Safety Data Sheet: Hydrochloric acid - Carl Roth

SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1 Product identifier

Identification of the substance Hydrochloric acid ROTIPURAN® Supra 35 %

Article number HN53

Registration number (REACH) not relevant (mixture)

Index number in CLP Annex VI [ 017-002-01-X ]

EC number [ 231-595-7 ]

CAS number [ 7647-01-0 ]

1.2 Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: Laboratory chemicalLaboratory and analytical use

Uses advised against: Do not use for squirting or spraying. Do not usefor products which come into direct contact withthe skin. Do not use for products which come in-to contact with foodstuffs. Do not use for privatepurposes (household).

1.3 Details of the supplier of the safety data sheetCarl Roth GmbH + Co KGSchoemperlenstr. 3-5D-76185 KarlsruheGermany

Telephone:+49 (0) 721 - 56 06 0Telefax: +49 (0) 721 - 56 06 149e-mail: [email protected]: www.carlroth.de

Competent person responsible for the safety datasheet:

:Department Health, Safety and Environment

e-mail (competent person): [email protected]

1.4 Emergency telephone number

SECTION 2: Hazards identification2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Section Hazard class Cat-egory

Hazard class andcategory

Hazardstatement

2.16 Substance or mixture corrosive to metals 1 Met. Corr. 1 H290

3.2 Skin corrosion/irritation 1B Skin Corr. 1B H314

3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318

Safety data sheetaccording to Regulation (EC) No. 1907/2006 (REACH)

Hydrochloric acid ROTIPURAN® Supra 35 %

article number: HN53Version: 4.0 enReplaces version of: 19.08.2020Version: (3)

date of compilation: 07.04.2017Revision: 05.05.2021

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Section Hazard class Cat-egory

Hazard class andcategory

Hazardstatement

3.8R Specific target organ toxicity - single exposure (respirat-ory tract irritation)

3 STOT SE 3 H335

For full text of abbreviations: see SECTION 16

The most important adverse physicochemical, human health and environmental effectsSkin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi-dermis and into the dermis.

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word Danger

Pictograms

GHS05, GHS07

Hazard statementsH290 May be corrosive to metalsH314 Causes severe skin burns and eye damageH335 May cause respiratory irritation

Precautionary statements

Precautionary statements - preventionP280 Wear protective gloves/protective clothing/eye protection/face protection

Precautionary statements - responseP303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin

with water [or shower]P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathingP305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsingP310 Immediately call a POISON CENTER/doctor

Hazardous ingredients for labelling: Hydrochloric acid .... %

Labelling of packages where the contents do not exceed 125 mlSignal word: Danger

Symbol(s)

H314 Causes severe skin burns and eye damage.

P280 Wear protective gloves/protective clothing/eye protection/face protection.P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to

do. Continue rinsing.P310 Immediately call a POISON CENTER/doctor.



article number: HN53

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contains: Hydrochloric acid .... %

2.3 Other hazards

Results of PBT and vPvB assessmentThis mixture does not contain any substances that are assessed to be a PBT or a vPvB.

SECTION 3: Composition/information on ingredients3.1 Substances

not relevant (mixture)

3.2 Mixtures

Description of the mixture

Name of sub-stance

Identifier Wt% Classification acc. toGHS

Pictograms Notes

Hydrochloric acid .... % CAS No7647-01-0

EC No231-595-7

Index No017-002-01-X

REACH Reg. No01-2119484862-

27-xxxx

34 – 37 Met. Corr. 1 / H290Skin Corr. 1B / H314Eye Dam. 1 / H318STOT SE 3 / H335

B(a)GHS-HCIOELV

NotesB(a): The classification refers to an aqueous solutionGHS-HC: Harmonised classification (the classification of the substance corresponds to the entry in the list according to 1272/

2008/EC, Annex VI)IOELV: Substance with a community indicative occupational exposure limit value

Name of sub-stance

Identifier Specific Conc. Limits M-Factors ATE Exposureroute

Hydrochloricacid .... %

CAS No7647-01-0

EC No231-595-7

Index No017-002-01-X

Met. Corr. 1; H290: C ≥ 0,1 %Skin Corr. 1B; H314: C ≥ 25 %

Skin Irrit. 2; H315: 10 % ≤ C < 25 %Eye Dam. 1; H318: C ≥ 25 %

Eye Irrit. 2; H319: 10 % ≤ C < 25 %STOT SE 3; H335: C ≥ 10 %

- -

For full text of abbreviations: see SECTION 16

SECTION 4: First aid measures4.1 Description of first aid measures

General notesTake off immediately all contaminated clothing. Self-protection of the first aider.

