Komponen A B C P 100 KpaEtana 13.8797 1582.18 -13.7622 Misal KomposisiPropana 13.7097 1872.82 -25.1011 X1 0

X2 1

Td1 184.3563Td2 230.8031Tn 230.7984 Tebakan Awal Ln P1 Sat 6.58976321 Ln P2 Sat

P1 Sat 727.608557 P2 Sat

Alpha 7.281083P1 Sat baru 728.1083

Tn Baru 230.8188

Delta 0.020444

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X1 Vs TY1 Vs T

ToC X1 X2 T(Kelvin) P1 Sat Baru Y1 Y2-42.2015 0 1 230.7985 727.61164472 0 7.276116

-53.90192 0.1 0.9 219.0981 480.28209393 0.480282 4.322539-62.07649 0.2 0.8 210.9235 348.94014325 0.69788 2.791521-68.13285 0.3 0.7 204.8672 270.58450614 0.811754 1.894092-72.84151 0.4 0.6 200.1585 219.51947214 0.878078 1.317117

4.604961 -76.64153 0.5 0.5 196.3585 183.97342893 0.919867 0.91986799.93136 -79.79786 0.6 0.4 193.2021 157.96551365 0.947793 0.631862

-82.47937 0.7 0.3 190.5206 138.18776253 0.967314 0.414563-84.79891 0.8 0.2 188.2011 122.68126333 0.98145 0.245363-86.83489 0.9 0.1 186.1651 110.21979349 0.991978 0.11022-88.64371 1 0 184.3563 100 1 0

GRAFIK PERBANDINGAN T VS P

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X1 Vs TY1 Vs T

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X1 Vs PY1 Vs P

Komponen A B C P 100 KpaEtana 13.8797 1582.18 -13.7622 Misal KomposisiPropana 13.7097 1872.82 -25.1011 X1 1

X2 0

Td1 184.356293 -88.64371Td2 230.803101 -42.1969Tn 184.356193 -88.64381 Tebakan Awal Ln P1 Sat 4.605165 Ln P2 Sat

P1 Sat 99.95172 P2 Sat

A 1.80681711

i=1 i=2In (gamma) 0 1.806817gamma 1 6.089889

Alpha 14.2259P1 Sat Baru 100

Tn Baru 184.3563

Delta 0.0001

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Margules ɣi P = ɣi xi Pi Sat P 100 Kpa

ToC X1 X2 ɣ1 ɣ2 T (Kelvin) P sat Y1-42.2015 0 1 4.776761 1 230.7985 727.6116 0

1.949825 -74.40571 0.1 0.9 4.067627 1.017473 198.5943 204.3035 0.831037.026036 -81.51885 0.2 0.8 3.103086 1.07334 191.4812 145.0374 0.900127

-83.98528 0.3 0.7 2.394828 1.173985 189.0147 127.9575 0.919309-84.94661 0.4 0.6 1.902991 1.331049 188.0534 121.7419 0.926695-85.38911 0.5 0.5 1.564244 1.564244 187.6109 118.9612 0.930422-85.73053 0.6 0.4 1.331922 1.905801 187.2695 116.8497 0.933809-86.17073 0.7 0.3 1.175193 2.408277 186.8293 114.1707 0.939209-86.80063 0.8 0.2 1.074526 3.158428 186.1994 110.421 0.949202-87.63994 0.9 0.1 1.018177 4.302164 185.3601 105.575 0.967447-88.64371 1 0 1 6.089889 184.3563 100 1

GRAFIK PERBANDINGAN T VS P

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X1 Vs PY1 Vs P

Y27.2761161.8708591.2453951.0515420.9722660.9304220.8907690.8248640.6975130.454201

0

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Komponen A B CAseton 14.3145 2756.22 228.06Etanol 16.8958 3795.17 230.918

KelvinTd1 56 329Td2 78.4 351.4Tn 67.2 340.2 Tebakan Awal

Data UNIFACk Rk Qk vK(1) vK(2)

CH3 1 0.9011 0.848 1 1CH2 2 0.6744 0.54 0 1CH3CO 19 1.4457 1.488 1 0OH 15 1 1.2 0 1

Main Group k k=1 k=2 k=19 k=15CH3 m=1 0 0 476.4 986.5CH2 m=1 0 0 476.4 986.5CH3CO m=5 156.4 156.4 84 0OH m=9 26.76 26.76 0 164.5

°C

P 100Misal Komposisi

X1 0.4X2 0.6

Aseton C3H6O CH3CO-CH3Etanol C2H6O CH3-CH2-OH

i=1 i=2 (H-18)(H-15) ri 2.3468 2.5755 Beta-ik(H-16) qi 2.336 2.588(H-17) e-ki k=1 0.3630 0.3277

k=2 0.0000 0.2087k=19 0.6370 0.0000k=15 0.0000 0.4637

(H-21) tau-mk k=1 k=2 k=19 k=15m=1 1.0000 1.0000 0.2465 0.0550m=1 1.0000 1.0000 0.2465 0.0550m=9 0.9244 0.9244 1.0000 0.6166m=5 0.6315 0.6315 0.7812 1.0000

