CANNON AFB COVER SHEET - Index of

524 File: 17G J.P.

CANNON AFB NEW MEXICO

ADMINISTRATIVE RECORD COVER SHEET

AR File Number________ i

r ;i iL4

FINAL WORK PLAN

File:

J.P. I, 21/

SITE INSPECTION (SI) FOR

AREA OF CONCERN - D CANNON AIR FORCE BASE

NEW MEXICO

VOLUME II OF II APPENDICES B - F

CONTRACT NO. DACW4S-94-D-0049 DELIVERY ORDER NO. 0004

AUGUST, 1996

PREPARED FOR:

U.S. ARMY CORPS OF ENGINEERS OMAHA DISTRICT OMAHA, NEBRASKA

ATTN: MR. DOUG MELLEMA

PREPARED BY:

IMS, P.C. ENVIRONMENTAL & ENGINEERING 115 METRO PARK ROCHESTER, NY 14623 TEL: (716) 427-0690

2

FINAL WORK PLAN

SITE INSPECTION (SI) FOR

AREA OF CONCERN - D CANNON AIR FORCE BASE

NEW MEXICO

VOLUME II OF II APPENDICES B - F

CONTRACT NO. DACW4S-94-D-0049 DELIVERY ORDER NO. 0004

AUGUST, 1996

PREPARED FOR:

U.S. ARMY CORPS OF ENGINEERS OMAHA DISTRICT OMAHA, NEBRASKA

ATTN: MR. DOUG MELLEMA

PREPARED BY:

¡MS, P.C. ENVIRONMENTAL & ENGINEERING 115 METRO PARK ROCHESTER, NY 14623 TEL: (716) 427-0690

APPENDIX B

APPENDIX C

APPENDIX D

APPENDIX E

APPENDIX F

5'4 3

TABLE OF CONTENTS

VOLUME II OF II

QUALITY ASSURANCE PLAN, QUANTERRA, INC.

QUALITY ASSURANCE PLAN, O'BRIEN & GERE

MATERIAL SAFETY DATA SHEETS - ASBESTOS

SAFETY GUIDELINES FOR DRILLING INTO SOIL AND ROCKS

COLD STRESS

Cannon AFB - Site AOC-D Draft Work Plan 2/28196

5J4

LIST OF ACRONYMS AND ABBREVIATIONS

ACC Air Combat Command

- ACM Asbestos Containing Material

ACGIH American Conference of Governmental Industrial Hygienists

AFB Air Force Base

AIT-lA American Industrial Hygiene Association

AOC Area of Concern

APR Air Purifying Respirator

ASTM American Society of Testing and Materials

- BEC Base Environmental Coordinator

°C Degree Celsius

CAT Certified Asbestos Inspector

CDLT Contract Data Loading Tool

CERCLA Comprehensive Environmental Response, Compensation and Liability Act, I 9O

CFR Code of Federal Regulations

CIH Certified Industrial Hygienist

CLP Contract Laboratory Protocol

COC Chain-of-Custody

CPR Cardiovascular Pulmonary Resuscitation

DQO Data Quality Objective

DQCR Data Quality Control Report

EKG Electrocardiogram

Cannon AFB Site AOC-D Draft Work Plan ji 2/28196

5


Degrcc Fahrenheit

FSP Field Sampling Plan

GCIMS Gas Chromatograph/Mass Spectrometer

gpm Gallons per minute

HEPA High Efficiency Particulate Air

HSA Hollow Stem Auger

HQ Headquarters

HTW Hazardous and Toxic Waste

ID Inside diameter

IDL Instrument Detection Limit

IDLH Immediately Dangerous to Life or Health

IDW Investigation Derived Waste

TDWMP Investigation Derived Waste Management Plan

IMS IMS, P.C. Environmental & Engineering

IRP Installation Restoration Program

IRPIMS Installation Restoration Program Information Management System

LCS Laboratory Control Sample

LIMS Laboratory Information Management System

MCE Mixed Cellulose Ester

MDL Method Detection Limit

MRD Missouri River Division

Cannon AFB Site AOC-D Draft Work Plan 'lt 2/28196

t- J

G


MS Matrix Spike

.- MSD Matrix Spike Duplicate

MSDS Material Safety Data Sheet

MSHA Mining Safety and Health Administration

MSL Mean Sea Level

- NIOSH National Institute for Occupational Safety and Health

NIST National Institute of Standards and Technology

NRR Noise Reduction Rating

- OB&G O'Brien & Gere

OEW Ordnance and Explosive Waste

OSHA Occupational Safety and Health Administration

OVA Organic Vapor Analyzer

PARCC Precision, Accuracy, Representativeness, Completeness, Comparability

PCM Phase Contrast Microscopy

PEL Permissible Exposure Limit

PhD Photoionization Detector

PPE Personal Protective Equipment

PAH Polynuclear Aromatic Hydrocarbon

PVC Polyvinyl Chloride

QA Quality Assurance

QAP Quality Assurance Plan

Cannon AFB Site AOC-D Draft Work Plan IV 2128/96

5L:4


QAPP Quality Assurance Project Plan

QC Quality Control

QCSR Quality Control Summary Report

REL Recommended Exposure Limit

RPD Relative Percent Difference

RRF Relative Response Factor

SB Soil Boring

SDG Sample Delivery Group

SI Site Inspection

SOP Standard Operating Procedure

SSHP Site Safety and Health Plan

STEL Short Term Exposure Limit

SVOC Semivolatile Organic Compound

TAL Target Analyte List

TCL Target Compound List

TFW Tactical Fighter Wing

TLV Threshold Limit Value

TM Technical Manager

TRPH Total Recoverable Petroleum Hydrocarbons

TWA Time Weighted Average

USACE U.S. Army Corps of Engineers

Cannon AFB - Site AOC-D Draft Work Plan y 2/2g196

54 k


USEPA U.S. Environmental Protection Agency

UXO Unexploded Ordnance

W-C Woodward-Clyde

VOC Volatile Organic Compounds

Cannon AFB - Site AOCI) Draft Work Plan Vi 2/28/96

5.

Appendix Tab

Kevin M Bull Quality Assurance Manager

Quanrerra Incorpora ted 5910 Breckenridge Parkway, Suite H - Tampa, Florida 33610

813 621-0784 Telephone 813 623-6021 Fax

May 28, 1996

IMS Environmental & Engineering 115 Metro Park Rochester, NY 14623

Attention: Praveen Srivastava, Ph.D.

Dear Dr. Srivastava

JJuanterra Ennmnmental

Servkes

This correspondence is in regard to our telephone conversation of May 28, 1 996, pertaining to the validation of Quanterra Tampa by the Anny Corps of Engineers (IJSACE).

- On January 10, 1 996, Quanterra Tampa received an extension to the current validation from the USACE

, through until January 10, 1 997. I have enclosed a copy of the memorandum from the USACE pertaining

- to this extension. In addition to this extension, however, the revalidation of Quanterra Tampa by the USACE began in February 1996. Since that time, Quanterra Tampa has completed the preliminary documentation process, as well the analyses of performance evaluation samples as required by the USACE. In May 1996, Quanterra Tampa was notified that a laboratory audit would be conducted in the next few weeks. We anticipate hearing from the laboratory audit team in the very near future regarding this event.

Additionally, I have contacted the State of Nebraska regarding the certification of laboratories for the purposes of analyzing environmental samples. According to the State of Nebraska, the only laboratory - certification program pertains to the analysis of drinking waler samples. I have been informed, however, that the State of Nebraska's Department of Environmental Quality does have regulations pertaining to the actual methods used by laboratories for the analysis of environmental samples. Mr. Tom Lamberson, of - this department, was unavailable at the time of mv phone call. however, I will follow up with him pertaining to this regulation. I will then pass this information along to you.

If Quanterra can be of further assistance on this matter, please call me at (813) 621-0784

Sincerely,

= Cc: Randy Grubbs, Laboratory Director

Steve Tafuni, Project Manager

- Enclosure

3603646A.DOC

.L. DEPARTMENT OF THE ARMY U.S. ARMY CORPS OF ENGINEERS - MRD

HTRW MANDATORY CENTER OF EXPERTISE 12565 WEST CENTER ROAD

OMAHA NEBRASKA 68144-36Q

PEPLYTO June 28, 1995 ATTENTION OF

Hazardous, Toxic and Radioactive Waste Center of Expertise

Quanterra, Inc. 5910 Breckenridge Parkway Suite H Tampa, Florida 33610

Gentlemen:

- This correspondence addresses the ongoing validation status of Quanterra, Inc. of Tampa, FL by the U.S. Army Corps of Engineers (USACE) Hazardous, Toxic and Radioactive Waste Center of Expertise (HTRW MCX) for HTRW analysis.

With the inclusion of the recent successful analysis for Cyanide (by EPA 9010A/9012), Herbicides (by EPA 8150A), Polychiorinated Biphenyls (by EPA 8080 in water and soil), Pesticides (by EPA 8080) and TRPH (by EPA 9071/418.1 in soil), your laboratory has successfully analyzed performance evaluation samples as listed below:

ii'I 8240 Volatile Organics Water

.- 8270 Semivolatile Organics Water 8270 Semivolatile Organics Soil

8080 Organochiorine Pesticides Water 8080 Polychiorinated Biphenyls Water 8080 Polychiorinated Biphenyls Soil

8150A Herbicides Water

- 5W-846 TAL Metals Water SW-846 TAL Meta1s' Soil

- 418.1 TRPH Water 9071/418.1 TRPH Soil

9010A/9012 Cyanide Water various .nions2 Water

i

U. S. Army Corps of Engineers -

Hazardous1 Toxic, and Radioactive Waste Center of Expertise

(HTRW CX) Oniaha,NE

s

s

To: Kcvm Dull

Ql lice: Quintera

City, Suie: Tampa, FL

Itioni 813421-0784

FAX: 8J3423.6021

Dt iiioie

No. c(Pa: I

(IrcIudingCovcr)

From: FJcua Wcb,ucr

Office: C1!MRO4X-C

Omaha, NE Phoc: 402.G97-2574

USACE Validation Status for Quanterr EviÑnmcntaI Setvices of Tampa, PL

The Laboratory Validation Committee of the HTRW CX normully grants a six-month extenaiov of an 18-month validation period to a laboratory that was awarded a cormact bcfore the expiration date. This period allows time for the laboratory to undergo the revalidetion proccss or to complete the project (if the project w' be completed within, that time frame).

Due to problems with the resolution of the PY96 budget, the Laboratory Validation Committee - ha5 decided to grant an additional six-month extnsiun ofihe current validation period (tbr a total ofa one-year extension) to a laboratory thai was awarded a contract beforc the expiration date.

Quanterra Environmental Services of Tampa, FL had a USACE HTRW X validation fr HTRW chemical analyses which expired on 111 0196. On 12/14/95, they were requested to be - revalidated, and the validation prvcess was initiatcd l'y our ofYcc.

This extension offfic,U5ACE HTRW CXvalldation vll expire on J/30f97.

-

s

1.3

w

-2-

Mod 8015 Total Petroleum Hydrocarbons Water Mod 8015 Total Petroleum Hydrocarbons Soil

Remarks: 1.) TAL Metals: Aluminum, antimony, arsenic, barium, beryllium, cadmium, calcium, chromium, cobalt, copper, iron, lead, magnesium, manganese, mercury, nickel, potassium, selenium, silver, sodium, thallium, vanadium and zinc.

2) Anions: chloride, fluoride, sulfate, nitrate, and ortho-phosphate.

- Based on the successful analysis of the performance evaluation samples indicated in the table in paragraph two above, your laboratory will be validated for multimedia sample analysis by the methods listed above. The period of validation for all parameters has been previously established and expires on January 10, 1996.

USACE reserves the right to conduct additional laboratory auditing or to suspend validation status for any or all of the listed parameters if deemed necessary. It should be noted that your laboratory may not subcontract USACE analytical work to any other laboratory location without the approval of this office. This laboratory validation does not guarantee the delivery of any analytical samples from a TJSACE Contracting Officer Representative.

If you have any questions or comments please contact Ms. Elena Webster at (402) 697-2574.

Sincerely,

11ARCIA C. Director, Toxic and Center of

DAVIES, PH.D. USACE Hazardous, Radioactive Waste Expertise

5 ¿ 4 1 Section No. One Revision No.: 11

Date: 10/15/95 Page: loll

Coii'iehensive

Quality Assurance Plan

QA Number 870270G ir

Quanterra Incorporated 5910 Breckenridearkway, Suite H

Tampa, FL 33610 (813) 621-0784

prepared by

Q uanterra Incorporated 1'

5910 Breckenridge Parkway, Suite H Tampa, FL 33610

(813) 621-0784 C'r -

.L

;.T

:uIij

Randall /Grubbs Laboraty Director

Kevin i"L Bull Laboratory QA Manager

SylviS. Labie DER-QA Officer

1- J t- I

Date

c/49S Date

Date

II

524 15

- SectionNo.: -IQ RevisionNo.: 22

- Date: 10/15/95

- Page: 1-of5

- TABLE OF CONTENTS

- QA PLAN ELEMENTS

of Revision

- Section Title PaQ. Date

1.0 Title Page 1 10115195

2.0 Table of Contents 5 10115195

3.0 Statement ofPolicy 3 10115195 - 3.1 Introduction 10/15/95 3.2 Mission 10/15/95

4.0 Organization and Responsibility 6 10/15195 4. 1 Capabilities 10115195

4.2 Key Personnel 10l15I95 - 4.3 Laboratory Personnel 10/15/95

5.0 Quality Assurance Objectives (Precision, Accuracy, MDL's) 63 10/15/95

6.0 Sampling Procedures 42 10/15/95 6. I Sample Collection Guidelines 10/15/95 6.2 Sampling Capabilities 10/15/95 6.3 Decontamination and Cleaning Procedures 10/15/95 6.4 Sample Preservation Holding Times, Container Types, 10/15/95

Required Sample Volumes 6.5 Sample Transportation 10/15/95 6.6 Sample Collection Quality Control Procedures 10/15/95 6.7 Sampling Protocols 10/15/95 6.8 Special Sampling Considerations 10/15/95 6.9 Reagent and Standard Storage 10/15/95 6.10 Waste Disposal 10/15/95

7.0 Sample Custody 28 10/15/95 7.1 Sample Custody Objectives 10/15/95 7.2 Field Custody 10/15/95 7.3 Laboratory Custody 10/15/95

524 j1 SectionNo.: Revision No.: Date: O/15/95 Page: 2of5

QA PLAN ELEMENTS

# of Revision Section Title Pages Date

8.0 Analytical Procedures 9 10115/95 8 . i Field Screening Methods Summary i 0/15195 8.2 Analytical Methods Summary 10/15/95 8.3 Laboratoiy Glassware Cleaning Procedures 10/15/95 8.4 Laboratory Reagent Storage Procedures 10/15/95 8.5 Laboratory Waste Disposal Procedures 10/15/95 8.6 Mobile Laboratory Analytical Capabilities 10/15/95

9.0 Calibration 18 10/15/95 9. I Instrumentation 10/15/95 9.2 Standards 10/15/95 9.3 Calibration 10/15/95

10.0 Preventative Maintenance 7 10/15/95 10.1 Documentation ofMaintenarice and Repair Activiiies 10/15/95 10.2 Contingency Plans for Equipment Failure 10/15/95 I 0.3 Mobile Laboratory' Set-Up and Preventative Maintenance Requirements i 0/15/95

11.0 Quality Control Checks and Routines to Assess Precision, Accuracy and Calculation of Method Detection Limits 9 10/15(95

i 1.1 Quahty Control Checks 10/15/95 1 1.2 Assessment ofPrecision and Accuracy 10/15/95 11.3 Method Detection Limits 10/15/95

12.0 Data Reduction, Validation and Reporting 73 10/15195 12.1 Data Reduction 10/15195 12.2 Data Validation 10/15195 12.3 Data Reporting 10/15/95

13.0 Corrective Action 6 10/15/95 13.1 Nonconformance and Corrective Action 10/15/95 13.2 Batch QC Corrective Action 10/15/95 13,3 Method-Specific Corrective Action 10/15/95

14.0 Performance and Systems Audits 4 10/15/95 14.1 Systems Audits 10/15/95 14.2 Performance Audits 10/1 5/95 14.3 Data Audits and Spot Assessments 10/15/95

15.0 Quality Assurance Repôrts 1 10115/95 15.1 External QA Reports 10/15/95 15.2 Internal QAReports 10/15/95 -" 15.3 Project QA Reports 10/15/95

524 17

- Section No. : RevisionNo.: Date: 10/15/95

- Page: 3of5 FiGURES

Revision Figure DescriDtion Section- Date

- 4-1 Corporate Organizational Chart 4 4-4 10/15/95 4-2 Laboratory Supervisor Organizational Chart 4 4-5 10/15/95 4-3 Laboratory Personnel Organizational Chart 4 4-6 10/15/95

- 7-1 Sample Container Label 7 7-8 10/15/95 7-2 Laboratory Sample Seal 7 7-9 10/15/95

- 7-3 Sampling Kit Instruction Form 7 7-10 10/15/95 7-4 Chain-of-Custody Form 7 7-1 1 10/15/95 7-5 Sample Receipt Form 7 7-12 10/15/95

- 7-6a Sample Receiving Logbook 7 7-13 10/15/95 7-6b Sample Receiving Logbook (Showing sarnpk disposai record) 7 7- 1 4 10/15/95 7-7 Sample Custody Logbook 7 7-15 10/15/95

- 7-8a Sample Anaiysis Requisition (internal) 7 7-16 10/15/95 7-8b Sample Analysis Requisition (External) 7 7-17 10/15/95 7-9 Laboratory Bench Worksheet (GC Volatiles) 7 7- 1 8 10/15/95 7-10 Laboratory Bench Worksheet (GC/MS Semivolatiles) 7 7-19 10/15/95 - 7-1 1 Laboratory Bench Worksheet (Metals) 7 7-20 10/15/95 7-12 Laboratory Bench Worksheet (Wet Chemistry) 7 7-21 10/15/95 7-13 Gas Chromatography Volatile Organics Instrument Logbook 7 7-22 10/15/95 -, 7-14 GCJMS Instrument Logbook 7 7-24 10/15/95 7-15 Organic Extractions Logbook 7 7-25 10/15195 7-16 Dry Weight Logbook 7 7-26 10/15/95 7-17 pH Logbook 7 7-27 10/15/95 7-18 TCLP Extraction Logbook 7 7-28 10/15/95

9-1 Laboratory Standard Tracking Logbook 9 9-18 10/15/95

12-1 Sample Final Report 12 12-9 10/15/95

13-I Nonconformance Memo 13 13-4 10/15/95

14-1 Internal Systems Audit Checklist Outline 14 14-3 10/15/95 14-2 Internal QA Data Audit Checklist 14 14-4 10/15/95

A-1 Analytical Data Summary A 3 12/04/91 A-2 Standard Calibration Curve A 4 12/04/91

B-1 Analytical Results Summary B 3 12/04/91

E-1 House Trailer Mobile Laboratory Floor Plan E 3 10/20/93 E-2 Semi Trailer Mobile Laboratory Floor Plan E 4 10/20/93

52 .:1 j F Section No.: -

Revision No.: 22 Date: 10115/95

Page: 4of5 -

TABLES Revision

Table Description Section - Page # Date

5- 1 Data Quality Objectives Field Analytical Parameters Water Matrix 5 5-2 10/15/95

5-2 Data Quality Objectives Wet Chemistry Parameters Water Matrix 5 5-5 10/15/95

5-3 Data Quality Objectives Metal Parameters by ICP, GFAA & Cold Vapor 5 5-9 10/15/95

5-4 Data Quality Objectives GC Volatile Organics Parameters 5 5-14 10/15/95

5-5 Data Quality Objectives GC/MS Volatile Organics Parameters 5 5-23 10/15/95

5-6 Data Quality Objectives GC Semi-Volatile Organics Parameters 5 5-40 10/15/95

5-7 Data Quality Objectives HPLC Polynucear Aromatic Hydrocarbons 5 5-47 1 0/15/95

5-8 Data Quality Objectives GC/MS Semi-Volatile Organics Parameters 5 5-49 10/15/95

6-1 Sampling Capabilities 6 6-2 10/15/95

6-2 General Use Sampling Equipment 6 6-3 10/15/95

6-3 Sampling Equipment 6 6-4 10/15/95

6-4 Preservation Summary for Aqueous Matrices 6-3 1 10/15/95

6-5 Preservation Summary for Sohd Matrices 6 6-37 10/15/95

6-6 Standard and Reagent Storage 6 6-4 1 10/15/95

8-1 Laboratory Reagent Storage S 8-7 10/15/95

9-1 Field Analytical Instrumentation 9 9-1 10/15/95

9-2 Laboratory Major Analytical Instrumentation 9 9-2 10/15/95

9-3 Standards Sources and Preparation 9 9-10 10/15/95

10-1 Preventative Maintenance Procedures 10 10-3 10/15/95

Field Instrumentation/Equipment 10-2 Preventative Maintenance Procedures 10 10-4 10/15/95

Laboratory Instrumentation/Equipment

11-1 Student's t Values at the 99% Confidence Level 11 11-9 10/15/95

13-1 Corrective Action 13 13-2 10115195

524 19

SectionNo.: Revision No.: Date: 10/15/95

- Page: 5of 5

APPENDICES -

Appendix # of Revision

IP Description Page Date

j.- A. MethOd Validation for Total Phenols in SoillSediment NA Repealed

- B. Method Validation for Alternate Heating NA Removed Source for Aqueous Metals Digestion

C. Method Validation for Total Fluoride in 4 12/04/91 - SoillSediment - 340.1/340.2 MOdified (FLDEP Approved 8-26-92)

- D. MethOd Validation for Alternate Analysis of NA Repealed

Sulfur, Tin and Titanium by Inductively Coupled Plasma Atomic Emission Spectroscopy

E. Method Validation for the Analysis of 407 01/17/95 Volatile Organic Compounds by EPA 624 or EPA 8240 - Aqueous Only (FLDEP Approved 3-14-94)

F. Floor plans of Mobile Laboratories 4 10/20/93 * For Preliminary Contamination Assessments Only

G. Continuous Liquid - Liquid Extraction Variation of EPA 04/21/93 Method 3520 (FLDEP Approved 3-14-94)

H. Method Validation for the Analysis of 01/18/95 Volatile Organic Compounds by EPA 625 or EPA 8270 (Hexachlorophene by EPA 3510 and EPA 3550 only)

I. Method Validation for the Analysis of 04/26/95 Volatile Organic Compounds by EPA 601 or EPA 8010

J. Method Validation for the Analyis of 10/15/95 Hexachlorobenzene by EPA Method 608 8080 - Aqueous Only

w.

4

524 20

Section No.: Three - Revision No.:

Date: 10/15/95

Page: lpf3

3.0 Statement of Policy

3.1 Introduction

Quanterra Incorporated (Quanterra) was formed in June 1994 as a joint venture of MetPath, Inc. (a subsidiary of Corning Incorporated) and IT Corporation (a subsidiary of International Technology Corporation). Quanterra's predecessors operated as Enseco and International Technology Analytical Services. Quanterra Incorporated has its headquarters in Englewood, Colorado.

Quanterra Tampa began operation in 1985 as one of the Wadsworth/ALERT Laboratories. Wadsworth/Alert was an independent testing laboratory organized to deliver comprehensive and reliable analytical services to its clients in a responsive and complete manner. Wadsworth/ALERT Laboratories, Inc. was headquarterec in North Canton, Ohio, which had been a leading independent laboratory for over 50 years. The Wadsworth network was purchased by Coming and added to the Enseco network in 1991.

Quanterra lampa offers conventional and mobile laboratory services with a particular emphasis on

- providing full-service analytical capabilities. The laboratory maintains a number ofanalytical programs designed to fulfill the needs of its clients in the technical aspects of environmental control and regulatory compliance. These analytical programs include:

CERCLA-ENVIRONMENTAL ASSESSMENT Contamination Profiles and Assessments

- Groundwater Monitoring/Surface Water Evaluations and SoillSedirnent, Subsurface Investigations

Complete Analytical Characterizations Priority Pollutants - Hazardous Substance List Parameters Appendix VII, IX Constituents Herbicides, Pesticides, PCBs Trihalomethanes (THMs) Metals

- Surface Surveys and Investigations Wipes, Swabs, etc.

- Restoration Project Monitoring and Evaluations

Clean-up Monitoring and Evaluation

- - Treatment System Evaluation and Monitoring

Compliance Monitoring and Evaluations Quality Control Verification - Long-Term Compliance Verification

5

524 21

TSCA SURVEYS PCB Surveys

Environmental Surveys Air, Water, Soil

Waste Product Surveys Oils, Fluids, Waxes, Sludges

Factory Contamination Surveys

RCRA-INDUSTRIAL WASTE MANAGEMENT Characteristic Waste Parameters

Igrulability Reactivity Corrosivity EP Toxicity, TCLP

Hazardous Waste Analysis Descriptive Properties Physical Properties Disposal Parameters Chemical Composition

Organic, Inorganic, Metallic Composition

Groundwater Monitoring Quarterly Monitoring Parameters

Suitability, Quality, and Contamination Parameters Radioactivity

Complete Analytical Characterizations Appendix VII, LX Analysis

Delisting Petitions Lagoon, Pile, Sludge Pond, Waste Stream Characterizations

NPDES-INDUSTRIAL PRETREATMENT Permitting, Compliance Monitoring and Evaivation

Water, Wastewater, and Industrial Effluent Analysis EPA Form 2C Analysis

Parts, A, B, and C Complete Analytical Characterizations

Section No.: Revision No.: Date: Page:

Three 12

10115195

2 of 3

-

524 22

Section No.: Three Revision No.: Date: 10/15195

Page: 3of3

SDWA-DRINKING WATER Compliance Monitoring and Evaluation

Regulated Parameters Herbicides, Pesticides Trihalomethanes (THMs) Metals

Complete Analytical Characterizations

Treatment System Monitoring and Evaluation

3.2 Mission - _______

Quantrra's mission is to be recognized as the premier provider ofenvironmental laboratory services by

- being world class in quality and technology, and by setting the standard ofexcellence within the industry. Quanterra's management is committed to providing quality services that meet the requirements of our clients and satisfy regulatory requirements. Management is dedicated to providing an environment that encourages the achievcment of excellence, demands integrity in all aspects of its operation, and requires active participation of all associates and vendors in meeting its quality goals.

The Comprehensive Quality Assurance Plan is the internal guidance document in administering the QAJQC program of Quanterra Tampa. As such, it is written so that it meets or exceeds all requirements of the Florida Department of Environmental Regulation as outlined in the Florida Administrative Code 62-160.

-

-

524 23

Section No.: Revision No.: Date: 10/15/95 Page: 1 of6

4.0 Organization and Responsibility

4.1 Capabilities

Quanterra Tampa maintains personnel and equipment for operations associated with field and laboratory operations.

- 4.2 Key Personnel

The general responsibilities of key personnel involved in field and laboratory operations with respect to - QAiQCareasfollows:

4.2.1 Vice-President and General Manager of Laborator' Operations

The Vice-President and General Manager of Laboratory Operations (General Manager) is responsible for evaluating the information supplied by the Laboratory Director (Laboratory Manager). The General

- Manager determines the effectiveness of Quarnerra's Quality Management System, and is responsible for implementing the Quality Management Plan (QMP) and the Quaiity Assurance Manacment Plan (QAMP). This responsibility includes the commitment to provide the leadership and financial resources

- necessary to ensure that the laboratory and staff are able to offer the highest quality, scientifically sound and legally defensible data and services to our clients. The General Manager reports directly to the President and CEO of Quanterra.

4.2.2 Laboratory Director

- The Laboratory Director oversees daily operations of the analytical laboratory, and thus, he/she is

responsible for implementation of the QMP and QAMP within the laboratory. Responsibilities include interacting with group coordinators and project managers to coordinate projects and workload. In addition,

= the Laboratory Director assumes responsibility for maintaining method compliance in the laboratory, He/she interacts with the QA Manager in the laboratory and ensures the incorporation of such requirements into daily operations. The Laboratory Director aids the QA Manager in addressing corrective actions and

- preparing the laboratory to meet certification and approval program requirements. The Laboratory Director reports to the General Manager.

- 4.2.3 Operations Mafla2er

The Operations Manager supervises the daily activities ofthe Operational Groups. This person supervises

- QC activities performed as part of the routine analytical operations. The Operations Manager reports to the Laboratory Director.

521 2

Section No.: Four Revision Noe: 15

Date: 10/15/95 Page: 2of6

4.2.4 Laboratory Quality Assurance Manazer

The QA Manager supervises QA functions pertaining to laboratory analytical operations. These responsibilities include managing certification and approval programs, maintaining QC objective data, conducting internal QA audits and overseeing external audits initiating and managing corrective action based on internal QC data, and prepanng and submitting any quality assurance plans. Other functions include: establishing standard operating procedures based on current industry standards, and preparing quality assurance reports for management, clients, and regulatory agencies. The QA Manager is responsible for ensuring that all final data meets the criteria of the Quality Control program and reports directly to the Regional QA Director and indirectly to the Laboratory Director.

4.2.5 Samplin2 Team Leader (Supeiisor)

The Sampling Team Leader implements and supervises all laboratory and field activities pertaining to the sampling group. This individual is responsible for ensuring that all sampling activities are conducted iii accordance with documented sampling procedures. This person also ensures that proper quality control procedures are incorporated into the daily operation of the group, including proper documentation of all sampling activities and subsequent timely submittal of samples to the laboratory. The Sampling Team Leader reports to the Laboratory Director.

4.2.6 Analytical Team Leader fSupervisor)

The Analytical Team Leader implements and supervises all analytical activities pertaining to the respective analytical group. This individual is responsible for reviewing raw data and analytical results. He/she also ensures that the proper quality control requirements are incorporated into the daily operation of the group. The Analytical Team Leader reports to the Laboratory Director.

4.3 Laboratory Personnel

ADMINISTRATION

Naine Responsibilities

Jim Kaiser President/ CEO, Quanterra Incorporated Peggy S. Sleevi Corporate Director ofQA, Quanterra Incorporated Robert E. George General Manager, Quanterra Eastern Region George GatIiri Regional Director of QA, Quanterra Eastern Region Randall C. Grubbs Operations Manager/Laboratory Director Kevin M. Bull Laboratory Quality Assurance Manager

524 25

Section No.: Four Revision No.: Date: 10/15/95 Page: 3of6

LABORATORY OPERATIONS

Name pibjIjties

Jeff Graham Customer Service Manager Rob Corden Shipping Supervisor Carol McNulty Receiving Supervisor Richard Detar Metals Supervisor Julie Woods Wet Chemistry Supervisor Sue Barton GCIMS Semi-Volatile Organic Supervisor Steve Bell GCIMS Volatile Organic Supervisor Jesslyn Frater GC Volatile Organic uper'isor Allen Mitchell GC & HPLC Semi-Volatile Organic Supervisor Mark Hopkins Organic Extractions Supervisor David Gann Sampling Group Supervisor

-

8

524 2G

Section No.: Four Revision No.: 15 - Date: 10115/95 Page: 4of6

FIGURE 4.1

CORPORATE ORGANIZATIONAL CHART

QUANTERRA INCORPORATED CORPORATE

ORGANIZATIONAL CHART

JAMES KAISER PRESIDENT/CEO

QUANTERRA INCORPORATED ENGLEWOOD, COLORADO

ROBERT E. GEORGE GENERAL MANAGER, EASTERN REGION

QUANTERRA INCORPORATED NORTH CANTON, 01-110

RANDALL C. GRUBBS LABORATORY DIRECTOR

TAMPA, FLORIDA

OPERATIONS I ILABORA

GEORGE GATLIN REGIONAL DIRECTOR of QA1

NORTH CANTON, OHIO

LAB, O.A. MANAGER

524 27

Section No.: Revision No.: Date: 10115/95

Page: 5of6

RANDALL C. GRUBBS KEVIN M. BULL LAB DIRECTOR LAB QA MANAGER

FIELD OPERATIONS I LABORATORY OPERATIONS

DAVID GANN CAROL MCNULTY ROB CORDEN SAMPLING GROUP RECEWING SHIPPING

- SUPERVISOR SUPERVISOR SUPERVISOR

RICHARD DETAR I

JULIE WOODS METALS f- WET HEMITRY

SUPERVISOR I

SUPERVISOR

SUE BARTON i E

STEVE BELL OC/MS SEMI VOA }- GCIMS VOA

SUPERVISOR__J [

SUPERVISOR

JESSLYN FRATER i

[ALLEN MITCHELL - GCVOA f-- -J GCSEMIVOA

SUPERVISOR j j _ SUPERVISOR

- MARK HOPKINS EXTRACTIONS

a SUPERVISOR

'i,

524 28

Section No.: Four Revision No.: Date: 10/15/95 Page: 6of6

FIGURE 4.3

LABORATORY PERSONNEL ORGANiZATIONAL CHART

Laboratory Director Randy Grubbs

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524 29 Section: Five Revision No. :Q Date: 10/15/95

PaSe: I of 69

5.0 QA Tar!ets for Precision, Accuracy and Method Detection Limits

The Accuracy, Precision and Method Detection Limit values presented in the following sections are based upon local

laboratory historical data and method validation studies using spikes, replicates and standards where available. EPA method control data, advisory limits or limits generated from corporate historical data, are used where historical data is not available. These limits are replaced with local laboratory historical data within one year from the addition of those analytes to the CompQAP.

5.1 Field Analytical Parameters

Field analytical parameters are listed in Table 5-l.

'o

524 ,fl

TABLE S-1

DATA QUALITY OBJECTIVES

FIELD ANALYTICAL PARAMETERS WATER MATRIX

Parameter

pH

Specific Conductance

Temperature

Dissolved Oxygen

Residual Chlorine

Section: Fi'

Revision No. :2 Date: IO/15/° Pase: 2of

Method

EPA 150.1

SM 25 lOB

SM 2550B

EPA 360.1

SM 4500Cl G

524 31 Section: Five Revision No. :20 Date: 10/15/95 Page: 3 of 69

-

5.2 Laboratory Data Ouality Objectives

The laboratory data quality objectives are presented in Tables 5-2 through 5-8 as outlined below. The tables are organized into analytical groups. For the current revision of this plan, data quality objectives are listed for just two matrices; water and soil/sediment. "Water" (W) encompasses groundwater, surfàce water and leachates from toxicity characterizations. "Soil/Sediment" (S) covers all solids and soils as well as chemical waste. Future revisions may further divide objectives more

specifically as data becomes available. The following summary notes the page numbers on which these groups/tables begin.

Page Analytical Group Tables Included

- 5 Wet Chemistry 5-2

- 10 Metals 5-3

- 16 GC Volatile Organics 5_4

25 GCÍMS Volatile Organics 5-5

44 GC Semi-Volatile Organics 5-6

- 52 HPLC 5-7

54 GCIMS Semi-Volatile Organics 5-8

67 Data Quality Objectives Notations and Explanations for Tables 5-2 through 5-8

11

524 32

5.3 Preparation Methods Summary

Section: Fi Revision No.:2 Daze: 10/15/95

Page: of

Sample preparation methods are presented in Table 5-9 (pages 62 through 63). Where preparations are not indicated for a method, these procedures are contained in the analytical methods themselves

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80

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120

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SM 5

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20

L

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12

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522

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Dem

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20

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mg/

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0.8

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N

A

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0.

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2.8

2.3

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A

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0.

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18

0.2

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hg

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N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

2.3

NA

N

A

NA

N

A

NA

N

A

NA

N

A

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N

A

NA

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0 D

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10

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95

Page

: 9o

f69

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MD

L

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SD

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ge

Ran

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jjgL

L

nm/k

g N

A

NA

N

A

NA

N

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L

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N

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NA

N

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0 D

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10

/15/

95

Page

: 10

of69

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5-3

D

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A Q

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(continued)

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MD

L

Met

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Mat

rix

Ana

lytc

/Com

ponc

nt

% R

SD

ßg

%R

R

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m

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EPA

202

.2

W

Alu

min

um

L

L

NA

E

PA 2

04.2

W

A

ntim

ony

14

L

74-1

02

L

1.8

NA

SM

3113

13

W

Ant

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14

L

74-1

02

L

IJ

NA

E

PA2O

6.2

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19

L

80

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L

1.

8 N

A

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13B

W

A

rsen

ic

19

L

80-1

19

L

1.8

NA

E

PA 2

08.2

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B

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m

30

L

50-150

L

NA

E

PA 2

10,2

W

B

eryl

lium

30

L

50

-150

L

N

A

EPA

213

.2

W

Cad

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m

14

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90-1

18

L

0.7

NA

SM

3113

8 W

C

adm

ium

14

L

90

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L

0,

7 N

A

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218

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Chr

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12

L

90-1

19

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0.5

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311

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12

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90

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L

0,5

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C

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L

50-150

L

NA

E

PA 2

20.2

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C

oppe

r 30

L

50-150

L

NA

E

PA 2

36.2

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on

30

L

50-1

50

L

NA

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24

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76-1

24

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30

L

50-150

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SM

311

1 B

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Si

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30

L

50

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N

A

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279

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200

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282

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30

L

50

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L

N

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286

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30

L

50-1

50

L

NA

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Z

inc

30

L

50-1

50

L

NA

SW

846

7041

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A

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L

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27

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L

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R

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No.

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Dat

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1011

5195

Page

: ho

f 69

TA

BL

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DA

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OB

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TIV

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(con

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Prec

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Accuracy2

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MD

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Mat

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Ana

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% R

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R

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2 N

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L

77

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N

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6 71

31

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L

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L

71

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L

N

A

0.25

SW

8467

191

W

Chr

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m

12

L

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19

L

0.5

NA

S

24

L

67-1

15

L

NA

1.

2 SW

846

7421

W

L

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24

L

76-1

24

L

i

NA

S

22

L

77-1

22

L

NA

0.

05

SW84

6 77

40

W

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nium

20

L

76

-116

L

2

NA

S

26

L

67-1

19

L

NA

0,

1 SW

846

7841

W

ili

alliu

m

13

L

50-1

02

L

2 N

A

S 13

L

50

-102

L

N

A

0.1

SW84

6 60

10

S A

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L

87

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L

N

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10

L

87-1

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L

62

NA

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N

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23

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17

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NA

0.

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21

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12

L

83

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L

N

A

0.07

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15

L

81

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NA

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N

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0.05

W

19

L

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I

NA

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Bor

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15

L

85-1

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L

NA

0.

35

w

15

L

85-1

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L

34

NA

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17

L

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L

NA

0.

17

w

15

L

76-1

10

L

3 N

A

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alci

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17

L

90-1

37

L

NA

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31

L

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Rev

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o. :2

0 D

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10

/15/

95

Page

: 12

of69

T

AB

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5-3

D

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A Q

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(con

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Prcc

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MD

L

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SD

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ge

%R

R

anc

mgg

14

L

KO

-108

L

N

A

0.12

21

L

74

-117

L

2

NA

15

L

85

-113

L

N

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0.11

16

L

83

-115

L

3

NA

13

L

88

-liS

L

N

A

0.14

23

L

. 79

-125

L

5

NA

II

L

90

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L

N

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1,0

19

L

82-1

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L

45

NA

34

L

65

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L

N

A

1.0

21

L

68-1

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L

17

NA

30

L

50

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N

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0.12

30

L

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L

0.

0.00

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15

L

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L

NA

3.

1 21

L

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L

16

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90

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N

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0.05

2 18

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3

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NA

0.

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11

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L

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13

L

84-1

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L

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0.

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21

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72-1

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L

10

NA

9

L

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L

NA

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L

47

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N

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15

15

L

83-1

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180

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14

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85

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N

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2.6

18

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91-1

27

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60

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17

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Dat

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1011

5195

Page

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9 T

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5-3

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Met

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20

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180

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12

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3

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16

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W

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50

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30

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30

L

50

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L

3

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30

L

50

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L

N

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30

L

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50

L

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30

L

50

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L

N

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0.05

S

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30

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30

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50

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L

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50

L

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30

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L

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30

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Mat

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19

L

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15

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Cal

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31

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C

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19

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62

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17

N

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21

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N

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A

34

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3

NA

14

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17

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10

/15/

95

Page

: 15

of69

T

AB

LE

5-3

D

AT

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Met

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Prec

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c.

Accuracy2

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200

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m

11

L

82-1

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21

L

72-1

14

L

i

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9

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82-1

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L

26

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15

L

33

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L

34

N

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91

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L

3

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20

L

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0.4

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12

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L

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L

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33

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3

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L

2

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3

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3

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30

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3

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L

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Met

hod

Mat

rix

jte/C

onip

onen

t % R

SD

Ran

ge

jß,

EPA

502

.2

W

Ben

zcne

16

L

70

-117

l3

rom

obcn

zcnc

17

L

78

-114

B

rorn

ochl

oror

neth

anc

10

L

87-1

08

Bro

mod

ichl

orom

etha

ne

24

L

72-1

23

Bro

mof

orm

15

L

75

-125

B

rom

omet

hane

18

L

37

-145

n-

I3ut

ylbc

nzcn

c 13

L

86

-112

se

c-B

utyl

benz

ene

11

L

84-1

08

tcrt

-But

y!be

nzen

c 12

L

88

-1 i

l C

arbo

n te

trac

hlor

idc

16

L

8 l-

129

Chl

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ne

12

L

79-1

08

Chl

oroc

than

c 23

L

82

-121

C

hlor

ofor

m

12

L

85-1

09

Chl

oron

icth

ane

21

L

75-1

31

2-C

lilor

otol

uene

24

L

75

-124

4-

Chl

orot

olue

nc

24

L

75-1

24

Dib

ro'm

ochl

orom

etha

ne

21

L

87-1

30

1,2-

Dib

rom

o-3-

chlo

ropr

opan

e 27

L

78

-134

1,

2-D

ibro

moe

than

c 27

L

66

-120

D

ibro

mom

etha

ne

17

L

68-1

18

1,2-

Dic

hlor

oben

zene

17

L

85

-119

1,

3-D

ichl

orob

enze

ne

17

L

81-1

15

l,4-D

ichl

orob

cnze

nc

15

L

84-1

15

ç i,

I I

I (

I I

t L

Sect

ion:

Fi

ve

Rev

isio

n N

o.:2

0 D

ate:

10

/15/

95

Page

: 16

of69

Con

e.

MD

L

Ran

ge

mgJ

kg

L

0.5

NA

L

0.

7 N

A

L

0.1

NA

L

1.

0 N

A

L

0.7

NA

L

1.

0 N

A

L

0.6

NA

L

0.

4 N

A

L

0.6

NA

L

0.

8 N

A

L

0.4

NA

L

1.

0 N

A

L

0.6

NA

L

1.

0 N

A

L

0.5

NA

L

0.

5 N

A

L

1.0

NA

L

0.

3 N

A

L

1,0

NA

L

1.

0 N

A

L

0.7

NA

L

0.

8 N

A

L

0.8

NA

(dl

N)

r

t t

I

(

I

'

I I

I (

V

(

.

Sect

ion:

Fi

ve

Rev

isio

n N

o. :2

0 D

ate:

10

/15/

95

Page

: 17

of69

T

AB

LE

5-.4

D

AT

A Q

UA

LL

TY

OB

JEC

TIV

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cc V

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AT

ILE

OR

GA

NIC

S (C

ontin

ued)

Pr

ccis

ion'

C

onc.

Accuracy2

Con

.c.

MD

L

Met

hod

Mat

rix

Ana

lyte

/Com

pone

nt

% R

SD

igc

ß ßírn

mgJ

çg

EPA

502

.2

W

Dic

hior

odif

luor

omet

hanc

15

L

83

-128

L

G

A

NA

(C

ontin

ued)

1,

1-D

ichi

oroe

than

e 17

L

83

-I 1

7 L

O

. N

A

1,2-

Dic

hlor

octh

ane

16

L

75-1

39

L

1.0

NA

1,

1-D

ichi

oroe

then

e 27

L

48

-130

L

0.

6 N

A

cis-

1,2-

Dic

hl:o

roct

hcnc

21

L

67

-1 1

1 L

0.

4 N

A

tran

s-1,

2-D

ichl

oroc

t.hen

c 17

L

81

-1 1

5 L

0.

8 N

A

1,2-

Dic

hior

opro

panc

15

L

75

-123

L

0.

7 N

A

1,3-

Dic

hlor

opro

panc

12

L

90

-117

L

0.

6 N

A

2,2-

Dic

hlor

opro

pane

15

L

79

-107

L

0.

7 N

A

1,1-

Dic

hlor

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pcnc

10

L

91

-106

L

0.

4 N

A

l,3-D

ichl

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ropc

nc

30

L

50-1

50

L

NA

E

thyl

benz

ene

10

L

84-1

06

L

0.5

NA

H

exac

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ad je

ne

10

L

95-1

08

L

0.3

NA

Is

opro

pylb

enze

ne

10

L

86-1

03

L

0.4

NA

p-

Isop

ropy

ltolu

ene

11

L

91-1

14

L

0.6

NA

M

ethy

lcnc

chl

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e 19

L

82

-122

.L

1.

0 N

A

Met

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ther

30

L

50

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L

N

A

Nap

htha

lene

12

L

92

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5 L

0.

6 N

A

n-Pr

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bcnz

enc

12

L

88-i

12

L

0.6

NA

St

yre:

nc

216

L

8412

86

L

0.1

NA

1,

1,1,

2-T

ctra

chlo

roct

hane

21

L

72

-116

L

0.

7 N

A

1,1,

2,2-

Tet

rach

loro

etha

nc

19

L

70-1

26

L

0.1

NA

T

etra

chlo

roct

hcne

13

L

75

-127

L

0.

6 '

NA

T

olue

nc

16

L

70-1

17

L

0.4

NA

1,

2,3-

Tri

chlo

robc

nzcn

c 10

L

86

-104

L

0.

4 N

A

1,2,

4-T

rich

loro

benz

ene

10

L

86-1

04

L

0.5

NA

1,

1,1-

Tri

chlo

roet

hane

14

L

81

-125

L

0.

5 N

A

1,1,

2-T

rich

loro

etha

nc

17

L

81-1

33

L

0.5

NA

Cil

Sect

ion:

Fi

ve

Rev

isio

n N

o.

Dat

e:

10/1

5/95

Page

: 18

of69

T

AB

LE

5-4

D

AT

A Q

UA

LIT

Y O

BJE

CT

IVE

S

Met

hod

Mat

rix

Ana

lyte

/Com

pone

nt

EPA

502

.2

Tri

chlo

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(C

ontin

ued)

T

rich

ioro

fluo

rom

etha

nc

W

¡ ,2

,3-T

rich

loro

prop

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I ,2

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rim

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lbcn

zcnc

I ,3

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rim

ethy

lben

.zcn

e V

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chl

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o-X

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c m

-Xyl

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p-X

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c

EPA

601

, W

B

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l chl

orid

e SW

846

8010

B

rom

oben

zene

B

rom

ochi

orom

etha

nc

Bro

mod

ichl

arom

etha

nc

Bro

mof

orrn

B

rom

omet

hanc

C

arbo

n te

trac

hior

ide

Chi

orob

enze

ne

Chl

oroe

than

c

2-C

hior

oeth

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eth

er

Chl

orof

orm

i -C

hlor

ohcx

anc

Chi

orom

etha

ne

2-C

hior

otol

uene

H

Dib

rom

ochi

orom

etha

nc

Dib

rorn

orne

than

c i ,2

-Dic

hlor

obcn

zene

I ,3

-Dic

hlor

abcn

.zcn

e I ,4

-Dic

hJor

oben

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i,

CC

VO

LA

TIL

E O

RC

AN

ICS

(Con

tinue

d)

Prec

isio

n'

Con

e.

Accuracy2

Con

c.

MD

L

% R

SD

Rng

Ran

ge

ig(

mJk

g 13

L

75

-123

L

0.

4 N

A

14

L

87-1

31

L

1.0

NA

17

L

72

-122

L

0.

4 N

A

10

L

90-1

09

L

0.5

NA

11

L

89

-112

L

0.

6 N

A

22

L

44-1

76

L

0.2

NA

21

L

84

-128

L

0.

5 N

A

21

L

84-1

28

L

0.3

NA

21

L

84

-128

L

0.

6 N

A

10

L

86-1

06

L

0.48

N

A

17

L

78-1

14

L

0.51

N

A

30

L

50-1

50

L

NA

22

L

61

-133

L

0.

20

NA

14

L

75

-125

L

0.

23

NA

18

L

37

-145

L

0.

44

NA

16

L

81

-129

L

0.

17

NA

24

L

58

-133

L

0.

13

NA

23

L

82

-121

L

0.

41

NA

21

L

50

-156

L

0.

43

NA

12

L

85

-109

L

0.

33

NA

12

L

58

-133

L

0.

62

NA

21

L

75

-131

L

0.

35

NA

24

L

75

-124

L

0.

62

NA

21

L

87

-130

L

0.

17

NA

17

L

68

-118

L

0.

46

NA

il

L

85-1

19

L

0.26

N

A

17

L

81-1

15

L

0.32

N

A

15

L

84-1

15

L

0.28

I I

C

(

I I

I

c-fl

Sect

ion:

Fi

ve

Rev

isio

n N

o. :Q

D

ate:

10

/15/

95

Pagc

: 19

of69

T

AB

LE

5-4

D

AT

A Q

UA

LIT

Y O

BJE

CT

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S

CC

VO

LA

TIL

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RG

AN

ICS

(Con

tinue

d)

Precision1

Coi

c.

Accuracy2

Con

e.

MD

L

Met

hod

Mat

rix

Ana

lyte

lCom

pone

nt

% R

SD

jgc

gf

mg/

kg

EPA

601

, W

D

ichi

orod

iflu

orom

etha

nc

15

L

83-1

28

L

0.26

N

A

SW84

6 80

10

1,i-

Dic

hlor

octh

ane

17

L

83-1

17

L

0.26

N

A

(Con

tinue

d)

1,2-

Dic

hlor

oeth

anc

16

L

75-1

39

L

0.60

N

A

I,l-

Dic

hlor

octh

cne

28

L

43-1

31

L

0.28

N

A

cis-

1,2-

Dic

hlor

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cne H

24

L

69-1

21

L

0.20

N

A

tran

s-1,

2-D

ich!

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tlìcn

c 17

L

Si

-i 1

5 L

0.

21

NA

1,

2-D

ich.

loro

prop

ane

15

L

75-1

23

L

0.25

N

A

cis-

1,3-

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opro

pcnc

14

L

78

-122

L

0.

20

NA

tr

ans-

1,3-

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penc

21

L

65

-128

L

0.

24

NA

M

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lene

chl

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e 19

L

82

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L

0.

21

NA

I,

1,1,

2-T

etra

chlo

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21

L

72

-116

L

0.

57

NA

1,

1,2,

2-T

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chlo

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hanc

19

L

70

-126

L

0.

25

NA

T

etra

chlo

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13

L

75

-127

L

0.

19

NA

1,

1,1-

Tri

chlo

roet

hanc

14

L

81

-125

L

0.

26

NA

1,

1,2-

Tri

chlo

roct

hane

17

L

81

-133

L

0.

25

NA

T

rich

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ethe

ne

13

L

75-1

23

L

0.23

N

A

Tri

chlo

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met

hanc

14

L

87

-131

L

0.

36

NA

1,

2,3-

Tri

chlo

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opan

c 17

L

72

-122

L

0.

51

NA

V

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chl

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e 22

L

44

-176

L

0.

39

NA

CJ1

Met

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Mat

rix

EPA

602

, W

SW

846

8020

EPA

601

MO

D,

W

SW84

6 80

10

Mod

.

SW84

6 80

10

S

Ana

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/Com

nonc

nt

Ben

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C

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i ,

2-D

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ne

I ,3

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obcn

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i ,4

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E

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cnc

Tol

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Met

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r

Xyl

encs

E

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dibr

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1 ,2

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ch

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Ben

zy!

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B

rom

obcn

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B

rom

odic

hior

omet

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B

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m

Bro

mor

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Car

bon

tctr

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hlor

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C

hlor

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2-C

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eth

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Chl

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1 -C

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Chl

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etha

ne

2-C

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Il

TA

BL

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-4

DA

TA

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AL

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TIV

ES

GC

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LA

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RC

AN

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(Con

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d)

Prec

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n'

Con

c.

%R

SD

Rg

15

L

24

L

17

L

17

L

15

L

IO

L

16

L

16

L

21

L

25

L

20

L

t I

Accuracy2

Con

c.

Ran

ge

70-1

17

L

58-1

33

L

85-1

19

L

81-1

15

L

84-1

15

L

84-1

06

L

70-1

Il

L

75-1

08

L

84-1

28

L

81-1

35

L

80-1

20

L

Sect

ion:

Fi

ve

Rev

isio

n N

o.:2

0 D

atc:

10

/15/

95

Page

: 20

of69

MD

L

ugL

0.5

NA

0.

2 N

A

0.7

NA

0.

8 N

A

0.8

NA

0.

2 N

A

0.2

NA

0.

2 N

A

0.2

NA

0.

01

NA

0.

1 N

A

27

L

58-1

12

L

NA

.

0.95

6 11

L

82

-106

L

N

A

0.27

31

L

65

-127

L

N

A

0.25

28

L

77

-125

L

N

A

0.62

36

L

37

-148

L

N

A

0.48

24

L

62

-111

L

N

A

0.30

19

L

74

-114

L

N

A

0.34

25

L

67

-117

L

N

A

0,44

36

L

54

-127

L

N

A

0,81

17

L

66

-125

L

N

A

0.26

15

L

75

-119

L

N

A

0.30

33

L

67

-134

L

N

A

0,27

13

L

84

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L

N

A

0.23

t I

I t

C

I t

(

cj1

CiD

I I

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l

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(

f

(

(

Sect

ion:

Fi

ve

Rev

isio

n N

o. :j

D

ate:

10

/15/

95

Page

: 21

of 6

9 T

AB

LE

5-4

D

AT

A Q

UA

LIT

Y O

BJE

CT

IVE

S

CC

VO

LA

TIL

E O

RG

AN

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(Con

tinue

d)

Prcc

isio

n'

Con

c.

Accuracy2

Con

e.

MD

L

Met

hod

Mat

rix

Ana

lyte

/Com

pone

nt

% R

SD

Ran

ge

jg

gf

çg

SW84

6 80

10

S D

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moc

hior

omet

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31

L

69

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L

N

A

0.26

(C

ontin

ued)

D

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niom

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ne

28

L

86-1

43

L

NA

04

4 I,

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ne

16

L

83-1

17

L

NA

0.

32

1,3-

Dic

hlor

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16

L

83

-1 1

7 L

N

A

0.34

1,

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cnie

ne

16

L

83-1

17

L

NA

0.

33

Dic

hior

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than

e 22

L

83

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L

N

A

0.87

1,

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ichi

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than

c IS

L

63

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L

N

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0.25

12

-Dic

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16

L

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0.32

1,

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thcn

c 30

L

45

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L

N

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0.27

ci

s-1,

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then

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L

69

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N

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0.

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L

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0.24

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20

L

22-1

78

L

NA

0.

19

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26

L

58-1

25

L

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22

Met

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25

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83-1

25

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28

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72

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chlo

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24

L

56

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L

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22

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65

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28

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0 D

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10

/15/

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Page

: 24

of 6

9

MD

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D

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10

/15/

95

Page

: 26

of69

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30

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30

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30

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10

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95

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' 15

L

85

-140

L

1.

20

NA

4-

Chl

orot

olue

ne"

15

L

66-1

19

L

0.66

N

A

Dib

rom

ochl

orom

etha

nc

8 L

79

-125

L

0.

56

NA

D

ibro

mom

etha

ne'

IS

L

87-1

41

L

1.40

N

A

l.2-Dichlorobenzene7

15

L

73-1

25

L

0.58

N

A

1,3-Dichlorobenzene7

15

L

77-1

19

L

0.70

N

A

1,4-Dichiorobenzene7

15

L

74-1

22

L

0.78

N

A

IS.)

cJ1

cJ1

cj1

Sect

ion:

Fi

ve

Rev

isio

n N

o:20

D

ate:

10

/15/

95

Page

: 28

of69

T

AB

LE

5-5

D

AT

A Q

UA

LIT

Y O

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IVE

S G

C ¡

MS

VO

LA

TIL

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RG

AN

ICS

(con

tinue

d)

Met

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Mat

rix

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tyte

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pone

nt

Prec

isio

n'

Con

c,

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MD

L

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ç ßg

L

k E

PA 6

24

SW84

6 82

40

Dic

hlor

odif

luor

ornc

than

e 12

L

79

-105

L

0.

89

NA

(C

ontin

ucd)

1,

1-D

ichi

oroe

than

e 12

L

82

-109

L

0.

63

NA

1,

2-D

ichi

oroe

than

c 17

L

76

-12g

L

0.

60

NA

w

1,

1-D

ichi

oroe

then

c 19

L

63

-123

L

0.

58

NA

ci

s-(,

2-D

ich1

ooet

hen&

' 26

L

63

-142

L

0.

69

NA

tr

ans-

1,2-

Dic

hlor

octh

cnc

12

L

79-1

09

L

0.74

N

A

1,2-

Dic

hior

opro

pane

15

L

88

-118

L

0.

70

NA

ci

s-1,

3-D

ichl

orop

rope

ne

12

L

ß4-1

09

L

0.40

N

A

tran

s-1,

3-D

ichl

orop

ropc

nc

12

L

84-1

09

L

0.47

N

A

Eth

ylbc

nzen

e 14

L

85

-115

L

0.

64

NA

2-

Hcx

anon

e8

18

L

85-1

23

L

2.20

N

A

Met

hyle

nc c

hlor

ide

19

L

77-1

35

L

0.62

N

A

4-M

ethy

l-2-

pcnt

anon

c (M

IBK

) 23

L

63

-133

L

3.

19

NA

St

yren

e*

22

L

52-1

20

L

074

NA

1,

1,2,

2-T

etra

chio

roet

hanc

17

L

77

-ill

L

0,68

N

A

Tct

rach

loro

ethe

ne

14

L

8 1-

110

L

082

NA

T

olue

ne

23

L

75-1

22

L

1,05

N

A

1,1,

1-T

richl

oroc

than

c 13

L

8 1-

110

L 0.

72

NA

1,

1,2-

Tric

hlor

octh

anc

14

L 84

-1 1

4 L

0.53

N

A

Tri

chlo

roct

hcnc

10

L

75

-115

L

0.74

N

A

Tri

chlo

rofl

uoro

mct

hanc

15

L

82

-1 1

3 L

0.

79

NA

V

inyl

acc

tate

21

L

83-1

25

L

0.65

N

A

Vin

yl c

hlor

ide

24

L

56-1

52

L

0,68

N

A

Xyl

cnes

(to

tal)

* 17

L

83-1

18

L

0.54

N

A

t

Eth

ylen

e D

ibro

mid

e lO

..6

I i

I

25

1,

L 81

-135

I

L

I I

1.40

I

NA

I

c-I

f

f

,

I

I

I

I

t

I

I

(

(

I

I

(

'q

(

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ion:

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ve

Rev

isio

n N

o. :

Dat

e:

10/1

5/95

Page

: 29

of 6

9 T

AB

LE

S-5

D

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A Q

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LIT

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CT

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S C

C /M

S V

OL

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S (c

ontin

ued)

Mct

hod

Mat

rix

Ana

lyte

/Com

pone

nt

Prec

isio

n'

Con

c.

Accuracy2

Con

c.

MD

L

Ran

ge

gLL

m

gçg

EPA

624

W

A

PPE

ND

IX I

X

SW84

6 82

40

AD

DE

ND

UM

A

ceto

nitr

ile

3g

L

26-1

02

L

17

NA

B

is(2

-chl

oroc

thox

y)m

etlia

n&'

20

L

40-1

60

L

0.80

N

A

2-C

hlor

o-1,

3-B

utad

ienc

68

L

34

-170

L

4

NA

(C

hior

opre

ne)

3-C

hlor

opro

penc

29

L

51

-Ill

L

0.5

NA

(A

lly!

Chl

orid

e)

Chi

orom

ethy

lmet

hyl

ethe

r 20

L

40

-160

L

1.

2 N

A

Cyc

lohe

xane

" 20

L

40

-160

L

1.

6 N

A

1,2-

Dib

rom

o-3-

chlo

ropr

opan

c 16

L

99

-132

L

0.

9 N

A

tran

s-1,

4-D

ichl

oro-

2-bu

tcnc

38

L

3

1-10

8 L

2

NA

1,

4-D

ioxa

nc

20

L

84-1

24

L

44

NA

E

thyl

met

hacr

ylat

e 10

L

67

-88

L

0.6

NA

lo

dom

etha

ne

13

L

83-1

10

L

0.7

NA

. Is

obut

yl A

lcoh

ol

29

L

77-1

36

L

132

NA

Is

opro

pano

l 20

L

L

10l6

0 L

16

N

A

Isop

renc

H

20

L

40-1

60

L

1.2

NA

M

ctha

cryl

onitr

ilc

52

L

30-1

33

L

6 N

A

Met

hyl

met

hacr

ylat

e 9

L

79-9

7 L

0.

5 N

A

Prop

ioni

trile

(E

thyl

Cya

nidc

) 20

L

70

-130

L

6.

9 N

A

1,1,

1,2-

Tet

rach

loro

etha

nc

7 L

68

-82

L

0.4

NA

l,2

,3T

rich

loro

prop

anc

12

L

78-1

04

L

0.7

NA

1,

I,2-

Tri

chlo

ro-1

,2,2

- 15

L

56

-138

L

i

NA

tr

iflu

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c.n -J

Sect

ion:

Fi

ve

Rcv

sion

No.

:20

Dat

e:

10/1

5/95

Page

: 30

of69

T

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LE

5-5

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A Q

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S (c

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Met

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Mat

rix

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/Con

ipon

ent

Piccisiont

Con

e.

Accuracy2

Con

c,

MD

L

1I2

ßgç

L

mg/

kg

SW84

6 82

40

S A

ceto

ne

1g

L

80-1

20

L

NA

1.

63

Acr

olei

n 11

L

87

-119

L

N

A

4.70

A

cryl

ortit

rile

18

L

21

-12g

L

N

A

7.89

13

en2:

cnC

13

L

87

-114

L

N

A

0.62

B

rom

odic

hior

omet

hane

21

L

67

-ill

L

NA

0.