Following inhalationProvide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.




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Following skin contactAfter contact with skin, wash immediately with plenty of water. Immediate medical treatment re-quired because corrosive injuries that are not treated are hard to cure.

Following eye contactIn case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-ing eyelids apart and consult an ophthalmologist. Protect uninjured eye.

Following ingestionRinse mouth immediately and drink plenty of water. Call a physician immediately. If swalloweddanger of perforation of the esophagus and the stomach (strong corrosive effects).

4.2 Most important symptoms and effects, both acute and delayedCorrosion, Risk of blindness, Gastric perforation, Risk of serious damage to eyes, Irritation, Cough,Dyspnoea

4.3 Indication of any immediate medical attention and special treatment needednone

SECTION 5: Firefighting measures5.1 Extinguishing media

Suitable extinguishing mediaco-ordinate firefighting measures to the fire surroundingswater spray, alcohol resistant foam, dry extinguishing powder, BC-powder, carbon dioxide (CO₂)Unsuitable extinguishing mediawater jet

5.2 Special hazards arising from the substance or mixtureNon-combustible.

5.3 Advice for firefightersIn case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas-onable distance. Wear self-contained breathing apparatus. Wear full chemical protective clothing.

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnelUse personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do notbreathe vapour/spray.

6.2 Environmental precautionsKeep away from drains, surface and ground water. The product is an acid. Before discharge intosewage plants the product normally needs to be neutralised.




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6.3 Methods and material for containment and cleaning up

Advice on how to contain a spillCovering of drains.

Advice on how to clean up a spillAbsorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents).

Other information relating to spills and releasesPlace in appropriate containers for disposal. Ventilate affected area.

6.4 Reference to other sectionsHazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-patible materials: see section 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage7.1 Precautions for safe handling

Use extractor hood (laboratory). When diluting/dissolving, always have the water ready first, thenslowly stir in the product. Handle and open container with care. Provision of sufficient ventilation.Clear contaminated areas thoroughly.

Advice on general occupational hygieneWash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.

7.2 Conditions for safe storage, including any incompatibilitiesKeep container tightly closed. Keep only in original container.

Incompatible substances or mixturesObserve hints for combined storage.

Consideration of other advice:

Specific designs for storage rooms or vesselsRecommended storage temperature: 15 – 25 °C

7.3 Specific end use(s)No information available.

SECTION 8: Exposure controls/personal protection8.1 Control parameters

National limit values

Occupational exposure limit values (Workplace Exposure Limits)

Country

Name of agent CAS No Identi-fier

TWA

[ppm]

TWA[mg/m³]

STEL

[ppm]

STEL[mg/m³]

Ceiling-

C[ppm]

Ceil-ing-C[mg/m³]

Nota-tion

Source

EU hydrogen chloride 7647-01-0

IOELV 5 8 10 15 2000/39/EC

MT hydrogen chloride 7647-01-0

OELV 5 8 10 15 CAP. 424

NotationCeiling-C Ceiling value is a limit value above which exposure should not occurSTEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-

minute period (unless otherwise specified)




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NotationTWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8

hours time-weighted average (unless otherwise specified)

Relevant DNELs of components of the mixture

Name of sub-stance

CAS No End-point

Threshold level

Protectiongoal, route of

exposure

Used in Exposure time

Hydrochloric acid ....%

7647-01-0 DNEL 8 mg/m³ human, inhalat-ory

worker (industry) chronic - local ef-fects

Hydrochloric acid ....%

7647-01-0 DNEL 15 mg/m³ human, inhalat-ory

worker (industry) acute - local ef-fects

8.2 Exposure controls

Individual protection measures (personal protective equipment)

Eye/face protection

Use safety goggle with side protection. Wear face protection.

Skin protection

• hand protectionWear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to checkthe resistance to chemicals of the protective gloves mentioned above together with the supplier ofthese gloves. The times are approximate values from measurements at 22 ° C and permanent con-tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If indoubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respectivebreakthrough time is doubled / halved. The data apply only to the pure substance. When transferredto substance mixtures, they may only be considered as a guide.

• type of materialNBR (Nitrile rubber)

• material thickness>0,3 mm

• breakthrough times of the glove material>480 minutes (permeation: level 6)

• other protection measuresTake recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) isrecommended.




