7

Tulsipura (A7) 1.2 1.6 1.4 1.6

Boru (A8) 0.8 1.4 1.1 1.4

Kalol (A9) 1.2 1.8 1.5 1.8

Note: Values denoted by symbol “<” indicates Below Detection Limits (BDL), NS: Standard

Not Specified, 8-hourly average.

OBSERVATION:

Based on data obtained, it could be stated that, during the study period the values of PM10 at

monitored locations is ranged between 69.0 – 80.0 µg/m3 while the values PM2.5 fluctuates in the

range of 39.0 – 49.0 µg/m3. The values of SO2 and NOx were observed to be in the range of 10.0

– 28.0 µg/m3 and 10.0 -20.0 µg/m3 respectively. The values of VOC were observed between

0.2-1.1 µg/m3. The values of NH3 were observed to be in range 0.5-7.8 mg/m3. The values of CO

were observed to be in range 0.8-1.9 mg/m3. The average concentration of PM10, PM2.5, SO2 ,

NOx, VOC, NH3 and CO are within prescribed limit at all locations. The values of HCl and Cl2

were recorded to be BDL.

These concentrations at all AAQM locations were primarily caused by local phenomena

including vehicular movement and natural dusting due to human activities and wind movement.

3.4 WATER ENVIRONMENT

There are two categories of water environment:

1) Ground water 2) Surface water

Nine locations with project site were selected for ground water sampling and surface water

sampling. Collected samples were analyzed for drinking water quality parameters like physic-

chemical parameters and heavy metals. During study period, the sampling was done for one

time. The map viewing location for sampling points is shown at Figure 3.4. The analysis results

are presented at Table 3.5 & 3.8.



FIGURE: 3.4

LOCATION OF GROUND WATER QUALITY MONITORING STATIONS

TABLE: 3.5

DETAILS OF GROUND WATER SAMPLING LOCATIONS

Sr.

No. Sampling locations

Sample

ID



1. Project Site GW1 ------ Residential Area

2. Alindra GW2 1.44 km, NNE Residential Area

3. Varsada GW3 8.93 km, ESE Residential Area

4. Halol GW4 8.42 km, SSE Residential Area

5. Kanjari GW5 6.86 km, SSW Residential Area

6. Khakharia GW6 5.63 km, WSW Residential Area

7. Tulsipura GW7 7.84 km, West Residential Area

8. Boru GW8 4.02 km, NNW Residential Area

9. Kalol GW9 4.16 km, NNE Residential Area

N



TABLE: 3.6

WATER QUALITY PARAMETERS (GROUND WATER SOURCES)

Parameter Unit

IS 10500 : 2012 Sampling Location (Borewell)

Desirable

Limit

Permis

sible

Limit

Project

Site-

Madhvas

Alindra Varsada Halol Kanjari Khakharia Tulsipura Boru Kalol

pH -- 6.5-8.5 6.5-8.5 7.91 7.94 7.78 7.5 7.93 7.86 8.02 8.09 7.72

Colour Pt.co.scale 5 25 1 1 2 1 1 1 1 1 1

Total Hardness mg/l 300 600 530 280 ND 800 620 270 ND 190 504

Calcium mg/l 75 200 490 200 ND 720 560 230 ND 140 496

Magnesium mg/l 30 100 10 19 ND 19 15 10 ND 12 2

Chloride mg/l 250 1000 90 74 20 180 95 70 135 50 235

Iron mg/l 0.3 1 0.7 ND 4.05 ND 0.21 0.2 0.17 0.1 0.01

Free residual

Chlorine mg/l --- --- ND ND ND ND ND ND ND ND ND

TDS mg/l 500 2000 632 289 169 1000 555 307 561 388 736

Sulphate mg/l 200 400 112 96 97 95 105 92 94 94 91

Alkalinity mg/l 200 600 696 168 216 768 480 264 480 456 456

Sodium mg/l --- --- 149.6 50.4 20.5 447 119.3 63.5 231.5 67 171

Potassium mg/l --- --- 4.7 5.4 7.8 103.8 4.6 4.7 4.8 4.9 12.9

COD mg/l 4 --- 4 4 12 12 12 4 8 4 8

BOD mg/l 1 --- ND ND ND ND ND ND ND ND ND



*ND-Not Detected

Detectable limit for Free Residual Chlorine- 1 mg/l

Observation: Observation: Quality of Ground Water

It was observed from the analysis report that:

• pH of the groundwater samples is recorded in the range of 7.5- 8.09 as against the IS: 10500 drinking water standard of 6.5 to 8.5.

• Total hardness in the groundwater samples recorded from 190 mg/l to 800 mg/l. It is found within the permissible limits (600 mg/l). Samples collected

from Halol & Kanjari, total hardness is found to be exceeding the permissible limit.

• Chloride concentrations varied from 20 mg/l to 235 mg/l in the groundwater samples which are within the limit (1000 mg/l).

• Calcium concentrations in the samples are almost found higher than the permissible limit (200 mg/l). only Alindra & Boru’s calcium concentration are in

permissible limit.

• Sulphate concentrations of all locations are found to be in the range of 91-112 mg/l.

• Magnesium concentrations varied between 2-19 mg/l. All the sample results are found to be within the permissible limits (100 mg/l).

• The level of total dissolved solids (TDS) recorded in the groundwater samples varied from 169 mg/l to 1000 mg/l.

• Total alkalinity varied from 216 mg/l to 696 mg/l in the groundwater samples. Only at project site & Halol location, alkalinity is found slightly higher than

the limit (600 mg/l).

Analysis of collected samples reveals that rests of the parameters satisfy the permissible limits as per IS 10500:2012 specified for drinking water and

H ence are suitable for drinking, however it is suggested that the water may disinfected by boiling or by use of chlorine tablets before use.



FIGURE: 3.5

LOCATION OF SURFACE WATER QUALITY MONITORING STATIONS

TABLE: 3.7

DETAILS OF SURFACE WATER SAMPLING LOCATIONS

Sr.

No Sampling locations

Sample

ID



1. Narmada River -Main Canal SW1 3.84 km, NNW Residential Area

2. Kalol SW2 4.27 km, NNE Residential Area

3. Goma River SW3 1.0 km, NE Residential Area

4. Varsada SW4 8.81 km, ESE Residential Area

5. Maswad SW5 6.60 km, SE Residential Area

6. Halol SW6 8.44 km, SSE Residential Area

7. Kanjari SW7 6.83 km, SSW Residential Area

8. Khakharia SW8 5.57 km, WSW Residential Area

9. Tulsipura SW9 7.69 km, West Residential Area

N



TABLE: 3.8

WATER QUALITY PARAMETERS (SURFACE WATER SOURCES)

Parameter Unit

Is 10500:2012 Sampling Location

Desirable

Limit

Permissi

ble Limit

Narmad

a river

(SW1)

Kalol

(SW2)

Goma

river

(SW3)

Varsada

(SW4)

Maswad

(SW5)

Halol

(SW6)

Kanjari

(SW7)

Khakhria

(SW8)

Tulsipara

(SW9)

pH -- 6.5- 8.5 6.5-8.5 7.99 7.9 7.73 8.25 8.37 8.18 7.8 7.67 7.81

Colour Pt.co.

scale 5 15 1 2 1 2 1 1 1 1 1

Odour -- UB -- UB UB UB UB UB UB UB UB UB

Total

Hardness mg/l 300 600 12 148 32 ND 24 108 64 26 38

Calcium mg/l 75 200 ND 72 16 ND 16 42 26 8 16

Magnesium mg/l 30 100 3 18 4 ND 2 16 9 4 5

Chloride mg/l 250 1000 25 160 80 25 65 35 45 20 25

Iron mg/l 0.3 1 0.26 0.54 0.4 0.95 0.29 0.48 0.9 0.4 0.4

Free

residual

Chlorine

mg/l -- -- ND ND ND ND ND ND ND ND ND

TSS mg/l -- -- 12 24 20 20 16 12 18 14 6

TDS mg/l 500 2000 142 458 322 89 188 217 168 101 146

Sulphate mg/l 200 400 8 12 10 9 9 14 15 9 8

Alkalinity mg/l 200 600 192 312 288 108 144 228 168 108 192

Sodium mg/l -- -- 19.1 183.3 98.1 26.2 57.7 27.1 26.7 19.7 19

Potassium mg/l -- -- 5.2 16.4 6 6.2 5.3 5.6 6.8 7.9 5.2

COD mg/l -- -- ND ND 12 8 4 4 8 12 4

BOD mg/l -- -- ND ND ND ND ND ND ND ND ND



Parameter Unit

Is 10500:2012 Sampling Location

Desirable

Limit

Permissi

ble Limit

Narmad

a river

(SW1)

Kalol

(SW2)

Goma

river

(SW3)

Varsada

(SW4)

Maswad

(SW5)

Halol

(SW6)

Kanjari

(SW7)

Khakhria

(SW8)

Tulsipara

(SW9)

E.Coli -- --

Shall not

be

detectabl

e in any

100 ml

sample

Absent Absent Absent Absent Absent Absent Absent Absent Absent

M.P.N

MPN

Index

/1000

ml

-- -- 3 5 5.6 9.6 5 6.3 5.6 5 9.6

UB- Unobjectionable

Observation: From the table above, it can be observed that surface water qualities in terms of various essential and desirable characteristics are

found within the limits specified by IS 10500:2012.



Sampling Method: The samples were collected as per Indian standard IS: 3025 (part-1) for

ground water and surface water quality assessment.

Analysis Method: The analysis method followed for the measuring different parameters to

evaluate water quality is given in Table 3.9.

TABLE: 3.9

METHOD OF ANALYSIS

Sr.

No Parameters Applicable Standard Method of Analysis Detection Limit

1. pH APHA(22nd Edition) 4500 H+ B Electrometric

Method 0.01

2. Color in Pt. Co. Sc.

APH (22nd Edition) Spectrophotometer

(analogous to APHA 2120 C) (Platinum Cobalt

Method)

1

3. Total hardness

(as CaCO3) in mg/l

APHA(22nd Edition) 2340 C: Page 2 – 37

EDTA Titrimetric Method 2

4. Calcium

(as Ca) in mg/l

APHA (22nd Edition) 3500- Ca : B Page 3 – 65

EDTA Titrimetric Method 2

5. Magnesium

(as Mg) in mg/l

APHA(22nd Edition) – 3500 - Mg : B Page 3 –

84 Calculation Method 2

6. Chloride

(as Cl) in mg/l

APHA(22nd Edition) 4500-Cl-B-Argentometric

method 1

7. Iron

(as Fe) in mg/l By NOVA 60 spectrophotometer (Triazine) 0.01

8. Residual Free

Chlorine in mg/l Iodometric method 1

9. TSS in mg/l APHA (22nd Edition) 2540-D-Total Suspended

Solids Dried at 103-1050C 4

10. TDS in mg/l APHA (22nd Edition) 2540 C Total Dissolved

Solid Dried at 180˚C 4

11. Sulphate

(as SO4) in mg/l

APHA (22nd Edition) 4500–SO4-2 E: Page 4-

188 Turbid metric Method/ IS 3025 (Part 24)

1986 (Reaffirmed 1986) Gravimetric Method

1

12. Alkalinity

(as CaCO3) in mg/l

APHA (22nd Edition) – 2320 B: Page 2 – 27

Titration Method 2

13. Sodium in mg/l Flame photo meter --

14. Potassium in mg/l Flame photo meter --

15. COD in mg/l APHA(22nd Edition)– 5220 B Open Reflux

Method 4

16. BOD in mg/l IS: 3025 (Part – 44) 1993

(Reaffirmed 1999) 1

17. E.coli APHA- 9221 D (Presence Absence Test) --

18. MPN Coliform

Count APHA -9221 C --



3.5 NOISE ENVIRONMENT

Noise can be defined as an unwanted sound. It interferes with speech and hearing. If intense

enough, it can damage hearing, or is otherwise irritating. Noise can also disturb natural wildlife

and ecological system.