64

Bro

mof

omi

22

L

58-1

25

L

NA

0.

63

l3ro

mom

etha

ne

i

L

7-1

10

L

NA

0.

68

2-B

utan

one

(ME

K)

17

L

5-1

19

L

NA

1,

98

Car

bond

isul

fide

9

L

81-1

25

L

NA

0.

66

Car

bon

tetr

achl

orid

c 18

L

66

-125

L

N

A

0.58

C

hlor

oben

zene

21

L

72

-115

L

N

A

1.88

C

hlor

oeth

ane

11

L

82-1

14

L

NA

0.

62

2-C

hior

oeth

yl v

inyl

eth

er

15

L

80-i

ll L

N

A

0.54

C

hlor

ofor

m

15

L

87-I

il

L

NA

0,

52

Chl

orom

etha

nc

18

L

79-1

15

L

NA

0.

64

Dib

rom

omet

hari

e 15

L

87

-141

L

N

A

0.56

D

ibro

moc

hlor

omet

hane

16

L

71

-125

L

N

A

1.40

1.2-Dichlorobcnzcne1

15

L

73-1

25

L

NA

0.

58

1,3-Dichlorobcnzcnc7

15

L

77-1

19

L

NA

0.

70

1,4-Dichlorobcnzcne7

15

L

74-1

22

L

NA

0.

78

Dic

hlor

odif

luor

omct

hanc

12

L

79

-105

L

N

A

0.89

1,

1-D

ichl

oroc

than

c 12

L

87

-112

L

N

A

0.63

1,

2-D

ichl

oroe

than

e 16

L

78

-1 1

0 L

N

A

0.60

1,

1-D

ichl

oroe

then

c 28

L

60

-145

L

N

A

0.58

tr

ans-

1,2-

Dic

hlor

octh

ene

10

L

81-1

07

L

NA

0.

74

1,2-

Dic

hlor

opro

pane

13

L

88

-109

L

N

A

0.70

ci

s-1,

3-D

ichl

orop

ropc

nc

14

L

74-1

25

L

NA

0.

40

t t

t I

t i

I

(

i

1 1

I I

(

t t

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Rev

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n N

o. :

Dat

e:

10/1

5/95

Page

: 31

of 6

9 TABLE 5-5

DATA QUALITY OI3JECTL VES

GC IMS VOLATILE ORGANICS

(con

tinue

d)

Method

Mat

rix

Ana

lyte

/Com

pone

nt

Prec

isio

n'

Con

c.

Accuracy2

Con

ç M

DL

R

amze

R

ange

gL

m

g/lg

SW84

6 82

40

S tr

ans-

1,3-

Dic

hlor

opro

penc

14

L

74

-125

L

N

A

0.47

(C

ontin

ued)

E

thyl

bcnz

cne

14

L

74-1

25

L

NA

0.

64

2-H

exan

one

17

L

87-1

29

L

NA

2.

20

Met

hyle

ne c

hlor

ide

22

L

86-1

30

L

NA

0.

62

4-M

ethy

I-2-

pcnl

anon

c(M

IBK

) 12

L

90

-125

L

N

A

3.19

St

yrcn

c 21

L

57

-122

L

N

A

0.74

1,

l,2,2

-Tct

rach

loro

ctha

nc

24

L

71-1

17

L

NA

0.

68

Tet

rach

ioro

ethe

ne

10

L

80-1

07

L

NA

0.

82

Tol

uene

12

L

85

-109

L

N

A

1.05

l,1

,1-T

rich

loro

ctha

ne

12

L

83-1

08

L

NA

. 0.

72

11,2

-Tri

chto

roet

hane

19

L

75

-1 1

3 L

N

A

0.53

T

nchl

oroc

thcn

e 19

L

64

-103

L

N

A

0.74

T

rich

loro

fluo

rom

etha

nc

18

L

82-1

18

L

NA

0.

79

Vin

yl a

ceta

te

10

L

90-1

17

L

NA

0.

65

Vin

yl c

hlor

ide

24

L

71-1

19

L

NA

0.

68

Xyl

cnes

(to

tal)

10

L

80

-106

L

NA

0.

54

Eth

ylen

e D

ibro

mid

e'°

25

L

8 1-

135

L

NA

1.

40

c-J,

r)

c-11

LO

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Sect

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Fi

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Rev

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n N

o, :2

0 D

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10

115/

95

Page

: 32

of69

T

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DA

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QU

AL

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OB

JEC

TIV

ES

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¡M

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(.71

Mat

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/Com

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Prec

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n'

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onc.

M

DL

%ISI)

Ran

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llLL

m

gg

SW84

6 82

40

S A

PPE

ND

IX IX

A

DD

EN

DU

M

Ace

toni

trile

38

L

26

-102

L

N

A

17

2-C

hlor

o-1,

3-B

utad

ienc

68

L

34

-170

L

N

A

4 (C

hior

opre

nc)

3-C

hlor

opro

penc

29

L

51

-111

L

N

A

0.5

(Atly

l C

hlor

idc)

l,2

-Dib

roni

o-3-

chlo

ropr

opan

e 16

L

99

-132

L

N

A

0.9

tran

s-1,

4-D

ichl

oro-

2-bu

tcL

le

38

L

31-1

08

L

NA

2

1,4-

Dio

xane

20

L

84

-124

L

N

A

44

Eth

yl r

ncth

acry

la(c

10

L

67

-88

L

NA

0.

6 lo

dom

etha

ne

13

L

83-1

10

L

NA

0.

7 Is

obut

yl A

lcoh

ol

29

L

77-1

36

L

NA

13

2 M

etha

cryl

onitr

ilc

52

L

30-1

33

L

NA

6

Met

hyl

met

hacr

ylat

e 9

L

79-9

7 L

N

A

0.5

1,l,1

,2-T

ctra

chlo

roct

hanc

7

L

68-8

2 L

N

A

0.4

1,2,

3-T

rich

loro

prop

anc

12

L

78-1

04

L

NA

0.

7

'I I

i

I t

I I

I I

t I

t t

I

f i

t I

I I

I I

(

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I

(

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Fi

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Rev

isio

n N

o. :

Dat

e:

10/1

5/95

Page

: 33

of69

T

AB

LE

5-5

D

AT

A Q

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Y O

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CT

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S C

C /M

S V

OL

AT

ILE

OR

CA

NIC

S (c

ontin

ued)

Met

hod

Mat

rix

Ana

lytd

Com

ponc

nt

Precision1

Con

c.

Accuracy2

Con

c.

MD

L

JL)

Prng

Bìf

lg

mgJ

kg

SW84

6 82

40

S A

ceto

ne

15

H

87-1

15

1-1

NA

5.

8 A

crot

cin

15

H

87-1

19

H

NA

5.

9 A

cryl

onitr

ile

36

H

21-1

28

H

NA

8.

4 B

enze

n:e

18

H

83-1

19

H

NA

0,

7 B

rom

odic

hior

omet

hane

22

H

67

-1 1

1

H

NA

0.

7 B

rom

ofor

m

10

H

58-1

25

H

NA

0.

3 B

rorn

ornc

than

c 20

H

63

-125

H

N

A

0.8

2-B

utan

one(

ME

K)

23

1-1

76-1

23

H

NA

9.

5 C

arbo

n di

sulf

ide

24

H

75-1

45

H

NA

1.

0 C

arbo

n tc

trac

hlor

ide

21

H

75-1

35

H

NA

0.

9 C

hlor

obcn

zcne

21

H

72

-115

H

N

A

0.4

Chl

oroc

than

e 25

H

67

-1 1

7 H

N

A

0.7

2-C

hior

oeth

yl v

inyl

eth

er

IS

H

80-1

11

H

NA

1.

0 C

hlor

ofor

m

15

H

87-1

11

H

NA

0.

4 C

horo

mct

hane

20

H

71

-112

H

N

A

0.8

Dib

rom

oine

than

e IS

H

87

-141

H

N

A

0.14

D

ibro

moc

:hlo

rom

ctha

nc

14

H

69-1

25

H

NA

0.

3 I.2-Dichlorobenzenc7

IS

1-1

73-1

25

I-1

NA

0.

06

1,3-Dichlorobcnzcnc7

15

H

77-1

19

H

NA

0.

07

1,4-Dichlorobcnzene1

15

H

74-1

22

H

NA

0.

08

Dic

htor

odif

luor

omet

hanc

12

H

79

-105

H

N

A

0.8

1,1-

Dic

hlor

oeth

ane

18

H

85-1

23

1-1

NA

0,

3 1,

2-D

ichl

oroe

than

e 22

H

78

-1 1

0 H

N

A

0.9

1,1-

Dic

hlor

octh

ene

25

H

66-1

20

H

NA

0.

6 tr

ans-

1,2-

Dic

hlor

octh

cne

18

H

81-1

07

1-1

NA

0.

8 1,

2-D

ichl

orop

ropa

ne

13

H

88-1

09

H

NA

0.

1

t',

o'

Sect

ion:

Fi

ve

Rev

isio

n N

o. :2

0 D

ate:

W

/15/

95

Page

: 34

of69

T

AB

LE

5-5

D

AT

A Q

UA

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Page

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o. :2

0 D

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10

/15/

95

Page

: 38

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16

64-1

22

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02

53-1

07

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22-1

5 8

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6

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4 33

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isio

n N

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95

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: 46

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Con

c.

MD

L

BaE

! (u

gf Ji

m f

kg

L

0.00

68

L

0.78

12

L

1.40

L

0.

5241

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0.

4295

L

0.

5419

L

0.

1852

L

0.

0996

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0.

1362

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0.

3651

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0.04

L

0.

05

L

0.07

L

0.

04

L

0.04

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0.

40

L

0.06

L

0.

07

L

0.05

L

0.

06

L

0,05

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0.

05

L

0.05

L

0.

06

L

0.05

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95

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: 47

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MD

L

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(ugJ

L/m

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' SW

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36

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0.

08

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aphc

nc

3 1

L

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74

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16

L

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6 81

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25

-1 1

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rich

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20

L

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20

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23

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0.09

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Accuracy2

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c.

MD

L

Rfl

Rngc

jge

(u/L

/mW

kg)

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6814

0 W

Fc

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onth

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20

L

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41

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64

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5 D

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al

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64

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onne

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6 M

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63-1

89

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9 Fe

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20

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18

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50

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: 49

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A Q

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Accuracy2

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c.

MD

L

jge

(uL

/mg)

33

L

22

-105

L

03

1 20

L

40

-160

L

1.

25

20

L

40-1

60

L

0.89

20

L

40

-160

L

0.

05

20

L

40-1

60

L

0.88

20

L

40

-160

L

0.

35

20

L

40-1

60

L

56.3

2 20

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40

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L

55

.10

35

L

28-1

25

L

0.06

29

L

40

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0.

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35

L

35-1

50

L

0.44

20

L

40

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L

0.

71

20

L

40-1

60

L

0.35

20

L

40

-160

L

0.

04

20

L

40-1

60

L

0.42

20

L

40

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L

0.

16

20

L

40-1

60

L

21.7

20

L

40

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21

.5

27

L

40-1

25

L

0.03

29

L

40

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05

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51

W

SW84

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CC

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MI-

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RC

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L

74

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zon

345

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70-1

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11

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9 L

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5-T

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Sect

ion:

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ve

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isio

n N

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95

Page

: 50

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Con

c.

MD

L

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(ugf

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0.

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L

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0.70

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0.

02

L

0,04

4 L

0.

061

L

1.0

L

0.63

L

0.

04

L

77

L

76

L

0A3

L

0.01

2 L

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L

0.09

L

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L

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0.09

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0.

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L

0.

19

L

0,26

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j D

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10

/15/

95

Page

: 51

of 6

9 T

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L

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Urn

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846

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18

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50.1

506

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0.00

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L

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n N

o.:2

0 D

ate:

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/15/

95

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: 52

of69

.

TA

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0.45

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Fi

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Rev

isio

n N

o. :j

Q

Dat

e:

10/15/95

Page

: 53

of 6

9 T

AB

LE

5-7

D

AT

A Q

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(continued)

Met

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Mat

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/Com

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Prec

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Con

e.

Accuracy2

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e.

MD

L

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(ug/L/mg/kg)

SW84

6 83

10

S D

iben

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23

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28.3

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50-150

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50-150

L

29.7

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L

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L

26.6

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thre

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50

L

10-155

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18.6

1 Py

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L

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846

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o. :2

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9 T

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2.

6 Fl

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60-1

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13

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: 60

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/15/

95

Page

: 61

of 6

9 T

AB

LE

5-8

D

AT

A Q

UA

LL

TY

OB

JEC

TiV

ES

CC

/MS

SEM

I-V

OL

AT

ILE

OR

CA

NIC

S (coitiud)

Met

hod

Mat

rix

Ana

lyte

/Com

pone

nt

Precision1

Con

c.

Accuracy2

Con

e.

MD

L

iRD

Ran

ge

?'i1

Ran

ge

(ug/

L/m

g/kg

)

SW84

6 82

70

W

APP

EN

DIX

IX

(B

NA

s)

AD

DE

ND

UM

(C

ontin

ued)

o-

Tol

uidi

nc

25

L

48-9

9 L

I

0,0,

0-T

riet

hyl-

15

L

54

-85

L

2 Ph

osph

orot

hioa

te

l,3,5

-Tri

nitr

obcn

zcnc

20

L

5-

85

L

i

Isod

rin

12

L

86-1

14

L

9 K

epon

c 35

L

67

-141

L

14

0 T

hion

azin

16

L

85

-123

L

15

M

ethy

l Pa

rath

ion

21

L

80-1

32

L

20

Dis

ulfo

ton

14

L

46-7

5 L

Pa

rath

ion

11

L

87-1

14

L

11

Fzui

iphu

r 51

L

27

-131

L

19

Ph

orat

e 20

L

27

-62

L

2 Pe

ntac

hlor

octh

ane

22

L

12-5

8 L

7

Sulf

otep

p 17

1

29-6

4 L

13

EPA

625

W

D

ioxi

n Sc

reen

N

on-Q

uant

-

-

-

-

(Sel

ectiv

e Io

n M

onito

ring

)

SW84

6 82

70

S A

ccna

phth

enc

22

L

34-1

22

L

0.13

(B

NA

s)

Ace

naph

thyl

cnc

21

L

29-1

22

L

0.15

A

nthr

acen

c 35

L

22

-130

L

0.

17

Ben

zidi

ne

15

L

l-22

L

0.

30

Bcn

zo(a

)ant

hrac

cnc

39

L

23-1

02

L

0.13

H

enzo

(b)f

luor

anth

ene

25

L

23-1

24

L

0.18

B

enzo

(k)f

luor

anth

ene

35

L

20-1

27

L

0.13

o

(ji

C-D

Met

hod

Mat

rix

Ana

lyte

/Com

pone

ni

TA

BL

E 5

-8

DA

TA

QU

AL

ITY

OB

JEC

fIV

ES

CC

/MS

SEM

I-V

OL

AT

ILE

OR

GA

NIC

S (continucd)

Precision1

Con

c.

Accuracy2

SW84

6 82

70

S B

en.z

o(g,

h,i)

pery

lene

65

(B

NA

s)

Ben

zo(a

)pyr

cnc

35

(Con

tinue

d)

Ben

zyl

alco

hol

35

bis(

2-C

hlor

oiso

prop

yl)c

ther

26

(2

,2-O

xybi

s (1

-Chl

orop

ropa

nc)

bis(

2-E

thyl

hcxy

l)ph

thal

atc

35

4-B

rorn

ophe

nyl

phen

yl e

ther

35

But

yl b

enzy

l ph

thal

atc

38

2-C

hlor

onap

htha

lenc

23

4-C

hlor

ophc

nyl

phen

yl c

thcr

43

C

hrys

ene

30

Dib

cnzo

(a,h

)ant

hrac

cnc

48

Di-

n-bu

tyl

phth

alat

e 25

I

2-D

ich1

orob

cnze

ne

43

i ,3

-Dic

hlor

obcn

zcnc

43

I ,4

-Dic

:hlo

robn

czcn

e 43

3,

3'-I

jicht

orob

enzi

dine

45

Die

thyl

phth

alat

c 43

Dim

cthy

lpht

hala

te

44

2,4-

Din

itrot

olue

ne

4 1

2,6-

Din

itrot

olue

nc

4 I

Di-

n-oc

tylp

htha

late

3

1

Fluo

rant

hene

27

Fl

uore

nc

30

Hex

achl

orob

enze

ne

37

Hcx

achi

orob

utad

jcnc

33

Hex

achl

oroc

yclo

pent

adie

ne

3 1

Hex

achl

oroe

than

e 25

ç t

I I

i

1u IE

';

L

L

L

L

L L

L

L L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

10-1

50

22-1

26

21-1

63

34-1

14

11-1

00

5 1-

122

7-12

2 50

-125

37

-124

16

-107

22

-216

2

8-10

3 20

-132

20

-132

20

-132

10

-146

12

-143

26

-115

10

-119

10

-1 1

9

14-9

3

20-1

4 8

20-1

3 8

2 2-

108

24-1

16

2-55

8-

80

Con

c.

Bg L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

L

Sect

ion:

Fi

ve

Rev

isio

n N

o. :2

0 D

ate:

10

/151

95

Page

: 62

of 6

9

MD

L

(uL

/mgf

kg

0.13

0.

16

0.21

0.

14

0.18

0.

12

0.16

0.

16

0.13

0.

12

0.14

0.

14

0.15

0.

14

0.16

0.

14

0.18

0.

12

0.17

0.

13

0.20

0.

31

0.13

0.

11

0.16

0.

16

0.17

I f

(il r)

'z,

t f.

i

r

i

i

i

u

i

i

i

i

i

¿

i

(

'

(

Sect

ion:

Fi

ve

Rev

isio

n N

o.:2

0 D

ate:

10

/15/

95

Page

: 63

of 6

9 T

AB

LE

5-8

D

AT

A Q

UA

LIT

Y O

BJE

CT

IVE

.S

CC

/MS

SEM

I-V

OL

AT

ILE

OR

GA

NIC

S (couthnied)

Met

hod

Mat

rix

Ana

lyte

/Com

pone

nt

Prccision1

Con

c,

Acc

urac

y C

onc.

M

DL

RQ

ß

Q

SW84

6 82

70

S In

dcr*

o(l,2

,3-c

d)py

rcnc

50

L

22

-200

L

0i

6 (B

NA

s)

Isop

horo

ne

50

L

22-2

00

L

0. 1

1

(Con

tinue

d)

1-M

ethy

lnap

htha

lcne

31

L

15

-1 1

1 L

01

3 2-

Met

hyln

apht

halc

nc

31

L

IS-i

ll L

0.

10

Nap

htha

lcne

21

L

29

-112

L

0.

14

2-N

itroa

nilin

c 42

L

32

-165

L

0.

16

3-N

itroa

nilin

c 4g

L

31

-177

L

0.

17

4-N

iroa

ni1i

nc

47

L

38-2

29

L

0.22

N

itrob

enze

ne

31

L

10-1

01

L

0.14

n-

Nitr

oso-

dim

cthy

lam

inc

21

L

13-6

5 L

0.

30

n-N

itros

o--d

iphc

nyla

min

c 31

L

28

-121

L

0.

30

n-N

itros

o-di

-n-p

ropy

larn

inc

44

L

25-1

14

L

0.21

Ph

enan

thre

ne

35

L

22-1

27

L

0.16

Py

rcn

26

L

38-1

41

L

0.15

1,

2,4-

Tri

chlo

robe

nzcn

c 24

L

38

-136

L

0.

16

Ben

zoic

aci

d 34

L

16

-72

L

0.50

4-

Chl

oro-

3-m

ethy

lphe

nol

35

L

29-1

01

L

0.19

2-

Chl

orop

hcno

l 29

L

19

-100

L

0.

10

2,4-

Dic

hior

ophe

nol

32

L

16-1

14

L

030

2,4-

Din

icth

ylph

cnol

30

L

26

-100

L

0.

30

2,4-

Din

itrop

heno

l 34

L

9-

96

L

0.20

2-

Mct

hyl-

4,6-

dini

trop

hcno

l 32

L

15

-100

L

0.

30

2-M

cthy

lphc

nol

32

L

10-1

03

L

0.30

4-

Mct

hylp

heno

l 32

L

10

-103

L

0.

30

2-N

itrop

heno

l 29

L

16

-103

L

0.

20

4-N

itrop

heno

l 58

L

10

-147

L

0.

70

Pent

achl

orop

heno

l 39

L

10

-1 1

2 L

0.

20

Phen

ol

24

L

15-1

12

L

0.30

Sect

ion:

Fi

ve

Rev

isio

n N

o. :2

0 D

atc:

10

/15/

95

Page

: 64

of69

TABLE 5-8

DATA QUALITY OBJECTIVES

GC/MS S

EM

I-V

OL

AT

ILE

OR

GA

NIC

S (coitiiiud)

Met

hod

Mat

rix

Ana

lyte

/Com

pone

nt

Prcc

isio

n'

Con

c.

Accuracy2

Con

e.

MD

L

Ran

ge

B1!

1iQ

(u

WL

/mgl

kg)

SW84

6 82

70

W

2,4,

5-T

rich

ioro

phen

ol

41

L

13-1

36

L

0.40

B

NA

s 2,

.4,6

-Tri

chlo

roph

cnol

30

L

2

1-1

12

L

0. 1

1

(Con

tinue

d)

bis(

2-C

hlor

octh

oxy)

met

hanc

46

L

19

-113

L

0.

12

bi(2

-Ch1

oroe

thyI

)cth

cr

54

L

10-1

38

L

0.30

1,

2-D

iphe

nyih

ydra

zine

5

L

67 -

91

L

0.

06

SW84

6 82

70

S A

PPE

ND

IX I

X

AD

DE

ND

UM

A

ceto

phen

one

23

L

50-9

6 L

0.

1 2-

Ace

tyla

min

oflu

oren

e 24

L

65

-1 1

4 L

0.

4 4-

Arn

inob

iphe

nyl

36

L

32-1

06

L

0.2

Ani

linc

17

L

43-9

1 L

0.

28

Ara

mite

1

50

L

33-1

03

L

0.1

Ara

mite

2 46

L

10

-65

L

0.1

2-se

c-B

utyl

-4,6

-din

itrop

hcno

l 40

L

63

-145

L

0.

1 (D

inos

eb)

4-C

hlor

oani

line

17

L

43-9

1 L

0.

2 C

hlor

oben

zila

te

23

L

20-6

6 L

0.

2 D

iaH

ate

1 17

L

48

-83

L

0.1

Dia

llate

2

20

L

52-9

2 L

0.

1 D

ibcn

zofu

ran

11

L

85-1

17

L

0.1

2,6-

Dic

horo

phcn

oI

14

L

73-l

OI

L

0,2

Dim

etho

ate

44

L

10-6

5 L

0.

4 p-

(Diin

cthy

larn

ino)

azob

cnze

ne

19

L

18-5

7 L

0.

1 71

2-D

irne

tliyl

benz

[ala

utiu

-ace

ue

23

L

24-7

1 L

0.

1 3,

3-D

imet

hyl

bcnz

idin

c 55

L

10

-9 1

L

0.3

a,a-

Dim

ethy

lphc

neth

ylam

ine

31

L

22-8

5 L

0.

7 m

-Din

itrob

cnzc

nc

18

L

12-2

4 L

0.

2

"1

I I

I 'I

I I

I I

I I

i

i

I

t I

'I I

I I

I I

I I

(:

I'

(

Sect

ion:

Fi

ve

Rev

isio

n N

o. :j

Q

.

Dat

e:

10/1

5/95

Page

: 65

of 6

9 T

AB

LE

5-8

D

AT

A Q

UA

LIT

Y O

BJE

CT

IVE

S

CC

/MS

SEM

I-V

OL

AT

ILE

OR

GA

NIC

S ( cotflinucd)

Met

hod

Mat

rix

aIyt

c/C

ornp

onen

t Precision1

Con

c.

Accuracy2

Con

c.

MD

L

%S1)

ßiin

ie

Ran

g (u

g/L

/mg/

kg)

SW84

6 82

70

S A

PPE

ND

iX I

X

(Con

tinue

d)

AD

DE

ND

UM

Dip

heny

tarn

ine

[3

L

39-6

6 L

0.

1 E

thyl

met

hane

sulf

onat

e D

L

40

-67

L

0.3

Hex

achi

orop

hene

50

L

10

-110

L

76

2 H

exac

hior

opro

penc

11

L

44

67

L

0.1

Isos

afro

lc 1

16

L

26

-59

L

0.1

Isos

afro

le 2

21

L

19

-63

L

0.1

Met

hapy

rilc

nc

21

L

26-6

9 L

0.

3 3-

Met

hylc

hola

nthr

cne

8 L

16

-33

L

0.3

3-M

ethy

lphe

nol

23

L

50-9

7 L

0.

1 M

ethy

l m

etha

nesu

lfon

ate

13

L

37-6

4 L

0.

3 1,

4-N

apht

hoqu

inon

e 25

L

13

-37

L

0.2

1-N

apht

hyla

min

e 19

L

40

-78

L

0.2

2-N

apht

hyla

min

c 16

L

39

-72

L

01

4-N

itroq

nino

line-

I-ox

idc

10

L

34-8

8 L

0.

2 n-

Nitr

osod

i-n-

buty

larn

inc

30

L

64-1

24

L

0.2

n-N

itros

odie

thyl

amin

e 15

L

40

-170

L

0.

5 n-

Nitr

osom

ethy

leth

ylam

inc

22

L

43-9

0 L

0.

1 n-

Nitr

osom

orph

olin

e 25

L

42

-94

L

0.1

n-N

itros

opip

erid

ine

16

L

45-7

8 L

0.

1 n-

Nitr

osop

yrro

lidin

e 26

L

46

-98

L

0.1

n-N

itro-

o-to

luid

ine

12

L

60-1

40

L

0.!

Pent

achl

orob

enze

ne

15

L

55-8

7 L

0.

1 Pc

ntac

hlor

oriit

robe

nzen

c 23

L

50

-96

L

0.6

Phcn

acet

in

15

L

75-I

SO

L

0.2

N.)

(ji

r-o

(J.)

Scci

on:

Five

R

evis

ion

No.

:20

Dat

c:

10/1

5/95

Pa

ge:

66of

69

TA

BL

E 5

-8

DA

TA

QU

AL

ITY

OB

JEC

TIV

ES

CC

/MS

SEM

I-V

OL

AT

ILE

OR

GA

NIC

S (continued)

Met

hod

Mat

rix

Prec

isio

n'

Con

c.

Accuracy2

Con

c.

MD

L

ßL)

Ran

ge

(ug/

Um

g/kg

SW

846

8270

S

APP

EN

DIX

IX

(C

ontin

ued)

A

DD

EN

DU

M

p-Ph

cny1

encd

iani

nc

21

L

47-8

9 L

0.

4 2-

Pico

line

20

L

51-9

1 L

0.

6 Pr

onar

nide

26

L

60

-114

L

0.

1 Py

ridi

nc

22

L

63-1

05

L

0.2

Safr

ole

14

L

31-6

0 L

0.

1

1.2.

4.5-

Tct

rach

loro

bcnz

enc

19

L

48-8

6 L

0.

1 2.

3.4.

6-T

ctra

chlo

roph

cnol

44

L

39

-128

L

0.

2 o-

Tol

uidi

nc

25

L

48-9

9 L

0.

1 0,

0,0-

Tri

ethy

l-

15

L

54-8

5 L

0.

1 Ph

osph

orot

hioa

tc

1,3,

5-T

rini

trob

cnzc

nc

20

L

5-85

L

0.

1 Is

odri

n 12

L

86

-114

L

. 0.

3 K

epon

e 35

L

67

-141

L

4.

0 T

hion

azin

16

L

85

-123

L

0.

4 M

ethy

l Pa

rath

ion

21

L

80-1

32

L

0.6

Dis

ulfo

ton

14

L

46-7

5 L

0.

1 Pa

rath

ion

11

L

87-1

14

L

0.3

Fam

phur

51

L

27

-131

L

0.

5 Ph

orat

e 20

L

27

-62

L

0.1

Pent

achl

oroe

than

e 22

1

12-5

8 1

0.15

Su

lfot

cpp

17

L

29-6

4 L

04

3

EPA

625

S

Dio

xin

Scre

en

Non

-Qua

nt

-

-

-

-

Sele

cted

Ion

M

onito

ring

(

I I

I I

I I

i

I I

I

t

Data Quality Objective Table Notations and Explanations

524 5

Section: Five Revision No. :Q Date: 10/15/95

Page: 67of69

The following notations are used throughout the data quality objectives tables to convey the following explanations as listed below.

Notation ExplanatiQfl

Relative Percent Difference (R.PD) unless otherwise noted -

2 Percent recovery unless otherwise noted. 3 Method detection limits are not applicable to this analysis. 4 In-house generated limits from the North Canton/Corporate facility. These limits will be

- updated with limits from the Florida fcility database as they are acquired with a maximum time frame of one year from date of Comprehensive QAP approval.

5 Method limits or targets. -

6 Advisory limits or targets. 7 Parameter is only listed under EPA 600 senes ofanalytical methods. 8 Parameter is only listed under EPA SW 846 series ofanalytical methods.

- 9 These additional parameters are analyzed by this method for the full Appendix IX analytical list.

10 This parameter is only analyzed by this method upon special request. - 11 This parameter is supported by a method validation study found in Appendix E or

Appendix H. 12 Laboratory established control limits from CompQAP 8150 list.

- 13 Limits calculated based on water MDL's.

Data Quality Objective Table References

The following sources have been used to obtain the analytical methods identified in the data quality objective tables.

40 CFR Part 136, Appendix A, Test Procedures for Analysis of Organic Pollutants, July 1989

DER-SOP for Unionized Animonia, Rev. 1, 10/3/83

Methods for Chemical Analysis ofWater and Wastes. EPA 600/4-79-020. Revised March 1983.

Methods for the Determination of Organic Compounds in Drinking Water. EPA 600/4-88/039, December - 1988.

Procedures for Handling and Chemical Analysis of Sediments and Water Samples. EPAJCorps of Engineers CE-81-1. March 1981.

Standard Methods for the Examination pfWater and Wastewater. 18th Edition. 1992.

U;'-,. Test Methods for Evaluation Solid Waste - Physical/Chemical Methods. EPA/SW 846. 3rd Ethtion. 1986 and its Revision II Dated January 1995.

43

5?i 9f;

Parameter

Semi-Volatiles (Organics)

EPA 8080, 8140, 8141, 8270, 8310

Purgcabes (Volatile Organics)

SW846 8010,8020, 8240,8260

Ethylene Dibromide SW846 8010 (Mod.), 8240,8260

Metals (ICP) SW846 6010

Metals (GFAA) EPA 204.2(Sb), 213.2(Cd), 218.2(Cr), 239.2(Pb), 279.2(11)

Section: Five Revision No. :20 Date: 10/15/95 Page: 68 of 69

TABLE 5-9

SAMPLE PREPARATION METHODS SUMMARY

Matrix Prep Method Notes

WaterfLeachate EPA 3510, 3520

Solid EPA 3540, 3550

Waste EPA 3580

WaterlLeachate EPA 5030

Solid/Waste EPA 5030

Water/Leachate EPA 5030

Solid.!Waste EPA 5030

Water/Leachate EPA 3010

Solid/Waste EPA 3050 WaterfLeachate/Sojjd/ Waste EPA 3005

Water EPA 600/4-79-020, Paragraph 4.1

524 97 Section: Five Revision No. :Q Date: 1O/15/9 Page: 69of69 '., TABLES-9

SAMPLE PREPARATION METHODS SUMMARY - (continued)

Parameter Matrix Prep Method Notes

Metals (GFAA) - SW846 704 1(Sb), 7060(M) Water/Leachate EPA 3020 3

7131(Cd),7191(Cr), SolidfWaste EPA 3050 WaterfLcachate/

- 7421(Pb), Solid/Waste EPA 3005

7740(Se), 7841(1])

Halogens Solid/Vv'aste EPA 5050 (Draft) SW846 9252

- Hydrocarbons (TRPH) So1id/Wste EPA 9071

SW846 9073 (Draft)

Nitrate-Nitrite Solid!Waste EPA/CE pg 3-183

Nivate, Nitrite EPA 353.3

Total Kjeld.ahl Nitrogen Solid/Waste EPA/CE pg 3-20 1

EPA 351.3 ,1

Phosphorous Solid/Waste EPA/CE pg 3-223 (ortho) EPA 365.2 EPA/CE pg 3-227 (Total)

- EPA/CEpg3-232

Reactive Cyanide Waste EPA SW846 SW846 9010 7.3.3.2

Reactive Sulfide Waste EPA SW846

SW846 9030 7.3.4.2

SPLP Extract inn Water/Solid/Waste EPA SW846 1312 4

- TCLP Extraction Water/Solid/Waste EPA SW846 1311 4

EPTOX Extraction Water/Solid/Waste EPA SW846 1310 4

NOTES

1. For matrices which are classified as waste but are solid or aqueous in nature, the preparation method

appropriate to the nature of the sample may be used.

2. Method 3040 (solvent dissolution) may be used for certain projects. According to the nature of the project - requirements and nature of the samples.

3. EPA 7060 and EPA 7740 are prepared according to the methods and not EPA 3020

4. The leachate extracts can be analyzed by any method appropriate for the analysis of waters.

44

524 93

Section No.: Revision No.: Date: 10/15/95 Page: 1 of 42

6.0 Samplin2 Procedures

6.1 Sample Collection Guidelines

Quanterra Tampa offers full e1d sampling capabilities, as well as advises clients as to the proper handling of samples submitted to the laboratory. Upon request, the laboratory also provides sample containers for use by client sampling teams.

Quanterra Tampa references USEPA-approved and FDEP-recogrnzed sample collection methods and equipment for guidance in field activities as outlined in the following technical publications:

a) EPA Region ¡V Engineering Support Branch Standard Operating Procedures and Quality Assurance Manual (February, 1991)

b) FDEP-QAS Guidance Documents

c) FDEP Manual for Preparing Quality Assurance Plans (September 30, 1992)

The guidelines provided in this CompQAP as well as these references will be available to all field personnel both in-house and in the field.

6.2 Sampling Capabilities

Table 6-1 summarizes Quanterra Tampa's current sample collection capabilities by parameter group. Table 6-2 lists general sampling equipment used for most field sample collection events. Table 6-3 gives a summary of the sampling equipment utilized by Quanterra Tampa along with the intended matrix - parameters and restrictions associated with each piece of equipment.

45

524 9;

TABLE 6.-1

SAMPLING CAPABILITIES

Section No.: Revision No.: 13 - Date: 10/15/95 Page: 2 of 42

Major Analytical Group Matrix Group

Volatile Organics Drinking water, surface water, groundwater, wastewater, sediments, soils, liquid and solid hazardous wastes

Extractable Organics Drinking water, surface, water, groundwater, wastewater, sediments, soils, liquid and solid hazardous wastes

Metals Drinking water, surface water, groundwater, wastewater, sediments, soils, liquid and solid hazardous wastes

Inorganic Anions Drinking water, groundwater, surfàce water, wastewater, sediments, soils, liquid and solid hazardous waste

Organics Drinking water, groundwater, surface vater, wastewater, sediments, soils, liquid and solid hazardous waste

Physical Properties Drinking water, groundwater, surface water, wastewater, sediments, soils, liquid and solid hazardous waste

Microbiology Drinking water, groundwater, surface water, wastewater

Cyanide Drinking water, groundwater, surface water, wastewater, sediments, soils, liquid and solid hazardous waste

a

-

524 1.00

Section No.: Six Revision No.: U Date: 10/15/95 Page: 3 of 42

TABLE 6-2

GENERAL USE SAMPLING EQUIPMENT

Equipment Type Matrix

Orion SA2 i O Portable pH Meter \Vater pH Determination

Markson 200 Portable Conductivity Meter Water Conductivity Determination

YSI 5 lB Portable Oxygen Meter Water Field Dissolved Oxygen Determinations

NarrDw Range pH Paper Water Verification of Presentation Techniques

Tape Measure Water Well Depth Determination

Flow Meter Water Flow Rate Determination

Braided Nylon Cord Water Welt Purging and Bailing

Hand Pump Pressure Sprayers All Equipment Decontamination

Stainless Steel Buckets All Intermediate Container and Equipment Decontamination

Disposable Latex Gloves All Personnel Protection

Ice Chests All Sample Transportation

5 Gallon Plastic Bucket Water Well Purging (calibrated at 1 gallon intervals)

Century OVA 128 All Total Organic Vapor Portable Organic Vapor Analyzer Determination

Roctest Model Model CPR6 Water Well Water Level Water Level Indicator Determinations

Dayton Model 3W 178G Water Electrical Supply for Generator Grundfos Pump

Nalgene Carboy All Analyte-free Water Container

46

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Section No.: Revision No Date: Page:

NOTES & RESTRICTIONS

524 106

Six 13

10/15/95 9 of 42

1. When purging for organics or metals, the entire length of tubing (or pipe) or the portion which comes in contact with the formation water should be constructed of teflon or stainless steel. If other materials (i.e., rigid PVC, polyethylene or polypropylene) are used, the following protocols must be followed: 1) contact with formation waters will be minimized by slowly withdrawing the pump from the water column during the last phase of purging, thus removing from the well any water which has contacted the exterior of the pump and/or tubing; 2) a single well

volume must be removed with the sampling device before sampling begins. Tygon' must never be used for purging when organics are of interest.

2. Equipped with foot valve to prevent bacldlow of purged water into the well.

3. The flexible tubing used for the peristaltic pump should be medical grade silicone tubing. Delivery tubing must be constructed of suitable non-metallic materials.

4. Purging a well by bailer is not the preferred or recommended technique.

5. If sampling for metals analysis, equipment will be made of stainless steel or a suitable non-metallic parameter.

_,_, 6. Liner should be either stainless steel or teflon. Ifsa.mples are transported in liner to the laboratory, then VOC sample should be taken from the interior ofthe core.

7. Samples for Volatile Organic analysis should not be taken from a composited sample.

8. For extractible organics, Masterfiex Penstaltic Pump, used for purposes ofsampling extractible organics, must be configured as specified in Figure 4 . i O of DEP-QA-00 1/90.

49

524 tÚ;1

Section No.: i2 Revision No.: 13

Date: 10/15/95 Page: 10of42

6.3 Decontamination and CIeann Procedures

The decontamination and cleaning procedures outlined in this section are to be used by all sampling personnel to - clean sampling and other field equipment prior to use. Sufficient clean equipment should be transported to the field so that an entire event can be conducted without the need for cleaning equipment in the field. Equipment which is not cleaned in the field is immediately rinsed with tap water and tagged with sampling location for transport back to the lab for cleaning using in-house protocol. Field cleaning procedures are included to cover times when the amount of precleaned equipment available is insufficient to complete the sampling event. Specific cleaning and quality control procedures are presented in the following sections.

6.3.1 C1eanin Materials

a) Laboratory -standard brands of phosphate-free and ammonia-free laboratory detergent Detergent such as Liquinox.

b) Hydrochloric Acid -prepared from reagent grade hydrochloric acid and deionized water.

c) Nitric Acid -prepared from reagent grade nitric acid and deionized water.

d) Isopropanol -pesticide grade to be used as standard cleaning solvent. Other solvents may be substituted for a particular investigation iftheir use is deemed necessary.

e) Tap Water -obtained from any municipal water treatment system.

f) Analyte-free Water -water that has been treated in such a way as to be characterized as having no analytes of interest at or above the detection limit for those analytes. Analyte-free water may be deionized, distilled and/or "polished" with additional carbon beds.

g) Cleaning Brushes -brushes shall not be ofthe wire wrapped type and should be constructed of appropriate material which allows for sufficient scrubbing action in the presence of cleaning fluids while not compromising the integrity ofthe brush.

6.3.2 Decontamination and Cleaning Procedures for General Use Equipment

For those types ofequipment which are not ±rectly used for sampling, such as tape measures, probes, meters, etc., the basic cleaning protocol will be to scrub with soapy water, rinse thoroughly with tap water, then ari analyte-free water. Any equipment used in direct sampling procedures, such as buckets, trays, auto samplers, tubing, etc., should be cleaned as outlined in Section 6.3.3. Equipment which is not reused, such as bailer lanyards and disposable gloves, should be containerized and disposed ofproperly.

Analyte-free water containers will be either virgin sampling containers (see 6.3.4) or ofthe Naglene Carboy type. Reusable containers will be kept covered at all times and the exterior washed with laboratory detergent and analytr- free water as needed. Between uses, the interior shall be solvent rinsed twice with Isopropanol and then thorough rinsed with analyte-free water.

524 108

Section No.: 'Revision No.: 13 Date: 10/15195

Page: 11pf42

All ice chests and reusable shipping/transport containers will be washed with laboratory detergent (interior and

exterior) and rinsed with tap water and air-dried prior to storage. In the event of severe contamination, the container

will be subjected to the cleaning procedures used for field sampling equipment. If the container is still visibly

contaminated after cleaning, it will be removed from service and disposed of properly.

6.3.3 Decontamination and Cleaning Procedures for Field Sampling and Purging Eguipment

Controlled Procedures

1. Clean with hot soapy water using Liquinox detergent and scrubbing with a brush as necessary to dislodge

particulates and films.

2. Rinse thoroughly with hot tap water.

3. Rinse with 15% reagent grade hydrochloric acid. This step would be omitted for any metallic sampling equipment.

4. Rinse thoroughly with analyte-free water.

5. Rinse thoroughly with isopropanol.


__ 7. An in-house equipment blank will be taken for each batch ofequipment cleaned, with a maximum of 20

pieces ofequipnient per batch.

- 8. Allow all equipment to air dry before storage.

9. Carefully wrap equipment in aluminum foil for storage and transport to site.

Note: When sampling equipment has been exposed to samples containing oil, grease or other hard-to-remove materials, t may be necessary to rinse the equipment before step i above with pesticide-grade acetone,

- followed by pesticide-grade hexane then pesticide-grade acetone again.

- On-Site Procedures

i . Clean with soapy water using Liquinox detergent and scrubbing with a brush as necessary to dislodge

- particulates and films.


, 3. Rinse with 15% reagent grade hydrochloric acid. This step would be omitted for any metallic sampling equipment.

4, Rinse thoroughly with analyte-free water.

50

524

7

I O i

Section No.: Revision No: 13

Date: 10/15/95 Page: 12 pf42

Rinse thoroughly with isopropanol.

Rinse thoroughly with analyte-ftee water. If analyte-free water is not available, do not rinse with deionized -- or distilled water, but just allow to air dry as long as possible.

Allow all equipment to air dry as long as possible, then wrap with aluminum foil.

Note: When sampling equipment has been exposed to samples containing oil, grease or other hard-to-remove materials, it may be necessary to rinse the equipment before step I above with pesticide-grade acetone, followed by pesticide-grade hexane then pesticide-grade acetone again. If field equipment is heavily contaminated and cannot be cleaned by these procedures, then it should be discarded or stored until more rigorous methods may be employed at the base of operations.

Teflon Tubing Protocol

1. Soak all tubing completely in a non-contaminating container filled with hot soapy water. Brush or wipe 3way a'iy visible contaminations from the outside ofthe tubing as well as inside the ends.

2. Rinse tubing exterior and ends thoroughly with hot tap water, 15% reagent grade nitric acid, analyte-free water, isopropanol and analyze-free water.

3 . Using a field type pump, pump large quantities of hot soapy water and hot tap water through the connected tubing.

4. Again using the field type pump, pump the rinse reagents as described in (2) above through the tubing. Allow the add and solvent to remain in tubing for 15 minutes each before water rinses.

5. Rinse the exterior with analyte-free water once again and allow to air dry before storage.

6. Carefully wrap the tubing lengths in aluminum foil with connectors still attached for storage and transport to site.

Note: Ifthe tubing cannot be adequately cleaned by these or other procedures (three solvent rinses described above), then it will be removed from service and disposed of.

524 110

Section No.:

-- RevisionNo.: U Date: 10/15/95 Page: 13pf42

6.3.4 Procedures for ObtaininîSarnle Containers

.-. All sample containers are currently obtained in virgin condition. These containers meet the EPA anayte specific

concentration requirements for quality controlled sample containers. The cIean1iness" ofall containers is further verified through the analysis oftrip blanks, equipment rinsate blanks (outlined in Section 6.3.5) and an rn-house

verification program. The effectiveness of the sample container cleanliness and storage program will be spot checked by collecting analyte-free water in standard sample containers and submitting them to the laboratory for a series of routine trace organic and inorganic analyses. Non-trace level techniques (organic and inorganic) will only

- be performed if sample container contamination is indicated by other routine blanks. These container blanks will be

collected at a minimum of one set per manufctured lot and/or shipping lot of sample containers. All containers that have left the lab facility must be used by the sampler for that event or destroyed if returned unused. Records of

- vendor certification, receiving dates of container lots as well as results from equipment nnsate blanks and container blanks are maintained on-site.

- 6.3.5 Quali' Control Procedures for Cleanin! Operations

This section establishes guidelines for specific quality control procedures to monitor the effectiveness of the sampling equipment cleaning procedures and sample container cleanliness. These procedures shall be carried out by sampling personnèl and the results documented and monitored by the QA Manager.

- a) Rinsate Blank -the effectiveness ofthe cleaning procedures shall be monitored by nnsing cleaned equipment with analyte-free water and submitting the collected rinse water to the laboratory for analysis of routine trace metal, inorganic anions, and extractable and

- purgeable organic parameters. One piece ofequipment per equipment type shall be selected for this procedure each time equipment is cleaned.

.- The laboratory analysis ofall rinsate blanks must demonstrate that all analytes ofinterest are below the routine detection limit. Any necessary corrective action will be initiated by the QA Manager.

- 63.6 Handling and Stora!e of Cleaned Sampling Eiuipment and Containers

All equipment and sample containers that are cleaned utilizing these procedures shall be labelled with tiì cleaning

- date. Cleaned items will be stored in a contaminant-free environment and segregated from contaminated equipment. Sampling items returned unused from the field will be subjected to cleaning procedures prior to any subsequent use

or storage.

6.4 Sample Preservation, Holdin2 Times, Container Tvpes Required Sample Volumes

- Pre-preserved containers are provided to clients and utilized by field sampling crews. Bottles are labelled with the type of test(s) to be performed and with the type of preservative used, if any. Appropriate preservatives are also used for each test during the collection offield equipment and procedural quality control samples in order to

- monitor any contaminants that may be introduced by the preservative. The client/sampling crew receives

%_., instructions for filling each type ofcontainer provided, as well as additional preservative from the same source as that from which the containers were preserved. In the case of multiple preservatives, bottles and preservatives are

- supplied separately to f.cilitate the proper preservation procedure. Appropriate sample preservation, maximum

51

524 lii

Section No.: Six Revision No: U Date: 10/15/95 Page: 14of42

recommended holding times and container types, and required sample volumes are outlined by parameter group and matrix in Table 6-4 (Aqueous Matrices) and Table 6-5 (Non-Aqueous Matrices).

6.5 Sample Transportation

Sample coolers containing the appropriate bottles are provided to the client or acquired by the sampling team. Chain-of-custody documentation begins at this point by the release ofthe cooler/bottles to the sampling team. After sample collection, the containers are packed in wet ice and returned to the laboratory via persoriai delivery' or professional courier. Samples are delivered to the laboratory for analysis as soon as practical after sample - collection. (In general, less than twenty-four (24) hours will elapse before sample delivery.) The samples are properly preserved, packaged for transport, and accompanied by chain-of-custody documentation prior to shipment or transport to the laboratory. The samples are submitted to the designated sample custodian for proper acceptance - into the laboratory. The laboratory routinely uses professional courier services such as UPS or FedEx to ship bottles and samples. When using professiona! courier services, the bottles and/or coolers muse. be sealed with sample seals (see Section 7.1 .2.b and Figure 7-2). All shipping documents and receipts are maintained with the - project and/or client file. The laboratory also offers personal courier service to clients and accepts sample deliveries from client-chosen courier services.

6.5.1 Non-Hazardous Samples

Environmental samples are transported in commercially obtained high-density, polypropylene coolers. Proper - packaging of samples using foam and/or bubble-pack and wet ice is done ro prevent breakage. Watertight plastic bags are used to prevent sampling instructions, chain-of-custody records and other paperwork from being damaged.

6.5.2 Hazardous Samples

Hazardous samples as defined in the D.O.T. Hazardous Material Table (CFR 1 72. 1 0 1) are transported as specified in the regulations. Other potentially hazardous samples are packaged and shipped as follows:

Samples are placed in 32 oz. glass jars with ThE-lined lids or polyethylene bottles, as appropriate. All filled containers have sufficient air-space to allow for sample expansion. Samples to be analyzed for low-level volatile organics are placed in 40 mL vials with no headspace and with appropriate septum lids. The sample containers are then sealed in a polyethylene zip-lock bag. Bagged containers are placed inside a I gallon paint can surrounded by inert packing material (cg. vermiculite). The can is sealed and placed in a DOT-12B fiberboard box or equivalent and properly labelled in accordance with DOT specifications (49 CFR 172.10 1).

.6.6 Sample Coiledion Ouality Control Procedures

The following sample collection quality control standards and procedures must be followed during all sampling events.

6.6.1 Experience Requirements

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All Quanterra Tampa field personnel must have compteted four weeks of field training under supervision of a qualifed trainer on appropriate types of field studies before conducting similar sampling programs without supervision. During this period, the employee receives instruction in sample site selection, preparation of equipment and materials, sample collection techniques for various matrices, preservation and documentation procedures, packing and shipping of samples, and associated quality control procedures. All sampling personnel will be required

- to review and be familiar with all applicable protocols contained in this document and its associated references.

6.6.2 Documentation and Traceability Requirements

All sample collection activities are traceable through field records to the person collecting the sample and to the specific piece ofsanipling equipment used to collect the sample (where appropriate). In a similar fashion, all - maintenance and calibration records for sampling equipment are kept so that they, too, are traceable. SPecific types of field documentation maintained include sample custody forms (eg., sample labels, sample seals, and chains-of custody), and the fleid sample notebook. A more thorough discussion of documentation as well as sample forms is

found in Section 7.

6.6.3 Field Oualitv Control Samples

The following field quality control samples will be collected during field sampling events at a frequency which is

outlined in Section 11.1.

Trip Blanks

- To ensure the integrity of containers for volatile compounds a representative container is filled with analyte-free water, taken into the field with the empty sample containers, and returned for analysis without being opened. This sample is known as a trip blank. When feasible all sample aliquots for volatile compound analysis will be placed in

a separate shipping container such that only one trip blank per container will be needed. In these cases each site will be segregated by ziplock bags.

Equipment Blanks

If sampling equipment must be cleaned on-site and reused, equipment blanks are required to determine the

- effectiveness ofthe cleaning procedures used. Equipment blanks are collected by preserving the final rinse water in

an appropriate container and submitting it to the laboratory for analysis in the same cooler as thç remaining samples.

Field Duplicates

Duplicate sampling procedures are used during sample collection procedures to measure the precision of the

'i__' sampling process. Duplicate samples are collected for each procedure and matrix when a client requests this procedure, when duplicates are specified by protocol, and/or at a frequency outlined in Section 1 1 . i . i . Field duplicates are collected by sampling from successively collected volumes or portions, e.g. from the next bailer of - sample water. The duplicate samples will be preserved and submitted for the same analyses as the required

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samples. Duplicate sample data will be generated and reported with the required samples and reviewed by the QA Manager as a part of normal laboratory quality control procedures. The Operations Manager and Sampling Group Supervisor will be apprised of any anomalies involving field duplicate data and will initiate corrective action as - necessary.

Field Split Samples

The use ofa split sample is predominantly at the discretion ofthe consulting or sampling firm. Its purpose is to measure variability between laboratories. A split sample is where two samples are taken from a single, larger homogeneous sample. Consequently, weH mixed wastes or liquids would be the only sample types for which a true split may be taken. If there is not sufficient liquid sample in the sampling device to fill all containers in a single sample "pull then a method of mixing in a larger container is required. Alternatively, containers may be filled by successive "pulls" provided the portion of the device used is alternated between containers. Split sample acquisition and reporting is initiated by the client and as such the client is responsible for initiating any corrective action or investigative procedures.

6.7 Sampling Protocols

Parameters to be measured arc usually dictated by the purpose ofan investigation and should be based on requirez monitoring conditions or on the field investigator's knowledge ofthe investigation. From this knowledge, all samples should be collected from the least to the most contaminated areas. In addition, any wells containing free product will not be sampled for trace analysis. Generally, for ter sampling, all pieces ofcquipment and/or non- preserved containers should be pre-rinsed with sample vater before the actual sample is taken. This does not apply to pre-preserved containers or to those samples taken for volatile organics analysis, total recoverable petroleum hydrocarbons, oil & grease or bateriologica] samples.

Representative sampling sites and the type and construction ofsampling equipment selected is dictated by the type of investigation undertaken. The material that sampling equipment is constructed of can affect sample results. Materials used for construction and/or preparation ofthe sampling equipment must not contaminate the sample being collected and must be readily cleaned so that samples are not cross-contamninated

Personnel handling samples should always car a new pair ofdisposable latex gloves for personal safety as well as preventing the possibility of cross-contamination between samples.

During ail sampling events, the field notebook is used to document sampling activitiès, including descriptions of sample locations and any other data deemed necessary to allow future traceability ofthe event by reviewing the sampling documentation.

The following represents the preferred order ofsample collection from a given location.

1. VOC 5. Total Metals 2. TOX 6. Dissolved Metals 3. TOC 7. Microbiological 4. Extractable Organics 8. Inorganics

(as well as TRPH and O&G) 9. Radionuclides

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6.7.1 Wstewater Samplin!

The wide variety of conditions existing at different sampling locations require that some judgement be made

regarding the methodology and procedure for collection of a representative sample of wastewater.

6.7.1.1 Wastewater Sampling Site Considerations

lirfluent wastewaters are preferably sampled at points of highly turbulent flow in order to ensure proper mixing

while avoiding taking samples from either the surface or bottom of the strean. In all cases, samples should be

collected upstream from recirculated plant supernatant and sludges, and the samples should be completely untreated.

Where applicable, effluent wastewater samples should be collected at the location specified in the NPDES permit or

at the most representative site downstream from ail entering wastewater streams prior to discharge into thc

receiving waters.

6.7.1.2 Wastewater Sampling

- Equipment

_' Specific equipment which may be used for wastewater sampling includes the following with restrictions and exceptions as noted in Table 6-3 and Section 6.8.

Automatic Sampler- ISCO Models 2700, 2710, 3710 Stainless Grab Ann With Teflon Cup Pre-rinsed Sample Containers

Composite Sampling

- Automatic samplers may be used to collect composite samples over various time periods. Aliquot size will normally be 100 mL per hour or thirty minute interval. Ifrefrigeration is recommended or desired during

compositing, the sample container can be packed th ice. Composite sau&ples must be taken from the receiving

- waters unless homogenous mixing is demonstrated and noted. In lieu ofautornatic equipment or if personal, continuous observation ofthe stream is required, manual equipment may be used over extended periods oftime to collect the composite sample.

- Grab Sampling

Grab samples will normally be obtained using a grab arm with a teflon cup or a sample container itself. The best - method includes inverting the container, lowering to the desired depth and tipping the collection container so that the mouth ofthe container faces upstream. With the exception ofoil and grease sampling, microbiological sampling,

- and pre-preserved containers, ail containers shall be rinsed twice prior to filling.

-

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6.7.1.3 Wastewater Sampling Protocol

a) Determine flow variability using flow meter and record in field notebook.

b) If flow is highly variable, conduct sampling on a flow-proportional basis noting the proportional volumes to be taken in the field notebook.

c) If flow is not significantly variable, conduct sampling on a time-proportional basis noting the beginning arid

ending times in the field notebook. - d) Rinse and fill a clean sampling cup or sample container with the sample water by tipping the container in the

stream so that the mouth of the container faces upstream and measure pH, specific conductivity, and temperature. Record results and tune in the field no:ebook.

e) Fill three (3) VOA containers as specified in Section 6.8.1 (Special Considerations for Sampling Volatile Organics). Label and seal vials and record ID numbers and time in the field notebook. Put vials in zip-lock plastic bag and place on ice in sample cooler.

f) Rinse non-preserved sample bottles with sample and fill to within 1/2 inch oftop. Label and seal bottles, recorr' ID numbers and time in the field notebook. Place samples on ice in sample cooler.

g) Fill preserved sample bottles slowly. Do not pre-rinse containers which contain preservative. Cap and invert bottle to mix preservative.

h) Vetif pH ofacid-preserved or base-preserved samples by pouring a small amount ofsample into a clean container or sampling cup and measuring pH using test strips.

i) IfpH is correct for the type ofprcservative, label and seal bottle, record pH, sample ID and time in field notebook and place vial on ice in zip-lock bag.

i) IfpH is not correct, add additional acid or base until the correct pH is achieved. Record additional acid or base volume in notebook.

k) Complete chain-of-custody documentation.

I) Pack samples and associated paperwork for safe transport to the laboratory.

6.7.2 Surface Water Sampling

A surface water sampling program is based upon a variety offctors, mainly study objectives and water use. It is important to assess the characteristics ofthe water body being sampled in order to obtain a representative sample of surface water which meets the objective ofthe study. Various bodies ofwater, including lakes, ponds, impoundments, streams, rivers, and estuary waters present unique sampling challenges. In addition to physical access, anomalies such as stratification, mixing, sediment deposition, and salinity must be considered when developing a sampling program for surface water.

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6.7.2.1 Surface Water Sa.mplin Site Considerations

Sample site selection for surface water should be made with consideration to accessibility, water flow, presence of sediment and study objectives. Typically, sampling site selection will be pre-detcrrnined by the site specific sampling plan or client request. Special care should be exercised when collecting samples relative to the sampler's vessel and body. Whenever possible, samples should be taken from the bow of the boat or upstream from the sampler or boat. Care must also be taken not to disturb any sediments in the immediate area of sample collection. The field notebook should describe environmental conditions and relative positions of sampling equipment such as motors or generators which could affect the samples.

6.7.2.2 Surface Water Sampling Considerations

Specific equipment which may be used for surface water sampling includes the following items with restrictions and/or exceptions as noted in Table 6-3 and Section 6.8.

- VanDom Sampler Teflon Nansen Bottle

- Stainless Steel Grab Ann With Teflon Cup Pre-rinsed Sample Containers Automatic Samplers - ISCO Models 2700,2710,3710

Types of Samples

Special consideration must be given to the type of sample being collected. The overall protocol as outlined in

Section 6.7.2.3 is applicable to all types of sampling techniques given the specific considerations presented below.

Point Sampling

This would essentially be a grab sample where a pre-rinsed container or grab arm is inverted into the water then tipped so that its mouth faces the flow (if any).

Depth Specific Sampling

- Samples may be obtained at specified depths by utilizing a VanDom Sampler. The cylinder is lowered to the desired depth while water is flowing freely through it. At the appropriate depth, a messenger is sent down the rope causing the two stoppers to close tightly. The cylinder is then brought to the surface and samples are collected from a valve on the sampler. Depth ofsainpling is recorded in the field notebook.

In the case ofa teflon Nansen bottle, samples are obtained at specified depths by lowering the inverted bottle to the - desired depth. A messenger is sent down the rope causing the bottle to turn to an upright position. Once the bottle has been allowed to fill completely it may be retrieved and samples taken by gently pouring from the bottle.

- Pump Sampling

A peristaltic pump may be used for certain surface water applications which could include compositing from - several sites or depth specific sampling.

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6.7.2.3 Surface Water Sampling Protocol

a) Select sampling site and provide access to the site by extending, wading, boat or other suitable means.

b) Measure total depth of water and flow rate (if applicable) at the sampling site and record in field notebook.

c) Rinse and fill a clean sampling cup or sample container with the sample water by tipping the container iii the water so that the mouth of the container faces upstream (if applicable) and measure pH, specific conductivity, dissolved oxygen and temperature. Record results and time in field notebook.

d) For depth specific samples lower the appropriate sampling device with a measured length of rope to the desired - depth. Retrieve sample and measure pH, specific conductivity, dissolved oxygen and temperature of the water. Record results, time and depth in field noi.ebook.

e) Fill three (3) VOA containers as specified in Section 6.8. 1 (Special Considerations for Sampling Volatile Organics). Label and seal vials and record II) numbers and time in the field notebook. Put vials in zip-lock plastic bag and place on ice in sample cooler. -

f) Rinse non-preserved sample bottles with sample and fill to within 1/2 inch oftop. Label and seal bottles, reco ID numbers and time in the field notebook. Place samples on ice in sample cooler.

g) Fill preserved sample bottles 510w!)'. Do not pre-nnse containers which contain preservative. Cap and invert bottle to mix preservative.

h) Verify pH of acid-preserved or base-preserved samples by pouring a small amount of sample into a clean container or sampling cup and measuring pH using test strips.

i) lfpH is correct for the type ofpreservative, label and seal bottles, record pH, sample ID numbers arid time in field notebook and place vials on ice in zip-lock bag(s).

i) IfpH is not correct, add additional acid or base until the correct pH is achieved. Record additional acid or base volume in notebook.

k) Complete chain-of-custody documentation.

1) Pack samples and associated paperwork for safe transport to the laboratory.

6.7,3 Groundwater Monitor Wells Samplìn2

Groundwater is usually sampled through an in-place well, either temporarily or permanently installed. Groundwater wells with in-place permanent plumbing will be sampled as in Section 6.7.4.

'-J

6.7.3.1 Groundwater Samp1in Site Consideratians

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Installation of groundwater monitoring wells is limited to experienced and knowledgeable persons such as hydrogeologists. For the purpose of this manual it will be assumed that only pre-existing, adequately developed groundwater wells or other pre-existing, accessible groundwater sources will be sampled by Quanterra Tampa personnel. Whenever it is necessary to use the gas powered generator, care will be taken to assure that it is down wind from the sampling site.

6.7.3.2 Groundwater Samplinz Considerations

Equipment

Specific equipment which may be used for groundwater purging and/or sampling includes the following items with restrictions and/or exceptions as noted in Table 6-3 and Section 6.8.

