,irat::2NsJ ?.

i i:ai97R:(A2-11',16 -06:7

' :.-, .r;€ t-- -

ISBN

2"d

Sustailntemalional Conli|cncc on

rrebF lecLrrclocY t)c\.cl{)Dnrenl(rcs r r))

Brli. October'

PROCEEDI}.IGS

t0l

t),^\',\\1 LlNl\'Fll!tr(rl1

"Dr tc!,'ftuX Su':t,ttnal'h 1,, lt u'logv

for A Better l\tturc

;,P.OCI] DINCS

sci.!rifi( (onuir!.(1l,,oi I Nx\i, Red ia(unr\ia'lr('<'ntrl"d3Nr:tItotSariql'(Pr.: .d.4\vorld lter.\rabl. Encrgr)Pnii rt,iKu.chli(alioobulNxtonrLUr\cbny,S.d[(or.a]Iha Bunh lilrrirM (UnLvivcBily olwalloncon!, A!$El;)rrol Jac ky.o Lnn(Chorbul Na!o.?l Unn€sny, Sou(ltKora)P'ol Htr Ru,hur iHuangh. UDivc^ryolsciercennd T<hnolo,ey, Cl',o1)rrol: Monbscr Dcudr (s.ur!i vall.r UDtrcrsny.Eg?t)Pr.i A€\indcraur,bd (LJrv.r!,\ orNc! so hwals,Auimhi)Pmr Tlori cd Tin? \:ndh,r(LnL)r Ltr ltrrr'sny, Indoncsh)r'.r l\1.d.,\li K.tiq s (tjdi\{r U.LveAn!,I'ldoneni)

r.'rLY.lml.Dena)Lt !u cof-! rloi (llo ch,11,nh cl)r r,1[1 slii rr (Ud.]yarx (i'n\.r$ry.Irdoncs;a)Dr \\ .,.J! An.nm(lrdrrrn L r{'rr,rd.ndiia)l, I) rl PrL\trDrru \' (r'ii.ij.i i, (i'tr!.'aty. lndoncsn)

.i I r\rn'y. rrd.rcir)

I I nr$i.!r{xl( .nLEnce.'tS!.r!,nrl)1. .rltrd.-r! D.vek)p'ncnr

t\, I i lI r! St dr i,rtbl e k.h'! olotr1, 1 i].ttr' Iinut.'

NIECHANICAI-'}CI\ET'R!N(;

t\l dl( ) I

Fur\ I'll) RJrio Cin (rlld of 01) C.nriu.0:l\ \/I'rhlc lirtsmisri.

Irt 0l0D ljo)

(tD ll0)

(rD r ri)

MIOD

2t]2)

\i r."

lD lri

Th. \r,'rh.d olirlrfc tu rbe' 1nd rlrcturation:l ot.rrl.r fl rh.,.n.ui NnJ nccuLicn.. dirriburirN olrlre crem and Enr\rLl'Nnd|.s.rnrachine .

tri'.,i,.r. .il F n'rl'r'L "rP'.r 'r-ri r' n,i dAlr' rium

inn. Srudt A r)_s,!.1 Fooi Serits lrnn! nfun Ma.lrire

a.iiiu::tr,,r \rr.l.r* Hi,al:.rs o! \\Ic1il!g Al!r!q!r:r \1C io!l",,h\\.id..t tur Nl.lrl lred Gs (Mlcl lnd Tu.s!.n l'1e'1Grs

d Crea'i-M{nulrdudrg Fro(6 For Sman venical Axn \vindlu'r.r bl"d<

Srul! PhFaland Nltchrn,cal Pmpcdr6 olVcAckl Maknal'i

*aj," roLr"y.rsr"" r" ca

CfD !s AidingTool ro l''!dict Airflov 3nd Tlrcmral Perlonn.ncc

ol lluildr gs. Ca:r Study: AnooN ta(c and Tlr'nnxlle h rn rr' r',l . o' I nn ^r)ufAr"ir\'Lrl.d .f.lrcnri.rl !.arrrnls on rlr rcnsilc steDsrir:n,lIl3nnni|ilil\ ol F|c' nrulb$ j_ fiher r.inlirccd Pl A rornNnt!'

