PG Chemistry Syllabus 2018.pdf - Sarah Tucker College

1

CURRICULUM & SYLLABUS FOR

UG/PG/M Phil/Ph.D CHEMISTRY PROGRAMME

CBCS-SEMESTER SYSTEM

REVISED 2018

MSc Chemistry Curriculum

DEPARTMENT OF CHEMISTRY & RESEARCH CENTRE

SARAH TUCKER COLLEGE (AUTONOMOUS)

Tirunelveli-627007, Tamil Nadu, India

(Established 1895)

Website: www.sarahtuckercollege.in

Phone: 04622534780 Extn.49

E-mail :[email protected]

Fax : 04652-229800

http://www.sarah/

2

DEPARTMENT OF CHEMISTRY & RESEARCH CENTRE

Department Profile

Sarah Tucker College, founded in 1895 enjoys a heritage of 120 years as a Christian minority

institution of higher education for women. It functions under the management of Tirunelveli

Diocesan Trust Association and affiliated to Manonmaniam Sundaranar University, Tirunelveli. The

college offers a wide variety of UG, PG, M.Phil and Ph.D programmes.Chemistry was introduced in

PUC course in the year 1962, as a core subject at the UG level in 1971, PG level in 1986 and

elevated to research department in 2013. Ever since its inception, by the dedication and efficiency of

the faculty members, the department has become strong and viable.

Vision

* To develop a Scholastic, Vibrant, Compassionate, Modern and Modest Student

community.

Mission

* To equip ourselves for accomplishing our visionary ends and to make our Department an

amazing place for learning.

Objectives

* To Dedicate ourselves to mould and channelise the student power.

* To plan, budget and determine the goals for the coming years.

* To mobilize and support civil and social programme by students.

* To enhance research activities in the department

3

BOARD OF STUDIES MEMBERS IN CHEMISTRY

Members who contribute to the framing of Curriculum and Syllabi in the board of

studies meeting held on 20thMarch 2018. Modified curriculum and syllabi were

approved and recommended to place before the Academic Council.

Dr.R.BABY SUNEETHA : University Nominee

Assistant Professor ofChemistry

VOC College, Tuticorin

Dr P.Kulanthai Pandi : Subject Expert

Associate Professor of Chemistry,

Sri K.G.S. Arts College,Srivaikundam

Dr. H.Perumpadaiyan : Subject Expert


Sri K.G.S. Arts College,Srivaikundam

Dr. R.Venkat Raman : Subject Expert


Sri Paramakalyani College,Alwarkurichi

Dr.Jeslin Kanaga Inba : Illustrious Alumnus

Assistant Professor of Chemistry,

Sathakathulla Appa College,Tirunelveli.

Mr. Varghese : Industrialist

General Manager, Konam Latex Private Ltd,

Peruvilai, Nagercoil

4

Staff members of Department of Chemistry and Research Centre

1. Dr.V.Rama M.Sc.,M.Phil.,Ph.D, Associate Professor and Head of the Department

2. Mrs. Suganthi Angelin M.Sc.,M.Phil.,B.Ed Associate Professor

3. Dr.J. Rajula Jasmine Usha M.Sc.,M.Phil.,Ph.D Associate Professor

4. Mrs. Anita Gloria Chellam M.Sc.,M.Phil Associate Professor

5. Mrs. C.Juliet Florence M.Sc.,M.Phil Associate Professor

6. Mrs. A. Mary Ratna Sylvia M.Sc.,M.Phil.,B.Ed Associate Professor

7. Mrs. A.K.Alice Kalavathy M.Sc.,M.Phil.,B.Ed Associate Professor

8. Mrs. Jenoviah Esther Thavaseeli M.Sc.,M.Phil.,B.Ed Associate Professor

9. Dr.R.SujathaM.Sc.,M.Phil.,Ph.D, Associate Professor

10. Dr. J.Shakina,M.Sc.,M.Phil.,B.Ed.,PGDCA.,Ph.D.,NET, Assistant Professor

11. Dr.T.Sheela Retna Joy M.Sc.,M.Phil.,Ph.D Assistant Professor

12. Dr.N.Rexin Alphonse M.Sc.,M.Phil.,Ph.D Assistant Professor

13. Dr. S. Stella. M.Sc.,Ph.D., NET Assistant Professor

5

TESTING AND EVALUATION FOR UG AND PG COURSES

Sl.No Internal marks External marks Total marks

1. Theory (25) Theory (75) 100

2. Practical (40) Practical (60) 100

PG

Internal External Overall

Theory No Minimum 50% (38/75) 50% (50/100)

Practical 50% (20/40) 50% (30/60) 50% (50/100)

6

END SEMESTER EXAMINATION

QUESTION PATTERN FOR ESE (UG/PG)

Sl.No Sections Marks 1. Part : A Questions with multiple choice - 10

(Two from each unit) 10 x 1 = 10 2. Part : B Questions with internal choice - 5

(one from each unit) 5 x 5 = 25 3. Part : C Questions with internal Choice - 5

(one from each unit) 5 x 8 = 40

Total 75 marks

QUESTION PATTERN FOR CIA (PG)

Sl.No. Section Marks

1. Part : A Questions –4 4 x 1 = 4

2. Part : BQuestions with Internal Choice – 2 2 x 5= 10

3. Part : CQuestions with Internal Choice – 2 2 x 8 = 16

Total 30 marks

For PG

Test : Average of best two tests - 15

Assignment - 5

Seminar - 5

25 marks

7

PG Chemistry Syllabus

Sarah Tucker College (Autonomous), Tirunelveli-7

PG (Science) Programme – Course Structure Under CBCS

(Applicable to the candidates admitted from the Academic year 2018-2019 onwards)

Department of Chemistry

Sem Nature of

the Subject Name of the paper

Hours

per

week

Credit Marks

I

Core-1 18-1PCY01 Organic Chemistry-I 4 4 100

Core-2 18-1PCY02 Inorganic Chemistry-I 5 4 100

Core-3 18-1PCY03 Physical Chemistry-I 5 4 100

Core

Practical -1

18-

1PCYL01

Organic analysis of

bifunctional compounds

and Preparations-

4 2 100

Core

Practical -2

18-

1PCYL02

Inorganic qualitative

Analysis-I 4 2 100

Core

Practical -3

18-

1PCYL03

Physical Chemistry

Practical-I 4 2 100

Elective 1 18-1PCYE1 Advanced topics in

inorganic chemistry 4 4 100

Extra Credit

Course 1*

Total 30 22 700

II

Core-4 18-2PCY04 Organic Chemistry-II 5 4 100

Core-5 18-2PCY05 Inorganic Chemistry-II 4 4 100

Core-6 18-2PCY06 Physical Chemistry-II 5 4 100

Core

Practical -4

18-

2PCYL04

Separation and analysis of

organic mixture 4 2 100

Core

Practical -5

18-

2PCYL05

Inorganic quantitative

Analysis-I 4 2 100

Core

Practical -6

18-

2PCYL06

Physical Chemistry

Practical-II 4 2 100

Elective 2 18-2PCYE2 Research Methodology

and Green chemistry 4 4 100

Extra Credit

Course 1*

Total 30 22 700

III

Core-7 18-3PCY07 Organic Chemistry-III 4 4 100

Core-8 18-3PCY08 Inorganic Chemistry-III 4 4 100

Core-9 18-3PCY09 Physical Chemistry-III 4 4 100

Core

Practical-7

18-

3PCYL07

Organic estimations and

preparations 1 4 2 100

8

Core

Practical-8

18-

3PCYL08

Inorganic quantitative

Analysis- II 4 2 100

Core

Practical-9

18-

3PCYL09

Physical Chemistry

Practical-III 4 2 100

Project 18-

3PCYE3PJ 6 6 100

Paper

Presentation 1*

Total 30 24 700

IV

Core-10 18-4PCY10 Organic Chemistry-IV 5 4 100

Core-11 18-4PCY11 Inorganic Chemistry-IV 5 4 100

Core-12 18-4PCY12 Physical Chemistry-IV 4 4 100

Core

Practical -10

18-

4PCYL10

Organic estimations and

Preparations-II 4 2 100

Core

Practical -11

18-

4PCYL11 Inorganic Preparations 4 2 100

Core

Practical -12

18-

4PCYL12

Physical Chemistry

Practical-IV 4 2 100

Elective 4 18-4PCYE4 Nanochemistry 4 4 100

Paper

Presentation 1*

Total 30 22 700

Grand Total 120 90 2800

Total Credits 90

Extra Credits 2

9

M.Sc Programme outcome

On completion of M.Sc programme, the students will be able to

Program Outcomes for M.Sc Courses (Sarah Tucker College)

On completion of M.Sc Programme, the students will be able to

PO 1 Show a mastery of foundational material, both in terms of concepts and problem

solving skills, needed for higher education continuing success in science disciplines.

(Proficiency)

PO 2 Acquire knowledge and demonstrate problem solving ability in core and in all areas.

(Critical thinking)

PO 3 Achieve the ability design a variety of experimental techniques, data analysis, and

presentation skills. (Creativity and Imagination)

PO 4 Obtain ‘hands-on’ out-of-class experiential learning component, related to their choice

of specialty in their chosen major (Team Work, communication)

PO 5 Attain success after graduation, leading to professional programmes, employment in

industrial, lab positions, teaching careers, and other career paths (Life-long Learning)

PO 6 Design and carry out theory in practice (Creativity and Imagination)

PO 7 Imbibe ethical, moral and social standards in personal as well as social life leading to

highly civilized and civilized personality (Social Responsibility)

10

Programme specific outcome- M.Sc Chemistry

PSO.No PROGRAMME SPECIFIC OUTCOMES

STUDENTS OF M.SC. CHEMISTRY WILL BE ABLE TO

PO Addressed

PSO1 have a firm foundation in the fundamentals, employ critical

thinking, logical reasoning and efficient problem solving skills in

the frontier areas of chemistry. (Proficiency)

PO1,PO2

PSO2 explore new areas of research in both chemistry and allied fields of

science and technology. (Critical thinking)

PO2

PSO3 use modern library research tools to locate, retrieve and evaluate

scientific information (Creativity and Imagination)

PO3,PO6

PSO4 enhance team work skills for successful career and communicate

the results of scientific work in oral, written and electronic formats

to both scientists and the public at large. (Team Work,

communication)

PO4

PSO5 Pursue research and other higher education gain specific placements

in R &D institutes to get opportunities at all level of chemistry,

Pharmaceutical Chemistry, food products and life oriented material

industries. (Life-long Learning)

PO5

PSO6 appreciate the central role of chemistry in our society and use this as

a basis for ethical behavior in issues facing chemists including an

understanding of safe handling of chemicals, environmental issues

and key issues facing our society in energy, health and medicine.

(Social Responsibility)

PO7

PSO7 face the qualifying examinations like GATE, SET, TET, TNPSC,

CSIR-UGC with confidence(Life-long Learning)

PO5

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SEMESTER-I

Organic Chemistry-I

Core-1 Organic Chemistry – I hours/ week-4

Sub Code: 18-1PCY01

Credits-4

Objectives

To understand the reaction mechanism in organic chemistry

Tounderstand the concepts of stereochemistry,

To study the aromaticity of benzenoid and non-benzenoidcompounds

To study the importance of reagents in organic synthesis.

Unit I Investigation of Reaction Mechanism

Reactive intermediates in organic chemistry –Formation, structure and stability of carbanions,

carbocations, free radicals. Kinetic and thermodynamic control of reactions – methods of

determining reaction mechanisms – kinetic methods – primary and secondary kinetic isotope

effects – non kinetic methods – study of intermediates, product analysis, Isotopic labeling –

stereochemical studies and cross over experiments. Structure and reactivity – Hammett

equation (Derivation not required) - Taft equation.

Unit II Stereochemistry -I

Chirality - prochirality - Enantiotopic and diastereotopic atoms – optical activity of

Biphenyls, Allenes and Spiranes – R S Notation –planar chirality in paracyclophanes and

Ansa compounds- Stereoselective and stereospecific Reactions –Asymmetric synthesis –

Cram’s Rule, Prelog’s Rule,Cram’s chelation model and Felkin Ahn model.

CO.

No.

Expected Learning Outcomes

On successful completion of this course,

student should be able to:

PSO Addressed Cognitive

Level

CO -1 Understand the reactive species involved in the

reactions and the methods of determining

reaction rate product analysis

PSO1,PSO7 U,K

CO-2 Learn the concept of stereochemistry and its

importance.