- Grundfos Redi-Flo 2 submersible pump Automatic Sampler-peristaltic purnp-ISCO Models 2700,2710,3710 Teflon arid Stainless steel bauers Masterfiex Peristaltic pump

When organics and/or metals are being sampled, then all equipment coming in contact with the well water will be teflon or stainless steel. The only exception would be as noted in note i from Table 6-3.

Well Purging

J_n order to clear the well of stagimnt water which may not be representative ofihe groundwater conditions present, wells will be purged until three to five times the volume ofstanding water in the well has been removed. Specific conductance, temperature and pH will be measured after each purge and will be recorded in the field notebook along with a record ofthe volume purged. The amount purged is considered adequate when either the parameters measured do not deviate more than 5% afìer a minimum ofthree well volumes or when five well volumes have been - purged. Ifa well is pumped dry, this constitutes ai adequate purge and the well can be sampled following recovery.

The determination ofthe volume ofstanding water in a well is made by measuring the depth ofthe water in the well - and the depth ofthe well itself. Both measurements should be in feet utilizing a tape measure with an accuracy of 0. 1 feet. These measurements should always be made from the top ofthe well casing unless otherwise noted in notebook. The difference ofthese values provides the actual height ofthe water column (h) in feet. The diameter - ofthe well (d) in inches can then be used in the following formula, along with the height (h) and a conversion factor, to provide the sampler with the volume (y) in gallons ofthe standing water.

LJ V =(0.041)(d) (h)

After determining the volume of water in the well itself, purging will be accomplished using a teflon or stainless - steel bailer or appropriate pump. To the extent that it is feasible, purging should be conducted from the top of the -- water column working down as level decreases. Ifpurging is performed by a pump without the proper inert tubing, then the last well volume will be purged by using an appropriate bailer.

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Upon completion of purging, separate bauers will be used to conduct sampling. Sampling must occur within six (6) hours (ten (10) hours for slow wells) after purging is complete. Braided nylon cord used to haul bauers, will not be ailowed to touch the ground or casing, and will be discarded after one use. Care must be taken when purging (and sampling) wells so that water in the well is not contaminated by disturbing the well casement causing particles to f1l into the water.

6.7.3.3 Groundwater Monitor Well Samilin Protocol

a) Record the diameter of the well casing and the casing composition (if known) in the field notebook.

b) Place aluminium foil or heavy duty plastic sheeting on ground around well casing to protect equipment from contamination. -

c) Record the water level depth and well depth using the Roctest CPR-6 water level indicator or a decontaminated measuring tape, in the field notebook.

d) Calculate volume ofwater present in the well and record in notebook. Use the following calculation: V=(0.041)(d2)(h) V = volume of water in gallons d diameter of well in inches h height of water in well in feet

e) Begin purging procedure using a teflon bailer or suitable pump. Measure and record purged volumes using a calibrated bucket.

f) Measure pH, specific conductance and temperature after three (3) well volumes have been purged and record data, noting date and time in notebook.

g) Continue purging at one gallon intervals until (a) five (5) weIl volumes have been purged or (b) until pH, specific conductance, and temperature readings are within ± 5% for consecutive samples or (c) the well is purged dry. Record data along with date and time in field notebook.

h) Replace purging bailer or pump with sampling bailer and rinse by removing an additional bailer full of well water.

h) Fill three (3) VOA containers as specified in Section 6.8. 1 (Special Considerations for Sampling Volatile Organics). Label and seal vials and record ID numbers and time in the field notebook. Put vials in zip-lock plastic bag and place on ice in sample cooler.

i) Rinse non-preserved sample bottles with sample and fill to within 1/2 inch oftop. Label and seal bottles, record ID numbers and time in the field notebook Place samples on ice in sample cooler.

i) Fill preserved sample bottles slowly. Do not pre-rinse containers which contain preservative. Cap and invert bottle to mix preservative.

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k) Verify pH of acid-preserved or base-preserved sainp les by pouring a small amount of sample into a clean

container or sampling cup and measuring pH using test strips.

I) If pH is correct for the type of preservative, label and seal bottles, record pH, sample ID and tizne in field

notebook and place vials on ice in zip-lock baa(s).

m) 1f pH is not correct, add additional acid or base until the correct pH is achieved. Record additional acid or base

volume in notebook.

n) Complete chain-of-custody documentation.

o) Pack samples and associated paperwork for safe transport to the laboratory.

p) Re-secure monitor wells (if applicable) before leaving site.

6.7.4 Potable WaterSamn

Potable water sampling is typically conducted through use ofa permanently-installed well, production well, or taps

which are serviced directly by potable water supplies. This type of sampling is also applicable to groundwater wells which are serviced by permanent or "in-place" plumbing.

6.7.4.1 Potable Water Sampling Site Considerations

- Similar care and techniques used in groundter sampling are applicable to samples of potable tcr drawn from

wells. When sampling potable water from production taps, taps selected should be supplied with water from a service pipe connected directly to a water main in The segment ofinterest and ifpossible, should not be separated from the segment of interest by a storage tank. Aerator, strainer, and hose attachments on the tap must be removed

before sampling.

6.7.4.2 Potable WaterSaniplin! Considerations

Equipment

- There is no specific purging or sampling equipment required for sources with in-place plumbing. The only equipment would be a bucket to measure purge volume and possibly an intermediate container for taking samples.

- Well and Line Purging

Ifthere is a known volume ofthe well, sei-vice pipes or storage tank, then that volume should be purged before - sampling begins. Otherwise, the cold water tap should be opened (as much as possible without splashing) for fifteen minutes. At this point the site should be considered purged and sampling may begin using a reduced flow

rate ofabout 500 mL/mm. -

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6.7.4.3 Potable Water Samn! Protocol

a) If sampling from wells, follow groundwater sampling protocol found in Section 6.7.3.3 of this manual

b) If sampling from production wells with taps, remove any attachments and begin purging procedure by opening the cold water tap until a maximum flow is achieved without splashing. Measure the flow rate using calibrated bucket, and record rate in field notebook. Allow line to purge for fifteen (15) minutes or until service line has been completely cleared. Record purge time and time of day in field notebook.

c) Prior to collecting samples the flow rate should be reduced to approximately 500 niL/min (O. I galhnin).

d) Rinse clean sampling cup or container with sample and collect sufficient volume to measure pH, specific conductance, and temperature in field notebook.

e) Fill three (3) VOA containers as specified in Section 6.8.1 (Special Considerations for Sampling Volatile Orgariics). Label and seal vials and record ID numbers and tirite in the field notebook. Put vials in zip-lock plastic bag and place on ice in sample cooler.

d) Rinse non-preserved sample bottles with sample and fill to within 1/2 inch of top. Label and seal bottles, record ID numbers and time in the field notebook. Place samples on ice in sample cooler.

e) Fill preserved sample bottles slowly. Do not pre-rinse containers which contain preservative. Cap and invert bottle to mix preservative.

f) Verify pH ofacid-preserved or base-preserved sampLes by pouring a small amount ofsaniple into a clean container or sampling cup and measuring pH using test strips.

g) If pH is correct for the type of preservative, label and seal bottle, record pH, sample ID numbers and time in field notebook and place vials on ice in zip-lock bag(s).

h) IfpH is not correct, add additional acid or base until the correct pH is achieved. Record additional acid or base volume in notebook.

i) Complete chain-of-custody documentation.

i) Pack samples and associated paperwork for safe transport to the laboratory.

6.7.3 SoiL/Sediment Samplin2

Soil sampling is performed lo obtain information on an area or tract of land. Strategic sampling may provide valuable data as to the nature ofthe site with a minimum number ofsamples and effort. Sediment sampling is a procedure to obtain solid type samples from where a "runoff' has occurred (a land based surface sample) or from the bottom of some water body.

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6.7.5.1 Soil/Sediment Sampling Site Considerations

- Areas selected for soil sampling will be situated in order to collect a representative fraction with the minimum

number of samples. Selection of sampling Sites will be determined by client direction, site specific sampling plan

andlor determination of the most appropriate sampling points by the sample collector after evaluation of topographical features such as surface runoff direction. Initial site investigation generally involves the selection of sampling sites which provide pertinent data from which a more specific sampling plan may be established, if necessary. At no time will samples for analysis be taken from the auger flights or cuttings from hollow flights. Also any samples used to make geologicalllithological or vapor determinations will not be used for trace analyses.

6.7.5.2 Soil/Sediment Sampling Considerations

Equipment

Specific equipment which may be used for soil and sediment sampling includes the following items with the restrictions and/or exceptions as noted in Table 6-3 and Section 6.8. AlI samples are mixed thoroughly before being placed in containers, with the exception ofVOC samples and those samples which remain in a tube or core.

Stainless Steel Trowel, Scoop, Spoon, Spatula Stainless Steel Hand Auger and Corer

- Stainless Steel Shovel, Shelby and Split Spoon Stainless Steel or Glass Mixing Tray

Sediment Sampling

Surface sediments will be sampled like soil samples. When sediment from below a body ofwater is desired, then

- some special considerations must be made. In calm water the sediment may be sampled using an open scoop, spoon, trowel, etc. For moving bodies ofwater a closed container should be used to "grab" the sediment and bring it to the surface without losing the fine particles. The procedures outlined in Section 6.7.5.3 are applicable to

- sediment sampling with the understanding ofthe above noted considerations.

Shallow Subsurface Sampling Techniques

- Shallow subsurface soil samples may be collected by digging a hole with a stainless steel shovel and collecting a sample at the desired depth using a stainless steel spoon or a shelby tube. Care should be taken to remove all loose

-- soil and backfill from the hole before sampling. The Shelby tube is pushed into the soil to be sampled and removed. - The sample is then transferred to a sample container or sealed in the tube for shipment to the laboratory.

Deeper Subsurface Soil Sampling

For deeper sampling using hand equipment, a stainless steel auger is used to bore a hole until the desired depth is

achieved. A clean auger bucket, Shelby tube or split-spoon is used to collect the sample.

The stainless steel hand auger consists ofa bucket, a boring extension, and handle. At the bottom ofthe bucket are tvo cutting edges. Boring is achieved by turning the handle and applying downward pressure.

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The split-spoon sampler is used to collect a sample at a pre-determined depth by inserting it into a pre-drilled hole and forcing it into the undisturbed soil at the bottom of the hole. The split-spoon is retrieved from the hole and opened to collect the undisturbed portion of the sample. - The core sampler provides the ability to simultaneously drill a hole while preserving the column of soillsediment. This column is then either composited or sampled at specified "depths".

6.7.5.3 Soil/Sediment Sampling Protocol

a) Locate and record sampling site in field notebook using site description and/or topographical map.

b) Prepare the sampling site by removing any surface matter such as vegetative growth or debris. Record any comments regarding characteristics of sampling site (e.g. color, odor, debris, etc) in field notebook.

c) If subsurface samples are desired, prepare a hole or trench to the desired depth using a stainless steel shovel or auger.

d) Remove any loose backfill material which remains in the hole.

e) Collect sample at desired depth using stainless steel spoon, hand auger with clean bucket, split-spoon or sheF tube. Record depth ofsarnpling in field notebook.

f) Transfer undisturbed portion ofsample to a clean glass or stainless steel pan and fill VOA vials with undisturbed portion.

g) Leaving no headspace in the container, cap and label vials, record sample ID, depth ofsample, and time of day in notebook, and place in zip-lock bag on ice.

h) Aller thorough mixing, fill remaining sample containers to within 1/2 inch oftop. Cap and label bottles, place on ice and record sample ID and time in field notebook.

i) Complete chain-of-custody documentation.

i) Pack samples and associated paperwork for transport to the laboratory.

k) Where applicable, backfill sampling holes which were excavated before leaving the site.

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6.7.6 WastefDrurn Samplin2

6.7.6.1 General Considerations

Sampling closed containers shall be considered a high-hazard operation. Sampling and safety procedures outlined in

- Ouanterra Tampa Health and Saifetv Manuai will be strictly observed during hazardous sampling operations. In addition, all personnel involved in hazardous sampling operations must have successfully complet&f OSHA's forty (40) hour safety training course and any subsequent update requirements. Additional safety guidance will be referenced in the draft EPA Safety Manual for Hazardous Waste Site Investigation. Hazardous conditions must always be assumed present when sampling a container, and appropriate caution exercised. When possible, historical information (including any labels) relating to the container should be obtained and reviewed prior to sampling. Should radioactive, shock-sensitive or other ectremely hazardous materials of this type be suspected present, appropriate experts will be called upon to screen a site before any sampling may take place.

6.7.6.2 Waste/Drum Samplin2 Considerations

Equipment

Specific equipment which may be used for waste sampling includes the following items with the restrictions and/or exceptions as noted in Table 6-3 and Section 6.8.

- Disposable profile tube for sampling drums containing homogeneous or stratified liquids. Sparkproof barrel %Tench for opening vaste drums. Various stainless steel equipment (described for soil/sediment) for sampling solid or semi-solid vastes. Sample containers.

Open Container Sampling

Open containers generally present less hazard than closed containers and should be sampled first when both types of containers are present in order to farnilianze the sampling team with the types ofmatenals that may be present in - closed containers.

For liquid waste samples, a disposable glass profile tube will be used to collect a representative sample in case of - multiple layers. Ifa representative sample is not possible through use ofa profile tube (i.e. larger tanks), other measures may be necessary such as collecting the sample through a valve or spigot. In cases where representation ofthe sample is questionable, notes to that effect will be made in the field notebook and the Project Manager notified. If layers are sampled separately then the layer sampled must be clearly identified.

For solid waste samples, stainless steel spoons (with extension devices, if needed) and/or push-tubes may be used to - collect representative samples. Compositing ofthe waste is necessary ifthe solid waste pile or container is considered to be non-homogeneous. A stainless steel pan and spoon may be used to homogenize the sample fractions collected.

58

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Section No.: Six Rvision No.: 13 - Date: 10115195

Page: 28 of 42

Where possible, ail waste samples should be composited with depth to provide a representative sample. Exceptions encountered should be noted in the field notebook.

Closed Container Sampling

Closed containers must be considered extremely hazardous from the standpoint of unknown factors relating to toxicity, explosion, or fire. Spark-proof barrel wrenches are used to open closed containers. Full compliance with applicable Health and Safety protocols are required when opening closed containers. Two or more persons must be present in the sampling area and a third present in a designated safe area before closed containers are opened. Once opened, container sampling may proceed following open container sampling protocol.

6.7.6.3 Waste Sampling Protocol

a) Locate sampling site on map or suitable reference for future reference. Record this information in the field notebook as well as what type of container is being sampled.

b) Determine whether the waste to be sampled presents a high-hazard condition. Take necessary steps to ensure compliance with applicable safety standards.

c) 1f waste is in a closed container, provide access to the container by removing the lid (bung) using a spark pro barrel wrench.

d) If liquid waste is contained in a large tank, locate a valve or port appropriate for collecting the sample. Using either a profile tube or spigot, fill an appropriate sample container with liquid to within 1/2 inch ofthe top. Cap and label the sample, record sample ID and time ofday in the field notebook, and store the sample for transport per applicable preservation requirements and hazardous sample handling protocols.

e) When using profile tubes to sample liquid vaste, sample by placing thumb over hole and dipping tube into waste. Remove tube and note layer profiles and drain sample into container. Record physical description of sample, including depths ofstratifications, ifany, in the field notebook along with other pertinent sample data.

f) Ifwaste is solid, collect a representative sub-sample at appropriate depths using push tubes, or stainless steel spoon with extension device.

g) Composite solid waste sample in stainless steel pan with stainless steel spoon and transfer composite sample to appropriate container. Cap and label bottle, record sample ID, physical description and time ofday in the field notebook.

h) Pack samples according to hazardous waste sample transportation and preservation protocols. Include completed chain-of-custody papers and associated paperwork for transport.

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6.8 Special Sampling Considerations

Situations which require aditiona1 or special steps during the sampling procedure to ensure sample integrity are outlined below.

6.8.1 Volatile Organic Samples

Samples to be analyzed for the presence of volatile organic compounds are collected and stored in 40 mL septum vials with screw caps with a Teflon-lined silicon disk in the cap (teflon side toward sample).

Multiple samples from the same site are always collected when sampling for volatile organics and special attention will be given to minimizing headspace in the sample container, regardless of sample matrix. No samples being ccllected for volatile organic compounds Will be composited or mixed.

The sampler will determine, either historically or by on-site testing ifwater to be sampled contains chlorine. If the water contains no chlorine, sample vials containing four drops of concentrated HCI should be filled with the sample and labelled HCI-preserved. Care should always be taken when collecting volatile samples so that aeration due to

- splashing is minimized. This may be accomplished by gently pouring the water sample down the side ofthe vial. The vial is then slightly overfilled (convex meniscus) so that Wien the screw cap is tightened, head space is eliminated. Sample vials containing water to be analyzed for volatile organics should be checked upon completion

- offilling by Invertmg the veal, tappmg the vial gently against your hand and looking for the presence ofair bubbles. Ifany bubbles are present, the procedure should be repeated. Soil samples should be placed in the vials

minimizing mixing and headspace.

- Ifthe water sample contains chlorine, then it should be collected into a vial containing four drops of concentrated HC1, but not filled to the top. Four drops of 10% sodium thiosulfate should then be added, the vial "topped off' vith sample, capped tightly and mixed thoroughly. All containers should be clearly marked with preservative

contents to avoid confusion in the field.

6.8.2 Composite Samples

6.8.2.1 Water Samples

When necessary, field compositing ofwater samples may be performed using the following guidelines.

a) Use equivalent aliquots (minimum I 00 mL) when mixing a composite.

b) Composite samples may be collected in a precleaned, sample-rinsed plastic or stainless steel bucket, depending on desired analyses. a

c) After adding equivalent aliquots of each sub-sample to be composited, gently swirl the water to allow compete mixing without aeration.

d) Transfer the resulting composite to sample bottles using standard sampling protocols as outlined previously in

this manual.

59

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Date: 10/15/95 Page: 30of42

e) Compositing volatile organic samples in the field is not recommended unless specified by FDEP.

6.8.2.2 Solid Samples

When necessary, field compositing of solid samples may be performed using the following guidelines. All individual solid sub-samples should be mixed thoroughly in a stainless steel pan using a stainless steel spoon.

a) Transfer equivalent aliquots of soil sub-samples to a clean stainless steel or glass mixing pan. Equivalent aliquots may be determined by weight (ifa balance is available) or estimated by volume. The field sarnple?s notebook should specif' the method and all weights or volumes of sub-samples.

b) Mix thoroughly using a stainless steel spoon.

c) Fill sampling containers from the pan following standard sampling protocols outlined previously in this manual.

d) Compositing volatile organics samples is not recommended unless specified by FDEP.

6.8.3 Dissolved Constituent Samples

When sampling for dissolved constitutents, the peristaltic pump equipped on the positive pressure sidewith a orn piece, in-line, non-contaminating disposable O.45um or l.Oum fitter (see further) will be usd. All samples for traT metal analysis must use a I .Oum filter, whereas samples for analysis ofdissolved constituents (orthophosphorous, silica, dissolved metals, etc.) must use the O.45um filter. The sample will be filtered directly from the well into a sample container for immediate preservation. lfthe well is greater than 25 feet deep then the submersible pump will be used to bring the water to the surface and filtered or will proceed at that point as described above. Upon ClientTFDEP request an additional non-filtered sample must be taken. AddiTionally, any time filtered samples are taken, at least one filtered equipment blank ofanalyte-free vater should be taken and analyzed.

6.8.4 Oil and Grease Samples

When sampling for oil and grease analysis, samples should never be composted nor should intermediate containers be used unless absolutely necessary. In addition, sample containers and bauers should not be rinsed with sample before collection.

6.8.5 Bacteriological Samples

When sampling activities include collection for microbiological types ofanalysis, the maintenance of sterile containers is very important. This would encompass such things as avoiding any contact with tops or edges of containers and keeping containers sealed until needed. Other considerations require no compositing be performed and that samples reach the laboratoiy within the 6 hour holding time. The holding time constraint may require the use ofpersonal and/or professional couriers to shuttle samples to the laboratory as soon as they are collected.

-

Parameter

BacterologicaL

Coliform, Fecal and Total.

Radiological:

Alpha, Beta, and Radium

Metals:

Chromium VI

Mercury

Metals, except above

Physical Properties:

Acidity

Alkalinity

Biochemical Oxygen Demand

Bromide

Carbon, Total Organic

Chemical Oxygen Demand

Chionde

54 128

Section No.: Revision No.: U Date: 10/15/95 Page: 31 of 42

TABLE 6-4

PRESERVATION SUMMARY FOR AQUEOUS MATRICES

Recommended Container' Preservative2 HpIdin Time3

Amount Required

P,G Cool, 4°C 6 hours 250 mL 008% Na2S2O34

P,G HNO3 to pH<2 6 months 2 L

P,G Cool, 4°C 24 hours 250 mL

P,G I-1NO3 to pH<2 28 days 250 mL

P,G HNO3 to pH<2 6 months i L

P,G Cool, 4°C 14 days 250 niL

P,G Cool, 4°C 14 days 250 mL

P,G Cool,4°C 48 hours 500 mL

P,G None Required 28 days 250 mL

P,G Cool, 4°C 28 days 4 x 40 mL H2SO4 to pH<2

P,G Cool, 4°C 28 days 250 mL H2SO4 to pH<2

P,G None Required 28 days 250 mL

524 l2ni

SectionNo.: Revision No. : 13

Date: 10/15/95 '- Page: 32of42

TABLE 6-4

PRESERVATION SUMMJÌRY FOR AQUEOUS MATRICES (continued)

Recommended Amount P&ameter Container Preservative2 Holding Time3 uired

Chlorine, Total P,G None Required Analyze immediately 250 mL = and Residual

Color P,G Cool, 4°C 48 hours 500 mL

Conductivity P,G Cool, 4°C 28 days 250 mL

Cyanide, Total P,G Cool, 4°C 14 days6 100 mL and Amenable to NaOH to pH>126 Chlorination O.6g ascorbic

acid4

Fluoride P None Required 28 days 250 mL

Hardness P,G 1-!NO3 to pH<2 6 mos. 100 mL

Halogens, Total P,G Cool, 4°C 28 days 2 x 250 mL Organic HSO4 to pH<2

Hydrocarbons, Total G Cool, 4°C 28 days 2 L Recoverable Petrol, HCI to pH<2 (IR)

Nitrogen, Ammonia P,G Cool, 4°C 28 days 250 mL H2SO4 to pH<2

Nitrogen, Unionized P,G Cool, 4° 28 days 7 L Ammonia H2SO4 to pH<2

Na2S2O 500mL

Nitrogen, Kjeldahl P,G Cool, 4°C 28 days i L H2SO4 to pH<2

Nitrogen, Nitrate P,G Cool, 4°C 48 hours 250 mL

Nitrogen, P,G Cool, 4°C 28 days 250 mL Nitrate - Nitrite 1-12SO4 to pH<2

Parameter

Nitrogen, Nitrite

Nitrogen, Organic

Odor

Oil and Grease

Oxygen, Dissolved P robe

Oxygen, Dissolved Winider

Hydrogen Ion (p1-I)

Phenolics

Phosphorus, Orthophosphate

Phosphorus, Elemental

Phosphorus, Total

Residue, Total Solids (TS)

Residue, Filterable Solids (TDS)

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Section No.: Revision No.: 13

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TABLE 6-4

PRESERVATION SUMMARY FOR AQUEOUS MATRICES (continued)

Recommended Amount Container' Preservative Holding Time3 R&iuired



G Cool, 4°C 6 hours 500 mL

G Cool, 4°C 28 days I L

H2SO4 to pH<2

G, Bottle None Required Analyze immediately 300 mL and Top

G, Bottle Fix on-site, 8 hours 300 mL and Top store in dark

P,G None Required Analyze immediately 25 mL

G Cool, 4°C 28 days i L

HSO4 to pH<2

P,G Filter 48 hours i L

Immediately Cool, 4°C

G Cool, 4°C 48 hours 250 mL




61

524 lUi

Parameter

Residue, Non- Filterable Solids (TSS)

Residue, Settleable

Residue, Volatile

Silica

Sulfate

Sulfide

Sulfite

Surfactants (MBAS)

Temperature

Turbidity

Orgnrìics:

BasefN'eutral Acid Extractables (GCIMS)

Polynuclear Aromatic Hydrocarbons

PesticidesfPCB's, Herbicides


Date: 10/15/95 Page: 34of42

TABLE 6-4

PRESERVATION SUMMARY FOR AQUEOUS MATRICES - (continued)

Recommended Amount - Container' Preservative2 1-lokling Time3 Bçuired

P,G Cool, 4°C 7 days i L -



P, G Cool, 4°C 28 days 500 mL


P,G Cool,4°C Add 7 days I L Zinc Acetate and NaOH to pH>9

P,G None Required Analyze immediately 250 ml

P,G Cool, 4°C 48 hours i L

P,G None Required Analyze immediately 250 mL


G, TFE Cool, 4°C Lined Cap .008% Na2S2O4

G, TFE Cool, 4°C Lined Cap .008% Na2S2O34

Store in Dark

G, TFE Cool, 4°C Lined Cap Store in Dark

7 days until extraction, i L 40 days after



'-I

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Section No.: Sií

Revision No.: i3 Date: 10/15/95 Page: 35 of 42

TABLE 6-4

PRESERVATION SUMMARY FOR AQUEOUS MATRICES (continued)

Recommended Parameter i. Container ., Preservative . . 3 Holding Tuiie

Purgeable G, TFE Cool, 4°C 14 days 1-lalocarbons Lined Cap .008% Na2SO34 (EPA 601,501.1)

Purgeable G, TFE Cool, 4°C 14 days5

Aromatics Lined Cap .008% Na2S2O34 (EPA 602,624,502.2) HCI to pH<2

Volatile Organ.ics (EPA 8010, 8020,8240):

No Residual G, TFE Cool, 4°C 14 days

Chlorine Lined Cap 4 Drops RC!

Residual G, TFE Collect Sample 14 days Chlorine Lined Cap in a 40 mL VOA

Container Preserved with 4 drops of concentrated HC 1.

Add 4 drops of 10% Na2S2O3. Cap tightly and mix Cool, 4°C

Amount ReQuired

3 x 40 mL

3x4OmL

3x40 mL

3x40 mL

62

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Section No.: Revision No.: 13 - Date: 10/15/95 Page: 36of42

NOTES

1. P = polyethylene, G = glass.

2. Preservative should be contained in the containers as sample is added or added to the sample immediately. Each aliquot of composite samples should be preserved at collection if possible. Automatic compositing samplers should be maintained at 4°C until preservation can be performed.

3. Holding times listed are maximum recommended times for each particular preparation or analysis; therefore, every effort will be made to analyze/prepare the samples as soon as possible alter sampling.

4. Preservative required only if residual chlorine is known to be present.

5. If pH is not adjusted, samples must be analyzed within seven days of sampling.

6, If the sampler determines sulfide to be present (using lead acetate paper), then the sample may be shipped preserved with NaOH and analyzed within 24 hours or it can be treated in the field using cadmium nitrate before preservation.

7. Temperature, pH and salinity (if applicable) must be measured on site at the time of sample collectio Laboratory analysis of the ammonium ion concentration should be conducted within eight hours of samplZ_ collection. Ifprompt analysis ofammonia is impossible, preserve samples with H2SO4 to pH between 1.5 and 2. Acid-preserved samples, stored at 4°C, may be held up to 28 days for ammonia determination.

Parameter

Radiological:

Alpha, Beta, Radiums

Metals:

Chromium VI

Mercury

Metals, except above

Physical Proprties:

Acidity

Alkalinity

Bromide

Chloride

Cyanide, Total and Amenable to Chlorination

Fluoride

Halogens, Total Organic

Hydrocarbons, Total Recoverable Petrololeum

Nitrogen, Ammonia

Nitrogen, Kjeldahl

524 134


TABLE 6-5

PRESERVATION SUMMARY FOR SOLID MATRICES

Recommended Container' Preservative2 Holding Time3

P,G Cool, 4°C 6 months

Amount Required

200 g

P,G Cool, 4°C 24 hours 50 g

G Cool 4°C 13 days 50 g P Cool, 4°C 28 days 50 g

P,G Cool, 4°C 6 months 50 g

P,G Cool, 4°C 14 days 50g

P,G Cool, 4°C 14 days 50 g

P,G None Required 28 days 50 g

P,G None Required 28 days 50 g


P None Required 28 days 50 g


G Cool, 4°C 28 days 100 g



63

524 1í:i

Parameter

Nitrogen, Nitrate

Nitrogen, Nitrite - Nitrite

Nitrogen, Nitrite

Nitrogei, Organic

Oil and Grease

Hydrogen Ion (pH)

Phenolics

Phosphorus, Orthophosphate

Phosphorus, Elemental

Phosphorus, Total

Silica

Sulfate

Sulfide

Sulfite

garucs:

Base/NeutrallAcid Extractables

Section No.: Six Revision No.: 13 - Date: 10/15/95 ' Page: 38 of 42

TABLE 6-5

PRESERVATION SUMMARY FOR SOLID MATRICES (continued)

Container' Preservative2

P,G Cool, 4°C

P,G Cool, 4°C

P,G Cool, 4°C

P,G Cool, 4°C

G Cool, 4°C

P,G None Required

G Cool, 4°C

P,G Cool, 4°C

G Cool, 4°C

P,G Cool, 4"C

P CooL, 4°C

P,G Cool, 4°C

P,G Cool, 4°C

P,G Cool, 4°C

G, TFE Cool, 4°C

Lined Cap

Recommended Holding Time3

48 hours

28 days

48 hours

48 hours

28 days

Analyze immediately

28 days

48 hours

48 hours

28 days

28 days

28 days

28 days

Analyze immediately

Amount ReQuired

50 g

50g

50g

50 g

50g

50g

50 g

50 g

50 g

50g

50g

50g

50g

50 g

14 days until extraction, 150 g 40 days after

524 136

Section No.:

- Revision No.: Date: 10/15/95 Page: 9pf42

TABLE 6-5

PRESERVATION SUMMARY FOR SOLID MATRICES (continued)

1

Recommended Amount

Parameter Container' Preervative Holding Time3 Required

Polynuclear G, TFE Cool, 4°C 14 days until ectraction, 150 g Aromatic Lined Cap 40 days aÍer Hydrocarbons

Pesticides/PCB's, G, TFE Cool, 4°C 14 days until extraction, 150 g

Herbicides Lined Cap 40 days after

Volatile Organics G, TFE Cool, 4DC 14 days 150 g Lined Cap

NOTES

i . P = polyethylene, G glass.

2. Preservative should be contained in the containers as sample is added or added to the sample immediately.

Each aliquot of composite samples should be preserved at collection, if possible. Automatic compositing

samplers should be mathtamed at 4°C until preservation can be performed.

3. Holding times listed are maximum recommended times for each particular preparation or analysis; therefore,

every effort will be made to analyze/prepare the samples as soon as possible after sampling.

64

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Section No.: Revision No: 13

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6.9 Reagent and Standard Storage

Reagents and standards maintained for field use will be stored in the laboratory in appropnate cabinets, refrigerators, or designated areas along with routine laboratory reagents and standards. Reagents and standards maintained for field use will be clearly labelled as such. Table 6-6 summarizes the storage method for each reagent and standard maintained by the laboratory for field use. - Sample containers containing preservative are not stored at the laboratory. Preservative is added to sample containers immediately prior to field activities. When shipping containers, the preservatives are included in

separate containers in concentrations consistent with federal regulations.

Chemical

Nitric, Hydrochloric and Sulfuric Acids

Isopropanol

Analyte-Free Water

pH Standards

Conductivity Standards

Chlorine Test Reagents

Assorted Dry Chemicals and Aqueous Solutions

524 138

Section No.: Six Revision No.: i. Date: 10115195

Page: 41 of42

TABLE 6-6

STANDARD AND REAGENT STORAGE

Method of Storage

Origina! Containers, Acid Safety Cabinet, Segregated by Acid Type

Original Containers, Solvent Safety Cabinet in Volatiles Lab

Acquired from Laboratory System Prior to Use

Laboratory Reagent Cabinet in Wet Lab


Refrigerator in Wet Lab


- r

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Date: 10/15/95 Page: 42of42

6.10 Waste Disposal

Quariterra Tampa maintains a waste disposal program that is followed both in the field and at the laboratory. The

field disposal program is designed to safely and legally dispose of contaminated sample material and any introduced solvents, cleaning solutions or reagents associated with the sampling procedures. The program requires that all

vastes be segregated in terms of water solubility, evaporative solvents, and sample waste.

6.10.1 Solvent Waste Disposal

Solvents used in the decontamination process (isopropanol and acetone) are collected in an open bucket. Ail wastes are drummed and disposed of consistent with the waste characterization. Any remaining solvent is to be carried back to the lab and containerized with the flammable vaste solvents for disposal by a commercial disposal company.

All other solvents used at a sampling site are segregated and containerized according to flammability and chlorination. These containers are transported to the lab where they are emptied into the appropriate waste solvent drums. These drums are then available for disposal by a commercial disposal company as described in Section 8.5.1.

6.10.2 Aqueous Waste Disposal 'w

Aqueous based waste generated in the field is containerized and transported back to the laboratory' for proper disposal as outlined in Section 8.5.2.

6.10.3 Other Waste Disposal

All other items considered contaminated, such as gloves, disposable equipment, toweling, etc., should be

segregated, containerized and tagged with sampling site and date. These wastes will be transported to the laboratory for further segregation (ifnecessary) and proper disposal as described in Section 8.5.3.

- 524 130

Section No.: Seven - Revision No.: .LQ

'-J Date: 10/15/95 Page; 1 of 28

7.0 Sample Custody

7.1 Samole Custody Objectives

A sample is physical evidence collected from a site or from the environment. As such, a sample must be

documented in a manner which provides all information necessary for proper analysis and legal defense of sample results. Legal sample custody is defined as maintaining the sample in one of the following

situations: 1) In the actual possession of the sampler or transferee. 2) In the view of the person having possession. 3) Secured by the sampler or transferee in such a way that the sample cannot be tampered

with. Documentation (chain-of-custody) begins when sample containers are prepared and submitted to the client and continues through sample analysis, reporting and disposal. Legal chain-of-custody procedures which are used by Quanterra Tampa for all sampling events are described in the following sections.

7.1.1 Le2aI Chain-of-Custody Procedures

Legal chain-of-custody documentation is necessary to track the possession of each sample from collection through analysis. To be legally defensible, this documentation should always be done using waterproof ink.

- Any corrections required on all laboratory and field records will be made by drawing a single line through the error and initialing and dating the correction.

__i . . - The cham-of-custody procedure begins when pre-cleaned, appropnately preserved bottles are prepared by the laboratory for transport to sampling sites. The bottle record/sampling instructions form and chain-of-

custody form are completed by the Sample Custodian aid indicate that the laboratory has relinquished

- clean sample containers to the sampler.

Field personnel are responsible for maintaining a continuous legal chain-of-custody throughout the

- sampling process. This includes keeping containers secured and sealed at all times and documenting all

activities on the chain-of-custody form and in the field notebook. Samples must be submitted to the laboratory under the supervision ofthe field sampler or by a courier with seals maintaining the integrity of the sample set.

Samples submitted to the Laboratory are accompanied by the chain-of-custody form. This form is

completed and sealed within the sample transport container to be opened and examined by the laboratory - Sample Custodian. All entries ori the chain-of-custody form must coincide with the corresponding sample labels. Additionally, a sample receipt form is completed for each sample shipment. If discrepancies are noted by the Sample Custodian, the client or sampler must be contacted to resolve any conflicting - information.

All pertinent sample custody forms are reviewed by the Project Manager and maintained until completion - of the project, at which time a copy of each is included in the final analytical report. The Sample Custodian logs-in the samples using a sample receiving logbook as well as an electronic data system (described in Section 12) which generates laboratory bench sheets. Each sample which is logged into the

- laboratory is given a unique identification number and placed in labelled storage areas. Samples removed - from these storage areas are tracked by way of a sample custody logbook. Other methods of interna! chain- of-custody include bench worksheets and preparation and instrument logbooks. Periodically, expired

-. samples are purged and disposed of using waste disposal procedures described in Section a.s. This purging is also documented in the sample receiving logbook.

66

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Section No.: Seven Revision No.: 10

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7.1.2 Sample Custody Forms

Quanterra Tampa and client sampling teams are provided with the following forms which are used in the sample documentation process and to ensure sample integrity. An example of each of the following forms is presented in Figures 7-1 to 7-8 at the end of this section.

a) Sample Labels (Figure 7-1): Laboratory sample labels are used to ensure proper identification and management of collected samples. These gummed labels are completed and affixed to each sample container at the time of collection. Entries on the sample label include field sample identification designation, sampling location, date and time of collection, sampler name, and additional pertinent field information. These labels may be commercially (by container vendors) or privately printed.

b) Sample Seals (Figure 7-2): Laboratory sample seals are used to detect unauthorized tampering of samples prior to laboratory acceptance. Sample Seals are affixed to the sample transport containers and/or sample containers in a manner that requires seal breakage in order to access the contents of the containers. Unauthorized seal breakage indicates possible tampering and renders a sample or the transport container of samples suspect.

c) Sampling Instructions Form (Figure 7-3): This form is used to provide a record ofall containers sent for a specific site. The itemized list provides information regarding type and size of container, expected matrix of samples, containers needed per sample, the method, holding time and preservative needed for each sample. There is also space provided for the transport containers being used to be identified. On the reverse of this form are general sampling instructions and notifications.

d) Chain-of-Custody Form (Figure 7-4): This multi-copy form, pre-printed with Quanterra Tampa's name, address and phone number, provides space for signatures and titles of all persons involved in the chain-of-custody (beginning with container receipt) to be entered with The corresponding date and time of possession. Other pertinent information includes client identification, project identification or sampling location, field sample identification and description, date and time ofsaniple collection, sample container amounts, required analyses, sample preservation information and any relevant comments. A copy of this completed form is included in all analytical results summary packages.

e) Sample Receipt Form (Figure 7-5): This checklist is used to record the type of shipping container and the completeness of paperwork associated with the samples. This checklist also records condition and preservation of samples, completeness of labels, adequacy of remaining holding time and the appropriateness of preservation techniques used. The action taken to resolve any discrepancies is noted on this forni as well. A copy of this completed form is included in all analytical result summary packages.

524 142

Section No.: Seven Revision No.: Date: 10/15/95 Page: 3 of 28

f) Sample Receiving Logbook (Figure 7-6a): This logbook provides a legally bound consecutive reference of all sample lots received by the - laboratory. Information contained in the logbook consists of identification numbers, analyses requested, sample matrix, client name and site and number of bottles received. This logbook is

also used to document the disposal of samples, by stamping the original logsheet with "Samples Disposed Of" (Figure 7-sb)

g) Sample Custody Logbook (Figure 7-7): The sample custody logbook is used by those lab personnel who prepare samples for analyses. When a sample is removed from its storage area, the analyst/technician enters the sample I.D., time and initials. When a sample is returned, consumed or disposed of the proper notation with time, date and initials is documented as well.

h) Laboratory Analytical Request Form (Figure 7-8):

- The laboratory analytical request form is used in addition to the chain-of-custody form when sending either samples or extracts to another fcility for preparation or analysis. This form provides spaces to record sampling time and date; field identification number; laboratory identification number; any sample preparation procedures which have been performed and the date and time performed; and the specific matrix and analyses which are being requested. Distinct forms are used for transfers that are internal to Quanterra (Figure 7-8a) or external to

- the Quanterra network (Figure 7-8b).

7.2 Field Custody

Data relating to field sampling operations is recorded on the appropriate sample custody forms, including sample labels, sample seals, and chain-of-custodies as well as being kept in the field sample notebook. The field personnel are responsible for receiving the sampling containers from the sample custodian and documenting possession of them throughout the sampling process.

The specific methods for the various forms of documentation are outlined above in section 7.1.2, The protocol which designates how these forms and documents create a continuous, traceable flow of information is as follows. Sample containers are received from the lab with labels speciiiing the project

-- name, analysis, and any preservative already in the container. The sampler is responsible for assigning a unique identification number to each site sampled and placing that number ori all sample container labels from that site. The number may be referenced from a project map and should be clearly identified in the field sampling notebook. This number or designation will be used on the chain-of-custody and sample seals - (if applicable). The laboratory identification number (see Section 7.3. 1) will reference the field sample identification number on all bench worksheets and reports. By utilizing the field sample notebook and corresponding chain-of-custody for a sampling event, a continuous flow of secure custody and relevant - information can be maintained.

6i

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Section No.: Seven Revision No.: 10

Date: 10/15/95 Page: 4 of 28

7.2.1 Field Sample Notebook

Data from all samples taken by field personnel is entered in a hard-cover, permanently-bound field sample - notebook consisting of consecutively-numbered 8 l/2' x 11" pages. The field sample notebook contains entries which document pertinent field data for each sample collected, including:

Client Name and address offield client Project or sampling Location - Exact location ofeach sample collection point Sampling methodology and equipment, including purging/preparatory equipment and IDs Order ofsarnple collection - Analytical parameters for each sample Process generating sample (as applicable) Date and time of sample collection - Description of field conditions (such as weather, etc.) Field sample identification or designation Field observations andlor measurements - Quality control samples collected References such as maps, sketches, photographs Preservation and transport descriptions, including pH (if checked) and any additional preservatives Name and signature of sample collector List of visitors or personnel on site during sampling Information necessary to describe and retrace any unique fkld sampling procedure Any field decontamination procedures performed

In addition to the information above, site and sample type specific information will also be entered into the field sampling notebook. This information is outlined in each sampling protocol (see Section 6.7) and includes things like calculations of well volumes, flow rates for in-place plumbing and moving surface waters, type of plumbing, if kno, depth of sampling and purging volumes, tunes and stabilization parameter results.

Field sampling notebooks are maintained chronologically by a designated laboratory records clerk for a rnininium period of five years upon completion of a project. By referencing sampling dates, all records associated with a particular sampling event may be compiled and referenced.

7.2.2 SampLe Transport

The protocols and documentation associated with transport of sample kits and/or samples have been described in Section .5.

7.3 Laboratory Custody

Evidentiary documentation procedures are utilized by the laboratory in a manner which is continuous with field sampling and subsequent sample submittal to the laboratory. These documentation procedures are continued through analysis, reporting, and disposal ofall samples as outlined in the following sections.

524 144

Seclion No.: Seven Revision No.: Date: 10/15/95 Page: 5 of 28

7.3.1 Sample Receipt Documentation

- The laboratory Sample Custodian (Section 4.2.7) receives and documents all samples submitted to the laboratory. This person examines the condition, preservation, and accompanying documentation of all

submitted samples prior to approval and formal acceptance by the laboratory. Any sample, preservation, or - documcntation discrepancies (i.e. broken container, improper or inadequate preservation, inadequate sample volume, inadequate sample documentation, etc.) must be resolved in coordination with the submitting party and laboratory project manager before formal acceptance is executed. All required

- acceptance data is then recorded and documented in the laboratory sample receiving log and laboratory computerized data management system. In addition, a cooler receipt form is filled out for each container in

which sanip1es were received which details pertinent information regarding the condition of the sanp1es - upon receipt. A copy of the cooler receipt form is included with the final report submitted to the client,

Upon completion of sample documentation, the sample custodian assigns a unique laboratory tracking number and storage location identification to the sample. The laboratory computerized data management

- system generates laboratory bench worksheets, project summary sheets and pre-gumrned sample identification labels. These labels contain The sample identification number, client identification, and storage location among other things and are placed on all sample containers for each unique site. The - samples are then placed in the secure sample storage area. The laboratory tracking number is used by the laboratory computerized data management system and laboratory analysts to reference documentation of preparation, analysis and reporting information pertaining to that particular sample in the various

- laboratory operations logbooks.

A laboratory project manager is assigned to each project, or batch of samples entered into the sample

- receiving logbook and laboratory data management system. Upon completion of duties by the sample custodian, the laboratory project manager verifies interpretation of custody forms and subsequent data entry by comparing a computer-generated analysis summary form with sample custody papers. At this point, any discrepancies which were documented by the sample custodian are investigated by the project manager and brought to the attention of the submitting party. Upon completion of analysis, sample results and the associated data entry are likewise reviewed and acted upon by the project manager.

7.3.2 Laboratory Bench Worksheets

- All paperwork generated by the Sample Custodian via the laboratory data management system contains similar information. The laboratory bench worksheets (examples given in Figures 7-9 through 7-12) contain information such as sampling date, field identification number, number of containers for that site,

- all storage locations, the client name and the laboratory Project Manager's name. There are places on these worksheets for the analyst/technician to write preparation data (including dates and initials), and analytical results (including dates, initials arid instrument run numbers ifappropriate). The Sample Custodian places

- these worksheets in a convenient location to alert analysts ofnew "in-house" samples. Worksheets for rush turnaround or minimum holding time projects are hand delivered by the Sample Custodian to the appropriate analyst.

68

524 145

Section No.: Seven Revision No: 10

Date; 10/15/95 Page: 6 of 28

7.3.3 Laboratory Operations Lo2book

Data generated from the preparation, analysis and reporting of each sample is documented in the appropriate logbook pertaining to each procedure performed in the laboratory. Laboratory logbook entries include the identification of the person performing the procedure, the date it was performed and a detailed description of the procedure itself. Sample results are also included in the laboratory Iogbook The laboratory tracking number assigned to each sample is used for documenting all laboratory procedures in the laboratory logbook. Examples of each laboratory logbook used by the laboratory are included in Figures 7-13 through 7-18.

7.3.4 Sample Storage Documentation

Sample storage location is documented by assigning specific locations to each sample. The sample storage location is entered into the laboratory computerized data management system and subsequently appears on ait documentation associated with the sample (i.e. laboratory tracking number sample label, laboratory analysis worksheets, project man.agernent and tracking documents, etc.). Each sample is required to be returned to the storage location indicated on the sample tracking number label upon completion of lab procedures. The sample custodian is responsible for managing compliance with storage location requirements.

The Sample Custodian places all samples in their designated storage areas . These areas are separate from standards, extracts and reagents and are segregated according to the different types of tests for which they are being submitted. More specifically, the volatile organics analysis samples are stored in a separate VOA refrigerator with access by VOA analysts. Likewise, samples for metals analysis are stored in a central storage room (room temperature) while all other samples are stored in a secure walk-in cooler (4-6°C). A sample custody log is maintained as described in Section 7.1.2.g and Figure 7-7.

The laboratory sample tracking number label applied to each sample is color-coded according to date of sample receipt. This allows samples to be purged from storage location for disposal in a systematic manner. Upon expiration of appropriate holding and storage times, samples are staged for disposal. The staging procedure consists of purging storage locations of samples bearing the appropriate color-coded sample tracking number label inthcai.in expiration of necessary storage time. Once verification of project completion and storage time expiration has been made, samples are properly disposed. Typically, all samples are held for a minimum of 30 days alter the final analytical report has been sent to the client. Sample disposal is documented in the laboratory waste disposal logbook.

Extract and digestate disposal is bandIed by each individual analytical group. These ectracts/digectates are maintained for 30 days after final reporting arid then disposed of properly. Specifics of the waste disposal program are described in Section 8.4.

524 14

Section No.: Seven -- Revision No.:

Date: 10115/95

Page: 7 of28

7.3.5 Inter-Laboratory Sample Shipment

- It is necessary at tunes to ship samples andior sample extracts to another laboratory for analysis. Typical situations requiring shipment of samples to a third-party include meeting required turnaround or holding times, parameters not handled in-house, instrument malfunction, etc. Documentation of sample custody for - inter-laboratory shipments include chain-of-custody and laboratory sample analysis request form (see Section 7. 1.2.h and Figure 7-8).

7.3.6 Reporting of Sample Results

Evidence of sample custody documentation is included with the fuial analytical reports submitted to the - client. All reports include a copy of the chain-of-custody and the cooler receipt form, and a copy of any other pertinent sample documentation such as field logs, shipping papers, sample seals, etc. The onginal chain-of-custody form and cooler receipt forni are maintained with associated laboratory records. Lack of compliance with appropriate documentation requirements is addressed in a quality control narrative appended to the final report. Also, any documented discrepancy associated with sampling, sample transport, laboratory acceptance, sample storage or sample analysis is addressed in a quality control narrative appended to the final report. A sample final report is discussed in Section 12.3 and Figures 12-1

through 12-22.

52(1 ¡4;

FIGURE 7-1

SAMPLE CONTAJR LABEL

Cflent Date

Sise lime

Sampie I D

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Section No.:

Date: iQLil95 '-

Page:

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524 14]

FIGURE 7-3

SAMPLING KiT INSTRUCTION FORM

Smpte Kit (nstrüctjori Form

Section No.: Seven

Revision No.: 10 - Date: 10/15/93

Page: 10 of28

Quote !Sar:

h' cooIr or boffles are missing or bruken , please nO(y IJorory immediately: Quanterra Environmental Seniics 5910 Breckenq!arway Suite H

pFlonda 361O (!131G21-0784 pqO4tCT ÑAM

Reue5d by

EMatrix # of container Type Method Hold time Preserv.

i I

Tpritre bl5ink. hc been included n ssch sIüpjng cwtinr. PI.a. do rc* Cu5ody s.als i%v b.n p.o.4dqd wt4cñ m.y bs us. to st U sttppnq eO.taier duflng ranpo.'t been if.. mpef and the LOocory. isrist Cire h.n har.dlng cuU or cD.mUvs pm#'ite .nd pr..9rsef..d DoIs.

Do no fln pr..psw..d Dot.s witt, wnpM.

8ILOT# Pyeservalive Lot# Diue Conc. ¿OMLPRE. HC 4Qm f12504 500ml HNO3 liter P NaCH liter A Other

PRPAREO BY: Verified by:

Comments:

- Interlabora tory Chain of Cirntody

C1IE4T CODE ________

- OUOT I SAP NUMBER . ,4n-1 Ciod Reod

FIGURE 7-4

CHAIN-OF-CUSTODY FORM

8EC(ERlOG PKWY.. STE. H TAMPA. FL 33 P-C*E (Il1)tOA FAX øI3)?4OI

524 150

Section No.: Seven

Revisión No.: 1.2

Date: 10/15/95

Page: H of2S

(ijuan terra ç__.

82766 PROJ. NO. PROJECT ÑAME,tOCATION

PARAMETER

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524 151

FIGURE 7-5

SAMPLE RECEIPT FORM

Section No: Seven

Revision No.: -10

Date: 10/15/95

Page: 12 of28

uan1rra Erv rcn ntai SErdicas, Tarrpa - Sampi! Shipp& Evaivaticr and Rcipt Forni

stRivedbr Dz:Reziv____________ Sizz

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Qerz coo!:r C!i:z cooier

Qzzra hpp:r Box - Arr, 'NO rsor..s or dis zicic should b: xzid L- the Cc:f ¡:E.

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524152

Section No.: 5ven Revision No: Date: 10115195

Page: 13 of28

FIGURE 7-6A

SAMPLE RECEiVING LOGBOOK

IMÇ. un Osti: 9/fli95

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OQ NATR1 tIATE 1I.J! DATE: 9/19/95 STO*CE LOCATION; .f SAMPLE 10: M'J3 C4!MT5:

aoo-ooc00 ANALYSIS: XX-I15EV-9(COO_t.) xxI-54O3-96(TPHI

3-Sl lOI1- .. INITIALS: FAS RECEIVING DATE: 9/1/V5 DATE gEPCQTED JT:

COI MATRIX: UATE DUE DATE: 9/W195 STOLACE LOCTlOM: ..1

SAMPLE ID: COMMENTS:

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3511OIt- .._ INITIALS: NC) !CETYJNG DATE; 9J1/9S OAT! EPOTEO cJT:_______

001 MATPIA: WATU Ott! DATE: 9/26f95 STDAOE LOCATION: . SAPL! TO: á22S MJ2

COMM!NTS: - C0000-00000) ANALYSIT: X-I5-0BI4TRPNI

002 MATRI*: V4TE DUE OATS; 9/26/95 STOACE LOC).T(ON: w

SAMPLE ¡O: 67225 MJ3

COMMENTS: (0000-00000)

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003 M.*Y1X: JATE 0(1! DATE: 4126/95 STOAE LOCATION: w

SAMPLE IO: 67226-01 OIt SAATO COM$CNTS: - (0000-00000)

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8511O7)- INITIALS: FE RECEIVING OAT!: 9/I2/5 DATE EPOTED JT:

aci MATrN: I1ATEP uu OAr!: 9fl7195 TO&ACE LOCATION: i . SA?PLS ID: 1O6-M'.l-O CCM)4E41S: **p. det.,pit/pcbs ird herb's .t be

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(0000-00000) ANALYSIS; G-I-O4-O3-3(N4OI0_L ) ALIO40036O1O_L I SEO4JN36(H70TO_L) JA.I000.36(M6OI0). I

S(-I-4.00-36(MóCI0_L I CAI-O4-ß0-3A(M6O1O_L I CO-I-4-O036M6QO_L I C0-1-04-DQ-36(M6O1OL I

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71

524 153

Section No.: Seven Revision No.: -io Date: 10/15/95 Page: 14 of 28

FIGURE 7-6B

SAMPLE RECEIVING LOGBOOK (Showing saniple disposai record)

sO8D .;e 3O

SAPPL! EEL'I1G LO I4EET n

a-50260023- O4?7 rMui.tLs; C RECEIVING OATE ¿f231c5 O*T PCqT 1:

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524 154 Section No.: Severi

Revision No.: - IQ Date: 10/15/95

Pase: -- 15 pf28

FIGURE 7-7

SAMPLE CUSTODY LOGBOOK

QUANTERRA ENVIRONMENTAL SERVICES, TAMPA SAMPLE CUSTODY LOG

DATE 9ME SAMPLE LO. AMOUNT BY RETURNED AMT. BY

TAKEM DATE TiME

J.1 _ j

73

524 155

FIGURE 7-SA

SAMPLE ANALYSIS REQUISITION TERNAL)

Section No.: Seven Revision No.: W

Date: 10115/95

Page: 16 of2S

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524 156

Section No.: Seven

Revision No.: j..Q

Date: 10/15/95

Page: 17 of28

FLORD. TRACKING NUMBER

CLIENT SAMPLE

ID

DATE SAMPLED

(FAX) ANALYTICAL

DUE DATE

(HARD COPY) REPORT DUE

DATE

NUMBER OF CONTAINERS

PARAMETERS

:

ADDITIONAL COMMENTS: PBY/COMPANY RELINQUISHED ACCEPTED BY/COMPANY

____i DATE TIME

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524 137

Section No.: Seven

Revision No.: -10 - Date: 10115/95

Page: ig of28

FIGURE 7-9

LABORATORY BENCH WORKSHEET GC Volatiles

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524 158

Section No.: Seven Revision No.: Date: 10/15/95 Page: 19 pf2S

FIGURE 7-10

LAB OPATORY BENCH WORKSHEET GCI'MS Semi-Volatiles

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eTlTThelE .......... ) ry* ........... ........ ') ibn:(1.h)4ritf,rac.e .....

rIthrCE* ............ 3nzjCanthrIM ...... LQ ...... :o

"Cì)pTFW ........ IO ....... 'O 3z()rt.rJntMr.e ......

nZçi)p!ryteM ....... 'Q . . .

no(k)ftirantheo ..... tO ...... phenL ether . iO ethyt nthta ........ 'O

utyt .izyt hthtite . . . O ,ithyteno1 ...... tO . O ttate ...... tO

(2-'itrethyU ti3r . . LO -n-4,o-1i r-,phent .

b;-,troisaprpy() ether IO 2,-'trhea( ....... LO a-Lr-3-*ethyLpfleet ..... 0 2.4-O nítr,tue ...... tO

....... IO 2-Di3e* ....... O -,tor.whenoU ........ 10 Di-r-cty1 phtiU' ..... tO

4-rjphen)'1 ph,nt ether. . bi-Ethythsy) hthaLae . tO

4 cC'.'IE5

itrienzene-'5 (Q - 131 )

-tucrbh,yt (07 - 1? )

Ter$inyL-14 (01) - t.Z

2-FIioropenot (0x3 - 11. )

(01) -

IL )

75

524 159

Section No.: Seven

Revision No.: IO

Date: 10/15/95

Page: 20 of2S

FIGURE 7-11

LABORATORY BENCH WORKSHEET Metals

i: :;ii ft :: ;';. c.:i7 i3 : 3:1?:?

aïz u :. : XT

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ro: 94 (5'-7) 4c-

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qinniq OrpTh .00 ili Th .00

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TCJ(13it) -) rETLS, T0T.

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io/c, 0Jc', 1/10/9

.'o ic_ PPTCH Pt / :._:r:cN

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3-l-1) ci::2-t-2 'j -

524 160

Section No.: Seven

Revision No.: j.Q

Date: 10/15/95

Page: 21 of28

FIGURE 7-12

LABORATORY BE4CH WORKSHEET Wet Chemistry

- s 4t; /I1/i7'5

ZT Di J,L'SI3 T 321 Jsr i. ir

ZJIZ4 OtV3T: _____

C2iT CtE 79273 LAB &'c-: I9O1O7-'O

ccw e: !irE:

ID: Tfl02700

ií o: t/o. ctr r.iz: 9t5/?5 ST3E LArro4: v( i IUtC TE 9t27/15

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&I5IS LCC. UIE E £E! LRiIIS Dl!. DE UI-54-DB 02 9/28/9 0/00/00/ mqit 1.0 _J _/ (THtR I 10f23/9 C13-1-03 As Receive

76

524 iGl

Section No.: Seven Revision No.: -10 Date: 10/15/95 '-.- Page: 22 of28

FIGURE 7-13

GAS CHROMATOGRAPHY VOLATILE ORGANICS INSTRUMENT LOGBOOK (Page 1 of2)

QUANTERRA ENVIRONMENTAL SERVICES, TAMPA GAS CHROMATOGRAPHY INSTRUMENT LOGBOOK - VOLATILES

Anityst:__________ Bjt:h:______________ ArTÌI.: STD:__________ Amt.: STD:__________ instrument:______________ Amt.: lS/SS:____________ Amt.: IS/SS:____________ Prcgrnm:____________ AmL:_LCS/MS/MSD:_________ Amt.: LCS/MS(MSD:_________ Calibra Uon;______________

ALS 5rnpt ID Arnoulil Dale Run # List KRI Cornmcrit Purged /

Total lnj__________ STOS__________ Good In]__________ instr. RR__________ Dii RR__________ Carry RR__________

000

524 162

Section No.: Seven

Revision No.: j.Q

Date: 19/15(95

Page: 23 of 28

FIGURE 7-13

GAS CHROMATOGRAPHY VOLATILE ORGANICS INSTRUMENT LOGBOOK (Page 2 of 2)

QUANTERRA ENVIRONMENTAL SERVICES, TAMPA GS CHROMATOGRAPHY INSTRUMENT LOGBOOK - VOLATILES

- Progrm______________________ Application_______________________

Column: Flow Re; iype

- Lençth rT ______mi/miri of_ l.. mm DF UM

PID: f4CD: MoceI Mocel_____________ - TeMa C 'ren'.p _C

R.;n;e/Ae;-:in Reaccr Temp C Mae-Up mi/miti o(_ ?rnot Row nil/min

_____mUmm cf Hyirçen .o;ampir Model___________ Metflad_________

Purge and Trip: Temp Program: Trap Type initl Terna _ C Hold min - Preie;_C_min Rimp_________ C/mm to C HoId_ min Pur_ _mir-. _C Ramp_________ CJtnin C o1 min 3r pure _min C P.am__________ Chnin o C i-iold_ min Prel1ea_ _C Ramp__________ C/mm C -ok mir - Oes3r_ _min _C aie_ min C Tha r..in time min

Prorarn AppUcation

Column: Flow Type

- Lençth n ______nil/min U. mm DF um

- PIO: HECO: Mocel Model____________ Terna C Tenip_____

RflÇeAtef%U3tiOfl ReacorTemp C

- M.ke-p mi/mirt o( Propanol Flow mVin ______nil/min of Hydrogen

Autoamp4erModeI___________ Method________

Purge and Trap: Temp Proqram: Tp Type frutal Temp___________ C Hoid_ min

C/mm o C Hole min Purçe_ _min C R.amp__________ Cknin t3 C Hold_ min Dry' purge _niin _C Ramp________ C/mm to C 14o1d_ min Preneat_ _C P.amg C/un to C Hold min Descro_ _min _C ake_ _min _c Total run time min

77

524 163

AniySt(s)

MSA/ MSB1 ?1SC

VOA1 IVOA#2lVOA3

ALS Lab 1.0., Std. , etc. POS

Section No.: Seven

Revision No.: IP Date: 10/15/95

Page: 24 of 28

FIGURE 7-14

GC/MS rNSTRuMENT LOGBOOK

ÏAN1RA ENVIRONMENTAL SERVTCES, TAMPA GC/MS INSTRUMENT LOG

Oat e

Tune file (for 70s only) Sequence - Batci, on Chern Server

ISIss#__________

Client Code Data File Dii JMisc. Amt. Inj. Method Analysis S

I (on Cham Server)

AddiIinal lnformatlonl Maintenance:

Codr R4.fect R Ree,th.ct X Sc,een S Rnfect Co, ÑL,,bf 01 O.k,tcns '0 (1.2.3..)

sS# - Comments

MS VO,\ (VO1 1) 267

524 164

Section No.: Seven

Revision No.: 10

Daze: 10115195

Page: 23 of 28

FIGURE 7-15

ORGANIC EXTRACTIONS LOGBOOK

QIJANTERRA ENVIRONMENTAL SERVICES, TAMPA BNAIPAH/I-iPLC EXTRACTIONS LOGBOOK

Prep D[e: Matrix : Soil I H20 I TCIP I Waste Concentration dale: Initials:

Initials: -

Extraction Method:

ISAMPLE w. WEIGHTNOLUME pH SURROGATE = L In4JI FffiaI L J' "' Date FnI Date An,unI Am1 I

-L _ H E' t'

N'tes: Solvent Loi # Amount Batch TirneOn: __

- TimeOfi:

78

524 165

FIGURE 7-16

DRY WEIGHT LOGBOOK

QUANTERRA ENVIRONMENTAL SERVICES, TAMPA

Section No.: Seven Revision No.: IO - Date: 10/15/95 Page: 26 of 28

Sarnpre rD Dish weight FnaI wt. + diSti Wi FinII wt. . Dísh wt Jriitial wt. - Dish wt Fin2 wtJIT1itaIwt.Ç9I% Dry Weigti BATCH #

Date entered

+

--- ___________

AnaFyt:

__________ _________i_____________ _____________ Time entered:

. Oven temp.:

Date removed ,

- - -- ___________ Analyst

Time removed :

______________ Oven temc.

Comments

. _________________________ _______________________________________ ____________________________________ I

O 02400

54 166

Section No.: Seven Revision No.: -lo

Date: 10/1 5/95 Page: 27 of2S

FIGURE 7-17

pH LOGBOOK

QUANTERRA ENVIRONMENTAL SERVICES, TAMPA pH

4 Buffer ST C BatcM 5 Buffer STD

____________EXP._________ EXP.__________ Soil SOP LM.WALT-1410

7 Buffer S1t) EXP._________ Water SOP LM-WALT-1470 10 Buffer ST EXP

(2 pt. slope) x (3 pi etf) 3 pt slope 4-

MV Calibre 4 Temp

7

Oate/Analyst lSampie ID J soiL.s pH Comments .: ..: J Water vol. ,,

____________ _______L______ _______ ______ ________

___t____ H _ 3i 79

WETCHEM 4350

524 16?

