Safety Data Sheets - Power Dry

Safety Data SheetsProduction

Power Dry KC

03/23/2018

Safety Data Sheet Index

Binder: Power Dry KC - Production

#2 Diesel Fuel - #2 Diesel Fuel 68334-30-5 ACCUSTANDARD, INC. 04/20/2016 4

#2 Diesel Fuel - Purex UltraPacks The Dial Corporation 09/13/2011 11

1-K KEROSENE, LS - 1-K KEROSENE, LS BP PRODUCTS NORTH AMERICAINC.

12/12/2014 17

1.0 M CITRIC ACID - 1.0 M CITRIC ACID 77-92-9 HAMPTON RESEARCH 01/10/2017 30

2CTJ1 - Car Wash Soap Concentrate - 2CTJ1 -Car Wash Soap Concentrate

3M - Automotive Aftermarket 05/08/2007 39

2U135 - Soap Hand 1 G - 2U135- Soap Hand1G

GOJO Industries, Inc. 10/15/2007 41

3M Hi-Strength 90 Bulk Adhesive, Clear - 3MHi-Strength 90 Bulk Adhesive, Clear

3M - Industrial Adhesives andTapes

12/06/2017 43

A07265 ZEP SS CLEANER ZUSCP16 STK20N16 - A07265 ZEP SS CLEANER ZUSCP16STK 20N16

ZEP Inc. 05/05/2015 56

A1121 Tire Shine - A1121 Tire Shine Omega Industrial Supply Inc 06/10/2015 66

AIRIEL SPICE AIR REFILLS - AIRIEL SPICEAIR REFILLS

ECOLAB CO. 04/22/2009 70

AMSOIL Metal Protector - AMSOIL MetalProtector

Amsoil Inc 03/30/2016 74

AVENGE PRO - AVENGE PRO Bridgepoint Systems 06/15/2013 85

Big Bubble Leak Detector - Big Bubble LeakDetector

J.C. WHITLAM MANUFACTURINGCOMPANY

07/10/2015 91

BLM TIRE WET 5GL - BLM TIRE WET 5GL ZEP Inc. 02/08/2017 97

C L R - CALCIUM LIME & RUST REMOVERENHANCED FORMULA - CLR- Calcium Lime &Rust Remover (Enhanced Formula)

Jelmar, LLC 03/01/2009 106

Clorox Bleach - Clorox Bleach The Clorox Company 01/05/2015 111

Conoco Gasoline, Unleaded, with MTBE (AllGrades) - Conoco Gasoline, Unleaded, withMTBE (All Grades)

ConocoPhillips 02/13/2003 132

Dri-Eaz MILGO SR - Dri-Eaz MILGO SR Legend Brands Products 03/24/2015 143

FAB SET - CR12 - FAB SET - CR12 Bridgepoint Systems 02/01/2011 152

Freeze-proof RV & Marine -50 °F BurstAntifreeze - Freeze-proof RV & Marine -50 °FBurst Antifreeze

South Win Ltd. 03/27/2015 156

Product Name CAS Number Manufacturer Version Date Page

of 276Page 2 of 276Page 2 of 276Page 2 of 276

Burst Antifreeze

Graffiti Gone - Graffiti Gone QuestSpecialty Corporation 11/10/2014 166

Gumout Regane Auto Parts Cleaner &Degreaser - Gumout Regane Auto PartsCleaner & Degreaser

ITW Global Brands 05/13/2015 171

KILL ODOR PLUS - KILL ODOR PLUS Chemspec 09/08/2014 181

Liquid HE 150 XPT - Liquid HE 150 XPT Drilling Specialties Company 04/10/2013 188

Mass Air Flow Sensor Cleaner - Mass Air FlowSensor Cleaner

CRC Industries, Inc. 08/07/2017 199

Microban Milgo Plus - Microban Milgo Plus Legend Brands 04/03/2017 211

Northex Anti-Freeze - Northex Anti-Freeze CADILLAC OIL COMPANY 10/09/2014 221

On and Gone – Mould and Mildew StainRemover - On and Gone – Mould and MildewStain Remover

7681-52-9 ClearTech Industries, Inc. 02/03/2015 224

POWDERED DEFOAMER - POWDEREDDEFOAMER

GENICARE INC. 11/01/2002 235

PURELL Advanced Hand Sanitizer - PURELLAdvanced Hand Sanitizer

GOJO Industries, Inc. 03/18/2015 237

Purple Power - Purple Power Leysons Products, a division of1787528 Ontario Inc.

12/19/2017 252

Scotch-gard Shoe Guard Liquid Shoe Polishwith Water Repellent - Scotch-gard Shoe GuardLiquid Shoe Polish with Water Repellent

3M - Materials Resource Division 02/12/2014 258

ShockWave - ShockWave Fiberlock Technologies, Inc. 04/08/2009 267

Truckmount Descaler - Truckmount Descaler 5329-14-6 PROCHEM - Kärcher NorthAmerica

02/24/2009 269

Ultrapac Trafficlean - Ultrapac Trafficlean PROCHEM - Kärcher NorthAmerica

11/12/2013 273

Product Name CAS Number Manufacturer Version Date Page


SAFETY DATA SHEET

SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

1.1 - Product Identifiers

Catalog Name: SDF-BL-100ML

Description: #2 Diesel Fuel

CAS No.: 68334-30-5

1.2 - Relevant Identified Uses of the Substance or Mixture

Laboratory Chemical Reference Material

1.3 - Supplier Details

Company: AccuStandard, Inc.125 Market St.New Haven, CT 06513 USA

Telephone Number: 203-786-5290

Fax: 203-786-5287

Email: [email protected]

1.4 - Emergency Telephone Number

Emergency Phone #: AccuStandard, Inc.1-203-502-7070 (USA) 1-203-502-7070 (International)

24 hours / 7 days a week

SECTION 2 - HAZARDS IDENTIFICATION

2.1 - GHS Label Elements

2

02

HEALTH

FLAMMABILITY

PHYSICAL HAZARD

2

2

0Signal Word: Warning

Hazard Codes:

H226 - Flammable liquid. (Flammable liquids, category 3)

H302 - Harmful if swallowed. (Acute toxicity, oral, category 4)

H305 - Aspiration hazard if swallowed - may be harmful if swallowed and enters airways. (Aspiration hazard,catagory 2)

H315 - Irritating to skin. (Skin corrosion/irritation, category 2)

H320 - Irritating to eyes. (Eye damage/irritation, category 2B)

H413 - May cause long-term adverse effects in the aquatic environment.

Precautionary Codes:

P202 - This product should only by used by persons trained in the safe handling of hazardous chemicals.

P210 - Store in a cool dry place away from ignition sources.

SDS Date: 4/20/2016 Page 1 of 7


AccuStandard, Inc. Catalog Number: SDF-BL-100MLSAFETY DATA SHEET

SECTION 2 - HAZARDS IDENTIFICATION - continued

2.1 - GHS Label Elements - continued

P260 - Do not breathe vapor.

P262 - Do not get in eyes, on skin or clothing.

P264 - Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readilyavailable.

P284 - Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (seeTLV/PEL), or a risk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved airsupplied respirator is advised. Use a full-face respirator with multi-purpose combination (US) or type ABEK(EN14387) respirator cartridges in absence of proper environmental control. Always use respirators andcomponents tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Engineering and/or administrative controls should be implemented to reduce exposure.

P331 - Ingestion: Do NOT induce vomiting. Call a physician or poison control center immediately. Never giveanything by mouth to an unconscious person.

P338 - Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses andcontinue flushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers.

P360 - Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Getmedical attention if symptoms occur. Wash clothing before reuse.

P404 - Store in a tightly closed container.

2.2 - Other Hazards

2.2.1 - Symptom of Exposure Health/Environment

Flammable liquid. (Flammable liquids, category 3)

Ingestion may cause drowsiness, blood pressure depression, diarrhea, nausea, and decrease in red blood cells.

Aspiration hazard if swallowed - may be harmful if swallowed and enters airways. (Aspiration hazard, catagory 2)

Causes depression of central nervous system.

Inhalation of excessive vapor or mist concentrations may be irritating to the respiratory passages. May causeheadache, dizziness, nausea, vomiting and loss of coordination can result, depending on the concentration andexposure time.

May cause long-term adverse effects in the aquatic environment. (H413)

2.2.2 - Potential Health Effects

Irritating to eyes. (Eye damage/irritation, category 2B)

Irritating to skin. (Skin corrosion/irritation, category 2)

May be harmful if absorbed through the skin. (Acute toxicity, dermal, category 5)

Irritating to mucous membrane and upper respiratory system.

May be harmful if inhaled. (Acute toxicity, inhalation, category 5)

Harmful if swallowed. (Acute toxicity, oral, category 4)

2.2.3 - Routes of Entry

Inhalation, ingestion or skin contact.

2.2.4 - Carcinogenicity

California Proposition 65 cancer hazard.

This product is or contains a component that is not listed (ACGIH, IARC, NTP, OSHA) as a cancer causing agent.

SECTION 3 - COMPOSITION / ANALYTES DATA

Description: #2 Diesel Fuel

Synonyms: N/A




SECTION 3 - COMPOSITION / ANALYTES DATA - continued

Molecular Weight: N/A

Molecular Formula: N/A

EC#: 269-822-7

Index#: 649-224-00-6

ACGIH -TLV (mg/m³) OSHA -PEL (mg/m³)

Analyte CAS Number % Concentration TWA STEL Skin TWA STEL Skin

# 2 Diesel Fuel 68334-30-5 100.000

SECTION 4 - FIRST AID MEASURES

4.1 - First Aid Procedures - General

Get medical assistance for all cases of overexposure.

4.2 - Eye Contact

Eye contact: Immediately flush with plenty of water. After initial flushing, remove and contact lenses and continueflushing for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. (P338)

4.3 - Skin Contact

Skin contact: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medicalattention if symptoms occur. Wash clothing before reuse. (P360)

4.4 - Inhalation

Inhalation: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seekimmediate medical attention.

4.5 - Ingestion

Ingestion: Do NOT induce vomiting. Call a physician or poison control center immediately. Never give anything bymouth to an unconscious person. (P331)

SECTION 5 - FIRE FIGHTING MEASURES

5.1 - Flammable Properties

Vapors can travel to a source of ignition and flash back.

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.

5.2 - Extinguishing Media

Use alcohol foam, carbon dioxide, or dry chemical when fighting fires involving this material.

Water or foam may cause frothing.

Do not spray water directly on oil fire.

Water spray to cool fire-exposed containers and disperse vapors.

5.3 - Protection of Firefighters

As in any fire, wear self-contained breathing apparatus pressure demand, MSHA/NIOSH (approved or equivalent)and full protective gear.




SECTION 6 - ACCIDENTAL RELEASE MEASURES

6.1 - Spill Response

Wear suitable protective equipment listed under Exposure Controls / Personal Protection. Eliminate any ignitionsources until the area is determined to be free from explosion or fire hazards. Contain the release and eliminate itssource, if this can be done without risk. Dispose as hazardous waste. Comply with Federal, State and localregulations.

SECTION 7 - HANDLING AND STORAGE

Store in a tightly closed container. (P404)

Store in a cool dry place away from ignition sources.

Do not breathe vapor. (P260)

Use with adequate ventilation.

Do not get in eyes, on skin or clothing. (P262)

Avoid prolonged or repeated exposure.

This product should only by used by persons trained in the safe handling of hazardous chemicals. (P202)

SECTION 8 - EXPOSURE CONTROLS

8.1 - Engineering Controls/PPE

Wash thoroughly after handling. Do not take internally. Eye wash and safety equipment should be readily available.(P264)

8.2 - General Hygene Considerations

Respiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), or arisk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved air suppliedrespirator is advised. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387)respirator cartridges in absence of proper environmental control. Always use respirators and components testedand approved under appropriate government standards such as NIOSH (US) or CEN (EU). Engineering and/oradministrative controls should be implemented to reduce exposure.

Material should be handled or transferred in an approved fume hood or with adequate ventilation.

Protective gloves should be worn to prevent skin contact.

(Nitrile or equivalent)

Use eye protection tested and approved under the appropriate government standards such as NIOSH (US) or EN166 (EU).

All recommendations are advisory only and must be evaluated by an industrial hygienist and/or safety officer familiarwith the specific situation of anticipated use, such as concentration and amount of the substance in the workplace. Any recommendation should not be construed as offering an approval for any specific use of the product.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Light color to brown oily liquid

Odor: Kerosene-like

Odor Threshold: N/A

pH: N/A

Melting Point: < -38 °C

Boiling Point: 171.5 - 315.5 °C (340 - 600 °F)

Flash Point: 130 °F (54 °C) (tcc)

Evaporation Rate (Butyl Acetate=1): 10-11 (approx.)




SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES - continued

Flammability Class: N/A

Lower Flammability Level: 0.4

Upper Flammability Level: 6

Vapor Pressure: >1 mmHg

Vapor Density (Air = 1): 5 (approx.)

Specific Gravity: 0.85 - 0.93 g/cm3

Solubility in Water: Insoluble

Partition Coefficient: N/A

Autoignition Temperature: 230°C

Decomposition Temperature: N/A

Viscosity: 11 cSt (40 °C)

VOC Content: N/A

Percent Volatile: 99+

SECTION 10 - STABILITY AND REACTIVITY

Stability: Stable

Materials to Avoid: Oxidizers

Hazardous Decomposition: Carbon oxides; Hydrocarbons

Hazardous Polymerization: Will not occur

Condition to Avoid: Heat; Contact with ignition sources

SECTION 11 - TOXICOLOGICAL INFORMATION

Human Health Toxicity

See section 2 for specific toxicological information for the ingredients of this product.

LD50 (Oral): Rat - 490 mg/kg

LD50 (Dermal) : Rabbit - >2000 mg/kg

LC50 (Inhalation): Rat - >20 mg/L

Aspiration hazard if swallowed - may be harmful if swallowed and enters airways. (Aspiration hazard, catagory 2)

No other information related to the toxicological properties of this product is available at this time.

SECTION 12 - ECOLOGICAL INFORMATION

Environmental Toxicity

By complying with sections 6 and 7 there should be no release to the environment.

LC50 (Fish): 35mg/L 96H

EC50 (Aquatic Invertebrate): N/A

BCF: N/A

Readily biodegradable. Contains constituents with the potential to bioaccumulate.

No other information related to the ecological properties of this product is available at this time.




SECTION 13 - DISPOSAL CONSIDERATIONS

Recycle or incinerate at any EPA approved facility or dispose in compliance with Federal, State and localregulations. Empty containers must be triple-rinsed prior to disposal.

SECTION 14 - TRANSPORT INFORMATION

Transportation Information (DOT/IATA)

UN Number: UN1202

Class: 3

Packing Group: III

Proper Shipping Name: Diesel fuel

Poison by Inhalation: No

Marine Pollutant: No

SECTION 15 - REGULATORY INFORMATION

This product is or contains a variable complex mixture of components, principally hydrocarbons, blended toperformance, rather than chemical specifications, and typically contains the following components:Naphtha (petroleum) light-heavy catalytic cracked, full-range reformed/alkylyte, sweetened; Butane; Proprietaryadditives.

May also include varying amounts of the following components:Benzene; Cumene; Cyclohexane; Ethylbenzene; Naphthalene; Hexane; Toluene; Xylene.

All components are listed on the TSCA Inventory.

For laboratory, research and development use only. Not for manufacturing or commercial purposes.

In addition to federal and state regulations, local regulations may apply. Check with your local regulatory authorities.

SECTION 16 - OTHER INFORMATION

This document has been designed to meet the requirements of OSHA, ANSI, GHS and CHIPs regulations. Chemicals are classified using the Globally Harmonized System for Classification and Labeling of Chemicals.

The statements contained herein are offered for informational purposes only and are based on technical data thatwe believe to be accurate. The manufacturer will not assume any liability for the accuracy and completeness of thisinformation. Final determination of the suitability of the material is the responsibility of the user. Although certainhazards are described herein, the user should not presume that these are the only hazards that exist. Sinceconditions and manner of use are outside of the manufacturers control, we make

NO WARRANTY OF MERCHANTABILITY, EXPRESSED OR IMPLIED, AND ASSUME NO LIABILITYRESULTING FROM ITS USE.

Legend : N/A = Not Available ND = Not Determined NR = Not Regulated

Alteration of any information contained herein without written permission from the manufacturer is strictly prohibited.

HMIS/NFPA HAZARD INDEX

0 - Minimal1 - Slight2 - Moderate3 - Serious4 - Severe

* - Additional Hazard




GHS HAZARD INDEX

Category 1 - Most SevereCategory 5 - Least Severe

**** End of Document ****



_____________________________________________________________________________________________The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672

Page 1 of 6

MATERIAL SAFETY DATA SHEETMSDS G-113 REVISION 0

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

The Dial Corporation Medical Emergencies: 1-888-689-908219001 N. Scottsdale Road Chemtrec: 1-800-424-9300 (24 Hours Daily)Scottsdale, Arizona 85255-9672 Other Information: 1-888-468-6673

PRODUCT: Purex® UltraPacks DATE OF ISSUE: September 13,2011

TRADE NAMES/SYNONYMS: Purex® UltraPacks Liquid Laundry Detergent – Free & Clear, Mountain Breeze

CHEMICAL FAMILY: Mixture

I.D. NUMBERS: IDH# 1599132 (F&C); IDH# 1599135 (Mountain Breeze)

SECTION 2: HAZARD IDENTIFICATION

EMERGENCY OVERVIEW

CAUTION: This product is clear to pale yellow or clear blue liquid with a pleasant odor. Direct contact witheyes causes irritation. Harmful if swallowed. Repeated or prolonged excessive exposure with skin can result indefatting and drying which may result in irritation and dermatitis. Keep out of reach of children. No significantenvironmental effects. Not a fire hazard. Product is stable.

This product is labeled in accordance with regulations administered by the Consumer Product Safety Commission.The use pattern and exposure in the workplace are generally not consistent with those experienced by consumers.The requirements of the Occupational Safety and Health Administration applicable to this Material Safety Data Sheetdiffer from the requirements of the CPSC and as a result, this MSDS may contain additional health hazardinformation not pertinent to consumer use and not found on the product label.

REGULATORY STATUS

This material is considered to be hazardous under OSHA’s Hazard Communication Standard (29 CFR 1900.1200).This MSDS should be retained and available for employees and other users of this product.

POTENTIAL HEALTH EFFECTS

NOTE: The acute health effects described below are those which could potentially occur for the finished product.They are based on the toxicology information available for the finished product and/or each hazardous ingredient,and are consistent with the product type and the likelihood of a specific route of exposure. Known chronic healtheffects related to exposure to a specific ingredient are indicated.

EYE CONTACT: This product may cause moderate-to-severe irritation with pain, tearing, and blurred vision.

SKIN CONTACT: Repeated or prolonged excessive exposure can result in defatting and drying of the skin whichmay result in irritation and dermatitis.

INGESTION: Ingestion may cause severe irritation or burns to esophagus, mouth, and stomach with nausea,vomiting and diarrhea.

INHALATION: Unlikely to occur due to the physical properties of the product. Mists may cause respiratorytract irritation.

CHRONIC HEALTH EFFECTS: None known.

MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE: Persons withhistory of chronic skin conditions.

POTENTIAL ENVIRONMENTAL EFFECTS

See Section 12: Ecological Information.


PUREX® ULTRAPACKS MSDS G-113 (Rev. 0) September 13, 2011

The Dial Corporation • 19001 N. Scottsdale Road • Scottsdale, AZ 85255-9672Page 2 of 6

SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS

Based on our hazard evaluation, the following chemical substance(s) in this product have been identified as hazardous.

INGREDIENT CAS NUMBER PERCENT (w/w)

Alcohol Ethoxylates 68213-23-0 / 68551-12-2 30 – 60 %

Alcohol Ether Sulfate 68081-91-4 10 – 30 %

Glycerin 56-81-5 10 – 30 %

Propylene Glycol 57-55-6 5 – 10 %

SECTION 4: FIRST AID MEASURES

EYES: Immediately rinse eyes with plenty of water for at least 15 minutes while holding eyelids open. Get medicalattention if pain or irritation persist.

SKIN: Rinse affected area with large amounts of water until no evidence of product remains. Get medical attention ifirritation persists.

INGESTION: Treat symptomatically and supportively. Maintain airway and respiration. If vomiting occurs, keep headbelow hips to prevent aspiration. Dilution by rinsing the mouth and giving a glass of water to drink is generallyrecommended. If unconscious, the victim should not be given anything to drink. Contact physician or local poisoncontrol center.

INHALATION: Remove from exposure area to fresh air. Keep affected person warm and at rest. Treatsymptomatically and supportively.

NOTE TO PHYSICIAN: The physician's judgment should be used to control symptoms and clinical condition based onthe individual reactions of the patient.

SECTION 5: FIRE FIGHTING MEASURES

FLAMMABLE PROPERTIES

OSHA FLAMMABILITY CLASSIFICATION: Not applicable FLASH POINT: None

UPPER FLAMMABILITY LIMIT: Not applicable LOWER FLAMMABILITY LIMIT: Not applicable

AUTO-IGNITION TEMPERATURE: Not applicable

FIRE AND EXPLOSION HAZARD: Negligible fire hazard when exposed to heat or flame.

HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and oxides of nitrogen.

EXTINGUISHING MEDIA

Dry chemical, carbon dioxide, water spray or regular foam.

PROTECTION OF FIREFIGHTERS

In case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Move containerfrom fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames untilwell after fire is out. Use flooding amounts of water as a fog, solid streams may be ineffective. Avoid breathing vapors;keep upwind.

SECTION 6: ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONSWear skin, eye and respiratory protection as recommended in Section 8. Stop or reduce any leaks if it is safe to do so.Spills present a slipping hazard. Keep unnecessary personnel away. Ventilate spill area if possible. Ensure clean-up isconducted by trained personnel only. Make sure area is slip-free before re-opening to traffic.




ENVIRONMENTAL PRECAUTIONSSmall or household quantities may be disposed in sewer or other liquid waste system. For larger quantities check withyour local water treatment plant.

METHODS FOR CONTAINMENT AND CLEAN UPSMALL SPILLS: Contain and absorb with sand or other absorbent material and place into containers for later disposal.Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement.Recover by pumping or by using a suitable absorbent material and place into containers for later disposal. Dispose insuitable waste container.

SECTION 7: HANDLING AND STORAGE

HANDLING:Avoid contact with eyes, skin and clothing. Do not take internally. Use with adequate ventilation. Avoid generatingaerosols and mists. Keep the containers closed when not in use. Wash thoroughly after handling

STORAGE:Store in original containers in a cool dry area. Store away from excessive heat and incompatible substances. Storageareas for large quantities (warehouse) should be well ventilated. Keep the containers tightly closed when not in use.

SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION

This product is a laundry care product. The use of this product by consumers is safe under normal and reasonableforeseen use. The information provided below refers to the occupational settings.

WORKER EXPOSURE LIMITSThe following exposure limits exist for the ingredients listed below. The TLV-TWA is the ACGIH Threshold Limit Value– Time Weighted Average. TLV-Ceiling Limit is the ACGIH Threshold Limit Value – Ceiling Limit. PEL-TWA is theOSHA Permissible Exposure Limit.

INGREDIENT CAS NUMBER EXPOSURE LIMITGlycerin 56-81-5 TLV-TWA: 10 mg/m3 (mist), PEL-TWA: 5mg/m3 (respirable fraction),

PEL-TWA: 10mg/m3 (total mist)

ENGINEERING CONTROLS: Provide local exhaust or general dilution ventilation to keep potential exposure toairborne contaminants as low as possible.

RESPIRATOR: None required under normal use conditions. If respiratory protection is required, it must be based onthe contamination levels found in the workplace, must not exceed the working limits of the respirator and be jointlyapproved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration(NIOSH-MSHA).

FOR FIRE FIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressuremode. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure demand orother positive-pressure mode.

CLOTHING: Protective clothing (impervious to liquids) is required where splashing of product may occur.

GLOVES: Chemical-resistant gloves are required where repeated or prolonged skin contact may occur.

EYE/FACE PROTECTION: Splash-proof safety glasses are required to prevent eye contact where splashing of productmay occur.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Clear to pale yellow or clear blue liquid.

ODOR/ODOR THRESHOLD: Pleasant fragrance PHYSICAL STATE: Liquid

pH (@ 25°C): 11.0 VAPOR DENSITY: Not available

BOILING POINT: Not available VAPOR PRESSURE: Not available




MELTING/FREEZING POINT: Not available FLASH POINT: See Section 5.

FLAMMABLE PROPERTIES: See Section 5. SOLUBILITY IN WATER: Complete

DENSITY/SPECIFIC GRAVITY: 1.030 g/ml @ 25°C EVAPORATION RATE: Not available

OCTANOL/WATER PARTITION COEFFICIENT (Kow): Not available

VISCOSITY: 350 cps @ 25 C CLOUD POINT: Not determined

SECTION 10: STABILITY AND REACTIVITY

CHEMICAL STABILITY: Stable under normal ambient temperature (70°F, 21°C) and pressure (1 atm).

CONDITIONS TO AVOID: Avoid storing in direct sunlight and avoid extremes of temperature.

INCOMPATIBLE MATERIALS: Strong oxidizers and reducing agents.

HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition products may include oxides of carbon.

POSSIBILITY OF HAZARDOUS REACTIONS: Polymerization does not occur under normal temperatures andpressures.

SECTION 11: TOXICOLOGICAL INFORMATION

PRODUCT INFORMATION SUMMARY: This product is a laundry care product. The use of this product by consumersis safe under normal and reasonable foreseen use. Direct contact with eyes may cause irritation. It may be harmful Ifswallowed. Repeated or prolonged excessive exposure with skin can result in defatting and drying which may result inirritation and dermatitis.

COMPONENT ANALYSIS: The following toxicity information is for the hazardous ingredient(s) when used as technicalgrade and is provided as reference for the occupational settings.

PRODUCT / INGREDIENT LD50 / DRAIZE SCORE TOXICITY / IRRITATION RATING

ACUTE ORAL TOXICITYAlcohol Ethoxylate > 2,000 mg/kg (rat) Practically Non-hazardousGlycerin 12,600 mg/kg (rat) Non-hazardousACUTE DERMAL TOXICITYGlycerin > 10,000 mg/kg (rabbit) Non-hazardous

SENSITIZATION: This product is not considered a skin or respiratory sensitizer.

CARCINOGENICITY: None of the ingredients in this product are listed as carcinogens by the International Agency forResearch on Cancer (IARC), the National Toxicology Program (NTP) or the Occupational Safety and HealthAdministration (OSHA).

MUTAGENICITY: None of the ingredients in this product are known to cause mutagenicity.

REPRODUCTIVE/FETAL/DEVELOPMENTAL TOXICITY: None of the ingredients in this product are known asreproductive, fetal, or developmental hazards.

TARGET ORGAN TOXICITY: None of the ingredients in this product are known to have target organ toxicity.

EPIDEMIOLOGICAL INFORMATION: None of the ingredients in this product are known to have health-relatedinformation in working populations.

SECTION 12: ECOLOGICAL INFORMATION

This product is anticipated to be safe for the environment at concentrations predicted in household settings undernormal use conditions. The following toxicity information is available for the hazardous ingredient(s) when used astechnical grade and is provided as reference for the occupational settings.

PRODUCT / INGREDIENT LC50 / ED50 (mg/L) TOXICITY RATING

VERTEBRATES




Alcohol Ethoxylate 96h LC50: 1 - 10 mg/l (fish) ToxicGlycerin 96-hr LC50: 50 mg/L (Oncorhynchus mykiss) HarmfulPropylene Glycol 96h LC50: 700 mg/l (Pimephales promelas)

(static)Practically Non-hazardous

INVERTEBRATESAlcohol Ethoxylate 48h EC50: 1 - 10 mg/l (Daphnia magna) ToxicGlycerin 24-hr EC50: > 500 mg/L (Daphnia magna) Practically Non-HazardousPropylene Glycol 48h EC50: >1,000 mg/l (Daphnia magna) Practically Non-hazardous

ENVIRONMENTAL FATE: No environmental fate data exists for the product. The product is anticipated to be rapidlybiodegradable.

PERSISTENCE AND DEGRADABILITY: The persistence and degradability of this product has not been determined.

BIOACCUMULATION POTENTIAL: The bioaccumulation potential of this product has not been determined.

MOBILITY: The mobility of this product (in soil and water) has not been determined.

SECTION 13: DISPOSAL CONSIDERATIONS

WASTE NUMBER AND DESCRIPTION: Not applicable, not regulated.

DISPOSAL CONSIDERATIONS: This product is not a RCRA hazardous waste and can be disposed of in accordancewith federal, state and local regulations.

SECTION 14: TRANSPORT INFORMATION

GROUND TRANSPORTDOT Hazard Class: Not regulated Packing Group: Not applicableDOT Proper Shipping Name: Not applicable Shipping Label Information: Not applicableUN/NA Number: Not applicable

AIR TRANSPORT (ICAO/IATA) MARINE TRANSPORT (IMDG/IMO)ICAO/IATA Hazard Class: Not regulated IMDG/IMO Hazard Class: Not regulatedICAO/IATA Proper Shipping Name: Not applicable IMDG/IMO Proper Shipping Name: Not applicable

SECTION 15: REGULATORY INFORMATION

UNITED STATES:

OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200:The Occupational Safety and Health Administration requires Material Safety Data Sheets to provide any hazards thatmay be associated with the product, and make this information available in the workplace. Since the use pattern andexposure in the workplace are generally not consistent with those experienced by consumers, this MSDS may containadditional health hazard information not pertinent to consumer use.

EPA - SARA TITLE III SECTION 313: Not applicable - Consumer product.

EPA CERCLA/SARA TITLE III SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:This product contains no CERCLA/SARA Title III materials. This product contains no hazardous chemicals reportableunder Sections 311/312. This product contains no hazardous chemicals reportable under Section 304.

TSCA: All components of this product are listed on U.S. Toxic Substances Control Act (TSCA) chemical substanceinventory.

STATE REGULATIONSCALIFORNIA PROPOSITION 65: This product does not contain substances listed under California Proposition 65.

CANADA:

CANADIAN ENVIRONMENTAL PROTECTION ACT:INVENTORY STATUS: Some components of this product are not listed on the Canadian Domestic Substances List(DSL) nor the NDSL.




WORKER HAZARDOUS MATERIALS INFORMATION SYSTEM:WHMIS CLASSIFICATION: D2B.

SECTION 16: OTHER INFORMATION

DISCLAIMER: The information contained herein is provided in good faith and is believed to be correct as of the datehereof. However, The Dial Corporation makes no representation as to the comprehensiveness or accuracy of theinformation. It is expected that individuals receiving the information will exercise their independent judgment indetermining its appropriateness for a particular purpose. Accordingly, The Dial Corporation will not be responsible fordamages of any kind resulting from the use of or reliance upon such information. No representations, or warranties,either expressed or implied of merchantability, fitness for a particular purpose or of any other nature is made hereunderwith respect to the information set forth herein or to the product to which the information refers.

NFPA RATINGS (Scale 0-4, where 4=high degree of hazard): HEALTH=1 FLAMMABILITY=1 REACTIVITY=0HMIS RATINGS (Scale 0-4, where 4=severe hazard): HEALTH=2 FLAMMABILITY=1 REACTIVITY=0

MSDS CREATION DATE: 09/13/11SUPERCEDES:REVISION DATE:REVISION:


1-K Kerosene, LS

SAFETY DATA SHEET

Product name

Section 1. Identification

SDS #

Product use Fuel.

Code 10925

Supplier BP Products North America Inc.150 West Warrenville RoadNaperville, Illinois 60563-8460USA

EMERGENCY HEALTH INFORMATION:

1 (800) 447-8735

Outside the US: +1 703-527-3887 (CHEMTREC)

EMERGENCY SPILL INFORMATION:

1 (800) 424-9300 CHEMTREC (USA)

OTHER PRODUCT INFORMATION

1 (866) 4 BP - MSDS (866-427-6737 Toll Free - North America)email: [email protected]

10925

Relevant identified uses of the substance or mixture and uses advised against

Section 2. Hazards identification

FLAMMABLE LIQUIDS - Category 3SKIN IRRITATION - Category 2SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -Category 3ASPIRATION HAZARD - Category 1

Classification of the substance or mixture

Signal word Danger

Hazard statements Flammable liquid and vapor.Causes skin irritation.May be fatal if swallowed and enters airways.May cause drowsiness and dizziness.

Hazard pictograms

Precautionary statements

Prevention Keep away from heat, sparks, open flames and hot surfaces. - No smoking.Do not breathe vapor.Wear protective gloves and eye protection.Avoid release to the environment.

Response IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.IF ON SKIN: Wash with plenty of soap and water.If skin irritation occurs, seek medical advice/attention.

GHS label elements

OSHA/HCS status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Date of issue 12/12/2014.

Page: 1/131-K Kerosene, LS

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Product name Product code

Version 1 Format LanguageUS

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Section 2. Hazards identificationStorage Store in a well-ventilated place. Keep cool.

Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazards not otherwise classified

None known.

Section 3. Composition/information on ingredients

There are no ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Substance/mixture

Occupational exposure limits, if available, are listed in Section 8.

Substance

Kerosene 8008-20-6 100Contains:xylene 1330-20-7 < 1Naphthalene 91-20-3 0.5 - 1

Ingredient name CAS number %

Do not induce vomiting. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.Aspiration hazard if swallowed. Can enter lungs and cause damage. Get medical attention immediately.

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.Eyelids should be held away from the eyeball to ensure thorough rinsing. Check for and remove any contact lenses. Get medical attention.

If inhaled, remove to fresh air. Get medical attention.

If exposure to vapor, mists or fumes causes drowsiness, headache, blurred vision or irritation of the eyes, nose or throat, remove immediately to fresh air. Keep patient warm and at rest. If any symptoms persist obtain medical advice.

Section 4. First aid measures

Eye contact

Inhalation

Ingestion

Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.Product can be aspirated on swallowing or following regurgitation of stomach contents,and can cause severe and potentially fatal chemical pneumonitis, which will require urgent treatment. Because of the risk of aspiration, induction of vomiting and gastric lavage should be avoided. Gastric lavage should be undertaken only after endotracheal intubation. Monitor for cardiac dysrhythmias.

Description of necessary first aid measures

Specific treatments No specific treatment.

Indication of immediate medical attention and special treatment needed, if necessary

See Section 11 for more detailed information on health effects and symptoms.

Most important symptoms/effects, acute and delayed

Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention.



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Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous combustion products

Specific hazards arising from the chemical

Combustion products may include the following:carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)other hazardous substances.

Flammable liquid and vapor. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA)and full turnout gear.

Special protective equipment for fire-fighters

In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray.

Extinguishing media

Do not use water jet.

Suitable extinguishing media

Unsuitable extinguishing media

Special protective actions for fire-fighters

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area.Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Dike spill area and do not allow product to reach sewage system and surface or ground water. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilled product. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres. Dispose of via a licensed waste disposal contractor.

Immediately contact emergency personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Put on appropriate personal protective equipment.Floors may be slippery; use care to avoid falling. Eliminate all ignition sources.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

Large spill

Eliminate all ignition sources. Stop leak if without risk. Move containers from spill area.Absorb with an inert material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor. The method and equipment used must be in conformance with appropriate regulations and industry practice on explosive atmospheres.

Small spill

Methods and materials for containment and cleaning up

For non-emergency personnel

For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapor, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. Wear self-contained breathing apparatus. Wear a suitable chemical protective suit. Chemical resistant boots. See also the information in "For non-emergency personnel".



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Section 7. Handling and storage

Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Store and use only in equipment/containers designed for use with this product. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Light hydrocarbon vapors can build up in the headspace of tanks. These can cause flammability/explosion hazards even at temperatures below the normal flash point (note:flash point must not be regarded as a reliable indicator of the potential flammability of vapor in tank headspaces). Tank headspaces should always be regarded as potentially flammable and care should be taken to avoid static electrical discharge and all ignition sources during filling, ullaging and sampling from storage tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to work procedures. Entry to any tanks or other confined space requires a full risk assessment and appropriate control measures to be put in place in conformance with appropriate regulations and industry practice on confined space entry. When the product is pumped (e.g. during filling,discharge or ullaging) and when sampling, there is a risk of static discharge. Ensure equipment used is properly earthed or bonded to the tank structure. Electrical equipment should not be used unless it is intrinsically safe (i.e. will not produce sparks).Explosive air/vapor mixtures may form at ambient temperature. If product comes into contact with hot surfaces, or leaks occur from pressurized fuel pipes, the vapor or mists generated will create a flammability or explosion hazard. Product contaminated rags,paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use.

Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Take precautionary measures against electrostatic discharges.Avoid contact of spilled material and runoff with soil and surface waterways. Avoid contact with eyes, skin and clothing. Empty containers retain product residue and can be hazardous. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Do not reuse container. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Do not swallow. Aspiration hazard if swallowed. Can enter lungs and cause damage. Never siphon by mouth.

Precautions for safe handling

Kerosene ACGIH TLV (United States). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. Issued/Revised: 1/2003

naphthalene ACGIH TLV (United States). Absorbed through skin. TWA: 52 mg/m³ 8 hours. Issued/Revised:5/1996 TWA: 10 ppm 8 hours. Issued/Revised:5/1996

Section 8. Exposure controls/personal protection

Ingredient name Exposure limits

Control parameters

Occupational exposure limits



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Section 8. Exposure controls/personal protectionOSHA PEL (United States). TWA: 50 mg/m³ 8 hours. Issued/Revised:6/1993 TWA: 10 ppm 8 hours. Issued/Revised:6/1993

xylene ACGIH TLV (United States). STEL: 651 mg/m³ 15 minutes. Issued/Revised: 5/1996 STEL: 150 ppm 15 minutes. Issued/Revised:5/1996 TWA: 434 mg/m³ 8 hours. Issued/Revised:5/1996 TWA: 100 ppm 8 hours. Issued/Revised:5/1996OSHA PEL (United States). TWA: 435 mg/m³ 8 hours. Issued/Revised:6/1993 TWA: 100 ppm 8 hours. Issued/Revised:6/1993

Hand protection Wear chemical resistant gloves. Nitrile gloves.

Do not re-use gloves. Protective gloves must give suitable protection against mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will deteriorate over time due to physical and chemical damage. Inspect and replace gloves on a regular basis. The frequency of replacement will depend upon the circumstances of use.

Recommended: Safety glasses with side shield or chemical goggles.Eye/face protection

Environmental exposure controls

Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Appropriate engineering controls

All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained.Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards.Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits.The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures

Individual protection measures

Skin protection

Consult your supervisor or Standard Operating Procedure (S.O.P) for special handling instructions.

While specific OELs for certain components may be shown in this section, other components may be present in any mist,vapor or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only.



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Use only with adequate ventilation. If ventilation is inadequate, use a NIOSH certified respirator with an organic vapor cartridge and P95 particulate filter.

If operating conditions cause high vapor concentrations or the TLV is exceeded, use NIOSH-certified, supplied-air respirator.

Use with adequate ventilation.In case of insufficient ventilation, wear suitable respiratory equipment.If there is a requirement for the use of a respiratory protective device, but the use of breathing apparatus (independent of ambient atmosphere) is not required, then a suitable filtering device must be worn.The filter class must be suitable for the maximum contaminant concentration (gas/vapor/aerosol/particulates) that may arise when handling the product.The correct choice of respiratory protection depends upon the chemicals being handled,the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions.Recommended: If ventilation is inadequate, use respirator that will protect against organic vapor and dust/mist.

Respiratory protection

Body protection Use of protective clothing is good industrial practice. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing)then chemical resistant aprons and/or impervious chemical suits and boots will be required. Wear suitable protective clothing. Footwear highly resistant to chemicals.When there is a risk of ignition from static electricity, wear anti-static protective clothing.For greatest effectiveness against static electricity, overalls, boots and gloves should all be anti-static. When there is a risk of ignition wear inherently fire resistant protective clothes and gloves. Work clothing / overalls should be laundered on a regular basis.Laundering of contaminated work clothing should only be done by professional cleaners who have been told about the hazards of the contamination. Always keep contaminated work clothing away from uncontaminated work clothing and uncontaminated personal clothes. When the risk of skin exposure is high (from experience this could apply to the following tasks: cleaning work, maintenance and service, filling and transfer, taking samples and cleaning up spillages) then a chemical protective suit and boots will be required. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: Wear clothing and footwear that cannot be penetrated by chemicals or oil.

Other skin protection Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Section 9. Physical and chemical properties

Physical state

Melting point

Vapor pressure

Liquid.

Not available.

Not available.

Hydrocarbon.Odor

pH

Clear (May be dyed)Color

Evaporation rate Not available.Flash point Closed cup: >37.778°C (>100°F) [Tagliabue.]

Not available.

Not available.Odor threshold

Appearance

Boiling point 171.11 to 287.78°C (340 to 550°F)

Flammability (solid, gas)

Lower and upper explosive (flammable) limits

Lower: >0.7%Upper: <5%

Not applicable. Based on - Physical state



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Relative density

Vapor density

Solubility

0.83

Not available.

Insoluble in the following materials: cold water.

Auto-ignition temperature 210°C (410°F)

Not available.

Viscosity Kinematic: 1 to 1.9 mm2/s (1 to 1.9 cSt) at 40°C

Partition coefficient: n-octanol/water

Decomposition temperature Not available.

Density

Solubility

Not available.

insoluble in water.

Section 10. Stability and reactivity

Hazardous decomposition products

Conditions to avoid

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Incompatible materials

Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.Under normal conditions of storage and use, hazardous polymerization will not occur.

Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information.

Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.

Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.halogenated compounds.

Section 11. Toxicological information

Specific target organ toxicity (single exposure)

Kerosene (petroleum) Category 3 Not applicable. Narcotic effectsxylene Category 3 Not applicable. Respiratory tract

irritation

Name Category

Aspiration hazard

Name Result

Kerosene (petroleum) ASPIRATION HAZARD - Category 1xylene ASPIRATION HAZARD - Category 1

Route of exposure

Target organs

Information on toxicological effects

Kerosene (petroleum) - 3 -naphthalene - 2B Reasonably anticipated to be a human carcinogen.xylene - 3 -

Product/ingredient name NTPIARCOSHA

Classification

IARC :2B - Possible carcinogen to human.3 - Not classifiable as a human carcinogen.

NTP :Possible - Reasonably anticipated to be human carcinogens.



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Information on the likely routes of exposure

Can cause central nervous system (CNS) depression. Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or fatal if liquid is aspirated into lungs.

Ingestion

Skin contact Causes skin irritation.