PSO1,PSO7 U,K

CO-3 Identify the importance of conformational

analysis in organic chemistry

PSO1,PSO7 U,K

CO-4 Understand the concept of aromaticity of

benzenoid and non benzenoid compounds

PSO1,PSO7 U,K

CO-5 Learn the basic mechanism of oxidation in

organic compounds and to acquire knowledge

about the reagents which causes oxidation in

various compounds.

PSO1,PSO7 U,K

12

Unit III Stereochemistry – II

Conformational analysis of mono and disubstituted cyclohexanes – Effect of conformation on

physical properties – hydrogen bonding, dopole moment. Conformation and reactivity in

acylic systems – steric and stereoelectronic effects – cis elimination, E2 elimination,

intramolecular rearrangement – neighbouring group participation.

Reactivity in cyclohexane systems – esterification – oxidation – substitution reaction – E2

elimination –intramolecular rearrangements - neighbouring group

participation.Conformations of decalins and perhydro- phenanthrenes.

Unit IV Aromaticity and Novel rings

Benzenoid and non – benzenoid aromatic compounds – Huckel’s rule – concept of

aromaticity, homoaromaticity and antiaromaticity – Systems with 2, 4, 6, 8 and 10 electrons –

annulenes, azulene, tropolones and sydnones. Nomenclature of bicyclic and tricyclic systems

Unit V Oxidation – Reduction

Hydroxylation involving permanganate and Osmium tetroxide - Baeyer – Villiger oxidation,

Barbier – Wieland degradation -Oxidation with silver carbonate as silver oxides (Fetizon’s

reagent) - DMSO oxidation – PDC – Lemieux Von Rudloff reagent – Lemieux Johnson

Reagent. Vilsmeier reaction – super hydride – selectrides - sodium cyano borohydride – Di-

isobutyl aluminum hydride – Birch reduction.

References:-

Unit I

1. J.March, Advanced Organic Chemistry – Wiley – 4TH edition , 1992

2. I.L. Finar Organic Chemistry – Vol.II ELBS, 5thedition , 2000

3. P.Sykes A Guide book to mechanism in Organic chemistry orient Longman, 1989

4. J.M. Harris and C. Wamser Fundamentals of organic reaction mechanism – Wiley &

sons, 1976

5. S.M. Mukherji & S.P. Singh Reaction mechanism in Organic Chemistry Macmilan

India Ltd, 2015.

6. F.A.Carey and R.J. Sundberg Advanced Organic Chemistry Part A –Springer, 2007.

7. F.A. Carey Organic Chemistry Tata MC Graw Hill, New Delhi 5th reprint 2005

8. MichaEl B.Smith, Organic synthesis – McGraw Hill International Edition Chemistry

series 1994

9. Paula Yurkanis Bruice Organic Chemistry. Third Edition Pearson Education Asia,

2002.

Units II&III

1. E.L. Eliel, Stereo Chemistry of Carbon compounds – Mcgraw hill 1999

2. I.L. Finar Organic Chemistry Vol, II – ELBS, 5th edition, 2000

3. K.Mislow Introduction to stereochemistry – W. A. Benjamin, 1965

4. V.M.Potapov, Stereo Chemistry - Mir Publishers 1979

13

5. P.S. Kalsi, Stereo Chemistry – Conformation and Mechanism – New age international

(P) Ltd., 2000

6. Paula Yurkanis, Organic Chemistry – Third Edition – Pearson Education Asia 2002

7. Micheal B.Smith, Organic Synthesis – Mc Graw Hill International edition, 1994

Unit IV

1. G.M Badger, Aromatic Character and Aromaticity Cambridge Chemistry Text book

Series, 1969

2. P.J. Garratt, Aromaticity – Mcgraw Hill International edition, 1971

3. Jerry March, Advanced Organic Chemistry – Wiley, 5thedition , 1992

4. I.L. Finar, Organic Chemistry Vol I – ELBS, 5th edition 2000

5. A.N. Nesemaynov and N.A. Nesmeyanonv, Fundamentals of organic chemistry Vol

2 MTR Publishers, 1977

6. R.E. Ireland Organic synthesis, Prentice Hall of India Private Ltd, New Delhi, 1988

Unit V

1. J.March, Advanced Organic Chemistry Wiley , 5th edition 1992

2. R.T. Morrison & R.N Boyd, Organic Chemistry – 6th edition Prentice Hall 1994

3. Michael B.Smith, Organic synthesis Mcgraw Hill International edition 1994

4. R.O.C. Norman, Principles of organic synthesis – Chapman and Hallk London

1993

5. W. Carruthers, Some modern methods of organic synthesis- Cambridge university

press 1983

6. P. Sykes, A Guide book to mechanism in Organic chemistry – Orient Longman,

1989

7. J.M Swan and D.S. & C. Black Organometallics in organic synthesis, Chapman

and Hall, London, 1974

8. Gurdeep Chatwal – M. Yadav Organometallic Chemistry – Himalaya publishing

house., 1st edition, 1992

14

Inorganic Chemistry I

Core-2 Inorganic Chemistry – I hours/ week-5

Sub Code: 18-1PCY02 Credits-4

Objectives

• To make students understand the theory and applications of nuclear chemistry,

• Tounderstand the structure and applications of inorganic chains, rings and cage

• compounds

• To get an idea about the various crystal structures and defects

• To get an idea about stability and reaction mechanism of co-ordination complexes

• To study about Lanthanides and Actinides.

Unit I Nuclear Chemistry

Thermal and nuclear reactions, Q-value, capture cross section, threshold energy and

excitation functions. Types of nuclear reactions – spallation, fission and fusion – Fissile and

Fertile isotopes. Nuclear fission – characteristics – product distribution – theories of fission

(liquid drop model only) – Nuclear fusion and stellar energy, Nuclear reactors – Nuclear

materials and waste disposal. Radiation hazards and protection, Atomic power projects in

India.

Unit II Inorganic chains, rings and cages

Silicates – Classification of silicates with examples – Structures of ortho, pyro, chain, cyclic

and sheet silicates. Structure and properties of zeolites ,Felspar and ultramarine– Intercalation

chemistry of Graphite – physical properties of intercalation compounds. Polymeric sulphur –

nitrogen compounds – phosphonitrilic compounds – Boron nitride - Borazines – General

methods of preparation, and properties of boranes – Structure and bonding in boranes -

Preparation, properties and structure of carboranes – Wade’s rules.

Unit III Solid state Chemistry

Structure of typical crystals such as Rock salt, Zinc blende, Wurtzite, Fluorite, Anti Fluorite,

pervoskite, Cdl2, Rutile and CsCl. Crystal defects – points, line and plane defects – Instrinsic

point defects – Schottky and Frenkel defects – Extrinsic point defects – non

CO.

No.

Students will able to PSO

Addressed

Cognitive

Level

CO-1 learn about the various types of nuclear reactions and

also about the disposal of nuclear waste

PSO1,PSO7 K

CO-2 attain more knowledge about silicates, boranes and

carboranes.

PSO1,PSO7 K

CO-3 understand the type of crystal defects and study about

super conductors and their applications.

PSO1,PSO7 U

CO-4 Understand the reaction mechanisms and methods of

determination of stability constant.

PSO1,PSO7 U

CO5 Understand the chemistry of Lanthanides and actinides. PSO1,PSO7 U

15

stoichiometricdefects, colour centers – Electronic structure of solids – free electron and Band

theory – Types of solids – conductors, insulators, Intrinsic and extrinsic semiconductors –

Band structure and applications. Super conductor – high temperature super conductors –

Properties and applications.

Unit IV Coordination Chemistry – I

Stability of complexes – stepwise and overall stability–Factors affecting stability of

complexes, chelate and template effect. Determination of stability constant, by

potentiometric, Bjerrum and spectrophotometric methods. Reaction Mechanisms –ligand

substitution reactions of square planar complexes – Trans effect and its theories – use of trans

effect in synthesis of complexes – substitution reactions in octahedral complexes – Acid

hydrolysis, Base hydrolysis and anation reaction. Electron transfer reactions –

complementary and non – complementary reactions – lnner sphere and outer sphere

mechanisms.

Unit V Lanthanides and actinides

Lanthanides and actinides correlation of electronic structures – occurrence and properties of

the elements – chemistry of separation of Np. Pu and Am from U fission products – common

and uncommon oxidation states – comparison with transition elements – lanthanide and

actinide contractions –spectral and magnetic characteristics of lanthanides and actinides –

similarities between actinides and lanthanides.

References

1. Samuel Glasstone, Source Books of Atomic Energy East West press private Ltd.,

New Delhi, 1969.

2. H.J. Arnikar Essentials of Nuclear Chemistry Wiley Eastern Ltd., India 4th Edn.,

2000.

3. L.V. Azaroff Introduction to solids Tata Megraw Jill publishing Ltd., New Delhi

1989.

4. G. Friedlander, J.W. Kennedy and N.M. Miller, Nuclear and Radiation Chemistry,

John Wiley, 1981.

5. James E. Huheey, Ellen A. Kieter and Richard L. Kieter Inorganic Chemistry, 4th

Edition, Happer college publishers, 1993.

6. F.A. Cotton, Geoffrey Wilkinson, Carlos A. Marilo and Manfred Bocyhman,

Advanced Inorganic Chemistry, Wiley Inter science publication. 6th De., 1999.

7. G.S. Manku, Theoretical Principles of Inorganic Chemistry, Tata McGraw Hill, 12th

reprint, 2004.

8. K.F. Purcell and J.C. Kotz, Advanced Inorganic Chemistry, Saunders Goldern

Publishers.

9. M.C. Day Jr and selbin, Theoretical Inorganic Chemistry, 2nd Ed., East West Press

2000.

10. J.D. Lee, Concise Inorganic Chemistry, ELBS, 2006.

11. A.F. Wells, Structural Inorganic Chemistry Oxford science Publication, London,

1971.

16

PHYSICAL CHEMISTRY – I

Core-3 Physical Chemistry – I hours/ week-5


Objectives

• To use concepts of thermodynamics/kinetics/equilibrium to make predictions and give

explanations about chemical systems and fundamental properties of matter .

• To gain an in-depth knowledge of electrochemistry,

• To gain a knowledge of the postulates of Quantum Mechanics

CO.

No.




PSO

Addressed

Cognitive

Level

CO1 Learn the reaction rate theories and reactions in

solution.

PSO1, PSO7 K, U

CO2 Explain the applications of irreversible

thermodynamics.

PSO1, PSO7 K, U

CO3 Study the theory of Debye Huckel rule, limitations

and its applications, structure of electrical double

layers of Stern-Guoy-Chapman model

PSO1, PSO7 U

CO4 Draw the phase diagram for ternary systems. PSO1, PSO7 K, U

CO5 Understand the basic principles of Quantum

Mechanics

PSO1, PSO7 K, U

Unit I Chemical Kinetics

Reaction in solution, factors affecting reaction rates in solution, ARRT to reactions in

solution, volume of activation and its significance, primary and secondary salt effects -

acidity functions- Bronsted relationship. Fast reaction techniques – relaxation methods,

temperature jump and pressure jump method- reactions in flow systems, continuous and

stopped flow.

Unit II Irreversible Thermodynamics

Non equilibrium thermodynamics – entropy production-heat flow, matter flow for open

system-forces and fluxes-Onsagar reciprocal relationship-verification. Thermoelectricity-

electro kinetic and thermomechanical effects-application of irreversible thermodynamics to

biological systems.

Unit III Electrochemistry-I

Debye–Huckel theory of ion interaction – derivation and experimental verification – Activity

coefficient – Debye-Huckel limiting law - Verification and Modifications of Debye- Huckel

limiting law – Kinetics of electrode processes – Butler Volmer equation- Tafel curves-

polarisable and non polarisable electrodes– Lipmann equation - electrical double layer-Stern

model,Guoy model-Chapman model-electro capillary phenomena

17

Unit IV Phase rule

Three component systems –Graphical representation of ternary system- partially miscible

three liquid systems- formation of one pair, two pairs and three pairs of partially miscible

liquids,phase diagram-effect of temperature-systems composed of two solids and a liquid,no

chemical combination,double salt formation(not decomposed, decomposed),hydrate

formation(not dehydrated, dehydrated),–Schreinemaker’s wet residue method.

Unit V Quantum Mechanics – I

Schrodinger time independent equation- Wave function - operators – linear and hermitian

operator- method of setting up of quantum mechanical operators-. Eigen functions and

eigenvalues – Degeneracy- Orthogonality and normalisations of wave functions, commuting

and non commuting operators – Non commuting operators and uncertainty principle-

Postulates of quantum mechanics

References

1. K.J. Laidler, Chemical Kinetics, Tata McGraw Hill, New Delhi.

2. Gurdeep Raj,Chemical Kinetics,Goel Publishing House,Meerut,VI Revised Edition.

3. Samuel H.Maron and Carl F.Prutton, Principles of Physical Chemistry, Oxford and

IBH Publishing Co.Pvt.Ltd, NewDelhi, Fourth Edition.

