840 Chapter 26

What Yoursquoll LearnYou will apply the conceptsyou have learned to a studyof the chemistry of Earthrsquosenvironment

You will explore the waysin which human activitiesaffect the chemical natureof the environment

Why Itrsquos ImportantA knowledge of chemistrywill help you develop adeeper appreciation for theenvironment and an increasedawareness of the effect ofhuman activities on Earthrsquosair land and water

Chemistry in theEnvironment

CHAPTER 26

This satellite photo of Earthshows some of our planetrsquosunique features features thatallow it to sustain life

Visit the Chemistry Web site atchemistrymccom to find linksabout chemistry in the environ-ment

IampE 1a 1b 1d

840-869_Ch26-866418 5906 412 PM Page 840

261 Earthrsquos Atmosphere 841

DISCOVERY LAB

Materials

soil600-mL beaker400-mL beakers (2)spoons (3)powdered lime (CaO)funnelfilter paper (2)250-mL beakers (2)ring stand with ringstirring rod

Clarification of Water

Municipal water-treatment plants sometimes have to remove mudfrom the water after rainwater washes dirt into reservoirs One

way to do this is to use chemicals that cause the mud particles toclump together and settle to the bottom of the treatment tank aprocess called sedimentation

Safety Precautions Lime is an irritant It is harmful if inhaledor swallowed

Procedure

1 Place two spoonfuls of soil into a 600-mL beaker Add water andstir until the water is muddy

2 Divide the muddy water into two equal samples in two 400-mLbeakers Label the beakers Lime and Control

3 Slowly sprinkle a spoonful of powdered lime (CaO) over the sur-face of the muddy water in the beaker labeled Lime Do not addlime to the control beaker Allow both beakers to remain undis-turbed Observe the beakers every five minutes until 15 minuteshave elapsed Record your observations

4 Filter the treated water through a funnel that contains a paper fil-ter Collect the filtrate in a 250-mL beaker Observe whether or notthe water samples become clearer after filtration

5 Repeat step 4 for the control using a clean filter and beaker

Analysis

How long did it take for the treated water to begin to clear Howdid the addition of lime speed up the process of sedimentation Didthe paper filter help the water become clearer

Objectivesbull Describe the structure and

composition of Earthrsquosatmosphere

bull Identify common chemicalreactions in the atmosphere

bull Analyze how human activi-ties affect the atmosphere

Vocabularyatmospheretropospherestratosphere

Section 261 Earthrsquos Atmosphere

To the best of our knowledge Earth is the only planet capable of supportinglife as we know it One glance at the photo on the opposite page helps explainwhy See those wispy clouds They are part of a protective envelope theatmosphere that blankets Earth and plays a key role in maintaining life

A Balanced AtmosphereTake a deep breath Yoursquove just inhaled part of Earthrsquos atmosphere The atmo-sphere extends from Earthrsquos surface to hundreds of kilometers into space Alargely gaseous zone the atmosphere contains the air we breathe the cloudsoverhead and the all-important substances that protect Earth and its inhabitantsfrom the Sunrsquos most powerful radiation Chemical reactions that occur in theatmosphere help maintain a balance among the different atmospheric gases buthuman activities such as burning fossil fuels can change this balance

840-869_Ch26-866418 5906 412 PM Page 841

Structure of Earthrsquos AtmosphereEarthrsquos atmosphere is divided into five layers based on altitude and temper-ature variation The lowest layermdashthe tropospheremdashextends from Earthrsquossurface to a height of approximately 15 km as shown in Figure 26-1Temperatures in the troposphere generally decrease with increasing altitudereaching a minimum of 58degC at 12 km Rain snow wind and other weatherphenomena occur in this layer We live our entire lives within the troposphereOnly astronauts in spacecraft go beyond its reach

Above the troposphere temperatures increase with altitude reaching amaximum of nearly 2degC at about 50 km This region of the atmosphere iscalled the stratosphere The stratosphere contains a layer of ozone a gas thathelps shield Earthrsquos surface from the Sunrsquos harmful ultraviolet radiationOzone protects Earth by absorbing solar radiation which raises the temper-ature of the stratosphere in the process You read about the ozone layer inChapter 1 as you began your study of chemistry

Beyond the stratosphere lie the mesosphere and the thermosphereTemperatures in the mesosphere decrease with altitude because there is littleozone in the air to absorb solar radiation The thermosphere is a region of rap-idly increasing temperatures This is because the relatively few gas moleculesin this region have extremely high kinetic energies At an altitude of about200 km temperatures can reach 1000degC

The outermost layer of the atmosphere is the exosphere Extending fromabout 500 km outward the exosphere marks the transition from Earthrsquos atmo-sphere to outer space There is no clear boundary between the two howeverThere are simply fewer and fewer molecules of gas at increasingly higher alti-tudes Eventually there are so few molecules that for all practical purposesEarthrsquos atmosphere has ended

Composition of Earthrsquos AtmosphereJust as the temperature of the atmosphere varies by altitude so does its com-position Roughly 75 of the mass of all atmospheric gases is found in thetroposphere Nitrogen and oxygen make up the vast majority of these gasesHowever there are a number of minor components The percent compositionof dry air near sea level is summarized in Table 26-1

842 Chapter 26 Chemistry in the Environment

Figure 26-1

Earthrsquos atmosphere has five layers that vary in compositiontemperature altitude and pressure Which layer would you expect to have the great-est pressure

500

100

75

50

25

0

Thermosphere(temperature increases)

Exosphere

Alt

itu

de

(km

)

Mesosphere(temperature decreases)

Stratosphere(temperature increases)

Troposphere(temperature decreases)

Composition of Dry Air Near Sea Level

Component Percent

Nitrogen 78

Oxygen 209

Argon 0934

Carbon dioxide 0033

Neon 000182

Helium 000052

Methane 000015

Krypton 000011

Hydrogen 000005

Nitrous oxide 000005

Xenon 0000009

Table 26-1

840-869 Ch26-866418 41204 639 PM Page 842

In addition to gases the troposphere contains solids in the form of dustsalts and ice Dustmdashtiny particles from Earthrsquos surface ash soot and plantpollenmdashenters the atmosphere when it is lifted from Earthrsquos surface and car-ried by wind The dust particles can cause sunsets to show spectacular col-ors as you can see in Figure 26-2 Salts are picked up from ocean spray Iceis present in the form of snowflakes and hailstones The troposphere also con-tains liquids the most common of which is water in the form of droplets foundin clouds Water is the only substance that exists as a solid liquid and gas inEarthrsquos atmosphere

Because Earth has a strong gravitational field most gases are held rela-tively close to the surface of the planet Only lighter gases such as heliumand hydrogen rise to the exosphere These light gases consisting of moleculesthat have absorbed radiation from the Sun move so rapidly that they are ableto escape Earthrsquos gravitational field Thus therersquos a small but constant seep-age of gases into outer space

Chemistry in the Outer AtmosphereEarth is constantly being bombarded with radiation and high-energy particlesfrom outer space The short-wavelength high-energy ultraviolet (UV) radia-tion is the most damaging to living things Because this radiation is capableof breaking the bonds in DNA molecules it can cause cancer and geneticmutations How can we exist here Life as we know it is possible primarilybecause two processes which occur in the thermosphere and the exosphereshield us from most of this radiation

Photodissociation Photodissociation is a process in which high-energyultraviolet solar radiation is absorbed by molecules causing their chemicalbonds to break In the upper atmosphere the photodissociation of oxygenabsorbs much of the high-energy UV radiation and produces atomic oxygen

O2(g) high-energy UV 0 2O(g)

The amount of atomic oxygen in the atmosphere increases with increasingaltitude Why is this true Because so much of the UV radiation that entersthe atmosphere is absorbed in the photodissociation of oxygen most of theoxygen above 150 km is in the form of atomic oxygen Below this altitudethe percentage of atomic oxygen decreases and most of the oxygen in thetroposphere is in the form of O2 molecules

261 Earthrsquos Atmosphere 843

Figure 26-2

When sunlight strikes dust particles in the atmosphere it isscattered in all directions Theblue portion of the light is scattered away from your eyesleaving the reds oranges andyellows you see here

840-870 Ch26-828378 11501 714 AM Page 843

Chem MC-843

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1627431

844 Chapter 26 Chemistry in the Environment

O2 O O

0

O2O O3

0

0

O

UV

UV

O3 O3X

0

X

O3 O2

a

b

d

c

An oxygen molecule formstwo oxygen atoms by photo-dissociation

An oxygen atom combineswith an oxygen molecule toform an energized ozone molecule (O3)

The energized ozone mole-cule collides with molecule XExcess energy is transferred to Xproducing ozone and an ener-gized X molecule (X)

The oxygen molecule thatforms when ozone photo-dissociates is available to startthe ozone cycle anew

d

c

b

aFigure 26-3

Ozone molecules are formed in the stratosphere Refer toTable C-1 in Appendix C for akey to atom color conventions

Photoionization The second process that absorbs high-energy solar radia-tion is photoionization which occurs when a molecule or atom absorbs suf-ficient energy to remove an electron Molecular nitrogen and oxygen as wellas atomic oxygen undergo photoionization in the upper atmosphere Note thata positively charged particle is produced for every negatively charged elec-tron in the atmosphere so neutrality of charge is maintained

N2 high-energy UV 0 N2 e

O2 high-energy UV 0 O2 e

O high-energy UV 0 O e

Ultraviolet radiation with the very highest energy is absorbed during photo-dissociation and photoionization in the upper atmosphere Because most ofthis harmful radiation does not reach Earthrsquos surface life can exist

Chemistry in the StratosphereIn addition to light gases the upper atmospheremdashmore specifically the strato-spheremdashcontains a substance called ozone In Chapter 1 you learned aboutthe ozone layer and how it contributes to shielding Earthrsquos surface from ultra-violet radiation Now letrsquos examine the chemical reactions that lead to the for-mation of ozone in the stratosphere

Formation of ozone Although the UV radiation with the very highestenergy has been absorbed by photoionization reactions in the outer atmos-phere much of the UV radiation that has sufficient energy to cause pho-todissociation still reaches the stratosphere In the stratosphere theseultraviolet waves are absorbed by O2 molecules which are more plentiful herethan in the upper atmosphere The O2 molecules are split into two atoms ofoxygen These highly reactive atoms immediately collide with other O2 mol-ecules forming ozone (O3) The O3 molecule that forms is highly unstablebecause its bonds contain excess energy that was gained from the UV radia-tion To achieve stability the energized O3 molecule must lose this excessenergy by colliding with another atom or molecule denoted in Figure 26-3as molecule X and transferring energy to it Usually N2 or O2 molecules aremost abundant and serve as energy-absorbing molecules for the reaction

840-869 Ch26-828378 2702 0902 PM Page 844

Chem MC-844

null

15344261

261 Earthrsquos Atmosphere 845

Figure 26-4

Freon-11 and Freon-12 are verystable compounds due to thestrength of the CmdashF and CmdashClbonds Because these bonds areso strong Freon molecules arenot easily broken down in thetroposphere In the strato-sphere however high-energyradiation causes the bonds tobreak

CFCl3

Freon-11 CF2Cl2

Freon-12

The formation of O3 and the transfer of excess energy to molecule X aresummarized below Remember that X is most often N2 or O2 An asterisk ona molecule indicates that the molecule is energized

O(g) O2(g) 0 O3(g)

O3(g) X(g) 0 O3(g) X(g)

The ozone molecule does not last long after being formed Ozone canabsorb high-energy solar radiation and photodissociate back to O2 and O thusstarting the ozone cycle anew If high-energy radiation were not absorbed byozone and oxygen molecules it would penetrate the troposphere and possi-bly damage or kill living things

Thinning of the ozone layer As you read in earlier chapters F SherwoodRowland and Mario Molina have proposed that chlorofluorocarbons (CFCs) areresponsible for the thinning of the ozone layer that has been observed in thestratosphere CFCs such as Freon-11 (CFCl3) and Freon-12 (CF2Cl2) shownin Figure 26-4 have been used as coolants in refrigerators and air condition-ers and as propellants in spray cans They also have been used as foaming agentsin the manufacture of some plastics CFCs are highly stable molecules in thetroposphere After release they eventually diffuse into the stratosphere wherethey become unstable in the presence of the high-energy radiation found at thisaltitude The CFCs absorb high-energy UV radiation causing photodissocia-tion in which the carbon-chlorine bonds in the molecules are broken

CF2Cl2(g) high-energy UV 0 CF2Cl(g) Cl(g)

The atomic chlorine formed from this reaction reacts with stratospheric ozoneto form chlorine monoxide (ClO) and O2

Cl(g) O3(g) 0 ClO(g) O2(g)

The chlorine monoxide then combines with free oxygen atoms to regeneratefree chlorine atoms and oxygen molecules

ClO(g) O(g) 0 Cl(g) O2(g)

Because Cl atoms speed up the depletion of ozone and are first used and thenre-formed they function as a catalyst The net result of these reactions is theconversion of ozone into O2

O3(g) O(g) 0 2O2(g)

Each Cl atom remains in the stratosphere for about two years before it isdestroyed in other reactions During this time it is capable of catalyzing thebreakdown of about 100 000 molecules of ozone

Environmental HealthInspectorAre you concerned about thequality of the air you breathethe water you drink and thefood you eat If so you mightbecome an environmentalhealth inspector

Also called sanitarians manyenvironmental health inspec-tors work for local state andfederal governments Theyanalyze air water and food toidentify possible contaminantsThey might inspect dairiesrestaurants hospitals process-ing plants and industriesWhen they find contaminantsthey look for the source stopthe pollution and require thepolluter to clean it up

LAB

See page 964 in Appendix E forModeling Ozone Depletion

840-869 Ch26-866418 41204 639 PM Page 845

844 Chapter 26 Chemistry in the Environment

O2 O O

0

O2O O3

0

0

O

UV

UV

O3 O3X

0

X

O3 O2

a

b

d

c

An oxygen molecule formstwo oxygen atoms by photo-dissociation

An oxygen atom combineswith an oxygen molecule toform an energized ozone molecule (O3)

The energized ozone mole-cule collides with molecule XExcess energy is transferred to Xproducing ozone and an ener-gized X molecule (X)

The oxygen molecule thatforms when ozone photo-dissociates is available to startthe ozone cycle anew

d

c

b

aFigure 26-3

Ozone molecules are formed in the stratosphere Refer toTable C-1 in Appendix C for akey to atom color conventions

Photoionization The second process that absorbs high-energy solar radia-tion is photoionization which occurs when a molecule or atom absorbs suf-ficient energy to remove an electron Molecular nitrogen and oxygen as wellas atomic oxygen undergo photoionization in the upper atmosphere Note thata positively charged particle is produced for every negatively charged elec-tron in the atmosphere so neutrality of charge is maintained

