TX Print Job - Portland Clean Air

Material Number / Product Name:600005274 - CP-RA 100 P1A Developer Regenerator

Associated Product Codes / Catalog Numbers:03816677, 816677

Product size as shipped: 55G

1 PRODUCT AND COMPANY IDENTIFICATION

Distributed in the U.S.A. by:FUJIFILM U.S.A., Inc.200 Summit Lake Drive Valhalla, NY 10595-1356

Distributed in Canada by:FUJIFILM Canada, Inc.600 Suffolk CourtMississauga, Ontario L5R 4G4

Distributed Internationally by:FUJIFILM Hunt Chemicals U.S.A., Inc.40 Boroline RoadP.O. Box 320Allendale, NJ 07401-0320

Emergency Telephone (24 Hrs.):Transport-CHEMTREC inside NA: 800-424-9300Transport-CHEMTREC outside NA: 703-527-3887Transport-CANUTEC Inside Canada:613-996-6666Medical-PROSAR inside NA: 877-935-7387

Non-emergency Telephone:U.S.A.: 800-473-3854Canada: 800-263-5018

MSDS are available at:USA: http://www.fujifilmusa.com/msdsCanada: http://www.fujifilm.ca/msdsFUJIFILM Hunt: http://www.fujihuntusa.com/

Intended Use: For Processing RA-4 CompatibleEmulsions

2 HAZARDS IDENTIFICATION

Emergency OverviewPhysical State: LiquidColor: YellowOdor: Amine

WARNING!Harmful if swallowed. May be harmful if absorbed through skin. May cause skin and eye irritation.

Potential Health Effects

Inhalation: May cause slight respiratory tract irritation.

Eye Contact: Irritating to eyes.

Skin Contact: May be harmful if absorbed through skin. May cause skin irritation.

600005274 - CP-RA 100 P1A DeveloperRegenerator

Revision: 01-Sep-2009

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Ingestion: Harmful if swallowed.

Target Organ(s): | Skin | Eye |

Potential Physical / Chemical Effects: This product is not flammable or combustible.

OSHA Regulatory Status: This product is hazardous according to OSHA 29CFR 1910.1200.

Environment: Not regarded as an environmental hazard under current legislation.

3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Concentration*Water 7732-18-5 60 - 80%†Triethanolamine 102-71-6 10 - 20%†N,N'-Diethyl Hydroxylamine 3710-84-7 5 - 10%Bis-triazinylamino stilbene derivative NJTSRN31765300002-9363p

0.5 - 1.5%

Sodium chloride 7647-14-5 0.5 - 1.5% * All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.† This chemical is hazardous according to OSHA/WHMIS criteria.

4 FIRST AID MEASURES Inhalation: Move into fresh air and keep at rest. Get medical attention if symptoms persist.

Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Getmedical attention.

Skin Contact: Remove contaminated clothes and rinse skin thoroughly with water for at least 15 minutes. Get medicalattention.

Ingestion: Rinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, the head should be kept low so thatstomach vomit doesn't enter the lungs. Get immediate medical attention.

5 FIRE-FIGHTING MEASURES

Extinguishing Media: Extinguish with foam, carbon dioxide, dry powder or water fog.

Unsuitable Extinguishing Media: Do not use water jet as an extinguisher, as this will spread the fire.

Special Fire Fighting Procedures: Use standard firefighting procedures and consider the hazards of other involvedmaterials.

Unusual Fire & Explosion Hazards: None known.

Hazardous Combustion Products: Carbon Dioxide, Carbon Monoxide, Nitrogen Oxides



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Protective Measures: Selection of respiratory protection for fire fighting: follow the general fire precautions indicated inthe workplace. Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

6 ACCIDENTAL RELEASE MEASURES

Personal Precautions: Avoid inhalation of vapors and contact with skin and eyes. Wear suitable protective clothing. SeeSection 8 of the MSDS for Personal Protective Equipment.

Spill Cleanup Methods: Absorb in vermiculite, dry sand or earth and place into containers.