4. S. Glasstone, Thermodynamics for Chemists, van Nostrand Co.Inc., New York.

5. J.Rajaram and Kuriacose,Thermodynamics for Students of Chemistry,Shobanlal

Nagin Chand &Co.,Jalandhar,Second Edition.

6. L.Antropov, Theoretical electrochemistry, MIR Publications, Moscow.

7. S.Glasstone, An introduction to Electrochemistry, van Nostrand, New York.

8. B.Viswanathan, S. Sundaram and others, Electrochemistry-principle and applications,

S.V. Publishers Pvt Ltd, Chennai, first edition ,2000.

9. J.N.Gurtu and Mrs S. Razdan, Phase Rule, Pragati Prakashan, Meerut, India.

10. Gurdeep Raj, Phase Rule, Goel Publishing House, Meerut, U.P

11. A.K.Chandra,Introductory Quantum Chemistry,Tata McGraw Hill,Co.Ltd, New

Delhi, Fourth Edition,1994.

12. I.N.Levine,Quantum Chemistry,Prentice Hall of India,New Delhi,Fourth Edition.

18

Elective-1

Elective-1 Advanced topics in Inorganic Chemistry hours/ week-4

Sub Code: 18-1PCYE1 Credits-4

Objectives

• To gain an in-depth knowledge in Bio- Inorganic Chemistry,

• To understand the chemistry of Supramolecular compounds

• To understand the charactercteristics of Organometallic compounds

Unit I Inorganic Chemistry in Biology I

Metalloenzymes and their synthetic models. Enzymes in dioxygen managements-superoxide

dismutase, peroxidises and catalases, oxidases and mono oxygenases (cytochrome P450). Zinc

enzymes-carbonic anhydrase, carboxy peptidase and alcohol dehydrogenase; the structural

role of zinc and zinc constellations.

Unit II Inorganic Chemistry in Biology II

Inhibition and poisoning of enzymes – Xanthine oxidase and metallothionines. Ionophores

(valinomycin) and Na/K+ pump in cells. Biological role of calcium. Chelate therapy –

therapeutic chelating agents, anti-cancer Pt complexes and their interaction with nucleic

acids. Cu in Wilson’s disease– Gold compounds and antiarthritic agents. Metal complexes as

probes of nucleic acids.

Unit III Supramolecular compounds

History, development and classification chelate, macrocyclic and template effect, cation

binding hosts-crown ethers, cryptands and spherands, metal ion selectivity of crown ethers

and cryptands.

Unit IV Inorganic Materials

Synthesis of inorganic materials, high temperature reactions and experimental methods,

solution and hydrothermal methods and low temperature reactions electronic, magnetic and

optical properties of inorganic materials. Fullerences: Buckminster fullerences and fullerides.

Unit V Organometallic Chemistry

Transition metal – hydrogen compounds. General synthetic methods, Chemical behaviour,

characterization and H bridges, mononuclear polyhydrides, carbonyl hydrides and molecular

CO.

No.

Students will able to PSO Addressed Cognitive

Level

CO-1 Understand the biological processes and self-

assembling systems.

PSO1, PSO5,PSO7 K

CO-2 Constructing complex materials and molecular

machinery.

PSO1, PSO2,PSO7 U

CO-3 Acquire an advanced level of knowledge in

supramolecular chemistry.

PSO1, PSO2, PSO7 U

CO-4 Get an in-depth knowledge in inorganic

materials.

PSO1, PSO5,PSO7 U

CO5 Know about organometallic chemistry PSO1, PSO5,PSO7 A

19

hydrogen compounds. Transition metal-carbon compounds, metal-c-single bond compounds

and their reactions, alkylidyne complexes. Cyclometallation reactions.

References

1. J.E Huheey, E.A. Keeter and R.A. Keiter, Inorganic Chemistry 2,3 & 4th edn, Harper

Collins College Publishers, New York 1993.

2. I. Bertini, H.B. Gray, S.J. Lippard and J.S. Valentine, Bioinorganic Chemistry, Viva

Books Pvt. Ltd., New Delhi 1998

3. B. Douglas, D. Mc Daniel and J. Alexander, Concepts and Models of Inorganic

Chemistry 3rd ed, John wiley & sons, New York 1994

4. F.A. Cotton & Wilkinson, Advanced Inorganic Chemistry 3,4, & 5th edn., John wiley &

sons Ltd., New York 1988.

5. J.W. Steed and J.L Atwood, supramolecular Chemistry, John wiley &nsons Ltd., New

York 2000.

6. M.T. Weller, Inorganic materials Chemistry Primers, Oxford Science publications,

Reprint 1996.

7. D.E. Fenton, Bio co-ordination Chemistry, Oxford Chemistry Primers, Oxford Science

Publications,1995.

SEMESTER I

Core Practical 1 Organic analysis of bifunctional compoundsandPreparations- Hrs / Week 4

Subject code : 18-1PCYL01

Credit 2

CO.

No.





Level

CO1 understand the systematic organic substances

analysis.

PSO1,PSO4,PSO6 A

CO2 understand the tests involved in the identification of

special elements and detect the various functional

groups.

PSO1,PSO4,PSO6 A

CO3 prepare solid derivatives for functional groups PSO1,PSO4,PSO6 A

CO4 prepare simple organic compounds. PSO1,PSO4,PSO6 A

CO5 understand the techniques involved in drying and

recrystallization by various methods

PSO1,PSO4,PSO6 A

Examination hr:6

20

I. Analysis of a bifunctional compound

a. Elements present

b. Saturation / Unsaturation

c. Aliphatic / Aromatic

d. Functional group

e. Solid derivative

Semi micro preparation and capillary reactions are recommended for saving the

cost of chemicals.

II. Preparations

1. p- Bromoacetanilide from acetanilide

2. m- Nitro benzoate from methyl benzoate

3. p- nitro acetanilide from acetanilide

4. Preparation of Neroline from β-naphthol

5. Dibenzalacetone from benzaldehyde

6. Preparation of di-β-naphthol from β-naphthol

7. Preparation of Anthroquinone from Anthracene

8. Preparation of Benzilic acid from Benzil

9. Preparation of 1,2,3,4 tetrahydrocarbazole from cyclohexanone

10. Preparation of benzophenoneoxime from benzophenone

Students are expected to submit at the time of practical examination, atleast six

recrystallised samples of the derivatives they have prepared during the regular course of

analysis

Course Outcome

Students will be able to

• understand the systematic organic substances analysis.

• understand the tests involvedin the identification of special elements

• learn and detect the various functional groups.

• prepare solid derivatives for functional groups.

• prepare simple organic compounds.

• .

Reference:

Lab Manual prepared by Department of Chemistry, Sarah Tucker College

Evaluation for Practicals

Internal Assessment – 40 Marks, External Assessment – 60 Marks: Total : 100 Marks

Distribution of Marks Exam hour- 6h

Internal Assessment : 40 Marks External Assessment : 60 Marks: Total

21

Attendance : 10 Experiment :40

100 Experiment = 20 Viva-voce :5

Model = 10 Record: 15

I SEMESTER

Core Practical 2 Inorganic Chemistry – I

Hrs / Week : 4

Subject code : 18-1PCYL02 Credit : 2

1. Semi micro qualitative analysis of inorganic mixture containing two less-familiar

cations and two familiar cations .

W, , Se, Mo, Ce, Th, Zr, Ti, V, U and Li

Pb.Bi,Cu,Cd,Mn,Ni,Co, Zn, Ba and Sr

References:

1. V.V. Ramanujam, ‘Inorganic Semimicro Qualitative analysis, 3rd revised Edn, The

National publishing Co., Chennai, 1988.

2. ‘Vogel’s Text Book of Quantitative Chemical Analysis’, Eds. G.H. Jeffrey, J.Banett, J.

Mendham and R.C. Denney, ELBS, 5th Edn. Reprint 1991.

Examination hr:6







CO.

No.





Level

CO1 Identify rare and common metals using semi

micro method.

PSO1,PSO4,PSO6 A

CO2 Analyse metal ions from water and other

industrial effluents.

PSO1,PSO4,PSO6 A

CO3 Acquire knowledge of experimental skills.

PSO1,PSO4,PSO6 A

22


SEMESTER I

Core Practical -3 Physical Chemistry Practical–I

Hrs / Week : 4


Examination hr:6

1. Thermo chemistry

Solution enthalpy by thermometric method, Determination of unknown weight of solute

in the given solution

a) Ammonium oxalate/Water

b) Naphthalene/Toluene

2. Conductivity:

a) HCl + CH3COOH Vs NaOH

b) NH4Cl + HCl Vs NaOH

3.Phase Diagram for compound formation

a) Naphthalene-metadinitrobenzene

b) Diphenylamine-benzophenone

4. Kinetic study of hydrolysis of methyl acetate

CO.

No.





Level

CO1 Determine the heat of solution and solubility of

any compound.

PSO1,PSO4,PSO6 A

CO2 Understand compound formations in phase

diagram

PSO1,PSO4,PSO6 A

CO3 Carry out Conductometric titrations to check for

the presence of pollutants in soil and water.

PSO1,PSO4,PSO6 A

CO4 Calculate the rate of reactions using kinetic studies

PSO1,PSO4,PSO6 A

23

Reference:

Lab Manual prepared by Department of Chemistry, Sarah Tucker College








SEMESTER-II

Core-4 Organic Chemistry – II hours/ week-5


Objectives

• To understand the mechanism of substitution and addition reaction.

• To study the chemistry of mechanism heterocyclic compounds and Terpenoids

• To learn the importance of amino acids, proteins and enzymes.

CO.

No.





Level

CO -1 Acquire knowledge about the mechanism of

nucleophilic, electrophilic and elimination

reactions.

PSO1,PSO5,PSO7 U

CO-2 Learn the mechanism of addition reactions of

carbon – carbon double bond.

PSO1,PSO5,PSO7 A

CO-3 Study the preparation and properties of some

heterocyclic compounds.

PSO1,PSO5,PSO7 U

CO-4 Study of terpenoids, its classification,isoprene

rule and the structure elucidation of some

important terpenoids.

PSO1,PSO5,PSO7 U

CO-5 Learn about the classification and biological

role of Amino acids and Proteins and the

theories of enzymes and kinetics of enzyme

PSO1,PSO5,PSO7 U

24

Unit I Reaction Mechanism

Aliphatic Nulceophilic substitution: SN1 and SN2 mechanism – Effect of substrate structure,

attacking nucleophile, the leaving group & reaction medium – ambident nucleophiles –

competition between SN1 & SN2 reaction in benzylic, vinylic and arylhalides – SNi

mechanism and NGP. Aromatic nucleophilic substitution: SNAr, SN1 and benzyne

mechanism.

Unit II Addition to carbon- carbon multiple bonds

Addition to carbon – carbon double bond – Mechanism and stereochemical factors in the

following: Hydrogen, halogen, hydrogen halides, hypohalous acid, ozone, hydroboration,

hydroxylation, Michael addition and epoxidation. Addition of hydrogen to carbon – carbon

triple bond

Unit III Heterocyclic compounds

Synthesis and reactions of oxazole, Imidazole, Thiazole. coumarins. Structure elucidation of

flavones, cyanin, caffeine, Theobromine and Theophylline.

Unit IV Terpenoids

Classification – Isoprene rule – Structure elucidation of α-pinene, camphor, zingiberene, α-

cadinene, squalene and abietic acid – Biosynthesis of mono and di terpenoids.

Unit V Amino acids, Proteins and Enzymes

Introduction- - Peptide bond - synthesis of peptides by solid phase technique-Proteins

– classification – properties- structure- determination of amino acid sequence –denaturation

and renaturation of protein molecules –synthesis and structural elucidation of glutathione and

oxytocin.

Classification and properties-specificity, -Mechanism of enzyme action – Lock and Key

model and induced fit models-Kinetics of enzyme reaction-Michaelis-Menten equation

(derivation)-Km and Vmax –their significance-LB plot inhibition-Mechanism of inhibition

(competitive, non- and uncompetitive)- Cofactors – prosthetic groups of enzymes

Reference:

Unit I

1. J. March Advanced Organic Chemistry – Wiley, 5th edition 1992

2. P. Sykes, A Guide book to mechanism in Organic Chemistry in Organic Chemistry –

1989

3. R.T. Morrison &.N. Boyd, Organic Chemistry, Prentice Hall of India Private Ltd,

New Delhi, 1999.