No known significant effects or critical hazards.Eye contact

May be harmful by inhalation if exposure to vapor, mists or fumes resulting from thermal decomposition products occurs. Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis.

General

No known significant effects or critical hazards.Carcinogenicity

No known significant effects or critical hazards.Mutagenicity

No known significant effects or critical hazards.Teratogenicity

Developmental effects No known significant effects or critical hazards.

Fertility effects No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion Adverse symptoms may include the following:nausea or vomiting

Adverse symptoms may include the following:irritationredness

Eye contact Adverse symptoms may include the following:pain or irritationwateringredness

Potential chronic health effects

Delayed and immediate effects and also chronic effects from short and long term exposure

Numerical measures of toxicity

Not available.

Acute toxicity estimates

Routes of entry anticipated: Oral, Dermal, Inhalation.

Potential acute health effects

Potential immediate effects

May be harmful by inhalation if exposure to vapor, mists or fumes resulting from thermal decomposition products occurs. Vapor, mist or fume may irritate the nose, mouth and respiratory tract.

Short term exposure

Potential delayed effects Not available.


Not available.

Long term exposure

Potential delayed effects Not available.

Inhalation Can cause central nervous system (CNS) depression. May cause drowsiness and dizziness.

Inhalation Adverse symptoms may include the following:nausea or vomitingheadachedrowsiness/fatiguedizziness/vertigounconsciousness



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Section 11. Toxicological informationAspiration of this product into the lungs can cause chemical pneumonia and can be fatal.Aspiration into the lungs can occur while vomiting after ingestion of this product. Do not siphon by mouth.

Other information

Additional information Middle distillate: From skin-painting studies of petroleum distillates of similar composition and distillate range, it has been shown that these types of materials often possess weak carcinogenic activity in laboratory animals. In these tests, the material is painted on the shaved backs of mice twice a week for their lifetime. The material is not washed off between applications. Therefore, there may be a potential risk of skin cancer from prolonged or repeated skin contact with this product in the absence of good personal hygiene. This particular product has not been tested for carcinogenic activity, but we have chosen to be cautious in light of the findings with other distillate streams.

Occasional skin contact with this product is not expected to have serious effects, but good personal hygiene should be practiced and repeated skin contact avoided. This product can also be expected to produce skin irritation upon prolonged or repeated skin contact. Personal hygiene measures taken to prevent skin irritation are expected to be adequate to prevent risk of skin cancer.

Diesel exhaust particulates have been classified by the National Toxicological Program (NTP) to be a reasonably anticipated human carcinogen. Exposure should be minimized to reduce potential risk.

Naphthalene has been reported to cause developmental toxicity in mice after oral exposure to relatively high dose levels, but developmental toxicity was not observed in NTP (National Toxicology Program) sponsored studies in rats and rabbits. Ingestion or inhalation of naphthalene can result in hemolysis and other blood abnormalities, and individuals (and infants) deficient in glucose-6-phosphate dehydrogenase may be especially susceptible to these effects. Inhalation of naphthalene may cause headache and nausea. Airborne exposure can result in eye irritation. Naphthalene exposure has been associated with cataracts in animals and humans.

Xylenes: Xylene has been reported to cause central nervous system effects at concentrations above the recommended exposure limit. Xylene vapor becomes irritating at relatively high levels. In one study, eye irritation was reported at exposures of 460 ppm and in one person at 230 ppm after 15 minutes. In another study, no one reported eyes, nose and throat irritation at mixed xylene exposures up to 230 ppm for 30 minutes.Dermal LD50 is expected to be greater than 10g/kg in rabbits, based on test results from similar materials.

Mixed xylenes caused slight hearing loss in rats exposed to 800 ppm in the air for 14 hours/day for six weeks. There is no information available for lower concentrations;however, similar chemicals that have caused these hearing effects at similar concentrations have not caused effects at lower concentrations.

Pregnant animals exposed to xylene or its isomers have been reported to cause development toxicity in rodents when exposed by inhalation. The developmental effects observed consisted of delayed development and minor skeletal variations, but no malformations. Because of the high exposure levels used in these studies, we do not believe that these results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure limits.

Xylene and its isomers are not genotoxic.

Technical grade xylene has been tested in a National Toxicology Program carcinogenicity study in rats and mice dosed orally for two years. There was no evidence of carcinogenicity.



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Section 12. Ecological information

Mobility Spillages may penetrate the soil causing ground water contamination.

Bioaccumulative potential

Toxicity

Persistence and degradability

Soil/water partition coefficient (KOC)

Not available.

Mobility in soil

No testing has been performed by the manufacturer.

Inherently biodegradable

This product is not expected to bioaccumulate through food chains in the environment.

Other ecological information Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.

Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Disposal methods

United States - RCRA Toxic hazardous waste "U" List

Naphthalene 91-20-3 Listed U165Xylene 1330-20-7 Listed U239

Ingredient CAS # Status Reference number

Section 14. Transport information

3

KEROSENE

3

KEROSENE

UN1223

3

UN1223 UN1223

DOT Classification

IMDG IATA

UN number

UN proper shipping name

Transport hazard class(es)

TDG Classification

UN1223

KEROSENE

3

Kerosene



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Section 14. Transport informationIII III III

This product may be re-classified as "Combustible Liquid," unless transported by vessel or aircraft. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials in package sizes less than the product reportable quantity.

Reportable quantity100 lbs / 45.4 kg [14.45 gal /54.699 L]Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity)transportation requirements.

RemarksPassenger aircraft: 60L Cargo Aircraft Only: 220L

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

Emergency schedules (EmS)F-E, S-E

The environmentally hazardous substance mark may appear if required by other transportation regulations.

Packing group

Additional information

Environmental hazards

Special precautions for user

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No. Yes. No.

Not available.

MARPOL Annex 1 rules apply for bulk shipments by sea.Category: gas oils, including ship's bunkers

Proper shipping name

III

No.

-



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Section 15. Regulatory informationU.S. Federal regulations

The following components are listed: KEROSINE; NAPHTHALENE; XYLENEMassachusetts

SARA 313

Product name CAS number Concentration

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

naphthalene 91-20-3 0.5 - 1xylene 1330-20-7 0 - 1

naphthalene 91-20-3 0.5 - 1xylene 1330-20-7 0 - 1

Form R - Reporting requirements

Supplier notification

New Jersey The following components are listed: KEROSENE; FUEL OIL #1; NAPHTHALENE;MOTH FLAKES; XYLENES; BENZENE, DIMETHYL-

Pennsylvania The following components are listed: KEROSINE (PETROLEUM); NAPHTHALENE;BENZENE, DIMETHYL-

State regulations

SARA 302/304

No products were found.

Composition/information on ingredients

SARA 311/312

Classification Fire hazardImmediate (acute) health hazardDelayed (chronic) health hazard

Other regulations

All components are listed or exempted.United States inventory (TSCA 8b)

All components are listed or exempted.

All components are listed or exempted.

All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.

China inventory (IECSC)

Japan inventory (ENCS)

Korea inventory (KECI)

Philippines inventory (PICCS)

Australia inventory (AICS)

California Prop. 65 WARNING: This product contains a chemical known to the State of California to cause cancer.naphthalene

Canada inventory All components are listed or exempted.

REACH Status For the REACH status of this product please consult your company contact, as identified in Section 1.

Section 16. Other informationHazardous Material Information System (U.S.A.)

2

2

0

*

National Fire Protection Association (U.S.A.)

Health

Flammability

Physical hazards

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.

Personal protection X



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Section 16. Other information

History

Date of issue/Date of revision

Notice to reader

Date of previous issue

Indicates information that has changed from previously issued version.

Key to abbreviations ACGIH = American Conference of Industrial HygienistsATE = Acute Toxicity EstimateBCF = Bioconcentration FactorCAS Number = Chemical Abstracts Service Registry NumberGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)OEL = Occupational Exposure LimitSDS = Safety Data SheetSTEL = Short term exposure limitTWA = Time weighted averageUN = United NationsUN Number = United Nations Number, a four digit number assigned by the United Nations Committee of Experts on the Transport of Dangerous Goods.

12/12/2014.

No previous validation.

02

2Health

Special

Instability/Reactivity

Flammability

All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material.Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited.



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HR2-831 www.hamptonresearch.com Page 1 of 9

Safety Data SheetRevision Date: 01/10/2017

Version: 1.1 Date Printed:

SECTION 1: Identification of the substance/mixture and of the company/undertaking

According to Regulation (EC) No 1907/2006

1.1 Product identifiers Product Name : 1.0 M Citric acid Product Number : HR2-831 REACH No. : A registration number is not available for this substance as the substance

or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.

CAS Number : 77-92-9

1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances.

1.3 Details of the supplier of the Safety Data Sheet Company : Hampton Research 34 Journey

Aliso Viejo, CA 92656-3317 United States

Telephone : 949 425 1321 Telephone technical support is available 8:00 a.m. to 4:30 p.m. USA Pacific Standard Time.

Fax : 949 425 1611 Fax Technical Support is available 24 hours a day.

e-mail : [email protected] e-mail Technical Support is available 24 hours a day.

1.4 Emergency telephone number Emergency phone : 949 425 1321 For CHEMTREC Assistance : 800 424 9300 For CHEMTREC Assistance : 703 527 3887 (International)

SECTION 2: Hazards Identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 Eye irritation (Category 2)

Classification according to EU Directives 67/548/EEC or 1999/45/EC Irritating to eyes.

2.2 Label elements Labelling according Regulation (EC) No 1272/2008 [CLP]

GENERIC EU MSDS - NO COUNTRY SPECIFIC DATA - NO OEL DATA



Pictogram :

Signal word : Warning

Hazard statement(s) H319 : Causes serious eye irritation.

Precautionary statement(s) P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

Supplemental Hazard Statements

: none

According to European Directive 67/548/EEC as amended. Hazard symbol(s) :

R-phrase(s)

R36 : Irritating to eyes.

S-phrase(s)

S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

2.3 Other hazards - none

(CONTINUED) - SECTION 2: Hazards Identification

SECTION 3: Composition/Information on Ingredients

3.1 Substances

RTECS Merck Beilstein SARA MDL # PubChem Substance IDGE7350000 14,2326 782061 No MFCD00011669 24856611

Synonym : Citric acid anhydrous Formula : C6H8O7 or HOC(COOH)(CH2COOH)2

Molecular Weight : 192.13 CAS Number : 77-92-9 EC Number : 201-069-1

Component ConcentrationCitric acid CAS-No. 77-92-9 EC-No. 201-069-1

-



SECTION 4: First Aid Measures

4.1 Description of first aid measures General Advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact Wash off with soap and plenty of water. Consult a physician.

In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes as a precaution and consult a physician.

If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed Vomiting, Diarrhoea, Damage to tooth enamel., Dermatitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. The most important known symptoms and effects are described in the labeling (see Section 2.2) and/or in Section 11.

4.3 Indication of any immediate medical attention and special treatment needed no data available

SECTION 5: Fire Fighting Measures

5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Special hazards arising from the substance or mixture Carbon oxides

5.3 Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary.

5.4 Further Information no data available

SECTION 6: Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Ensure adequate ventilation. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.



(CONTINUED) - SECTION 6: Accidental Release Measures

6.3 Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

6.4 Reference to other sections For disposal see section 13.

SECTION 7: Handling and Storage

7.1 Personal Precautions Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Normal measures for preventive fire protection. For precautions see section 2.2. Normal measures for preventive fire protection.

7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.

SECTION 8: Exposure Controls/Personal Protection

8.1 Control parameters Components with workplace control parameters

8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

Personal protective equipmentEye/face protectionFace shield and safety glasses Use equipment for eye protection tested and approved underappropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove’s outer surface) to avoid skin contact with this product. Dispose of contami-nated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Immersion protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 480 min Material tested:Dermatril® (Aldrich Z677272, Size M)



(CONTINUED) - SECTION 8: Exposure Controls/Personal Protection

Splash protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 30 min Material tested:Dermatril® (Aldrich Z677272, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail [email protected],test method: EN374If used in solution, or mixed with other substances, and under conditions which differ from EN 374,contact the supplier of the CE approved gloves. This recommendation is advisory only and must beevaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipateduse by our customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

SECTION 9: Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

a) Appearance Form: Fine Crystals Color: White b) Odor no data available c) Odor Threshold no data available d) pH 1.2 - 1.5 at 25°C e) Melting point/freezing point 153 - 159°C (lit.) f) Initial boiling point and boiling range

no data available

g) Flash point no data available h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits

no data available

k) Vapor pressure no data available l) Vapor density no data available m) Relative density no data available n) Water solubility no data available



(CONTINUED) - SECTION 9: Physical and Chemical Properties

o) Partition coefficient: noctanol/water

no data available

p) Autoignition temperature no data available

q) Decomposition temperature

no data available

r) Viscosity no data available

s) Explosive properties no data available

t) Oxidizing properties no data available

9.2 Other safety information Surface tension no data available Relative vapour density no data available

10.1 Reactivity no data available

10.2 Chemical stability no data available

10.3 Possibility of hazardous reactions no data available

10.4 Conditions to avoid no data available

10.5 Incompatible materials Oxidizing agents, Bases, Reducing agents, Nitrates

10.6 Hazardous decomposition products Other decomposition products - no data available

In the event of fire: see section 5

SECTION 10: Stability and Reactivity

SECTION 11: Toxicological Information

11.1 Information on toxicological effects Acute toxicity LD50 Oral - rat - 5.400 mg/kg

LD50 Dermal - rat - > 2.000 mg/kg

Skin irritation / corrosion Skin - rabbit - Mild skin irritation - OECD Test Guideline 404



(CONTINUED) - SECTION 11: Toxicological Information

Serious eye damage/eye irritation Eyes - rabbit - Irritating to eyes. - OECD Test Guideline 405

Respiratory or skin sensitization Prolonged or repeated exposure may cause allergic reactions in certain sensitive individuals.

Germ cell mutagenicity no data available

Chronic exposure

IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

Reproductive toxicity no data available

Specific target organ toxicity - single exposure Inhalation - May cause respiratory irritation.

Specific target organ toxicity - repeated exposure no data available

Aspiration hazard no data available

Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes Causes serious eye irritation.

Signs and Symptoms of Exposure Vomiting, Diarrhoea, Damage to tooth enamel., Dermatitis. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Additional information RTECS: GE7350000

SECTION 12: Ecological Information

12.1 Toxicity Toxicity to fish mortality LC50 - Leuciscus idus melanotus - 440 mg/l - 48 h Method: OECD Test Guideline 203

Toxicity to daphnia and static test - Daphnia magna (Water flea) - 1.535 mg/l - 24 h other aquatic invertebrates



(CONTINUED) - SECTION 12: Ecological Information

12.2 Persistence and degradability no data available

12.3 Bioaccumulative potential no data available

12.4 Mobility in soil no data available

12.5 Results of PBT and vPvB assessment no data available

12.6 Other adverse effects no data available

SECTION 13: Disposal Considerations

13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated packaging Dispose of as unused product.

SECTION 14: Transportation Information

14.1 UN number ADR/RID: - IMDG: - IATA: -

14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods

14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: -

14.4 Packaging group ADR/RID: - IMDG: - IATA: -

14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no

14.6 Special precautions for user no data available



SECTION 16: Other Information

DISCLAIMERFor research use only. Not for drug, household, or other use.

WARRANTYThe above information is believed to be correct but does no purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of this product. Hampton Research Corp., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and condi-tions of sale.License granted to make unlimited paper copies for internal use only.

© 1991-2017 Hampton Research Corp.

SECTION 15: Regulatory Information

This safety datasheet complies with the requirements of Regulation (EC) No 1907/2006.

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture no data available

15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out.


3M™ Hi-Strength 90 Bulk Adhesive, Clear 12/06/17

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Safety Data Sheet

Copyright,2017,3M Company.All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 09-2094-2 Version Number: 12.00Issue Date: 12/06/17 Supercedes Date: 03/18/16

SECTION 1: Identification

1.1. Product identifier3M™ Hi-Strength 90 Bulk Adhesive, Clear

Product Identification Numbers62-4479-7536-8, 62-4479-8532-6, 62-4479-9532-5

1.2. Recommended use and restrictions on use

Recommended useAdhesive, Industrial use

1.3. Supplier’s detailsMANUFACTURER: 3MDIVISION: Industrial Adhesives and Tapes DivisionADDRESS: 3M Center, St. Paul, MN 55144-1000, USATelephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classificationFlammable Liquid: Category 2.Serious Eye Damage/Irritation: Category 2A.Specific Target Organ Toxicity (single exposure): Category 3.

2.2. Label elementsSignal wordDanger

SymbolsFlame | Exclamation mark |

Pictograms



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Hazard StatementsHighly flammable liquid and vapor.

Causes serious eye irritation. May cause drowsiness or dizziness.

Precautionary Statements

Prevention:Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Wash thoroughly after handling.

Response:IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

Storage:Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up.

Disposal:Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

SECTION 3: Composition/information on ingredients

Ingredient C.A.S. No. % by WtAcetone 67-64-1 25 - 35 Trade Secret *Non-Volatile Components Trade Secret* 20 - 30 Trade Secret *Cyclohexane 110-82-7 15 - 25 Trade Secret *Pentane 109-66-0 15 - 25 Trade Secret *Cyclopentane 287-92-3 < 2 Trade Secret *Isopentane 78-78-4 < 2 Trade Secret *



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*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation:Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.

Eye Contact:Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention.

If Swallowed:Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment requiredNot applicable

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing mediaIn case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

5.2. Special hazards arising from the substance or mixtureClosed containers exposed to heat from fire may build pressure and explode.

Hazardous Decomposition or By-Products Substance ConditionAldehydes During CombustionHydrocarbons During CombustionCarbon monoxide During CombustionCarbon dioxide During CombustionToxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fightersWater may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresEvacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and



__________________________________________________________________________________________

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could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautionsAvoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.

6.3. Methods and material for containment and cleaning upContain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations.

SECTION 7: Handling and storage

7.1. Precautions for safe handlingFor industrial or professional use only. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer.

7.2. Conditions for safe storage including any incompatibilitiesStore in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limitsIf a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component.Ingredient C.A.S. No. Agency Limit type Additional CommentsPentane 109-66-0 ACGIH TWA:1000 ppmPentane 109-66-0 OSHA TWA:2950 mg/m3(1000 ppm)Cyclohexane 110-82-7 ACGIH TWA:100 ppmCyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm)Cyclopentane 287-92-3 ACGIH TWA:600 ppmAcetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human

carcinAcetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm)Isopentane 78-78-4 ACGIH TWA:1000 ppm

ACGIH : American Conference of Governmental Industrial HygienistsAIHA : American Industrial Hygiene AssociationCMRG : Chemical Manufacturer's Recommended GuidelinesOSHA : United States Department of Labor - Occupational Safety and Health AdministrationTWA: Time-Weighted-Average



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STEL: Short Term Exposure LimitCEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controlsUse general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended:Indirect Vented Goggles

Skin/hand protectionSelect and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing.Gloves made from the following material(s) are recommended: FluoroelastomerNitrile Rubber


An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulatesHalf facepiece or full facepiece supplied-air respiratorOrganic vapor respirators may have short service life.

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical propertiesGeneral Physical Form: Liquid Odor, Color, Grade: clear-light yellow, mild solvent odorOdor threshold No Data AvailablepH Not ApplicableMelting point Not ApplicableBoiling Point 36 ºCFlash Point -40 ºF [Test Method:Closed Cup]Evaporation rate 28 [Ref Std:ETHER=1]Flammability (solid, gas) Not ApplicableFlammable Limits(LEL) 1.6 % volumeFlammable Limits(UEL) 9.4 % volumeVapor Pressure <=500 mmHg [@ 18.5 ºC]Vapor Density >=1 [Ref Std:AIR=1]Density 0.77 g/mlSpecific Gravity 0.77 [Ref Std:WATER=1]



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Solubility in Water NilSolubility- non-water No Data AvailablePartition coefficient: n-octanol/ water No Data AvailableAutoignition temperature No Data AvailableDecomposition temperature No Data AvailableViscosity 100 - 500 centipoise [@ 73.4 ºF ]Hazardous Air Pollutants 0 % weight [Test Method:Calculated]Molecular weight No Data AvailableVOC Less H2O & Exempt Solvents <=531 g/l [Test Method:calculated SCAQMD rule 443.1]Solids Content 20 - 30 %

SECTION 10: Stability and reactivity

10.1. ReactivityThis material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stabilityStable.

10.3. Possibility of hazardous reactionsHazardous polymerization will not occur.

10.4. Conditions to avoidHeatSparks and/or flames

10.5. Incompatible materialsStrong oxidizing agents

10.6. Hazardous decomposition productsSubstance Condition None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information

The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.



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May cause additional health effects (see below).

Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.

Eye Contact:Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Single exposure may cause target organ effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

Toxicological DataIf a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute ToxicityName Route Species ValueOverall product Dermal No data available; calculated ATE >5,000 mg/kgOverall product Inhalation-

Vapor(4 hr)No data available; calculated ATE >50 mg/l

Overall product Ingestion No data available; calculated ATE >5,000 mg/kgAcetone Dermal Rabbit LD50 > 15,688 mg/kgAcetone Inhalation-

Vapor (4 hours)

Rat LC50 76 mg/l

Acetone Ingestion Rat LD50 5,800 mg/kgPentane Dermal Rabbit LD50 3,000 mg/kgPentane Inhalation-

Vapor (4 hours)

Rat LC50 > 18 mg/l

Pentane Ingestion Rat LD50 > 2,000 mg/kgCyclohexane Dermal Rat LD50 > 2,000 mg/kgCyclohexane Inhalation-

Vapor (4 hours)

Rat LC50 > 32.9 mg/l

Cyclohexane Ingestion Rat LD50 6,200 mg/kgNon-Volatile Components Dermal Rabbit LD50 > 2,000 mg/kgNon-Volatile Components Ingestion Rat LD50 > 5,000 mg/kgIsopentane Dermal Rabbit LD50 3,000 mg/kgIsopentane Inhalation-

Vapor (4 hours)

Rat LC50 > 18 mg/l

Isopentane Ingestion Rat LD50 > 2,000 mg/kgCyclopentane Dermal LD50 estimated to be > 5,000 mg/kgCyclopentane Inhalation-

Vapor (4 hours)

Rat LC50 > 25.3 mg/l

Cyclopentane Ingestion Rat LD50 > 5,000 mg/kgATE = acute toxicity estimate



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Skin Corrosion/IrritationName Species Value

Acetone Mouse Minimal irritationPentane Rabbit Minimal irritationCyclohexane Rabbit Mild irritantNon-Volatile Components Professio

nal judgement

No significant irritation

Isopentane Rabbit Minimal irritationCyclopentane Rabbit Minimal irritation

Serious Eye Damage/IrritationName Species Value

Acetone Rabbit Severe irritantPentane Rabbit Mild irritantCyclohexane Rabbit Mild irritantIsopentane Rabbit Mild irritantCyclopentane Rabbit Mild irritant

Skin SensitizationName Species ValuePentane Guinea

pigNot classified

Isopentane Guinea pig

Not classified

Respiratory SensitizationFor the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell MutagenicityName Route Value

Acetone In vivo Not mutagenicAcetone In Vitro Some positive data exist, but the data are not

sufficient for classificationPentane In vivo Not mutagenicPentane In Vitro Some positive data exist, but the data are not

sufficient for classificationCyclohexane In Vitro Not mutagenicCyclohexane In vivo Some positive data exist, but the data are not

sufficient for classificationIsopentane In vivo Not mutagenicIsopentane In Vitro Some positive data exist, but the data are not

sufficient for classification

CarcinogenicityName Route Species ValueAcetone Not

SpecifiedMultiple animal species

Not carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental EffectsName Route Value Species Test Result Exposure

DurationAcetone Ingestion Not classified for male reproduction Rat NOAEL 1,700

mg/kg/day13 weeks

Acetone Inhalation Not classified for development Rat NOAEL 5.2 during



__________________________________________________________________________________________

Page 9 of 13

mg/l organogenesis

Pentane Ingestion Not classified for development Rat NOAEL 1,000 mg/kg/day

during organogenesis

Pentane Inhalation Not classified for development Rat NOAEL 30 mg/l


Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 mg/l

2 generation

Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l

2 generation

Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l

2 generation

Isopentane Ingestion Not classified for development Rat NOAEL 1,000 mg/kg/day


Isopentane Inhalation Not classified for development Rat NOAEL 30 mg/l


Target Organ(s)

Specific Target Organ Toxicity - single exposureName Route Target Organ(s) Value Species Test Result Exposure

DurationAcetone Inhalation central nervous

system depressionMay cause drowsiness or dizziness

Human NOAEL Not available

Acetone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification


Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l

6 hours

Acetone Inhalation liver Not classified Guinea pig

NOAEL Not available

Acetone Ingestion central nervous system depression

May cause drowsiness or dizziness


poisoning and/or abuse

Pentane Inhalation central nervous system depression


Multiple animal species

NOAEL Not available

not available

Pentane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

Not available

NOAEL Not available

not available

Pentane Inhalation cardiac sensitization Not classified Dog NOAEL Not available

not available

Pentane Ingestion central nervous system depression


Professional judgement

NOAEL Not available

not available

Cyclohexane Inhalation central nervous system depression


Human and animal

NOAEL Not available

Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

Human and animal

NOAEL Not available

Cyclohexane Ingestion central nervous system depression



NOAEL Not available

Isopentane Inhalation central nervous system depression


Multiple animal species

NOAEL Not available

not available

Isopentane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification

Not available

NOAEL Not available

not available

Isopentane Inhalation cardiac sensitization Not classified Dog NOAEL Not not available



__________________________________________________________________________________________

Page 10 of 13

available Isopentane Ingestion central nervous

system depressionMay cause drowsiness or dizziness


NOAEL Not available

not available

Cyclopentane Inhalation central nervous system depression


similar compounds

NOAEL Not available

Cyclopentane Ingestion central nervous system depression



NOAEL Not available

Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test Result Exposure

DurationAcetone Dermal eyes Not classified Guinea

pigNOAEL Not available

3 weeks

Acetone Inhalation hematopoietic system

Not classified Human NOAEL 3 mg/l

6 weeks

Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l

6 days

Acetone Inhalation kidney and/or bladder

Not classified Guinea pig

NOAEL 119 mg/l

not available

Acetone Inhalation heart | liver Not classified Rat NOAEL 45 mg/l

8 weeks

Acetone Ingestion kidney and/or bladder

Not classified Rat NOAEL 900 mg/kg/day

13 weeks

Acetone Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day

13 weeks

Acetone Ingestion hematopoietic system

Not classified Rat NOAEL 200 mg/kg/day

13 weeks

Acetone Ingestion liver Not classified Mouse NOAEL 3,896 mg/kg/day

14 days

Acetone Ingestion eyes Not classified Rat NOAEL 3,400 mg/kg/day

13 weeks

Acetone Ingestion respiratory system Not classified Rat NOAEL 2,500 mg/kg/day

13 weeks

Acetone Ingestion muscles Not classified Rat NOAEL 2,500 mg/kg

13 weeks

Acetone Ingestion skin | bone, teeth, nails, and/or hair

Not classified Mouse NOAEL 11,298 mg/kg/day

13 weeks

Pentane Inhalation peripheral nervous system

Not classified Human NOAEL Not available

occupational exposure

Pentane Inhalation heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory system

Not classified Rat NOAEL 20 mg/l

13 weeks

Pentane Ingestion kidney and/or bladder

Not classified Rat NOAEL 2,000 mg/kg/day

28 days

Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l

90 days

Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 90 days



__________________________________________________________________________________________

Page 11 of 13

mg/lCyclohexane Inhalation kidney and/or

bladderNot classified Rabbit NOAEL 2.7

mg/l10 weeks

Cyclohexane Inhalation hematopoietic system

Not classified Mouse NOAEL 24 mg/l

14 weeks

Cyclohexane Inhalation peripheral nervous system

Not classified Rat NOAEL 8.6 mg/l

30 weeks

Isopentane Inhalation peripheral nervous system

Not classified Human NOAEL Not available

occupational exposure

Isopentane Inhalation heart | skin | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | muscles | nervous system | eyes | kidney and/or bladder | respiratory system

Not classified Rat NOAEL 20 mg/l

13 weeks

Isopentane Ingestion kidney and/or bladder

Not classified Rat NOAEL 2,000 mg/kg/day

28 days

Aspiration HazardName ValuePentane Aspiration hazardCyclohexane Aspiration hazardIsopentane Aspiration hazardCyclopentane Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.

SECTION 12: Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.

SECTION 13: Disposal considerations

13.1. Disposal methodsDispose of contents/ container in accordance with the local/regional/national/international regulations.

Incinerate in a permitted waste incineration facility. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): D001 (Ignitable)



__________________________________________________________________________________________

Page 12 of 13

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal RegulationsContact 3M for more information.

EPCRA 311/312 Hazard Classifications:Physical HazardsFlammable (gases, aerosols, liquids, or solids)

Health Hazards

Serious eye damage or eye irritationSpecific target organ toxicity (single or repeated exposure)

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by WtCyclohexane 110-82-7 Trade Secret 15 - 25

15.2. State Regulations Contact 3M for more information.

15.3. Chemical InventoriesThe components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information

NFPA Hazard ClassificationHealth: 2 Flammability: 4 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.


DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES



__________________________________________________________________________________________

Page 13 of 13

NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M

3M USA SDSs are available at www.3M.com


SAFETY DATA SHEET

A07265 ZEP SS CLEANER ZUSCP16 STK 20N16

Version 1.0 Revision Date 05/05/2015 Print Date 05/26/2015

1 / 10

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Material name : A07265 ZEP SS CLEANER ZUSCP16 STK 20N16 Material number : 000000000001041003

Manufacturer or supplier's details

Company : Zep Inc.

Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318

Telephone : 404-352-1680

Emergency telephone numbers

For SDS Information : Compliance Services 1-877-428-9937

For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded

For a Transportation Emergency

: CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616

Note: This product is labeled as a consumer product in accordance with the United States Consumer Product Safety Commission regulations. The warnings presented below in this Safety Data Sheet (SDS) comply with the 2012 OSHA Hazard Communication Standard (GHS - Globally

Harmonized System of Classification and Labeling). The requirements for the labeling and warnings of consumer products may differ from those required for GHS based hazard communication.

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Appearance Aerosol containing a liquefied gas

Colour opaque

Odour pleasant

GHS Classification

Flammable aerosols : Category 1 Gases under pressure : Liquefied gas

GHS Label element

Hazard pictograms :

Signal word : Danger

Hazard statements : H222 Extremely flammable aerosol.

H280 Contains gas under pressure; may explode if heated.

Precautionary statements : Prevention:

P210 Keep away from heat, hot surfaces, sparks, open flames

and other ignition sources. No smoking.


SAFETY DATA SHEET



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P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after

use. Storage: P410 + P412 Protect from sunlight. Do not expose to

temperatures exceeding 50 °C/ 122 °F.

Potential Health Effects

Carcinogenicity:

IARC No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH No component of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.

OSHA No component of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Hazardous components

Chemical Name CAS-No. Concentration [%]

alkanes, C12-14-iso- 68551-19-9 >= 10 - < 20

butane 106-97-8 >= 10 - < 20

propane 74-98-6 >= 1 - < 5

SECTION 4. FIRST AID MEASURES

General advice : Move out of dangerous area.

Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.

If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.

In case of skin contact : If on clothes, remove clothes.

If skin irritation persists, call a physician.

Wash off immediately with plenty of water for at least 15 minutes.

In case of eye contact : Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing.

If eye irritation persists, consult a specialist.


SAFETY DATA SHEET



3 / 10

If in eyes, rinse with water for 15 minutes.

If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

DO NOT induce vomiting unless directed to do so by a physician or poison control center.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Alcohol-resistant foam

Carbon dioxide (CO2) Dry chemical Water spray jet


: High volume water jet

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion

products

: Carbon dioxide (CO2)

Carbon monoxide Smoke Silicon oxides

Specific extinguishing methods

:

Use extinguishing measures that are appropriate to local

circumstances and the surrounding environment.

Further information : For safety reasons in case of fire, cans should be stored

separately in closed containments. Use a water spray to cool fully closed containers.

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if necessary.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions,

protective equipment and emergency procedures

: Ensure adequate ventilation.

Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive

concentrations. Vapours can accumulate in low areas.

Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.


: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Sweep up or vacuum up spillage and collect in suitable container for disposal.


SAFETY DATA SHEET



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SECTION 7. HANDLING AND STORAGE

Advice on safe handling : For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the

application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms.

Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations.

Always replace cap after use. Do not breathe vapours or spray mist.

Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 °C. Do not open by force or throw into fire even after use. Do not spray on flames or

red-hot objects. No smoking. Observe label precautions.

Keep in a dry, cool and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards.

Materials to avoid : Do not store near acids.

Oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value type (Form of

exposure)

Control parameters /

Permissible concentration

Basis

butane 106-97-8 TWA 800 ppm

1,900 mg/m3

NIOSH REL

TWA 800 ppm 1,900 mg/m3

OSHA P0

propane 74-98-6 TWA 1,000 ppm ACGIH

TWA 1,000 ppm 1,800 mg/m3

NIOSH REL

TWA 1,000 ppm 1,800 mg/m3

OSHA Z-1

TWA 1,000 ppm

1,800 mg/m3

OSHA P0

Personal protective equipment

Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.


SAFETY DATA SHEET



5 / 10

Hand protection

Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Eye protection : Ensure that eyewash stations and safety showers are close to the workstation location. Tightly fitting safety goggles

Skin and body protection : impervious clothing

Choose body protection according to the amount and

concentration of the dangerous substance at the work place.

Hygiene measures : Wash hands before breaks and at the end of workday.

When using do not smoke. When using do not eat or drink.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Aerosol containing a liquefied gas

Colour : opaque

Odour : pleasant

Odour Threshold : no data available

pH : not applicable

Melting point/freezing point : no data available

Boiling point : 100 °C

Flash point : no data available

Evaporation rate : < 1 n-Butyl Acetate = 1.0

Flammability (solid, gas) : Extremely flammable aerosol.

Upper explosion limit : no data available

Lower explosion limit : no data available

Vapour pressure : not determined

Density : 0.941 g/cm3

Solubility(ies)

Water solubility : insoluble


: no data available

Auto-ignition temperature : not determined

Thermal decomposition : no data available

Viscosity

Viscosity, kinematic : no data available


SAFETY DATA SHEET



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SECTION 10. STABILITY AND REACTIVITY

Reactivity : Stable

Chemical stability : Stable under normal conditions.


: No decomposition if stored and applied as directed.

Vapours may form explosive mixture with air.

Conditions to avoid : Heat, flames and sparks.

Extremes of temperature and direct sunlight.

Incompatible materials : Acids

Oxidizing agents


: Carbon oxides

SECTION 11. TOXICOLOGICAL INFORMATION

Acute toxicity

Components:

butane:

Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h

LC50 rat: 1,355 mg/l

propane:

Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h

LC50 rat: 658 mg/l Exposure time: 4 h

LC50 rat: 1,355 mg/l

Skin corrosion/irritation

no data available

Serious eye damage/eye irritation

no data available

Respiratory or skin sensitisation

no data available

Germ cell mutagenicity


SAFETY DATA SHEET



7 / 10

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

alkanes, C12-14-iso-: butane: propane:

STOT - single exposure

no data available

STOT - repeated exposure

no data available

Aspiration toxicity

no data available

Further information

Product:

Remarks: no data available

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

no data available


no data available Bioaccumulative potential

Product:


: Remarks: no data available

Components: butane :


: Pow: 2.89

Mobility in soil

no data available

Other adverse effects

no data available Product:

Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I


SAFETY DATA SHEET



8 / 10

Substances

Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological information

: no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods

Waste from residues : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container.

Dispose of in accordance with local regulations.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.

SECTION 14. TRANSPORT INFORMATION

Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY

Transportation Regulation: IMDG (Vessel):

UN1950, AEROSOLS, 2.1, - Limited quantity

Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity

Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity

Transportation Regulation: TDG (Canada):

UN1950, AEROSOLS, 2.1, - Limited quantity

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.


SAFETY DATA SHEET



9 / 10

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Fire Hazard

Sudden Release of Pressure Hazard

SARA 302 : SARA 302: No chemicals in this material are subject to the

reporting requirements of SARA Title III, Section 302. SARA 313 : SARA 313: This material does not contain any chemical

components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop 65 This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other reproductive harm.

The components of this product are reported in the following inventories: TSCA On TSCA Inventory

DSL This product contains the following components that are not on the Canadian DSL nor NDSL.

AICS Not in compliance with the inventory

NZIoC Not in compliance with the inventory PICCS Not in compliance with the inventory IECSC Not in compliance with the inventory

Inventory Acronym and Validity Area Legend:

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)

SECTION 16. OTHER INFORMATION

Further information NFPA: HMIS III:

Flammability

Health

Insta

bility

3

4

0

Special hazard.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

4

2

3

0 = not signif icant, 1 =Slight, 2 = Moderate, 3 = High

4 = Extreme, * = Chronic


SAFETY DATA SHEET



10 / 10

OSHA GHS Label Information:

Hazard pictograms :

Signal w ord : Danger: Hazard statements : Extremely f lammable aerosol. Contains gas under pressure; may explode if heated.

Precautionary statements : Prevention: Keep aw ay from heat, hot surfaces, sparks, open f lames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.

Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F.

We believe the statements, technical information and recommendations contained herein are

reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations

to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep® , Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next

Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.


This brief provides a general overview of the Safety Data Sheet requirements in the Hazard Communication Standard OSHA’s 29 CFR 1910.1200(g) and Appendix D of 29 CFR 1910.1200).

Section 1 ~ Identification Identity (As Used On Label and List) A1121 Tire Shine

Date Prepared: 06-10-2015

Company Information: OMEGA INDUSTRIAL SUPPLY, INC

Emergency Telephone Number: 1-800-424-9300

Address (Number, Street, Suite/Apt#) 101 Grobric Ct #1

Telephone Number for Information: 1-800-571-7347

(City, State, and Zip Code) Fairfield, CA 94534

Signature of Prepare (Optional) REGULATORY DEPT.

Section 2 ~ Hazard(s) Identification Physical Hazards Flammable aerosols Category 1

Health Hazards Not classified

Environmental Hazards Not classified

OSHA Defined Hazards Not classified

Label elements

Signal Word: Danger

Hazard Statement Extremely flammable aerosol. Precautionary Statement Prevention

Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Do not spray on a open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.

Response Wash hands after handling.

Storage Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazards(s) not otherwise classified (HNOC)

Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.

Section 3 ~ Composition/Information on Ingredients

Components (Specific Chemical Identity, Common Name(s)) CAS No. %(Wt.) Butane 106-97-8 2.5 – 10% Propane 74-98-6 1 – 2.5% Other components below reportable levels - 90 – 100% *Designates that a specific chemival identity and/or percentage of composition has been withheld as a trade secret.

Section 4 ~ First Aid Measures

Eyes — Get medical attention if irritation develops and persists. Skin— Get medical attention if irritation develops and persists. Inhalation — If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. Ingestion — In the unlikely event of swallowing contact a physician or poison control center. Most Important Symptoms/Effects, Acute And Delayed — Direct contact with eyes may cause temporary irritation. Indication Of Immediate Medical Attention And Special Treatment Needed — Provide general supportive measures and treat symptomatically. General information— Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.

Section 5 ~ Fire Fighting Measures

Suitable Extinguishing Media – Water fog, foam, carbon dioxide (CO2) dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing Media – Do not use water jet as an extinguisher as this will spread the fire. Specific hazards arising from the chemical – Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. Special protective equipment and precautions for firefighters – Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots and in enclosed spaces, SCBA. Fire-fighting equipment/instructions –– Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods – Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards – Extremely flammable aerosol.

Section 6 ~ Accidental Release Measures

Personal Precautions, Protective Equipment And Emergency Procedures –Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods And Materials For Containment And Cleaning Up – Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental Precautions - Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination.


A1121 Tire Shine Page 2 of 4

Section 7 ~ Handling and Storage

Precautions For Safe Handling – Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For additional information on equipment bonding and grounding, refer to the Canadian Electrical Code in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or National Fire Protection Association (NFPA) 70, "National Electrical Code". Conditions for safe storage, including any incompatibilities – Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B)

Section 8 ~ Exposure Controls/Personal Protection

Occupational Exposure Limits:

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) US. NIOSH: Pocket Guide to Chemical Hazards

Components Type Value Components Type ValuePropane (CAS 74-98-6) PEL 1800 mg/m3 Butane (CAS 106-97-8) TWA 1900 mg/m3 1000 ppm 800 ppm Propane (CAS 74-98-6) TWA 1800 mg/m3 US. ACGIH Threshold Limit Values 1000 ppm Components Type Value Butane (CAS 106-97-8) STEL 1000 ppm Biological limit values No biological exposure limits noted for the ingredient(s)

Appropriate Engineering Controls – Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Respiratory Protection– If permissible levels are exceeded use NIOSH mechanical filter/organic vapor cartridge or an air-supplied respirator. Skin Protection Other– Wear suitable protective clothing. Hand Protection – Wear appropriate chemical resistant gloves. Eye/face protection – Wear safety glasses with side shields (or goggles). Thermal hazards – Wear appropriate thermal protective clothing, when necessary. General hygiene considerations – When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking and/or smoking. Routine wash work clothing and protective equipment to remove contaminants.

Section 9 ~ Physical Chemical Properties

Initial Boiling Point 212 °F (100 °C) estimated Specific Gravity 0.888 estimated

Vapor Pressure 45 – 55 psig @ 20°C estimated Melting/Freezing Point N/A

Vapor Density N/A Evaporation Rate (Butyl Acetate = 1) N/A

Solubility in Water N/A pH N/A

Appearance and Odor— Liquid, aerosol. VOC% -

Flash Point (Method Used): -156.0 °F (-104.4 °C) PROPELLANT estimated

Auto - Ignition Temperature: N/A

Lower Flammability Level: N/A

Upper Flammability Level: N/A

Section 10 ~ Stability and Reactivity

Stability: Unstable Stable Conditions to Avoid – Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Hazardous Polymerization:

May Occur Will Not Occur

Incompatibility (Materials to Avoid) – Strong oxidizing agents, nitrates, fluorine, chlorine. Hazardous Decomposition or Byproducts – No hazardous decomposition products are known. Reactivity – The product is stable and non-reactive under normal conditions of use, storage and transport.