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Respiratory protection

Respiratory protection necessary at: Aerosol or mist formation. Type: E (against acidic gases like sul-phur dioxide or hydrogen chloride, colour code: Yellow).

Environmental exposure controlsKeep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties9.1 Information on basic physical and chemical properties

Physical state liquid

Colour colourless - light yellow

Odour stinging

Melting point/freezing point -26 °C

Boiling point or initial boiling point and boilingrange

not determined

Flammability non-combustible

Lower and upper explosion limit not determined

Flash point not determined

Auto-ignition temperature not determined

Decomposition temperature not relevant

pH (value) <1 (in aqueous solution: 370 g/l, 20 °C)

Kinematic viscosity not determined

Solubility(ies)

Water solubility miscible in any proportion

Partition coefficient

Partition coefficient n-octanol/water (log value): not relevant (inorganic)

Vapour pressure 190 hPa at 20 °C

Density 1,18 g/cm³ at 20 °C

Relative vapour density information on this property is not available

Particle characteristics not relevant (liquid)

Other safety parameters




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Oxidising properties none

9.2 Other information

Information with regard to physical hazardclasses:

Corrosive to metals category 1: corrosive to metals

Other safety characteristics:

Miscibility completely miscible with water

SECTION 10: Stability and reactivity10.1 Reactivity

Substance or mixture corrosive to metals.

10.2 Chemical stabilityThe material is stable under normal ambient and anticipated storage and handling conditions of tem-perature and pressure.

10.3 Possibility of hazardous reactions

Dangerous/dangerous reactions with: strong oxidiser, Aldehydes, Aluminium, Amines, Carbide,Fluorine, Metals, Permanganates, Strong alkali,Danger of explosion: Alkali metals, Sulphuric acid, concentrated

10.4 Conditions to avoidKeep away from heat.

10.5 Incompatible materialsdifferent metals

Release of flammable materials withLight metals (due to the release of hydrogen in an acid/alkaline medium).

10.6 Hazardous decomposition productsHazardous combustion products: see section 5.

SECTION 11: Toxicological information11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Test data are not available for the complete mixture.

Classification procedureThe method for classification of the mixture is based on ingredients of the mixture (additivityformula).

Classification according to GHS (1272/2008/EC, CLP)

Acute toxicityShall not be classified as acutely toxic.

Skin corrosion/irritationCauses severe skin burns and eye damage.

Serious eye damage/eye irritationCauses serious eye damage.




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Respiratory or skin sensitisationShall not be classified as a respiratory or skin sensitiser.

Germ cell mutagenicityShall not be classified as germ cell mutagenic.

CarcinogenicityShall not be classified as carcinogenic.

Reproductive toxicityShall not be classified as a reproductive toxicant.

Specific target organ toxicity - single exposureMay cause respiratory irritation.

Specific target organ toxicity - repeated exposureShall not be classified as a specific target organ toxicant (repeated exposure).

Aspiration hazardShall not be classified as presenting an aspiration hazard.

Symptoms related to the physical, chemical and toxicological characteristics

• If swallowedIf swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects)

• If in eyescauses burns, Causes serious eye damage, risk of blindness

• If inhaledIrritation to respiratory tract, cough, Dyspnoea, pulmonary oedema

• If on skincauses severe burns, causes poorly healing wounds

• Other informationOther adverse effects: Circulatory collapse, Cardiac arrhythmias, Symptoms can occur only after sev-eral hours

11.2 Endocrine disrupting propertiesNone of the ingredients are listed.

11.3 Information on other hazardsThere is no additional information.

SECTION 12: Ecological information12.1 Toxicity

Shall not be classified as hazardous to the aquatic environment..

BiodegradationThe methods for determining the biological degradability are not applicable to inorganic substances.

12.2 Process of degradabilityData are not available.




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12.3 Bioaccumulative potentialData are not available.

12.4 Mobility in soilData are not available.

12.5 Results of PBT and vPvB assessmentData are not available.

12.6 Endocrine disrupting propertiesNone of the ingredients are listed.

12.7 Other adverse effectsData are not available.

SECTION 13: Disposal considerations13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-er in accordance with local/regional/national/international regulations.

Sewage disposal-relevant informationDo not empty into drains.

Waste treatment of containers/packagingsIt is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.

13.2 Relevant provisions relating to wasteThe allocation of waste identity numbers/waste descriptions must be carried out according to theEEC, specific to the industry and process. Waste catalogue ordinance (Germany).