Units II

1. J. March, Advanced Organic Chemistry Wiley , 5th edition 1992

action

25

2. R.T. Morrison & R.N Boyd, Organic Chemistry – 6th edition Prentice Hall 1994

3. Michael B.Smith Organic synthesis Mcgraw Hill International edition 1994

4. R.O.C. Norman, Principles of organic synthesis – Chapman and Hallk London 1993

Unit III

1. R.M. Acheson, Chemistry of Heterocyclic Compounds _Wiley Eastern 1973

2. I.L.Finar, Organic Chemistry, Vol. II ELBS, 5th edition, 2000

Unit IV

1. I.L. Finar Organic Chemistry – Vol. II ELBS, 5thedition , 2000

2. O. P. Agarwal, Chemistry of Organic Natural Products, Vol. 2, Goel Publishing

House, Meerut, 1997.

Unit V

1. Lehninger, Principles of Biochemistry, Fourth Edition, by David L. Nelson and

Michael M. Cox, Worth Publishers, New York, 2005.

2. Lubert Stryer, Biochemistry, W. H. Freeman and company, New York, 1975.

3. J. L. Jain, Biochemistry, Sultan Chand and Co.1999

Inorganic Chemistry- II

Core-5Inorganic Chemistry- II hours/ week-4


Objective

• To study the concept of Chemical bonding & Stereochemistry

• To gain Knowledge in Inorganic Chemistry of biological systems &Acid-Base

Chemistry and Non-aqueous Solvents.

• To give an insight into the Organometallic Chemistry

• To gain knowledge in inorganic chemistry of biological systems

CO.

No.

Students will able to PSO Addressed Cognitive

Level

CO-1 Apply the VSEPR model to determine the

molecular geometry.

PSO1,PSO5,PSO7 K

CO-2 Predict the types of intermolecular forces that a

compound can exhibit based on their structure.

PSO1,PSO5,PSO7 U

CO-3 Acquire a thorough Knowledge about various non

aqueous solvents.

PSO1,PSO5,PSO7 U

CO-4 Gain knowledge about the chemistry of metal

carbonyls and metallocenes.

PSO1,PSO5,PSO7 K

CO5 Study the applications of homogenous and

heterogenous catalysis and Know the importance

PSO1,PSO5,PSO7 U

26

Unit I Chemical bonding & Stereochemistry

VSEPR theory-Walsh diagram (triatomic molecules). Bent’s rule Apicophilicity dπ-pπ

bonds,M.O theory- symmetry and overlap. M.O.diagram of CO, F2, HF, and BeH2. Different

types of electrostatic interactions and their effects on properties. Fluxionality – Fluxional

molecules – Inversion of pyramidal molecule. Planar- tetrahedral interconversion. Trigonal

bipyramidal- square pyramidal interconversion.

Unit II Acid-Base Chemistry, Non-aqueous Solvents

Acid base concept – Arrehenius, Lowry-Bronsted, Lewis and Lux flood concepts. HSAB

concept - Theory and applications - symbiosis.Non-aqueous solvents, General properties and

classification of solvents, self ionisation and levelling effect. Reactions in non-aqueous

solvents – solute-solvent interaction.Reactions in Liquid NH3,Liquid SO2, Liquid H2SO4 and

liquid HF.

Unit III Organometallic Chemistry-I

Introduction - EAN rule & its correlation to stability - Metal carbonyls – General method of

preparation, properties, structure and bondingin metal carbonyls– IR study of metal

carbonyls. Preparation, properties and structural features of metal complexes with alkene,

allyl and arene(Chromocene). Metallocenes - Preparation, properties structure and bonding

in ferrocene.

Unit IV Organometallic Chemistry-II

Oxidative addition and reductive elimination. Insertion and elimination reactions;

Homogeneous catalysis - Wilkinson’s catalyst, (alkene hydrogenation-) Hydroformylation

and wacker process, carbonylation of alcohols and oxygenation of olefins. Heterogeneous

catalysis- Fischer Tropsch process and Ziegler- Natta polymerization.

Unit V Inorganic Chemistry of biological systems

Essential and trace elements in biological systems- Biological importance and toxicity of the

following element in biological systems. a) transition metals – Fe,Cu,Mo,W,V,Mn,Co and

Cr. b). Non metals- boron, silicon,bromine, Fluorine,iodineandSelenium. Metalloporphyrins-

Chlorophyll photosynthetic electrons transport sequence – biological electron transfer agents-

cytochromes- Iron sulphur protein- haemoglobin and myoglobin- corrin ring system- Vitamin

B12. Nitrogen fixation invivo and invitro.

References

1. James E. Huheey, Ellen A Keeter and Richard L. Keiter Inorganic Chemistry: Principles

of structure and Reactivity Harper Collin’s college publishers, Asia 1993.

2. F. Albert cotton Geoffrey Wilkinson culos A. Munioland Manfred Bochman, Advanced

Inorganic Chemistry Wiley Interscience publications New York 1999

of metals in biological systems

27

3. G.S Manku Therotical principle of Inorganic Chemistry, Tata Mcgraw Hill, New Delhi,

12th reprint 2004.

4. B.E Douglas, D.H Mc Daniel and J.J. Alexander Concepts and Models of inorganic

chemistry John wiley and sons, 3rd Edn 1994.

5. I. Bertinin H.B Gray S.J.Lippard and J.S. Valentine Bioinorganic Chemistry. Viva Book

Pvt Ltd.., New Delhi 1998.

6. K.F Purcell and J.C Kotz Advanced Inorganic Chemistry Saunders Golden publishers.

7. M.C Day Jr.and J.Selbin Theoretical Inorganic chemistry 2nd Ed East West Press Pvt.

Ltd..,2000

8. Chemistry in Non-aqueous solvents. Harry.H.Sisler Chapman and Hall Ltd.

9. Lubert Stryer, Biochemistry, W.H. Freemanand Company, New York, 1975.

PHYSICAL CHEMISTRY – II

Core-6 Physical Chemistry – II hours/ week-5 Sub Code: 18-2PCY06 Credits-4

Objective

• To solve the Schrödinger equation to obtain wave functions for some basic, physically

important systems

• To understand different approximation methods in quantum mechanics

• To apply the relevant equilibrium ensemble in a given situation

• To derive partition functions for the various ensembles.

• To study the various processes of photochemistry in detail

• To learn the importance of adsorption and adsorption isotherm

CO.

No.





Level

CO1 Apply the principles of Quantum Mechanics to

simple systems.

PSO1,PSO5.PSO7 K,U,A

CO2 Understand the different approximation

methods used in Quantum Mechanics.

PSO1,PSO5.PSO7 K,U

CO3 Learn the Maxwell – Boltzmann, Fermi – Dirac

and Bohr’s Einstein statistics Comparison and

applications to know about the Partition

functions.

PSO1,PSO5.PSO7 K,U

CO4 Explain the importance of electronically excited

molecules.

PSO1,PSO5.PSO7 K,U

CO5 Gain knowledge about adsorption isotherms. PSO1,PSO5.PSO7 K

28

Unit I

Quantum Mechanics – II Applications of quantum mechanics to simple system – free

particle- particle in ID Box- particle in 3D (Cubic and rectangular) box- simple harmonic

oscillator- rigid rotator - hydrogen atom.

Unit II Quantum Mechanics – III

Approximation methods – perturbation theory (first order only) and variation method – Born

Oppenheimer approximation secular equation and secular determinants – Helium atom–

electron spin and Pauli’s principle- Slater determinant –– Hartree- Fock self consistent field

method of many electron systems. LCAO approximation - M.O. method for H2+ and H2

Unit III Statistical Thermodynamics

Aim of statistical thermodynamics–Ensembles-microstates,macrostates Maxwell -

Boltzmann distribution law and its derivation – partition functions- Derivation of expressions

for translational, rotational and vibrational partition functions. Thermodynamic properties

from partition functions-E, S, A, H, G, P, Kp, Cp and Cv. Sacker–Tetrode equation- quantum

statistics – Fermi Dirac and Bose Einstein statistics, Einstein’s and Debye theories of heat

capacities of solids.

Unit IV Photochemistry

Physical properties of electronically excited molecules-excited state dipole moment-excited

state redox potentials-photo physical processes in electronically excited molecules-Jablonski

diagram-delayed fluorescence, P- type and E-type -Stern-Volmer equation and its

applications-experimental techniques in photochemistry-chemical actinometry

Unit V Surface Chemistry

Adsorption and absorption- adsorption of gases on solids-types, physisorption and

chemisorption - adsorption and desorption- Adsorption isotherms –types(I-V)- Derivation of

Langmuir, BET and Gibbs adsorption isotherms-Determination of surface area-Methods,

Harkins and Jura, Benton and White, BET, Point B, Adsorption on semiconductor surfaces.

References

1. A.K.Chandra,Introductory Quantum Chemistry,Tata McGraw Hill,Co.Ltd, New

Delhi, Fourth Edition,1994.

2. I.N.Levine,Quantum Chemistry,Prentice Hall of India,New Delhi,Fourth Edition.

3. J.Rajaram and Kuriacose,Thermodynamics for Students of Chemistry,Shobanlal

Nagin Chand &Co.,Jalandhar,Second Edition.

4. P.W.Atkins,Physical Chemistry,VI Edition,Oxford University Press,Oxford,1998.

5. Samuel Glasstone,Theoretical Chemistry,East-West Student’s Edition,1973.

6. K.K.Rohatgi Mukherjee,Fundamentals of Photochemistry,New Age International

Publishers,1986.

7. Dr. Gurdeep Raj, Advanced Physical Chemistry,Goel publishing house, Meerut,20th

revised and enlarged edition.

8. Gurdeep Raj,Surface Chemistry,Goel Publishing House,Meerut,III Edition

29

Elective–2

Elective 2: Research Methodology and Green Chemistry

Chemistry

hours/ week-4 Sub Code: 18-2PCYE2 Credits-4

Objectives:

• To understand the steps involved in research methodology

• To know the importance of green chemistry

• To learn the principles and applications of chromatographic techniques

Unit – I: Literature Survey and choosing a research problem

Survey of literature including patents. primary source – secondary source – including reviews

– treatise and monographs – literature survey – abstraction of research papers – possible ways

of getting oneself familiar with current literature.

Identification of research problem assessing the status of the problem guidance from the

supervisor – actual investigation and analysis of experimental results – communication, paper

etc., writing a thesis.

Unit – II: Introduction to green chemistry

Relevance and goals Anastas ‘twelve principles of green chemistry’ – Tools of green

chemistry: alternative starting materials, reagents, catalysis, solvents and processes with

suitable examples.

Unit III: Microwave mediated organic synthesis

CO.

No.


On successful completion of this

course, student should be able to:

PSO Addressed Cognitiv

e Level

CO -1 Learn about literature survey and the

art of thesis writing.

PSO2,PSO3,PSO5,P

SO6

U,K,A

CO-2 Know and understand the 12

principles of Green Chemistry and

distinguishing between recyclable and

non-recyclable materials

PSO1, PSO2,

PSO5,PSO6

U,K

CO-3 Learn and utilize microwaves for

carrying out organic reactions and

use solventless reactions as green

reactions.

PSO1, PSO2,

PSO5,PSO6

U,K

CO-4 Get some ideas about heterogeneous

catalysts and biocatalysts

PSO1, PSO2,

PSO5,PSO6

U,K,A

CO-5 Learn the importance of purification

and separation techniques

PSO1,PSO5 U,K,A

30

Microwave activation – advantage of microwave exposure – specific effects of microwave –

Neat reactions- solid support reactions – functional group transformations – condensation

reactions- oxidations, reduction reactions – multi component reactions

Green solvents- solvent free reactions- Reactions in Supercritical fluids-ionic liquids

Unit IV Supported catalysis and biocatalysts for green chemistry

Introduction – The concept of atom economy – supported metal catalysts – mesoporous

silicas – the use of Biocatalysts for green chemistry – modified biocatalysts – fermentations

and biotransformation – fine chemicals by microbial fermentations – vitamins and amino

acids – Baker’s yeast mediated biotransformations – biocatalyst mediated Baeyer – villiger

reactions – microbial polyester synthesis.

Unit V: Chromatographic Techniques

Principle and operation of column, thin layer gas and paper chromatographic methods. HPLC

and HPTLC – applications to organic compounds. Principle of Ion-exchange- preparation and

types of ion exchange resins – cation exchangers, anion exchangers – analytical applications

– solvent extraction methods,

References:

1. C. Mahadevan, Research Methodology, Sakuntala Publication, Nagercoil 1st edition

(2000).