Section 11 ~ Toxicological Information

Information on likely routes of exposure Ingestion – Expected to be a low ingestion hazard. Inhalation – Prolonged inhalation may be harmful. Skin contact – No adverse effects due to skin contact are expected. Eye contact – Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics: Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute Toxicity:

Product Species Test Results

Butane (CAS 106-97-8) Inhalation – LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l



Acute toxicity Continued: Propane (CAS 74-98-6) Acute Inhalation – LC50 Mouse 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h

Skin corrosion/irritation: Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation: Direct contact with eyes may cause temporary irritation.

Respiratory sensitization: Not available Skin sensitization: This product is not expected to cause skin sensitization.

Germ cell mutagenicity: No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity: This product is not considered to be a carcinogen by IARC, ACGIH, NTP or OSHA.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed.

Reproductive toxicity; This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity - single exposure: Not classified Specific target organ toxicity - repeated exposure: Not classified.

Aspiration hazard – Not available. Chronic effects – Prolonged inhalation may be harmful.

Section 12 ~ Ecological Information

Ecotoxicity Product Species Test Results 11 oz Tire Shine (CAS Mixture) Aquatic Crustacea EC50 Daphnia 1595.2933 mg/l, 48 hours estimated Fish LC50 Fish 145.3649 mg/l, 96 hours estimated * Estimates for product may be based on additional component data not shown. Persistence and degradability: No data is available on the degradability of this product. Bioaccumulative potential: No data available.

Partition coefficient n-octanol / water (log Kow) Butane 2.89 Propane 2.36 Mobility in soil: No data available.

Other adverse effects: No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

Section 13 ~ Disposal Considerations

Disposal instructions: Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations: Dispose in accordance with all applicable regulations. Hazardous waste code: The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

US RCRA (Resource Conservation and Recovery Act ) Hazardous Waste U List: Reference: Waste from residues / Unused products: Dispose of accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

Section 14 ~ Transport Information

US Depart. of Transportation (DOT) Water Transportation (IMDG) Air Transportation (IATA)

Proper Shipping Name: Aerosols, flammable Proper Shipping Name: Aerosols Proper Shipping Name: Aerosols, flammable

Hazard Class: 2.1 Hazard Class: 2.1 Hazard Class: 2.1

UN Number: UN1950 UN Number: UN1950 UN Number: UN1950

Packing Group: Not applicable Packing Group: Not applicable Packing Group: Not applicable

Labels(s): 2.1 Label(s): None Label(s): 2.1

Special Provisions: N82 Environmental Hazard Marine Pollutant: No Environmental Hazards: No

Packaging Exceptions: 306 Packaging Exceptions: Ltd. Qty. Packaging Exceptions: Ltd. Qty.

Special precautions for user: Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. DOT

IATA;IMDG

General Information: IMDG Regulated Marine Pollutant



Section 15 ~ Regulatory Information

US Federal Regulations: This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated.

CERCLA Hazardous CERCLA Hazardous Not listed. Listed.

Listed.

SARA 304 Emergency Release Notification: Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050): Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA):

Hazard categories: Immediate Hazard – No; Delayed Hazard – No; Fire Hazard – Yes; Pressure Hazard – Yes; Reactivity Hazard – No.

SARA 302 Extremely Hazardous Substance: No listed.

SARA 311/312 Hazardous Chemical: No.

SARA 313 (TRI reporting); Not regulated.

Other Federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List: Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):

Butane (CAS 106-97-8) Propane (CAS 74-98-6)

Safe Drinking Water Act (SDWA): Not regulated.

US State Regulations

US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act

US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK

Butane (CAS 106-97-8) Butane (CAS 106-97-8) Butane (CAS 106-97-8) Butane (CAS 106-97-8)

Propane (CAS 74-98-60 Propane (CAS 74-98-60 Propane (CAS 74-98-60 Propane (CAS 74-98-60

US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins.

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

Australia Australian Inventory of Chemical Substances (AICS) No

Canada Domestic Substances List (DSL) Yes

Canada Non-Domestic Substances List (NDSL) No

China Inventory of Existing Chemical Substances in China (IECSC) No

Europe European Inventory of Existing Commercial Chemical Substances (EINECS) No

Europe European List of Notified Chemical Substances (ELINCS) No

Japan Inventory of Existing and New Chemical Substances (ENCS) No

Korea Existing Chemicals List (ECL) No

New Zealand New Zealand Inventory No

Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) No

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

Section 16 ~ Other Information NFPA HMIS Key

HEALTH 1 1 4= Severe

FLAMMABILITY 2 2 3= Serious

REACTIVITY 1 1 2= Moderate

OTHER/PROTECTION - X 1= Slight

0= Minimal Disclaimer: Omega Industrial Supply, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.


AIRIEL SPICE AIR REFILLS

915074-01

Ecolab Co.5105 Tomken RoadMississauga ON L4W 2X5 1-800-352-5326

EMERGENCY HEALTH INFORMATION: 1-800-328-0026Outside United States and Canada CALL 1-651-222-5352 (in USA)

22-April-2009

Material Safety Data Sheet

Trade name

Supplier

CodeDate of issue

Section 1. Chemical product and company identification

AIRIEL SPICE AIR REFILLS

:

:

:Product use : Air Freshener

Section 2. Hazards identificationPhysical state

Emergencyoverview

Liquid. [absorbed liquid (wipes, pads, ...)]

CAUTION!

MAY CAUSE EYE IRRITATION.Avoid contact with eyes. Wash thoroughly after handling.

:

:

Routes of entry : Skin contact, Eye contact, Inhalation, Ingestion


No known significant effects or critical hazards.

Slightly irritating to the eyes.


Slightly irritating to the skin.EyesSkin

InhalationIngestion

::

::

See toxicological information (section 11)


Perfume ingredient. Mixture 60 - 100Name CAS number % by weight

Do not induce vomiting. Never give anything by mouth to an unconscious person. If irritationpersists, get medical attention.

In case of contact, immediately flush eyes with plenty of water. Remove contact lenses andflush again. Get medical attention if irritation persists.In case of contact, immediately flush skin with plenty of water. Remove contaminated clothingand shoes. Get medical attention if irritation persists. Wash clothing before reuse. Cleanshoes thoroughly before reuse.If irritation persists, get medical attention.

Section 4. First-aid measuresEye contact

Skin contact

InhalationIngestion

:

:

::

Not available.If the product is in its liquid form: 62.7778 °C (Closed cup)Not available.

Section 5. Fire-fighting measuresAuto-ignition temperatureFlash pointFlammable limits

:::

No specific data.

Use dry chemical, CO2, water spray (fog) or foam.

Hazardous thermaldecomposition productsFire-fighting media andinstructions

:

:


AIRIEL SPICE AIR REFILLS Page: 2/4

Use water spray to keep fire-exposed containers cool. Dyke area of fire toprevent runoff.

Combustible liquid. In a fire or if heated, a pressure increase will occur and thecontainer may burst, with the risk of a subsequent explosion.

Special protective equipment forfire-fighters

Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode.

:

Risk of explosion of the product in the presence of mechanical impact: Not available.

Risk of explosion of the product in the presence of static discharge: Not available.

Use suitable protective equipment (section 8). Do not allow to enter drains or watercourses.

If emergency personnel are unavailable, contain spilt material. For small spills, add absorbent(soil may be used in the absence of other suitable materials) and use a non-sparking orexplosion-proof means to transfer material to a sealable, appropriate container for disposal.For large spills, dyke spilt material or otherwise contain it to ensure runoff does not reach awaterway. Place spilt material in an appropriate container for disposal.

Environmentalprecautions


: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.Inform the relevant authorities if the product has caused environmental pollution (sewers,waterways, soil or air).

Personalprecautions

:

Methods forcleaning up

:

Keep out of the reach of children. Keep container tightly closed. Keep container in a cool, well-ventilated area.

Wash thoroughly after handling.

Section 7. Handling and storageHandlingStorage

::

Do not store above the following temperature: 10°C


Personal protection :

Consult local authorities for acceptable exposure limits.

No protective equipment is needed under normal use conditions.



Eyes

SkinRespiratory

:

::

No protective equipment is needed under normal use conditions.Hands :

:Engineering measures No special ventilation requirements.

Not available.

Liquid. [absorbed liquid (wipes, pads, ...)]

7 [Conc. (% w/w): 100%]

Not available.0.9

Not available.Not available.

Not available.

Fragrance-like.Clear.

Boiling/condensation pointMelting/freezing point

Section 9. Physical and chemical propertiesPhysical state

pH

Relative densityVapour pressureVapour densityOdour threshold

Evaporation rateLogKow

OdourColour

::::

:::::

:: Not available.

Not available.

:



The product is stable. Under normal conditions of storage and use, hazardouspolymerisation will not occur.

Section 10. Stability and reactivityStability :

Not available.Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

Not available.Conditions of instability

Hazardous decompositionproductsHazardous polymerisation

:::

: Under normal conditions of storage and use, hazardous polymerisation will notoccur.

Reactivity



Carcinogenic effectsMutagenic effects No known significant effects or critical hazards.Teratogenic effects No known significant effects or critical hazards.

Toxicity data

:

:

Not available.Target organs :



Slightly irritating to the eyes.


Slightly irritating to the skin.EyesSkinInhalationIngestion

::::

No known significant effects or critical hazards.Sensitization to Product :Synergistic products(toxicologically)

:

Reproductive effects : No known significant effects or critical hazards.

Not available.

No known significant effects or critical hazards.:

Not applicable.

Section 12. Ecological informationEcotoxicityIngredient name Species PeriodNot available.

The generation of waste should be avoided or minimised wherever possible. Avoid dispersal ofspilt material and runoff and contact with soil, waterways, drains and sewers. Disposal of thisproduct, solutions and any by-products should at all times comply with the requirements ofenvironmental protection and waste disposal legislation and any regional local authorityrequirements.

Waste disposal

Section 13. Disposal considerations:

Consult your local or regional authorities.


See shipping documents for specific transportation information.UN Classification

Certain shipping modes or package sizes may have exceptions from the transportregulations. The classification provided may not reflect those exceptions and maynot apply to all shipping modes or package sizes.

Not regulated.



Section 15. Regulatory information

All components are listed or exempted.WHMIS Not controlled under WHMIS (Canada). Manufactured Article.:

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and theMSDS contains all the information required by the Controlled Products Regulations.

Canada inventory :

Notice to readerThe above information is believed to be correct with respect to the formula used to manufacture the productin the country of origin. As data, standards, and regulations change, and conditions of use and handling arebeyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS ORCONTINUING ACCURACY OF THIS INFORMATION.

Date of issue


22-April-2009.

10-May-2006.

:

:

Responsible name : Regulatory Affairs

Hazardous MaterialInformation System (U.S.A.)

1

0

0

Flammability

Physical hazards

:


1-800-352-5326

Health


AMSOIL Metal Protector

Aerosol.

GHS product identifier

Product type

Emergency telephone number (with hours of operation)

:

:

:

Code : AMPSC/CMPSC

Manufacturer :

R

AMSOIL Metal Protector

SAFETY DATA SHEET

Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada

Lubricant and Protectant.

: AMSOIL INC.Bordner, Ladner, GervaisScotia Plaza, 40 King St WToronto, ON, Canada M5H 3Y4Tel: +1 416-367-6547

Section 1. IdentificationDateVersion

::

03/30/20167

AMSOIL INC.One AMSOIL CenterSuperior, WI 54880Tel: +1 715-392-7101

CHEMTREC: Within USA and Canada: 1-800-424-9300;Outside USA and Canada: +1 703-741-5970 (collect calls accepted)(24/7)

Identified uses :

Initial Supplier(Canada)

FLAMMABLE AEROSOLS - Category 1GASES UNDER PRESSURE - Compressed gasAQUATIC HAZARD (ACUTE) - Category 2AQUATIC HAZARD (LONG-TERM) - Category 2

Classification of the substance or mixture

:

Signal word : Danger

Hazard statements :

Hazard pictograms :

Precautionary statements

GHS label elements

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Section 2. Hazards identification

Extremely flammable aerosol.Contains gas under pressure; may explode if heated.Toxic to aquatic life with long lasting effects.

1/11 03/30/2016:Date of issue


AMSOIL Metal Protector AMPSC/CMPSC

Prevention :

Response :

Storage :

Disposal :

Hazards not otherwise classified (HNOC)

Physical hazards not otherwise classified (PHNOC)

: None known.

Health hazards not otherwise classified (HHNOC)

: None known.

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Avoid release to the environment. Pressurized container: Do not pierce or burn, even after use.

Collect spillage.

Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store in a well-ventilated place.

Dispose of contents and container in accordance with all local, regional, national and international regulations.

Ingredient name CAS number%

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Other means of identification

: Not available.

CAS number : Not applicable.

Substance/mixture

Product code : AMPSC/CMPSC

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.


Distillates, hydrotreated light ≥50 - ≤75 64742-47-8Distillates, hydrotreated heavy naphthenic ≥1 - ≤3 64742-52-5

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention if irritation occurs.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.

Eye contact

Inhalation :

:

Description of necessary first aid measures

Section 4. First aid measures

2/11 03/30/2016:Date of issue



Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe.Never give anything by mouth to an unconscious person.

Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Skin contact

Ingestion :

:

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.

Specific treatments : No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Eye contact

Over-exposure signs/symptoms

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing



:

:

:

Eye contact : Adverse symptoms may include the following:irritationredness


See toxicological information (Section 11)

Indication of immediate medical attention and special treatment needed, if necessary

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

None known.


:


:

Section 5. Fire-fighting measures

3/11 03/30/2016:Date of issue



Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Hazardous thermal decomposition products

Specific hazards arising from the chemical

Decomposition products may include the following materials:carbon dioxidecarbon monoxide

Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway,sewer or drain.

Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.


:

:

:

Special protective actions for fire-fighters

:



:

: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.


For non-emergency personnel

For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

:Spill


4/11 03/30/2016:Date of issue



Advice on general occupational hygiene

Conditions for safe storage,including any incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Protect from sunlight. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination.

:

:

Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous.

:


Section 7. Handling and storage


: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Control parameters

United States

Distillates, hydrotreated light ACGIH TLV (United States, 3/2015). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours.

Distillates, hydrotreated heavy naphthenic ACGIH TLV (United States, 3/2015). TWA: 5 mg/m³ 8 hours. Form: Inhalable fractionNIOSH REL (United States, 10/2013). TWA: 5 mg/m³ 10 hours. Form: Mist STEL: 10 mg/m³ 15 minutes. Form: MistOSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours.

Ingredient name Exposure limits




None.

Canada

5/11 03/30/2016:Date of issue



Hand protection

Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use.

Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.

Eye/face protection

Respiratory protection :

:

:

Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti-static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.

:

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.

Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.

Hygiene measures :

Individual protection measures

Skin protection

Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Physical state

Melting point

Vapor pressure

Relative density

Vapor density

Liquid. [Aerosol.]

Not available.

Not available.

Not available.

Not available.

Solvent.Odor

pH

Clear.Color

Evaporation rate Not available.

Flash point Not available.

Not available.

Not available.Odor threshold

:

:

:

:

:

:

:

:

:

:

:

Appearance

Boiling point : Not available.

Flammability (solid, gas) : Not available.

Lower and upper explosive (flammable) limits

: Not available.


6/11 03/30/2016:Date of issue



Solubility Insoluble.

Auto-ignition temperature Not available.

Not available.

Viscosity Not available.


:

:

:

:

Decomposition temperature : Not available.

Volatility Not available.:

Aerosol product

Type of aerosol : Spray


Conditions to avoid Avoid all possible sources of ignition (spark or flame).

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

The product is stable.Chemical stability

Reactive or incompatible with the following materials: oxidizing materials.

:

:

:

Incompatible materials :


: Under normal conditions of storage and use, hazardous reactions will not occur.

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Section 10. Stability and reactivity

Acute toxicity

Product/ingredient name Result Species Dose Exposure

Carcinogenicity

Irritation/Corrosion

Sensitization


Distillates, hydrotreated heavy naphthenic

LD50 Oral Rat >5000 mg/kg -

There is no data available.


Classification

Product/ingredient name

Distillates, hydrotreated light - - - A3 - -

ACGIH EPA NIOSHNTPIARCOSHA


7/11 03/30/2016:Date of issue



Information on the likely routes of exposure

Inhalation : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Ingestion

Skin contact : No known significant effects or critical hazards.

No known significant effects or critical hazards.:Eye contact

No known significant effects or critical hazards.General :

No known significant effects or critical hazards.Carcinogenicity :

No known significant effects or critical hazards.Mutagenicity :

No known significant effects or critical hazards.Teratogenicity :

Developmental effects : No known significant effects or critical hazards.

Fertility effects : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Skin contact

Ingestion

Inhalation Adverse symptoms may include the following:respiratory tract irritationcoughing



:

:

:

Eye contact : Adverse symptoms may include the following:irritationredness


Delayed and immediate effects and also chronic effects from short and long term exposure

Specific target organ toxicity (single exposure)

Specific target organ toxicity (repeated exposure)

Aspiration hazard

Name Result

: Dermal contact. Eye contact. Inhalation. Ingestion.



: No known significant effects or critical hazards.

Short term exposure

Potential delayed effects : No known significant effects or critical hazards.


: No known significant effects or critical hazards.

Long term exposure

Potential delayed effects : No known significant effects or critical hazards.



Distillates, hydrotreated light ASPIRATION HAZARD - Category 1Distillates, hydrotreated heavy naphthenic ASPIRATION HAZARD - Category 1

8/11 03/30/2016:Date of issue



Numerical measures of toxicity

Acute toxicity estimates



Other adverse effects : No known significant effects or critical hazards.

Toxicity

Product/ingredient name SpeciesResult Exposure


Soil/water partition coefficient (KOC)

: There is no data available.

Mobility in soil

Distillates, hydrotreated light Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days



Section 12. Ecological information

The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container.

:Disposal methods

Section 13. Disposal considerations

9/11 03/30/2016:Date of issue



Aerosols, flammable (each not exceeding 1 L capacity)

2.1

-

Aerosols, flammable (each not exceeding 1 L capacity).Marine pollutant

2.1

-


UN1950

2.1

-

UN1950 UN1950

RemarksLimited quantity

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

Emergency schedules (EmS)F-D, S-U


The environmentally hazardous substance mark may appear if required by other transportation regulations.


DOT IMDG IATA

UN number

UN proper shipping name


Packing group

Additional information


No. Yes. No.

AERG : 126

Special precautions for user

Transport in bulk according to Annex II of MARPOL and the IBC Code

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

: Not available.

:

TDG

Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2), 2.7 (Marine pollutant mark).

The marine pollutant mark is not required when transported by road or rail. Remarks Limited quantity

Yes.

UN1950


2.1

-

U.S. Federal regulations :

: Not listed

: Not listed

: Not listed

: Not listed

Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)

Clean Air Act Section 602 Class I Substances

Clean Air Act Section 602 Class II Substances

DEA List I Chemicals (Precursor Chemicals)

Section 15. Regulatory information

United States inventory (TSCA 8b): All components are listed or exempted.

10/11 03/30/2016:Date of issue




The following components are listed: Carbon dioxide, gas


Massachusetts :

SARA 313

California Prop. 65

: Not listed

New York : None of the components are listed.

New Jersey : The following components are listed: Carbon dioxide, gas

Pennsylvania : The following components are listed: Distillates, hydrotreated light; Carbon dioxide, gas;Distillates, hydrotreated heavy naphthenic

State regulations

SARA 302/304

SARA 304 RQ : Not applicable.


SARA 311/312

Classification : Fire hazardSudden release of pressure

Name % Fire hazard

Sudden release of pressure

Reactive Immediate (acute)health hazard

Delayed (chronic)health hazard



Distillates, hydrotreated light ≥50 - ≤75 Yes. No. No. No. No.

Canadian lists

The following components are listed: Distillates, hydrotreated lightCanadian NPRI :

CEPA Toxic substances : The following components are listed: Carbon dioxide, gas

Canada

DEA List I Chemicals (Precursor Chemicals)


History

Prepared by :

Date of issue mm/dd/yyyy


Version :

:

:

7

03/30/2016

02/15/2016

AMSOIL INC.Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.


11/11 03/30/2016:Date of issue


SAFETY DATA SHEET This Safety Data Sheet conforms to ANSI Z400.5, and to the format requirements and the International Chemical Safety Cards of the Global Harmonizing System. THIS SDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD) IMPORTANT: Read this SDS before handling & disposing of this product. Pass this information on to employees, customers, & users of this product. SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER PRODUCT IDENTITY: AVENGE PRO PRODUCT PURPOSE: SPOTTER COMPANY IDENTITY: Bridgepoint Systems COMPANY ADDRESS: 4282 S 590 W COMPANY CITY: Salt Lake City, UT 84123 COMPANY PHONE: 1-800-658-5314 EMERGENCY PHONES: INFOTRAC: 1-800-535-5053 (USA) SECTION 2. HAZARDS IDENTIFICATION WARNING! EXPOSURE PREVENTION: STRICT HYGIENE! HAZARD STATEMENTS: H100s = General, H200s = Physical, H300s = Health, H400s = Environmental H315 Causes skin irritation. H320 Causes eye irritation. H335 May cause respiratory irritation. PRECAUTIONARY STATEMENTS: P100s = General, P200s = Prevention, P300s = Response, P400s = Storage, P500s = Disposal P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present & easy to do - Continue rinsing. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS MATERIAL CAS# EINECS# WT % Sodium Carbonate 497-19-8 - Trade Secret 1-Methoxy-2-propanol 107-98-2 203-539-1 Trade Secret TRACE COMPONENTS: Trace ingredients (if any) are present in < 1% concentration, (< 0.1% for potential carcinogens, reproductive toxins, respiratory tract mutagens, and sensitizers). None of the trace ingredients contribute significant additional hazards at the concentrations that may be present in this product. All pertinent hazard information has been provided in this document, per the requirements of the Federal Occupational Safety and Health Administration Standard (29 CFR 1910.1200), U.S. State equivalents, and Canadian Hazardous Materials Identification System Standard (CPR 4). SEE SECTIONS 8, 11 & 12 FOR TOXICOLOGICAL INFORMATION. SECTION 4. FIRST AID MEASURES EYE CONTACT: For eyes, flush with plenty of water for 15 minutes & get medical attention. SKIN CONTACT: In case of contact with skin immediately remove contaminated clothing. Wash thoroughly with soap & water. Wash contaminated clothing before reuse. INHALATION: After high vapor exposure, remove to fresh air. If breathing is difficult, give oxygen. If breathing has stopped, trained personnel should immediately begin artificial respiration. If the heart has stopped, trained personnel should immediately begin cardiopulmonary resuscitation (CPR).


of 6 COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013 SECTION 4. FIRST AID MEASURES (CONTINUED) SWALLOWING: Rinse mouth. Do NOT induce vomiting. GET MEDICAL ATTENTION IMMEDIATELY. Do NOT give liquids to an unconscious or convulsing person. SECTION 5. FIRE FIGHTING MEASURES FIRE & EXPLOSION PREVENTIVE MEASURES Above flash point, use a closed system, ventilation, explosion-proof electrical equipment, lighting. EXTINGUISHING MEDIA Use dry powder, alcohol-resistant foam, water spray, carbon dioxide. . use appropriate extinguishing media. SPECIAL FIRE FIGHTING PROCEDURES Water spray may be ineffective on fire but can protect fire-fighters & cool closed containers. Use fog nozzles if water is used. Do not enter confined fire-space without full bunker gear. (Helmet with face shield, bunker coats, gloves & rubber boots). Use NIOSH approved positive-pressure self-contained breathing apparatus. UNUSUAL EXPLOSION AND FIRE PROCEDURES Isolate from oxidizers, heat, & open flame. Closed containers may burst if exposed to extreme heat. Applying to hot surfaces requires special precautions. SECTION 6. ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTIVE MEASURES: Keep unprotected personnel away. Remove all ignition sources. Wear appropriate personal protective equipment given in Section 8. ENVIRONMENTAL PRECAUTIONS: Keep from entering storm sewers and ditches which lead to waterways. CONTAINMENT AND CLEAN-UP MEASURES: Stop spill at source. Dike and contain. Wash away remainder with plenty of water. SECTION 7. HANDLING AND STORAGE HANDLING Use only with adequate ventilation. Avoid breathing of vapor or spray mist. Avoid prolonged or repeated contact with skin. Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear goggles, face shield, gloves, apron & footwear impervious to material. Wash clothing before reuse. Check for peroxides prior to distillation, eliminate if found. STORAGE Keep in fireproof surroundings. Keep separated from strong oxidants. Keep cool. Keep dry. Keep in the dark. Use ventilation along the floor. Do not store above 49 C/120 F. Keep container tightly closed & upright when not in use to prevent leakage. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION MATERIAL CAS# EINECS# TWA (OSHA) TLV (ACGIH) Sodium Carbonate 497-19-8 - None Known None Known 1-Methoxy-2-propanol 107-98-2 203-539-1 None Known 100 ppm MATERIAL CAS# EINECS# CEILING STEL(OSHA/ACGIH) HAP 1-Methoxy-2-propanol 107-98-2 203-539-1 None Known 150 ppm No This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1%.


of 6 COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED) RESPIRATORY EXPOSURE CONTROLS A respiratory protection program that meets OSHA 29 CFR 1910.134 and ANSI Z86.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. VENTILATION LOCAL EXHAUST: Necessary MECHANICAL (GENERAL): Acceptable SPECIAL: None OTHER: None Please refer to ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. PERSONAL PROTECTIONS: Wear OSHA Standard goggles & gloves as a standard practice. SECTION 9. PHYSICAL & CHEMICAL PROPERTIES APPEARANCE: Clear Liquid ODOR: Lemon ODOR THRESHOLD: Not Available pH (Neutrality): 9.5 MELTING POINT/FREEZING POINT: Not Available BOILING RANGE (IBP,50%,Dry Point): > 100 C / >212 F FLASH POINT (TEST METHOD): > 93 C / > 200 F (PMCC) EVAPORATION RATE (n-BUTYL ACETATE=1): Not Applicable FLAMMABILITY CLASSIFICATION: Class III-B LOWER FLAMMABLE LIMIT IN AIR (% by vol): Not Available UPPER FLAMMABLE LIMIT IN AIR (% by vol): Not Available VAPOR PRESSURE (mm of Hg)@20 C 17.1 VAPOR DENSITY (air=1): 0.732 GRAVITY @ 68/68 F / 20/20 C: DENSITY: 1.054 SPECIFIC GRAVITY (Water=1): 1.055 POUNDS/GALLON: 8.788 WATER SOLUBILITY: Complete PARTITION COEFFICIENT (n-Octane/Water): Not Available AUTO IGNITION TEMPERATURE: Not Available DECOMPOSITION TEMPERATURE: Not Available VOCs (>0.044 Lbs/Sq In) : Not Available TOTAL VOC'S (TVOC)*: 0.2 Lbs/Gal NONEXEMPT VOC'S (CVOC)*: 0.2 Lbs/Gal HAZARDOUS AIR POLLUTANTS (HAPS): 0.0 Wt% NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C) Not Available VISCOSITY @ 20 C (ASTM D445): Not Available * Using CARB (California Air Resources Board Rules). SECTION 10. STABILITY & REACTIVITY STABILITY Stable under normal conditions. CONDITIONS TO AVOID Isolate from oxidizers, heat, & open flame. MATERIALS TO AVOID The substance can presumably form explosive peroxides, under the influence of light & air. Check for peroxide prior to distillation, eliminate if found. Reacts with strong oxidants, acid chlorides, acid anhydrides, causing fire & explosion hazard. HAZARDOUS DECOMPOSITION PRODUCTS Carbon Monoxide, Carbon Dioxide from heating. HAZARDOUS POLYMERIZATION Will not occur.


of 6 COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013 SECTION 11. TOXICOLOGICAL INFORMATION ACUTE HAZARDS EYE & SKIN CONTACT: Primary irritation to skin, defatting, dermatitis. Absorption thru skin increases exposure. Primary irritation to eyes, redness, tearing, blurred vision. Liquid can cause eye irritation. Wash thoroughly after handling. INHALATION: Anesthetic. Irritates respiratory tract. Acute overexposure can cause serious nervous system depression. Vapor harmful. Breathing vapor can cause irritation. Acute overexposure can cause harm to kidneys, blood, nerves, liver, lungs. SWALLOWING: Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea. SUBCHRONIC HAZARDS/CONDITIONS AGGRAVATED CONDITIONS AGGRAVATED Chronic overexposure can cause harm to kidneys, blood, nerves, liver, lungs. Persons with severe skin, liver or kidney problems should avoid use. CHRONIC HAZARDS CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS: This product has no carcinogens listed by IARC, NTP, NIOSH, OSHA or ACGIH, as of this date, greater or equal to 0.1%. Product may contain impurities which may alter toxic properties. IRRITANCY OF PRODUCT: This product is irritating to contaminated tissue. SENSITIZATION TO THE PRODUCT: No component of this product is known to be a sensitizer. MUTAGENICITY: This product is not reported to produce mutagenic effects in humans. EMBRYOTOXICITY: This product is not reported to produce embryotoxic effects in humans. TERATOGENICITY: This product is not reported to produce teratogenic effects in humans. REPRODUCTIVE TOXICITY: This product is not reported to cause reproductive effects in humans. A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (such as: within the eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process. MAMMALIAN TOXICITY INFORMATION No mammalian information is available on this product. SECTION 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. EFFECT OF MATERIAL ON PLANTS AND ANIMALS: This product may be harmful or fatal to plant and animal life if released into the environment. Refer to Section 11 (Toxicological Information) for further data on the effects of this product's components on test animals.


of 6 COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013 SECTION 12. ECOLOGICAL INFORMATION (CONTINUED) EFFECT OF MATERIAL ON AQUATIC LIFE: No aquatic environmental information is available on this product. MOBILITY IN SOIL Mobility of this material has not been determined. DEGRADABILITY This product is completely biodegradable. ACCUMULATION Bioaccumulation of this product has not been determined. GREEN INGREDIENTS >99.5% of ingredients are approved or on an approved list of at least one third party green certification organization. This >99.5% threshold earns our manufacturer Green Balance designation. SECTION 13. DISPOSAL CONSIDERATIONS Processing, use or contamination may change the waste disposal requirements. Do not dispose of on land, in surface waters, or in storm drains. Waste should be recycled or disposed of in accordance with regulations. Large amounts should be collected for reuse or consigned to licensed hazardous waste haulers for disposal. ALL DISPOSAL MUST BE IN ACCORDANCE WITH ALL FEDERAL, STATE, PROVINCIAL, AND LOCAL REGULATIONS. IF IN DOUBT, CONTACT PROPER AGENCIES. SECTION 14. TRANSPORT INFORMATION DOT/TDG SHIP NAME: Not Regulated DRUM LABEL: None IATA / ICAO: Not Regulated IMO / IMDG: Not Regulated EMERGENCY RESPONSE GUIDEBOOK NUMBER: None SECTION 15. REGULATORY INFORMATION EPA REGULATION: SARA SECTION 311/312 HAZARDS: Acute Health All components of this product are on the TSCA list. This material contains no known products restricted under SARA Title III, Section 313 in amounts greater or equal to 1%. STATE REGULATIONS: THIS PRODUCT MEETS REQUIREMENTS OF SOUTHERN CALIFORNIA AQMD RULE 443.1 & SIMILAR REGULATIONS CALIFORNIA SAFE DRINKING WATER & TOXIC ENFORCEMENT ACT (PROPOSITION 65): This product contains no chemicals known to the State of California to cause cancer or reproductive toxicity. INTERNATIONAL REGULATIONS The components of this product are listed on the chemical inventories of the following countries: Australia (AICS), Canada (DSL or NDSL), China (IECSC), Europe (EINECS, ELINCS)G Japan (METI/CSCL, MHLW/ISHL), South Korea (KECI), New Zealand (NZIoC), Philippines (PICCS), Switzerland (SWISS), Taiwan (NECSI), USA (TSCA). CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) B2: Flammable Liquid. D2B: Irritating to skin / eyes. This product has been classified in accordance with hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the CPR.


of 6 COMPANY IDENTITY: Bridgepoint Systems SDS DATE: 06/15/2013 PRODUCT IDENTITY: AVENGE PRO ORIGINAL: 06/15/2013 SECTION 16. OTHER INFORMATION HAZARD RATINGS: HEALTH (NFPA): 1, HEALTH (HMIS): 1, FLAMMABILITY: 1, PHYSICAL HAZARD: 0 (Personal Protection Rating to be supplied by user based on use conditions.) This information is intended solely for the use of individuals trained in the NFPA & HMIS hazard rating systems. EMPLOYEE TRAINING See Section 2 for Risk & Safety Statements. Employees should be made aware of all hazards of this material (as stated in this SDS) before handling it. SDS DATE: 06/15/2013 NOTICE Bridgepoint Systems disclaims all expressed or implied warranties of merchantability or fitness for a specific use, with respect to the product or the information provided herein, except for conformation to contracted specifications. All information appearing herein is based upon data obtained from manufacturers and/or recognized technical sources. While the information is believed to be accurate, we make no representations as to its accuracy or sufficiency. Conditions of use are beyond our control, and therefore users are responsible for verifying the data under their own operating conditions to determine whether the product is suitable for their particular purposes and they assume all risks of their handling, and disposal of the product. Users also assume all risks in regards to the publication or use of, or reliance upon information contained herein. This information relates only to the product designated herein, and does not relate to its use in combination with any other material or process.


J.C. Whitlam Big Bubble Gas Leak Detector Page 1 of 6

Safety Data Sheet

SDS ID: Stock Code LD Revision date: July 10, 2015 Section 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product name: Big Bubble Leak Detector Synonyms: None Chemical family: Surfactant mixture Producer: J.C. Whitlam Manufacturing Company 200 West Walnut Street P.O. Box 380 Wadsworth, Ohio 44282-0380 www.jcwhitlam.com Telephone:

330-334-2524 Available during normal business hours

Emergency: 330-334-2524 Available during normal business hours

Section 2. HAZARDS IDENTIFICATION

GHS Classification in accordance with 29 CFR 1910.1200 Skin Corrosion/Irritation, Category 3 Eye Damage/Irritation, Category 2B GHS Label elements, including precautionary statements: Warning Hazard statements H316 Causes mild skin irritation H320 Causes eye irritation

Precautionary Statements P264 Wash skin thoroughly after handling. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Get medical attention/advice. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+313 If eye irritation persists: Get medical advice/ attention. Hazards not otherwise classified or not covered by GHS

Ingestion: May cause abdominal discomfort, nausea, and diarrhea. Carcinogenic: No ingredients listed by the IARC, NTP, OSHA, or the ACHIH.

Section 3. COMPOSITION / INFORMATION ON INGREDIENTS Material information:

Name CAS No. Weight %

Alpha-(Nonylphenyl)-(Omega-hydroxypoly (oxy-1,2-ethanediyl)

9016-45-9 1

Non-hazardous ingredients Not Applicable 99 *Note: The above weight percentages are represented in ranges as estimates. Due to variation among production batches, component percentages may vary.



Section 4. FIRST AID MEASURES

General Advice: Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.

Inhalation: Move exposed persons to fresh air. If the person is not breathing or breathing

is irregular, provide artificial respiration or oxygen by trained personnel. Consult a physician.

Skin contact: Wash affected skin with soap and water. Get medical attention if symptoms

occur. Wash contaminated clothing before reuse. Ingestion: Do not induce vomiting, unless instructed to do so by a physician or poison

control center. Never give anything by mouth to an unconscious person. If conscious and alert, rinse the mouth with water. Consult a physician.

Eye contact: Check for and remove any contact lenses, if easy to do so. If eye irritation

persists, consult physician after flushing eyes with tepid water for 15 minutes.

Section 5. FIREFIGHTING MEASURES

Suitable extinguishing media:

Use extinguishing measures that are suitable to local circumstances and the surrounding fire and environment.

Specific hazards:

Combustion products may include carbon oxides.

Advice for Firefighters:

Full protective equipment including self-contained breathing apparatus should be used. Do not allow run-off from fire-fighting to enter drains or water courses.

NFPA rating: HMIS rating: Health: 1 1 Flammability: 0 0 Instability/reactivity: 0 0 Other: N/A A (PPE)

Section 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Large Spill:

Immediately contact emergency personnel. Evacuate any potentially affected area and isolate personnel from entry. Personnel must have appropriate training, per Occupational Safety and Health Administration (OSHA) 29 CFR 1910.120. Do not touch damaged containers or spilled material unless wearing appropriate protective equipment (Section 8).

Methods for Containment and Clean up

Shut off source if possible and if safe. Prevent entry into waterways and sewers. Advise applicable authorities if material has entered sewers or water courses.

Hazardous

FP - Below 73 F

Stable

N/A

FIRE

SPECIAL

HEALTH

R E A C T I V I T Y

3 2 0

Slightly Hazardous

Will not burn

Stable

N/A

FIRE

SPECIAL

HEALTH

R E A C T I V I T Y

0 1 0



Section 7. HANDLING AND STORAGE

Handling: Avoid breathing vapors. Avoid contact with eyes, skin, or clothing. Wash thoroughly with soap and water after handling.

Storage: Keep all containers tightly closed when not in use. Do not store with incompatible materials. See Section 10, Stability and Reactivity.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Occupational Exposure Limits: Name CAS No. ACGIH® TLV®

Exposure Limits: Federal

OSHA PELs OSHA PELs 1989 C


9016-45-9 None None None

All exposure limits listed are 8-hour time weighted average (TWA) — except where noted otherwise. A Time Weighted Average (TWA) is an average exposure over the course of an 8-hour work shift. B A Short Term Exposure Limit TWA over the course of 15 minutes. PEL — Permissible Exposure Limit is the maximum 8-hour TWA concentration of a chemical that a worker may be exposed to under Occupational Safety and Health Administration (OSHA) regulations. C Federal OSHA 1989 PELs were vacated but are in use and enforced by many state OSHA plans.

Engineering measures: Handle is accordance with good industrial hygiene and safety practices. Wash hands before breaks and at the end of the workday.

PERSONAL PROTECTIVE EQUIPMENT

Respiratory protection: For nuisance exposures, use type N95 (US) or type 1 (Europe Union EN 143) particle/mist respirator. For higher level protection, use type OV/AG/P99 (US) respirator cartridges. Use respirators and components approved by NIOSH.

Skin and body protection: Wear impervious clothing and gloves to prevent contact. Use the manufacturer’s degradation and permeation data for protective material selection.

Eye protection: Wear safety spectacles with unperforated sideshields. Hygiene measures: Avoid repeated or prolonged skin exposure. Wash hands before

eating, drinking, smoking, or using toilet facilities. Promptly remove contaminated clothing and launder before reuse.

Other precautions: Do not let the product enter drains.



Section 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Fluorescent yellow liquid Physical state (solid/liquid/gas): Liquid Substance type (pure/mixture): Mixture Color: Yellow Odor: None Molecular weight: Not available pH: Not Applicable Boiling point/range (5-95%): 212°F, 100°C Melting point/range: 32°F, 0°C Decomposition temperature: Not Available Specific gravity: 1.01 Vapor density: (AIR = 1) Not available Vapor pressure: Not available Evaporation rate (Butyl acetate= 1): Not available Flash point, method used: Not flammable Water solubility: 100% VOC Content: Not available Auto-ignition temperature: Not applicable Flammable limits in air — lower (%): Not applicable Flammable limits in air — upper (%): Not applicable

Section 10. STABILITY AND REACTIVITY

Reactivity: No data available Stability: Stable under recommended storage conditions Possibly hazardous reactions: No data available Conditions to avoid: No data available Incompatible Materials: Strong oxidizing agents. Hazardous decomposition products: By fire, see Section 5. Other decomposition

products: No data available Polymerization: Will not occur.

Section 11. TOXICOLOGICAL INFORMATION

Acute toxicity: Skin and eye irritation.

Product information: Name CAS No. Inhalation: Dermal: Oral:


9016-45-9 No data available No data available No data available

LC50 — The concentration of the chemical in air that kills 50% of the test animals in a given time (usually four hours). Chronic toxicity: No component of this product, present at levels greater than or equal to 1% is identified as a probable, possible, or confirmed human carcinogen by the IARC, NTP, OSHA, and ACGIH. Sensitization: Not known to cause sensitization in humans.



Section 12. ECOLOGICAL INFORMATION

Ecotoxicity effects: No data available.

Persistence No data available. Degradability: No data available.

Section 13. DISPOSAL CONSIDERATIONS

Cleanup Considerations:

This product is not a hazardous waste as defined under RCRA 40 CFR 261. The material destined for disposal must be characterized properly and may differ from the product described in this SDS if mixed with other wastes.

Section 14. TRANSPORT INFORMATION

Please refer to DOT regulation 49 CFR 172.101: Transport information: This material is not regulated under DOT when transported via

U.S. commerce routes: and IATA, and IMO via international routes Hazardous Materials Description: (DOT and IATA): UN/identification no.: Not Applicable Proper shipping name: Not Applicable Hazard class: Not Applicable Packing group: Not Applicable DOT reportable quantity (lbs.): Not Applicable

Section 15. REGULATORY INFORMATION

U.S. federal regulatory information: U.S. RCRA (40 CFR 261) This product is not a hazardous waste as defined under RCRA 40 CFR 261. State and community right-to-know regulations: The following component(s) of this material are identified on the regulatory lists below: U.S. TSCA Chemical inventory Section 8(b) OSHA — This product is determined to be hazardous as defined in the OSHA Hazard Communications Standard (29 CFR 1910.1200) CERCLA Sections 102a/103 (40 FR 302.4): No ingredients are listed. Some Components of this product are listed in the following sections of SARA: SARA Title III Section 302 — N/A SARA Title III Section 304 — N/A SARA Title III Section 313 — This product does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels. SARA Title III Sections 311/312 Hazardous Categories (40 CFR 370.21)

Acute health hazard: Yes Chronic health hazard: No Fire hazard: No Reactive Hazard: No Pressure Hazard: No



California Proposition 65 Components This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm. NOTE: User must consult with applicable state and local agencies for special specifics, determinations or compliance obligations regarding this product.

Section 16. OTHER INFORMATION

The information and recommendations contained herein are based upon tests, data, and information resources believed to be reliable. However, the J.C. Whitlam Manufacturing Company, Inc., and its related operations or divisions (Whitlam) do not guarantee the accuracy or completeness, nor shall any of this information constitute a warranty, whether expressed or implied, as to the safety of goods, the merchantability of the goods or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage may be required. Whitlam assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of this data. No warranty against infringement of any patent, copyright or trademark is made or implied.


SAFETY DATA SHEET

BLM TIRE WET 5GLVersion 1.2 Revision Date 02/08/2017 Print Date 05/11/2017

1 / 9

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Material name

: BLM TIRE WET 5GL

Material number : 000000000030003745


Company : Zep Inc.

