Post on 24-Mar-2023
Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG)Technische Schoolstraat 43 A, B-2440 Geelhttp://www.big.be© BIG vzw
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
1 / 12
13
4-1
62
39
-66
9-e
n
Product number: 39806
SAFETY DATA SHEETBased upon Regulation (EC) No 1907/2006, as amended by Regulation (EU) No 2015/830
NOVACARE SHAMP-WAX
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifierProduct name NOVACARE SHAMP-WAX:Registration number REACH Not applicable (mixture):Product type REACH Mixture:
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1 Relevant identified uses
Detergent according to Regulation (EC) No 648/2004
1.2.2 Uses advised against
No uses advised against known
1.3. Details of the supplier of the safety data sheet
Supplier of the safety data sheet
Manufacturer of the product
1.4. Emergency telephone number24h/24h (Telephone advice: English, French, German, Dutch) :
SECTION 2: Hazards identification
2.1. Classification of the substance or mixtureClassified as dangerous according to the criteria of Regulation (EC) No 1272/2008Class Category Hazard statements
Eye Dam. category 1 H318: Causes serious eye damage.
Skin Irrit. category 2 H315: Causes skin irritation.
Aquatic Chronic category 3 H412: Harmful to aquatic life with long lasting effects.
2.2. Label elements
Contains: isotridecanol, ethoxylated.
Signal word DangerH-statements
Causes serious eye damage.H318Causes skin irrita on.H315Harmful to aqua c life with long las ng effects.H412
P-statementsWear protec ve gloves, protec ve clothing and eye protec on/face protec on.P280Wash hands thoroughly a er handling.P264Avoid release to the environment.P273IF ON SKIN: Wash with plenty of water and soap.P302 + P352IF IN EYES: Rinse cau ously with water for several minutes. Remove contact lenses, if present and easy to do.Con nue rinsing.
P305 + P351 + P338
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
2 / 12Product number: 39806
Immediately call a POISON CENTER/doctor.P310
2.3. Other hazardsNo other hazards known
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Conc. (C) Classification according to CLPNameREACH Registration No
Note RemarkCAS NoEC No
C≤10%69011-36-5 Acute Tox. 4; H302Eye Dam. 1; H318
(1)(10) Constituentisotridecanol, ethoxylated
C≤3%95-38-5202-414-9
Acute Tox. 4; H302STOT RE 2; H373Skin Corr. 1C; H314Eye Dam. 1; H318Aquatic Acute 1; H400Aquatic Chronic 1; H410
(1)(9)(10) Constituent2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
(1) For H-statements in full: see heading 16(9) M-factor, see heading 16(10) Subject to restrictions of Annex XVII of Regulation (EC) No. 1907/2006
SECTION 4: First aid measures
4.1. Description of first aid measuresGeneral:
Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: performresuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: preventasphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victimcalm, avoid physical strain. Depending on the victim's condition: doctor/hospital.
After inhalation:Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
After skin contact:Wash immediately with lots of water. Soap may be used. Do not apply (chemical) neutralizing agents without medical advice. Take victim to a doctor ifirritation persists.
After eye contact:Rinse immediately with plenty of water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Do not apply (chemical)neutralizing agents without medical advice. Take victim to an ophthalmologist.
After ingestion:Rinse mouth with water. Do not apply (chemical) neutralizing agents without medical advice. Consult a doctor/medical service if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed4.2.1 Acute symptoms
After inhalation:No effects known.After skin contact:Tingling/irritation of the skin.After eye contact:Corrosion of the eye tissue.After ingestion:Headache. Vomiting. Gastrointestinal complaints. Diarrhoea. Drowsiness.
4.2.2 Delayed symptomsNo effects known.
4.3. Indication of any immediate medical attention and special treatment neededIf applicable and available it will be listed below.
SECTION 5: Firefighting measures
5.1. Extinguishing media5.1.1 Suitable extinguishing media:
Small fire: Quick-acting ABC powder extinguisher, Quick-acting BC powder extinguisher, Quick-acting class B foam extinguisher, Quick-acting CO2 extinguisher.
