Attachment I - Hanford.gov

59
Attachment I

Transcript of Attachment I - Hanford.gov

Attachment I

CHPRC CONDITION REPORT FORMStatus: Analysis CR NUMBER: CR-2011I 2037

Issue Identification and Processing

Initiator: Initiating IDetifedBannister, Roland J Document: 6/23/2011d

Title of Issue:Extent of Condition review for S3000 containers

Description of Issue:Extent of Condition Review arose from the Causal Analysis regarding the breached drum found in 2404WBon April 26, 2011. The scope of the review was to assess all other known S3000 (homogenous solids) wastestreams to identify containers that appear to have a similar waste matrix and packaging configuration to theparent drum of the breached HEDL drum. These containers are considered to be of high risk of breaching,and therefore need to be placed into secondary containment until such time as the perceived corrosive effectsof the waste are eliminated.

Requirements Not Met: (Orders, Requirements, Procedures) Responsible Project/Program:None. Good management practice to minimize future impacts of WASTE AND FUELSpossible leak/breach of drum with waste matrix and packaging MANAGEMENT PROconfiguration known to have caused containment failure.

Other Related Documents:Date Submitted: Extent of Condition Review for

6/23/2011 RL-CPRC-WRAP-201 1-0002,WRAP-201 1-0002 Causal_____________________________________________________ Analysis

Immediate Action(s) Taken:None. These containers are subject to weekly RCRA inspections. No issues have been identified to date.

Recommended Corrective Actions:Place "high risk" drums into secondary containment until such time as the perceived corrosive effects of thewaste are eliminated.

Initiator Comments:Suggest R. Bannister be responsible for coordinating response activities to completion.

Associated Files

Issue Significance, Analysis, Extent of Condition, Action Assignment, and ClosureSignificance Level: Date Submitted to Responsible Date CAP was approved by Responsible

Track Until Fixed Manager: Manager/Delegate:6/23/20 11 - McCarthy, Edward T

ORPS Compliance Determination NTS

Significant Level Justification:Screened as Track Umsntil Fixed (TUF).

This CR does not identify a compliance issue but instead identifies potential future issues and suggestssolutions to a future problem. As a TUF, this CR will track to closure those actions taken to address the statedconditions.

DBW

Extent of Conditions:

Causal Analysis Method Used: Analysis Completion Date:

Analysis Results:

Trend Codes:

MS06 - Hazard Identification/AnalysisWMV - Waste Management

Cause Codes:

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INDUSTRIAL HYGIENE CHAIN OF CUSTODY AND LABORATORY REQUEST

Contractor: CH2M HILL Plateau Remediation Company Date Sampled: 05/17/2011

COA: ICACN:L I ISurvey No.: 11-23277 -Ghost Wipe 2404be sample

Contact Name: Kelm, Fred R[~Phone: (509)372-1947 -) -1~9' Date Needed: cSI oReturn Report To: Graden, Clinton MSIN: H8-20 Phone: (509)376-4254

Laboratoryr Sample lDIType/Description Required Analysis

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2DJ LoqContractor: CH2M HILL Plateau Remediation Company Date Sampled: 05/17/2011

COA: CACN: 71 i ll oL- Survey No.: 11-23271 -2404 WB be Area and Personal sampling

Contact Name: Kelm, Fred R lhPhone: (509)372-1947L3,- c13 I Date Needed: -/ /Return Report To: Graden, Clinton MSIN: HB-20 IPone: (509)376-4254

Laboratory Sample lDlType/Description Required AnalysisLog No.

Vj If ['f'w7r/7 11 -23271 -1 -Al / 37 mm MCE Filter (general) Beryllium Area

III ImiliEmnmiiuiiiuhil ________________

Z4 11-23271-1 -A2 I37 mm MCE Filter (general) Beryllium Area

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6D 11 -23271 -1 -P1 37 mm MCE Filter (general) Beryllium Personal

Special Instructions:

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PRCIHS- Chain of Custody

INDUSTRIAL HYGIENE CHAIN OF CUSTODY AND LABORATORY REQUEST

Contractor: CH2M HILL Plateau Remediation Company Date Sampled: 05/11/2011

COA: ICAC N:' 7) ThlCCkA- I ISurvey No.: 11-23283 - 2404WB Recovery Laundry

Contact Name: Campbell, Robert A I '\j Phone: (509)373-9599 inIDate Needed: C)IJ 7

Return Report To: Graden, Clinton' MSIN: 1-8-20 IPhone: (509)376-4254

Laboratory Sample IDlTypelDescription Required AnalysisLog No.