3.5.1 RECONNAISSANCE

In order to measure the noise sources and to identify the background noise levels, the noise

pollution survey around the site was carried out.

3.5.2 METHODOLOGY FOR NOISE MONITORING

Noise standards have been designated as per the Noise Pollution (Regulation & Control) Rules,

2000 Notified by Ministry of Environment and Forests, New Delhi, February 14, 2000. The

ambient noise standards are presented in Equivalent noise levels (Leq). The measurements were

carried out at each monitoring location during day time and night time. Noise survey was

conducted using Sound Level Meter.

3.5.3 NOISE MONITORING LOCATIONS

A total of nine locations including with project site were identified for ambient noise monitoring

in the study area. The noise monitoring locations are listed in Table 3.10 and shown in Figure

3.6.

FIGURE: 3.6

LOCATION OF NOISE MONITORING STATIONS

N



TABLE: 3.10

DETAILS OF NOISE LEVEL SAMPLING LOCATIONS

Sr.

No

.

Location Sampl

e ID Area Category

LEQ (dB (A))

Day Time Night Time

1. Project Site N1 Residential Area 47-54 35-42

2. Alindra N2 Residential Area 45-52 33-40

3. Varsada N3 Residential Area 46-55 34-40

4. Halol N4 Residential Area 47-56 38-43

5. Kanjari N5 Residential Area 46-53 35-40

6. Khakharia N6 Residential Area 47-53 38-44

7. Tulsipura N7 Residential Area 45-52 35-40

8. Boru N8 Residential Area 46-54 32-38

9. Kalol N9 Residential Area 45-56 34-42

OBSERVATION: The noise levels during daytime varied from 45-52 dB (A) Leq to 47-56 dB

(A) Leq in the study area. The night time noise level in the study area is in the range of 32-38 dB

(A) Leq to 38-44 dB (A) Leq.

TABLE: 3.11

CPCB RECOMMENDATIONS FOR COMMUNITY NOISE EXPOSURE

Area

Code

Category of area Leq. (dBA) (Daytime)

(06:00 to 21:00hrs.)

Leq. (dBA) (Night time)

(21:00 to 06:00hrs.)

A Industrial area 75 70

B Commercial Area 65 55

C Residential Area 55 45

D Silence Zone 50 40

Note 1 : Silence zone is defined as areas up to 10 meters around such premises as hospitals,

education, institutions and courts. The silence zones are to be declared by the Component

Authority.

Note 2 : Mixed categories of areas should be declared as one of the four above mentioned

categories by the Component Authority and the corresponding standard shall apply.

(Source: The Noise Pollution (Regulation & Control) Rules, 2000).

3.6 SOIL ENVIRONMENT

3.6.1 BASELINE DATA

Description of soil environment has become vital particularly when the treated effluent is to be

discharge on land for disposal or treatment. The soil environment is usually described by

determining the physical and chemical characteristics of soil samples collected from site with

the help of auger/spade. The composite soil sample was collected from project site and the

villages within 10 km radius. The samples were collected to determine physical and chemical



characteristic of soil. The selected soil sampling locations are given in Table 3.12 and shown in

Figure 3.7.

TABLE: 3.12

DETAILS OF SOIL QUALITY SAMPLING LOCATIONS

Sr.

No. Location

Sample

ID



1. Project Site S1 ------ Residential Area

2. Alindra S2 1.44 km, NNE Residential Area

3. Varsada S3 8.93 km, ESE Residential Area

4. Halol S4 8.42 km, SSE Residential Area

5. Kanjari S5 6.86 km, SSW Residential Area

6. Khakharia S6 5.63 km, WSW Residential Area

7. Tulsipura S7 7.84 km,West Residential Area

8. Boru S8 4.02 km, NNW Residential Area

9. Kalol S9 4.16 km, NNE Residential Area

FIGURE: 3.7

LOCATION OF SOIL MONITORING STATIONS

TABLE: 3.13

DETAILS OF SOIL QUALITY PARAMETERS

Parameter Unit Madhvas

(Project

Site)

Kalol Varsada Halol Alindr

a

Bora Tulsipur

a

Khakhri

a

Kanjari

pH -- 7.4 8.10 7.6 7.86 7.52 7.51 7.92 8.11 7.76

Moisture % 2.20 5.4 6.9 8.4 3.5 2.6 8.6 2.9 4.2

Organic

(Loss on

ignition)

% 0.6 0.5 0.4 0.4 0.5 0.3 0.5 0.3 0.4

Calcium Meq/100gm 34.60 28.41 38.64 31.85 17.77 26.40 40.50 33.47 35.20

Magnesium Meq/100gm 5.87 9.80 7.82 11.73 19.70

Sodium Meq/100gm 3.11 2.95 4.11 3.08 2.91 4.02 3.55 3.75 4.09

N



3.7 LAND USE PATTERNS

The land use pattern of the study area has been studied by satellite imaginary picture of

National Remote Sensing Centre, Govt. of India. Details are covered in Table 3.14.

TABLE: 3.14

LAND USE STATISTICS OF THE STUDY AREA

The Proximity to Sea/Water bodies from the project site is presented in Table No.: 3.15 as

follows.

TABLE: 3.15

PROXIMITY TO SEA/WATER BODIES

Sea/ Water Bodies Aerial Distance from the Project site

Narmada Canal (Main Canal) 3.84 km, NNW

Goma River 1.00 km, NE

Karad River 0.54 km, North

Parameter Unit Madhvas

(Project

Site)

Kalol Varsada Halol Alindr

a

Bora Tulsipur

a

Khakhri

a

Kanjari

Potassium Meq/100gm 0.98 1.07 0.85 0.87 1.29 1.55 0.23 1.23 2.55 EC µmS/cm 1.55 1.50 1.26 1.42 1.99 1.30 1.56 1.30 1.41

Bulk

Density

Gm/cc 1.47 1.44 1.57 1.45 1.44 1.40 1.51 1.56 1.44

ESP % 7.6 8.6 10 9.4 8.8 8.5 8.7 9.3 10.2 Total

phosphorus

Mg/100gm 18.4 11.2 17.5 18.3 17.1 18.2 13.1 17.4 11.5

Total

Nitrogen

Mg/100gm 12.6 13.2 15.2 13.8 12.4 14.3 15.2 15.3 14.9

Nitrate Mg/100gm 4.3 2.9 5.9 5.7 5.7 4.1 5.2 4.8 5.3 Zinc Mg/100gm 5.8 3.0 3.4 3.7 4.6 5.3 5.4 3.8 4.7

Copper Mg/100gm 1.2 1.7 0.9 2.4 3.2 3.7 4.9 2.9 3.5 Iron Mg/100gm 102.6 105.

2

104.6 106.

8

103.5 104.

6

107.3 104.3 105.3

Chromium Mg/100gm 3.0 3.5 3.3 2.9 2.8 3.1 2.7 2.2 3.4 Boron Mg/100gm 1.50 1.37 3.32 2.80 3.12 2.70 1.56 2.36 3.12

Sr. No. Legends Area (Ha) Percentage

1 Habitation 783.27 2.49

2 Water Bodies 536.48 1.71

3 Industrial Area 260.93 0.83

4 Dry river bed area 194.49 0.62

5 Land with Shrubs 2898.84 9.23

6 Land without Shrubs 4.92 0.01

7 Agriculture Land 26737 85.11

Total 31415.93 100.0%



FIGURE: 3.8

LAND COVER MAP WITH VILLAGE LOCATION / LAND USE MAP WITH STUDY AREA



3.8 GEOLOGICAL, BIOLOGICAL ENVIRONMENT FEATURES OF THE AREA

3.8.1 PHYSIOGRAPHY:

The district has high variation in topography which represents the diverse geological condition.

The western part of the district constitute Pediplain, composed of weathered, unconsolidated

medium to coarse grained material having gentle to moderate slope. There are scattered alluvial

deposits such as flood palin, valley fills etc formed along major river courses composed of clay,

silt, sand, gravel and kankar deposits with gentle slope. There are small scattered sedimentary

and volcanic dissected hills. Pavagadh hills, south of the district near Halol, rises abruptly to a

height of 829.36 m AMSL and is with high relief and steep slopes. The northern, eastern and

southern part of the district have undulated topography ranging the elevation more than 400m,

constitute moderately to highly dissected hills of Aravallis range. They have high relief and steep

slopes. The area occupies by the quartzite has an undulating topography where as phyllite and

mica schist occupy broad intermontane valley. The southern border of the district is marked by a

hill range with roughly east – west and forms a surface water divide particularly between

Narmada and Mahi basin.

3.8.2 HYDROGEOLOGY:

3.8.2.1 Geology: Geologically, Panchmahal district is the manifestation of diverse geological

extension from Lower Proterozoic to Holocene with different rock types such as granitic to

basalt and limestone to alluvium. The stratigraphy of Panchmahal district is presented in table 9.

The oldest formation in the area is Aravallis Super group comprises of various meta-sediments

belongs to Lower Proterozoic. The post-Delhi intrusive, Godhra granite and gneisses were

intruded into older Aravalli. Both Aravallis and granite-gneiss have undergone many orogenic

movement. They are overlain at places by Lower cretaceous fluvial and marine sequences,

namely Bagh beds and Lametas. Lower Cretaceous rocks are overlain by Deccan basalts,

extrusive rock formation; occur as sporadic exposure in the form of cappings over older rocks.

The youngest formation found in the district is the alluvium, occur as pediments, sand dunes,

valley fills and flood plain as isolated patches.

Map showing general hydrogeology of the district is given below figure: 3.9.



FIGURE 3.9

HYDROGEOLOGICAL MAP OF PANCHMAHAL DISTRICT

3.8.3 GROUNDWATER REGIME MONITORING:

Ground water regime monitoring is the basic component of groundwater management and it is

carried out in parts of Panchmahal district through National Hydrograph Network Stations

(NHNS or NHS). NHSs are observation wells, comprising of dug wells and purpose built bore

wells – known as piezometers. There are 19 NHS and 9 piezometers as part of the NHS. Depth to

water level map of pre monsoon and post monsoon period and annual fluctuation of water level

are prepared with data of NHS for year 2012. With available data of systematic and reappraisal

hydrogeological surveys carried out in the district. The water level of the district is described

below:

Depth to Water Level (Nov 2012): The northern and northwestern part of the district underlain

by hard rock formation have water level in range of 0 to 5m BGL while western part of

Lunavada taluka of the district ranged within 5 to 20m BGL. Areas along eastern part of the

district from north to south have water levels of 5 to 20m BGL. Isolated patches of 10 to 20m

BGL water level observed in the southern part of the Ghoghamba taluka, western part of the

Kalol and Lunawada taluka.

Map showing depth of water level of the district is given below figure: 3.9.

(BGL – Below Ground Level)



FIGURE 3.10

DEPTH OF WATER LEVEL MAP OF PANCHMAHAL DISTRICT DURING NOV-2012

3.8.4 SEISMICITY: The Gujarat state can be divided broadly into four tectonic units:

(i) The Saurashtra-Deccan Trap Plateau in the west.

(ii) The Kutch-Ahmedabad-Surat belt in the centre.

(iii) The Banas Kantha- Sabar Kantha- Panchmahal metamorphic igneous terrain in the

northeast and the Ambadunagar – Rajpipla-Songadh Deccan Trap Plateau in the south –

east.

