6. SOLID STATE - WordPress.com
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E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988 6. SOLID STATE Choose the best answer: 1. Graphite and diamond are a) Covalent and molecular crystals b) ionic and covalent crystals c) both covalent crystals d) both molecular crystals 2. An ionic compound AxBy crystallizes in fcc type crystal structure with B ions at the centre of each face and A ion occupying entre of the cube. the correct formula of AxBy is a) AB b) AB3 c) A3B d) A8B6 3. The ratio of close packed atoms to tetrahedral hole in cubic packing is a) 1:1 b) 1:2 c) 2:1 d) 1:4 4. Solid CO2 is an example of a) Covalent solid b) metallic solid c) molecular solid d) ionic solid 5. Assertion : monoclinic sulphur is an example of monoclinic crystal system Reason: for a monoclinic system, a≠b≠c and α=γ= 90 0 β ≠ 90 0 a) Both assertion and reason are true and reason is the correct explanation of assertion. b) Both assertion and reason are true but reason is not the correct explanation of assertion. c) Assertion is true but reason is false. d) Both assertion and reason are false. 6. In calcium fluoride, having the flurite structure the coordination number of Ca2+ ion and F- Ion are (NEET) a) 4 and 2 b) 6 and 6 c) 8 and 4 d) 4 and 8 7. The number of unit cells in 8 gm of an element X ( atomic mass 40) which crystallizes in bcc pattern is (NA is the Avogadro number) a) 6.023 X 10 23 b) 6.023 X 10 22 c) 60.23 X 10 23 d) 6 023 ×10 23 8. × 40 8. The number of carbon atoms per unit cell of diamond is a) 8 b) 6 c) 1 d) 4 9. In a solid atom M occupies ccp lattice and( 1/3) of tetrahedral voids are occupied by atom N. find the formula of solid formed by M and N. a) MN b) M3N c) MN3 d) M3N2 www.Padasalai.Or www.Padasalai.Or www.Padasalai.Or www.Padasalai.Or www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasa ww.Padasalai.Org ww.Padasalai.Org ww.Padasalai.Org ww.Padasalai.Org ww.Padasa www.Padasalai.O www.Padasalai.O www.Padasalai.O www.Padasalai.O www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasalai.Org www.Padasala ww.Padasalai.Org ww.Padasalai.Org ww.Padasalai.Org ww.Padasalai.Org ww.Padasala Padasalai TrbTnpsc
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E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
6. SOLID STATE
Choose the best answer:
1. Graphite and diamond are
a) Covalent and molecular crystals b) ionic and covalent crystals
c) both covalent crystals d) both molecular crystals
2. An ionic compound AxBy crystallizes in fcc type crystal structure with B ions at
the centre of each face and A ion occupying entre of the cube. the correct formula of AxBy is
a) AB b) AB3 c) A3B d) A8B6
3. The ratio of close packed atoms to tetrahedral hole in cubic packing is
a) 1:1 b) 1:2 c) 2:1 d) 1:4
4. Solid CO2 is an example of
a) Covalent solid b) metallic solid c) molecular solid d) ionic solid
5. Assertion : monoclinic sulphur is an example of monoclinic crystal system
Reason: for a monoclinic system, a≠b≠c and α=γ= 900 β ≠ 900 a) Both assertion and reason are true and reason is the correct explanation of
assertion.
b) Both assertion and reason are true but reason is not the correct explanation
of assertion.
c) Assertion is true but reason is false.
d) Both assertion and reason are false.
6. In calcium fluoride, having the flurite structure the coordination number of
Ca2+ ion and F- Ion are (NEET)
a) 4 and 2 b) 6 and 6 c) 8 and 4 d) 4 and 8
7. The number of unit cells in 8 gm of an element X ( atomic mass 40) which
crystallizes in bcc pattern is (NA is the Avogadro number)
a) 6.023 X 1023 b) 6.023 X 1022
c) 60.23 X 1023 d) 6 023 ×1023
8. × 40
8. The number of carbon atoms per unit cell of diamond is
a) 8 b) 6 c) 1 d) 4
9. In a solid atom M occupies ccp lattice and( 1/3) of tetrahedral voids are occupied
by atom N. find the formula of solid formed by M and N.