MVIfDj7I 7 1-22301/Ghost Wi~ en Ex ) Beryllium

R5 11-23283-002/ GhostW WIjEnl Ex ) Beryllium

1I1111 li II11111 Ui111111 II ___________________________________

11-23283___0031 / Ghost Wie Env E ) Beryllium

I________________MR miili 1146 1

LO i 111111 lM1t , ~e~~, 2 3 28 3 -004 /Ghos t ~en ~ ~ Beryllium

10 11 -23283-005/Ghost W eEnv Ej) Beryllium

PZ 11 -23283-006/Ghost Wi ejEnv Ej Beryllium

111111 II i I II IIIi____________________________7_

Special Instructions:

\k Signature Printed Name Date Time

Relinquished Byi _______

Received By: 7

Relinquished By:.___________ _______________

[Received By: _____________ __________ ______

Rlinquished By:

Received By: _____________________________

Additional Comments:

21- -0 1112621.-01 li

W 112621 ANALYTICAL REQUEST FOR1. ZREGULARZ Status L30

RUSH Status Requested - ADDITIONAL CHARGERESULTS REQUIRED BY___________

DATEL CONTACT ALS SALT LAKE PRIOR TO SENDING SAMPLES

2. Date JL Purchase Order No. 4. Quote No. __________

3. Company Name ___________ _______ ALS Project Manager 'Pa-u AAddress -\- Q. 5 Cv G-Sc) t\Zl N) '3' 'sCi 5. Sample Collection

__ _ _ __ _ _ _ ___a,_ _ _ _ __ _ _ _ Sampling Site._ _ _ _ _ _ _ _ _ _ _

Person to Contact ~'~jfQ Industrial Process________________

Teepon Date of Collection ____

Fax Telephone (5)ej ~ fY) Time Collected _________

E-mail Address ~CZ~ A T E .AcfDate of Shipment ~ Y iBilling Address (if different trom above) Chain of Custody No. _______________

t'~~A CCCL11~-§T6J-JCD 6. How did you first learn about ALS ?

7. REQUEST FOR ANALYSES________________________

Laboratory Use Only Client Sample Number matrix* Sample Volume ANALYSES REQUESTED - Use method number if known Units- er

-004___

Q-Cos _

Specify: Solid sorbent tube, e.g. Charcoal; Filter type; Impinger solution; Bulk sample; Blood; Urine; Tissue; Soil; Water; Other1. pg/sample 2. mg/rn3 3. ppm 4. % 5. pg/in3 6.-__(other) Please indicate one or more units in the column entitled Units-

Comments

Possible Contamination and/or Chemical Hazards7. Chain of Custody (Optional)

Relinquished by KAAA-'5c1tJhQRALc' Date/TimeIl pa

Received by -,!. Date/Time -((2(

!N Relinquished by _____________________________Date/Time _____________________

Received byDaeim

960 West LeVoy Drive/Salt Lake City, UT 84123 800-356-9135 or 801-266-7700 /FAX: 801-268-9992ALS Environmental

ALS Laborator14 GOuP Quality Control Sample

ANALYTICAL CHEISTRY & TES]NG SEVICES Batch Report AAnalysis Information

LMB: 218129Analyzed: 05/11/2011 08:03

Units: ug/sample ___________________________________

Analyte IResult IRL____________________ __________

Beryllium ND 0,00708

.LboatorygControl Sample -Laboratory Cntrol Sape DupipIcte

LCS: 218130 LCSD: 218131

Analyzed: 05/11/2011 08:05 Analyzed: 05/11/2011 08:07

Units: ug/sample________________

Analyte Result ITarget % Recovery IQC Limits Result IRPD IQG Limits _____

Beryllium 11.3 10 113 83.9 138.6 11.1 1.43 0 20

Q aaAppod aRviewed by~

Symbols and Definitions* - See Comments section for more information RPD - Relative % Difference (Spike / Spike Duplicate)

A - Sample result is greater than 4 times the spike added. ND - Not DetectedOC results are not adjusted for moisture correction. where applicable.