Major fire: Class B foam (not alcohol-resistant).5.1.2 Unsuitable extinguishing media:
Small fire: Water (quick-acting extinguisher, reel); risk of puddle expansion.
Major fire: Water; risk of puddle expansion.
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
3 / 12Product number: 39806
5.2. Special hazards arising from the substance or mixtureUpon combustion: formation of CO, CO2 and small quantities of nitrous vapours.
5.3. Advice for firefighters5.3.1 Instructions:
Take account of environmentally hazardous firefighting water. Use water moderately and if possible collect or contain it.
5.3.2 Special protective equipment for fire-fighters:Gloves (EN 374). Face shield (EN 166). Protective clothing (EN 14605 or EN 13034). Heat/fire exposure: compressed air apparatus (EN 136 + EN 137).
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency proceduresNo naked flames.6.1.1 Protective equipment for non-emergency personnel
See heading 8.26.1.2 Protective equipment for emergency responders
Gloves (EN 374). Face shield (EN 166). Protective clothing (EN 14605 or EN 13034).
Suitable protective clothingSee heading 8.2
6.2. Environmental precautionsContain released product. Dam up the liquid spill. Prevent soil and water pollution. Prevent spreading in sewers.
6.3. Methods and material for containment and cleaning upTake up liquid spill into absorbent material, e.g.: sand, saw dust. Scoop absorbed substance into closing containers. Carefully collect the spill/leftovers. Cleancontaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling.
6.4. Reference to other sectionsSee heading 13.
SECTION 7: Handling and storageThe information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposurescenarios that correspond to your identified use.
7.1. Precautions for safe handlingKeep away from naked flames/heat. Observe normal hygiene standards. Keep container tightly closed. Do not discharge the waste into the drain.
7.2. Conditions for safe storage, including any incompatibilities7.2.1 Safe storage requirements:
Storage temperature: < 50 °C. Keep container in a well-ven lated place. Protect against frost. Keep out of direct sunlight. Meet the legalrequirements.
7.2.2 Keep away from:Heat sources.
7.2.3 Suitable packaging material:No data available
7.2.4 Non suitable packaging material:No data available
7.3. Specific end use(s)If applicable and available, exposure scenarios are attached in annex. See information supplied by the manufacturer.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters8.1.1 Occupational exposure
a) Occupational exposure limit valuesIf limit values are applicable and available these will be listed below.
b) National biological limit valuesIf limit values are applicable and available these will be listed below.
8.1.2 Sampling methodsIf applicable and available it will be listed below.
8.1.3 Applicable limit values when using the substance or mixture as intendedIf limit values are applicable and available these will be listed below.
8.1.4 Threshold valuesDNEL/DMEL - Workers2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
ValueEffect level (DNEL/DMEL) Type Remark
0.46 mg/m³DNEL Long-term systemic effects inhalation
14 mg/m³Acute systemic effects inhalation
0.06 mg/kg bw/dayLong-term systemic effects dermal
2 mg/kg bw/dayAcute systemic effects dermal
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
4 / 12Product number: 39806
PNEC2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
ValueCompartments Remark
< 0.01 mg/lFresh water
< 0.01 mg/lMarine water
< 0.01 mg/lFresh water (intermittent releases)
0.27 mg/lSTP
0.376 mg/kg sediment dwFresh water sediment
0.038 mg/kg sediment dwMarine water sediment
0.075 mg/kg soil dwSoil
8.1.5 Control bandingIf applicable and available it will be listed below.
8.2. Exposure controlsThe information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposurescenarios that correspond to your identified use.8.2.1 Appropriate engineering controls
Keep away from naked flames/heat. Carry operations in the open/under local exhaust/ventilation or with respiratory protection.8.2.2 Individual protection measures, such as personal protective equipment
Observe normal hygiene standards. Do not eat, drink or smoke during work.a) Respiratory protection:
Respiratory protection not required in normal conditions. Insufficient ventilation: wear respiratory protection.b) Hand protection:
Protective gloves against chemicals (EN 374).Materials Measured
breakthrough timeRemark Protection index
nitrile rubber > 480 minutes 0.35 mm Class 6
c) Eye protection:Protective goggles (EN 166).
d) Skin protection:Head/neck protection. Protective clothing (EN 14605 or EN 13034).