a) MN b) M3N c) MN3 d) M3N2
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
10. The composition of a sample of wurtzite is Fe 0.93O 1.00 what % of Iron present
in the form of Fe3+ ?
a) 16.05% b) 15.05% c) 18.05% d) 17.05%
11. The ionic radii of A+ and B− are 098×10-10.m and 1.81× 10 -10.m the
coordination number of each ion in AB is
a) 8 b) 2 c) 6 d) 4
12. CsCl has bcc arrangement, its unit cell edge length is 400pm, its inter atomic
distance is
a) 400pm b) 800pm c) √3 100×pm d) (3√ /2) ×400 pm
13. A solid compound XY has NaCl structure. if the radius of the cation is 100pm ,
the radius of the anion will be
a) (100/ 0414) b) (0. 732 100) c) 100× 0414 d) (0.414/ 100 )
14. The vacant space in bcc lattice unit cell is
a) 48% b) 23% c) 32% d) 26%
15. The radius of an atom is 300pm, if it crystallizes in a face centered cubic lattice,
the length oif the edge of the unit cell is
a) 488.5pm b) 848.5pm c) 884.5pm d) 484.5pm
16. The fraction of total volume occupied by the atoms in a simple cubic is
a)
√ b)
c)
d)
√
17. The yellow colour in NaCl crystal is due to
a) excitation of electrons in F centers
b) reflection of light from Cl- ion on the surface
c) refraction of light from Na+ ion
d) all of the above
18. If ‘a’ stands for the edge length of the cubic system ; sc , bcc, and fcc. Then the
ratio of radii of spheres in these systems will be respectively.
a) 1
√
√
b) (√ √ √ )
c) 𝟏
𝟐
√
𝟏
𝟐√𝟐 d)
1
√
1
√
19. if ‘a’ is the length of the side of the cube, the distance between the body
centered atom and one corner atom in the cube will be
a)
√ b)
√ c )
√
d)
√
𝟐
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
20. Potassium has a bcc structure with nearest neighbor distance 4.52 A0 . its
atomic weight is 39. its density will be
a) 915 kg m-3 b) 2142 kg m-3 c) 452 kg m-3 d) 390 kg m-3
21. Schottky defect in a crystal is observed when
a) unequal number of anions and anions are missing from the lattice
b) equal number of anions and anions are missing from the lattice
c) an ion leaves its normal site and occupies an interstitial site
d) no ion is missing from its lattice.
22. The cation leaves its normal position in the crystal and moves to some
interstitial position, the defect in the crystal is known as
a) Schottky defect b) Fcenter c) Frenkel defect d)non-stoichiometric defect
23. Assertion: due to Frenkel defect, density of the crystalline solid decreases.
Reason: in Frenkel defect cation and anion leaves the crystal.
a) Both assertion and reason are true and reason is the correct explanation of
assertion.
b) Both assertion and reason are true but reason is not the correct explanation
of assertion.
c) Assertion is true but reason is false.
d) Both assertion and reason are false
24. The crystal with a metal deficiency defect is
a) NaCl b) FeO c) ZnO d) KCl
25. A two dimensional solid pattern formed by two different atoms X and Y is
shown below. The black and white squares represent atoms X and Y respectively.
the simplest formula for the compound based on the unit cell from the pattern is
a) XY8 b) X4Y9
c) XY2 d) XY4
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
Define unit cell.
A basic repeating structural unit of a crystalline solid is called a unit cell.
2. Give any three characteristics of ionic crystals.
1. Ionic solids have high melting points.
2. These solids do not conduct electricity, because the ions are fixed in their lattice
positions.
3. They do conduct electricity in molten state (or) when dissolved in water because,
the ions are free to move in the molten state or solution.
4. They are hard as only strong external force can change the relative positions of
ions.
3. Differentiate crystalline solids and amorphous solids.
4. classify the following solids
a. P4------Molecular solid
b. Brass---Metallic solid
c. diamond---Covlent solid
d. NaCl ----Ionic Solid
e. Iodine ----Molecular solid
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
5. Explain briefly seven types of unit cell.
Cubic Lattice: Cubic lattice is formed into three possible geometries of unit cells: primitive,
body-centred and face centred unit cells. In a cubic lattice, all the edges are equal and the
angle between their faces is 90° that is, mutually perpendicular.
