Is Chapter 11 Too Favorable to Debtors? Evidence from Abroad
Contaminated Groundwater Remediation– Usage of Water Harvesting under Favorable Circumstances
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Transcript of Contaminated Groundwater Remediation– Usage of Water Harvesting under Favorable Circumstances
Open Access e-Journal
Earth Science India- www.earthscienceindia.info
Popular Issue, V (II), April, 2012, p. 1-12
1
Contaminated Groundwater RemediationContaminated Groundwater RemediationContaminated Groundwater RemediationContaminated Groundwater Remediation–––– Usage of Water Usage of Water Usage of Water Usage of Water
Harvesting under Favorable CircumstancesHarvesting under Favorable CircumstancesHarvesting under Favorable CircumstancesHarvesting under Favorable Circumstances
Rolland Andrade, R. Rangarajan and D.N.V Lakshmi Devi
While the problem is enormous in the industrialized countries for which
the statistics are most readily available, in proportion to population, the
problem is undoubtedly of similar magnitude or more in most developing
countries of the world like India…………… The concept of artificial
recharge structure can be extended in pollution mitigation studies under
favorable site criterions, as it requires no addition of artificial chemicals
or processing plant.
In many countries of the world including India, groundwater constitutes the main source
of drinking water. But in recent decades, the groundwater quality has very much deteriorated
due to rapid industrialization and human mismanagement. Contaminants must often be removed
from groundwater before it reaches wells used by agriculture and municipal water supplies. The
removal of containment of pollutants is called remediation. Remediation is required when
concentrations of contaminants exceed or are expected to exceed predetermined levels for the
type of resource that is impacted. For the restoration of the contaminated aquifers, remediation
efforts are used at the contaminated source and plume to eliminate and extract the contaminants.
The remediation of contaminated aquifers is very complex, as the process of movement of
contaminants through the porous media is quite complex. The groundwater pollution
remediation can be carried out either by onsite techniques or in-situ methodologies. Even
though, in the recent times, many in-situ remediation methods have been developed, most of the
remediation works are still done on-site by pump and treat method. According to EPA
(Environmental Protection Agency) there are certain regulations published under Resource
Conservation and Recovery Act (RCRA), in which the already existing tanks or sites selected
for dumping mill tailings are to be cleaned to restore and protect groundwater resource.
Mining operation generates a large quantum of tailings otherwise termed as slimes or
leach residue, basically a mixture of fine disintegrated mineral particles and fluid, which needs
to be disposed safely without causing any environmental hazard like leaching and erosion by
wind or water. Tailings facilities consist of tailings ponds or lagoons, tailings dams and tailings
transport systems (generally pipelines). Usually a very large area is required to contain the
tailings which is man-made, and is the most critical elements of these facilities. The surface
disposal site is to be characterized for its sub-surface nature in order to understand its role in
environmental impact due to the loading of tailings. There is always possibility of contamination
of streams and groundwater system adjacent to the slimes dams which indirectly poses a
particular risk for the health of people in informal settlements where polluted stream water is
often consumed without appropriate treatment.
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Popular Issue, V (II), April, 2012, p. 1-12
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Fig.1. Schematic diagram showing geological cross section, geophysical image and well
monitoring through multi-parameter automatic logger.
In addition to this, long-term effects on cattle and crop farming and established drinking
water supply schemes are also of concern as shown by a number of recently launched projects
(Hearne and Bush, 1996; IWQS, 1999; Wade et al., 2000). Water being a universal solvent has
the ability to dilute certain salts and solids. In this paper the applicability of suitable surface
water harvesting and artificial recharge strategy development at feasible site conditions is
discussed briefly, for groundwater pollution remediation and dilution of contaminant plume due
to recharging water front is conceptually shown as models.
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Types and source of contaminants
The first step in groundwater contamination risk assessment is to identify potential
contaminant sources. Groundwater contamination occurs when man-made products such as
gasoline, oil, road salts and chemicals get into the groundwater and cause it to become unsafe
and unfit for human use. Some of the major sources of these products, called contaminants, are
storage tanks, septic systems, hazardous waste sites, landfills, and the widespread use of road
salts, fertilizers, pesticides and other chemicals. Generally contaminant source identification and
characterization can be more difficult than for other environmental pathways due to several
factors. Basically they can be categorized into three factors as mentioned below:
� First, the presences of groundwater contamination sources are generally hidden from
sight. Even when their existence is known, the characteristics of the sources are difficult
to measure.