8.2.3 Environmental exposure controls:See headings 6.2, 6.3 and 13
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical propertiesPhysical form Liquid
Odour Characteristic odour
Odour threshold No data available in the literature
Colour Variable in colour, depending on the composition
Particle size Not applicable (liquid)
Explosion limits No data available in the literature
Flammability Not classified as flammable
Log Kow Not applicable (mixture)
Dynamic viscosity 40 mPa.s ; 20 °C
Kinematic viscosity 40 mm²/s ; 40 °C
Melting point 0 °C
Boiling point 78 °C - 233 °C
Evaporation rate 0.3 ; Butyl acetate
Relative vapour density No data available in the literature
Vapour pressure 23 hPa ; 20 °C
Solubility Water ; insoluble
Relative density 1.0 ; 20 °C
Decomposition temperature No data available in the literature
Auto-ignition temperature 200 °C
Flash point No data available in the literature
Explosive properties No chemical group associated with explosive properties
Oxidising properties No chemical group associated with oxidising properties
pH 6.0
9.2. Other information1004 kg/m³ ; 20 °CAbsolute density
SECTION 10: Stability and reactivity
10.1. ReactivityHeating increases the fire hazard. Acid reaction.
10.2. Chemical stabilityStable under normal conditions.
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
5 / 12Product number: 39806
10.3. Possibility of hazardous reactionsNo data available.
10.4. Conditions to avoidPrecautionary measures
Keep away from naked flames/heat.
10.5. Incompatible materialsNo data available.
10.6. Hazardous decomposition productsUpon combustion: formation of CO, CO2 and small quantities of nitrous vapours.
SECTION 11: Toxicological information
11.1. Information on toxicological effects11.1.1 Test results
Acute toxicity
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Judgement is based on the relevant ingredientsisotridecanol, ethoxylated
Route of exposure Parameter Method Value Exposure time Species Valuedetermination
Remark
category 4 Literature studyOral2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Route of exposure Parameter Method Value Exposure time Species Valuedetermination
Remark
LD50 OECD 401 1265 mg/kg Rat (male /female)
Experimental valueOral
Data waivingDermal
Data waivingInhalation
ConclusionNot classified for acute toxicity
Corrosion/irritation
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Classification is based on the relevant ingredientsisotridecanol, ethoxylated
Result Method Exposure time Time point Species Valuedetermination
Route of exposure Remark
Serious eyedamage;category 1
Literature studyEye
2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Result Method Exposure time Time point Species Valuedetermination
Route of exposure Remark
Serious eyedamage
Equivalent toOECD 405
Rabbit Experimentalvalue
Eye 24; 72 hours Single treatment
Corrosive OECD 404 4 h Rabbit Experimentalvalue
Skin 1; 24 hours
ConclusionCauses skin irritation.Causes serious eye damage.Not classified as irritating to the respiratory system
Respiratory or skin sensitisation
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Judgement is based on the relevant ingredients2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Result Method Exposure time Observation timepoint
Species Value determinationRoute of exposure Remark
Not sensitizing Equivalent to OECD406
Guinea pig (male/ female)
Experimental valueSkin 24 hours
ConclusionNot classified as sensitizing for skin
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
6 / 12Product number: 39806
Not classified as sensitizing for inhalation
Specific target organ toxicity
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Judgement is based on the relevant ingredients2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Parameter Method Value Organ Effect Exposure timeRoute of exposure Species Valuedetermination
NOAEL OECD 422 20 mg/kgbw/day
No effect 31 day(s) - 51 day(s) Rat (male /female)
Experimentalvalue
Oral (stomachtube)
Dose level OECD 422 100 mg/kgbw/day
Mortality;body weight;foodconsumption
31 day(s) - 51 day(s) Rat (male /female)
Experimentalvalue
Oral (stomachtube)
Gastrointestinal tract;thymus
ConclusionNot classified for subchronic toxicity
Mutagenicity (in vitro)
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Judgement is based on the relevant ingredients2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Method Test substrate Effect Value determinationResult Remark