Section No.: Seven

Revision No. :

Date: 10/15/95

Page: 28 of2S

FIGURE 7-18

TCLP EXTRACTION LOGBOOK

TOE? E:c1-RAc1-Io{ LOGSET

ANALYST_____________________

TU?L_____________________

STARTDATE I ( STOPDATE I I

AM AM STT r : PM STOP TL : :

LABORATORY W. ANALYSES:TALSVOAZ-)ORGANtCS

M.AT?.E(: AQLEOUS (<.5% SOLIDS) ITL4.L WiG-T G AQtJOUS (>í% SOLIDS) FINAL EXTRACT VOLU 4L SOtJ3EDONT rI-IoJAL AQUWLJS VOLLJ ORCANIC UQIJID FINAL ? S.IJ. OT- (S?ECY)

EXTRACTID LUID TY?E: i OR 2 POSITION I lZ EXTRACTOR

LAEOP.ATORY LD. ANALY5ES:.ETAL5_VOA-)_QRCANCS__

M.ATRIX: AQUEOUS (<.W.SOL.ID$) INITIAL WEiC-T C,

AQUEOUS (>.5% SOLIDS) FINA: VOLtJ SOtLJSEDNT ADDITIONkL AQUEOUS VOLL Ml ORGANICLIQLrID FINAL?H S.U. OTI-R (SPECY)

EXTRACTION FLUID TYPE: I OR 2 POSITION 2/ ZEZ EXTRACTOR

LAOP.ATORY LD. ANALYSES: TALS VOA(-) OROANICS

MATRD(: AQUEOIJS(<.5% SOLDS) INITILWE[C-ii _G_ AQUEOUS (>.3% SOLDS) FINAL EXTRACT VOLIJIVE Ml SOflJ$EDNT ADDITIONAL AQUEOUS VOLIJ Ml ORCAYiC LIQUID FINAL ?1{ SU. OTI-ER (SPECIFY)

EXTRACTION FLUID TYPE: i OR 2 POSITION 3! ZZE EXTRACTOR

LA3ORATORY t.D. ANALYSES: TAL5_VOA(L)_ORGANTC5_

MATP.D(: AQUEOUS (<.5% SOLDS) rTrtAL W!iG?:T G AQUEOUS (>.5% SOLIDS) FINAL EXTRACT VOLU?E ML SOJ5ONT ADDITIONAL AQUEOUS VOLtJI.OE ML ORGANIC UQIJID FINAL PH S.U. OT?R (s?CIrfl

EXTRACTION FLUID TYPE: I OR 2 POSITION 4/ ZEZ EXTRACTOR

CO'NT5:

524 168

Section No.: EiQ.ht

Revision No.: Date: 10/15/95 Page: Ipf9

8.0 Analytical Procedures

The laboratory routinely uses only USEPA approved analytical methods and instrumentation. In the absence of US EPA guidance, methods approved by the Florida DEP are used. Analytical methods used by the laboratory for each project are presented in the associated final analytical report. Field methods are limited to p1-I, conductivity, temperature and dissolved oxygen for which the analytical procedures are described in Section 6.9 and soil gas screening as described below.

8.1 Field Screening Methods Summa

An organic vapor analyzer will be used for soil contamination. Organic vapor readings shall be obtained using a Century OVA 128 portable organic vapor analyzer having a flame ionization detector in the survey mcxle. The soil sample shall be brought to a temperature of between 20°C and 30°C in a haif-fifled, 16 ounce mason jar covered with aluminum foil The headspace shall be sampled five minutes thereaftei. The analyzer shall be calibrated in accordance with the manufacturer's instructions.

- 8,2 Analytical Methods Summary

Methods currently use4 by Quanterra Tampa are presented in Section 5.2 arid 5.3. Where matrices and/or analytes of interest are not included in the FDEP approved methods list, a method validation data package is provided in the referenced appendix as outlined below.

8.2.1 Total Phenols in Soil/Sediment

This method validation was not approved by the FLDEP (8-26-92) and has been removed from the CompQAP.

Appendix A contained the supporting method validation package for analysis of total phenols in a soil/sediment matrix. Appendix A has been repealed.

8.2.2 Alternate Hegtin2 Source for Aaueous MetalsDiestion

This method validation was approved by FLDEP (S-26-92) but has been removed from the CompQAP.

The use of the alternate heating source supported by the method validation data in Appendix B has been repealed. This alternate technique is no longer used at the Quanterra Tampa.

524 16'l

Section No.: Eiht Revision No.: 15 - Date: 10/15195 Page: 2of9

8.2.3 Total Fluoride in Soil/Sediment

This method validation has been approved by FLDEP (8-26-92).

Samples of a soil/sediment matrix are prepared and analyzed by modifying and combining EPA Methods 340.1 and 340.2. The modification is based on a distillation preparation and probe analysis procedure developed by EPA Region TV. A summaiy of the method follows:

Place 400 ml of deionized water in the all-glass distillation system (as described in Figure 1 of EPA MethOd 340. 1). Slowly add 200 ml of concentrated sulfuric acid and mix carefully. Add 25 to 3 5 boiling chips to the distillation flask. Pre-distill the acid/water mixture by heating to I 80°C, in order to properly adjust the acid/water ratio and to remove any Fluoride contamination that may be present. Discard the distillate from the pre-distillation. Weigh and add a representative O.5g to 5g portion to the distillation flask containing the acid/water mixture. Add 300 ml deionized water to the flask and repeat the distillation step by heating the acid/water mixture to 180°C until 300 ml of distillate has been collected. Analyze the distillate for Fluoride content using an Ion-Selective Electrode as outlined in EPA Method 340.2. -

Appendix C contains the supporting method validation package for the analysis of total fluoride with a soil/sediment matrix.

8,2.4 Alternate Analysis of Tin

This method validation was not approved by FLDEP (8-26-92) and has been removed from the CompQAP.

The quantitative determination of tin by Inductively Coupled Plasma Atonic Emission Spectroscopy (ICPA.ES) has been shown to be consistent with approved methodologies such as flame atomic absorption spectroscopy.

Appendix D contained a description of the method along with a supporting method validation package. Appendix D has been repealed.

8.2.5 Determination of Qranic Compounds in Aqueous Samples by EPA Method 624 or 8240

This method validation was approved by FLDEP (3-14-94).

Appendix E includes method validation data to support the analysis of a series of organic compounds by EPA Method 624 or 8240. The strictest criteria ofeither method has been met during the generation of this data in order to validate both techniques.

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Section No.: Eight Revision No.: Date: 10/15/95

Page: 3of9

8.2.6 Dioxin Screening Technique

Quanterra Tampa performs the Selected Ion Monitoring (SIM) GCIMS technique to screen for the presence of 2,3,7,8 - TCDDD as described in EPA Method 625. This method is approved and is applicable using water (EPA 625) or SoilíSedirnent matrices by applying SIM to SW846 Method 8270.

8.2.7 Modification to EPA Method 3520

This method validation was approved by FLDEP (3114/94).

Coming Incorporated has developed an alternate, low volume solvent extraction system for continuous liquid/liquid extractions. This technique is performed using the Coming One-Step Extraction vessel. The method validation study included in Appendix G has been approved by the EPA as a replacement for any continuous liquid/liquid techniques performed under NPDES, RCRA and CLP programs.

8.2.7 Determination of OrEanic Compounds in Samples by EPA Method 625 or 8270

This method validation was approved by FLDEP (2/21195)

Appendix H includes method validation data to support the analysis of a series of organic compounds by , EPA Method 625 or 8270. The strictest criteria ofeither method has been met during the generation of this -

data in order to validate both techniques. (Hexachiorophene only for 3510 and 3550).

- 8.2.8 Determination of Or2anic Compounds in Samples b EPA Method 601 or 8010

Appendix I includes method validation data to support the analysis of a series of organic compounds by EPA Method 60 1 or 80 1 0. The strictest criteria of either method has been met during the generation of this - data in order to validate both techniques.

8.2.9 Determination of Hexachlorobenzene in Samples by EPA Method 608 or 8080

Appendix J includes method validation data to support the analysis of a Hexachlorobenzene by EPA Method 608 or 8080. The strictest criteria ofeither method has been met during the generation ofthis data - in order to validate both techniques.

1

81

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Section No.: Revision No.: Date: 10/15/95 Page: 4of9

8.3 Laboratory Glassware Cleaning Procedures

Quanterra Tampa maintains specific glassware-cleaning guidelines wiiich ensure that glassware used in the

laboratory will not interfere with analytes of interest during the actual testing procedure. As presented in

the following section, cleaning procedures are specific for the analyses being performed. Cleaning materials

are outiined in Section 6,3.1.

8.3.1 Organic's Glassware Cleaning Procedures

a) After using a piece of glassware, it is rinsed with the last solvent used and carried to the dirty

glassware area. If it is visibly dirty, it should be washed immediately.

b) The glassware is immersed in a hot, soapy solution of water and laboratory detergent (pH> 10). An appropriate scrub brush is used to scrub the entire interior surface.

c) Rinse the glassware three times vigorously with hot tap water. If the glassware is still visibly dirty, or if spotting or beading occurs, repeat b).

d) After completing the hot tap water rinse, rinse the glassware three times with analyte-free water and place it in the clean ding area. Technical grade methanol and an oven may be used at this point to rinse out water and speed the drying process. Volumetric glassware should not be heated.

e) After drying, the glassware should be spot and stain free. 1f it is not, then repeat the entire procedure.

f) When possible place the glassware in the muffle-oven and muffle the glassware for a minimum of two hours at 400°C, preferably overnight.

g) Clean glassware is inverted (where applicable) and stored prior to use in a designated clean storage location.

h) Before use, glassware is be pre-rinsed with the solvent inherent to a given procedure.

Volarile Organic Glassware Deviation

i) Glassware designated for use in volatiles analyses is maintained in a separate area from semivolatile glassware. Volatiles glassware is rinsed with the following reagents prior to use:

i . Analyte-free water 2. Purge and trap grade methanol 3. Analyte-free water

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Section No.: Eigh Revision No. : 15

%-, Date: 10/15/95 Page: Sof9

8.3.2 Metals Glassware Cleanin2 Procedures

a) After using a piece of glassware, it is rinsed with the last solvent used and carried to the dirty glassware area. If it is visibly dirty, it should be washed immediately.

b) The glassware is immersed in a hot, soapy solution of water and laboratory detergent. An appropriate scrub brush is used to scrub the entire interior surface.

c) Rinse the glassware three times vigorously with hot tap water. If the glassware is still visibly dirty, or if spotting or beading occurs, repeat b).

d) After completing the hot tap water rinse, rinse the glassware three times with analyte-free water and place it in the clean drying area.

e) After air drying, the glassware should be spot and stain free. If it is not, then repeat the entire procedure.

f) Place the glassware in a designated clean storage location free from interferences or contamination.

g) Metals glassware is rinsed with the following reagents prior to use:

1. Analyte-free water 2. 50% nitric acid 3. Analyte-free water

w o,,

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Section No.: Eight Revision No.: 15

Date: 10/15195 Page: 6of9

8.3.3 Wet Chemistry Glassware Cleaniiw Procedures

a) After using a piece of glassware, it is rinsed with the last solvent used and carried to the dirty glassware area. If it is visibly dirty, it should be washed immediately.

b) The glassware is immersed in a hot, soapy solution of water and laboratory detergent. (Omit this step for glassware designated for use in Phosphate determinations.) An appropriate scrub brush is

used to scrub the entire interior surface.

c) Rinse the glassware three times vigorously with hot tap water. If the glassware is still visibly dirty. or if spotting or beading occurs, repeat b).

d) Mer completing the hot tap water rinse, rinse the glassre three times with analyte-free water and place it in the clean drying area.

e) After air drying, the glassware should be spot and stain free. If it is not, then repeat the entire procedure.

F) Place the glassware in a designated clean storac location free from interferences or contamination. Glassware designated for Phosphate determinations is labelled and maintained separately from other glassware.

g) Glassware used in the detennination of Phosphate or Nutrients is rinsed with the following reagents prior to use:

i . Analyte-free vater 2. 50% hydrochloric acid 3 . Analyte-free water

h) Glassware used in TRPH determinations is rinsed with Freon-1 13 prior to use.

8.4 Laboratory Reagent Storaze Procedures

Reagents used for laboratory procedures are purchased from various commercial sources. Records of reagent purchases are maintained by the laboratory. All reagents obtained by the laboratory are labelled with the received and opened date and managed on a rotating stock basis. Laboratory standards are acquired and maintained separately from samples and other chemicals in the same manner as reagents. Storage protocols for laboratory reagents for use in organic, metals, and inorganic methodology are outlined in Table 8-1.

524 174

Section No.: Eiút Revision No.: Date: 10/15/95 Page: 7of9

TABLE 8-1

- LABORATORY REAGENT STORAGE

- Reagent Method of Stora!e

Laboratory Detergent Stored in original containers at each cleaning station.

Nitric Acid Stored in original containers in vented cabinets designed for acid storage

in Metals Preparations Laboratory.

- Sulfuric Acid Stored in otiginal containers in vented cabinets designed for acid storage

in Organic Preparationz Laboratory.

- Hydrochloric Acid Stored in Original containers in vented cabinets designed for acid storage

in Metals Preparations Laboratory.

- Non-Flammable Organic Stored in original containers ìn vented cabinets designed for solvent

Solvents storage in Organic Preparations Laboratory.

- Flanunable Organic Stored in original containers in vented cabinets designed for flammabLe

Solvents solvent storage in Organic Preparations Laboratory.

.- Purge and Trap Methanol Stored in original containers in vented cabinets designed for flammable

solvent storage in Volatile Organics Laboratory.

Isopropanol Stored in original containers in vented cabinets designed for flammable solvent storage in Volatile Organics Laboratory.

Inorganic Reagents Stored in original containers in cabinets or refrigerator designed for reagent storage in Wet Chemistry Laboratory.

- Sodium Sulfate Stored in glass containers steel pans in a dessicator (after muffling in

stainless steel pans) in the Wet Chemistry and Organics Preparation Laboratories.

Organic Reagents Stored in original containers or preparation glassware in refrigerator in

Wet Chemistry and Organics Preparation Laboratories.

Acetic Acid Stored in original containers in vented cabinets segregated from Inorganic Acids in Metals Preparation Laboratories.

- 83

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Section No.: Eight Revision No.: 15

Date: 10/15/95 Page: Sof9

8.5 Laboratory Waste Disposal Procedures

Quanterra Tampa maintains a formal waste disposal program. The disposal program is designed to safely and legally dispose of expired environmental samples and chemical wastes generated by laboratory procedures. Client samples are retained in a controlled access area for 30 days after the analytical report date. If prior arrangements have been made with the client, the samples are returned to the project site by commercial carrier or internal courier. Samples which constitute an excessive volume for disposal or a non-

conforming waste stream are returned to the client.

8.5.1 Solvent Waste Disposal

Processes generating waste organic solvents in the laboratory include organic sample preparation and standard/reagent preparation. Flammable, chlorinated and freon approved waste solvent storage containers are maintained in fume hoods in the appropriate laboratories for segregation and collection of waste solvent. When full, the contents of these containers arc transferred to the corresponding 55 gallon drums for disposal as described in Section 8.5.4.

Solvent extracts are stored chronologically in a refrigerator approved for flammable solvent storage. Upon expiration of required holding times, sample extracts are disposed of by pouring the extract into the appropriate solvent storage container and placing the empty extract container into the appropriate solid waste container. Similarly, other waste solvents are disposed of by placing them in the appropriate vaste collection container for proper disposal by the laboratory. Residual solvents generated from extraction of aqueous samples are allowed to separate from the aqueous matrix for a minimum of 24 hours in a carboy. The water is then decanted into the sink and the remaining solvent is placed ui a solvent collection container.

8.5.2 Aqueous Waste Disposal

Aqueous waste, including aqueous samples, digestates, dilute standards and reagents are neutralized to a pH of 5 to 7 before discarding into the sanitary sewer with copious amounts of rinse water. Concentrated standards or reagents are neutralized and containerized in an aqueous waste drum which is then disposed of by a commercial disposal company, as outlined in Section 8.5.4.

8.5.3 Solid Wste Disposal

Solid laboratory wastes can be divided into hazardous and non-hazardous classifications. All solid samples submitted to the laboratory are considered to be hazardous and are disposed of as such. Upon expiration of appropriate holding times, solid samples are transferred to the solid hazardous waste drum. Non-pumpable liquids and semi-solids (such as oils or sludges) are also consolidated into the solids' drum. Any sample containers which may contain sample residue are added to the drum for disposal as well . Section 8.5.4 outlines disposal protocol for solid waste. Waste deemed non-hazardous (i.e. empty sample containers, disposable pipets, etc.) is collected in the laboratory and disposed ofseparately by conventional means.

- 524 171

Section No.: Eiht Revision No.: Date: 10/15/95 Page: 9of9

8.5.4 Laboratory Chemical Waste Disposal

Laboratory wastes which do not fit into any aforementioned category are disposed of by contracting a third party who is qualified to perform Lab Pack Disposal or by returning the waste to the party from whom it was obtained (if applicable).

8.5.5 Waste DisDosal Documentation

Fifty-five gallon drums are maintained by the laboratory in compliance with RCRA regulations for disposal of waste solvents. Sampling and analysis of full drums are done in compliance with requirements imposed by the appropriate disposal company used by the laboratory. The laboratory typically uses Universal Waste and Transit for transport of laboratory wastes.

All records of waste disposal are maintained in the Laboratory Waste Disposai Log. Records include results of analyses performed on the waste, waste disposal manifests, correspondence from disposal firms and any other information necessary to document the disposal of laboratory wastes.

8.6 Mobile Laboratory Analytical Capabilities

All requirements listed in Section 8.0 through Section 8.5 apply to any mobile laboratory facility set-up by - Quanterra Tampa.

All analytical methods listed in Sections 5.1, 5.2 and 5.3, and Sections 8.0, 8.1 and 8.2 can be performed - for screening analyses and qualitative data in the mobile laboratory. Glassware cleaning procedures outlined in Section 8.3 will be followed in the mobile laboratory. Reagent tracking and storage iii the

- mobile laboratory will be maintained as outlined in Section 8.4. Waste disposal will be performed in the - mobile laboratory as outlined in Section 85.

-

w

w

84

w

w

524 177

Section No.: Nine Revision No.: li Date: 1015/95 Page: of18

9.0 Calibration Procedures and Frequency

9.1 Instrumentation

Quanterra Tampa uses EPA approved instrumentation desired to meet or exceed EPA method performance specifications. A list of Field Analytical Equipment is presented in Table 9-1 and a list of current Laboratory Major Analytical Instrumentation is presented in Table 9-2.

All instrumentation located at Quanterra Tampa can be removed from the facility and set-up in a mobile laboratory. When it is technically not feasible or analytically not prudent to use existing instrumentation, similar instrumentation will be purchased or leased to provide analytical capabilities in a mobile laboratory. This additional equipment will be specifically referenced in a CompQAP revision, addendum, or in a site

specific quality assurance plan at the time the mobile laboratory is initiated.

TABLE 9-1

FIELD ANALYTICAL INSTRUMENTATION

Name, Model, Purchase Date

YSI 5 IB Portable/Stationary Oxygen Meter 1990

Field grade thermometers Various Dates

Orion SA2IO Portable pH Meter I 993

Century OVA 128 Portable Organic Vapor Analyzer i 993

Hach DRIOO Colorimeter Date Unknown

Specifics

Field dissolved oxygen measurements

Field temperature measurements

Field pH and conductivity measurerucrits

Field organic vapor determination

Field determination ofresidual chlorine

85

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Section No.: Nine Revision No.: 14 - Date: 10/15/95 Page: 2of 18

TABLE 9.2

LABORATORY MAJOR ANALYTI CAL INSTRUMENTATION

Name, Model, Purchase Date Specifics

VOLATILE ORGANICS:

Perkin Eimer 8500 GC PID detector and I-IECD detector in series; Tekmar LSC 4000 1989 concentrator; Tekrnar ALS 4200 autosampler; SF4290 dual

channel integrator; Nelson Turbochrom Ill chromatography software.

Perkin Elmer 8500 GC ND detector and 1-LECD detector in series; Tekrnar LSC 2000

1990 concentrator; Tekmar ALS 2050 autosampler; SP4290 dual channel integrator; Nelson Turbochrorn HI chromatography software.

Hewlett Packard 5890-II GC Dual, Tandem 0.1. PII) detectors and OJ. HECD detectors; 1991 Dual 0.1. 4460A sample concentrators. Dual 0.1. MPM-16

autosamplers; Nelson Turbochrom III chromatography software.

Hewlett Packard 5890 GC Electron Capture Detector; Tekmar LCS concentrator: 1988 0.1. 4460A concentrator; 0.!. MPM-16 autosampler;HP 3394A

integrator.

Hewlett Packard 5890 GC-II Tandem 0.!. PIDIFID detectors; Hewlett Packard FID detector;

1992 Nelson Turbochrom HI chromatography software. Tekmar 7000 Head space unit.

Hewlett Packard 5890 GC Connected with HP5970 Mass selective detector; Tekmar LSC

1989 2000 concentrator; Tekmar ALS 2016 autosampler.

Hewlett Packard 5970 MSD Electron impact Mass Selective detector; RiT-6 1000E-series 1989 computer; Aquarius software with EPA library; HP 7914 tape

drive; HP rugged writer printer.

Hewlett Packard 5890 OC Connected with 1-1P5970 Mass selective detector; Tekmar LSC 1992 2000 concentrator; Tekrnar ALS 2050 autosampler.

Hewlett Packard 5970 MSD Electron impact Mass Selective detector; RTE-6 i 000E-serics i 992 computer; Aquarius software with EPA library; HP 79 14 tape

drive; 1-IP rugged writer printer.

524 179

Section No.: Nine RevsionNo.: 14

-4 Date: 10/15/95 Pase: 3pf18

TABLE 9-2

LABORATORY MAJOR ANALYTiCAL INSTRUMENTATION (continued)

Name, Mode], Purchase Date Specifics

SEMI-VOLATILE ORGANICS:

Hewlett Packard 5890 GC Dual Electron Capture Detectors; HP 7673A auto-injector; HP 1988 Turbochrom 4 data station

Hewlett Packard 5890 GC Dual flame photometric detectors with 7673 A autosarnpler and 1993 HP Turbochrom 4 data station

Hewlett Packard 5890 GC 1993



Hewlett Packard 5970 MSD 1990

- Hewlett Packard 5890 GC 1993

Hewlett Packard 5972 MSD 1993

Hewlett Packard 1050/1 046A HPLC 1993

w

Dual nitrogen phosphorus detectors and HP Turbochrorn 4 data station

Dual electron capture detectors with Leap autosampler and HP Turbochrom 4 data station

Connected with HP5970 Mass selective detector; HP 7673 auto -injector and RTE-A data system

Electron impact Mass Selective detector; RiT-A i 000-series computer; Aquarius GC/MS softre Rev, F with HP 9144 tape drive; HP rugged writer printer. NIS/EPA/NIH 751(162K mass spectral database.

Connected with HP 5972 Mass selective detector; HP 7673 auto -injector and Chemstation data systcm.

ElMS Detector, HP Chem Station B.02.02 with G1034C ver. C.0 i .05; EnviroQuant Target Compound software; NISIEPAJNIH 75K MS Database; 1-IP Vectra 486/66 PC; internal Colorado Jumbo 250 archive system; 7686 PrepSiation System.

HPLC with diode array and Fluorescence detectors; autosampler and Chemstation data system

86 w

524 ir'

Section No.: Nine Revision No.: 14

Date: 10115195

Page: 4of18

TABLE 9-2 - LABORATORY MAJOR ANALYTICAL INSTRUMENTATION

(continued)

Name, Model, Purchase Date

ORGANIC EXTRACTIONS:

Organornation 120 Evaporators 1989, 1991

Organomation 111 Nitrogen Evaporator 1988

Te1ar 500 Sonicator 1987

Fisher HN-SII Centrifuge 1991

Despatch 1000V Muffle-Oven 1991

Branson Sonifier 450 Sonicator 1993

Gyrotory Shaker - Mode! G2 1993

Thermolyne-Type 37600 1992

ABC GPC System 1993

Specifics

Two eight-place steam bath units or Kuderna-Danish concentration; closed system for re-collection of distilled solvents.

Twelve-place nitrogen blowdown unit for micro- concentration of exacts with heated bath.

Macro and Micro horn tips; Sonic disruption extractor; equipped with sound-proof box.

Four-place centrifuge; 50 mL tube capacity.

Capable of 1400°F temperature; 6 cubic feet interior; recirculation fan.

Macro Tip with box

0-500 RPM Rotary Shaker, used for Herb soils (8150) and method 89-45.

Vortex mixer

GPC sample unit (Autoprep 1000) with 23 sample 1993

positions; ABC UVD- i detector and ABC SCR- 1 chart recorder.

524 181

Section No.: Ìthn

RevisionNo.: j

Date: 10/15195

Page: 5pf18 - TABLE 9-2

LABORATORY MAJOR ANALYTICAL INSTRUMENTATION (continued)

Name. Model, Purchase Date

METALS:

Leeman Labs PS 1000 ICP 1989

Perkin Elmer 51 OOZ GFAA 1989

Perkin Elmer 51 OOZ GFAA 1993

Thermo Jarrel Ash ICP 61 1993

Thermo Jarre I Ash ICP 61 Super Trace 1994

Leeman Labs PS200 1994

Coleman 5013 Hg Analyzer 1989

CEM MDS-81D Microwave - 1988

Specifics

Sequential Atomic Emission Detectors; ACER 915 Pc with PS-senes ICP software; Okidata 320 printer.

Graphite Atomizer with Zeeman Background Correction; IBM PS/2 Model 50 with PE 5100 software; PE AS-60 autosanipler; Dual Electrodeless Discharge Lamp power supply; Epson LX-800 printer.

Graphite Atomizer ih Zeeman Background Correction; IBM PSI2 Model 70 with PE 5100 software; PE AS-60 autosanipler; NEC Pinwritcr P2200

Simultaneous Atomic Emission Detectors

Simultaneous ICI' with autosarnpler and axial torch

Automated cold vapor and data station

Manual, closed-system cold vapor mercury analyzer; Lloyd 450 linear chart recorder.

Programmable microwave oven with turntable.

87

524 18:


Date: 10/15/95 Page: 6of18

TABLE 9-2

LABORATORY MAJOR ANALYTICAL INSTRUMENTATION (continued) -

Name. Model, Purchase Date

WET CHEMISTRY/MISCELLANEOUS:

Buck HC404 Spectrophotometer 1990

Flach 2100A Nephelometer 1990

YSI 32 Conductance Meter 1990

YSI SiB Oxygen Meter 1990

Fisher 925 pH/TSE Meter 1990

Flach 456 Digestion Block 1990

CSA 1341 Calorimeter 1984

WAL Rotary Extractor 1989

Pensky-Marten Flash Tester 1990

Fisher Scientific Versa-bath 1-lot Water Baths 1984, 1991

Incubator,Labline Instruments, Inc. 1992

Specifics -

Direct read, Infrared hydrocarbon analyzer; multiple cell path-lengths.

Direct reading turbidimeter.

Temperature compensation; direct reading.

Direct reading Dissolved Oxygen meter; Probe withstirrer.

Multi-point calibration; temperature compensation; Ion-selective electodes for fluoride and ammonium

Chemical Oxygen Demand reaction heater; 25 sample capability vith timer.

Parr Bomb/Calorimeter with stirrer; remote ignition; stainless steel bomb.

Two 8-place rotary extractor; satisfies TCLP/EPTOX construction and performance requirements.

Closed cup with stirrer; electric heating mantle.

Two baths with stainless steel tank with removable cover.

Equatherm Ambi-Hi-Lo Chamber

524 183

Section No.: Nine Revision No.: 14 Daze: 10/15/95 Page: 70f 18 - TABLE 9-2

LABORATORY MAJOR ANALYTICAL INSTRUMENTATION (continued)

Name, ModelL Purchase Date

WET CFEMISTRY (continued)

01 Analytical Model 700 TOC analyzer 1993

Therrnolyne Type 1400 Muffle Furnace

Fisher Scientific Isotemp Drying Oven Model 655F

Scientific Products TempCon Gravity Convention Oven

PE UVIUIS Spectrometer Lambda 2

with Super Sipper 1992

Mitsubishi Kasei Corp. TOX 10 Sigma 1993

Dionex 4500 1993

Lachat Quikchem AE 1994

Specifics

Autosampler (ASM) Model SHLR Epson FX85

12000 C Temperature range

220° C Temperature range

210°C Temperature range

Okidata Microline 320 printer

5 channel preparator

Ion chrornatograph with autosa.rnpler and A1450 data station

Automated flow injection ion analyzer

524 181

Section No.: Nine Revision No.: 14 - Date: 10/15/95 Page: 8of18

TABLE 9-2 - LABORATORY MAJOR ANALYTICAL INSTRUMENTATION

(continued)

Name, Model. Purchase Date Siecifics - MISCELLANEOUS

Millipore ZHE extractors 1990

Millipore Filter Apparatus 1990

Fisher Filter Apparatus 1990

S/P 182 Analytical Balance 1989

Sartorius 200 Analytical Balance 1990

Sartorius 3100 Toploading Balances (2) 1990

Mettler 3600 Toploading Balance 1984

Two stainless steel extractors with inlet pressure gauge; meets TCLP requirements.

Positive pressure device; stainless steel with teflon coating; meets TCLP!EPTOX requirements

Positive pressure stainless steel device; meets TCLP/EPTOX requirements.

- 524 185

Section No.: Nine RevisionNo.: 14

Date: 10115195

Page: 9of18 9.2 Standards

9.2.1 Receipt and Traceability

Receipt of laboratory analytical StaIId&dS is documented in the appropriate laboratory standard tracking logbook (see Figure 9-1). A separate logbook is maintained for each of the major analytical groups: Metals, Volatile Organics, Wet Chemistry and Semi-Volatile Organics. The logbook contains information listing receipt date, manufacturer's lot number, standard name, concentration, and expiration date, and the assinent of a unique tracking number. The logbook is used as a reference for purging expired standards from their storage locations for disposai. Records including certificates of traceability and manufacturer's assay arc maintained by the laboratory in addition to records of standard orders and packing slips, in order to document the acquisition of standards. Upon receipt and subsequent entry into the standard tracking logbook, each standard is labelled vith receiving and expiration dates and a unique tracking number, then placed in the appropriate storage location indicated in the logbook.

9.2.2 Standard Sources and Preparation

To ensure the highest purity possible, all primary reference standards and standard solutions used by - Quanterra Tampa obtained from the National Institute of Standards and Technology, CRADA or A2LA

vendors, or other reliable commercial sources. Procedures for the preparation of working standards from neat and stock standards acquired by the laboratory are documented in the appropriate laboratory standards tracking logbook by analytical group as presented in Table 9-3.

9.2.3 Standardization of Titrating Solutions

- Quanterra Tampa purchases manufacturer's standardized and certified titrating solutions. The solutions are verified in the laboratory by analyzing an independently-obtained check standards and solutions. The

- - laboratory acquires titrants from Banco, RICCA and Mallinkrodt.

9.2.4 Mobile Laboratory Standards Requirements

Procedures for standards receipt, traceability and preparation will be followed in the mobile laboratory as outlined in Section 9.2.1, Section 9.2.2 and Section 9.2.3 . Preparation, storage and shelf-life criteria

- outlined in Table 9-3 will be used in the mobile laboratory

-

89

524 18h

TABLE 9-3


Date: 10/15/95 Page: lOofI8

STANDARDS SOURCES AND PREPARA11ON

Standard Source Preoaration Procedure Storage

Gas Chromatography - Volatiles:

UltraScientific Dilution into VOA Freezer (A2LA), Supelco; Methanol for >1000 ppm in Working Standard Methanol Chemservice; Neat

Gas Chromatography - Semi-Votatiles

Ultra Intermediates Semi-Vol Freezer Scientific,(A2LA), Prepared by Supelco, Diluting Source Accustandard Standard into Chemservice: Neat Acetone or Hexane Standards and 200 - >2000 ppm Standards in Solution

HPLC - Semi-Volatiles

Ultra Intermediates Semi-Vol Freezer Scientific,(A2LA), Prepared by Supelco, Diluting Source Accustandard Standard into Chemservice: Neat Acryoraitnie Standards and 200 - >2000 ppm Standards in Solution

Frequency

Monthly, Weekly (Gasses)

Semi-Annual (Stocks)


524 187


Date: 10115195

Page: liofiS

TABLE 9-3

STANDARDS SOURCES AND PREPARATION (continued)

Standard Source Preparation Procedure Storage

Gas Chromatography/Mass Spectrometry - Volatiles:

Chemserv: Neat Dilution into VOA Freezer Standards Methanol for UltraScientific Working Standard (A2LA), Accustandard/ Supelco: >1000 ppm in Methanol

Gas Chromatography/Mass Spectrometry - Semi-Volatiles:

Chemserv: Neat In Dichiorornethane: Semi-Vol Freezer Standards Dilute Neats into UltraScientific Intermediate Stock. (A2LA) >1000 ppm Dilute Intermediate in Stock into Working Dichioromethane Standard.

iicncv

Monthly, (Gasses Weekly)

SemiAnnual (Stocks)

90

524 18


Date: 10/15/95 Page: 12of18

TABLE 9-3

STANDARDS SOURCES AND PREPARATION (continued)

Standard Source Preparation Procedure Storage

Metals (Includes ICP, GFAA, and Mercury Analyzer):

NIST and VHG Dilution of Source Rm. Temp. >500 ppm Solutions for Intermediate .15% HNO3

Standard Rm. Temp.

Dilution of .15% HNO3 Intermediate for Working Standard

Ion-Selective Electrode (includes pH, Fluoride, and Ammonia):

ORION Prepared No Preparation Wet Chem Solutions Necessary Refrigerator

Spectrophotometer (includes Cyanide, Phenol, Phosphate, MBAS, Chloride, Sulte, Nitrate, and Nitrite):

ORION, Banco, No Preparation Wet Chem Ma]linkrodt, EPA Necessary Refrigerator and Ricca Prepared Solutions

Miscellaneous (includes COD/BOD, Acidity, Alkalinity, Turbidity, Hardness):

Ricca, Hach and No Preparation Wet Chem Mallinkrodt Necessary Refrigerator Prepared Solutions

Freuencv


Daily (Working Standards)

Semi-Annual

Semi-Annual

Semi-Annual

-

- 9.3 Calibration

524 189 Section No: Nine Revision No.: 14

Date: 10/15/95

Page: 13 of 18

Quanterra Tampa maintains specific procedures for the operation and calibration of all analytical instruments. Along with proper maintenance, these practices ensure optimum instrument performance and accuracy. These procedures include proper operator training and supervision, mandatory instrument performance specifications, and systematic instrument calibration, verification, and monitoring schedules.

9.3.1 Field Instrument Calibration

Calibrations will be performed in the field before analysis ofany samples, every four hours, and at the end of the day When multiple sites are to be sampled in the same day, a calibration verification before subsequent analysis at a different site is all that is required. All calibration, verification and sample analysis data will be recorded in the field sampler's logbook.

Automatic samplers are calibrated prior to each use by collecting a sample into a container with graduations and determining sample volume taken. Adjustments may then be made as appropriate to collect the correct sample volume for that event.

- Dissolved oxygen meters will be calibrated against saturated air daily or before use and against the winkler titration on an annual basis. The OVA meter will be calibrated daily or before each use using a single

- calibration span gas per manufacturers instructions. Carbon filters will be employed to distinguish between VOHs and methane when appropriate and if necessary background correction will be made for ambient air measurements.

9.3.2 Laboratory Instrument Calibration

The laboratory utilizes mandatory instrument performance specifications to constantly ensure optimum instrumental performance. These performance specifications require acceptable instrument response to - specific performance standards prior to initiating further instrument calibration and analyses. Acceptable instrument response criteria are based upon EPA or manufacturer analytical method specifications, Initial instrument calibration curves are generated, verified, and routinely monitored throughout the duration of all - instrumental analyses. All calibration and verification data is documented and filed chronologically. In the case of a method or project calibration requirement that is more stringent than those listed, the most stringent will be used. Specific calibration procedures for laboratory instruments, including the frequency - and standards used, are listed below.

i . Gas ChromatograDhv & HPLC -

a) A multi-point calibration curve shall be generated initially, each time method-specified continuing calibration criteria are not met, or a minimum of once per month. For EPA 600 - series methods the initial calibration will consist of 3 standards covering the linear range of the instrument to be utilized for analysis. For EPA SW846 methods a curve consisting of 5 standards will be similarly produced initially. Criteria for acceptable calibration curve - responses shall be followed as specified in the appropriate method.

b) Continuing calibration standards shall be analyzed when initia! calibration is not - performed, and after every 10 samples. Specifications for acceptance criteria for EPA 600 series and EPA SW846 methods will be followed for each analyte detected in the sample.

91

524 IY


Date: 10/15/95 Page: 14of18

c) Internal standards are added to each standard and sample.

d) System cleanliness is verified with analysis of a method blank prior to system calibration.

2. Cas Chromatorat,hvfMass Spectrometrv

a) The instrument shall be tuned to meet EPA established abundance criteria for DFTPP or

BFB to assure acceptable library search capabilities. For EPA 600 series methods the GC/MS shall be tuned a minimum of on per 24 hours. For EPA SW846 methods the GC/MS shall be tuned a minimum of once per 12 hours.

b) A multi-point calibration curve shall be generated initially, each time method-specified continuing calibration criteria are not met, or a minimum of once per month. For EPA 600 series methods the initial calibration will consist of 3 standards covering the linear range of the instrument to be utilized for analysis. For EPA SW846 methods a curve consisting of 5 standards will be similarly produced initially. Criteria for acceptable calibration curve responses shall be followed as specified in the appropriate method.

c) Continuing calibration standards shall be analyzed once per tune (when initial calibration is

not perfomied). Specifications for acceptance criteria for EPA 600 series and EPA SW846 methods will be followed for each analyte detected in the sample.

d) Internal standards are added to each standard and sample.

e) System cleanliness shall be verified by the analysis ofa method blank after tuning and prior to system calibration.

3 . Selected Ion Monitoring by Gas ChrornatograDhvfMass Specirornetrv (Dioxin Screen)

a) The GCIMS shall be operated as described above for base/neutral determinations.

b) The instrument shall be set up to acquire data in the SIM mode using the ions specific for 2,3,7,8- TCDD at m/z 257, 320 and 322.

c) A single standard at 1 mg(L is analyzed to verify screening efficiency.

d) An instrument blank is analyzed to verify system cleanliness.

4, lnductive1vÇguileiP1asma Atomic Emission Spectrophotomet'

a) A multi-point calibration curve shall be generated initially, each time method-specified continuing calibration criteria are not met, or a minimum of once per week. The initial calibration will consist of 3 standards covering the linear range of the instrument to be utilized for analysis. The curve will be accepted ifthe calculated standard values deviate more than l0% from their true values. The curve will be verified before each sample set by analyzing an Initial Calibration Verification standard which must be within i 0% of the true value.

.524 191

Section No.: Nine - Revision No.: 14

Date: 10/15/95

Page: 15of18 - b) Continuing calibration standards shall be analyzed after every IO samples. The calibration curve shall be re-sloped when continuing calibration standards indicate a RSD in excess of 10%.

c) Elemental interferences shall be evaluated by the analysis of an interference check sample at the beginning and end of each sample set.

d) System cleanliness shall be verified by the analysis of an instrument blank prior to system calibration and after every 10 samples.

5. Atomic Absorption Spectrophotometrv

a) A multi-point calibration curve shall be generated each time the method is performed. The initial calibration will consist of 5 standards covering the linear range of the instrument to be utilized for analysis. The curve will be verified before samples are analyzed by analyzing an Initial Calibration Verification standard which must be detected at ±10% of the true value or the curve Will be regenerated.

b) Continuing calibration standards shall be analyzed after every 10 samples. The calibration curve shall be re-sloped when continuing calibration standards indicate a RSD in excess of 10%. The calibration curve shall be regenerated if the re-slope standard is not within 20% of the original curve.

c) System cleanliness shall be verified by the analysis of an instrument blank prior to system calibration and after every 10 samples.

6. Ion Selective Electrodes

a) A multi-point calibration curve shall be generated initially, each time samples are to be analyzed. The initial calibration will consist of 3 standards (5 when directly reading - millivolt values) covering the linear range of the instrument to be utilized for analysis.

I . When reading concentrations from the meter, the calibration curve is calculated and - contained within the meter. The efficiency of such a curve must be greater than 0.96 and two verification standards must be detected at ±10% oftheir true value.

2. When reading millivolts from the meter, the values are entered into a Lotus 123® spreadsheet which calculates a concentration curve based on the method of least squares. The correlation coefficient of this curve must be 0,996 or greater and the - Initial Calibration Verification standard must be within i 0% of the true value or the curve must be regenerated.

b) Continuing calibration standards shall be analyzed after every 10 samples. The calibration , curve shall be regenerated when continuing calibration standards indicate a RSD in excess of 10%.

c) System cleanliness shall be verified by the analysis of a method/instrument blank prior to system calibration and after every i O samples. 92

524 19'


Dale: 10/15/95 Page: 16of18

7. UVIVJS Spectrophptpmeter

a) A multi-point calibration curve shall be generated initially and/or each time samples are to be analyzed. The initiai calibration 11 consist of 3 standards covering the linear range of the instrument. The initial calibration curve must have a RSD of less than or equal to 20%.

b) Continuing calibration standards shall be analyzed alter every 10 sampLes. The calibration curve shall be regenerated when continuing calibration standards indicate a RSD in excess of 10%.

c) System cleanliness shall be verified by the analysis of an instrument/method blank prior to system calibration and after every 10 samples.

8. Infrared SDectrophotometer

a) A multi-point calibration curve shall be generated initially and/or each time samples are to be analyzed. The initial calibration will consist of 3 standards covering the linear range of the instrument, The initial calibration curve must have an RSD of less than or equa] to 20%.

b) Continuing calibration standards shall be analyzed after every 10 samples. The calibration curve shall be regenerated when continuing calibration standards indicate a RSD in excess of 10%.

c) System cleanliness shall be verified by the analysis of a method blank prior to system calibration and after every 10 samples.

9. Baianccs

a) Balances are calibrated and certified annually by a vendor-certified technician utilizing paired Class S weights. Daily checks using Class S weights verifies the continuing accuracy ofthe calibration.

10. Flow Injection Ion Analyzer

a) A multi-point calibration curve shall be generated initially and/or each time samples are to be analyzed. The initial calibration will consist of at least 3 standards covering the linear range of 'the instrument. The initial calibration curve must have a correlation coefficient greater than or equal to 0.995.

b) Continuing calibration standards shall be analyzed after every 10 samples. The calibration curve shall be regenerated when continuing calibration standards indicate a % difference in excess of 10%.

c) System cleanliness shall be verified by the analysis of an instrument/method blank prior to system calibration and after every 10 samples.

a

a 11. Ion Chromatography

524 193

Section No.: Revision No.: Date: 10115195

Page: 17 of 18

a) A multi-point calibration curve shall be generated initially and/or each time samples are to - be analyzed. The initial calibration will consist of at least 3 standards covering the linear range of the instrument. The initial calibration curve must have a correlation coefficient greater than or equal to 0.995.

a b) Continuing calibration standards shall be analyzed after every 10 samples. The calibration

curve shall be regenerated when continuing calibration standards indicate a % difference in excess of 10%.

c) System cleanliness shall be verified by the analysis of an instrumentimethod blank prior to system calibration and after every 10 samples.

12 Miscellaneous Thstruments

a) Additional inorganic analyses using a single-point standard for quantitation include COD, BOD, Alkalinity, Acidity, Turbidity, Hardness, and Specific Conductance. Specifications listed in the individual methods and/or instrument manuals shall be followed for these analyses.

b) All refrigerators, freezers, and oven temperatures are monitored twice daily (Monday through Friday, excluding Holidays).

9.3.3 Mobile Laboratory Calibration Requirements

The calibration procedures detailed in Section 9.3 will be followed in the mobile laboratory.

- An initial calibration and method verification will be performed each time an instrument is placed into a service in the mobile laboratory. Method verification will include a method detection limit study to ensure the operational integrity ofthe instrumentation. This data will be supplied in the tables in Section 5 of the CompQAP, or in a site specific quality assurance plan at the time of data generation. Instrument - calibration will be verified according to method specification and as outlined in Section 9.3.

a

a

93

524 191

Section No.: Nine

Revision No: Date: 10/15/95 Page: 18 of 18

FIGURE 9-1

LABORATORY STANDARD TRACKING LOGBOOK

QUANTERRA ENVIRONMENTAL SERVICES, TAMPA

LABORATORY STANDARDS TRACKING FORM

Sour:e PrepraUon

::::_:ate Let No. Purity ExiraEion Inttial Flrii Oiiuert FInII CorcentratIOr sStndrd * !xp.Dtc

T:

H

t 3 NOTE: OC cMck3 $S eq.4rsd btoi. u*ç arty ni. to pre1r. 0 Immpie.

LSl t3 250077

524 195

Section No. :Ten Revision No.: 12

Date 10/15/95 Page: lof7

10.0 Preventative Maintenance

Quanterra Tampa maintains a routine training and laboratory equipment maintenance program for all major instrumentation. Laboratory Instrument Service Logbooks are assigned to each instrument to detail and document the service of all equipment included within this program. A program of routine maintenance procedures ensures minimal downtime, as well as proper performance of analytical instruments. A substantial spare parts inventory is also rnaintaiIied to assure timely repair of instruments. Specific preventive maintenance procedures for field equipment are listed in Table 10-1 and for laboratory equipment in Table 10-2.

10.1 Documentation of Maintenance and Repair Activities

Routine and non-routine maintenance procedures for laboratory instrumentation are documented in instrument-specific maintenance logbooks. Each logbook is kept near the associated instrument and is updated as necessary to indicate maintenance and repair activities. Logbook entries inc'ude the date, initials of the person(s) performing the maintenance and/or repair, a description of the problem or reason for the action, a brief summary and the result of the activity.

A logbook containing information pertaining to daily checks of various laboratory equipment is also maintained by the QA Manager. This logbook is used daily to document performance of analytical balances, the laboratory D.I. water system, refrigerator temperatures and oven temperatures. If necessary,

f repairs and/or maintenance to each of these systems is effected before use by the laboratory each day. Defective equipment is removed from service when timely repair is not possible. Vendor-specific files are maintained which document routine service and repair of laboratory equipment not performed by laboratory

- personnel.

10.2 Contin!encv Plans for Equipment Failure

- In the event of equipment failure which may affect the proper performance of any laboratory activity, the

. QA Manager and Laboratory Director are immediately notified. The cause ofthe failure, and any affect on the quality assurance associated with that particular activity prior to and at the time of the íilure are determined. Appropriate corrective action is implemented. 1f necessary, laboratory data associated with the petiod of inferior equipment performance will be qualified or invalidated. The affected client will be notified in the case that final data is impacted.

1f available, work will be switched to backup equipment until necessary repairs are completed. Factors such as sample holding time and integrity, client urgency and anticipated repair time will be monitored. 1f necessary, a subcontractor will be chosen to complete the task. Appropriate consideration will be given to necessary approvals, certifications, and client acceptance ofthe subcontractor.

94

524 196

Section No. :Ten Revision No.: 12 - Date 10115195

Page: 2of7 10.3 Mobile Laboratory Set-Up and Preventative Maintenance Requirements - The preventative maintenance schedule outlined in Section 10.0 will be followed in the mobile laboratory.

Maintenance logs will be maintained for each instrument in the mobile laboratory outlined in Section 10.1. - A complete system check will be performed before the instrument or equipment is used for analysis in the mobile laboratory. At a miniinum, maintenance points listed in Table 10-1 and Table 10-2 will be checked. All power will be provided by the contractor at the mobile fciIity location. -

-

-i

524 197

Section No. :

RevisionNo.: 12

-, Date 10/15/95 Page: 3of7

- TABLE 10-i

PREVENTATIVE MAINTENANCE PROCEDURES

- FIELD INSTRUMENTATION/EQUIPMENT

- INSTRUMENT ACTIVITY FREQUENCY

pH Meter Check Probe Solutions Daily Check for Cracks Daily - Check Reference Jundions Daily Clean Probe Each Use

- Conductivity Meter Clean Probe Each Use

Check Standard Solutions Daily

Dissolved Oxygen Check Membrane Daily Meter Change Membrane As Needed

OVA Meter Check Filters Each Use Check Concentration Alarm Each Use Check Flame Jition Each Use Check Pump Each Use Check Battery Daily Check Gas Supply Each Use Check Lead Wire Each Use Check Connectors Each Use

Grundlos Submersible Check Converter Each Use Pump Check Converter Connector Each Use

Check Lead Wires Each Use Check Inner Rings Bi-Weekly Check Inner Impeller Bi Weekly Cheek Inner Shalt Bi-Weeldy

Masterfiex Check Battery Each Use Perisaltic Pump Check Inner-Housing Pumb Bed Each Use

- Check Inner-House Tubing Each Use

Water Level Indicator Check Wire Each Use - Check Probe Each Use

Check Battery Each Use

95

524 19s -

Section No.:Ten Revision No.: 12 - Date 10115/95

Page: 4of7 TABLE 10-2 -

PREVENTATiVE MANTENANOE PROCEDURES LABORATORY NSTRUMENTAT1ON/EQU!PMENT

INSTRUMENT ACTIVITY FREOUENCY

Gas Chromatography Replace Septa Daily

Mass Spectrometer Clean Inj. Port Daily Clean Source Weekly Change Pump Oil Quarterly Clip Column Lea1er Daily Check Gasses Daily Check for Leaks *j Ne4ed Check Autosaiiipler Aiiiment Daily

Gas Chromatography Replace Septa Weekly & HPLC Clean Inj. Port As Needed

Clip Column Leader As Needed

Check Reagents (HECD) Weekly Replace Nickel Tube (HECD) Monthly Clean Lamp (PID) Monthly Clean and Refoil (ECD) Annually Clean Jet (FID) Monthly Check Gasses Daily Check for Leaks *As Needed

Check Autosampler Aligmnent Daily

Purge and Trap Replace Trap Monthiy Bake Lines Monthly Clean Sample Vessels Each Use Check Gasses Daily Perform Leak Check SAS Needed

S-EVAP Steanibath Empty Solvent Reservoirs Daily Check Condenser Tubing Daily Check Water Level Daily Monitor Temperature Each Use

N-EVAP Blowdown Check Water Level Daily Monitor Temperature Each Use Check Gas Daily Check Gas Tips Each Use

Sonic Disrupter Clean Horn Each Use Tighten Horn/Tip Daily Check Tuning Frequency Each Use

5Whenever gas pathway is altered or as needed

524 193

Section No. :Ten - Revision No.: i2

;

Date 10/15/95 Page: 5of7

TABLE 10-2

- PREVENTATWE MAINTENANCE PROCEDURES LABORATORY INSTRUMENTATION/EQUIPMENT

(continued) -

INSTRUMENT ACTIVITY FREOUENCY

- Centrifuge Check Balance Each Use Lubricate Bearings As Needed

- Atomic Absorption Clean Windows Weekly Furnace Change Graphite Tube Daily

Check Gasses Daily - Check Optics Annually

Check Autosampler Tubing Daily Check Autosaxnpler Alignment Daily Check Rinse/Drain Bottles Daily Change Graphite Contacts Semi-Annually Flush Autosampler Tubing Each Use

Inductively Coupled Check Aspiration Tubing Daily Plasma Clean Torch Assembly Monthly

Clean Spray Chamber Monthly Check Gasses Daily Clean/Lube Pump Rollers As Needed Check O-Rings Monthly

Spectrophotometer, Clean Cell After each Use Infrared Clean Windows Weekly

Calibrate Wavelengths As Needed

Spectrophotometer, Clean Cell After each Use UV/Visible Clean Windows Weekly

Calibrate Wavelengths As Needed Check Aspiration Tubing Before Each Use

Mercury Cold Vapor Check Tubing Daily Analyzer Clean Sparger After Each Sample

Clean Windows Monthly Change Source Lamp As Needed

Microwave Oven Check Turntable Daily Clean Interior Monthly Check Exhaust Daily

96

524 200

INSTRUMEC(T

ISE Meter

Conductivity Meter

Dissolved Oxygen Meter

Bomb Calorimeter

Turbidimeter

Ion Chromatograph

Autoanalyzer

Digestion Block

Flashpoint Tester

Section No. Ten Revision No.: 12 - Date 10/15/95 Page: 6of7

TABLE 10-2

PREVENTATIVE MAINTENANCE PROCEDURES LABORATORY INSTRUMENTATION/EQUIPMENT -

(continued)

ACTIVITY FREQUENCY

Clean Probe After Each Use

Check Probe for Cracks Daily

Check Reference Junctions Daily Check Probe Solutions Daily

Clean Probe Each Use

Check Standard Solutions Daily

Check Membrane Daily Change Membrane As Needed

Clean Interior Parts After Each Use

Resurface Interior Quarterly/As Needed

Replace Platinum Wire After Each Use

Check Oxygen Tubing Before Each Use

Clean Cell Each Use

Check Tubing Daily Check for Bubbles Each Use

Check for Leaks Each Use

Check Pump Daily

Check Tubing Each Use

Check tör Leaks Each Use

Check Bubbles Each Use

Check Pump Each Use

Check Valves Each Use

Check Detector Heads Each Use

Check/Adjust Temperature Monthly/As Needed

Check Tubing Daily Clean Sample Cup Eaeh Use

Check Gas Daily Clean Flash Assembly Daily

Check Stirrer Daily

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Section No. : RevisionNo.: 12 -

, Date 10/15/95 Page: 7f2

TABLE 10-2

PREVENTATWE MAINTENANCE PROCEDURES LABORATORY INSTRUMENTATION/EQUIPMENT -

(continued)

- INSTRUMENT ACTIVITY FREOUECY

Hot Water Baths Check Temperature Daily Check Water Level Daily

ZHE Vessels Check O-Rings Each Use Check For Leaks Each Use Check Piston Each Use

Filtration Apparatus Check O-Rings Daily Check For Leaks Each Use Replace Screen As Needed

Rotaty Extractor Check RPMs Before Each Use Tighten Screws/Bolts Weekly/As Needed

Laboratory Balances Check AccuracyfLinearity Daily Calibrate/Certify Annually/As Needed

Laboratory Ovens Temperature Monitoring Daily Temperature Adjustments As Needed

Incubators Temperature Monitoring Daily - Temperature Adjustments As Needed

Laboratory Temperature Monitoring Daily Refrigerators Temperature Adjustments As Needed

D.I. Water System Conductance Monitoring Daily - Resin and Carbon Tank Changes As Needed

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524 202 Section : Eleven Revision No.: 13

Date: 10/15/95 Page: 1 of9

11.0 Quality Control Checks, Routines to Assess Pre-cision and Accuracy and Calculation of Method Detection Limits

11.1 Quality Control Checks

11.1.1 Field Quality Control Checks

Minimum requirements for Field Quality Control Checks and the frequency at which the check is performed are outlined below.

Minimum Type of OC Check Frequency Procedure

Equipment Blank 5% per analyte group Fill or rinse pre-cleaned equipment (Pre-Cleaned) per equipment type used, with analyte-free water. Fill appropriate

or i per sampling event container, preserve, document, and ofsame math; whichever transport in same manner as samples. is more frequent.

Equipment Blank When equipment is cleaned Fill or rinse pre-cleaned equipment (Field Cleaned) in the field, 5% per with analyte-free water. Fill appropriate

analyte group, per equip. container, preserve, document, and type used, or i per field transport in sanie manner as samples. cleaning procedure per sampling event of same matrix, whichever is more frequent.

Trip Blank One per VOC method, Fill appropriate container with per shipping container. analyte-free ter,

preserve and document. Place in container for transport with bottles to and from site and analyzed for VOCs

Field Duplicate Óne per sampling event with Fill the appropriate container with a 5 or more samples of similar successively collected volume or portion matrx at a 10% frequency of the original sample. Preserve, thereafter. document, and transport in the same

manner as samples.

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11.1.2 Laboratory Quality Control Checks

Method specific Quality Control Checks will be followed where applicable. Where QC checks arc not outlined in the appropriate method, or are less stringent, minimum requirements for Laboratory Quality Control Checks and the frequency with which the check is performed are outlined below.


Method Reagent Blank One per sample set. Analyte-free matrix is processed in sanie manner as samples.

Matrix Spike/Duplicate 5% of samples received Sample and duplicate fortified with per matrix, known mount of analyte, processed in

same manner as samples. Duplicate and spike recovery data is obtained and assessed.

Sample Duplicate 10% of samples received Duplicate aliquot of sample is processed per matrix: applicable when same manner as sample. Precision spiking is not feasible, data is obtained.

Reagent Matrix Spikes One per sample set or 5%, Analyte-free matrix, fortified with known (Laboratory whichever is greater. amount of analyte obtained from an Control Sample) independent source is processed in same

manner as samples.

Blind QC Check Samples Semi-annually Duplicate samples containing a known amount of analyte are submitted to the laboratory as blind checks are processed as routine uri1movii samples. Known concentrations are made available after submission of reported results.

Calibration Check After calibration, then 5% Calibration reference standard is used to Standards of analytical deterrni.nations check validity of standard curve used for

in a sequence calibration during a sequence of determinations.

Analytical Spike(Post Spike) All GFAA determinations Sample fortified with known amount of analyte at the time of analysis. Analyzed immediately after the corresponding sample. Spike recovery is obtained and assessed.

-


Standard at 1-2 PQL

Surrogate Spikes

Internal Standards

As part of the initiai calibration curve or quality control check of the initial calibration. Alternatively, a continuing calibration standard may be used. The minimum frequency will be once per method on the days that analysis is performed.

524 ¿(J4 Section.: Eleven Revision No.: 13


An initial calibration, continuing calibration, or quality control standard will be fortified with the appropriate analytes. The number of analytes in the standard will be determined by the type of standard. In addition the critcria placed on this standard will be consistent th the type of standard.

All GC and GC/MS All samples and QC samples are fotified determinationswith known amounts of analyte compound analogs prior to processing. Recovery data is obtained.

All GC and GC/MS All samples, standards and QC checks are determinations fortified with compound(s) ofsimìlar characteristic to analyte(s) prior to analysis. Internal standard response is used to assess and correct for variances during analysis.

11.2 Assessment ofPrecision and Accuracy

- Quanterra Tampa uses specific routine procedures to assess the precision and accuracy of field and laboratory data. These procedures include the use of statistical data, quality control charts and detection limit studies, as outlined in the following sections.

11.2.1 Laboratory Data Precision and Accuracy Assessment

Procedures used to determine precision and accuracy targets are listed below.

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524 2Oj Section: Eleven Revision No.: 13


Method Purpose Concentration Level Method References

Matrix Spikel Matrix Precision Low Level All ter methods when feasible.

Duplicate and Accuracy Data Mid Level All soil methods including those

applied to waste samples, when feasible.

Sample Duplicate Matrix Precision NA All methods where it is not feasible to spike analyte or

or parameter of interest.

Reagent Matrix Method Accuracy Data Low Level All methods where spiking is

Snike feasible.

(Laboratory Control Sample)

Blind QC Check Method Accuracy Low level All methods.

Sample and Precision

Calibration Calibration Low Level All methods.

Check Standard Accuracy and Stability -

Surrogate Spike Method Efficiency Low Level All GC and OC/MS methods. for Each Sample

Mid Level GC & GC/MS VOA medium level.

Internal Chromatographic Low Level All Chromatographic analyses.

Standards Efficiency

Explanations:

Low level concentrations are the levels which fall between the minimum detection limit and 3 to 5 times

that detection limit. Mid level concentrations are at or about the mean concentration between the minimum detection limit and

'the upper end of the linear range. High level concentrations which fall at or about the upper end of the linear range.

