Tatanama Dan Isomerisasi Senyawa Kompleks Ponco

5/25/2018 Tatanama Dan Isomerisasi Senyawa Kompleks Ponco

1/11

12/20/2011

@.. 1

(. 2) (. 2)

:

1. K (3 )

2. I K (4 )

3. K (7 )

4. K (6 )

5. : K (1 )

H, J. E., K, E. A., K, . L., 1993, , 4 ., H C C,

, D. L. , D. A., 2004, , 3 ., H I, A

A, ., , ., , J., , D. F., , ., A,F., 2009, , 5 ., , K

C , . G., D, ., H, . ., H, A. ., 2005, , IAC , C, K

B, . ., , . ., , D. ., 2009, , , C ,C, K

E, 2007, , J 1, B, I

, K. H., 2012, , G I,

()()

C C

(://..///00108545)

J C C

(://...///00958972.)

I C C

(://..///13877003)

I C A

(://..///00201693)

E J I C

(://..///09924361)

A J C

(://...//51.)

,

(

)


2/11

12/20/2011

@.. 2

K

/, :

1. , :

(H4)3CC5 = (II)

F(H3)4(C)23 = (III)

2. , , :

(H4)3CC5 = (3)

F(H3)4(C)23 = (+1)

K

1. Senyawa Kompleks Netral2. Senyawa Kompleks Ionik3. Senyawa Kompleks ber-Isomer4. Senyawa Kompleks dgn Ligan Jembatan5. Senyawa Kompleks dgn Ligan Ambidentat6. Senyawa Kompleks dgn Ligan Polidentat7. Senyawa Kompleks Multi-Inti

8. Senyawa Kompleks dgn Ligan Tak Jenuh9. Metalosena10.Senyawa Kompleks Polimer

(E, 2 007, , J 1, B , . 35

51, I)

:

D , ( ).A (0), :

C(H3)3(2)3 = (III)

(C)4 =

:

D ( ) , , ., :

C(H3)4C23= (III)

C(H3)4C23= (III)

I () , (). H .

(I) , A(H)2C

(II), K3F(C)6

B ( ) , , .

(II) , C(H3)44(III) , C(H3)6C3


3/11

12/20/2011

@.. 3

Logam Anion Kompleks Logam Anion KompleksBesi Ferrate Timbal Plumbate

Tembaga Cuprate Timah Stannate

Perak Argentate Nikel Nickelate

Emas Aurate Seng Zincate

:

( ). A , , :

K3CC5 = (II)C2F(C)6 = (II)

: ( )

() ( ) , :C2(H3)= (II)

NH3

NH3

NH3

B3(H3)2 = (III)

C2 = (II)

3

3

3

3

3

3

IAC, 1994:151

, J 1, E, 2007, B, I


4/11

12/20/2011

@.. 4

B

B

,

E

C ?

1. (III)

2. (II)

3. (III)

4. (III)

C ?

1. CB(H3)54 2. F(H3)6C(C)6

3. C(4)(H3)5C 4. F(H)(H2)5(3)2

I K

I I K

I I I

I

K LI L


5/11

12/20/2011

@.. 5

I

I

I

I

HH

, , ::

CC ( ( ))

22 ( ( ))

( ( ))

I

Co

N

NH3

H3N NH3

H3N NH3

OO 2+

Co

O

NH3

H3N NH3

H3N NH3

NO

2+

Ag

S

Ph3Sb SbPh3

SbPh3

C

N

Ag

N

Ph3Sb SbPh3

SbPh3

C

S

H

,

J ,

,

, :

C(H3)6C(C)6 C(C)6C(H3)6

C(H3)4C4 (H3)4CC4

C()3C(C24)3 C()2(C24)C()(C24)2

I K


6/11

12/20/2011

@.. 6

C(H3)5B4 C(H3)5B2+ + 4

2

C(H3)5(4)B C(H3)5(4)+ + B

(H3)4C2B2 (H3)4C22+ + 2B

(H3)4B2C2 (H3)4B22+ + 2C

I I

C(H2)6C3

C(H2)5CC2.H2

C(H2)4C2C.2H2

C(H2)6C2

C(H2)5CC.H2

C(H2)4C2.2H2

I

()2C

2 ()