Negative with metabolicactivation, negativewithout metabolicactivation
OECD 471 Bacteria (S.typhimurium) Experimental value
Negative with metabolicactivation, negativewithout metabolicactivation
OECD 476 Chinese hamster ovary(CHO)
Experimental value
Mutagenicity (in vivo)
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Judgement is based on the relevant ingredients
Conclusion
Not classified for mutagenic or genotoxic toxicity
Carcinogenicity
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Judgement is based on the relevant ingredients
Conclusion
Not classified for carcinogenicity
Reproductive toxicity
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Judgement is based on the relevant ingredients2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Method Value Exposure time Species Effect OrganParameter Valuedetermination
NOEC OECD 422 > 60 mg/kgbw/day
Rat (male /female)
No effectDevelopmental toxicity (Oral (stomach tube))
Experimentalvalue
NOAEL OECD 422 > 20 mg/kgbw/day
Rat (male /female)
No effect51 day(s)Maternal toxicity (Oral(stomach tube))
Experimentalvalue
NOAEL (P) OECD 422 > 20 mg/kgbw/day
Rat (male /female)
No effect31 day(s) - 51 day(s)Effects on fertility (Oral (stomach tube))
Experimentalvalue
NOAEL (F1) OECD 422 > 60 mg/kgbw/day
Rat (male /female)
No effect31 week(s) - 51week(s)
Experimentalvalue
ConclusionNot classified for reprotoxic or developmental toxicity
Toxicity other effects
NOVACARE SHAMP-WAX
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
7 / 12Product number: 39806
No (test)data on the mixture available
Chronic effects from short and long-term exposure
NOVACARE SHAMP-WAX
No effects known.
SECTION 12: Ecological information
12.1. Toxicity
NOVACARE SHAMP-WAX
No (test)data on the mixture available
Classification is based on the relevant ingredients2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Parameter Method Value Duration Species Test design Fresh/saltwater
Value determination
Acute toxicity fishes LC50 OECD 203 0.3 mg/l Danio rerio Static system Fresh water96 h Experimental value;Nominalconcentration
Acute toxicity crustacea EC50 OECD 202 0.163 mg/l Daphnia magna Semi-staticsystem
Fresh water48 h Experimental value;GLP
Toxicity algae and otheraquatic plants
ErC50 OECD 201 0.03 mg/l Desmodesmussubspicatus
Static system Fresh water72 h Experimental value;GLP
Long-term toxicity fish Data waiving
Long-term toxicity aquaticcrustacea
Data waiving
Toxicity aquatic micro-organisms
EC50 26 mg/l Bacteria Literature study;Acute
IC50 OECD 209 26 mg/l Activated sludge Static system Fresh water180 minutes Experimental value;Nominalconcentration
ConclusionHarmful to aquatic life with long lasting effects.
12.2. Persistence and degradabilityisotridecanol, ethoxylated
Biodegradation waterDurationMethod Value Value determination
28 day(s)OECD 301B: CO2 Evolution Test 82 % Experimental value2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Biodegradation waterDurationMethod Value Value determination
28 day(s)OECD 301B: CO2 Evolution Test 1 % Experimental value
Conclusion
The surfactant(s) is/are biodegradable according to Regulation (EC) No 648/2004
12.3. Bioaccumulative potentialNOVACARE SHAMP-WAX
Log Kow
Temperature Value determinationMethod ValueRemark
Not applicable (mixture)
isotridecanol, ethoxylated
BCF fishes
ValueMethod Duration Species Value determinationParameter
232.5 l/kg 54 h - 72 h Pimephales promelas Experimental valueBCF
Log Kow
TemperatureRemarkMethod Value Value determination
22 °COECD 117 6.4 Weight of evidence approach2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
BCF fishes
ValueMethod Duration Species Value determinationParameter
371.8 l/kg; Freshweight
BCFBAF v3.00 Calculated valueBCF
Log Kow
TemperatureRemarkMethod Value Value determination
25 °C8.53 Calculated
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
8 / 12Product number: 39806
Conclusion
Does not contain bioaccumulative component(s)
12.4. Mobility in soilisotridecanol, ethoxylated
(log) Koc
Value determinationValueMethodParameter
QSAR2.376 - 2.645log Koc2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
(log) Koc
Value determinationValueMethodParameter
Calculated value5.1SRC PCKOCWIN v2.0log Koc
Conclusion
Contains component(s) that adsorb(s) into the soilContains component(s) with potential for mobility in the soil
12.5. Results of PBT and vPvB assessmentDoes not contain component(s) that meet(s) the criteria of PBT and/or vPvB as listed in Annex XIII of Regulation (EC) No 1907/2006.