Environmental Precautions: Avoid discharge into drains, water courses or onto the ground.

7 HANDLING AND STORAGE

Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing mists or vapors. Do not taste or swallow. Washat the end of each work shift and before eating, smoking and using the toilet. Use only with adequate ventilation.

Storage: Store in a cool and well-ventilated place. Keep container closed when not in use.

8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limits: Chemical Name Source Type Exposure Limits Notes Triethanolamine US. ACGIH

TLVTWA 5 mg/m³

Consult Canadian Provincial Regulations and/or Mexican Regulations on exposure limits, if applicable.

Engineering Controls: Adequate ventilation should be provided so that exposure limits are not exceeded. Observe goodindustrial hygiene practices.

Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), anapproved respirator must be worn. In the United States of America, if respirators are used, a program should be institutedto assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: High-efficiency particulaterespirator. Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter,cartridge or canister. Contact health and safety professional or manufacturer for specific information.

Eye Protection: Wear approved safety goggles.

Hand Protection: Wear protective gloves. Suitable gloves can be recommended by the glove supplier.

Skin Protection: Wear appropriate clothing to prevent any possibility of skin contact.

Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material andbefore eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

Environmental Exposure Controls: Environmental manager must be informed of all major spillages.



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9 PHYSICAL AND CHEMICAL PROPERTIES

Color: YellowOdor: AmineOdor Threshold: No data available. Physical State: LiquidpH: 10.4 Melting Point: No data available.Freezing Point: Not applicable.Boiling Point: >100°C (212°F)Flash Point: >96°C (205°F)Evaporation Rate: No data available. Flammability Limit - Upper (%): No data available.Flammability Limit - Lower (%): No data available.Vapor Pressure: 15 mmHg @20°C (Approximate)Vapor Density (Air=1): No data available.Specific Gravity: 1.04 Solubility in Water: Completely Soluble Solubility (Other): Not applicable.Partition Coefficient (n-Octanol/water): No data available.Autoignition Temperature: Not applicable.Decomposition Temperature: No data available. Volatile Organic Compounds (VOC): 0 lbs/gal Viscosity: Not applicable.

10 STABILITY AND REACTIVITY

Stability: Stable under normal temperature conditions

Conditions to Avoid: Excessive heat.

Incompatible Materials: Strong oxidizing agents. Strong acids. Strong bases.

Hazardous Decomposition Products: No data available.

Possibility of Hazardous Reactions: No data available.

11 TOXICOLOGICAL INFORMATION

Specified Substance(s)Acute Toxicity: Chemical Name Test ResultsN,N'-Diethyl Hydroxylamine Dermal LD50 (Rabbit): 1300 mg/kgN,N'-Diethyl Hydroxylamine Oral LD50 (Rat): 2190 mg/kg

Listed Carcinogens: Chemical Name IARC NTP OSHA ACGIHTriethanolamine 3 Not Listed Not Listed Not Listed

IARC: 1 = Carcinogenic to Humans; 2A = Probably Carcinogenic to Humans; 2B = Possibly Carcinogenic to Humans; 3 = Not classifiable as tocarcinogenicity to humans; 4 = Probably not carcinogenic to humans; Not listed = Not evaluated by IARC.



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ACGIH: A1 = Confirmed Human Carcinogen; A2 = Suspected Human Carcinogen; A3 = Confirmed Animal Carcinogen; A4 = Not classifiableas a human carcinogen; A5 = Not suspected to be a human carcinogen; Not listed = Not evaluated by ACGIH.

Product Information Acute Toxicity: Harmful if swallowed. May be harmful if absorbed through skin. May cause skin and eye irritation.

Chronic Toxicity: No data available.

12 ECOLOGICAL INFORMATION

Ecotoxicity: No data available. Mobility: The product is water soluble and may spread in water systems.

Persistence and Degradability: No data available.

Bioaccumulation Potential: No data available. 13 DISPOSAL CONSIDERATIONS

General Information: Dispose of waste and residues in accordance with local authority requirements.