Address : 1310 Seaboard Industrial Blvd., NW Atlanta, GA 30318

Telephone : 404-352-1680

Emergency telephone numbers

For SDS Information : Compliance Services 1-877-428-9937

For a Medical Emergency : 877-541-2016 Toll Free - All Calls Recorded

For a Transportation Emergency

: CHEMTREC: 800-424-9300 - All Calls Recorded. In the District of Columbia 202-483-7616

Recommended use of the chemical and restrictions on use

Recommended use : Transportation Wash


Emergency Overview

Appearance liquid

Colour blue

Odour odourless

GHS Classification

Eye irritation : Category 2B

GHS label elements

Signal word : Warning

Hazard statements : H320 Causes eye irritation.

Precautionary statements : Prevention:

P264 Wash skin thoroughly after handling. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/

attention.



SAFETY DATA SHEET


2 / 9

Substance / Mixture : Mixture

Hazardous components

Chemical name CAS-No. Concentration [%]

Propane-1,2-diol, propoxylated 25322-69-4 >= 20 - < 30

The exact percentages of disclosed substances are withheld as trade secrets.


General advice : Do not leave the victim unattended.

If inhaled : If unconscious place in recovery position and seek medical

advice. If symptoms persist, call a physician.

In case of skin contact : In case of contact, immediately flush skin with plenty of water. Take off contaminated clothing and shoes immediately. Get medical attention if irritation develops and persists.

Wash contaminated clothing before re-use.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids.

Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear.

Do not give milk or alcoholic beverages.

Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

Most important symptoms and effects, both acute and delayed

: Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Effects are dependent on exposure (dose, concentration,

contact time). Causes eye irritation. Review section 2 of SDS to see all potential hazards.

Notes to physician : Treat symptomatically. Symptoms may be delayed.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Hazardous combustion products

: Carbon dioxide (CO2) Carbon monoxide

Smoke Specific extinguishing methods

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Further information : Standard procedure for chemical fires.


SAFETY DATA SHEET


3 / 9

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if necessary.



: Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas.

Material can create slippery conditions.

Environmental precautions : No special environmental precautions required.


: Wipe up with absorbent material (e.g. cloth, fleece). Keep in suitable, closed containers for disposal.

Neutralise with acid.


Advice on safe handling : For personal protection see section 8.

Smoking, eating and drinking should be prohibited in the

application area.

Conditions for safe storage : Electrical installations / working materials must comply with

the technological safety standards.

Materials to avoid : Do not freeze.


Components with workplace control parameters

Components CAS-No. Value type (Form of

exposure)

Control parameters /


Basis

Propane-1,2-diol, propoxylated 25322-69-4 TWA

(aerosol)

10 mg/m3 US WEEL

Engineering measures : effective ventilation in all processing areas


Respiratory protection : No personal respiratory protective equipment normally

required.

Hand protectionMaterial : Gloves Remarks : The suitability for a specific workplace should be discussed

with the producers of the protective gloves. Eye protection : Safety glasses


SAFETY DATA SHEET


4 / 9

Skin and body protection : Choose body protection according to the amount and

concentration of the dangerous substance at the work place.

Protective measures : Wear suitable protective equipment.

When using do not eat, drink or smoke.

Hygiene measures : General industrial hygiene practice.


Appearance : liquid

Colour : blue

Odour : odourless

Odour Threshold : No data available

pH : 10.3 - 11

Melting point/freezing point : No data available

Boiling point : No data available

Flash point : Not applicable

Evaporation rate : No data available

Upper explosion limit : No data available

Lower explosion limit : No data available

Vapour pressure : No data available

Relative vapour density : No data available

Relative density : 0.99 - 1.02

Density : No data available

Solubility(ies)

Water solubility : No data available


: No data available

Auto-ignition temperature : not determined

Thermal decomposition : No data available

Viscosity

Viscosity, kinematic : No data available


Reactivity : Stable

Chemical stability : Stable under normal conditions.


SAFETY DATA SHEET


5 / 9

Possibility of hazardous

reactions

: Stable under recommended storage conditions.

No hazards to be specially mentioned.

Conditions to avoid : No data available

Incompatible materials : No data available


: Carbon oxides


Potential Health Effects

Aggravated Medical Condition

: None known.

Symptoms of Overexposure : Effects are immediate and delayed. Symptoms may include irritation, redness, pain, and rash. Effects are dependent on exposure (dose, concentration,

contact time).

Carcinogenicity:

IARC No component of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

ACGIH No component of this product present at levels greater than or


OSHA No component of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

NTP No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

Acute toxicity

No data available


No data available


Product:

Remarks: Irritating to eyes.

Respiratory or skin sensitisation

No data available


No data available


SAFETY DATA SHEET


6 / 9

Carcinogenicity

No data available


No data available

Propane-1,2-diol, propoxylated:

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Aspiration toxicity

No data available

Further information

Product:

Remarks: No data available

SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity

No data available


No data available


Product:


: Remarks: No data available

Mobility in soil

No data available


No data available Product:

Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances

Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

Additional ecological : No data available


SAFETY DATA SHEET


7 / 9

information


Disposal methods

Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Empty containers should be taken to an approved waste

handling site for recycling or disposal.


Transportation Regulation: 49 CFR (USA): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IMDG (Vessel): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Cargo Air):

NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: IATA (Passenger Air): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

Transportation Regulation: TDG (Canada): NOT REGULATED AS DANGEROUS GOODS OR HAZARDOUS MATERIAL

The product as delivered to the customer conforms to packaging requirements for shipment by road under US Department of Transportation (DOT) regulations. Additional transportation classifications noted above are for reference only, and not a certification or warranty of the suitability of the packaging

for shipment under these alternative transport regulations.


TSCA list : No substances are subject to a Significant New Use Rule. No substances are subject to TSCA 12(b) export notification

requirements.

EPCRA - Emergency Planning and Community Right-to-Know Act



SAFETY DATA SHEET


8 / 9

Components CAS-No. Component RQ (lbs)

Calculated product RQ (lbs)

2,2'-iminodiethanol 111-42-2 100 *

*: Calculated RQ exceeds reasonably attainable upper limit.


This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Acute Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting

requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with

known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

California Prop 65 WARNING! This product contains a chemical known to the

State of California to cause cancer.

2,2'-iminodiethanol 111-42-2 ethylbenzene 100-41-4

WARNING: This product contains a chemical known to the

State of California to cause birth defects or other reproductive harm.

methanol 67-56-1

The components of this product are reported in the following inventories:

TSCA On TSCA Inventory DSL All components of this product are on the Canadian DSL

For information on the country notification status for other regions please contact the manufacturer’s regulatory group.

Inventory Acronym and Validity Area Legend:

TSCA (USA), DSL (Canada), NDSL (Canada)



SAFETY DATA SHEET


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Further information

NFPA: HMIS III:

OSHA - GHS Label Information:

Signal w ord : Warning: Hazard statements : Causes eye irritation.

Precautionary statements : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously w ith water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical

advice/ attention.

Version: 1.2

Revision Date: 02/08/2017

Print Date: 05/11/2017

We believe the statements, technical information and recommendations contained herein are

reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations

to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor.

Zep Inc. markets products under well recognized and established brand names such as Zep®, Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Mis ty®, Next

Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®, Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC Forward Chemicals®,Rexodan®, Mykal™, and a number of private labeled brands.

Flammability

Health

Insta

bility

1

0

0

Special hazard.

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

0

0

1

0 = not signif icant, 1 =Slight, 2 = Moderate, 3 = High

4 = Extreme, * = Chronic


MSDS ID: 03C0309 03/09

JELMAR MATERIAL SAFETY DATA SHEET

CLR CALCIUM LIME & RUST REMOVER ENHANCED FORMULA

Page 1 of 5

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Jelmar LLC Emergency Phone Number: 1(800) 323-5497 (USA) Address: 5550 W. Touhy Ave. Monday – Friday 8:30 A.M. – 4:30 P.M. CST Skokie, IL 60077 Emergency Contact: Chemtrec 1(800) 424-9300 Product Name: CLR- Calcium Lime & Rust Remover (Enhanced Formula) MSDS ID: 03C0309 Chemical Family: Aqueous Acidic Cleaner Formula: Proprietary Mixture

SECTION 2 – HAZARDS IDENTIFICATION PHYSICAL STATE: Liquid COLOR: Crystal clear, lime green ODOR: Slightly sour WARNING OVERVIEW: Irritating to eyes, respiratory tract and mucous membranes. Use with adequate ventilation. Avoid breathing mist or dust. Keep container closed when not in use. POTENTIAL HEALTH EFFECTS ROUTES OF EXPOSURE: Eyes. Skin. Inhalation. Ingestion. TARGET ORGANS: No data. EYE CONTACT: Irritation and blurred vision. Effects may vary depending on length of exposure, solution concentration, and first aid measures. Prolonged contact may cause permanent damage. SKIN CONTACT: Prolonged contact may cause dermatitis, and itching. INHALATION: Irritation, breathing difficulties, headaches, dizziness. INGESTION: Oral burns, vomiting, and gastrointestinal disturbance. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE TO PRODUCT: Eye, skin, and respiratory disorders. CANCER INFORMATION: This product does not contain >0.10% of the known potential carcinogens listed in NTP, IRAC, or OSHA. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCT AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN.

SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS Component CAS# OSHA HAZARD % by Weight 1. Water 7732-18-5 NO 70-81 2. Lactic Acid 79-33-4 YES 15-20 3. Gluconic Acid 526-95-4 N0 2-4 4. Lauryldimethyl Hydroxysultaine 13197-76-7 N0 1-4 5. Propylene Glycol Normal Butyl Ether 5131-66-8 YES 1-2

SECTION 4 – FIRST AID MEASURES EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse. Get immediate medical attention if irritation persists.


MSDS ID: 03C0309 03/09



Page 2 of 5

INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A PHYSCIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest.

SECTION 5 – FIRE FIGHTING MEASURES FLAMMABILTY: Not flammable FLASH POINT: None (100º C): Method: TOC EXPLOSIVE LIMITS IN AIR: Not available EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Water spray, dry chemical, alcohol foam or carbon dioxide. FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies. HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to irritating gases and vapors. FIRE AND EXPLOSION HAZARDS: None known.

SECTION 6 – ACCIDENTAL RELEASES MEASURES Steps to be taken in Case Material is Released or Spilled: Avoid contact with skin and eyes Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves. Large Spill: Use personal protection recommended in Section 8. Isolate area, and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters.

SECTION 7- HANDLING AND STORAGE STORAGE: Store in cool, well-ventilated area, away from heat. Keep containers tightly closed. Avoid contact with combustible materials, wood, and organic materials. Store in original container in a secure area away from children and pets. HANDLING: Avoid contact with eyes, skin or clothing. May be harmful or fatal if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hand thoroughly after use. Consumer size containers (14, 28, and 42 fluid ounces and gallon containers), should be rinsed and recycled. Empty 5gallon containers and 55gallon drums, may contain product residue in form of vapor, dried product, or liquid, and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE THESE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN.


MSDS ID: 03C0309 03/09



Page 3 of 5

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: None required during normal household use. If product is used in an industrial setting, respiratory protection must be worn if ventilation does not eliminate symptoms or keep levels below recommended exposure limits. If mist or dust is present, wear NIOSH-Approved respirator for dusts and mists, NIOSH-Approved self-contained breathing apparatus, NIOSH-Approved full-face piece positive-pressure, air-supplied respirator. DO NOT exceed limits established by respirator manufacturer. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of product. EYE PROTECTION: Not required during normal household usage. Industrial users wear safety goggles. Do not wear contact lenses. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves. OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective clothing and footwear where direct contact with chemicals in this product is possible. WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling. EXPOSURE GUIDELINES: OSHA ACGIH COMPONENT PEL STEL/C TWA STEL/C 1. Water N.E. N.E. N.E. N.E. 2. Lactic Acid N.E N.E. N.E. N.E. 3. Gluconic Acid N.E. N.E. N.E. N.E. 4. Lauryldimethyl Hydroxysultaine N.E. N.E. N.E. N.E. 5. Propylene Glycol Normal Butyl Ether N.E. N.E. N.E. N.E.

SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Boiling point: 100º C / 212º F Specific Gravity: 1.05 – 1.06 Vapor Pressure: N.D. Percent Volatiles: ~78.6% (Calculated) Freezing Point: N.D. Evaporation Rate: N.D. (nBuAc=1) Melting Point: N.D. VOC (Wt%): <1.5 (Calculated) Vapor Density (mm Hg): N.D. VOC (LBS/GAL): <0.13 (Calculated) pH: @20ºC ~2 Solubility in Water: 100%

SECTION 10 – STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Avoid elevated temperatures. INCOMPATIBLE MATERIALS: Strong oxidizing agents, metals, acids, and bases. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating gases and vapors and carbon oxides. POSSIBILITY OF HAZARDOUS REACTIONS: No data.

SECTION 11 – TOXICOLOGICAL INFORMATION ACUTE ORAL EFFECTS: A dose of 5 ml/kg was given to 5 male and 5 female rats and no mortality occurred in 14 days. The acute oral LD50 was found to be > 5 ml/kg. The product is not toxic by oral ingestion in accordance with FHSA / CPSC Guidelines. SKIN: Not a primary dermal irritant in accordance with FHSA / CPSC Guidelines. EYE: Irritant in accordance with FHSA / CPSC Guidelines.


MSDS ID: 03C0309 03/09



Page 4 of 5

SECTION 12- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: No data available. CHEMICAL FATE INFORMATION: 28-day biodegradation <60%. The matter is biodegradable.

SECTION 13 – DISPOSAL CONSIDERATIONS HAZARDOUS WASTE NUMBER: D002 DISPOSAL METHOD: Dispose of in a permitted hazardous waste management facility following all local, state, and federal regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. Follow label warnings, since containers may retain some reside of the product. Processing, use or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations.

SECTION 14 - TRANSPORTATION INFORMATION DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT. Identification Number: N.A. Packaging Group: N.A. UN Number: N.A. TDG Classification: Not Regulated IMDG Classification: Not Regulated IATA Classification: Passenger – Not Regulated WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR.

SECTION 15 – REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventory requirements. SARA TITTLE III SECTION 311/312 CATEGORY: IMMEDIATE (ACUTE) HEALTH HAZARARD: YES DELAYED (CHRONIC) HEALTH HAZARD: YES FIRE HAZARD: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE HAZARD: NO SARA SECTIONS 302/304/313/HAP: COMPENT RQ (LBS) RQ (LBS) TPQ (LBS) SEC 313 HAP (1*) (2*) (3*) (4*) (5*) Water N.A. N.A. N.A. NO NO Lactic Acid N.A. N.A. N.A. NO NO Gluconic Acid N.A. N.A. N.A. NO NO Lauryldimethyl Hydroxysultaine N.A. N.A. N.A. NO NO Propylene Glycol Normal Butyl Ether N.A. N.A. N.A. NO NO


MSDS ID: 03C0309 03/09



Page 5 of 5

____________________________REGULATORY AGENCIES________________________________ *1: CERCLA Reportable Quantity *2: SARA Reportable Quantity *3: SARA EHS Threshold Planning Quantity

*4: SARA 313 Toxic Chemical / Category *5: U. S. EPA Hazardous Air Pollutant

INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES AUSTRALIA (ACIS) NO* KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL ) NO PHILIPPINES YES STATES RIGHT TO KNOW: California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and Wisconsin. None. The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm.

SECTION 16 – OTHER INFORMATION NFPA Rating System: Health-1 / Flammability-0 / Reactivity-0 / Special Hazard - None Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent from freezing. Other Precautions: None required. MSDS ABBREVIATIONS: N. A.: Not Applicable N. D.: Not Determined N.E.: Not Established C: Ceiling Limit HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound Revision: Section 11 March 2009 R. A. Gaudreault Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR LLC offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR LLC be responsible for damages of any nature whatsoever resulting from use of or reliance upon said information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS.


SAFETY DATA SHEET

Issuing Date January 5, 2015 Revision Date New Revision Number 0

Page 1 / 10

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product identifier

Product Name Clorox® Bleach


Synonyms None


Recommended use Laundry and household bleach

Uses advised against No information available

Details of the supplier of the safety data sheet

Supplier Address

The Clorox Company of Canada Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3

Emergency telephone number

Emergency Phone Numbers For Medical Emergencies, call: 1-800-446-1014 For Transportation Emergencies, call Chemtrec: 1-800-424-9300

2. HAZARDS IDENTIFICATION


Clorox® Bleach Revision Date New

Page 2 / 10

Classification

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Serious eye damage/eye irritation Category 2A

GHS Label elements, including precautionary statements

Emergency Overview

Signal word Warning

Hazard Statements

Causes serious eye irritation

Appearance Clear, pale yellow Physical State Liquid Odor Bleach

Precautionary Statements - Prevention

Wash hands and any exposed skin thoroughly after handling. Wear eye protection/face protection such as safety glasses.

Precautionary Statements - Response

Eyes

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Precautionary Statements - Storage

None

Precautionary Statements - Disposal

None


Not applicable.

Unknown Toxicity

0.06% of the mixture consists of ingredient(s) of unknown toxicity

Other information

Very toxic to aquatic life with long lasting effects.

Interactions with Other Chemicals

Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds.



Page 3 / 10

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No Weight % Trade Secret

Sodium hypochlorite 7681-52-9 1 - 5 *

Sodium hydroxide 1310-73-2 0.1 - 1 *

* The exact percentage (concentration) of composition has been withheld as a trade secret.

4. FIRST AID MEASURES

First aid measures

General Advice Show this safety data sheet to the doctor in attendance.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get medical attention if irritation develops and persists.

Skin Contact Take off contaminated clothing. Rinse skin with plenty of water. If irritation develops, call a doctor.

Inhalation Move to fresh air. If breathing is affected, call a doctor.

Ingestion Drink a glassful of water. Call a poison control center or doctor immediately. DO NOT induce vomiting unless told to do so by a poison control center or doctor.

Protection of First-aiders Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section 8).


Most Important Symptoms and Effects

Stinging and irritation of eyes.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically.



Page 4 / 10

5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media

CAUTION: Use of water spray when fighting fire may be inefficient.

Specific Hazards Arising from the Chemical

No information available.

Explosion Data

Sensitivity to Mechanical Impact None.

Sensitivity to Static Discharge None.

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES


Personal Precautions Avoid contact with eyes, skin, and clothing. Use personal protective equipment as required.

Other Information Refer to protective measures listed in Sections 7 and 8.


Environmental Precautions See Section 12 for ecological Information.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material.

7. HANDLING AND STORAGE Precautions for safe handling

Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product.

Conditions for safe storage, including any incompatibilities

Storage Keep containers tightly closed in a dry, cool and well-ventilated place.

Incompatible Products Toilet bowl cleaners, rust removers, acids, and ammonia-containing products.



Page 5 / 10

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Sodium hydroxide 1310-73-2

Ceiling: 2 mg/m3 TWA: 2 mg/m

3

IDLH: 10 mg/m3

Ceiling: 2 mg/m3

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health.


Engineering Measures Showers Eyewash stations Ventilation systems

Individual protection measures, such as personal protective equipment

Eye/Face Protection If splashes are likely to occur: Wear safety glasses with side shields (or goggles). None required for consumer use.

Skin and Body Protection Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact.

Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

Hygiene Measures Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product.



Page 6 / 10

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical and Chemical Properties

Physical State Liquid Appearance Clear Odor Bleach Color Pale yellow Odor Threshold No information available

Property Values Remarks/ Method pH ~12.5 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point Not flammable None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air

Upper flammability limit No data available None known

Lower flammability limit No data available None known

Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.05 None known Water Solubility Soluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available

Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available

10. STABILITY AND REACTIVITY

Reactivity

Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds.

Chemical stability

Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Conditions to avoid

None known based on information supplied.


Toilet bowl cleaners, rust removers, acids, and ammonia-containing products.

Hazardous Decomposition Products




Page 7 / 10

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

Product Information .

Inhalation Exposure to vapor or mist may irritate respiratory tract.

Eye Contact May cause eye irritation.

Skin Contact Prolonged contact may cause irritation.

Ingestion Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea, vomiting, and diarrhea.

Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation

Sodium hypochlorite 7681-52-9

8200 mg/kg (Rat) >10000 mg/kg (Rabbit) -


- 1350 mg/kg (Rabbit) -


Symptoms May cause redness and tearing of the eyes.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Sensitization No information available.

Mutagenic Effects No information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH IARC NTP OSHA


- Group 3 - -

IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans

Reproductive Toxicity No information available.

STOT - single exposure No information available.

STOT - repeated exposure No information available. Chronic Toxicity Carcinogenic potential is unknown.

Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI).

Aspiration Hazard No information available.

Numerical measures of toxicity - Product Information

The following values are calculated based on chapter 3.1 of the GHS document

117.20 mg/l ATEmix (4 hr)



Page 8 / 10

12. ECOLOGICAL INFORMATION

Ecotoxicity

Very toxic to aquatic life with long lasting effects.

Persistence and Degradability


Bioaccumulation




13. DISPOSAL CONSIDERATIONS

Disposal methods

Dispose of in accordance with all applicable federal, state, and local regulations.

Contaminated Packaging

Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.

14. TRANSPORT INFORMATION

DOT NOT REGULATED

TDG UN-No UN3082

Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

Hazard Class 9

Packing Group III

Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT

ICAO UN-No UN3082


Hazard Class 9

Packing Group III

Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III

IATA UN-No UN3082


Hazard Class 9

Packing Group III

Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III



Page 9 / 10

IMDG/IMO UN-No UN3082


Hazard Class 9

Packing Group III

EmS No. F-A, S-F

Marine Pollutant Product is a marine pollutant according to the criteria set by IMDG/IMO

Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT

15. REGULATORY INFORMATION Chemical Inventories

TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing.

DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute Health Hazard Yes

Chronic Health Hazard No

Fire Hazard No

Sudden Release of Pressure Hazard No

Reactive Hazard No

Clean Water Act

This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

Chemical Name CWA - Reportable

Quantities CWA - Toxic Pollutants CWA - Priority Pollutants

CWA - Hazardous Substances


100 lb X


1000 lb X

CERCLA

This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs Extremely Hazardous Substances

RQs RQ


100 lb - RQ 100 lb final RQ

RQ 45.4 kg final RQ


1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ



Page 10 / 10


California Proposition 65

This product does not contain any Proposition 65 chemicals.

U.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois


X X X X


X X X X

International Regulations

Canada

WHMIS Hazard Class

D2B - Toxic materials

16. OTHER INFORMATION

NFPA

Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards -

HMIS

Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection B

Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501

Revision Date New

Revision Note Reference

New 1076851/173214.001

General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

End of Safety Data Sheet


FICHE DE DONNÉES DE SÉCURITÉ

Date d'émission 5 janvier 2015

Date de révision Nouvelle

Numéro de révision 0

Page 1 / 11

\1. IDENTIFICATION DE LA SUBSTANCE/DE LA PRÉPARATION ET DE LA SOCIÉTÉ/L’ENTREPRISE

Identificateur de produit

Nom du produit Eau de Javel Clorox®

Autres moyens d’identification

Synonymes Aucun

Utilisation recommandée pour le produit chimique et restrictions en matière d’utilisation

Utilisation recommandée Lessive et eau de Javel domestique

Utilisations déconseillées Aucune information disponible

Renseignements concernant le fournisseur de la fiche de données de sécurité

Adresse du fournisseur

The Clorox Company of Canada Ltd. 150 Biscayne Crescent Brampton, Ontario L6W 4V3

Numéro de téléphone d’urgence

Numéros de téléphone d’urgence Pour des urgences médicales, appelez : 1 800 446-1014 Pour des urgences en matière de transport, appelez Chemtrec : 1 800 424-9300


Eau de Javel Clorox® Date de révision Nouvelle

Page 2 / 11

2. IDENTIFICATION DES DANGERS

Classification

Ce produit chimique est considéré comme dangereux selon la norme sur la communication des renseignements à l’égard des matières dangereuses 2012 d’OSHA (29 CFR 1910.1200)

Lésions oculaires graves/irritation oculaire Catégorie 2A

Éléments d’étiquetage SGH, y compris les conseils de prudence

Vue d’ensemble des procédures d’urgence

Mot indicateur Avertissement

Mentions de danger

Provoque une sévère irritation des yeux

Apparence Transparent, jaune pâle État physique Liquide Odeur Javellisant

Conseils de prudence - Prévention

Se laver les mains et toute peau exposée à fond après manutention. Porter une protection oculaire/faciale telle que des lunettes de sécurité.

Conseils de prudence - Réaction

Yeux :

EN CAS DE CONTACT AVEC LES YEUX : Rincer prudemment avec de l’eau pendant plusieurs minutes. Retirer les verres de contact si la victime en porte et qu’il est possible de les retirer facilement. Continuer à rincer. Si l’irritation oculaire persiste : Obtenir une consultation médicale ou des soins médicaux.

Conseils de prudence - Stockage

Aucun

Conseils de prudence - Élimination

Aucun

Dangers non classés ailleurs (DNCA)

Sans objet.

Toxicité inconnue

0,06 % du mélange est constitué d’ingrédients de toxicité inconnue

Autres informations

Très toxique pour les organismes aquatiques, entraîne des effets à long terme

Interactions avec d’autres produits chimiques

Réagit avec d’autres produits chimiques domestiques tels que nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac pour produire des gaz dangereux, comme le chlore et autres produits chlorés.



Page 3 / 11

3. COMPOSITION / INFORMATION SUR LES COMPOSANTS

Nom chimique No CAS % en poids Secret commercial

Hypochlorite de sodium 7681-52-9 1 - 5 *

Hydroxyde de sodium 1310-73-2 0,1 - 1 *

* Le pourcentage (concentration) exact de composition est retenu comme un secret commercial.

4. PREMIERS SOINS

Premiers soins

Conseils généraux Présenter cette fiche signalétique au médecin traitant.

Contact avec les yeux Rincer immédiatement avec une grande quantité d’eau, également sous les paupières, pendant au moins quinze minutes. Retirer les verres de contact si la victime en porte et qu’il est possible de les retirer facilement. Continuer à rincer. Garder les yeux grands ouverts lors du rinçage. Ne pas frotter la partie touchée. Obtenir des soins médicaux si une irritation se produit et persiste.

Contact avec la peau Retirer les vêtements contaminés. Rincer la peau avec beaucoup d’eau. En cas d’irritaiton, appeler un médecin.

Inhalation Déplacer à l’air frais. Si la respiration est touchée, appeler un médecin.

Ingestion Boire un verre d’eau. Appeler immédiatement un centre antipoison ou un médecin. NE PAS provoquer de vomissements à moins d’en avoir reçu la directive d’un centre antipoison ou d’un médecin.

Protection des secouristes Éviter le contact avec la peau, les yeux ou les vêtements. Utiliser l’équipement de protection individuel requis. Porter des vêtements de protection individuelle (voir la section 8).

Symptômes/effets les plus importants, aigus et retardés

Symptômes/effets les plus importants

Picotement et irritation des yeux.

Indications quant à la nécessité éventuelle d’une prise en charge médicale immédiate ou d’un traitement spécial

Notes au médecin Traiter en fonction des symptômes.



Page 4 / 11

5. MESURES À PRENDRE EN CAS D’INCENDIE

Agents extincteurs appropriés

Utiliser des mesures d’extinction appropriées aux circonstances locales et à l’environnement immédiat.

Agents extincteurs inappropriés

ATTENTION : L’utilisation d’une pulvérisation d’eau pour combattre un incendie peut se révéler inefficace.

Dangers spécifiques du produit

Aucune information disponible.

Données sur les risques d’explosion

Sensibilité à un choc mécanique Aucune.

Sensibilité à une décharge statique Aucune.

Équipement de protection et précautions pour les pompiers

Comme avec tout incendie, porter un appareil respiratoire autonome à demande de pression, MSHA/NIOSH (homologué ou équivalent) et une tenue de protection complète.

6. MESURES À PRENDRE EN CAS DE DÉVERSEMENTS ACCIDENTELS

Précautions individuelles, équipement de protection et mesures d’urgence

Précautions individuelles Éviter tout contact avec les yeux, la peau et les vêtements. Utiliser l’équipement de protection individuelle requis.

Autres informations Consulter les mesures de protection données aux sections 7 et 8.

Précautions relatives à l’environnement

Précautions relatives à l’environnement

Voir la Section 12 pour des données écologiques.

Méthodes et matériaux pour l’isolation et le nettoyage

Méthodes d’isolation Empêcher d’autres fuites ou déversements lorsqu’il est possible de le faire en toute sécurité.

Méthodes de nettoyage Absorber et conteneuriser. Laver les résider et les envoyer à un égout sanitaire. Contacter une installation de traitement sanitaire à l’avance pour s’assurer de sa capacité à traiter le matériel emporté.

7. MANUTENTION ET STOCKAGE Précautions relatives à la sécurité de manutention

Manutention Manipuler conformément aux bonnes pratiques de sécurité et d’hygiène industrielle. Éviter le contact avec la peau, les yeux et les vêtements Ne pas manger, boire ou fumer en manipulant le produit.

Conditions de sécurité de stockage, y compris les incompatibilités

Stockage Conserver les récipients bien fermés dans un endroit sec, frais et bien ventilé.

Produits incompatibles Nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac.



Page 5 / 11

8. CONTRÔLE DE L’EXPOSITION/PROTECTION INDIVIDUELLE

Paramètres de contrôle

Directives relatives à l’exposition

Nom chimique ACGIH TLV OSHA PEL NIOSH IDLH

Hydroxyde de sodium 1310-73-2

Valeur plafond : 2 mg/m3 TWA : 2 mg/m

3

IDLH : 10 mg/m3

Valeur plafond : 2 mg/m3

ACGIH TLV : Conférence américaine des hygiénistes industriels gouvernementaux - valeur limite d’exposition OSHA PEL : Administration de la sécurité et de la santé professionnelle - limites d’exposition admissibles NIOSH IDLH : Dangereux immédiatement pour la santé ou la vie.

Contrôles d’ingénierie appropriés

Mesures techniques Douches Douches oculaires Systèmes de ventilation

Mesures de protection individuelle telles que les équipements de protection individuelle

Protection des yeux/du visage En cas d’éclaboussures probables : Porter des lunettes de sécurité à écrans latéraux (ou des lunettes à coques). Aucune nécessaire pour une utilisation par le consommateur.

Protection de la peau et du corps Porter des gants en caoutchouc ou en néoprène s’il existe une possibilité d’un contact répété ou prolongé avec la peau.

Protection respiratoire En cas d’irritation ou de dépassement des limites d’exposition, vous devez porter une protection respiratoire approuvée NIOSH/MSHA. Des respirateurs à adduction d’air à pression positive peuvent être requis pour des concentrations élevées de contaminants atmosphériques. Une protection respiratoire doit être fournie conformément à la réglementation locale en cours.

Mesures d’hygiène Retirer et laver les vêtements contaminés avant de les réutiliser. Éviter le contact avec la peau, les yeux ou les vêtements. Ne pas manger, boire ou fumer en manipulant le produit.



Page 6 / 11

9. PROPRIÉTÉS PHYSIQUES ET CHIMIQUES

Propriétés physiques et chimiques

État physique Liquide Apparence Transparent Odeur Javellisant Couleur Jaune pâle Seuil olfactif Aucune information

disponible

Propriété Valeurs Remarques/ Méthode pH ~ 12,5 Aucune connue Point de fusion/point de congélation Aucune donnée disponible Aucune connue Point d’ébullition / Domaine d’ébullition

Aucune donnée disponible Aucune connue

Point d’éclair Ininflammable Aucune connue Taux d’évaporation Aucune donnée disponible Aucune connue Inflammabilité (solide, gaz) Aucune donnée disponible Aucune connue Limites d’inflammabilité dans l’air

Limite supérieure d’inflammabilité Aucune donnée disponible Aucune connue

Limite inférieure d’inflammabilité Aucune donnée disponible Aucune connue

Tension de vapeur Aucune donnée disponible Aucune connue Densité de la vapeur Aucune donnée disponible Aucune connue Densité ~ 1,05 Aucune connue Solubilité dans l’eau Soluble dans l’eau Aucune connue Solubilité dans d’autres solvants Aucune donnée disponible Aucune connue Coefficient de partage : n-octanol/eau

Aucune donnée disponible Aucune connue

Température d’auto-inflammation Aucune donnée disponible Aucune connue Température de décomposition Aucune donnée disponible Aucune connue Viscosité cinématique Aucune donnée disponible Aucune connue Viscosité dynamique Aucune donnée disponible Aucune connue Propriétés explosives Non explosif Propriétés comburantes Aucune donnée disponible

Autres informations Point de ramollissement Aucune donnée disponible Teneur en COV (%) Aucune donnée disponible Dimension de particules Aucune donnée disponible Distribution granulométrique Aucune donnée disponible



Page 7 / 11

10. STABILITÉ ET RÉACTIVITÉ

Réactivité

Réagit avec d’autres produits chimiques domestiques tels que nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac pour produire des gaz dangereux, comme le chlore et autres produits chlorés.

Stabilité chimique

Stable dans les conditions de stockage recommandées.

Risque de réactions dangereuses

Aucun dans des conditions normales de traitement.

Conditions à éviter

Aucune connue selon les renseignements fournis.

Matériaux incompatibles

Nettoyants de cuvette de toilette, les produits antirouille, les acides et les produits à base d’ammoniac.

Produits de décomposition dangereux

Aucune connue selon les renseignements fournis.

11. DONNÉES TOXICOLOGIQUES

Les voies d’exposition probables

Renseignements sur le produit .

Inhalation Une exposition aux vapeurs ou à la bruine peut irriter les voies respiratoires.

Contact avec les yeux Peut causer une irritation des yeux.

Contact avec la peau Un contact prolongé peut causer une irritation.

Ingestion Une ingestion peut provoquer une irritation des muqueuses et du tractus gastro-intestinal, des nausées, des vomissements et une diarrhée.

Informations sur les composants

Nom chimique DL50 orale DL50 cutanée CL50 par inhalation

Hypochlorite de sodium 7681-52-9

8 200 mg/kg (rat) > 10 000 mg/kg (lapin) -


- 1350 mg/kg (lapin) -

Informations sur les effets toxicologiques

Symptômes Peut causer une rougeur et un larmoiement des yeux.

Les effets retardés et immédiats ainsi que les effets chroniques dus à une exposition à court et long terme

Sensibilisation Aucune information disponible.

Effets mutagènes Aucune information disponible.

Cancérogénicité Le tableau ci-dessous indique si chaque agence a inscrit un ingrédient comme étant cancérigène.



Page 8 / 11

Nom chimique ACGIH CIRC NTP OSHA


- Groupe 3 - -

CIRC (Centre international de recherche sur le cancer) Groupe 3 - Ne peut être classifié pour la cancérogénicité chez les humains

Toxicité pour la reproduction Aucune information disponible.

Toxicité pour certains organes cibles - exposition unique


Toxicité pour certains organes cibles - exposition répétée


Toxicité chronique Le potentiel cancérogène est inconnu.

Effets sur les organes cibles Appareil respiratoire, yeux, peau, tractus gastro-intestinal (GI).

Danger par aspiration Aucune information disponible.

Valeurs numériques de la toxicité - Information sur le produit

Les valeurs suivantes sont calculées selon le chapitre 3.1 du document SGH :

117,20 mg/l ETAmél (4 h)

12. DONNÉES ÉCOLOGIQUES

Écotoxicité

Très toxique pour les organismes aquatiques, entraîne des effets à long terme.

Persistance et dégradation


Bioaccumulation


Autres effets nocifs


13. DONNÉES SUR L’ÉLIMINATION DU PRODUIT

Méthodes d’élimination

Éliminer conformément à tous les règlements fédéraux, provinciaux et locaux.

Récipients contaminés

Ne pas réutiliser les récipients vides. Éliminer conformément à tous les règlements fédéraux, provinciaux et locaux.

14. INFORMATIONS RELATIVES AU TRANSPORT

DOT NON RÉGLEMENTÉ

TMD Numéro ONU UN3082

Désignation officielle de transport

MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A.

Classe de danger 9

Groupe d’emballage III

Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III, POLLUANT MARIN



Page 9 / 11

OACI : Numéro ONU UN3082



Classe de danger 9


Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III

IATA Numéro ONU UN3082



Classe de danger 9


Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III

IMDG/OMI Numéro ONU UN3082



Classe de danger 9


EmS No F-A, S-F

Polluant marin Le produit est un polluant marin selon les critères fixés par l’IMDG/OMI

Description UN3082, MATIÈRE DANGEREUSE DU POINT DE VUE DE L’ENVIRONNEMENT, LIQUIDE, N.S.A. (HYPOCHLORITE DE SODIUM), 9, III, POLLUANT MARIN

15. INFORMATIONS SUR LA RÉGLEMENTATION Inventaire de produits chimiques

TSCA Tous les composants de ce produit sont soit inscrits sur l’inventaire TSCA 8(b) ou sont exempts d’inscription.

LIS/LES Tous les composants sont inclus dans la LIS ou la LES. TSCA - États-Unis - Section 8 (b) de l’inventaire TSCA (loi réglementant les substances toxiques) LIS/LES – liste intérieure des substances/liste extérieure des substances pour le Canada

ÉTATS-UNIS Règlements fédéraux

SARA 313

Section 313 du titre III de la loi du Superfund Amendments and Reauthorization Act de 1986 (SARA). Ce produit ne contient aucun produit chimique soumis aux exigences en matière de rapport de la Loi et du titre 40 du Code of Federal Regulations, partie 372

SARA 311/312 Catégories de dangers Risque aigu pour la santé Oui

Danger chronique pour la santé Non

Risque d’incendie Non

Danger de libération soudaine de pression Non

Danger de réaction Non

Loi sur la qualité de l’eau (Clean Water Act)

Ce produit contient les substances suivantes qui sont des polluants réglementés conformément à la loi sur la qualité de l’eau (Clean Water Act) (40 CFR 122.21 et 40 CFR 122.42)



Page 10 / 11

Nom chimique CWA - quantités à déclarer CWA - polluants toxiques CWA - polluants

prioritaires CWA - substances

dangereuses


100 lb X


1000 lb X

CERCLA

Sous sa forme commerciale, ce produit contient une ou plusieurs substances réglementées comme une substance dangereuse en vertu de CERCLA (Comprehensive Environmental Response Compensation and Liability Act) (40 CFR 302)

Nom chimique Quantités à déclarer de

substances dangereuses Quantités à déclarer de

substances très dangereuses Quantité à déclarer (QD)


100 lb - QD 100 lb QD finale

QD 45,4 kg QD finale


1000 lb - QD 1000 lb QD finale QD 454 kg QD finale



Page 11 / 11

États-Unis - Réglementation des états

Proposition 65 de la Californie

Ce produit ne contient aucun produit chimique de la proposition 65.

Règlement d’état sur le droit à l’information aux États-Unis

Nom chimique New Jersey Massachusetts Pennsylvanie Rhode Island Illinois


X X X X


X X X X

Règlements internationaux

Canada

Classe de dangers du SIMDUT

D2B - Matières toxiques

16. AUTRES INFORMATIONS

NFPA

Danger pour la santé 2 Inflammabilité 0 Instabilité 0 Propriétés physiques et chimiques -

HMIS

Danger pour la santé 2 Inflammabilité 0 Danger physique 0 Protection individuelle B

Préparée par Product Stewardship 23 British American Blvd. Latham, NY 12110 1 800 572-6501

Date de révision Nouvelle

Note de révision Référence

Nouvelle 1076851/173214.001

Avis de non-responsabilité général À notre connaissance et selon nos renseignements et notre opinion à la date de publication de cette fiche signalétique, les renseignements fournis dans cette dernière sont exacts. Les renseignements donnés sont conçus uniquement comme un guide pour la manipulation, l’utilisation, le traitement, l’entreposage, le transport, l’élimination et le rejet sécuritaires du produit et ne doivent pas être considérés comme une garantie ou une norme de qualité. Les renseignements sont liés uniquement au produit particulier indiqué et peuvent ne pas être valides pour un tel produit utilisé en association avec toute autre substance ou dans tout autre procédé, sauf si indiqué dans le texte.

Fin de la fiche signalétique


SAFETY DATA SHEET

Issue Date 22-Mar-2015

Revision Date 24-Mar-2015

Version 2

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1. PRODUCT AND COMPANY IDENTIFICATION

Product identifier

Product Name Dri-Eaz MILGO SR Product Code LBCMGOBLLB-MSR Customer Code F448 Formula code W.20404 /LG-F1050 Other means of identification


Recommended Use Professional Deodorizer Uses advised against Use only as stated on label.


Manufactured For / Distributed By Legend Brands Products 15180 Josh Wilson Road Burlington, WA 98233 800-932-3030

Emergency telephone number

24 Hour Emergency Phone Number 1-800-535-5053


Classification

Acute toxicity - Oral Not classified

Acute aquatic toxicity Category 3

Chronic aquatic toxicity Category 3

Flammable liquids

Category 3

Label elements

Emergency Overview

Warning

Hazard statements

Harmful to aquatic life with long lasting effects

Flammable liquid and vapor


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Precautionary Statements - Prevention - Avoid release to the environment - Keep away from heat/sparks/open flames/hot surfaces. — No smoking - Keep container tightly closed - Ground/bond container and receiving equipment - Use explosion-proof electrical/ventilating/lighting/equipment. - Use only non-sparking tools - Take precautionary measures against static discharge - Wear protective gloves/protective clothing/eye protection/face protection

Precautionary Statements - Response - Specific Treatment (See Section 4 on the SDS)

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

IF SWALLOWED: Rinse mouth. DO NOT induce vomiting. Drink plenty of water.

In case of fire: Use CO2, dry chemical, or foam for extinction.

Precautionary Statements - Storage - Store in a well-ventilated place. Keep cool

Precautionary Statements - Disposal - Dispose of contents/container to an approved waste disposal plant


Other Information

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity


Chemical Name CAS No. Weight-% Trade Secret

Ethanol 64-17-5 3-7 *

Ethoxylated Secondary Alcohol 84133-50-6 1-5 *

Trade Secret Proprietary .1-1 *

Glutaraldehyde 111-30-8 .1-1 *

.


First aid measures

General advice If symptoms persist, call a physician.

Skin Contact Immediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician.


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Eye contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Keep eye wide open while rinsing If symptoms persist, call a physician

Inhalation Immediate medical attention is not required. If symptoms persist, call a physician. Move to fresh air in case of accidental inhalation of vapors or decomposition products.

Ingestion Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Do NOT induce vomiting.

Self-protection of the first aider Use personal protective equipment as required.