Wednesday, May 11, 2011

Page 1 of 1 QOS V1.6

ALS Labaratorj G~roupAAICAL CHEMISTRY & TESi ING SEWIES ANALYTICAL REPORTA

Report Date May 11, 2011

Bruce Hey Phone: (509) 373-7197Mission Support Alliance Fax: (509) 372-0456P.O. Box 650MSIN S3-30 E-mail: [email protected], WA 99352

Client Project ID: Mission Support AllianceOSO6l11Purchase Order: 24952

Workorder: 1112621Project Manager Paul Pope

Analytical ResultsSample ID: 11-23079-001 Media: Ghost Wipe Collected: 05/04/2011Lab ID: 1112621001 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

Sample ID:~ 11-23079-002 Media: Ghost Wipe Collected: 05/04/2011Lab ID: 1112621002 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

Sample ID: 11-23079-003 Media: Ghost Wipe Collected: 05/04/2011Lab ID: 1112621003 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

Sample ID: 11-23079-004 Media: Ghost Wipe Collected: 05/04/2011Lab ID: 1112621004 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/samnple)Beryllium <0.0071 0.0071

ALS USA, Corp.Wed, 05/11/11 10:38 AM Paqtc ~ALS Laboratorq GroupPage 1 of 4 A Camppae#& Bmfs Limied Comnpany IHIREP-V1O.1

ALS Laborator14 GroupANIAL'1CAL CHEE 1STP$ & TESNG SERVICES ANALYTICAL REPORTA

Client Project ID: Mission Support AllianceOSO6l 1Purchase Order: 24952

Workorder: 1112621Project Manager Paul Pope

Analytical ResultsSample~ ID: 11-23079-005 Media: Ghost Wipe Collected: 05/04/2011Lab ID: 1112621005 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

[Sample ID: 11-2307'9-006 Media: Ghost Wipe Collected: 05/04/2011Lab ID: 1112621006 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

[Sample ID: 1 1-23079-007 Media: Ghost Wipe Collected: 05/04/2011Lab ID: 1112621007 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

[Sample ID: 11-23063-001 Media: Ghost Wipe Collected: 05/03/2011[Lab ID: 1112621008 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

[Sample ID: 11-23063-002 Media: Ghost Wipe Collected: 05/03/2011[Lab I D: 1112621009 Received: 05106/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

ALS USA, c-orp.Wed, 05/11/11 10:38 AM PatabeALS Laiboratarq GroupPage 2 of 4 A Camp1Broitus sbmked Company IHREP-V1O.1

ALS Laborator14 GOuPANALYTICAL CHEMISTRY & TES ING HERVICES ANALYTICAL REPORT A S

Client Project I D: Mission Support AllianceO5O6l 1Purchase Order: 24952

Workorder: 1112621Project Manager Paul Pope

Analytical ResultsSample ID: 11-23063-003 Media: Ghost Wipe Collected: 05/03/2011Lab ID: 1112621010 Received: 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

SSample ID: 11-23063-004 Media: Ghost Wipe Collected: 05/03/2011ILab ID: 1112621011 Received:, 05/06/2011

Method: NIOSH 7300 Mod. Prepared: 05/10/2011Analyzed: 05/11/2011

Analyte ug/sample RL (ug/sample)Beryllium <0.0071 0.0071

Report Authorization

Method: NIOSH 7300 Mod.