13.3 RemarksWaste shall be separated into the categories that can be handled separately by the local or nationalwaste management facilities. Please consider the relevant national or regional provisions.

SECTION 14: Transport information14.1 UN number or ID number

ADR/RID/ADN UN 1789

IMDG-Code UN 1789

ICAO-TI UN 1789

14.2 UN proper shipping name

ADR/RID/ADN HYDROCHLORIC ACID

IMDG-Code HYDROCHLORIC ACID

ICAO-TI Hydrochloric acid

14.3 Transport hazard class(es)

ADR/RID/ADN 8




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IMDG-Code 8

ICAO-TI 8

14.4 Packing group

ADR/RID/ADN II

IMDG-Code II

ICAO-TI II

14.5 Environmental hazards non-environmentally hazardous acc. to the dan-gerous goods regulations

14.6 Special precautions for userProvisions for dangerous goods (ADR) should be complied within the premises.

14.7 Maritime transport in bulk according to IMO instrumentsThe cargo is not intended to be carried in bulk.

14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additionalinformation

Proper shipping name HYDROCHLORIC ACID

Particulars in the transport document UN1789, HYDROCHLORIC ACID, 8, II, (E)

Classification code C1

Danger label(s) 8

Special provisions (SP) 520

Excepted quantities (EQ) E2

Limited quantities (LQ) 1 L

Transport category (TC) 2

Tunnel restriction code (TRC) E

Hazard identification No 80

International Maritime Dangerous Goods Code (IMDG) - Additional information

Proper shipping name HYDROCHLORIC ACID

Particulars in the shipper's declaration UN1789, HYDROCHLORIC ACID, 8, II

Marine pollutant -

Danger label(s) 8


Limited quantities (LQ) 1 L

EmS F-A, S-B




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Stowage category C

Segregation group 1 - Acids

International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information

Proper shipping name Hydrochloric acid

Particulars in the shipper's declaration UN1789, Hydrochloric acid, 8, II

Danger label(s) 8

Special provisions (SP) A3


Limited quantities (LQ) 0,5 L

SECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Relevant provisions of the European Union (EU)

Restrictions according to REACH, Annex XVII

Dangerous substances with restrictions (REACH, Annex XVII)

Name of substance Name acc. to inventory CAS No Restriction No

Hydrochloric acid this product meets the criteria forclassification in accordance with Reg-

ulation No 1272/2008/EC

R3 3

LegendR3 1. Shall not be used in:

- ornamental articles intended to produce light or colour effects by means of different phases, for example in orna-mental lamps and ashtrays,- tricks and jokes,- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,2. Articles not complying with paragraph 1 shall not be placed on the market.3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume,or both, if they:- can be used as fuel in decorative oil lamps for supply to the general public, and,- present an aspiration hazard and are labelled with R65 or H304,4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to theEuropean Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisation(CEN).5. Without prejudice to the implementation of other Community provisions relating to the classification, packagingand labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the market, thatthe following requirements are met:(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indeliblymarked as follows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December 2010, ‘Just a sipof lamp oil - or even sucking the wick of lamps - may lead to life-threatening lung damage’;(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indeliblymarked by 1 December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lung damage’;(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged inblack opaque containers not exceeding 1 litre by 1 December 2010.6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier, inaccordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and fuel fordecorative lamps, labelled R65 or H304, intended for supply to the general public.7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with R65or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill lighterfluids labelled R65 or H304 to the competent authority in the Member State concerned. Member States shall makethose data available to the Commission.

List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate listNone of the ingredients are listed. (Or Concentration of the substance in a mixture: <0.1 % Mass con-centration)




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Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap-plication of lower and upper-tier re-

quirements

Notes

not assigned

Deco-Paint Directive

VOC content 0 %0 g/l

Industrial Emissions Directive (IED)

VOC content 0 %

VOC contentWater content was discounted

0 g/l

Directive on the restriction of the use of certain hazardous substances in electrical andelectronic equipment (RoHS)none of the ingredients are listed

Regulation concerning the establishment of a European Pollutant Release and TransferRegister (PRTR)none of the ingredients are listed

Water Framework Directive (WFD)none of the ingredients are listed

Regulation on the marketing and use of explosives precursorsnone of the ingredients are listed

Regulation on drug precursors

Name of substance CAS No Classification CN Code Thresholdlevel

Hydrochloric acid .... % 7647-01-0 Category 3 2806 10 00

Regulation on substances that deplete the ozone layer (ODS)none of the ingredients are listed

