Nanorefrigerant effect on performance of domestic refrigerator
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Transcript of Nanorefrigerant effect on performance of domestic refrigerator
www.ijcrt.org © 2018 IJCRT | Volume 6, Issue 2 April 2018 | ISSN: 2320-2882
IJCRT1812587 International Journal of Creative Research Thoughts (IJCRT) www.ijcrt.org 1254
Nanorefrigerant effect on performance of domestic
refrigerator: A Review
1Nihit D. Doshi 1Post Graduate Student
1ME – Thermal Engineering 1SVMIT, Bharuch 392001, INDIA
Abstract: Vapor compression refrigeration systems consume high-grade energy and contribute to global
warming and ozone layer depletion due to the environmentally unfriendly refrigerants. The use of
nanorefrigerants offer good performance in domestic refrigerator in terms of energy consumption and cooling
time. In this study, a review of the previous studies carried out with the use of nanorefrigerants in refrigeration is
presented. An attempt has been made to cover the current status, possibilities, and problems related to the use of
nanorefrigerants as alternative refrigerants. Nanorefrigerant properties, environmental impact and characteristic
are also presented. Results showed that nanorefrigerants can offer proper refrigerants as compare to hydrocarbons
from the standpoint of environment impact, energy efficiency, Energy consumption and compressor discharge
temperatures.
Keywords - Nanorefrigerant, Domestic refrigerator, Power consumption, Cooling time.
I. INTRODUCTION
1.1 DOMESTIC REFRIGERATOR:
A domestic refrigerator has become one of the most important household appliances all over the world. More
than millions of domestic refrigerators are manufactured by many company every year. A domestic refrigerator is
small cold storage where several food products such as ice cream, meat, fish, milk, fruits, vegetables, water etc. can
be stored at reduced temperatures. The most common domestic refrigerator uses a vapour compression refrigeration
system for maintaining required storage conditions, even though many refrigerators use the principle of triple fluid
vapour absorption refrigeration system. Domestic refrigerators are available in many sizes and designs. The domestic
refrigerator is specified by the storage volume (gross or net), like a 300 litre refrigerator means a domestic
refrigerator with an internal storage volume of 300 litres. The domestic refrigerators are available in many sizes from
about 100 litres to about 600 litres. Currently, most of these units use either HFC-134a or hydrocarbons as
refrigerants. They use hermetic compressor with a capillary tube as an expansion device. The condenser of small
refrigerators are of natural convection type, while larger refrigerators may have a fan for forced air circulation over
the condenser.
1.1.1 Internal parts of the Domestic Refrigerator
The internal parts of the refrigerator are ones that do actual working of the refrigerator. Some of the internal parts
are located at the back of the refrigerator and some inside the main compartment of the refrigerator. Some internal
parts of the domestic refrigeratror are:
1)Refrigerant: The refrigerant flows through all the internal parts of the refrigerator. It is the refrigerant by which the
cooling effect occurred in the evaporator. It absorbs the heat from the substance to be cooled in the evaporator and
release it to the atmosphere via condenser.
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2) Compressor: The compressor is located at the back of the refrigerator and in the bottom area. The compressor
sucks the refrigerant from the evaporator and discharges it at high pressure and temperature. The compressor is run by
the electric motor and it is the major power consuming component of the refrigerator.
3) Condenser: The condenser is the thin coil of tube of copper located at the back of the refrigerator. The refrigerant
from the compressor enters the condenser where it is cooled by the atmospheric air thus losing heat absorbed by it in
the evaporator and the compressor. Fins are placed in the condenser for increasing heat transfer rate.
4) Expansion valve or the capillary: The refrigerant leaving the condenser enters the expansion valve. When
the refrigerant is passed through the capillary its pressure and temperature decreases suddenly.
5) Evaporator or Chiller: The refrigerant at very low pressure and temperature enters the evaporator or the
freezer. Generally in domestic refrigerators the plate types of evaporator is used. The refrigerant takes the heat
from the substance to be cooled in the evaporator and evaporated then it is sucked by the compressor. This cycle keeps
on repeating.
6) Thermostat: To control the temperature inside the refrigerator thermostat is used and sensor of it is connected
to the evaporator. The thermostat setting can be done by the round knob inside the refrigerator compartment. When
the set temperature is reached inside the refrigerator the thermostat stops the electric supply to the compressor and
compressor stops and when the temperature decreases below certain level it restarts the supply to the compressor.
7) Defrost System: The defrost system of the refrigerator removes the excess ice from the surface of the evaporator.
The defrost system can be operated manually by the thermostat button or there is automatic system consists of the
electric heater and the timer.
The external parts of the refrigerator are: freezer compartment, thermostat control, refrigerator compartment, crisper,
refrigerator door compartment, light switch etc.
1.1.2 External parts of the Domestic Refrigerator
The external parts of the compressor are the parts that can be seen externally and used for the many purposes.
1) Freezer compartment: The food items that are to be placed at the freezing temperature are stored in the freezer
compartment. The temperature here is below zero degree Celsius so the water and many other fluids freeze in this
compartment.
2) Thermostat control: The thermostat control consists of the round knob with the tempera- ture scale that maintain
the required temperature inside the refrigerator. Proper setting of the thermostat as per the requirements save the lots of
refrigerator electricity bills.
3) Refrigerator compartment: The refrigerator compartment is the biggest part of the refrigerator. All the food
items that are to be maintained at temperature above zero degree Celsius but in cooled condition are placed in this
compartment. The refrigerator compartment can be divided into number of smaller shelves like meat keeper and others
as per the requirement.
4) Crisper: The highest temperature in the refrigerator compartment is maintained in the crisper. The food items
that can remain fresh even at the medium temperature like fruits, vegetables, etc in this part.
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5) Refrigerator door compartment: There are number of smaller subsections in the refrigerator main door
compartment. Many of these are egg compartment, butter, dairy, etc.