(iv) The zone of rift systems coinciding with the course of the Narmada and the Tapi rivers

in the south - east.

The project area comes under the moderate risk zone - III in the National Zoning Atlas as

shown in Figure no. 3.11.



FIGURE: 3.11

SEISMIC ZONES IN INDIA

(Source: cgwb.gov.in/District Profile/Gujarat)

3.8.5 ECOLOGICAL INFORMATION

The study of the environmental components like flora and fauna is required to assess the

biological diversity of the region. Flora and fauna can be used for biological surveillance in

assessing the environmental status. The ecological interpretation of study area is based on

secondary sources of information.



Water is the basic and essential resource for the survival of flora and fauna. The flora being the

primary producer influences the fauna of the region. The characteristics of flora depends upon

the intensity of sunlight, type of soil, quality of air, including the quality and quantity of water

available, etc.

3.8.6 FOREST

There are no patches of reserved forest or protected forests/wildlife sanctuaries, ecological

sensitive areas within the 10 kms radial periphery of the study area.

3.8.7 FLORA

The list of flora found during field survey is given in Table 3.16.

TABLE: 3.16

LIST OF FLORA

Sr. No. Botanical Name Common Name Family

(I) TREES

1 Ailanthus excelsa Arduso Simarubaceae

2 Acacia ferruginea Alan Celastraceae

3 Acacia leucophloea Aledi or Aal or Rangori Rubiaceae

4 Acacia nilotica indica Ambedo Anacardiaceae

5 Acacia Senegal Amla Euphorbiaceae

6 Adina cordifolia Amli Caesalpiniaceae

7 Aegle mamelos Aniyar or Rijiado Mimosae

8 Analgium salvifolium Anjan Caesalpiniaceae

9 Anogeissus latifolia Cornacea Cornaceae

10 Anona squamosa Aritha Sapindaceae

11 Azadirachta indica Ashotri Caesalpiniaceae

12 Balanites roxburghii Baval Mimosae

13 Bauhinia recemosa Bahedo Combretaceae

14 Borassus flabellifer Bhangaro Papilionaceae

15 Boswellia serrata Bili Rutaceae

16 Bridelia retusa Biyo Papilionaceae

17 Buchanania iarizan Bor Rhamnaceae

18 Butea monosperma Charoli Anacardiaceae

19 Cassia fistula Dantio, Asan Euphorbiaceae

20 Cochlospermum religiosum Dhaman Tiliaceae

21 Cordia dichotoma Dhavdo Combretaceae

22 Dalbergia latifolia Dudhi Apocynaceae

23 Dalbergia sisoo Ganiyari Bixinaceae

24 Elacodendron glaucum Gandobaval Mimosae




25 Emblica officinaalis Garmalob Caesalpiniaceae

26 Erythina suberosa Ghatbor Rhamnaceae

27 Eucalyptus spp Gol Urticaceae

28 Ficus benghalensis Gorad Mimosae

29 Ficus religiosa Gorasamli Mimosae

30 Grewia tiliaefolia Gugal Burseraceae

31 Hardwickia binata Gundi Boraginaceae

32 Holoptelea integrifolia Haldarvo Rubiaceae

33 Hymenodictiyon excelsum Hingor Simarubaceae

34 Lannea coromandalica Humbumbh Anonaceae

35 Lnga dulce Jambu Myrtaceae

36 Mangifera indica Kadayo Sterculiaceae

37 Miliusa tomentosa Kagar Mimosae

38 Morinda tinctoria Bhamarchal Rubiaceae

39 Moringa oleifera Kanaji Ulnaceae

40 Petrocarpus marsupium karvali Urticaceae

41 Proposes juliflora Kesuda Papilionaceae

42 Sapindus emarginatus Kusum Sapindaceae

43 Schleichera oleosa Limdo Meliaceae

44 Soymida febrifuga Monia Anacardiaceae

45 Sterblus asper Nilgiri Myrataceae

46 Sterculia urens Papal Urticaceae

47 Syzygium Rohan Meliaceae

48 Tamarindus indica Sargwo Moringaceae

49 Terminalia bellerica shisam Caesalpiniaceae

50 Trema orientalis Sisoo Papilionaceae

51 Wrightia tinctoria Sitafal Anonaceae

52 Zizyphus mauritiana Tad Palmae

53 Zizyphus xylophyrus Vad Urticaceae

(II) CLIMBERS

1 Abrus precatorius Amarvel Covolvulaceae

2 Carissa conjesta Arun Menispermaceae

3 Celastrus paniculata Asan Menispermaceae

4 Cocculus hirsutus Chairo Dioscoreaceae

5 Cocculus labea Chanoti Caesalpinieae

6 Combretum ovalifolium Dodi Asclepiadaceae

7 Cressa cretica Galo Menispermaceae

8 Cuscuta reflexa Karamdo Apocynaceae

9 Demia extensa Kharo jam Convoivulanceae

10 Dioscoria oppositifolia Kuvech Papilionaceae

11 Leptadenia reticulate Malkakani Celastraceae




12 Mucuna pruriens Moti kakani Combertaceae

13 Tinospora cordifolia Varsha dodi Asclepidanceae

(III) SHRUBS & HERBS

1 Abutilon indicum Adusa Acanthaceae

2 Adhatoda vasica Ankado Asclepiadaceae

3 Cadaba fruiticosa Awar or awal Caesalpiniaceae

4 Calotropis gigntia Dano Verbenaceae

5 Caparis sepiaria Dhatura Solanaceae

6 Capparis deciduas Kalikanthar Capparaceae

7 Carvia callosa Kantharmadith Mimoseae

8 Cassia auriculata Kanski Malvaceae

9 Cassia tora Karedo Capparaceae

10 Datura inoxia Karvi Acanthaceae

11 Dichrostachys cinerea Khordu Capparaceae

12 Euphorbia nerifolia Kuda Apocynaceae

13 Gymnosporia Montana Muradsing sterculiaceae

14 Helicteres isora nagod Verbenaceae

15 Holarrhena antidysenterica Parijat Oleaceae

16 Indigofera pulchella puwad Caesalpiniaceae

17 Lantana camara Thor Euphorbiaceae

18 Nytanthus arbortristis Vico Celastraceae

19 Vitex nigundo Zill Papilionaceae

(IV) GRASSES

1 Sorghum halepense Baru Gramineae

2 Themeda triandra Bhathdu Gramineae

3 Apluda mutica Bhangoru(Karedi) Gramineae

4 Cynodon Dactylon Daro or Dub Gramineae

5 Arundinella pumila Dhudu Gramineae

6 Dichanthium annulatum Jinjavo Gramineae

7 Aristida funiculata Lapdu Gramineae

8 Dendrocalamus strictus Manvel bamboo Gramineae

9 Aristida hystrix Kadi Khasli Gramineae

10 Saccharum spontaneum kakudu Gramineae

11 Bambusa arundinacea Katas bamboo Gramineae

12 Setaria glaucia Kunchi (Pajala) Gramineae

13 Cymbopogon citratus Pusha Gramineae

14 Themeda quadrivalvis Rathedu Gramineae

15 Cymbopogon martinil Rosha Gramineae

16 Heteropogon contortus Shulki Gramineae

17 Panicum antidotale Shulki Gramineae

18 Cenchrus ciliaris shulki Gramineae



3.8.8 FAUNA

Some of the fauna found in study area is listed in Table 3.17.

TABLE: 3.17

LIST OF FAUNA

Sr.

No. Scientific Name Local Name Family Name

(I) WILD ANIMALS

1 Muntiac muntjak Barking dear Bovidae

2 Lepus nigricollois Black naped Hare Leporidae

3 Panthera pardus Common Indian leopard felidae

4 Presbytis entellus Common langur Cebidae

5 Tetracerus quadricomis Four horned Antilope Bovidae

6 Vulpes bengalensis Fox Canidae

7 Hyaena hyaena Hyaena Hynedae

8 Pteropus giganteus Indian Flying Fox Canidae

9 Bandicota bengalensis Indian Mole Rat Sciuridae

10 Canis aureus Jackal Canidae

11 Felius chaus Jungle Felidae

12 Herpestes edwardsi Mongoose Herpestidae

13 Funambulus Pennati Palm-Squirrel Sciuridae

14 Macaca mulatta Rhesus Monkey Cercopithecidae

15 Melursus ursinus Sloth Bear Ursidae

(II) BIRDS

1 Dicrurus adsimillis Bechstenin Black Drongo, King Crow -

2 Oriolus xanthorns Linnaeus Black headed Oriole -

3 Coturnix coromandelica Gmelin Black Breaster Quail -

4 Psittacula cyanocephala

Linnaeus Blossom headed parakeet -

5 Coracias benghalensis Linnaeus Blue Joy or Indian Roller -

6 Columa livia Gmelin Blue rock pigeon -

7 Strnus pagodarum Gmelin Brahminy Myna -

8 Bubulcus ibis Linnaeus Cattle Egret --

9 Turdodies Caudatus Dumont Common Babbler -

10 Acridotherus tristis Linnaeus Common Myna -

11 Ploceus philippinus Linnaeus Common Weaver bird ,Baya -

12 Hirundo rustica Linnaeus Common Swallow -

13 Alcedo atthis Linnaeus Common Kingfisher -

14 Tockus Birostris Scopoli Common Grey hornbill -

15 Milvus migrans Boddaert Common Pariah Kite -

16 Caprimulgus asiaticus Latham Common India Night jar --



17 Treron phoenicoptera Latham Common Sandgrouse -

18 Pterocles exustus Temminck Common Peafowl -

19 Pavo cristatus Temminck Common Quail or grey Quail -

20 Tringa Hypoleucos linnaeus Common Sandpiper -

21 Centropus sinensis Stephens Crow-pheasant or Coucal -

22 Megalaima haemacephala

Muller Crimson breasted Barbet -

23 Laniua excubitor Linnaeus Grey Shrike -

24 Denopium benghalensis

Linnaeus Golden Backed wood pecker -

25 Gallus sonneratii Temminck Grey Jungle Fowl -

26 Francolinus pondicerianus

Gmelin Grey Partridge -

27 Corvus splendens Viellot House crow -

28 Upupa epops Linnaeus Hoopoe -

29 Saxicoloides fulicata Linnaeus Indian Robin -

30 Courvus macrorhynchos Wagler Jungle Crow -

31 Turdoides straiatus Dumony Jungle Babbler -

32 Eudynamys scolopacea

Linnaeus Koel -

33 Motacilla madeeraspatenis

Gmelin Large Pied Wagtail -

34 Megalaima zeylanica Large Green Barbet -

35 Psittacula eupatria Linnaeus Large India Parakeet --

36 Merops superciliosus Linnaeus Green bee Eater -

37 Streptopelia Senegalensisi Little Brown dove -

38 Calidris Minuta Leisler Little Stint -

39 Copsychus saularis Linnaeus Magpie-Robin -

40 Nectarinia asiatica Lathum Paradise Flycatcher -

41 Nectarinia sciatica Lathum Purple Sunbird -

42 Ceryle rudis Linnaeus Pied Kingfisher -

43 Pycnonotus cafer Linnaeus Redvented Bulbul -

44 Phoenicurus ochruros Gmelin Red start -

45 Dicrurus paradiseus Linnaeus Racket tailed Drongo -

46 Psittacula Krameri Scopoli Rose ringed Parakeet -

47 Vanellus Psittacula Krameri

Scopoliondicus Boddaert Red Wattled Lapwing -

48 Athena Brama Temminck Spotted Owlet -

49 Streptopelia chinensis Scopoli Spotted Dove -

50 Ortnotomus sutorius Pennant Tailor Bird -



3.9 SOCIO-ECONOMIC ENVIRONMENT

As assessment of socio-economic environment forms an integral part of an EIA study, baseline

information for the same was collected during the study period. The baseline socio-economic

data collected for the study region, before the proposed expansion is operational, has been

identified for the four major indicators viz. demography ,civic amenities, economy and social

culture. The baseline status of the above indicators is compiled in forthcoming sections.