� Second, sources that are only present in very small quantities may still pose a potentially
great health risk, depending on the toxicity of the substances.
� Third, groundwater contamination sources are often very long-lived. Disposal of
hazardous material in the ground may pose a threat to groundwater for hundreds or even
thousands of years.
Present source of groundwater pollution / contamination might be the consequence of
activities carried out years ago. Analogously, current waste disposal activities may affect
groundwater quality, and possibly human health, far into the future. This is a natural
consequence of the fact that aquifers are open systems with exchange of water, substances and
energy across the system boundaries. The main inputs of substances into the groundwater occur
from the land surface through the soil zone by infiltration. A contaminant plume due to an
industrial source can spread with time (often many years) with the natural groundwater flow
over large distances of many kilometers and thus poses a long-term danger to water supply
system based on the same aquifer. The groundwater contamination is very high in most of the
industrialized countries.
While the problem is enormous in the industrialized countries for which the statistics are
most readily available, in proportion to population, the problem is undoubtedly of similar
magnitude or more in most developing countries of the world like India. In India, the percentage
of sewered population is nearly negligible in most of the rural areas and is moderate in most of
the medium and small towns.
As a result, the contamination of groundwater by pollution from unsewered areas is one
of the most important environmental problems facing the country. The major groundwater
contamination source compiled by the U.S. Congress office of technology assessment (1984) is
tabulated in Table.1 (Gorden, 1984; Pye et.al., 1983). Of the various types of groundwater
contamination reported from across the world, based on their origin they have been classified
under three major categories as natural, agricultural and industrial contaminants. Each of these
sources is distinctly different from one another, and how to treat toxic plumes and waste
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deposits is one of the most complicated question of the present day, as it has legal, technical,
economical and many scientific aspects.
Fig.2. Schematic diagram showing source of contamination, recharge structures (surface and
subsurface), bore wells monitoring quality of groundwater and its presentation as a line
chart.
Of the above enlisted sources of pollutants, industries and mines are the huge source of
ground water pollution, it produces pollutants that are extremely harmful to people and the
environment, which includes:
� Asbestos – This pollutant is a serious health hazard and carcinogenic. Asbestos fibers
can be inhaled and cause illnesses such as asbestosis, mesothelioma, lung cancer,
intestinal cancer and liver cancer.
� Lead – This is a metallic element and can cause health and environmental problems. It is
a non-biodegradable substance so is hard to clean up once the environment is
contaminated. Lead is harmful to the health of many animals, including humans, as it can
inhibit the action of bodily enzymes.
� Mercury - This is a metallic element and can cause health and environmental problems.
It is a non-biodegradable substance so is hard to clean up once the environment is
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contaminated. Mercury is also harmful to animal health as it can cause illness through
mercury poisoning.
� Nitrates – The increased use of fertilizers means that nitrates are more often being
washed from the soil and into rivers and lakes. This can cause eutrophication, which can
be very problematic to marine environments.
� Phosphates - The increased use of fertilisers means that phosphates are more often being
washed from the soil and into rivers and lakes. This can cause eutrophication, which can
be very problematic to marine environments.
� Sulphur – This is a non-metallic substance that is harmful for marine life.
� Oils – Oil does not dissolve in water, instead it forms a thick layer on the water surface.
This can stop marine plants receiving enough light for photosynthesis. It is also harmful
for fish and marine birds.
� Petrochemicals – This is formed from gas or petrol and can be toxic to marine life.
Water harvesting and artificial recharge
Concept and Application:
Water harvesting refers to collection and storage of rain water. It also refers to other
activities aimed at harvesting surface or groundwater, prevention of losses through evaporation
and seepage. Other hydrological studies and engineering interventions, which are aimed at
conservation and efficient utilization of the limited water endowment of a physiographic unit
such as a watershed is also termed as water harvesting. The various aspects of water harvesting
identified by the working groups in India are construction of permanent/portable storage
structures, farm ponds either for supplemental irrigation or for augmentation of ground water,
check dams, percolation tanks at appropriate sites based on geological consideration; design of
percolation tanks, reclamation/revitalization of traditional water arresting structures, recharge
through wells, control of evaporation from surface water bodies, prevention of seepage looses in
appropriate situations, enhancement of runoff through mechanical and chemical treatment in
catchment area, sub-surface dams to arrest base-flow of ground water, soil and water
conservation practices comprising contour and terrace bunding, control of sea water incursion in
coastal aquifers and control of transpiration without affecting normal plant growth.