N2 high-energy UV 0 N2 e

O2 high-energy UV 0 O2 e

O high-energy UV 0 O e

Ultraviolet radiation with the very highest energy is absorbed during photo-dissociation and photoionization in the upper atmosphere Because most ofthis harmful radiation does not reach Earthrsquos surface life can exist

Chemistry in the StratosphereIn addition to light gases the upper atmospheremdashmore specifically the strato-spheremdashcontains a substance called ozone In Chapter 1 you learned aboutthe ozone layer and how it contributes to shielding Earthrsquos surface from ultra-violet radiation Now letrsquos examine the chemical reactions that lead to the for-mation of ozone in the stratosphere

Formation of ozone Although the UV radiation with the very highestenergy has been absorbed by photoionization reactions in the outer atmos-phere much of the UV radiation that has sufficient energy to cause pho-todissociation still reaches the stratosphere In the stratosphere theseultraviolet waves are absorbed by O2 molecules which are more plentiful herethan in the upper atmosphere The O2 molecules are split into two atoms ofoxygen These highly reactive atoms immediately collide with other O2 mol-ecules forming ozone (O3) The O3 molecule that forms is highly unstablebecause its bonds contain excess energy that was gained from the UV radia-tion To achieve stability the energized O3 molecule must lose this excessenergy by colliding with another atom or molecule denoted in Figure 26-3as molecule X and transferring energy to it Usually N2 or O2 molecules aremost abundant and serve as energy-absorbing molecules for the reaction

840-869 Ch26-828378 2702 0902 PM Page 844

Chem MC-844

null

15344261

261 Earthrsquos Atmosphere 845

Figure 26-4

Freon-11 and Freon-12 are verystable compounds due to thestrength of the CmdashF and CmdashClbonds Because these bonds areso strong Freon molecules arenot easily broken down in thetroposphere In the strato-sphere however high-energyradiation causes the bonds tobreak

CFCl3

Freon-11 CF2Cl2

Freon-12

The formation of O3 and the transfer of excess energy to molecule X aresummarized below Remember that X is most often N2 or O2 An asterisk ona molecule indicates that the molecule is energized

O(g) O2(g) 0 O3(g)

O3(g) X(g) 0 O3(g) X(g)

The ozone molecule does not last long after being formed Ozone canabsorb high-energy solar radiation and photodissociate back to O2 and O thusstarting the ozone cycle anew If high-energy radiation were not absorbed byozone and oxygen molecules it would penetrate the troposphere and possi-bly damage or kill living things

Thinning of the ozone layer As you read in earlier chapters F SherwoodRowland and Mario Molina have proposed that chlorofluorocarbons (CFCs) areresponsible for the thinning of the ozone layer that has been observed in thestratosphere CFCs such as Freon-11 (CFCl3) and Freon-12 (CF2Cl2) shownin Figure 26-4 have been used as coolants in refrigerators and air condition-ers and as propellants in spray cans They also have been used as foaming agentsin the manufacture of some plastics CFCs are highly stable molecules in thetroposphere After release they eventually diffuse into the stratosphere wherethey become unstable in the presence of the high-energy radiation found at thisaltitude The CFCs absorb high-energy UV radiation causing photodissocia-tion in which the carbon-chlorine bonds in the molecules are broken

CF2Cl2(g) high-energy UV 0 CF2Cl(g) Cl(g)

The atomic chlorine formed from this reaction reacts with stratospheric ozoneto form chlorine monoxide (ClO) and O2

Cl(g) O3(g) 0 ClO(g) O2(g)

The chlorine monoxide then combines with free oxygen atoms to regeneratefree chlorine atoms and oxygen molecules

ClO(g) O(g) 0 Cl(g) O2(g)

Because Cl atoms speed up the depletion of ozone and are first used and thenre-formed they function as a catalyst The net result of these reactions is theconversion of ozone into O2

O3(g) O(g) 0 2O2(g)

Each Cl atom remains in the stratosphere for about two years before it isdestroyed in other reactions During this time it is capable of catalyzing thebreakdown of about 100 000 molecules of ozone

Environmental HealthInspectorAre you concerned about thequality of the air you breathethe water you drink and thefood you eat If so you mightbecome an environmentalhealth inspector

Also called sanitarians manyenvironmental health inspec-tors work for local state andfederal governments Theyanalyze air water and food toidentify possible contaminantsThey might inspect dairiesrestaurants hospitals process-ing plants and industriesWhen they find contaminantsthey look for the source stopthe pollution and require thepolluter to clean it up

LAB

See page 964 in Appendix E forModeling Ozone Depletion

840-869 Ch26-866418 41204 639 PM Page 845

261 Earthrsquos Atmosphere 845

Figure 26-4

Freon-11 and Freon-12 are verystable compounds due to thestrength of the CmdashF and CmdashClbonds Because these bonds areso strong Freon molecules arenot easily broken down in thetroposphere In the strato-sphere however high-energyradiation causes the bonds tobreak

CFCl3

Freon-11 CF2Cl2

Freon-12

The formation of O3 and the transfer of excess energy to molecule X aresummarized below Remember that X is most often N2 or O2 An asterisk ona molecule indicates that the molecule is energized

O(g) O2(g) 0 O3(g)

O3(g) X(g) 0 O3(g) X(g)

The ozone molecule does not last long after being formed Ozone canabsorb high-energy solar radiation and photodissociate back to O2 and O thusstarting the ozone cycle anew If high-energy radiation were not absorbed byozone and oxygen molecules it would penetrate the troposphere and possi-bly damage or kill living things

Thinning of the ozone layer As you read in earlier chapters F SherwoodRowland and Mario Molina have proposed that chlorofluorocarbons (CFCs) areresponsible for the thinning of the ozone layer that has been observed in thestratosphere CFCs such as Freon-11 (CFCl3) and Freon-12 (CF2Cl2) shownin Figure 26-4 have been used as coolants in refrigerators and air condition-ers and as propellants in spray cans They also have been used as foaming agentsin the manufacture of some plastics CFCs are highly stable molecules in thetroposphere After release they eventually diffuse into the stratosphere wherethey become unstable in the presence of the high-energy radiation found at thisaltitude The CFCs absorb high-energy UV radiation causing photodissocia-tion in which the carbon-chlorine bonds in the molecules are broken

CF2Cl2(g) high-energy UV 0 CF2Cl(g) Cl(g)

The atomic chlorine formed from this reaction reacts with stratospheric ozoneto form chlorine monoxide (ClO) and O2

Cl(g) O3(g) 0 ClO(g) O2(g)

The chlorine monoxide then combines with free oxygen atoms to regeneratefree chlorine atoms and oxygen molecules

ClO(g) O(g) 0 Cl(g) O2(g)

Because Cl atoms speed up the depletion of ozone and are first used and thenre-formed they function as a catalyst The net result of these reactions is theconversion of ozone into O2

O3(g) O(g) 0 2O2(g)

Each Cl atom remains in the stratosphere for about two years before it isdestroyed in other reactions During this time it is capable of catalyzing thebreakdown of about 100 000 molecules of ozone

Environmental HealthInspectorAre you concerned about thequality of the air you breathethe water you drink and thefood you eat If so you mightbecome an environmentalhealth inspector

Also called sanitarians manyenvironmental health inspec-tors work for local state andfederal governments Theyanalyze air water and food toidentify possible contaminantsThey might inspect dairiesrestaurants hospitals process-ing plants and industriesWhen they find contaminantsthey look for the source stopthe pollution and require thepolluter to clean it up

LAB

See page 964 in Appendix E forModeling Ozone Depletion

840-869 Ch26-866418 41204 639 PM Page 845

An estimated several million tonsof CFCs have diffused into the stra-tosphere A significant change in theloss of ozone was first observed inthe mid-1980s when researchersbegan tracking an annual thinning ofthe ozone layer over the South Poleduring certain months of the yearFigure 26-5 shows satellite photosof the progressive thinning of the ozone layer over AntarcticaScientists have recently found a similar but smaller area of thinningover the North Pole

Because CFCs appear to play arole in the process of ozone destruc-tion many countries have stoppedmanufacturing and using these com-pounds It will take many yearshowever before the concentration ofozone in the stratosphere returns toits former levels Why is this true

Chemistry in the TroposphereThe composition of the troposphere varies from area to area mostly as a resultof human activities Some compounds that may be present in only minutequantities in the air above a remote rain forest area may be present in muchhigher quantities over a large city If you live in a city you may have noticedthat the air occasionally appears hazy as it does in Figure 26-6 The hazethat you see is a form of air pollution more commonly known as smog

Photochemical smog In large cities such as Los Angeles Denver andMexico City a hazy brown blanket of smog is created when sunlight reactswith pollutants in the air Because the smog forms with the aid of light itis called photochemical smog The smog-producing pollutants enter the

846 Chapter 26 Chemistry in the Environment

Figure 26-5

Ozone distribution in the south-ern hemisphere was mapped bya NASA satellite from 1980 to1994 Observe the area of lowest ozone concentration(purple) over Antarctica Howhas it changed

Figure 26-6

Smog reduces visibility irritatesthe eyes and damages vegeta-tion This smog was photo-graphed over New York City

840-870 Ch26-828378 11701 243 AM Page 846

Chem MC-846

null

105271965

troposphere when fossil fuels such as coal natural gas and gasoline areburned Figure 26-7 shows one of the major sources of smog

The burning of fossil fuels in internal combustion engines causes nitrogenand oxygen to react forming nitrogen oxides such as NO and NO2

N2(g) O2(g) 0 2NO(g)

2NO(g) O2(g) 0 2NO2(g)

The NO2 in turn photodissociates in the presence of high-energy UV thatpenetrates through the upper atmosphere to form atomic oxygen whichcombines with O2 to form ozone

NO2(g) high-energy UV 0 NO(g) O(g)

O(g) O2(g) 0 O3(g)

In the troposphere ozone can irritate your eyes and lungs and increase yoursusceptibility to asthma and pneumonia

Photochemical smog also contains unburned hydrocarbons and carbonmonoxide both of which come from the exhaust of automobile enginesThese pollutants can be reduced or eliminated from the atmosphere in a vari-ety of ways Cleaner running engines and catalytic converters greatly reduceNO and hydrocarbon levels Strict federal tailpipe emission standards areencouraging automobile manufacturers to develop new cars that are poweredby electricity or alternative fuels such as natural gas

Acid rain Sulfur-containing compounds are normally present in small quan-tities in the troposphere However human activities have greatly increased theconcentration of these compounds in the air Sulfur dioxide (SO2) is the mostharmful of the sulfur-containing compounds

Most of the sulfur dioxide in the troposphere is produced when coal andoil that contain high concentrations of sulfur are burned in power plants Thesulfur dioxide that forms is oxidized to sulfur trioxide (SO3) when it com-bines with either O2 or O3 in the atmosphere When SO3 reacts with mois-ture in the air sulfuric acid is formed

SO3(g) H2O(l) 0 H2SO4(aq)

261 Earthrsquos Atmosphere 847

Figure 26-7

The combustion of petroleum inautomobiles is a major source ofsmog Sunlight acts on theexhaust gases of automobilesfactories power plants andhomes to produce smog

Earth ScienceCONNECTION

Not all soils and bodies ofwater are equally affected by

acid rain Soils that contain cal-cium carbonate from limestoneand lakes that are surrounded by and lie on top of calcium carbonate-rich soils are protectedfrom much of the acid rain dam-age The hydrogen ion in acidrain combines with the dissolvedcarbonate ions from the lime-stone to produce hydrogen carbonate ions The hydrogencarbonatecarbonate solution inthe water and soil serves as abuffer absorbing additionalhydrogen ions from acid rain andmaintaining a stable pH Areasthat contain silicate rocks andsoil are affected to a greaterdegree by acid rain SouthernMichigan and the AdirondackMountain region of northernNew York are especially suscepti-ble to acid rain damage becauseof the large percentage of sili-cate rocks found there

840-869 Ch26-828378 3802 113 PM Page 847

Chem MC-847

null

1456051

848 Chapter 26 Chemistry in the Environment

Figure 26-8

Acid-rain damage to buildingsstatues and trees amounts tobillions of dollars a year

Acid Rain in a BagMaking a Model Acid precipitation often fallsto Earth hundreds of kilometers away fromwhere the pollutant gases enter the atmospherebecause the gases diffuse through the air and arecarried by the wind In this lab you will modelthe formation of acid rain to observe how thedamage caused by acid varies with the distancefrom the source of pollution You also willobserve another factor that affects the amountof damage caused by acid rain

Materials plastic petri dish bottom 1-gallonzipper-close plastic bag white paper droppers004 bromocresol green indicator 05M KNO210M H2SO4 clock or watch

Procedure 1 Place 25 drops of 004 bromocresol green

indicator of varying sizes in the bottom half ofa plastic petri dish so that they are about 1 cmapart Be sure that there are both large andsmall drops at any given distance from the cen-ter Leave the center of the petri dish empty

2 Place a zipper-close plastic bag on a piece ofwhite paper

3 Carefully slide the petri dish containing thedrops of indicator inside the plastic bag

4 In the center of the petri dish place one largedrop of 05M KNO2 To this KNO2 drop addtwo drops of 10M H2SO4 CAUTION KNO2 andH2SO4 are skin irritants Carefully seal the bagObserve whether the mixing of these twochemicals produces any bubbles of gas This isthe pollution source

5 Observe and compare the color changes thattake place in the drops of indicator of differentsizes and distances from the pollution sourceRecord your observations every 15 seconds

6 To clean up carefully remove the petri dishfrom the bag rinse it with water then dry it

Analysis1 As the gas reacts with water in the drops two

acids form 2NO2 H2O 0 HNO3 HNO2What are these acids

2 Did the small or large drops change color firstWhy

3 Did the distance of the indicator drops fromthe pollution source have an effect on howquickly the reaction occurred Explain

4 State two hypotheses that will explain yourobservations and incorporate the answersfrom questions 2 and 3 in your hypotheses

5 Based on your hypotheses in question 4 whatcan you infer about the damage done toplants by acid fog as compared with acid rain

miniLAB

Acidic air pollution is created also whennitrogen oxides from car exhausts com-bine with atmospheric moisture to formnitric acid In either case when thisacidic moisture falls to Earth as rain orsnow it is known as acid rain You canmodel the formation of acid rain in theminiLAB on this page

Acid rain increases the acidity of sometypes of soil resulting in the removal ofessential nutrients from the soil The lossof nutrients adversely affects the arearsquosvegetation leaving trees and other plantswith less resistance to disease insectsand bad weather Acid rain also increasesthe acidity of streams rivers and lakeswhich can kill or harm aquatic life AsFigure 26-8 shows damage to trees and

to outdoor surfaces can be extensive The acid in precipitation reacts withCaCO3 the major component of marble and limestone What products are produced by this reaction

840-869 Ch26-866418 41204 640 PM Page 848

troposphere when fossil fuels such as coal natural gas and gasoline areburned Figure 26-7 shows one of the major sources of smog