Tetragonal Lattice: The formation of tetragonal lattice takes place in
two geometries of unit cells: primitive and body centred unit cells. In a tetragonal lattice,
only one edge has different length and angle between respective edges is 90° that is,
mutually perpendicular
Orthorhombic Lattice: There are four types of orthorhombic lattice mainly:
primitive, end-centred, body-centred and face centred. In orthorhombic lattice, the edge
lengths are unequal in nature and the angle between respective edges is 90° that is,
mutually perpendicular
Monoclinic Lattice: Monoclinic lattice is formed from two types of
unit cells namely: primitive and end centred. Monoclinic lattice has unequal sides and two
angles between the faces of the lattice are 90°.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
Hexagonal Lattice: Hexagonal lattice is formed from only one type of unit cell that is,
primitive. In hexagonal lattice, only one side and two angles are 90° and one angle is 120°.
Rhombohedral Lattice: Rhombohedral Lattice is also formed from one type of unit cell that
is, primitive. In Rhombohedral Lattice all the sides are equal and two angles between the
faces of the rhombohedral lattice are less than 90°.
Triclinic Lattice: The formation of triclinic lattice also takes place from one type of unit cell
that is, primitive. In triclinic lattice all the sides are unequal and none of the angles between
the faces of the triclinic lattice are 90°.
6. Distinguish between hexagonal close packing and cubic close packing.
Hexagonalclosepacking:
when the tetrahedral voids of the second layer is covered by the spheres of the third
layer. so that the spheres of the third layer are exactly aligned with those of the first
layer, we get a pattern of spheres which is repeated in alternate layers. This pattern
can be written in the form of ABAB ....... pattern. This structure is called hexagonal
close packed (hcp) structure. Magnesium and zinc metals have this pattern
cubic close packing: When the third layer is placed above the second layer in a
manner such that its spheres cover the octahedral voids. and the spheres of the
third layer are not aligned with first or the second layer, arrangement is called CCP
type.This pattern of layers is often written as ABCABC ........... This
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
structureiscalledcubicclosepacked(ccp)
7. Distinguish tetrahedral and octahedral voids.
Tetrahedral voids: The vacant space among four spheres having tetrahedral
arrangement is called tetrahedral hole. the co-ordnation number of
tetrahedral void is four.
Octahedral Void: The void formed by equilateral triangles with apices in
opposite direction is called octahedral void. the co-ordination number of
octahedral void is six
There is two terahedral sites for each sphere and there is only one octahedral
site for each sphere.
8. What are point defects?
(i) If the deviation occurs due to missing atoms, displaced atoms, the imperfection
is known as point defect.
(ii)such defect arise due to imperfect packing during the original crystalliasation or
may arise from thermal vibrations of atoms at elevated temperatures.
9. Explain Schottky defect.
Schottky defect arises due to the missing of equal number of cations and
anions from the crystal lattice. This effect does not change the stoichiometry of the
crystal. Ionic solids in which the cation and anion are of almost of similar size show
schottky defect. Example: NaCl. Presence
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
10. Write short note on metal excess and metal deficiency defect with an example.
Metal excess defect:
Metal excess defect arises due to the presence of more number of metal ions as
compared to anions. Alkali metal halides NaCl, KCl show this type of defect. The
electrical neutrality of the crystal can be maintained by the presence of anionic
vacancies equal to the excess metal ions (or) by the presence of extra cation and
electron present in interstitial position.
For example, when NaCl crystals are heated in the presence of sodium vapour,
Na+ ions are formed and are deposited on the surface of the crystal. Chloride
ions (Cl-) diffuse to the surface from the lattice point and combines with Na+
ion. The electron lost by the sodium vapour diffuse into the crystal lattice and
occupies the vacancy created by the Cl- ions. Such anionic vacancies which are
occupied by unpaired electrons are called F centers. Hence, the formula of NaCl
which contains excess Na+ ions can be written as Na Cl
Metal deficiency defect:
Metal deficiency defect arises due to the presence of less number of cations
than the anions. This defect is observed in a crystal in which, the cations have
variable oxidation states.