12.6. Other adverse effectsNOVACARE SHAMP-WAX
Greenhouse gasesNone of the known components is included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014)Ozone-depleting potential (ODP)Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009)
isotridecanol, ethoxylatedGroundwater
Groundwater pollutant
SECTION 13: Disposal considerationsThe information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposurescenarios that correspond to your identified use.
13.1. Waste treatment methods13.1.1 Provisions relating to waste
European UnionHazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014 and Regulation (EU) No 2017/997.Waste material code (Directive 2008/98/EC, Decision 2000/0532/EC).20 01 29* (separately collected fractions (except 15 01): detergents containing hazardous substances). Depending on branch of industry and productionprocess, also other waste codes may be applicable.
13.1.2 Disposal methodsRemove to an authorized incinerator equipped with an afterburner and a flue gas scrubber with energy recovery. Remove waste in accordance with localand/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed togetherif this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entitiesthat store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Do notdischarge into drains or the environment. Dispose of at authorized waste collection point.
13.1.3 Packaging/ContainerEuropean Union
Waste material code packaging (Directive 2008/98/EC).15 01 10* (packaging containing residues of or contaminated by dangerous substances).
SECTION 14: Transport information
Road (ADR)14.1. UN number
UN number 3082
14.2. UN proper shipping nameEnvironmentally hazardous substance, liquid, n.o.s. (2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol)
Proper shipping name
14.3. Transport hazard class(es)Hazard identification number 90
Class 9
Classification code M6
14.4. Packing groupPacking group III
Labels 9
14.5. Environmental hazardsEnvironmentally hazardous substance mark no
14.6. Special precautions for userSpecial provisions 274
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
9 / 12Product number: 39806
Special provisions 335
Special provisions 375
Special provisions 601
Limited quantities Combination packagings: not more than 5 liters per inner packaging forliquids. A package shall not weigh more than 30 kg. (gross mass)
Rail (RID)14.1. UN number
UN number 3082
14.2. UN proper shipping nameEnvironmentally hazardous substance, liquid, n.o.s. (2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol)
Proper shipping name
14.3. Transport hazard class(es)Hazard identification number 90
Class 9
Classification code M6
14.4. Packing groupPacking group III
Labels 9
14.5. Environmental hazardsEnvironmentally hazardous substance mark no
14.6. Special precautions for userSpecial provisions 274
Special provisions 335
Special provisions 375
Special provisions 601
Limited quantities Combination packagings: not more than 5 liters per inner packaging forliquids. A package shall not weigh more than 30 kg. (gross mass)
Inland waterways (ADN)14.1. UN number
UN number 3082
14.2. UN proper shipping nameEnvironmentally hazardous substance, liquid, n.o.s. (2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol)
Proper shipping name
14.3. Transport hazard class(es)Class 9
Classification code M6
14.4. Packing groupPacking group III
Labels 9
14.5. Environmental hazardsEnvironmentally hazardous substance mark no
14.6. Special precautions for userSpecial provisions 274
Special provisions 335
Special provisions 375
Special provisions 601
Limited quantities Combination packagings: not more than 5 liters per inner packaging forliquids. A package shall not weigh more than 30 kg. (gross mass)
Sea (IMDG/IMSBC)14.1. UN number
UN number 3082
14.2. UN proper shipping nameenvironmentally hazardous substance, liquid, n.o.s. (2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol)
Proper shipping name
14.3. Transport hazard class(es)Class 9
14.4. Packing groupPacking group III
Labels 9
14.5. Environmental hazardsMarine pollutant -
Environmentally hazardous substance mark no
14.6. Special precautions for userSpecial provisions 274
Special provisions 335
Special provisions 969
Limited quantities Combination packagings: not more than 5 liters per inner packaging forliquids. A package shall not weigh more than 30 kg. (gross mass)
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
10 / 12Product number: 39806