The burning of fossil fuels in internal combustion engines causes nitrogenand oxygen to react forming nitrogen oxides such as NO and NO2

N2(g) O2(g) 0 2NO(g)

2NO(g) O2(g) 0 2NO2(g)

The NO2 in turn photodissociates in the presence of high-energy UV thatpenetrates through the upper atmosphere to form atomic oxygen whichcombines with O2 to form ozone

NO2(g) high-energy UV 0 NO(g) O(g)

O(g) O2(g) 0 O3(g)

In the troposphere ozone can irritate your eyes and lungs and increase yoursusceptibility to asthma and pneumonia

Photochemical smog also contains unburned hydrocarbons and carbonmonoxide both of which come from the exhaust of automobile enginesThese pollutants can be reduced or eliminated from the atmosphere in a vari-ety of ways Cleaner running engines and catalytic converters greatly reduceNO and hydrocarbon levels Strict federal tailpipe emission standards areencouraging automobile manufacturers to develop new cars that are poweredby electricity or alternative fuels such as natural gas

Acid rain Sulfur-containing compounds are normally present in small quan-tities in the troposphere However human activities have greatly increased theconcentration of these compounds in the air Sulfur dioxide (SO2) is the mostharmful of the sulfur-containing compounds

Most of the sulfur dioxide in the troposphere is produced when coal andoil that contain high concentrations of sulfur are burned in power plants Thesulfur dioxide that forms is oxidized to sulfur trioxide (SO3) when it com-bines with either O2 or O3 in the atmosphere When SO3 reacts with mois-ture in the air sulfuric acid is formed

SO3(g) H2O(l) 0 H2SO4(aq)

261 Earthrsquos Atmosphere 847

Figure 26-7

The combustion of petroleum inautomobiles is a major source ofsmog Sunlight acts on theexhaust gases of automobilesfactories power plants andhomes to produce smog

Earth ScienceCONNECTION

Not all soils and bodies ofwater are equally affected by

acid rain Soils that contain cal-cium carbonate from limestoneand lakes that are surrounded by and lie on top of calcium carbonate-rich soils are protectedfrom much of the acid rain dam-age The hydrogen ion in acidrain combines with the dissolvedcarbonate ions from the lime-stone to produce hydrogen carbonate ions The hydrogencarbonatecarbonate solution inthe water and soil serves as abuffer absorbing additionalhydrogen ions from acid rain andmaintaining a stable pH Areasthat contain silicate rocks andsoil are affected to a greaterdegree by acid rain SouthernMichigan and the AdirondackMountain region of northernNew York are especially suscepti-ble to acid rain damage becauseof the large percentage of sili-cate rocks found there

840-869 Ch26-828378 3802 113 PM Page 847

Chem MC-847

null

1456051

848 Chapter 26 Chemistry in the Environment

Figure 26-8

Acid-rain damage to buildingsstatues and trees amounts tobillions of dollars a year

Acid Rain in a BagMaking a Model Acid precipitation often fallsto Earth hundreds of kilometers away fromwhere the pollutant gases enter the atmospherebecause the gases diffuse through the air and arecarried by the wind In this lab you will modelthe formation of acid rain to observe how thedamage caused by acid varies with the distancefrom the source of pollution You also willobserve another factor that affects the amountof damage caused by acid rain

Materials plastic petri dish bottom 1-gallonzipper-close plastic bag white paper droppers004 bromocresol green indicator 05M KNO210M H2SO4 clock or watch

Procedure 1 Place 25 drops of 004 bromocresol green

indicator of varying sizes in the bottom half ofa plastic petri dish so that they are about 1 cmapart Be sure that there are both large andsmall drops at any given distance from the cen-ter Leave the center of the petri dish empty

2 Place a zipper-close plastic bag on a piece ofwhite paper

3 Carefully slide the petri dish containing thedrops of indicator inside the plastic bag

4 In the center of the petri dish place one largedrop of 05M KNO2 To this KNO2 drop addtwo drops of 10M H2SO4 CAUTION KNO2 andH2SO4 are skin irritants Carefully seal the bagObserve whether the mixing of these twochemicals produces any bubbles of gas This isthe pollution source

5 Observe and compare the color changes thattake place in the drops of indicator of differentsizes and distances from the pollution sourceRecord your observations every 15 seconds

6 To clean up carefully remove the petri dishfrom the bag rinse it with water then dry it

Analysis1 As the gas reacts with water in the drops two

acids form 2NO2 H2O 0 HNO3 HNO2What are these acids

2 Did the small or large drops change color firstWhy

3 Did the distance of the indicator drops fromthe pollution source have an effect on howquickly the reaction occurred Explain

4 State two hypotheses that will explain yourobservations and incorporate the answersfrom questions 2 and 3 in your hypotheses

5 Based on your hypotheses in question 4 whatcan you infer about the damage done toplants by acid fog as compared with acid rain

miniLAB

Acidic air pollution is created also whennitrogen oxides from car exhausts com-bine with atmospheric moisture to formnitric acid In either case when thisacidic moisture falls to Earth as rain orsnow it is known as acid rain You canmodel the formation of acid rain in theminiLAB on this page

Acid rain increases the acidity of sometypes of soil resulting in the removal ofessential nutrients from the soil The lossof nutrients adversely affects the arearsquosvegetation leaving trees and other plantswith less resistance to disease insectsand bad weather Acid rain also increasesthe acidity of streams rivers and lakeswhich can kill or harm aquatic life AsFigure 26-8 shows damage to trees and

to outdoor surfaces can be extensive The acid in precipitation reacts withCaCO3 the major component of marble and limestone What products are produced by this reaction

840-869 Ch26-866418 41204 640 PM Page 848

848 Chapter 26 Chemistry in the Environment

Figure 26-8

Acid-rain damage to buildingsstatues and trees amounts tobillions of dollars a year

Acid Rain in a BagMaking a Model Acid precipitation often fallsto Earth hundreds of kilometers away fromwhere the pollutant gases enter the atmospherebecause the gases diffuse through the air and arecarried by the wind In this lab you will modelthe formation of acid rain to observe how thedamage caused by acid varies with the distancefrom the source of pollution You also willobserve another factor that affects the amountof damage caused by acid rain

Materials plastic petri dish bottom 1-gallonzipper-close plastic bag white paper droppers004 bromocresol green indicator 05M KNO210M H2SO4 clock or watch

Procedure 1 Place 25 drops of 004 bromocresol green

indicator of varying sizes in the bottom half ofa plastic petri dish so that they are about 1 cmapart Be sure that there are both large andsmall drops at any given distance from the cen-ter Leave the center of the petri dish empty

2 Place a zipper-close plastic bag on a piece ofwhite paper

3 Carefully slide the petri dish containing thedrops of indicator inside the plastic bag

4 In the center of the petri dish place one largedrop of 05M KNO2 To this KNO2 drop addtwo drops of 10M H2SO4 CAUTION KNO2 andH2SO4 are skin irritants Carefully seal the bagObserve whether the mixing of these twochemicals produces any bubbles of gas This isthe pollution source

5 Observe and compare the color changes thattake place in the drops of indicator of differentsizes and distances from the pollution sourceRecord your observations every 15 seconds

6 To clean up carefully remove the petri dishfrom the bag rinse it with water then dry it

Analysis1 As the gas reacts with water in the drops two

acids form 2NO2 H2O 0 HNO3 HNO2What are these acids

2 Did the small or large drops change color firstWhy

3 Did the distance of the indicator drops fromthe pollution source have an effect on howquickly the reaction occurred Explain

4 State two hypotheses that will explain yourobservations and incorporate the answersfrom questions 2 and 3 in your hypotheses

5 Based on your hypotheses in question 4 whatcan you infer about the damage done toplants by acid fog as compared with acid rain

miniLAB

Acidic air pollution is created also whennitrogen oxides from car exhausts com-bine with atmospheric moisture to formnitric acid In either case when thisacidic moisture falls to Earth as rain orsnow it is known as acid rain You canmodel the formation of acid rain in theminiLAB on this page

Acid rain increases the acidity of sometypes of soil resulting in the removal ofessential nutrients from the soil The lossof nutrients adversely affects the arearsquosvegetation leaving trees and other plantswith less resistance to disease insectsand bad weather Acid rain also increasesthe acidity of streams rivers and lakeswhich can kill or harm aquatic life AsFigure 26-8 shows damage to trees and

to outdoor surfaces can be extensive The acid in precipitation reacts withCaCO3 the major component of marble and limestone What products are produced by this reaction

840-869 Ch26-866418 41204 640 PM Page 848

As human dependence on fossil fuels has increased so has the acidity ofrain About 200 years ago rain had a pH between 6 and 76 almost neutralToday it is common in many regions for rain to have a pH between 4 and45 or even lower In fact the pH of rain in Wheeling West Virginia has beenmeasured at 18 midway between the acidity of lemon juice and that of stom-ach acid What do you think might account for this extreme acidity

Given the damaging effects of acid rain measures have been taken toreduce SO2 emissions into the environment High-sulfur coal may be washedbefore it is burned in power plants or the SO2 that is produced when coalburns may be removed during the burning process This removal is accom-plished by adding powdered limestone (CaCO3) to the combustion chamberalong with the coal as shown in Figure 26-9 The limestone is decomposedto lime (CaO) and carbon dioxide

CaCO3(s) 0 CaO(s) CO2(g)

The lime then reacts with SO2 to form calcium sulfite

CaO(s) SO2(g) 0 CaSO3(s)

About half of the SO2 from coal is removed by adding solid limestonepowder to the combustion material The rest of the SO2 must be removed byscrubbing the reaction gas with a shower of CaO and water In this stepthe remaining SO2 is converted into solid CaSO3 which precipitates as awatery slurry Most of the sulfur is removed from the coal-burning process

261 Earthrsquos Atmosphere 849

Figure 26-9

Follow the process as this powerplant removes the sulfur fromcoal to reduce air pollutionWhere is the sulfur found at theend of the process

Water + CaOCombustion chamber

Coal

CaCO3

CaOAir

SO2 scrubberS + O2 0 SO2

CaSO3 slurry

Stack

Waste slurry

CaSO3 + SO2

Section 261 Assessment

1 Compare and contrast the major layers of theatmosphere in terms of temperature altitude andcomposition

2 Write the equations for the chemical reactions thatlead to the formation of ozone in the stratosphere

3 What is the source of the sulfur that contributes tothe formation of acid rain

4 Thinking Critically Hydrogen is the most abun-dant element in the universe Why is it so rare inEarthrsquos atmosphere

5 Applying Concepts Explain why the followingstatement is true Ozone in the troposphere is con-sidered a pollutant but ozone in the stratosphere isessential for life on Earth

chemistrymccomself_check_quiz

840-869 Ch26-866418 41204 640 PM Page 849

850 Chapter 26 Chemistry in the Environment

Section 262 Earthrsquos Water

Objectivesbull Trace the cycle of water in

the environment

bull Identify the chemical com-position of seawater

bull Describe methods of desali-nation and relate the short-age of freshwater in someregions to the developmentof desalination techniques

bull Outline the steps of awater-treatment process

Vocabularyhydrospheresalinitydesalination

Look back at the photo of Earth in the chapter opener The blue oceans clearlyillustrate the abundance of water on Earth Water is a rare substance on otherplanets On Earth however water is found as a solid liquid and gas through-out the environment You have read that the presence of an atmosphere is crit-ical for the existence of living things on Earth Because living things cannotexist without water it too is essential for life

The HydrosphereWater is the most abundant substance in the human body and the most com-mon substance on Earth covering approximately 72 of the surface of thisplanet All the water found in and on Earthrsquos surface and in the atmosphereis collectively referred to as the hydrosphere More than 97 of this surfacewater is located in the oceans Another 21 is frozen in glaciers and polarice caps That leaves a meager 06 available as liquid freshwater

The Water CycleBoth seawater and freshwater move through Earthrsquos atmosphere its surfaceand below its surface in a process known as the water cycle You may alsosee the water cycle referred to as the hydrologic cycle In this cycle watercontinually moves through the environment by the processes of evaporationcondensation and precipitation The Sun provides the energy for theseprocesses Follow Figure 26-10 as you read about the water cycle

Solar radiation causes liquid water to evaporate into a gaseous state Theresulting water vapor rises in the atmosphere and cools As it cools the watervapor again becomes a liquid when it condenses on dust particles in the airforming clouds Clouds are made of millions of tiny water droplets that col-lide with each other to form larger drops When the drops grow so large thatthey can no longer stay suspended in the clouds they fall to Earth in the formof precipitationmdashrain snow sleet or hail

Figure 26-10

The water cycle powered by theSun circulates water throughthe atmosphere Earthrsquos surfaceand below its surface

840-869 Ch26-828378 06292001 0839 AM Page 850

Chem MC-850

null

1317066

CMC_Spn_C26-S02

null

6562015

Most of the falling precipitation soaks into the ground and becomes part ofgroundwater the underground water that collects in small spaces between soiland rock particles If the soil becomes saturated with water the excess waterflows along Earthrsquos surface and into lakes and streams This is called runoff

Look again at Figure 26-10 As you can see water cycles through theatmosphere on Earthrsquos surface and under the surface Can atmosphericprocesses affect the hydrosphere The answer is most definitely yes Processesthat take place in the atmosphere such as the formation of acid rain can havea direct impact on the hydrosphere The interrelatedness of the componentsof the environment is an important concept to keep in mind as you exploreEarthrsquos water beginning with the vast and mighty seas

Earthrsquos OceansIf yoursquove ever swallowed a gulp of seawater you know that it tastes quitedifferent from tap water Seawater contains dissolved salts which give thewater a salty taste Where do the salts come from Rivers and groundwaterdissolve elements such as calcium magnesium and sodium from rocks andminerals Flowing rivers then transport these elements to the oceans Eruptingvolcanoes add sulfur and chlorine to the oceans as well

Salinity is a measure of the mass of salts dissolved in seawater It is usu-ally measured in grams of salt per kilogram of seawater The average salin-ity of ocean water is about 35 g per kg so ocean water contains about 35dissolved salts Most of these salts dissociate in water and are present in theform of ions Table 26-2 lists the ions in seawater Note that chlorine andsodium are the most abundant ions in seawater Although Earthrsquos oceans arevast the proportions and quantities of dissolved salts are nearly constant inall areas Indeed they have stayed almost the same for hundreds of millionsof years Why is this so As rivers volcanoes and atmospheric processes addnew substances to seawater elements are removed from the oceans by bio-logical processes and sedimentation Thus the oceans are considered to bein a steady state with respect to salinity

Desalination In some areas of the world such as the Middle East fresh-water is scarce Can the people in these areas drink the much more abundantocean water Because seawater has a high salinity it canrsquot be consumed byliving organisms If humans are to use ocean water for drinking and for irri-gation of crops the salts must first be removed The removal of salts fromseawater to make it usable by living things is called desalination