51 Dicaeum erythrorhychos

Latham Tickell’s Flower pecker -

52 Dicrurus caerulescens Linnaeus White bellied Drongo -

53 Halcyon smyrensis Linnaeus White Breasted Kingfisher -

54 Gyps benghatensis Gmelin White backed Vulture Or

Bengal Vulture -

55 Picoidedes mahrattensis Latham Yellow fronted pied Wood

pecker -

(III) FISH

1 Catla Catla Catla, Bawas

2 Cyprimus carpio Common Carp Carp

3 Wallago attu Fresh Water Shark Magara ,Mulley

4 Labeo fimbriatus Fringe-Lipped Carp Begado,Bilgi

5 Labeo callasu Kalbasu Bagado,Kalavat

6 Cirrehina marigala Mrigal Nagari

7 Labeo rohita Rohu Rohu

8 M.Seangala Singala Katiya

9 Ophiocephalus Stiatus Snake headed fish Murral,Dol

(IV) SNAKES

a. Non Poisonous Snakes

1 Natrix piscator Checkered keel black -

2 Typhlops braminus Common blind Snak -

3 Python molurus Indian Pythone Ajgar

4 Eryx johnni John's sand Boa Andhhi,Chakram

5 Plyas mucosus Rat Snake Dhaman

6 Psamnophis leithi Sand Snake -

7 Oligodon venestua Wolf Snake Shankh bangani

b. Poisonous Snakes

8 Naja naja Cobra Naag

9 Bungarus Caeruleus Common Krait Konotaro

10 Vipera Russelli Russell Viper Chitar,Fuisa

11 Echis carinatus Saw scale Viper Chitar



SETTLEMENTS AND DEMOGRAPHIC PATTERN

3.9.1 DEMOGRAPHIC DATA WITHIN THE REGION OF INTEREST

Demography covers the information related to population density sex ratio and literacy level of

the public in the study area.

TABLE: 3.18

DEMOGRAPHIC DATA

Sr.

No. Name of Villages

No. of

Households

Total

Population

Total

Male

Total

Female

1 Abhetwa 579 2935 1508 1427

2 Alindra 82 411 213 198

3 Alva 86 491 239 252

4 Ankaliya 47 253 125 128

5 Bakrol 468 2230 1137 1093

6 Baletiya 291 1432 738 694

7 Barola 95 348 178 170

8 Bhadroli 74 371 184 187

9 Boru 69 324 163 161

10 Chandrapura 148 761 392 369

11 Chhabapura 323 1744 891 853

12 Delol 1579 7154 3746 3408

13 Derol 304 1508 778 730

14 Dolatpur 547 3018 1545 1473

15 Ghoda 340 2166 1089 1077

16 Halol 2870 14474 7448 7026

17 Intwadi 59 342 175 167

18 Jantral 126 519 262 257

19 Jeli 156 632 318 314

20 Jetpur 625 3165 1597 1568

21 Kalol 2996 14687 7562 7125

22 Kandach 217 886 451 435

23 Kanetiya 92 513 261 252

24 Kanjari 111 528 264 264

25 Khakharia 185 839 436 403

26 Khandoli 89 670 328 342

27 Khandeval 439 2091 1059 1032

28 Maghasar 248 1142 606 536

29 Madhvas 514 2692 1335 1357

30 Maruva 437 2378 1228 1150

31 Maswad 275 1720 904 816

32 Medapur 954 6788 3446 3342

33 Muvala 118 576 295 281



Sr.

No. Name of Villages

No. of

Households

Total

Population

Total

Male

Total

Female

34 Navaria 144 858 417 441

35 Nesda 1304 8916 4430 4486

36 Nevariya 117 714 374 340

37 Palasa 1964 9685 4987 4698

38 Pingali 723 3460 1793 1667

39 Radhanpur 169 849 456 393

40 Ratanpura 546 3397 1721 1676

41 Sama 317 2149 1105 1044

42 Shamladevi 640 3226 1702 1524

43 Tarkhanda 305 1572 774 798

44 Varsada 240 1587 826 761

45 Zaradaka 53 271 142 129

(Source: Census-2011 for Tal: Kalol; Dist: Panchmahal)

3.9.2 LITERACY RATE

The literacy rate is a major factor, which influences the socio-cultural condition of a particular

place. Details of literacy rate in percentage in district Panchmahal and Taluka Kalol are given in

Table no. 3.19.

TABLE: 3.19

LITERACY RATE WITHIN 10 KM RADIAL DISTANCE OF STUDY AREA

Sr.

No Village Name District

Total

Population

Population

< 06 Years

Population

Literate

Literacy

(%)

1. Abhetwa Panchmahal 2935 420 1790 60%

2. Alindra Panchmahal 411 61 234 56.9%

3. Alva Panchmahal 491 89 221 45%

4. Ankaliya Panchmahal 253 42 94 37.15%

5. Bakrol Panchmahal 2230 347 1232 55%

6. Baletiya Panchmahal 1432 252 758 53%

7. Barola Panchmahal 348 38 215 61.78%

8. Bhadroli Panchmahal 371 59 208 56%

9. Boru Panchmahal 324 52 199 61.4%

10. Chandrapura Panchmahal 761 108 523 69%

11. Chhabapura Panchmahal 1744 218 1080 62%

12. Delol Panchmahal 7154 807 2300 76.48%

13. Derol Panchmahal 1508 240 953 63.2%

14. Dolatpur Panchmahal 3018 510 1791 59.34%



Sr.

No Village Name District

Total

Population

Population

< 06 Years

Population

Literate

Literacy

(%)

15. Ghoda Panchmahal 2166 399 1269 59%

16. Halol Panchmahal 14474 2163 8755 60.5%

17. Intwadi Panchmahal 342 54 186 55%

18. Jantral Panchmahal 519 37 409 78.8%

19. Jeli Panchmahal 632 47 508 80.38%

20. Jetpur Panchmahal 3165 545 1564 49%

21. Kalol Panchmahal 14687 1872 9573 65.2%

22. Kandach Panchmahal 886 52 696 78.56%

23. Kanetiya Panchmahal 513 77 291 56.7%

24. Kanjari Panchmahal 528 59 403 76.33%

25. Khakharia Panchmahal 839 92 494 58.93 %

26. Khandoli Panchmahal 670 183 225 33.6%

27. Khandeval Panchmahal 2091 325 536 88.10%

28. Maghasar Panchmahal 1142 148 806 81%

29. Madhvas Panchmahal 2692 397 1730 64%

30. Maruva Panchmahal 2378 398 1331 56%

31. Maswad Panchmahal 1720 349 889 52%

32. Medapur Panchmahal 6788 1239 3558 52.42%

33. Muvala Panchmahal 576 81 393 68.28%

34. Navaria Panchmahal 858 175 471 55%

35. Nesda Panchmahal 8916 1522 4772 53.52%

36. Nevariya Panchmahal 714 122 354 50%

37. Palasa Panchmahal 9685 1229 7042 72.7%

38. Pingali Panchmahal 3460 515 2085 60.26%

39. Radhanpur Panchmahal 849 109 575 68%

40. Ratanpura Panchmahal 3397 532 1956 57.58%

41. Sama Panchmahal 2149 435 628 29.2%

42. Shamladevi Panchmahal 3226 432 953 81.35%

43. Tarkhanda Panchmahal 1572 183 1079 68.6%

44. Varsada Panchmahal 1587 260 587 37%

45. Zaradaka Panchmahal 271 25 190 70.11%




3.9.3 OCCUPATIONAL STRUCTURE

In economic development of the region its geographical location, natural resources, business and

employment, industries and manpower play vital role. Table 3.20 provides the occupational

patterns in all villages of Kalol Taluka.

TABLE: 3.20

OCCUPATIONAL STRUCTURE

Sr.

No

Name

of Area

Total

Population

Worker Population Total Non

worker

population

Emplo

yment

Ratio

%

Total

Worker

Main

Worker

Marginal

Worker

1. Abhetwa 2935 991 695 296 1944 33.76

2. Alindra 411 114 101 13 297 27.74

3. Alva 491 128 103 25 363 26.07

4. Ankaliya 253 136 114 22 117 53.75

5. Bakrol 2230 1154 730 424 1076 51.75

6. Baletiya 1432 727 625 102 705 50.77

7. Barola 348 224 222 2 124 64.37

8. Bhadroli 371 89 53 36 282 23.99

9. Boru 324 152 127 25 172 46.91

10. Chandrapura 761 263 182 81 498 34.56

11. Chhabapura 1744 963 925 38 781 55.22

12. Delol 7154 3063 1923 1140 4091 42.82

13. Derol 1508 780 366 414 728 51.72

14. Dolatpur 3018 1535 778 757 1483 50.86

15. Ghoda 2166 1065 406 659 1101 49.17

16. Halol 14474 7154 3868 3286 7320 49.43

17. Intwadi 342 171 100 71 171 50.00

18. Jantral 519 282 277 5 237 54.34

19. Jeli 632 263 237 26 369 41.61

20. Jetpur 3165 1743 807 936 1422 55.07

21. Kalol 14687 6936 4933 2003 7751 47.23

22. Kandach 886 517 250 267 369 58.35

23. Kanetiya 513 283 152 131 230 55.17

24. Kanjari 528 277 150 127 251 52.46

25. Khakharia 839 436 429 7 403 51.97

26. Khandoli 670 336 159 177 334 50.15

27. Khandeval 2091 436 429 7 1655 20.85

28. Maghasar 1142 417 417 0 725 36.51

29. Madhvas 2692 856 680 176 1836 31.80

30. Maruva 2378 1216 150 1066 1162 51.14

31. Maswad 1720 879 367 512 841 51.10




Main worker: Who has worked last year for six month or more?

Marginal worker: Who has worked last year for less than six months?

Non-worker: Who did not work at all during the reference period of one year?

Distribution of main worker and marginal worker into further following four categories are

shown in Table 3.20

• Cultivators

• Agricultural labors

• Household industry

• Other Worker

32. Medapur 6788 3493 1998 1495 3295 51.46

33. Muvala 576 374 157 217 202 64.93

34. Navaria 858 464 436 28 394 54.08

35. Nesda 8916 4590 1666 2924 4326 51.48

36. Nevariya 714 296 165 131 418 41.46

37. Palasa 9685 3421 2952 469 6264 35.32

38. Pingali 3460 1845 957 888 1615 53.32

39. Radhanpur 849 341 288 53 508 40.16

40. Ratanpura 3397 907 832 75 2490 26.70

41. Sama 2149 1148 901 247 1001 53.42

42. Shamladevi 3226 1723 1352 371 1503 53.41

43. Tarkhanda 1572 442 426 16 1130 28.12

44. Varsada 1587 870 508 362 717 54.82

45. Zaradaka 271 176 174 2 95 64.94



TABLE: 3.21

DISTRIBUTION OF WORKERS

Sr.

No.