14.7. Transport in bulk according to Annex II of Marpol and the IBC CodeAnnex II of MARPOL 73/78 Not applicable, based on available data
Air (ICAO-TI/IATA-DGR)14.1. UN number
UN number 3082
14.2. UN proper shipping nameEnvironmentally hazardous substance, liquid, n.o.s. (2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol)
Proper shipping name
14.3. Transport hazard class(es)Class 9
14.4. Packing groupPacking group III
Labels 9
14.5. Environmental hazardsEnvironmentally hazardous substance mark no
14.6. Special precautions for userSpecial provisions A158
Special provisions A197
Special provisions A97
Passenger and cargo transportLimited quantities: maximum net quantity per packaging 30 kg G
SECTION 15: Regulatory information
European legislation:
VOC content Directive 2010/75/EU
VOC content Remark
0.080 %
5.823 g/l
Ingredients according to Regulation (EC) No 648/2004 and amendments
5-15% non-ionic surfactants, <5% cationic surfactants
REACH Annex XVII - Restriction
Contains component(s) subject to restrictions of Annex XVII of Regulation (EC) No 1907/2006: restrictions on the manufacture, placing on the marketand use of certain dangerous substances, mixtures and articles.
Designation of the substance, of the group ofsubstances or of the mixture
Conditions of restriction
· isotridecanol, ethoxylated· 2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
Liquid substances or mixtures fulfilling thecriteria for any of the following hazard classesor categories set out in Annex I to Regulation(EC) No 1272/2008:(a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8types A and B, 2.9, 2.10, 2.12, 2.13 categories1 and 2, 2.14 categories 1 and 2, 2.15 types Ato F;(b) hazard classes 3.1 to 3.6, 3.7 adverseeffects on sexual function and fertility or ondevelopment, 3.8 effects other than narcoticeffects, 3.9 and 3.10;(c) hazard class 4.1;(d) hazard class 5.1.
1. Shall not be used in:— ornamental articles intended to produce light or colour effects by means of differentphases, for example in ornamental lamps and ashtrays,— tricks and jokes,— games for one or more participants, or any article intended to be used as such, even withornamental aspects,2. Articles not complying with paragraph 1 shall not be placed on the market.3. Shall not be placed on the market if they contain a colouring agent, unless required forfiscal reasons, or perfume, or both, if they:— can be used as fuel in decorative oil lamps for supply to the general public, and,— present an aspiration hazard and are labelled with H304,4. Decorative oil lamps for supply to the general public shall not be placed on the marketunless they conform to the European Standard on Decorative oil lamps (EN 14059) adoptedby the European Committee for Standardisation (CEN).5. Without prejudice to the implementation of other Community provisions relating to theclassification, packaging and labelling of dangerous substances and mixtures, suppliers shallensure, before the placing on the market, that the following requirements are met:a) lamp oils, labelled with H304, intended for supply to the general public are visibly, legiblyand indelibly marked as follows: “Keep lamps filled with this liquid out of the reach ofchildren”; and, by 1 December 2010, “Just a sip of lamp oil — or even sucking the wick oflamps — may lead to life- threatening lung damage”;b) grill lighter fluids, labelled with H304, intended for supply to the general public are legiblyand indelibly marked by 1 December 2010 as follows: “Just a sip of grill lighter may lead tolife threatening lung damage”;c) lamp oils and grill lighters, labelled with H304, intended for supply to the general publicare packaged in black opaque containers not exceeding 1 litre by 1 December 2010.6. No later than 1 June 2014, the Commission shall request the European Chemicals Agencyto prepare a dossier, in accordance with Article 69 of the present Regulation with a view toban, if appropriate, grill lighter fluids and fuel for decorative lamps, labelled H304, intendedfor supply to the general public.7. Natural or legal persons placing on the market for the first time lamp oils and grill lighterfluids, labelled with H304, shall by 1 December 2011, and annually thereafter, provide dataon alternatives to lamp oils and grill lighter fluids labelled H304 to the competent authorityin the Member State concerned. Member States shall make those data available to theCommission.'