I r. r\\scnnnrq I'ne{ijlfrn fl Tlnee Nhcels B'.!cl€ Crrf

(lt)

\II

\'1 rl

v 2l

\1Jl

i!{ ,0

\1 Sl

('Ff IO -- -ftrfordanec ol Repenuve lyp. oa Biogas Desul turi7f,r llladerlD ll0) frofl Sreel CtipsN.

rjolodrc] r:n! Nr D i{ 6l

I inc ^Icr\urcinlrr

Nlcr|od rr Pt \ \l l0l

l.rLLl. And lDprcl sr,€ngtlr ol tslmboo I'ibcr ltci'rlo'..d FN\l(inn|dil€r A\'\lr rxtnt \lrl."rll Fo' Abo!€ K cc Pro{h.u.Sockor

NI l0 (lD ll0)of llcpciitirc typc ofBiog:'s Destrlfu.izc' M.ile lronr

Stccl Chips Wasie

tldiy lrh a NriG,\R :,t \l'dc\l (IPTAI(,\', Dcrn Ngrkan Xeiul I\nF lLC'\R,\l

.h4!d,lht4dj@ad

lbdEtr: lhis rts.arch d.\clop.J Etcnri\e rtpr oi bi3rs desullnri-r br url'/ng \i!ercl chits tum n€kl lo.rin-! Proc.ss ot tuniie lhe:nnerling Ftes\ \$ (trdrctetl on

relchit! prior con,t:crnr.! ro y eld r hillcr lhe purpose olrnn lins \rs ro:li,.i',dc rhc

drdual sr.ers b \. rs b l.r tlroY dtrron to oJcuri'r ordcrroobhrf tr r.\rd. .1;rcsdual

rrcss .liDrinrrdd. tlt st.lc\in\ is l{sr hle r, corllj.dnig as a biller Tlr. rl r.r inq Frocc*sascrmcd oLr b-\ bunrlfg rlre r.on chrp ar 900(Cl Dunng$c annealir-! fl...sr dle mo rli!ldd Nith o\teen !) Iorn i on.iid. (|cror) inJ il dunng oxidario. diere is I \rcr uPor rldrairhc $. iron bogore fe(Oll)r {i1l tE lbmtd BorholFerorand Iic((lllr. rr. rercfvebiljslnd therelore Jblc r! eli!rinrts 1he HrS conraninanr iosido thc bio-qas Iti.r.suhlronde process ol il.sulphuiarlon is p'e.lpirarion of sulfur (S) in the rom ol li.isr in rhe

iurlace orn..Lchips \hich sill r.duce rhd perfomance ol desulfun?€r Ihe rllcctivirv oldesultuizer rhcd is rc..vsr by rca.ritrs nre rqsr in $e e.re Iimc wirh O: rnd ll o. rh.rcior.d€ desullui,s.aD be u5ed rePdnilely

Ke! \ods hydrt,g. nrllid.. \an€. n i .h N. I uming pruc.ss. bioga

I.INl RODLCIION

Jhis \rrli r !odriNitrg lor.!r ilihll \orL lnidJlri. :1)ll) As r:lr.nrdi\e Lr rhe

FD!\ibl. .tr.,g]. rlre unli^loir 01 hio33s llurld be Pfttnorcd especiall' lllr tre d*.lopng.otrDlnri drc tr) lnnpltrn\ $d lo$ co! ol irr5hlldnr A i'nprove'neDr 1.r h.ter ptu.cssihorldriorLl\r\\nrrJu.tlorrhco0ri'n,.rcn,lr,\ssellkm\\nrharhv{h):entullldclll:S) rL1\r\i ldniJ nr ih. ho!rs ind:t rrillt ln rhe Lle!tL)tin! county fi. bro-!ns di!ensrt. n!i r) rrl(.,! \irlr roiPn.r{ t) radr.t q .hdri,n .{l rh. H'S c.fl.nrni$r Snnn'.r'1lreligrn.i i, rl,. ,ic'rL.+,i cotror y r .!rfnd.J \rnh .. p.nenr lnr lihe.og rhc HrS