Augmentation of ground water resources through artificial recharge can be considered as an
activity which supplements the natural process of recharging the aquifers through percolation of
a fraction of the rainfall through the soil to the water table. Thus it becomes relevant in
situations mostly witnessed in Indian subcontinent, where the rainfall is seasonal (monsoonal)
and is not uniform over the year. Subsequently the quantum of natural recharge is inadequate to
meet the increasing demand on ground water resources.
Methods of Recharge:
Of many methods in artificial recharge, the broad classification to categorize them into two
groups based on the process of artificial inducement of surface water into groundwater system is
direct method, and indirect method. Water from surface sources are conveyed or stored in-situ at
places above the aquifer areas, where it is made to percolate and recharge the ground water, are
coined as direct method. Were as in the latter, the transfer of surface water is induced or it takes
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place as a consequence of a human activity which is not specifically aimed at recharging the
aquifers.
Induced recharge is effected by locating the ground water abstraction wells near influent
streams. The second type of indirect recharge is that arising out of seepage from stream or canal
or lake beds and return flow from irrigation. Under direct recharge, surface water from a river or
lake is transported to a suitable site, where it is made to enter the aquifer, thus increasing the
ground water supply.
In this paper the application of direct recharge in contaminant transport remediation is
explored. For direct recharge many methods are available and they can be grouped under three
categories: a) when the aquifer is shallow, water spreading may be applied by flooding over
areas or conveying water to basins and ditches; b) when an aquifer is situated at moderate depth,
the aquifer can be recharged through flooding of pits and shafts and c) in case of high
overburden thickness or confining aquifer conditions, recharge can only be effected by injecting
the water directly into the aquifer using boreholes/tube wells.
Application in groundwater remediation:
During the past decade, ground water scientists and engineers have devised a number of
methods to contain and or remediate groundwater contamination. The groundwater pollution
remediation technologies can be generally classified into onsite techniques and in-situ
techniques. The commonly used onsite techniques are pump and treat method, air sparing soil
water extraction, in-situ redox manipulation, permeable reactive barriers, phytoremediation etc.
The in-situ technologies, which directly remediate contaminated groundwater, are still not well
developed, primarily because site characterization is complex, expensive and inaccurate.
Moreover, contaminant plume and its migration with time are often difficult to define exactly.
So far the concept of artificial recharge and surface water harvesting was applied for
sustainability of aquifer system and also for in-situ dilution of groundwater bearing excessive
fluoride, arsenic, and other geogenic contaminants. The concept of aquifer recharge through
human intervention of surface water inducement at appropriate site locations can be extended in
groundwater remediation studies on a large scale. Especially in shallow to moderately deeper
polluted aquifer system, application of artificial recharge can be explored in in-situ dilution of
contaminants in groundwater. Some of the recharge measures and strategies which can be
applied in conjunction with other pre-existing techniques are briefly described further in this
paper.
Artificial recharge remediation technology
Surface Water Harvesting is the most common form of water harvesting practiced all
over the world. In many centuries construction of percolation ponds and irrigation tanks were
practiced to harvest surface runoff. The sizes of the tanks and their influential command area
vary widely. In India, the culture of surface water harvesting is widely seen in the southern
peninsular shield area indicating the water stress mainly in drinking water sector.
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Fig.3.Conceptual model showing cascading format of artificial recharge structures creating an
intermittent subsurface zone of dilution of migrating contaminant plume.
The basic objective in constructing a water harvesting structure is to collect and retain
the maximum possible amount of runoff generated from its catchment area. In general, the size
of the structure and design of a SWHS (Surface Water Harvesting Structure) also plays an
important role in its efficacy. Based on extensive research and study carried out by different
schools of thoughts all over the world, it is suggested that the smaller the catchment area, the
more efficient is the runoff collection (Evenrari, 1971; Boughton and Stone, 1985).
This concept can be extended in deliberating groundwater contaminant dilution at
feasible site locations. Apart from water crises there are several blocks in semi arid Indian
subcontinent where the drinking water sector is facing quality problem from variable sources.
As per Indian standard specification for drinking water IS: 10500-1983, there are certain
characteristics with specifications of groundwater shown in Table.2. Any of these components
beyond permissible limit is a contaminant and can causes adverse affects to life forms.