6) Switch: This is the small button that operates the small light inside the refrigerator. As soon the door of the
refrigerator opens, it supplies electricity to the bulb and it starts, while when it is closed the light from the bulb stops.
This helps in starting the internal bulb only when required.
1.2 HISTORY OF REFRIGERANT:
Refrigerant:
Refrigerants are the working medium used in refrigerating systems which evaporates by absorbing the heat from the
space that is to be cooled and producing the cooling effect.
First Generation Refrigerants
At the starting of 19th century mechanical refrigeration were characterized by use of natural refrigerants.
Refrigerators that were built in the late 1800s to 1929 used the first generation refrigerants like methyl chloride,
ammonia and sulphur dioxide. The common refrigerants for the first hundred years included whatever worked and
whatever was available. Approximately all the first generation refrigerants were flammable, toxic or both and highly
reactive.
Ammonia
It is denoted by R717 and is also a very old refrigerant used in vapour compression and ab- sorption refrigeration
systems. They have a lower molecular weight, wide range of working temperature because of its high critical point,
high latent heat of vapourization and easy leak detection. It is highly toxic, highly irritating and flammable.
Sulphur Dioxide
Sulphur dioxide is generally used in 1920s and 1930s and it has been replaced first by methyl chloride and later by
more favourable fluorocarbon refrigerants. It is highly toxic but non- explosive and non-flammable. It is non-
corrosive in pure state but when it combines with mois- ture it forms sulphurous acids and sulphuric acids which are
highly corrosive.
Methyl Chloride
Methyl chloride was first used in 1878. Methyl chloride is a colourless extremely flammable gas with a mildly sweet
odour. Methyl chloride is corrosive to aluminium, zinc, magnesium.
Second Generation Refrigerants
The second generation refrigerants were found by a shift to chlorofluoro chemicals for safety and durability. They
disregarded compounds that are unstable, toxic, yielding insufficient volatility and inert gases based on their low
boiling point. In 1928, Midgley and his colleagues done crit- ical observations of flammability and toxicity of
compounds containing elements like carbon, nitrogen, oxygen, sulphur, hydrogen, fluorine, chlorine and bromine.
Their first publication was on fluorochloro refrigerants and it showed how the variation of chlorination and
fluorination of hydrocarbons influences boiling point, flammability and toxicity of the refrigerants. Thus CFC
refrigerants used as the second generation of refrigerants. CFC is a non-toxic, non-flammable gas with high mass. It
is a good refrigerant because it can be compressed easily to liquid and rejects lots of heat when it evaporates.
R-11
R 11 is non-flammable and non-explosive. So it can be considered as safe. It is used in the applications like air
conditioning of small buildings, factories, departmental stores, theatres etc.
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R-12
R12 is a highly versatile refrigerant that is used for wide range of refrigeration and air con- ditioning applications. R12
is non-toxic, non-flammable, and non-explosive. It is suitable for wide range of operating conditions.
Third Generation Refrigerants
The third generation refrigerants based on hydro chlorofluorocarbon (HCFC) and hydro fluoro- carbon (HFC) have
been developed to replace second generation refrigerants. The advantages of it is same as CFC without damaging the
EarthâĂŹs ozone layer, but they were developed before the environmental impact of fluorine was fully understood.
This effect has been termed as Global Warming Potential (GWP).
Next Generation Refrigerants
HCFC/HFC such as R22 and R134a are on the way to phase-out due to environmental concern. Under medium
and long term refrigerants like HFC chlorine free and their blend, low GWP refrigerant (R1234yf,1234ze) and
halogen free refrigerant (natural refrigerant) are looking as the feasible options for future refrigerant at current
position.
Figure 1.1: Generation of Refrigerant
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Table 1.1: Environment properties of Refrigerants
Type ASHRAE
number
Chemical name Chemical formula ODP GWP
CFCs R11 Trichlorofluoro methane CCl2F 1 4750
CFCs R12 Dichlorodifluoro methane CCl2F2 1 10900
HCFCs R22 Chlorodifluoro methane CHClF2 0.05 1810
HCFCs R141b 1,1-Dichloro-
1-1fluoroethane
C2H3FCl2 0.12 725
HFCs R407c R32/125/143a 23±2%CH2F2
25±2%C2HF5
52±2%C2H2F4
0 1774
HFOs R1234yf 2,3,3,3-Tetrafluoro propane C3H2F4 0 4
HC R290 Propane C3H8 0 3.3
HC R600a Isobutane C4H10 0 3
Table 1.2: Thermodynamic properties of the refrigerants
ASHRAE
number
Atmospheric life
(year)
Molecular mass Critical
pressure
(Kg/mol)
Normal boiling
point (bar)
Critical temperature
(℃)
R11 45 137.4 4408 23.77 197.96
R12 100 120.9 4136 -29.8 111.97
R22 12 86.5 4990 -40.7 96.14
R141b 9.3 116.9 4250 32 204.2
R407c 15.657 86.2 4634 -43.8 86.05
R1234yf 0.0301 114 —– -29.4 ——
R290 12 44.1 4248 -42.1 96.7
R600a 12 58.1 3640 -11.7 134.7
1.3 NANO REFRIGERANT:
A nano-refrigerant is a special class of refrigerant in which the nanoparticles are suspended and immersed in the base
refrigerant. The concept of immersing the solid particles into a fluid was first said by Maxwell (1873). He immersed
millimetre and micrometre sized particles into the base fluid in order to increase the thermos physical properties of
the fluid. With the advent of nanotechnology, Choi (1995) gave a new concept of immersing nanoparticles in the
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base fluid and called it as nanofluids. The purpose of the development of nanofluids is to increase the heat transfer
performance of various heat transfer fluids and lately, this concept has been extended to the refrigerants as well.
The key points of nano refrigerants are:-
1) The use of nano refrigerants will increase in smaller and lighter refrigeration systems.