For example, in FeO crystal, some of the Fe2+ ions are missing from the crystal
lattice. To maintain the electrical neutrality, twice the number of other Fe2+
ions in the crystal is oxidized to Fe3+ ions. In such cases, overall number of
Fe2+ and Fe3+ ions is less than the O2- ions. It was experimentally found that
the general formula of ferrous oxide is FexO, where x ranges from 0.93 to 0.98.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
11. Calculate the number of atoms in a fcc unit cell.
.
i) face-centred cubic:
A face atomis sharedequally between two unit cells and therefore a face atom
contributes only fN
2
to the unit cell.
The number of atoms per unit cell in fcc = c fN n
8 2
= 8
8 +
6
2
= 1 + 3 = 4
Nf = Number of atoms at the faces.
12. Explain AAAA and ABABA and ABCABC type of three dimensional packing with the help of neat diagram.
(i) AAA… type:
Linear arrangement of spheres in one direction is repeated in two dimension i.e.,
more number of rows can be generated identical to the one dimensional
arrangement such that all spheres of different rows align vertically as well as
horizontally as shown in the fig. If we denote the first row as A type
arrangement, then the above mentioned packing is called AAA type, because
all rows are identical as the first one. In this arrangement each sphere is in
contact with four of its neighbours.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
(i) ABAB.. Type:
In this type, the second row spheres are arranged in such a way that they fit in
the depression of the first row as shown in the figure. The second row is denoted as
B type. The third row is arranged similar to the first row A, and the fourth one is
arranged similar to second one. i.e., the pattern is repeated as ABAB….In this
arrangement each sphere is in contact with 6 of its neighbouring spheres.
On comparing these two arrangements (AAAA...type and ABAB….type) we found
that the closest arrangement is ABAB…type.
(iii) ABC.. Type:
Alternatively, the third layer may be placed over the second layer in such a way
that all the spheres of the third layer fit in octahedral voids. This arrangement
of the third layer is different from other two layers (a) and (b), and hence, the
third layer is designated (c). If the stacking of layers is continued in
abcabcabc… pattern, then the arrangement is called cubic close packed (ccp)
structure.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
13. Why ionic crystals are hard and brittle?
1. Ionic solids have high melting points.
2. These solids do not conduct electricity, because the ions are fixed in their lattice
positions.
3. They do conduct electricity in molten state (or) when dissolved in water
because, the ions are free to move in the molten state or solution.
4. They are hard as only strong external force can change the relative positions of
ions
14. Calculate the percentage efficiency of packing in case of body centered cubic crystal.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
15. What is the two dimensional coordination number of a molecule in square close packed layer?
In two dimensional square close−packed layer, a molecule touches four neighbor
atoms. Therefore, 4 is the two dimensional coordination number of a molecule in
square close packed layer
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
16. Experiment shows that Nickel oxide has the formula Ni0.96 O 1.00 . What
fraction of Nickel exists as of Ni2+ and Ni3+ ions?
Formula is Ni0.98O1.00
So the ration of Ni : O = 98:100
So if there are 100 atoms of oxygen then 98 atoms of Ni
Let number of atoms of Ni+2 = x
Then number of atoms of Ni+3 = 98–x
Charge on Ni = charge on O
So that oxygen has charge –2
3(98–x) + 2x = 2 (100)
294 –3x +2x = 200
–x = – 94
x = 94
Percentage of Ni+2 = (atom of Ni+2/total number of atoms of Ni)100
=100(94/98)*100
= 96%
Percentage of Ni+3 =100 – Ni+2
=100 – 96
= 4 %
17. What is meant by the term “coordination number”? What is the coordination number of atoms in a bcc structure?
The coordination number of an atom, ion or molecule is the number of constituent particles which touch that particular atom, atom or molecule.
In a body–centered cubic structure coordination number is 8.
18. An element has bcc structure with a cell edge of 288 pm. the density of the element is 7.2 gcm-3. how many atoms are present in 208g of the element.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
19. Aluminium crystallizes in a cubic close packed structure. Its metallic radius is 125pm. calculate the edge length of unit cell.
Given: Radius (r) = 125 pm
To find: Edge length of unit cell (a) = ?