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Table-1: Source of groundwater contamination.
CATEGORY I- SOURCES DESIGNED TO
DISCHARGE SUBSTANCES
Nonhazardous waste
Subsurface percolation (e.g., septic tanks and cesspools) Nonwaste
Injection wells Open burning and detonation sites
Hazardous waste Radioactive disposal sites
Nonhazardous waste (e.g., brine disposal and drainage) CATEGORY III- SOURCES DESIGNED TO
RETAIN SUBSTANCES DURING TRANSPORT
OR TRANSMISSION
Non waste (e.g., enhanced recovery, artificial recharge,
solution mining, and in situ mining)
Pipelines
Land application Hazardous waste
Waste water (e.g., spray irrigation ) Nonhazardous waste
Waste water byproducts (e.g., sludge) Nonwaste
Hazardous waste Material transport and transfer operations
Non hazardous waste Hazardous waste
CATEGORY II - SOURCES DESIGNED TO
STORE, TREAT, AND/OR DISPOSE OF
SUBSTANCES; DISCHARGE THROUGH
UNPLANNED RELEASE
Nonhazardous waste
Landfills Nonwaste
Industrial hazardous waste CATEGORY IV-SOURCES DISCHARGING
SUBSTANCES AS CONSEQUENCE OF OTHER
PLANNED ACTIVITIES
Industrial nonhazardous waste Irrigation practices (e.g., return flow)
Municipal sanitary Pesticide applications
Open dumps, including illegal dumping (waste) Fertilizer applications
Residential (or local) disposal (waste) Animal feeding operations
Surface impoundments De-icing salts application
Hazardous waste Urban runoff
Nonhazardous waste Percolation of atmospheric pollutants
Waste tailings Mining and mine drainage
Waste piles Surface mine-related
Hazardous waste Underground mine-related
Nonhazardous waste CATEGORY V- SOURCES PROVIDING
CONDUCT OR INDUCING DISCHARGE
THROUGH ALTERED FLOW PATTERNS
Materials stockpiles (non waste) Production wells
Graveyards Oil (and gas) wells
Animal burial Geothermal and heat-recovery wells
Above-ground storage tanks Water – supply wells
Hazardous waste Other wells (non waste)
Nonhazardous waste Monitoring wells
Nonwaste Exploration wells
Underground storage tanks Construction excavation
Hazardous waste CATEGORY VI- NATURALLY OCCURING
SOURCES WHOSE DISCHARGE IS CREATED
AND/OR EXACERBATED HUMAN ACTIVITY
Nonhazardous waste Ground water-surface water interactions
Nonwaste Natural leaching
Containers
Hazardous waste
Saltwater intrusion/brackish water up coning (or
intrusion of other poor-quality natural water)
Source: Office of Technology Assessment (1984)
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Table-2: Specifications for Drinking Water Quality.
S. No Characteristics Maximum
Permissible
limits
Adverse Effects Beyond
Permissible limits
Alternative Extended
limits if no toxicity
confirmed
1. Color
(Hazen units)
10 Consumer
acceptance decreases
50
2. Odor Unobjectionable -- --
3. Taste Agreeable -- --
4. Turbidity (niu) 10 Consumer acceptance decreases 25
5. T.D.S.(mg/l) 500 Palatability decreases.
May cause gastrointestinal
irritations
3000
(WHO Limits:1500)
6. pH value 6.5 to 8.5 Mucous membrane affected 9.2
7. Total hardness as
CaCO3 (mg/l)