Area

Name

Main worker Marginal worker

Cultivators Agricultural

Labours

Household

Industry Others Cultivators

Agricultural

Labours

Household

Industry Others

Kalol Taluka

1 Abhetwa 372 1064 17 461 14 286 6 77

2 Alindra 265 250 0 233 4 40 0 4

3 Alva 29273 37002 474 13773 2300 17718 159 2692

4 Ankaliya 511 1361 76 3086 26 623 14 764

5 Bakrol 90 267 0 95 14 394 0 28

6 Baletiya 275 206 1 189 13 3 0 2

7 Barola 97 149 0 50 49 198 0 4

8 Bhadroli 151 404 1 159 2 12 0 14

9 Boru 664 2047 23 435 43 327 2 49

10 Chandrapura 155 167 11 29 18 11 0 4

11 Chhabapura 208 42 0 39 1 169 0 22

12 Delol 62 149 8 223 18 31 5 67

13 Derol 240 600 1 89 1 9 0 0

14 Dolatpur 64 3 0 43 0 172 0 6

15 Ghoda 29 52 0 6 0 0 0 0

16 Halol 482 1257 5 265 53 109 2 31

17 Intwadi 162 319 0 103 28 25 0 4

18 Jantral 33 39 1 55 3 53 0 23

19 Jeli 282 278 1 86 0 13 0 5

20 Jetpur 150 238 5 65 1 15 0 2



(Source: Census-2011 for Panchmahal District)

21 Kalol 68 152 0 78 0 37 0 4

22 Kandach 271 542 15 657 5 252 0 99

23 Kanetiya 294 739 29 977 33 195 16 97

24 Kanjari 188 499 7 225 47 383 12 56

25 Khakharia 156 297 17 407 16 154 2 36

26 Khandoli 165 734 34 2539 20 147 9 238

27 Khandeval 928 1905 30 1367 70 514 6 95

28 Maghasar 285 297 0 287 4 5 0 5

29 Madhvas 350 587 9 336 4 32 0 51

30 Maruva 114 104 8 324 9 8 0 53

31 Maswad 550 788 72 1147 115 308 80 118

32 Medapur 190 185 30 355 13 259 15 113

33 Muvala 560 666 8 583 51 593 2 85

34 Navaria 503 290 27 344 40 151 5 43

35 Nesda 272 600 1 41 3 8 0 0

36 Nevariya 327 509 0 177 25 31 2 5

37 Palasa 123 69 0 44 1 403 0 4

38 Pingali 209 140 5 14 0 10 0 0

39 Radhanpur 333 666 2 88 7 50 1 8

40 Ratanpura 444 864 21 663 16 50 1 37

41 Sama 893 992 31 452 29 1110 14 256

42 Shamladevi 168 583 7 389 2 295 1 31

43 Tarkhanda 336 561 30 4224 13 49 10 664

44 Varsada 40 113 34 17 2 9 1 3

45 Zaradaka 77 468 1 104 0 5 0 0



3.10 TRAFFIC SURVEY

3.10.1 RECONNAISSANCE

The traffic survey, to ascertain the traffic density in the study area was conducted on the road

near the project site. The composition of Traffic includes Two Wheelers, Three Wheelers like

Goods & Passenger Autos, Four Wheeler & Heavy Vehicles like Trucks, Lorries and Busses etc.

3.10.2 TRAFFIC SURVEY OF THE STUDY AREA

Data was collected by physically counting the number of vehicles in SH-87. The hourly counts

were carried out for the different types of vehicles. The variation in the traffic flow at the given

road along with the numbers of vehicles during peak hour & lean hour is presented in the table

below. While it’s graphical representation is done in figure below.

TABLE: 3.22

STATE HIGHWAY (SH-87)

Location Heavy

vehicle

Four

wheel

Three

wheel

Two

wheel

Bullock

carts

Madhvas 742 301 29 42 12

PCU rating as per Indian

Road Congress (IRC) 3 1 0.5 0.5 8

PCU 2226 301 14.5 21 80

TOTAL PCU 3053

Total

vehicle

during

Lean

Hrs.

Name and No. of Vehicle % Composition

Heavy

vehicle

Four

wheel

Three

wheel

Two

wheel

Bullock

carts Heavy

Four

wheel

Three

wheel

Two

wheel

Bullock

carts

3053 742 301 29 42 12 24.30 9.86 0.95 1.38 0.39

Location Heavy

vehicle

Four

wheel

Three

wheel

Two

wheel

Bullock

carts

Madhvas 839 318 34 72 15

PCU rating as per Indian road

Congress (IRC)

3 1 0.5 0.5 8

PCU 2517 318 17 36 120

TOTAL 3008

Total

vehicle

during

Peak

Hrs.

Name and No. of Vehicle % Composition

Heavy

vehicle

Four

wheel

Three

wheel

Two

wheel

Bullock

carts

Heavy

vehicle

Four

wheel

Three

wheel

Two

wheel

Bullock

carts

3008 2517 318 17 36 120 83.68 10.57 0.57 1.20 3.99



CHAPTER - 4

IDENTIFICATION & ASSESSMENT OF IMPACT

INTRODUCTION

This chapter identifies and predicts the potential impacts on different environmental components

due to the construction and operation of the project. It details all the potential impacts on

biophysical and socio-economic components of the local environment due to the proposed

activities and sub-activities.

Prediction of impacts is the most important component in the Environmental Impact Assessment

studies. Several qualitative and quantitative techniques and methodologies are used to conduct

analysis of the potential impacts likely to build up as a result of the development activities on

physico-chemical, ecological and socio-economic environments. Such predictions are

superimposed over the baseline (pre-project) status of the environmental quality to derive at the

ultimate (post-project) scenario of environmental conditions. The prediction and identification of

impacts helps to minimize the adverse impacts and maximize the beneficial impacts on

environmental quality during pre and post project execution.

The proposed project would create impacts on the environment in two distinct phases:

1) During the construction phase which may be regarded as temporary or short term.

2) During operation phase which would have long term effects.

4.1 IDENTIFICATION OF IMPACT

Identification of significant impacts for the project is a prominent step in the process of

environmental impact assessment. This provides a way forward to other elements of EIA study

such as quantification and evaluation of site specific impacts exclusively from the project.

Although, variety of concerns/ issues are identified while describing existing (baseline)

environmental status, it is necessary to identify the likely critical impacts on various components

of environment due to proposed project.

For construction and operation phases of the proposed project the “Network Method” has been

adopted for identification of impacts, which involves understanding of cause-condition effects

relationships between an activity and the consequences/ impacts on environmental and socio-

economic parameters for identification of significant impacts and has been found to be the most

appealing tool.



The impact networks have been delineated for construction and operation phases of proposed

project. The type of identified potential impacts on various environmental components i.e. Air,

Noise, Water and Land are presented in below Figure 4.1 to 4.6.

It should be noted that in these illustration the lines are to be read as “might have an effect on”.

4.1.1 IMPACT DURING CONSTRUCTION PHASE

The impact during construction will be localized and short term with permanent changes in

profile of the project site as compared to the current conditions. Impact will be primarily related

to the civil works and less intensive impact is expected during erection of the equipment and trial

operation. The various activities involved in construction phase of a proposed project are listed

below:

A) Excavation B) Construction C) Erection/Installations of equipment and machinery

D) Transportation E) Material handling F) Employment of labour

4.1.2 IMPACT ON AIR ENVIRONMENT

The main source of emission during the construction phase is the movement of equipment and

vehicles at site. Equipment deployed during the construction phase is also likely to result in

marginal increase in the levels of SO2, NOX, and PM and fugitive emissions. The impact is

reversible, marginal and temporary in nature. The construction activities at site will be restricted

to civil and structural fabrication. The main sources of air pollution are:

• Fugitive dust emissions from digging, filling, material handling, transportation and use of

construction machinery etc.

• Increase in traffic volume resulting in additional vehicular emissions from vehicles bringing

construction material and labour onsite.

• The impact will be for short duration and will be confined to the project boundary.

• However, use of tarpaulin for covering the material being transported in trucks, sprinkling of

water will control the dust generated and proper maintenance of vehicle will be carried out.

Mitigation Measures:

Water sprinkling will be regularly carried in order to arrest the fugitive dust to the maximum

extent possible. All construction equipment will be maintained properly. Only “PUC” certified

vehicles of contractor will be deployed at site. The green belt will reduce fugitive emissions in

the environment.



FIGURE: 4.1

IMPACT NETWORK ON AIR ENVIRONMENT

Activity

Primary

Impact

Secondary

Impact

Tertiary

Impact

Project

Operational

Phase

Release of Heat

Climatic

Changes

Impact on Human,

Flora and Fauna

Release of Air

Pollutants

Change in Air

Quality Impact on

Visibility

Aesthetic

Impact

Particulates

Deposition on

Water, Land

Impact on

Agricultural produce Impact on Human,

flora & fauna

Impact on

Economic Output Impact on

Socio – Cultural

Environment



FIGURE: 4.2

IMPACT NETWORK ON NOISE ENVIRONMENT

Noise

Emission

Change in

Ambient Noise

Level

Health

Risks

Impact on Work

Output & Efficiency

Impact on fauna &

population

Impact on

Economic Output

Impact on Socio-cultural

Environment

Operational

Phase

Activity

Primary

Impact

Secondary

Impact

Tertiary

Impact

Project



FIGURE: 4.3

IMPACT NETWORK ON WATER ENVIRONMENT

Activity

Primary

Impact

Secondary

Impact

Tertiary

Impact

Project

Operation Phase

Release of

wastewater

Abstraction of

Water

Impact on Hydraulics of

Water Courses

Impact on Hydraulic

Water Courses

Impact on

Aquatic Life

Cost of Water

Treatment

Impact on

Amenity /

Recreation

Impact on Economic

Output

Impact on Socio-Cultural

Environment

Environmental

health

And Aesthetic Risk



FIGURE: 4.4

IMPACT NETWORK ON GROUND WATER ENVIRONMENT

Activity

Primary

Impact

Secondary

Impact

Tertiary

Impact

Release of wastewater on land

Project

Operation Phase

Disturbance of soil

Impact on Flora and

Fauna

Impact on agricultural

production

Impact on Economic

Output


Environment

Abstraction of water

Change in Ground water

Regime: Soil Moisture /

water level/ Flow Pattern/

Salt water instruction

Impact on

landscape

Impact on Soil

Biota

Impact on livestock

Change in structure of

Soil: Ground level

Addition /Removal of

substances or Heat to

/form the soil



FIGURE: 4.5

IMPACT NETWORK ON SOCIO-ECONOMIC AND CULTURAL ENVIRONMENT

Activity

Primary

Impact

Tertiary

Impact

Secondary

Impact

Effect on

Human

Health

Project

Operational

Phase

Net Income

output

Air, Water,

Land,

Noise

pollution

Change in

Economic

Base of the

region

Effect on

visual

Environment

Economic input

Capital/O&M Cost

Economic

output

Product Cost

Development

of Ancillary

Industries

Better

product

availability

Employment

opportunity Aesthetic

Risk

Effect on

Agriculture

& fisheries

Effect on

Buildings

Materials

Monuments

Saving foreign

Exchange



FIGURE: 4.6

IMPACT NETWORK ON LAND ENVIRONMENT

Activity

Primary

Impact

Secondary

Impact

Tertiary

Impact

Disposal of waste

water & Sludge

on Land

Toxic Substances on

Land, Particulate

Deposition on Land

Impact on flora & fauna

Impact on

Agricultural Produce

Impact on Landscape

Impact on Economic

Output


Environment

Project

Operational

Phase

Disturbance of

land

Abstraction of

water

Change in ground

Water Regime /Salt

Water intrusion

Change in soil

Texture & Permeability

Soil Salinity

Impact on Live stock



4.2 PREDICTION AND ASSESSMENT OF IMPACT

The predication and assessment of impact on the environmental parameters have been carried

out. For assessing the impact, the baseline data of environmental status were considered. The

change in the environmental parameters due to manufacturing activities of the industry has been

superimposed on the status data.