Formula: r = a 2 √2 × Calculation: Since Al crystallizes in Face centred cubic
(FCC) structure From formula, a = r × 2 × √2 = 125 × 2 × 1.4142
∴ a = 353.5 pm
20. If NaCl is doped with 10-2 mol percentage of strontium chloride, what is the concentration of cation vacancy?
GivenConetration of SrCl2 = 10−2 mol%
Concentration is in percentage so that take total 100 mol of solution
Number of moles of NaCl = 100 – moles of SrCl2
Moles of SrCl2is very negligible as compare to total moles so Number of moles
of NaCl = 100
1 mol of NaCl is dipped with = 10−2/100 moles of SrCl2
= 10–4 mol of SrCl2
So cation vacancies per mole of NaCl =10–4 mol
1 mol = 6.022 x1023 particles
So cation vacancies per mole of NaCl = 10–4 x 6.022 x1023
= 6.02 x1017
So that, the concentration of cation vacancies created by SrCl2 is 6.022 × 107 per mol of NaCl.
21. KF crystallizes in fcc structure like sodium chloride. calculate the distance
between K+ and F− in KF.( given : density of KF is 248 3 .g cm− )
We know that D= z×M
a3×NA
D=z×Ma3×NA Given Density = 2.48 g/cm3
z = number of atoms per unit cell.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
Given KFis NaCl type So, z will be 4.
M = molar mass of KF = 58.08 g/mol
a = edge length NA = avagadro number = 6.022 x 1023. Putting all the values in above equation
(1) we get: a3= 4×58.8
2.48×6.023×1023 a3=4×58.82.48×6.023×1023
= 232.32
1.5×10−24cm3
=232.321.5×10−24cm3
a=5.37×10−10cm
a=5.37×10−10cm = 537 pm
Edge length a = 2(rc+ra)
2(rc+ra) rc+ra =9/2
rc+ra 537/2 =268pm
22. An atom crystallizes in fcc crystal lattice and has a density of 10 gcm
-3 with
unit cell edge length of 100pm. calculate the number of atoms present in 1 g of
crystal.
Edge length of the unit cell a =100pm = 100X10-10 cm
= 1X10-8 cm
Volume of unit cell = a3 = (1X10-8)3 = 1X10-24 cm3
Given mass =1gm
Density = mass/volume
Volume =mass/density = 1/10 gcm-3
No of unit cells in 1 gm of the substance = given volume/volume of unit cell
0.1cm3/1X10-24 = 1X1023
Substance is FCC ,hence it contains 4 atoms in it
Then the no of atom = 4 X 1X1023 = 4 X1023 23. Atoms X and Y form bcc crystalline structure. Atom X is present at the corners
of the cube and Y is at the centre of the cube. What is the formula of the compound?
The atom at the body centre makes a contribution of 1 to the unit cell, while the
atom at the corner makes a contribution of 1/8to the unit cell.
Thus, number of atoms Y per unit cell
= Number of atoms × Contribution per unit cell
= 8 (at the corners) × 1/8 atoms per unit cell
= 1
Thus, number of atoms X per unit cell
= Number of atoms × contribution per unit cell
= 1 (at the body centre) × 1
= 1
Thus, the formula of the given compound is XY.
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Padasalai TrbTnpsc
E.M.GOVT .HR SEC SCHOOL,PANPOLI,TIRUNELVELI
S.VISHNU SANKAR., M.Sc.,MPhil.,B.Ed. P.G.ASST .9443101988
24. Sodium metal crystallizes in bcc structure with the edge length of the unit cell
4.3× 10-8
. cm. calculate the radius of sodium atom.
Edge length of the crystal a= 4.3 X 10-8 cm
Sodium has body centred cubic.
For BCC r =√3 a/4
√3x 4.3 X 10-8/4 =1.86 X 10-8 cm (or )186 X 10-10 cm (or ) 186 pm
25. Write a note on Frenkel defect
Frenkel defect arises due to the dislocation of ions from its crystal lattice. The ion
which is missing from the lattice point occupies an interstitial position. This defect is shown by ionic solids in which cation and anion differ in size. Unlike Schottky
defect, this defect does not affect the density of the crystal. For example AgBr, in
this case, small Ag+ ion leaves its normal site and occupies an interstitial position
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