2. Green Chemistry – Environmentally benign reactions – V.K.Ahluwalia. Ane Books

India (Publishers). (2006).

3. Green Chemistry – Designing chemistry for the environment- edited by

Paul.T.Anastas& Tray C.Williamson . Second edition, (1998)

4. Green Chemistry – Frontiers in benign chemical synthesis and processes – edited by

Paul.T.Anastas& Tray C.Williamson. Oxford University Press. (1998).

5. Green Chemistry – Environment friendly alternatives – edited by Rashmi Sanghi &

M.M. Srivastava, Narora Publishing House. (2003).

SEMESTER II

Core Practical 4 Separation and analysis of organic mixture

Hrs / Week : 4


CO.

No.




PSO Addressed Cogniti

ve

Level

CO -1 familiarize the solubility of organic

substances in ether.

PSO1,PSO4,PSO5 A

CO-2 learn the separation of bimixtures PSO1,PSO4,PSO5 A

CO3 understand the tests involved in the

identification of special elements

PSO1,PSO4,PSO5 A

31

Examination hr:6

1. Separation and analysis of two component mixtures.

2. Analysis of the two components and the following are reported

a. Elements present

b. Saturation / Unsaturation

c. Aliphatic / Aromaticd

d. Functional group

e. Solid derivative

3. Capillary reactions are recommended for saving the cost of chemicals.

Course Outcome


• familiarize the solubility of organic substances in ether.

• learn the pilot separation of bimixtures.

• understand the systematic organic substances analysis.

• understand the tests involvedin the identification of special elements

• understand the tests involved in the identification of special elements

• prepare solid derivatives for functional groups.

Reference:

➢ A.I .Vogel,A Text book of practical organic chemistry.

➢ Lab Manual prepared by Department of Chemistry, Sarah Tucker College








CO4 understand the tests involved in the

identification of special elements

PSO1,PSO4,PSO5 A

CO5 prepare solid derivatives for functional

groups

PSO1,PSO4,PSO5 A

32

SEMESTER II

Core Practical -5 Inorganic Quantitative Analysis-I

Hrs / Week : 4


1.Estimation of Cu (II) by EDTA titration in the presence of either Pb(II) or Ba (II).

Separation Pb(II) or Ba (II) by precipitation.

2.Estimation of Zn (II) by EDTA titration in the presence of either Pb(II) or Ba (II).

Separation Pb(II) or Ba (II) by precipitation.

3.Estimation of Cr(III) and Fe(III) in a mixture by EDTA titration (kinetic Masking)

4.Estimation of Mg (II)and Mn (II) in a mixture by EDTA titration. (Masking by F-).

5..Estimation of Pb in solder alloy by EDTA titration.(Masking by F-).

6..Estimation of Ca(II) in antacid or diet supplement pill by EDTA titration (substitution

tion).Calcium in Tablet.

7.Determination of Barium using Methyl thymol Blue Indicator.

8. Estimation of Bismuth using xylenol orange indicator.

References:

1. G.H. Jeffrey, J.Banett, J.Mendham and R.C. Denney Vogel’s, Eds Text Book of

Quantitative Chemical Analysis’, ELBS, 5th Edn. Reprint 1989.

2. I.M.Kolthoff ,V.A.Stenger,Volumetric Analysis,2nd Ed..,Interscience Publishers ,New

york ,1947 ..

3. A.Malathi,Experimental Inorganic /Physical Chemistry An Investigative Integrated

Approach to Practical Project work,Woodhead Publishing Limited ,Reprint 2010.





CO.

No.





Level

CO1 Estimate the metal ions like Cu(II), Zn(II),Cr(III),

Pb(II),Mg (II),Fe (III).

PSO1,PSO4,PSO5 A

CO2 determine metal ions like calium from antacid or

diet supplementary pills.

PSO1,PSO4,PSO5 A

CO3 Estimate two metal ions using kinetic masking

principle .

PSO1,PSO4,PSO5 A

33

SEMESTER II

Core Practical 6 Physical Chemistry Practical-II

Hrs / Week : 4


Examination hr:6

1. Thermo chemistry

Solution enthalpy by thermometric method, Determination of unknown weight of

solute in the given solution

1. Oxalic acid /Water

2. Potassium Dichromate / Water

2. Conductivity:

a. Determination of dissociation constant of a weak acid

b. CH3COONa +CH3COOH Vs NaOH

c. CH3COONa + CH3COOH Vs HCl

d. CuSO4+ HCl vs NaOH

e. HCl+CH3COOH+CuSO4 vs NaOH



Distribution of Marks Exam hour-6h

Reference


➢ Lab Manual prepared by Department of Chemistry, Sarah Tucker College.

CO.

No.





Level

CO1 Determine the heat of solution and solubility of any

compound.

PSO1,PSO4,PSO5 A

CO2 Calculate the dissociation of weak acid.

PSO1,PSO4,PSO5 A

CO3 Carry out Conductometric titrations to check for the

presence of pollutants in soil and water.

PSO1,PSO4,PSO5 A

34

Internal Assessment : 40 Marks External Assessment : 60 Marks Total




SEMESTER-III

Core -7 Organic Chemistry -III Hours/ week :4

Sub Code : 18-3PCY07 Credits :4

Objectives

To learn, understand the principles and applications of UV-Vis, IR, NMR and Mass

spectroscopy.

To study the reactivity of carbonyl group.

To acquire knowledge about general methods of structure elucidation and the

synthesis of alkaloids.

Unit –I Spectroscopy –I

A quick overview of UV and IR spectroscopy -Woodword-Fieser rules, Scott rules.

Application of UV-Vis. Spectroscopy to dienes, polyenes and alpha-beta unsaturated

carbonyl compounds. Absorption spectra of aromatic compounds and heterocyclic

compounds. Stereochemical–factors in electronic spectroscopy-charge transfer complexes

and spectra.

IR

Hooks law-overtone bands, combination bands and Fermi resonance-Finger Print region-

characteristic group frequencies information derivable from IR spectrum (Instrumentation not

CO.

No.




PSO Addressed Cognit

ive

Level

CO -1 Learn and understand the principle and applications

of ultraviolet spectroscopy and infra-red

spectroscopy in organic structure determination

PSO1,PSO5,PSO7 U

CO-2 Know about the Nuclear magnetic resonance

spectroscopy. Proton chemical shift, spin-spin

coupling, coupling constants and applications to

organic structures, 13C resonance spectroscopy,

HOMOCOR, HETCOR, NOESY, DEPT and

INADEQUATE techniques

PSO1,PSO5,PSO7 U

CO-3 Acquire knowledge about Mass spectroscopy PSO1,PSO5,PSO7 U

CO-4 Understand the mechanism of reactions given by

carbon-oxygen double bond

PSO1,PSO5,PSO7 U

CO-5 Gain knowledge about the synthesis and structure

of alkaloids

PSO1,PSO5,PSO7 U

35

necessary), factors influencing vibrational frequency.

Unit –II Spectroscopy-II

CW and FT NMR- relaxation effects- chemical shift-factors affecting chemical shift- spin-

spin splitting-first order spectra-non first order spectra-simplification of complex spectra

using double resonance technique, shift reagents. NOE in stereochemistry, C13NMR

spectroscopy- principle- chemical shift-Introduction to 1-D pulse technique- J- resolved 2D-

NMR- Two dimensional NMR spectroscopy. HOMOCOR, HETCOR, NOESY, DEPT and

INADEQUATE techniques. (Instrumentation not necessary)

Unit –III Mass Spectrometry

Introduction- basic principle- ion production-EI, CI, FAB- molecular ion peak –Base peak-

Metastable peak - Nitrogen rule- Even electron Rule-Mclafferty rearrangement – Retro Diel’s

Alder reaction- factors affecting fragmentation- fragmentation patterns of hydrocarbons,

hydroxyl compounds, alcohols, ethers,ketones, aldehydes, carboxylic acids, amines, nitro

compounds, alicyclic and heterocyclic compounds. Problems based on UV –vis, IR, NMR

and mass spectrometry

ORD and CD

Principle -types of ORD curves- axial haloketone rule-octant rule-applications of these in the

determination of configuration and conformation of simple monocyclic and bicyclic ketones.

Unit-IV Name Reactions

Addition to carbon- oxygen double bonds -Electrophilic, Nucleophilic additions -

stereochemistry of addition. Addition to carbonyl group- Claisen condensation, Darzen

glycidic ester, Wittig, Reformatsky, Grignard, Dieckmann - Chichibabin and Diels Alder

reactions - Stobbe condensation-Ziegler alkylation.

Unit V Alkaloids

Occurrence, classification, structural elucidation and synthesis of quinine, morphine, lysergic

and reserpine and Tylophorine – Biosynthesis of alkaloids.

References

Unit I,II&III

1. W. Kemp , Organic spectroscopy – New York.(Third edition ), palgrave, 2003.

2. S.M. Silverstin, G.V. Bassler and T.C. Morrill - Spectrometric identification of

organic compounds, -Wiley- VI edition, 1981.

3. J.R.Dyer, Application of absorption spectroscopy – Prentice Hall,1987.

4. D. H. Williams and I. Fleming, Spectroscopic Methods in Organic Chemistry, 6th

Edn, McGraw-Hill, New York, 2007

5. D.H. Williams and R.D.Bower, Mass Spectrometry – Principles and Applications – I.

Howe – McGraw Hill.

6. I.L.Finar , Organic Chemistry, Vol II (ELBS) V Edition 2000

7. Jag Mohan, Organic Spectroscopy Principles and Application, Narosha Publishing

36

house, 2000.

Unit IV

1. Michael, B. Smith, Organic synthesis-McGraw Hill international edition, 3th Edn,

2011.

2. R.E. Ireland, organic synthesis, prentice Hall of India(p) Ltd, 1969.

3. F.A. Carey, Organic Chemistry, Tata McGraw hill New Delhi, 5th edition 2005.

4. J.March , Advanced Organic chemistry , Wiley, 4th Edition 1992

5. P.Skyes, A Guide book to Mechanism in Organic Chemistry – Orient Longmann, 1986.

6. R.O.C Norman. Principle of Organic Synthesis, Cambridge University Press , 1983

Unit V

1. I.L. Finar, Organic Chemistry, Vol. II ELBS, 5thedition , Pearson Education.

Singapore , Pvt.Ltd , 2000

2. O.P. Agarwal Chemistry of organic natural produces, Vol.II- Goel Publishing House,

2004.

3. Gurdeep . R. Chatwal, Chemistry of Natural products , Vol II , Goel Publishing House,

2004.

Inorganic Chemistry – III

Core-8 Inorganic Chemistry – III hours/ week-4


OBJECTIVES

• To understand the principle and applications of chromatographic techniques

• To study about the various instrumental analytical techniques.

• To study the preparation and applications of tracer techniques.

37

Unit I Chromatographic Techniques

Principle and operation of column, thin-layer,gas and paper Chromatographic methods.

HPLC and HPTLC - applications to inorganic substances. Ion-exchange –principle, types of

ion exchange resins-cation exchangers, anion exchangers-principle, preparations

andanalytical applications.

Unit II Spectro Analytical Techniques

Spectroanalytical techniques- Principle and applications. Colorimetry- Spectrophotometry

and fluorimetry. Flame photometry, Atomic absorption, atomic emission and atomic

Fluorescence spectroscopy. Light scattering techniques- Nephelometry _ turbidimetry.

Thermoanalytical techniques of Spectra.

UnitIII Thermoanalytical Techniques

Principle, Instrumentation and application of Thermo Gravimetric Analysis (TGA),

Differential Thermal Analysis (DTA) and Differential Scanning Colorimetry(DSC)-Factors

affecting TGA and DTA. Simultaneous TGA and DTA curve. Thermometric Titrations.

Unit IV Electro analytical methods

Stripping voltametry-cyclic voltametry.Coulometry-classification-controlled current

coulometry_ controlled potential coulometry-advantage of coulometric methods.

Amperometry-amperometric titrations.

Unit V Tracer Technique

Preparation of Tracers-Applications of Radioisotopes as traces-chemical investigations-

physico –chemical- Analaytical application-Radio chromatography-Isotopic dilution analysis-

Neutron absorptiometry-and Radiometric titrations-Age determinations- Medical

Applications-agricutural applications and Industrial applications

References

CO.

No.