300 Encrustation and adverse effects
on domestic use
600
8. Calcium as Ca(mg/l) 75 -do- 200
9. Magnesium 30 -do- 100
10. Copper as Cu(mg/l) 0.05 Astringent taste discoloration &
corrosion of metallic parts
1.5
11. Iron as Fe(mg/l) 0.3 Taste & appearance affected.
Promotes iron bacteria
1.0
12. Manganese as Mn
(mg/l)
0.1 Taste & appearance affected 0.5
13. Chloride as Cl(mg/l) 250 Taste & palatability reduced. 1000
14. Sulphates as SO4
(mg/l)
150 Gastrointestinal irritations when
magnesium or sodium are
present
400 ( provided Mg
does not exceed 30)
15. Nitrate as NO3(mg/l) 45 Methane moglobinemia
Takes place
No relaxation
16. Fluoride as F(mg/lt) 0.6-1.2 Low Fluoride cases are linked
with dental care. Above 1.5
causes fluorosis
1.5
17. Phenolic compounds
as C H OH(mg/l)
0.001 Objectionable taste and odor 0.002
18. Mercury as Hg(mg/l) 0.001 Toxicity increases No relaxation
19. Cadmium as Cd(mg/l) 0.01 -do- -do-
20. Selenium as Se(mg/l) 0.01 -do- -do-
21. Arsenic as As (mg/l) 0.05 -do- -do-
22. Cyanide as CN(mg/l) 0.05 Water becomes toxic -do-
23. Lead as Pb(mg/l) 0.1 -do- -do-
24. Zinc as Zn(mg/l) 5 Astringent taste opalescence 15
25. Anionic detergents as
MBAS (mg/l)
0.2 Frothing in water 1
26. Chromium as Cr (mg/l) 0.05 Carcinogenic No relaxation
27. Poly nuclear aromatic
hydrocarbons as PAH
(mg/l)
__ -do- __
28. Mineral oil(mg/l) 0.01 Undesirable taste and odor 0.03
29. Residual free chlorine
(mg/l)
0.2
(Minimum)
__ 0.5 for protection
against viral infection
Source : Indian standard specification for drinking water IS: 10500-1983
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There are several criteria based on which any artificial recharge structures are designed and
executed for harvesting surface runoff. Some of the general features which are to be considered
in planning site selection is geomorphology, geology, rainfall pattern, depth to water table, soil
type, order of stream present etc. Surface geophysical investigation helps in understanding the
subsurface distribution of the lithology, aquifer depth, presence of hydraulic barrier like dykes,
depth to the basement etc. With the recent development in technology, the surface geophysical
data acquisition and presentation has improved many folds, which gives a 2D and 3D image of
the subsurface for a desired depth of interest. Based on these investigated results in
corroboration with appropriate elevation correction, sites are selected for puncturing the aquifer
to a desired depth, which is known as bore wells or tube wells.
These observation bore wells are used for monitoring the quality of groundwater and also to
understand the correlation of ground water level with seasonal variation. With the advent of
multi-parameter automatic water level recorders, the aquifer response to natural and induced
recharge has become more appropriate, as more than two parameter can be recorded and studied
under in-situ condition over a considerable period of time. A schematic diagram showing the
application of geophysics in site allocation and mapping of subsurface, followed by bore well
execution and monitoring is shown in Fig.1.
Industrial, mining or domestic waste ground sites pose major threat to groundwater
contamination on a large scale with time. Several attempts have been made in the recent past,
across the country to map the subsurface migration of this contaminant plume. Deeper migration
of the contaminant through the zone of unsaturation to the aquifer is a complex phenomenon to
understand (Rowe and Booker, 1990; Tiwary et.al., 2005). Mining waste, factory outlets or
domestic waste dump sites are usually planned without proper subsurface understanding of the
dump site.
It is a usual practice to preoccupy any vacant land devoid of day to day human activity,
close to the vicinity of the parent mining plant or factory. There are instances where due to non
availability of land, agricultural land or any other land close to the urban area are converted into
waste dump sites. Considering a case were the source of any known dump site is located and the
water quality is monitored in and around the dump site before and after commissioning of the
site is schematically represented in Fig.2. As discussed earlier, based on geophysical
investigation and proper understanding the subsurface geology and geomorphology, bore wells
are drilled for monitoring the water quality through multi parameter loggers. The response in
terms of concentration variation over time is shown as an inset in Fig.2. Contaminants in
groundwater have a tendency to migrate along the hydraulic gradient through highly permeable
formation. Once the source of contaminant and its direction of migration is known, accordingly
suitable sites across existing stream courses are selected for investigation for site feasibility to
construct appropriate artificial recharge structure, like check dam as shown in the figure. The
basic purpose for such a structure is to dilute the contaminant beyond its area of influence.
Depending upon the type of contaminant like excess chlorine, pigments etc., can be restricted in
its course of migration by constructing a subsurface barrier across the hydraulic gradient. The
barrier can be a simple filter media or can be in combination with activated charcoal and filter
media (coarse gravel and sand bed).
