neraca massa

kapasitas 80000 ton/tahun dalam patii sagukapasitas kg per hari 242424.2 kg/hari pati 84.70%kapasitas kg per jam 10101.01 kg/jam air 14%basis (pati kering) 1000 kg/jam impuritis 1.30%berat pati 1180.638 kg/jam mol pati kering 6172.84 mol/jamair 165.2893 kg/jamimpuritis 15.34829 kg/jam 1. mixerberat pati 1180.638 kg/jammol pati:air #1:8mol air 49382.72 mol/jamberat air 888888.9 g/jam pati sagu 1180.638berat air total 888.8889 kg/jam komp pati 1000berat air yang ditamba 723.5996 kg/jam air 165.2893mol pati: butanol #1:8,5 impuritis 15.34829mol butanol 52469.14 mol/jamberat butanol 3882716 g/jamberat butanol 3882.716 kg/jammol pati:AL #1:6 2. butanolisismol AL 37037.04 mol/jamberat AL 6902963 g/jam pati 1000berat AL 6902.963 kg/jam air 888.8889pati:pTSA B #1:0.02326 butanol 3882.716mol pTSA B 143.5802 mol/jam impuritis 15.34829berat pTSA B 27311.83 g/jamberat pTSA B 27.31183 kg/jampati:pTSA T #1:0,0167 x=98% reaksi note: dalam reaksi harus molmol pTSA T 103.0864 mol/jam 6049.383 Pati Butanol BGberat pTSA T 19609.1 g/jam mula 6172.839506173 52469.14 -berat pTSA T 19.6091 kg/jam bereaksi 6049.382716 6049.383 6049.383mol pati:NaOH #1:0,0829 sisa 123.4567901728 46419.75 6049.383mol NaOH 511.7284 mol/jamberat NaOH 20469.14 g/jamberat NaOH 20.46914 kg/jam 3. transasetalisasi pTSAmol air:APG kasar#pela #1:1 Dodecanolberat H2O2 2% dari APG kasar

pati 20air 997.7778butanol 3435.062pTsa 27.31183BG 1592.574impuritis 15.34829

2835.951x=46,88% reaksi note: dalam reaksi harus mol

mixer1

2

reaktor butanolisis3

4

reaktor transasetalisasi

BG Dodecanol APG Butanol6049.383 37037.03703704 - -2835.951 2835.951 2835.951 2835.9513213.432 34201.08603704 2835.951 2835.951

e = 90% 4. polishing filter memisahkan pati,impuritis,

patipati 20 airair 997.7778 butanolbutanol 3644.922 pTsapTsa 46.92093 pati 18 BGBG 845.9751 impuritis 13.81346 impuritisimpuritis 15.34829 DodecanolDodecanol 6374.398 APGAPG 988.2438

5. separator memisahkan butanol dan air dengan produk atas berupa butanol 7.7% dan air 92,3%pada produk atas berupa air sebanyak kandungan air pada pati

0.105 aire= 98% butanol

butanol 3882.716 pati 2air 723.5996 air 997.7778

butanol 3644.922pTsa 46.92093

pati 1000 BG 845.9751 patiair 888.8889 impuritis 1.534829 airbutanol 3882.716 Dodecanol 6374.398 butanolimpuritis 15.34829 APG 988.2438 pTsa

pTsa 27.31183 BGimpuritisDodecanol

mol berat APGpati 123.4568 20air 6049.383 997.7778 6. tangki netralisasi NaOH 20.4691358butanol 46419.75 3435.062 Air 20.4691358pTsa 27.31183BG 6049.383 1592.574impuritis 15.34829

dalam reaksi harus mol pati 2 patiair air 19.95556 airbutanol 72.89844 butanol6049.383 pTsa 46.92093 pTsa6049.383 BG 845.9751 BG

impuritis 1.534829 impuritisDodecanol 6374.398 Dodecanol

19.6091 APG 988.2438 APG6902.963 NaOH

NaPTSx=100% reaksi note: dalam reaksi harus mol

NaOH pTSA NaPTS airmol berat m 511.7284 246.666 - -

pati 20 b 246.666 246.666 246.666 246.666air 997.7778 s 265.0624 0 246.666 246.666butanol 2835.951 3644.922pTsa 46.92093 e=98% al terdistilasi menjadi produk atas butanolBG 3213.432 845.9751 8. distilasi 1 Dodecanolimpuritis 15.34829 AirDodecanol 34201.09 6374.398 totalAPG 2835.951 988.2438

total 12933.59 kg/jam pati 2dalam reaksi harus mol air 44.86468

mixer 3

reaktor butanolisis

5

separator

tangki netralisasi

Distilasi

total umpa 13917.47 kg/jam butanol 72.89844BG 84.59751impuritis 1.534829 patiDodecanol 6374.398 airAPG 988.2438 butanolNaOH 10.6025 BG

memisahkan pati,impuritis, NaPTS 5.234746 impuritistotal 7584.375 Dodecanol

APG2 NaOH

997.7778 NaPTS3644.92246.92093845.97511.5348296374.398988.2438

Distilasi

memisahkan butanol dan air dengan produk atas berupa butanol 7.7% dan air 92,3%pada produk atas berupa air sebanyak kandungan air pada pati