Disposal Instructions: Disposal recommendations are based on material as supplied. Disposal must be in accordance withcurrent applicable laws and regulations, and material characteristics at time of disposal. 14 TRANSPORT INFORMATION

DOT Not regulated.

TDG Not regulated.

IATA Not regulated.

IMDG Not regulated.

15 REGULATORY INFORMATION

Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of theCanadian Controlled Products Regulations, Section 33, and the MSDS contains all required information.

WHMIS Classification: D2BMexican Dangerous Statement: This product is dangerous according to Mexican regulations. Inventory Status

This product or all components are listed or exempt from listing on the following inventory: TSCA US Regulations

CERCLA Hazardous Substance List (40 CFR 302.4): Not regulated.



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SARA Title IIISection 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): Not regulated.

Section 311/312 (40 CFR 370): X Acute (Immediate) Chronic (Delayed) Fire Reactive Pressure Generating

Section 313 Toxic Release Inventory (40 CFR 372): Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated.

Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Not regulated.

Drug Enforcement Act: Not regulated. TSCA

TSCA Section 4(a) Final Test Rules & Testing Consent Orders: Not regulated.

TSCA Section 5(a)(2) Final Significant New Use Rules (SNURs) (40CFR 721, Subpt. E): Not regulated.

TSCA Section 5(e) PMN-Substance Consent Orders: Not regulated.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Not regulated. State Regulations

Massachusetts Right-To-Know List: Triethanolamine

Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act (Act. 451 of1994)): Not regulated.

Minnesota Hazardous Substances List: Triethanolamine

New Jersey Right-To-Know List: Not regulated.

Pennsylvania Right-To-Know List: Triethanolamine

Rhode Island Right-To-Know List: Triethanolamine

16 OTHER INFORMATION

HAZARD RATINGS

Health Hazard Fire Hazard Instability Special HazardNFPA 2 1 0 --

Health Hazard Flammability Physical Hazard Personal ProtectionHMIS 2 1 0 C

Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe



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Personal Protection codes: C - Safety Glasses, Gloves, Apron

Issue Date: 01-Sep-2009 Supercedes Date: 08-Oct-2007 Disclaimer: This information is provided without warranty. The information is believed to be correct. This informationshould be used to make an independent determination of the methods to safeguard workers and the environment.



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600005275 - CP-RA 100 P1B Developer Regenerator

Revison: 08-Oct-2007

Page: 1 of 7

Material Number / Product Name: 600005275 - CP-RA 100 P1B Developer Regenerator Associated Product Codes / Catalog Numbers: 03816678, 816678 Product size as shipped: 55G 1 PRODUCT AND COMPANY IDENTIFICATION Distributed in the U.S.A. by: FUJIFILM U.S.A., Inc. 200 Summit Lake Drive Valhalla, NY 10595-1356 Distributed in Canada by: FUJIFILM Canada, Inc. 600 Suffolk Court Mississauga, Ontario L5R 4G4 Distributed Internationally by: FUJIFILM Hunt Chemicals U.S.A., Inc. 40 Boroline Road P.O. Box 320 Allendale, NJ 07401-0320

Emergency Telephone (24 Hrs.): Transport-CHEMTREC inside NA: 800-424-9300 Transport-CHEMTREC outside NA: 703-527-3887Transport-CANUTEC Inside Canada: 613-996-6666 Medical-PROSAR inside NA: 877-935-7387 Non-emergency Telephone: U.S.A.: 800-473-3854 Canada: 800-263-5018 MSDS are available at: USA: http://www.fujifilmusa.com/msds Canada: http://www.fujifilm.ca/msds FUJIFILM Hunt: http://www.fujihuntusa.com/

Intended Use: For Processing RA-4 Compatible Emulsions

2 HAZARDS IDENTIFICATION Emergency Overview Physical State: Liquid Color: Yellow Odor: Sulfur DANGER! Causes skin, eye and digestive tract burns. Harmful if swallowed. May cause allergic skin reaction. Potential Health Effects Inhalation: Corrosive. Eye Contact: Causes eye burns. Skin Contact: Causes burns. May cause allergic skin reaction.



