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    LEMBAR JAWABAN

    Ujian Tengah Semester Genap 2010-2011

    Mata Kuliah Teknologi Informasi

    Hari/tanggal : Selasa, 1 Mei 2012Waktu : 08.00 09.30 wib

    Pengampu : Nor Basid Adiwibawa Prasetya, S.Si.,M.Sc.

    Peserta Ujian/NIM : Laksmi Dewi P / J2C009037

    Email : [email protected]

    Jawaban:

    1. a. Judul Artikel: Photocatalytic self-cleaning properties of

    cellulosic fibers modified by nano-sized zinc oxide

    b. Abstrak: Nano-sized zinc oxide was synthesized and deposited

    onto cellulosic fibers using the solgel process at ambienttemperature. The prepared materials were characterized using

    several techniques including scanning electron microscopy,

    transmission electron microscopy, diffuse reflectance

    spectroscopy, X-ray diffraction and thermogravimetric analysis.

    X-ray diffraction studies of the ZnO-coated fiber indicate

    formation of the hexagonal crystal phase which was satisfactory

    crystallized on the fiber surface. The electron micrographs show

    formation of zinc oxide nanoparticles within 1015 nm in size

    which have been homogeneously dispersed on the fiber surface.

    The prepared materials show significant photocatalytic self-

    cleaning activity, which was monitored by diffuse reflectance

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    spectroscopy. The photoactivity was studied upon measuring the

    photodegradation of methylene blue and eosin yellowish under

    UVVis irradiation. The photocatalytic activity of the treated

    fabrics was fully maintained performing several cycles of

    photodegradation.

    Keywords: Cellulosic fiber;Coating;Photocatalysis;Self-

    cleaning;Nano-sized zinc oxide

    2. Judul Artikel:Novel 3-alkanoyl/aroyl/heteroaroyl-2H-chromene-2-thiones: synthesis and evaluation of their antioxidant

    activities.

    Singh OM, Devi NS, Thokchom DS, Sharma GJ.

    a.Nama jurnal: Europen Journal Medical Chemistry

    b. Volume: 45

    c. Issue: 6

    d. Tanggal terbit: 2010 June

    e. Halaman: 22502257

    f. Abstrak: A facile, convenient and highyielding synthesis of a combinatorial library of3-

    alkanoyl/aroyl/heteroaroyl-2H-chromene-2-thiones has been

    developed by the condensation of easily accessible -

    oxodithioesters and salicylaldehyde/substituted 2-

    hydroxybenzaldehydes under solvent-free conditions. The

    assessment of radical scavenging capacity of the compoundstowards the stable free radical2,2-diphenyl-1-picrylhydrazyl

    http://www.ncbi.nlm.nih.gov/pubmed?term=%22Singh%20OM%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed?term=%22Devi%20NS%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed?term=%22Thokchom%20DS%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed?term=%22Sharma%20GJ%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed/20170989http://www.ncbi.nlm.nih.gov/pubmed/20170989http://www.ncbi.nlm.nih.gov/pubmed?term=%22Singh%20OM%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed?term=%22Devi%20NS%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed?term=%22Thokchom%20DS%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed?term=%22Sharma%20GJ%22%5BAuthor%5Dhttp://www.ncbi.nlm.nih.gov/pubmed/20170989
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    (DPPH) was measured and these compounds were found to

    scavenge DPPH free radical efficiently. Five selected

    compounds were able to protect curcumin from the attack ofsulfur free radical generated by radiolysis of glutathione

    (GSH). The newly synthesized compounds exhibitedprofoundantioxidantactivities. Five of them rendered

    comparatively high antioxidant capacity.

    3. a. Nama Jurnal: Carbohidrate research

    Scope: which includes all aspects of carbohydrate chemistry and

    biochemistry. Articles published in the journal cover sugars and

    their derivatives (also cyclitols, and model compounds for

    carbohydrate reactions), oligo- and polysaccharides, nucleosides,

    nucleotides, and glycoconjugates.

    These systems are considered from the viewpoints of:

    chemical synthesis;

    the study of structures and stereochemistry;

    reactions and their mechanisms;

    isolation of natural products;

    physicochemical studies;

    macromolecular dynamics;

    analytical chemistry; biochemistry (biosynthesis,

    metabolism, degradation, structural and functional

    biochemistry, enzyme mechanisms, glycosidases and glycosyl

    transferases, etc.);

    action of enzymes;

    immunochemistry;

    technological aspects;

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    glycomics;

    glycoinformatics;

    glycobiology

    The journal includes normal length research papers, mini reviews,

    notes, rapid communications and book reviews together with

    notices of meetings concerned with carbohydrates.

    b. Nama Jurnal: chemical reviews

    Scope: Chemical Reviews is one of the most highly regardedand highest-ranked journals covering the general topic of

    chemistry.

    The mission of Chemical Reviews is to provide comprehensive,authoritative, critical, and readable reviews of important recent

    research in organic, inorganic, physical, analytical, theoretical, and

    biological chemistry.