Dissolved salts can be removed from seawater by distillation a simpleprocess in which the seawater is boiled to evaporate the volatile water Purewater vapor is collected and condensed leaving the nonvolatile salts behindThis process is quite energy intensive and is not practical for a large-scaleoperation It is rarely used commercially

You learned in Chapter 15 that osmosis is the flow of solvent moleculesthrough a semipermeable membrane from a region of higher solvent con-centration to a region of lower solvent concentration If a high-enough pres-sure is applied to the system osmosis can be reversed that is the solvent canbe forced to flow from low to high concentrations of solvent This process iscalled reverse osmosis In a modern desalination plant seawater is forcedunder pressure into cylinders containing hollow semipermeable fibers Acylinder holds more than three million fibers each of which has the diame-ter of a human hair The water molecules pass inward through the walls ofthe fibers and the salts are held back Desalinated water flows through theinside of the fibers and is collected

262 Earthrsquos Water 851

Ionic Composition ofSeawater

Dissolved Percent in ion seawater

Chloride (Cl) 5504

Sodium (Na) 3061

Sulfate (SO42) 768

Magnesium (Mg2) 369

Calcium (Ca2) 116

Potassium (K) 110

Hydrogen carbonate (HCO3

) 041

Bromide (Br) 019

All others 012

Table 26-2

BiologyCONNECTION

What happens if you drink sea-water The ions in the water

enter your blood from the diges-tive tract Your kidneys canrsquotremove the ions fast enough sothe ion concentration remainshigh in the blood Water movesout of your cells by osmosis caus-ing dehydration The cells shriveland begin to malfunction Mean-while your body begins to swellas the volume of blood and thefluid surrounding cells increasesdue to the additional waterDehydration causes the thirst center of your brain to signalyour kidneys to stop makingurine so the ions arenrsquot removedfrom your body

840-869 Ch26-828378 2702 0903 PM Page 851

Chem MC-851

null

2368336

Figure 26-11 shows how seawater can be desalinated under pressure byreverse osmosis The largest desalination plant in the world is located inJubail Saudi Arabia where it produces 50 of the countryrsquos drinking waterby the reverse osmosis of seawater from the Persian Gulf Smaller desalina-tion plants are in operation in Israel California and Florida

Earthrsquos FreshwaterHow much water do you use in a day The answer may surprise you An aver-age person needs to drink about 15 L per day for survival But this is only asmall fraction of the total amount of water used for daily activities In theUnited States about 7 L of water per person per day is used for cooking anddrinking about 120 L for bathing laundering and housecleaning 80 L forflushing toilets and 80 L for watering yards Massive quantities of water arealso used in agriculture and industry to produce food and other productsFigure 26-12 shows the major consumers of water in the United States bydaily percentage

Recall that only 06 of the hydrosphere is made up of liquid freshwaterAlmost all of this freshwater is found as groundwater and other undergroundsources Very small amounts (001) come also from surface water such as

Figure 26-11

This room in a desalinationplant houses thousands of cylinders

Each cylinder contains millions of tiny fibers acrosswhich reverse osmosis takesplace Maintaining the highpressure necessary for thisprocess makes it very energyintensive

b

a

Fiber

Cylinder

Hollow fibers of semipermeable

membrane

Water molecules Salt particles

Pure water to collector

Figure 26-12

Industry and farming use mostof the freshwater in the UnitedStates Residential use accountsfor about 12

42Farms

46Industry

12Residential

852 Chapter 26 Chemistry in the Environment

a

b

840-870 Ch26-828378 11501 718 AM Page 852

Chem MC-852

null

9236815

lakes and rivers and the atmosphere provides a tiny amount (0001) as watervapor Freshwater essential for life on Earth is our most precious resourceUnfortunately human activities can affect the quality of freshwater

Human Impact on the HydrosphereA freshwater stream may look sparkling and clean but itrsquos probably not safefor drinking Many rivers and lakes in the United States are polluted Bacteriaand viruses enter water supplies through contamination by sewage and indus-trial wastes Wastes from landfills and mines leak into groundwater reservoirsPesticides herbicides and fertilizers are picked up by rainwater and carriedinto streams Streams flow into rivers and rivers empty into oceans In addi-tion coastal cities pump waste directly into the oceans For this reason muchof the oceansrsquo pollution is found along the coasts of continents

A major cause of freshwater pollution however is caused by legal every-day activities Water is polluted when we flush toilets wash hands brush teethand water lawns The main culprits are nitrogen and phosphorusmdashtwo ele-ments found in household detergents soaps and fertilizers Nitrogen andphosphorus are difficult to remove from sewage and wastewater They con-tribute to water pollution by causing certain algae and bacteria to reproducerapidly in the water The result is an algal bloom shown in Figure 26-13When the algae die they decompose a process that consumes oxygen Theresult is the depletion of oxygen in the water Without sufficient oxygen fishand other aquatic organisms cannot survive

Municipal Water and Sewage TreatmentAs you have learned the water that most people use for their daily activitiescomes from lakes rivers reservoirs and underground sources Because it hasbeen exposed to a variety of contaminants it must be purified at a water treat-ment plant before it can be used

The treatment of water in municipal treatment plants usually involves fivesteps coarse filtration sedimentation sand filtration aeration and steriliza-tion The water is first passed through a screen to remove large solids It thenenters large settling tanks where sand and other medium-sized particles settleout Often CaO (powdered lime) and Al2(SO4)3 (alum) are added to coagu-late small particles and bacteria These clumps of particles settle out of solu-tion during a sedimentation step as you saw in the DISCOVERY LAB Aftersettling the water is filtered through a bed of sand The filtered water is thensprayed into the air in a process called aeration During aeration oxygen com-bines with many of the harmful dissolved organic substances in the water oxi-dizing them to harmless compounds

262 Earthrsquos Water 853

Figure 26-13

Algae often experience a popu-lation explosion when fertilizeris carried into lakes and pondsWhen the algae die and decayoxygen in the pond is depletedand fish may die as a result

Topic WastesTo learn more about wastesvisit the Chemistry Web siteat chemistrymccomActivity Imagine you are partof a team building a self-con-tained space station List dif-ferent biological andindustrial wastes the societywill produce Suggest strate-gies and technologies to copewith those wastes

840-869 Ch26-866418 41204 641 PM Page 853

Most of the falling precipitation soaks into the ground and becomes part ofgroundwater the underground water that collects in small spaces between soiland rock particles If the soil becomes saturated with water the excess waterflows along Earthrsquos surface and into lakes and streams This is called runoff

Look again at Figure 26-10 As you can see water cycles through theatmosphere on Earthrsquos surface and under the surface Can atmosphericprocesses affect the hydrosphere The answer is most definitely yes Processesthat take place in the atmosphere such as the formation of acid rain can havea direct impact on the hydrosphere The interrelatedness of the componentsof the environment is an important concept to keep in mind as you exploreEarthrsquos water beginning with the vast and mighty seas

Earthrsquos OceansIf yoursquove ever swallowed a gulp of seawater you know that it tastes quitedifferent from tap water Seawater contains dissolved salts which give thewater a salty taste Where do the salts come from Rivers and groundwaterdissolve elements such as calcium magnesium and sodium from rocks andminerals Flowing rivers then transport these elements to the oceans Eruptingvolcanoes add sulfur and chlorine to the oceans as well

Salinity is a measure of the mass of salts dissolved in seawater It is usu-ally measured in grams of salt per kilogram of seawater The average salin-ity of ocean water is about 35 g per kg so ocean water contains about 35dissolved salts Most of these salts dissociate in water and are present in theform of ions Table 26-2 lists the ions in seawater Note that chlorine andsodium are the most abundant ions in seawater Although Earthrsquos oceans arevast the proportions and quantities of dissolved salts are nearly constant inall areas Indeed they have stayed almost the same for hundreds of millionsof years Why is this so As rivers volcanoes and atmospheric processes addnew substances to seawater elements are removed from the oceans by bio-logical processes and sedimentation Thus the oceans are considered to bein a steady state with respect to salinity

Desalination In some areas of the world such as the Middle East fresh-water is scarce Can the people in these areas drink the much more abundantocean water Because seawater has a high salinity it canrsquot be consumed byliving organisms If humans are to use ocean water for drinking and for irri-gation of crops the salts must first be removed The removal of salts fromseawater to make it usable by living things is called desalination

Dissolved salts can be removed from seawater by distillation a simpleprocess in which the seawater is boiled to evaporate the volatile water Purewater vapor is collected and condensed leaving the nonvolatile salts behindThis process is quite energy intensive and is not practical for a large-scaleoperation It is rarely used commercially

You learned in Chapter 15 that osmosis is the flow of solvent moleculesthrough a semipermeable membrane from a region of higher solvent con-centration to a region of lower solvent concentration If a high-enough pres-sure is applied to the system osmosis can be reversed that is the solvent canbe forced to flow from low to high concentrations of solvent This process iscalled reverse osmosis In a modern desalination plant seawater is forcedunder pressure into cylinders containing hollow semipermeable fibers Acylinder holds more than three million fibers each of which has the diame-ter of a human hair The water molecules pass inward through the walls ofthe fibers and the salts are held back Desalinated water flows through theinside of the fibers and is collected

262 Earthrsquos Water 851

Ionic Composition ofSeawater

Dissolved Percent in ion seawater

Chloride (Cl) 5504

Sodium (Na) 3061

Sulfate (SO42) 768

Magnesium (Mg2) 369

Calcium (Ca2) 116

Potassium (K) 110

Hydrogen carbonate (HCO3

) 041

Bromide (Br) 019

All others 012

Table 26-2

BiologyCONNECTION

What happens if you drink sea-water The ions in the water

enter your blood from the diges-tive tract Your kidneys canrsquotremove the ions fast enough sothe ion concentration remainshigh in the blood Water movesout of your cells by osmosis caus-ing dehydration The cells shriveland begin to malfunction Mean-while your body begins to swellas the volume of blood and thefluid surrounding cells increasesdue to the additional waterDehydration causes the thirst center of your brain to signalyour kidneys to stop makingurine so the ions arenrsquot removedfrom your body

840-869 Ch26-828378 2702 0903 PM Page 851

Chem MC-851

null

2368336

Figure 26-11 shows how seawater can be desalinated under pressure byreverse osmosis The largest desalination plant in the world is located inJubail Saudi Arabia where it produces 50 of the countryrsquos drinking waterby the reverse osmosis of seawater from the Persian Gulf Smaller desalina-tion plants are in operation in Israel California and Florida

Earthrsquos FreshwaterHow much water do you use in a day The answer may surprise you An aver-age person needs to drink about 15 L per day for survival But this is only asmall fraction of the total amount of water used for daily activities In theUnited States about 7 L of water per person per day is used for cooking anddrinking about 120 L for bathing laundering and housecleaning 80 L forflushing toilets and 80 L for watering yards Massive quantities of water arealso used in agriculture and industry to produce food and other productsFigure 26-12 shows the major consumers of water in the United States bydaily percentage

Recall that only 06 of the hydrosphere is made up of liquid freshwaterAlmost all of this freshwater is found as groundwater and other undergroundsources Very small amounts (001) come also from surface water such as

Figure 26-11

This room in a desalinationplant houses thousands of cylinders

Each cylinder contains millions of tiny fibers acrosswhich reverse osmosis takesplace Maintaining the highpressure necessary for thisprocess makes it very energyintensive

b

a

Fiber

Cylinder

Hollow fibers of semipermeable

membrane

Water molecules Salt particles

Pure water to collector

Figure 26-12

Industry and farming use mostof the freshwater in the UnitedStates Residential use accountsfor about 12

42Farms

46Industry

12Residential

852 Chapter 26 Chemistry in the Environment

a

b

840-870 Ch26-828378 11501 718 AM Page 852

Chem MC-852

null

9236815

lakes and rivers and the atmosphere provides a tiny amount (0001) as watervapor Freshwater essential for life on Earth is our most precious resourceUnfortunately human activities can affect the quality of freshwater

Human Impact on the HydrosphereA freshwater stream may look sparkling and clean but itrsquos probably not safefor drinking Many rivers and lakes in the United States are polluted Bacteriaand viruses enter water supplies through contamination by sewage and indus-trial wastes Wastes from landfills and mines leak into groundwater reservoirsPesticides herbicides and fertilizers are picked up by rainwater and carriedinto streams Streams flow into rivers and rivers empty into oceans In addi-tion coastal cities pump waste directly into the oceans For this reason muchof the oceansrsquo pollution is found along the coasts of continents

A major cause of freshwater pollution however is caused by legal every-day activities Water is polluted when we flush toilets wash hands brush teethand water lawns The main culprits are nitrogen and phosphorusmdashtwo ele-ments found in household detergents soaps and fertilizers Nitrogen andphosphorus are difficult to remove from sewage and wastewater They con-tribute to water pollution by causing certain algae and bacteria to reproducerapidly in the water The result is an algal bloom shown in Figure 26-13When the algae die they decompose a process that consumes oxygen Theresult is the depletion of oxygen in the water Without sufficient oxygen fishand other aquatic organisms cannot survive

Municipal Water and Sewage TreatmentAs you have learned the water that most people use for their daily activitiescomes from lakes rivers reservoirs and underground sources Because it hasbeen exposed to a variety of contaminants it must be purified at a water treat-ment plant before it can be used

The treatment of water in municipal treatment plants usually involves fivesteps coarse filtration sedimentation sand filtration aeration and steriliza-tion The water is first passed through a screen to remove large solids It thenenters large settling tanks where sand and other medium-sized particles settleout Often CaO (powdered lime) and Al2(SO4)3 (alum) are added to coagu-late small particles and bacteria These clumps of particles settle out of solu-tion during a sedimentation step as you saw in the DISCOVERY LAB Aftersettling the water is filtered through a bed of sand The filtered water is thensprayed into the air in a process called aeration During aeration oxygen com-bines with many of the harmful dissolved organic substances in the water oxi-dizing them to harmless compounds

262 Earthrsquos Water 853

Figure 26-13

Algae often experience a popu-lation explosion when fertilizeris carried into lakes and pondsWhen the algae die and decayoxygen in the pond is depletedand fish may die as a result

Topic WastesTo learn more about wastesvisit the Chemistry Web siteat chemistrymccomActivity Imagine you are partof a team building a self-con-tained space station List dif-ferent biological andindustrial wastes the societywill produce Suggest strate-gies and technologies to copewith those wastes

840-869 Ch26-866418 41204 641 PM Page 853

Figure 26-11 shows how seawater can be desalinated under pressure byreverse osmosis The largest desalination plant in the world is located inJubail Saudi Arabia where it produces 50 of the countryrsquos drinking waterby the reverse osmosis of seawater from the Persian Gulf Smaller desalina-tion plants are in operation in Israel California and Florida