Symptoms Any additional important symptoms and effects are described in Section 11: Toxicology Information.


Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use. Dry chemical. Carbon dioxide (CO2). Water spray (fog). Alcohol resistant foam.

Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire.

Specific hazards arising from the chemical Keep product and empty container away from heat and sources of ignition. Risk of ignition.

Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus

pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear



Personal precautions Use personal protective equipment as required. Remove all sources of ignition. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Pay attention to flashback. Take precautionary measures against static discharges.


Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.


Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Soak up with inert absorbent material. Dam up. Pick up and transfer to properly labeled containers. Take precautionary measures against static discharges.

7. HANDLING AND STORAGE



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Advice on safe handling Use with local exhaust ventilation. All equipment used when handling the product must be grounded. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors).


Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers.

Incompatible materials None known based on information supplied.


Control parameters

Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Ethanol 64-17-5

STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m

3

(vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m

3

IDLH: 3300 ppm TWA: 1000 ppm

TWA: 1900 mg/m3

2-Propanol 67-63-0

STEL: 400 ppm TWA: 200 ppm

TWA: 400 ppm TWA: 980 mg/m

3

(vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m

3

(vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m

3

IDLH: 2000 ppm TWA: 400 ppm

TWA: 980 mg/m3

STEL: 500 ppm STEL: 1225 mg/m

3

Glutaraldehyde 111-30-8

Ceiling: 0.05 ppm activated and inactivated

(vacated) Ceiling: 0.2 ppm (vacated) Ceiling: 0.8 mg/m

3

Ceiling: 0.2 ppm Ceiling: 0.8 mg/m

3

NIOSH IDLH Immediately Dangerous to Life or Health

Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).


Engineering Controls Showers, Eyewash stations & Ventilation systems


Eye/face protection Wear safety glasses with side shields (or goggles).

Skin and body protection No special technical protective measures are necessary.

Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.

General Hygiene When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.


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Information on basic physical and chemical properties

Physical state Liquid

Appearance Clear

Color Blue Green

Odor Lemon

Odor threshold No Information available

Property Values

Remarks • Method

pH 6.0 - 8.0

Specific Gravity 1

Viscosity Water Thin

Melting point/freezing point No Information available

Flash point 51 °C 124 °F

Boiling point / boiling range No Information available

/

Evaporation rate Same as water


Flammability Limits in Air

Upper flammability limit: No Information available

Lower flammability limit: No Information available

Vapor pressure No Information available

Vapor density No Information available

Water solubility Soluble in water

Partition coefficient No Information available

Autoignition temperature No Information available

Decomposition temperature No Information available

Other Information

Density Lbs/Gal 8.23

VOC Content (%) 6.7


Reactivity No data available

Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied.



Inhalation No data available.

Eye contact May cause irritation.

Skin Contact Prolonged contact may cause redness and irritation.

Ingestion May be harmful if swallowed.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Ethanol 64-17-5

= 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h


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2-Propanol 67-63-0

= 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h


= 252 mg/kg ( Rat ) = 560 µL/kg ( Rabbit ) = 0.1 mg/L ( Rat ) 4 h


Symptoms No Information available.


Sensitization No Information available.

Germ cell mutagenicity No Information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.

Chemical Name ACGIH IARC NTP OSHA

Ethanol 64-17-5

A3 Group 1 Known X

ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen

IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Not classifiable as a human carcinogen

NTP (National Toxicology Program) Known - Known Carcinogen

OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present

Reproductive toxicity No Information available.

STOT - single exposure No Information available.

STOT - repeated exposure No Information available.

Chronic toxicity Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage. Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin.

Target organ effects Blood, Central nervous system, EYES, Liver, Reproductive System, Respiratory system, Skin.

Aspiration hazard No Information available.

Numerical measures of toxicity - Product Information

Unknown Acute Toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity



Ecotoxicity

Chemical Name Algae/aquatic plants Fish Crustacea

Ethanol 64-17-5

- 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50

static 13400 - 15100: 96 h Pimephales promelas mg/L LC50

flow-through

9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna

mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50


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Ethoxylated Secondary Alcohol 84133-50-6

- 3.2: 96 h Pimephales promelas mg/L LC50

3.2: 48 h water flea mg/L EC50


0.61: 72 h Desmodesmus subspicatus mg/L EC50 0.84: 96 h Desmodesmus subspicatus mg/L

EC50

7.8 - 22: 96 h Lepomis macrochirus mg/L LC50 static 2.6 - 4.8: 96 h

Oncorhynchus mykiss mg/L LC50 flow-through 7.8 - 13: 96 h

Oncorhynchus mykiss mg/L LC50 static 5.4: 96 h Pimephales promelas mg/L LC50 static

14: 48 h Daphnia magna mg/L EC50 0.56 - 1.0: 48 h Daphnia

magna mg/L EC50 Static

Persistence and degradability No Information available.

Bioaccumulation No Information available.

Chemical Name Partition coefficient

Ethanol 64-17-5

-0.32


0.22

Other adverse effects No Information available


Waste treatment methods

Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging Do not reuse container. US EPA Waste Number D001

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste Status

Ethanol 64-17-5

Toxic Ignitable


Toxic


Note: The basic description below is specific to the container size. This information is provided for at a glance DOT information.

Please refer to the container and/or shipping papers for the appropriate shipping description before tendering this material for shipment. For additional information, please contact the distributor listed in section 1 of this SDS.

U.S. Department of Transportation (USDOT)

4x1 Gallon Case Not regulated

Pails & Drums (<119 Gallons) Not regulated

15. REGULATORY INFORMATION International Inventories

TSCA Does not comply

DSL/NDSL Does not comply

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List


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US Federal Regulations

SARA 313

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

SARA 311/312 Hazard Categories

Acute health hazard Yes

Chronic Health Hazard No

Fire hazard Yes

Reactive Hazard No

Sudden release of pressure hazard No

CWA (Clean Water Act)

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42)

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material


California Proposition 65

This product contains the following Proposition 65 chemicals

Chemical Name California Prop. 65

1,4-DIOXANE - 123-91-1 Carcinogen

Ethylene oxide - 75-21-8 Carcinogen Developmental

Female Reproductive Male Reproductive


Chemical Name New Jersey Massachusetts Pennsylvania

Ethanol 64-17-5

X X X

2-Propanol 67-63-0

X X X


X X X

Sodium Sulfate 7757-82-6

- X X

U.S. EPA Label Information

EPA Pesticide Registration Number Not Applicable

Additional information No Information available.

16. OTHER INFORMATION HMIS


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Health hazards

2

Flammability

2

Physical hazards

0

Personal protection

B

Prepared By Regulatory Department Issue Date 22-Mar-2015 Revision Date 24-Mar-2015 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.



MATERIAL SAFETY DATA SHEET

PRODUCT NAME: FAB SET CR12

SECTION 1: COMPANY AND PRODUCT IDENTIFICATION

Distributed By: Bridgepoint Systems, 4282 W 590 W, Salt Lake City, Utah 84123Company Phone Number: 801-261-1282Emergency Phone Number: 1-800-535-5053 (Infotrac)Date Prepared: 02/01/2011

Hazard Rating (Zero=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme)Fire: 0 Health: 1 Reactivity: 1

SECTION 2: COMPOSITION/INFORMATION ON COMPONENTS

HAZARDOUS INGREDIENTS: OSHA PEL TLVGlycolic Acid (CAS # 79-14-1) N/E N/ECitric Acid (CAS # 77-92-9) N/E N/E

SECTION 3: HAZARDS IDENTIFICATION

Immediate Health Effects

Eye Contact: May cause temporary eye irritation; injury to eye tissue unlikely.

Skin Contact: Frequent or prolonged contact may cause temporary irritation. Skincontact may aggravate an existing dermatitis condition.Inhalation: May cause slight temporary irritation.Ingestion: Small amounts swallowed incidental to normal handling operations are not likelyto cause injury; swallowing amounts larger than that may cause temporary injury.

Primary Routes of Entry: Eyes, skin contact/absorption, inhalation or ingestion.

Signs/Symptoms of Overexposure: Gastrointestinal irritation (nausea, vomiting, diarrhea),and/or irritation to the skin, eyes, nose, throat, and respiratory tract.

Target Organ Effects: Irritation of the skin and eyes. Irritation of lungs possible ifmists/aerosols are inhaled.

Reproductive/Developmental Information: No data available.

Carcinogenicity: NTP: Known – No; Anticipated – No OSHA: No IARC: No

Long Term Effects: No data available.


MATERIAL SAFETY DATA SHEETPRODUCT NAME: FAB -SET CR12

Page 2 of 4


E ye Contact: Immediately irrigate with flowing water continuously for 15 minutes. If irritationpersists consult medical personnel.Skin Contact: Wash with soap and water. If irritation persists consult medicalpersonnel.Inhalation: Move to fresh air. If irritation persists consult medical personnel.Ingestion: If swallowed, DO NOT induce vomiting unless directed to do so by medicalpersonnel. If injured party is conscious, give two glasses of water. Seek medical attention.

SECTION 5: FIRE-FIGHTING MEASURES

Flashpoint: >212° FExplosive limits: No dataAutoignition temperature: No dataGeneral Hazard: IrritantFire Fighting Procedures: Wear self-contained breathing apparatus and full protective clothing.Use water spray to cool nearby containers and structures exposed to fire.Hazardous Decomposition Products: During a fire, smoke may contain the original material inaddition to unidentified toxic and/or irritating compounds. Hazardous combustion productsmay include and are not limited to carbon dioxide and carbon monoxide.


Keep all unnecessary personnel away. Prevent additional discharge of material. Preventmaterial from entering sewers, watercourses, or low areas. Contain and absorb spilled materialwith sand or earth. Consult an expert on disposal of recovered material and ensure conformity tolocal disposal regulations.


Store out of reach of children; keep container closed; store in a cool well-ventilated placeaway from strong oxidizing or alkaline products. Avoid contact with skin and eyes. Use in awell-ventilated area; do not breathe vapors. Wash hands thoroughly after handling.

SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls: Normal room ventilation is satisfactory for limited use.

Eye Protection: Safety glassesSkin Protection: Use gloves impervious to this material when prolonged or frequentlyrepeated contact could occur.Respiratory: No respiratory protection should be needed.Exposure guidelines: N/E



Page 3 of 4


Odor: Light Apple ScentPhysical State: Liquid.Appearance: Clear, Light GreenpH: 2.0Specific Gravity: 1.008Boiling Point: N/DFreezing/Melting Point: N/DVapor Pressure: N/DVapor Density: N/DSolubility in Water: Complete


Chemical stability: StableIncompatibility with other substances: Strong oxidizing or alkaline agentsReactivity: None known.Hazardous Decomposition Products: Exposure to fire may liberate carbon dioxide, carbonmonoxide, organic acids, and other unidentified thermal decomposition products from thisproduct or its packaging.


Route of Entry: Eye contact, and skin absorption/contact.

Effects of Acute Overexposure to Product:Eye Contact: May cause temporary eye irritation, redness, tearing and blurred vision.Skin Contact: May cause temporary skin irritation, defatting and dermatitis.Inhalation: Inhalation of mist or vapor may cause temporary respiratory irritation,temporary central nervous system effects including dizziness, weakness, fatigue,nausea, and headache.Ingestion: May cause gastrointestinal temporary irritation with nausea, vomiting anddiarrhea, aspiration into the lungs can cause chemical pneumonitis.

Effects of Chronic Overexposure to Product:Exposure limits: N/D for mixtureTeratogenicity: NoneReproductive toxicity: NoneSensitization to Product: None knownMutagenicity: NoneCarcinogenicity: None


Please refer to Section 6 for information regarding accidental releases and Section 15 forregulatory reporting information.



Page 4 of 4


Contain with chemical absorbent material. Do not dispose of on the land, in surface waters, or instorm drains. Small spills and waste may be flushed into a waste treatment sewer where localregulations permit. Larger quantities should be collected for reuse or consigned to a licensedhazardous waste hauler for disposal in accordance with federal, state and local regulations. Alldisposal must be in accordance with all federal, state and local regulations.


No restrictions for Ground, Air, or Maritime Transportation in accordance with 49 CFR parts

100-185.


Glycolic Acid (CAS # 79-14-1) CERCLAAll components are listed on TSCA.

CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act

16. OTHER INFORMATION

This product has no established regulatory information. All regulatory information given isbased on individual components of the mixture by component number. While this informationand recommendations set forth herein are believed to be accurate and reliable, it is providedwithout warranty regarding its accuracy. BRIDGEPOINT SYSTEMS MAKES NOWARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROMRELIANCE THEREON. Users must determine safe conditions for use and assume liability forany loss, injury, damage or expense resulting from use of this product.

N/A = Not applicable N/D = Not determined N/E = Not established


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Safety Data Sheet Issuing Date: 1-Jun-2008 Revision Date: 27-Mar-2015 SDS Number: 9174

Product identifier

Product Name

Freeze-proof RV & Marine -50 °F Burst Antifreeze

Stock Numbers 130425 / 130414 / 130421


Synonyms Not available.


Recommended Use RV & Marine Antifreeze.

Uses advised against Not available.


Supplier Name South/Win, Ltd.

Supplier Address 112 Maxfield Rd.

Greensboro, NC 27405 US

Supplier Phone Number Phone: (800) 648-4393

Fax: (336) 398-5680

Emergency Phone: CHEMTREC: (800) 424-9300

GHS INFORMATION

Classification:

LABEL ELEMENTS

Hazard Pictograms(s):

Signal Word:

Hazard Statements:

PRECAUTIONARYSTATEMENTS

Prevention:

Response:

Storage:

Disposal:

Hazards Not Otherwise Classified:

Not hazardous according to OSHA criteria (29 CFR 1910.1200).

Not hazardous according to WHMIS 2015 criteria.

None

None

Not applicable.

Not applicable.

Not applicable.

Not applicable.

Not applicable.

Not applicable.

1. Identification of the Substance / Preparation and of the Company / Undertaking

2. Hazards Identification


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Ingredients with Unknown Toxicity: None

This material is not considered hazardous by the OSHA Hazard Communication Standard, 2012 (29 CFR 1910.1200). This material is not considered hazardous by the Hazardous Products Regulations, 2015.

Ingredient(s)

Common name / Synonyms

CAS No.

% wt./wt.

1,2-Propanediol Propylene glycol 57-55-6 55 - 65

Water Not available. 7732-18-5 35 - 40

Phosphoric acid, potassium salt (1:2) Potassium phosphate, dibasic 7758-11-4 1 - 4

Inhalation: If inhaled: Call a poison center or doctor if you feel unwell.

Eye Contact:

Skin Contact:

Ingestion:

Acute and delayed symptoms and effects: May cause respiratory irritation. Signs/symptoms

may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

If in eyes: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a poison center or doctor if you feel unwell.

Acute and delayed symptoms and effects: May cause eye irritation. Signs/symptoms may

include redness, swelling, pain, tearing, and blurred or hazy vision.

If on skin: Wash with plenty of soap and water. Call a poison center or doctor if you feel unwell.

Acute and delayed symptoms and effects: May cause skin irritation. Signs/symptoms may

include localized redness, swelling, and itching.

Store in a well-ventilated place. Keep cool.

If swallowed: Call a poison center or doctor if you feel unwell. If vomiting occurs naturally, have victim lean forward to reduce the risk of aspiration. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person.

Acute and delayed symptoms and effects: May cause gastrointestinal irritation.

Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

General Advice: In case of accident or if you feel unwell, seek medical advice immediately. (Show the

label or SDS where possible.)

3. Composition / Information on Ingredients

4. First-Aid Measures


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Note to Physicians: Symptoms may not appear immediately.

FLAMMABILITY AND EXPLOSION INFORMATION

Not flammable or combustible by OSHA / WHMIS criteria. Material will not burn unless preheated.

Sensitivity to Mechanical Impact: This material is not sensitive to mechanical impact.

Sensitivity to Static Discharge: This material is sensitive to static discharge at temperatures at or above the flash point.

MEANS OF EXTINCTION

Suitable Extinguishing Media: Dry chemical, CO2 or alcohol-resistant foam. Move containers from fire

area if you can do it without risk.

. Unsuitable Extinguishing Media: Not available.

Products of Combustion: Oxides of carbon. Oxides of phosphorus.

Protection of Firefighters:

Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution. Wear positive pressure self- contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection.

Emergency Procedures:

Personal Precautions:

Environmental Precautions:

Methods for Containment:

Methods for Clean-Up:

Other Information:

Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

Do not touch or walk through spilled material. Use personal protection recommended in Section 8.

Keep out of drains, sewers, ditches, and waterways.

Stop leak if without risk. Do not flush to sewer or allow to enter waterways.

Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.

See Section 13 for disposal considerations.

5. Fire-Fighting Measures

6. Accidental Release Measures



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Handling:

Do not swallow. Avoid breathing mist, vapours, or spray. Avoid contact with eyes, skin, or clothing. See Section 8 for information on Personal Protection Equipment. Storage:

Store in a well-ventilated place; keep container tightly closed. Store at temperatures below 40°C (104 °F). Do not reuse container. Avoid container damage while storing. Store away from incompatible materials. See Section 10 for information on Incompatible Materials. Keep out of the reach of children.

Exposure Guidelines Component

Water [CAS No. 7732-18-5]

ACGIH: No TLV established.

OSHA: No PEL established.

Propylene glycol [CAS No. 57-55-6]



Potassium phosphate, dibasic [CAS No. 7758-11-4]



PEL: Permissible Exposure Limit

TLV: Threshold Limit Value

Engineering Controls: Not normally required.

7. Handling and Storage

8. Exposure Controls / Personal Protection


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PERSONAL PROTECTIVE EQUIPMENT (PPE)

Eye/Face Protection:

Hand Protection:

Skin and Body Protection:

Wear safety glasses with side shields or chemical goggles. Use equipment for eye protection that meets the standards referenced

by CSA Standard CAN/CSA – Z94. 3-92 and OSHA regulations in

29 CFR 1910.133 for Personal Protective Equipment.

Wear protective gloves. Neoprene rubber gloves are recommended. Consult manufacturer specifications for further information.

Wear protective clothing.

Respiratory Protection:

General Hygiene Considerations:

Not required under normal use conditions.

Handle according to established industrial hygiene and safety practices. Consult a competent industrial hygienist to determine hazard potential and/or the PPE manufacturers to ensure adequate protection.

Appearance: Clear or dyed liquid.

Colour: Colourless or dyed.

Odour: Characteristic.

Odour Threshold: Not available.

Physical State: Liquid.

pH: 8.5 to 11

Melting Point / Freezing Point:

15.6 °C (60 °F)

Initial Boiling Point: Not available.

Boiling Point: 108.3 °C (227 °F) at 760 mHg

Flash Point: 109 °C (228 °F) (PMCC) (estimated)

Evaporation Rate: Not available.

Flammability (solid, gas): Not applicable.

Lower Flammability Limit: 2.6 % (Propylene glycol)

Upper Flammability Limit: 12.6 % (Propylene glycol)

Vapor Pressure: Not available.

9. Physical and Chemical Properties


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Vapor Density: Not available.

Relative Density: 1.030 to 1.040 (Water = 1) at 15 °C (59 °F)

Solubilities: Soluble in water.

Partition Coefficient: n- Octanol/Water:

Not available.

Auto-ignition Temperature: 371 °C (699.8 °F) (Propylene glycol)

Decomposition Temperature:

Not available.

Viscosity: Not available.

Percent Volatile, wt. %: 55 to 65

VOC content, wt. %: Not available.

Density: 8.62 lb/gal

Coefficient of Water/Oil Distribution:

Not available.

Reactivity: Contact with incompatible materials. Sources of ignition. Exposure to heat.

Chemical Stability: Stable under normal storage conditions.

Possibility of Hazardous Reactions:

Reactions:

None known.

Conditions to Avoid: Contact with incompatible materials. Sources of ignition. Exposure to heat.

.

Incompatible Materials: Strong acids. Strong bases. Oxidizers.

Hazardous Decomposition Products: Not available.

10. Stability and Reactivity


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EFFECTS OF ACUTE EXPOSURE

Product Toxicity

Oral: Not available.

Dermal: Not available.

Inhalation: Not available.

Component Toxicity

Component CAS No. LD50 oral LD50 dermal LC50

Water 7732-18-5 > 90 mL/kg (rat) Not available. Not available.

Potassium phosphate,

dibasic

7758-11-4 Not available. Not available. Not available.

Propylene glycol 57-55-6 20000 mg/kg (rat) 20800 mg/kg (rabbit) Not available.

Likely Routes of Exposure: Eye contact. Skin contact. Inhalation. Ingestion.

Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Central nervous system.

Symptoms (including delayed and immediate effects)

Inhalation: May cause respiratory irritation. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Eye: May cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Skin: May cause skin irritation. Signs/symptoms may include localized redness, swelling, and itching.

Ingestion: May cause gastrointestinal irritation. Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Skin Sensitization: Not available.

Respiratory Sensitization: Not available.

Medical Conditions Aggravated By Exposure: Not available.

EFFECTS OF CHRONIC EXPOSURE (from short and long-term exposure)

Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Central nervous system.

11. Toxicological Information


of 10


Chronic Effects:

Prolonged or repeated contact may dry skin and cause irritation.

Carcinogenicity: This product does not contain any carcinogens or potential carcinogens as listed by the ACGIH, IARC, OSHA, or NTP.

Mutagenicity: Not available.

Reproductive Effects: Not available.

Developmental Effects

Teratogenicity: Not available.

Embryotoxicity: Not available.

Toxicologically Synergistic Materials: Not available.

Ecotoxicity: Not available.

Persistence / Degradability: When released into the soil, this material is expected to readily degrade. When released

into the water, this material is expected to have a half-life between 1 and 10 days. Bioaccumulation/Accumulation: Not available.

Mobility in Environment: Not available.

Other Adverse Effects: Not available.

Disposal Instructions: Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements.

U.S. Department of Transportation (DOT)

12. Ecological Information

13. Disposal Considerations

14. Transport information

Proper Shipping Name: Not regulated

Class: Not applicable.

UN Number: Not applicable.

Packing Group: Not applicable.

Label Code: Not applicable.


of 10


Canada Transportation of Dangerous Goods (TDG)

Chemical Inventories

US(TSCA)

The components of this product are in compliance with the chemical notification requirements of

TSCA.

Canada(DSL)

The components of this product are in compliance with the chemical notification requirements of the NSN Regulations under CEPA, 1999.

Federal Regulations

United States


SARA Title III

No components are listed.

State Regulations Massachusetts

New Jersey

US New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5)

Component CAS No. RTK List

Propylene glycol 57-55-6 Listed.

Section 15: REGULATORY INFORMATION

Proper Shipping Name: Not regulated.

Class: Not applicable.

UN Number: Not applicable.

Packing Group: Not applicable.

Label Code: Not applicable.

US Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of Massachusetts Regulations Section 670.000)

No components are listed.

15. Regulatory information


of 10


Pennsylvania

California

California Prop 65: This product does not contain chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.

Prepared By: Randy Boitz

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

US Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)

Component CAS No. RTK List

Propylene glycol 57-55-6 Listed.

16. Other information


Safety Data Sheet Graffiti Gone

PAGE 1 of 5

SECTION I - IDENTIFICATION

PRODUCT NAME: Graffiti Gone PRODUCT CODE: 2210 PRODUCT USE: Paint and Varnish Remover COMPANY NAME: QuestSpecialty Corporation COMPANY ADDRESS: PO Box 624 Brenham, TX 77834 COMPANY PHONE: 1-800-231-0454 EMERGENCY PHONE: 800-255-3924

SECTION II – HAZARDS IDENTIFICATION

CLASSIFICATION: Flammable Aerosol: Category 1 Liquefied Gas Skin Irritant: Category 2 Eye Irritant: Category 2A Acute Toxicity Inhalation: Category 4 Specific Target Organ Toxicity (Single Exposure): Category 3 Aspiration Hazard: Category 1 HAZARD STATEMENT(S): DANGER: Extremely Flammable Aerosol Contains gas under pressure: May explode if heated. Causes

skin irritation , serious eye irritation, and may cause respiratory irritation. Harmful if inhaled. May be fatal if swallowed and enters airways.

This product contains the following percentage of chemicals of unknown toxicity: 6% PRECAUTIONARY STATEMENTS: Keep away from heat, sparks, open flames, and hot surfaces. -No smoking. Do not spray on an

open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Wash hands thoroughly after handling. Wear protective gloves and protective glasses. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If swallowed: Immediately call a poison center or doctor. Do NOT induce vomiting. Store locked up. Dispose of contents and container in accordance with local, state, and national regulations. Avoid breathing fumes, mist, vapors, and spray. Use only outdoors or in a well-ventilated area. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell.

SYMBOL: HAZARDS NOT OTHERWISE CLASSIFIED: N/A

SECTION III – COMPOSITION/INFORMATION ON INGREDIENTS

HAZARDOUS INGREDIENT CAS NUMBER PERCENT

Acetone 67-64-1 30-60% Xylene 1330-20-7 15-40% Propane/n-Butane 68476-86-8 10-30% Ethyl Benzene 100-41-4 5-10%

SECTION IV - FIRST AID MEASURES

EYES: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.

INGESTION: Rinse mouth with water. Do not induce vomiting unless directed by medical authority. Seek medical attention. INHALATION: If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel

unwell. SKIN: If on skin: Wash with plenty of water. If skin irritation occurs: get medical attention. ACUTE HEALTH HAZARDS: Inhalation: dizziness, drowsiness, weakness, fatigue, and serious nervous system depression Eye: stinging, tearing, redness, blurred vision Oral: Aspiration risk



PAGE 2 of 5

Skin: Defatting and dermatitis CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone

marrow, central nervous system (CNS). NOTE TO PHYSICIAN: There is no specific treatment regimen. Treatment of overexposure should be directed at the control of

symptoms and the clinical condition of the patient.

SECTION V – FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, foam, water spray for cooling. UNSUITABLE EXTINGUISHING MEDIA: Water spray/stream. SPECIAL FIRE FIGHTING PROCEDURES: Wear NIOSH approved Self Contained Breathing Apparatus with a full face piece

operated in a positive pressure demand mode with full body protective clothing when fighting fires. Use water spray only to cool exposed containers.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep away from sparks, open flames, and hot surfaces. No smoking. Do not spray on an open flame or other ignition source.

HAZARDOUS COMBUSTION PRODUCTS: Oxides of carbon

SECTION VI – ACCIDENTAL RELEASE MEASURES

PERSONAL PROTECTIVE EQUIPMENT: Refer to section VIII for proper Personal Protective Equipment. SPILL: Wpe up with rag or use some absorbent clay material. remove any source of ignition. use non-sparking tools and equipment. WASTE DISPOSAL: Dispose of in accordance with local, State and Federal regulations. Do not puncture or incinerate container. Do

not reuse empty container. Wrap container and place in trash collection. RCRA STATUS: Waste solvent likely considered U239 (Xylene), hazardous, under RCRA, however product should be fully

characterized prior to disposal (40 CFR 261).

SECTION VII – HANDLING AND STORAGE

HANDLING AND STORAGE: Protect from sunlight. Store in a well ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Pressurized container: Do not pierce or burn, even after use. Store locked up.

OTHER PRECAUTIONS: Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warning and precautions listed for the product. Keep out of the reach of children

INCOMPATIBILITY: Concentrated nitric & sulfuric acid mixtures, oxidizing materials, chloroform, alkalis, chlorine cmpnds, acids, plastics, rubber, coatings.

SECTION VIII – EXPOSURE CONTROLS/PERSONAL PROTECTION

HAZARDOUS INGREDIENT OSHA PEL ACGIH TLV Acetone 1000 ppm 500 ppm Xylene 100 ppm 100 ppm Propane/n-Butane 1000 ppm 1000 ppm Ethyl Benzene 100 ppm 100 ppm

ENGINEERING CONTROLS / VENTILATION: Use only in well ventilated areas or outside. Forced ventilation required. Local

exhaust preferred to general. RESPIRATORY PROTECTION: Not required with normal use. Wear NIOSH/MSHA approved respiratory protection if exposure

limits are exceeded. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses and chemical resistant gloves ADDITIONAL MEASURES: Wash hands thoroughly after handling. Avoid breathing vapors.

SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Clear Aerosol Spray ODOR: Solvent odor ODOR THRESHOLD: N/D BOILING POINT: >150 FREEZING POINT: N/D



PAGE 3 of 5

FLAMMABILITY: Flammable Aerosol FLASH POINT: 65°F AUTOIGNITION TEMPERATURE: N/D LOWER FLAMMABILITY LIMIT: N/D UPPER FLAMMABILITY LIMIT: N/D VAPOR PRESSURE (mm Hg): 77.3 @ 77°F (25°C) VAPOR DENSITY (AIR=1): > 2 EVAPORATION RATE: > 1 SPECIFIC GRAVITY (H2O=1): 0.87 @ 77° F pH: N/A SOLIDS (%): 7.5% SOLUBILITY IN WATER: 3% PARTITION COEFFICIENT: n-OCTANOL/WATER (KOW): N/D VOLATILITY INCLUDING WATER (%): > 80% VOLATILE ORGANIC COMPOUNDS (VOC): 50% DIELECTRIC STRENGTH (Volts): N/D DECOMPOSITION TEMPERATURE: N/D VISCOSITY: N/D

SECTION X – STABILITY AND REACTIVITY DATA

REACTIVITY: None Known CHEMICAL STABILITY: Stable CONDITIONS TO AVOID: Temperatures greater than 122°F and sources of ignition. INCOMPATIBILITY: Concentrated nitric & sulfuric acid mixtures, oxidizing materials, chloroform, alkalis, chlorine cmpnds, acids,

plastics, rubber, coatings. HAZARDOUS DECOMPOSITION OR BY-PRODUCT: Oxides of carbon POSSIBLE HAZARDOUS REACTIONS: None Known

SECTION XI – TOXICOLOGICAL INFORMATION

TOXICOLOGICAL INFORMATION: Acetone (67-64-1) LD50 (Oral, Rat) 5800 mg/kg; LD50 (Oral, Mouse) 3000 mg/kg; LD50 (Oral, Rabbit) 5340 mg/kg; LC50 (Inhalation, Rat, 8hr) 50100 mg/m3; LC50 (Inhalation, Mouse, 4hr) 44,000 mg/m3 Xylenes (1330-20-7) LD50 (Oral, Rat) 4300 mg/kg; LD50 (Oral, Mouse) 2119 mg/kg; LD50 (Dermal, Rat) 1700 mg/kg

ROUTES OF ENTRY: Ingestion, Inhalation, Skin EYES: Redness, irritation, causes temporary corneal opacity INGESTION: May cause nausea, diarrhea, vomiting, depending on the amount ingested. INHALATION: Causes dizziness, nausea, vomiting, excessive or prolonged exposure may cause unconsciousness, death. SKIN: Causes severe irritation, localized defatting. MEDICAL CONDITION AGGRAVATED: None known ACUTE HEALTH HAZARDS: Inhalation: dizziness, drowsiness, weakness, fatigue, and serious nervous system depression Eye: stinging, tearing, redness, blurred vision Oral: Aspiration risk Skin: Defatting and dermatitis CHRONIC HEALTH HAZARDS: May cause damage to the following organs: blood, kidneys, liver, mucous membranes, bone

marrow, central nervous system (CNS). CARCINOGENICITY: OSHA: No ACGIH: No NTP: No IARC: No OTHER: N/A

SECTION XII – ECOLOGICAL INFORMATION

ECOLOGICAL INFORMATION: Acetone (67-64-1) LC50 (Trout, 96hr) 5540 mg/L; LC50 (Bluegill, 96hr) 8300 mg/L; LC50 (Fathead Minnow, 96hr) 7500 mg/L

BIODEGRADABILITY: Component or components of this product are not biodegradable. BIOACCUMULATION: This product is not expected to bioaccumulate. SOIL MOBILITY: This product is mobile in soil. OTHER ECOLOGICAL HAZARDS: This material is toxic to aquatic life.



PAGE 4 of 5

SECTION XIII – DISPOSAL CONSIDERATIONS

WASTE DISPOSAL: Dispose of in accordance with local, State and Federal regulations. Do not puncture or incinerate container. Do not reuse empty container. Wrap container and place in trash collection.

RCRA STATUS: Waste solvent likely considered U239 (Xylene), hazardous, under RCRA, however product should be fully characterized prior to disposal (40 CFR 261).

SECTION XIV - TRANSPORTATION INFORMATION

PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: N/A AIR SHIPMENT PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: None SHIPPING BY WATER: VESSEL (IMO/IMDG) PROPER SHIPPING NAME: Aerosols, Ltd. Qty. HAZARD CLASS/DIVISION: 2.1 UN/NA NUMBER: UN 1950 PACKAGING GROUP: None ENVIRONMENTAL HAZARDS WATER: 2102

SECTION XV - REGULATORY INFORMATION

TSCA STATUS: All Chemicals are listed or exempt. CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Xylenes (1330-20-7) Reportable

Quantity = 100 lbs Ethylbenzene (100-41-4): RQ 1000lbs SARA 311/312 HAZARD CATEGORIES: Fire Hazard SARA 313 REPORTABLE INGREDIENTS: Xylenes - 1330-20-7 CLEAN WATER ACT: None STATE REGULATIONS: Xylenes - 1330-20-7 - Connecticut hazardous material survey, Illinois chemical safety act, New York acutely

hazardous substances, Rhode Island RTK hazardous substances, Pennsylvania RTK, Minnesota, Michigan critical material, Massachusetts RTK, Massachusetts spill list, New Jersey spill list, Louisiana spill reporting, California Director's List of Hazardous Substances.

INTERNATIONAL REGULATIONS: Xylenes - EINECS, WHMIS (Canada): CLASS B-2. CLASS D-2A. DSCL (EEC): R10- Flammable. R21- Harmful in contact with skin. R36/38- Irritating to eyes and skin. S2- Keep out of the reach of children. S36/37- Wear suitable protective clothing and gloves. S46- If swallowed, seek medical advice immediately and show this container or label.

NFPA HEALTH: 2 HMIS HEALTH: 2 NFPA FLAMMABILITY: 3 HMIS FLAMMABILITY: 3 NFPA REACTIVITY: 1 HMIS REACTIVITY: 1 NFPA OTHER: None HMIS PROTECTION: B

SECTION XVI - ADDTIONAL INFORMATION

PREPARATION BY: Jonathon Jarvis DATE PREPARED: 12/16/2013 REVISION DATE: 11/10/2014 N/A = Not Applicable; N/D = Not Determined



PAGE 5 of 5

DISCLAIMER: To the best of our knowledge, information contained herein is accurate. However there is no assumption of liability for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazard which exists. The information contained in this SDS was obtained from current and reliable sources; however, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions or handling, storage and disposal of this product are beyond the control of the manufacturer, the manufacturer will not be responsible for loss, injury, or expense arising out of the products improper use. No warranty, expressed or inferred, regarding the product described in this SDS shall be created or inferred by any statement in this SDS. Various government agencies may have specific regulations regarding the transportation, handling, storage, use, or disposal of this product which may not be covered by this SDS. The user is responsible for full compliance.


1. IDENTIFICATION

Product identifier Product Name Gumout Regane Auto Parts Cleaner & Degreaser

Other means of identification Product Code 11893Document SKU 540001Synonyms None

Recommended use of the chemical and restrictions on use Recommended Use Automotive parts cleaner & degreaserUses advised against All other applications


Company Phone Number 1-855-888-198824 Hour Emergency Phone Number (CHEMTREC) 1-800-424-9300 or 1-703-527-3887 (U.S.)

(RMPDC) 1-877-504-9352 (U.S.)

E-mail address [email protected]


Classification

OSHA Regulatory StatusThis chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)

Serious eye damage/eye irritation Category 2Reproductive toxicity Category 2Specific target organ toxicity (single exposure) Category 3Specific target organ toxicity (repeated exposure) Category 2

Label elements

Emergency Overview

_____________________________________________________________________________________________

Page 1 / 10

Revision Date 13-May-2015

Manufacturer Address

Causes serious eye irritationSuspected of damaging fertility or the unborn childMay cause drowsiness or dizzinessMay cause damage to organs through prolonged or repeated exposure

Distributor

SAFETY DATA SHEET

Version 1

Supplier AddressITW Global Brands6925 Portwest Dr., Suite 100Houston, TX 77024

Warning


_____________________________________________________________________________________________

Precautionary Statements - PreventionObtain special instructions before useDo not handle until all safety precautions have been read and understoodUse personal protective equipment as requiredWash face, hands and any exposed skin thoroughly after handlingWear eye/face protectionDo not breathe dust/fume/gas/mist/vapors/sprayUse only outdoors or in a well-ventilated area

Precautionary Statements - ResponseIF exposed or concerned: Get medical advice/attentionIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attentionIF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing

Precautionary Statements - StorageStore locked upStore in a well-ventilated place. Keep container tightly closedDo not expose to temperatures exceeding 122 °F (50 °C)Keep out of reach of children

Precautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC) Not applicable

Other Information Causes mild skin irritation. Harmful to aquatic life with long lasting effects.


substance(s)

Chemical Name CAS No Weight-% Trade SecretACETONE 67-64-1 60 - 100 *TOLUENE 108-88-3 5 - 10 *

CARBON DIOXIDE 124-38-9 5 - 10 **The exact percentage (concentration) of composition has been withheld as a trade secret.


Description of first aid measures

General advice Get medical advice/attention if you feel unwell.

_____________________________________________________________________________________________

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Revision Date 13-May-201511893 - Gumout Regane Auto Parts Cleaner &Degreaser

Appearance Colorless to light yellowliquid

Physical state Aerosol Liquid Odor Acetone


_____________________________________________________________________________________________

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medicaladvice/attention.

Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.Wash contaminated clothing before reuse.

Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing. If symptoms persist, call a physician.

Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to anunconscious person. Call a physician.

Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.


Symptoms See section 2 for more information.


Note to physicians Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing mediaDry chemical, CO2, sand, earth, water spray or regular foam

Unsuitable extinguishing mediaNone.

Specific hazards arising from the chemicalExtremely flammable. Contents under pressure and can explode when exposed to heat or flames.

Explosion data Sensitivity to Mechanical Impact None.Sensitivity to Static Discharge May be ignited by friction, heat, sparks or flames.

Protective equipment and precautions for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.



Personal precautions Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas.Do not get in eyes, on skin, or on clothing. Do not puncture or incinerate cans. Contentsunder pressure. Use personal protective equipment as required.


Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additionalecological information.


Methods for containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovelinto suitable containers for disposal.

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations.

7. HANDLING AND STORAGE


Advice on safe handling Contents under pressure. Do not puncture or incinerate cans. Handle in accordance withgood industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contactwith skin, eyes or clothing. Wash contaminated clothing before reuse. Use personalprotective equipment as required.


Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Do not expose totemperatures exceeding 50 °C/122 °F. Keep away from sunlight, ignition sources and othersources of heat. Keep out of the reach of children.

Incompatible materials Strong oxidizing agents


Control parameters

Exposure Guidelines .Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

ACETONE 67-64-1

STEL: 750 ppmTWA: 500 ppm

TWA: 1000 ppmTWA: 2400 mg/m3

(vacated) TWA: 750 ppm(vacated) TWA: 1800 mg/m3

(vacated) STEL: 2400 mg/m3 Theacetone STEL does not apply to thecellulose acetate fiber industry. It is

in effect for all other sectors(vacated) STEL: 1000 ppm

IDLH: 2500 ppmTWA: 250 ppm

TWA: 590 mg/m3

TOLUENE 108-88-3

TWA: 20 ppm TWA: 200 ppm(vacated) TWA: 100 ppm

(vacated) TWA: 375 mg/m3

(vacated) STEL: 150 ppm(vacated) STEL: 560 mg/m3

Ceiling: 300 ppm


TWA: 375 mg/m3

STEL: 150 ppmSTEL: 560 mg/m3

CARBON DIOXIDE 124-38-9

STEL: 30000 ppmTWA: 5000 ppm



(vacated) STEL: 30000 ppm(vacated) STEL: 54000 mg/m3


TWA: 9000 mg/m3


NIOSH IDLH Immediately Dangerous to Life or Health


Engineering Controls ShowersEyewash stationsVentilation systems


Eye/face protection Wear safety glasses with side shields (or goggles).

Skin and body protection Wear protective gloves and protective clothing.

Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, asappropriate.

_____________________________________________________________________________________________

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11893 - Gumout Regane Auto Parts Cleaner &Degreaser



_____________________________________________________________________________________________

General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning ofequipment, work area and clothing is recommended.



Physical state Aerosol; LiquidAppearance Colorless to light yellow liquidOdor AcetoneOdor threshold No information available

Explosive properties No information availableOxidizing properties No information available

Other Information

Softening point No information availableMolecular weight No information availableVOC Content (%) 9.6Density 0.798 g/cm3Bulk density No information available


Reactivity

Chemical stabilityStable under recommended storage conditions.

Possibility of Hazardous ReactionsNone under normal processing.

Conditions to avoidHeat, flames and sparks. Extremes of temperature and direct sunlight. Temperatures >50 °C / 122 °F.

Incompatible materialsStrong oxidizing agents

_____________________________________________________________________________________________

Page 5 / 10

Setaflash Closed Cup

pH

Partition coefficient No information available

Not Applicable

Evaporation rate 14.4

Autoignition temperature 465 °C / 869 °FDecomposition temperature No information available

Butyl acetate = 1

Kinematic viscosity No information available

Flammability (solid, gas) No information available

Dynamic viscosity No information available

Property

Flammability Limit in Air

Melting point / freezing point No information available

Upper flammability limit: No information available

Values

Lower flammability limit: No information available


Vapor pressure No information available

Boiling point / boiling range 56 °C / 133 °F

Stable under normal use

Vapor density No information available

Remarks • Method

Relative density 0.798

Flash point

Water solubility Miscible in water

-20 °C / -4 °F


Solubility in other solvents No information available


_____________________________________________________________________________________________

Hazardous Decomposition ProductsCarbon oxides



Inhalation May cause irritation of respiratory tract.

Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes.

Skin contact May cause skin irritation and/or dermatitis.

Ingestion Ingestion may cause irritation to mucous membranes.

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50ACETONE 67-64-1

= 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h

TOLUENE 108-88-3

= 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h


Symptoms No information available.


Sensitization No information available.Germ cell mutagenicity No information available.Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.Chemical Name ACGIH IARC NTP OSHATOLUENE 108-88-3

- Group 3 - -

IARC (International Agency for Research on Cancer)Not classifiable as a human carcinogenChronic toxicity May cause adverse liver effects.Target Organ Effects Central nervous system, Central Vascular System (CVS), Eyes, kidney, Liver, Respiratory

system, Skin.