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Ingestion: Harmful if swallowed. Target Organ(s): | Eye | Respiratory system | Skin | Potential Physical / Chemical Effects: This product is not flammable or combustible. OSHA Regulatory Status: This product is hazardous according to OSHA 29CFR 1910.1200. Environment: The environmental hazard of the product is considered to be limited. 3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Concentration* Water 7732-18-5 70 - 90% †Para-Phenylenediamine Derivative (CD3) 25646-71-3 10 - 20% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. † This chemical is hazardous according to OSHA/WHMIS criteria. 4 FIRST AID MEASURES Inhalation: Move injured person into fresh air and keep person calm under observation. Get medical attention immediately. Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention immediately. Continue to rinse. Skin Contact: Remove contaminated clothes and rinse skin thoroughly with water. Chemical burns must be treated by a physician. Ingestion: Rinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Seek immediate medical attention. 5 FIRE-FIGHTING MEASURES Extinguishing Media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable Extinguishing Media: None. Special Fire Fighting Procedures: Use standard firefighting procedures and consider the hazards of other involved materials. Unusual Fire & Explosion Hazards: None known. Hazardous Combustion Products: Carbon Oxides, Nitrogen Oxides, Sulfur Oxides 6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid any exposure. Persons susceptible for allergic reactions should not



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handle this product. Wear protective clothing as described in Section 8 of this safety data sheet. Spill Cleanup Methods: Absorb in vermiculite, dry sand or earth and place into containers. Environmental Precautions: Avoid discharge into drains, water courses or onto the ground. 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing mist or vapor. Do not taste or swallow. Wash at the end of each work shift and before eating, smoking and using the toilet. Storage: Store in a cool and well-ventilated place. Store in a dry place. Keep container closed when not in use. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits: No exposure limits noted for ingredient(s) on ACGIH, OSHA and WEEL lists. Consult Canadian Provincial Regulations and/or Mexican Regulations on exposure limits, if applicable. Engineering Controls: Provide adequate ventilation. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Eye Protection: Wear approved safety goggles. Hand Protection: Wear protective gloves. Suitable gloves can be recommended by the glove supplier. Skin Protection: Wear appropriate clothing to prevent any possibility of skin contact. Hygiene Measures: Provide eyewash station and safety shower. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Environmental manager must be informed of all major spillages. 9 PHYSICAL AND CHEMICAL PROPERTIES Color: Yellow Odor: Sulfur Odor Threshold: No data available. Physical State: Liquid pH: 1.2 Melting Point: No data available.



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Freezing Point: No data available. Boiling Point: >100°C (212°F) Flash Point: No data available. Evaporation Rate: No data available. Flammability Limit - Upper (%): No data available. Flammability Limit - Lower (%): No data available. Vapor Pressure: 15 mmHg @20°C (Approximate) Vapor Density (Air=1): Not applicable. Specific Gravity: 1.2 Solubility in Water: Completely Soluble Solubility (Other): No data available. Partition Coefficient (n-Octanol/water): No data available. Autoignition Temperature: No data available. Decomposition Temperature: No data available. Volatile Organic Compounds (VOC): 0 Viscosity: Not applicable. 10 STABILITY AND REACTIVITY Stability: This product is stable under expected conditions of use. Conditions to Avoid: Excessive heat. Incompatible Materials: Strong oxidizing agents. Strong acids. Strong bases. Nitrites. Hazardous Decomposition Products: No data available. Possibility of Hazardous Reactions: No data available. 11 TOXICOLOGICAL INFORMATION Specified Substance(s) Acute Toxicity: Chemical Name Test Results Para-Phenylenediamine Derivative (CD3)

Oral LD50 (Rat): 152 mg/kg

Listed Carcinogens: None. Product Information Acute Toxicity: Causes skin, eye and digestive tract burns. Harmful if swallowed. Chronic Toxicity: May cause allergic skin reaction. 12 ECOLOGICAL INFORMATION Ecotoxicity: No data available. Mobility: The product is water soluble and may spread in water systems.