Earthrsquos FreshwaterHow much water do you use in a day The answer may surprise you An aver-age person needs to drink about 15 L per day for survival But this is only asmall fraction of the total amount of water used for daily activities In theUnited States about 7 L of water per person per day is used for cooking anddrinking about 120 L for bathing laundering and housecleaning 80 L forflushing toilets and 80 L for watering yards Massive quantities of water arealso used in agriculture and industry to produce food and other productsFigure 26-12 shows the major consumers of water in the United States bydaily percentage

Recall that only 06 of the hydrosphere is made up of liquid freshwaterAlmost all of this freshwater is found as groundwater and other undergroundsources Very small amounts (001) come also from surface water such as

Figure 26-11

This room in a desalinationplant houses thousands of cylinders

Each cylinder contains millions of tiny fibers acrosswhich reverse osmosis takesplace Maintaining the highpressure necessary for thisprocess makes it very energyintensive

b

a

Fiber

Cylinder

Hollow fibers of semipermeable

membrane

Water molecules Salt particles

Pure water to collector

Figure 26-12

Industry and farming use mostof the freshwater in the UnitedStates Residential use accountsfor about 12

42Farms

46Industry

12Residential

852 Chapter 26 Chemistry in the Environment

a

b

840-870 Ch26-828378 11501 718 AM Page 852

Chem MC-852

null

9236815

lakes and rivers and the atmosphere provides a tiny amount (0001) as watervapor Freshwater essential for life on Earth is our most precious resourceUnfortunately human activities can affect the quality of freshwater

Human Impact on the HydrosphereA freshwater stream may look sparkling and clean but itrsquos probably not safefor drinking Many rivers and lakes in the United States are polluted Bacteriaand viruses enter water supplies through contamination by sewage and indus-trial wastes Wastes from landfills and mines leak into groundwater reservoirsPesticides herbicides and fertilizers are picked up by rainwater and carriedinto streams Streams flow into rivers and rivers empty into oceans In addi-tion coastal cities pump waste directly into the oceans For this reason muchof the oceansrsquo pollution is found along the coasts of continents

A major cause of freshwater pollution however is caused by legal every-day activities Water is polluted when we flush toilets wash hands brush teethand water lawns The main culprits are nitrogen and phosphorusmdashtwo ele-ments found in household detergents soaps and fertilizers Nitrogen andphosphorus are difficult to remove from sewage and wastewater They con-tribute to water pollution by causing certain algae and bacteria to reproducerapidly in the water The result is an algal bloom shown in Figure 26-13When the algae die they decompose a process that consumes oxygen Theresult is the depletion of oxygen in the water Without sufficient oxygen fishand other aquatic organisms cannot survive

Municipal Water and Sewage TreatmentAs you have learned the water that most people use for their daily activitiescomes from lakes rivers reservoirs and underground sources Because it hasbeen exposed to a variety of contaminants it must be purified at a water treat-ment plant before it can be used

The treatment of water in municipal treatment plants usually involves fivesteps coarse filtration sedimentation sand filtration aeration and steriliza-tion The water is first passed through a screen to remove large solids It thenenters large settling tanks where sand and other medium-sized particles settleout Often CaO (powdered lime) and Al2(SO4)3 (alum) are added to coagu-late small particles and bacteria These clumps of particles settle out of solu-tion during a sedimentation step as you saw in the DISCOVERY LAB Aftersettling the water is filtered through a bed of sand The filtered water is thensprayed into the air in a process called aeration During aeration oxygen com-bines with many of the harmful dissolved organic substances in the water oxi-dizing them to harmless compounds

262 Earthrsquos Water 853

Figure 26-13

Algae often experience a popu-lation explosion when fertilizeris carried into lakes and pondsWhen the algae die and decayoxygen in the pond is depletedand fish may die as a result

Topic WastesTo learn more about wastesvisit the Chemistry Web siteat chemistrymccomActivity Imagine you are partof a team building a self-con-tained space station List dif-ferent biological andindustrial wastes the societywill produce Suggest strate-gies and technologies to copewith those wastes

840-869 Ch26-866418 41204 641 PM Page 853

lakes and rivers and the atmosphere provides a tiny amount (0001) as watervapor Freshwater essential for life on Earth is our most precious resourceUnfortunately human activities can affect the quality of freshwater

Human Impact on the HydrosphereA freshwater stream may look sparkling and clean but itrsquos probably not safefor drinking Many rivers and lakes in the United States are polluted Bacteriaand viruses enter water supplies through contamination by sewage and indus-trial wastes Wastes from landfills and mines leak into groundwater reservoirsPesticides herbicides and fertilizers are picked up by rainwater and carriedinto streams Streams flow into rivers and rivers empty into oceans In addi-tion coastal cities pump waste directly into the oceans For this reason muchof the oceansrsquo pollution is found along the coasts of continents

A major cause of freshwater pollution however is caused by legal every-day activities Water is polluted when we flush toilets wash hands brush teethand water lawns The main culprits are nitrogen and phosphorusmdashtwo ele-ments found in household detergents soaps and fertilizers Nitrogen andphosphorus are difficult to remove from sewage and wastewater They con-tribute to water pollution by causing certain algae and bacteria to reproducerapidly in the water The result is an algal bloom shown in Figure 26-13When the algae die they decompose a process that consumes oxygen Theresult is the depletion of oxygen in the water Without sufficient oxygen fishand other aquatic organisms cannot survive

Municipal Water and Sewage TreatmentAs you have learned the water that most people use for their daily activitiescomes from lakes rivers reservoirs and underground sources Because it hasbeen exposed to a variety of contaminants it must be purified at a water treat-ment plant before it can be used

The treatment of water in municipal treatment plants usually involves fivesteps coarse filtration sedimentation sand filtration aeration and steriliza-tion The water is first passed through a screen to remove large solids It thenenters large settling tanks where sand and other medium-sized particles settleout Often CaO (powdered lime) and Al2(SO4)3 (alum) are added to coagu-late small particles and bacteria These clumps of particles settle out of solu-tion during a sedimentation step as you saw in the DISCOVERY LAB Aftersettling the water is filtered through a bed of sand The filtered water is thensprayed into the air in a process called aeration During aeration oxygen com-bines with many of the harmful dissolved organic substances in the water oxi-dizing them to harmless compounds

262 Earthrsquos Water 853

Figure 26-13

Algae often experience a popu-lation explosion when fertilizeris carried into lakes and pondsWhen the algae die and decayoxygen in the pond is depletedand fish may die as a result

Topic WastesTo learn more about wastesvisit the Chemistry Web siteat chemistrymccomActivity Imagine you are partof a team building a self-con-tained space station List dif-ferent biological andindustrial wastes the societywill produce Suggest strate-gies and technologies to copewith those wastes

840-869 Ch26-866418 41204 641 PM Page 853

The final step in water treatment sterilization is accomplished by treatingthe water with substances that kill bacteria The most commonly used substanceis liquefied chlorine gas Chlorine reacts with water to form hypochlorous acid(HClO) which destroys any remaining microorganisms in the water

Cl2(aq) H2O(l) 0 HClO(aq) H(aq) Cl(aq)

Figure 26-14 summarizes the flow of water through a water treatment plantIn addition to water treatment plants cities and towns also have sewage

treatment plants to maintain clean water supplies The steps involved in sewagetreatment are similar to those used to treat water The incoming sewage is fil-tered to remove debris and larger suspended solids Then as in conventionalwater treatment the sewage is passed into large settling tanks where sus-pended solids settle out During aeration the sewage water comes into con-tact with large amounts of air and the increased oxygen levels promote therapid growth of bacteria needed to biodegrade the wastes After treatmentabout 90 of solids and dissolved biodegradable wastes have been removed

A final treatment removes many inorganic pollutants such as the toxicheavy metals Cd2 and Pb2 This treatment is usually expensive but anincreasing percentage of wastewater treatment facilities are taking this extrastep to ensure that toxic substances do not enter water supplies Before releaseinto the environment the processed water is treated with Cl2 to kill anyremaining bacteria

854 Chapter 26 Chemistry in the Environment

Figure 26-14

Most public water systems usethese steps to treat water forhuman consumption

Section 262 Assessment

6 Use the water cycle to explain how the hydrosphereand atmosphere are interrelated

7 Sequence the five steps involved in municipalwater treatment

8 Explain why much of the water that comes out ofyour faucet is ldquorecycledrdquo water

9 Thinking Critically Why does desalination byreverse osmosis require the use of high pressure

10 Making and Using Graphs Use the data inTable 26-2 Ionic Composition of Seawater tomake a bar graph showing the percentages of themost abundant ions in seawater

Settling tanks

Sandfilter

CaO andAl2(SO4)3added Aeration

Waterintake

Coarse filtrationscreen

Storagetank

To users

Chlorineadded

chemistrymccomself_check_quiz

840-869 Ch26-866418 41204 641 PM Page 854

263 Earthrsquos Crust 855

Objectivesbull Identify Earthrsquos major

regions

bull List the major elements inEarthrsquos crust

bull Describe the composition ofminerals

Vocabularylithosphere

Section Earthrsquos Crust

Earth is a large dynamic planet that has existed according to best estimatesfor approximately 46 billion years When Earth was newly formed it was ahuge molten mass As this mass cooled it differentiated into regions of vary-ing composition and density These regions or layers include a dense cen-tral core a thick mantle and a thin crust The core is further divided into asmall solid inner core and a larger liquid outer core Figure 26-15 showsEarthrsquos layers

Gravity caused more-dense elements to sink beneath less-dense elementsin molten Earth Hence the core is composed mostly of iron and smallamounts of nickel In contrast to the dense core the less-dense outer regionat first consisted mostly of rock as oxygen combined with silicon aluminummagnesium and small amounts of iron This lighter outer region later sepa-rated into the mantle and the crust as Earth cooled further Many light ele-ments such as hydrogen escaped Earthrsquos gravitational force and are nowfound mostly in space

Earthrsquos crust makes up about one percent of Earthrsquos mass Oceanic crustlies beneath Earthrsquos oceans Continental crust is the part of the crust beneathlandmasses

The LithosphereYou have already studied the liquid outer part of Earthmdashthe hydrospheremdashand the gaseous atmosphere Each of these parts has a distinct compositionand environmental chemistry as you have learned

The solid crust and the upper mantle make up the region called the litho-sphere Oxygen is the most abundant element in the lithosphere Unlike thehydrosphere and the atmosphere the lithosphere contains a large variety ofother elements including deposits of alkali alkaline earth and transition metalelements Table 26-3 lists the most abundant elements in the continental crustportion of the lithosphere With the exception of gold platinum and a few otherrare metals that are found free in nature most metallic elements occur as com-pounds in minerals A mineral is a solid inorganic compound found in natureMinerals have distinct crystalline structures and chemical compositions Mostare combinations of metals and nonmetals

263

Figure 26-15

Earthrsquos layers include a smallinner core and large outer coreof high density a thick mantleof medium density and a verythin crust of low density

Outer core (2300 km)

10ndash12 gcm3

Crust (5ndash40 km)28 gcm3 Mantle (2900 km)

33ndash55 gcm3

Inner core(1200 km)

12ndash13 gcm3

Abundance of Elements inthe Continental Crust

ElementPercent by mass

Oxygen 452

Silicon 272

Aluminum 82

Iron 58

Calcium 51

Magnesium 28

Sodium 23

Potassium 17

Other elements 17(Ti H Mn Cu Pb Zn Sn etc)

Table 26-3

840-869 Ch26-828378 06292001 1029 AM Page 855

Chem MC-855

null

14466461

CMC_Spn_C26-S03

null

7235939

Many industrially important metals are found in the form of oxides sulfidesor carbonates Recall that oxides are compounds of metals combined with oxy-gen sulfides are compounds of metals combined with sulfur and carbonatesare compounds of metals combined with both carbon and oxygen Table 26-4lists some oxide sulfide and carbonate minerals and their common names Theoxides are formed largely from transition metals on the left side of the peri-odic table because these elements have lower electronegativities and tend tolose bonding electrons when they combine with the oxide ion The elementson the right side of the table and in some of the other groups have higher elec-tronegativities and tend to form bonds with sulfur that are more covalent incharacter The alkaline earth metals (2A) are usually found as carbonates inthe marble and limestone of mountain ranges Thus periodic properties governthe state of combination in which elements are found in nature Figure 26-16shows the major mineral sources for most of the elements Magnesium andcalcium carbonates cause water to become hard The How It Works featureat the end of the chapter shows how hard water can be softened

856 Chapter 26 Chemistry in the Environment

Figure 26-16

This periodic table shows themineral sources for most elements

Some Common Oxide Sulfide and Carbonate Minerals

Oxides Sulfides Carbonates

SnO2 (cassiterite) CuFeS2 (chalcopyrite) MgCO3 (magnesite)

TiO2 (rutile) PbS (galena) CaCO3 (calcite)

Al2O3 (bauxite) HgS (cinnabar) SrCO3 (strontianite)

Fe3O4 (magnetite) FeS2 (pyrite) BaCO3 (witherite)

FeCr2O4 (chromite) ZnS (sphalerite)

FeTiO3 (ilmenite)

MnO2 (pyrolusite)

Fe2O3 (hematite)

Table 26-4

Carbonatessulfates

Sulfides

Uncombined

Oxides

Halide salts or brines

Phosphates

Silicates

H

Li

Na

K

Rb

Cs

Be

Mg

Ca

Sr

Ba

Sc

Y

La

Ti

Zr

Hf

V

Nb

Ta

Cr

Mo

W

Mn

Re

Fe Co Ni Cu

Ag

Au

Zn

Cd

Hg

B

Al

Ga

In

Tl

C

Si

Ge

Sn

Pb

Ce Pr Nd

U

Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu

N

P

As

Sb

Bi

O

S

Se

Te

F

Cl

Br

I

He

Ne

Ar

Kr

Xe

1A1

2A2

3B3

4B4

5B5

6B6

7B7 8

8B9 10

1B11

2B12

3A13

4A14

5A15

6A16

7A17

8A18

840-869 Ch26-866418 41204 641 PM Page 856

Many industrially important metals are found in the form of oxides sulfidesor carbonates Recall that oxides are compounds of metals combined with oxy-gen sulfides are compounds of metals combined with sulfur and carbonatesare compounds of metals combined with both carbon and oxygen Table 26-4lists some oxide sulfide and carbonate minerals and their common names Theoxides are formed largely from transition metals on the left side of the peri-odic table because these elements have lower electronegativities and tend tolose bonding electrons when they combine with the oxide ion The elementson the right side of the table and in some of the other groups have higher elec-tronegativities and tend to form bonds with sulfur that are more covalent incharacter The alkaline earth metals (2A) are usually found as carbonates inthe marble and limestone of mountain ranges Thus periodic properties governthe state of combination in which elements are found in nature Figure 26-16shows the major mineral sources for most of the elements Magnesium andcalcium carbonates cause water to become hard The How It Works featureat the end of the chapter shows how hard water can be softened