The following values are calculated based on chapter 3.1 of the GHS document .ATEmix (oral) 5580 mg/kgATEmix (dermal) 129032 mg/kgATEmix (inhalation-dust/mist) 63.5 mg/l


Ecotoxicity

Chemical Name Algae/aquatic plants Fish CrustaceaACETONE

67-64-1- 4.74 - 6.33: 96 h Oncorhynchus

mykiss mL/L LC50 6210 - 8120: 96h Pimephales promelas mg/L LC50

static 8300: 96 h Lepomismacrochirus mg/L LC50

10294 - 17704: 48 h Daphniamagna mg/L EC50 Static 12600 -12700: 48 h Daphnia magna mg/L

EC50

_____________________________________________________________________________________________

Page 6 / 10




_____________________________________________________________________________________________

TOLUENE 108-88-3

433: 96 h Pseudokirchneriellasubcapitata mg/L EC50 12.5: 72 hPseudokirchneriella subcapitata

mg/L EC50 static

15.22 - 19.05: 96 h Pimephalespromelas mg/L LC50 flow-through12.6: 96 h Pimephales promelas

mg/L LC50 static 5.89 - 7.81: 96 hOncorhynchus mykiss mg/L LC50

flow-through 14.1 - 17.16: 96 hOncorhynchus mykiss mg/L LC50

static 5.8: 96 h Oncorhynchusmykiss mg/L LC50 semi-static 11.0 -

15.0: 96 h Lepomis macrochirusmg/L LC50 static 54: 96 h Oryziaslatipes mg/L LC50 static 28.2: 96 h

Poecilia reticulata mg/L LC50semi-static 50.87 - 70.34: 96 h

Poecilia reticulata mg/L LC50 static

5.46 - 9.83: 48 h Daphnia magnamg/L EC50 Static 11.5: 48 hDaphnia magna mg/L EC50

Persistence and degradabilityNo information available.

BioaccumulationNo information available.

MobilityDisperses in water.

Chemical Name Partition coefficientACETONE

67-64-1-0.24

TOLUENE 108-88-3

2.65

Other adverse effectsNo information available


Waste treatment methods

Disposal of wastes Recover or recycle if possible. Disposal should be in accordance with applicable regional,national and local laws and regulations.

Contaminated packaging Do not reuse container.

US EPA Waste Number U002 U220

Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series WastesACETONE

67-64-1- Included in waste stream:

F039- U002

TOLUENE 108-88-3

U220 Included in waste streams:F005, F024, F025, F039,K015, K036, K037, K149,

K151

- U220

Chemical Name RCRA - HalogenatedOrganic Compounds

RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes

_____________________________________________________________________________________________

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_____________________________________________________________________________________________

TOLUENE 108-88-3

- - Toxic wastewaste number F025Waste description:

Condensed light ends, spentfilters and filter aids, and

spent desiccant wastes fromthe production of certain

chlorinated aliphatichydrocarbons, by free

radical catalyzed processes.These chlorinated aliphatic

hydrocarbons are thosehaving carbon chain lengths

ranging from one to andincluding five, with varyingamounts and positions of

chlorine substitution.

-

This product contains one or more substances that are listed with the State of California as a hazardous waste.

Chemical Name California Hazardous Waste StatusACETONE

67-64-1Ignitable

TOLUENE 108-88-3

ToxicIgnitable


DOT UN/ID no UN 1950Proper shipping name: Aerosols, Flammable, Consumer Commodity, Limited Quantity (LQ)Hazard Class 2.1

IATA UN/ID no UN 1950Proper shipping name: Aerosols, flammable, Consumer commodity, Limited Quantity (LQ)Hazard Class 2.1

IMDG UN/ID no UN 1950Proper shipping name: Aerosols, flammable, Consumer Commodity, Limited Quantity (LQ)Hazard Class 2.1

15. REGULATORY INFORMATIONInternational Inventories TSCA CompliesDSL/NDSL CompliesEINECS/ELINCS CompliesENCS Not determinedIECSC Not determinedKECL Not determinedPICCS Not determinedAICS Not determined

Legend: TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListEINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical SubstancesENCS - Japan Existing and New Chemical SubstancesIECSC - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical Substances

_____________________________________________________________________________________________

Page 8 / 10




_____________________________________________________________________________________________

PICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical Substances

US Federal Regulations

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name SARA 313 - Threshold Values %TOLUENE - 108-88-3 1.0SARA 311/312 Hazard Categories

Acute health hazard NoChronic Health Hazard NoFire hazard NoSudden release of pressure hazard NoReactive Hazard No

CWA (Clean Water Act)This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42)

Chemical Name CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances

TOLUENE 108-88-3

1000 lb X X X

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)ACETONE

67-64-15000 lb - RQ 5000 lb final RQ

RQ 2270 kg final RQTOLUENE 108-88-3

1 lb - RQ 1 lb final RQRQ 0.454 kg final RQ


California Proposition 65WARNING: This product contains chemicals known to the state of California to cause birth defects or other reproductive harm Thisproduct contains the following Proposition 65 chemicals

Chemical Name California Proposition 65TOLUENE - 108-88-3 Developmental

Female ReproductiveU.S. State Right-to-Know Regulations

Chemical Name New Jersey Massachusetts PennsylvaniaACETONE

67-64-1X X X

TOLUENE 108-88-3

X X X

CARBON DIOXIDE 124-38-9

X X X

U.S. EPA Label Information EPA Pesticide Registration Number Not applicable

NFPA (National Fire Protection Association)HMIS (Hazardous Material Information System)_____________________________________________________________________________________________

Page 9 / 10


Flammability 3 Physical hazards 0 Personal protection BHealth hazards 2


Flammability 3 Instability 0 -HMIS NFPA

Health hazards 2


_____________________________________________________________________________________________

Revision Date 13-May-2015Revision Note 2

DisclaimerThe information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and beliefat the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text.


_____________________________________________________________________________________________

Page 10 / 10



Revision Date 08-Sep-2014Version 1

Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

Product name KILL ODOR PLUSProduct code W.20234

Emergency telephone number Chemtrec: 1-800-424-9300 for US +1 703-527-3887 outside US

2. Hazards identificationEmergency OverviewMay cause central nervous system depressionMay cause adverse kidney effects

Potential Health Effects Acute toxicity

Eyes May cause slight irritation.

Skin No known effect based on information supplied.

Inhalation May be harmful if inhaled.

Ingestion No known effect based on information supplied.

Chronic Effects May cause adverse liver effects.

Aggravated Medical Conditions Central nervous system. Preexisting eye disorders. Blood disorders. Kidney disorders. Liverdisorders. Skin disorders. Respiratory disorders. Hematopoietic system.

Interactions with Other Chemicals Use of alcoholic beverages may enhance toxic effects.

Environmental hazard See Section 12 for additional Ecological Information.

3. Composition/information on ingredients

Component CAS-No Weight %ETHANOL, 2-BUTOXY-

111-76-2 ( 10-30 )111-76-2 10-30

Butylated hydroxytoluene (BHT) 128-37-0 ( <0.1 )

128-37-0 <0.1

4. First aid measures

_____________________________________________________________________________________________

General advice Show this material safety data sheet to the doctor in attendance.

Eye contact

08-Sep-2014 - W.20234 - 1 - WPNA - English -

Remove contact lenses. Rinse thoroughly with plenty of water for at least 15 minutes andconsult a physician.

Page 1 / 7

Manufacturer Chemspec901 North Newkirk StreetBaltimore, MD 21205


KILL ODOR PLUS_____________________________________________________________________________________________

Skin contact Wash off immediately with soap and plenty of water. Remove all contaminated clothes andshoes.

Inhalation Move to fresh air.

Ingestion Gently wipe or rinse the inside of the mouth with water.

Notes to physician Treat symptomatically.

5. Fire-fighting measures

Flammable Properties Not flammable.

Flash point Not determined. Not Determined

Suitable extinguishing media Water spray. Foam. Dry powder.

Explosion Data Sensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.

Protective Equipment andPrecautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.

6. Accidental release measures

Personal precautions Use personal protective equipment.

Environmental precautions No special environmental precautions required.


Methods for cleaning up Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth,diatomaceous earth, vermiculite) and transfer to a container for disposal according to local /national regulations (see section 13).

7. Handling and storage

Advice on safe handling Wear personal protective equipment.

Technical measures/Storageconditions

Use only in area provided with appropriate exhaust ventilation. Keep tightly closed in a dryand cool place.

8. Exposure controls/personal protection

Exposure Guidelines .

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH MexicoETHANOL, 2-BUTOXY-

111-76-2TWA: 20 ppm TWA: 50 ppm

TWA: 240 mg/m3


(vacated) S*S*


TWA: 24 mg/m3



Butylated hydroxytoluene(BHT)

128-37-0

TWA: 2 mg/m3 inhalablefraction and vapor

(vacated) TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3

STEL: 20 mg/m3

Component British Columbia Alberta Quebec Ontario TWAEV

_____________________________________________________________________________________________

ETHANOL, 2-BUTOXY- 111-76-2 ( 10-30 )

TWA: 20 ppm TWA: 20 ppmTWA: 97 mg/m3


TWA: 20 ppm

Butylated hydroxytoluene (BHT) 128-37-0 ( <0.1 )

TWA: 2 mg/m3


TWA: 10 mg/m3

Page 2 / 7

STEL: 10 mg/m3 TWA: 2 mg/m3


KILL ODOR PLUS_____________________________________________________________________________________________Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962

(11th Cir., 1992).

Engineering Measures ShowersEyewash stationsVentilation systems.

Personal Protective Equipment Hand Protection Rubber gloves Rubber/latex/neoprene or other suitable chemical resistant glovesEye/Face Protection Safety glasses with side-shields. Goggles.Skin and body protection Skin and body protection.Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved

respiratory protection should be worn. Positive-pressure supplied air respirators may berequired for high airborne contaminant concentrations. Respiratory protection must beprovided in accordance with current local regulations.

Hygiene measures When using, do not eat, drink or smoke.

10. Stability and reactivity

Stability/Reactivity Stable under recommended storage conditions.

Incompatible products None known based on information supplied.

Conditions to Avoid Direct sources of heat.

Hazardous Decomposition Products Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense blacksmoke.

Hazardous Polymerization Hazardous polymerization does not occur.

11. Toxicological information

9. Physical and chemical properties

Physical state LiquidAppearance Clear liquidOdor CleanColor Yellow

Explosive properties no data available

Other information Volatile organic compounds (VOC)content

15%

Melting/freezing pointFreezing Point Not Determined

Property Values Remarks • Methods pH 7.3Boiling point/boiling range Not DeterminedFlash Point Not DeterminedEvaporation rate no data availableExplosion Limits

upperlower

Vapor pressure no data availableVapor density no data availableSpecific Gravity 1.011 g/cc

_____________________________________________________________________________________________

Viscosity, kinematic no data availableWater solubility no data available



Page 3 / 7

no data available


KILL ODOR PLUS_____________________________________________________________________________________________

Acute toxicity

Product Information The product itself has not been tested.

Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationETHANOL, 2-BUTOXY- 470 mg/kg ( Rat ) 220 mg/kg ( Rabbit ) 450 ppm ( Rat ) 4 h

Butylated hydroxytoluene (BHT) 890 mg/kg ( Rat )

Chronic toxicity

Chronic toxicity May cause adverse liver effects

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.

Chemical Name ACGIH IARC NTP OSHA MexicoETHANOL, 2-BUTOXY- A3 Group 3


Group 3

ACGIH: (American Conference of Governmental Industrial Hygienists)A3 - Animal CarcinogenIARC: (International Agency for Research on Cancer)Group 3 - Not Classifiable as to Carcinogenicity in Humans

Target Organ Effects Blood Central nervous system Eyes Hematopoietic System Kidney Liver Respiratorysystem Skin

12. Ecological information

Ecotoxicity No information available. .

Chemical Name Toxicity to algae Toxicity to fish Toxicity to daphniaand other aquatic

invertebrates

Toxicity tomicroorganisms

Toxicity to otherorganisms

ETHANOL, 2-BUTOXY- LC50: 96 h Lepomismacrochirus 1490

mg/L static LC50: 96 hLepomis macrochirus

2950 mg/L

EC50: 48 h Daphniamagna 1000 mg/L


EC50: 72 hPseudokirchneriellasubcapitata 6 mg/L

EC50: 72 hDesmodesmus

subspicatus 0.42 mg/LPersistence and degradability No information available.

Bioaccumulation .

Mobility No information available.

_____________________________________________________________________________________________

Chemical Name log PowETHANOL, 2-BUTOXY- 0.81

Butylated hydroxytoluene (BHT) 4.17


13. Disposal considerations

Page 4 / 7


KILL ODOR PLUS_____________________________________________________________________________________________Waste Disposal Methods This material, as supplied, is not a hazardous waste according to Federal regulations (40

CFR 261). This material could become a hazardous waste if it is mixed with or otherwisecomes in contact with a hazardous waste, if chemical additions are made to this material, orif the material is processed or otherwise altered. Consult 40 CFR 261 to determine whetherthe altered material is a hazardous waste. Consult the appropriate state, regional, or localregulations for additional requirements.

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling ordisposal.


DOT Not regulated

MEX Not regulated

15. Regulatory informationInternational Inventories TSCA CompliesDSL CompliesEINECS/ELINCS CompliesENCS CompliesIECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC Complies

TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListEINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical SubstancesENCS - Japan Existing and New Chemical SubstancesIECSC - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical SubstancesPICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical SubstancesNZIoC - New Zealand Inventory of Chemicals"-" - Unknown. Not listed.

U.S. Federal Regulations

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical Name Weight % SARA 313 - Threshold Values %ETHANOL, 2-BUTOXY- 10-30 1.0

SARA 311/312 Hazard Categories Acute Health Hazard NoChronic Health Hazard No

_____________________________________________________________________________________________

Fire Hazard NoSudden Release of Pressure Hazard No


Reactive Hazard

Page 5 / 7

No


KILL ODOR PLUS_____________________________________________________________________________________________Clean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42):

Chemical Name CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances

Sodium hydroxide 1000 lb X

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

Chemical Name Hazardous Substances RQs Extremely Hazardous SubstancesRQs

RQ

Sodium hydroxide 1000 lb RQ 1000 lb final RQRQ 454 kg final RQ

U.S. State Regulations

California Proposition 65This product does not contain any Proposition 65 chemicals.


Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode IslandETHANOL, 2-BUTOXY- X X X X

Sodium hydroxide X X X


X X X

International Regulations

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) andthe MSDS contains all the information required by the CPR.

WHMIS Hazard ClassNon-controlled


Prepared By Chemspec Regulatory Affairs/Product Safety

Revision Date 08-Sep-2014Revision Note No information available.

Legend: NIOSH IDLH: Immediately Dangerous to Life or Health

DisclaimerThe information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guide for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered as a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterial or in any process, unless specified in the text.

NFPA

_____________________________________________________________________________________________

Health Hazard 2 Flammability 0 Stability/Reactivity 0 Physical and chemicalhazards -

HMIS Health Hazard 2


Flammability 0

Page 6 / 7

Physical Hazard 0 Personal protection -


KILL ODOR PLUS_____________________________________________________________________________________________

_____________________________________________________________________________________________

End of Material Safety Data Sheet

08-Sep-2014 - W.20234 - 1 - WPNA - English - Page 7 / 7



Liquid HE® 150 XPT

Version 1.3 Revision Date 2013-04-10

MSDS Number:100000014523 1/11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product information

Trade name : Liquid HE® 150 XPT Material : 1111304, 1103273, 1099686

Use : Drilling Fluid Additive Company : Drilling Specialties Company

10001 Six Pines Drive The Woodlands, TX 77380

Emergency telephone: Health: 866.442.9628 (North America) 1.832.813.4984 (International) Transport: North America: CHEMTREC 800.424.9300 or 703.527.3887 Asia: +800 CHEMCALL (+800 2436 2255) EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600

Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com

SECTION 2: Hazards identification

Emergency Overview

Physical state: Liquid Color: Opaque Odor: Slight hydrocarbon OSHA Hazards : Combustible Liquid GHS Classification

: Flammable liquids, Category 4

GHS-Labeling

Signal Word : Warning

Hazard Statements : H227: Combustible liquid

Precautionary Statements : Prevention:



Liquid HE® 150 XPT


MSDS Number:100000014523 2/11

P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P264: Wash skin thoroughly after handling. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P370 + P378: In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.

Carcinogenicity:

IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.

ACGIH No ingredient of this product present at levels greater than or



Synonyms : HE® 150 Liquid Liquid Acid Gelling Agent

Molecular formula : Mixture

Component CAS-No. Weight % Distillates (petroleum), Hydrotreated light

64742-47-8 30 - 60


General advice : Move out of dangerous area. Show this material safety data

sheet to the doctor in attendance. Do not leave the victim unattended.

If inhaled : If unconscious place in recovery position and seek medical

advice. If symptoms persist, call a physician. In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well

with water. If on clothes, remove clothes. In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact



Liquid HE® 150 XPT


MSDS Number:100000014523 3/11

lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear. Never give anything by mouth to

an unconscious person. If symptoms persist, call a physician.

SECTION 5: Firefighting measures

Flash point : > 77 °C (> 171 °F) Method: ASTM D 93

Autoignition temperature : 225 °C (437 °F)


: Carbon dioxide (CO2).


: High volume water jet.


: Wear self contained breathing apparatus for fire fighting if necessary.

Further information : For safety reasons in case of fire, cans should be stored

separately in closed containments. Use a water spray to cool fully closed containers.

Fire and explosion protection

: Do not spray on an open flame or any other incandescent material. Keep away from open flames, hot surfaces and sources of ignition.


: No data available.


Personal precautions : Use personal protective equipment. Environmental precautions : Prevent product from entering drains. Prevent further leakage

or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.

Methods for cleaning up : Contain spillage, and then collect with non-combustible

absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal.


Handling

Advice on safe handling : Avoid formation of aerosol. Do not breathe vapors/dust. Avoid

contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or



Liquid HE® 150 XPT


MSDS Number:100000014523 4/11

exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations.

Advice on protection against fire and explosion

: Do not spray on an open flame or any other incandescent material. Keep away from open flames, hot surfaces and sources of ignition.

Storage

Requirements for storage areas and containers

: No smoking. Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.


Engineering measures

Adequate ventilation to control airborned concentrations below the exposure guidelines/limits. Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances.


Respiratory protection : Wear a supplied-air NIOSH approved respirator unless

ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-Purifying Respirator for Dusts and Mists / P100. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.

Hand protection : The suitability for a specific workplace should be discussed

with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eye protection : Eye wash bottle with pure water. Tightly fitting safety goggles. Skin and body protection : Choose body protection in relation to its type, to the

concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Protective suit. Safety shoes.

Hygiene measures : When using do not eat or drink. When using do not smoke.



Liquid HE® 150 XPT


MSDS Number:100000014523 5/11

Wash hands before breaks and at the end of workday.



Appearance

Physical state : Liquid Color : Opaque Odor : Slight hydrocarbon Safety data

Flash point : > 77 °C (> 171 °F) Method: ASTM D 93

Lower explosion limit : 0.6 %(V)

Upper explosion limit : 5.1 %(V)

Oxidizing properties : No

Autoignition temperature : 225 °C (437 °F)

Molecular formula : Mixture

Molecular Weight : Not applicable

pH : 7

Boiling point/boiling range : 208 °C (406 °F)

Vapor pressure : < 1.00 MMHG

at 20 °C (68 °F)

Relative density : 0.96

Density : 958.6 g/l

Water solubility : dispersible


: No data available

Viscosity, dynamic : 20,000 cP

Viscosity, kinematic : 71.821 mm2/s at 40 °C (104 °F)

Relative vapor density : 6.2 (Air = 1.0)

Evaporation rate : 0.1




Liquid HE® 150 XPT


MSDS Number:100000014523 6/11

Chemical stability : This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.


Conditions to avoid : Heat, flames and sparks. Other data : No decomposition if stored and applied as directed.


Liquid HE® 150 XPT Skin irritation : May cause skin irritation.

Liquid HE® 150 XPT Eye irritation : May cause eye irritation.

Vapors may cause irritation to the eyes, respiratory system

and the skin. Liquid HE® 150 XPT Aspiration toxicity : May be fatal if swallowed and enters airways. Liquid HE® 150 XPT Further information : Solvents may degrease the skin. Symptoms of overexposure may be headache, dizziness,

tiredness, nausea and vomiting. Concentrations substantially above the TLV value may cause narcotic effects. Solvents may degrease the skin.


Toxicity to fish Distillates (petroleum), Hydrotreated light

: LL0: 1,000 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout)

LL0: 1,000 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout)

Toxicity to daphnia and other aquatic invertebrates Distillates (petroleum), Hydrotreated light

: EL0: 1,000 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)

EL0: 1,000 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea)



Liquid HE® 150 XPT


MSDS Number:100000014523 7/11

Toxicity to algae Distillates (petroleum), Hydrotreated light

: EL50: 1,000 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)

EL50: 1,000 mg/l Exposure time: 72 h Species: Pseudokirchneriella subcapitata (green algae)

Elimination information (persistence and degradability) Biodegradability : No data available

Additional ecological information

: No data available


The information in this MSDS pertains only to the product as shipped.

Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.

Product : Do not dispose of waste into sewer. Do not contaminate

ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product.

Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.

SECTION 14: Transport information

The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition). Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the MSDS and the bill of lading.

US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY. Testing (ASTM D4206) has shown product does not sustain combustion.

IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.



Liquid HE® 150 XPT


MSDS Number:100000014523 8/11

IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))

NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.

ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS)

NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.



National legislation

SARA 311/312 Hazards : Fire Hazard

Acute Health Hazard


: This material does not contain any components with a CERCLA RQ.

SARA 302 Reportable Quantity

: This material does not contain any components with a SARA 302 RQ.

SARA 302 Threshold Planning Quantity

: SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 304 Reportable Quantity

: This material does not contain any components with a section 304 EHS RQ.



Liquid HE® 150 XPT


MSDS Number:100000014523 9/11

SARA 313 Ingredients : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Clean Air Act Ozone-Depletion Potential

: This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).

This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).


Pennsylvania Right To Know : Distillates (petroleum), Hydrotreated light - 64742-47-8 New Jersey Right To Know : Distillates (petroleum), Hydrotreated light - 64742-47-8 California Prop. 65 Ingredients

: This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects.

Notification status Europe REACH : On the inventory, or in compliance with the inventory United States of America US.TSCA : Not On TSCA Inventory Canada DSL : This product contains one or several components that

are not on the Canadian DSL nor NDSL. Australia AICS : Not in compliance with the inventory New Zealand NZIoC : Not in compliance with the inventory Japan ENCS : Not in compliance with the inventory Korea KECI : Not in compliance with the inventory Philippines PICCS : Not in compliance with the inventory China IECSC : Not in compliance with the inventory



Liquid HE® 150 XPT


MSDS Number:100000014523 10/11


NFPA Classification : Health Hazard: 1

Fire Hazard: 1 Reactivity Hazard: 0

Further information

Legacy MSDS Number : CPC00467

Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this MSDS pertains only to the product as shipped.

The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of

Government Industrial Hygienists LD50 Lethal Dose 50%

AICS Australia, Inventory of Chemical Substances

LOAEL Lowest Observed Adverse Effect Level

DSL Canada, Domestic Substances List

NFPA National Fire Protection Agency

NDSL Canada, Non-Domestic Substances List

NIOSH National Institute for Occupational Safety & Health

CNS Central Nervous System NTP National Toxicology Program

CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals

EC50 Effective Concentration NOAEL No Observable Adverse Effect Level

EC50 Effective Concentration 50% NOEC No Observed Effect Concentration

EGEST EOSCA Generic Exposure Scenario Tool

OSHA Occupational Safety & Health Administration

EOSCA European Oilfield Specialty Chemicals Association

PEL Permissible Exposure Limit

EINECS European Inventory of Existing Chemical Substances

PICCS Philippines Inventory of Commercial Chemical Substances

MAK Germany Maximum Concentration Values

PRNT Presumed Not Toxic

GHS Globally Harmonized System RCRA Resource Conservation Recovery Act

>= Greater Than or Equal To STEL Short-term Exposure Limit

IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthorization Act.

IARC International Agency for Research on Cancer

TLV Threshold Limit Value

IECSC Inventory of Existing Chemical TWA Time Weighted Average

0

1

1



Liquid HE® 150 XPT


MSDS Number:100000014523 11/11

Substances in China

ENCS Japan, Inventory of Existing and New Chemical Substances

TSCA Toxic Substance Control Act

KECI Korea, Existing Chemical Inventory

UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological Materials

<= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System

LC50 Lethal Concentration 50%


SAFETY DATA SHEET

1. Identification

Mass Air Flow Sensor CleanerProduct identifier


No. 05110 (Item# 1003729)Product code

Mass air flow sensor cleanerRecommended use

None known.Recommended restrictions

Manufacturer/Importer/Supplier/Distributor information

Manufactured or sold by:

CRC Industries, Inc.Company name

885 Louis Dr.Address

Warminster, PA 18974 US

Telephone

215-674-4300General Information

800-521-3168Technical Assistance

800-272-4620Customer Service

800-424-9300 (US)24-Hour Emergency

703-527-3887 (International)(CHEMTREC)

www.crcindustries.comWebsite

2. Hazard(s) identification

Category 1Flammable aerosolsPhysical hazards

Compressed gasGases under pressure

Category 2Skin corrosion/irritationHealth hazards

Category 2BSerious eye damage/eye irritation

Category 2Reproductive toxicity (fertility)

Category 3 narcotic effectsSpecific target organ toxicity, single exposure

Category 1Aspiration hazard

Category 2Hazardous to the aquatic environment, acutehazard


Category 2Hazardous to the aquatic environment,long-term hazard

Not classified.OSHA defined hazards

Label elements

Signal word Danger

Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal ifswallowed and enters airways. Causes skin irritation. Causes eye irritation. May causedrowsiness or dizziness. Suspected of damaging fertility. Toxic to aquatic life with long lastingeffects.

1 / 12

Material name: Mass Air Flow Sensor Cleaner

No. 05110 (Item# 1003729) Version #: 02 Revision date: 08-07-2017 Issue date: 06-30-2014

SDS US


Precautionary statement

Prevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,even after use. Do not apply while equipment is energized. Extinguish all flames, pilot lights andheaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation;maintain ventilation during use and until all vapors are gone. Open doors and windows or useother means to ensure a fresh air supply during use and while product is drying. If you experienceany symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist orvapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eyeprotection/face protection. Avoid release to the environment.

Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Washwith plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminatedclothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable forbreathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water forseveral minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyeirritation persists: Get medical advice/attention. If exposed or concerned: Get medicaladvice/attention. Collect spillage.

Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose totemperatures exceeding 50°C/122°F. Exposure to high temperature may cause can to burst.

Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.

Hazard(s) not otherwise

classified (HNOC)Static accumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.

3. Composition/information on ingredients

Mixtures

CAS number %Chemical name Common name and synonyms

107-83-52-methylpentane 40 - 50

64742-49-0naphtha (petroleum), hydrotreatedlight

20 - 30

540-84-12,2,4-trimethylpentane 5 - 10

124-38-9carbon dioxide 5 - 10

110-54-3n-hexane 5 - 10

109-66-0n-pentane 1 - 3

75-83-22,2-dimethylbutane < 1

79-29-82,3-dimethylbutane < 1

96-14-03-methylpentane < 1

67-56-1methanol < 1

Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISONCENTER or doctor/physician if you feel unwell.

Inhalation

Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Getmedical advice/attention. Wash contaminated clothing before reuse.

Skin contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

Eye contact

Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.

Ingestion

Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Irritation of eyes. Exposed individuals may experience eye tearing,redness, and discomfort. Skin irritation. May cause redness and pain.

Most important

symptoms/effects, acute and

delayed

Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.

Indication of immediate

medical attention and special

treatment needed

IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance.

General information

2 / 12



SDS US


5. Fire-fighting measures

Water fog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth maybe used for small fires only.


Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing

media

Contents under pressure. Pressurized container may rupture when exposed to heat or flame. Thisproduct is a poor conductor of electricity and can become electrostatically charged. If sufficientcharge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulationmay be significantly increased by the presence of small quantities of water or other contaminants.Material will float and may ignite on surface of water. During fire, gases hazardous to health maybe formed.

Specific hazards arising from

the chemical

Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Special protective equipment

and precautions for firefighters

Fire-fighting

equipment/instructionsIn case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so withoutrisk. Containers should be cooled with water to prevent vapor pressure build up.

Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture whenexposed to heat or flame.

General fire hazards

6. Accidental release measures

Keep unnecessary personnel away. Remove all possible sources of ignition in the surroundingarea. Many gases are heavier than air and will spread along ground and collect in low or confinedareas (sewers, basements, tanks). Wear appropriate protective equipment and clothing duringclean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathingequipment. Do not touch or walk through spilled material. Ventilate closed spaces before enteringthem. Use appropriate containment to avoid environmental contamination. Local authorities shouldbe advised if significant spillages cannot be contained. For personal protection, see section 8 ofthe SDS.

Personal precautions,

protective equipment and

emergency procedures

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keepcombustibles (wood, paper, oil, etc.) away from spilled material. Prevent entry into waterways,sewer, basements or confined areas. Stop the flow of material, if this is without risk. For wastedisposal, see section 13 of the SDS.

Methods and materials for

containment and cleaning up

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground. Use appropriate containment to avoid environmentalcontamination.



Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Minimize fire risks from flammable and combustible materials (includingcombustible dust and static accumulating liquids) or dangerous reactions with incompatiblematerials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray buttonis missing or defective. Do not spray on a naked flame or any other incandescent material. Do notsmoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind,or expose containers to heat, flame, sparks, or other sources of ignition. Use caution aroundenergized equipment. The metal container will conduct electricity if it contacts a live source. Thismay result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist orvapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Pregnant orbreastfeeding women must not handle this product. Should be handled in closed systems, ifpossible. Use only in well-ventilated areas. Wear appropriate personal protective equipment.Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrialhygiene practices. For product usage instructions, see the product label.


Level 3 Aerosol.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,heat or other sources of ignition. This material can accumulate static charge which may causespark and become an ignition source. Avoid spark promoters. Store in a well-ventilated place.Store away from incompatible materials (see Section 10 of the SDS).

Conditions for safe storage,

including any incompatibilities



The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.At this time, the other constituents have no known exposure limits.

3 / 12



SDS US


US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

ValueComponents Type

PEL 2350 mg/m32,2,4-trimethylpentane(CAS 540-84-1)

500 ppm

PEL 9000 mg/m3carbon dioxide (CAS124-38-9)

5000 ppm

PEL 260 mg/m3methanol (CAS 67-56-1)

200 ppm

PEL 400 mg/m3naphtha (petroleum),hydrotreated light (CAS64742-49-0)

100 ppm

PEL 1800 mg/m3n-hexane (CAS 110-54-3)

500 ppm

PEL 2950 mg/m3n-pentane (CAS 109-66-0)

1000 ppm

US. ACGIH Threshold Limit Values


STEL 1000 ppm2,2-dimethylbutane (CAS75-83-2)

TWA 500 ppm

STEL 1000 ppm2,3-dimethylbutane (CAS79-29-8)

TWA 500 ppm

STEL 1000 ppm2-methylpentane (CAS107-83-5)

TWA 500 ppm

STEL 1000 ppm3-methylpentane (CAS96-14-0)

TWA 500 ppm

STEL 30000 ppmcarbon dioxide (CAS124-38-9)

TWA 5000 ppm

STEL 250 ppmmethanol (CAS 67-56-1)

TWA 200 ppm

TWA 50 ppmn-hexane (CAS 110-54-3)

TWA 1000 ppmn-pentane (CAS 109-66-0)

US. NIOSH: Pocket Guide to Chemical Hazards


Ceiling 1800 mg/m32,2,4-trimethylpentane(CAS 540-84-1)

385 ppm

TWA 350 mg/m3

75 ppm

Ceiling 1800 mg/m32,2-dimethylbutane (CAS75-83-2)

510 ppm

TWA 350 mg/m3

100 ppm

Ceiling 1800 mg/m32,3-dimethylbutane (CAS79-29-8)

510 ppm

TWA 350 mg/m3

100 ppm

Ceiling 1800 mg/m32-methylpentane (CAS107-83-5)

510 ppm

TWA 350 mg/m3

100 ppm

4 / 12



SDS US


US. NIOSH: Pocket Guide to Chemical Hazards


Ceiling 1800 mg/m33-methylpentane (CAS96-14-0)

510 ppm

TWA 350 mg/m3

100 ppm

STEL 54000 mg/m3carbon dioxide (CAS124-38-9)

30000 ppm

TWA 9000 mg/m3

5000 ppm

STEL 325 mg/m3methanol (CAS 67-56-1)

250 ppm

TWA 260 mg/m3

200 ppm

TWA 400 mg/m3naphtha (petroleum),hydrotreated light (CAS64742-49-0)

100 ppm

TWA 180 mg/m3n-hexane (CAS 110-54-3)

50 ppm

Ceiling 1800 mg/m3n-pentane (CAS 109-66-0)

610 ppm

TWA 350 mg/m3

120 ppm

Biological limit values

ACGIH Biological Exposure Indices

ValueComponents Determinant Specimen Sampling Time

15 mg/l Methanol Urine *methanol (CAS 67-56-1)

0.4 mg/l 2,5-Hexanedion, withouthydrolysis

Urine *n-hexane (CAS 110-54-3)

* - For sampling details, please see the source document.

Exposure guidelines

US - California OELs: Skin designation

methanol (CAS 67-56-1) Can be absorbed through the skin.

n-hexane (CAS 110-54-3) Can be absorbed through the skin.

US - Minnesota Haz Subs: Skin designation applies

methanol (CAS 67-56-1) Skin designation applies.

US - Tennessee OELs: Skin designation


US ACGIH Threshold Limit Values: Skin designation


n-hexane (CAS 110-54-3) Can be absorbed through the skin.

US NIOSH Pocket Guide to Chemical Hazards: Skin designation


Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station.

Appropriate engineering

controls


Wear safety glasses with side shields (or goggles).Eye/face protection

Skin protection

Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton/butyl.Hand protection

Wear appropriate chemical resistant clothing.Other

5 / 12



SDS US


If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use aNIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-containedbreathing apparatus in confined spaces and for emergencies. Air monitoring is needed todetermine actual employee exposure levels.


Wear appropriate thermal protective clothing, when necessary.Thermal hazards

Observe any medical surveillance requirements. When using do not smoke. Always observe goodpersonal hygiene measures, such as washing after handling the material and before eating,drinking, and/or smoking. Routinely wash work clothing and protective equipment to removecontaminants.

General hygiene

considerations


Appearance

Liquid.Physical state

Aerosol.Form

Colorless.Color

Alcoholic.Odor

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling

range

123 °F (50.6 °C) estimated

Flash point < 0 °F (< -17.8 °C) Tag Closed Cup

Evaporation rate Very fast.

Not available.Flammability (solid, gas)

Upper/lower flammability or explosive limits

Flammability limit - lower

(%)

0.9 % estimated

Flammability limit - upper

(%)

36 % estimated

Vapor pressure 3201.3 hPa estimated

Vapor density > 1 (air = 1)

Relative density 0.7 estimated

Solubility (water) Not available.

Partition coefficient

(n-octanol/water)

Not available.

Auto-ignition temperature 489.2 °F (254 °C) estimated

Decomposition temperature Not available.

Viscosity (kinematic) Not available.

Percent volatile 93.8 % estimated

10. Stability and reactivity

The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity

Material is stable under normal conditions.Chemical stability

No dangerous reaction known under conditions of normal use.Possibility of hazardous

reactions

Heat, flames and sparks. Contact with incompatible materials.Conditions to avoid

Strong oxidizing agents.Incompatible materials

Carbon oxides. Formaldehyde.Hazardous decomposition

products



Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may beharmful.

Skin contact Causes skin irritation.

6 / 12



SDS US


Eye contact Causes eye irritation.

Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.

Symptoms related to the

physical, chemical and

toxicological characteristics

Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Irritation of eyes. Exposed individuals may experience eye tearing,redness, and discomfort. Skin irritation. May cause redness and pain.


Acute toxicity May be fatal if swallowed and enters airways.

Test ResultsComponents Species

2,2,4-trimethylpentane (CAS 540-84-1)

Inhalation

Acute

LC50 Rat 118 mg/l, 4 Hours

naphtha (petroleum), hydrotreated light (CAS 64742-49-0)

Dermal

Acute

LD50 Rabbit > 2000 mg/kg

n-hexane (CAS 110-54-3)

Dermal

Acute

LD50 Rabbit > 1300 mg/kg

Oral

LD50 Rat 15840 mg/kg

n-pentane (CAS 109-66-0)

Inhalation

Acute

LC50 Rat 364 mg/m3, 4 Hours

Vapor

Oral

* Estimates for product may be based on additional component data not shown.

LD50 Rat > 2000 mg/kg

Causes skin irritation.Skin corrosion/irritation

Causes eye irritation.Serious eye damage/eye

irritation

Respiratory sensitization Not a respiratory sensitizer.

This product is not expected to cause skin sensitization.Skin sensitization

No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.


Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of Carcinogenicity

Not listed.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not regulated.

US. National Toxicology Program (NTP) Report on Carcinogens

Not listed.

Suspected of damaging fertility.Reproductive toxicity

Specific target organ toxicity -

single exposure

May cause drowsiness and dizziness.

Specific target organ toxicity -

repeated exposure

Not classified.

Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting,may cause chemical pneumonia, pulmonary injury or death.

7 / 12



SDS US


Chronic effects Prolonged inhalation may be harmful.


Toxic to aquatic life with long lasting effects.Ecotoxicity

Components Test ResultsSpecies

2-methylpentane (CAS 107-83-5)

Aquatic

Acute

EC50Crustacea 1 - 10 mg/l, 48 hoursDaphnia

LC50Fish 1 - 10 mg/l, 96 hoursFish

methanol (CAS 67-56-1)

Aquatic

LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)

Acute

EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna)

LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)


Aquatic

Acute

EC50Crustacea 1 - 10 mg/l, 48 hoursDaphnia

LC50Fish 1 - 10 mg/l, 96 hoursFish

* Estimates for product may be based on additional component data not shown.


Aquatic

LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas)

No data is available on the degradability of this product. Persistence and degradability


Partition coefficient n-octanol / water (log Kow)

2,2,4-trimethylpentane 5.18

2,2-dimethylbutane 3.82

2,3-dimethylbutane 3.42

2-methylpentane 3.74

3-methylpentane 3.6

methanol -0.77

n-hexane 3.9

n-pentane 3.39

Bioconcentration factor (BCF)

naphtha (petroleum), hydrotreated light 10 - 25000

No data available.Mobility in soil

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim ordispose in sealed containers at licensed waste disposal site. Do not allow this material to drain intosewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or usedcontainer. Contents under pressure. Do not puncture, incinerate or crush. Dispose in accordancewith all applicable regulations.

Disposal of waste from

residues / unused products

D001: Waste Flammable material with a flash point <140 FHazardous waste code

Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal.

Contaminated packaging

8 / 12



SDS US



DOT

UN1950UN number

Aerosols, flammable, Limited QuantityUN proper shipping name

2.1Class


-Subsidiary risk

2.1Label(s)

Not applicable.Packing group

Read safety instructions, SDS and emergency procedures before handling.Special precautions for user

N82Special provisions

306Packaging exceptions

NonePackaging non bulk

NonePackaging bulk

IATA

UN1950UN number

Aerosols, flammable, Limited QuantityUN proper shipping name

2.1Class


-Subsidiary risk


10LERG Code


Allowed with restrictions.Passenger and cargo

aircraft

Other information

Allowed with restrictions.Cargo aircraft only

IMDG

UN1950UN number

AEROSOLS, Limited QuantityUN proper shipping name

2.1Class


-Subsidiary risk


No.Marine pollutant


Not available.EmS


15. Regulatory information

All components are on the U.S. EPA TSCA Inventory List.This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.

US federal regulations

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

SARA 304 Emergency release notification

Not regulated.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not regulated.

US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance


CERCLA Hazardous Substance List (40 CFR 302.4)

2,2,4-trimethylpentane (CAS 540-84-1) Listed.

methanol (CAS 67-56-1) Listed.

n-hexane (CAS 110-54-3) Listed.

n-pentane (CAS 109-66-0) Listed.

CERCLA Hazardous Substances: Reportable quantity

2,2,4-trimethylpentane (CAS 540-84-1) 1000 LBS

methanol (CAS 67-56-1) 5000 LBS

9 / 12



SDS US


n-hexane (CAS 110-54-3) 5000 LBS

n-pentane (CAS 109-66-0) 100 LBS

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the NationalResponse Center (800-424-8802) and to your Local Emergency Planning Committee.

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List



Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)


Not regulated.Safe Drinking Water Act

(SDWA)

Not regulated.Food and Drug

Administration (FDA)

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - YesReactivity Hazard - No

Section 311/312

Hazard categories

NoSARA 302 Extremely

hazardous substance

US state regulations

US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.

(a))






US. New Jersey Worker and Community Right-to-Know Act


2,2-dimethylbutane (CAS 75-83-2)



carbon dioxide (CAS 124-38-9)





US. Massachusetts RTK - Substance List











US. Pennsylvania Worker and Community Right-to-Know Law











10 / 12



SDS US


US. Rhode Island RTK







US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductiveharm.

US - California Proposition 65 - CRT: Listed date/Developmental toxin

methanol (CAS 67-56-1) Listed: March 16, 2012

Volatile organic compounds (VOC) regulations

EPA

VOC content (40 CFR

51.100(s))

95 %

Not regulatedConsumer products

(40 CFR 59, Subpt. C)

State

Not regulatedConsumer products

VOC content (CA) 95 %

VOC content (OTC) 95 %

International Inventories

Country(s) or region Inventory name On inventory (yes/no)*

YesAustralia Australian Inventory of Chemical Substances (AICS)

YesCanada Domestic Substances List (DSL)

NoCanada Non-Domestic Substances List (NDSL)

YesChina Inventory of Existing Chemical Substances in China (IECSC)

YesEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS)

NoEurope European List of Notified Chemical Substances (ELINCS)

NoJapan Inventory of Existing and New Chemical Substances (ENCS)

YesKorea Existing Chemicals List (ECL)

YesNew Zealand New Zealand Inventory

YesPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS)

YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).