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The subsurface barrier is followed by a surface recharge structure like check dam or
percolation tank on its downstream. This will help in further dilution of contaminated water
filtering out of the subsurface barrier. Under favorable conditions recharge structures can be
designed across existing stream courses, downstream of contaminant plume migration in a
cascading format, so as to cause intermittent dilution of the contaminated groundwater flow. The
conceptualized visual of artificial recharge is shown in Figure.3. Further in order to understand
the rate of dilution and check the efficiency of these structures over groundwater pollution
mitigation approach, observational bore wells are to be drilled at regular intervals on either side
of these structures and are to be monitored in space and time.
The concept of artificial recharge structure can be extended in pollution mitigation studies
under favorable site criterions, as it requires no addition of artificial chemicals or processing
plant. Several attempts have been made successfully in mitigating excess groundwater fluoride
and sustaining the source for drinking water purpose through integrated geohydrological and
artificial recharge approach (Andrade, 2009).
Conclusion
This paper has been attempted to highlight the effectiveness and suitability of artificial
recharge and water harvesting in integration with different site criterions in mitigating some of
the pollutants in groundwater. Groundwater contamination is a problem which arose with the
human race in the field of industrialization and urbanization. There are several methodologies
and strategies adopted for tackling any respective problem, which either ends up with improper
management or inadaptability due to high cost of execution. Water harvesting and artificial
recharge depends mainly on natural precipitation over an area of study. Depending upon the
subsurface information and geohydrological investigations, appropriate structures are
recommended for in-situ dilution of contaminated groundwater flow. Of the many contaminants,
some of them can be managed through this approach. Also the cost of maintenance and
execution is negligible in course of time. The approachability of this methodology is represented
as conceptual models in this paper, which might require further refinement from engineering
point of view. Acknowledgement: The authors are thankful to Dr.Y.J.Bhaskar Rao, acting Director of National Geophysical
Research Institute for his encouragement and support towards the submission of this article for publication. We
also extend our gratitude towards Dr. R.N. Atavale and Dr. D.Muralidharan for educating us with the concept and
prospects of recharge studies in Indian scenario.
Suggested Readings:
1. Hearne C. L and Bush R. A (1996) Investigation into the impact of diffuse seepage from gold-mines in the
Klerksdorp region on water quality in the Vaal River, Phase 1. Report No. CED/011/96 for the Klerksdorp
Mine Managers Association (KMMA). Johannesburg. Unpublished.
2. IWQS (Institute for Water Quality Studies, DWAF) (1999) Report on the radioactivity monitoring programme
in the Mooi River (Wonderfonteinspruit) catchment. Report No. N/C200/00/RPQ/2399.
3. Wade P.W, Woodbourne S, Morris WM, Vos P and Jarvis NV (2000) Tier 1 Risk Assessment of Radionuclides
in Selected Sediments of the Mooi River. WRC-Project No K5/1095. 93 pp.
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4. Gordon, W. (1984) A Citizens Handbook on Groundwater Protection. New York: Natural Resources Defense
Council, Inc.
5. Pye, V.I., Patrick, R., and Quarles, J. (1983) Groundwater Contamination in the United States. Philadelphia:
University of Pennsylvania Press.
6. Boughton, J.C and Stone, J.J, “Variation of runoff with watershed area in semi-arid location”, 1985, Jr. of Arid
Environment, Vol.9, pp.13-25.
7. Evenari, M., “Stone mounds and the mechanics of runoff”, a chapter in the book, “The Negev: the challenge of
a desert, Oxford University Press, U.K. 1971, pp.127-147.
8. Rolland Andrade, “Sustainable Groundwater Development and Quality Management in Nalgonda District –
Andhra Pradesh through Integrated Geohydrological and Artificial Recharge Approach”, Ph.D Thesis, 2009,
Osmania University. Pages 1-280.
9. Ethan Grossman and Jennifer McGuire, “Groundwater remediation”, http://oceanworld.tamu.edu / resources
/environment-book / groundwaterremediation.html, 2008.
10. R. K. Tiwary, R. Dhakate, V. Ananda Rao and V. S. Singh, “Assessment and prediction of contaminant
migration in ground water from chromite waste dump”, Environ Geol (2005) 48: 420–429.
11. R.Kerry Rowe & John R. Booker, “Contaminant migration through fractured till into an underlying aquifer”,
Canadian Geotech. Jour. 27, 484-495 (1990).
Rolland Andrade, R. Rangarajan and D.N.V Lakshmi Devi belong to National Geophysical
Research Institute, Council of Scientific and Industrial Research, Hyderabad, INDIA
Corresponding author: [email protected]