856 Chapter 26 Chemistry in the Environment

Figure 26-16

This periodic table shows themineral sources for most elements

Some Common Oxide Sulfide and Carbonate Minerals

Oxides Sulfides Carbonates

SnO2 (cassiterite) CuFeS2 (chalcopyrite) MgCO3 (magnesite)

TiO2 (rutile) PbS (galena) CaCO3 (calcite)

Al2O3 (bauxite) HgS (cinnabar) SrCO3 (strontianite)

Fe3O4 (magnetite) FeS2 (pyrite) BaCO3 (witherite)

FeCr2O4 (chromite) ZnS (sphalerite)

FeTiO3 (ilmenite)

MnO2 (pyrolusite)

Fe2O3 (hematite)

Table 26-4

Carbonatessulfates

Sulfides

Uncombined

Oxides

Halide salts or brines

Phosphates

Silicates

H

Li

Na

K

Rb

Cs

Be

Mg

Ca

Sr

Ba

Sc

Y

La

Ti

Zr

Hf

V

Nb

Ta

Cr

Mo

W

Mn

Re

Fe Co Ni Cu

Ag

Au

Zn

Cd

Hg

B

Al

Ga

In

Tl

C

Si

Ge

Sn

Pb

Ce Pr Nd

U

Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu

N

P

As

Sb

Bi

O

S

Se

Te

F

Cl

Br

I

He

Ne

Ar

Kr

Xe

1A1

2A2

3B3

4B4

5B5

6B6

7B7 8

8B9 10

1B11

2B12

3A13

4A14

5A15

6A16

7A17

8A18

840-869 Ch26-866418 41204 641 PM Page 856

263 Earthrsquos Crust 857

Figure 26-17

Metals are extracted from theirores and used for many purposes

Section 263 Assessment

11 Name and describe Earthrsquos major regions

12 Why does the composition of Earthrsquos crust differso greatly from that of its core

13 What is a mineral List some common mineralsthat exist as metallic oxides as carbonates and as sulfides

14 Thinking Critically Nitrogen makes up 0002of Earthrsquos lithosphere but 78 of the atmosphereHow can you explain this difference

15 Applying Concepts What is an ore Under whatconditions would a mineral not be an ore

Galena is a major ore of lead The material that holdsa stained glass window together contains leadc

Mercury is extracted from cinnabar and used in instru-ments that measure blood pressure and temperaturea Bauxite is the major ore of aluminum a metal

with many usesb

Iron can be extracted from many ores includinghematite Because iron is so strong it is used as theframework for large buildings

d

The metals in a mineral cannot always be extracted from the mineral in aneconomically feasible way Sometimes the concentration of the mineral inthe surrounding rock is too low for the mineral to be mined at a reasonablecost The cost of energy needed to mine extract or purify the metal also maybe too high If the metal can be extracted and purified from a mineral at areasonable profit the mineral is called an ore Several ores and the metalsextracted from them are shown in Figure 26-17

chemistrymccomself_check_quiz

840-869 Ch26-866418 41204 641 PM Page 857

CO2Cellular respiration

Limestonecliff

Dissolved CO2

Photosynthesis

Fossilfuels

858 Chapter 26 Chemistry in the Environment

Section 264 Cycles in the Environment

Objectivesbull Trace the pathways of car-

bon and nitrogen throughthe environment

bull Compare and contrast thegreenhouse effect andglobal warming

Vocabularygreenhouse effectglobal warmingnitrogen fixation

Did you know that the atoms of carbon nitrogen and other elements in yourbody are far older than you In fact theyrsquove been around since before lifebegan on Earth The amount of matter on Earth never changes As a result itmust be recycled constantly You learned about the water cycle earlier in thechapter A number of elements cycle through the environment in similar dis-tinct pathways

The Carbon CycleCarbon dioxide (CO2) constitutes only about 003 of Earthrsquos atmosphereHowever it plays a vital role in maintaining life on Earth There is a fine bal-ance in nature between the processes that produce carbon dioxide and thosethat consume it You have learned that green plants algae and some bacte-ria remove carbon dioxide from the atmosphere during photosynthesis Doyou recall what products are formed during this process Photosynthesis pro-duces carbon-containing carbohydrates which animals ingest when they eatplants and other animals Both plants and animals convert the carbohydratesto CO2 which is released into the atmosphere as a waste product of cellularrespiration Once in the atmosphere the CO2 can be used again by plants

Figure 26-18 shows the carbon cycle Carbon dioxide in the atmosphereis in equilibrium with an enormous quantity that is dissolved in oceans lakesand streams Some of this dissolved CO2 was once in the form of calciumcarbonate (CaCO3) the main component of the shells of ancient marine ani-mals The shells were eventually converted into limestone which representsa large store of carbon on Earth When the limestone was exposed to theatmosphere by receding seas it weathered under the action of rain and sur-face water producing carbon dioxide Some of this CO2 was released into theatmosphere This process continues todayFigure 26-18

Carbon cycles in and out of theenvironment through manypathways

IampE 1d

840-869_Ch26-866418 5906 415 PM Page 858

Carbon dioxide also enters the atmosphere when plants and animals decom-pose Recall from Chapter 22 that the remains of ancient plants and animalswere converted under pressure to fossil fuels When fossil fuels are burnedthe carbon is converted to CO2 As yoursquoll learn the burning of fossil fuelsand other human activities may be disrupting the balance of the carbon cycle

Upsetting the balance To understand the effect of human activities on thecarbon cycle it is first necessary to explore a phenomenon known as thegreenhouse effect The greenhouse effect is the natural warming of Earthrsquossurface that occurs when certain gases in the atmosphere absorb some of thesolar energy that is converted to heat and reflected from Earthrsquos surface AsFigure 26-19 shows the process works much like a greenhouse Sunlightreaches Earth and is converted to heat but the heat canrsquot easily escape throughthe greenhouse gases to travel back into space Instead the heat is absorbedby molecules of greenhouse gases and transferred to the atmosphere whereit warms Earthrsquos surface Without the greenhouse effect the surface of ourplanet would be too cold to sustain life as we know it

Carbon dioxide is a major greenhouse gas Most CO2 occurs naturally Butwhen we burn fossil fuels huge quantities of CO2mdashmore than 5 billion met-ric tons a yearmdashare added to the atmosphere Moreover the amount of CO2that is removed from the atmosphere by photosynthesis is being reduced bythe continued destruction of vast forested areas particularly rain forests Asa result of these activities the level of atmospheric CO2 has been increasingslowly over the past 200 years Diagram a in the problem-solving LAB onthe next page shows that the rate of increase is accelerating

Increases in greenhouse gases such as CO2 lead to corresponding increasesin the greenhouse effect Some scientists have predicted that these increaseswill cause global temperatures to rise a condition known as global warming

Scientists donrsquot agree on the causes or the consequences of global warm-ing but they do know that average global temperatures are increasingslightlymdashabout 05degC over the past 100 years At present levels of fossil-fuelconsumption some scientists predict that global temperatures could increaseby as much as 03degC each decade during the twenty-first century Althoughthis may seem like a small amount it may result in the largest increase inglobal temperatures since the end of the last ice age

264 Cycles in the Environment 859

Reflected heat lost toouter space

Earths atmosphere

Light fromthe Sun

Reflected heat absorbedby atmosphere

Figure 26-19

About 25 of the sunlight thatstrikes Earthrsquos atmosphere isreflected back into space Mostof the remaining 75 isabsorbed by atmospheric gasesand Earth in the form of heat

840-869 Ch26-866418 41204 641 PM Page 859

While scientists continue to study and debate the issue of global warmingmost concede that it has the potential to change Earthrsquos climate and that tam-pering with the climate could be dangerous Thus a drastic reduction in theuse of fossil fuels is considered by many to be essential to slow and eventu-ally stop global warming For this reason alternative energy resources suchas solar power are now important areas of scientific research You can learnabout one type of alternative energy sourcemdashsolar pondsmdashby doing theCHEMLAB at the end of the chapter

The Nitrogen CycleNitrogen is an essential component of many substances that make up livingorganisms It is a key element in protein molecules nucleic acids and ATPLike other elements the supply of nitrogen on Earth is fixed It must be recy-cled as shown in Figure 26-20 Follow the diagram as you read about thenitrogen cycle

Although nitrogen makes up 78 of Earthrsquos atmosphere most living thingscanrsquot use nitrogen in its gaseous state It must be fixed or converted to a use-ful form by a process called nitrogen fixation

860 Chapter 26 Chemistry in the Environment

problem-solving LAB

Global warming fact or fictionDrawing Conclusions Environmental issuesaffecting the entire planet usually involve somany variables that it is often difficult to pinpointa primary source of the problem Conflicting datafrom many experiments often divide the views ofthose in the scientific community The effect ofcarbon dioxide emissions on global warming hasbeen a particularly controversial issue becauseefforts to reduce carbon dioxide emissions mayrequire humans to make dramatic changes intheir lifestyles and could exact enormousdemands on the world economy

AnalysisEach graph shows an indicator that is being usedto monitor global warming Diagram a shows theatmospheric CO2 concentration for the past millen-nium Diagram b shows the average temperature

change of Earthrsquos surface during the past millen-nium Diagram c shows the average temperaturechange of Earthrsquos atmosphere since 1978

Thinking Critically1 Before the twenty-first century what was the

trend (the dotted line in diagram b) for Earthrsquosaverage surface temperature What does thistrend predict for the average surface tempera-ture in the year 2000

2 What do the atmospheric temperature datasuggest How does this compare to the surfacedata What could cause this discrepancy

3 In comparing these three graphs how strong isthe relationship between global warming andthe concentration of carbon dioxide in theatmosphere Is there a reason for concernWhat other environmental influences wouldyou consider to help answer this question

800 1200 1600 2000Year

260

280

300

340

360

380

320

CO2

conc

entr

atio

n p

pm (b

y vo

lum

e)

a

04

02

0

02

04

06

Year1978 1984 1990 1996

Tem

per

atu

re c

han

ge

(C

)

Balloon-based temperaturesSatellite-based temperatures

cYear

Tem

per

atu

re c

han

ge

(C

)

10

05

0

10

05

800 1200 1600 2000b

IampE 1d

840-869_Ch26-866418 5906 415 PM Page 860

Two primary routes for nitrogen fixation exist in nature In the atmospherelightning combines N2 and O2 to form NO

N2(g) O2(g) 0 2NO(g)

Once NO is formed it is oxidized to NO2

2NO(g) O2(g) 0 2NO2(g)

In the atmosphere rain converts NO2 to HNO3 which then falls to Earth asaqueous NO3

2NO2(g) H2O(l) 0 HNO2(aq) HNO3(aq)

Nitrogen fixation is also accomplished by nitrogen-fixing bacteria whichlive in the soil and on the roots of certain legumes such as peas beanspeanuts and alfalfa In this process N2 is first reduced to NH3 and NH4

then oxidized to NO3

Plants absorb nitrate ions through their roots and use them to synthesize

complex nitrogen compounds Because animals canrsquot synthesize these com-plex molecules they must get them by eating plants or other animals Nitrogencompounds that are unused by the animalsrsquo bodies are excreted as waste Soilmicroorganisms convert this waste to N2 and nitrogen is recycled back intothe environment

264 Cycles in the Environment 861

Figure 26-20

In the nitrogen cycle atmo-spheric nitrogen gas is convertedto nitrates which plants use tomake biological compoundsEventually nitrates are con-verted back to nitrogen gas

N2

Nitrates

Lightning

Bacteria in soil and on roots

Animal wastes

Death

Decaybacteria

Plants

Section 264 Assessment

16 Diagram and label the important parts of the carbon cycle

17 Describe the two primary routes of nitrogen fixation

18 What two cellular processes are important parts of the carbon cycle

19 Thinking Critically Levels of CO2 a majorgreenhouse gas fluctuate on a seasonal basisRecalling how carbon is cycled through the envi-ronment explain the seasonal fluctuations of CO2

20 Applying Concepts How might the greenhouseeffect lead to global warming

chemistrymccomself_check_quiz

840-869 Ch26-866418 41204 642 PM Page 861

862 Chapter 26 Chemistry in the Environment

Pre-Lab

1 Read the entire CHEMLAB

2 Prepare all written materials that you will take intothe laboratory Include safety precautions and pro-cedure notes

3 Water is transparent to visible light but opaque toinfrared radiation How do you think these proper-ties will affect your solar pond model

4 If you used only tap water in your model convec-tion currents would bring warmer less dense waterfrom the bottom to the surface Do you think thiswill happen with your solar pond model Explainyour answer

5 Predict which of the two layers of the model willhave the higher final temperature Explain yourprediction

Procedure

1 Prepare a saturated table salt (NaCl) solution byheating 100 mL of tap water in a beaker on a hotplate When the water is boiling slowly addenough table salt to saturate the solution while stir-ring with a stirring rod Remove the beaker fromthe hot plate with beaker tongs and allow the solu-tion to cool slowly overnight

2 The next day prepare the solar pond model Placethe black plastic dish on the lab bench where youwant to run the experiment Use a small piece ofwaterproof tape to attach one of the temperatureprobes to the bottom of the black plastic dish Plugthis probe into Channel 1 of the CBL SystemSlowly pour the 100 mL of saturated salt solutioninto the dish

3 Carefully add about 100 mL of tap water on top ofthe saturated salt-water layer in the dish Use carenot to mix the two layers Suspend the end of thesecond temperature probe in the tap-water layerand plug it into Channel 2 of the CBL System

Safety Precautions

bull The light bulb will become hot when it is turned onbull Do not touch the hot plate while it is on

ProblemBuild a small-scale modelof a solar pond and testhow it traps and storessolar energy

Objectivesbull Construct a small-scale

solar pond using simplematerials

bull Collect temperaturedata as the solar pondmodel heats and cools

bull Hypothesize as to whya solar pond is able totrap and store energy

MaterialsCBL Systemgraphing calculatorChemBio programlink-to-link cabletemperature probes (2)150-watt light bulbsocket and clamp for

bulbblack plastic frozen-

dinner dish

waterproof tapetable salthot platestirring rod250-mL beakerbeaker tongsTI-Graph Link (optional)ring stand and clamp250-mL graduated

cylinder

Solar PondIf you made a list of popular types of alternative energy sources

solar energy probably would be near the top Of course the energywe use from all sources ultimately originates from the Sun It wouldseem that solar energy would be the easiest to use The problem ishow to store solar energy when the Sun is not shining In this experi-ment you will investigate one method that could be used to trapand store solar energy

CHEMLAB CBL26

IampE 1a Select and use appropriate tools and technology(such as computer-linked probesspreadsheets and graphingcalculators) to perform testscollect data analyze relationshipsand display data Also coversIampE 1b