977.8222 0.923 mol APG in 2835.9513572.024 0.077 9. Pelarutan air 51.04712

pati 2 pati 2air 0.897294 air 51.94441butanol 1.457969 butanol 1.457969

2 BG 84.59751 BG 84.5975119.95556 impuritis 1.534829 impuritis 1.53482972.89844 Dodecanol 127.488 Dodecanol 127.48846.92093 APG 988.2438 APG 988.2438845.9751 NaOH 10.6025 NaOH 10.60251.534829 NaPTS 5.234746 NaPTS 5.2347466374.398988.2438

0.50.5 7.penyaringan memisahkan BG dengan efisiensi 90 %

mol berat2

246.666 44.86468 pati 2 pati 272.89844 air 44.86468 air 44.86468

0 0 butanol 72.89844 butanol 72.89844845.9751 BG 845.9751 BG 761.3776 BG 84.597511.534829 impuritis 1.534829 NaPTS 47.11271 impuritis 1.5348296374.398 Dodecanol 6374.398 Dodecanol 6374.398988.2438 APG 988.2438 APG 988.2438

265.0624 10.6025 NaOH 10.6025 NaOH 10.6025246.666 52.34746 NaPTS 52.34746 NaPTS 5.234746

71.440476246.91

43.967396362.318

butanol 1.428809

tangki pelarutan

Dodecanol 124.9382e 98% distilasi 2 Air 0.879348

20.8972941.45796984.59751 pati 21.534829 air 0.897294

127.488 butanol 1.457969988.2438 BG 84.59751

10.6025 impuritis 1.534829 pati 25.234746 Dodecanol 127.488 air 0.017946

APG 988.2438 butanol 0.029159NaOH 10.6025 BG 84.59751NaPTS 5.234746 impuritis 1.534829

Dodecanol 2.549759APG 988.2438NaOH 10.6025NaPTS 5.234746

Distilasi

e=90%10. bleaching

H2O2 19.76488 0.3air 46.11805 0.7total 65.88292

pati 2air 0.017946butanol 0.029159BG 84.59751impuritis 1.534829Dodecanol 2.549759APG 988.2438 patiNaOH 10.6025 airNaPTS 5.234746 butanol

BGimpuritisDodecanolAPGNaOHNaPTS

Bleaching

kapasitas 80000 ton/tahun dalam patii sagukapasitas kg per hari 242424.24242 kg/hari pati 84.70%

kapasitas kg per jam 10101.010101 kg/jam air 14%basis (pati kering) 17795.621519 kg/jam impuritis 1.30%berat pati 21010.178889 kg/jam mol pati ke 109849.5air 2941.4250444 kg/jamimpuritis 273.13232555 kg/jamberat pati 21010.178889 kg/jammol pati:air #1:8mol air 878796.12438 mol/jamberat air 15818330.239 g/jamberat air total 15818.330239 kg/jamberat air yang ditambahkan pada butanol 12876.905194 kg/jammol pati: butanol #1:8,5 komponenmol butanol 933720.88215 mol/jamberat butanol 69095345.279 g/jamberat butanol 69095.345279 kg/jammol pati:AL #1:6mol AL 659097.09328 mol/jamberat AL 122842516.25 g/jamberat AL 122842.51625 kg/jampati:pTSA B #1:0.02326mol pTSA B 2555.0997316 mol/jamberat pTSA B 486031.07095 g/jamberat pTSA B 486.03107095 kg/jampati:pTSA T #1:0,0167 komponenmol pTSA T 1834.4869096 mol/jamberat pTSA T 348956.09995 g/jamberat pTSA T 348.95609995 kg/jammol pati:NaOH #1:0,0829mol NaOH 9106.5248389 mol/jamberat NaOH 364260.99355 g/jamberat NaOH 364.26099355 kg/jammol air:APG kasar#pelarutan #1:1berat H2O2 2% dari APG kasar

komponen

patiimpuritispTSABGtotal

mix point 6

komponen masuk9

fraksi

pati 0.000617impuritis 0.000474pTSA 0.016858BG 0.982051Dodekanol 0total 1


komponen masuk14

fraksibutanol 0pati 0.000117impuritis 8.983E-05pTSA 0.005493BG 0.186241Dodekanol 0.80806APG 0total 1