2) The refrigeration systems using of nanorefrigerants will consume less compressor power it means they will be
more energy efficient.
There were three main advantages by using nanoparticle in the refrigerator. Firstly, nanoparticles can increase the
solubility between the lubricant and the refrigerant. For example, TiO2 nanoparticles could be used as additives to
increase the solubility between mineral oil and hydrofluorocarbon (HFC) refrigerant. The refrigeration systems
using the mixture of R134a and mineral oil added with nanoparticles TiO2 gives better performance by returning
more lubricant oil back to the compressor and have the similar performance compared to the systems using polyol-ester
(POE) and R134a. Secondly, the thermal conductivity and heat transfer characteristics of the refrigerants should be
increased which have been sanctioned by a lot of investigations. Boiling heat transfer characteristics of Al2O3
nanoparticles mixed in R22 refrigerant increase the heat transfer characteristic of the refrigerant and the bubble size
decrease and move rapidly near the heat transfer surface. Finally, nanoparticles immersed in lubricant should decrease
the friction coefficient and wear rate. The friction coefficient of the mineral oil immersed with 0.1 vol.% fullerene
nanoparticles decrease compare to raw lubricant which increase the efficiency of the compressor.
The nanoparticles can be appended into the refrigeration system in two different ways. In one way the nanoparticles
can be appended to the refrigeration system by first adding them into the lubricant to make a nanoparticles and
lubricant mixture. Then the mixtures put into the compressor as the lubricant. In the other way nanoparticles and
traditional refrigerant can be dispersed directly to make nano-refrigerant. Both ways improve performance of the
refrigerator with the appended nanoparticles. Isobutane (R600a) is more widely used in domestic refrigerator be-
cause of its better energy performances.
In fact, many researchers have studied other thermophysical properties as well such as viscosity, specific heat and
surface tension. The study of boiling heat transfer involves complexities and these complexities increases due to the
addition of nanoparticles in the refrigerant. In past, various results have been done in which the boiling heat transfer
performance for nanorefrigerants was found to be higher in comparison to that of the base refrigerant without
nanoparticles. Major work has been done using refrigerant nanolubricant pair. The friction coefficient decreases upto
90 % when raw oil is replaced by nano-oil and it has better lubricating characteristics in comparison to the raw oil.
Fullerene C60 nano-oil increases the COPs of the compressors and decreases in the compressor shell temperatures
which is desirable since a lower compressor shell temperature improve lubricant stability.
Nanofluids as an advanced type of working fluid have attracted due to their capabilities in heat transfer enhancement.
Nanofluids are mixtures of ultrafine particles and common working fluids such as water and oil. When a refrigerant is
used as the base fluid the suspension is called a nanorefrigerant. By adding the flow boiling of CuO nanoparticles in a
mixture of R134a/polyol-easter oil (POE) with 0.5 % weight concentration has no effect on heat transfer
enhancement. The R134a/Al2O3 nanorefrigerant with a refrigerator save the energy and increase COP. The
concentration of the flow boiling characteristics of the R113/CuO nanorefrigerant inside a horizontal tube at
different nanoparticle concentrations increase the heat transfer.
R134a/SiO2 nanorefrigerant having different volume concentrations decrease in convective boiling heat transfer
coefficient compared to pure R134a. The R134a/POE mixtures having CuO nanoparticles with different volume
fractions increases the heat transfer with increasing volume fractions. Polyolester lubricant of different mass
fraction and volume fraction of Al2O3 nanoparticles increases the heat transfer using Al2O3 nanoparticles instead of
an R134a/polyolester mixture. The usage of nanorefrigerant in the refrigerant system increases COP and minimizes
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the length of the capillary tube and it is also cost effective. The potential of R12/TiO2/mineral oil nanorefrigerant
enhances the COP of a vapor compression refrigeration system. The usage of nanorefrigerant in the vapor-
compression refrigeration system decreases compressor work while increases the COP.
1.4 PROPERTIES OF REFRIGERANTS:
To enable use of smaller compressors and other equipment the refrigerant should have smaller vapor density. To
ensure maximum heat absorption during refrigeration, a refrigerant should have high enthalpy of vaporization.
Thermal conductivity of the refrigerant should be high for rapidly heat transfer during condensation and evaporation.
In order to have large range of isothermal energy transfer, the refrigerant should have critical temperature above the
condensing temperature. To have minimum change in entropy during the throttling process, the specific heat should
be minimum. The refrigerant used in air conditioning, food preservation etc. should not be toxic in nature as they will
come into contact with human beings.
1.4.1 Physical properties of nanorefrigerants
The thermo physical properties and flow properties are important to gauge the effectiveness of a nanofluid or a
nanorefrigerant. The thermal conductivity, viscosity, specific heat, latent heat, density and surface tension are some
of the most important thermo physical properties of a fluid. Most of the research in past have been done on the thermal
conductivity of nanofluids. But lately, the studies based on viscosity have also done. It is important to extend this
research to other thermophysical properties since it will give a good idea of the heat transfer performance of
nanorefrigerants.
1.4.1.1 Thermal conductivity of nanorefrigerants
The thermal conductivity is one of the most important thermophysical property of a nanorefrigerant because the
boiling and convective heat transfer coefficients are a function of the thermal conductivity of the fluid. The thermal
conductivity of nanofluids depends on the thermal conductivity values of nanoparticles and base fluid, nanoparticle
volume fraction, nanoparticle size, temperature, base fluid material.
1.4.1.2 Viscosity of nanorefrigerants
The addition of nanoparticles to the refrigerant increase in viscosity of the resultant nanorefrigerant. The increment in
the thermal conductivity and heat transfer of nanorefrigerant is much higher than the increase in viscosity. The
effective viscosity of a nanorefrigerant increases with an increase in particle volume fraction but decreases with an
increase in temperature.