On successful completion of the course,



Level

CO-I Understand the principle, method and

applications of Chromatography

PSO1,PSO5,PSO7 U

CO-2 Know about the various Spectro Analytical

Techniques

PSO1,PSO5,PSO7 U

CO-3 Learn about the various Thermo Analytical

Techniques

PSO1,PSO5,PSO7 U

CO-4 Know about the various electro Analytical

Techniques

PSO1,PSO5,PSO7 U

CO-5 Understand the preparation and applications of

tracer techniques

PSO1,PSO5,PSO7 U

38

1. D.A.Skoog, F.J.Holler and T.A.Nieman, Principles of Instrumental Analysis, Thomson,

5th edition, 6th reprint, 2006.

2. D.A. Skoog, D M West, F J Holler,S R Crouch, Fundamentals of Analytical

chemistry,Thomson Asia Pvt.Ltd., 8th edition,3th reprint 2005.

3. B K Sharma,Instrumental methods of chemical analysis,Goel Publishing House,23rd

edition 2004.

4. V Suryanarayana Rao, Polargraphy and Alied Techniques,University Press 2002.

5. H H Willard, L L Merritt,J A Dean and F A Settle. Instrumental methods of

analysis,6thedition,CBS Publishers 1986.

6. G H Jeffery, J Bassett,J Mendham and R C Denney,Vogel’s text book of quantitative

chemical analysis ELBS,5th edition,1989.

7. H. J. Arnikar, Essentials of Nuclear Chemistry Wiley Eastern Ltd., India 4th Edition,

2000.

Physical Chemistry – III

Core-9 Physical Chemistry – III hours/ week-4

Sub Code:18-3PCY09 Credits-4

Objective

➢ To make the students learn about spectroscopy and applications of group

theory .

Unit I Group Theory-I

Symmetry- symmetry elements, symmetry operations, matrices for symmetry operations,

defining properties of a group, types of groups- abelian, non-abelian and cyclic groups, point

groups, Identification of point groups of molecules, Group multiplication tables, Order and

class of a group, Similarity transformation, representation of groups- reducible and

CO.

No.





Level

CO1 find the point group of a molecule and construct

character table of a point group

PSO1,PSO5,PSO7 U

CO2 Calculate the normal modes of vibrations, normal

mode analysis.

PSO1,PSO5,PSO7 A

CO3 Determine the symmetry operations of any small

and medium-sized molecule and apply point group

theory to the study of hybridisation and selection

rules for absorption.

PSO1,PSO5,PSO7 An

CO4 To understand rotational, vibrational, Raman and

electronic spectra.

PSO1,PSO5,PSO7 U

CO5 Understand techniques of X-ray photoelectron

spectroscopy, Auger electron spectroscopy, and

depth profiling.

PSO1,PSO5,PSO7 U

39

irreducible representations of groups,Great Orthogonality Theorem and properties of

irreducible representations, Construction of character table ( C2 ,C2V, D2,C2h, and C3V)

Unit II Group theory-II

Symmetry of normal modes of vibrations, normal mode analysis, spectral selection rules of

vibrational spectra IR and Raman active fundamentals-water, cis N2F2, ammonia. Application

of the rule of mutual exclusion principle to trans N2F2, trans dichloro ethylene.

Unit III Group theory-III

Hybridisation of molecules like CH4, BF3 and PtCl42- -symmetry selection rule for electronic

transition in simple molecules (formaldehyde, ethylene, Benzene), HMO theory and

calculation of delocalization energy for 1,3-butadiene and cyclopropenyl system..

Unit IV Spectroscopy-I

Microwave-rotational spectroscopy – Microwave-rotational spectroscopy of diatomic

molecules -intensity of spectral lines, isotopic substitution, polyatomic-linear, symmetric top

molecules, asymmetric top molecules-applications. IR–vibration spectra - harmonic

Oscillator- anharmonic oscillator- overtones and hot bands- concept of group frequencies,

Fermi resonance- vibrating diatomic molecule- P,sQ,R lines-vibration of poly atomic

molecules-Influence of rotation on the spectrum of poly atomic molecules.FTIR, IR and

Raman active fundamentals. Rotational Raman and vibrational Raman spectroscopy -

Theories of Raman effect-Classical and quantum theory-Pure rotational Raman spectra-

vibrational Raman spectroscopy.

Unit- V Spectroscopy – II

Electronic spectra–Electronic spectra of diatomic molecules - Born Oppenheimer

approximation –Vibrational coarse structure-Frank Condon principle, rotational fine structure

- dissociation energy and Fortrat diagram. Photoelectron spectroscopy – basic principles-

Ultra violet photoelectron spectroscopy(UPES)- X-ray photoelectron spectroscopy (XPES)-

Applications of ESCA.

References

1. F.A Cotton, Chemical application of group theory, Wiley Eastern Ltd, New Delhi,

1990 .

2. P.K.Bhattacharya, Group Theory and its chemical applications, Himalayan Publishing

House,1986.

3. M.S.Gopinathan and V.Ramakrishnan, Group theory in Chemistry, Vishal

Publication, Jalandhar, 1998.

4. K.V.Raman, Group theory and its applications to Chemistry, Tata Mc Graw Hill, New

Delhi, 1990.

5. C.N Banwell, E.M.Mc Cash, Fundamentals of molecular spectroscopy, Tata Mc Graw

Hill, New Delhi,1997 and 2012.

6. G.Aruldhas, Molecular Structure And Spectroscopy, 2nd Edition, PHI Learning Pvt.

Ltd., 2004.

http://www.google.co.in/aclk?sa=l&ai=CMthTSo_oUpOXK-OmiQfg-oHICbTLobsDjKL_0Ueo4LuORAgGEAFQmvfRLWDlgoCAmA6gAZTHj-EDyAEHqQIuHxU-nUNRPqoEJ0_QXae24RjsvOflNpJcZ6m-FIGM9_bDzwKWZ4RzIij2_r2ZnPEBBcAFBaAGJoAH1LjwHpAHAuASpdeY_-as47LbAQ&sig=AOD64_3kr54Sh5aPrWFVhEZmk-GiIaWcbw&ctype=5&rct=j&q=aruldhas+molecular+structure+and+spectroscopy&ved=0CH8Q9A4&adurl=http://www.flipkart.com/molecular-structure-spectroscopy-2nd/p/itmdytczxgvjwcjf%3Fpid%3D9788120332157%26cmpid%3Dcontent_book_8965229628_gmc_pla%26tgi%3Dsem,1,G,9226359,g,search,,19319548220,1o1,,,c,,,,,,,


40

SEMESTER III

Core Practical -7 Organic Quantitative Analysis Hrs/week :4

Subject code :18-3PCYL07 Credits :2

Examination-6hrs

Organic Estimations and Preparations (double stage)

A. List of Estimations

1. Ethyl Methyl ketones

2. Formalin

3. Saponification value of an oil

4. Determination of percentage purity in an unsaturated acid

5. Estimation of hydroxyl groups

B. List of two stage preparations

1.p- Bromoaniline from acetanilide

2. m- Nitrobenzoic acid from methyl benzoate

3. Benzpinacolone from benzophenone

4. Benzanilide from benzophenone

5. Aminoazobenzene from aniline

C) For Class work only

Download the following spectra from interpret and give interpretation.

Differentiate the following pair by H1 NMR spectra.

Maleic acid and fumaric acid

Aqueous ethyl alcohol and pure ethyl alcohol

Interprete the following C13 NMR spectra

a) OFF-Resonance decoupled C13 spectrum of menthol

b) DEPT spectrum of isopentyl acetate

c) Interpret the mass spectrum of anisole and benzoic acid

Course Outcome

CO.

No.





Level

CO1 Understand the process of determination of ketone

and formalin

PSO1,PSO4,PSO6 A

CO2 Determination of percentage purity in an unsaturated

acid

PSO1,PSO4,PSO6 A

CO3 Prepare organic compound in double stage process. PSO1,PSO4,PSO6 A

CO4 Purify the compound by recrystalization process. PSO1,PSO4,PSO6 A

CO5 To interpret Spectral data of the given organic

compound.

PSO1,PSO4,PSO6 A

41

On successful completion of the course, the students will be able to

• Determine of the quantity of ketone & formaline

• learn the importance of saponification value of an oil.

• acquire knowledge about saturation / unsaturation of fats.

• study the saponification value of oil.

Reference:


➢ A.I.Vogel ,A text book of quantitative organic Analysis 1989.

➢ Lab Manual prepared by Department of Chemistry, Sarah Tucker College








Core practical -8

Core Practical -8: InorganicQuantitative Analysis - II Hrs / week : 4

Subject code : 18-3PCYL08 Credits: 2

CO.

No.





Level

CO 1

accurately determine the amount of the

substance by selective precipitation of the

PSO1,PSO4,PSO6 A

42

Quantitative estimation of a mixture containing two metal ions.

1. Cu(II) volumetric and Ni(II) gravimetric

2. Fe(II) volumetric and Cu(II) gravimetric

3. Cu(II) volumetric and Zn(II) gravimetric

4. Ca(II) volumetric and Ba(II) gravimetric

Reference

1.Mounir A.Malatti,Experimental Inorganic /Physical Chemistry An Investigative

Integrated Approach to Practical Project work,Woodhead Publishing Limited ,Reprint

2010.

2.W.G.Palmer, Experimental Inorganic chemistry, Cambridge University Press,

Reprint 1970.

Core Practical 9

Core practical -9 Physical Chemistry Practical - III Hrs/week : 4

Subject code :18-3PCYL09 Credit :2

substance from an aqueous solution.

CO2 Amount of the substance was determined

accuqurately and precisely

PSO1,PSO4,PSO6 A

CO 3 determine metal ions from waste water

and other industrial effluents

PSO1,PSO4,PSO6 A

CO4 acquire the skills both in volumetric and

gravimetric analysis.

PSO1,PSO4,PSO6 A

CO.

No.





Level

CO 1 Learn how to remove toxic metals,

sewage waste from aqueous solution

PSO1,PSO4,PSO6 A

CO2 Determine the end point of coloured

solution without using indicators using

potentiometric titrations

PSO1,PSO4,PSO6 A

CO 3 Be aware of ground water pH. PSO1,PSO4,PSO6 A

43

I Adsorption

1. Adsorption of Acetic acid on activated charcoal-Verification of Freundlich

isotherm-determination of unknown concentration.

2. Adsorption of Oxalic acid on activated charcoal-Verification of Freundlich

isotherm-determination of unknown concentration.

II Potentiometry

Potentiometric titrations

(i) Redox

1. FAS - Ce4+

2. FAS – K2Cr2O7

(ii) Precipitation

3. KCl – AgNO3

4. Determination of solubility product of sparingly soluble salts by concentration cell

method

5. Determination of pH of a buffer solution by Quinhydrone electrode

Reference

Lab manual prepared from the department of chemistry,Sarah tucker college.





Project

Project Hours/ week : 6

Sub Code : 18-3PCYE3PJ Credits : 6

Project -Individual Project

Course Outcome

CO.

No.

Expected Learning

Outcomes

On successful completion of

this course, student should

be able to:


Level

44

Evaluation

Internal Assessment :40 Marks

External Assessment :60 Marks

Total : 100 Marks

Distribution of Marks

Internal Marks: 40 Marks External Assessment : 60 Marks

Presentation : 20

Presentation

: 40

Viva-voce : 20

Viva-voce :

20

SEMESTER – IV

Core-10 Organic Chemistry -IV Hours/ week : 5

Sub Code: 18-4PCY10 Credits : 4

.

Objectives

• To understand the general principles of organic photochemistry

• To study the reactivity of carbonyl compounds and olefins

• To study the molecular rearrangement reactions

• To learn the use and importance of reagents in Organic Synthesis

• To acquire knowledge about organic synthesis

• To learn the chemistry of cholesterol, sex hormones and bile acids

CO1 refer literature through modern

tools and software

PSO2,PSO3,PSO4,PSO5,PSO6,PSO7 U

CO 2 use modern equipments and

instruments

PSO2,PSO3,PSO4,PSO5,PSO6,PSO7 A

CO3 synthesise new compounds and

characterize materials

PSO2,PSO3,PSO4,PSO5,PSO6,PSO7 C

CO 4 Interpret the results PSO2,PSO3,PSO4,PSO5,PSO6,PSO7 An

CO5 Communicate the results and

discussions to various research

forums

PSO2,PSO3,PSO4,PSO5,PSO6,PSO7 A

CO.

No.




Level

45

Unit I Organic Photochemistry

Thermal vs photochemical reaction-Jablonski Diagram-Photo sensitization – Photochemistry

of excited ketones-Norrish Type I and Type II reactions-Paterno-Buchi reaction-Di-ᴨ-

methane rearrangement-photoreduction-photochemistry of olefins- cis-trans isomerisation-

Photooxidation.

Pericyclic reactions-electrocyclic reaction-cycloaddition reactions-sigmatropic

rearrangement-Frontier molecular orbital Theory-Orbital correlation diagram method-

stereochemistry of pericyclic reactions.