pemisahan

komponen masuk15

fraksibutanol 0.024788pati 0.000118impuritis 9.064E-05pTSA 0.005542BG 0.099823Dodekanol 0.752912APG 0.116726total 1

separator

komponen masuk16

fraksibutanol 0.027536pati 0.000131impuritis 0.000101pTSA 0.006157Dodekanol 0.836405APG 0.129671total 1

mix point 7

komponen masuk19

fraksipati 0.000135impuritis 0.000104pTSA 0.006331Dodekanol 0.860088APG 0.133342NaOH 0air 0total 1

reaktor netralisasi

komponen masuk21

fraksipati 0.000134impuritis 0.000103pTSA 0.006296Dodekanol 0.855363APG 0.13261NaOH 0.002747air 0.002747NapTS 0total 1

distliasi 1

komponen masuk keluar22 23

fraksi laju fraksipati 0.000134 17.79562 0impuritis 0.000103 13.65662 0pTSA 0.00063 83.49872 0Dodekanol 0.855363 113436.4 0.995976APG 0.13261 17586.41 0NaOH 0.001555 206.2359 0air 0.003283 435.3723 0.004024NapTS 0.006322 838.4023 0total 1 132617.8 1

distilasi 2


fraksi laju fraksipati 0.000729 17.79562 0impuritis 0.000559 13.65662 0pTSA 0.00342 83.49872 0Dodekanol 0.232282 5671.819 1APG 0.720229 17586.41 0NaOH 0.008446 206.2359 0NapTS 0.034336 838.4023 0total 1 24417.82 1

bleaching

komponen masuk26 27

fraksi laju fraksipati 0.000935 17.79562 0impuritis 0.000718 13.65662 0pTSA 0.004388 83.49872 0Dodekanol 0.014903 283.591 0APG 0.924161 17586.41 0NaOH 0.010838 206.2359 0NapTS 0.044058 838.4023 0h2o2 0 0 0.3air 0 0 0.7total 1 19029.59 1

filtrasi


fraksi laju fraksipati 0.000881 17.79562 0impuritis 0.371203 7499.058 1pTSA 0.004133 83.49872 0Dodekanol 0.014038 283.591 0APG 0.5 10101.01 0NaOH 0.010209 206.2359 0NapTS 0.041501 838.4023 0h2o2 0.040625 820.6992air 0.017411 351.7282total 1 20202.02 1

pelarutan

komponen masuk30 31

fraksi laju fraksi

pati 0.001385 17.79562 0impuritis 0.011669 149.9812 0pTSA 0.006496 83.49872 0Dodekanol 0.022064 283.591 0APG 0.785891 10101.01 0NaOH 0.016046 206.2359 0NapTS 0.06523 838.4023 0h2o2 0.063853 820.6992 0air 0.027366 351.7282 1total 1 12852.94 1

mix point 2

komponen

masuk keluar1 2 3

fraksi laju fraksi laju fraksi lajuair 1 12876.91 0 0 0.157089 12876.91

mol/jam butanol 0 0 1 69095.35 0.842911 69095.35total 1 12876.91 1 69095.35 1 81972.25

mix point 3komponen masuk keluar

3 4 5 6 Butanol fraksi laju fraksi laju fraksi laju fraksi laju Air

air 0.157089 69095.35 0.14 2941.425 0 0 0.152881 15818.33 totalbutanol 0.842911 12876.91 0 0 0 0 0.667791 69095.35pati 0 0 0.847 17795.62 0 0 0.171991 17795.62impuritis 0 0 0.013 273.1323 0 0 0.00264 273.1323 pTSApTSA 0 0 0 0 1 486.0311 0.004697 486.0311total 1 81972.25 1 21010.18 1 486.0311 1 103468.5

reaktor butanolisis separatorkomponen masuk keluar komponen masuk keluar

6 7 7 8fraksi laju fraksi laju fraksi laju fraksi laju

air 0.152881 15818.33 0.225088 17756.08 butanol 0.225088 17756.08 1 61129.06butanol 0.667791 69095.35 0.774912 61129.06 air 0.774912 61129.06 0 0pati 0.171991 17795.62 0.012094 355.9124 total 1 78885.13 1 61129.06impuritis 0.00264 273.1323 0.009281 273.1323pTSA 0.004697 486.0311 0.016516 486.0311BG 0 0 0.962108 28312.61total 1 103468.5 2 108312.8

sentrifusemasuk keluar e

7 10 11fraksi laju fraksi laju fraksi laju

0.012094 355.9124 0.565798 338.1168 0.000617 17.795620.009281 273.1323 0.434202 259.4757 0.000474 13.656620.016516 486.0311 0 0 0.016858 486.03110.962108 28312.61 0 0 0.982051 28312.61