1.4.1.3 Pressure Drop in nanorefrigerants
The pressure drop in nanorefrigerants increases because of the addition of nanoparticles. The increase in pressure
drop is due to the increase in the effective viscosity of the nanorefrigerant. The specific pressure drop increases with
the increase in the particle volume fraction. The pressure drop of the nanorefrigerant increases with increase in particle
mass fraction.
1.4.1.4 Other thermophysical properties of nanorefrigerants
There are many other properties like specific heat, density, latent heat and surface tension. The specific heat capacity
of nanofluids and nanorefrigerants is thermophysical property which is important because of its uses in energy and
exergy performance analysis of the system. The specific heat of nanofluids rely on the type of nanoparticles, volume
concentration of nanoparticles, temperature and the type of base fluid. Therefore, the specific heat of nanofluids can
either increase or decrease by the addition of nanoparticles.
1.5 ENVIRONMENTAL IMPACT
The halogenated refrigerants have a long history of emission from refrigeration, air conditioning and other uses. The
halogenated refrigerants are a family of chemical compounds come from the hydrocarbons (methane and ethane) by
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replacement of chlorine and fluorine atoms for hydrogen. The emission of chlorine and fluorine atoms present in
halogenated refrigerants is liable for the most of environmental effects with serious implications for the future
development of the refrigeration based industries.
1.5.1 Ozone Depletion Potential
The first major environmental effect that affect the refrigeration based industries is ODP due to man made chemicals
into the atmosphere. Chlorine based refrigerants are enough to reach the stratosphere where the chlorine atoms act as
a catalyst to diminish the stratospheric ozone layer (which protects the earth surface from direct UV rays). About 90%
of the ozone exists in the stratosphere between 10 and 50 km above the earth surface.
1.5.2 Global Warming Potential
The second major environmental impact is GWP which is because of the absorption of infrared emissions from the
earth causing an increase in global earth surface temperature. While so- lar radiation at 5800 K and 1360 W/m2
reaches the earth, more than 30% is reflected back into space and most of the remaining radiation passes through the
atmosphere and arrives the surface. This solar radiation heats up the earth radiating energy with a spectral peak in the
infrared wave- length range. This infrared radiation cannot pass through the atmosphere because of absorption by GHG
including the halogenated refrigerants. As a result, the temperature of atmosphere increases, which is called as the
global warming. During the formulation of Kyoto protocol, countries around the world have voluntarily committed
to decrease the GHG emissions. HFC refrigerants have large values of atmospheric lifetime and GWP compared
to chlorine based refrigerants.
1.6 CHARACTERISTICS OF REFRIGERANTS
Refrigerants are substances that change from the liquid to the gaseous state to reduce the temperature of a devices. This
chemical process is used over and over again in refrigerators, air conditioners and other machines to maintain the items
inside cool. Different refrigerants are used depending on the location, the type of machine and the application of items
that are refrigerated.
1.6.1 Boiling Point
A refrigerant should have a boiling point in a particular range that fits the machine in which it is used. A refrigerant
with a lower boiling point tends to have a better ability to cool. Refrigerants with higher boiling points is more efficient and
do work good in a smaller machine. Most refrigerants have a boiling point between - 27.4 and - 49 degrees Fahrenheit,
though many have a boiling point as high as 48.2 degrees Fahrenheit.
1.6.2 Toxicity
A refrigerant is classified as a Class A refrigerant if there is no toxicity identified in concentrations less than 400 parts per
million. If there is toxicity identified in this small amount, the substance is a Class B refrigerant. Class 1 refrigerants
are completely nonflammable, Class 2 types are moderately flammable and Class 3 substances are highly flammable.
A good refriger- ant has the proper combination of safety and functionality.
1.6.3 Stability
Refrigerants must be stable substances that do not decompose under the pressures and temperatures of the refrigerator
system. A less stable substance might dissolve the plastics used in the motor and seals of the system. The refrigerant
should also not react chemically with the lubricants and other substances used in the refrigerator. Originally,
chlorofluorocarbons (CFCs) were used as refrigerants until it was decided that they were unstable when they came
into con- tact with the ozone particles in the upper atmosphere.
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1.6.4 Odor
A good refrigerant has no odor when it is in a low concentration so that the devices does not have a chemical smell at all
times. This refrigerant also has a different odor at higher concentrations so that when a device has chemical leaks,
they can be instantly identified.
1.6.5 Pressure
Generally all the new refrigerants operate at a higher pressure than the refrigerants they replace. In many cases the
pressure can be substantially higher, which means that the refrigerant can be used only in equipment designed to use
it.
1.6.6 Material compatibility
The primary safety concern is with wearing of materials, such as motor insulation, which can lead to electrical
shorts, and seals, which can result in leaks.
1.6.7 Flammability
Leakage of a flammable refrigerant could result in explosions. Some new refrigerants are zeotropes which can change
composition under many leakage scenarios.
II. LITERATURE REVIEW
1. In June 2017, Ms. Vidya N. Lakhorkar, Mr. Sulas G. Borkar [1] worked on Performance Evaluation of Domestic
Refrigerator Using Eco-Friendly Refrigerant: A Review. This paper is a review of one of the ecofriendly
refrigerant used in the domestic refrigerator. The performance of the refrigerator was studied using R134a
refrigerant and mixture of propane R290 and isobutene R600a (50/50). Then this increases performance because
of mixture of propane R290 and isobutene R600a (50/50) was compared with performance of refrigerator
working with R134a and percentage of increment was calculated on the basis of COP, refrigerating effect, power
required to run the compressor, etc. It can be concluded that hydrocarbon refrigerant gives good results as
compared to the existing refrigerant R134a. The hydrocarbon refrigerant have low value of GWP (Global
warming potential) as compared to the R134a. So it does not harm the ozone layer and hydrocarbon can be
consider as ecofriendly refrigerant. It reduces energy consumption by 11.1+% compare to R134a. It increases
COP up to 3.25-3.6%. It also reduces Pull down time 11.6 compare to R134a%.