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Persistence and Degradability: No data on possible environmental effects have been found. Bioaccumulation Potential: No data available on bioaccumulation. Other Adverse Effects: No data available. 13 DISPOSAL CONSIDERATIONS General Information: Dispose of waste and residues in accordance with local authority requirements. Disposal Instructions: Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Confirm disposal procedures with environmental engineer and local regulations. RCRA Information: D002 14 TRANSPORT INFORMATION DOT UN No.: UN3265 Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Para-Phenylenediamine Derivative) Class: 8 Packing Group: III Label(s): 8 TDG UN No.: UN3265 Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Para-Phenylenediamine Derivative) Class: 8 Packing Group: III IATA UN No.: UN3265 Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Para-Phenylenediamine Derivative) Class: 8 Packing Group: III Label(s): 8 IMDG UN No.: UN3265 Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s. (Para-Phenylenediamine Derivative) Class: 8 Packing Group: III EmS No.: F-A, S-B 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required



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information. WHMIS Classification: D1B, D2B, E Mexican Dangerous Statement: This product is dangerous according to Mexican regulations. Inventory Status This product or all components are listed or exempt from listing on the following inventory: TSCA US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Not regulated. SARA Title III Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): Not regulated. Section 311/312 (40 CFR 370): X Acute (Immediate) X Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Not regulated. Drug Enforcement Act: Not regulated. TSCA: TSCA Section 4(a) Final Test Rules & Testing Consent Orders: Not regulated. TSCA Section 5(a)(2) Final Significant New Use Rules (SNURs) (40CFR 721, Subpt. E): Not regulated. TSCA Section 5(e) PMN-Substance Consent Orders: Not regulated. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Not regulated. State Regulations Massachusetts Right-To-Know List: Not regulated. Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act (Act. 451 of 1994)): Not regulated. Minnesota Hazardous Substances List: Not regulated. New Jersey Right-To-Know List: Not regulated. Pennsylvania Right-To-Know List: Not regulated. Rhode Island Right-To-Know List: Not regulated.



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16 OTHER INFORMATION HAZARD RATINGS Health Hazard Fire Hazard Instability Special Hazard NFPA 3 1 0 -- Health Hazard Flammability Physical Hazard Personal Protection HMIS 3* 1 0 C Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe *- Chronic Health Effect Personal Protection codes: C - Safety Glasses, Gloves, Apron Issue Date: 08-Oct-2007 Supercedes Date: 24-Sep-2007 Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment.

600005276 - CP-RA 100 P1C Developer Regenerator


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Material Number / Product Name: 600005276 - CP-RA 100 P1C Developer Regenerator Associated Product Codes / Catalog Numbers: 03816679, 816679 Product size as shipped: 55G 1 PRODUCT AND COMPANY IDENTIFICATION Distributed in the U.S.A. by: FUJIFILM U.S.A., Inc. 200 Summit Lake Drive Valhalla, NY 10595-1356 Distributed in Canada by: FUJIFILM Canada, Inc. 600 Suffolk Court Mississauga, Ontario L5R 4G4 Distributed Internationally by: FUJIFILM Hunt Chemicals U.S.A., Inc. 40 Boroline Road P.O. Box 320 Allendale, NJ 07401-0320

Emergency Telephone (24 Hrs.): Transport-CHEMTREC inside NA: 800-424-9300 Transport-CHEMTREC outside NA: 703-527-3887Transport-CANUTEC Inside Canada: 613-996-6666 Medical-PROSAR inside NA: 877-935-7387 Non-emergency Telephone: U.S.A.: 800-473-3854 Canada: 800-263-5018 MSDS are available at: USA: http://www.fujifilmusa.com/msds Canada: http://www.fujifilm.ca/msds FUJIFILM Hunt: http://www.fujihuntusa.com/

Intended Use: For Processing RA-4 Compatible Emulsions

2 HAZARDS IDENTIFICATION Emergency Overview Physical State: Liquid Color: Colorless Odor: None DANGER! Causes severe skin, eye and digestive tract burns. Harmful if swallowed. Potential Health Effects Inhalation: Causes severe burns. Eye Contact: Causes severe eye burns. Skin Contact: Causes severe skin burns.