Regulation concerning the export and import of hazardous chemicals (PIC)none of the ingredients are listed

Regulation on persistent organic pollutants (POP)none of the ingredients are listed

UN Convention against Illicit Traffic in Narcotic Drugs and Psychotropic Substances

Name of substance CAS No Listed in HS code

Hydrochloric acid .... % 7647-01-0 Table II 2806.10




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National inventories

Country Inventory Status

AU AICS all ingredients are listed

CA DSL all ingredients are listed

CN IECSC all ingredients are listed

EU ECSI all ingredients are listed

EU REACH Reg. all ingredients are listed

JP CSCL-ENCS all ingredients are listed

KR KECI all ingredients are listed

MX INSQ all ingredients are listed

NZ NZIoC all ingredients are listed

PH PICCS all ingredients are listed

TR CICR not all ingredients are listed

TW TCSI all ingredients are listed

US TSCA all ingredients are listed

LegendAICS Australian Inventory of Chemical SubstancesCICR Chemical Inventory and Control RegulationCSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)DSL Domestic Substances List (DSL)ECSI EC Substance Inventory (EINECS, ELINCS, NLP)IECSC Inventory of Existing Chemical Substances Produced or Imported in ChinaINSQ National Inventory of Chemical SubstancesKECI Korea Existing Chemicals InventoryNZIoC New Zealand Inventory of ChemicalsPICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)REACH Reg. REACH registered substancesTCSI Taiwan Chemical Substance InventoryTSCA Toxic Substance Control Act

15.2 Chemical Safety AssessmentChemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other informationIndication of changes (revised safety data sheet)Alignment to regulation: Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Restructuring: section 9, section 14

Section Former entry (text/value) Actual entry (text/value) Safety-relev-

ant

2.1 Classification according to Regulation (EC) No1272/2008 (CLP):

change in the listing (table)

yes

2.1 The most important adverse physicochemical,human health and environmental effects:

Skin corrosion produces an irreversible dam-age to the skin; namely, visible necrosis through

the epidermis and into the dermis.

yes




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Section Former entry (text/value) Actual entry (text/value) Safety-relev-

ant

2.3 Other hazards:There is no additional information.

Other hazards yes

2.3 Results of PBT and vPvB assessment:This mixture does not contain any substances

that are assessed to be a PBT or a vPvB.

yes

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

2000/39/EC Commission Directive establishing a first list of indicative occupational exposure limit values in imple-mentation of Council Directive 98/24/EC

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-

land Waterways)

ADR Accord européen relatif au transport international des marchandises dangereuses par route (EuropeanAgreement concerning the International Carriage of Dangerous Goods by Road)

ADR/RID/ADN European Agreements concerning the International Carriage of Dangerous Goods by Road/Rail/InlandWaterways (ADR/RID/ADN)

ATE Acute Toxicity Estimate

CAP. 424 Occupational Health and Safety Authority Act (CAP. 424)

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

CN Code Combined Nomenclature

DGR Dangerous Goods Regulations (see IATA/DGR)

DNEL Derived No-Effect Level

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-fier of substances commercially available within the EU (European Union)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

Eye Dam. Seriously damaging to the eye

Eye Irrit. Irritant to the eye

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-tions

HS Harmonized Commodity Description and Coding System (Harmonized System, drawn up by the WorldCustoms Organisation)

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air




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Abbr. Descriptions of used abbreviations

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

index No The Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation(EC) No 1272/2008

IOELV Indicative occupational exposure limit value

Met. Corr. Substance or mixture corrosive to metals

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

ppm Parts per million

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-tions concerning the International carriage of Dangerous goods by Rail)

Skin Corr. Corrosive to skin

Skin Irrit. Irritant to skin

STEL Short-term exposure limit

STOT SE Specific target organ toxicity - single exposure

SVHC Substance of Very High Concern

TWA Time-weighted average

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

Key literature references and sources for dataRegulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU.Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN). International Mari-time Dangerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

Classification procedurePhysical and chemical properties. The classification is based on tested mixture.Health hazards. Environmental hazards. The method for classification of the mixture is based on in-gredients of the mixture (additivity formula).

List of relevant phrases (code and full text as stated in chapter 2 and 3)

Code Text

H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H335 May cause respiratory irritation.

DisclaimerThis information is based upon the present state of our knowledge. This SDS has been compiled andis solely intended for this product.




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Safety Data Sheet: Hydrochloric acid - Carl Roth

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Transcript of Safety Data Sheet: Hydrochloric acid - Carl Roth