1 29427.69 1 597.5925 1 28830.1

mix point 6

masuk keluar9 10 11 12laju fraksi laju fraksi laju fraksi laju

17.79562 0 0 0 0 0.000117 17.7956213.65662 0 0 0 0 8.983E-05 13.65662486.0311 1 348.9561 0 0 0.005493 834.987228312.61 0 0 0 0 0.186241 28312.61

0 0 0 1 122842.5 0.80806 122842.528830.1 1 348.9561 1 122842.5 1 152021.6


masuk keluar14 15

laju fraksi laju0 0.024788 3734.595

17.79562 0.000118 17.7956213.65662 9.064E-05 13.65662834.9872 0.005542 834.987228312.61 0.099823 15039.66122842.5 0.752912 113436.4

0 0.116726 17586.41152021.6 1 150663.5

pemisahan

masuk keluar15 16 17

laju fraksi laju fraksi laju3734.595 0.027536 3734.595 0 017.79562 0.000131 17.79562 0 013.65662 0.000101 13.65662 0 0834.9872 0.006157 834.9872 0 015039.66 0 0 1 15039.66113436.4 0.836405 113436.4 0 017586.41 0.129671 17586.41 0 0150663.5 1 135623.8 1 15039.66

masuk keluar16 18 19

laju fraksi laju fraksi laju3734.595 1 3734.595 0 0 butanol17.79562 0 0 0.000135 17.79562 pati13.65662 0 0 0.000104 13.65662 impuritis834.9872 0 0 0.006331 834.9872 pTSA113436.4 0 0 0.860088 113436.4 Dodekanol17586.41 0 0 0.133342 17586.41 APG135623.8 1 3734.595 1 131889.2 total

masuk keluar pati19 20 21 impuritis

laju fraksi laju fraksi laju pTSA17.79562 0 0 0.000134 17.79562 Dodekanol13.65662 0 0 0.000103 13.65662 APG834.9872 0 0 0.006296 834.9872 total113436.4 0 NaOH 0.855363 113436.417586.41 0 0 0.13261 17586.41

0 0.5 364.261 0.002747 364.2610 0.5 364.261 0.002747 364.261

131889.2 1 728.522 1 132617.8

masuk keluar21 22 pati

laju fraksi laju impuritis17.79562 0.000134 17.79562 pTSA13.65662 0.000103 13.65662 751.4885 Dodekanol834.9872 0.00063 83.49872 14.57044 APG113436.4 0.855363 113436.4 NaOH17586.41 0.13261 17586.41 air

364.261 0.001555 206.2359 total364.261 0.003283 435.3723

0 0.006322 838.4023 reaksi132617.8 1 132617.8 pTSA

4389.5873950.628438.958783.49872

keluar23 24

laju fraksi laju0 0.000729 17.79562 fraksi laju0 0.000559 13.65662 pati 0.000134 17.795620 0.00342 83.49872 impuritis 0.000103 13.65662

107764.6 0.232282 5671.819 pTSA 0.00063 83.498720 0.720229 17586.41 Dodekanol 0.855363 113436.40 0.008446 206.2359 APG 0.13261 17586.41

435.3723 0 0 NaOH 0.001555 206.23590 0.034336 838.4023 air 0.003283 435.3723

108199.9 1 24417.82 NapTS 0.006322 838.4023total 1 132617.8

24417.82

keluar25 26

laju fraksi laju0 0.000935 17.795620 0.000718 13.656620 0.004388 83.49872 fraksi laju

5388.228 0.014903 283.591 pati 0.000729 17.795620 0.924161 17586.41 impuritis 0.000559 13.656620 0.010838 206.2359 pTSA 0.00342 83.498720 0.044058 838.4023 Dodekanol 0.232282 5671.819

5388.228 1 19029.59 APG 0.720229 17586.41NaOH 0.008446 206.2359NapTS 0.034336 838.4023

22

24

total 1 24417.82

masuk keluar27 28

laju fraksi laju0 0.000881 17.795620 0.371203 7499.0580 0.004133 83.498720 0.014038 283.5910 0.5 10101.010 0.010209 206.23590 0.041501 838.4023 fraksi laju

351.7282 0.040625 820.6992 pati 0.000935 17.79562820.6992 0.017411 351.7282 impuritis 0.000718 13.656621172.427 1 20202.02 pTSA 0.004388 83.49872