16. Other information, including date of preparation or last revision

06-30-2014Issue date

08-07-2017Revision date

Allison YoonPrepared by

Version # 02

CRC # 599C/1002635Further information

Health: 2*Flammability: 4Physical hazard: 0Personal protection: B

HMIS® ratings

Health: 2Flammability: 4Instability: 0

NFPA ratings

11 / 12



SDS US


NFPA ratings

02

4

The information contained in this document applies to this specific material as supplied. It may notbe valid for this material if it is used in combination with any other materials. This information isaccurate to the best of CRC's knowledge or obtained from sources believed by CRC to beaccurate. Before using any product, read all warnings and directions on the label. For furtherclarification of any information contained on this (M)SDS consult your supervisor, a health & safetyprofessional, or CRC Industries, Inc..

Disclaimer

This document has undergone significant changes and should be reviewed in its entirety.Revision Information

12 / 12



SDS US


SAFETY DATA SHEET

Revision Date 03-Apr-2017Version 2.01

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name Microban Milgo PlusProduct code W.20403

1.2 Relevant identified uses of the substance or mixture and uses advised against

Recommended Use Disinfectant CleanerRestrictions on use Professional Use OnlyEPA Registration Number 70385-6

Other information This SDS is reviewed as an US EPA registered product.

1.3 Details of the supplier of the safety data sheet

Supplier Legend BrandsProRestore Products15180 Josh Wilson RoadBurlington, WA 98233800-932-3030

1.4 Emergency telephone number

Emergency telephone number INFOTRAC 1-800-535-5053 (North America)1-352-323-3500 (International)

2. Hazards identification

2.1 Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910.1200

OSHA Regulatory StatusThis product is regulated by EPA- not subject to 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).

Skin corrosion/irritation Category 1Serious eye damage/eye irritation Category 1

2.2 Label elements

Signal WordDanger

Hazard StatementsCauses severe skin burns and eye damage

_____________________________________________________________________________________________03-Apr-2017 - W.20403 - 2.01 - AGHS - English - Page 1 / 10


_____________________________________________________________________________________________W.20403 - Microban Milgo Plus Revision Date 03-Apr-2017

Precautionary Statements - PreventionDo not breathe dusts or mistsWash face, hands and any exposed skin thoroughly after handlingWear protective gloves/protective clothing/eye protection/face protection

Precautionary Statements - ResponseImmediately call a POISON CENTER or doctorIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsingImmediately call a POISON CENTER or doctorIF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ showerWash contaminated clothing before reuseIF INHALED: Remove person to fresh air and keep comfortable for breathingImmediately call a POISON CENTER or doctorIF SWALLOWED: Rinse mouth. Do NOT induce vomiting

Precautionary Statements - StorageStore locked up

Precautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant

2.3. Other Hazards Hazards not otherwise classified (HNOC) Not Applicable

2.4 Other information

Not Applicable

Unknown Acute Toxicity 3.30002499% of the mixture consists of ingredient(s) of unknown toxicity

3. Composition/Information on Ingredients

Substance Mixture

Chemical Name CAS No. Weight-%Ammonium chloride compound 68424-85-1 1 - 5

TETRASODIUM EDTA 64-02-8 1 - 5Ethanol 64-17-5 1 - 5

The exact percentage (concentration) of composition has been withheld as a trade secret.

4. First aid measures

4.1 Description of first-aid measures

General advice No information available.

Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Skin contact Wash skin with soap and water.

Inhalation Remove to fresh air.




Ingestion Clean mouth with water and drink afterwards plenty of water.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms See Section 2.2, Label Elements and/or Section 11, Toxicological effects.

4.3 Indication of any immediate medical attention and special treatment needed

Notes to physician Treat symptomatically.

5. Fire-Fighting Measures

5.1 Extinguishing media

Suitable extinguishing mediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable Extinguishing Media None.

5.2 Special hazards arising from the substance or mixture

Special HazardImmediately place absorbent material in a sealed water-filled metal container to avoid spontaneous combustion of absorbentmaterial contaminated with this product.

Hazardous Combustion Products No information available.

Explosion DataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.

5.3 Advice for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.


6.1 Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation, especially in confined areas.

6.2 Environmental precautions

See Section 12 for additional Ecological information.

6.3 Methods and materials for containment and cleaning up


Methods for cleaning up Pick up and transfer to properly labeled containers.


7.1 Precautions for safe handling

Hygiene measures Handle in accordance with good industrial hygiene and safety practice.

7.2 Conditions for safe storage, including any incompatibilities

Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.




Materials to Avoid No materials to be especially mentioned.


8.1 Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL British Columbia Alberta Quebec Ontario TWAEVEthanol 64-17-5

STEL: 1000 ppm TWA: 1000 ppmTWA: 1900 mg/m3

STEL: 1000 ppm TWA: 1000 ppmTWA: 1880 mg/m3


STEL: 1000 ppm

8.2 Appropriate engineering controls

Engineering Measures ShowersEyewash stationsVentilation systems.

8.3 Individual protection measures, such as personal protective equipment

Eye/Face Protection Safety glasses with side-shields.

Skin and body protection Wear chemical resistant footwear and clothing such as gloves, an apron or a whole bodysuit as appropriate.

Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment.

Hygiene measures See section 7 for more information




10. Stability and Reactivity

10.1 Reactivity

No data available

10.2 Chemical stability

Stable under recommended storage conditions

10.3 Possibility of hazardous reactions

None under normal processing.

10.4 Conditions to Avoid

Extremes of temperature and direct sunlight.

10.5 Incompatible Materials


10.6 Hazardous Decomposition Products



9.1 Information on basic physical and chemical properties Physical state Liquid

9.2 Other information Volatile organic compounds (VOC)content

0.06 lb/gal

Appearance Clear liquid Color Colorless

Odor Slight Odor Threshold No information available

Property Values Remarks • Methods pH 11.5 - 12.5Melting/freezing point No information availableBoiling point/boiling range No information availableFlash Point Not ApplicableEvaporation rate No information availableFlammability (solid, gas) No information availableFlammability Limits in Air

upper flammability limit No information availablelower flammability limit No information available

Vapor pressure No information availableVapor density No information availableSpecific Gravity 1.01Water solubility Soluble in waterSolubility in other solvents No information availablePartition coefficient No information availableAutoignition temperature No information availableDecomposition temperature No information availableViscosity, kinematic No information availableViscosity, dynamic No information available

Explosive properties No information availableOxidizing Properties No information available





11.1 Acute toxicity

Numerical measures of toxicity: Product Information


Unknown Acute Toxicity 3.30002499% of the mixture consists of ingredient(s) of unknown toxicity

Oral LD50 11,311.00 mg/kgDermal LD50 13,009.00 mg/kgLC50 (Dust/Mist) 78.10 mg/lLC50 (Vapor) 545.00 mg/l

Numerical measures of toxicity: Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationAmmonium chloride compound

68424-85-1344 mg/kg ( Rat ) 340 mg/kg ( Rabbit ) -

TETRASODIUM EDTA 64-02-8

1658 mg/kg ( Rat ) - -

Ethanol 64-17-5

- - = 124.7 mg/L ( Rat ) 4 h

11.2 Information on toxicological effects

Skin corrosion/irritationProduct Information • No information availableComponent Information• No information available

Serious eye damage/eye irritationProduct Information • Causes serious eye damageComponent Information• No information available

Respiratory or skin sensitizationProduct Information • No information availableComponent Information• No information available

Germ cell mutagenicityProduct Information • No information availableComponent Information• No information available

CarcinogenicityProduct Information • No information availableComponent Information• No information available





Product Information • No information availableComponent Information• No information available

STOT - single exposureNo information available

STOT - repeated exposureNo information available

Other adverse effectsProduct Information • No information availableComponent Information• No information available

Aspiration hazardProduct Information • No information availableComponent Information• No information available


12.1 Toxicity

Ecotoxicity No information available

8.075 % of the mixture consists of components(s) of unknown hazards to the aquatic environment

Ecotoxicity effectsChemical Name Toxicity to algae Toxicity to fish Toxicity to daphnia and other

aquatic invertebratesTETRASODIUM EDTA

64-02-8EC50: 72 h Desmodesmus

subspicatus 1.01 mg/LLC50: 96 h Lepomis macrochirus 41mg/L static LC50: 96 h Pimephales

promelas 59.8 mg/L static

-

Ethanol 64-17-5

- LC50: 96 h Oncorhynchus mykiss12.0 - 16.0 mL/L static LC50: 96 hPimephales promelas 100 mg/Lstatic LC50: 96 h Pimephalespromelas 13400 - 15100 mg/L

flow-through

LC50: 48 h Daphnia magna 9268 -14221 mg/L EC50: 48 h Daphnia

magna 2 mg/L Static

12.2 Persistence and degradability


12.3 Bioaccumulative potential

Discharge into the environment must be avoidedChemical Name log Pow

Ethanol 64-17-5

-0.32

12.4 Mobility in soil


12.5 Other adverse effects


Do not discharge effuent containing this product into lakes, streams, ponds, estuaries, oceans or other water unless in accordancewith the requirments of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been



notified in writing prior to the discharge. Do not discharge effuent containing this product to sewer systems withour previouslynotifying the local sewage treatment plant authority. For guidance, conatct your State water board or Regional office of the EPA.

13. Disposal Considerations

13.1 Waste treatment methods

Disposal of wastes: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is aviolation of Federal Law. If these wastes can not be disposed of by use according to label instructions, contact your State Pesticideor Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance.70385-6 (containers equal to or less than 5 gallons) Container Disposal: Non-refillable container. Do Not reuse or refill thiscontainer. Triple rinse container (or equivalent) promptly after emptying. Triple rinse as follows: empty the remaining contents intoapplication equipment or a mix tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full with water andrecap. Shake for 10 seconds. Pour rinsate into application equipment or mix tank or store rinsate for later use or disposal. Drain for10 seconds after the flow begins to drip. Repeat this procedure two more times. Then offer for recycling if available or puncture anddispose of in sanitary landfill, or by incineration, or, if allowed by state and local authorites, by burning. If burned, stay out of smoke.70385-6 for container over 5 gallons Container Disposal: Non-refillable container. Do Not reuse or refill this container. Triple rinseas follows: Empty the remaining contents into application equipment or a mix tank. Fill the container 1/4 full with water. Replaceand tighten closures. Tip container on its side and roll it back and forth, ensuring at least one complete revolution, for 30 seconds.Stand the container on its end and tip it back and forth several times. Turn the container over onto its other end and tip it back andforth several times. Empty the rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Repeat thisprocedure two more times. Then offer for recycling if avaiable or puncture and dispose of in a sanitary landfill, or by incineration, or,if allowed by state and local, by burning. If burned, stay out of smoke.Contaminated packaging: Do not reuse container.

14. Transport Information

DOT Not regulated

MEX Not regulated

IMDG Not regulated

IATA Not regulated

15. Regulatory information15.1 International Inventories

TSCA CompliesDSL CompliesEINECS/ELINCS CompliesENCS -IECSC CompliesKECL CompliesPICCS CompliesAICS CompliesNZIoC -

TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL - Canadian Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals


15.2 U.S. Federal Regulations



SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

15.3 Pesticide Information

U.S. EPA Pesticide Information

15.4 U.S. State Regulations

California Proposition 65This product contains the following Proposition 65 chemicals:

Chemical Name California Prop. 65Ethanol - 64-17-5 Carcinogen

DevelopmentalMETHANOL - 67-56-1 Developmental


Legend: ACGIH (American Conference of Governmental Industrial Hygienists)Ceiling (C)DOT (Department of Transportation)EPA (Environmental Protection Agency)IARC (International Agency for Research on Cancer)International Air Transport Association (IATA)International Maritime Dangerous Goods (IMDG)NIOSH (National Institute for Occupational Safety and Health)NTP (National Toxicology Program)OSHA (Occupational Safety and Health Administration of the US Department of Labor)PEL (Permissible Exposure Limit)Reportable Quantity (RQ)Skin designation (S*)STEL (Short Term Exposure Limit)TLV® (Threshold Limit Value)TWA (time-weighted average)

Revision Date 03-Apr-2017Revision NoteNo information availableDisclaimerThe information provided on this SDS is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guide for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered as a warranty or quality specification. The information

EPA Pesticide Registration Number 70385-6EPA StatementThis chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labelingrequirements under federal pesticide law. These requirements differ from the classification criteria and hazard information requiredfor safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on thepesticide label:

EPA Pesticide LabelDANGER Corrosive. Causes irreversible eye damage and skin burns. Harmful if swallowed or absorbed through the skin. Donot get in eyes, on skin, or on clothing. Wear goggles or face shield, protective clothing and rubber gloves when handling.Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash before reuse.

NFPA Health Hazard 3 Flammability 0 Instability 0 Physical and chemicalhazards -

HMIS Health Hazard 3 Flammability 0 Physical Hazard 0 Personal protection X




relates only to the specific material designated and may not be valid for such material used in combination with any othermaterial or in any process, unless specified in the text.




Safety Data Sheet

Northex Anti Freeze

Cadillac Oil Co - Detroit, MI Date Prepared or Revised: October 9, 2014 Page 1 of 3

SECTION 1: PRODUCT AND COMPANY INFORMATION

Manufacturer Cadillac Oil Company, 13650 Helen, Detroit, Michigan 48212 · (313) 365-6200 Product Family Anti-Freeze Trade Name(s) Northex Anti-Freeze Recommended Uses Freeze prevention

24-Hour Emergency Phone Number, Chem-Tel: (800) 255-3924

SECTION 2: HAZARD IDENTIFICATION

EMERGENCY OVERVIEW

HMIS

HEALTH *2

Physical Hazards Not Classified FLAMMABILTY 1

PHYSICAL HAZARD 0

Health Hazards See Below PERSONAL PROTECTION See Section 8

Signal Word WARNING

Acute Toxicity Oral Category 4 – Harmful if swallowed Precautionary Statements Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/ physician. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS Number Percentage Ethylene glycol 107-21-1 >90


Skin Contact Remove contaminated clothing. Wash area of contact with soap and water. Wash clothing before reuse. Get medical attention if

irritation occurs and persists. Eye Contact Remove contact lenses. Flush with water until all traces of material are gone. Eyelids should be held away from the eyeball to

ensure thorough rinsing. Get medical attention if irritation persists. Inhalation Remove affected person from source of exposure. Get medical attention if discomfort persists. Give artificial respiration if not

breathing. Ingestion Do not induce vomiting because of danger of aspiration into lungs. If spontaneous vomiting occurs, monitor for breathing

difficulty. Get medical attention.

SECTION 5: FIREFIGHTING MEASURES

Basic Firefighting Procedures

Use water spray, dry chemical, foam or CO2 to extinguish fire. Use a water spray to cool fire-exposed containers, structures and to protect personnel. Exposed firefighters should wear MSHA/NIOSH approved self-contained breathing apparatus with full-face mask and full protective equipment. Flush spills away from sources of ignition.

Unusual Fire and Explosion Hazards Combustible at high temperatures. Irritating or toxic substances may be emitted.


Safety Data Sheet

Northex Anti Freeze



Refer to Section 8: Exposure Control and Personal Protection Emergency Action

Isolate release area and keep unnecessary people away. Exercise caution regarding personnel safety and exposure. Spill/Leak Procedure

Floor and surfaces may be slippery. Dike with sand or other noncombustible material. Flush area with water provided runoff does not enter drain or sewer; use absorbent material and dispose of properly.


Refer to Section 8: Exposure Control and Personal Protection Handling Avoid contact with skin, eyes and clothing. Avoid breathing vapors or mists. Do not ingest. For industrial use only. Use good

hygiene practices when handling product, including changing and laundering work clothes after use. Ground equipment as required. The shipping and storage container is not designed to be pressurized. Do not use pressure to empty the container as it may rupture with explosive force. Containers should be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly. Empty containers may contain residue or vapors. Do not cut, grind, drill, weld or reuse containers.

Storage Store product in closed containers in a well-ventilated area away from heat, sources of ignition and incompatibles. Do not store in unlabeled containers.

SECTION 8: EXPOSURE CONTROL AND PERSONAL PROTECTION

Component ACGIH TLV OSHA Ethylene glycol 100 ppm 50 ppm / 125 mg/m

3

Engineering Controls

Use appropriate ventilation to maintain airborne concentration limits below recommended exposure limits. Eye and Face Protection

Wear safety glasses; use face shield if splashing is possible. Skin Protection

Oil or chemical resistant gloves (e.g. nitrile rubber) should be used to avoid prolonged contact. Respiratory Protection

Not normally needed. A NIOSH or MSHA approved respirator should be used in areas with high vapor concentrations or misting.


Appearance/Physical State Fluorescent liquid Flash Point (°F/°C) 254 °F

Specific Gravity (Water=1) See data sheet Upper/Lower Flammability Limits (Vol. %) Not Determined

pH 7.5 – 11.0 Auto-ignition Temperature (°F/°C) Not Determined

Solubility in Water Complete Decomposition Temperature (°F/°C) Not Determined

Odor Characteristic Vapor Pressure (kPa at 20°C / 68°F) Not Determined

Odor Threshold Not Determined Vapor Density (Air-=1) >1

Melting/Freezing Point (°F/°C) Not Determined Partition Coefficient (n-octanol/water) Not Determined

Boiling Range (°F/°C) Not Determined Viscosity (40°C mm2/s) or (cSt at 40°C) Not Determined

Initial Boiling Point (°F/°C) Not Determined Critical Temperature Not Determined

Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Those should be requested separately.


Safety Data Sheet

Northex Anti Freeze



Reactivity Does not react under normal conditions of use. Chemical Stability Stable under normal conditions of use. Stability/Incompatibility Avoid contact with strong oxidizers. Conditions to Avoid Open flame or sources of ignition. Hazardous Reactions/Decomposition Products

Does not decompose under normal conditions; combustion may produce CO, CO2, volatile hydrocarbons and other possibly toxic gases.


Likely Routes of Exposure Skin, eyes Acute Effects LD50 oral (rat) 4,700 mg/kg; LD50 dermal (rabbit) 10,626 mg/kg. Excessive contact, inhalation or

ingestion may cause irritation or discomfort. Refer to Sections 2 and 4 for recommended actions. Medical conditions aggravated by long term exposure Eye, skin and respiratory disorders. Chronic Effects Any acute symptoms may be aggravated. Refer to Sections 2 and 4 for recommended actions. Symptoms Not Available. Carcinogenicity Ethylene glycol has not been found to be a carcinogen by NTP, IARC or OSHA.


Ecotoxicity Toxicity levels for various aquatic organisms have been found to be high. Persistence and Biodegradability Not Determined Bioaccumulative Potential Does not bioaccumulate Mobility in Soil Not Determined

SECTION 13: DISPOSAL CONSIDERATION

Dispose of this product in compliance with all applicable federal, state and local regulations.


DOT Environmentally hazardous substance, liquid, N.O.S. (Ethylene glycol); UN3082, Cl 9, PG III


Chemical Inventory Lists All ingredients are listed on TSCA and DSL SARA (311/312) Reportable Hazard Categories Acute health hazard, chronic health hazard SARA Section 313 Ethylene glycol (CAS 107-21-1) – 95%


Notice The information presented herein is based on data considered to be accurate as of the date of preparation of this Safety Data

Sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information, nor is any authorization given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by the vendor for any damage or injury resulting from abnormal use, from failure to adhere to recommended practices, or from any hazards inherent in the nature of the product. This SDS complies with the requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200

Prepared By Cadillac Oil Co. Laboratory


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Section 01 - Identification

Product Identifier On and Gone – Mould and Mildew Stain Remover.

Product Use and Restrictions on Use

Removal of mold stains.

24-Hour Emergency Phone Phone: 1 (306) 664 – 2522 Alternative Phone: 1 (800) 387-7503

Section 02 - Hazard Identification

GHS-Classification

Skin Corrosion/Irritation Category 1A

Serious Eye Damage/Eye Irritation Category 1

Acute Aquatic Toxicity Category 1

Chronic Aquatic Toxicity Category 1

STOT-Single Exposure Category 3

Signal Word Danger

Hazard Statements Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation. Very toxic to aquatic life with long lasting effects.


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Physical Hazards

Corrosive To Metals Category 1

Signal Word Warning

Hazard Statement May be corrosive to metals.

Pictograms

Precautionary Statements Store locked up. Keep only in original container. Store container tightly closed in well-ventilated place. Store in corrosive resistant/container with a resistant inliner. Use only outdoors or in well-ventilated area. Absorb spillage to prevent material damage. Wear protective gloves/clothing and eye/face protection. Wash thoroughly after handling. Do not breathe dust or mist. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. W ash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Avoid release to the environment. Collect spillage.

Section 03 - Composition / Information on Ingredients

Chemical Name

CAS Number

Weight %

Unique Identifiers

Sodium Hypochlorite 6% 7681-52-9 95% None Surfactant Solution Mixture 5% None

Common Name and Synonyms

None


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Section 05 - Fire Fighting Measures

Section 04 - First Aid Measures

Inhalation Can release corrosive chlorine gas Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary edema can be delayed up to 48 hours after exposure. Seek immediate medical attention.

Rem brea pers

Skin Contact / Absorption

As quickly as possible, flush with lukewarm, gently flowing water for at least 20 minutes, or until the chemical is removed. If irritation persists, repeat flushing. Under running water, remove contaminated clothing, shoes and leather goods. Completely decontaminate clothing, shoes and leather goods before reuse, or discard. Obtain medical advice immediately.

Rem med

Eye Contact

Contact lenses should never be worn when working with this product. Flush immediately with lukewarm, gently flowing water for at least 20-30 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. DO NOT INTERRUPT FLUSHING. Take care not to rinse contaminated water into the unaffected eye or onto the face. Seek immediate medical attention.

Cont imm com

Ingestion

NEVER give anything by mouth if victim is rapidly losing consciousness, is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 240 to 300 mL (8 to 10 oz.) of water to dilute material in stomach. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Rinse mouth and repeat administration of water. Quickly transport victim to an emergency care facility.

Additional Information Provide general supportive measures (comfort, warmth, rest). Consult a doctor and/or the nearest Poison Control Centre for all exposures except minor instances of inhalation or skin contact.

Suitable Extinguishing Media Sodium hypochlorite solutions do not burn. Extinguish fire using extinguishing agents suitable for the surrounding fire and not contraindicated for use with sodium hypochlorite. Cool exposed containers with water.

Unsuitable Extinguishing Media DO NOT use dry chemical fire extinguishing agents containing ammonium compounds (such as some A:B:C agents), since an explosive compound can be formed.

Specific Hazards Arising From the Chemical

Chlorine, hydrogen chloride gas, oxygen gas and disodium oxide. NOTE: releases chlorine when heated above 35°C.

Special Protective Equipment and Precautions for Fire-Fighters

Wear NIOSH-approved self-contained breathing apparatus and protective clothing. The decomposition products of sodium hypochlorite, such as chlorine and hydrogen chloride are extremely hazardous to health. Do not enter without wearing specialized protective equipment suitable for the situation. Firefighter's normal protective equipment (Bunker Gear) will not provide adequate protection.


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Further Information Sodium hypochlorite solutions will not accumulate static charge. Since these

solutions do not burn, they will not be ignited by a static discharge. Sodium hypochlorite is not combustible (will not burn). It decomposes when heated, giving off corrosive chlorine gas and hydrogen chloride. Solutions decompose when exposed to sunlight, giving off oxygen gas. However, the amount of oxygen produced is not sufficient to cause combustion. Explosive decomposition may occur under fire conditions and closed containers may rupture violently due to rapid decomposition, if exposed to fire or excessive heat for a sufficient period of time.

Section 06 - Accidental Release Measures

Personal Precautions / Protective Equipment / Emergency Procedures

Wear appropriate personal protective equipment. Ventilate area. Only enter area with PPE. Stop or reduce leak if safe to do so. Prevent material from entering sewers. Flush with water to remove any residue.

Environmental Precautions Harmful to aquatic life in very low concentrations. May be dangerous if it enters water intakes. Prevent material from entering sewers or confined spaces. Notify local health and wildlife officials. Notify operators of nearby water intakes.

Methods and Materials for Containment and Cleaning Up

Do not touch spilled material. Prevent material from entering into soil, ditches, sewers, waterways and/or groundwater.

Contain spill with earth, sand or absorbent material which does not react with spilled material.

SMALL SPILLS: Soak up spill with absorbent material which does not react with spilled chemical [sawdust, Cob grit, Zorb-all®. Hazorb®. Put material in suitable, covered, labelled containers. Flush area with water [AFTER material has been cleaned up with an absorbent material]. Contaminated absorbent material may pose the same hazards as the spilled product. Collect in suitable and properly labeled containers.

LARGE SPILLS: Contact fire and emergency services and supplier for advice.

Section 07 - Handling and Storage Precautions for Safe Handling This material is a CORROSIVE liquid. This material is a slipping hazard.

Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Avoid generating mists. Prevent the release of mists into the workplace air. Inspect containers for damage or leaks before handling. Label containers. Never add water to a corrosive. Always add corrosives to water. When mixing with water, stir small amounts in slowly. Use cold water to prevent excessive heat generation. Never return contaminated material to its original container. Have suitable emergency equipment for fires, spills and leaks readily available.


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Conditions for Safe Storage Store in a cool, dry, well-ventilated area, out of direct sunlight and away from heat

sources. Strong solutions (greater than 10% available chlorine) may slowly give off chlorine during storage, especially when warm (above 18°C). Vent caps may be required to prevent a build-up of pressure that could cause containers to burst. Always store in original labelled container. Keep containers tightly closed when not in use and when empty. Empty containers may contain hazardous residues. Protect label and keep it visible. Keep away from incompatible materials, such as acids, metals, primary or aromatic amines, ammonia and ammonia salts. – see section 10 for more information.

Section 08 - Exposure Controls / Personal Protection

Exposure Limit(s)

Component Regulation Type of Listing Value

Sodium hypochlorite AIHA WEEL-STEL 2mg/m3 (15 min)

Chlorine ACGIH TLV-TWA 0.5 ppm

Engineering Control(s)

Ventilation Requirements Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and control of process conditions must be provided in accordance with all fire codes and regulatory requirements. Supply sufficient replacement air to make up for air removed

by exhaust systems.

Other

Emergency shower and eyewash must be available and tested in accordance with regulations and be in close proximity.

Protective Equipment

Eyes/Face Chemical goggles, full-face shield, or a full-face respirator is to be worn at all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury.

Hand Protection

Impervious gloves of chemically resistant material (rubber or PVC) should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse.


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Skin and Body Protection Body suite, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse.

Guidelines for sodium hypochlorite, less than 30%: RECOMMENDED (resistance to breakthrough longer than 8 hours): Butyl rubber, Natural rubber, Neoprene rubber, Nitrile rubber, Polyethylene, Polyvinyl chloride, Viton(TM), Silver Shield/4H(TM) (polyethylene/ethylene vinyl alcohol), Tychem(TM) SL (Saranex(TM)).

There is evidence that this material can cause serious skin injury (e.g. corrosion or absorption hazard). Recommendations are NOT valid for very thin natural rubber, neoprene, nitrile and PVC gloves (0.3 mm or less). Resistance of specific materials can vary from product to product. Breakthrough times are obtained under conditions of continuous contact, generally at room temperature. Evaluate resistance under conditions of use and maintain clothing carefully.

Impervious boots of chemically resistant material should be worn at all times. No special footwear is required other than what is mandated at place of work.

Respiratory Protection No specific guidelines are available. Contact chemical manufacturer/supplier for advice. Respiratory protection guidelines for chlorine gas are available.

NIOSH RECOMMENDATIONS FOR CHLORINE CONCENTRATIONS IN AIR: Up to 5 ppm: (APF = 10) Chemical cartridge respirator*; SAR*.

Up to 10 ppm: (APF = 25) SAR operated in a continuous-flow mode;* Powered, air-purifying respirator with cartridge(s)*. (APF = 50) Chemical cartridge respirator with a full facepiece and cartridge(s); Air- purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back- mounted canister; SCBA with a full facepiece; Full facepiece SAR.

The respirator use limitations specified by the approving agency and the manufacturer must be observed. Recommendations apply only to NIOSH approved respirators. Air-purifying respirators do not protect against oxygen-deficient atmospheres.

A NIOSH-approved respirator suitable for chlorine is recommended. Where a higher level of protection is required, use a self-contained breathing apparatus.

Thermal Hazards Not Available

Section 09 - Physical and Chemical Properties

Appearance

Physical State Liquid


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Colour Clear, greenish-yellow solution.

Odour Strong chlorine odour.

Odour Threshold Not Available

Property

pH 12.6

Melting Point/Freezing Point Not Available

Initial Boiling Point and Boiling Range Slowly decomposes above 40°C

Flash Point Not Applicable

Evaporation Rate Not Available

Flammability Non-Flammable

Upper Flammable Limit Not Applicable

Lower Flammable Limit Not Applicable

Vapour Pressure (mm Hg, 20oC) Not Available

Vapour Density (Air=1) Not Available

Relative Density Not Available

Solubility(ies) Not Available

Partition Coefficient: n-octanol/water Not Available

Auto-ignition Temperature Not Available

Decomposition Temperature Slowly decomposes above 40°C

Viscosity Not Available

Explosive Properties Pressure buildup in containers could result in an explosion when heated or in contact with acidic fumes. Vigorous reaction with oxidizable organic materials may result in a fire.

Specific Gravity (Water=1) 1.09

% Volatiles by Volume Not Available

Formula Not Available

Molecular Weight Not Available

Section 10 - Stability and Reactivity

Reactivity Sodium hypochlorite solutions decompose slowly at normal temperatures releasing low concentrations of corrosive chlorine gas. Decomposition is influenced by temperature, concentration, pH, ionic strength, exposure to light and the presence of metals, such as copper, nickel or cobalt, metal oxides, e.g. rust and other impurities, such as acids and amines. Hypochlorites react with urea to form nitrogen trichloride which explodes spontaneously in air.


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Chemical Stability Unstable at temperatures above 40°C, in sunlight, and in contact with acid.

Possibility of Hazardous Reactions Hazardous polymerization will not occur. Reacts exothermically with acids. Reacts with ammonia, amines and ammonia salts to produce chloramines. Decomposes on heating to produce chlorine gas.

Conditions to Avoid Heat, sunlight, strong acids, the presence of metals and other impurities.

Incompatible Materials PRIMARY AMINES: (e.g. ethylamine) and AROMATIC AMINES (e.g. aniline) - react to form explosively unstable N-mono- or di- chloramines. AMMONIUM SALTS: (e.g. ammonium sulfate and ammonium nitrate), AMMONIA, UREA or PHENYLACETONITRILE: - form explosive nitrogen trichloride, if acid is present. ACIDS: (especially hydrochloric acid) - contact releases corrosive chlorine gas. METALS: (especially copper, aluminum, nickel, and cobalt) - accelerate decomposition. REDUCING AGENTS: (e.g. hydrides, such as lithium aluminum hydride) - cause a violent reaction. ETHYLENEIMINE (AZIRIDINE): - form the explosive N- chloroethyleneimine. METHANOL: - can form explosive methyl hypochlorite, especially in the presence of acids or other etherification catalysts. FORMIC ACID: - becomes explosive at 55°C. FURFURALDEHYDE: - drop wise addition of the aldehyde to a 10% excess of sodium hypochlorite solution at 20-25°C can lead to a violent explosion. ETHANEDIOL (ETHYLENE GLYCOL): erupts violently after an induction period of about 4 to 8 minutes. SODIUM ETHYLENEDIAMINETETRACETATE (EDTA) SOLUTION and SODIUM HYDROXIDE SOLUTION: mixing the three solutions leads to vigorous foaming decomposition.

Hazardous Decomposition Products Chlorine (by reaction with acids), oxygen (by reaction with nickel, copper, tin, manganese, iron), sodium chloride, sodium chlorate, with increased temperature.

Section 11 - Toxicological Information

Acute Toxicity

Component Oral LD50 Dermal LD50 Inhalation LC50

Sodium Hypochlorite 8910mg/kg (rat, undiluted) > 10,000mg/kg (rabbit, undiluted)

> 5250mg/m3 (rat, 4hr exposure, concentration not

specified)

~7540mg/kg (female mouse, 50% solution )

Chronic Toxicity – Carcinogenicity

Component IARC

Sodium Hypochlorite Group 3: Not classifiable as to its carcinogenicity to humans. [hypochlorite salts]


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Skin Corrosion/Irritation Very dilute solutions have caused negligible irritation, while more concentrated

solutions have caused corrosive injury to skin and eyes.

Ingestion Burning of the mouth and throat, abdominal cramps, nausea, vomiting, diarrhea, shock. May lead to convulsions, coma, and even death.

Inhalation Irritant of the nose and throat, causing coughing, difficulty breathing, and pulmonary edema.

Serious Eye Damage/Irritation May cause severe irritation with corneal injury which may result in permanent impairment of vision, even blindness. Chemical burns may occur.

Respiratory or Skin Sensitization Negative results (0/20 guinea pigs sensitized) have been obtained for 8% sodium hypochlorite solution in a skin sensitization test. Insufficient details are available to evaluate a report of a positive result (positive reactions in 2/10 animals) obtained using 6% sodium hypochlorite (pH 11.2) with the guinea pig ear swelling test for non-immunological contact urticaria.

Germ Cell Mutagenicity The available information does not suggest that sodium hypochlorite is mutagenic.

Reproductive Toxicity There is insufficient information available to draw conclusions.

STOT-Single Exposure May cause respiratory irritation.

STOT-Repeated Exposure Not Available

Aspiration Hazard Prolonged or repeated overexposure causes lung damage.

Synergistic Materials Not Available

Section 12 – Ecological Information

Ecotoxicity

Component Toxicity to Algae Toxicity to Fish Toxicity to Daphnia and Other Aquatic Invertebrates

Sodium Hypochlorite Not Available LC50(Salmo gairdneri, 96hr): 0.172mg/L

LC50(Daphnia magna, 96hr): 2.1mg/L

Not Available LC50(Ictalurus punctatus, 96hr): 0.156mg/L

LC50(Gammarus fasciatus, 96hr): 4mg/L

Biodegradability Not Available

Bioaccumulation No evidence to support any rating.

Mobility Not Available

Other Adverse Effects Not Available

Section 13 - Disposal Considera tions Waste From Residues/Unused Products Dispose in accordance with all federal, provincial, and/or local regulations including

the Canadian Environmental Protection Act.

Contaminated Packaging Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act.


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Section 14 - Transport Information

Section 15 - Regulatory Information

NOTE: THE PRODUCT LISTED ON THIS SDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS SDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.

Section 16 - Other Information

Preparation Date February 3, 2015

Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations.

Attention: Receiver of the chemical goods / SDS coordinator

As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution® initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request.

If you have any questions or concerns please call our customer service center or technical service department.

UN Number UN 3266

UN Proper Shipping Name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

Transport Hazard Class(es) 8

Packaging Group III

Environmental Hazards Listed as a marine pollutant under Canadian TDG Regulations Schedule 1, Column 10.

Transport in Bulk Not Available

Special Precautions Not Available

TDG

Other Secure containers (full and/or empty) with suitable hold down devises during shipment and ensure all caps, valves, or closures are secured in the closed position.


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References

1) CHEMINFO: Sodium Hypochlorite Solutions. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/cheminfo/records/351E.html#TOC11

2) CHRIS: Sodium Hypochlorite. (2014) Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/chris/records/1119.html

3) RTECS: Hypochlorous acid, sodium salt. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/rtecs/records/NH3486300.html

4) HSDB: Sodium Hypochlorite. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/hsdb/records/748.html

5) CESARS: Chlorine/hypochlorite. (2014). Retrieved from Canadian Centre for Occupational Health and Safety: http://ccinfoweb2.ccohs.ca/cesars/records/777.html

6) IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. List of classifications by alphabetical order. Agents Classified by the IARC Monographs, Volumes 1-111. http://monographs.iarc.fr/ENG/Classification/index.php

24 Hour Emergency Number - All Locations – 1(306) 664-2522 Alternative - 1(800) 387-7503



http://ccinfoweb2.ccohs.ca/cheminfo/records/351E.html#TOC11

http://ccinfoweb2.ccohs.ca/chris/records/1119.html

http://ccinfoweb2.ccohs.ca/rtecs/records/NH3486300.html

http://ccinfoweb2.ccohs.ca/hsdb/records/748.html

http://ccinfoweb2.ccohs.ca/cesars/records/777.html

http://monographs.iarc.fr/ENG/Classification/index.php

MATERIAL SAFETY DATA

SHEET

Page 1 of 2

POWDERED DEFOAMER LC160

HAZARD RATING 4=Extreme 3=High 2=Moderate 1=Slight 0=Insignificant *=See Section IV

fire

health

special

0 0 0

reactivity

SECTION 1
Date Prepared: 11/01/02
S

EMERGENCY Spill, Leak, Fire, Exposure or Accident Call Day or Night CHEM-TEL INC.: 800-255-3924 INFORMATION Telephone Number: 800-933-9133

A

SECTION 2 Hazardous Ingredients/Identity Information

GENICARE INC. 1407 Mahalo Place, Rancho Dominguez, CA 90220

Hazardous Components CAS # % (Optional) Threshold Limit None
SECTION 3 Physical/Chemical Characteristics Boiling Point: N/A Specific Gravity (Water=1): N/A Vapor Pressure (mm Hg.): N/A Melting Point: ND Vapor Density (Air=1): N/A Evaporation Rate: N/A pH= N/A (Butyl Acetate=1) olubility in Water: Complete ppearance and Odor: White Free Flowing Powder SECTION 4 Fire and Explosion Hazard Data
Flash Point (Method Used): <200 Degrees F TCC Extinguishing Media: Dry Chemical, Foam, CO2 or Water Spray Special Fire Fighting Procedures: Wear self-contained breathing apparatus whenever fighting chemical fires Unusual Fire and Explosion Hazards: None known
SECTION 5 Reactivity Data
Stability: Unstable Conditions to Avoid: None known Stable X Incompatibility (Material to Avoid): None known Hazardous Decomposition or By-products: Hazardous May Occur Conditions to Avoid: None known Polymerization: Will Not Occur X
SECTION 6 Health Hazard Data Routes of Entry: Inhalation, Eyes, Skin, Ingestion Signs and Symptoms of Exposure: Inhalation: Minimally irritating. Eyes: Slight temporary irritation. Skin: No effect. Ingestion: Unlikely, no effect in small in small quantities. Carcinogen: No


Genicare Inc., 1407 Mahalo Place, Rancho Dominguez, CA 90220 POWDERED DEFOAMER

Page 2 of 2 Medical Conditions Generally Aggravated By Exposure: None known Emergency and First Aid Procedures Inhalation: Remove to fresh air. Give resuscitation if not breathing. Get immediate medical attention. Eyes: Flush eyes with lots of water for at least 15 minutes. Get immediate medical attention. Skin: Wash skin with soap and water. Remove contaminated clothing. Call for medical attention if ill effect or irritation develops. Ingestion: Give large amounts of water. Do not induce vomiting. Never give water to an unconscious person. Get immediate medical attention. SECTION 7 Control Measures

Respiratory Protection: None normally needed. If required use NIOSH approved canister type respirator. Ventilation: General or mechanical. Protective Gloves: Where hand contact is possible, wear impermeable gloves. Eye Protection: Where eye contact is possible, wear chemical goggles. No contact lenses. Other Protective Clothing or Equipment: As required by employer rules. Work/Hygienic Practices: Wash hands thoroughly after using. Practice good personal hygiene. SECTION 8 Precautions for Safe Handling and Use

Steps to be Taken in Case Material is Released or Spilled: Sweep or shovel up spilled material into DOT approved wash container. Flush spill area with water. Waste Disposal Method: Treatment, storage, transportation and disposal of this material must be in accordance with applicable federal, state and local regulations. Precautions to be Taken in Handling or Storage: Keep in closed container. Other Precautions: None known SECTION 9 Transportation and Reporting Data

DOT Regulated As Hazardous: No X Yes *Subject to the reporting requirements of SARA Title III, Section 313 and 40 CFR Part 372. No X Yes NA = Not Applicable ND = Not Determined NE = Not Established The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. GENICARE INC. assumes no responsibility for personal injury or property damage to vendees, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of the material.


SAFETY DATA SHEET

PURELL® Advanced Hand Sanitizer

Version 1.2


MSDS Number: 36799-00003

Date of last issue: 02/10/2015 Date of first issue: 12/12/2014

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SECTION 1. IDENTIFICATION

Product name

: PURELL® Advanced Hand Sanitizer


Company name of supplier

: GOJO Industries, Inc.

Address

: One GOJO Plaza, Suite 500 Akron OH 44311

Telephone

: 1 (330) 255-6000

Emergency telephone

: 1-800-424-9300 CHEMTREC


Recommended use

: Hand Sanitizer

Restrictions on use

: This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.


GHS Classification

Flammable liquids

: Category 3

Eye irritation

: Category 2A

GHS Label element

Hazard pictograms

:

Signal Word

: Warning

Hazard Statements

: H226 Flammable liquid and vapor. H319 Causes serious eye irritation.


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Precautionary Statements

: Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards

Vapors may form explosive mixture with air.


Substance / Mixture

: Mixture

Hazardous ingredients

Chemical Name CAS-No. Concentration (%)

Ethanol 64-17-5 >= 50 - < 70

Propan-2-ol 67-63-0 >= 1 - < 5


General advice

: In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.

If inhaled

: If inhaled, remove to fresh air. Get medical attention if symptoms occur.

In case of skin contact

: Wash with water and soap as a precaution. Get medical attention if symptoms occur.

In case of eye contact

: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn.


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Get medical attention.

If swallowed

: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.


: Causes serious eye irritation.

Protection of first-aiders

: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.

Notes to physician

: Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES


: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)


: High volume water jet

Specific hazards during fire fighting

: Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.

Hazardous combustion prod-ucts

: Carbon oxides

Specific extinguishing methods

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.


: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.



: Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions : Discharge into the environment must be avoided.


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Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.


: Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.


Technical measures

: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation

: Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation.

Advice on safe handling

: Do not breathe vapors or spray mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.

Conditions for safe storage

: Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.

Materials to avoid

: Do not store with the following product types: Strong oxidizing agents


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Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases


Ingredients with workplace control parameters

Ingredients CAS-No. Value type (Form of exposure)

Control parameters / Permissible concentration

Basis

Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3

NIOSH REL

TWA 1,000 ppm 1,900 mg/m3

OSHA Z-1

STEL 1,000 ppm ACGIH

Propan-2-ol 67-63-0 TWA 200 ppm ACGIH

STEL 400 ppm ACGIH

TWA 400 ppm 980 mg/m3

NIOSH REL

ST 500 ppm 1,225 mg/m3

NIOSH REL

TWA 400 ppm 980 mg/m3

OSHA Z-1

Biological occupational exposure limits

Ingredients CAS-No. Control parameters

Biological specimen

Sam-pling time


Basis

Propan-2-ol 67-63-0 Acetone Urine End of shift at end of work-week

40 mg/l ACGIH BEI

Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.