2. In 2017, Tejaswi Saran Pilla, Pranay Kumar Goud Sunkari et al.[2] worked on Experimental evaluation
Mechanical performance of the compressor with mixed refrigerants R-290 and R-600a. Hence, in the present
work, two refrigerants are chosen (R-290 and R-600a) to evaluate the mechanical performance of compressor of
domestic refrigerators. The present work aims at investigation of mechanical performance of compressor with
mixed refrigerants (R-290 and R-600a). The boiling point of the each of the refrigerant is different and hence the
specific volume occupied by each is different. This in turn affects the work input required. Hence, the present work
is aimed at evaluating the compressor performance with mixed refrigerants. The present work concludes that 60%
of R290 and 40% of R600a composition has better performance in all parameters such as mass flow rate, power
consumption, experimental COP, Carnot COP and discharge temperature. Small compressors can be use instead
of usual one to obtain equal performances by using 10% of R290 and 90% of R600a composition. Because it also
has better performance parameters along with 60% of R290 and 40% of R600a composition and also it consumes
low power hence energy will save. It has highest Carnot COP. It means almost equals to ideal cycle for some
extent.
3. In October 2015, Teboho Ramathe, Zhongjie Huan and Aggrey Mwesigye [3] worked on Experimental Study on
the Thermal Performance of R600a, R290 and R600a/R290 Mixtures in a Retrofit R134a Refrigeration System.
In this paper, the experimental thermodynamic performance evaluation of the hydrocarbons R600a, R290 and
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their mixtures used in a vapour compression refrigeration system that utilizes R134a as a working fluid was
carried out. Firstly, a theoretical analysis was developed to evaluate the feasibility of the retrofit by employing
the vapour compression refrigeration cycle. The evaporation temperatures were ranging from -25 ℃ to 3 ℃and
the condensation temperatures ranging from 25 ℃ to 65 ℃with superheating and subcooling degrees constant at 5
℃. The thermodynamic and thermophysical properties were obtained using REFPROP soft- ware. Lastly, based
on the results obtained from the theoretical analysis, the experimental comparison of the refrigeration cycle
performance was conducted using a refrigeration system designed for R l34a. The results show that both pure
R600a and R290 cannot be recommended as drop-in substitutes for R134a due to their significant differences in
thermophysical properties. A mixture of R600alR290 50%/50% composition was found to be the most
appropriate alternative refrigerant for the Rl34a system retrofit with a comparative thermal performance.
Hydrocarbons perform favourably in comparison with halo- carbon refrigerants.
4. In June 2015, DEEPAK PALIWAL, S.P.S.RAJPUT [4] worked on EXPERIMENTAL ANALYSIS OF
HYDROCARBON MIXTURES AS THE NEW REFRIGERANT IN DOMESTIC REFRIGERATION
SYSTEM. As and when an existing system of R134a has to be recharged it is suggested to retrofit the system
with new/natural and alternative refrigerants. This investigation focuses on mixture ratio of pure hydrocarbon
R290 and R600a uses in 200 liter domestic refrigeration system by certain changes in con- denser and capillary.
The outcome of this work is 80g mixture of R600a/R290 (60/40 by wt%) give better performance than 80g mixture
of R600a/R290 (70/30 by wt%). COP of R600a/R290 (60/40 by wt%) mixture is higher in the range 22%-26.3%
than mixture R600a/R290 (70/30 by wt%) for capillary of 3.5m length and 0.036 inches diameter. During the
experiments it is found that 0.036 inches dia. capillary is more suitable as expansion device than 0.031 inches dia.
capillary at all length . It is also find out that by increasing the length of capillary in the system hydrocarbon
mixture give better results. Refrigerating effect of R600a/R290 (60/40 by wt%) mixture was higher in the range
26.8%-37% in lower evaporating temp. and higher 22.8% -48.8% in higher evaporating temp. than R600a/R290
(70/30 by wt %) for 3.5m length capillary 0.031 inches dia. and 0.036 inches diameter. Energy Consumption of
R600a/R290 (60/40 by wt %) mixture was higher in the range 19.6% - 30.7% than R600a/R290 (70/30 by wt %)
mixture for capillary 3.5 M length and .036 inches diameter.
5. In May 2014, Mao-Gang He, Xin-Zhou Song et al. [5] worked on Application of Natural Refrigerant Propane and
Propane/Isobutane in Large Capacity Chest Freezer. In this paper, some researches have been conducted on
natural refrigerant propane (R290) and its mixtures substituting for 1,1,1,2-Tetrafluoroethane (R134a) used in a
large-capacity chest freezer (BD-625). To examine the application possibilities of R290 and its mixtures to the
large-capacity freezer, their thermodynamic and refrigeration performances from both theoretical analysis and
experimental test have been done. The theoretical analysis shows that R290 is higher by 87.7% and 54.2% than
R134a in mass and volumetric refrigerating capacity respectively. Propane/Isobutene (R290/R600a, 90/10 wt%)
is higher by 48.3% and 2.4% than R134a in volumetric refrigerating capacity and COP respectively. So R290
and its mixtures (R290/R600a) can meet the requirements of large-capacity refrigeration and energy
conservation as the alternatives of R134a. The experimental test shows that the power consumption of the
experimental freezer charged with R290 is lower by 26.7% than that of R134a. The ratio of R290/R600a is
93.75/6.25Wt% when it is used in the freezer and the corresponding power consumption is lower by 27.5% than
that of R134a. The charging amount of R290 is less than that of R134a, which is in line with the safety standards,
So R290 can be used in the large capacity chest freezer. The COP of R290 is lower by about 4.7% than that of
R600a from the theoretical calculation. The experimental test shows the power consumption of the ratio
R290/R600a is 1.71 kWh/24h, which is lower by 1.2% than that of R290 in the tested freezer.