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524 2ú6 Section: Eleven - Revision No.: Date: 10/15/95

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11.2.2 Formulas Used to Calculate Precision and Accuracy

- Formulas used to calculate Precision and Accuracy of each type of QC Check are presented below.

a. Precision = Relative Percent Difference -1C1-C211[(C1+C2)/2] x loo (RPD)

- where, and C2 are concentrations of duplicate spikes or samples.

b. Accuracy (Percent Recovery) = (observed Conentration) x loo (% R) (expected Concentration)

c. Analytical Control Limits:

Accuracy Precision

Upper Control Limit Mean %R + 3S Mean RPD + 3S Upper Warning Limit Mean %R + 2S Mean RPD + 2S Lower Warning Limit Mean %R 2S Lower Control Limit Mean %R - 3S

- Where S = Standard Deviation -,

d. For Atrazine and Sirnazine in water (Method 8141A ), accuracy is calculated as % Recovery ± (3*Standard Deviation). Percent Recovery and Standard Deviation are from SW846, 3rd Edition, "Test - Methods for Evaluating Solid Waste, Physical /Chernical Methods". Internally-derived accuracy will be evaluated as data becomes available. Precision is calculated as 2*(Standard Deviation) for the purposes of this revision. Standard Deviation is from SW846, 3rd Edition. Internally-derived precision will be - evaluated as Mean Relative Percent Deviation + 3 (Standard Deviation) as data becomes available. For Atrazine and Simazine in solid matrices (Method S 14 lA), no literature targets for accuracy and precision were available, and thus, limits in Section 5.0 are advisory only. Internally-derived accuracy and precision will be evaluated as data becomes available.

e. For Method 8151, where method limits were available, accuracy is calculated as % Recovery ± - (3*Standard Deviation). Percent Recovery and Standard Deviation are from SW846, 3rd Edition, "Test

Methods for Evaluating Solid Waste, Physical /Chernical Methods". Internally-derived accuracy will be evaluated as data becomes available. Precision is calculated as 2*(Standard Deviation) for the purposes of

- this revision. Standard Deviation is from SW846, 3rd Edition. Internally-derived precision will be evaluated as Mean Relative Percent Deviation + 3 (Standard Deviation) as data becomes available. For Method 8151, where no method limits are available in the literature, yet internally-derived Method 8150 limits were available, precision and accuracy are from Method 8150 in the CompQAP. Internally-derived accuracy and precision will be evaluated for Method 8151 as data becomes available. Where no literature targets are available and where no internally-derived data is available for Method 8 150 from the

- CompQAP, limits in Section 5.0 are añvisory only. Internally-derived accuracy and precision will be =- evaluated as data becomes available.

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11.2.3 Quality Control Charts

Section : Eleven Revision No.: 13

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Page: 6of9

Quality control charts are computer generated, graphical representations of the mean percent recovery and mean relative percent difference for each method commonly used in the laboratory. These charts also delineate the warning and control limits established by historical laboratory data. The quality control charts provide a continuous indication of method performance by visibly comparing actual control recovery data to acceptable method performance criteria. Control charts will be generated and reviewed for trends, by the QA Manager, in evaluation of recurring nonconformances in a particular analytical area.

11.3 Method Detection Limits

The method detection limit (MDL) is the lowest concentration of an element or compound that can be measure with 99% confidence that the analyte concentration is greater than zero. It is determined that by analyzing a sample of a particular matrix which contains the analyte as outlined below and in 40 CFR Part 136 Appendix B. MDL determinations are performed annually or upon acquisition of new instrumentation.

a) Estimate the detection limit using one of the following: - 1. The concentration value That corresponds to an instrument signal/noise ratio 2.5 to 5.

2. The concentration equal to three times the standard deviation of replicate measurements of the analyte in reagent water.

3. The region ofthe standard curve that shows a significant change in sensitivity.

4. Instrument limitations.

b) After the detection limit has been estimated it must also be calculated using the following procedure,

i . If the MDL is to be determined in analyte-free water, prepare a standard at a concentration between one and five times the estimated MDL.

2. Ifthe MDL is to be determined in another sample matrix, analyze the sample. Ifthe measured level of analyte is less than the MDL, add a knoi amount of analyte to bring the level between one and five times the estimated MDL, Thenproceed to step c).

3. Ifthe level ofanalyte in sample is between one and five times the MDL, proceed to step c).

4. Ifthe measured concentration ofanalyte is greater than five times the estimated MDL, either:

a. Obtain a different sample with a lower level ofanalyte, or

b. Usethe original samp[e as is ifthe analyte level does not exceed ten times the MDL of the analyte in reagent water.

524 208 Section : Eleven Revision No.: Date: 10/15/95 Page: 7of9

c) Process a minimum of seven aliquots of the sample through the entire analytical procedure.

- 1. These seven aliquots may be processed at one time if the estimated MDL is thought to closely approach the value of the true MDL.

- 2. Where the estimate is in question, two aliquots may be processed at this time.

a. If these measurements indicate that the sample is in the approximate range for MDL determination, five additional aliquots will be processed. All seven measurements are then used for calculation of the MDL.

b. If the measurements show that the sample is not in the correct range, re-estimate the MDL and repeat the process.

d) Calculate the variance (S2) and standard deviation (S) of the replicate measurements as follows:

n (n ';

n x- xiJ i-I

j

where X(i= i to n) are the analytical results in the method reporting units obtained from the "n" sample aliquots and S refers to the sum of the X values from i = 1 to n.

e) Compute the MDL as follows:

7'DT - (S)

t(n.l l-a0.99)

where:

MDL = the method detection limit

t (n.l. ID.99) = the student's t value appropriate for a 99% confidence level and a standard deviation estimate with n- i degrees of freedom.

s = Standard deviation ofthe replicate analyses.

f) The detection limit will be verified on a yearly basis. Ifthe above criteria are not met during the verification, the detection limit study will be done again in full.

g) Students t values are shown m Table 11-1.

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h) For Atrazine and Simazine in ter (Method 814 lA), MDLs are from SW846, 3rd Edition, "Test Methods for Evaluating Solid Waste, Physical /Chemical Methods". Internally-derived MDLs will be evaluated as data becomes available. For Atrazine and Simazine in solid matrices (Method 8141 A), no literature targets for MDLs were available, and thus, MDLs in Section 5.0 are advisory only. Internally-derived MDLs will be evaluated as data becomes available.

i) For Method 8151, where MDLs were available, they are from SW846, 3rd Edition, "Test Methods for Evaluating Solid Waste, Physical ¡Chemical Methods". Where no MDLs are available in the literature, yet internally-derived Method 8150 MDLs were available, MDLs listed in Section 5.0 - are from Method 8150 in the CompQAP. Where no literature targets are available and where no internally-derived data is available for Method 8150 from the CompQAP, MDLs in Section 5.0 are advisory only. Internally-derived MDLs will be evaluated as data becomes available.

524 210 Section : Eleven Revision No.: j Date: 10115195

Page: 9o19

TABLE 11-1

STUDENTs t VALUES AT THE 99% CONFIDENCE LEVEL

Number Qf Replicates Freedom Degrees of t.99

- 7 6 3.143

8 7 2.998

9 8 2.896

10 9 2.821

11 10 2.764

16 15 2.602

21 20 2.528

26 25 2,485

31 30 2.457

61 60 2.390

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12.0 Data Reduction, Validation and Reporting

Quanterra Tampa utilizes the laboratory computerized data management system to record, document, and assimilate pertinent laboratory technical and administrative data. This computerized system provides data m.an.agement functions for a number of component laboratory activities including: laboratory sample acceptance, sample analytical results, sample status and tracking, analytical QAJQC, fina! report generation, and client invoicing. The data management system enhances efficient coordination among these component laboratory activities by providing a highly automated, standardized communication network for data transfer and correlation. This system is summarized below.

The computerized laboratory data management system (QuantlMS) assigns a unique laboratory identification number to each sample and records pertinent technical and administrative sample data. Technical sample data includes client sample identification, sample description, sampling date, required analytical parameters, and requested comp!etion date. Administrative data is necessary for the final reporting and invoicing of sample results.

The data system assimilates data recorded by the sample custodian and generates laboratory worksheets for distribution to the appropriate analyst. These worksheets identify 'the analytical parameters and associated - methods necessary to complete the requested sample analyses, along with the appropriate completion due dates. The due date requirements not only specify requested completion dates, but identi' rnaxinium

:-' allowable holding times for samples and/or extracts prior to analysis. The data system also automatically generates appropriate worksheets for the analysis of systematic quality control samples in accordance with laboratory QC procedures

- Specified laboratory personnel enter all completed sample analytical results and associated QC data into the data management system. The system's various data processing capabilities then automatically provide a number of component laboratory data management functions such as statistical evaluations arid - associated quality control charts, final sample analytical result reports, and sample tracking and status reports.

e

-

e

w

12.1 Data Reduction

Quanterra Tampa completes laboratory documentation measures to ensure the integrity and legal validity of ail sample analytical results. These documentation measures encompass all sampling and analytical activities to create a traceable, legai history of each sample and subsequent analysis. All documented information is recorded in bound, consecutively-numbered analytical logbooks and/or the computerized data system. Raw data files and associated data reduction records are maintained by the laboratory in appropriately labelled files to allow systematic retrieval.

12.1 .1 Data Reduction - Documentation Records

Component analytical documentation measures pertaining to data generation arid reduction are outlined below arid iii Section 7.

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Field Sample Logbooks

Data from all samples taken by laboratory personnel is entered in a hard-cover, bound laboratory field sample logbook consisting of consecutively-numbered 8 1/2" x 11" pages. This laboratory field sample logbook contains entries which document pertinent field data for each sample

including:

Client Name and address of field client Project or sampling location Exact location of sample point Sampling methodology Process generating sample (as applicable) Sample container numbers and volumes Date and time of collection Field sample identification number or designation Field observations and/or measurements References such as maps, sketches, or photographs Preservation and transport statement Name(s) arid signature(s) of sample collector(s)

Location of sample points is referenced to an established system, or if this is not available, given in such a mariner that it can be clearly identified.

Laboratory Worksheets

The analytical specifcations arid subsequent results ofeach sample submitted to the laboratory are recorded on various Laboratory worksheets. The worksheets are generated by the laboratory computerized data management system from sample information initially entered into the computer by the Sample Custodian. Pertinent information on the worksheets includes sample identification, specified analytical parameters and methodology, holding times and due date requests, pertinent sample manipulation and preparation information, quality control data, and final analytical results as reported by the appropriate analyst. These worksheets are retained by the laboratory and stored alphabetically (by client) and sequentially in files to allow systematic retrieval. Worksheets are retained by the laboratory or the controlled off-site storage ficility for seven years after completion.

Laboratori Method Lo2books

All laboratory analyses are entered into various laboratory method logbooks which categorically record and document the raw data for each analytical parameter routinely determined by the laboratory. Each analytical parameter and/or activity is assigned a particular logbook which records pertinent preparation, ectraction, and instrumental data for each sample, as applicable. This information can include laboratory identification number, initial sample volume or weight, extraction volumes, dilution factors, instrument values and analyst name(s). These logbooks also

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Section No.: Twelve Revision No.: - 9 Date: 10/15/95 Page: 3 of 73

systematically include and fcilitate sample manipulations required by the laboratory quality control plan. Method logbooks are retained by the QA Manager and stored sequentially at the laboratory or the controlled off-site storage facility for seven years after completion.

Laboratory Instrument Lobooks

- All laboratory analyses requiring analytical instrumentation are recorded in various laboratory instrument logbooks which categorically record and document analytical instrument settings and performance data. These logbooks record instrument calibration data, specific sample amounts, instrument parameters, dates, analyst identification., and corresponding performance data for each sample. Where possible, laboratory method Iogbooks and laboratory instrument logbooks are consolidated into one logbook and laboratory instrument logbocks are consolidated into one unit. Instrument logbooks are retained by the QA Manager and stored sequentially at the laboratory or the controlled off-site storage facility for seven years after completion.

Laboratory Raw Data Fie

All raw data generated by laboratory equipment (such as integrating recorders, strip chart - recorders, instrument data systems and secondary computer systems) pertaining to sample analytical data collection and reduction procedures are categorically filed in the laboratory raw ,-, dala file. The files arid the data included within are appropriately labelled with client and sample - identification information to allow systematic retrieval and assessment of necessary information. Data files are filed alphabetically and sequentially by the analyst and are retained by the laboratory or the controlled off-site storage facility for seven years after completion.

Laboratory Electronic Data File

In addition to the laboratory raw data file, all raw data generated by instrument-specific computerized data systems are maintained on magnetic media for a period of one year after completion. Tape backups are sequentially numbered, and stored at the laboratory or the off-site - storage facility in a climate-controlled environment. A categorized file containing full directory listings of each stored tape is maintained sequentially to allow systematic retrieval of rnagntic data,

12.1.2 Data Reduction - Field Reportable Data

Field measurements may include pH, specific conductance, temperature, dissolved oxygen and/or residual chlorine. Ail ofthese parameters will be read directly from the instruments and the results entered into the legally bound field notebook by the field sampler. Conductivity and pH meters vill be internally - compensated for temperature and the conductivity cell constant is one. The only possible data calculation for field personnel would be a sample dilution, if necessary, when testing for residual chlorine or conductivity.

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5d 2.11

Section No.: Twelve Revision No.: 2 Date: 10/15/95 Page; 4of73

12.L3 Data Reduction - Laboratory Reportable Data

AIL calculations in the laboratory are carried out as specifrd in the particular methods. Linear and logarithmic regressions are performed by computers with either instrument specific software and formulas or Lotus 123® or Microsoft EXCEL® spreadsheet package. A list of those instruments/methods which provide a direct readout are listed below, Following this are typical formulas used to reduce raw data to a reportable form.

Direct Reading Measurements

Measurements that typically do not require any particular calculation are Turbidity, pH, Flash Point, Residual Chlorine, Color, Ammonia (EPA 350.3), Fluoride, Odor. In addition, the ICP and Graphite Furnace AA provide data which is often in the final reportable form. Temperature compensations for all appUcabl measurements in the lab are performed internally by the measurement device.

Conductivity Cell Constant

The cell constant for the laboratory conductivity meter is calculated as follows:

C=(O.0014 13)(RKCI)[1 + 0.0 l91(t-25)] Where, RKCI measured resistance iii ohms

t = observed temperature in °C.

Method of Least Squares

The MethOd of Least Squares is a type of linear regression analysis which assumes a linear relationship between the variables. It is used with the Lotus l23® or Microsoft EXCEL® program to provide a calibration curve and calculate sample concentrations from instrument responses. The formula for this analysis is as follows:

y = a + bx Where, y = the dependent variable (measured value, response factor, etc.)

a the y intercept when x = O (calculated) b = slope ofthc line (calculated) X = independent variable (analyte amount or concentration, etc.)

External Standard Calibration

These calculations are utilized in chromatographic analyses to provide an approximation of the analyte concentration based on the response of a single standard or the mean value of a series of standards, without the use ofan internal standard. The calculation is used as follows:

Concentration (ug/g or ugh) [RI x A x VrJ/[Vs X V1] X dilution Where, RI standard amount (ng) f std response (counts)

A = sample response (counts) vs = initial sample volume (mi) or weight (g) Vf = final sample volume (ml); N/A for Purge and Trap analysis vi = sample volume injected (ul); N/A for Purge and Trap analysis

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Internal Standard Calibration

The internal standard is used ro assess the variations which occur during a particular chromatographic analysis. The calculation used is described in the methodology as follows:

Concentration (ug/g or ugh) [C x AJ/[V1 x Rfx A] x dilution Where, Rf= standard amount (ng) I std response (counts)

A = sample response (counts) v = initial sample volume (nit) or weight (g) ci, = amount ofinternal standard added to extract or saniple A = response of internal standard (counts)

- 12.1.4 Data Reduction - Analyst Responsibilities

Ail analytical results are calculated using equations specified in the methodology being performed. Values - are calculated by the analyst performing the test using either a manual calculator, Lotus spreadsheet, or instrument-specific computerized data system.

- Specific duties ofthe analyst regarding data reduction include:

.-., Generation and compilation ofraw data generated by proper use ofthe appropriate methodology. - Programming of calculators and/or computers with the proper equation, as specified iii the applicable methodology.

Data entry into the appropriate formula. -- Generation offinal results and detection limits from the raw data using the appropriate formula.

- Documentation ofihe above steps in the form of written calculations or computer printouts ;vhich specify raw data, formulas used, and naI results. - Generation and proper storage of the raw data file associated with the analysis of particular

- sample. Data entry of the reportable results Onto the appropriate worksheet with analyst's initials and the

date of analysis.

12.2 Data Validation -

Quanterra Tampa's Quality Assurance! Quality Control Program is designed to ensure the scientific and legal validity ofall samples and analytical results. The QAJQC Program consists ofa thorough laboratory - documentation network in combination with systematic inclusion of various analytical quality control practices and checks.

-

The data validation process includes a series of checks desied to ensure axiherence to standard QC protocol during the data collection, interpretation, calculation, and reporting process. Specific duties of each person in the process are assigned as follows:

i 05

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Section No. : Twelve Revision No. : 2 - Date: 10/15/95 Page: 6of73

12.2.1 Data Validation - Field

Field Analyst

The field analyst is responsible for sample procurement which follows the appropriate methodology and associated QC protocol. The feld analyst is also responsible for performing the necessary field analytical procedures with the proper QC samples. The analyst is responsible for making the proper entries into the field sample logbook so that all necessary information is clearly identified and documented. The analyst is responsible for evaluating the entries, QC data, and all supporting documentation for completeness and accuracy.

Field Supervisor

The field superviscr is responsible for reviewing the field sample logbook and any supporting documentation (such as chain-of-custody) on a daily basis. This review should caver calculations, accuracy of any maps, appropriateness of aiw QC samples taken or analyzed, any caiibrations performed and compLeteness. The fieLd supervisor is also responsible for evaluating all QC data from the sampling event to ensure that it is within the given control limits. Any deviations from standard sampling protocol or from the established QC program in place for that sampling event should be noted in the logbook and on the chain-of-custody documentation. If the deviations affect the integrity ofthe saniples or the quality ofthe feld measurements then the QA Manager and the appropriate laboratory personnel are notified as soon as possible.

SampleCustodian

The sample custodian is responsible for receiving the samples from the field personnel and logging the samples into the laboratory data management system. The custodian is also responsible for reviewing the chain-of-custody and condition of the samples upon receipt. Any discrepancies are noted on a sample/cooler evaluation form and brought to the attention of the quality control coordinator and project manager. The custodian is responsible for generating the appropriate laboratory worksheets and an analytical request swnrnary.

Project Manager

The project manager reviews the summary, sample/cooler evaluation form and chain-of-custody to ensure they are congruous and correct. Any discrepancies are noted on the summary and brought to the attention ofthe client and the QA Manager.

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12.2.1 Data Validation - Laboratory

- Laboratory Analyst

The laboratory analyst is responsible for performing analyses foUowing the appropriately approved

- methodology and associated QC protocol. Raw data generated as such is then interpreted, calculated and assimilated into final results. Assocìaied quality control data is assessed by the analyst for compliance with the QC Plan. This includes verification ofthe standardization process, assessment ofmethod blank results, method blank spike resu!ts, and matrix spike duplicate results, and where applicable, internal standard and surrogate spike recoveries. In order to facilitate the validation process, the worksheets provided to the analyst for reporting purposes contain all quality

- control Ifruits needed to assess compliance ofthe barious QC check samples. Upon completion of reporting, the analyst places all worksheets ofa particular sample set along with the associated raw data into a file. The file is then submitted to a trained data review analyst for approval. Before submittal, the analyst is required to clearly identify any deviations to standard QC protocol on the - worksheet associated th the affected sample.

-

Data Review Analyst

The data review analyst is responsible for verifying the content of the data file submitted by the _1 Laboratory Analyst. Data review analysts are assigned based upon amount of experience in a

particular laboratory section, knowledge of QC protocols and corrective action procedures, and training in the data review and reporting process. Review analysts are chosen by and receive training from the QA Manager and laboratory manager. Specific duties of the review analyst include veriing completeness and accuracy of all necessary raw data, identifying any obvious data anomalies, vei-ing the proper interpretation of the data, spot checking of calculations, proong result entries on worksheets, and assessing compliance of applicable QC check samples. Any deviations from standard QC protocol are discussed with the analyst and brought to the attention of the QA Manager. Any necessary quali&ations to the data are documented on the sample worksheets and are carried through the reporting process in a manner similar to the sample results to be included in the final report. The data review analyst may request the analyst to review andlor re-analyze samples ifhe/she feels that verification ofmple data is warranted.

Oualitv Assurance Manazer

The QA Manager oversees the data review process. This person is responsible for training, assiiing and supporting data review analysts. The QA Manager investigates any deviations in

Q C protocol and ensures appropriate corrective action procedures are taken when necessary. The QA Manger has oversiglit of all narratives to reports which contain any anomalous sample or QC sample data.

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Page: 8of73

Data Entry Analyst

The data entry analyst receives laboratory worksheets for entry into the computerized data reporting system. Duties include verifng the data reviewers initials are on the worksheet, entering sample and associated QC data into the system, printing out results in the nal report format, and proofreading the results for any daza entry errors which may have occurred. This person is also responsible for maintaining the current copies of any corrective action worksheets associated with the sample data, ich have been included by the analyst, data review analyst, and/or QA Manager.

Proect Manager

The project manager is responsible for proofing the data entiy of all sample and QC sampe rcsIts. The project manager reviews all results in the final reporting format and draws comparisons to the analytical worksheets. The project manager is also trained to assess compliance ofpresented data with proper QC protocols. This person verifies that any deviations to accepzable procedures have been addressed in a narrative by the quality control officer, to be included in the final report. A copy of all applicable chain-of-custodies associated with the sampies being reported is reviewed by the project manager for completeness. At this point, overall project data is assessed for completeness and accuracy. Site historical data is reviewed (if applicable), and any anomalies are investigated. The project manager may request the analyst to review andi'or reanalyze samples if he/she feels that verification ofsarnple data is warranted. The project manager reviews the final report copy before submission to the lab director for final review and then the client.

Laboratory Director

The laboratory director may conduct the final review and comparison of workshccts and reported data. This person may conñrm that the appropriate QC checks and data validation have been carried out by reviewing and comparing data and narrations contained on the worksheets and the final report.

i 3Doina As detailed in previous sections, alL laboratory and field analytical results are reviewed by involved analyst(s), reporting personnel, and the project manager, and possibly the QA Manager and the Laboratory Director prior to final reporting. These individuals conuirrn that ail analytical requests have been satisfied, associated quality control data are within acceptable performance limits, and any anomalies have been appropriately investigated and addressed.

The nal analytical results report includes appropriate introductory comments, any QC narratives (when applicable), ari analytical methods summary, sample analytical results, a QAJQC program summary, and associated QC data results. The sample results and QC results are generated in a uniform format by the laboratory computerized data management system. When the report is assembled it is copied onto letterhead paper and sent for review by the project manager and possibly the Laboratory Director. A sample final report is presented in Figure 12-1 pages I through 22.

-

w

e

FIGURE 12-1

SAMPLE FINAL REPORT (Tota! 65 pages)

ANALYTICAL REPORT

PROJECT NO. PEEP. EVAL.

w? 034

ZEVIN BULL

INC.

QUANTERA INCOR? ORATED Certification Nuibers : E84059 ,S84297

FDE? Co=pDAP: 870270G

?roect Ma.nager

Ji.ze 14, :1995

524 219

Section No. : Twelve

Revision No.;

Date: IO/U195

Page: 9r73

107

524 20

EXECUTIVE SUMMARY Detection Highlights

B5E09 0003

?ARAETE R

TRACE TALC0NC i os/a9/95

Al urni nuzr .r s e ri i c 3eryiliurn Cadiniwn Cobalt Chromium Copper Iron Mercury Mangan e s e Nickel Le ad Se1enurri Vanadium Zinc

TRACE 'OETÀLCONC 2 05/09/95

Al uzrtinum ' s e n i c

e ry 1]. i um Cadmium Cobalt C h r orr i um Cooper Iron Mercury Marigane se Nickel Lead Sel e ri i um Van adj um Ziric

TRACE TALC0C 3 05/09/95

Silver Molybdenum Antimony Strontium Titanium Thallium

2

REPORTING ?2StJLT LIMIT UNIT TOD -

929 1.0 ug/L MCAW 200.7 122 1.0 u/L MCAW 200.7 13.3 1.0 ug/L MCAiW 200.7 13.2 1.0 ug/L MCAW 200.7 - 130 1.0 ug/L MCAWW 200.7 92.6 1.0 ug/L MCAWW 200.7 47.8 1.0 ug/L MCAW 200.7 630 1.0 ug/L MCAW 200.7 1.3 0.20 ug/L MCXW 245.1 288 1.0 ug/L MW 200.7 82.6 1.0 ug/L MCAW 200.7 190 1.0 ug/L MCAWW 200.7 198 1.0 ug/L MCAWW 200.7 5.220 1.0 ug/L MCAW 200.7 493 1.0 ug/L MCAW 200.7

2,470 1.0 ug/L MCA 200.7 452 1.0 ug/L MCAW! 200.7 91.2 1.0 u/L NCAW 200.7 214 1.0 ug/L CAW 200.7 329 1.0 ug/L MCA 200.7 354 1.0 ug/L MCA 200.7 273 1.0 ug/L MCAW 200.7 967 1.0 ug/L MCAW4 200.7 1.3 0.20 ug/L MCAW 245.1 1,430 1.0 ug/L MCA4W 200.7 797 1.0 ug/L MCAW 200.7 493 :.o ug/L iCAW 200.7 427 1.0 ug/L MCAW 200.7 9,170 1.0 ug/L MCA4 200.7 - 966 1.0 ug/L CA1 200.7

35.4 1.0 ug/L MCAWW 200.7 30.9 1.0 ug/L MCAJW 200.7 123 1.0 ug/L MCAWW 200.7 43.9 1.0 ug/L MCAW4 200.7 34.3 1.0 ug/L MCAWW 200.7 223 1.0 ug/L t'CAWW 200.7

EXECUTIVE SUMMARY - Detection Highlights 25E09 00 03

a

-

-

-

a

RE?ORTIG PARTER RESULT LIMIT IT

TRACE ?TALC0NC 3 05/09/95

TRACE TÀLCONC 4 05/09/95

Silver 251 Molybdenum 250 Antimony - 425 Strontium 290 Titanium 134 Thallium 80

MINERALS CONC lA & 13 05/09/95

Specific Conductance 420 ardness 80.0

Total Dissolved Solids 245 Fluoride 2.1 Chloride 58.5 Sulfate 50.8 Alkalinity, Total 47.0 Calcium 22,400 Potassium 33,000 Magnesium 6,380 Sodium 30,300

MINERALS CONC 2A & 23 05/09/95

Specific Conductance 867 Hardness 312 Total Dissolved Solids 675 Fluoride 0.57 Chloride 253 Sulfate 7.5 Alkalinity. Total 10.0 Calcium 82,900 Potassium 9.330 Magnesium 29,600 Sodium 13,200

MINERALS CONC 3 05/09/95

pH Aqueous 7.6

MINERALS CONC 4 05/09/95

oH Aqueous 8.8

3

524 221

1.0 ug/L MCW 200.1 1.0 ug/L MCAW.1 200.7 1.0 ug/L MCAWW 200.7 1.0 ug/L MCAWW 200.7 1.0 ug/L Mc.AWW 200.7 1.0 ug/L MCW 200.7

0.05C umhos/crn MCAW 120.1 0.90 mg/L MCAWW 130.2 5.0 mg/L MCAW 160.1 0.010 mg/I.. MCA4 340.2 2.0 mg/I.. MCAWW 325.3 2.0 mg/I., MCAWW 375.4 5.0 mg/I.. MCAWW 310.1 1.0 ug/L. MCAW 200.7 1.0 ug/L MCAWW 200.7 1.0 ug/L MCA4W 200.7 1.0 ugh.. MCAWW 200.7

0.050 u.ithos/c.n MC.AWW 120.1 1.8 mg/L MCAWW 130.2 5.0 mg/L MCAWW 160.1 0.010 rng/L MCA4W 340.2 10.0 mg/L MCAWW 325.3 1.0 mg/L MCAWW 375.4 5.0 mg/L MCA 310.1 1.0 ugiL MCA4W 200.7 1.0 ug/L MCAWW 200.7 1.0 ug/L MCAWW 200.7 1.0 ug/L MCAWW 200.7

0.050 su MCAWW 150.1

0.050 su MCAWW 150.1

10F

524 22'

EXECUTIVE SUMMARY - Detection Highlights

35 ZU 9 00 03

REPORTING PA?METER P.ESLT LIt!IT NIT tTHOD

NDTRIENT CONC 1 05/09/95

Nitrogen, r1ia 7.1 0.20 mg/L CA4W 350.2 Phosphorous, Ortho 0.94 0.10 mg/L HCAWW 365.2 Nitrate 6.0 0.050 mg/L MC.W 353.3

NUTRIENT CONC 2 05/09/95

Nitrogen, Aznon±a 3.3 0.10 mg/L 350.2 Phosphorous, Orth 0.46 0.10 m/L WW 365.2 Nitrate 22.7 0.25 mg/L 1CAWW 353.3

NUTRIENT CONC 3 05/09/95 -

Nitrogen, Total je1dah1 3.9 1.0 mg/I. Mc.AW 351.3 Phozphorous, Tozal 4.1 0.040 mg/L !C.W 365.2

NUTRIENT CONC 4 05/09/95

Nitrogen, Total Kjeldahl 16.2 1.0 rg/L !CAW 351.3 - Phosphorous, Total 2.1 0.040 mg/L CA4W 365.2

DLMD CONC 1 05/09/95

3iochemical Oxygen Demand 28.3 0.40 g/L MCW 405.1 5 Day

Carbon, Total Organic 20.8 1.0 rng/L MCAW 415.1 Chemical Oxygen Demand 53.9 14.0 rng/L 4CAW 410.1

DMAD CONC 2 05/09/95

Biochemical Oxygen Demand 10.4 0.40 mg/L CAWW 405.1 - 5 Day

Carbon, Total Organic 7.3 1.0 rng/L MCAW 415.1 - Chenica1 Oxygen Demand 19.0 14.0 mg/L MCAW 410.1

PCB IN WATER CONC 1 05/09/95

PUB-1250 1,4 1.0 ug/L USEPA 608

PCB IN WATER CONC 2 05/09/95 -

PCB-1016 4.9 1.0 ug/L USEPA 608

PCB IN OIL CONC 1 05/09/95

PCB-1260 35 5.0 ug/L USEPA 608

4

-

-

-

-

524 23

EXECUTIVE SUMMARY Detection Highlights

355090003

R.EPOTING PARATER RESEJLT LIMIT UNIT ThOD

PCB I OIL CONC 2 05/09/95

PCB-1254 15 5.0 ug/L USEPA GOS

PESTICIDE CONC 1 05/09/95

Aidriri 1.5 0.10 ug/L USEPA 408 4,4'-DDD - 4.1 0.14 ug/L USEPA GOS 4,4'-DDE 2.7 0.060 ug/L 3SE?A 608 4,4' -DOT 2.7 0.10 ug/L USEPA 603 Dieldriri 4.4 0.16 ug/L USEPA 608 epzach1or 2.1 0.12 ug/L USEPA 608

Meptachior epoxide 1.9 0.080 ug/L USEPA 638

?ESTICIDE CONC 2 05/09/95

Aldrin 0.30 0.050 ug/L USEPA 608 4,4'-DDD 1.3 0.070 ugiL USEPA 608 4,4'-DDE 1.1 0.030 ug/L rJSEPA 408 4,4'-DDT 1.4 0.050 ug/L USEPA GOB Dieldriri 1.7 0.030 ug/L USEPA GOS Hecach1or 0.36 0.060 ug/L USEPA 608 HeDach1or epoxjd 0.35 0.040 u/L USEPA 603


Chiordarie 2.2 1.0 ug/L tJSEPA 608


Chlordane 5.1 5.0 ug/L tJSEPA 608

VOLATILE H.ALOCAP.BON CONC 1 05/09/95

romodich1orcmethane 74 1.0 ug/L tJSE?A 601 Bromoform 54 0.20 ug/L USEPA 601 Carbon tetrachioride 69 0.80 ug/L USEPA 601 Chiorobenzerie 58 0.40 ug/L USEPA 60]. Dibromochiorometharie 66 1.0 ug/L tJSEPA 601 Chloroform 65 0.60 ug/L USEPA 601 1,2-Dichioroetharie 72 1.0 ug/L TJSEPA 601 Methylene chloride 65 1.0 ug/L USEPA 601 Tetrachioroethene 60 0.60 ug/L USEPA 601 1,1,1-Trichioroetharie 50 0.50 ug/L USEPA 601

5

109

524 224

EXECUTIVE SUMMARY - Detection Highlights 35E09 0003

REPORTING TEP. P..EStLT LIMIT UNIT

Trichloroether 55 0.70 u/L VOLATILE OCAR3ON CONC 2 05/09/95

Bromodichlorornethana 19 1.0 ug/L Br000r 15 0.20 ug/L Carbon cetrachioride 16 0.80 ug/L Chlorcber2zerie 15 0.40 ug/L Dibrojnochlororethane 15 1.0 ug/L Chloroforri 16 0.60 ug/L 1,2-Dichloroethan 14 1.0 ug/L Nethylene ch].oride 11 1.0 u/L Tetrachlcroethe-ie 15 0.60 ug/L 1,11-Tich1oroethane 15 0.50 ugiL Trichiorcethene 11 0.70 ug/L

VOLATILE AOATICS CONC 1 05/09/95

Ber.zene 12 0.50 g/L 1,2-Dichlorobenzene 15 0.70 u9/L 1,3-Dichlorobenzene 17 0.30 eq/L 1,4-Dichlorobenzene 19 0.50 ug/L Ethylbenzene 20 0.20 ug/L Toluene 21 0.20 ug/L

VOLATILE A0MATICS CONC 2 05/09/95

Benzene 50 0.50 ug/L 1,2-Dichlorobenzene 66 0.70 ug/L 1,3-Dichlorobenzene 61 0.80 ug/L 1,4-Dichlorobenzene 50 0.50 ug/L Ethy1benzne 43 0.20 ug/L Toluene 64 0.20 ug/L

TOTAL CYANIDE CONC 1 05/09/95

Cyanide, Total 0.12 0.0010 rng/L

TOTAL CYANIDE CONC 2 05/09/9 5

Cyanide, Total 0.56 0.0050 Tng/L

NON-FILTEpLE RESIDDE (TSS) CONC 1 05/09/95

Solids, Total Suspended 35.5 2.3 mg/L

6

THOD tJSEPA 601

USEPA 601 tJSEPA 601 USEPA 601 USEPA 601 USEPA 601 USEPA 601 USEPA 601 USEPA 601 USEPA 601 USEPA 601 USEPA 601

USEPA 602 USEPA 502 USEPA 602 IISEPA 602 USE?A 602 USEPA 502

USEPA 602 USEPA 02 USEPA 602 USEPA 602 T3SEPA 602 USEPA £02

'ICAWW 335.2

NCAWW 335.2

MCAq 160.2

-

-

-

F

524 22

EXECUTIVE SUMMARY Detectiön Highlights

35E090003

REPORTING ?ARAMETER RE$tJLT LIMIT tJNIT frThOD

NON-'ILTERA3LE RESIDUE (Tss) CONC 2 05/09/95

Solids, Total Suspended 19.3 2.3 rng/L MCAW 160.2

OIL & GREASE CONC 1 05/09/95

Oil and Grease, 10.3 5.0 mg,'L MCAWW 413.1 Gravimetric -

OI1 GREASE CONO 2 05/09/95

Oil and Grease, 15.0 5.0 rng/L M-W 413.1 Gravimetrj c

TOTAL PRENOLICS CONO 1 05/09/95

Phenolics 0.050 0.030 gIL CAW 420.1

TOTAL PHENOLICS CONC 2 05/09/95

Phenolics 0.37 0.030 rng/L MCAWW 420.1

TOTAL .ESIDUAL CHLORINE CONC 1 05/09/95

Chlorine, Total P.esidua]. 0.092 0.030 rng/L MC1 330.5 TOTAL RESIDUAL CHLORINE CONC 2 05/09/95

Chlorine, Total Residual 0.14 0.030 rng/L MCAW4 330.5

7

110

5a4 22

ANALYTICAL METHODS SUM1IARY

Parameters MetF'ods

Volatile Organics USEPA 601 Volatile Organics USEPA 602 ?eSt/PCB USPA 608 PCB Effluent Samples USEPA 608 Specific Conductance CAWW 120.1

ardness MC.PWW 130.2 pH Aeous MWW 150.1 Total Dissolved Solids MCAW 160.1 Solids, Total Susended MCAW 160.2 Silver MCAW 200.7 Aluminum MCAWW 200.7 Azs&iic MCW 200.7 Beryllium MCAW 203.7 Calcium MC. 200.7 Cadmium MCAW 200.7 Cobalt CAW 200.7 Chrorium MCAWW 200.7 Copper CAW 200.7 Iron MCAW 200.7 Potassium MCAW4 200.7

nesium MCAWW 200.7 Manganese MCAWW 200 .7 frolybderium MCAWW 200.7 Sodium MCAT 200.7 Nickel MCAW 200.7 Lead MCAWW 200.7 Antimony !CW,l 200.7 Strontium CAT' 200.7 Titanium '!CATW 200.7 Thallium MCA'TW 200.7 Vanadium MCAWl 200.7 Zinc MCAW 200.7 Mercury MCAWW 245 .1 Chlorine, Total esidual MCAWW 330.5 yanide Total MCAWW 335.2

Fluoride MCAW 340.2 Nitrogen, A.nonia MCAW'W 350.2 Nitrogen, Total Kjeldahl MCAW 351.3 Phosphorous, Ortho MCAW 365.2 Phosphorous, Total MCAW 365.2 Biochemical Oxygen Demand MCAWW 405.1

- S Day Carbon, rotai Organic MCA7W 415.1 Nitrate MCArW 353.3 Oil and Grease, MCWW 42.3.1 Gravimetri c

Selenium MCAWW 200.7 Chemical Oxygen Demand MCAiW 410.1

?4 227

- ANALYTICAL METHODS SUMI\1ARY

Paramte:s

Chioríde MCAWW 325.3 Pheriolics NC..WW 420.1 £u1ate MCW,4 1ka1inity, Total MCW 310.1

-

- References:

cww Iethods fo Chetd.ca1 Analysis of Water azd Wastes, EMSL: . Cincinnati, OH: frrch 1923 arid subseauent revisions

- USEP. Nethods for Organic Chemical Aa1vsis of unicipa1 arid

Industrial 4astewaer, 4OCFP., Part 136, pendix A

- October 21984 and subsecuent revisions

-

-

9

111

524 228 SAMPLE SUMMARY

The analytical results the sanpies listed below are presented n the rclloirìg pages.

WO L.3OPTORY ID SAMPLE IDENTIFICATION DATE ITI $.MPi[

A4F9 35E090003-OO1 TRACE TALCONC i 5/09195 ÀFC 3E09O003-002 TP.ACE TALCOC 2 5/09/95 A4FD 35E090003-003 T?JCE FTALCONC 3 5/09/95 A4F6F 5E090003-004 T?.ACE TALCOC 4 5/09/95 A4FSJ B5E090003-005 MINERALS CONC lA & 13 5/09/95 A4F6L 35E09O003-00 MINERALS CONC 2A & 25 5/09/95 A4FN 35E090003-007 MINEPALS CONt 3 5/09/95 A4FG? B5E090003-O0 MiALS COC 4 5/09/95 A4V 5E090003-009 NtJTRIENT CONC 2. 5/09/95 A-F73 35E090003-0l0 NIJTPIENT CONC 2 5/09/95 A4F77 35E090003-0l1 NUTRIENT CONC 3 5/09/95 A4F7A 35E090003-012 JTPIZT CONC 4 5/09/95 AF7C 35E090003-013 DEMAND CONC J. 5/09/95 A4F7F 351090003-014 DEMAND CONC 2 5/09/95 A4F7W 5E090003-015 PCB IN WATER CONC 1 5/09/95 A4F7X 35E090003-01G PCE IN WATER CONC 2 5/09/95 A4F32 35E090003-017 PCE IN OIL CONC 1 5/09/95 A4F33 35E390003-018 PCE IN OIL CONC 2 5/09/95 A4F84 35E090003-019 PESTICIDE CONC 1 5/09/95 A4F35 35E090003-020 PESTICIDE CONC 2 5/09/95 A4F85 35E090003-021 PESTICIDE CONC 3 5/Q9/ A4F37 35E090003-022 PESTICIDE CONC 4 5/09/95 A4F89 35E090003-023 vOLATILE ALOCAPBON CONC 1 5/09/95 A4F2A 35=090003-024 VOLATILE HALOCAR3ON CONC 2 5/09/95 A4F8C 35E090003-025 VOLATILE APO1ATICS CONC 1 5/09/95 A4FSD 35E090003-02 VOLATILE AROMATICS CONC 2 5/09/95 A4FB 35E090003-027 TOTAL CAIDE CONC 1 5/09/95 A4F3F 35E090003-028 TOTAL CYANIDE CONC 2 5/09/95 A4FG 35E090003-029 NON-FILTERABLE RESIDUE CTSS) CONC 1 5/09/95 A4F3 35E090003-030 NON-FILTERABLE RESIDUE (TSS> CONC 2 5/09/95 A4FJ 35E090003-03l OIL & G?EASE CONC 1 5/09/95 A;F8< 35E090002-032 OIL & GP.EASE CONC 2 5/09/95 A4FaL 35E090003-033 TOTAL PENOLICS CONC 1 5/09/95 A4FaH 35E090003-034 TOTAL PENOLICS CONC 2 5/09/95 A4F8N 35E090003-035 TOTAL RESIDtJAL CLOPINE CONC 1 5/09/95 A4F8P. 35E090003-036 TOTAL ?..ESIDt3AL CiLOP.INE CONC 2 5/09/95

w

524 229

QUATERRA, INC.

_'i.s' TRACE TALCONC 1

WO : A469 DATE SAMPLED: 5/09/95 LA3 :5E090O03-001 TI SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

- REQUESTED TALS .................. REPORTING PREPARATIOt

PARATER RESULT LINIT UNIT T-OD ANALYSIS D?..TE T_C

Aluiinur 928 J.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171 Arsenic 122 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171 Bery11iur 13.3 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171

Cadiu 13.2 - 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171 Cba1t 130 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171 Chniuxi 92.6 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171

Copper 47.8 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171 Iron 650 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 513317]. Manganese 288 1.0 ug/L MC.AWW 200.7 5/15- 5/24/95 5135171

icke1 82.6 1.0 ug/L MC»W 200.7 5/15- 5/24/95 5135171 Lead 190 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171 Vanadi 5,220 1.0 ug/L MCAW 200.7 5/15- 5/24/95 5135171

Zinc 493 1.0 ug/L NCAWW 200.7 5/15- 5/24/95 5135171 Mercury 1.8 020 ug/L MCAWW 245.1 5/25- 5/26/95 5138121 Se1eniu - 198 1.0 ug/L MCA-.'W 200.7 5/15- 5/24/95 3135171

OTE AS R.EC EI VED

117

521 23c

WO #: A4FGC LAB :35EO9Q00J-002 MATRIX: PE ST?2W

PWTE7. RESULT

)1uiinu 2,470 Arsenic 452 3ery11iu 91.8

Cadi 214 Cobalt 329 Choii.i 354

Coe 873 Iron 967 Manganese 1,430

Nickel 797 Lead 493 Vanadjut 9.170

Zinc 966 Mercury 1.3 Seleniun . 427

0TE AS R.EC PJV

12

QUANTERRA, INC.

TRACE T.ALCONC 2

- - - REQUESTED METALS

REPORTING LIMIT tJN!T

1.0 ug/L MC

1.0 ug/L MC

1.0 ug/L MC

1.0 u/L MC

1.0 ug/L MC

1.0 ug/L MC.

1.0 ug/L MC

1.0 ug/L MC,

1.0 ug/L NC.

1.0 ug/L MC.

1.0 ug/L MC.

1.0 ug/L MC

1.0 ug/L MC

0.20 ug/L MC

1.0 ug/L MC

DATE SAMPLED: 5/09/9 TIME SANPLEI): DATE RECEIVED: 5/09/9c

?RE?AR.TjON . QC THOD ?NALYSIS DATE BATC

AWW 200.7 5/15- 5/24/95 51353.7: AW4 200.7 5/15- 5/24/95 5135: AWW 200.7 5/15- 5/24/95 5135-1

»w 200.7 5/15- 5/24/95 5135: »zw 200.7 5/15- 5/24/95 513s:1 AW 200.7 5/15- 5/24/95 5135173

AWW 200.7 5/15- 5/24/95 5135 1

200.7 5/15- 5/24/95 5135l-1 AWW 200.7 5/15- 5/24/95 5135171

AWW 200.7 5/15- 5/24/95 51353 .1

AWW 200.7 5/15- 5/24/95 51351T1 WW 200.7 5/15- 5/24/95 5]. 71

ww 200.7 5/15- 5/24/95 51351-,-1

w 245.1 5/25- 5/26/95 5138121 W 200.7 5/15- 5/24/95 51351 1

-

524 231

QtTANTEP.RA, INC.

TRACE METALCONC 3

WO t: A4F5D DATE SAMPLED: 5/09/95 LAB :35EO90003-003 TL SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

REQUESTED METALS ------------------ P..EPOP..TING PR2PARATIO4 QC

PARATEP. P.ESULT LIt-SIT UNIT ThOD ANALYSISDATE 3ATCH

Silver 35.4 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 513517:. Molybdenu. 30.9 1.0 ug/L MCA 200.7 5/15- 5/24/95 5135J.7 Antimony 123 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171

Strontium 43.9 1.0 ug/L MCAWW 200.7 5/15- 5/26/95 5135171 Titaniut 36.3 1.0 ug/L McA7 200.7 5/15- 5/26/95 5135171 Thallium 228 1.0 ug/L MCA 200.7 5/15- 5/24/95 5135171

AS R.EC TVED

13

113

524 232

QrA.NTERPA, INC.

TR?.CE MTALCONC 4

DATE SA'íPLED: 5/09/5 LAB :3509C0O3-0O4 TI.M SAMPLED: ATIX: PE STND DATE RECEIVED: 5/09/9

REQtTESTEDTALS - - REPORTING PREPRTION - QC

?AP.TER RESULT LINT UNIT THOD NP.LYSIS D.TE BATC

Silver 251 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 513S'7: M1ybdenu. 250 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135 Atior.y 425 1.0 ug/L MCA' 200.7 5/15- 5/24/95 5135x4

Strotiu. 290 - 1.0 ug/L MCAr.4 200.7 5/15- 5/25/95 5135 Titaniuri 134 1.0 ugIL MCAW 200.7 5/15- 5/2G/95 5135: Tlia1iiur 860 1.0 ug/L MCAW 200.7 5/15- 5/24/95 513517:

NOTE. .S REC E]Y)

- 524 233

QRRA. INC. NIERALS COlC.1A & 13

WO : A4F6J DATE SAMPLED: 5/09/95 - L)B #: 35E090003-005 TL SAMPLED: MATRIX: PE STAND DATE RECEIVED; 5/09/95

REQUESTED TALS ------------------ REPORTING PREPARATION QC PARATER P.EStLT LIIIT UTT METHOD ANALYSIS DATE 3ATCH

C1ciu 22,400 1.0 u/L MCAWW 200.7 5/15- 5/24/95 5135171 33,000 1.0 ug/L MCAW 200.7 5/15- 5/25/95 5135171

MagneSiurn 6,390 1.0 ug/L MCAWW 200.1 5/15- 5/24/95 5135171

Sodiu.i 30,30e 1.0 ug/L MCAWJ 200.7 5/15- 5/25/95 5135171

OTE AS REC EIV)

15

114

524 231

WO : A4F6L LAB :.B5E0900O3-00 MATRIX: PE STAND

QANTERRA, INC.

MINERALS CONC 2A & 23

- REQUESTED TÀLS

R.EPORTIG

DATE SAMPLED: 5/09/9E TL SAMPLED: DATE RECEIVED: 5/09/95

PP.E?ARATIO - QC ?ARATER RESULT LI!IT UNIT ThOD ANALYSIS DATE ATC-

Calcium 82,900 1.0 ug/L MCAWW 200.7 5/15- 5/24/95 5135171 Potassium 9,830 1.0 ug/L MCAWW 200.7 5/15- 5/26/95 51351 L

Magnesium 29,600 1.0 u;/L MCAWW 200.7 5/J.5- 5/24/95 51351..

Sodiu 18,2 1.0 ug/L MCAWW 200.7 5/15- 5/25/95 51351 -

?ot A$ RECEP

16

- 524 235

EXECUTIVE SUrvThaRv Detection Highlights

--, 35E03000J

FOTING ?RATF. ?.E5tLT LIET tJIT

- Tic1oroethere 5 0.70 ug/L USZ?? O1

VOL)TIL LOC).RON COC 2 05/09/95

- 3rcodich1orctia 19 1.0 ug/L t3SE 01

czroföz-rr i 0.20 ug/L USZ?A 01

Carbcri. tetrach1aide 1 O.aO ug/L tSE?? 602.

Ch1orobezerie 15 0.40 eg/L USE?. 601

Dibroioc1orcethae 15 1.0 ug/L SEA 601 Ch1orofo 16 0.60 ug/L 501

1,2-Dic1oroezh 14 1.0 ug/L OSE??. 501

- Methylene chloride 11 1.0 ug/L US?A 601 Tezrachloroethene 15 0.60 ug/L US?? 602.

2.,1,1-Trichlorcethe 15 0.50 u/1 US?A 601 Tich1croetheze 11 0.70 uc/L tSE?A SOI

OATLE APO2ATCS CC 1 05/09/93

- 3ezee 12 0.50 u/L US? 602

1,2-Dichìccbezee 15 0.70 uc/L S?A 602 l,3-Dich1ocberene 17 0.20 u/L USE? 402

1,4-Dichlorobezee 19 0.20 u/L USE??. 602

- Ehy1bezee 20 0.20 ug/L US?A 402 To1uee 0.20 uc/ US? 602

- V01TILE AROMATZCS COC 2 05/09/95

3ezene 50 0.50 ug/L us: 502

ì,2-Dic1orober'.ze 44 0.70 ug/L 3S? 602

- 1,3-Dich1crobezee Si 0.20 ic/L SE?A 602

1,4-Dieh1crobeerie 40 0.30 u/L US5?P 602

Ethy1beze 43 0.20 ug/L USE?A 602

To1uere 64 0.20 ug/ t.S?A 602

TOTAL C?ANIZ CONC 1 05/09/95

Ciariide, Toa1 0.12 0.0010 rtg/L CAW4 335.2

TOTAL CYANIE CONC 2 05/09/95

Cyaiide, Toa1 0.34 0.0050 rng/L 335.2

O-?ILTERABLE RESI (TSS) CONC 1 05/09/95

Solids, Total Susper.ded 35.6 2.3 rlg/L c?.W 160.2

s r;

115

521 23

EXECTJTIVE SUM.\IARY Detectiou Highlights

35E0900Ú 3

OP.TG .ZS1LT t::.tT c-;:

9C3 IN OIL C0C 2 05/09/95

?C3-1254 J5 5.0 ug/L

?ZSTICLDZ COTC 1 0/09/95

1.5 0.10

4,4' -ODD 0.14 u/L

4.4-DDE 2. 0.00 4,-Y-DOT 0.10

Gig zach1 I.. 0.12

pz".1 0.030

?ESTICIOE COC 2 0/09/95

-DOD L. 0.O7

4,4 -DDE LI 0.030

4,4 -DOT 1.4 0.053 1.' 3.J30 13g

zch1 iz 035 0.34)

PESTICIDE c;c 3 03/09/95

1.0

ESTCIDE COIC 4 05/09/93

'OLATILE LOCA...3ON CONC 1 03109/95

3rrtcdi1cethar. 74 1.0

O 70

ecracoid.e G9 0.C) ugi'L

C1rber.zer. sa 0.40 33 1.0 ug/L

Ch1ofr 35 0.30 u;/L 1,2-CihL 72 1.0 ug,'!.

1hy1 ch1i 55 1.0 uçfL 30 0.3 U;IL

1,!,1Trl orDe 50 0.30 ug!L

5zp.:, 503

os

usz 50a

tjSzP 303 303

?; 505 JSE?. 305

I?.- Ç0 - "-.,.-. .,;-

sz-.

USE?:. 303

tj5E? 303

USZ? 501 USE? cni.

USZ?. 01 tJSE.3. 501

301 - us' ;o

U5E?; 301

tJSZ?.\ SOL

CJSE??. SQL

CJS?? 0L -

EXECUTIVE StJMi\IARY - Detection Highïights

S 5 00 0 3

'.ZPOTC. 3LT Z..I1IT

JT?.IETT COC L 05/39/95

0.0 osp'.oroes, Or:'.o 0.2- 0.1.0

izaz .0 0.050

tTP.:zNT CQC 2 05/09/95

:i:rogen. 'L3 1.5 ?hcspQrus. O:h O.4

rUTRITT COTC 3 05/09/35

Tcza.. !(1daì 4

T?.ZIT C0tC 4 35/09/95

z:.i :<j1h1 P s1crcu5. T:aL

COC . 05/09/95

c?teica1 O::;r. 5 Day

Carcr, TL aic 20.9 Cherrica1 Oxv; 39

DL'AND COC 2 05/09/95

3icerrica1 O:c.r. Denand 10.4 - 5 Day

Carcr. Totii Orgaiic Ceia1 C:ve ard !S.0

?C3 I KATER CCXC 3. 05/09/93

?C3-120 1.4

?C3 I1 1ATR COIC 2 05/09/95

4.9

PCB 1 OIL CONC L 05/09/95

?C3-120 35

19

0.10 0.10 /L (3.25

L.a 0.040

1.0 0.040

40

1.0 3.4.0

0.40

1.0 14.0

1.0 ug/L

1.0

5.0 ug/L

524 237

D

:.C.:r; 3 50 .2 35.2

:C.:'4 3 3 . j

350 2

:!Cr., 3 s .

-r 5 3 . 3

3L.2 ::c;; 2.2

:si.; 5.:

405..

4 10 .

:c:; 405.1

:-!? 41C .1 4 10 . i

CSE??. 505

USE?? 505

' O5

116

524 23

EXECUTIVE StJIMÀRY - Detection HighIihts

S 30 9 00 0 3

O?.T

tT tjT:T

?CZ TLCQ7C 3 05/09/95

AC TLCOC 4 05/09/95

S.1':er 25.1

250

423

23

Tariu 134

Tha11.0

COtC lA :3 C5,'09 /95

5c±fi Cc:ac 420

Tcl Dssoi;e 51!zs 245

1ri 39.5

Su1a: i:',. T:ai $7.0

33.00C

5,330

32,3CC

IRAL5 C0TC 2A & 25 05/09/55

Secific Cduc:ze 37 3.12

Ta.1 D slve 5a3.jd5 S'73

S'luaride 0. si

253

5u1a '7.3

...1a1itiiy, Total ta.o

Ca1ciu 2,9O0

?oasziurt 9330

gr.esiu 295C0

Sodi.i l,200

:i1ZP_ALS C0TC 3 05/09/95

7.

7'IP_ÀLS C0C 4 05/09/95

pH Aeus

20

.1.0 u/L '!CA 200.7

L .0 ug/L. 200

1.0 uc/L. 200.7

1.0 eg/ CA 200.7

1.0 ug/ 200.7

.1.0 u''L 20O.

0.050 .cs/c .10.L

0.90 /: 130.2

5.0 !;a .1

0.010 / 340.2

2.0 :: 325.3

2.0 373 .4

5.0 .1 -

10 '.q/: 273.7 - 2cc.

1.3 ug: :. :.!Cr' 200.7

.1 .0 ugf L IZAi 700 . 7

0.050 s/cl C' 120.1 1.3 nc/L A 130 .2

5.0 g/L MAW'

0.010 igJL 340.2

10.0 mg/L 325.3

i . O mg ¡ 373.

5.0 mg/L 310.1

1.0 u/' 'CAW1 200.7

1.0 u/Z .!OTW 200.7

1.0 u/L ' 200.7

1.0 uc/L CAW 200.7

0 .050 su '!CAW' 150.1

0.050 Su !c»r; 150.1

- 524 239

EXECU'TIVE StTh'IMÁRY Detection HighIigf its

, 5O9O003

RE?OTI p_p_A_.rp. SULT LI!IT UNIT

TR.AC MZTALCOC i 05/09/95

Aiuznirit.-n i.o ug/L 00.7

122 1.0 u/L 3e:'11iwti .3,J 2.0 ufL 2OO.

!32 !.G uç/L 200.7

;_; Cobalt 130 i.o u/L 200.7 Ch:crniurt u/L 200.7 Cppr .. 47.8 ì.0 ug/L 200.7

I:ri 3O 1.0 u/r C?W 200.7

ieru'y 0.20 C?t 245.1 Xa:ianeSe 283 iC ug/L &!CXri 200.7 Tike1 i.0 :Cr 2007

Lead 190 1.0 c/L 200.7

S1eniun 1.0 uc/L 4C?I 200.7

Iaadiurr 522O 1.0 t.g/ 200.7 493 1.0 ug/ CAT1 200.7

TRACE ITALC0TC 2 05/09/95

- A1t.iriu. 2,470 1.0 uc/ 200.7

?.ser1ic 432 1.0 IT 200.7 3eilLi 31.3 1.0 :!xrl 200.7

Caiun 214 1.0 ug/ !CA 200.7

- 329 1.0 200.7

C1US 354 1.0 Ug/L 200.7 Capper 373 1.0 ug/ 200.7

- IO 97 1.0 tg/L CA4 200.7

CUIY 1.3 0.20 ug/L MC.S 245.1 Manganese 1,430 1.0 ug/L MCX4 200.7 ike1 797 1,0 ug/L MCA1 200.7

Lead 493 1.0 ug/L 'IC 200.7 Seleriiwn 47 1.0 ug/L IC4 200.7 Vanadiwi ,iio 1.0 ug/L ZC1 200.7

__ ZIC 9 1.0 ug/L Ci 200.7

TRACE METALC0C 3 05/09/95

Silver 35.4 1.0 ugIL HCfli 200.7 30.9 1.0 ug/L 200.7

Antimony 123 1.0 ug/L trc: 200.7 Srontiwr 43.9 1.0 ug/L C'í 200.7 Ticaniuzi 3.3 1.0 ug/L t!C?' 200.7 Tha1li-n 223 1.0 ug/L Mc?W 200.7

2! -

- 117

521 QDANTERRA, INC.

MINERALS CONC lA & 13

WO : A4FGJ DATE SAMPLED: 5/09/9 LAB #:35E090003-005 TI SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

- INORGANIC ANALYTICAL REPORT

REPORTING PP.EPAP..ATION QC ?APA5TEP. REStYLT LI$IT tNIT T-OD ANALYSIS DATE 3ATC}

Specific Conducta:ice 420 0.050 umhos/c_MCAWW 120.1 6/06/95 5158084 ar&iess 80.0 0.90 g/L MCAWW 130.2 6/06/95 5l59 4

TotaJ. Dissolved Solids 245 5.0 g/L MCAWW 160.1 6/06- 6/07/95 51592_3

Fluoride - 2.1 0.010 cig/L MCAWW 340.2 6/06/95 5158C2 Chloride 58.5 2.0 ig/L MCAWW 325.3 6/06/95 5160C 9

Sulfate 50.8 2.0 g/L MCAW 375.4 6/06/95 51608

Alkalinity, Total 47.0 5.0 g/L .MCAW 310.1 5/06/95 5159C 3

AS R.ECEIVW

c4LDRJOE W.0 UN BY ION CHROMAT0GA?KY SWATE W,j P.JN BY CON OTOGA?HY

22

524 241

QTERRA, INC.

INER.ALS CONC 2A & 2E

WO #: À45L DATE SAMPLED: 5/09/95 LAB :35E090003-006 TI SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

---------------- INORGANIC ANALYTICAL REPORT ............... REPORTING PREPARATION - QC

P_RATER RESULT LIMIT UNIT THOD ÀNAL?SI$ DATE BATCH

Specific Conductance 867 0.050 uOS/MCAWW 120.1 6/06/95 5156084 Hardness 312 1.8 ç/L MCAWW 130.2 6/06/95 5159144 Total Dissolved Solids 675 5.0 g/L MCAW 160.1 6/06- 6/07/95 5159143

Fluoride - 0.57 0.010 ;/L MCA4 340.2 6/06/95 5158082 Chloride 253 10.0 ng/L MCAWW 325.3 6/06/95 5160089 Sulfate 7.5 1.0 ;/L NCA4 375.4 6/06/95 5160088

Alkalinity, Total 10.0 5.0 g/L MCAWW 310.1 5/06/95 5159093

OTE AS RZCETVED - C-(LORD! W,$ P.L14 BY CHROLtACApHy SUL7ATE W, 9Y O4 CHROMAToApHy

23

lip

524 24

QUANTZRR.A, INC.

MINALS COC 3

WO : A4FGN DATE SAMPLED 5/09/9 LAB :B5E090003-007 TL SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

---------- INORGANIC ANALYTICAL REPORT -------------- REPORTING PREPARATION QC

?APJTER RESULT LIMIT UNIT !2T:-OD 'sIs DATE BATC

eH .Aql.leDus 7.6 0.050 su MCAWW 150.1 6/06/95 516312

OTE AS RECEIVED

24

s-

w

w

F

524 243

QIIANTERRA, INC.

MINERALS CONC 4

WO : A4F6P DATE SAMPLED: 5/09/95 LA :35E090003-00a T SAMPLED: MATRIX: PE STAND DATE RECEIVED; 5/09/95

----------- INORGANIC ANALYTICAL REPORT REPORTING PREPA.ATIO QC

PARATEP. RESULT LIMIT UNIT THOD AALYS!S DATE TCH

pH Aueous 9.8 0.050 su MCAW 150.1 6/06/95 5153127

-

w

OTE. AS RCVE

25

i iq

524 241

QUANTER., INC.

NUTRIENT CONC i

WO #: A4FGV DATE SAMPLED: 5/09/9 LAS :35EO9O0O3-009 TI1 SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

------------- ORGANIC ANALICAL REPORT -------------- REPORTING PREPAPATION - QC

P.RATSR RESULT LIMIT UNIT THOD ANALYSIS DATE 3ATC

Nitrogen, Aonia 7.1 0.20 g/L MCAWW 350.2 6/09/95 51600R1 Phosphorous. Ortho 0.94 0.10 g/L MCAWW 365.2 6/09/95 5160 C

Nitrate 6.0 0.050 g/L NC.AW 353.3 6/09/95 5i601

OTE. AS RECEIVED

26

-

524 245

QU?_'TERRA, INC.