Dodekanol 0.014903 283.591APG 0.924161 17586.41NaOH 0.010838 206.2359NapTS 0.044058 838.4023total 1 19029.59

keluar e 98%29 30

laju fraksi laju fraksi laju0 0.001385 17.79562 pati 0.000881 17.79562

7349.077 0.011669 149.9812 impuritis 0.371203 7499.0580 0.006496 83.49872 pTSA 0.004133 83.498720 0.022064 283.591 Dodekanol 0.014038 283.5910 0.785891 10101.01 APG 0.5 10101.01 impuritis0 0.016046 206.2359 NaOH 0.010209 206.23590 0.06523 838.4023 NapTS 0.041501 838.4023

0.063853 820.6992 h2o2 0.040625 820.69920.027366 351.7282 air 0.017411 351.7282

7349.077 1 12852.94 total 1 20202.02

masuk keluar31 32 laju air 72% APG

laju fraksi laju

26

28

29

30

0 0.000884 17.79562 fraksi laju0 0.007452 149.9812 pati 0.001385 17.795620 0.004149 83.49872 impuritis 0.011669 149.98120 0.014091 283.591 pTSA 0.006496 83.498720 0.501897 10101.01 Dodekanol 0.022064 283.5910 0.010247 206.2359 APG 0.785891 10101.010 0.041658 838.4023 NaOH 0.016046 206.23590 0.040779 820.6992 NapTS 0.06523 838.4023

7272.727 0.378842 7624.455 h2o2 0.063853 820.69927272.727 1 20125.67 air 0.027366 351.7282

total 1 12852.94

fraksi 1 fraksi 1

air 12876.91 butanol 69095.35

berat fraksibutanol 69095.35 0.842911air 12876.91 0.157089total 81972.25 1

fraksi berat fraksi berat0.842911 69095.35 Pati 0.847 17795.620.157089 12876.91 Air 0.14 2941.425

1 81972.25 0.013 273.1323total 1 21010.18

fraksi berat1 486.0311 laju fraksi

air 15818.33 0.152881butanol 69095.35 0.667791pati 17795.62 0.171991

273.1323 0.00264 air 0.225088pTSA 486.0311 0.004697 butanol 0.774912

keluar total 103468.5 1 total 19

fraksi laju fraksi laju0 0 air 0.152881 15818.331 17756.08 butanol 0.667791 69095.35 pati1 17756.08 pati 0.171991 17795.62 impuritis

impuritis 0.00264 273.1323 pTSApTSA 0.004697 486.0311 BGtotal 1 103468.5 total

reaksi x=98 %pati butanol BG air

m 109849.5 933720.9 0 0b 107652.5 107652.5 107652.5 107652.5s 2196.99 826068.4 107652.5 107652.5 mol

355.9124 61129.06 28312.61 1937.745 kg/jam

95%fraksi laju

fraksi laju

1

3

2

6

5

4

3

6 7

7 11

10

pati 0.012094 355.9124impuritis 0.009281 273.1323pTSA 0.016516 486.0311 fraksi laju pati 0.000617 17.79562BG 0.962108 28312.61 pati 0.565798 338.1168 impuritis 0.000474 13.65662total 1 29427.69 impuritis 0.434202 259.4757 pTSA 0.016858 486.0311

total 1 597.5925 BG 0.982051 28312.61total 1 28830.1

fraksi lajupTSA 1 348.9561 fraksi laju

Dodekanol 1 122842.5

fraksi laju

pati 0.000617 17.79562impuritis 0.000474 13.65662pTSA 0.016858 486.0311BG 0.982051 28312.61 fraksi lajutotal 1 28830.1

pati 0.000117 17.79562impuritis 8.983E-05 13.65662pTSA 0.005493 834.9872BG 0.186241 28312.61Dodekanol 0.80806 122842.5total 1 152021.6

fraksi laju fraksi laju

butanol 0.024788 3734.595pati 0.000117 17.79562 pati 0.000118 17.79562impuritis 8.983E-05 13.65662 impuritis 9.064E-05 13.65662pTSA 0.005493 834.9872 pTSA 0.005542 834.9872BG 0.186241 28312.61 BG 0.099823 15039.66Dodekanol 0.80806 122842.5 Dodekanol 0.752912 113436.4total 1 152021.6 APG 0.116726 17586.41

total 1 150663.5reaksi x 46.88%BG Dodecanol APG Butanol107652.5 659097.1 0 0

50467.5 50467.5 50467.5 50467.557185.02 608629.6 50467.5 50467.5 mol15039.66 113436.4 17586.41 3734.595 kg/jam