    In addition to the general reviews, the journal has published since

    1985 periodic thematic issues focusing on a single theme ordirection of emerging research

    c. Nama Jurnal: Green Chemistry

    Scope:based on, but not limited to, the definition proposed byAnastas and Warner (Green Chemistry: Theory and Practice, P. T.Anastas and J. C. Warner, Oxford University Press, Oxford,

    1998): Green chemistry is the utilisation of a set of principles that

    reduces or eliminates the use or generation of hazardous

    substances in the design, manufacture and application of chemical

    products.

    d. Nama Jurnal:Journal of Herbs, Spices and Medicinal Plants

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    Scope: TheJournal of Herbs, Spices & Medicinal Plants is an

    essential reference filled with recent research and other valuable

    information associated with herbs, spices, and medicinal

    plants. TheJournalserves as a focus point through which

    investigators and others may publish material of importance to the

    production, marketing, and utilization of these plants and

    associated extracts. The journal covers the following topics:

    growth, development, horticulture, ecology, physiology, genetic,

    chemistry, and economics.

    Original articles, review articles, and book reviews provide

    information of interest to an international audience of researchers,

    teachers, technicians, and managers involved with productionand/or marketing of herbs, spices, and medicinal plants. Managers

    of food companies, food processing facilities, medical research

    laboratories, government agencies, and others interested in new

    chemicals, food additives, international trade, patents, and other

    items can easily review new findings.

    TheJournal of Herbs, Spices & Medicinal Plants is a forum in

    which recent research and other information associated with herbs,

    spices, and medicinal plants is shared. TheJournalrepresents a

    centralized database accessible by investigators within the

    international community that work with or have an interest in

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    herbs, spices, and medicinal plants.

    e. Nama Jurnal: Journal of Organic Chemistry

    Scope: The Journal of Organic Chemistry (JOC) welcomes

    original contributions of fundamental research in all branches ofthe theory and practice of organic chemistry.

    The Journal of Organic Chemistry now publishes JOC Featured

    Articles-full papers selected by Editor-in-Chief C. Dale Poulter

    and the JOC Associate Editors for special consideration asexceptional contributions to the journal as identified during thereview process. Upon acceptance, the galley proofs of these

    selected manuscripts are prepared and sent to the author on an

    expedited schedule to facilitate more rapid online and print

    publication.

    JOC Featured Articles are listed online as Article ASAPs on the

    JOC home page as soon as the corrected galley proof is returned.

    f. Nama Jurnal: Current Medicinal Chemistry

    Scope: Current Medicinal Chemistry covers all the latest and

    outstanding developments in medicinal chemistry and rationaldrug design. Each issue contains a series of timely in-depth

    reviews written by leaders in the field covering a range of thecurrent topics in medicinal chemistry. Current Medicinal

    Chemistry is an essential journal for every medicinal chemist who

    wishes to be kept informed and up-to-date with the latest and most

    important developments

    g. Nama Jurnal: Tetrahedron Letter

    Scope: Tetrahedron Letters provides maximum dissemination ofoutstanding developments in organic chemistry. The journal is

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    published weekly and covers developments in techniques,

    structures, methods and conclusions in experimental and

    theoretical organic chemistry. Rapid publication of timely andsignificant research results enables researchers from all over the

    world to transmit quickly their new contributions to large,international audiences

    h. Nama Jurnal: Chemical Communication

    Scope: Chemical Communications publishes preliminary

    accounts of original and significant research that will appeal to a

    wide general readership or be of exceptional interest to the

    specialist. Following publication of a communication a full paper

    should be prepared and submitted to an appropriate journal.

    Acceptance in Chemical Communications does not guaranteesubsequent publication in the RSC's journals. Short articles that are

    detailed enough should be submitted as a complete account to the

    appropriate RSC journal

    i. Nama Jurnal: Journal of Organometallic Chemistry

    Scope: the journal has been enlarged to encompass important

    research on organometallic complexes in bioorganometallic

    chemistry andmaterial sciences, and of heavier main group

    elements in organometallic chemistry.

    j. Nama Jurnal: Electroanalysis

    Scope: Electroanalysis is an international, peer-reviewed journal

    covering all branches of electroanalytical chemistry, including

    both fundamental and application papers as well as reviews

    dealing with analytical voltammetry, potentiometry, new

    electrochemical sensors and detection schemes and practical

    applications.

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    Serving as a vital communication link between the research labs

    and the field, Electroanalysis helps you to quickly adapt the latest

    innovations into practical clinical, environmental and industrialapplications. Electroanalysis provides the most comprehensive

    coverage of the field and is the number one source for informationon electroanalytical chemistry

    4. a. CAS Registry number: 67-66-3

    Nama senyawa: Kloroform

    Rumus molekul senyawa: CHCl4

    b. Gambar Spektra:

    Spektra MS

    MS-NW-0078 SDBS NO. 894

    chloroform

    CHCL3 (Mass of molecular ion: 118)

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    Source Temperature: 210 C

    Sample Temperature: 25 C

    Spektra CNMR

    ppm Int. Assign.

    77.22 1000 1

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    Spektra HNMR

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    Assign. Shift(ppm)

    A 7.256

    Spektra IR

    Spektra RAMAN

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    Spektra ESR

    N