Penny A. Foote Anna Petersen

Analyst Peer Review

Laboratory Contact InformationPhone: (801) 266-7700 ALS Laboratory Group (formerly DataChem Laboratories, Inc.)Email: [email protected] 960 W Levoy DriveWeb: www.datachem.com Salt Lake City, Utah 84123

ALS USA, Corp.Wed, 05/11/11 10:38 AM rxtofikeALS Laboratorq GroupPage 3 of 4 A CampW Shers bmed wpany IHREP-V1O.1

ALS Laborator!4 GroupANALYTICCAL CHEMISTRY & TESTINC SERVICES ANALYTICAL REPORTA

Client Project ID: Mission Support AIlianceO5O6l 1Purchase Order: 24952

Workorder: 1112621Project Manager Paul Pope

General Lab CommentsThe results provided in this report relate only to the items tested.Samples were received in acceptable condition unless otherwise noted.Samples have not been blank corrected unless otherwise noted.This test report shall not be reproduced, except in full, without written approval of ALS.

ALS is accredited by ANSI/ACLASS (ISO 17025:2005) for specific fields of testing as documented in its current scope ofaccreditation (ID#AT-1421) which is available on request by contacting your project manager or view on the internet athttp://www.aclasscorp.com. The quality systems implemented in the laboratory apply to all technologies performed by ALS.

ALS provides professional analytical services for all samples submitted. ALS is not in a position to interpret the data and assumesno responsibility for the quality of the samples submitted.

All quality control samples processed with the samples in this report yielded acceptable results unless otherwise noted.

DefinitionsLOD = Limit of Detection = MDL = Method Detection Limit, A statistical estimate of method/media/instrument sensitivity.LOQ = Limit of Quantitation = RL = Reporting Limit, A verified value of method/media/instrument sensitivity.ND = Not Detected, Testing result not detected above the LOD or LOQ.** No result could be reported, see sample comments for details.< This testing result is less than the numerical value.(This testing result is between the LOD and LOQ and has higher analytical uncertainty than values at or above the LOQ.

ALS USA, Corp.Wed, 05/11/11 10:38 AM FanofteALS Laborato GroupPage 4 of 4 A CampoeN& Bm~wbm Canpany IHREP-V10.1

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Attachment 11

TRU Retrieval Project (WRAP, T Plant, LPCS, & TRU)John Trevino WRAPRpt #: Date Entered: Date Observed: Last Modified Date:37167 04/28/20 11 04/28/20 11 04/28/201 1

Entry Type: ARRA Include in CIR: No Hours in Field:

Title:Recovery plan - Recent leaky waste drum event.Summary:The FR attended a meeting to plan for recovery of the leaking waste drum. The work will be done on SOBA toaddress the high rad potentials, the potential acid vapors, and the beryllium potentials since the drum was aberyllium drum. The recovery will involve fork lift operations (using SOBA) to get to the drum. An AJHA meetingwill be held and the AJHA will be developed; the recovery package will be reviewed at a meeting chaired by theHRB chairman to be sure the hazards are adequately identified and controlled.

TRU Retriegva-l Project (WRAP, T Plant, LPCS, & TRU)

John Trevino WRAPRpt #: Date Entered: Date Observed: Last Modified Date:

37266 05/04/2011 05/04/2011 05/04/2011

Entry Type: AR 1A Include in CIR: No Hours in Field:

Title:Post Job Re'iv/esn learned meeting for repackaging of leaky waste drum HEDL-63.Summary:

Key informalonifacts discussed during the meeting.