840-869_Ch26-866418 5906 415 PM Page 862

CHEMLAB 863

4 Connect the graphing calculator to the CBLSystem using the link cable Turn on both unitsRun the ChemBio program Choose 1SET UPPROBES from MAIN MENU Choose 2 probesUnder SELECT PROBE choose 1TEMPERA-TURE Enter 1 for Channel This is for the probeat the bottom of the salt water Under SELECTPROBE choose 1 TEMPERATURE Enter 2 forChannel This is for the probe in the tap-waterlayer

5 Under MAIN MENU choose 2 COLLECTDATA Choose 2 TIME GRAPH For timebetween samples in seconds choose 30 For num-ber of samples choose 60 This will allow theexperiment to run for 30 minutes Set the calcula-tor to use this time setup Input the followingYmin = 0 Ymax = 30 Yscl = 1 Do not start col-lecting data yet

6 Position the 150-watt light bulb about 15 to 20 cmover the top of the solar pond model Turn on thelight Press ENTER on the calculator to begin col-lecting data After about 6 to 8 minutes turn offthe light bulb and move it away from the solarpond model Do not disturb the experiment untilthe calculator is finished with its 30 minute run

Cleanup and Disposal

Rinse the salt solution off the temperature probes

Analyze and Conclude

1 Graphing Data Make a copy of the graphfrom the graphing calculator If you have TI-Graph Link and a computer do a screen

print

2 Interpreting Graphs Describe the shape of eachcurve in the graph of time versus temperaturebefore and after the light bulb was turned offExplain the significance of the difference

3 Comparing and Contrasting Which layer ofyour solar pond model did the best job of trappingand storing heat

4 Applying Concepts Why does the graph oftime versus temperature decrease more rapidly nearthe surface when the light bulb is turned off

5 Forming a Hypothesis Make a hypothesis toexplain what is happening in your model

6 Designing an Experiment How would you testyour hypothesis

7 How might your results havebeen different if you had used a white dish by mis-take instead of a black dish Explain

Real-World Chemistry

1 Water in a lake rises to the surface when heatedand sinks to the bottom when cooled in a processcalled convection Compare and contrast the den-sity of the water as it rises with the density of thewater as it sinks

2 The El Paso Solar Pond was the first in the worldto successfully use solar pond technology to storeand supply heat for industrial processes It wasbuilt with three main layers a top layer that con-tains little salt a middle layer with a salt contentthat increases with depth and a very salty bottomlayer that stores the heat Which layer has thegreatest density The least density Why doesnrsquotthe storage layer in the El Paso Solar Pond cool byconvection

Error Analysis

CHAPTER 26 CHEMLAB

840-869 Ch26-828378 06292001 0900 AM Page 863

1 Predicting Would you expect a water sof-tener to be effective in removing materialssuch as sugar alcohol grease and oilExplain your answer

2 Using Resources Find information aboutwater softening processes that use ions otherthan sodium ions Report your findings to theclass

Water SoftenerWater that contains substantial amounts of dissolvedcalcium and magnesium salts is called hard waterWater acquires these salts when it passes through soiland rocks that contain calcium and magnesium carbon-ates While these salts are not toxic they react withsoaps and detergents to form an insoluble scum onsinks bathtubs and showers When clothes are washedin hard water some of the insoluble material adheresto the clothes and alters the way they feel A devicecalled a water softener can solve the hard-water prob-lem by removing the excess calcium and magnesiumions

How It Works

864 Chapter 26 Chemistry in the Environment

Ion exchangeresin

Softening process

Softened watercontaining sodiumsalts flows to faucets

Hard water flows over an ion exchangecolumn containing pellets coated with sodium ions

Because sodium is morereactive than calcium sodium and calcium ions exchange places

Sodium ions attach to the resin and the resin releasestrapped calcium ions

Calcium ions andbrine solution flowto the sewer

When the sodium ions on the resin are used up they are replaced by flowing a brine solution through the ion exchange resin

Recharge process

Ca2

Na

Na

Na

Na

Na

Na

Na

Na

Na Ca2Ca2

Ca2

Ca2

Ca2

Na

Na

Ca2

Ca2

Ca2

Ca2

1

2

3

4

5

6

840-869 Ch26-866418 41204 643 PM Page 864

1 Predicting Would you expect a water sof-tener to be effective in removing materialssuch as sugar alcohol grease and oilExplain your answer

2 Using Resources Find information aboutwater softening processes that use ions otherthan sodium ions Report your findings to theclass

Water SoftenerWater that contains substantial amounts of dissolvedcalcium and magnesium salts is called hard waterWater acquires these salts when it passes through soiland rocks that contain calcium and magnesium carbon-ates While these salts are not toxic they react withsoaps and detergents to form an insoluble scum onsinks bathtubs and showers When clothes are washedin hard water some of the insoluble material adheresto the clothes and alters the way they feel A devicecalled a water softener can solve the hard-water prob-lem by removing the excess calcium and magnesiumions

How It Works

864 Chapter 26 Chemistry in the Environment

Ion exchangeresin

Softening process

Softened watercontaining sodiumsalts flows to faucets

Hard water flows over an ion exchangecolumn containing pellets coated with sodium ions

Because sodium is morereactive than calcium sodium and calcium ions exchange places

Sodium ions attach to the resin and the resin releasestrapped calcium ions

Calcium ions andbrine solution flowto the sewer

When the sodium ions on the resin are used up they are replaced by flowing a brine solution through the ion exchange resin

Recharge process

Ca2

Na

Na

Na

Na

Na

Na

Na

Na

Na Ca2Ca2

Ca2

Ca2

Ca2

Na

Na

Ca2

Ca2

Ca2

Ca2

1

2

3

4

5

6

840-869 Ch26-866418 41204 643 PM Page 864

Study Guide 865

CHAPTER STUDY GUIDE26

Vocabulary

Summary261 Earthrsquos Atmospherebull Earthrsquos atmosphere is divided into the troposphere

stratosphere mesosphere thermosphere and exo-sphere The layers vary according to altitude andtemperature

bull Nitrogen and oxygen make up the majority of theatmospheric gases

bull Photodissociation and photoionization are importantprocesses that absorb high-energy ultraviolet radia-tion in the upper atmosphere

bull The ozone layer in the stratosphere forms a protec-tive barrier against harmful high-energy ultravioletradiation Levels of ozone have been depleted bychemical reactions with CFCs in the upper atmo-sphere above the North and South Poles

bull Photochemical smog is a major pollutant in manyurban centers and is formed from chemicals that areproduced principally by internal combustionengines

bull Emissions of SO2 from the burning of fossil fuelshave led to the production of acid rain

262 Earthrsquos Waterbull Water is continuously recycled in the environment

by the processes of evaporation condensation andprecipitation

bull Earth has massive oceans that contain large quantitiesof dissolved salts Salinity is a measure of the massof these dissolved salts

bull Salinity is expressed as grams of salt per kilogramof seawater

bull Reverse osmosis can be used to desalinate oceanwater and make it fit for human use

bull Freshwater is a precious natural resource Municipalwater supplies must be treated to ensure that theyare safe to use Sewage treatment plants processwater that has been used so that it can be returnedsafely to the environment

263 Earthrsquos Crustbull Earth is divided into a core mantle and crust The

core is further divided into an inner and outer coreThe crust is where living things reside The crustcan be divided further into the solid lithosphere liq-uid hydrosphere and gaseous atmosphere

bull The lithosphere contains a large number of ele-ments Most of these occur as minerals

bull Minerals are solid inorganic compounds found innature They have distinct crystalline structures andchemical compositions Minerals of various ele-ments are found in the lithosphere mainly as oxidescarbonates and sulfides

bull An ore is a substance commonly a mineral fromwhich the metal it contains can be extracted andpurified at a reasonable profit

264 Cycles in the Environmentbull Carbon dioxide one of the principal components in

the carbon cycle is taken up by plants during photo-synthesis and given off by plants and animals as aproduct of cellular respiration

bull The CO2 in the atmosphere is a major cause of thegreenhouse effect Increases in greenhouse gasesmay cause global warming Scientists do not agreeon the causes or consequences of global warming

bull Nitrogen gas is converted into biologically usefulnitrates by nitrogen fixation Nitrogen is returned tothe atmosphere by a cycle in the environment

bull atmosphere (p 841)bull desalination (p 851)bull global warming (p 859)bull greenhouse effect (p 859)

bull hydrosphere (p 850)bull lithosphere (p 855)bull nitrogen fixation (p 860)

bull salinity (p 851)bull stratosphere (p 842)bull troposphere (p 842)

chemistrymccomvocabulary_puzzlemaker

840-869 Ch26-866418 41204 644 PM Page 865

866 Chapter 26 Chemistry in the Environment

Go to the Chemistry Web site at chemistrymccom for additional Chapter 26 Assessment

Concept Mapping21 Complete the concept map using the following terms

roots of legumes nitrogen oxides soil bacteria nitro-gen fixation nitrogen gas lightning

Mastering Concepts22 What is ozone (261)

23 Why is smog more correctly termed photochemicalsmog (261)

24 What kind of radiation causes molecules to be ionizedin the upper atmosphere (261)

25 What is the basis for the division of the atmosphereinto layers (261)

26 How do chlorine atoms act as a catalyst for ozonedecomposition (261)

27 What steps can be taken to reduce sulfur dioxide emissions into the environment (261)

28 What provides the energy for the water cycle (262)

29 What are the two most abundant ions in seawater (262)

30 Why does the chemical composition of the oceansremain constant over time (262)

31 What is the function of a semipermeable membrane inreverse-osmosis desalination (262)

32 What are the four most abundant elements in the litho-sphere (263)

33 How does the position of a metal in the periodic tabledetermine whether the element exists in nature as anoxide a carbonate or a sulfide (263)

34 During what process is CO2 from the troposphere con-verted into carbohydrates (264)

35 What is the greenhouse effect (264)

36 In what two ways is nitrogen fixed (264)

Mastering ProblemsCalculations About the Atmosphere (261)37 How many liters of nitrogen are there in a 253-liter

sample of air

38 Identify the layer of the atmosphere that is representedby the following graph of temperature versus altitude

39 Assuming a temperature of 200degC and an atmo-

spheric pressure of 729 mm Hg calculate the numberof particles of carbon dioxide gas in one cubic meterof dry air

Calculations About the Hydrosphere (262)40 Water must have a salt concentration less than 500

ppm by mass to be fit for human use Assuming thatthe salt is all NaCl what is the molarity of this con-centration

41 Construct a circle graph to illustrate the amount ofwater used for various purposes by an average personeach day

42 What is the molarity of NaCl in a saltwater solutionwith a salinity of 6 gkg Assume that the only salt inthe solution is NaCl and that the solution has a densityof 10 gmL

CHAPTER ASSESSMENTCHAPTER ASSESSMENT26

convert

to

by

2 3

1and

in

and

4

5

6

7

Tem

per

atu

re (

C)

0 10 20 30 40 50605040302010

010

Altitude (km)

chemistrymccomchapter_test

840-869 Ch26-866418 41204 644 PM Page 866

Assessment 867

CHAPTER 26 ASSESSMENT

Calculations About the Lithosphere (263)43 Table 26-5 shows the mass percent of iron in the uni-

verse in Earth as a whole and in various layers ofEarth Explain the differences in terms of the processthat caused formation of Earth

44 Earthrsquos crust is 087 hydrogen by mass The litho-sphere is only 015 hydrogen Account for this dif-ference

45 What is the mass percent of iron in each of the follow-ing iron minerals FeS2 Fe2O3 Fe3O4 If the iron canbe extracted with equal ease from all three mineralswhich would you use as a source of iron

Calculations About Natural Cycles (264)46 About 30 million tons of HNO3 are produced each

year when lightning fixes nitrogen in the atmosphereWhat is the mass percent of nitrogen in HNO3 Howmuch nitrogen does 30 million tons of HNO3 contain

47 If a plant consumes 50 g carbon dioxide in the processof photosynthesis during a given time period howmany liters of oxygen would it produce at 1 atm and25degC The balanced equation for photosynthesis is

6CO2 6H2O 0 C6H12O6 6O2

Mixed ReviewSharpen your problem-solving skills by answering thefollowing

48 Why must living organisms rely on nitrogen fixationfor their source of nitrogen

49 What is the major cause of the greenhouse effect

50 What is the purpose of adding CaO and Al2(SO4)3 inmunicipal water treatment

51 Write balanced equations for the destruction of ozoneby CFCs

52 Why does nitrogen cause freshwater pollution

53 In what form do plants use nitrogen In what biologi-cal molecules is nitrogen found

54 Write balanced equations showing the formation ofacid rain

55 Using balanced equations compare photoionizationand photodissociation of an oxygen molecule in theupper atmosphere

56 What two elements would you expect to be mostabundant in Earthrsquos hydrosphere Why

Thinking Critically57 Recognizing Cause and Effect Environmental

chemistry has a number of cause-and-effect relation-ships Describe these relationships in a) the formationof acid rain b) ozone depletion

58 Interpreting Data Why are photodissociation andphotoionization reactions more common in the upperatmosphere than in the lower atmosphere

59 Applying Concepts Why do oxygen atoms exist fora longer period of time in the upper atmosphere thanin the stratosphere

Writing in Chemistry60 Write a short story tracing the path that a carbon atom

in a carbon dioxide molecule might follow Assumethat the CO2 molecule is in the troposphere

61 Prepare an instruction sheet for a portable reverse-osmosis desalination apparatus that can be used forcamping Research and include information on howefficient the apparatus is how much pressure must beused and how much drinking water can be producedin a given amount of time

62 Metallurgy is the study of extracting and purifyingmetals from their ores Conduct research to learn howiron is extracted from its ores how it is purified andhow steel is made Make a poster showing the steps inthese processes and include a short summary of eachstep and the chemical equations involved

Abundance of Iron in Various Locations

Location Percent by mass

Whole universe 019

Whole Earth 346

47

Mantle 133

Core 886

Table 26-5

Atmosphere LithosphereHydrosphere

840-869 Ch26-828378 06292001 0901 AM Page 867

868 Chapter 26 Chemistry in the Environment

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

63 Why is it necessary to perform repeated experimentsin order to support a hypothesis (Chapter 1)

64 A 4901-g sample of lead displaces 45 mL of waterWhat is the density of lead (Chapter 2)

65 Are the following physical or chemical changes(Chapter 3)

a water boilsb charcoal burnsc sugar dissolves in tead potassium reacts with watere an ice cube melts

66 The isotope of carbon that is used to date artifacts con-tains six protons and eight neutrons What is theatomic number of this isotope How many electronsdoes it have What is its mass number (Chapter 4)

67 Table 26-6 shows abundance of the two isotopes ofsilver found in nature The more abundant isotope hasan atomic mass of a little less than 107 but the aver-age atomic mass of silver on the periodic table isabout 1079 Explain why it is higher (Chapter 5)