: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and


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use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.

Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks

: Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.

Eye protection

: Wear the following personal protective equipment: Safety goggles

Skin and body protection

: Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).

Hygiene measures

: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.


Appearance

: liquid

Color

: clear, light green

Odor

: alcohol-like

Odor Threshold

: No data available

pH

: 6.5 - 8.5

Melting point/freezing point

: No data available

Initial boiling point and boiling range

: 76 °C


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Flash point

: 24 °C

Evaporation rate

: No data available


: Not applicable

Upper explosion limit

: No data available

Lower explosion limit

: No data available

Vapor pressure

: No data available

Relative vapor density

: No data available

Density

: 0.881 g/cm3

Solubility(ies) Water solubility

: soluble


: Not applicable

Autoignition temperature

: No data available

Decomposition temperature

: The substance or mixture is not classified self-reactive.

Viscosity Viscosity, kinematic

: 3,500 - 23,000 mm2/s (20 °C)

Explosive properties

: Not explosive

Oxidizing properties

: The substance or mixture is not classified as oxidizing.


Reactivity

: Not classified as a reactivity hazard.

Chemical stability

: Stable under normal conditions.

Possibility of hazardous reac-tions

: Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents.

Conditions to avoid

: Heat, flames and sparks.


: Oxidizing agents


: No hazardous decomposition products are known.


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Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact

Acute toxicity

Not classified based on available information.

Product:

Acute oral toxicity

: Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method

Ingredients:

Ethanol: Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg

Acute inhalation toxicity

: LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor

Propan-2-ol: Acute oral toxicity

: LD50 (Rat): > 5,000 mg/kg

Acute inhalation toxicity

: LC50 (Rat): 72.6 mg/l Exposure time: 4 h Test atmosphere: vapor

Acute dermal toxicity

: LD50 (Rat): > 5,000 mg/kg



Product:

Result: No skin irritation

Ingredients:

Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Propan-2-ol: Species: Rabbit Result: No skin irritation


Causes serious eye irritation.

Ingredients:


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Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Propan-2-ol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days

Respiratory or skin sensitization

Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information.

Product:

Assessment: Does not cause skin sensitization.

Ingredients:

Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Propan-2-ol: Test Type: Buehler Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative



Ingredients:

Ethanol: Genotoxicity in vitro

: Test Type: In vitro mammalian cell gene mutation test Result: negative

Genotoxicity in vivo

: Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative

Propan-2-ol: Genotoxicity in vitro

: Test Type: Bacterial reverse mutation assay (AMES) Result: negative

Genotoxicity in vivo

: Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Species: Mouse Application Route: Intraperitoneal injection Result: negative


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Carcinogenicity


Ingredients:

Propan-2-ol: Species: Rat Application Route: inhalation (vapor) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative IARC

No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

OSHA

No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.

NTP

No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.



Ingredients:

Ethanol: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative

Propan-2-ol: Effects on fertility

: Test Type: Two-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative

Effects on fetal development

: Test Type: Embryo-fetal development Species: Rat Application Route: Ingestion Result: negative

STOT-single exposure


Ingredients:

Propan-2-ol: Assessment: May cause drowsiness or dizziness.


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STOT-repeated exposure


Repeated dose toxicity

Ingredients:

Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Propan-2-ol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapor) Exposure time: 104 w Method: OECD Test Guideline 413

Aspiration toxicity



Ecotoxicity

Ingredients:

Ethanol: Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h

Toxicity to algae

: EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d

Toxicity to bacteria

: EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h

Propan-2-ol: Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): > 10,000 mg/l Exposure time: 24 h

Toxicity to algae

: ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800 mg/l


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Exposure time: 8 d

Toxicity to bacteria

: EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16 h


Ingredients:

Ethanol: Biodegradability

: Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d

Propan-2-ol: Biodegradability

: Result: rapidly degradable


Ingredients:

Ethanol: Partition coefficient: n-octanol/water

: log Pow: -0.35

Propan-2-ol: Partition coefficient: n-octanol/water

: log Pow: 0.05

Mobility in soil

No data available


No data available


Disposal methods

Waste from residues : Dispose of in accordance with local regulations.

Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum.


International Regulation

UNRTDG UN number : UN 1987

Proper shipping name : ALCOHOLS, N.O.S.


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(Ethanol, Propan-2-ol)

Class : 3

Packing group : III

Labels : 3

IATA-DGR UN/ID No. : UN 1987

Proper shipping name : Alcohols, n.o.s.

(Ethanol, Propan-2-ol)

Class : 3

Packing group : III

Labels : Flammable Liquids

Packing instruction (cargo aircraft)

: 366

Packing instruction (passenger aircraft)

: 355

IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S.

(Ethanol, Propan-2-ol) Class : 3 Packing group : III Labels : 3 EmS Code : F-E, S-D Marine pollutant : no


Not applicable for product as supplied.

Domestic regulation

49 CFR UN/ID/NA number : UN 1987

Proper shipping name : ALCOHOLS, N.O.S.

Class : 3

Packing group : III

Labels : FLAMMABLE LIQUID

ERG Code : 127

Marine pollutant : no


EPCRA - Emergency Planning and Community Right-to-Know


This material does not contain any components with a CERCLA RQ.


This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard


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Acute Health Hazard

SARA 302

: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313

: The following components are subject to reporting levels established by SARA Title III, Section 313:

Propan-2-ol

67-63-0 3.4086 %


Pennsylvania Right To Know

Ethanol 64-17-5 50 - 70 %

Water 7732-18-5 30 - 50 %

Propan-2-ol 67-63-0 1 - 5 %

New Jersey Right To Know

Ethanol 64-17-5 50 - 70 %

Water 7732-18-5 30 - 50 %

Propan-2-ol 67-63-0 1 - 5 %

California Prop 65 This product does not contain any chemicals known to the

State of California to cause cancer, birth, or any other reproductive defects.

The ingredients of this product are reported in the following inventories:

AICS

: All ingredients listed or exempt.

Inventories

AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)


SAFETY DATA SHEET


Version 1.2




15 / 15


Further information

NFPA: HMIS III:

Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI : ACGIH - Biological Exposure Indices (BEI) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-

its for Air Contaminants ACGIH / TWA : 8-hour, time-weighted average ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour

workday during a 40-hour workweek NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded

at any time during a workday OSHA Z-1 / TWA : 8-hour time weighted average Sources of key data used to compile the Material Safety Data Sheet

: Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/

Revision Date

: 03/18/2015

The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-formation and belief at the date of its publication. The information is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid-ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un-less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in-cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8

Flammability

Health

Insta

bility

2

3

0

FLAMMABILITY

PHYSICAL HAZARD

HEALTH

3

0

2

Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic


Purple Power

Safety Data Sheet

Product Identifier Purple Power

Other Means ofIdentification

Code No. 330

Leysons Products, a division of 1787528 Ontario Inc., 1366 Sandhill Drive, Ancaster, Ontario,L9G 4V5, (905) 648-7832

Recommended Use

SDS No.

Emergency Phone No.

SECTION 1. IDENTIFICATION

Manufacturer

All purpose cleaner and degreaser.

0235

CANUTECH, 613-996-6666, 24-hr for Emergencies involving Dangerous Goods

Restrictions on Use Use only as directed according to label instructions.

Label Elements

SECTION 2. HAZARD IDENTIFICATION

DangerCorrosiveCauses severe eye damage and skin irritation or burns.May be harmful if swallowed.

Classification

Skin irritation - Category 2; Serious eye damage - Category 1


Chemical Name CAS No. Other Identifiers% Other Names

2-Butoxyethanol 111-76-2 5-10

Ethanolamine 141-43-5 1-5

Alcohols, C9-11, ethoxylated, liquids 68439-46-3 1-5

Inhalation

If irritation is experienced, remove person to fresh air.Get medical advice or attention if you feel unwell or are concerned.

Skin Contact

In case of contact, immediately flush skin with plenty of water.Call a physician if irritation develops or persists.

SECTION 4. FIRST-AID MEASURES

First-aid Measures

SDS No.:

Date of Preparation:

0235

Page of 0601

December 19, 2017

Product Identifier: Purple Power - Ver. 1

Date of Last Revision:


Call a physician if irritation develops or persists.Eye Contact

Immediately rinse the contaminated eye(s) with lukewarm, gently flowing water for 15-20 minutes, while holding theeyelid(s) open.Remove contact lenses, if present and easy to do.If eye irritation persists, get medical advice or attention.

Ingestion

Never give anything by mouth if person is rapidly losing consciousness, or is unconscious or convulsing. Do notinduce vomiting.If vomiting occurs naturally, lie on your side in the recovery position. Rinse mouth with water again.Immediately call a Poison Centre or doctor.

Immediate Medical Attention and Special Treatment

Medical Conditions Aggravated by Exposure

Asthma, skin allergies.

Target Organs

Eyes, skin, respiratory system, digestive system.

Extinguishing Media

Suitable Extinguishing Media

Not combustible. Use extinguishing agent suitable for surrounding fire.

Unsuitable Extinguishing Media

None known.

Specific Hazards Arising from the Product

This product presents no unusual hazards in a fire situation.

Special Protective Equipment and Precautions for Fire-fighters

Wear full fire fighting equipment and respirator.

SECTION 5. FIRE-FIGHTING MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures

Use the personal protective equipment recommended in Section 8 of this safety data sheet.Increase ventilation to area or move leaking container to a well-ventilated and secure area.

Environmental Precautions

Do not allow into any sewer, on the ground or into any waterway.If the spill is inside a building, prevent product from entering drains, ventilation systems and confined areas.Minimize the use of water to prevent environmental contamination.

Methods and Materials for Containment and Cleaning Up

Contain and/or absorb spill with commercial absorbents and then place into a suitable container for disposal.


Precautions for Safe Handling

Do not get in eyes, on skin or on clothing.Do not breath gas/fumes/vapour/spray.Do NOT ingest.Keep containers tightly sealed when not in use.

Conditions for Safe Storage

Store in a cool dry area away from incompatible materials.Keep out of reach of children in a tightly closed container away from food, drink and animal feed.


SDS No.:


0235

Page of 0602

December 19, 2017





ACGIH TLV® OSHA PEL

Chemical Name TWA STEL TWA Ceiling

Control Parameters

AIHA WEEL

8-hr TWA TWA

Ethanolamine 3 ppm 6 ppm

2-Butoxyethanol 20 ppm 25 ppm

Alcohols, C9-11, ethoxylated, liquids Notestablished

Notestablished

Appropriate Engineering Controls

Individual Protection Measures

Skin Protection

Respiratory Protection

Eye/Face Protection

Use in well ventilated areas. In case of insufficient ventilation, wear suitable respiratory equipment.

Wear protective gloves and clothing to prevent skin contact.

Wear chemical safety goggles and face shield when contact is possible.

Use ventilation adequate to keep exposures (airborne levels of vapour) below the recommended exposure limits.Provide eyewash and safety shower if contact or splash hazard exists.Use local exhaust ventilation, if general ventilation is not adequate to control amount in the air.

pH 12.5 - 13.2

Appearance Clear purple liquid.

Vapour Pressure Not available

Flash Point Not applicable

Melting Point/Freezing Point ~ 0 ºC (32 ºF) (freezing)

Upper/Lower Flammability orExplosive Limit

Not available (upper); Not available (lower)

Solubility Soluble in water


Bulk Density ~ 1.03 kg/L

Basic Physical and Chemical Properties

LiquidPhysical State

Other Information

Chemical Stability

Normally stable.

Conditions to Avoid

High temperatures.Freezing.Incompatible materials.

Incompatible Materials

Strong acids (e.g. hydrochloric acid), strong oxidizing agents (e.g. perchloric acid), strong reducing agents (e.g.hydrides).


Reactivity

Not reactive under normal conditions of use.

SDS No.:


0235

Page of 0603

December 19, 2017




Incompatible Materials

Strong acids (e.g. hydrochloric acid), strong oxidizing agents (e.g. perchloric acid), strong reducing agents (e.g.hydrides).

Hazardous Decomposition Products

May include but are not limited to oxides of carbon, nitrogen and ammonia.

Skin Corrosion/Irritation

May cause irritation or symptoms such as redness, edema, drying, defatting or cracking of the skin.

Serious Eye Damage/Irritation

May cause severe irritation or burns.


STOT (Specific Target Organ Toxicity) - Single Exposure

Inhalation

May cause irritation of the respiratory system.

Skin Absorption

May cause irritation on prolonged contact.

Ingestion

Harmful if swallowed.

No chronic effects are expected provided adequate person protection is taken during usage.

STOT (Specific Target Organ Toxicity) - Repeated Exposure

Respiratory and/or Skin Sensitization

Not expected to produce any respiratory system problems when used in a well ventilated area.

Carcinogenicity

Not known to cause cancer.

Development of Offspring

Not known to harm the unborn child.


Not known to cause effects on sexual function or fertility.

Germ Cell Mutagenicity

Acute Toxicity

Sexual Function and Fertility

Effects on or via Lactation

Not known to cause effects on or via lactation.

May be drawn into the lungs (aspirated) if swallowed or vomited.

Aspiration Hazard

Inhalation.Skin contact.Skin absorption.Eye contact.Ingestion.

Likely Routes of Exposure

Chemical Name LC50 LD50 (oral) LD50 (dermal)

Ethanolamine > 1.21 mg/L (rat) (4-hourexposure)

1720 mg/kg (rat) 1000 mg/kg (rabbit)

2-Butoxyethanol 450 ppm (rat) (4-hourexposure)

530 mg/kg (rat) 400-500 mg/kg (rabbit)

Alcohols, C9-11, ethoxylated,liquids

1378 mg/kg (rat) > 2000 mg/kg (rabbit)

SDS No.:


0235

Page of 0604

December 19, 2017




Germ Cell Mutagenicity

Not known to be a mutagen.

Interactive Effects

No information was located.

May cause long-term adverse effects in the aquatic environment.




Readily biodegradable (test method #301D, OECD).

Ecotoxicity

Persistence and Degradability

Mobility in Soil

Bioaccumulative Potential


Dispose of contents and container in accordance with local, regional, national and international regulations.

Disposal Methods


UN No. Proper Shipping NamePackingGroup

Transport HazardClass(es)

Regulation

2491 Ethanolamine Solution 8 IIICanadian TDG

Special Precautions Not applicable

Transport in Bulk According to Annex II of MARPOL 73/78 and the IBC Code

Not applicable


Canada

WHMIS 1988 Classification

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations andthe SDS contains all of the information required by the Controlled Products Regulations.

Safety, Health and Environmental Regulations

Class EClass D2B

D2B - Toxic (Skin irritant; Eye irritant); E - Corrosive

Disclaimer The user of this product assumes all risks incident to the use of this product.To the best of our knowledge, the information contained herein is accurate.However, the supplier assumes no liability whatsoever for the accuracy or completeness of theinformation contained herein.No representation of warranties, either expressed or implied, of merchantability, fitness for aparticular purpose or of any other nature are made hereunder with respect to the information orthe product to which the information refers.The data contained on this sheet apply to the products supplied to the user.


SDS Prepared By Mark Bryans

Phone No. (905) 648-7832 ext 351

Date of Preparation December 19, 2017

SDS No.:


0235

Page of 0605

December 19, 2017




Disclaimer

To the best of our knowledge, the information contained herein is accurate.However, the supplier assumes no liability whatsoever for the accuracy or completeness of theinformation contained herein.No representation of warranties, either expressed or implied, of merchantability, fitness for aparticular purpose or of any other nature are made hereunder with respect to the information orthe product to which the information refers.The data contained on this sheet apply to the products supplied to the user.

SDS No.:


0235

Page of 0606

December 19, 2017




Scotchgard™ Shoe Guard Liquid Shoe Polish with Water Repellent 02/12/14

__________________________________________________________________________________________Page 1 of 9

Safety Data Sheet

Copyright,2014,3M Company.All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.


SECTION 1: Identification

1.1. Product identifierScotchgard™ Shoe Guard Liquid Shoe Polish with Water Repellent

Product Identification NumbersJF-1000-8282-1

1.2. Recommended use and restrictions on use

Recommended useShoe Polish with Water Repellent

1.3. Supplier’s detailsMANUFACTURER: 3MDIVISION: Materials Resource DivisionADDRESS: 3M Center, St. Paul, MN 55144-1000, USATelephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification

2.1. Hazard classificationSerious Eye Damage/Irritation: Category 2B.

2.2. Label elementsSignal wordWarning

SymbolsNot applicable

PictogramsNot applicable

Hazard StatementsCauses eye irritation.



__________________________________________________________________________________________Page 2 of 9

Precautionary StatementsGeneral:Keep out of reach of children.

Prevention:Wash thoroughly after handling.

Response:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

2.3. Hazards not otherwise classifiedNone.

3% of the mixture consists of ingredients of unknown acute oral toxicity.


Ingredient C.A.S. No. % by WtWATER 7732-18-5 90 - 95CARNAUBA WAX 8015-86-9 1 - 3TRI(BUTOXYETHYL) PHOSPHATE 78-51-3 1 - 3ACRYLATE POLYMER Trade Secret* 1 - 3ACRYLATE POLYMER SALT Trade Secret* 1 - 3FLUOROCHEMICAL ACRYLATE POLYMER Trade Secret* < 13-IODO-2-PROPYNYL BUTYLCARBAMATE 55406-53-6 < 0.051,2-BENZISOTHIAZOLIN-3-ONE 2634-33-5 < 0.025

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret.


4.1. Description of first aid measures

Inhalation: Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention.

Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention.

If Swallowed: Rinse mouth. Do not induce vomiting. Get immediate medical attention.

4.2. Most important symptoms and effects, both acute and delayedSee Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment requiredNot applicable.



__________________________________________________________________________________________Page 3 of 9

SECTION 5: Fire-fighting measures

5.1. Suitable extinguishing mediaIn case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixtureNone inherent in this product.

Hazardous Decomposition or By-ProductsSubstance ConditionCarbon monoxide During CombustionCarbon dioxide During CombustionHydrogen Fluoride During CombustionToxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fightersWhen fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.


6.1. Personal precautions, protective equipment and emergency proceduresEvacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautionsAvoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.

6.3. Methods and material for containment and cleaning upContain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible.


7.1. Precautions for safe handlingAvoid eye contact. Do not breathe thermal decomposition products. Keep out of reach of children. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment.

7.2. Conditions for safe storage including any incompatibilitiesNo special storage requirements.


8.1. Control parameters




__________________________________________________________________________________________Page 4 of 9

No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS.

8.2. Exposure controls

8.2.1. Engineering controlsProvide appropriate local exhaust when product is heated. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended:Indirect Vented Goggles

Skin/hand protectionSelect and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing.Gloves made from the following material(s) are recommended: Polymer laminate


Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.


9.1. Information on basic physical and chemical propertiesGeneral Physical Form: Liquid Odor, Color, Grade: White color liquid with mild odor.Odor threshold No Data AvailablepH 7.9 - 8.3 Melting point Not ApplicableBoiling Point 212 ºFFlash Point No flash pointEvaporation rate No Data AvailableFlammability (solid, gas) Not ApplicableFlammable Limits(LEL) Not ApplicableFlammable Limits(UEL) Not ApplicableVapor Pressure <=18 mmHg [@ 68 ºF]Vapor Density No Data AvailableDensity 0.98 - 1.02 g/mlSpecific Gravity 0.98 - 1.02 [Ref Std: WATER=1]Solubility in Water Complete



__________________________________________________________________________________________Page 5 of 9

Solubility- non-water No Data AvailablePartition coefficient: n-octanol/ water No Data AvailableAutoignition temperature No Data AvailableDecomposition temperature No Data AvailableViscosity No Data AvailableVolatile Organic Compounds 2.77 g/lPercent volatile 92 - 93


10.1. ReactivityThis material is considered to be non reactive under normal use conditions.

10.2. Chemical stabilityStable.

10.3. Possibility of hazardous reactionsHazardous polymerization will not occur.

10.4. Conditions to avoidNone known.

10.5. Incompatible materialsNone known.

10.6. Hazardous decomposition productsSubstance ConditionNone known.

Refer to section 5.2 for hazardous decomposition products during combustion.

Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product.


The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.



__________________________________________________________________________________________Page 6 of 9

Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.

Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion:No health effects are expected.

Toxicological DataIf a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification.

Acute ToxicityName Route Species ValueOverall product Ingestion No data available; calculated ATE > 5,000 mg/kgCARNAUBA WAX Ingestion LD50 estimated to be > 5,000 mg/kgTRI(BUTOXYETHYL) PHOSPHATE Dermal Rabbit LD50 > 5,000 mg/kgTRI(BUTOXYETHYL) PHOSPHATE Inhalation-

Dust/Mist (4 hours)

Rat LC50 > 6.4 mg/l

TRI(BUTOXYETHYL) PHOSPHATE Ingestion Rat LD50 4,700 mg/kgFLUOROCHEMICAL ACRYLATE POLYMER Dermal LD50 estimated to be > 5,000 mg/kgFLUOROCHEMICAL ACRYLATE POLYMER Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg3-IODO-2-PROPYNYL BUTYLCARBAMATE Dermal Rabbit LD50 > 2,000 mg/kg3-IODO-2-PROPYNYL BUTYLCARBAMATE Inhalation-

Dust/Mist (4 hours)

Rat LC50 0.67 mg/l

3-IODO-2-PROPYNYL BUTYLCARBAMATE Ingestion Rat LD50 1,056 mg/kg

ATE = acute toxicity estimate

Skin Corrosion/IrritationName Species Value3-IODO-2-PROPYNYL BUTYLCARBAMATE Rabbit Minimal irritation

Serious Eye Damage/IrritationName Species Value3-IODO-2-PROPYNYL BUTYLCARBAMATE Rabbit Corrosive

Skin SensitizationName Species Value3-IODO-2-PROPYNYL BUTYLCARBAMATE Multiple

animal species

Sensitizing

Respiratory SensitizationName Species Value

Germ Cell MutagenicityName Route ValueFLUOROCHEMICAL ACRYLATE POLYMER In Vitro Not mutagenic

CarcinogenicityName Route Species Value


Reproductive and/or Developmental EffectsName Route Value Species Test Result Exposure

Duration



__________________________________________________________________________________________Page 7 of 9

Target Organ(s)

Specific Target Organ Toxicity - single exposureName Route Target Organ(s) Value Species Test Result Exposure

Duration

Specific Target Organ Toxicity - repeated exposureName Route Target Organ(s) Value Species Test Result Exposure

Duration3-IODO-2-PROPYNYL BUTYLCARBAMATE

Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure

Rat NOAEL .00116 mg/l

90 days

Aspiration HazardName Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components.


Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components.

Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components.


13.1. Disposal methodsDispose of contents/ container in accordance with the local/regional/national/international regulations.

Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.


15.1. US Federal RegulationsThis material contains one or more substances that are subject to a TSCA Consent Order. Contact 3M for more information.



__________________________________________________________________________________________Page 8 of 9

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by WtTRI(BUTOXYETHYL) PHOSPHATE (GLYCOL ETHERS)

78-51-3 1 - 3

This material contains a chemical which requires export notification under TSCA Section 12[b]:

Ingredient (Category if applicable) C.A.S. No Regulation StatusFLUOROCHEMICAL ACRYLATE POLYMER Trade Secret Toxic Substances Control Act (TSCA) 5

SNUR or Consent Order ChemicalsApplicable

15.2. State RegulationsContact 3M for more information.

15.3. Chemical InventoriesThe components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information.

The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information.

The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International RegulationsContact 3M for more information.



NFPA Hazard ClassificationHealth: 3 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard ClassificationHealth: *2 Flammability: 0 Physical Hazard: 0 Personal Protection: X - See PPE section.

Hazardous Material Identification System (HMIS® III) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® III ratings are to be used with a fully implemented HMIS® III program. HMIS® is a registered mark of the American Coatings Association (ACA).



__________________________________________________________________________________________Page 9 of 9


DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

3M USA SDSs are available at www.3M.com


Per OSHA-recommended ANSI Z400.1-2004 standard format & in accordance with European standard format

SECTION 1: PRODUCT AND COMPANY IDENTIFICATIONProduct Name: ShockWave™Product Description: EPA Registered Disinfectant/Sanitizer/Cleaner/Fungicide (10oz) Product Code: 8311Manufacturer: Fiberlock Technologies, Inc.

Address: Fiberlock Technologies150 Dascomb RoadAndover MA, 01810

Contact Info:Tel: (800) 342-3755

Fax: (978) 475-6205Emergency Phone: 24 Hour Contact: CHEM-TEL: (800) 255-3924 INTERNATIONAL 24 HOUR EMERGENCY Phone: 813-248-0585

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTSNon-hazardous:

Hazardous:

Chemical Name CAS# Percent OSHA PEL ACGIH TLV

1 - Dimethyl Benzyl Ammonium Chloride

68391-01-5 < 2.25 Not Established Not Established

2 - Dimethyl Ethylbenzyl Ammonium Chloride

68956-79-6 < 2.25 Not Established Not Established

This product does not contains any toxic chemical(s) subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 and of 40 CFR 372.

SECTION 3: HAZARDS IDENTIFICATIONPotential Health Hazards: Skin Contact: Skin irritant. Prolonged or repeated contact may cause dermatitis.

Eyes Contact: Severe eye irritant. Liquid and mists may injure the eyes causing corneal damage.

Inhalation: Inhalation of vapors or mists may cause irritation of the throat and respiratory tract. High vapor concentrations may cause central nervous system effects.

Ingestion: Irritating to the mouth, throat, and gastrointestinal system. Burning, pain, and diarrhea expected with large doses.

SECTION 4: FIRST AID MEASURESEyes: Immediately flush eyes with large amounts of water for 15 minutes holding eyelids open. Get medical attention immediately.

Skin: Remove contaminated clothing. Flush affected areas with large quantities of water. Seek medical attention if irritation persists.

Ingestion: Drink 3-4 glasses of milk or water. Do not induce vomiting. Get medical attention immediately.

Inhalation: Remove victim to fresh air and monitor. Seek medical attention if symptoms persist.

MATERIAL SAFETY DATA SHEETSHOCKWAVE™ 10 OZ

SECTION 5: FIRE-FIGHTING MEASURES

Product is non-combustible

Flash point: Autoignition Temperature:

F: Not flammableC: Not flammable

F: Not EstablishedC: Not Established

Flammable Limits in Air: (% BY VOLUME)

UPPER: Not applicableLOWER: Not applicable

Extinguishing Media:

Use extinguishing media appropriate for surrounding fire

Water Spray OK

Carbon Dioxide NO

Foam NO

Dry Chemical OK

Halon NO

Other N/A

SPECIAL FIRE FIGHTING PROCEDURES: Self-contained breathing apparatus and protective clothing should be worn when fighting chemical fires. Use water spray to keep fire-exposed containers cool.


Accidental Release Measures:Personal Precautions: Do not get in eyes. Do not take internally. Avoid skin contact. Prevent prolonged or repeated breathing of vapor or spray mists. Keep unnecessary people away. Floor may be slippery, use care to avoid falling. Remove all sources if ignition. Ventilate the area. Remove with inert absorbent.Environmental Precautions: Keep spills and cleaning run-offs out of municipal sewers and open bodies of water. Comply with local, national and state regulations.


Handling and Storage: Maximum Storage Temperature: 100°F (38°C), minimum 35°F (2°C). Keep closure tight and containers upright to prevent leakage.

Product is non-combustible.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Precautions: Use only with adequate ventilation.

Work Hygienic Practices: Avoid contact with skin. Do not get in eyes. Do not take internally. Avoid breathing vapors or spray mists.

Ventilation: Use in well-ventilated areas. Provide local exhaust to keep TLV ofSection 2 ingredients below acceptable limit.

Respiratory Protection: No special requirements. Avoid breathing mists.

Eye Protection: Chemical goggles recommended when spraying diluted product.

Skin Protection: Wear neoprene, rubber, vinyl, or nitrile gloves to prevent skin contact if prolonged skin contact is likely. Wash hands before eating, smoking or using the wash room.

Other Protective Equipment: Eyewash station should be provided nearby.

MSDS DATE: 4/8/09

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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIESAppearance: Thin liquid Solubility in Water: Total

Odor: Pleasant odor

Color: Light Blue

Boiling Point: 210°F Viscosity @ 77°F: 60-75 Kreb Units

Evaporation Rate:(Butyl Acetate=1)

Slower Vapor Density(AIR = 1) @ 68°F:

Heavier

Vapor Pressure: 20mm Hg @ 68 F

Specific Gravity (H2O = 1) @ 68°F:

1.040

pH 11.5-12.0 Percent Volatile 90+


Stability: Stable

Incompatibility: None

Hazardous Decomposition or By-Products: Will not occur.

Hazardous Polymerization: Will not occur.


Toxicological Information:No Data Available

SECTION 12: ECOLOGICAL INFORMATIONEcological Information:No Data Available


Waste Disposal Method:Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution. Do not dump into sewers, any body of water or onto the ground.

SECTION 14: TRANSPORT INFORMATIONU.S. Department of Transportation Proper Shipping Name: Hazard Class: “Not Regulated” ID Number: Packing Group: Label Statement: “Keep From Freezing” Class: Cleaning Compound


U.S. Federal Regulations: TSCA (TOXIC SUBSTANCE CONTROL ACT): All components of this product are in compliance with the inventory listing requirements of the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): Releases of this material to air, land, or water are not reportable to the National Response Center under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) or to state and local emergency planning committees under the Superfund Amendments and Reauthorization Act (SARA) Title III Section 304.

SARA TITLE III (SARA 313): No ingredients in this product are subject to SARA 313 (40 CFR 372.65C) Supplier Notification.

SARA TITLE III (SARA 311/312): Ingredients in this product are subject to SARA 311/312 Immediate (acute) Health Hazard Supplier Notification.

CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No Components of this product are on the California Proposition 65 lists.

New Jersey Right to Know Hazardous Substance List: This product contains no components subject to reporting requirements.

Canada: Workplace Hazardous materials Information System (WHMIS)-listed material: This product contains the following components subject to reporting requirements: Sodium carbonate.


To comply with New Jersey DOH Right-To-Know labeling law (NJAC 8:59 – 5.1 & 5.2)

CAS. No.: CHEMICAL INGREDIENTS7732-18-5 Water

68391-01-5 Dimethyl Benzyl Ammonium Chloride

68956-79-6 Dimethyl Ethylbenzyl Ammonium Chloride

9016-45-9 Nonionic Surfactant

497-19-8 Sodium Carbonate

(+) Contents Partially Unknown

HMIS HAZARD RATING

Health 2 Flammability 0 Physical Hazard 0 Personal Protection B

HAZARD INDEX: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe

This company cannot anticipate all conditions of handling and use of this product. Therefore, this company accepts no responsibility for results obtained by the application of this information, or the safety and suitability of our products either alone or in combination with other products. It is the responsibility of the user to provide a safe workplace, using the health and safety information contained herein as a guide. This company will accept no liability for damages or loss incurred from theimproper handling and use of this product.

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PRODUCT AND COMPANY IDENTIFICATION1ManufacturerPROCHEMKärcher North America325 S. Price RoadChandler, AZ 85224Contact:Telephone Number:FAX Number:E-Mail:Web

Prochem [email protected]

Emergency Telephone: (800) 535-5053 [Infotrac]

Truck Mount DescalerFebruary 24, 2009E551

Product Name:Revision Date:MSDS Number:

HAZARDS IDENTIFICATION2Eyes; Skin; Inhalation; Ingestion;Route of Entry:Eyes; Skin;Target Organs:Minimal respiratory tract irritation may occur with exposure to a large amount of materialInhalation:May Cause Irritation.Skin Contact:May Cause Irritation.Eye Contact:Small amounts swallowed incidental to normal handling operations are not likely to cause injury;swallowing amounts larger than that may cause temporary injury.

Ingestion:

HMIS III-ratings (scale 0-4): Health = 3, Fire = 0, Physical Hazard = 0

COMPOSITION/INFORMATION ON INGREDIENTS3Ingredients: Cas # Chemical Name ---------------------------------------------------------------- 5329146 | Sulfamic acid OSHA Regulatory Status:This MSDS contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product.

Truck Mount Descaler

Material Safety Data Sheet Revision Date: February 24, 2009MSDS Number: E551

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FIRST AID MEASURES4If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention.Inhalation:Wash with soap and water. If irritation persists consult medical personnel.Skin Contact:Immediately flush eyes with large amounts of water for at least 15 minutes, lifting eyelidsoccasionally to facilitate irrigation. Get immediate medical attention.

Eye Contact:If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If injuredparty is conscious, give two glasses of water. Seek medical attention.

Ingestion:

FIRE FIGHTING MEASURES5

Wear self contained breathing apparatus and other protective clothing. Use any standard agent - choose the one mostappropriate for type of surrounding fire.

Flash Point: N/A

ACCIDENTAL RELEASE MEASURES6Keep away from drains and ground water. Keep all unnecessary personnel away. Spill area may be slippery.Sweep Up, Place In Bag and Hold For Waste Disposal. Ventilate Area and Wash Spill Site After Material Pickup is Complete. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.

HANDLING AND STORAGE7Avoid contact with eyes, skin, or clothing; Consider normal working hygiene. Handle withcare and avoid spillage on the floor (slippage). Keep away from sources of ignition; washthoroughly after handling.

Handling Precautions:

Store out of reach of children; keep container closed; store in a cool well-ventilated placeaway from strong oxidizing or alkaline product.

Storage Requirements:

EXPOSURE CONTROLS/PERSONAL PROTECTION8Normal room ventilation is satisfactory for limited use.Engineering Controls:HMIS PP, X | Consult your supervisor for special instructionsProtective Equipment:

PHYSICAL AND CHEMICAL PROPERTIES9WhiteAppearance:PowderPhysical State:NoneOdor:1.1 - 1.6 @ 1% SolutionpH:N/DVapor Pressure:N/DVapor Density:

N/DBoiling Point:N/DFreezing/Melting Pt.:SolubleSolubility:N/ASpec Grav./Density:



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STABILITY AND REACTIVITY10Product is stable under normal conditions.Stability:None KnownConditions to avoid:None KnownMaterials to avoid (incompatability):Exposure to fire may liberate carbon dioxide, carbon monoxide, organic acids,and other unidentified thermal decomposition products from this product or itspackaging.

Hazardous Decomposition products:

Will not occur.Hazardous Polymerization:

TOXICOLOGICAL INFORMATION11Route of Entry: Eye contact, and Skin absorption/contact Effects of Acute Overexposure to Product:

Eye Contact: Causes eye irritation, redness, tearing and blurred vision Skin Contact: Causes skin irritation, defatting and dermatitis Inhalation: Inhalation of mist or vapor may cause temporary respiratory irritation; temporary central nervous system

effects including dizziness, weakness, fatigue, nausea, and headache. Ingestion: May cause temporary gastrointestinal irritation with nausea, vomiting and diarrhea.

None of the components in this product are listed by NTP, IARC or OSHA as a carcinogen.

ECOLOGICAL INFORMATION12Refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information.

DISPOSAL CONSIDERATIONS13Dispose of in accordance with local regulations.

TRANSPORT INFORMATION14

Refer to bill of lading or container label for DOT or other transportation hazard classification. Ship in accordance with 49 CFR parts 100-185.

REGULATORY INFORMATION15COMPONENT / (CAS/PERC) / CODES ---------------------------------------------------------------- *Sulfamic acid (5329146), WHMIS 1% REGULATORY KEY DESCRIPTIONS ---------------------------------------------------------------- WHMIS= Workforce Hazardous Material Information System



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OTHER INFORMATION16This document is prepared in accordance with 29 CFR 1910.1200. The purpose of this section is to ensure that the hazards of all chemicals produced or imported are evaluated, and that information concerning their hazards is transmitted to employers and employees. All information appearing herein is based upon data obtained from the raw material manufacturer and/or recognized technical sources. While the information above is believed to be true and accurate, the author makes no representations as to its accuracy or sufficiency. Conditions of use are beyond the manufacturer's control; therefore the users are responsible to verify this data under their own particular conditions, applications and regulations to determine if the product is suitable for their particular purposes. The users assume all risks of product use, handling, disposal, reliance upon, publication or use of the information contained herein. This information applies only to the product designated above and does not necessarily apply to its use in combination with other materials, products, chemical compounds, structures or processes. Prepared by: EHS Manager Phone Number: [480] 899-7000

END OF MSDS DOCUMENT



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PRODUCT AND COMPANY IDENTIFICATION1ManufacturerPROCHEMKärcher North America325 S. Price RoadChandler, AZ 85224

[email protected]

Emergency Information: INFOTRAC 1-800-535-5053 International 1-352-323-3500

Ultrapac TrafficleanNovember 12, 201344-43HS711

Product Name:Revision Date:Version:MSDS Number:

Phone:Fax:Email:Web:

HAZARDS IDENTIFICATION2Eyes; Skin; Inhalation; Ingestion;Route of Entry:

Target Organs: Eyes; Skin;Inhalation: Minimal respiratory tract irritation may occur with exposure to a large amount of materialSkin Contact: May cause irritation.Eye Contact: May cause irritation.Ingestion: Small amounts swallowed incidental to normal handling operations are not likely to cause injury; swallowing amounts

larger than that may cause temporary injury.

110

B | Safety Glasses,Gloves

11 0

Health = 1, Fire = 1, Reactivity = 0H1/F1/PH0

NFPA:HMIS III:

GHS Classifications: Health, Acute toxicity, 5 DermalGHS Phrases:

Ultrapac Trafficlean

Safety Data Sheet Revision Date: November 12, 2013MSDS Number: S711

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GHS Precautionary Statements: IF ON SKIN: Wash with soap and water. Call a POISON CENTER or doctor/physician if you feel unwell.

Warning, H313 - May be harmful in contact with skin

GHS PICTOGRAMS: No GHS Pictograms

HAZARDS IDENTIFICATION3

CAS # Percent Chemical Name ---------------------------------------------------------------- 111762 | <24% | Ethylene glycol monobutyl ether OSHA Regulatory Status:This MSDS Contains valuable information critical to the safe handling and proper use of this product. This MSDS should be retained and available for employees and other users of this product.

Ingredients:

FIRST AID MEASURES4If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention.Wash with soap and water. If irritation persists consult medical personnel.Immediately flush eyes with large amounts of water for at least 15 minutes, lifting eyelids occasionally to facilitateirrigation. Get immediate medical attention.If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. If injured party is conscious,give two glasses of water. Seek medical attention.

Inhalation:Skin Contact:Eye Contact:Ingestion:

FIRE FIGHTING MEASURES5

Wear self-contained breathing apparatus and other protective clothing. Use any standard agent - choose the one most appropriate for typeof surrounding fire.

Flash Point: 200°FFlash Point Method: Closed Cup

ACCIDENTAL RELEASE MEASURES6Keep away from drains and ground water. Keep all unnecessary personnel away. Spill area may be slippery. Pick up excess with inert absorbent material and place into separate waste container. Ventilate area and wash spill site after material pickup is complete. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations.



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HANDLING AND STORAGE7Avoid contact with eyes, skin, or clothing; Consider normal working hygiene. Handle with care and avoidspillage on the floor (slippage). Keep away from sources of ignition; wash thoroughly after handling.Store out of reach of children; keep container closed; store in a cool well-ventilated place.

Handling Precautions:Storage Requirements:

EXPOSURE CONTROLS/PERSONAL PROTECTION8Normal room ventilation is satisfactory for limited use.HMIS PP, B | Safety glasses, Gloves

Ethylene glycol monobutyl ether 111-76-2 OSHA PEL 50 ppm - 240 mg/m3

Engineering Controls:Personal Protective Equip:

PHYSICAL AND CHEMICAL PROPERTIES9

Liquid9.44 lb/gallon9.5 - 10.2 as is

Physical State:Spec Grav./Density:pH:

Odor:Solubility:

MintSoluble

Appearance: Opaque Caramel

STABILITY AND REACTIVITY10Product is stable under normal conditions.None knownNone knownExposure to fire may liberate carbon dioxide, carbon monoxide, organic acids, and other unidentifiedthermal decomposition products from this product or its packaging.Will not occur

Stability:Conditions to Avoid:Materials to Avoid:Hazardous Decomposition:Hazardous Polymerization:

TOXICOLOGICAL INFORMATION11Toxicity Data:Ethylene glycol butyl ether 111-76-2 Oral ( LD 50): 917 mg/kg - Rat Inhalation ( LC 50): 2900 mg/m3/7H - Rat Skin irritation: Mild Eye irritation: Mild Sensitation: Not considered an occupational sensitizer



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ECOLOGICAL INFORMATION12On the basis of available information, this material is not expected to produce any significant environmental effects when recommended use instructions are followed.

DISPOSAL CONSIDERATIONS13Dispose of in accordance with local regulations.

TRANSPORT INFORMATION14

Ship in accordance with 49 CFR parts 100-185. Non-hazardous for air, sea and road freight.DOT Class: Not regulated #

REGULATORY INFORMATION15COMPONENT / (CAS/PERCENT) / CODES ---------------------------------------------------------------- *Ethylene glycol monobutyl ether (111762 <24%) HAP, MASS, OSHAWAC, PA, TXAIR, WHMIS REGULATORY KEY DESCRIPTIONS ---------------------------------------------------------------- All components are listed on TSCA HAP = Hazardous Air Pollutants MASS = MA Massachusetts Hazardous Substances List OSHAWAC = OSHA Workplace Air Contaminants PA = PA Right-To-Know List of Hazardous Substances TXAIR = TX Air Contaminants with Health Effects Screening Level WHMIS = Workforce Hazardous Material Information System

OTHER INFORMATION16This document is prepared in accordance with 29 CFR 1910.1200. The purpose of this section is to ensure that the hazards of all chemicals produced or imported are evaluated, and that information concerning their hazards is transmitted to employers and employees. All information appearing herein is based upon data obtained from the raw material manufacturer and/or recognized technical sources. While the information above is believed to be true and accurate, the author makes no representations as to its accuracy or sufficiency. Conditions of use are beyond the manufacturer's control; therefore the users are responsible to verify this data under their own particular conditions, applications and regulations to determine if the product is suitable for their particular purposes. The users assume all risks of product use, handling, disposal, reliance upon, publication or use of the information contained herein. This information applies only to the product designated above and does not necessarily apply to its use in combination with other materials, products, chemical compounds, structures or processes. Prepared by: EHS Manager Phone Number: [480] 899-7000



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