ERIE CONC 2

WO : A4F73 DATE SAZLED: 5/09/93 LAB :.35E090003-010 TI SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

---------- INORGANIC ANALYTICAL REPORT --------------- REPORTING PP.EPARATIO - QC

PAR»ETEP. RESULT LIMIT UNIT tTHOD ANALYSIS DATE BATCH

Nitrogen, A=onia 3.8 0.10 g/L MCAWW 350.2 6/09/95 516008 Phosphorous. Otho 0.46 0.10 g/L MCAWW 365.2 6/09195 516011C Nitrate 22.7 0.25 g/L MCAWW 353.3 6/09/95 5160111

SOTE. XS C5IVZD

-

-

27

120

524 241

QANTERRA, INC.

NrRIENT CONC 3

WO *: A4F77 DATE SAMPLED: 5/09/9 LAB :B5E090003-011 T SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

----------- INORGANIC ANALYTICAL REPORT -------------- - REPORTING PREPARATIDN QC

?AMTER REStThT LIMIT !IT THOD ANALYSIS DATE 3ATC

Nitrcgei. Total Kjeldahl 3.8 1.0 g/L MCAW 351.3 6/06/95 5159095 Piosphoz-ous, Total 4.1 0.040 mg/L MCAWW 365.2 6/08/95 51591 )

NOTEZ AS .ZCV!O

2g

- 524 247

QUANTERP..A NC.

NDTRIENT C0C 4

WO : A4F7A DATE SAMPLED: 5/09/95 - LA #:B5E090003-012 TIME SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

- INORGANIC ANALYTICAL REPORT --------------- RZPORTIG PREP RATOS - QC

PARAMETER RESULT LIMIT OIT METHOD ANALYSIS DATE LATCH

Nitroge Total Kjeldahl 16.2 1.0 gJL MCAWW 331.3 6/08/95 5159095 Phohorous, Total 2.1 0.040 mg/L MCAW4 355.2 6/08/95 5159140

OTE AS RCVD

29

121

54 248 -

QDATL.P.A, INC.

DEAD CONO i -

WO : A4F7C DATE SAMPLED; 5/09/9 LAB :'35E09a003-0l3 TIì SAMPLED; MATP.X: PE STAND DATE RECEIVED: 5/09/9

----------- INORGANIC ANALICAL REPORT -------------- - .Z?ORTING PREPARATION QC

?APTER RESULT LI!IT UNIT ThOD ANALYSIS DATE BATC

Biochemical Oxygen Demand 28.8 0.40 mg/L MCAWW 405.1 6/07- 6/12/95 5163131 5 Cay

Caraon. Total Organic 20.8 1.0 mg/L MCA 415.1 6/07/95 5159].1 Chemical Oxygen Demand 53.9 14.0 mg/L MCAWW 410.1 6/07/95 5159142

NOT AS RECEIVEO

30

524 249 QATERRX, INC.

DAND CONC 2

WO #: A4F7 DATE SAMPLED: 5/09/95 LAB #:-35E090003-014 TL SAMPLED: KATRE PE ST.ND DATE RECEIVED: 5/09/95

INORGA1C ANALYTIC)..L REPORT --------------- REPORTIMG PREPARATION QC

PAP TER P.EStJLT LIMIT IT ThOD ANALYSIS DATE 3ATC

Biochemical Oxygen Demand 10.4 0.40 mg/L CAW 405.1 6/07- 6/12/95 5163131 - 5 Day

Caroon, Total Organ.c 7.3 1.0 mg/L MCAWW 415.1 6/07/95 5159141 Chemical Oxygen Demand 19.0 14.0 mg/L CAWW 410.1 6/07/95 5159142

-,

NOTE AZ P.CVED

3'

122

524 2O

ODANTERRA, INC.

CB IN WATER CONC 1

WO 4: A4'7W1O1 LAB : 35E090003-015 MATRIZ: PE STAND

------------- GC Sei-Vo1ati1es -

REStJLT REPORTING

DATE SAMPLED: 5/09/95 TL SAMPLED: DATE RECEIVED: S/09/95

EXTRACTION- QC - PARAfrTER (u/L1 LINT TMOD ANALYSIS DATE 3ATC1

PC3-1016 ND 1.0 tJSEPA 603 05/11-05/16/95 51320

PC3-1232 No 1.0 USEPA 608 05/11-05/16/95 51320

PC3-1248 ND 10 USEPA 608 05/11-05/16/95 5132045

PCB-1254 ND 1.0 USEPA 603 05/11-05/16/95 51320-.

PCB-1260 1.4 1.0 SEPA 608 05/11-05/16/95 5132045

ASR.ECDVW

D OT DECT) AT TI STATED ORTNC LIMIT

32

524 251

QUANRL, INC.

PCB IN WATER CONC 2 WO #: A4F7X1QI. DATE SAMPLED: 5/09/95 LA : 35E090003-0].4 TL SAMPLED: - MATRI PE STP.ND DATE RECEIVED: 5/09195 ------------------ GC Sei-Ve1atj1es ------------------

RESULT REPORTING EXTACTIO- QC PAP.ATER (u/L) LIMIT THOD ANALYSIS DATE BATCH

PCB-1016 4.9 1.0 USEPA 608 05/11-05/16/95 5132045 - 9C3-1232 ND 1.0 USEPA 608 05/11-05/1.6/95 5132045 PCB-1248 ND 1.0 USEPA 608 05/11-05/].6/95 5132045

9C3-1254 ND 1.0 USEPA 603 05/11-05/16/95 5132045 PC3-1260 ND 1.0 LTSE?A 608 05/11-05/16/95 5132045

-f

-

-

OTE AS R.EC TVED

- D OT DTECT AT TUE STATE) REPOPT!(C Lr

- 33

- 123

524 25

QR.A INC.

?CB IN OIL CONC i

WO : A4F82101 DATE SAMPLED: 5/D9/9 LA3 : 35E090003-017 TL SAMPLED: MATIX PE ST?2D DATE RECEIVED: 5/09/9v

------------ GC Seii-V1ati1eg ------------------ RESULT P.EPORTING EXTRACTION- QC

PAPTER (uc/L) LIMIT ThOD ANALYSIS DATE BATCH

PC3-1016 ND 5.0 USEPA 608 05/15-05/22/95 5135 3E

?C3-1232 ND 50 USEPA 608 05/15-05/22/95 51350-E PC3-1248 ND 5.0 [JSEPA 608 05/15-05/22/95 513508E

PC3-1254 ND 5.0 USEPA 603 05/15-05/22/95 5135_5 PCB-1260 35 5.0 USEPA 609 05/15-05/22/95 5133086

OTE AS R.EC V) SO SOT DTECT AT TRE ST,kT ORTC LICT

34

- 524 253

QUANTER.A, INC.

?CB IN OIL CONC 2 Wo #: A4F83101 DATE SAMPLED: 5/09/95 LAB #: 35E090003-018 TI} SAM.PLD: - KATRIX-: PE STAND DATE RECEIVED: 5/09/95 ------------------ GC Sei-Vo1ati1gs ------------------

RESULT REPORTING EXTRACTION- QC PAR TER (uLL) LIMIT ZEThOD ANALYSIS DATE BATC-

?CB-1014 ND 5.0 USEPA 408 05/15-05/23/95 5135084 PCB-1232 ND 5.0 USEPA 408 05/15-05/23/95 5135086 PCB-1248 ND 5.0 tJSEPA 408 05/15-05/23/95 5135084

PCB-1254 15 5.0 USEPA 608 05/15-05/23/95 5135086 PC3-1260 ND 5.0 USEPA 608 05/15-05/23/95 5135084

----J

-

r-OTE. A$ RECEV - 'D .'OT DECT AT TFTh STAT R.ORTL'C urr

35

124

524 254

QUANTERRA, INC

PESTICIDE CONC i -' WO : A4F94101 DATE SANLED: 5/09/95 I3 : 35E090003-019 TflE SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

------------- GC Sei-Vo1ati1es ------------------ RESULT REPO.TIG EXTRACTIOt'T- QC -

P?ATER (u/L) LIMIT THOD ANALYSIS DATE BATCH

Aidrin 1.5 0.10 USEPA 609 05/11-05/16/95 5l32O 4,4'-DDD 4.1 0.14 USEPA 609 05/11-05/16/95 5132048 4,4' -DDE 2.7 0.060 USEPA 609 05/11-05/16/95 51320'.

4,4'-DDT 2.7 0.10 USEPA 609 05/11-05/16/95 51320 Dield.rjn 4.4 0.16 USEPA 608 05/11-05/16/95 5132048 etach1or 2.1 0.12 USEPA 608 05/11-05/16/95 5132O

ieptach1or epoxLde 1.9 0.080 trSEPA 608 05/11-05/16/95 5132048

SUROGTE RECOVERY i ACCEPTA3LE LIMITS

Terachloro-rn-xylene 78 33 - 122) Dibuty1ch1orerdate 83 C 13 129)

OTE AS REC '(ED

36

524 255

QUANTERRA, iNC.

PESTICIDE CONC 2 WO : A4F85].01 DATE SAMPLED: 5/09/95 LA3 : 35E090003-020 TI SAMPLED: MATRIX PE STAND DATE RECEIVED: 5/09/95 ------------------ GC Sei-Vo1ati1es ------------------

RESULT REPORTING EXTRACTION- QC PAR.?TEP. (uq/L) LIMIT ThOD ANALYSIS DATE BATCH

Aldziri 0.30 0.050 USEPA 608 05/11-05/16/95 513204e 4,4'-DUD 1.3 0.070 USEPA 608 05/11-05/16/95 5132048 4.4'-DDE 1.1 0.030 USEPA 608 05/11-05/16/95 5132048

4,4' -DDT 1.4 0.050 USEPA 608 05/11-05/16/95 5132048 Dje1drjr 1.7 0.080 USEPA 608 05/11-05/16/95 5132048 ieptach10 0.36 0.060 USEPA 608 05/11-05/16/95 513204e

Heptachior pcxide 0.35 0.040 USEPA 608 03/11 05/16/95 5132048

StJRROGATE RECOVERY ACCEPTABLE LIMITS

Tetracnloro-rn-xylene 75 ( 33 122) - Dibutyichioreridace 87 C 18 129)

?OTE R.W

- 37

125

524 256

QUANrEa.v., INC.

?ESTICIDE COC 3

WO : A4F86101 DATE SAMPLED: 5/09/9 LAB #: 35E090003-021 TI SAMPLED: MATRIX PE STAND DATE RECEIVED: 5/O9/9

------------ GC Sei-Vc1ati1es ------------------ RESULT RE?ORTIG EXTRACTION. QC -

?AR.TER (ua/L) LINIT TMOD ANALYSIS DATE BATC:-1

Chldane 2.2 1.3 DSZPA GOB 05/11-05/19/95 5132

SURP.OGATE RC0VERY

Terrach1oro-m-xv1en Dibuty1ch1orendae

OTF ..S ECTVE

38

ACCEPTABLE LIMITS

91 33 - 122) 103 lB 129)

524 257

Q ERRA, INC.

PEsTICIDE COC 4 WO : A4F87101 DATE SAMPLED: 5/09/95 LA3 : 35E090003022 TI1 SAMPLED: MATRIX-: PE STAND DATE RECEIVED: 5/09/95 ------------ GC 5-eii-Vo1ati1es ------------------

RESULT REPO.TING EXTRACTION- QC PARATEg (uqL LIMIT ANALYSTS DATE 3ATC

Chiordane 5.]. 5.0 USEPA 608 05/11-05/19/95 5132048

SU?PLCGATE P.ECOVEP.Y ACCE?TABLE LIt1IT

Tetrachloro-rrt-xylene DL ( 33 122)

Diuzy1ch1orerdate DIL ( 18 129)

AS P,EC IV

39

126

524 258

QUANTER.A, INC.

VOLATILE HALOCARBOÑ CONC i

WO #: A4F89101 LAB : 35E090003-023 MATRIX-: PE STAND

-------------- GC Volatiles -

Bocdich1orie thane Br ozio f o= Carbn tetrachioride

Chiorobenzene Dibrornoch1croethane Chrcfor

1,. 2-Dichloroethane ethylene chloride Teti-achlooethene

1, 1. 1-Trichioroethane Tri chloroethene

SLTRP.CGATE P.ECOVERY

rotrtcchl oromethane

'0 TE. AS REC V)

40

(uQ/L) LIMIT

74 1.0 54 0.20 69 0.80

58 0.40 66 1.0 65 0.60

72 1.0 65 1.0 60 0.60

50 0.50 65 0.70

DATE SAMPLED: 5/09/9 TL SAMPLED: DATE RECEIVED: 5/09/95

EXTRACTION- QC ThOD ANALYSIS DATE BATC:-

USE?A 601 06/01/95 515305 SE?A 601 06/01/95 3153045

USEPA 601 06/01/95 51530

USEPA 601 06/01/95 51530 USEPA 601 06/01/95 5153045 USEPA 601 06/01/95 51530

USEPA 601 05/01/95 5153045 USEPA 601 C6/01/95 51530' USEPA 601 06/01/95 51530.

USEPA 601 06/01/95 5153045 USEPA 601 06/01/95 51530-

ACCEPTABLE LIMITS

99 ( 78 - 122)

524 25

Q ERRA, INC.

VOLATILE RALOCAR3ON CONC 2 WO : A4FBA1O1 DATE SAMPLED: 5/09/95 LA.3 : 35E090003-024 TI SAMPLED: MATRIX: P2 STAND DATE RECEIVED: 5/09/95 ------------------- GC Volatiles -------------------

RESULT REPORTING EXTR.CTION- QC PARATEP. (uJL) LIMIT ST4OD ANALYSIS DATE BATCH

= Bromodich1orosethane 19 1.0 SEPA 601 06/01/95 5153045 otiofori 18 0.20 USEPA 601 06/01/95 5153045

Carbon tetrachioride 16 0.90 SEPA 601 06/01/95 5153045

Chiorobenzene 15 0.40 USEPA 601 06/01/95 5153045 Dibroch1romethane 15 1.0 USEPA 501 06/01/95 5153045

- 15 0.50 USEPA 601 06/01/95 5153045

= 1,2-Dih1oroethane 14 1.0 USEPA 601 06/01/95 5153045 Nethylene chloride u i.o USEPA 601 06/01/95 5153045 Tetrachioroethene 15 0.60 USEPA 601 06/01/95 5153045

1,1..1-Trichloroethane 15 0.50 USEPA 601 05/01/95 5153045 Trichioroetherie 11 0.70 USEPA 601 06/01/95 5153045

f

SUR?.OGATE RECOVERY ACCEPTABLE LIMITS

Bromochloromethazte 87 ( 78 - 122)

oTh AS R.EC DV

41

127

524 26h

QA.NTER.RA. INC.

VOLATILE AROMATICS CONC 1

WO : A4F8CJ.01 DATE SMPLED: 5/09/ LAB #: 5E090003-O25 TI SA(PLED: ATRIX PE STAND DATE RECEIVED: 5/O9/

GC Volatiles ------------------- RESULT REPORTING EXTRACTION- QC

PRATER (uo/L LIMIT T-:oD ANALYSIS DATE BATCi

12 0.50 USEPA 602 06/01/95 515: 4

1,2-Dich1orobenzeri 15 0.70 USEPA 602 06/01195 515304 1,3-Dich1óroenzene 17 0.80 USEPA 602 06/01/95 5153Ö4

1,4-Dich1oobenzene 19 0.80 USEPA 602 06/01/95 5l51-4 Ethy1berzene 20 0.20 USE??. 602 06/01/95 515304: Toluene 21 0.20 USE??. 602 06/01/95 515= 4:

SJP.OGATE P.ECOP.Y

Tif1uoroto1uerie 101

OTE AS P.EC EIVED

42

ACCEPTABLE LIMITS

1 73 131)

- 524 261

QUANTERRA, INC.

'.-1 VOLATILE APOMATICS CONC 2 WO : A4F8D1OÎ DATE SAMPLED: 5/09/95 LA #: 35E090003024 TI? SAMPLED: MATRIX-: PE STAND DATE RECEIVED: 5/09/95 ------------------- GC Volatiles -------------------

RESULT REPORTING EXTRACTION- QC PAATEP. (uq/L) LIMIT ThOD ?NALYSIS DATE BATCH

Eenzerie 50 0.50 USEPA 602 06/01/95 5153046 - l,2-Di1ilcrobenzene 66 0.70 USEPA 602 06/01/95 5153046 1,3-Dichloobenzene 61 0.80 USEP.A 602 06/01/95 5153046

l,4-Dichlocbenee 60 0.80 USEPA 602 06/01/95 5153046 Ethy1benene 48 0.20 USEPA 602 06/01/95 5153046 Toluene 64 0.20 USEPA 602 06/01/95 5153046

n

SURROGATE RECOVERY

Trifluorotoluerie

SOTE. A.S REC

43

ACCEPTABLE LINITS

102 73 - 131)

128

524 26

QUANTER.RA, INC.

TOTAL CYANIDE CONC i

WO #: A4F8E DATE SAMPLED: 5/09/9E LAB #:35E090003-027 TIME SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/9

----------- INORGANIC ANALYTICAL REPORT --------------- REPORTING PREPARATION QC

PAP.ATER RESULT LIMIT UNIT ThOD ANALYSIS DATE EATC

Cyanide, Total 0.12 0.0010 mg/L MCAWW 335.2 6/07/95 51631"9

OTE AS PECD'TED

-

r

e

524 263

QANTSRRÀ, INC.

TOTAL CYANIDE CONC 2

WO : A4F8F DATE SAMPLED: 5/09/95 LAB #:.B5E09O003'028 TL SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

---------- INORG»IC ARALrICAL REPORT --------------- REPORTING PREPARATION QC

PA?TEP. RESULT LIMIT UNIT T?OD ANALYIS DA BATCH

Cyanide,, Total 0.86 0.0050 =g/L MCAW 335.2 6/07/95 5163129

OTE. A.S RECVW

45

129

524 261

QUANTERRA, INC.

NON-PILTERASLE RESIDUE (TSS) CONC J

WO : A4F8G DATE SAMPLED: 5/09/9

LA3 :.B5E090O03-O29 TI SAMPLED:

MATRIX; PE STAND DATE RECEIVED: 5/09/95

----------- INORGANIC ANALYTICAL REPORT -------------- - PPORTING PP?ARATION QC

PAPATER REStJLT LIMIT IT ThOD ANALYSIS DATE 3ATC

Solids, Tta1 Suspeiided 35.6 2.3 /L MCAWW 160.2 6/12/95 516312E

O1t A R1CVZ

46

- 524 265

QANTERRA, INC.

NON- FILTERABLE RESIDUE (TSS) CONC 2

WO : A4FBH DATE SAMPLED: 5/09/95 LAB :35E090003-030 TL SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

---------------- INORGANIC ANAL'!TICAL REPORT --------------- REPOP.TING P?RATIO QC

RESULT LIMIT tWIT ANALYSIS DATE BATCH

Solids.. Total Suspended 19.5 2.3 g/L MCAW 150.2 6/12/95 516312E

w

-

w

OTE AZ RECEVED

w

47

/

130

524 266

QUTERP, INC.

OIL & GREASE CONC i

WO : A4FBJ DATE SAMPLED: 5/09/ LAB #:35E090003-031 TI SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/9

---------- INORGANIC ANALYTICAL REPORT -------------- -- REPORTING PREPARATION QC PAT RESULT LIMIT tJIT 5THQD ANALYSIS DATE 3AT

Oil ad Grease, 10.3 5.0 g/L MCAWW 413.1 6/00- 6/09/95 5159"9 Graviine tri c

OTL AS RECEJVED

43

524 267

QUANTER.k, INC.

OIL & GRASE CONC 2

WO : A48X DATE SAMPLED: 5/09/95 LAB :BSE090003-032 TI SANPLD: MATRIX: PE STAND DATE ECEIVZD: 5/09/95

---------------- INORGANIC ANAL'fTCAL REPORT --------------- REPORTING PREPARATION - QC

?ARATER RESW.T LZMIT tNIT FThOD ANALYSIS DATE SATC

Oil aid Grease. 15.0 5.0 g/L NCAWW 413.1 6/08- E/09/95 5159094 Gavìmetric

-

-f

-

OTE AS P.ZCVZD -

a

w

49

131

524 26

QtJANTERRA, INC.

TOTAL ?HZOLICS CONC

WO ; À4FBL DATE SAMPLED: 5/09/9 LA :B5EO90003-033 TI SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/O9/9

---------- INORGANIC ANALYTICAL REPORT -------------- REPORTING PREPARATION QC

PARATER P,EStJLT LIMIT UNIT T-!OD LISDATE BATC

Pheiolics 0.050 0.030 g/L MCAW 420.1 6/12/95 51631

OTE AS R.EC VED

J

50

524 269

QEPP.A, INC.

TOTAL PENOLICS CONC 2

WO #: A4F8M DATE SA.pLED: 5/09/95 LA? #:.35E090003-034 TI SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

---------- INORGANIC ANALfrICAL REPORT --------------- REPORTING ?RE?ARATIO.T QC P»TER RESULT LThIIT UNIT fr5ThOD ANALYSIS DATE ?ATCf

PhenoJ.ics 0.37 0.030 g/L MCAWW 420.1 6/12/95 53.63130

NOTEZ AS R.ECEXVZD

e

e

e 51

132

524 270

QUANTERRA, INC.

TOTAL RESIDZIAL CHLORINE CONC J

WO #: A4F8N DATE SAMPLED: 5/09/9 LAB #;35E090003035 TI1 SAMPLED: MATRIX: PE STAND CATE RECEIVED: 5/O9/9

----------- INORGANIC ANALYTICAL REPORT -------------- RE?OPLTIG PREPARATION - QC

PARATER RESULT LIMIT UNIT TOD ANALYSIS DATE BATC

Chicrine, Thtal Residual 0.092 0.030 /L MCAWW 330.5 6/12/95 51630R5

OTE AS R.CVD

52

- 524 271

QUAZR.RA INC.

TOTAL RESIDUAL CMLORINE CONC 2

WO : A4F3R DATE SAMPLED; 5/09/95 - LAB :B5EO9O003-O3 TINE SAMPLED: MATRIX: PE STAND DATE RECEIVED: 5/09/95

- INORGANIC ANALYTICAL REPORT --------------- REPORTING ?RE?WTION QC pPT. RESULT LIMIT UNIT THOD .NALYSI5 DATE 3ATCH

Ch1oie, Total Residual

-

0.14 0.030 g/L MC»4W 330.5 6/12/95 5].63085

-

-

SOTE AS RECVW

-

- 53

133

524 27,

Quality Control Summary

Q uanterri QC Program Summary

Method Blanks

Uiboratorv Control Sampfts

'viatrix Spikef1atrix Spike Dupicatcs

Cha in - of-Cus t odv

54

524 273

Q uantex-ra Quality Control Program Sum rnry

__ Quantra Envjronmentl Servcs conSider5 COfltflLOUS znalytica[ method perforriance evauazorts to be n

, ntegrat portion o th data pckag. and rouriney in:udes the perzinn Q.-VQC d3t 3S5OCaed wkh analytk2C

rsut3. Brief discussions of the various QAIQC procdurs utiliz:d to measure czetbIe method and rnrrix performance follow. Further documenraion oNpecific poIices nd procedures L'i use re availabk, upon request. from the Quanterr Qua(itv Control Department.

The program described below provides Qu;nt-'s interpreraton o QC requirements described in SW-346, 3rd edition -Finas Update If. Addtiona intrpretatioris specffic to other aspects o methods performed, such as

instrumertt eaUbr3tion and bench procedures. are described n progrm-specWc docmenLs (e.g. US Corps of Engrieers, AECEE. etc.) and assoced method standard opectirtg procedures. \Vhere exptcit progrzrn r:quir:mts or project requirements exist, certain ctemers of the Quarirerra QC Progrr may be superseded by these requirernens.

Ekmencs ,fthe Ötiintrn flC Prprn

Wiier other clear regu[:cry guidance, :ontract pec'ifications. or client requirements are not ava.bbe, the . Quanrerra QC Program provides guidance for Batch QC requirmens. The Quality Conrro[ Batch is a set of up to

20 fleW sampks ofsimilnr matrix, which are processed ogether under the same cond.ions. within the same rime frame. fncuded ¡n each QuaUtv Contro' Batch s a Method B'ank. Laboratory Cc'.trol Smpk. and Manix Spike Duplicare. For methods that require independent sample prparzion prior to anIysi. th QC Batch is deflned at

= the preparation stage. For methods that do not require indepmdnt rnpIe prepartion. the QC Batch is defined at the instrument. The QC Batch Number is provided on each result page l'i ssocaon with the paraimeter(s)

presented, and my be used to rosc-reference samp!e results wfth the :t.socbtd QC

vkthod Blank Evuicions

___# Laboratory araIytic[ method blanks are sysremaricatly prepared and analyzed n order o .ontinuousIy eva!uae the

system interCrence and backgrourd cotaminatio kvets associated with each aptabte analyrkat method. vÍthod bLanks icude att aspects of ctuaI 'aboratory procedures in%'oving sarrpfe preprarion and anaIyss.

substirwin aratvre-free .vater or sorid for the actual sampk. Under noa( crurnsrnces. the Method Blank should riot xhibc ana[yres oFintersz above the reported detectior limit. Due to che presence ofsom anatyres L, a

typical laboratori setting, the following common taboratory conrzrninanrs are excepois o this ruk, provided the:í are not present i1 the method biank nc greater than five limes the reportirg lImit.

Volatiles Srni-Volatiles Mj Methylenc chloride Dimethyl phthalac Calcium Toluen Dieihyt phthalate Magnesium

- 2-Butanore Di-n-butyt-phthalnte Sodium A:et:th Butyl benzy phtha1at

Bis (2-ethyihexyl) phtha late

A method blank is performed with each anal>ical batch. A minimum of Wo of all laborazo' analyses are method blanks.

Lborator.' Control Samole

Known concetratons of dignaEed matrix spike (target anatyte) compounds are added to a method btank prior to

extraction and analysis. Percent recovery determinations of individual target analyces in the LCS demonstrate the - taborazorys method performance for the QC Batch refative to these target analytes (or other individual components represented by a subset ocorurol artalytes). Percent recovery data is displayed alongside acceptance criteria, that 15

typically derived from bbortory hitorica data. Failure of a Laboratory Control Sample to meet estbtished recovery criteria for control analytes is cause for corrective actions to occur, which typically includes re-extraction and re-arta[y5is of all samples a.ssocited with the QC Batch. An LCS is performed with each anatytical batch. A minimum of5% ofall laborcory analyses are laboratory control samples.

55

t- i 34

524 274

Q uanterra Quality Control Program Summary (continued) -

Surrca Spike Recovrv EvaIuaons

For GC and CC/MS analyses. known conceGaion of designad surrogate spikes. consisting of a number of sLrniar. non-rnthod compounds or method compound anzIogus. ar zdded ro sample fraions prior o sample ext-action and analysis. The ptrcent recovery deterrnùiarions calcuCated from the subsequent ana'ysis is one indication ofthe overalL method efficiency för thc indivithat sample. The surroga spike rcovcry data is displayed a(ongsde azceprarice limits at the bottom of each apptkabte aralyzica result report page. Where sufñcienc laboraory-generated data does not yet exist to determine appropriate control limits, advisory !ims may b cnad Unti' sufficient data is collected co allow implernent:iort ofeontrol limits.

Mrth Sike/Matrix Spk Duplicate (MS/MSD EvaFuatiors

In conjunction with the analysis ofa client-provided field sarnp[e, a known conc:ntion ofdesignated maùix spike coipounds (targe zialyres) are added to two aliquots of the actual sample. Percent recovery determinacins ar calculated frorn.both spikedaliquots, using crget.anale oncenrations aLreadyrcsentin the anial sample ai a baseline. The percent reovry determinations indkate the accuracy ofthe methospeciflc rothe target aiFytes (or other individual :omponenzs represented by a subset or conol ana[ytes) in the thdividua ampIe matrix. Comparison ofihe percent recoveries in the two spiked aliquots yields a relative percent difference (RPD). Percent recovery and relative perzenr difference data is disp'ayed alongside historical crireri that may be used to judge jrdjvidual sa.mple maix effects for specific analytes. MS/MSD thta is evaluated by the laboratory with respect ro

the iidividua[ sarnpe matrix. ¡ri cases whet: LMS/MSD data indicate sainpl method performance ouiside of historica! cri:ria th labortorj onoo( samp'e results are referenced to cnsu:. accpable method performance by the laboratory for the sample batch. For analyses which ar napropriatly suzed for mathx spikes (g. OH), non- pikd duplicate analyses are performed to generare precision data. Maix spike duplicates are rypically

performed ort at leas: one sample within each analytical batch. A minimum of 10% ofall jaboratory nalys a maix spikes or dup1icars. - Correc:ive Action EvaIuatpng

fte goal oÉ the Quancerra Quality Conrro Program is to gr.era: data that demonaes process control, arid altows for clnt usabiliry ordata. Where the anayticat process is demonstrated :o vary from established criteria, or cften recuirernents have not been mcc, data evaluation resulting in corrective action may be required. Corrective action may inzlude re-preparation and/or reanalysis of field 'samples and QC samples. Where appropriate or necessary to allow proper interpretation of results prese:iced in the final report, details of corrective actions taken during the Laboratory processing ofsa'nples are prescntd as a case narrative atthc front ofthe report. Alternatively, routine corrctiv: ztion such as reanalysis, may be fooutoted on individual sample result pages.

¿n.].iLi. Result Otß.1ifirFIas

Where applicable , data qualifiers may be appcndd to anayticaI results in order Lo allow for proper intcrpr:tation ofthe r:sut presented. Typically, the presence ofdata quaifler flag on an aralytical result page is accompanied by a footnote explaining the qualifier. Common data qualifiers include. bu are no limited to the following:

J -indicates an estimated concentration is reported due to rzi:thod lirnitations.such as matrix interference or instrumental dection lirnitatiori.

B -indicates the presence oía particu'ar arialyte in the associated lzboraory method blank. DIL -iadicates percent recovery determination was not possible due co dilution associated with the sample

matrix conditions or high target analyte concentrations. X -indicates internal standards used for a GC or GCIMS ana'ysis did no: meet established criteria, typically

due o a sample matrix effect. E -indicates an esimaed concentration is reported due to arialyte response bcyond the established

instrumental calibration rarge, typically due to presence ofa wide range oftarget anayte concentrations.

524 275 ITRA-LAS BLAN}Z P..EPORT

r.-

LAB : 35F020000-045

------------------- CC Volatiles ------------------- RESULT REPORTING PREPAPTION - QC PAATE (tcxfL) Lfl!XT ANALYSIS D BATCH

- Broznodichlorometharie 1.0 6/01/95 5153045 Brornoform ND 0.20 6/01/95 5153045 Carbon tetrachloride ND 0.80 6/01/95 5153045 Chiorobenzene ND 0.40 6/01/95 5153045 Dibrorriochloromethane - ND 1.0 6/01/95 5153045 Chlorofcrn ND 0.60 6/01/95 5153045 - 1,2-Dichioroethane ND 1.0 6/01/93 5153045 1ethvLene chloride ND 1.0 6/01/95 5153045 Tetrach1roethee ND 0.60 6/01/93 5153045 i,1,1-Trichloroethane ND 0.50 6/01/95 5153045 Trich1orothee ND 0.70 6/01/95 5153045

SUP.P.OGATE RECOVEFY BroraochlorctTethane 101.

OTE

(ONZ rCT.D)

57

ACCE?T3LE LIt1IS 73 - 122)

135

524 27

INTRA-LAB BLANK REPORT

LAB : 35F020000-046

- GC Volatiles

RESULT REPORTING PREPARATION - QC

PARATER (uqíL) LIMT ANALYSIS DATE 3ATC

enzer1 ND 0.50 6/01/95 5l530Z

1,2-Dih1orobenzerie ND 0.70 6/01/95 5153044

1,3-Dichlorobenzene ND 0.80 6/01/95 51530.

14-Dich1orobenzen ND 0.80 6/01/95 5153046

Ethvlbenzerie - ND 0.20 6/01/95 51530-

Toluerie ND 0.20 5/01/95 51530-

SQ?.P.OGAT RECOVERY Trifluroto1uene 103

SOTF

D ÇrOE DETECTED)

5g

ACCEPTABLE LB-lITS

73 - 131)

t

524 277

INTRA-LAB BW.NZ REP0.T

LAB #: 35E120000-045

------------ GC Semi-Volatiles

RESt3LT PPORTING PREP?.RATIO QC (ua/L) LIMIT ANALYSIS DATE BATCH

PC3-1016 ND 1.0 5/11- 5/16/95 5132045 PCB-1232 ND 1.0 5/11- 5/16/95 5132045 PCB-1248 ND 1.0 5/11- 5/16/95 5132045

PCB-1254 ND 1.0 5/11- 5/16/95 5132045 PC3-1260 - ND 1.0 5/11- 5/16/95 5132045

-

-

SUROGAT RECOVERY Tetrach1oro-m-xy1ere

e SOTF

D ÇO4! TCTZD)

59

ACCZ?TABLE LflITS 93 C 33 - 122)

136

524 27

LAB : 55E150000-086

INTRA-LAB BL.A.NX RE?ORT

GC Sei-V01ati1es

RESULT REPORTING PR.E?ARTION - QC PA.TER (u/L) LIMIT ANALYSIS D.TE TC

PC3-1016 ND 0.50 5/15- 5/20/95 5135086 PCB-1232 ND 0.50 5/15- 5/20/95 51350P PC3-1248 ND 0.50 5/15- 5/20/95 51350

PC-1254 ND 0.50 5/15- 5/20/95 5135086 POE-1260 ND 0.50 5/15- 5/20/95 51350

SUROGTE P..ECOVERY Tezrath1or-rn-xy1ene 103

N0TE

D CNONE DETECTED)

60

ACCETA3LE LIMITS 32 - 154)

s

s

s

s

LAB #: 35E120000-048

INTRA LAB BLANX REPORT

GC Semi-VoJ.atjles

524 279

.ESULT REPOaTING PREPARATION - QC (u]L) LIMIT ANALYSIS DATE BATCH

A1drir ND 0.050 5/11- 5/16/95 5132048 Ch1odane ND 0.79 5/11- 5/16/95 5132048 4,4'-DDD ND 0.070 5/11- 5/16/95 5132048

4,4'-DDE ND 0.030 5/3.1. 5/16/95 5132048 4.4'-DDT - ND 0.050 5/11- 5/16/95 5132048 Dieldrín ND 0.080 5/11- 5/16/95 5132048

epah1or ND 0.060 5/11- 5/16/95 5132048 ieptach1or epoxid ND 0.040 5/ii- 5/16/95 5132048

SURP.OGATE P.ECOVEY Tetrachloro-rn-xylene Oibuty1ch1orenate

NOTE.

ND (NOs! DE.1!CED)

61

ACCEPTABLE LIMITS 78

( 33 - 122) 87

( 18 - 129)

137

524 2Sf)

Z.3 : 35E090003

INTRA - LA3 3AN ?EPOPT

TALS

RE?ORTiN ?AfrTEP. RESULT LI!!IT L!T T-OD ?.NALYSS

3TC : 5135171 ND 1.3 /L MCAW 200.7 5/15- 2

ND 1.0 eg/L MCAW 200.7 5115- 5/:

ND - 1.0 u/L fCW 200.7 5/15- 2

ND 1.3 uq/L MCA 200.7 5/15- 5'2

Ca1cii 1.0 ug/L CAW 200.7 5/15- 2

C!uri ND 10 uc/L !CAW 200.7 5/15- 2

ND 1.0 ig/L NC.W 200.7 5/15- 2

Chc!urn ND 1.0 ug/L !CW 200.7 5/15- 5/2

Copper ND 1.0 g/L MCAW 200.7 5/15 2-

ND 10 ug/L iC.4 200.7 5/15- 5/2.

?oassiu. ND 10 ug/L MC.TW 200.7 5/15- 5 2

esi ND 1.0 ug/L MCW 230.7 3/15- 5_2-

ND 1.0 ç/L MCAW 200.7 5/15- 5

ND 1.0 u/L Mc.W4 200.7 5/15- 5-r2$

Sodiu,i ND 1.0 /L CAW 200.7 5/15 5/2

Nickel ND 1.0 ug/L CAW 200.7 S/15 5/24

Lead ND 1.0 ug/L 200.7 5/15- s'4

SOTE

-0 OT DETECTED ATTr- STATED E?OTtNG L!0T

62

INTRA-L.A3 BLAN'.< .ORT

LAB #: 35E090003

524 281

- METALS

REPORTING ?REPAR.ATION - PARTER SULT LIMIT UNIT TQD ANALYSIS DAT

BATCH:5135171 Antimony ND 1.0 ug/L MCAW 200.7 5/15- 5/24/9: S1enium ND 1.0 mg/L MCAW 200.7 5/15- 5/24/9: Strontium ND 1.0 ug/L MCA 200.7 5/15- 5/25/9:

Titanium ND 1.0 ug/L MCAWW 200 7 5/15- 512619f Thallium ND 1.0 ug/L MCAWW 200.7 5/15- 512419f Vanadium ND 1.0 ug/L MCAWW 200.7 5/15- 512419f

Zinc -

ND 1.0 ugh, MCAWW 200.7 5/15- 5/24/9

BATCH :5138121 Mercury ND 0.20 ug/L MCA 245.1 5/25- 5/26/95

- D OT DrrECThD AT ThE STAD R.EPORTI$G LIMIT

63

-

524 28

LAS *: 35E090003

CHECX SAN2LE REPORT

ItORGANIC A L'fTICAL REPORT

SPIKE PERCENT -

COMPOUND F..ECOVEP.Y LIMITS

Specific Conductance 100 (87-105) hardness 100 (95-108) p- Acueous 100 (90-110)

Total Dissolved Soli 100 (77-115) Solids, Total Suspended 89 (77-115) Cyanide 94 (56-128)

Fluoride 102 (93-114) Nizrogn, &oia 100 (78-113) Nitrogen, Total Kje1daL1 100 (84-122)

Phcshcrcus, Ortho 104 (74-127) Phcshorcus, Total 105 (74-127) Siochemical Oxygen Demand 96 (48-112)

5 Day

Carbon, Total Organic itraze

Cil and Grease, Graieic

Chemca1 Oxyger. Demand Chloride Phenolics

Sulfate Alkalinity, Total

64

108 (90-117) 107 (63-130) 103 (35-125)

PREPAPATION Q/C ANALYSIS DATE BATC

4/06/95 5l580 6/06/95 51591 4/06/95 51G31

6/06- 6/07/95 51591- 6/12/95 51631_ 6/07/95 5143129

6/06/95 5153W 6/09/95 5150OT 6/08/95 5159095

6/09/95 51601_ 6/08/95 5159140 6/07- 6/12/95 514

6/07/95 3159141 6/09/95 516011 6/08- 6/09/95 5l590

105 (81-114) 6/07/95 515914 94 (36-117) 6/06/95 51003 96 (64-102) 6/12/95 5163130

100 (80-120) 6/06/95 516008_ 104 (90-110) 6/06/95 5159093

524 283

c:Ec:< SALE REP0T

QC B.ATC:: 5153045 LAB #: 35F020000-045 C PRE?AP.ATI01 DATE: 6/01/95 -

DATE A}ZALYZED: 6/01/95

------------------- GC Volatiles ------------------- S? IKE PERCENT Q/C - CO0tJD RECOVERY LThiTS

1,1-Diehlorc'ethene 115 (28-167) Nethvlene chloride 110 (25-162) Ch1o;oorni 111 (49-133) 1,1,1-Trichloroethan- 107 (41-138) Carbon tetrachioride 127 (43-143) - 1,2-Dichioroethane 108 (51-147) Trich1oethene 107 (35-146) Brotnodichioromethane 124 (42-172) Tetrachlorcethene 109 (26-142) Drcrnoch1orornethane 128 (24-191) Chlorobenzene 130 (38-150)

121 (13-159)

-

65

139

524 281

QC ATCI-: 5153046 LAB : 35F020000-G46 C

CEC SAM'LE REPORT

GC Volatiles

SPIKE

?REPA.R.TIO DATE: 6101/95 DATE ANALYZED: 6/01/95

PERCENT c/C

COM?OLTND COVE?.Y LIMITS

Berizene 112 (39-150)

Toluene 111 (46-148) - Ezhylbenzerie 114 (32-1GO)

13-Dich1oroenzene -. 108 (50-141)

1,4-Dichlorobenzene 105 (42-143)

1'-Dich1orobenzne 107 (37-154)

LCS - DCS REPORT

QC BATCH: 5132045 LAB : 5E12O00O-045 C

w

524 285

WO #: PREPARATIO1 DATE: 5/11/95 DATE ANALYZED: 5/16/95

------------ GC Seii-Vo1atjles ----------------- LCS DCS

PERCENT PERCENT Q/C RPD COOUD RECORY RECOVERY LIMITS RPD LIMITS

PC-1U16 93 loo C4-122) 1.7 29 PCB-1260 93 96 (28-146) 3.9 27

w

e

w

e

e

- ilcubconj .rs pc-iiorrn bcton roimthng to .o4d round-cff tyran ist ct!cu'-'rd cuIts

67

140

524 28

QC BATCH: 513508G LAB : 35E150000-08G C

LCS - DCS REPORT

GC Semi-Volatiles

WO :

PREP _ATIO DATE: 5/15/95 DATE ANALYZED; 5/20/95

LCS DCS PEP.CENT PERCENT Q/C RPD

COOUND RECOVERY RECOVERY LIMITS RPD LI-IITS

?C3-101G 101 102 (-122) 0.51 29

?CB-12G0 93 97 (28-14G) 4.2 27

. prfomd btor o ...'ed r,nd-oI'f i

63

524 287

LCS - DCS .EPORT

QC BATcTh 5132048 WO :

LAB : B5E120000-048 C PREPARATIOÑ I)ATE: 5/11/95 DATE ANALYZED: 5/16/95

------------------ GC Seti-Vo1ati1es ----------------- - LCS DCS

PERCNT PE?.CENT Q/C COCUND P..ECOVEY RECOVERY LIMITS R?D LIMITS

gaaBC (Lindane) 83 80 (68-142) 4.1 44 eptadi1or 75 73 (68-136) 2.2 40 A1d.n 69 65 (65-125) 6.2 32 Dieldrin 73 76 (66-136 2.2 34 Endrin

a 79 (63-142) 2.1 37 4,4'-DDT 88 97 (62.142) 10 51

e

e

tkth,n, pq4 md o ..&4 o.d-off ,,on Mid

69

- z1

524 28

LAB : 351090003

CHECK SAMPLE E?ORT

TALS

S P I Kl PERCENT Q/C PPEPP..ATiO -

COM?OtYND RECOP.Y LINITS ANALYSIS DATI

3ATCH : 5135171

Silver 98 (34-113) 5/15- 5/24/95

Aluminum 98 (23-117) 5/15- 5/24/95

rsenic 98 (30-120) 5/15- 5/24/95

3r-j11iurn 100 (31-112) 5/15- 5/24/95

Calcium 102 (85-121) 5/15- 5/24/95

Cadmium 101 (83-117) 5/15- 5/24/95

Coba1 100 (87-115) 5/15- 5/24/95

Chroiium 100 (89-117) 5/15- 5/24/95

Copper 97 (90-110) 5/15- 5/24/95

Iron 103 (36-124) 5/15- 5/24/95

Potassium 104 (9-131) 5/15- 5/25/95

Magnesium 100 (81-118) 5/15- 5/24/95

Manganese 102 (86-114) 5/15- 5/24/95

1o1ybderiurri 97 (85-118) 5/15- 5/24/95

Sodium 101 (93-117) 5/15- 5/25/95

ickl 101 (8-114) 5/15- 5/24/95

Lead 99 (33-117) 5/15- 5/24/95

93 (73-113) 5/15- 5/24/95

Selenium 99 (80-120) 5/15- 5/24/95

Sroniui 99 (30-120) 5/15- 5/25/95

Titanium 95 (-) 5/15- 5/26/95

Thallium 99 (33-130) 5/15- 5/24/95

Vanadium 101 (90-113) 5/15- 5/24/95

Zinc 100 (75-110) 5/15- 5/24/95

BATCH:513 2121 !ercur'/ 102 (75-121) 5/25- 5/26/95

70

524 289 - a -

Section No. : Thirteen Revisiofl No. : 9 V' Date: 10/15/95 Page: I of6

13.0 Corrective Action

13.1 Nonconformances and Corrective Action

Corrective action action is a measure taken to rectify conditions that are aiverse to quality, and where necessary, to preclude their recurrence. Corrective actions should be timely, determine the root cause and evaluate any propagation ofthe error or problem, Unplanned deviations from an established protocol or plan, that is, the events that often give rise to corrective actions, are termed nonconformances. The deviation may be the result ofQuanterra Tampa's actions, and thus deemed a deficiency, or the result of actions outside ofthe control of Quanterra Tampa, and then termed an anomaly.

According to Quanterra Tampa's Standard Operating Procedure (SOP) TAMP-QA-0004 (Nonconformance and Corrective Action), all employees ;e responsible for identifying problems that may affect quality. In addition, individuals outside of Quanterra Tampa (for instance individuals representing the FDEP) can identi' conditions adverse to quality through the review of records, audits, or performance audits. Such identification is docuniented on a Nonconformance Memo (Figure 13-1).

Once identified, laboratory managementlsupervisory staff are responsible for assigning an individual to perform the corrective action. In addition, project management staff has the responsibility of contacting laboratory clients regarding nonconformances and subsequent corrective actions. Actions by both

-, laboratory and project management are documented by means of the initiating Nonconformance Memo (NCM). The QA Manager is responsible for oversight ofihe corrective action process, which is to incude the implementation ofthe NCM, the tracking ofNCMs, and confirmation ofthe corrective action.

13.2 Batch OC Corrective Action

Quality control requirements ofmethods that are contained within SW846, and methods that are performed when no specific program is specified, are described in QA Policy No. QA-003 (Quanterra Quality Control Program). This document establishes criteria for QC samples/elements associated with a batch of samples (Batch QC), as defined by SWS46. The criteria and associated corrective actions are described in Table 13-1. Any deviations from the established criteria are addressed by means ofan NCM, described in section I 3 . I . Corrective actions to the deviations are adrcssed as previously described.

= 13.3 Method-Srecific Corrective Actions

Method-specific criteria, for methods and procedures performed by Quanterra Tampa, are contained within SOPs developed and implemented by the laboratory. Each employee performing the method or procedure is to document any deviations from the SOP by means of the MCM. Corrective actions to the deviations are addressed as previously described.

-

524 2:)í)

Section No : Thirteen Revision No. : 9

Date: 10/15/95 - Page: 2of6

TABLE 13.1

CORRECTWE ACTION

oc Activity Acceptance Criteria Corrective Action

-

Equipment Blank < LDL (Reporting) -

Reprocess equipment and reanalyze or "flag' data.

Trip Blank < LDL (Reporting)'1

Verify contamination and investigate. 'Flag' data.

Field Duplicate Duplicate result must be Reanalyze then recollect within 20% of sample samples and reprocess value. them.

Field Measurements Within established control Reanalyze then reprocess Precision and Accuracy limits. any affected saniples.

Initial Instrument Blank Inst. response < MDL Prepare another and determine cause.

Calibration Check 10% ofexpected value Reanalyze then recahbrate Standards and rerun.

Method Reagent Blanks < LDL (Reporting) Reanalyze then reprocess entire batch.

Reagent Matrix Spike Within established control Reanalyze then reprocess (Laboratory Control limits. entire batch. Sample)

Matrix Spike and Relative percent deviation Reanalyze then reprocess Duplicate must be within established sample, matrix spike,

control limits. matrix spike duplicate.

. Sample Duplicate Duplicate result must be Reanalyze both sample and within 15%oforiginal duplicateandthen sample value. reprocess sample and

duplicate.

- Surrogate Spikes

- Internal Standard

TABLE 13-1 CORRECTIVE ACTION

(continued)

Within established control lth *.

-50% to +150% of the calibration check.

24 291

Section No. : Thirteen Revision No. : 9 Date: 10115/95 Page: 3of6

Reanalyze then reprocess any affected samples.

Reanalyze then reprocess any affected samples.

Notes:

* Certain common lab contaminants are acceptable provided their concentration does not exceed five times the practical quantitation limit.

- ** Acceptable method performance for Base/Neutral Acid extractables is indicated by two (2) ofthree (3) .

surrogates for each fraction with a minimum recovery often ( i 0) percent each. For Pesticides one

- (1) oftwo (2) surrogates meeting performance criteria is acceptable.

-

524 29

FIGURE 13-1

NONCONFORMANCE MEMO

LAORÂTORY NOCCFORMÀ>CE MEMO (Cfl L.4a.t, .Me'. (PJ .

Section No.: Thirteen Revision No.: - 2 Date: 10/15/95 Page: 4of6

I L Lthi !C

$a;L Ne.:

Sc? oAd: Cf Cr

rÛ icd äq):

GC-Vc cc.i Q: Gc-S1?LC W.. ij

3 Ls ?-ñ CC(S-VCC n

c(r,,v?« * r: 'a): ' -'Y /.VC.!

3.4&' r ày______ ¿J ''Q7 C.'7 t: :7. QC i

J L lgr_3it t.

. := 4.1 h:. : V bok ha t. SC? Q. ,-' .

2 z O .

¿1. L.a'w" 3 . y..::: r ij

2 c.-.-..::L It C

2 2::.

2 .

2:. LZ... ,i.»

2 . C:ç.1 O :

O J.

2 1.

3 . .-,ç..)

2

2 22. Ceir

3

! 'w 2 . c4 ________________________________

O1.. c ________________________________________

OLi. C3D j _____________________________________

CCthc Cao

Ci& by ( nd t: CL= ___________________

O 3

C On oh J Q Oc.-

?j 3: tÇZ 4 c):

Pi;; ..

a

I

a

524 293

Section No.: Thirteen Revision No.: 2 Date: 10/15/95 Page: 5 of6

FIGTJRE13-1

NONCONFORMAI4CE MEMO (continued)

Mno (NQ lu, 4 tI -

- T. 4. .yd .d ,,,..wd by .11 ca

RbiE- fo CA

Aø- iiüalj ijid

Gp LIOo. Ma çan

r-' - OJfr C Lfiv A1,r2,ee Riw To i, p(.d y Q. C

C Fr iau I-= Q c:cy

zp QÑC__________________________________________ Ow:

Leot Tm Cpyitc V To o. opI.:.d y Q.- 9"''

C tuird or Vcib7

oenformic. Mem,, 2oiur

Q.IJQC parur - Th. Q .p...a1 .. of.¼ 1r,.i

Piç2a(2

144

524 291

Section No. : Fourteen

- Revision No. : 2

-, Date: 10/15/95 Page: i of 4

- 14.0 Performance and Systems Audits

Quanterra Tampa maintains an internal system ofperformancc and systems audits to Verify the quality of

- its measurement systems. These audits are conducted on a regular basis as a part of normal laboratory operations. In addition, the laboratory participates in a number of federal, state, and private laboratory certification audit and/or approval programs in order to demonstrate its analytical capabilities and

- expertise. Participation in these programs requires the laboratory tö demonstrate acceptable laboratory performance through satisfctory completion ofroutirie systems and/or performance audits.

- 14.1 Systems Audits

14.1..1 Internal Audits

- An annual systems audit is performed under the direction ofthe Corporate Director of Quality As3urance. Fliis audit is performed to assess each laboratory's adherence to the requirements of Quanterra's Quality Management System, as defined by the Quality Management Plan (QMP), and the Quality Assurance Management P(an (QAMP). The systems audit also assesses the status of corrective actions from other audits at Quanlerra Tampa. The Corporate Director of Quality Assurance appoints a lead auditor to conduct the systems audit. A corporate check list is used to document the audit (see Figure 14-1 for audit - checklist outline).

-, 14.1.2 External Audits

Quanterra Tanipa participates in On-site e'cternal systems audits by the State of Florida Department of Health and Rehabilitative Services (FDHRS). This annual audit is required for certification by the FDHRS = and is also required by the FDEP. The FDEP QA section is at liberty to conduct an on-site audit at their discretion or in conjunction with a site specific QAPP. Additionally, Quanterra Tampa encourages audits by its clients and other regulatory agencies. Agencies that have previously audited Quanterra Tampa - include the New Jersey Department of Environmental Protection and Energy, the New York Department of Health, the North Carolina Department of Environment, Health, and Natural Resources, and the Air Force Center for Environmental Excellence.

14.2 Performance Audits

- Quariterra Tampa participates in performance audits at a minimum of four times per year. The samples that comprise the performance audit may be supplied internally or externally as blind or double-blind samples. Internal performance audits may be conducted by the QA Manager, or under the guidance of the - Corporate Director of Quality Assurance. External performance audits that Quanterra Tampa partakes in are conducted by the EPA (Water Supply and Water Pollution Studies), the Army Corps of Engineers, and the New York Department of Health. All results of performance audits, whether internal or external, are - reported to the Regional QA Director and the Laboratory Manager. All performance audits that are identified as unacceptable are investigated. This investigation and the subsequent corrective action are also reported to management.

145

524 295

Section No. : Fourteen Revision No.: 2 Date: 10/15/95 -

Page: 2of4

14.3 Data Audits and Spot Assessments

In addition, data audits are conducted by the QA Manager in accordance th QA Policy No. QA-006. The data audit is used to identify any lab errors that may have occurred during the laboratory activities. The findings (see Figure 14-2 for example of data audit checklist) and corrective actions resulting from the data audit are reported to the Regional QA Director and 'the Laboratory Manager.

Spot assessments are conducted to monitor or observe a process or activity in order to verify conformance to the specified requirements ofihat activity. The QA Manager determines the scope ofthe assessment, but it may be directed by client inquiries, trends in recorded nonconformances, performance audits, or other sources. The results of the spot assessment and any necessary corrective actions are reported to the Laboratory Manager.

Data audits and spot assessments should each be performed on a monthly basis.

524 296

Section No. : Fourteen

Revision No.: -9

Date: 10/15/95

Page: 3 of4

FIGURE 14-1

INTERNAL SYSTEMS AUDIT CHECKLIST OUTLfl4E

Quanterra YY95 Audit Chack1it Out1je

. L 1ityIOpui Fü A. QIity A B. AUdWSpQC

1. L Ii1 QiJiy Syz Audits 3. Exi*I Midit

C. Suior Rxth D. PE Si=,ie Recoii E. NoococIom'nceJConctivc Atio F. Compuzr Saftsrc VaiiocNaidz.ion Rcds G. Tnining Fi1

QSupm1 IL Cuceai Sv w.. Sample Rpt/Log-1nJStcragdDspou1 - A.S0P3

B. Trig C. Softwu Verfic2flOu1 n. Sa RcdpC E. Sacc Log-Ii F. Sap4c Sorg.1Tntc1 COC G. Sample BocI H. Sace Dspo L D±a Rurding Pmctic _, - 1V. Rerd Man2nt

V. Projcct ifaaagenat

vi-vn. Sample paraei (Inorganic md Oraic) A. SOPs B. MaseÑJ Pruwc md Coatrol C. Piodic £qtaipmsc CalThrarion D. Staodaid.s ?rrpazzion aod Stocg E. Spc SIIntcra1 baùi of Custody - F. Da Rcde Pr G. Data Review H. Concivc Acziöo Process L Txining

- J. S0*'2rs Vcsifica&ioo

. .y-xUI. Simple Ana1yss Vm - Metais, DC - We Oic. X - GCMS Sesnivoatfles. X! . CC Se=avoI&üJ. Xii - GcMS VoIasMs, li . C VoLati1es

A. SOPs B. MateÑi Procwcst md Cottol C. Stsidsrs Prepsrsxiocs sod S.xsge ID. Saplc Storsge/tiueroal CCC E. CaJibrstios (Peiiodc asid Opersxiocal) - 1. Periodic Epm Ciibrstioes

2. Opmxioas1 Ca1ibsiioos . F. Prtvcoive Maiitccanoe

C. Ttig zitiaion/Rodisg Tie H. S=p1c Aisaiysis

- r. QC Sample aIysis

: Da Review K. Dctoe Liit Studies L. Data Rnfing Pncices M. C.orrive Mtioo N. Traicng

= - o. Softwsz Vezfficioo , P. PE Results

Q. Other Cozzets

,av. Padiochenstry SuppInent A. Feilites B. Sample Reipi a4 Dposa1 C. Sanple/QC Sample Aaiysis D. SOPs

e

i 46

524 297 Section No.: Fourteen Revision No.: 9

Date: 10/15/95 Page: 4 of 4

FIGURE 14-2

INTERNAL QA DATA AUDIT CHECKLIST

TERNAL QA DATA ATJDIT CHECKLIST

PROJECT Axzditor______________________

DATE RECEIVTh:______________ Darn Audited

DATE REP 0RT):_____________ PROJECT ThWOI AMT:__________

CHAIN OF CUSTODY AD LOG Th4 YES NO NA

1. Chain of Cutedv pr and propcliy si I

2. Chain of Custody and 10-m aç L If no, have all dis o1vod

L b. Is there adopiaxe docun aziosi to support env

I.

3. C1itsnazneandaddrs 4. Aoo/CNarnc

Date sampkd

LD*te reccived/re1od [j. Çliect proit lidentifier

Lab mp!e (rorded on 1on shz) Client Sample IDe (ansctibcd correcdy) j _____

LO. AnaMie Riired L____ ______ _____

____ ___ FINAL REPORT REVIEW YES NO I NA

- Coverletteriscorct 2. Anomalies documented in £nal report as appropriate

3. Samole ID (sample descriptions/lab IDe 000ect) 4. Methods and method numbers are correctly renorted

3. All reoucered parameters repored for each same 16. Report format is ccsistent with PA/Client rueet j J

17. Noted client reenests completed 18. Data paclQe complete 19. Comparative data support: (8015 vs 418.1, 8015 vs 602/8020, 601/8010 and 602/8020 vs 624/8240, Phenols vs 60418040 and 625/8270, TTLCvsSTLC, cooducùwty vs TOS, dissolved metals <total metals, ICP vs GFAA, TOS <TS,TSS <75, Cr(VI) < Cr,NHJ <TKN,TON<TKN, ortho- P <Total P, COD> lix BOD, Reactive CN <Total CN, Reactive Sulfide <Total Sulfide, COD - 2.Sx TOC, TDSISPCD between 0.55- 0.81, ninate < niri-axe/oitritc, nitrite <nitrate/nitrite, EPTOX orTCLP <0.OSx Total, pH vs alkalinity, fluent vs. effluent, sampl from same borins but difeetet depths, data vs sample dectiption. etc.)

OAuditors Siaxure Date_________________ (re', 1:7f94)

524 298

Section No. : Fifteen Revision No: IO

Date: 10/15/95 Page: I ofl

15.0 Oualitv Assurance Reports

15.1 External OA Reports

The QA Manager is responsible for filing a report with the FDEP, via the consulting firrn that has prepared the Category 4 QAPP. The preparation ofthe QA Report would be at the request ofthat firm, and at a - frequency of once per project (at completion) or every two years during a project. Typically, projects that Quanterra Tampa participates in do not require scheduled project audits and are usually less than two years in duration. When submitted, the QA Report would outline all criteria specified in Section D of the DEP - QAmanual.

15.2 Internal OA Reports

The QA Manager is responsible for preparing and submitting an internal report ofthe laboratory activities on a monthly basis. The report is laboratory specific and is submitted to the Regional QA Director and - Laboratory Manager by the tenth day of each month. The report sununarizes all quality control related activities of the lab, including percentages of QC samples; evaluations of method detection limit studies; systems audit results or performance evaluation results; a summary of any control problems encountered, - and the outcome ofany corrective action taken.

15.3 Project OA ReDorts

At the completion ofa sampling and/or analytical project a QA report Will accompany the analytical result report (see Figure 12- 1). In most cases this will include any QC sample results that support the data - presented and a summary of the QA/QC program. In addition, the narrative of the analytical report contains information as to nonconformances and corrective actions that were taken to resolve these nonconformances.

147

Kea M. Rigil Qua1iy Assurance Manager

Quan terra Incorporated 5910 Breckenridge Parkway, Suite H Tampa, Fío 33610

873 621-0784 Telephone 813 623-6021 Fax

January 10, 1996

IMS Environmental & Engineering 115 Metro Park Rochester, NY 14623

- Attention: Praveen Srivastava, Ph.D.

Dear Dr. Snvastava:

524 299 Quan terra

Environmental Services

Please consider this letter an addendum to the previous letter of January 10, 1996. Included in this follow-up correspondence, are the following:

TC lists for SW846 Method 8260 and 8270; LCS and MS/MSD control limit criteria for SW846 Method 8260; - . LCS and MS/MSD control limit criteria for SW846 Method 8270; and LCS and MS/MSD control limit criteria for SW846 Method 6010 and 6010 Trace.

Additionally, the control limit criteria for some analytes not included on the enclosed information are included in the following table.

AnalytefMethod LCL j UCL RPD MS/MSD

LCL UCL J BPD

Carbazole by 8270 34 J 132 30 34 132

_ 30

Benzo(b)fluorantheneby 8270

39 I

113 30 43 110 30

TRPHby 9071/418.1 72 120 25 86 143 12

If Quanterra Tampa can be of further assistance on this matter, please call Steve Tafuni or meat (813) 621-0784.