Aromaticity analysis-Huckel-mobius and Dewar approach.

Unit II Molecular Rearrangements

Migratory aptitude of groups-Mechanisms and stereochemical aspects of the following

rearrangement. Wagner-Meerwein, Demjanov, Favorski, Stevens, sommlet Hauser, Cope,

Pinacol-Pinacolone, Beckmann, Wittig, Jacobson and photo Fries rearrangement. Free

Radicals-Generation and stability of free radicals. Mechanisms of Barton, Sandmeyer,

Gomberg-Bachmann, Ullmann, Hundsdiecker, Pschorr Hoffmann-Lofter-Freytag reaction.

Unit III Reagents in Organic Synthesis

Use of the following reagents in organic synthesis - LiAlH4, NaBH4, Dichloro

Dicyanobenzoquinone (DDQ), SeO2, Gilman reagent (Lithium dialkyl cuprate), Lithium

diisopropylamide (LDA), DCC, Peterson’s synthesis- tri-n-butyltinhydride - Woodward-

Prevost hydroxylation - lead tetraacetate, HIO4, 1,3-Dithiane - Organometallic reagents in

organic synthesis-Methyllithium, Aluminium tertiary butoxide and Aluminium isopropoxide,

DMSO.

Unit IV Principles of Organic Synthesis

Synthon - synthetic equivalent - functional group interconversions - uses of protecting group

and activating group - Robinson annulation reaction-retrosynthetic -Key intermediates-Linear

and convergent approach to synthesis. Stereoselectivity-problem of geometrical and optical

isomerism- disconnection approach - retrosynthetic analysis of the following molecules: 2,4-

dimethyl -2-hydroxypentanoic acid, cascarillic acid, Ci.-Jasmone, Baclofan, Twistane and Tri


CO -1 Know the photochemistry of carbonyl compounds,

olefins and Pericyclic reactions

PSO1,PSO5,PSO7 U

CO-2 Understand the mechanism of molecular

rearrangements and reactions.

PSO1,PSO5,PSO7 U

CO-3 Get an idea about the synthetic use of reagents in

organic synthesis.

PSO1,PSO5,PSO7 A

CO-4 Acquire knowledge about planning an organic

synthesis and synthesize organic compounds from

available simple compounds

PSO1,PSO5,PSO7 C

CO-5 Learn the chemistry of cholesterol and other

biologically important hormones and steroids.

PSO1,PSO5,PSO7 U

46

hexyl phenidyl.

Unit V Steroids

Occurrence – classification – reactions, structural elucidation of cholesterol. Synthesis and

structure of Ergosterol and testosterone,

Oestrone, Oestriol, Equilinin and progesterone – Bile acids – Prostogladins - General

study – structure and synthesis of PGE1, and PGF1.

References:

Unit I

1. R.T. Morrison & R.N. Boyd, Organic Chemistry- Prentice Hall 6th edition, 1999.

2. H. Pine, Organic Chemistry- Mcgraw Hill, Acedemic Press, 2011.

3. P.M. Coxon & Halton, Organic Photo chemistry, Cambridge University press, 1974.

4. G.B. Gill and M.R.Wills, Pericyclic Reactions, Chapman and Hall London, 1974

5. C.H. Depuy and O.L. Chapman, Molecular Reactions and Photo chemistry Prentice

Hall,1975

6. S.M. Mukherji,Pericyclic Reactions, Macmillan India Press, Madras, 1976

Unit II

1. J. March, Advanced organic Chemistry-, 4th Edn, John wiley, New York, 1992.

2. DE. Mayo Molecular Rearrangements.Interscicence, New Yark, 1963.

3. J.N. Gurtu R. Kapoor., Organic reactions and reagents. S. Chand & Co pvt. Ltd.

4. I.L.Finar Organic Chemistry Vol.II. ELBS, 5thedition , 2000

5. E.S. Gould ,Mechanisms and structure in Organic Chemistry. Henry Halt and Co,1959

6. Gurdeep R. Chatwal, Reaction Mechanism and reagents in Organic Chemistry,

Himalaya publishing House, 2012.

Unit III & IV

1. J. March., Advanced Organic Chemistry, 4th Edn, John wiley, New York, 1992.

1. P.Sykes ,A Guide Book To Mechanism In Organic Chemistry,.Orient Longman, 1986

2. F.A Carey And R. J. Sunderg ,Advanced Organic Chemistry, Springer, 2007

3. Michael B Smith ,Organic Synthesis , Mcgraw Hill Internationa Edition, 1994.

4. Gurdeep R. Chatwal ,Reaction mechanism and reagents in organic chemistry-, H

5. Press.1983

6. Swaren, A Programmed Synthetic approach – John wiley and Sons.

Unit V

1. I.L. Finar, Organic Chemistry Vol. II, ELBS, 5th edition, 2000.

2. Gurdeep R. Chatwal Chemistry of Natural Products, Vol. II , Himalaya Publishing

House, 2004.

3. Namwell, The Prostaglandins –Vol. I, Plenum Press 6

4. E. L. Eliel , Stereo chemistry of Carbon Compounds – Mc Graw Hill, 1999.

47

Inorganic Chemistry – IV Core-11 Inorganic Chemistry – IV hours/ week-5


Objective

• Attain a deep knowledge about electronic spectroscopy.

• Understand the principle and applications of Mossbauer spectroscopy

• Interpret the structures of inorganic and organometallic compounds using

NMR Spectra.

• Understand the applications of EPR spectroscopy

• Acquire knowledge about photochemistry.

Unit I Spectral Methods – I Electronic spectroscopy–L–S coupling and j-j coupling, schemes and microstates. Hund’s

rule and Term symbols , selection rules for electronic transition and hole formalism, Orgel

and Tanabe- Sugano diagrams, evaluation of 10Dq and β for octahedral d2&d8 systems.

Charge transfer spectra. Electronic spectra of lanthanide and actinide complexes.

Unit II Spectral Methods – II Mossbauer- Principle – isomer shift, quadrupole and magnetic interactions – MB

spectroscopy of octahedral high and low spin Fe (II) and Fe (III) complexes. Information on

oxidation state, pi-back co – ordination and structure in iron compounds. Mossbauer studies

on halides of Sn (II) and Sn (IV) compounds.

Photoelectron spectroscopy – Valence electron PES – core level PES- N2,O2,Sodium

Azide,Mo complex-Koopman’s theorem- X-PES (ESCA) – Fine structure in PE bands and

application to inorganic systems – Auger electron emission.

Unit III Spectral Methods – III NMR – Application of chemical shift and spin – spin coupling to structure determination

using multiprobe NMR (1H, 31p. 19F, 15N)- effect of quadrupolar nuclear on NMR spectra.

CO.

No.



Level

CO-I Attain a thorough knowledge about electronic

spectroscopy.

PSO1,PSO5,PSO7 U

CO-2 Know the principle of Mossbauer spectroscopy PSO1,PSO5,PSO7 U

CO-3 Determine The structures of inorganic and

organometallic compounds using NMR

Spectra.

PSO1,PSO5,PSO7 U

CO-4 Study the applications of EPR spectroscopy PSO1,PSO5,PSO7 U

CO-5 Acquire a vast knowledge about

photochemistry

PSO1,PSO5,PSO7 K

48

NMR studies on chemical exchange and dynamic processes in inorganic and organo metallic

compounds. NMR studies on fluxional molecules – Paramagnetic NMR and contact shift.

Lanthanide shift reagents.

Unit IV Spectral Methods – IV EPR – Application of hyperfine splitting and g – factor to structural determination, zero –

field splitting and Kramer’s degeneracy, covalency of M-L bonding by EPR study.

Application of EPR in the study of Jahn Teller distortion in Cu (II) complexes. Optical

isomerism in octahedral chelate complexes and their absolute configuration determination

from ORD and CD methods.

Unit V Photo Chemistry

Properties of Excited states,biomolecular deactivation and energy

transferprocesses.Ligandfield,Photochemistry-photosubstitution.photoisomerisationand redox

reactions-Synthesis, properties and charge transfer properties of Ruthenium and Chromium

bipyridyls.Solar energy conversion and its storage-Photolysis of water.

References 1. R. S. Drago Physical methods in Chemistry, W. B. Saunders, 1977.

2. Douglas, A. Skoog, F. James holler and Timothy A Nieman, Principles of

Instrumental Analysis, 2nd Edn, Thomson Asia Pvt, Ltd. Singapore.

3. E. A. V. Ebsworth David, W.H. Rankin Sleptren Credock, Structural Methods in

Inorganic Chemistry, ELBS, IV, 1988.

4. Adamson, Inorganic Photo chemistry, John Wiley and son, New York 1975.

5. Manas Chanda Atomic Structure and the Chemical bond including molecular

Spectroscopy, Tata Mc Graw Hill, New Delhi, 4th edition 8th reprint 2006 .

6. Concise Inorganic Chemistry, J.D. Lee, 3rd edition-1977 and 5th edition-2002.

Physical Chemistry – IV

Core-12 Physical Chemistry – IV hours/ week-4


CO.

No.





Level

CO1 Know about the NMR phenomenon and basic

theory of 1H and 13C NMR spectroscopy and

Know about the ESR and measure the g factor,

nuclear spin, and hyperfine coupling constant.

PSO1,PSO5,PSO7 U

CO2 Understand the basic principles of NQR

spectroscopy.

PSO1,PSO5,PSO7 U

CO3 Predict polymer structure and property

relationship and utilize common characterization

PSO1,PSO5,PSO7 U

49

Unit I Spectroscopy- III

PMR- theory, chemical shift, -spin spin splitting, relaxation time, line shape, line width and

FT-NMR, C-13 NMR. ESR spectroscopy – theory, g-value- Factors influencing g value,

methods of measuring g value - hyperfine structure -Zero field splitting and Krammer’s

degeneracy field, electron density calculation.

Unit IISpectroscopy- IV

NQR spectra – principles, comparison with NMR spectroscopy, splitting of quadrupole

energy levels, a symmetry parameter, effect of magnetic field on NQR spectrum –

Applications, H-bonding, phase transition , substituent effect and structural information.

Mossbauer Spectroscopy-Principle-isomer shift-quadruple splitting, Magnetic hyperfine

interaction-study of magnetic ordered materials, surface studies.

Unit III Commercial Polymers

Functional polymers, Fire retarding polymers - Biomedical polymers-contact lens, dental

polymers, artificial heart, Kidney, Skin and blood cells.Photoconducting polymers, polymer

composites, Carbon black,Carbon fiber, Semiforced conducting polymers composites

Unit IV Electro chemistry-II

Storage batteries and fuel cells, alkaline MnO2 cells, air cellsand solid electrolyte cell-

secondary cells-lead acid batteries,Ni-Cd batteries, Nickel metal hydrates Lithium batteries-

silver-zinc and sodium sulphur cell, fuel cells-H2-O2,H2- air and hydrocarbon –air cell.

Unit V Corrosion

Definition-types of corrosion-Corrosion of metals-hydrogen evolution types, Corrosion in

presence of depolarizer,differential oxygenation -Pourbaix diagram and Evans diagram-

methods of prevention of corrosion-surface coating-galvanization,cathodic protection-

Corrosion inhibition.

References

1. C.N.Banwell, M.Mc Cash, Fundamentals of Molecular Spectroscopy, Tata Mc Graw

Hill, New Delhi, 1997.

2. G.Aruldhas, Molecular Structure And Spectroscopy, 2nd Edition, PHI Learning Pvt.

Ltd., 2004.

and testing techniques to evaluate polymer

properties.

CO4 correlate structure, properties and applications of

some representative commercial polymers

PSO1,PSO5,PSO7 U

CO5 understand the different types of cells and their

applications and electrochemical corrosion

process and the corrosion process of various

materials

PSO1,PSO5,PSO7 U



50

3. F.W.Bill Meyer Jr, Text book of Polymer Science, Wiley-Interscience publication,

New York, 1984.

4. V.R.Gowriker, N.V.Viswanathan and Jeyadev Sreedhar, Polymer Science, Wiley

eastern Ltd, India ,1986.

5. J.O.M.Bockris and A.K.N.Reddy, Modern Electro Chemistry, Vol.1 & 2, Plenum

press, New York, 1988.

6. B.F.Straughan and S.Walker, Spectroscopy, Vol 3, Chapman and Hall Ltd, 1976.

7. Bahadur.P., Sastry.N.V., Principles of Polymer Science, 2nd Edition, Narosa

Publishing house ,Chennai, 2005.