The nature of the impacts due to said project activities are discussed here in detail. Each

parameters identified in the proceeding chapter, is singularly considered for the anticipated

impact due to various activities listed. The impact is quantified using numerical scores 0, 1, 2, 3,

4 and 5 in increasing order of activity. In order to assess the impact accurately, each parameter is

discussed in detail covering the following:

1) Project activities likely to generate impact

2) Quantification and prediction of impact

4.2.1 WATER ENVIRONMENT

4.2.1.1 CONSTRUCTION PHASE IMPACTS

During construction phase, water will be required for construction of structures, sprinkling for

dust suppression. The raw water for the various purposes will be supplied from own borewell.

There will no impact on surrounding ground water quality and quantity during construction

phase.

4.2.1.2 OPERATIONAL PHASE IMPACTS

Water consumption is primarily use for processing, washing, boiler, cooling, RO plant,

gardening and domestic purpose. The fresh water requirement for domestic and industrial

purpose will be met through own borewell. Average daily fresh water consumption of the unit

will be approx.77.0 KL/day and recovered water consumption is 145.0 KL/day. So, total water

consumption will be 222.0 KL/day (145.0 KL/day of recycled water + 77.0 KL/day of fresh

water). Total industrial effluent generation will be 162.0 KL/Day.

Mitigative measure: The domestic sewage water will be sent to Septic/soak pit. Industrial

effluent (162 KLD) will be sent in Effluent Treatment Plant. Out of 162 KLD Industrial

effluents, 7.0 KLD solvent strippers will be sent for co-processing. 155 KLD Effluent will be

treated in ETP and RO & recycle back in the unit. Unit will achieve zero liquid discharge.

Proper storage facility will be provided for raw material and hazardous waste. Hence, there will

be no impact on ground water and surface water quality. The details of waste water generation

are providing in chapter 2, Table 2.15.



4.2.2 AIR ENVIRONMENT


Dust will be generated during excavation and hauling operation and vehicle transportation on

unpaved tracks at the site. Other exhaust gases like PM 2.5, PM10, SO2, NOX, HCl, Cl2, NH3,

and VOC may be also slightly released into the local ambient air due to vehicular traffic

movement. Thus, the local ambient air quality may be temporarily affected. It will be confined

within the project boundary and expected to be negligible outside the plant boundaries.

Mitigative Measures:

Water sprinkling and provision of enclosures will allow the particles to settle down prior to

discharge. There will be provision of enclosures to construction area to allow the particles to

settle down prior to discharge.

4.2.2.2 OPERATION PHASE IMPACTS

Flue Gas Emission:

The sources of flue gas emission are from 3 TPH Boiler. 1 No. of D.G. set of 600 KVA capacity

will be installed which will be used only in-case of emergencies /power failure.

Process Gas Emission:

For Process emission, 3 nos. of Reactors will be installed with 2 stage water scrubber and 2 nos.

of Alkali scrubbers which will be installed as APCM.

Mitigative measure

For Boiler, there will be provision of multi cyclone separator and Bag Filter to control emission

of PM, SO2 & NOX. The unit will be using coal in boiler as fuel which will be provided

adequate stack height to control the emissions. There will be an alkali scrubber attached to the

reactor vessels to control emission of Cl2, HCL and NOX.. Two stage water scrubber will be

installed to control emission of NH3 from stack attached to Ammonia using reactor.

The air quality impacts of source are evaluated by use of model. The model stimulates the

relationship between air pollutants emission, meteorology and air chemistry, all of which are

determined by formulating impact scenario.

MODELING DETAILS

The dispersion of pollutants in the atmosphere is a function of several meteorological parameters

like temperature, wind speed and direction, mixing depths, inversion level etc. The air quality

impacts of source or collection of sources is evaluated by use of models. The model stimulates



the relationship between air pollutants emission, meteorology and air chemistry, all of which are

determined by formulating impact scenario. Estimation of emissions from the plant has been

made by Industrial Source Complex – Short Term (ISC-ST3) model developed by United States

Environment Protection Agency (USEPA). ISC-ST is based on a modified steady state Gaussian

Plume equation, and it has been recommended for use in EIA studies by Ministry of

Environment & Forests (MoEF) in EIA manual.

Based on the modeling results, the concentration of PM & SO2 summarized in the Table 4.2, the

concentration of NOX summarized in the Table 4.3, concentration of HCL, Cl2 and NH3 is

summarized in the Table 4.4.

TABLE: 4.1

DETAILS OF STACKS

Sources of gaseous

emissions

Boiler (3 Tons/

Hr) Reactor-I Reactor-II Reactor-III

Fuel used (Bio-Coal/Saw

Dust) -- -- --

Quantity of fuel 7.0 MT/day/

4.5 MT/day -- -- --

Type of emissions PM, SO2, NOX NH3 Cl2 HCl, NOX

Stack height (m) 30 Meter 11 Meter 11 Meter 11 Meter

Stack diameter at the

top (mm) 600 150 150 150

Stack gas exit

temperature (oC) 150 40 40 40

Stack gas exit velocity

(m/s) 7 6 6 6

APCM

Multi cyclone

separator &

bag filter

2 Stage Water

scrubber

Alkali

scrubber

Alkali

scrubber

Emissions Limit:

PM Concentration 150 mg//Nm3 -- -- --

NOx Concentration 50 ppm -- -- 25 mg/Nm3

SO2 Concentration 100 ppm -- -- --

NH3 Concentration -- 175 mg/ Nm3 -- --

Cl2 Concentration -- -- 9 mg/Nm3 --

HCl Concentration -- -- -- 20 mg/Nm3



TABLE: 4.2

CONCENTRATION OF PM & SO2

Highest

Values

Incremental increase in

Concentration (µg/m3) X Co-ord

(mts)

Y Co-ord

(mts) PM SO2

1 1.82 1.411 -1000 0

2 1.291 1.001 -1000 0

3 0.965 0.748 -1000 0

4 0.94 0.728 -1000 0

5 0.923 0.716 -1000 1000

6 0.876 0.679 -1000 0

7 0.852 0.661 -2000 0

8 0.835 0.647 -1000 0

9 0.817 0.633 -1000 1000

10 0.816 0.633 -1000 0

TABLE: 4.3

CONCENTRATION OF NOX

Highest

Values

Incremental increase in

Concentration (µg/m3) X Co-ord

(mts)

Y Co-ord

(mts) NOx

1 1.243 -1000 0

2 0.883 -1000 0

3 0.659 -1000 0

4 0.641 -1000 0

5 0.63 -1000 1000

6 0.596 -1000 0

7 0.578 -2000 0

8 0.568 -1000 0

9 0.567 -1000 1000

10 0.558 -1000 0



TABLE: 4.4

CONCENTRATION OF HCl, Cl2 & NH3

Highest

Values

Incremental increase in Concentration

(µg/m3) X Co-ord

(mts)

Y Co-ord

(mts) HCl Cl2 NH3

1 0.028 0.008 0.141 -1000 0

2 0.019 0.005 0.095 0 1000

3 0.018 0.005 0.093 -1000 0

4 0.018 0.005 0.092 -1000 0

5 0.018 0.005 0.091 0 1000

6 0.016 0.005 0.083 1000 1000

7 0.016 0.005 0.083 1000 -1000

8 0.016 0.005 0.083 -1000 0

9 0.016 0.004 0.081 1000 1000

10 0.016 0.004 0.081 -1000 -1000

Based on the modeling results, isopleths for SO2, NOX, PM, NH3, HCl and Cl2 were drawn and

were superimposed on an aerial view of the site using maps from Google Earth which is as

shown in the figures given below.



FIGURE: 4.7

ISOPLETHS OF SO2 (SITE COORDINATES 0, 0)



FIGURE: 4.8

ISOPLETHS OF NOx (SITE COORDINATES 0, 0)



FIGURE: 4.9

ISOPLETHS OF PM (SITE COORDINATES 0, 0)



FIGURE: 4.10

ISOPLETHS OF NH3 (SITE COORDINATES 0, 0)



FIGURE: 4.11

ISOPLETHS OF HCl (SITE COORDINATES 0, 0)



FIGURE: 4.12

ISOPLETHS OF Cl2 (SITE COORDINATES 0, 0)

Observations from dispersion modeling studies:

From the dispersion modeling studies conducted, it was observed that the maximum ground level

concentration occurs in the South West direction. The maximum incremental increase in

concentration for PM, SO2 and NO2 is 2.602 µg/m3, 2.027 µg/m3 and 1.437 µg/m3 respectively

at a distance of about 1 km in the South West direction. Whereas, the maximum incremental

increase in concentration for HCl and NH3 is 0.006 µg/m3 and 0.03 µg/m3 at a distance of about

1 km in the North East direction.

Conclusion:

There will be negligible impact on the GLC in NE direction.



4.2.3 NOISE ENVIRONMENT


Noise will be generated during the intermittent operation of machineries for site clearing and

construction work. Vehicular movement will be also a source of noise generation. There will be

sort term, localized and reversible impact on ambient noise levels during the construction

activities.

Mitigative measures: Operation of construction equipments generating higher noise will be

strictly restricted during 10 p.m. to 6 a.m. The construction machinery and equipment will be

well maintained. Provision of encloser, damper and other engineering control will control noise

pollution. Workers operating these equipments will be given ear plugs/muffs.


The sources of noise pollution will be D.G. sets and other noise generating units. Vehicular

movements during operation phase for loading/unloading of raw materials and finished products

and other transportation activity may also increase noise level.

Mitigative measures

Adequate noise control measures such as mufflers, silencers at the air inlet/outlet, anti vibration

pad for equipment with high vibration etc. is already provided. Housing/casing shall be provided

for all noise generating machines. Job rotation will reduce exposure to some extent. More ever,

PPE like earmuff and ear plugs is provided to the operators/worker exposed to high noise. The

green belt is further helpful in reducing the ambient noise level.

4.2.4 LAND ENVIRONMENT


As the project site is fairly flat terrain without any rock, there will be no blasting. As the site is

uneven, some leveling work will be required. Local workers will be engaged for construction

activities of proposed project. So, the construction phase of the project will not involve any

temporary housing for construction workers.

Mitigative measures: The solid waste generated during construction activity will be stored and

disposed properly. Sewage generated from sanitation facility will be disposed through soak pit.

Hence, there will be no significant adverse impact on land environment due to handling of

hazardous solids waste.




If the raw materials and hazardous wastes are not handled properly, it can pose danger of land

contamination and can affect land system adversely.

Transportation is one of the most important areas of concern associated with handling and

spillage of raw materials and hazardous waste because of the packaging and method of

transporting hazardous waste will prevent the likelihood that an accident or spill would occur.

Mitigative measures

The unit will closed hazardous waste storage area with impervious flooring. Transportation of

hazardous waste to the TSDF site is governed as per the Hazardous and

Other Wastes (Management and Transboundary Movement) Rules, 2016.

Separate collection system will provide for collection of spillage material. Impervious layer,

RCC roads and flooring is provided to area, where the chemical storage and handling activities

will be involved.

Separate storm water collection system is provided to prevent contamination of soil through

contaminated water.

Hence, there will be no significant adverse impact on land environment due to handling of

hazardous solids waste.