10

11

12

14

13

1514

e 100%

fraksi laju fraksi lajubutanol 0.024788 3734.595 butanol 0.027536 3734.595pati 0.000118 17.79562 pati 0.000131 17.79562impuritis 9.064E-05 13.65662 impuritis 0.000101 13.65662pTSA 0.005542 834.9872 BG 1 15039.66 pTSA 0.006157 834.9872BG 0.099823 15039.66 Dodekanol 0.836405 113436.4Dodekanol 0.752912 113436.4 APG 0.129671 17586.41APG 0.116726 17586.41 total 1 135623.8total 1 150663.5

fraksi lajuButanol 1 3734.595

fraksi laju0.027536 3734.5950.000131 17.79562 fraksi laju0.000101 13.65662 pati 0.000135 17.795620.006157 834.9872 impuritis 0.000104 13.656620.836405 113436.4 pTSA 0.006331 834.98720.129671 17586.41 Dodekanol 0.860088 113436.4

1 135623.8 APG 0.133342 17586.41total 1 131889.2

fraksi laju fraksi laju tangki berpengaduk 0.000135 17.79562 NaOH 0.5 364.2610.000104 13.65662 air 0.5 364.2610.006331 834.9872 total 1 728.5220.860088 113436.40.133342 17586.41

1 131889.2 fraksiNaOH 1

fraksi lajupati 0.000134 17.79562impuritis 0.000103 13.65662pTSA 0.006296 834.9872Dodekanol 0.855363 113436.4APG 0.13261 17586.41NaOH 0.002747 364.261air 0.002747 364.261total 1 132617.8

fraksi laju0.000134 17.79562

15 16

17

16

19

18

2019

21

2221

0.000103 13.65662 fraksi laju0.006296 834.9872 pati 0.000134 17.795620.855363 113436.4 impuritis 0.000103 13.65662

0.13261 17586.41 pTSA 0.00063 83.498720.002747 364.261 Dodekanol 0.855363 113436.40.002747 364.261 APG 0.13261 17586.41

1 132617.8 NaOH 0.001555 206.2359air 0.003283 435.3723

x 90% NapTS 0.006322 838.4023NaOH NapTS air total 1 132617.89106.525 0 03950.628 3950.628 3950.6285155.897 3950.628 3950.628 mol206.2359 838.4023 71.1113 kg/jam

fraksi lajudodecanol 0.995976 107764.6air 0.004024 435.3723total 1 108199.9

fraksi lajupati 0.000729 17.79562impuritis 0.000559 13.65662pTSA 0.00342 83.49872Dodekanol 0.232282 5671.819APG 0.720229 17586.41NaOH 0.008446 206.2359NapTS 0.034336 838.4023total 1 24417.82

fraksi lajudodecanol 1 5388.228

fraksi lajupati 0.000935 17.79562impuritis 0.000718 13.65662pTSA 0.004388 83.49872

22

24

23

26

25

Dodekanol 0.014903 283.591APG 0.924161 17586.41NaOH 0.010838 206.2359NapTS 0.044058 838.4023total 1 19029.59

fraksi lajuh2o2 0.3 351.7282air 0.7 820.6992total 1 1172.427

fraksi lajupati 0.000881 17.79562impuritis 0.000676 13.65662impuritis 2 0.370527 7485.402pTSA 0.004133 83.49872Dodekanol 0.014038 283.591APG 0.5 10101.01NaOH 0.010209 206.2359NapTS 0.041501 838.4023air 0.040625 820.6992h2o2 0.017411 351.7282

1 20202.02

fraksi lajupati 0.001385 17.79562impuritis 0.011669 149.9812pTSA 0.006496 83.49872Dodekanol 0.022064 283.591

fraksi laju APG 0.785891 10101.011 7349.077 NaOH 0.016046 206.2359

NapTS 0.06523 838.4023h2o2 0.063853 820.6992air 0.027366 351.7282total 1 12852.94

fraksi lajuair 1 7272.727

28

27

30

29

31

fraksi lajupati 0.000884 17.79562impuritis 0.007452 149.9812pTSA 0.004149 83.49872Dodekanol 0.014091 283.591 1000 567.6121APG 0.501897 10101.01 17795.62 10101.01NaOH 0.010247 206.2359NapTS 0.041658 838.4023h2o2 0.040779 820.6992air 0.378842 7624.455total 1 20125.67

32

pati 0.0032859676 355.9124impuritis 0.0025216989 273.1323pTSA 0.0044872902 486.0311BG 0.2613966941 28312.61air 0.1639332724 17756.08butanol 0.5643750769 61129.06

17756.08 total 1 108312.861129.0678885.13 butanol

fraksi laju separator

0.012094 355.9124 fraksi laju0.009281 273.1323 air 0.225088 17756.080.016516 486.0311 butanol 0.774912 61129.060.962108 28312.61 total 1 78885.13