8. B.Viswanathan, S.Sundaram and others, electrochemistry-principle and applications,

S.V.Publishers Pvt Ltd, Chennai, first edition, 2000.

9. B.K.Sharma, Electrochemistry, Goel Publishing House, Meerut, V Revised and

Enlarged edition, 1997-98.

Elective 4

Elective-3 : Nanochemistry hrs/ week-4

Sub Code: 18-4PCYE4 Credits-4

Objectives

To study the synthesis and applications of nanoparticles and dendrimers

CO.

No.





Level

CO1 Know what it takes to have a career in

nanotechnology

PSO1,PSO2,PSO5,PSO7 U

CO2 Understand the need to increase

Nanotechnology awareness


51

Unit 1 Introduction and Synthesis by physical methods

Nanoparticles - Definition - Size relationships of Chemistry - Nanoparticles of metals,

Semiconductors and Oxides - Synthesis – Bottom up and Top down processes - Synthesis by

physical methods – Inert gas condensation - arc discharge- laser ablation.

Unit II Synthesis of nano materials by Chemical methods

Synthesis by chemical methods-Chemical reduction, solgel method -chemical vapourisation

methods and its Applications. Synthesis in organized media.

Unit III Properties of Nano materials

Electronic properties, optical and magnetic properties-carbon nanotubes-single walled and

Multiwalled carbon nano tubes-synthesis -Properties of CNTS-quantum dots, Quantum wires,

Quantum wells-nano composites.

Unit IV Nano analytical techniques and Applications

Characterization of Nano particles Structural characterization of – XRD,Particle size

determination, Surface characterization – SEM, AFM, TEM,HRTEM.Applications –

nanomaterials in energy storage- solar cells, Nanomaterials for catalysis- Nanomaterials in

medicine- magnetic nanoparticles in cancer therapy.

Unit V Dendrimers

Introduction, types of dendrimers – anionic, cationic dendrimers, PAMAM dendrimers, PMI

dendrimers, Self-assembly, Synthesis-divergent and convergent methods, molecular

structure, light harvesting dendrimers – Non linear optical materials, NEMs, MEMs,

properties and applications.

References

1. C.N. R. Rao, Nanochemistry, Wiley Inter science, New York, 2001

2. C.P. Poole Jr. and F.J. Owens, Introduction to Nanotechnology, Wiley India(P) Ltd., New

delhi,2012

3. 3.K.J. Klabunde(Ed.) ‘Nanoscale materials in Chemistry’, John Wiley L. sons, Inc,

2001

4. T.Pradeep,A text book of nano science and nanotechnology,Tata Mc-Graw-Hill,New

Delhi,2012.

5. B.Viswanathan, Nanomaterials, Narosa Publishing House, Pvt.Ltd., New Delhi,2009

6. S.Shanmugam,Nanotechnology,MJP publishers,Chennai,2010.

CO3 Understand the definition of Nanotechnology PSO1,PSO2,PSO5,PSO7 U

CO4 Know and understand the processing of

Nanoprticles and Nanomaterials and


CO5 Know the application of Nanotechnology and

dendrimers


52

7. C.N.R.Rao,A.Muller and A.K.Cheetham, The Chemistry of Nanomaterials-

Synthesis,Properties and application,Wiley-VCH-verlog GMOH &Co.,Wilhelm,2004.

SEMESTER IV

Core Practical 10 Organic

Preparations(double stage)-II :

I

I Hrs/week :4

Subject code :18-4PCYL10 : Credits :2

Examination-6hrs

Organic Estimations and Preparations (double stage)

A. List of estimations

1. Glucose - Lane and Eynon methods

2. Glucose – Bertrand’s method

3. Iodine value of an oil

4. Estimation of Acetyl group

5. Purity of glucose

B. List of two stage preparations : Any 8

1. p- nitroaniline from acetanilide

2. sym-Tribromobenzene from aniline

3. Phthalimide from phthalic acid

4. S- benzylisothiuronium benzoate from thiourea

5. Phthalic anhydride to anthranilic acid

Students are expected to submit at the time of practical examination

the recrystallised samples of the final products for evaluation by the examiners.

CO.

No.





Level

CO1 Prepare the organic compounds in two stages and

recrysallise them using solvents

PSO4,PSO5,PSO6 A

CO2

Study the basic concepts of Chromatography,

extraction& isolation.

PSO4,PSO5,PSO6 A

CO3 Use their hands on experience inresearch PSO4,PSO5,PSO6 A

CO4 Understand the process of determination of glucose PSO4,PSO5,PSO6 A

CO5 Learn the importance of iodine value of an oil. PSO4,PSO5,PSO6 A

53

Course Work only

1. Isolation of carotene from carrot

2. Isolation of caffine from coffee

3. Separation of inks by TLC

Course Outcome


• prepare organic compounds in double stage process,

• purify the compound by recrystallization method.

• Study the basic concept of chromatography

• device and use their hands on experience inresearch.

Reference

1. A.I .Vogel,A Text book of practical organic chemistry.

2. A.I.Vogel ,A text book of quantitative organic Analysis 1989.

3. Lab manual prepared by department of chemistry ,Sarah Tucker college.





SEMESTER IV

Core Practical - 11 Inorganic Preparations

I

I Hrs/week :4

Subject code : 18-4PCYL11 Credits :2

Examination-6hrs

CO.

No.





Level

CO 1 accurately determine the amount of the substance

by selective precipitation of the substance from an

aqueous solution.

PSO4,PSO5,PSO6 A

CO2 Prepare the inorganic complexes and purify by PSO4,PSO5,PSO6 A

54

1.Preparation of Inorganic complexes and quantitative estimation by volumetric or

Instrumental methods.( a minimum of six complexes from the list below).

1. Preparation and Analysis of Potassium trioxalatochromate(III) trihydrate

K3[Cr2(C2O4)3].3H2O.

2.Preparation and Analysis of Potassium hexathiocyanatochromate(III) trihydrate

K3[Cr2(SCN]63H2O.

3. Preparation and Analysis of Potassium trisoxalatomanganate(III) trihydrate

K3[Mn(C2O4)3].3H2O.

4. Preparation and Analysis of Potassium trisoxalatoferrate(III) trihydrate

K3[Fe(C2O4)3].3H2O

5. Preparation and Analysis of Potassium trisoxalatocobaltate(III) trihydrate

K3[Co(C2O4)3].3H2O.

6. . Preparation and Analysis of Durrrant’s salt. K4[ (C2O4)2]. Co (OH)2Co(C2O4)2.3H2O.

7 . Preparation and Analysis of hexamminecobalt(III).Co(NH3)(NO2).

8. Preparation and Analysis of hexaamminecobalt(III)Chloride.[Co(C2O4)3].3H2O.

9. Preparation and Analysis of trinitrotriamminecobalt(III),Co(NH3)2(NO2)3]

!0. Preparation and Analysis of trans-dichlorobis(diaminoethane)cobalt(III)chloride,trans-

Co(en)2Cl2]Cl.

11. Preparation and Analysis of (NH4)2[VO(C2O4)2]2H2O.

12. Preparation and Analysis of tris(thiourea)copper(I)Sulphate

dehydrate,[Cu(tu)3]2SO4.2H2O.

References

1.Mounir A.Malathi,Experimental Inorganic /Physical Chemistry An Investigative Integrated

Approach to Practical Project work,Woodhead Publishing Limited ,Reprint 2010.

2.W.G.Palmer, Experimental Inorganic chemistry, Cambridge University Press, Reprint

1970.

3.George Brauer, Handbook of preparative Inorganic chemistry,2nd Edition, Academic

Press,1963.

4.G.H.Jeffery, J.bassett,J.Mendham and R.C.Denney , Vogel’s Text Book of Quantitative

Chemical Analysis, Revised 5th Edn.ELBS Reprint 1989.

recrystallisation

CO 3 determine metal ions from waste water and other

industrial effluents

PSO4,PSO5,PSO6 A

55

5.Geoffry Pass,Haydn Suteliffe,Practical Inorganic Chemistry-Preparations,reactions and

instrumental methods,Springer 1974.





Core Practical 12-

Physical Chemistry Practicals IV

:Hrs/week :4

Subject code :18-4PCYL12 : : Credits : 2

Examination-6hrs

I Adsorption

1. Adsorption of Oxalic acid/ Acetic acid on activated charcoal-verification of

Langmuir isotherm-determination of unknown concentration.

II Potentiometry

Potentiometric titrations

(i) Redox

1. KI – KMnO4

(ii) Precipitation

2. KCl+ KI – AgNO3

CO.

No.


On successful completion of this course, student

should be able to:

PSO Addressed Cogniti

ve

Level

CO 1 learn how to remove toxic metals, sewage waste from

aqueous solution

PSO4,PSO5,PSO6 A

CO2 determine the end point of coloured solution without

using indicators using potentiometric titrations

PSO4,PSO5,PSO6 A

CO 3 Determine the dissociation constant of a weak acid. PSO4,PSO5,PSO6 A

56

3. Determination of dissociation constant of a weak acid.

4. Determination of activity and activity coefficient of ions.(Course work only)

5.Study the kinetics of reaction between KI and potassium per sulphate (primary salt

effect) (Course work only)

6. Determine the stability constant for the formation of complex ion[Ag(NH3)2]+

potentiometrically(Course work only)


Distribution of Marks





57

Self learning Course

Clinical Chemistry

Sub Code:PCHS1 Credit : 1

Unit 1 Safety in Laboratory

Safety in Laboratory-importance-Safety-personal protection-chemical hazards-corrosive,

toxic, irritants-explosive hazards and flammability-physical hazards-fire.

Unit 2 First Aid

First Aid for accidents-important rules of first aid- first aid for cuts, abrasions, bleeding and

fractures-first aid for burns, fainting and poisonous bites-first aid box.

Unit 3 Blood and Urine

Blood: Importance of RBC, WBC and platelet- estimation of heamoglobin-red cell count.

Urine – estimation of glucose and urea.

Unit 4 Some Common diseases – causes and prevention

Insect borne diseases : Malaria, Plague and Filariasis Water borne diseases : Cholera,

Typhoid and Dysentery Air borne diseases: Influenza, Measles, Common cold and

Tuberculosis

Unit 5 Drug and treatment of some common diseases

Malaria, Plague, Filariasis, Cholera, Typhoid, Dysentery, Influenza, Measles, Common cold

and Tuberculosis

References

1. Jayashree Ghosh, A text book of pharmaceutical Chemistry, S. Chand and

Company Ltd., New Delhi, 3rd Revised Edition

2. G. D. Muir, Hazards in the chemical laboratory, The Chemical Society, London,

1980.

3. Sujit K. Chaudhuri, Concise Medical Physiology, New Central Book Agency(P)Ltd.

Calcutta, 2nd Edition, 1993.

4. Kanai L.Mukherjee, Medical Loboratory Technology, Volume I and II, Tata

McGraw Hill, Publishing Company Ltd. New Delhi, 1998.

58

SARAH TUCKER COLLEGE (AUTONOMOUS), TIRUNELVELI- 627 007

EXTRA CREDITS (FOR THE ACADEMIC YEAR 2018 ONWARDS)

Extra credits to be earned Course Minimum Maximum UG 5 15 PG 2 5 MCA 3 6 2.

The extra credits may be earned by choosing appropriate courses given in the table 3. S.No Details Credit

1 Scripture /Moral Instruction

UG 1 PG 1 If the candidate is absent for the exam, it will be treated

as arrear and she must reappear for the exam

2 Self Learning Courses (2 courses) may be taken

during III & IV semester for UG and I Isemester for PG

One credit per course 1

3 Certificate Courses - 30 hours

1 2

TAFTEE course - 60 hours 2

Can be taken up from I to VI Semesters for UG

Can be taken up from I to II Semesters for PG

4 Mini projects, Field project, Special practical and

Case study 1

5 In-plant Training (minimum 10 days) 1

(maximum 3 weeks) 2

6 Conferences, Seminars and Workshops related to their

department / Allied department

Participation in any 2 programmes

(International National / State / Regional) 1 Paper Presentation – International National 2 – National / State / Regional 1

7 Winners in competitions – (including sports)

a) National level 2 b) College / District / State 1

8 Holding positions such as Chairman, Secretaries of

College Union and Chapel Secretary 1

9 Blood Donation or any commendable activities

recognized by the Government or media (Proof to be

produced and credit to be finalised by the Awards

Committee) 1 4. If the students are not able to produce certificates at the end of the course due to some

valid reasons, kindly accept any other proof given by the course coordinator.

PG Chemistry Syllabus 2018.pdf - Sarah Tucker College

Documents

Transcript of PG Chemistry Syllabus 2018.pdf - Sarah Tucker College