6. In July 2013, Mehdi Rasti, SeyedFoad Aghamiri et al. [6] worked on Energy efficiency enhancement of a domestic
refrigerator using R436A and R600a as alternative refrigerants to R134a. This paper is devoted to feasibility study
of substitution of two hydrocarbon refrigerants instead of R134a in a domestic refrigerator. Experiments are
designed on a refrigerator manufactured for 105 g R134a charge. The effect of parameters including refrigerant
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type, refrigerant charge and compressor type are investigated. This research is conducted using R436A (mixture
of 46% iso-butane and 54% propane) and R600a (pure iso-butane) as hydrocarbon refrigerants, HFC type
compressor (designed for R134a) and HC type compressor (designed for R600a). It can be concluded that for HFC
type compressor, the optimum refrigerant charges are 60 g and 55 g for R436A and R600a. Moreover, for this type of
compressor, the energy consumption of R436A and R600a at the optimum charges is reduced about 14% and 7% in
comparison to R134a. On the other hand, when using HC type compressor, the optimum refrigerant charges for
R436A and R600a are both 50 g, and the energy consumption of R436A and R600a at the optimum charges are
reduced about 14.6% and 18.7%, respectively.
7. In September 2008, M. Mohanraj, S. Jayaraj et al. [7] worked on Experimental investigation of R290/R600a
mixture as an alternative to R134a in a domestic refrigerator. In the present work, an experimental investigation
has been made with hydrocarbon refrigerant mixture (composed of R290 and R600a in the ratio of 45.2:54.8 by
weight) as an alternative to R134a in a 200 l single evaporator domestic refrigerator. Continuous running tests
were performed under different ambient temperatures (24, 28, 32, 38 and 43 âŮęC), while cycling running
(ON/OFF) tests were carried out only at 32 C ambient temperature. It can be concluded that the hydrocarbon
mixture has lower values of energy consumption; pull down time and ON time ratio by about 11.1%, 11.6% and
13.2%, respectively, with 3.25 to 3.6% higher coefficient of performance (COP). The discharge temperature of
hydrocarbon mixture was found to be 8.5 to 13.4 K lower than that of R134a. Hence, the life of the compressor can
be improved. Temperature variation in the evaporator is found to be within 3 K. The miscibility of HCM with POE
was found to be good. 8. HCM also reduce the indirect global warming due to its higher energy efficiency. The
overall performance has proved that the above hydrocarbon refrigerant mixture could be the best long term
alternative to phase out R134a.
8. In January 2006, M. Fatouh, M. El Kafafy [8] worked on Assessment of propane or commercial butane mixtures as
possible alternatives to R134a in domestic refrigerators. The possibility of using hydrocarbon mixtures as
working fluids to replace R134a in domestic refrigerators has been evaluated through a simulation analysis in
the present work. The performance characteristics of domestic refrigerators were predicted over a wide range of
evaporation temperatures (-35℃to -10 ℃) and condensation temperatures (40℃to 60℃) for various working
fluids such as R134a, propane, commercial butane and propane/iso- butane/n-butane mixtures with various
propane mass fractions. The performance characteristics of the considered domestic refrigerator were
identified by the coefficient of performance (COP), volumetric cooling capacity, cooling capacity, condenser
capacity, input power to compressor, discharge temperature, pressure ratio and refrigerant mass flow rate. It can
be concluded that pure propane could not be used as a drop in replacement for R134a in domestic refrigerators
because of its high operating pressures and low COP. The coefficient of performance of the domestic refrigerator
using a ternary hydrocarbon mixture with propane mass fractions from 0.5 to 0.7 is higher than that of R134a.
Comparison among the considered working fluids confirmed that the average refrigerant mass flow rate of the
propane/commercial butane mixture is 50% lower than that of R134a. The pressure ratio of the hydrocarbon
mixture with 50%, 60% and 70% propane is lower than that of R134a by about 6.3%, 11.1% and 15.3%,
respectively. Finally, the reported results confirmed that the propane/iso-butane/n-butane mixture with 60%
propane is the best drop in replacement for R134a in domestic refrigerators under normal, subtropical and
tropical operating conditions.
9. In March 2004, Somchai Wongwises, Nares Chimres [9] worked on Experimental study of hydrocarbon mixtures
to replace HFC-134a in a domestic refrigerator. This work presents an experimental study on the application of
hydrocarbon mixtures to replace HFC- 134a in a domestic refrigerator. The hydrocarbons investigated are
propane (R290), butane (R600) and isobutane (R600a). A refrigerator designed to work with HFC-134a with a
gross capacity of 239 l is used in the experiment. The consumed energy, compressor power and refrigerant
temperature and pressure at the inlet and outlet of the compressor are recorded and analysed as well as the
distributions of temperature at various positions in the refrigerator. The refrigerant mixtures used are divided into
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three groups: the mixture of three hydrocarbons, the mixture of two hydrocarbons and the mixture of two hydro-
carbons and HFC-134a. The experiments are conducted with the refrigerants under the same no load condition
at a surrounding temperature of 25 ℃. It can be concluded that propane/butane 60%/40% is the most
appropriate alternative refrigerant to HFC-134a. The distributions of temperature in the frozen food storage
compartment and in the fresh food storage compartment in the refrigerator, energy consumed, compressor
power, refrigerant temperature and pressure at the inlet and outlet of the compressor were continuously recorded.
The best alternative mixture of HFC-134a in each group was selected and proposed based on the above
information.