1 29427.69 air

7989.9717439.71

7

9

8

tangki berpengaduk fraksi lajuAir 1 364.261

laju364.261 fraksi laju

NaOH 0.5 364.261Air 0.5 364.261

728.522komponen masuk keluar

33 35 35fraksi laju fraksi laju fraksi laju

NaOH 1 364.261 0 0 0.5 364.261air 0 0 1 364.261 0.5 364.261total 1 364.261 1 364.261 1 728.522

33 35

34

fraksi laju1 61129.06

fraksi laju1 17756.08

inline mixer

Butanol30

butanolair air

35 T

t ref 2981 1 butanol 69095.3452792 kg/jam

suhu 328 K airintegrl Cp 31156.1868451 j/kg k butanolQ but 2152747.48765 KJ/jam

2 1 air 12876.9051944 kg/jamsuhu 308 Kintegrl Cp 8871.33507057 j/kg kQ air 114235.340651 KJ/jamQin 2266982.8283 Kj/jam

3 Qout butanol 0.8429114106air 0.1570885894laju 81972.250474 kg/jamsuhu 327.18386618 K goal seekintegrl Cp dt 73148.274206 j/kg KQout 2266982.828 kj/jam

stirred tankQin 3 butanol

airlajusuhucpQin

4 patiairimpuritislajusuhucpQin

5 pTSAlajusuhucpQin

Qin 2579370.066

36

5

4 Stirred Tank

Qout 6 butanolairpatipTSAimpuritislajusuhuCp

heater Qout3 bar

133.5 steam 133.5Qin 6 butanol

airpatipTSA

6 7 lajusuhuCpQin

Qout 7 butanolairpatipTSAlajusuhuCpQoutQout-Qin

butanolisis

7 8 Qin 7 butanolairpatipTSA

delta standar -9572.448 kj/kg lajusuhu

delta H pembentukan Cpbutanol -3708.514 qinpati -1083.691 Qout 8 butanolBG -931.3194 airair -13433.33 pati

ptsar 107652.5 mol/jam BG

impuritislajusuhu

Cpqoutqout-qindQ/dT

92,053-3,9953*10^-2*E11-2,1103*10^-4*E11^2+5,3469*10^-7*E11^3)*1000/1883,877+5,6628*10^-1*E17-1,7208*10^-3*E17^2+2,278*10^-6*E17^3)*1000/74

E24*(F23*(92,053-3,9953*10^-2*E25-2,1103*10^-4*E25^2+5,3469*10^-7*E25^3)*1000/18+F22*(83,877+5,6628*10^-1*E25-1,7208*10^-3*E25^2+2,278*10^-6*E25^3)*1000/74)*(E25-298)/1000

a b0.8429114106 pati OH 5 13 -10.1450.1570885894 O 1 5.0312 -1.571881972.250474 kg/jam CH 7 2.2209 -1.435327.18386618 K 85.3375 -62.341873148.274206 j/kgK Cp 2657.6409 j/mol K

2266982.828 Kj/jam 16405.191 J/kg K0.847 Cp air 4335.4914 J/kg K

0.14 Cp impuritis 0 J/kg K0.013 a b

21010.178889 kg/jam pTSA CH3 1 3.8452 -0.33997303 K CH 4 4.0749 -1.0735

14502.165275 j/kgK C 2 1.957 -0.31938304693.08671 Kj/jam S 1 -1.643 2.307

1 OH 1 13 -10.145486.03107095 kg/jam O 2 5.0312 -1.5718

308 45.4302 -16.2543315830.574876 J/kg K cp 15830.574876 J/Kg K7694.1512606 Kj/jam a b

dodecyl gl CH3 1 3.8452 -0.33997

0.6677913732 CH2 11 2.7972 -0.0549670.1528806959 CH 6 4.0749 -1.07350.1719907829 OH 4 13 -10.1450.0046973838 O 2 5.0312 -1.57180.0026397641 120.9342 -51.10921103468.46043 kg/jam cp

313.5321608 K24929.046585 j/kg K2579370.0702 Kj/jam

0.6677913732 impuritis 0.00264 steam asumsi panas laten0.15288069590.1719907829 m 12401.6651 kg/jam0.0046973838103468.46043 kg/jam

313.5321608 K24929.046585 j/kg K2579370.0702 Kj/jam0.6677913732 impuritis 0.002640.15288069590.17199078290.0046973838103468.46043 kg/jam

413 K284229.8241 j/kg K

29408822.308 Kj/jam26829452.238 Kj/jam

0.6677913732 impuritis 0.002640.15288069590.17199078290.0046973838103468.46043 kg/jam

413 K284229.8241 j/kg K

29408822.308 Kj/jam0.5643750769

cp

265497.40.1639332724 482988.60.0032859676 578167.70.0044872902 217331.20.2613966941 294398.80.0025216989 0108312.82407 kg/jam