2C

2

I L

M

H2N

Cl

NH2 Cl

H2N H2NM

H2N

Cl

NH2

Cl

H2N NH2

Co

N

Cl

NH2

NH2

H2N

H2N

Co

N

Cl

NH2

NH2

H2N

H2N

(33)2()2) 2(43)2()2) 2


7/11

12/20/2011

@.. 7

()

C2(C)8 C

I K L

Co

C

C

OC

O

O

Co

CO

CO

CO

CO

CO

CoOC Co

CO

CO

CO

CO

COOC

OC

M

Cl

Cl

Cl M

Cl

Cl

Cl

Cl

Cl

MCl M

Cl

Cl

Cl

Cl

ClCl

Cl

2

(H3)2C2 (H3)2C2

I

Pt

H3N NH3

Cl Cl

Pt

Cl NH3

H3N Cl

Co

Cl

NH3

H3N NH3

Cl NH3

Co

Cl

Cl

H3N NH3

H3N NH3

Co

Cl

NH2

H2N NH2

ClH2N

Co

Cl

Cl

NH2

NH2

H2N

H2N

(3)42 (3)42

()22 ()22


8/11

12/20/2011

@.. 8

Pt

Cl

NO2

O2N NH3

Cl NH3

Pt

Cl

Cl

H3N NO2

O2N NH3

Pt

Cl

NO2

H3N NO2

Cl NH3

Pt

Cl

NH3

H3N NO2

O2N Cl

(2)2(3)22 (2)2(3)22

(2)22(3)2 2(3)2(2)2

( )

()

( ) ()

C(H3)3(2)3 C(H3)3(2)3

I(H2)3C3 I(H2)3C3

(H3)33+ (H3)33

+ = C, B, I

I


9/11

12/20/2011

@.. 9

Co

Cl

NO2

O2N Cl

O2N Cl

Co

Cl

NO2

O2N Cl

Cl NO2

Ru

Cl

OH2

H2O Cl

H2O Cl

Ru

Cl

OH2

H2O Cl

Cl OH2

()

()

C2(C)2(C) C2(C)2(C)

I

Re

OC Cl

ClOCRe

Cl CO

ClOC

(C)53

C()3(C)5.1,5H2

I

Ni

CN

CN

CN

CN

NC

3-

Ni

CN

NC CN

NC CN

3-

Co

C

C

OC

O

O

Co

CO

CO

CO

CO

CO

CoOC Co

CO

CO

CO

CO

COOC

OC


10/11

12/20/2011

@.. 10

C(B4)2 (II)

, ,

D

C(3(4)1 )2

D

(

)

II

Re

OC Cl

ClOCRe

Cl CO

COCl

Co

Cl

NO2

H3N Cl

H3N NO2

Co

Cl

NO2

Cl NH3

O2N NH3


11/11

12/20/2011

@.. 11

M

B

A

C D

A A

M

B

A

D C

A A

3 222

22

M

A

B

C A

C B

M

A

B

A C

B C

Latihan

Apakah pasangan berikut termasuk enansiomer ?

Co

Cl

Cl

H3N NO2

H3N NO2

Co

Cl

Cl

O2N NH3

O2N NH3

Pt

Cl NH3

H3N Cl

Pt

H3N Cl

Cl NH3

Co

H2O

Cl

H3N NO2

H3N NO2

Co

H2O

Cl

O2N NH3

O2N NH3

Co

NO2

NO2

H3N Cl

H3N H2O

Co

NO2

NO2

Cl NH3

OH2 NH3

II LL

Tatanama Dan Isomerisasi Senyawa Kompleks Ponco

Documents

Transcript of Tatanama Dan Isomerisasi Senyawa Kompleks Ponco