4.2.5 ECOLOGICAL ENVIRONMENT

1. The impact due to the proposed expansion on ecological parameters like natural

vegetation, cropping pattern, fisheries and aquatic life, forest land species diversity are

briefly summarized below:


It is an existing unit having various other units in its vicinity, undergoing expansion. The project

site is devoid of trees; it will not harbor any important flora. There will be no impact on natural

vegetation during construction. Since, the project is established on a non-agriculture land, it will

not to alter the crop production of the area. The project site is at a far distance from the forest

land, wild life sanctuaries and national parks. Hence, no adverse impact on this account is

anticipated.


The green belt will be developed by the unit within the premises having different species of

flora, which will lead to beneficial impact on ecological environment. There is necessary

environmental protection measures which have been planned under air pollution control system



designed to take care of release of the gaseous pollutants like PM, NOX, SO2, NH3, SO2 and HCl.

The waste water generated from the industrial activity will be partly sent to EICL, for its further

treatment and disposal and partly will be reused back in process. Whereas the effluent from the

domestic activities will be sent to soak pit.

Raw material and hazardous waste will be transported by road and will be stored in plant

premises.

Hence, no adverse impact on this account is anticipated.

4.2.6 INFRASTRUCTURE AND SERVICES


The plant is located on a non-agricultural private land of Madhvas village, having all essential

facilities such as water, power, post, and telecommunication.

Impact due to vehicular movement: Madhvas village is very nearer to state highway. It has

four lanes internal roads. At present there are no traffic issues in the project area. There will be 2-

5 truck / tanker moments will be increased. This will not results in any traffic issues. Also, the

unit will make parking arrangement of 8-10 Vehicles within the premises. The parking for staff

and worker’s vehicle is also available within the premises. This will have almost negligible

impact on road network.

The power requirement of total project of will be fulfilled from MGVCL. MGVCL is having

large amount of electricity production thus due to consumption of electricity no adverse impact

of electricity supply is predicted.

The unit is using water from own borewell. Also, the treated water will be used to conserve fresh

water. The infrastructure services e.g. roads, post and telegraph, communication, medical

facilities, education; housing will get improved in surrounding area.

4.2.7 SOCIO-ECONOMIC IMPACT


4.2.7.1.1 POPULATION

• During the peak construction phase, construction man power including construction workers

will be employed.

• However, to the maximum extent possible, construction workers will be employed from

within the study area.

• Since the construction phase of this project will be for short time period, the socio-economic

impact due to construction of this project is going to be temporary.



• Considering the above-mentioned factors, the construction phase of the project will have

minor impact on population in the study area.

4.2.7.1.2 EMPLOYMENT

• Around 20 workers will be employed in the construction work. This will increase

construction employment in the study area although temporality. Hence, the proposed

project will have minor impact on employment in construction phase.

4.2.7.1.3 TRANSPORTATION

• For transportation of construction material, the existing road infrastructure is adequate.

• Moreover, as the construction phase for the proposed project will be few months, the

impact would be temporary.


4.2.7.2.1 POPULATION: In the operational phase, about 102 workers/employee will be

employed for the project. This number of employee is very small compared to the total

population of the study area. Also as a social impact mitigation measure, Unit will endeavor to

employ most of these people from within the study area at worker level, subject to availability of

suitable manpower in the area. So the proposed project in its operational stage is not expected to

directly affect the total number or composition of population in the study area significantly.

However the population of the study area is expected to increase marginally due to migration of

persons from outside of the study area.

4.2.7.2.2 EMPLOYMENT: All efforts will be made to employ local people as far as possible.

In addition, employment will be generated by the secondary supporting activities e.g.

transportation, communication, boarding, daily utility services.

4.2.7.2.3 TRANSPORTATION: Because of the good network of transportation facilities in the

study area, the additional truck traffic generated during the operational phase is not expected to

bring any considerable load to the existing transportation system.

4.2.7.2.4 IMPACT DUE TO FIRE ACCIDENT: The project design and development has been

planned with care and all provisions have been made for the safety and security of the property

as well as the personnel.

4.2.7.2.5 IMPACT ON PUBLIC HEALTH: The discharge of waste materials (gaseous

emission and solid wastes) from the project can have some adverse impact on public health in the

surrounding area, if appropriate treatment procedures are not followed.



4.2.7.2.6 ACCIDENT HAZARD AND SAFETY: During operational phase accident / hazards

will be greatly minimized and ensure further safety of the local people. In addition, by adopting

mitigation measures it will ensure high safety standards.

Mitigative Measure

• Provision of adequate APCM and maintains of APCM will prevent emission from stacks and

reduce risk to the health of the people in the vicinity of the project site.

• All safety measures will be carried out to prevent any accident. The unit will also following

onsite /offsite emergency plan.

4.3 IMPACT MATRIX

The parameter discussed are presented in the form of a matrix in table 4.5. There will be both

construction and operation phases.

The quantification of impact is done using numerical scores 0 to 5 as per the following criteria.

Score 0 1 2 3 4 5

Severity

criteria

No

Impact

No

damage

Slight/short

term effect

Occasional

reversible

effect

Irreversible

/Long –term

effect

Permanent

damage



TABLE 4.5

ENVIRONMENT IMPACT MATRIX (WITH MITIGATION MEASURES)

Phase Activities during

The Phase

Air

quality

Water

quality

Noise

&

Odour

Land

Quality

Infra-

Structure

/Services

Ecological

environment

Health safety

& Aesthetics

Socio-Economic

Status

Con

stru

ctio

n

ph

ase

Excavation, civil work,

transportation of

construction vehicle 2 1 2 2 2 2 2 1

Op

erati

on

ph

ase

Water requirement 0 1 0 0 1 0 0 0

Material

Storage/handling/

Transport

2 1 2 2 2 2 2 0

Effluent discharge

(considering discharge

to CETP)

0 0 0 0 0 0 0 0

Utilities 2 1 1 1 1 1 1 0

Gaseous emissions 1 0 1 1 0 1 2 0

Fugitive emissions 1 0 0 0 0 0 1 0

Solid/hazardous waste

Disposal 1 1 1 1 1 1 1 0

Spills & Leaks 2 1 0 1 1 1 1 0

Plant Operations 2 2 1 0 1 1 2 1

Equipment Failures/

Shutdown/Startup 2 2 1 0 2 1 2 1

Transport of

workers/Movement

of vehicles

1 0 1 0 1 1 1 1

Cumulative score 16 10 10 08 12 11 15 04



TABLE 4.6

CUMULATIVE IMPACT CHART

Environmental Parameter Total Cumulative

Air Quality 16

Water Quality 10

Noise and Odor 10

Land Quality 08

Infrastructure/ Service 12

Ecological environment 11

Socio Economic Status 15

Health safety & Aesthetics 04

Conclusion:

Due to proposed project, identified impacts are as under:

The water will be use from own borewell within the premises. The unit proposes to reuse its 145

KLD of treated water back in industrial activities. So, there will be negligible impact on ground

water quality.

Even though after provision of APCM, there will be minor increase in ground level

concentration in ambient air due to operational activities of proposed project.

The unit will take adequate measure for storage, handling and disposal of hazardous waste.

Hence, there will be no significant adverse impact on land environment.

Engineering control, use of PPE, restriction of construction activity during 9 p.m. to 6 a.m., and

green belt will reduce impact of noise pollution due to construction work, vehicular movement

and noise generating equipment. There will be minor increase in ambient noise level and impact

is insignificant.

There will be no significant impact on crops & vegetation as the proposed APCM will take care

of flue gas emission and process emission. No impact on fisheries and aquatic life. Hence, no

adverse impact on this account is anticipated.

This will be a beneficial impact on the local socio-economic environment as increase in demand

for essential utilities and employment during both construction and operational phase.

There will be no impact on the local infrastructure services e.g. roads, post and telegraph,

communication, medical facilities & education. The housing facilities will be improved in

surrounding area.

There is a well laid down broad roads already existing in Madhvas village nearer to state

highway no. 87. At the full capacity of production, there will be 4 to 8 tanker/trucks per day for

transportation of raw material and finished good products.



CHAPTER -5

ANALYSIS OF ALERNATIVES (TECHNOLOGY & SITE)

5.1 INTRODUCTION


Dist. Panchmahal- 389330, Gujarat. The unit will be engaged in manufacturing of Pharma &

intermediate products.

5.2 SITE ALTERNATIVE

M/s. Ishanga Life Science Pvt. Ltd. will be located at private non-agricultural land of Madhvas

village. The total plot area of the unit is 6378 sq. m and Green belt area is approx. 2110 sq. m.

(33%).

Project site is approximately 3.87 km away from Halol – GIDC. It is largely an industrial area

dominated by small scale, Medium scale and large scale industries. Communication facility

available in the area is good. The nearest Domestic Airport is Vadodara, about 38.85 Km away

from the project site. A railway line of Bakrol is 3.20 km away from the project site. The project

site is very well connected with the both National Highway No.8 and State Highway No.87.

Infrastructure:

1. Good roads - Four lane road from Halol and good internal roads at the site.

2. Emergency water supply scheme.

3. Storm water drainage.

4. Transportation facility for movement of labor

5. Social infrastructure facilities

6. Alternative access to National Highways.

7. Common facilities such as banks, commercial services travel agencies, post office, fire

station, and police station.

8. Health care facilities including those for fire accidents.

9. Disaster management control facilities.

10. Railway line.

The project proponent did not consider any other alternative site for new project:

The land located in the non-agricultural land so there will be no alternative for site.

� The unit has procured applicable permissions for new plant.



� Uninterrupted availability of sufficient water (from CGWA authority).

� No significant physical displacement of the members of the public.

� Connectivity of the site via road and train to procure the raw materials and to dispatch the

products.

� Vicinity of common environmental infrastructure; like TSDF site.

Hence, project proponent did not consider any other alternative site for new unit.

5.3 TECHNOLOGY ALTERNATIVE

The unit will adopt latest and best technology available so far in the market. Moreover, the unit

is very conscious about the product quality and equally about the environmental protection and

resource conservation; and hence they will put their efforts for replacing/upgrading their plant

and machineries from time to time with the best available technology. The unit’s processes are

efficient and are tailor made to reduce the effluent as well as are based on green chemistry

wherever possible.



CHAPTER -6

ENVIRONMENTAL MONITORING PROGRAM

6.1 INTRODUCTION

Environmental monitoring describes the processes and activities that need to take place to

characterize and monitor the quality of the environment. Environmental monitoring is used in the

preparation of environmental impact assessments, as well as in many circumstances in which

human activities carry a risk of harmful effects on the natural environment. All monitoring

strategies and programmed have reasons and justifications which are often designed to establish

the current status of an environment and Prediction of the impact of future development and/or

alteration in the operation and design of installations. Environmental Monitoring Network is

operation phase of the project for monitoring of various environmental parameters like air, water,

noise, soil etc.

A well-defined environmental monitoring programme would be employed with trained and

qualified staff of Environmental Management Cell of the proposed project to monitor the

environmental attributes of the area with respect to EMP as well as the guidelines of the

GPCB/CPCB. Environment monitoring schedule proposed to be adopted by the project.

6.2 OBJECTIVES OF ENVIRONMENTAL MANAGEMENT PLAN

• To comply with the statutory requirements of monitoring for compliance with conditions of

NOC.

• To comply with the provision of Factory Act & MSIHC Rules.

• To verify the results of the impact assessment study in particular with regards to new

development.

• Identification of any significant adverse transformation in environmental condition to plan

additional mitigation measures; if & as required.

• To check or assess the efficiency of the controlling measures.

• To ensure that new parameters, other than those identified in the impact assessment study, do

not become critical through the commissioning of new project.

• To establish a data base for future Impact Assessment Studies for new project.

6.3 IMPLEMENTATION SCHEDULE OF MONITORING MEASURES

Monitoring should be done as periodically to understand the environmental condition of the site.