413 K

308847.99484 j/kg K33452198.529 Kj/jam4043376.2208

E24*(F23*(92,053-3,9953*10^-2*E25-2,1103*10^-4*E25^2+5,3469*10^-7*E25^3)*1000/18+F22*(83,877+5,6628*10^-1*E25-1,7208*10^-3*E25^2+2,278*10^-6*E25^3)*1000/74)*(E25-298)/1000

d2.62610.3786 a b d

0.69508 BG CH3 1 3.8452 -0.33997 0.1948918.37466 CH2 2 2.7972 -0.054967 0.10679

CH 6 4.0749 -1.0735 0.21413OH 4 13 -10.145 2.6261O 2 5.0312 -1.5718 0.3786

95.7594 -50.6145 12.95485d R cp 294398.84295

0.19489 8.31450.214130.11911 R39*(O45*(I45-B9)+P45*(I45^2-B9^2)/200+Q45*(I45^3-B9^3)/(3*100^2))*1000/190,22

-0.31234 Z32*(W37*(I96-B9)+X37*(I96^2-B9^2)/200+Y37*(I96^3-B9^3)/(3*100^2))*1000/2632.62610.3786

4.36059

d R0.19489 8.3145

0.106790.21413

2.62610.3786

13.91596

R8.3145

R39*(O45*(I45-B9)+P45*(I45^2-B9^2)/200+Q45*(I45^3-B9^3)/(3*100^2))*1000/190,22Z32*(W37*(I96-B9)+X37*(I96^2-B9^2)/200+Y37*(I96^3-B9^3)/(3*100^2))*1000/263

T Tpati 0.012126 379.64 140impuritis 0.006676 209.0108Ptsa 0.01656 518.4332bg 0.964638 30200.13total 1 31307.21

HE-102

pati 0.012126 379.64impuritis 0.006676 209.0108Ptsa 0.01656 518.4332bg 0.964638 30200.13total 1 31307.21

HE-103298

Tpati 0.000117 18.982 70impuritis 6.445E-05 10.45054 343pTSA 0.005493 890.6532BG 0.186245 30200.13Dodekanol 0.80808 131032total 1 162152.3

KomponenCp masuk Cp Keluar Laju Alir Q masuk Qkeluar Qsteampati 172265.1 61631.49 18.982 3269935.2624 1169888.9108impuritis 0 0 10.45054 0 0pTSA 75138.81 151970.7 890.6532 66922620.549 135353157BG 95076.09 199916.2 30200.13 2871310120 6037495968Dodekanol 1.22E+05 234812 131032 15974616849 30767895022

18916119524 36941914036 18025794512

Massa Steam

HE-104T 298

pati 0.000135 18.982 120impuritis 7.429E-05 10.4505401 393pTSA 0.006331 890.65315653

HE-103

HE-104

Dodekanol 0.860113 120998.83208APG 0.133346 18758.842134total 1 140677.75991

KomponenCp masuk Cp Keluar Laju Alir Q masuk Qkeluar Qsteampati 172265.1impuritis 0pTSADodekanolAPG

HE-104

HE-103

T110 pati 0.000117 18.982383 impuritis 6.445E-05 10.45054

pTSA 0.005493 890.6532BG 0.186245 30200.13Dodekanol 0.80808 131032total 1 162152.3

a b d RPATI OH 5 13 -10.145 2.6261 8.3145

O 1 5.0312 -1.5718 0.3786CH 7 2.2209 -1.435 0.69508

85.3375 -62.3418 18.37466Cp 172265.1

a b d RpTSA CH3 1 3.8452 -0.33997 0.19489 8.3145

CH 4 4.0749 -1.0735 0.21413C 2 1.957 -0.31938 0.11911S 1 -1.643 2.307 -0.31234OH 1 13 -10.145 2.6261O 2 5.0312 -1.5718 0.3786

45.4302 -16.25433 4.36059cp 75138.81 J/Kg K

a b d RBG CH3 1 3.8452 -0.33997 0.19489 8.3145

CH2 2 2.7972 -0.054967 0.10679CH 6 4.0749 -1.0735 0.21413OH 4 13 -10.145 2.6261O 2 5.0312 -1.5718 0.3786

95.7594 -50.614504 12.95485cp 95076.09

DodekanolA B C D91.986 2.63 -0.005946 5.50E-06

cp 1.22E+05HE-104

T90 pati 0.000135 18.982

363 impuritis 7.429E-05 10.4505401pTSA 0.006331 890.65315653

HE-104

Dodekanol 0.860113 120998.83208APG 0.133346 18758.842134total 1 140677.75991

HE-104

HE-103

neraca massa

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