- There is a process and procedure for selecting containers for repackaging and developing repackaginginstructions. *WMP 400, WIPP Procedures, Section 7.1.13, Waste Repackaging Guidance.] The procedurefocuses on rnmediating WIPP packaging & certification issues (e.g., treating or removing noncompliant items)versus instrL 'cticns for how to safely repackage waste.o Aerosol cais are crushed or removed from the drum.o Sealed cortainers (> 4 liters) are remediated by removing the lid/seal or puncturing the container.o Container;ed liquids (> 1 inch or 2.5 cm within the container) are absorbed or removed from the drum.o Free liquid; (> 1 % volume of the container) are absorbed or removed from the drum.The goal of tNs procedure is to provide instruction to the repackaging facilities to arrive at containers that meetthese expeclaticns.- There is a proceduralized process for repackaging waste in the TRU glovebox line. [WRP1 -OP-0725, TRUSorting Glovabox Operations] The procedure focuses on how to operate the glovebox equipment, removal ofprohibited itEms, and placing waste into the new waste drum. The procedure includes warnings for some hazardsthat may be 3-ncountered in the waste (i.e., pressurized inner containers, shock sensitive crystalline material,pyrophorics,and segregation of reactive materials) but does not provide instructions for treating acidic or causticmaterials (encept if being removed as a prohibited item).- Legacy infcrmation about the contents of older waste drums is incomplete and typically inconclusive. Informationabout the coitents of the HEDL drum was generic for the waste stream (such that all of the drums of this wastestream werelisted the same). The Solid Waste Information and Tracking System (SWITS) identifies the contentsas 27 kg of molic material (contaminated debris, paper, cloth, rags, wood, empty fiber or plastic containers, glass,piping, or otl'er solidls); no mention of liquids. The waste stream states "TRU Project Debris - Solvents, Organics,Metals," but any liquids (solvents or organics) should have been properly absorbed in the Vermiculite. The pHValue was icentified as > 2 - <1 2.5; Curie content: 10 DE-Ci.- The origina drum was originally packaged in 1979 (55 gallon drum, HEDL-63); the waste waspackaged/cmntained in a plastic inner container slightly smaller than the outer 55 gallon drum.* The drum vas buried for future retrieval in the Low Level Burial Ground (LLBG) 21 8-W-4C (late 70s, early 80s).The drum wzs retrieved and overpacked in an 85 gallon drum due to corrosion (breached container) in 2006.* The drum o:ntents were repackaged into two new waste drums in February 2011 (the drum was exited fromTRU Glovebx on February 9, 2011). Operating personnel said that the drum contained a lot of wet lookingabsorbent rmterial (Vermiculite). Four lbs of baking soda was spread over the wet absorbent material toneutralize it.- There are 15 drums listed in this HEDL waste stream; 2 have been repackaged; both contained acidic liquids,the other three daughter drums are being addressed (inspect & placed on spill pallets).- Other HED- waste drums of a different waste stream are being evaluated (but have not been repackaged).

Actions:

- Continue tc evaluate the extent of condition and address other at risk drums. In addition to general weeklyinspections cf waste drum storage, conduct more thorough inspections of the at risk drums for corrosion orleakage. Dedde if any additional drums need to be placed on spill pallets." Evaluate etgirieering controls for specific waste streams and revise procedures as appropriate." Evaluate th-e glovebox/repacking procedure and revise as necessary to address the issues. Add steps to therepackagingprocedure to address neutralization of acidic material, verification of adequate neutralization (i.e.,verify/test pror to placing waste in the new drum), or containing the material so that it doesn't corrode the drum." Strengthensteps and controls for tipping and unloading waste from drums in the glovebox." Evaluate tl-e Documented Safety Analysis requirements related to safe configuration of waste that is located inthe glovebox (e.g., , can waste be left on the sorting table over night or does it have to be containerized prior tocompleting tie shift.*Train perscinnEl according to the results of the evaluations and the procedure revisions.

- Review the actions of the previous drum leak event (August 2010). Evaluate if these actions were adequate.Take additional actions to address the event and prevent recurrence of drum acid attack events.

T3U Retrieval Project (WRAP, T Plant, LPCS, & TRU)Jphn Trevino WRAPR~t #: Date Entered: Date Observed: Last Modified Date:

3-3153 05/06/2011 05/06/20 11 05/06/20 11

Ertry 7ype: ARRA Include in CIR: No Hours in Field:

Title:Fhding - ineffective corrective actions for WRAP waste drum acid breach event from last August timeframe -

sinilar to last week's leaking drum event.Siimiary:The FR evaluated the corrective actions associated with Occurrence report EM-RL-CPRC-WRAP-2010O-0003(irvolving a drum that leaked due to residual acid attack). The cause analysis did not focus on the possibility thatre,:acking of waste drums could result in residual acids coming in contact with the metal drum interior. Thear~alysis seems to conclude that the event was isolated to the specific drum of waste and the what happened(sxralch the interior of the drum) during the repackaging. As a result of the leaking drum event from last week, theis~ue appears to be much broader and the cause analysis and corrective actions from last year's event weren'tefective to prevent recurrence. The following finding was written:

Fhding: The corrective actions associated with an event were not effect to prevent recurrence. The eventsin,'olved acid corrosion through the wall of new waste drums after the waste was repackaged into the new drumsinthe WRAP TRU glovebox.

ls~ue Type: Finding Significance Level: 2Slatement:The corrective actions associated with an event were not effect to prevent recurrence. The events involved acidccrrosion through the wall of new waste drums after the waste was repackaged into the new drums in the WRAPTIIU glovebox.Dtcussion:O~cu rrence report EM-RL-CPRC-WRAP-2010-0003 documented an event where a drum corroded through thewall of a new drum which was identified in August, 2010. The cause of this event focused on acid corrosion andccntents scratching the inside wall of the drum. The corrective actions do not address either and were inadequatetoprevent recurrence. Three of the four corrective actions address only the event problems and the recoveryactions. The forth corrective action states, 'Corrective Action 4: Review waste stream affected drum originated(e-ror in grammar). Add actions as determined appropriate." It is not clear what actions were identified to be takenbLt whatever actions were taken, they did not prevent recurrence. Actions should have been taken to identify andccmpletely absorb and neutralize any acids that could cause internal drum corrosion.Requirements:

- -0 CFR 830.122, Quality Assurance Criteria, states in part, "(c) Criteria 3, Management/Quality Improvement,(1' Establish and implement processes to detect and prevent quality problems. (2) Identify, control, and correctitens, services, and processes that do not meet established requirements. (3) Identify the causes of problemsard work to prevent recurrence as a part of correcting the problem. (4) Review item characteristics, processirmplementation, and other quality-related information to identify items, services, and processes needingirrprovement."

*DOE 0 414.1 C Quality Assurance, Section 4.b.(3) Management/Criterion 3 - Quality Improvement:(a Establish and implement processes to detect and prevent quality problems.(b Identify, control, and correct items, services, and processes that do not meet established requirements.(c Identify the causes of problems, and include prevention of recurrence as a part of corrective action planning.(d Review item characteristics, process implementation, and other quality-related information to identify items,sErvic es, and processes needing improvement.

- PRC-MVP-QA-599, Quality Assurance Program, states in part, "Quality improvement processes shall bee~tablished and implemented to satisfy the requirements of this section in accordance with 10 CFR 830.122 (c),"Criterion 3-Management/Quality Improvement," and DOE 0 414.1 C CRD, Attachment 2, 3.c,"%anagement/Criterion 3-Quality Improvement", which state.o E-stablish and implement processes to detect and prevent quality problems.o dentify, control and correct items, services, and processes that do not meet established requirements.o dentify the causes of problems, and include prevention of recurrence as a part of corrective action planning.

o Review item characteristics, process implementation, and other quality-related information to identify items,services, and processes needing improvement."Funct. Area: Trend Code: ISMS Funct.: Causa code:F&I CONOPS-INVST FEEDBK Lrnglmprov Issue Number: 9885

TRU Retrieval Project (WRAP, T Plant, LPCS, & TRU)John Trevino WRAPRpt #: Date Entered: Date Observed: Last Modified Date:37316 05/06/2011 05/06/2011 05/06/2011

Entry Type: ARRA Include in CIR: No Hours in Field:

Title:Recovery work - leaky drum in WRAP 2404-WB warehouse.Summary:The FR observed selected preparations, briefings, and performance of personnel entering 2404-WB in responseto the April 26 leaky drum event. Radiological levels in 2404-WB are extreme. The building is posted as aHCAJARA and also a Beryllium Controlled Area. A special RWP was written to support recovery operations.SOBA equipment and acid protective PPE were selected and used for entry. Wet rags were placed over the spillto keep contamination from drying up and becoming flighty. Soil cement was also used as appropriate totemporarily fix contamination until it is cleaned up and decontaminated. Paper, plastic, tapes, tarps, etc. wereplaced to minimize the spread of contamination. After several entries made on overtime last weekend, the teamreached the leaking drum on Tuesday night and were able to overpack it in an 85 gallon drum and bag the palletthat the drum was on. The drum was bagged 1 st and soda ash was placed in the bag to neutralize any acid thatleaks into the bag. The team continues to make daily entries to continue the cleanup operations. When the teamis able, the other at risk daughter drums will be placed on spill pallets. Plans are to place an engineered enclosureover the spill area so that it can be cleaned up /decontaminated within a controlled area (HEPA filtered, personnelon fresh air).