10. In November 2001, Y.S. Lee, C.C. Su [10] worked on Experimental studies of isobutane (R600a) as the refrigerant in
domestic refrigeration system. This paper presents an experimental study on the performance of a domestic vapor-
compression refrigeration system with isobutane (R600a) as the refrigerant. The input power of the compressor
varied be- tween 230 and 300 W, while the amount of the charged refrigerant was about 150 g. The expansion
and heat transfer components of the system were capillary tubes and plate heat exchangers, respectively. The
refrigeration temperatures were set at about 4 and -10℃ to simulate the situations of the cold storage and the
freezing applications. Both normal and extreme conditions were investigated in this work. The COPs of the
domestic vapor- compression refrigeration system under study are between 1.2 and 4.5 in the cold storage
application and between 0.8 and 3.5 in the freezing application. For the inlet temperature of the brine of 4 and -
10℃, the COPs are greater than 3.5 and 2.5 respectively if proper sizes of capillary tubes are chosen. The system
with two capillary tubes in parallel per- forms better in the cold storage and air conditioning applications, while that
with a single tube is suitable in the freezing application.
11. In March 2017, T. Vasudevan, N. Prakash et al. [11] worked on Experimental Investigation on Performance of
Refrigerant System using Titanium Dioxide. This project shows an experimental investigation of constant mass
of refrigerant gases R-134a and R-600a (70g) enhanced with varied TiO2 nanoparticles. Nanoparticles are
converted into nanofluids using distilled water as a base fluid. By adding nanofluid with refrigerants it improves
thermophysical properties and heat transfer characteristics of refrigerant and the con- centration used for
preparing nanofluids are (2 g/L, 2.5 g/L). Then Performance test are maintained at steady state includes power
consumption, compressor power input, cooling capacity and coefficient of performance. Analysis was based on
temperature and pressure readings obtained from appropriate gauges and power consumption is recorded by
energy meter which are attached to the kid. It has been noticed that the mechanical properties of finding C.O.P
in refrigeration system is achieved using two refrigerants R-134a and R- 600a with nano fluid. The comparison
itself shows that common water has less efficiency (for R- 134a it is 0.4888 and for R-600a it is 0.402) and it
consume more power (for R-134a it is 70 mins and for R-600a it is 91 mins) but while using nanofluid the efficiency
is increased (R-134a it is 0.5546 and for R-600a it is 0.584) and it consume less power R-134a it is 62 mins and for
R-600a it is 59.25 mins).
12. In April 2017, V.K. Dongare, Jyoti Kadam et al. [12] worked on ENHANCEMENT OF VAPOUR
COMPRESSION REFRIGERATION SYSTEM USING NANOFLUIDS. In past five years, nano-refrigerant
has become the input for large number of experimental and vapours compression systems because of shortage
of energy and environmental considerations. The conventional refrigerants have major role in global warming
and depletion of the ozone layer. By adding nanoparticles with refrigerants the coefficient of performance, heat
transfer rate and thermal conductivity will increased. Because of that power consumption rate will be reduced.
This paper compares coefficient of performance of refrigeration system with nanorefrigerants and without
nanorefrigerants such as R134a, Mo49 and blend of R290 and R600a. The COP of refrigeration system with
nanoparticles is more than COP of refrigeration system without nanoparticles. The COP of refrigeration system
with nanoparticles is increased by 4-5%. COP of CuO nanoparticles is more than Cop of Al2O3 nanoparticles
with refrigerants. COP also differs with types of refrigerants R134a, R290 & R600a. The heat transfer rate and
thermal conductivity of system will increased by using nanorefrigerants.
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13. In December 2016, M.S.Bandgar, R. N. Kare et al. [13] worked on VCR SYSTEM USING R-600a/ POE
OIL/MINERAL OIL/NANO-SiO2 AS WORKING FLUID: AN EXPER- IMENTAL INVESTIGATION. The
aim of this work is to evaluate the performance of Vapour Compression Refrigeration System using SiO2 nano
particles mixed with Poly- olester (POE) oil / Mineral oil (MO) as Nano lubricant and R-600a as a refrigerant. This
paper investigates which type of lubricant oil works better with SiO2 nanoparticles in the field of refrigeration.
POE Oil / Mineral Oil are mixed with Silica Nano particles by ultrasonic sonication and stirring process to prepare
the Nano lubricants. These Nano lubricants were used in the compressor of refrigeration system instead of
RL68H oil/SUNISO 3GS oil. An investigation was done on the compatibility of POE/Mineral oil mixed with
Silica (SiO2) Nano powder (at a concentration of 0.5%, 1% and 1.5% by mass fraction) as Nano lubricant. The
replacement of Polyol-ester lubricant by the mineral lubricant mixed with SiO2 reduces power consumption. It
gives better results at mass fraction of 0.5% for all combinations of Nano-oils. It was found that the time
required reducing the temper- ature of water though 10 ℃is less and the power consumption reduces by
12.02% when POE oil is replaced by a mixture of (MO 0.5% Silica). It has been observed that C.O.P. is increased
by 11.66% when POE is replaced by a Nano lubricant (mineral oil 0.5% of SiO2). The freezing capacity is better at
0.5% of SiO2 and it is highest for system using POE oil mixed with 0.5% SiO2 as lubricant. Thus the use of above
Nano lubricants in refrigeration system is favorable.
14. In 2015, Omer A. Alawi, Nor Azwadi Che Sidik et al. [14] worked on Nanorefrigerant effects in heat transfer
performance and energy consumption reduction: A review. The heat transfer performance and energy
consumption of various thermal devices may be augmented by active and passive techniques. One of the passive
techniques is the addition of nanoparticles to the common heat transfer fluids so that the thermal transport
properties of the prepared suspension (called nanofluid) will be enhanced as compared to the base fluid.
Nanorefrigerants are a special type of nanofluids which are mixtures of nanoparticles and refrigerants and have a
broad range of applications in diverse fields for instance refrigeration systems, air conditioning systems, and heat
exchangers. This review is performed in order to clarify the effect of nanorefrigerant properties on heat transfer
and pressure drop compared to pure refrigerant. Moreover, studies related to the thermophysical properties, and
applications of nanorefrigerants to some specific areas such as domestic refrigerators, heat pipes and air
conditioners are also summarized. Energy consumption can be reduced by using nanorefrigerants. It is reported
that the freezing speed and COP in cooling de- vices are increased by adding nanoparticles to the refrigerants.