R,ir.ri r.lirr 1l,. r(,..r\ qtrile !.irlrliii.Ll rnil rlilli.uh 10 b. i'npl!nr$r.d , Je!.loting.otr n.r ilr!j,.:,. nna.le r. hr ni, gij r Ll !. ) .. kItrc t. ncrt! rhtr.oriftle rhe novts d.fi.rrd r r rh.lr! I \ nrlrc.scr.us Fifhlrn d0.ro e\incnreol rh.ll:S nrllr Biu-!.s isiirli.In!!. r us.d ! l lndl lor tl,. i trirl(nnbrnioo cr-line Lr.hd,ictrl Sene'Ior to.innr !r lh.,nnhuiF, !lI.,br' riLl hIJLI!r,.dcrnJ r luNriotr .t Lllrrxnr .l 11,.

srllLr. rLllJiL (io|.r.l. t\ctsi\e!!rni.i\llo.c!rrliointtupriol.rhrtrrrj_{.nrr

I[. p,i tr Fl :.rl ofrlns reserrch ]s h,l€rcnT no,'licrt.d !onrponenr in rhc bLdstrs Jilcn.r:)i.nr rrrii Ll,. HrS co.rxirinanr ni{ I h! !\.!l r.ntrntrclv lnor orLy on. hDlc u\cl Lhe

n)rn rt rtrt \iL b. tr\.d i! Lrl usrD: rriL Td !n r l.hin\ rrt{r rrnc lor lhe nmD: f rtrcs

ol!(iqndt rrqh4ne t\raff.Ef4 e

\t

Iig I is drc sasre rhe iron chipsohai.cd tron'..ydc rhis lbD chips.,6ic r" beconE biogas

ihc rdr' in! nrulcn rila \hortLlkdpmnrr rLo'n rhe HrS cu, J,n,nJr, (Ni

EXPT

J '\ dr d hprhh) Erd,,J4v.r,','nr,,,,'en.nr Hsinrhelevctof/

Iri,Jrustr'bd'mmrch"'t.\!oqkn.,n,,.rn,bioeLjorrraerqua.,.,otco,nbu{iooJ r rrhncruon pdr! in rh.\ombrron !ta1cr arod;, rmpondnr;3{r, .heH.s96isl,rmful dnd penonared a6 riat shourd be mirinize ns exisre;ce in rhc bi.oi{

2. I,I'I'[R/TTTJRE STUDY

ri l\J'.! {lt'h iH(r .,.tut, roundd,co Jn nd ir rh.,'- "tcd rhrdtugcn.d,i..,.t..i, ioel. Jndd.4dt\d\.,..4\m.rc!.!.!. n tr'npr.,n'e,dt rhed, .o\.n,d.o,I'c.,, .m,nr n t;n:,co,i",ppi. n ro,r fi'.1 ol mtmal c.mbunjon engine (ibboos. r9?8r Smith, 2OOl, wi.ci6rer, 2002:

thc r.suh olcombu ion oflhc lns ur coDhtD ItrS ir a srlau and sufunr..ro$e lo mcrdls The I{2S coDr.rr rhd rcxrh 100 ppm c.n cause dearh ilic. 5.(a)

l.)?r) Ortrr {urcc ak6 infom lhar r1r H.S conlahimr w,ll rcduce rh(l

NI

ji rlic iIillrhon n, r!lnd, rl( l.n)!isD)

tr .d ll'( 'bl.i t J. \i!tr,]'J '

r,

re\u'., h.Jtrb'.ri, iL

l!u'.J LrLLlt! ' r.'

cr JrLl

rriD.s h.L rd\cr -lcden{iofn r[n gr nrorli elirnrxlcd or

inhatr\.r. 1008. Nnrdhii. 2012)

a.r{rrns"rnn lhct:or. Borh oi (hr\ reaclnio

&sulphurizr, oi pmc.sscs as

2Feiotl)i :tl,S Jlersr+6Hral

Ferq+ jH.s rfersr+lHro

Nh ch rlre tlrS n ol\.d \ill Iitld tht nn phur oride lhir. Td rhe h'lni.rD oild b.conre rc,d ii ( n 0scd in the(Crll'>) lhcLc ioir t, d\oid rhe nrn le crNrJ by HiS-ir l€asr l,a\c ro redlc. , rhc sl!. llreublsin. daD

lr89 ,n Nindhia.20l2, H:S n po$ible r. td!.c b! consid.r to

ll,S will Eacr b lhe bos notr ote ( [e(Olln) or ton oxrdc.fis sinrilar and rccolnize rs rhc rvny lLr.lmimre tlrs bv dry$itrcn iD lh. Fquaridn (l)axJ (l)