TRU Retrieval Project (WRAP, T Plant, LPCS, & TRU)John Trevino WRAPRpt #: Date Entered: Date Observed: Last Modified Date:

37569 05/20/20 11 05/02/20 11 05/20/2011

Entry Type: Routine Oversight Include in CIR: No Hours in Field:

Title:Recovery Plan, AJHA, & RWP - WRAP leaky waste drum.Summary:Reviewed the recovery plan, AJHA, and RWP for response to the leaky drum found in warehouse 2404-WB. Thedocuments appear to be adequate to safely conduct the work and several entries were already made using thedocuments. The recovery plan requires a pre-job brief of the hazards and controls which are included in the workdocuments. SOBA PPE and chemical resistant outer clothing and gloves were required for the recovery entrywork. The plan was presented to the WRAP HRB committee chairman. Personnel entered the building using therecovery plan and associated documents on May 1.Late entry from May2.

TRU Retrieval Project (WRAP, T Plant, LPCS, & TRU)

John Trevino WRAPRpt #: Date Entered: Date Observed: Last Modified Date:

37702 06/01/2011 05/20/2011 06/29/2011

Entry Type: ARRA Include in CIR: No Hours in Field:

Title:Extent of condition evaluation / actions - WRAP leaky waste drum.Summary:Late entry for May 20.

During the post job meeting held the week of May 2, the FIR questioned the extent of condition related to the leakydrum event and other drums that are considered high risk of acid attack and leakage due to their contents. Thedrums of highest risk of leakage are the second daughter drum packaged from drum HEDL-63 (sister drum to theleaky drum) and the two daughter drums packaged from HEDL-262 which are the only other daughter drums fromthis waste steam (see 0A37700). These drums are located in 2404-WB and will be placed on spill pallets whensupported by the recovery plan actions. The FR questioned if the other HEDL drums (1 3 drums) which have notbeen repackaged but are from the same waste stream have been inspected and placed on spill pallets. PROmanagement did not seem to believe that these drums are at risk of leaking and had not initiated actions toinspect them based in part because they have not yet been repackaged. The FIR emphasized that if one of theplastic inner liners started to leak in one these drums, another significant and costly leak could occur. Some ofthese drums were located in warehouse 2404-WB so they would have to be inspected after the recoveryoperations allow. But some of these drums were located in OWO with easy access allowing easy inspection. OnePRO manager told the FR that a management decision had been made to wait until an evaluation was conductedprior to inspecting these drums and placing them on a spill pallet. The FIR did not believe this was a gooddecision. After discussing the need to inspect the other at risk drums during the post job review and causalanalysis meetings during the weeks May 2 through May 9, the FIR became aware that the TRU Repackaging andProcessing manager had initiated actions to inspect the drums that were available at OWO and in the WRAPprocess area and these were placed on spill pallets on May 9th and May 10Oth. The FIR verified that the correctHEDL drums had been selected from the information available and that OWO had inspected these drums, movedthem to a common location, and placed them on spill pallets as appropriate.

Another set of at risk drums were identified and discussed. These were HEDL drums packaged during the late70s but are from a different waste stream. From radiography, these drums also contained an inner liner. Inaddition, their contents were much lower than the other 15 HEDL drums. However, when these were retrievedfrom Low Level Burial Ground 218-W-4O in 2006, these drums were highly corroded and were overpacked upsidedown (a technique used to overpack drums that were so corroded that they could not be safely tipped and slid intothe overpack drum). The FIR was concerned that that the inner containers for these drums could leak resulting in apossible acid attack of the overpack drum. This concern was based in part to the lack of knowledge of thepackaging and contents of these drums. On May 20 PRO conducted a review of this HEDL waste stream anddetermined that some of these drums had already been processed at PermaFix Northwest and their contentswere determined to be non acidic (neutral) thus putting to rest the concern for acid attack.