68 For each of the following elements tell how manyelectrons are in each energy level and write the elec-tron dot structure (Chapter 6)

a Ar d Alb Mg e Fc N f S

69 Use the periodic table to separate these 12 elementsinto six pairs of elements having similar properties(Chapter 7)

Ca K Ga P Si Rb B Sr Sn Cl Bi Br

70 Write the formula for the binary ionic compound thatforms from each pair of elements (Chapter 8)

a manganese(III) and iodineb calcium and oxygenc aluminum and fluorined potassium and sulfur

e zinc and brominef lead(IV) and oxygen

71 Name the following molecular compounds (Chapter 9)

a NOb IBrc N2O4d COe SiO2f ClF3

72 Classify each of the following reactions (Chapter 10)

a N2O4(g) 0 2NO2(g)b 2Fe(s) O2(g) 0 2FeO(s)c 2Al(s) 3Cl2(g) 0 2AlCl3(s)d BaCl2(aq) Na2SO4(aq) 0 BaSO4(s) 2NaCl(aq)e Mg(s) CuSO4(aq) 0 Cu(s) MgSO4(aq)

73 Calculate the total number of ions in 108 g of magne-sium bromide (Chapter 11)

74 Calculate the mass of AgCl formed when 856 g of sil-ver sulfide (Ag2S) react with excess hydrochloric acid(HCl) (Chapter 12)

75 Why will water in a flask begin to boil at room temper-ature as air is pumped out of the flask (Chapter 13)

76 How many moles are contained in a 244-L sample ofgas at 250degC and 202 kPa (Chapter 14)

77 How would you prepare 50 L of a 15M solution ofglucose (C6H12O6) (Chapter 15)

78 Compare the energy of the reactants and the productsfor a reaction in which H is negative Is the reactionendothermic or exothermic (Chapter 16)

79 Identify the following hydrocarbons as alkane alkeneor alkyne (Chapter 22)

a 1-hexyneb 3-methyldecanec propened cis-2-butene

80 Water is released in a reaction in which two differentfunctional groups condense to form an ester What two functional groups take part in this reaction(Chapter 23)

81 Name the two functional groups in an amino acid thatbecome linked when a peptide bond is formed(Chapter 24)

82 What element is formed if magnesium-24 is bom-barded with a neutron and then ejects a proton Writethe balanced nuclear equation (Chapter 25)

CHAPTER ASSESSMENT26

Abundance of Silver

Isotope Abundance

Ag-107 518

Ag-109 482

Table 26-6

840-869 Ch26-828378 2702 0908 PM Page 868

Standardized Test Practice 869

Use these questions and the test-taking tip to preparefor your standardized test

1 Photodissociation photoionization and photochemicalsmog are all caused by the reaction of atmosphericgases with high energy

a infrared radiation c cosmic raysb ultraviolet radiation d microwaves

2 What is the most abundant gas in Earthrsquos atmosphere

a O2 c CO2b N2 d H2

3 When high-sulfur coal is burned the following seriesof reactions occurs to produce acid rain

S(s) O2(g) rarr SO2(g)

3SO2(g) O3(g) rarr 3SO3(g)

SO3(g) H2O(l) rarr H2SO4(aq)

A coal is classified as high-sulfur by the United StatesDepartment of Energy if it contains more than 763 gof sulfur per unit A unit is defined as the amount ofcoal needed to produce 10 106 British thermal units(BTUs) of heat If a unit of coal containing 768 g ofsulfur is burned how much sulfuric acid (H2SO4) willbe produced

a 235 103 g c 706 103 gb 408 103 g d 753 104 g

Interpreting Graphs Use the graph to answer questions 4ndash6

4 The nitrogen cycle occurs in the oceans as well as inthe soil Nitrates (NO3

) at the surface of the oceanare almost completely used up by living organisms Asthese organisms die they sink As they sink the nitro-gen compounds inside their bodies are oxidized backto NO3

In very deep waters ocean currents mix the

water and decrease NO3 concentration These

processes explain why the graph shows NO3

concentration

a continuously decreasing with depthb continuously increasing with depthc decreasing and then increasing with depthd increasing and then decreasing with depth

5 Nitrate concentration reaches a maximum at approxi-mately what depth

a 5500 m c 3000 mb 500 m d 1500 m

6 At a depth of 4000 m about how many grams ofNO3

are found in each liter of seawater

a 16 103 g c 35 107 gb 22 103 g d 20 103 g

7 In the water cycle evaporation must be balanced bywhich processes

a condensation and sublimationb ionization and precipitationc precipitation and condensationd dissolution and precipitation

8 Because the denser elements sank to the center ofEarth as the new planet cooled all of the followingelements are relatively rare in Earthrsquos crust EXCEPT

a aluminum c platinumb gold d lead

9 Why do the proportions and amounts of dissolved saltsin the oceans remain almost constant

a the sources from which the ocean receives its saltshave constant compositions

b the rates at which salts are added to and taken fromthe oceans balance each other

c none of the dissolved salts are ever removed fromthe seawater

d living organisms have no use for any of the saltsdissolved in seawater

STANDARDIZED TEST PRACTICECHAPTER 26

If It Looks Too Good To Be True Beware ofanswer choices in multiple-choice questions thatseem ready-made and obvious Remember that onlyone answer choice for each question is correct Therest are made up by the test-makers to distract youThis means that they may look very appealingCheck each answer choice carefully before finallyselecting it

0 2 4 6Depth (km)

0

20

40

60

Nit

rate

(

mo

lL)

chemistrymccomstandardized_test

California Standards Practice

840-869_Ch26-866418 5906 417 PM Page 869

868 Chapter 26 Chemistry in the Environment

Cumulative ReviewRefresh your understanding of previous chapters byanswering the following

63 Why is it necessary to perform repeated experimentsin order to support a hypothesis (Chapter 1)

64 A 4901-g sample of lead displaces 45 mL of waterWhat is the density of lead (Chapter 2)

65 Are the following physical or chemical changes(Chapter 3)

a water boilsb charcoal burnsc sugar dissolves in tead potassium reacts with watere an ice cube melts

66 The isotope of carbon that is used to date artifacts con-tains six protons and eight neutrons What is theatomic number of this isotope How many electronsdoes it have What is its mass number (Chapter 4)

67 Table 26-6 shows abundance of the two isotopes ofsilver found in nature The more abundant isotope hasan atomic mass of a little less than 107 but the aver-age atomic mass of silver on the periodic table isabout 1079 Explain why it is higher (Chapter 5)

68 For each of the following elements tell how manyelectrons are in each energy level and write the elec-tron dot structure (Chapter 6)

a Ar d Alb Mg e Fc N f S

69 Use the periodic table to separate these 12 elementsinto six pairs of elements having similar properties(Chapter 7)

Ca K Ga P Si Rb B Sr Sn Cl Bi Br

70 Write the formula for the binary ionic compound thatforms from each pair of elements (Chapter 8)

a manganese(III) and iodineb calcium and oxygenc aluminum and fluorined potassium and sulfur

e zinc and brominef lead(IV) and oxygen

71 Name the following molecular compounds (Chapter 9)

a NOb IBrc N2O4d COe SiO2f ClF3

72 Classify each of the following reactions (Chapter 10)

a N2O4(g) 0 2NO2(g)b 2Fe(s) O2(g) 0 2FeO(s)c 2Al(s) 3Cl2(g) 0 2AlCl3(s)d BaCl2(aq) Na2SO4(aq) 0 BaSO4(s) 2NaCl(aq)e Mg(s) CuSO4(aq) 0 Cu(s) MgSO4(aq)

73 Calculate the total number of ions in 108 g of magne-sium bromide (Chapter 11)

74 Calculate the mass of AgCl formed when 856 g of sil-ver sulfide (Ag2S) react with excess hydrochloric acid(HCl) (Chapter 12)

75 Why will water in a flask begin to boil at room temper-ature as air is pumped out of the flask (Chapter 13)

76 How many moles are contained in a 244-L sample ofgas at 250degC and 202 kPa (Chapter 14)

77 How would you prepare 50 L of a 15M solution ofglucose (C6H12O6) (Chapter 15)

78 Compare the energy of the reactants and the productsfor a reaction in which H is negative Is the reactionendothermic or exothermic (Chapter 16)

79 Identify the following hydrocarbons as alkane alkeneor alkyne (Chapter 22)

a 1-hexyneb 3-methyldecanec propened cis-2-butene

80 Water is released in a reaction in which two differentfunctional groups condense to form an ester What two functional groups take part in this reaction(Chapter 23)

81 Name the two functional groups in an amino acid thatbecome linked when a peptide bond is formed(Chapter 24)

82 What element is formed if magnesium-24 is bom-barded with a neutron and then ejects a proton Writethe balanced nuclear equation (Chapter 25)

CHAPTER ASSESSMENT26

Abundance of Silver

Isotope Abundance

Ag-107 518

Ag-109 482

Table 26-6

840-869 Ch26-828378 2702 0908 PM Page 868

Standardized Test Practice 869

Use these questions and the test-taking tip to preparefor your standardized test

1 Photodissociation photoionization and photochemicalsmog are all caused by the reaction of atmosphericgases with high energy

a infrared radiation c cosmic raysb ultraviolet radiation d microwaves

2 What is the most abundant gas in Earthrsquos atmosphere

a O2 c CO2b N2 d H2

3 When high-sulfur coal is burned the following seriesof reactions occurs to produce acid rain

S(s) O2(g) rarr SO2(g)

3SO2(g) O3(g) rarr 3SO3(g)

SO3(g) H2O(l) rarr H2SO4(aq)

A coal is classified as high-sulfur by the United StatesDepartment of Energy if it contains more than 763 gof sulfur per unit A unit is defined as the amount ofcoal needed to produce 10 106 British thermal units(BTUs) of heat If a unit of coal containing 768 g ofsulfur is burned how much sulfuric acid (H2SO4) willbe produced

a 235 103 g c 706 103 gb 408 103 g d 753 104 g

Interpreting Graphs Use the graph to answer questions 4ndash6

4 The nitrogen cycle occurs in the oceans as well as inthe soil Nitrates (NO3

) at the surface of the oceanare almost completely used up by living organisms Asthese organisms die they sink As they sink the nitro-gen compounds inside their bodies are oxidized backto NO3

In very deep waters ocean currents mix the

water and decrease NO3 concentration These

processes explain why the graph shows NO3

concentration

a continuously decreasing with depthb continuously increasing with depthc decreasing and then increasing with depthd increasing and then decreasing with depth

5 Nitrate concentration reaches a maximum at approxi-mately what depth

a 5500 m c 3000 mb 500 m d 1500 m

6 At a depth of 4000 m about how many grams ofNO3

are found in each liter of seawater

a 16 103 g c 35 107 gb 22 103 g d 20 103 g

7 In the water cycle evaporation must be balanced bywhich processes

a condensation and sublimationb ionization and precipitationc precipitation and condensationd dissolution and precipitation

8 Because the denser elements sank to the center ofEarth as the new planet cooled all of the followingelements are relatively rare in Earthrsquos crust EXCEPT

a aluminum c platinumb gold d lead

9 Why do the proportions and amounts of dissolved saltsin the oceans remain almost constant

a the sources from which the ocean receives its saltshave constant compositions

b the rates at which salts are added to and taken fromthe oceans balance each other

c none of the dissolved salts are ever removed fromthe seawater

d living organisms have no use for any of the saltsdissolved in seawater

STANDARDIZED TEST PRACTICECHAPTER 26

If It Looks Too Good To Be True Beware ofanswer choices in multiple-choice questions thatseem ready-made and obvious Remember that onlyone answer choice for each question is correct Therest are made up by the test-makers to distract youThis means that they may look very appealingCheck each answer choice carefully before finallyselecting it

0 2 4 6Depth (km)

0

20

40

60

Nit

rate

(

mo

lL)

chemistrymccomstandardized_test

California Standards Practice

840-869_Ch26-866418 5906 417 PM Page 869

Standardized Test Practice 869

Use these questions and the test-taking tip to preparefor your standardized test

1 Photodissociation photoionization and photochemicalsmog are all caused by the reaction of atmosphericgases with high energy

a infrared radiation c cosmic raysb ultraviolet radiation d microwaves

2 What is the most abundant gas in Earthrsquos atmosphere

a O2 c CO2b N2 d H2

3 When high-sulfur coal is burned the following seriesof reactions occurs to produce acid rain

S(s) O2(g) rarr SO2(g)

3SO2(g) O3(g) rarr 3SO3(g)

SO3(g) H2O(l) rarr H2SO4(aq)

A coal is classified as high-sulfur by the United StatesDepartment of Energy if it contains more than 763 gof sulfur per unit A unit is defined as the amount ofcoal needed to produce 10 106 British thermal units(BTUs) of heat If a unit of coal containing 768 g ofsulfur is burned how much sulfuric acid (H2SO4) willbe produced

a 235 103 g c 706 103 gb 408 103 g d 753 104 g

Interpreting Graphs Use the graph to answer questions 4ndash6

4 The nitrogen cycle occurs in the oceans as well as inthe soil Nitrates (NO3

) at the surface of the oceanare almost completely used up by living organisms Asthese organisms die they sink As they sink the nitro-gen compounds inside their bodies are oxidized backto NO3

In very deep waters ocean currents mix the

water and decrease NO3 concentration These

processes explain why the graph shows NO3

concentration

a continuously decreasing with depthb continuously increasing with depthc decreasing and then increasing with depthd increasing and then decreasing with depth

5 Nitrate concentration reaches a maximum at approxi-mately what depth

a 5500 m c 3000 mb 500 m d 1500 m

6 At a depth of 4000 m about how many grams ofNO3

are found in each liter of seawater

a 16 103 g c 35 107 gb 22 103 g d 20 103 g

7 In the water cycle evaporation must be balanced bywhich processes

a condensation and sublimationb ionization and precipitationc precipitation and condensationd dissolution and precipitation

8 Because the denser elements sank to the center ofEarth as the new planet cooled all of the followingelements are relatively rare in Earthrsquos crust EXCEPT

a aluminum c platinumb gold d lead

9 Why do the proportions and amounts of dissolved saltsin the oceans remain almost constant

a the sources from which the ocean receives its saltshave constant compositions

b the rates at which salts are added to and taken fromthe oceans balance each other

c none of the dissolved salts are ever removed fromthe seawater

d living organisms have no use for any of the saltsdissolved in seawater

STANDARDIZED TEST PRACTICECHAPTER 26

If It Looks Too Good To Be True Beware ofanswer choices in multiple-choice questions thatseem ready-made and obvious Remember that onlyone answer choice for each question is correct Therest are made up by the test-makers to distract youThis means that they may look very appealingCheck each answer choice carefully before finallyselecting it

0 2 4 6Depth (km)

0

20

40

60

Nit

rate

(

mo

lL)

chemistrymccomstandardized_test

California Standards Practice

840-869_Ch26-866418 5906 417 PM Page 869