(2)

IlE r.\ r l,on] rhc plocss cl dcsulphurizatio h cquardn (ll.rd (:l is preciPibtion

i'nohdr ls ', llrc lom of Fe2Sl in lhe s0rla.. ol nccl chiDs *hich sill r€drce

dom.i ,r -rlpil,/.Ior lorccorflr' r'. tr\"ru 'ltu"nor nroe<;.,.. ' .' . LrqLrnrroor'/d r b) " r

" l\'le \' lrhc Jmcr neqih

;dH ()..,-, -!FloI',u"rl. clenenLrr "aJc'blern o"rSF'n1Jr ':008)

Fe2Sl'roll6ti2o -) rIelOH)3 +6S

I1leelc ref'ol n'llurrhenwasclcanedbvno$itrswarerinroih.d.nrlndzer

3. F,XPT,RIN'I fNTAL

A6 iDftnn.d d orr i'iital $ork (NniJhii.20l2) th€ e\NriDenrrl \r\ {dd.d bJ r.lecting ihe

s6re ol n.c!.hirs Onl\ rplal 3nd l.n! qpes ot chrPs \!cc s.lcr.J Lhtxnd.a!ingptucssq .o ucrtJ nr rf. fum.cc b) huni'rg $e chits ur 900"C \ rh \lo$lr- coolins The

oxidarior pr.csss NN !l!o h.ppetr dunng process ot dncali g !! vL.ld F€rOr and also

Fe(Oll),. l:j!. 1 is rhe app.rrmcc 01 rhc clrips afier rnncaling a d o\idlrior nroc6s. The

Esuh lio r procers ol .dnerlin.! is $. non .hips $nholt rcllul $'s' due ro trningpro..r\ rh.r.lo c lroilbl.I. bc r. rf.clsd d d bill.i lhc si7s.1 tr.h |r icr $6 I cm ofdiclidls \nh 6.nolliiitier. r.d rhc \F'Lhtus j0 grarn 8\hn\n iI li! 1

Tle."nlr"rr! 1,u.... "r $ndurrd by using.Jll.dricil J'c.rrd (!rLprdcd bv using

iyoo,'li: 1-*; r-r nthf. lh.r. \€rc l0billd$r\Ptu' ed;r rh\ 6€r.ch sith dalseilll.iri0:rxo,,\ir'$rrJai.l,rllttr\ctscrirrrlrc!iteflhi.gi' ii. thcbioe.srhentd lld\c,l ir nia tl,. r,iler \ith r1(.1r rb.utO l Llrerrhou lhisllltr! 'Jt trtrnrlerageoidt rlo",",.,i rl. U,,r".,,r.n lor . hous.hald lhc |Ln:rs c.or. t.rioi bebrc aMdi$ nrsiii d,r h,lL( rlrr \!rsLlertrt.,l dd nieasn'cd btusii! -!x'riri'/.rbdes'ribedinr'g.it"t i,"-"^,,.'"".,"'1,tr'.\.rtuhrnslon.rprorrnr Ld!.rhn)gai rlrd llowtorrh rhe b,iL.r Tl,.r,11'mn,enrotrhe!Ar'3sconduciedhiLFri-!\n!iienr'r'rNcanbdlrbo\nd Fi{ jtl)r 1\i \ih tr :011i