The heat transfer rate and pressure drop increase with increasing nanoparticle proportion. The heat transfer rate
in- creases with a decreasing nanoparticle dimension while the pressure drop decreases with a decreasing
nanoparticle dimension. The lubricant type has the potential to enhance the heat transfer rate.
15. In April 2015, A.Senthilkumar, R.Praveen [15] worked on PERFORMANCE ANALYSIS OF A DOMESTIC
REFRIGERATOR USING CUO âĂŞR600A NANO REFRIGERANT AS WORKING FLUID. The
application of nano refrigerants in refrigeration system is considered to be a potential way to improve the
energy efficiency and to make the use of environment-friendly refrigerants. In this paper it is reported a method
that uses natural gas to enhance the energy efficiency of refrigeration retorting method employing CuO - R600a
as alternate refrigerants. Thus reliability and performance of nano refrigerant in the working fluid have been
investigated experimentally. A new nano refrigerant is employed in the domestic refrigerator. The performances
of the nano refrigerant, such as the cooling capacity, energy efficiency ratio were determined. Combined with
refrigerator using pure R600a as working fluids. 0.1 & 0.5g/L concentrations of CuO - R600a can save 11.83% and
17.88% energy consumption respectively and the freezing velocity of CuO - R600a was more quickly than the
pure R600a system. So the above works have concluded that CuO - R600a can improve the performance of the
domestic refrigerator.
16. In April 2014, S. A. Fadhilah, R. S. Marhamah et al. [16] worked on Copper Oxide Nanoparticles for
Advanced Refrigerant Thermophysical Properties: Mathematical Modeling. Nanorefrigerant which is one kind
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of nanofluids has been introduced as a superior properties refrigerant that increased the heat transfer rate in the
refrigeration system. Many types of materials could be used as the nanoparticles to be suspended into the
conventional refrigerants. In this study, the effect of the suspended copper oxide (CuO) nanoparticles into the
1,1,1,2-tetrafluoroethane, R-134a is investigated by using mathematical modeling. The investigation includes
the thermal conductivity, dynamic viscosity, and heat transfer rate of the nanorefrigerant in a tube of evaporator.
The thermal conductivity of refrigerant-134a is 0.0139 W /mK at temperature of 26℃. Additional 1% volume
fraction has increased the thermal conductivity in range of 3.53âĂŞ8.38% up to 5% volume fraction. The
viscosity of nanorefrigerant is also showing great percentage of enhancement which is about 44.45% once
compared to the conventional refrigerant with only 1% of nanoparticles volume fraction. The heat transfer rate
of a tube of nanorefrigerant with 5% vol. fraction is about 1% enhancement.
17. In April 2013, R. Reji Kumar ,K. Sridhar et al.[17] worked on Heat transfer enhancement in domestic
refrigerator using R600a/mineral oil/nano-Al2O3 as working fluid. Aluminium oxide nanofluid is used for
enhancing the heat transfer capacity of the refrigerant in the refrigeration System. In this experiment heat transfer
enhancement was investigated numerically on the surface of a refrigerator by using Al2O3 nano-refrigerants,
where nanofluids could be a significant factor in maintaining the surface temperature within a required range.
The addition of nanoparticles to the refrigerant results in improvements in the thermophysical properties and heat
transfer characteristics of the refrigerant, thereby improving the performance of the refrigeration system. Stable
nanolubricant has been prepared for the study. The R600a refrigerant and mineral oil mixture with nanoparticles
worked normally. Freezing capacity of the refrigeration system is higher with mineral oil + alumina
nanoparticles oil mixture compared the system with POE oil. The power consumption of the compressor reduces
by 11.5% when the nanolubricant is used instead of conventional POE oil. The coefficient of performance of
the refrigeration system also increases by 19.6 % when the conventional POE oil is replaced with nanorefrigerant.
18. In August 2011, Shengshan Bi, Kai Guo et al. [18] worked on Energy Conversion and Management. In this work,
an experimental work was investigated on the nano-refrigerant. TiO2-R600a nano-refrigerants were used in a
domestic refrigerator without any system re- construction. The refrigerator performance was then investigated
using energy consumption test and freeze capacity test. It can be concluded that TiO2-R600a nano-refrigerants
work normally and safely in the refrigerator. Compared with refrigerator using pure R600a as working fluids, 0.1
and 0.5 g/L concentrations of TiO2-R600a can save 5.94% and 9.60% energy consumption respectively and the
freezing velocity of nanorefrigerant system was more quickly than the pure R600a system. above works have
demonstrated that nanoparticles can improve the performance of the domestic refrigerator.
III CONCLUSION
The present study gives a comprehensive review of the various studies related to use of nanorefrigerants in
refrigeration systems. Based on the results of different studies relevant to nanorefrigerants the following points
can be drawn:
The use of nanorefrigerants as refrigerants are not just good for the environment but also it can reduce the
energy consumption and offer proper refrigerants for the performance of domestic refrigerator.
The convenient thermodynamic and thermo-physical properties of nanorefrigerants assure that the
performance of the domestic refrigerator is comparable to the traditional refrigerants.
Nanorefrigerants offer interesting refrigerant as alternatives for conventional ones from the standpoint of
energy efficiency, cooling time and compressor's discharge-temperatures.
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IV ACKNOWLEDGEMENTS
I would like to thank Ass. Professor Hussain Pipwala for his invaluable guidance and patience during this work. He
took great efforts in providing good guidance and was enthusiastic about my work. He gave so many advices on this
work, expressing the idea. It was a pleasure working with him and more importantly, learning from him. I owe him
a great debt of gratitude. Many sincere thanks to Head of Department Dr. S.J.Thanki and Principal Dr. R.G.Kapadia
for the support in this work. I express my deep and sincere sense of gratitude to all the faculty members and institute
staff of Mechanical Engineering at Shri S’ad Vidya Mandal Institute of Technology.
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