TRU Retrieval Project (WRAP, T Plant, LPCS, & TRU)John Trevino WRAPRpt #: Date Entered: Date Observed: Last Modified Date:

38141 06/28/2011 06/01/2011 06/28/2011

Entry Type: ARRA Include in CIR: No Hours in Field:

Title:Oversight of recovery operations and radiological work practices - WRAP leaky waste drum.Summary:Late entry from June 1 st.

On April 26, WRAP personnel found a waste drum that was leaking a highly radioactive / strong acid liquid ontothe floor of waste storage warehouse 2404-WB (see Occurrence Report RL-CPRC-WRAP-201 1-0002,Contamination Found on Waste Drum). A recovery plan was developed. During May, WRAP performed almostdaily entries into 2404-WB as part of the recovery operations. The FR attended many of the planning meetings,prejob briefings and observed many of the entry operations that were accomplished during this period of time. TheRADCON organization did a good job identifying the extreme radiological hazards and risks associated with thiswork and the controls that needed to implemented. Concern was expressed that the leaky material could drywhich would cause it to be flighty and spread easily. Initial entries were made using Self Contained BreathingApparatus (SCBA) which provided a high level of protection to personnel entering the area. Wet rags were usedto cover the spilled material, to keep it wet, and to minimize contamination spread. This is considered a goodradiological practice. The FR observed radiological practices associated with donning and doffing of PPE andradiological surveys of personnel and equipment exiting the area. Donning and doffing of PPE and personnelconduct of radiological surveys was good. The FR had a comment on use of acid resistant tape over theprotective gloves; a lesson that was learned during an acid spill event that occurred at the Savannah River site.The WRAP team was able to find the appropriate tape and used it for operations involving a potential for contactwith the acidic material.

The FR identified one issue related to the spill recovery operations and radiological practices:

Finding: The Radiological survey map for WRAP warehouse 2404-WB was updated or maintained current to the

radiological postings and controls within 2404-WB.

Issue Type: Finding Significance Level: 2Statement:The Radiological survey map for WRAP warehouse 2404-WB was updated or maintained current to theradiological postings and controls within 2404-WB.Discussion:Following the radioactive waste drum leak that was found on April 26, the radiological postings within the WRAPwarehouse 2404-WB were changed as radiological conditions within the building changed. On one occasion, thesurvey map of the facility was not updated in a timely manner to reflect the current radiological conditions withinthe building. This issues was raised with the WRAP RADCON manager; the radiological survey map was updatewithin a short period of time. Rad personnel were briefed on management's expectations to keep the survey mapscurrent. When radiological conditions change significantly or if the Rad postings change, the Rad survey mapneeds to be updated in a timely manner to reflect the changed conditions.Requirements:

CHPRC-00073, CHPRC Radiological Control Manual, Part 5, Radiological Monitning and Surveys:

Article 551 states in part:

'#1. Monitoring of individuals and areas shall be performed to:a. Demonstrate compliance with the requirements of this Manual;b. Document radiological conditions;c. Detect changes in radiological conditions...

#11. Monitoring results should be reviewed by the cognizant radiological supervisor. The review should ensurethat all required surveys have been performed and that the documentation is accurate and complete.#12. Results of current surveys or survey maps should be conspicuously posted to inform personnel of the

radiological conditions...#14. Monitoring data in each building or area should be compiled and reviewed at least quarterly or upon entry..."

Article 552, Radiation Exposure Surveys, states in part,

"in addition to the requirements of Article 55 1, unless the survey frequency has been reduced and specificallyidentified in an approved Radiation Protection Technical Equivalency Determination (see Article 113.3), routineradiation surveys should be performed in accordance with the following minimum frequencies:

a. Weekly, in routinely occupied Radiological Buffer Areas and Radiation Areas;b. Upon initial entry, weekly during continuing operations, and when levels are expected to change in HighRadiation Areas;c. Weekly, for temporary Radiation Area boundaries to ensure that Radiation Areas do not extend beyond postedboundaries;d. Monthly, or upon entry, if entries are less frequent than monthly for Radioactive Material Areas..."Funct. Area: Trend Code: ISMS Funot.: Causal Code:

RP RADCON-RADPRC WORK OpExcel Issue Number: 10063