(tr

M

lier l00lir.A olbiosas pasirs desul tun zer, rhc ptucetsot l'' rccolcry s.sco.ducred bylur dicdcsulJi'r^rri b rhe warer wnh bubblins an i. order rercrion nrcqurrion (l) ro ecu.Ihc perronnh.€ or dcsulluriztion alrer l" rccolery ltrcD w.s evallarcd bv neddring rhcHrS .onr.ntlior helore and rlrer pNinS rhc JcsutturiTcr To en$c rhdr rhe denrtfunzdc.n be us.d r.0.riri!.l\ 2'i ccdrery was c.rdud.d rgdrn rtirr pasrn! I()(l liler.fbiogdrnd teie{lxgi I ns o.rLmanccaRerrscdadcsLlnriTer to. r rc nc\r t00 tnrr.tt o!a. ftcr.srll is !i,.inr.Lln, rhc Sraph foranrlyze

.1. RESrir_ [,\ND DISCUSSTON

,\ J!sni\ctuiulrisobrrinedinrhisrerarchrb[nriteposrb]ero, rh.Nrneot{eel chipsrob. uscd xs i l.nrlplru'i2xrion ol biogas reperirn€l)- l.i.!ue 6 sltre!,iptrotxbitirrol rd.nrLlitrlz.r !1 i'rrirl Frfonna.cc ricrlassrng 100lire. ni btr,$s lnnial\ (tje desutiunrdlrL i l. ,' e oufLirntrds'Jor t-J..., ,..0,.t ,nrt,*. ao"dr0% 3nc'rsc rr ruriiy.borr:100 |nerofbjogas

(.) (b)

Fr3fe 5 (a) Poiabb HrS sr.i. yd. (h)volun( rd{

V

FrlondDce ol desuh'nzer arrer lrtEcovery is p.o*nled in Iig 7 the lErlbmccN significandy ro e.ch 90% andjusr a iinle da€de unlil E.ch 35o/o atier passing r00al biqas Finally rhc Esuh lrom 2'd Rolery is depicEd iD Figure S. The p€rfo;dce

&$ltui/- -'i1'n. red e ro Ea!h ooeo Md g'adrd'l) de.re.* .9 ro red!h aourJ'0oob€ prooftd $ar rhe desullurizer develoFd in rhis reffh is work succestuly dd can

Fisu. 6 The p€nnmamc urd6urfu

5. CONCLUSION

ft cd b€ onclud.d lh:r rhe d6ulfuii2er rhar is d€v.loFd in rhis resdch issucca$tully !o Edlce H,S impuriry in rhe bioeis Ep.rirively. rhis is ncerds fun2er can b€ ue ml only one tine 6 d6ultunu r tt'al avaitabte in the mdkerbur can be ued Fp€div€ly.

€

ACKNOWLEDGEMENT

Thisrese.rch was suproned financiallr br' rbe minisrryofndional cducarion of lh€ Republiof lndo.c\ia rluurgh dnder lonmq nuhbr, r2)Sp,H/pUDir.t rdbn ll_.10t2 uod(Scn€nc oaNrtjotul Srratesic Rcsercb cnnt lHibah Skin Sbategis NasiohatJ

REFERENCESrreublein. D.,dan Srcinhau*r, A..2008. Biog,s rron W.st. and Ren*ibre R6onrce5,

Wiley-VCII Verlae CmbH & KCaA- Federal RcNblic of Cem.ry.

GibboDs. J ll. 1978- fnergy froh Bioloeiot Proc.sses,Mccas Hilt. tnc.New yo .

Nitrdiia. T C.T.2012, R.noval of H_l drosen Sulfide (B2S) Conhhinant in aiosls byUrilizing Solid W.ste Sr..l Chins lron Th. Pmc6s ofTurning.Ihe 27dllnrenarionalConleFnce on Solid warc T(hnotoAy and Manrsenrem Mdnh rl-14.2012 Philrdelphia. PA U.S A

Polpm*n. C . I t89, Orgrni. Nrste fiec) cting. John Wiley & Sons Ld, C,€ar Rrnain

snnh, J w, Meffe. S., walron P s. rnd Ellenor, D T. R" 2001. Hydrosen Suttid..emovrl?ro(e\r. US P,kn No DLlT l-0

M68

l.

h.srcr, L L..McMullin_Nl J..lluDr,J K..2002,ll€'no\ing llydrogen sulfidc tr.n AGrseoni Mirlure Using t'crric Ions Bondcd 1o Calcin.d Diatonrjle, IJS pierNo 6.500,217.

]V