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Ingestion: Causes digestive tract burns. Harmful if swallowed. Chronic Health Effects: None known. Target Organ(s): | Digestive tract | Eye | Skin | OSHA Regulatory Status: This product is hazardous according to OSHA 29CFR 1910.1200. Environment: The environmental hazard of the product is considered to be limited. 3 COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS-No. Concentration* Water 7732-18-5 50 - 70% †Potassium carbonate 584-08-7 20 - 40% †Potassium hydroxide 1310-58-3 5 - 10% EDTA, Potassium salt 7379-27-3 3 - 7% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. † This chemical is hazardous according to OSHA/WHMIS criteria. 4 FIRST AID MEASURES Inhalation: Move the exposed person to fresh air at once. Get medical attention immediately. Get medical attention if symptoms persist. Eye Contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Get medical attention immediately. Skin Contact: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Ingestion: Rinse mouth thoroughly. Call a physician or poison control center immediately. DO NOT induce vomiting. if victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than the hips to help prevent aspiration. 5 FIRE-FIGHTING MEASURES Extinguishing Media: Use fire-extinguishing media appropriate for surrounding materials. Unsuitable Extinguishing Media: Not applicable. Special Fire Fighting Procedures: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Unusual Fire & Explosion Hazards: None known. Hazardous Combustion Products: Carbon Oxides



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6 ACCIDENTAL RELEASE MEASURES Personal Precautions: Avoid any exposure. Wear protective clothing as described in Section 8 of this safety data sheet. Spill Cleanup Methods: Absorb in vermiculite, dry sand or earth and place into containers. For waste disposal, see section 13 of the MSDS. Environmental Precautions: Do not discharge into drains, water courses or onto the ground. 7 HANDLING AND STORAGE Handling: Avoid contact with eyes, skin, and clothing. Avoid breathing mist or vapor. Wash at the end of each work shift and before eating, smoking and using the toilet. Use only in well-ventilated areas. Storage: Store in a cool and well-ventilated place. Keep container closed when not in use. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits: Chemical Name Source Type Exposure Limits Notes Potassium hydroxide ACGIH Ceiling 2 mg/m³ Consult Canadian Provincial Regulations and/or Mexican Regulations on exposure limits, if applicable. Engineering Controls: Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors. Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Eye Protection: Wear tight-fitting goggles or face shield. Hand Protection: Wear chemical-resistant gloves. Contact glove manufacturer for specific information. Skin Protection: Wear appropriate clothing to prevent any possibility of skin contact. Hygiene Measures: Provide eyewash station and safety shower. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Environmental Exposure Controls: Environmental manager must be informed of all major spillages. 9 PHYSICAL AND CHEMICAL PROPERTIES