- Sincerely,

- Kevin M. Bull Quality Assurance Manager

Enclosure

CIA5OI 10.DOC

24 300

- Reporting Limits for

-.-, Target Compounds by

SW846 Method 8260 and 8270

-

524 301 Quote No.: 12959 Analytical TAT: 2]. - Revision: 1-00 Networkable (Y/N) : Y

Dated: 11/30/1995 Tics (Y/N) : N Printed: 9:09:04 - 1/10/1996 Dry Weight (Y/N) : Y

Client Number: 360364 Qualifiers (Y/N) : N Project Manager: Steve Tafuni

Protocol: A soils SAC: XX A 15 AF 36

- LiSt: 02001 Units: ug/kg

Test Description: SOLID, 8260, Volatile Organics, GC/MS (8

Synonym Name RL 00574 Chioromethane 10 00343 romomethane 10 02613 Vinyl chloride 10 00550 Chioroethane 10 01811 Methylene chloride 5 00011 Acetone 20 00459 Carbon disulfide 5 00943 l,l-Dichloroethene 5 00933 1,1-Dichioroethane 5 - 00952 l,2-Dichloroethene (total) 5 00569 Chloroform 00936 1,2-Dichj.oroethane 5 00372 2-utanone 20 02518 1,1,1-Trichloroethane 5 00463 Carbon tetrachioride 5 00323 Bromodichioromethane 5 00986 1,2-Dichioropropane s 00998 cis-1,3-Dichloroproperie 5 02525 Trjchloroethene 5 00535 Dibromochioromethane 5 02522 1,1,2-Trichloroethane 5 00196 Benzene 5 01000 trans-1,3-Diehloropropene 5 00340 Bromoform 5 01845 4-Methyl-2-pentanone 20 01515 2-Hexanone 20 02445 Tetrachioroethene S - 02439 1,1.2,2-Tetrachioroethane 5 02489 Toluene 5 00521 Chlorobenzene 5 01332 Ethylbenzene 5 02355 Styrene 5 02627 Xylenes (total) 5

524 302 Quote No. : 12959 Analytical TAT: 21 - Revision: 1-00 Networkable (YIN) : Y

Dated: 11/30/1995 Tics (YIN) : N Printed: 9:09:05 - 1/10/1996 Dry Weight (YIN) : Y

Client Number: 360364 Qualifiers (YIN) : N Project Manager: Steve Tafuni

Protocol: A soils SAC: XX A 11 FC 36

List: 02101 Units: ug/kg

Test Description: SOLID, 8270A, Base/Neutrals and Acids (8

Synon Name RL 02155 Phenol 330 00293 bis (2-Chioroethyl) ether 330

- 00600 2-Chlorophenol 330 00907 1,3-Dichlorobenzene 330 00910 1,4-Dichlorobenzene 330 00904 1,2-Dichlorobenzene 330 01851 2-Methyiphenol 330 00301 2,2' -Oxybis (1-Chioropropane) 330 01857 4-Methyiphenol 330

- 02024 N-Nitrosodi-ri-propylamine 330 01497 flexachioroethane 330 01972 Nitrobenzene 330 01566 Isophorone 330 01998 2-Nitrophenol 330 01145 2,4-Dimethylphenol 330 00289 bis (2-Chioroethoxy) methane 330 00971 2.4-Dichlorophenol 330 02515 1,2,4-Trichlorobenzene 330 01932 Naphthalene 330 00518 4-Chloroanjiine 330

- 01489 Hexachiorobutadiene 330 00578 4-Chloro-3-methylphenol 330 01829 2-Methylnaphthalene 330 01492 Hexachiorocyclopentadiene 330 02559 2,4,6-Trichioropheno]. 330 02555 2,4,5-Trichiorophenol 330 00589 2-Chloronaphthalene 330

- 01960 2-Nitroanjiine 1600 01149 Dimethyl phthalate 330 00005 Acenaphthylene 330 01193 2,6-Dinitrotcjluene 330 01964 3-Nitroaniline 1600 00001 Aceriaphthene 330 01187 2,4-Dinitropheno]. 1600

- 02001 4-Nitrophenol 1600 00863 Dibenzofuran 330 01191 2.4-Dinjtroto].uene 330 01082 Diethyl phthalate 330 00602 4-Chlorophenyl phenyl ether 330 01417 Fluorene 330 01968 4-Nitroanjljne 1600 01167 4,6-Dinitro-2-methylphenol 1600 02028 N-Nitrosodiphenylamine 330 00348 4-Bromophenyl phenyl ether 330 01482 Hexachlorobenzene 330

524 303 Quote No.: 12959 Analytical TAT: 21 - Revision: l-00 Networkable (YIN) : Y

Dated: 11/30/1995 Tics (V/N) : N Printed: 9:09:05 1/10/1996 Dry Weight (Y/N): Y

Client Number: 360364 Qualifiers (Y/N) : N Project Manager: Steve Tafuni

Protocol: A soils SAC: XX A 11 FC 36

List: 02101 Units: ug/kg

Test Description: SOLID, 8270A, Base/Neutrals and Acids (8

Synonym Name RL 02118 Pentachiorophenol 1600 02154 Phenanthrene 330 00122 Anthracene 330 02751 Carbazole 330 00891 Di-n-butyl phthalate 330 01414 Fluoranthene 330 02252 Pyrene 330 00403 Butyl benzyl phthalate 330 00918 3,3'-Dichlorobenzidine 660

- 00202 Benzo(a}anthracene 330 00633 Chrysene 330 00302 bis(2-Ethylhexyl) phthalate 330 01162 Di-n-octyl phthalate 330 00205 enzo(b)fluoranthene 330 00208 Benzo(k)fluoranthene 330 00211 Benzo(a)pyrene 330 01535 Indeno(1,2,3-cd)pyrene 330 00860 Dibenz(a,h)arithracerie 330 00210 Benzo(ghi)perylene 330

-

524 304 -

Control Limit Criteria - for

Target Compounds -i by -

SW846 Method 8260 and 8270 and 6010

-

Quality Control Limit Summary -

5 2 4 3 Q 5

Qc Type C LCS-DCS I4ethod AF Volatile Organics. GC/MS (8260) Location: 02 QtTh1'TERRA - T.NPA - Program: 92 US AlP. FORCE AFCEE (9/9) Extraction: All, non-specific extractions Matrix: s Solid Ligt: 02312

Syn# mpoun. Naine LCL UCL RPD

00011 Acetone 24.00 188.00 16.00 00196 Benzene 79.00 123.00 18.00 00323 Bromodichioromethane 74.00 115.00 23.00 - 00340 Bromoform 53.00 119.00 37.00 00343 Bromometharie 23.00 166.00 37.00 00372 2-Butanone 29.00 92.00 44.00 00459 Carbon disulfide 64.00 127.00 26.00 00463 Carbon tetrachioride 71.00 123.00 25.00 00521 Chiorobenzene 72.00 122.00 21.00 00535 Dibrornochioromethane 67.00 116.00 33.00 00550 Chioroethane 72.00 149.00 22.00 00569 Chloroform 65.00 120.00 28.00 00574 Chioromethane 56.00 184.00 37.00 - 00888 Dibromomethane 74.00 137.00 26.00 00924 Dichioroclifluoromethane 84.00 161.00 29.00 00933 1,1-Dichioroethane 62.00 120.00 17.00 00936 12-Dichloroethane 76.00 125.00 23.00 00943 1,1-Dichioroethene 66.00 124.00 22.00 00950 trans-1,2-Dichlcroethene 66.00 124.00 27.00 00952 1.2-Dichloroethene (total) 66.00 124.00 27.00 - 00986 1,2-Dichioropropane 79.00 121.00 20.00 00998 cis-1,3-Dìchloropropene 76.00 115.00 20.00 01000 trans-1,3-Dichlorcpropene 68.00 114.00 24.00 01332 Ethylbenzerle 73.00 130.00 24.00 01428 Trichiorofluoromethane 67.00 141.00 18.00 01515 2-Hexanone 35.00 119.00 34.00 01811 Methylene chloride 65.00 128.00 16.00 01845 4-Methyl-2-pentanone 32.00 184.00 40.00 02355 Styrene 76.00 125.00 29.00 02437 1,1,1,2-Tetrachioroethane 70.00 121.00 38.00 02439 1,1,2,2-Tetrachicroethane 65.00 124.00 38.00 02445 Tetrachioroethene 69.00 123.00 33.00 02489 Toluene 91.00 121.00 18.00 02518 1,.1,1-Trichloroethane 62.00 120.00 28.00 02522 1,1,2-Trichloroethane 80.00 121.00 20.00 02525 Trichioroethene 77.00 121.00 19.00 02563 1,2,3-Trichioropropane 72.00 137.00 42.00 02610 Vinyl acetate 75.00 125.00 35.00 02613 Vinyl chloride 83.00 132.00 25.00 02627 Xylenes (total) 80.00 132.00 30.00 02730 Bromofluoroberizene 14.00 121.00 .00 02863 Dibromofluoromethane 80.00 120.00 .00 02740 Toluene-dS 81.00 117.00 .00

-s

Quality Control Limit Summary 2 4 306

QC ?y'pe s MS-MSD ethod; AF Volatile Organics, GC/MS (8260)

Location: 02 QCJANTERRJ - TP.NPA ,.- Progran: 92 US AIR FORCE P.FCEE (9/93) Extraction: All, non-specific extractions

- Matrix: s Solid List: 02313

Svn# Compound jame LCL UCL RPD

00011 Acetone 9.00 97.00 39.00 00196 Benzene 84.00 123.00 14.00 - 00323 Bromodichioromethane 70.00 116.00 34.00 00340 Bromoform 46.00 85.00 34.00 00343 Bromomethane 39.00 123.00 31.00 00372 2-Butanone .00 87.00 46.00 - 00459 Carbon disulfide 51.00 118.00 29.00 00463 Carbon tetrachiaride 64.00 122.00 27.00 00521 Chiorobenzene 74.00 119.00 18.00

- 00535 Dibromochioromethane 54.00 118.00 37.00 00550 Chioroetharie 80.00 150.00 24.00 00569 Chloroform 60.00 119.00 22.00 00574 Chioromethane 41.00 166.00 31.00 - 00888 Dibromomethane 61.00 140.00 24.00 00924 Dichiorodifluoromethane 87.00 153.00 23.00 00933 ].,1-ichloroethane 59.00 125.00 19.00 0093G 1,2-Dichioroethane 70.00 129.00 25.00 00943 1,1-Dichioroethene 65.00 133.00 23.00 00950 trans-12-Di.chloroethene 60.00 126.00 20.00 00952 1,2-Dichioroethene (total) 60.00 126.00 20.00 0098G 12-Dichioroproparie 82.00 121.00 21.00 00998 cis-1,3-Dichloropropene 65.00 106.00 25.00 01000 trans-1.3-Dichloropropene 58.00 100.00 32.00 01332 Ethylbenzene 57.00 144.00 29.00 - 01428 Trichiorofluoromethane 61.00 138.00 23.00 01515 2-Hexanorie 4.00 76.00 48.00 01811 Methylene chloride 67.00 131.00 19.00 01845 4-Methyl-2-pentanone 27.00 109.00 33.00 02355 Styrene 63.00 120.00 18.00 02437 1,1,J.,2-Tetrachloroethane 68.00 118.00 27.00 02439 1,1,2,2-Tetrachioroethane 36.00 127.00 38.00 02445 Tetrachioroethene 59.00 123.00 24.00 02489 Toluene 71.00 125.00 21.00 02518 1,1,1-Trichloroethane 50.00 126.00 21.00 - 02522 1,1,2-Trichloroethane 71.00 116.00 27.00 02525 Trichioroethene 73.00 121.00 17.00 02563 1,2,3-Trich].oropropane 33.00 141.00 45.00 02610 Vinyl acetate 75.00 125.00 35.00 02613 Vinyl chloride 71.00 173.00 26.00 02627 Xylenes (total) 68.00 137.00 24.00 02730 Bromofluorobenzene 74.00 121.00 .00 02863 Dibromofluoromethane 80.00 120.00 .00 02740 Toluene-d8 81.00 117.00 .00 00318 Bromobenzene 84.00 117.00 20.00 00321 Bromochloromethane 73.00 107.00 20.00 00393 n-Butylbenzene 77.00 123.00 20.00

2 4 307 -

Quality Control Limit Summary

QC Type C LCS-DCS Method: FC Base/Neutrals arid Acids (8270) - Location: 02 QT3ANTEPA - TPNPA - Program: 92 US AIR FOICE AFCEE (9/93) Extraction: All, non-specific extractions

- Matrix: S Solid List; 02314

Syn# Comiound Name LCL UCL RPD

02155 Phenol 38.00 109.00 30.00 00293 bis(2-Chloroethyl) ether 44.00 106.00 30.00 - 00600 2-Chicrophenol 44.00 100.00 30.00 00907 1,3-Dìchlorobenzene 42.00 99.00 30.00 00910 1,4-Dichlorobenzene 44.00 99.00 30.00 00215 Benzyl alcohol 29.00 115.00 30.00 - 00904 1,2-Dichlorobenzene 46.00 97.00 30.00 01851 2-Methyiphenol 46.00 100.00 30.00 00298 bis(2-Chloroisopropyl) ether 36.00 166.00 30.00 02777 3-Methyipheno]. & 4-Methyiphenol 27.00 108.00 30.00 - 02024 N-Nitrosodi-n-prcpylaxnine 46,00 104.00 30.00 01497 Hexachioroethane 44.00 97.00 30.00 01972 Nitrobenzene 37.00 92.00 30.00 - 0156G Isophorone 51.00 105.00 30.00 01998 2-Nitrophenol 49.00 105.00 30.00 01145 2,4-DimethylphenoJ. 39.00 88.00 30.00 00289 bis(2-Chloroethoxy)methane 29.00 125.00 30.00 00971 2,4-Dichiorophenol 50.00 105.00 30.00 02515 1,2,4-Trichlorobenzene 46.00 101.00 30.00 01932 Naphthalene 47.00 104.00 30.00 00518 4-Chloroariiline 40.00 100.00 30.00 01489 Hexachiorobutadiene 46.00 100.00 30.00 00578 4-Chloro-3-methylphenol 58.00 112.00 30.00 01829 2-Methylnaphthalene 50.00 105.00 30.00 01492 Hexachlorocyciopentadiene 41.00 115.00 30.00 02559 2,4,6-Trichiorophenol 51.00 114.00 30.00 02555 2,4,5-Trichiorophenol 45.00 127.00 30.00 00589 2-Chlorcnaphthalene 55.00 105.00 30.00 01960 2-Nitroanjiine 62.00 117.00 30.00 01149 Dimethyl phthalate 63.00 119.00 30.00 00005 Acenaphthylene 56.00 112.00 30.00 - 01193 2,6-Dinitrotoluene 62.00 116.00 30.00 01964 3-Nitroaniline 50.00 99.00 30.00 00001 Acenaphthene 55.00 110.00 30.00 - 01187 2,4-Dinitrophenol 43.00 129.00 30.00 02001 4-Nitrophenol 40.00 143.00 30.00 00863 Dibenzofuran 58.00 112.00 30.00 01191 2,4-Dinitrotoluene 56.00 127.00 30.00 01082 Diethyl phthalate 61.00 125.00 30.00 00602 4-Chioropheny]. phenyl ether 56.00 117.00 30.00 01417 Fluorene 58.00 117.00 30.00 01968 4-Nitroariiline 53.00 125.00 30.00 01167 4,6-Dinitro-2-methylphenol 42.00 146.00 30.00 02028 N-Nitrosodiphenylamine 78.00 145.00 30.00 00348 4-Bromophenyl phenyl ether 62.00 115.00 30.00 01482 Hexachiorobenzerie 61.00 116.00 30.00

Quality Control Limit Summary - r 24 308

QC Typa C LCS-DCS Methoa: FC Base/Neutrals and Acids (8270) Location: 02 QUNTERRA - TAMPA Program: 92 US AIR FORCE - AFCEE (9/93) Extraction: All, non-specific extractions Matrix: S Solid List: 02314

Svn# Compound Name LCL UCL RPD

02118 Pentachiorophenol 40.00 125.00 30.00 02154 Phenanthrene 63.00 118.00 30.00 00122 Anthracene 63.00 125.00 30.00 00891 Di-n-butyl phthalate 55.00 134.00 30.00 01414 Fluoranthene 58.00 127.00 30.00 02252 Pyrene 68.00 116.00 30.00 00403 Butyl benzyl phthalate 65.00 125.00 30.00 00918 3,3'-Dichlorobenzidine 38.00 107.00 30.00 00202 Benzo(a)anthracene 69.00 119.00 30.00 00633 Chrysene .00 119.00 30.00 00302 bìs(2-Ethylhexyl) phthalate 66.00 124.00 30.00 01162 Di-n-octy]. phthalate 43.00 117.00 30.00 00205 Benzo(b)fluoranthene 45.00 113.00 30.00 - 00211 Benzo(a)pyrene 44.00 112.00 30.00 01535 Indenc(1,2,3-cd)pyrene 39.00 114.00 30.00 02669 Diberizo(a,h)anthracene 50.00 99.00 30.00 00210 Benzo(ghi)perylene 38.00 115.00 30.00 - 02736 Nitrobenzene-d5 10.00 155.00 .00 01425 2-Fluorobìphenyl 12.00 153.00 .00 02738 Terphenyl-d14 13.00 140.00 .00 - 01426 2-Pluorophenol 24.00 118.00 .00 02737 Phenol-d5 17.00 124.00 .00 02512 2,4,6-Tribromophenol 10.00 156.00 .00 02770 1-Methylnaphthalene 50.00 150.00 30.00 00209 Benzoic acid 10.00 121.00 30.00

-

-

w

Quality Control Limit Summary

QCType S

Method: FC Location: 02

program: 92 Extraction: Matrix: S List: 02315

S-NSD Base/Neutrals and Acids (8270) QUANTE RRA - TAMPA US AIR FORCE APCEE (9/93) All, non-specific extractions Solid

Svn# Compound Name

524 309

LCL UCL RPD

02155 Phenol 37.00 110.00 30.00 00293 bis(2-Chloroethyl) ether 10.00 138.00 30.00 00600 2-Chiorophenol 37.00 106.00 30.00 00907 1,3-Dichlorobenzene 36.00 99.00 30.00 00910 1,4-Dichlorobenzene 36.00 100.00 30.00 00215 Benzyl alcohol 36.00 114.00 30.00 00904 1,2-Dichlorobenzene 40.00 101.00 30.00 01851 2-Methyiphenol 43.00 109.00 30.00 00298 bìs(2-Chloroisopropyl) ether 42.00 102.00 30.00 02777 3-Methylphenol & 4-Methylpheriol 27.00 108.00 30.00 02024 N-Nitrosodi-n-propylaxnine 39.00 108.00 30.00 01497 Hexachioroethane 36.00 101.00 30.00 01972 Nitrobenzene 39.00 92.00 30.00 01566 Isophorone 42.00 110.00 30.00 01998 2-Nitrophenol 42.00 112.00 30.00 01145 2,4-Dimethyiphenol 45.00 128.00 30.00 00289 bis(2-Chloroethoxy)methane 41.00 110.00 30.00 00971 2,4-Dichiorophenol 42.00 116.00 30.00 02515 1,2,4-Trichlorobenzene 41.00 102.00 30.00 01932 Naphthalene 41.00 107.00 30.00 00518 4-Chioroaniline 35.00 88.00 30.00 01489 Hexachlorobutadiene 42.00 102.00 30.00 00578 4-Chloro-3-methylphenol 47.00 125.00 30.00 01829 2-Nethylnaphthalene 44.00 109.00 30.00 01492 Hexachiorocyclopentadiene 41.00 115.00 30.00 02559 2,4,6-Trichlorophenol 43.00 117.00 30.00 02555 2,4,5-Trich].orophenol 44.00 123.00 30.00 00589 2-Chloronaphthalexie 48.00 113.00 30.00 01960 2-Nitroaniljne 55.00 124.00 30.00 01149 Ditnethyl phthalate 54.00 123.00 30.00 00005 Acenaphthylene 48.00 119.00 30.00 01193 2,6-Dinitrotoluene 53.00 121.00 30.00 01964 3-Nitroaniline 55.00 124.00 30.00 00001 Acenaphthene 48.00 115.00 30.00 01187 2,4-Dinitrophenol 24.00 143.00 30.00 02001 4-Nitrophenol 29.00 143.00 30.00 00863 Dibenzofuran 50.00 116.00 30.00 01191 2,4-Dinitrotoluene 50.00 128.00 30.00 01082 Diethyl phthalate 52.00 126.00 30.00 00602 4-Chiorophenyl phenyl ether 54.00 115.00 30.00 01417 Fluorene 52.00 119.00 30.00 01968 4-Nitroaniline 44.00 114.00 30.00 01167 4,6-Dinitro-2-methylpheriol 41.00 107.00 30.00 02028 N-Nitrosodiphenylamine 66.00 154.00 30.00 00348 4-Bromophenyl pherlyl ether 53.00 114.00 30.00 01482 Hexachlorobenzerje 61.00 115.00 30.00

Quality Control Limit Summary 524 311)

QC Type S MS-MSD Method: FC Base/Neutrals and Acids (8270)

- Location: 02 QUTERRA - TP.MPA Program: 92 138 AIR FORCE AFCEE (9/93) Extraction: All, non-specific extractions Matrix: S Solid List: 02315

Svn* Comoun Name LCL UCL RPD

02118 Pentachiorophenol 19.00 125.00 30.00 02154 Phenanthrene 61.00 117.00 30.00 00122 Anthracene 65.00 119.00 30.00 00891 Di-n-butyl phthalate 42.00 132.00 30.00 01414 Fluoranthene 56.00 125.00 30.00 02252 Pyrene 62.00 119.00 30.00 - 00403 Butyl benzyl phthalate 55.00 131.00 30.00 00918 3,3'-Dichlorobenzidine 26.00 92.00 30.00 00202 Benzo(a)anthracene 65.00 121.00 30.00 00633 Chrysene 60.00 124.00 30.00 00302 bís(2-Ethylhexyl) phthalate 56.00 131.00 30.00 01162 Dì-n-octyl phthalate 33.00 123.00 30.00 00205 Benzo(b)fluoranthene 37.00 120.00 30.00 - 00211 Benzo(a)pyrene 47.00 110.00 30.00 01535 Indeno(l,2,3-cd)pyrene 40.00 113.00 30.00 02669 Dibenzo(a,h)anthracene 37.00 109.00 30.00 00210 Benzo(ghi)perylene 37.00 115.00 30.00 02736 Nitrobenzene-dS 10.00 155.00 .00 01425 2-Fluorobiphenyl 12.00 153.00 .00 02738 Terphenyl-d14 13.00 140.00 .00 - 0142E 2-Fluorophenol 24.00 118.00 .00 02737 Phenol-d5 17.00 124.00 .00 02512 2,46-Tribromophenol 10.00 156.00 .00 02770 1-Methylnaphthalene 50.00 150.00 30.00 00209 Benzoic acid 16.00 72.00 30.00

Quality Control Limit Summary a

524 311

QC Type C LCS-DCS Method: DQ Inductively Coupled Plasma (6010A)

-- Location: 02 Q[JATERRA - TNPA Program: 92 US AIR FORCE AFCEE (9/93) Extraction: All, non-specific extractions - Matrix: S Solid List: 02322

Syn# - Comppun Name LCL UCL RPD

02285 Silver 79.00 110.00 25.00 00088 Aluminum 78.00 104.00 25.00 00140 Arsenic 81.00 110.00 25.00 00194 Barium 8.00 111.00 25.00 00222 Beryllium 81.00 110.00 25.00 00413 Calcium 87.00 110.00 25.00 - 00411 Cadmium 84.00 110.00 25.00 00637 Cobalt 82.00 110.00 25.00 02952 Chromium 81.00 112.00 25.00 00643 Copper 82.00 110.00 25.00 01539 Iron 84.00 110.00 25.00 02214 Potassium 80.00 110.00 25.00 01618 Magnesium 81.00 110.00 25.00 - 01659 Manganese 84.00 112.00 25.00 01906 Molybdenum 81.00 110.00 25.00 02315 Sodium 82.00 110.00 25.00 01956 Nickel 86.00 110.00 25.00 01605 Lead 84.00 110.00 25.00 00128 Antimony 84.00 110.00 25.00 02281 Selenium 76.00 110.00 25.00 - 02477 Thallium 85.00 110.00 25.00 02607 Vanadium 83.00 110.00 25.00 02649 Zinc 81.00 110.00 25.00

a

a

Quality Control Limit Summary 21 31 2

QC Typa C LCS-DCS Method; JH Inductively Coupled Plasma (SO1OA Trace)

- Location: 02 QUTERRA ThMPA Program: 92 US AIR FORCE AFCEE (9/93) Extraction: All, non-specific extractions Matrix: S Solid List: 02323

Syn* pot.nd Nauta LCL UCL R.PD

00128 .ntimony 84.00 110.00 25.00 00140 Arsenic 81.00 110.00 25.00 01605 Lead 84.00 110.00 25.00 02281 Selenium 76.00 110.00 25.00 02477 Thallium 85.00 110.00 25.00

-

Quality Control Limit Summary 524 313

QC rpe S MS-MSD Method: DQ Inductively Coupled Plasma (6010A) Location: 02 QUANTEP.RA TAMPA Program: 92 US AIR FORCE AFCEE (9/93) Extraction: All, non-specific extractions Matrix: S Solid LiBt: 02233

Syn# mpo Name LCL UCL RPD

02285 Silver 80.00 120.00 20.00 00088 Aluminum 80.00 120.00 20.00 00140 Arsenic 80.00 120.00 20.00 00194 Barium 80.00 120.00 20.00 00222 Beryllium 80.00 120.00 20.00 00413 Calcium 80.00 120.00 20.00

- 00411 Cadmium 80.00 120.00 20.00 00637 Cobalt 80.00 120.00 20.00 02952 Chromium 80.00 120.00 20.00 00643 Copper 80.00 120.00 20.00 01539 Iron 80.00 120.00 20.00 02214 Potassium 80.00 120.00 20.00 01618 Magnesium 80.00 120.00 20.00 01659 Manganese 80.00 120.00 20.00 01906 Molybdenum 80.00 120.00 20.00 02315 Sodium 80.00 120.00 20.00 0195E Nickel 80.00 120.00 20.00 01605 Lead 80.00 120.00 20.00 00128 Antimony 80.00 120.00 20.00 02281 Selenium 80.00 120.00 20.00 02477 Thallium 80.00 120.00 20.00 02607 Vanadìum 80.00 120.00 20.00 02649 Zinc 80.00 120.00 20.00

-

524 314

Appendix Tab

Quality Assurance Manual 524 3 15

Analytical Services Asbestos Analysis Quality Assurance/Quality Control Description of Policy and Programs

February 1995

OBRIEN&GERE LABOflATOIRIES, INC.

QUALITY ASSURANCE MANUAL ASBESTOS ANALYSIS

FOR

OBG LABORATORIES, INC. 5000 BRITTONFIELD PARKWAY

SUITE 4942 SYRACUSE, NEW YORK 13221

(315) 437-0200

Revision O: February 1995

i

524 316

u

5?1 317

CONTENTS

1. Statement of Policy . i

1.1 Quality Assurance/Quality Control Objectives .......................... I

1.2 Laboratoiy Policy on QAJQC ....................................... I

2. Organization and Responsibility ................................... 2

3. QA Limits for Precision and Accuracy .............................. 5

4. Sampling Procedures ............................................ 6

4.1 Sample Containers ................................................ 6

4.2 Holding Times and Preservative ..................................... 6

4.3 Shipment ....................................................... 7

5. SampleCustody ................................................. 8

5.1 Cham of Custody Procedures ....................................... 8

5.2 Control of Incoming Samples ....................................... 8

5.3 Scheduling ...................................................... 9

5.4 Sample Tracking ................................................ 10

5.5 Location and Disposal ............................................ 10

5.6 Sample Transfer ................................................. 10

5.7 Computer Services ............................................... 10

6. .AnalyticalProcedures ........................................... 20

6.1 Analytical Methods .............................................. 20

6.2 Waste Disposal ................................................. 20

6.3 Cleaning of Glassware ............................................ 20

6.4 Quality of Lab Water ............................................. 20

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524 318

7. Calibration Procedures and Frequency . 21

7.1

7.2 7.2.1 7.2.2 7.2.3 7.2.4

Instrumentation ................................................. 21

Calibration ..................................................... 21 TEM.......................................................... 21 PCM.......................................................... 21 PLM.......................................................... 21 Balances....................................................... 21

7.3 Standards ...................................................... 22

8. PreventiveMaintenance ......................................... 23

8.1 Instrument Maintenance .......................................... 23

8.2 Maintenance Log ................................................ 23 -

9. Quality Control Checks, Routines to Assess Precision and Accuracy and Calculation of Method Detection Limits ........... 24

9.1 Method Detection Ljjij ........................................... 24

9.2 Method Accuracy and Precision .................................... 24

9.3 Intralaboratory QAJQC Program ................................... 24 9.3.1 Defmitions of Basic Terms ........................................ 25 9.3.2 Analytical Errors ................................................ 26

9.4 Control Charts .................................................. 26 9.5.1 Precision QC Charts ............................................. 26 9.5.2 Accuracy QC Charts .............................................. 27

10. Data Reduction, Validation and Reporting ......................... 29

10.1 Data Reduction ................................................. 32

10.2 Data Validation ................................................. 32

10.3 Data Storage ................................................... 33

11. Corrective Actions .............................................. 36

Revision O: Februaiy 1995 O'Brien and Gere Laboratories, Inc. II

e

e

-e

-

12.

12.1

12.2

12.3

12.4

13.

14.

524 319

Performance and System Audits .................................. 38

Internal System Audits ........................................... 38

External System Audits ........................................... 38

Performance Audits .............................................. 3g

Certifications ................................................... 39

QualityAssurance Reports ...................................... 40

Resumes...................................................... 41

Revision #0: February 1995 OBrien and Gere Laborazories, Inc. u'

TABLES

524 3D

3-1 Methods and Detection Limits 5

9-1 Laboratory QC Checks and Frequency . 28

Revision #0: Februwy 1995 -

o 'Brien and Gere Laboratories, Inc. iv

2d 32!

- FIGURES

- 2-1 Organization Chart 4

5-I ChainolCustody Il - S-2a Sample Bottle Request Form ........................... 12

5-2b Sample Bottle Request Form .......................... 13

5-3 SampleLabel ..................................... 14

5-4 Case File Form ..................................... 15

5-5 Sample Log-In Form 16

5-6 Sample Control Form - Part i ............................. 17

5-7 Sample Control Form - Part 2 ............................ 18

5-8 PackagelSample Schedule ................................. 19 --

10-1 TEM Instrument Log ...................................... 34

- 1ó-2 PLMAnalysisLog . 35

11-1 CorrectiveActionLog .. 37

_, Revision #0: Februwy ¡995 O'Brien and Gere Laboratories, ¡nc. V

APPENDIX

A. State Certifications

Revision *O: Februa,y 1995

524 322

O'Brienand G - ere Laboratories, Inc. vi

524 323

- 1. Statement of Policy

- OTh-ieii & Gere Laboratories, Inc. (Laboratories) is located in the corporate headquarters of O'Brien & Gere Limited in Smcuse, New York. The firm is engaged in the analysis of friable and non friable bulk materials, water, and air samples for asbestos along with the chemica! and microbiological analysis of environmental contaminants in a variety of mairices. The ability of the laboratory to - -accurately identify and quantify these contaminants is important. The decisions or conclusions based on these data are only as good as the documented quality ofthe data. The purpose ofthis manual is to document the procedures used to verif' the high quality ofthe data.

1..! Quality Assurance/Quality Control Program Objectives

Quality control is the routine application of procedures used in the laboratoiy and in the field for controlling the measurement process. Quality assurance is the total program for assuring the reliability of field and analytical data.

The goal ofthe laboratory Quality Assurance/Quality Control (QAJQC) Program is to produce data of adequate quality and to provide documentation to verify these results. The data have adequate - quality ifthe data have consistency (precision) and the uncertainty is small when compared to specific requirements (accuracy). These objectives are accomplished through the use of quality control samples such as duplicates, blanks, replicates, verified counts, and knowns. Use ofthis program maximizes - the validity ofthe data. Thus, the data can provide a reliable foundation on which to base decisions.

- An effort of the QAJQC Program is to provide coñtrol charts and control limits for monitoring the - laboratozy's daily performance and to plot trends over a period of time. These charts provide documentation that data collected, reported, or used by the laboratory are of known precision and accuracy. The QAJQC activities performed at Laboratories are carried out in accordance th - established federal and state protocols.

1.2 Laboratory Policy on QAJQC

Laboratories fully supports the QAJQC program outlined in this manual. This program has been - implancnted and is maintained to demonstrate that data reported by the laboratory are ofkno and - documented quality. The technical and support personnel who contribute to any portion of the laboratory analyses follow the QAJQC procedures outlined in this manual.

- The QA/QC manual is an integral part ofmutine laboratoiy practice. The contents of this manual vill be reevaluated and revised regularly.

- Requirements listed in a Quality Assurance Project Plan will override this document.

\_/ Revision #0: February 1995 O'Brien & Gere Laboratories, ¡nc.

524 324

- 2. Organization and Responsibility

Any organization consists ofa number ofpeople whose skill and responsibilities determine the quality - ofthe fmal product. The product ofLaboratories is analytical services. The laboratory functions as a chemical Iaboratoiy only. Personnel have sufficient training in their appointed positions to contribute to the analysis and reporting of high quality data. The training is achieved through internal training, - experience, and selected specialty courses.

Figure 2-1 is an organization chart ofthe laboratory staff.

The senior vice president's responsibilities include the development and monitoring of the internal systems necessary to assure quality ofthe analytical data. His duties include the planning necessary - to support methods development and for the acquisition ofpersonnel and instrumentation.

The day-to-day scheduling and coordination is handled by the asbestos manager who reports to the - senior vice president. The manager monitors the daily work load and redirects the section resources to complete project deadlines. The manager coordinates and distributes the project information to the section staff and reviews the output to verify its completeness and techthcal acceptability.

The manager's responsibilities include verification that analyses are conducted thin contract holding times and implementation of corrective action procedures recommended by the QAIQC Coordinator. - The manager works with the QAJQC Coordinator to keep the quality control procedures accurate and up to date. Together the tuanager and the QA/QC Coordinator work on revisions of procedures. In addition, the manager coordinates with the client to answer any complaints or any questions related to

- the analytical requirements of the projects.

Project supervisors, who are part of the customer service group, are responsible for monitoring individual projects and project specific QC. They handle client contact and work with the section supervisors to coordinate sample receipt schedules and report turn around times.

Weekly, the manags, section supervisors and project supervisors meet to discuss the progress of in- - house programs, stafFing, the schedule of analytical programs, instrument problems, and analytical quality control. This information is also forwarded to the senior vice president for consideration and

- planning.

The QA/QC Coordinator is responsible for the implementation, monitoring, and supervision of the QAJQC program. The QAJQC Coordinator reports to the administrative manager. The QA/QC - Coordinator verifies that the analyses are conducted in strict adherence to the procedures set forth in this manual. The QAJQC Coordinator's duties include:

- . Developing and implementing new QA/QC programs, including statistical techniques and procedures . Conducting regular audits and inspections of analytical procedures and applications

- s Daily monitoring of analytical parameter accuracy and precision . Discussing necessary corrective action procedures with the laboratory manager

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524 325 -

s Generating control charts and setting control and warning limits

-i-- Advising management of the status of the QAIQC program and giving recommendations for improvement

s Writing, submitting and updating Quality Assurance Plans

The sample custodians, who are part ofthe support stnfi are responsible for initiating chain of custody procedures. Upon receipt ofsamples, they vexify that the samples have been properly collected. After - receipt of samples, they are responsible for keeping them in a secure and restricted location.

Laboratories has a safety officer who is responsible for the distribution of the safety manual and the - scheduling ofsafety training sessions for new employees. The safety manual outlines safety policies, procedures, and guidelines. The safety officer, the section supervisors and the manager meet periodically to review the safety manual and update it as necessary.

-

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Figure 2-1

Organization Chart

OBG LABORATORIES ORGANIZATIONAL CHART

Plymouth Misting M.N. P.ttstiITh AthmristTativi Msnsgs

I OADC Ì iR.di*us

E.C. Tuft Ph.D

President

D.R. Hill

lot Vice President

S. Kaczmar Ph.D Vice President

L. Reichel UMS

D. R.H;uI M. G.rbe Org.nci M.n.gur Inorgsnl Man.ge

I I I Suppo.1 I CC/MS

I GC1 IMbestuil IWetChem

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524 32?

- 3. QA Limits for Precision and Accuracy

- The following table lists the detection limits and methods used in the laboratory.

Detection limits for airborne asbestos analysis depend on the volume of air collected. Therefore detection limit for airborne asbestos analysis by phase contrast microscopy is listed in units of - fibers/mm2.

hi the case of airborne asbestos by transmission electron microscopy or waterborne asbestos by transmission electron microscopy, minimimi detection limits are specifed by the method. In both cases,

- adequate grid openings are analyzed to achieve these detection limits.

- Table 3-1 Methods and Detection Limits

Method Matrix Detection Limit

EPA 600/4-83--043 Waterbome 10 MFL >O.5i.im . 0.2 MFL > 10pm

- Federal Register, Appendix A to Subpart E, Interim Airborne (TEM) 0.005 struc/cc Transmission Electron Microscopy Analytical Methods - Mandatory and Norimandatory - and Mandatory Section to

- Determine Completion of Response Actions

NIOSH 7400 Airborne (PCM) 12.7 fibers/mm2 Federal Register, Appendix A, 29 CFR I 926.58, OSHA Reference Method - Mandatory

EPA-600/M4-82-020 Friable Bulk i . % ELAP198.1

ELAP 198.1 Non-friable Bulk 1. % ELAP 198.4

-

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4. Sampling Procedures

A criLical conccm in any project, especially those where a large number of samples are required, is the - maintenance of sample integrity. A sample is physical evidence of a situation in the environment at a specific place and time. Therefore, an essential part ofsampling projects is proper collection and handling of the samples. Representative samples are collected through well-defmed protocols. The - client performs most ofthe sampling and thus assumes responsibility for properly obtaining, handling, and shipping the sample. If Laboratories is requested to collect samples, a well defined sampling protocol is followed. This sampling protocol includes the following elements:

. Sampling team members are competent and qualified . Proper sampling methods are used in the collection of a representative sample - . Equipment is accurately calibrated s Samples are properly handled to prevent contamination from outside sources or cross

contamination between samples, je, bulk samples are shipped in a separate container from air - samples . Samples are properly identified . Samples analyzed are the samples collected under reported conditions.

Laboratories does not routinely provide sampling services. The lab will give recommendations for proper sampling plans. Sampling Will be sibcontracted with a sampling pian being provided by the subcontractor.

4.1 Sample Containers

The laboratory, on occasion, will send out sample containers for the collection ofwaterborne asbestos samples. Since a preservative is not added to the sample containers for waterborne asbestos, it is

- imperative that samples be received by the laboratoty within 24 hours 0f collection. The client is responsible for verifying that the proper containers were received.

- Each sample is collected in a new, pre-cleaned container to minimize contamination.

4.2 Holding Times and Preservatives

- Laboratories follows the holding time requirements outlined in the method being utilized. Holding times vary depending upon matrix, protocol, and regulatoiy requirements. Expedient delivery and scheduling are paramount to obtain compliance wi± holding times. The LIMS assists in the - monitoring of holding times by incorporating a due date on the schedule queue. The analysts, when reviewing their schedule, are aware not only of the workload, but also of holding time requirements.

- If samples are received over their holding times, the client is notified so that resampling can be scheduled.

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4.3 Shipment

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Sample containers are shipped in coolers to the clients by common carrier or are picked up at the lab by the client. Glass bottles are wrapped in styrofoam to prevent breakage. Containers are put into - plastic zip-lock bags to prevent cross contamination or leakage in case one or more of the containers should break during shipment. When the samples are returned to the lab, they are repacked into the coolers in the same manner in which they were shipped and crushed ice is added to maintain the - temperature at 4° C. Jars are wrapped in styrofoam sheets and put in plastic bags to help prevent breakage and cross-contamination.

Laboratories adheres to regulations governing the shipment ofhazardous materials.

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524 3O 5. Sample Custody

- 5.1 Chain of Custody Procedures

The Iaboratoiy follows a strict chain of custody procedure. This procedure creates an accurate and legally defensible document that can be used to trace possession of a sample from its collection through analysis and fmal disposal. The chain ofcustody form is signed by all handlers ofthe samjile. An example ofa cham ofcustody is included as Figure 5-1.

A sample is considered in custody if it is:

. J_n actual physical possession - . In view after being in physical possession . In a locked repositoiy s In a secure, restricted area

Formal custody begins with the shipment of pre-cleaned properly preserved containers. The client contacts a project supervisor for sample bottles and the project supervisor submits a forni requesting - the proper containers to the sample custodian. An example of the sample bottle request form is included as Figures 5-2a and 5-2b. After the request is completed and signed, the form is filed in a binder and kept in the sample tagging room for Ititure reference.

Chain of custody forms are shipped with sample bottles. The field sampler/client is responsible for - filling in the sample location, date and time sampled, sample matrix, and analysis required on the cham - ofcustody. The field sampler signs the chain ofcustody when relinquishing custody and includes the form with the sample containers. Any comments that the sampler has are also listed on the chain of custody form The field sampler is also responsible for filling in the sample labels that are present on - every sample bottle. An example ofa sample label is included as Figure 5-3.

5.2 Control of Incoming Samples

Laboratories employs several sample custodians who arc responsible for verifying the receipt of samples. When samples are received, the sample custodians follow the steps outlined below.

Packages are checked to verif,r that the samples listed on the chain of custody were received. A notation is made of any missing or mislabeled samples.

2. Samples are checked and a notation is made of any samples that were recei'ed broken or damaged, or ifbulk samples were shipped in the same container as air samples.

- 3 . The Chain of Custody is signed and dated to verif' time of sample receipt.

4. Each sample is assigned a unique laboratory identification number to make tracking of samples - easier. Numbers are assigned sequentially. Each project is also assigned a unique project number that contains the client ID andjob number.

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5. Samples are logged into the UMS and the analyses are scheduled

The observations of the sample custodians and any comment that they have are noted on the chain of custody form or on the case file form. An example of the case file form is included as Figure 5-4. - Samples are not routinely rejected by the laboratoiy. When problems arise the client is notified of the deficiency and a decision is made to continue or resampJe. The decision is noted on the final report.

- The sample custodian tags each sample with a unique laboratory sampk number that is input into the computer and recorded onk the sample log-rn form. An example ofthe sample log-in form is included as Figure 5-5. The sample log-in form is filed in a three-ring binder and functions as a sample receipt - logbook.

The chain ofcustody effort is intensified at the request ofthe client. The intensified procedure starts - with the use ofred evidence tape in the field. Each container is sealed with the tape at the sampling site and shipped in sealed containers to the laboratory. When the samples are received by the laboratory, the condition of the sealed containers is recorded on part one of the sample control record and the laboratory numbers are assigned. An example of part one of the sample control record is included as Figure 5-6. Samples th red evidence tape must be signed in and out of the locked secured cooler using part two of the sample control record. An example of part two of the sample control - record is included as Figure 5.7.

Samples are stored in the asbestos laboratory.

Any eior made while completing the chain of custody forms are corrected by deleting the entry with one line through it, correcting the error, and dating and initialing the correction.

5.3 Scheduling

- The purpose of scheduling is to notify the manager, section supervisors, chemists and technicians of the arrival of a sample and the tests to be performed.

Analyses are scheduled on the LIMS by the sample custodians. A package/sample schedule is printed - for every batch ofsamples received. An example ofthe package/sample schedule is included as Figure 5-8. The analysts use the package/sample schedule to identify what samples they are required to analyze. The section supervisors review the package/sample schedule with the analysts to ensure - priorities and holding times are being met.

5.4 Sample Tracking

Our tracking system relies on project numbers and sample numbers. Therefore, laboratory sample numbs and client ID numbers are recorded on raw data and preparation logs. Samples are primarily tracked using the laboratory sample numbers. Project status is tracked using project numbers and sample numbers.

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5.5 Location and Disposal

Samples are stored in asbestos Iaboratoiy. Unless otherwise requested by the client, phase contrast samples are discarded immediately afier analysis has been completed. Bulk samples for polarized light - microscopy and airborne asbestos samples for transmission electron microscopy are retained for a period ofsix months before being discarded in an appropriate manner. Waterborne asbestos samples are retained for a period ofone month after analysis has been completed.

5.6 Sample Transfer

- If analysis ofthe samples is not possible at Laboratories, then the samples will be subcontracted to another approved laboratoiy. The samples will be packed in appropriate containers and shipped by common carrier or delivered by Laboraoiy personnel. A chain of custody listing Laboratories sample - number, sample preparation date and tests required will accompany the samples.

5.7 Computer Services

Laboratories has a UMS system in place. The system is used for scheduling, reporting and QC purposes.

.- The project supervisors are responsible for verifying that samples were scheduled properly. It is up to them to approve and distribute the sample schedule so that it-will appear on the proper woridists.

The QA/QC Coordinator is responsible for veriing that the QC data was input properly and that it is being calculated properly by the computer. Whenever control charts are printed or control limits - generated, the information is checked for accuracy.

Each analyst has a unique sign-on code and all data that they enter in the data base is associated sith - their sign-on code. A password has to be entered to gain access to the data base. System management also has several passwords that need to be entered in order to garn access to programs that allow changes to be made to the data base.

- A full backup of the data base is done weekly and a partial backup is done daily in order to protect against data lose w case of a system failure.

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O'Brien & Gere Laboratories, Inc.

FigureS-1

Chain of Custody

DBRIEN5GERE CHAIN OF CUSTODY RECORD

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524 333

METHOD OF SNIPMENT:

O3ttTN 5 GFE LA3ATDRIES. NC. w OBI... & G.. Ccmpw Pa,kwly PO. Bo 942 Sy.a. NV IOfll / )31$ 437.0200 FAX (315) 483.7554

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Figure 5-2a

Sample Bottle Request Form

OBRIENEGERE O'Brien I Cere Laboratnries, Lnc. LA3CtWD . Seapi. Container Request Fora

PROGRA1 INFOMION Cli.nt/ Coapany Nasa Div. Affiliate:

Proj act Eng.

Progrs or Program Title Survey:

Na. of Sampler Level of QC Docuent- 1 2 3 4 5 6 7 (circl, on.) ation

SAMPLE BOTTLE P: ARATO

Seinples: sites Matrix lysj Reauir.d

Bottles:

Bottle Typ.:

No. of Size of Glass or Analysis Bottles Bottle Plastic Preservativa

Standard T Ches (Check One)

(mor. information required an back)

524 334

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5

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Figure 5-2b

Sample Bottle Request Form

3jìpping and BxJ.i.ng Inornat.on

Address: Shipping ail.ing P.rsor

Company_________________________ Street__________________________ City/St./Zip

Telephon.I

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Method o.f Picktp Regular 2 Day Overnight Shipment Day: Du. Oat. Date:

Time:

Who will OBG Laboratories, tnc. (any method e Poy rr.ight Client record client job treight other

I under shipping address) than routine mail is paid by the Client)

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.abcratory Approval, and Siqnatures

Submitted By:_______________________ Date Submitted:______________________ Approved By: 05G Project Nc:______________________ Prepared By: Date Sent:

w-

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524 335

O'Brien & Gere Laboratories, Inc. 13

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Figure 5-3

Sample Label

Sample Descripflon:

Initials:______________________ _______________________________

Sample Date: Sample Time:__________

Project No.:______________ Lab No.:______________

Date Received__________ Time Received:

Preservaflon:

524 336

s

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524 337

Figure 5-4

Case File Form

ODa t,.aoaroxs, tc. SE PIlZ POIX

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Client: ___________________ Div. Raf. No. _____________ Program: - Location: City/Town Stat. _____________________ Date Racd: Tie. Recd: Sajiipler: Cuetody Seal: Intact Not Intact NA

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IELJzDAD p SEOIITY OU TO C.LE DATE TIME OElYlO I? MU OTIAlT DATI TIME

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2Z8OL'TION/CLItNT CO)OMT

Project Manager Approval: Date: ____________________ QA/QC Approval:

IP.MPII DIPOBAL Dispcaal Procedure:

- Signad: Date:

Revision #0: February ¡995 &Ènen & Gere Labora:or,e.y, Inc. 15

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--i Revision #0: Febnsary 1995 O'Brien & Gere Laboraiories, ¡nc. 16

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6. Analytical Procedures

524 342

6.1 Analytical Methods

A list of analytical methods used in the laboratoiy is included in Appendix B. Method numbers are cited from the following manuals:

U.S. EPA, Federal Register, 4OCFR, Part 136, (1-1-87 edition). U.S. EPA, Federal Register, Appendix A, 29 CFR 1926.58. New York State Department of Health, Environmental Laboratory Approval Program - Certification Manual. NIOSH - NIOSH Manual of Analytical Methods, Fourth Edition.

6.2 Waste Disposal

Laboratory workers are trained to be cautious when handling samples, spent chemicals, toxic, or dangerous materials. Laboratories has a hazardous waste officer who is responsible for coordinating and overseeing the disposal of waste and the cleanup of any accidental spills. The laboratory has a - hazardous waste room where waste is stored in DOT- approved 55-gallon drums until disposal. Laboratory hazardous wastes are manifested and disposed off-site at NYSDEC- and U.S. EPA- approved disposal facilities.

The method of sample disposal depends on the analytical data generated. The results are compared to RCRA criteria and local disposal ordinances and a decision is made in coordination with the hazardous waste officer as to the means of disposal. If the sample is classified as hazardous, it is placed in the appropriate drum in the hazardous waste room. Upon filling the drum, the hazardous waste officer manifests the drum, arranges for disposal and files the disposal logs.

6.3 Cleaning of Glassware

Glassware is cleaned in an Alconox solution. It is then rinsed with tap water followed by DI water and -allowed to dry. Glassware is stored inverted in drawers or a cabinet in the asbestos lab.

6.4 Quality of Lab Water

Deionized (1)1) water filtered through a 0.2 micron filter is used for asbestos analysis.

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524 343

7. Calibration Procedures and Frequency

7.1 Instrumentation

Laboratoties maintains state-of-the-art instrumentation. The fo1loing equipment is currently in use:

- One Philips CM-12 transmission electron microscope equipped with an EDAX PV9800 x-ray detector.

s Two Olympus BH-2 polarized light microscopes. - . One Nikon Labophot-Pol polarized light microscope. . Six Olympus CH-2 phase contrast microscopes. s One Dcnton Vacuum DV-502A Carbon Coater. - s One BioRad PT7150 RF Plasma Barrel Etcher. s One Mettler AEIOO analytical balance,

- 7.2 Calibration

Accurately calibrated instruments are a major concern at Laboratories. A brief explanation of the çalibration procedures used at Laboratories is summarized below. Detailed calibration procedures are described in the laboratoiy Standard Operating Procedures, which are available for procedures used in the laboratory.

7.2.1 TEM - Evy day that the TEM is used, the instmment is aligned, and the response of the x-ray detector - for silicon and iron is checked by analyzing an amosite standard. On a monthly basis the magnification and the camera constant are determined. On a quarterly basis the spot size is determined, and the beam current checked. Also on a quarterly basis, the x-ray detector

- response for the sodium peak in crocidolite and the magnesium and silicon peaks in chiysotile are checked. On a semi-annual basis the x-ray k-factors and resolution for manganese are determined

- 7.2.2 PCM

- The resolution, diameter ofthe graticle, and the centering ofthe phase rings is checked every

u-, day that the phase contrast microscopes used.,

7.2.3 PLM Every day that the polarized light microscopes are used, the iris and condenser diaphrams arc - focused and centered, the alignment of the polarizers and the crosshairs are checked and the objeclives arc centered. On a monthly basis the dispersion staining colors for amosite in 1.680

- EJ liquid are determined.

7.2.4 Balances Analytical balances are professionally calibrated and cleaned once a year. When the balanoes - are professionally calibrated, a document stating the specific balance model and serial number and the date calibrated is provided by the company doing the calibration. The balances are

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24 34

- checked dailyvith Class S weights. The weights mustread withn O.O5% ofthe iruevahe. 1f

-=-.Í_.#. the weight is out of the control limits, it Will be professionally recalibrated. The analyst performing the check, the date the balance was checked and the weights at which the balance

- was checked are recorded in a laboratory notebook.

7.3 Standards

Reference standards are obtained from third party sources such as NIST. In addition, performance evaluation samples are retained for use as knownslstandards.

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8. Preventive Maintenance

8.1 Instrument Maintenance

The lab has maintenance contracts on most major pieces of equipment. 1f the lab experienoes a - problem ith an analytical instrument, a serce call is made, and a certified technician is sent to correct -

the problem. The analysts are also trained in '1troubleshooting' their instruments to determine if outside assistance is needed.

w Routine maintenance as outlined by the manufacturers are followed on laboratory instrumentation.

1n the event of equipment failure, in tuost cases there is an alternate piece of equipment that can be - substituted. If there is no alternate equipment available, the sampling will be delayed if possible, or samples will be subcontracted to an alternate approved laboratory.

- 8.2 Maintenance Log

Maintenance logs are kept on every instrument in the lab. The logs are located near their respective - instrumenIs Maintenance, ether performed by laboratory personnel or by professional maintenance personnel, is documented as an entry in the appropriate logbook. Entries include the reason for maintenance, maintenance that was performed, individual performing the maintenance, the date of - maintenance, and the initials of the analyst in charge during the maintenance.

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- 524 3

9. Quality Control Checks, Routines to Assess Precision and Accuracy, and

Calculation of Method Detection Limits

When analyzing samples, the accuracy and precision ofthe data generated are determined through the analysis of duplicates, rep1cates, knowns, and field and laboratory blanks with each set of samples. In addition verified asbestos analysis is performed for airborne asbestos by TEM. Results of QC samples are charted against established limits.

9.1 Method Detection Limits

In the case ofbu]k asbestos analysis, dettion limits are established by the method. For phase contrast analysis, the detection limit is dependent on the volume of air collected. A minimum detection limit is specified for both airborne TEM and waterbome asbestos analysis and adequate grid openings are analyzed to achieve these detection limits.

9.2 Method Accuracy and Precision

Method accuracy is the ability Lo determine that the measurement of a known reference standard will be acceptably close to the defmed true value. This is measured by the analysis of a lcnownH. The result ofthe known sample must meet established criteria. A known not meeting criteria signifies an "out ofeontrol" situation and requires corrective action.

MethOd Precision is the ability to limit the spread of duplicate measurements performed by the same analyst (duplicates) relative to their average in a manner which approximates the bell-shaped nonnal - distribution. The analytical method precision is determined by reanalyzing a sample. Ideally, the analytical results will be identical; however, differences occur due to variations in the procedure. A quantiwive measure ofthese differences is assessed by determining the absolut.e differences between - duplicate results. In addition, method precision is checked by the reanalysis of a sample by a different analyst (replicates). Samples which do not meet laboratory established criteria signify an "out of control" situation and corrective action is rcquired.

9.3 Intralaboratory QAIQC Program

One ofibe main goals ofthis QAJQC manual is to establish guidelines for intralaboratoiy QC (QC that is performed within the ]aboratoiy). In addition, this manual provides a mechanism where QC procedures can be documented for review. - A quality control program is a systematic attempt to maintain the precision aiìd accuracy of analyses by detecting and preventing the recurrence of errors. By identifying the sources of errors, confidence

- in the precision and accuracy of analytical results can be established, and improvements in the analytical methods can be made.

In general, Laboraioiics quality control program incorporates the concepts of: a) calibration to attain accuracy, b) duplication and replication to establish precision limits, and c) use of Iaowns to confirm accuracy.

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524 34

Table 9-1 contains a list of laboratory QC checks and the frequency at which they are done. 1f method QC requirements are more stringent than the routine measures typically followed, the method QC requirements will be followed.

- 9.3.1 Definitions of Bask Terms

There are some basic terms that are frequently used when discussing asbestos QA/QC. Below are the defmitions of some common terms.

i . Laboratory Blank - The laboratory blank is a filter which is prepared and analyzed in the same - manner as the samples. These blanks are analyzed along with the samples to verify that: a) no false positives occur, and b) results are accurate and do not reflect contamination.

- 2. Field Blank - Field blanks are collected to determine the extent ofcontamination in the handling ofthe filters in the field. In the case ofPCM analysis. they are treated in the same manner as the field samples. Field blanks are not routinely analyzed in the case of airborne TEM analysis.

3. Filter Lot Blanks - Filter lot blanks are prepared and analyzed to determine if filters are contaminated in the manufacturing process. One percent ofnewly received cassettes are marked

- with the manufacturers lot number and submitted for analysis.

4. Duplicates - Duplicates are the reanalysis of a field sample by the saine analyst. The results of duplicate analyses provide information on overall precision of the analytical methodology. - Quantitative results are obtained by calculating the absolute difference ofthe samples.

-', 5 . Replicates - Replicates are the reanalysis of a field sample by a different analyst. The results - of replicate analyses provide information on overall precision of the analytical methodology. Quantitative results are obtained by calculating the absolute difference ofihe samples.

- 6. Knowns - A known is a performance evaluation sample which is routinely analyzed by the laboratory as a measure of overall accuracy. Results for a known are compared to the acceptable results for that performance evaluation sample.

7. Verified Asbestos Analysis - Verified asbestos analysis is a procedure in which a TEM grid opening is independently analyzed for asbestos by two or more TEM operators and in which a comparison and evaluation ofthe correctness ofthe analyses are made by a verifying analyst.

8. Performance Evaluation Samples - A set ofsamples sent to the laboratoiy by a certifying agency - to be analyzed. The Iaboratozy is unaware of the concentration of asbestos in the samples and the results must fall within certain limits. Up to ten sets of Performance Evaluation (?.E.) samples are analyzed per year (For example for PCM analysis: PAT's - quarterly, AAR's -

- quarterly, ELAP's - semi-annually). IfP,E. sample analysis is unacceptable, responses will be reported in a QA report if required.

9. Interlaboratory Exchange - Routinely, samples analyzed by the laboratory are submitted to an independent laboratoiy for reanalysis as a measure of accuracy. Results are evaluated and discrepancies are resolved between the laboratories.

- \.0 Revision # O: February 1995 0 Brien & Gere Laboraties. Inc.

25

524 34

9.3.2 Analytical Errors

- The laboratory is dedicated to minimizing errors that cause inaccurate results. There are three types of errors: determinate indeterminate, and systematic. Determinate errors are caused by improper - technique such as contamination. Indeterminate errors are those in which no cause can be assigned. Systematic errors are a bias common to a sequence or batch of results frequently induced by an indeterminate or determinate enor.

QC data is plotted on a daily basis and results are compared to established criteria to minimize out of control situations and analytical errors, Thcanalysts are familiar with the methods they are running, - and can detect when calibration standards and QC checks are not providing the proper results.

Errors are reduced by properly training the analysts and having written standard operating procedures

- for the analysts to use. The anaysLs are trained in good laboratory practices. Every effort is made to keep contamination to a minimum. Blanks are run with every group of sampks to check for contamination from glassware or standards.

9.4 Control Charts

- Control charts provide the necessaiy tools for detecting quality variations in the various analytical methodologies used. They are a continuous graphic indication ofthc state ofan analytical procedure with respect to quality. Control charts indicate when corrective action procedures are necessary and

- often assist in defming what corrective action procedures should be taken.

The control limits on QC charts set the criteria for assessing the significance of variations in the cal results. When the plotted QC data fall within these limits, the analytical methodologies are -

considered under control. Ifa data point falls outside the control limits, there is an indication that some assignable cause is present which has thrown the system out of conirol.

- Control limits can be considered action limits. They enable the laboratory to detect significant deviations in analytical procedures and to take corrective action before producing erroneous results.

- 9.4.1 Precision QC Charts

Precision QC charts are used for graphing the absolute difference ofduplicate and replicate samples. The charts are developed using up to 50 data points, depending on how often the parameter is analyzed by a pazlicular method. Once these data points have been collected, the warning and control limits on the QC charts are calculated by using the following method:

i . For each pair of duplicate/replicate samples calculate the absolute difference. 2. Calethemeanabsoluedîfferencebysummingthe absolute differences and divide - by the total number (n) ofduplicate sets. 3. Calculate the standard deviation (s). 4. Calculate the wanting and control limits.

t.'- Revision #0. February 1995 O'Brien & Gere Laboratories, Inc. 26

524 349

- TJCL - Absolute Diff. + 3s --

TJWL - Absolute Diff. 2s

- LWL . Aso1ute .Diff. - 2s

LCL - Absolute Diff. - 3s

- The LCL is always zero since it is impossible to have a negative RPD.

9.4.2 Accuracy QC Charts

Accuracy QC charts are used for graphing the results ofknois. The control limits are based on the results for the individual performance evaluation samples.

-

Revision #0: February 1995 O'Brien & Gere Laboratories, Inc. 27

524 3

- Table 9-1 Laboratory QC Checks and Frequency -

Laboratory Section QC Sample Frequency

- PCM Known Daily Duplicate 5% Field Blank Every batch Interlaboratory Exchange Quarterly - P.E. Samples Up to ten/year

PlM Duplicate 5%

- Replicate 5% Interlaboratory Exchange 0.5% Blank Daily P.E. Samples Up to eightfyear

NOB Duplicate 10% Known Each batch Blank Each batch - Interiaboratory Exchange 0.5% P.E. Samples As submitted

- TEM - Airborne Duplicate 5% Replicate 5% Verified Count 0.5% Laboratory Blank 10% - (4% analyzed) - Interlaboratory Exchange 0,5% P.E. Sample Up to fourlyear

-w' TEM - Waterbome Duplicate 5% Replicate 5% Verified Count 0.5% Laboratory Blank 10% - (4% analyzed)

- P.E. Sample Up to four/year

Revision #0: Febnuny 1995 O'Brien & Gere Laboratories, Inc. 28

10. Data Reduction, Validation and Reporting

524 35

10.1 Data Reduction

Data is generated from several different sources (scientific equipment, manual calculations, or computer generated). Most ofthe raw data is stored in hardcopy form and calculations are done to generate a fmal result. In several instances, the bench chemist performs calculations in a laboratory notebook and transfers the 1mal result onto the laboratory report form.

Calculations are either performed manually or by computer programs. Calculations are performed according to the method employed. They are based on sample matrix, method detection limits and dilutions or concentrations that may have been done. A briefdescription ofsome calculations used - follows:

1. Volume for PCM analysis:

Volume - Flow Rate X Time

Where: Flow Rate is in liters/minutes Time is in minutes -

2 Average Count for PCM analysis:

Avg- C - Fibers

Fields

- Where:

. Avg Ct = Average count for sample. Fibers = The total nUfllbCT offibers counted. - Fields = The total number offields counted

__, Revision #0: February 1995 O'Brien & Gere Laboratories, ¡nc. 29

524 3

3 Fibers/cc for PCM analysis:

Fibers/cc (Avg C - Bik Ct..) X (Filter Area)

Volume X Field Area 1000

- Where: Avg Ct = Average count for sample. Bik Ct = Average count for blank. - Filter Area = The area ofthe filter in mm (Generally 385 mm2).