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
11 / 12Product number: 39806
National legislation BelgiumNOVACARE SHAMP-WAX
No data available
National legislation The NetherlandsNOVACARE SHAMP-WAX
Waterbezwaarlijkheid A (2); Algemene Beoordelingsmethodiek (ABM)
National legislation FranceNOVACARE SHAMP-WAX
No data available
National legislation GermanyNOVACARE SHAMP-WAX
WGK 2; Verordnung über Anlagen zum Umgang mit wassergefährdenden Stoffen (AwSV) - 18. April 2017isotridecanol, ethoxylated
TA-Luft 5.2.5/I2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol
TA-Luft 5.2.5/I
National legislation United KingdomNOVACARE SHAMP-WAX
No data available
Other relevant dataNOVACARE SHAMP-WAX
No data available
15.2. Chemical safety assessmentNo chemical safety assessment has been conducted for the mixture.
SECTION 16: Other informationFull text of any H-statements referred to under heading 3:
H302 Harmful if swallowed.H314 Causes severe skin burns and eye damage.H315 Causes skin irritation.H318 Causes serious eye damage.H373 May cause damage to organs (gastrointestinal tract, thymus) through prolonged or repeated exposure if swallowed.H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.
(*) INTERNAL CLASSIFICATION BY BIGADI Acceptable daily intakeAOEL Acceptable operator exposure levelCLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in Europe)DMEL Derived Minimal Effect LevelDNEL Derived No Effect LevelEC50 Effect Concentration 50 %ErC50 EC50 in terms of reduction of growth rateLC50 Lethal Concentration 50 %LD50 Lethal Dose 50 %NOAEL No Observed Adverse Effect LevelNOEC No Observed Effect ConcentrationOECD Organisation for Economic Co-operation and DevelopmentPBT Persistent, Bioaccumulative & ToxicPNEC Predicted No Effect ConcentrationSTP Sludge Treatment ProcessvPvB very Persistent & very Bioaccumulative
M-factor10 Acute2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol ECHA
1 Chronic2-(2-heptadec-8-enyl-2-imidazolin-1-yl)ethanol ECHA
The informa on in this safety data sheet is based on data and samples provided to BIG. The sheet was wri en to the best of our ability andaccording to the state of knowledge at that me. The safety data sheet only cons tutes a guideline for the safe handling, use, consump on,storage, transport and disposal of the substances/prepara ons/mixtures men oned under point 1. New safety data sheets are wri en from
me to me. Only the most recent versions may be used. Unless indicated otherwise word for word on the safety data sheet, the informa ondoes not apply to substances/prepara ons/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offersno quality specifica on for the substances/prepara ons/mixtures in ques on. Compliance with the instruc ons in this safety data sheet doesnot release the user from the obliga on to take all measures dictated by common sense, regula ons and recommenda ons or which arenecessary and/or useful based on the real applicable circumstances. BIG does not guarantee the accuracy or exhaus veness of the
NOVACARE SHAMP-WAX
Revision number: 0601
Reason for revision: 9
Date of revision: 2019-10-21
Publication date: 2013-06-16
12 / 12Product number: 39806
informa on provided and cannot be held liable for any changes by third par es. This safety data sheet is only to be used within the EuropeanUnion, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own risk. Use of this safety data sheet issubject to the licence and liability limi ng condi ons as stated in your BIG licence agreement or when this is failing the general condi ons ofBIG. All intellectual property rights to this sheet are the property of BIG and its distribu on and reproduc on are limited. Consult themen oned agreement/condi ons for details.