(H-10) J-i 0.9448 1.0368(H-11) L-i 0.9392 1.0405(H-13) In (gamma-C) -0.0014 -0.0006(H-14) In (gamma-R) 0.2399 0.1089(H-7) In (gamma) 0.2385 0.1084

gamma-i 1.2693 1.1144

i=1 i=2 (H-19) k=1 0.3409k=1 0.9518 0.8291 Teta-ik k=2 0.1303k=2 0.9518 0.8291 k=9 0.2393k=19 0.7265 0.4944 k=5 0.2895k=15 0.4127 0.4932

(H-20) sk1 0.8752sk2 0.8752sk9 0.5816sk5 0.4630

HUKUM RAOULT P 100 Kpa

ToC X1 X2 T(Kelvin) P1 Sat Baru Y1 Y2-42.2015 0 1 230.7985 727.6116 0 7.276116

-53.90192 0.1 0.9 219.0981 480.2821 0.480282 4.322539-62.07649 0.2 0.8 210.9235 348.9401 0.69788 2.791521-68.13285 0.3 0.7 204.8672 270.5845 0.811754 1.894092-72.84151 0.4 0.6 200.1585 219.5195 0.878078 1.317117-76.64153 0.5 0.5 196.3585 183.9734 0.919867 0.919867-79.79786 0.6 0.4 193.2021 157.9655 0.947793 0.631862-82.47937 0.7 0.3 190.5206 138.1878 0.967314 0.414563-84.79891 0.8 0.2 188.2011 122.6813 0.98145 0.245363-86.83489 0.9 0.1 186.1651 110.2198 0.991978 0.11022-88.64371 1 0 184.3563 100 1 0

MARGULES P 100 Kpa

ToC X1 X2 ɣ1 ɣ2 T (Kelvin) P sat Y1 Y2-42.2015 0 1 4.776761 1 230.7985 727.6116 0 7.276116

-74.40571 0.1 0.9 4.067627 1.017473 198.5943 204.3035 0.83103 1.870859-81.51885 0.2 0.8 3.103086 1.07334 191.4812 145.0374 0.900127 1.245395-83.98528 0.3 0.7 2.394828 1.173985 189.0147 127.9575 0.919309 1.051542-84.94661 0.4 0.6 1.902991 1.331049 188.0534 121.7419 0.926695 0.972266-85.38911 0.5 0.5 1.564244 1.564244 187.6109 118.9612 0.930422 0.930422-85.73053 0.6 0.4 1.331922 1.905801 187.2695 116.8497 0.933809 0.890769-86.17073 0.7 0.3 1.175193 2.408277 186.8293 114.1707 0.939209 0.824864-86.80063 0.8 0.2 1.074526 3.158428 186.1994 110.421 0.949202 0.697513-87.63994 0.9 0.1 1.018177 4.302164 185.3601 105.575 0.967447 0.454201-88.64371 1 0 1 6.089889 184.3563 100 1 0

UNIFAC

ToC X1 X2 T (Kelvin) Psat Y1 Y2-42.20152 0 1 0.690008 1 230.7985 727.611 0 7.27611-50.58719 0.1 0.9 0.718682 0.997809 222.4128 542.8235 0.390118 4.874709

-57.6951 0.2 0.8 0.749292 0.990421 215.3049 415.4464 0.622582 3.291736-63.7422 0.3 0.7 0.781865 0.976372 209.2578 325.8788 0.76438 2.227254

-68.93749 0.4 0.6 0.816321 0.953816 204.0625 261.2762 0.853142 1.495257-73.45058 0.5 0.5 0.852394 0.920448 199.5494 213.4951 0.909909 0.982555-77.40651 0.6 0.4 0.889472 0.873443 195.5935 177.3876 0.946688 0.619752-80.88857 0.7 0.3 0.926333 0.80947 192.1114 149.673 0.970529 0.363468-83.93883 0.8 0.2 0.960634 0.724897 189.0612 128.264 0.985718 0.185956-86.55074 0.9 0.1 0.987966 0.616469 186.4493 111.8969 0.994952 0.068981-88.64371 1 0 1 0.483043 184.3563 100 1 0

ɣ1 ɣ2

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X1 VS P (HUKUM RAOULT)Y1 VS P (HUKUM RAOULT)X1 VS P (MARGULES)YI VS P (MARGULES)XI VS P (UNIFAC)Y1 VS P (UNIFAC)