Field Area The area ofthe graticule field in mm2 (Generally 0.00785 mm). Volume = Volume of air collected in liters.

4 Fibers/mm2 for PCM analysis:

Fibers/mm2 Avg Ct

Field Area

Where Avg Ct = Average count for sample. Field Area The area ofthe graticule fields in mm2 (Generally 0.00785 mm2).

-, 5 Structures/cc for ThM analysis:

s x FA Struc/cc -

GO X GA X Vol X 1000

- Where: si = Total number ofstructures in the sample. FA = The effective filter area in mm2. - GO = Number ofgrid openings analyzed. GA - The area of the grid opening in mm. Vol = The volume of air collected in liters.

__I., R,vision O: Februa'y 1995 O'Brien & Gere Laboratories, Inc. 30

524 3

6 Structures/mm2 for TEM analysis:

g strzicJmm2

GAXGO

- Where: Si : Number of structures counted GA = The area ofthe grid opening in mmi. - GO Number ofgrid openings analyzed.

7 Z-Test:

z- 0.8 X/(1/N1 + 1/N)

- Where: Y = The average of the natural log of the indoor sample asbestos concentration.

= The average ofthc natural log ofthe outdoor sample asbestos concentration.

- N = The total number ofindoor samples. - The total number ofoutdoor samples.

- s Percent combustible material for NOB analysis:

w-w % Cornbusib1e Maberial 100 x 2 3

w2-w1

. Where: w3 = Weight of crucible with ash.

'2 Weight ofcrucible with NOB material - WI Weight of crucible

Rri'Ision 4tO: February 1995 O'Brien & Gere Laboratories. Inc. 31

524 35

9 Percent Acid Soluble Material for NOB analysis:

-'II-- w-w % Acid Soluble Materia2 - 100 x

- Where: w5 = Weight offilter paper with dissolved ash. w4 = Weight oflilter paper. W2 Weight of crucible with NOB material WI - Weight of crucible

10 Percent Asbestos for NOB analysis:

w5 - w4 % Asbestos - P x

w-w1

- Where:

PI = Percentage asbestos as determined from the PLM or TEM examination. w5 = Weight of filter paper with dissolved ash. - w4 = Weight of filter paper. w2 = Weight of crucible th NOB material

- w = Weight of crucible

Other calculations perfomied in the laboratoty are similar in nature.

- Raw datais labeled with the sample number and date analyzed. An insirument log book serves as a table of contents for each analytical run. An example of an instrument log book sheet for ThM analysis is included as Figure 1 0-1 . An example of an analysis log sheet for PLM analysis is included - asFigurelO-2.

The analysts are responsible for transcribing the final results onto the preliminary laboratory report - forms for the test parameters that they analyze and documenting the analyses in the appropriate logbooks. The analysts are also responsible for entering their analytical data into the LIMS.

- 10.2 Data Validation

The first step ofthe data validation process is when QC data e entered onto the appropriate forms, - The analyst compares the results to the established control limits. The analyst informs the section supervisor of an out-of-control situation and the section supervisor insures that the analyst takes corrective action. Sample results are not reported until QAJQC criteria have been met.

- The QAIQC Coordinator reviews QC results monthly to verify that corrective measures are being taken

. and documented.

Revision #0: Februaiy 1995 O'Brien & Gere Laboratories, Inc. 32

524 3

-.'I-. The second step is after the data had been entered into the LIMS system. The data is checked by the section supervisor in charge ofthe Iaboratoiy section that generated the data. The section supervisor checks calculations, raw data, and QC samples. Any errors detected are reviewed with the analyst who made the error.

10.3 Data Storage

A copy ofthe naI laboratory report is retained by the laboratory. Laboratory reports are filed by client ID number and project number. This allows for data belonging to a specific client and project 'to be - filed together. Reports are kept at the laboratory for one year and are then stored at an access-restricted warehouse.

The original chain of custody forms and case file forms are filed with the final report. 11 the client requested specific QC be performed, copies ofthe QC will also be filed with the report.

Revision #O: February 1995 Q'9,jt!, & Gere Laboraiories, Inc. 33

524 356

Figure 10-1

TEM Instrument Log

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Revision 140: February 1995 O'Brien & Gere Laboratories, ¡nc. 34

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PLM Analysis Log

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Revirion #0: Febniay 1995 O'Brien & Gere Labo rato ri es, In c. 35

524 35

11. Corrective Actions

QC samples must meet established criteria. 1f they fail to neet these criteria, corrective actions are takea lithe alignment fails to meet QC criteria, the problem is located and corrected and the system realigned. Samples cannot be analyzed until the alignment meets the QC criteria. if duplicates are out of control, the data may be rejected and the samples reanalyzed. Alternatively, the sample data may - be accepted, depending upon many circumstances. The client is notified if QC data fails criteria and ultimately makes the decision on whether or not to accept the data. Ifthe data are accepted, they are marked with qualifiers to document that the QC did not meet established criteria.

The analyst who s responsible for running the samples is the first to assess the quality of the data. 1f

a problem is detected. the section supervisor is immediately notified. The quality ofthe data is also - checked by the section supervisor, followed by the QAJQC Coordinator, the project supervisor and the laboratoiy manager. Tfsamples need to be reanalyzed, the section supervisor is first consu1ted and the procedure is rescheduled. The analyst will compare the new result with the old one and note any - differences. The results are then discussed 'vith the section supervisor. If the new results meet the QC criteria, the results are then reported. If QC criteria still are not met, the results are reviewed with the project supervisor, the QA/QC Coordinator, and the client. A decision is then made to accept the data - or to resample. The decision-making process varies depending on the type ofproject and the ulthnate use ofthe data.

- JfQC data fails any ofthe limits, a corrective action log is filled out by the analyst and signed by the section supervisor, the QAJQC Coordinator and the project supervisor. A copy of a corrective action

-, log is included as Figure 1 1-1. The corrective action logs are then filed in a three-ring binder and kept

- in the laboratory.

Revision #0.' Februevy ¡995 O'Brien & Gere Laborazoñes, Inc. 36

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12. Performance and Systems Audits

12.1 Internal System Audits

An intcrnal audit is performed quarterly on each section of the Iaboratoiy for overall adherence to the guidelines and procedures outlined in this manual. Laboratoiy notebooks are checked to veri1 - signatures and dates. QC samples are checked for the proper frequency and compliance with established control limits. Proceduresarc revìcwed to verify compliance with specific methods and SOPs.

The QA/QC Coordinator is responsible for scheduling each audit. The results of the audit are discussed with the section supervisors and the manager. Changes or updates are implemented as - needed.

12.2 External System Audits

External system audits are performed yearly by several certifying agencies including New York State Department ofHealth, and the National Voluntary Laboratoiy Accreditation Program. Some audits - are unannounced, while others are scheduled in advance. The laboratory will allow audits, either planned or unplanned, during normal business hours.

-

Any excursions or deficiencies that are noted during an external audit, are resolved to the satisfaction ofthe agency conducting the audit. A copy ofthe audit report and our responses to the deficiencies are

-,,- kept on file in the laboratory. .

- 12.3 Performance Audits

- The laboratoiy also participates in the analysis ofPerformance Evaluation (P.E.) Samples. These are sent out up to ten times a year by many certi1ing agencies. Results must fall within certain limits in order to be acceptable. It is by successfully completing the P.R sample analysis that the laboratory obtains certification to perform sample analysis. The P.E. sample analysis also serves as a means of - comparison with other laboratories performing similar work. The laboratory participates in the following P.E. studies:

- 1. NewYork StateDepartment ofHealth Asbestos inWater and/or Air by TEM Proficiency Tests,

Fibers in Air (PCM) Proficiency Test, and Asbestos in (Bulk) Friable Material (PLM) Proficiency Test - 2. American Induatzial Hygiene AssociationAsbcstcs Analyst Registry and Bulk Asbestos Quality Assurance Program

3. National Institute for Occupational Safety & Health Proficiency Analytical Testing Program - 4. National Voluntaiy Laboratory Accreditation Program Bulk Asbestos Analysis and Airborne Asbestos Analysis.

- Data related to the P.E. sample analysis and the results ofthe analysis are maintained by the lab and filed in binders according to agency administering the P.E. samples. Ifany parameters are failed, the

- ReW;ion O: February 1995 O'Brkn & Gere Laboraiories, inc.

38

524 36

problem is investigated and an explanation/corrective action is 'iitten up and filed with the PE sample results.

12.4 Certifications

Appendix A is a table listing the agencies with which Laboratories holds certifications. Complete certification information is available from the laboratory.

Revision #0: Februaty 1995 O rBrien & Gere Laboratories, Inc. 39

13. Quality Assurance Reports

524 36

The QA/QC Coordinator is responsible for making periodic reports to management concerning QA - activities. Thesereports serveto documentlabpersonnel adhercn to QA requirements and to discuss any updates or changes necessary to the QC program. There are informal oral reports and formal written reports. Oral reports are given weekly during a meeting with the administrative manager.

- Formal written reports are given monthly to document QC activity in the PLM and TEM sections. Formai writ:Len reports are also given periodically to document results of section audits and review of control charts. The QAJQC Coordinator keeps a copy of quality assurance reports, whether informal or formal.

Revision #0: February ¡995 O'Brien & Gere Labora:ories, ¡ne. 40

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14. Resumes

Resumes of key personnel are available from the laboratory.

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Revision #0: Februa,'y ¡995 41

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Appendix Tab

ti

I SI-1KO

SHELL OIL COMPANY

840076 ASBESTOS

988

SHELL MATERIAL SAFETY DATA SHEET .-.---

BE SAFE. READ OUR PRODUCT SAFETY INFORMATION . . . AND PASS IT ON. PRODUCT LIABILITY LAW REQUIRES IT!

- ***************.***** MATERIAL SAFETY DATA SHEET 840076 04

ASBESTOS

09/10/95

5H MSDS: 840076 04 09/10/95

MANUFACTURERS NAME AND ADDRESS SHELL OIL COMPANY

.- PRODUCT SAFETY & COMPLIANCE P.O. BOX 4320

HOUSTON, TX 77210

TELEPHONE NUMBERS: 24 HOUR EMERGENCY ASSISTANCE

- SHELL: 713-473-9461 CHEMIREC: BOO-424-9300

GENERAL MSDS ASSISTANCE SHELL: 713-241-4819

SECTION I NAME

PRODUCT: ASBESTOS

CHEM NAME: AMOSITE, CHRYSOTILE, CROCIDOLITE ACUTE HEALTH HAZARD: i

----- AND OTHER FORMS COVERED BY THE OSHA HEALTH STANDARD

CHEM FAMILY: WASTE FIRE HAZARD: O

SHELL CODE: WWWWW REACTIVITY: O

SECTION II-A PRODUCT/Ir1GREOIENT

NO. COMPOSITION CAS PERCENT ===e ==

P ASBESTOS 1332-21-4 100

SECTION II-8 ACUTE TOXICITY DATA

NO. ACUTE ORAL LOSO ACUTE DERMAL LID5O ACUTE INHALATION LC5O =====- -==- rr

P NONE

SECTION III HEALTH INFORMATION

page 1 of 9

524 36

I SHEO 988

- SHELL OIL COMPANY 524 36 ASBESTOS THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUrREMErS UJDER THE OSI-lA

HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200).

EYE CONITACT:

OUST MAY CAUSE MECHANICAL IRPJTATOW TO THE EYES.

SKIN CONTACT: HIGH CONCENTRATIONS OF OUST ARE IRRITATING TO THE SKIN AND MAY CAUSE "ASBESTOS CORNS, BENIGN, WART-LIKE GROWTHS.

INHALATION:

INHALATION OF ASBESTOS FIBERS MAY CAUSE ASOESTOSIS (FIBROSIS OF THE LUNGS). . LUNG CANCER OR MESOTHELIOMA (SEE OTHER HEALTH EFFECTS).

- INGESTION:

ASBESTOS HAS A LOW LEVEL OF ACUTE TOXICITY UPON INGESTION.

- SIGNS AND SYMPTOMS:

IRRITATION AS NOTEO ABOVE. LUNG DAMAGE (SCARRING, AND TUMORS) MAY BE EVIDENCED BY SHORTNESS OF BREATH, COUGH, CHEST PArNJ. CYANOSIS (BLUISH

- DISCOLORATION OF THE SKrN), CLUBBING OF TI-lE FrNGERS, FATIGUE AND WEIGHT LOSS.

AGGRAVATED MEDICAL CONDrTIONS: PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. IMPAIRED LUNG FUNCTION FROM PREEXISTING DISORDERS MAY BE - AGGRAVATED BY EXPOSURE TO THIS MATERIAL.

- OTHER HEALTH EFFECTS: THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION. TI-lE NATIONAL TOXICOLOGY PROGRAM AND THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAVE DETERMINED

- THERE IS SUFFICIENT EVIDENCE FOR THE CAPCINOGENTCITV OF ASBESTOS IN ROTH HUMANS AND EXPERIMENTAL ANIMALS. THEREFORE, THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE FOLLOWED TO MINIMIZE EMPLOYEES EXPOSURE.

SEE SECTION VI FOR ADDITIONAL HEALTH INFORMATION.

SECTION IV I

OCCUPATIONAL EXPOSURE LIMITS

OSHA ACGIH NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL OTHER

- '- P 0.1 F/CC I F/CC* 2 F/CC,A1

Pl 0.5 F/CCAl P2 2 F/CC,A1 P3 0.2 F/CC,A1

i SHEO 988

- SHELL OIL COMPANY 524 36 ASBESTOS P4 2 F/CCA1

F!CC= FIBERS/CUBIC CENTIMETER; *3OMNUTE EXCWSION LrMrT. P1= AMOSITE; P2

CHRYSOTILE; P3 CPOCIDOLITE; P4 OTHER FORMS.

- SECTION V EMERGENCY AND FIRST AID PROCEDURES

EYE CONTACT: FLUSH EYES WITR PLENTY OF WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.

SKIN CONTACT: FLUSI-1 SKIN WITH WATER WHILE REMOVrNG CONTAMINATED CLOTHING AND SHOES. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. DO NOT REUSE CLOTHING OR SHOES UNTIL CLEANED.

- tNHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS

DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.

INGESTION: DO NOT INDUCE VOMITING. IN GENERALI NO TREATMENT IS NECESSARY

UNLESS LARGE QUANTITIES OF MATERIAL ARE INGESTED. HOWEVER, GET -. MEDICAL ADVICE.

----- NOTE TO PHYSICIAN:

- SECTION VI SUPPLEMENTAL F-JEALTH INFORMATION

ASBESTOS CAUSED NO DOSE-RELATED INCREASE IN SIsTE-C-1ROMATID EXCHANGE LEVELS IN - CHO-KI CELLS. HUMAN FIBROBLASTS OR HUMAN LYMPHOBLASTOID CELLS. HOWEVER,

MITOTIC DELAY WAS INDUCED IN CHO-Ki CELLS AND HUMAN FIBROBLASTS. CHINESE HAMSTER OVARIAN FIBRORLASTS SHOWED AN INCREASE IN THE SISTER CHROMATID EXCHANGE RATE UPON EXPOSURE TO ASBESTOS. ESCHERICHIA COLI AND SALMONELLA TYPHIMURIUM SHOWED ASBESTOS NOT TO E MUTAGENIC. CYTOGENETICS IN VITRO ASSAY FINDINGS WERE PosrTIvE; ASBESTOS WAS NOT METABOLICALLY ACTIVATED.

MARKED TO EXTREME HYPERPLASEA OF THE BONE MARROW AND ABERRATIONS OF HUMORAL AND CELLULAR IMMUNITY HAVE BEEN REPORTED IN INDIVIDUALS EXPOSED TO ASBESTOS.

- THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS CONCLUDED THE FOLLOWING: 'CIGARTETTE SMOKING AND OCCUPATIONAL EXPOSURE TO ASBESTOS FIBERS INCREASES LUNG CANCER INCIDENCE INDEPENDENTLY; WHEN THEY OCCUR TOGETHER, THEY ACT

- MULTIPLICATIVELY." THE HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE FOLLOWED TO MTNIMEZE EMPLOYEE EXPOSURE.

page 3 of 9

i SREO 988 - SHELL OIL COMPANY 524 36

ASBESTOS

SECTION VII PHYSICAL DATA

BOILING POINT (DEG F) : SPECIFIC GRAVITY (H20i) : VAPOR PRESSURE (MM HG)

NOT APPLICABLE >1 NOT APPLICABLE

MELTING POINT (DEG F) : SOLUBILITY (IN WATER) : VAPOR DENSITY (AIR1):

- NOT APPLICABLE NEGLIGIBLE NOT APPLICABLE

EVAPORATION RATE (NORMAL BLJTVL ACETATE = i): NOT APPLICABLE

APPEARANCE AND ODOR: FIBROUS SOLID, NO ODOR.

SECTION VIII FIRE AND EXPLOSION HAZARDS

FLASH POINT AND METHOD: FLAMMABLE LIMITS/% VOLUME IN AIR:

---- NONE LOWER: - UPPER: -

EXTINGUISHING MEDIA: USE WATER FOG, FOAM, DRY CHEMICAL OR CO2.

SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS: -

MATERIAL WILL NOT BURN. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS). INCLUDING A POSITIVE PRESSURE NIOSI-i APPROVED SELF-CONTAINED

- BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

SECTION IX (

REACTIVITY

STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR

CONDITIONS AND MATERIALS TO AVOID:

HAZARDOUS DECOMPOSITION PRODUCTS: - THERMAL DECOMPOSITION PRODUCTS ARE I4IGHTLY DEPENDENT ON THE COMBUSTION

CONDiTIONS. A COMPLEX MIXTURE OF AIRBORNE PARTICULATES AND GASES WflL EVOLVE

i sI-{o 988 - SHELL 011 COMPANiY

ASA ESTOS WHEN mrs MATERIAL UNJDEROOES PYrOLYSIS OP COMBUSTION.

---- SECTION X EMPLOYEE PROTECIr0N

RESPIRATORY PROTECTTON; DO NOT BEATME DUST. IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE

- LFMTS (SEC. Iv) USE A NTOS-1-APPROVED ESPTRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.1001 OR 1926.5B USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR EQUIPPED WITH HIGH-EFFICIENCY PARTICULATE CARTRIDGES. FOR ADDITIONAL REQUIREMENTS. REFER TO 29 CFR 1926.58(H).

PROTECTIVE CLOTHING: AVOID CONTACT WITH EYES. WEAR SAFETY GLASSES OR GOGGLES AS APPROPRIATE. AVOID CONTACT Will-I SKIN AND CLOTHING. WEAR CHEMICALRESISTANT GLOVES AND PROTECTIVE CLOTHING. FOR ADDTÍONAL REQUIREMENTS. REFER TO 29 CFR 1926.58(I).

ADIDTONAL PROTECTIVE MEASURES: FOR ADDITIONAL REQUIREMENTS, REFER TO 29 CFR 1926.58(G).

----.- SEC1ION XI ENVIRONMENTAL PROTECTION

SPILL OR LEAK PROCEDURES: - PREVENT BODILY CONTACT WITH SPILLED MATERIAL. WEAR PROTECTIVE CLOTHING AND APPROPRIATE RESPIRATOR. VACUUM THE AREA WITH VACUUM CLEANER EQUIPPED WITH HIGH-EFFICIENCY PARTICULATE AEROSOL (HEPA) FILTERS. FOR

- ADDITIONAL REQUIREMENTS ON CLEANUP AND DISPOSAL, REFER TO 29 CFR 1926.58(L) AND 40 CFR 61.150. AVOID GENERATING DUST. PUT INTO CONTAINERS FOR DISPOSAL.

SECTION XII :

SPECIAL PRECAUTIONS

FOR ADDITIONAL REQUIREMENTS. REFER TO 29 CFR 1926.58. 29 CFR 1910.1001. 40 CFR 61.145, AND 40 CFR 61.150.

- SECTION XIII TRANSPORTATION REQUIREMENTS

- DEPARTMENT OF TRANSPORTATION CLASSIFICATION; CLASS 9 (MISCELLANEOUS HAZARDOUS MATERIAL). III

page 5 of 9

¶2d 3

I SHEO 988 - SHELL OIL COMPANY

ASBESTOS 524 3

0.0.1. PROPER SHIPPING NAME: ASBESTOS

OTHER REQUIREMENTS: NA 2212, GUIDE 31. F4OMFRIABLE ASBESTOS AND FRIABLE ASBESTOS IN QUANTITIES OF LESS THAN 1 POUND PER CONTAINER ARE NOT REGULATED BY DOT.

SECTION XIV OTHER REGULATORY CONTROLS

THIS MATERIAL IS LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES.

IN ACCOROANCE WITH SARA TITLE ITT, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA SHEET (EDS) SHOULD ALWAYS BE COPIED AWD SENT WITH THE MSDS.

SECTION XV STATE REGULATORY INFORMATION

- THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PRODUCT SPECTFC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE APPLICABLE FOR STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY

- REQUIREMENTS YOU SHOULD CONTACT THE APPROPRIATE AGENCY IN YOUR STATE.

STATE LISTED COMPONENT CAS NUMBER PERCENT STATE CODE

ASBESTOS 1332-21-4 100 CA, FL, IL, MA,

ME, MN, PA RI,

CA65C

CA - CALIFORNIA HAZ. SUBST. LIST; CA65C, CA65R, CAG5C/R = CALIFORNIA SAFE - DRINKING WATER AND TOXICS ENFORCEMENT ACT OF 1986 OR PROP0SITON 65 LrST; CT -

CONNECTICUT TOXIC. SUBST. LIST; FL FLORIDA SUBST. LIST; IL = ILLINOIS TOX. SUBST. LIST; LA LOUISiANA HAZ. SUBST. LIST; MA MASSACHUSETTS SUBST.

- LrsT; MF MAINE HAZ. SUBST. LIST; MN MINNESOTA HAZ. SUBST. LIST; NJ

NEW JERSEY HAZ. SLJBST. LIST; PA PENNSYLVANIA HAZ. SUBST. LIST; RI RHODE ISLAND HAZ. SUBSI. LIST.

- CALIFORNIA PROPOSITION 65 FOOTNOTE: CA6SC THE CHEMICAL IDENTIFIED WITH THIS CODE IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. CA6SR THE CHEMICAL IDENTIFIED WITH THIS CODE IS KNOWN TO TI-lE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. CA65C/R = THE CHEMICAL IDENTIFIED WITH THIS CODE IS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BOTH CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.

- SECTION XVI SPECIAL NOTES

i SI-LEO 9fl8 - SHELL OIL COMPAIWY

ASBESTOS

- THIS MSDS REVISION I-JAS CHANGES IN SECTION XV - STATE REGIJLATÖRY INFORMATION

THE INFORMATION CONTAINED HEREIN IS BASED ON TI-LE DATA AVAILABLE TO VS AND IS

RELIEVED TO E CORRECT. HOWEVER. SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO flE OBTAINED FROM TI-LE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.

WE ARE PROVIDING OUR MOST RECENT MATERIAL SAFETY DATA SHEET AND/OR - ENVIRONMENTAL DATA SHEET. IF YOU WISH TO RECEIVE UPDATES TO THIS INFORMATION, PLEASE CALL SHELL'S GENERAL MSDS ASSISTANCE LINE (713-241-4819) TO ENSURE THAT YOU ARE ADDED TO SHELL'S REGULAR MSDS DISTRIBUTION SYSTEM.

BE SAFE. READ OUR PRODUCT

- SAFETY INFORMATION. . .AND

PASS fl ON. (PRODUCT LIABILITY LAW REQUIRES IT)

SHELL OIL COMPANY PRODUCT SAFETY AND COMPLIANCE P. 0. BOX 4320 HOUSTON, TX. 77210

********************** ENVIRONMENTAL DATA SHEET 840076 - 00

EDS: 4OO76 - 00 09110/95 PRODUCT NAME: ASBESTOS

----- PRODUCT CODE: WWWWW

MANUFACTURER'S NAME AND ADDRESS SHELL OIL COMPANY - P.O. BOX 4320 HOUSTON. TX 77210

- TELEPHONE NUMBERS: 24 HOUR EMERGENCY ASSISTANCE SHELL: 713-473-9461 CHEMTREC: 800-424-9300

FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE

CALL 713-241-2252

SECTION I PRODUCT COMPOSITION

-- NO. COMPOSITION CAS PERCENT ===== = = = =

P ASBESTOS 1332-21-4 100

---. SECTION II SARA TITLE III INFORMATION

NO. EMS RQ* EHS TPQ* SEC-313 313 CATEGORY 311/312 CATEGORY

524 37

1 SHEÖ 98R 524 37 - SHELL 011 COMPANY

ASBESTOS (*1) (*2) (*3) (*4) (*5)

========

------ P YES I-I-1, H-2

- *1 _ REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE. SEC 302 *2 THRESHOLD PLANWtNG QUANTITY, EXTREMELY HAZARr3OUS SUBSTANCE, SEC 302 *3 TOXIC CHEMICAL, SEC 313

- *4 _ CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.42, MUST BE USED ON TOXIC RELEASE INVENTORY FORM

*5 HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING HEALTH: H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD

.- H-2 = DELAYED {CHRONIC) HEALTH HAZARD

PHYSICAL: P-3 FIRE HAZARD P-4 = SUDDEN RELEASE OF PRESSURE HAZARD

- P-5 = REACTIVE HAZARD

SECTION III ENVIRONMENTAL RELEASE INFORMATION

EPA - COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT. UNDER EPA-CERCLA (SUPERFUND) RELEASES TO AIR, LAND OR t4ATER WHICH EXCEED - THE REPORTABLE QUANTITY MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, 800-424-aS02 .

- THE REPORTARLE QUANTITY (RQ) FOR A RELEASE OF THIS MATERIAL IS i LB.

-,--: SECTION IV I

RCRA INFORMATION

IF THIS MATERIAL BECOMES A WASTE, IT WOULD NOT BE A HAZARDOUS WASTE BY RCRA - CRITERIA (40 CFR 261). FOR DISPOSAL REQUIREMENTS. SEE 40 CFR 61.150.

WE ARE PROVIDING OUR MOST RECENT MATERIAL SAFETY DATA SHEET AND/OR ENVIRONMENTAL DATA SHEET. IF YOU WISH TO RECEIVE UPDATES TO THIS INFORMATION,

- PLEASE CALL SHELL'S GENERAL MSDS ASSISTANCE LINE (713-241-4819) TO ENSURE THAT YOU ARE ADDED TO SHELL'S REGULAR MSDS DISTRIBUTION SYSTEM.

SHELL OIL COMPANY P.O. BOX 4320 HOUSTON. TX 77210

FOR ADDITIONAL INFORMATION ON THIS ENVIRONMENTAL DATA PLEASE CALL - (713) 241-2252

FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-9461

-. T CHEMTREC: (800) 424-9300

page 8 of 9

i SHEO 988

- SHELL OIL COMPANY 524 374 ASBESTOS

--

THIS MSDS HAS BEEN PROVIDED IN AN ELECTRONIC FORMAT FOR USE IN THE CHEMTREC EMERGENCY RESPONSE PROGRAM AND/OR OTHER APPROVED PROGRAMS. THIS FORMAT MAY CONTAIN BLANKS WHERE INFORMATION WAS NOT AVAILABLE OR NOT APPLICABLE AND THEREFORE MAY NOT BE FULLY COMPLIANT WITH THE OSHA HAZARD COMMUNICATION STANDARD. IF YOU PURCHASE OR USE THIS SHELL PRODUCT AND HAVE NOT RECEIVED

- A MSDS FROM SHELL PLEASE CONTACT US AND WE WILL PROVIDE ONE. THIS WILL ENSURE THAT YOU RECEIVE UPDATES OF THIS INFORMATION.

page 9 of 9

524 375

Appendix Tab

-

-r ----- O?ERÀTI}G PROCEDURE

524 376

EXPETY GIELIES POR DRILLING INTO SOIL MD ROCKS

PR?OSE

The purpose of this operating procedure is to provide

- guide1ires for sate conduct of drilling operatiOrS .Jith truck-

i nounted and otber engthe-poered, drill rigs. The procedure

a'drsses off-road cveent of drill rigs, overhead and buried

utilities, use of augers, rotary and core drilling, and other

.

drilling operatiors arid activities. e

- - APPLICATION e

-: The guidelines shall be applied in all projects

-- in 'hich truck-counted, or other engine-powered, drill rigs are .

used. The guidelines are applicable to employees and a"ard

- rigs. For drill rigs operated by contractors, drill rig safety is . the responsibility of the contractor.

P-ESCNSIBILITY AND UTBORITY

: Drill rig safety and ainteriance is the responsibility of the dri1 rig operator;

_,,-.

- .( Noveer 1990 W- pagelof7

ti 524 377

_J SXFETY GIDELflrE8

r .--:-

Mcv-ExEN'r OF DRILL RIGS -

-. Before rnoving a rig, the operator tust do the fcllc.iing:

1. To the extent prctica1, walk the plarmed route of travel arid irspect it for depressions, gullies, ruts, and other

obstacles.

-i 2 . Check the brakes of the truck/carrier, especially if the

jterrair a1org the route of travel is rough or sloped.

1 3. Discharge all passengers before moving on rcugh or steep

t e r r a i r.

r' 4. Engage the front axle (on 4x4, 6x6, etc. vehicles) before

- traversing rough or steep terrain.

Driving drill rigs along the sides of hills or

eban)cnents should be avoided; however, if side-hill travel beccres

-

:

flecessary, the operator must conservatively evaluate the ability of

r:i :he rig to remain upright while on the hill or e.ban)ent. The

possibility that the presence of drilling tools on the rig TTay

TIreduce the ability of the rig to remain upright by raising the .

center of uass of the rig must be considerd.

! . .. Logs, ditches, road e-rbs, arid other long andthcrìzontal

i

t

obstacles should be nor-ally approached and driven over squarely,

:ot at ari angle.

¡I When close lateral or overhead clearance is encountered,

. the driver of the rig should be guided by another person on the

..

ground.

¶_ Novether 1990

page 2 of 7

i,

524 378

Loads ori the drill rig arid truck must be properly stced while the truck is moving, and theast must be in the tull lowered position.

- After the rig has been positioned to begir drilling, all -

brakes arid/or locks ustbe set before drilling begins. If the rig

- is positioned on a steep grade arid leveling of the ground 's

impossible or impractical, the wheel of the transport vehicle

- should be blocked and other means of preventing the rig from rovir.g

or topping over ep1oyed.

BURIED AND OVERHEAD C'DILITIES

- The location of overhead and buried utility lines 'ust be

determined before drilling begirs, and their locations should be

noted on boring plans or assignment sheets.

_c

- When overhead power lines are close by, the drill rig ::. mast should not be raised unless the distance between the rig ard

- the nearest power line is at least 20 feet or other distance as

required by local ordinances, whichever is greater. The drill rig

operator or assìstarit should walk completely around the rig to make

Tsure that proper distance exists.

Wheri the drill rig is positioned near an overhead line, . the rig ope'ator should be aware that hoist lines and power lines ,-

can be moved towards each other by wind. 1hen necessary and

; approved by the PM and the utility, powerlines ay be shielded,

- shut dowri, or moved by the appropriate personnel.

: Ncve.ber 1990

.,- page 3 of 7

J

-j

-j

ri

ri

'u---

524 379

CLEXRING Wcy

Before a drill rig is positioned to drill, the area

which the ri is to be positioned should be cleared of removable

obstacles and the rig should be leveled if sloped. The cleared/leveled area should be large enough to accommodate the rig and supplies.

82E USE OP AUGERS

Never place hands or fingers under the bottom of an auger flight or drill rods when hoisting the augers or rods over the top of another auger or rod in the ground or other hard surfaces, such as the drill rig platform.

Never allow feet to get under the auger or drill, rod

while they are being hoisted.

When drill is rotating, stay clear of the drill string

and other rotating components of the drill rig. Never reach behind or around a rotating auger for any reason,

Move auger cuttings away from the auger with a long-

handled shovel or spade; never use hands or feet.

Never clean an auger attached to the drill rig unless the

transmission is in neutral or the engine is off, and the auger has

stopped rotating.

SX?E BZ OP EAND TOOLS

OSHA regulations regarding hand tools should be observed

in addition to the guidelines provided below:

page 4 of 7

November 1990

-.. r'A )o - J Ou

f__ 1. Each tool should be used orly tò perform tasks for whic'.

,_( it was originally designed.

2 . Damaged tools should be repaired before use or discarded.

- . Safety goggles or g1asse should be vorn when using a

haer or chisel. 1earby co-workers and by-standers should be req-uired to wear safety goggles or glasses alsc - or to nove atay.

4. Tools should be kept cleaned and stored in an orderly rq

manner when not ifl use.

-w.

. BAYE 8E OF WIRE LINE HOISTS, WIRE ROPE, AND EOISTIG

-r .

EXRDW)

i,

Safety rules described in 29 CFR 1926.552 and guidelines

Tir contained ix-i the Wire RPEUser's Manual published by the American Iron and Steel Institute shall be used whenever wire line hoists, Tfwire rope, or hoisting hardware are used.

.t PROTECTIVE GEXR

- - -

MINIKt)C PROTECTIVE GE.,R

-r Items listed below should be worn by all ezers of the

1. drilling team. while engaged in drilling activities.

r r o Hard Hat;

o Safety Shoes (shoes or boots with steel toes and

Rshanks) ; and

. o Cloves.

r.

r« Noveaber 1990

page5of7

:7S

524 381

OT2 GEXR

Items listed below should be worn when conditions warrant their use. Some of the conditions are listed after each item.

j.. Safety Gogles or Glasses: Use when: (1) driving pins in and out of drive chains, (2) replacing keys in tongs, (3)

handling hazardous chemicals, (4) renewing or tightening gauge glasses, (5) breaking concrete, brick, or Cast

iron1 (6) cleaning material with chemical solutions, (7)

hamzering or sledging on chisels, cold cuts, or bars, (8)

cutting wire lines, (9) grinding on abrasive wheels, (10)

handling materials in powered or semi-powered form, (11)

scraping metal surfaces, (12) sledging rock bits or core

heads to tighten or loosen them, (13) hammering fittings

and connections, and (14) driving and holding rivets.

2. Safety Belts and Lifeline!: Safety belts and lifelines

should be worn by all persons working on top of an

elevated derrick beam. The lifeline should be secured at a position that .'i11 11ow person to f.L1 no mort.' th.in

eight feet.

3. Life Vests: Use for work over water.

TRAPPIC SAFETY

Drilling in streets, parking lots or other areas of

vehicular traffic requires definition of the work zones with cones,

warning tape, etc. and compliance with local police reçuiremerits.

page 6 of 7

November 1990

ti

r f-

T,

-n 'V

/H&S2

---J

524 38

Pik! SA.PETY

1. Fire extinquishers stall be kept on or near drill rigs for fighting small fires.

2. It. methane is suspected in the area, a combustible gas instrument (CGI) shall be used. to monitor the air near the borehole with all work to stop at 25 percent of the Lower Ecp1osive Limit.

3. 1ork shall stop during lightning storms.

page 7 of .7

November 1990

524 383

Appendix Tab

I i

I i

t

I

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J (

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;I.i

!;i i

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hici

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is I

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nead

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keis

cas

i he

ep

ca(c

dly

expo

sed

wut

hüij

advr

sc h

callh

cIIc

(s.

The

TLV

obl

ecliv

e is

to

pevi

tt Ih

e de

ep b

ody

Icm

pera

luro

hor

n IIi

ng b

elow

36°

C (

960e

1) a

nd

o pr

even

t co

ld ¡

njur

y io

bod

y ex

lser

nilic

s (d

eep

body

Ier

npea

. tw

e is

the

core

ten

peta

Iu,e

of

flue

body

det

erm

ined

by

conv

en.

iona

l m

etho

ds (

or

ccta

l tc

inpe

riuce

mea

sure

men

ls).

For

a

sjng

Io

occa

sion

al e

xpos

Ure

lo a

col

d en

viro

nmen

t. a

drop

¿n c

oe

lem

pora

ture

to

no l

ower

(ha

t 35

°C (

95°F

) sh

ould

be

perm

illed

. In

add

ilion

to

povi

sion

s la

r lo

lal b

ody

prol

eclio

n, I

ho T

LV o

bjec

. liv

e is

lo p

roto

l all

part

s of

ihe

bod

y w

illi

emt,)

isís

on

hand

s,

ted.

and

hea

d%tr

om c

old

njuc

y.

lnlro

duct

lon

Fal

al ü

xpou

res

Io c

old

amon

g w

orke

rs l

avc

alm

ost

a'w

ays

resu

lted

Irom

aci

donl

al e

xpos

ures

inv

olvi

ng t

ailu

re t

o es

cape

ho

rn l

ow e

nviro

nmen

tal a

ir le

rnpe

ralu

res

or f

rom

imm

ersi

on i

n 10

w te

mpe

ratu

re w

ater

. T

he s

ingl

e m

ost i

mpo

rlant

asp

ect o

h lif

e-

n th

reat

enin

g hy

poth

erm

ia is

the

fal

l in

itig

deep

cw

e te

mpe

ratu

re

ut li

te b

ody.

The

clin

ical

pre

sonl

alio

ns o

f vi

ctim

s ol

hyp

othe

rmia

O

ar

e sh

ow-t

in T

able

1.

Wor

kers

sho

uld

be p

otec

led

trum

exp

osur

e lo

col

d so

Iha

t lh

e de

ep c

ore

lem

pera

lure

doe

s no

t lat

i be

low

36°

C

(96.

0°F

): lo

wor

bod

y te

mpe

ratu

res

will

ver

i like

ly re

sult

in r

educ

ed

men

tal

aler

tnes

s. r

educ

tion

in r

atic

nal d

ecis

ion

mak

ing,

or

loss

of

con

scio

usne

ss w

ith t

he t

hrea

t of

tal

ai c

onse

quen

ces.

P

ain

in t

he

extr

emiti

es m

ay b

e th

e fir

st e

arly

war

ning

Oh

dang

er l

o co

ld s

tres

s. D

urin

g ex

posu

re lo

col

d, m

axim

um s

ever

o sh

iver

ing

deve

lops

whe

n th

e bo

dy te

mpe

ratu

re h

as ta

llen

to 3

5°C

(9

5°F

). T

his

mus

t be

tak

en a

s a

sign

oh

dang

er t

o th

e w

orke

rs

and

expo

sure

lo c

old

shou

ld b

-e im

med

iate

ly te

rmin

ated

for

any

wor

kers

whe

n se

vere

shi

verin

g be

com

es e

vide

nt.

Use

ful

phys

i- ca

l or

men

tal

wor

k is

lim

ited

whe

n S

ever

e sh

iver

ing

occu

rs.

Sin

ce p

rolo

nged

exp

osur

e to

col

d ai

r, o

r to

imm

ersi

on in

col

d w

aler

, al

tem

pera

ture

s w

ell a

bove

Ire

ezin

g ca

n le

ad l

o da

nger

- ou

s hy

poih

erni

la.

who

le b

ody

prot

ectio

n m

ust

be p

rovi

ded.

1.

A

dequ

ate

insu

latin

g dr

y cl

othi

ng l

o maintain c

ore

tem

pera

- lu

res

abov

e 36

°C (

96.8

°F) m

ust b

e pr

ovid

ed to

wor

kers

if w

ork

is p

erlo

rmed

in a

ir te

mpe

ratu

res

belo

w 4

°C (4

0°F

). W

ind

chill

co

olin

g ra

ta a

nd t

he c

oolin

g po

wer

oh

air

are

criti

cal

fact

ors.

W

ind

chill

! coo

ling

raie

is d

efin

ed a

s he

al l

oss

from

a b

ody

expr

esse

d in

wal

ls p

er m

eter

squ

ared

whi

ch is

a l

uncl

ion

oh

the

air

tem

pera

ture

and

win

d ve

loci

ty u

poit

the

expo

sed

body

j T

he h

ighe

r lIt

e w

ind

spee

d an

d lit

e lo

wer

lite

tem

pera

ture

in

the

wor

k ar

ea, l

ito g

roal

or th

e in

sula

tion

valu

e 01

lite

1,r

otcc

- liv

e cl

othi

ng r

equ

is

I. A

it eq

tsiv

iteiit

cllt

tl'ri

ipe,

alus

n c

li;u

t sc

litiit

Ilu

' .1:

tuia

l dry

hul

ls :

u,,

i Iu

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n ot

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riod

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g th

e sp

ecia

l pr

ecau

tions

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d. T

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reca

utio

nary

aC

tiOns

lo t)

o ta

ken

will

dep

end

upon

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phy

sica

l co

nditi

on o

f th

e w

orke

r an

d sh

ould

be

dolo

rmin

ed w

ith th

e ad

vico

ol

a ph

ysic

ian

with

kn

owle

dge

of th

e co

ld s

b'es

s la

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e m

edic

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ondi

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n ol

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wor

ker.

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uitlo

n m

d C

ontr

ol

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osed

ski

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ontin

uous

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osur

e sh

ould

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he

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illed

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n Ih

e aï

r sp

eed

and

tem

pera

ture

res

ults

in a

n eq

uiva

- le

nt c

hill

tem

pera

ture

ol -

2°C

(2S

.6F

). S

uper

ficia

l or

dee

p lo

cal

tissu

e Ir

eezi

ng w

ill

occu

r on

ly

at

tem

pera

ture

s be

low

- I

C

(3

02°F

) re

gard

less

ot

win

d sp

eed.

r-J

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r te

mpe

ratu

res

of 2

°C (

J5°F

) or

les

s, il

is

impe

a'al

ive

o th

at w

orke

rs w

ho b

ecom

e Im

mer

sed

in w

atcu

or

who

se c

olhi

ng

beco

mes

wet

be

imm

edia

tely

pro

vide

d a

chan

go o

f cl

othi

ng a

nd

be I

reat

ed (

or h

ypot

herm

ia.

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omm

ende

d lim

its l

oi p

i'ope

rly c

loth

ed w

orke

rs t

oi p

erio

ds

al w

ork

a1

tem

pera

ture

s be

low

fre

ezin

g ar

e sh

own

in

Tab

le 3

. S

peci

al p

rote

ctio

n of

th

e ha

nds

is

requ

ired

to m

aint

ain

man

ual

dext

erity

(or

the

pre

vent

ion

of a

ccid

ents

: 1.

11

fin

e w

ork

is to

be

perf

oim

ed w

ith b

are

hand

s fo

r mor

e th

an

10-2

0 m

inut

es in

an

envi

ronm

ent b

elow

16°

C (

60.8

°F).

spe

- ci

al p

rnvi

sion

s sh

ould

be

esta

blis

hed

loi

keep

ing

the

wor

kers

' ha

nds

war

m.

For

this

pur

pose

, w

arm

air

jots

, ra

dian

t hea

ters

(lu

el b

urne

r or

ele

ctric

rad

iato

r),

or c

onta

ct w

arm

pla

tos

may

be

util

ized

. Met

al h

andl

es o

f too

ls a

nd c

ontr

ol b

ars

Sho

uld

be

cove

red

by I

herm

al i

nsul

atin

g m

ater

ial a

t te

mpe

ratu

res

be.

tow

-1°

C (

30.2

°F).

2.

lt

the

air

tem

pera

ture

laits

bel

ow 1

6°C

(60

.8°F

) fo

r se

dent

ary.

4°

C (

39.2

F}

lot l

ight

. -7

°C (

19.4

°F)

for

mod

eral

e w

oik

and

fine

man

ual d

exte

rity

is n

ot r

equi

red,

the

n gl

oves

sho

uld

be

__

used

by

the

wor

kers

. T

o pr

even

t co

ntac

t (a

sIbi

le,

the

wor

kers

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uld

wea

r an

ti-

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act

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es.

I, W

hen

cold

sur

face

s be

low

-7C

C (

19.4

°F)

are

wilh

in r

each

, a

war

ning

sho

uld

be g

iven

to e

ach

wor

ker

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viso

r to

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vent

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524 386

TABLE 3. Threshold Lirnt Va!u Work/Warm-up Schedule for Four-Hour Shift

Air TemperatureSunny Sky No Noticeable Wind_J S mphWind 10 mph Wind 15 mphWmnd

. .

Max. f

Max. Mu. Max. Work j No. of Work No. of Work No. ot Work No. of Work

c (approx.) 'F (approx.) Period Breaks Period Breaks Period Break. Period Breaks Penad

-26e -28e l5ø to -19° (No. Bread) I (No. Breaks) 75 2 55 3

-29e 3 O -2O o -24e (Norm. Breaks) I 75m1n 2 55 min 3 40 min 4 :

-32 to -34e -25' w 29* 75 min 2 55 min 3 40 min 4 30 rrn 5 No:. 350 37o -3O o -34e 55

I 3 40 n 4 30 n 5 Nonmcrgency

,Jso O -39° -35° w -39° 40 min I

O mi 5 Non-emergency work should cease

-4o co -42m 4QO _44 30 min 5 Non-cmergcncy work should cae -43e 45 & below Non-emcrgncy work should ceasc

J

work should cesse 4.' j .t

.Vo(esfor Table 3: - i. Schcdueappies w moderaeto heavy work acriviry with warm-up breaks,ften (10) minues in a warm lccaior. .- Iimited physical moverrent): apply the schedule one step lower. For exanpk, at -35°C -O

no rioticcable wind (Step 4), a workcr a a job with little physicaì movement should have a maximum v.ork - minutes with 4 breaks in a 4-hour p.riOd (Step 5).

2. The foflowing is suggested as a guide for estimating wind velocity if accLrate information is not availabk

- .5 mph: ligh flag moves: IO mph: Jig flag ÑIly extended; 15 mph: raises newspaper sheer: 20 b.' : drifting snow.

-

3. Ifonly the wind chill cooling rate is available, a rough of thumb for applying it rather than the temp: - velocity factors given above would bc: 1) specia' warm.up breaks should be initiated at a wind chill co&ing 1750 W/m; 2) all non-niergercy work shou'd have ceased at or before a wind chill of. 2250 W/rn. In gea up schedule provided above sIighty under-compensates for the wind a the wamer temprarures, Assuming a:;m

:i and clothing appropriate for wirer work. On the other hand, th chart slightly over-compensates for the acuai in the colder ranges. since windy conditions rarely prevail at extremely low (emperatures.

-- 4. TLVs apply only for workers in dry clothing.

. Adapced from Occupational He.alth k Safety Division. Sask!chewan Dprtmcn of Labour.

page 3 of 5

CD

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ed t

i ;i

n es

ivig

()Ir

flel s

t .iI

O

belo

w 4

°C

(39

.201

) T

he w

okrs

shou

ld w

ca

colti

pso

Iecu

ive

cloi

hing

app

ropt

iale

1w

th

e le

vel

of c

old

and

pliy

scal

act

ivity

: i.

II th

e ai

r ve

loci

ly a

l th

e jo

b si

te i

s in

crea

sed

by w

ind,

dra

ft.

Ot ai

lilic

ial v

entil

atin

g eq

uipm

ent,

(he

cool

ing

efod

of

the

-win

d sh

ould

be

redu

ced

by s

hiel

ding

flic

wor

k ar

ea o

r by

wea

ring

an e

asily

rem

ovab

le w

indb

reak

gai

'men

l. 2.

II

only

ligh

t w

ork

is in

volv

ed a

nd i

f hu

e cl

othi

ng o

n th

e w

otke

r m

ay b

ecom

e w

et o

n Ih

e jo

b si

te.

the

ouhc

la

yer

al t

he c

loth

- ¡n

g in

use

may

be

ola

type

impe

rmea

ble

(ii w

ater

. W

illi m

öre

seve

re w

ork

unde

r su

ch c

ondi

tions

, (tie

out

er la

yer

shou

ld b

e w

ater

rep

elle

nt,

and

the

oute

rwea

r sh

ould

be

chan

ged

as i

l be

com

es w

ette

d. T

he o

uter

gar

men

ts s

houl

d in

clud

e pr

ovi.

sion

s lo

t ea

sy v

entil

atio

n in

ard

or I

o pr

even

t w

ettin

g of

inn

er

laye

rs b

y sw

eat.

lt w

ork

is d

one

at n

orm

at t

empe

ratu

res

or

iii a

hot

env

ironm

ent

belo

re e

nter

ing

the

cold

are

a hi

e em

- pl

oyee

sho

uld

mak

e su

re I

hat

clot

hing

is n

ot w

et a

s a

cons

e-

quen

ce o

f sw

eatin

g. I

l cl

othi

ng i

s w

et.

(lie

empl

oyee

sho

uld

chan

ge i

nto

dry

clot

hes

belo

re e

nter

ing

the

cold

are

a. T

he

wor

kers

sho

uld

chan

ge s

ocks

and

any

rem

ovab

le l

eft

inso

les

at r

egul

ar d

aily

inte

rval

s or

use

vap

or b

arrie

r bo

ots.

The

op-

tim

al l

eque

ncy

of c

hang

e sh

ould

be

dete

rmin

ed e

mpi

rical

ly

and

will

var

y in

divi

dual

ly a

nd a

ccor

ding

to

the

type

of

shoe

w

orn

and

how

muc

h th

e in

divi

dual

's f

eet

swea

t. 3.

II

expo

sed

area

s al

(he

body

.can

not

be p

role

cled

suf

ficie

ntly

lo

pre

vent

sen

satio

n of

exc

essi

ve c

old

or ti

'ost

bite

, pr

otec

tive

item

s sh

ould

be

supp

lied

in a

uxili

ary

heat

ed v

ersi

ons.

4.

II

the

avai

labl

e cl

othi

ng d

oes

not

give

ade

quat

e pr

otec

tion

to

prev

ent

hypo

ther

mia

or

fros

tbite

, w

ork

shou

ld b

e m

odifi

ed o

r su

spen

ded

until

ade

qual

e cl

othi

ng s

mad

e av

aila

ble

or u

ntil

wea

ther

con

diili

ons

impr

ove.

S

. W

orke

rs h

andl

ing

evap

orat

ive

liqui

d (g

asol

ine,

al

coho

l or

cl

eani

ng f

luid

s) a

h ai

r te

mpe

ratu

res

belo

w 4

C(3

9.2°

F) s

houl

d ta

ke s

peci

al p

reca

utio

ns Io

avo

id s

oaki

ng o

( clo

thin

g oc

glo

ves

with

the

liq

uids

bec

ause

al

the

adde

d da

nger

of

cold

inj

ury

due

to e

vapo

rativ

e co

olin

g. S

peci

al n

ote

Sho

uld

be t

aken

al

the

parli

cuta

rly a

cule

elle

cis

01 s

plas

hes

of "

cryo

geni

c Itu

ids"

or

tho

se li

quid

s w

ith a

boi

ling

poin

t th

at is

just

abo

ve a

mbi

ent

tem

pera

ture

.

Wor

k-W

arm

ing Regimen

U w

ork

is p

erfo

rmed

con

tinuo

usly

in t

he c

old

at a

n eq

uiva

- -

leal

chi

ll te

mpe

ratu

re ([

CT

) or

bel

ow -

7°C

(19.

4 O

F).

hea

led

war

m-

1119

S

licIle

iS (

teul

tS,

Cab

inS

re

st

oom

s, e

tc )

sh

ould

be

iiiac

le

Ivsi

);st

Ie n

earb

y. T

he w

wkc

r Iic

itild

be

enco

su a

qwt

lo u

Se

thes

e

I

t

t

C

f

t

.,.

:3Li

:i

i

-

:

.

:/

.

,

r

f

-t

:,Ii.

,lI,;

, ii

I*I,I

.51

1111

.1

I%S

s I5tit5II5y

it

5tII5

t lii

i I

:.,v4

,l st

y ut

tti.

iu

iviu

uiss

uii.u

il,sh

IisIks:iluIl:

I h.

, tis

% su

( h.

ei-y

sts

iei

111.

1. lll

iIilil

I. lli

i lii

:Iiis

ii II

IK(i5

IVs

tltu(

slI,

,tlC

lwS

isiC

SS

55

55ta

tisls

Iy.

In

*ihl

1t15

IlI1

.555

! uu

tilic

atus

siss

Is

it ,ll

ll5Ie

Çt5

utC

ic

tuin

lu

lise

,t %

eItII

t,A

/I te

ss c

i ste

(itq

(t s

e I I

UtIC

(( s

Iset

t.:(

It sr

' OU

IC( ta

'jci (

il C

luth

- In

g lu

0utd

be

rem

oved

asi

d th

ie

csna

iridc

r of

(liC

clo

thin

g lo

osen

ed

lo p

erm

it sw

eat

evap

orat

ion

o a

chan

ge o

f dr

y w

ork

clot

hing

pr

ovid

ed.

A c

hang

e of

dry

wor

k cl

othi

ng s

houl

d be

pro

vide

d as

ne

cess

ary

to p

reve

nt w

Ork

ers

from

ret

urni

ng t

o w

ork

with

wet

cl

othi

ng.

Uel

sydr

atio

n, o

r th

e lo

ss o

t bo

dy fl

uids

, oc

curs

insi

diou

sly

in t

Ise

cold

env

ironm

ent

and

may

inc

reas

e th

e su

scep

tibili

ty o

f Ils

e w

orke

r to

cold

inju

ry d

ue t

o a

sign

ifica

nt c

hang

e ¡n

blo

od It

ow

io th

e ex

trem

ities

. W

arm

sw

eet dr

inks

and

sou

ps s

houl

d be

ps'

ovid

. ed

al

the

wot

k si

te to

pro

vide

cal

oric

inta

ke a

nd I

luid

vol

ume.

The

in

take

nl c

offe

e sh

ould

be

hiut

ed b

ecau

se a

l th

e di

uret

ic a

nd c

ir-

cula

tory

effe

cts.

For

wor

k pr

actic

es a

t or

bel

ow -1

2°C

(lO

.4°f

l [C

T, t

he l

ot-

(ow

ing

shou

ld a

pply

:

I T

ise

wor

ker

shci

utd

tc u

nder

con

stan

t pr

otec

tive

obse

rvat

ion

(bud

dy s

yste

m o

r su

perv

isio

n).

2.

TI-

se w

ork

rate

sho

uld

not

be s

o hi

gh a

s to

cau

se h

eavy

sw

eat-

¡n

g th

at w

ill re

sult

in w

et c

loth

ing;

il h

eavy

wor

k m

ust

be d

one.

re

st p

erio

ds m

ust

be t

aken

in

heal

ed s

helte

rs a

nd o

ppor

tuni

ty

for

chan

ging

int

o dr

y cl

othi

ng s

houl

d be

,pro

vide

d.

3.

New

em

ploy

ees

shou

ld n

oI b

e re

quire

d to

wor

k lu

tIhim

e in

the

co

ld d

urin

g lIt

e fir

st d

ays

of e

mpl

oym

ent

until

the

y be

com

e ac

cusl

omed

to

the

wor

king

con

ditio

ns a

nd r

equi

red

prol

ec-

live

clol

bing

. 4.

T

he w

eigh

t ar

id b

ulki

ness

of

clot

hing

sho

uld

be i

nclu

ded

in

estim

atin

g th

e re

quire

d w

ork

perf

orm

ance

and

wei

ghts

to b

e lif

ted

by t

he w

orke

r,

S.

The

wor

k sh

ould

be

arra

nged

in s

uch

a w

ay th

at s

ittin

g st

ilt

or s

tand

ing

still

for

lon

g pe

riods

is m

inim

ized

. U

ripro

tecl

ed

met

al c

hair

seat

s sh

ould

not

be

used

. T

he w

orke

r sh

ould

be

prot

ecte

d fr

om d

rafts

to

the

grea

test

ext

ent

poss

ible

. 6.

T

he w

orke

rs s

houl

d be

ins

truc

ted

in s

atel

y an

d he

alth

pro

- ce

dure

s. T

he t

rain

ing

prog

ram

sho

uld

incl

ude

as a

min

imum

in

stru

ctio

n in

:

a.

Pro

per

ewai

'min

g pr

oCed

ures

and

app

sopr

iate

fui

'st

aid

trea

tmen

t. b.

P

rope

r cl

othi

ng p

ract

ices

. C

, P

rope

r ea

ting

and

drin

king

hab

its.

d.

hlec

ogrs

ihio

n 01

im

pend

ing

fros

tbite

. e

fleco

gnili

on o

f si

gns

and

sym

ptom

s nl

im

pend

ing

hypo

- lh

errn

ua o

r ex

cess

ive

cool

ing

al ih

e bo

dy e

ven

whe

n sh

iver

- iI1

(J

(tO

CS

no

t O

CC

SI(

I S

,ihs

woi

k pr

.ucI

sCtS

0

crc

(D

I 1

f

f

5v-.

i:iiI

Voi

l )I

icO

liiC

)iii,i

JCiu

IdIs

JlIS

t:

Spe

cial

des

ign

rqui

reni

eids

br

iebi

igc(

alO

( ro

oms

IflClU(Je

I he

tutto

win

g:

I Iii

rct

(icjti

ralo

( ro

oms.

lire

air

velo

city

sho

uld

be m

inim

ized

as

muc

h as

pos

sibl

e an

d sh

ould

noi

exc

eed

I m

eIer

/sec

(20

0 (p

m)

al t

he jo

b si

te.

Thi

s ca

n be

ach

ieve

d by

pro

pwly

deS

ìgnr

J ai

r di

strib

utio

n sy

stem

s.

2.

Spe

cial

win

d pr

otec

tive

doth

inçj

sho

uld

be p

rovi

ded

base

d up

on e

xist

ing

air

velo

citie

s to

whi

ch w

orke

rs a

re e

xpos

ed.

Spe

cial

cau

tion

shou

ld b

e ox

èrci

sed

whe

n w

orki

ng w

ith lo

x.

ic s

ubst

ance

s an

d w

hen

wor

kers

are

exp

osed

Io v

ibra

lion.

Col

d ex

posu

re m

ay r

equi

re r

educ

ed e

xpos

ure

limits

. E

ye p

rote

ctio

n fo

r wor

kers

em

ploy

ed o

ut-e

l-doo

rs in

a s

now

an

d/or

ice

-cov

ered

ter

rain

sho

uld

be s

uppl

ied.

S

peci

al s

afet

y go

ggle

s to

pro

tect

aga

inst

ultr

avio

let

light

and

gla

re (

whi

ch c

an

prod

uce

tem

pora

ry c

onju

nctiv

itis

and!

oi te

mpo

rary

loss

of

visi

on)

and

blow

ing

ice

crys

tals

sho

uld

be r

equi

red

whe

n th

ere

is a

n ex

- pa

nse

el s

now

cov

erag

e ca

us4n

g a

pote

ntia

l eye

exp

osur

e ha

zaíd

w

orkp

lace

mon

ilorin

g is

req

uire

d as

lol

ows:

L.1

i -

Sui

tabl

e th

errn

omef

ry s

houl

d be

ara

nged

at

any

wor

kpla

ce

whe

re th

e en

viro

nmen

tal t

empe

ralu

re is

belo

w l6

C (6

08°F

) u,

so

tha

t ov

eral

l com

plia

nce

with

thee

quire

men

Is o

f th

e T

IV

can

be m

aint

aine

d.

2.

Whe

neve

r th

e ai

r te

mpe

ratu

re a

t a w

orkp

lace

(alls

bel

ow -

I °C

(3

0.2°

F),

the

thy

bulb

tem

pera

ture

sho

uld

be m

easu

red

and

reco

rded

at

leas

t ev

ery

4 ho

urs.

3.

In

ind

oor w

orkp

lace

s, t

he w

ind

spee

d sh

ould

als

o be

rec

orde

d at

lea

st e

very

4

hour

s w

hene

ver

the

rate

of

air

mov

emen

t ex

ceed

s 2

met

ers

per

seco

nd (

5 m

ph).

4.

In

out

door

wor

k si

tuat

ions

, th

e w

ind

spee

d sh

ould

be

mea

s-

urod

and

rec

orde

d to

geth

er w

ith th

e ai

r te

mpe

ratu

re w

hene

ver

the

air

tem

pera

ture

is b

elow

-1°

C (

302°

F).

5.

T

he e

quiv

alen

t ch

ill t

empe

ratu

re s

houl

d be

obt

aine

d fr

om

Tab

le 2

in a

ll ca

ses

whe

re a

ir m

ovem

ent

mea

sure

men

ts a

re

requ

ired;

it s

houl

d be

rec

orde

d w

ith t

he o

ther

dat

a w

hene

ver

the

equi

vale

nt c

hill

tem

pera

ture

is b

elow

-7°

C (

19.4

°F).

E

mpl

oyee

s sh

ould

be

excl

uded

bro

m w

ork

in c

old

at -

1°C

(3

02°F

) or

béb

ow i

f th

ey a

re s

uffe

ring

from

dis

ease

s o

taki

ng

med

icat

ion

whi

ch in

terf

eres

with

nor

mal

bod

y le

mpe

ralu

re re

gu-

lalio

n ei

' re

duce

s to

lera

nce

Io w

ork

in c

old

envi

ronm

ents

. W

or-

I

i

I

I

I

I

ic's

tr

u ac

e iu

tilur

cly

expo

sed

Io t

cinp

eIal

ur

dow

-24

°C

I 2

°F)

will

r w

ir rd

s r

eeds

les

s i I

ran

live

ruile

s pe

r lro

ui'

o; a

u te

mpe

ratu

res

belo

w

18°C

(0°

F)

with

win

d sp

eeds

abo

ve l

,v

iiild

S p

er h

oui'

shou

ld b

e m

edic

ally

cet

liIid

as

suita

ble

(or

SuC

h ex

posu

res.

T

raum

a S

usta

ined

in b

reez

ing

or s

ubze

ro c

ondi

tions

re1

uire

5 sp

ecia

l at

lenh

ioci

bec

ause

an

inju

red

wor

ker

is p

redi

spos

ed lo

col

d in

jury

. S

peci

al p

rovi

sion

s sh

ould

be

mad

e to

pre

vent

hyp

othe

r-

mia

and

free

zing

al d

amag

ed ti

ssue

s in

add

ition

to p

rovi

ding

for

lirsI

aid

tre

atm

ent,

(JI

co

co

FINAL PAGE

ADMINISTRATIVE RECORD

FINAL PAGE

524 389

54 31Ç)

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