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Color: Colorless Odor: None Odor Threshold: Not applicable. Physical State: Liquid pH: > 14 Melting Point: No data available. Freezing Point: No data available. Boiling Point: >100°C (212°F) Flash Point: No data available. Evaporation Rate: No data available. Flammability (Solid): No data available. Flammability Limit - Upper (%): No data available. Flammability Limit - Lower (%): No data available. Vapor Pressure: 15 mmHg (Approximate) Vapor Density (Air=1): No data available. Specific Gravity: 1.42 Solubility in Water: Completely Soluble Solubility (Other): No data available. Partition Coefficient (n-Octanol/water): No data available. Autoignition Temperature: No data available. Decomposition Temperature: No data available. Volatile Organic Compounds (VOC): 0 lbs/gal Viscosity: Not applicable. Explosive Properties: No data available 10 STABILITY AND REACTIVITY Stability: This product is stable under expected conditions of use. Conditions to Avoid: Excessive heat. Incompatible Materials: Strong oxidizing agents. Strong acids. Strong bases. Hazardous Decomposition Products: None known. Possibility of Hazardous Reactions: No data available. 11 TOXICOLOGICAL INFORMATION Acute Toxicity: Chemical Name Test Results Potassium hydroxide Oral LD50 (Rat): 273 mg/kg Potassium carbonate Oral LD50 (Rat): 1870 mg/kg Listed Carcinogens: None. Product Information Acute Toxicity: Corrosive. Even small amounts may cause serious damage. Harmful if swallowed. Chronic Toxicity: No data available.



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12 ECOLOGICAL INFORMATION Ecotoxicity: No data available. Mobility: None known. Persistence and Degradability: No data on possible environmental effects have been found. Bioaccumulation Potential: No data available on bioaccumulation. Other Adverse Effects: No data available. 13 DISPOSAL CONSIDERATIONS General Information: Dispose of waste and residues in accordance with local authority requirements. Disposal Instructions: Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Confirm disposal procedures with environmental engineer and local regulations. RCRA Information: D002 14 TRANSPORT INFORMATION DOT UN No.: UN3266 Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (Potassium hydroxide, Potassium carbonate) Class: 8 Packing Group: III Label(s): 8 TDG UN No.: UN3266 Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (Potassium hydroxide, Potassium carbonate) Class: 8 Packing Group: III IATA UN No.: UN3266 Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (Potassium hydroxide, Potassium carbonate) Class: 8 Packing Group: III Label(s): 8 IMDG UN No.: UN3266 Proper Shipping Name: Corrosive liquid, basic, inorganic, n.o.s. (Potassium hydroxide, Potassium



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carbonate) Class: 8 Packing Group: III EmS No.: F-A, S-B 15 REGULATORY INFORMATION Canadian Controlled Products Regulations: This product has been classified according to the hazard criteria of the Canadian Controlled Products Regulations, Section 33, and the MSDS contains all required information. WHMIS Classification: D1B, E Mexican Dangerous Statement: This product is dangerous according to Mexican regulations. Inventory Status This product or all components are listed or exempt from listing on the following inventory: TSCA US Regulations CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Name RQPotassium hydroxide 1000 lbs SARA Title III Section 302 Extremely Hazardous Substances (40 CFR 355, Appendix A): Not regulated. Section 311/312 (40 CFR 370): X Acute (Immediate) Chronic (Delayed) Fire Reactive Pressure Generating Section 313 Toxic Release Inventory (40 CFR 372): Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): Not regulated. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3): Potassium hydroxide Drug Enforcement Act: Not regulated. TSCA: TSCA Section 4(a) Final Test Rules & Testing Consent Orders: Not regulated. TSCA Section 5(a)(2) Final Significant New Use Rules (SNURs) (40CFR 721, Subpt. E): Not regulated. TSCA Section 5(e) PMN-Substance Consent Orders: Not regulated. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D): Not regulated. State Regulations Massachusetts Right-To-Know List: Potassium hydroxide



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Michigan Critical Materials List (Michigan Natural Resources and Environmental Protection Act (Act. 451 of 1994)): Not regulated. Minnesota Hazardous Substances List: Potassium hydroxide New Jersey Right-To-Know List: Potassium hydroxide Pennsylvania Right-To-Know List: Potassium hydroxide Rhode Island Right-To-Know List: Potassium hydroxide 16 OTHER INFORMATION HAZARD RATINGS Health Hazard Fire Hazard Instability Special Hazard NFPA 3 1 0 -- Health Hazard Flammability Physical Hazard Personal Protection HMIS 3 1 0 C Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe Issue Date: 08-Oct-2007 Supercedes Date: 24-Sep-2007 Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment.

TX Print Job - Portland Clean Air

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