The mitigation measures suggested in the Chapter-4 should be implemented so as to reduce the

impact on environment due to the operations of the project. In order to facilitate easy



implementation, mitigation measures are phased as per the priority implementation. The priority

of the implementation schedule is given in Table 6.1.

TABLE 6.1

IMPLEMENTATION POLLUTION CONTROL MEASURES

Sr.

No.

Required

Measures Stage Remarks

1. Air pollution

control measures During operation stage

Adequate stack height for flue gas emission and

Scrubber system will be provided as APCM for

process gas emission.

2.

Ground Water

Criteria and

Drinking Water

parameter

During construction and

Operation stage.

As per IS: 10500 Standard

Quarterly monitor quality of water.

3. Waste Water

Treatment

Operation phase of the

project

Domestic effluent (15.0 KLD) will be disposed in

soak pit system.

Total industrial effluent generation will be 162.0

KL/Day. It will be treated in Effluent treatment

plant, RO Plant & recycle back in the unit. Out of

162 KLD Industrial effluent, 7.0 KLD solvent

stripper will be sent to co-processing. Unit will


4. Greenbelt development

During construction stage & operation stage.

Plantation will be done along the periphery within

premises. Total green belt area 30.10 % of plot

area.

5. Solid waste

disposal

Construction and

operation phase of the project.

Solid waste to be segregated and disposal as per

guideline.

6. Hazardous waste disposal

Operation phase of the project.

Collection /storage /transportation /disposal at

TSDF-& disposal as per Hazardous waste rule

2016.

6.4 POLLUTION MONITORING AND SURVEILLANCE SYSTEM

Regular monitoring of important parameters is of immense importance to assess the status of

environment during plant operation. With the knowledge of baseline conditions, a properly

planned monitoring program can serve as an indicator for assessment of any deterioration in

environment conditions. This will facilitate undertaking suitable measures to mitigate adverse

impact during the operation of the plant and further help to protect the environment in the area.

The main attributes for which monitoring shall be carried out are:

• Ambient Air Quality

• Stack Emission

• Effluent water Quality

• Noise Level

The above mentioned sources will be monitored so as to meet the requirements of the State

Pollution Control Board.



6.4.1 AMBIENT AIR QUALITY MONITORING

The ambient air quality with respect to PM10, PM2.5, SO2, NOx, HCl, Cl2, NH3, CO and VOCs

shall be monitored at ETP, process area, storage area and one location in downwind direction.

The frequency of monitoring will be every three month by external approved monitoring

agency.

The log book shall be maintained at environment cell for evaluation of impact and to decide

required migratory measures.

6.4.2 STACK MONITORING

All the flue gas stacks in the proposed project shall be monitored with respect to temperature,

oxides of nitrogen (NOX), Particulate Matter (PM) and Sulphur dioxide (SO2) level.

6.4.3 NOISE MONITORING

Monitoring of noise levels is essential to assess the effectiveness of Environmental

Management Plan implemented to reduce noise levels. A good quality sound level meter and

noise exposure meter may be procured for the same. Audiometric tests shall be conducted

periodically for the employees working close to the high noise sources. The noise levels due to

machines/equipments viz. compressor, motors, engines, etc shall be monitored regularly.

6.4.4 ENVIRONMENT MONITORING PLAN

The detailed environment monitoring plan is tabulated in Table 6.2.

TABLE: 6.2

ENVIORNMENT MONITORING PLAN

Sr.

No. Description Location

Parameter To

be Monitored Frequency of Monitoring

1.

Stack

Monitoring of

each stack

(Gas Emission

Monitoring Plan)

All Flue gas and

process gas

emission stacks.

PM10, PM2.5,

SO2, NOx, HCl, Cl2, NH3,CO and

VOCs.

Monitoring will be done by external monitoring agency every

three months.

Unit will Install 24x7 continuous

emission monitoring system at

process stacks to monitor stack

emission with respect to standards

prescribed in Environment

(Protection) Rules 1986 and

connected to SPCB and CPCB

online servers and calibrate these

system from time to time

according to equipment supplier

specification through labs

recognised under Environment

(Protection) Act, 1986 or NABL

accredited laboratories.

2.

Work Zone

Fugitive Emission

Monitoring Plan

Process area &

storage area

VOC, CO, PM,

Cl2, HCl,NH3

Unit will monitor fugitive

emissions in the plant premises at

least



once in every quarter through labs recognised under Environment

(Protection) Act,

1986.

3. Ambient Air

Monitoring Plan

four locations

(one within and

three outside the plant area at an

angle of 120

each), covering

upwind and

downwind

directions.

PM10, PM2.5,

SO2, NOx, HCl,

Cl2, NH3,CO and

VOCs.

1) Within premises ambient air

monitoring station will be

established in consultation with

GPCB.

2) Quarterly by external

monitoring agency.

Unit will install system to

carryout Ambient Air Quality

monitoring for common /criterion parameters relevant to the main

pollutants released

(e.g. PM10 and PM25 in

reference to PM emission, and

SO2 and NOx in reference to

SO2 and NOx emissions) within

and outside the plant area at least at four locations

(one within and three outside the

plant area at an angle of 120

each), covering upwind and

downwind directions.

4. Noise Monitoring

Any five location

within company

premises

Noise

Noise control measures including

acoustic hoods, silencers,

enclosures etc. on all sources of

noise generation/

Quarterly by internal monitoring

agency in day time and night

time.

5. Water Quality Monitoring

5.1 Effluent Quality Before

Neutralization

Primary

equalization tank

For TDS, pH,

COD,TSS, Ammonical

nitrogen, oil and

grease

1) The unit will provide online

continuous monitoring.

2) The unit will install web

camera with night vision

capability and flow meters in the

channel/ drain carrying effluent

within the premises.

3) Every three month by external

approved monitoring agency.

4) Every day by self-analytical

facility.

5.2 Effluent quality after neutralization

Neutralization Tank

For TDS, pH,

COD, TSS, Ammonical

nitrogen.

5.3

Water quality after

multiple effect

evaporator

MEE

For TDS, pH,

TSS, COD,

Ammonical nitrogen.

5.4 Water quality after

R. O. Reverse Osmosis

For TDS, pH,

TSS.

6. Water Quantity Monitoring

6.1 Inlet & Outlet ETP Quantity in KL 1) The unit will provide online

continuous monitoring.

2) The unit will install web

camera with night vision

capability and flow meters in the

channel/ drain carrying effluent

within the premises.

6.2 Inlet & Outlet Boiler Quantity in KL

6.3 Inlet & Outlet Cooling Tower Quantity in KL

6.4 Inlet Process Quantity in KL

6.5 Inlet Domestic Quantity in KL

6.6 Recycled Water MEE Condensate

& RO outlet Quantity in KL



7. Hazardous waste quantity Monitoring

7.1 ETP Waste Effluent

Treatment

Quantity

generated &

Disposed in MT

Record Maintain & disposal of

hazardous waste will be as per

Hazardous waste (Management

and Handling) Rules 2016.

7.2 Used Oil

Maintenance &

used lubricant oil

generated from

maintenance

activities

Quantity

generated &

Disposed in MT





7.3

Discarded

Containers/

Bags/Liners

Packing Materials

Quantity

generated &

Disposed in MT





7.4 Process Residue Mfg. Process

Quantity

generated &

Disposed in MT





7.5 Spent Carbon Mfg. Process & ETP

Quantity

generated &

Disposed in MT


hazardous waste will be as per Hazardous waste (Management


7.6 Spent catalyst Mfg. Process

Quantity

generated &

Disposed in MT



Hazardous waste (Management and Handling) Rules 2016.

7.7 Scrubber solution Mfg. Process

Quantity

generated &

Disposed in MT





7.8 Stripper solvent Effluent

Treatment

Quantity

generated &

Disposed in MT





7.9 MEE Salt MEE

Quantity

generated &

Disposed in MT





7.10 Membranes RO Plant

Quantity

generated &

Disposed in MT





8. Health status

of workers All workers

As suggested by

panel doctor

Once in a period of 6 months, to

ascertain physical fitness of the

person to do the particular job.

9. Electricity Consumption Monitoring

9.1 ETP Plant Effluent treatment

plant Electricity

Separate electricity meter and

daily reading will be noted. 9.2 MEE Plant MEE Plant Electricity

9.3 Air pollution

control system Scrubbers Electricity

10 Environment Audit

10.1 Environment audit will be carried out once in year through GPCB recognized schedule-1

Environment Auditors. This is as per directive of Hon. Gujarat High Court.



6.5 COST PROVISION FOR ENVIRONMENTAL MEASURES

For environment protection, management and pollution control and treatment and monitoring

systems, appropriate budgetary provision would be made and provision for recurring expenditure

for environment management of the project would be made. The details of budget allocation

during construction phase and operation phase are given in Chapter-2.

6.6 IN-HOUSEMONITORING EQUIPMENT AND CONSUMABLES

A well-equipped laboratory with consumable items will be established for monitoring of

important environmental parameter. Alternatively, monitoring can be outsourced from NABL /

MoEF recognized laboratory. Details of equipment& in-house monitoring facilities are shown in

table 6.3.

TABLE 6.3

LIST OF LAB EQUIPMENTS

Sr. No. Title

A M.E. (MEASURING EQUIPMENT):

1. Automatic Moisture Analyser

2. Bead Strength Tester

3. Conductivity Meter

4. Digital Balance

5. Digital Burette

6. Flame photometer

7. Gas Chromatograph

8. Glass Thermometer

9. Karl Fisher

10. pH Meter

11. Portable Spectrophotometer(Hach)

12. Referactometer

13. Resistivity Meter

14. Sieve

15. Turbidity Meter

16. Viscometer

B A.E. (AUXILLARY EQUIPMENT)

1. Centrifuge

2. COD Digester

3. Digital Shaking Machine

4. Electric Stirrer

5. Fume Hood Cupboard

6. Microscope

7. Muffle Furnace

8. Magnetic Stirrer

9. Oven

10. Vacuum Oven



6.7 ENVIRONMENTAL MANAGEMENT CELL

Company will ensure to conduct all business operations in compliance with applicable laws,

regulations and standards related to occupational Health, Safety and Environment. An

environmental management cell with adequate professional expertise and resources shall be

established to discharge responsibilities related to environmental management including

statutory compliance, pollution prevention, environmental monitoring, etc. The EMC will be

made responsible for all issues related to environmental management of the proposed project

facilities.

There shall be EHS leader for overseeing all environment and safety responses to ensure the

implementation of EMP mentioned during construction and operation phase including findings /

recommendations of third party audits and monitoring results as mentioned in the EMP.

At least one permanent employee with adequate educational and professional qualification and

experience to discharge responsibilities related to environmental management including statutory

compliance, pollution prevention, environmental monitoring will be employed by company and

will directly report to the director of the organization operations.

There is well defined system on repertory of any noncompliance or violation or deviation to the

directors. The organogram specially indicating environment management cell is given in figure

6.1. The company will develop Environment Policy, standard operating process/procedures one

at comes in to operation. The copy of Environment, Health and Safety Policy is attached as

Annexure- IX.

FIGURE: 6.1

FLOW DIAGRAM OF ENVIRONMENT MANAGEMENT CELL

Sr. Manager

(Safety)

Officer (Safety)

General Manager

(EHS Corporate)

Sr. Manager (Environment)

Officer (Environment)

Director (Technical)

Shift supervisor (ETP)

Shift operator (ETP)

Vice President

Site head

ISHANGA LIFE SCIENCE PVT. LTD. - Gujarat Pollution ...

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