Sudut Pandang Rekayasa Proses Pangan dalam...
Transcript of Sudut Pandang Rekayasa Proses Pangan dalam...
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Sudut Pandang Rekayasa Proses Pangan dalam Mempelajari Fenomena Dasar pada Ilmu Pangan
Kuantifikasi perubahan selama pengolahan/penyimpanan untuk penarikan kesimpulan.
Contoh Kasus : Penentuan Umur Simpan Produk
PURWIYATNO HARIYADIphariyadi.staff.ipb.ac.id
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
REKAYASA PROSES PANGAN ?
Food process engineering
• is a broad field that is concerned with the application of engineering principles and concepts to the handling, manufacturing, processing and distribution of foods.
(R P Singh, R.P. And Heldman, D.R. 2008. Introduction to Food Engineering. Academic Press)
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
REKAYASA PROSES PANGAN ?
• is concerned with feasibility and practicality, that is, will something work and how much will it cost?
• Food engineers are educated to analyze, synthesize, design, and operate complex
systems that manipulate mass, energy, and information to transform material and
energy into more useful form
Valentas, K.J., Levine, L and Clark, J.P. 1991. Food Processing Operation & Scale-up. Marcel
Dekker Incorporated).
Food process engineering
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
“MAKE”
REKAYASA PROSES PANGAN ? –Perkembangan 25 tahun terakhir .............
Efisiensi. - Batch continuous processing- Improving process reliability- Reducing waste products, and - Effective energy utilization
“bet
ter
valu
e o
f fo
od
s”
1970 ~1980 ~1990 ~2000 ~2013
FOOD SAFETY
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
“SERVICE”
“MAKE” “MAKE”
+ Melayani kebutuhan masyarakat;
Convinience, food service
REKAYASA PROSES PANGAN ? –Perkembangan 25 tahun terakhir .............
1970 ~1980 ~1990 ~2000 ~2013
“bet
ter
valu
e o
f fo
od
s”
FOOD SAFETY
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
“CARE”
“SERVICE”
“MAKE” “MAKE”
“SERVICE”
“MAKE”
+ ‘Care’ food business :
Perawatan kesehatan, kebugaranPerawatan lingkungan
Perawatan thd “sosial” fair trade
REKAYASA PROSES PANGAN ? –Perkembangan 25 tahun terakhir .............
1970 ~1980 ~1990 ~2000 ~2013
“bet
ter
valu
e o
f fo
od
s”
FOOD SAFETY
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Lebih personal:Perscribed
food and Nutrition
“CARE”
“SERVICE”
“MAKE”
“CARE”
“SERVICE”
“MAKE”
REKAYASA PROSES PANGAN ? – …KEDEPAN ?
“MAKE”
“SERVICE”
“MAKE”
1970 ~1980 ~1990 ~2000 ~2013
“bet
ter
valu
e o
f fo
od
s”
FOOD SAFETY
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
- You have to produce (even though with imperfect information)
ITP703 Anda sebagai Ahli Pangan
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
- You have to produce (even though with imperfect information)
- Thinking like an engineer- You don't have to be an engineer to think like one.- Many cases where it is a definite advantage to think
like an engineer.
ITP703 Anda sebagai Ahli Pangan
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
- You have to produce (even though with imperfect information)
- Thinking like an engineer- You don't have to be an engineer to think like one.- Many cases where it is a definite advantage to think
like an engineer.
- You have to examine the process(es) involved in the problem to be solved.
- You don’t only look at the symptoms of a problem but looks at the processes involved to get to the root cause of the problem.
ITP703 Anda sebagai Ahli Pangan
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
- You have to produce (even though with imperfect information)
- Thinking like an engineer- ……………………- …………………..
- …………………- ……………………..- Use proven analysis methods. Find and use a set of methods
that have been proven to work in analyzing problems.
ITP703 Anda sebagai Ahli Pangan
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
- You have to produce (even though with imperfect information)
- Thinking like an engineer- ……………………- …………………..
- …………………- ……………………..- Use proven analysis methods. Find and use a set of methods
that have been proven to work in analyzing problems. You have to know how to apply those methods BUT, more importantly, you have to know which methods to
apply to a given situation. YOU have to know about and uses appropriate tools
to carry those methods out.
ITP703 Anda sebagai Ahli Pangan
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
- You have to produce (even though with imperfect information):
- ……………- Learns why (not just how) something is done.
(If you only know how something is done, you will eventually do it wrong. You need to understand why something is done, to make sure that you are doing it correctly).
- Must come up with an answer to the problem.
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
- You have to produce (even though with imperfect information):
- ……………- ……………
- Keep your skills updated. (Applying an out-of-date solution is almost as bad as not providing any solution. You have to constantly looks to see if new, better solutions to a problem exist).
You must fully understand the“Physical, chemical, biological + engineering phenomena”
behind the problem you are facing (“object or problem of your study”)
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
"To measure is to know."
"If you can not measure it, you can not improve it."
"In physical science the first essential step in the direction of learning any subject is to find principles of numerical reckoning and practicable methods for measuring some quality connected with it. I often say that when you can measure what you are speaking about, and express it in numbers, you know something about it; but when you cannot measure it, when you cannot express it in numbers, your knowledge is of a meagre and unsatisfactory kind; it may be the beginning of knowledge, but you have scarcely in your thoughts advanced to the state of Science, whatever the matter may be." [PLA, vol. 1, "Electrical Units of Measurement", 1883-05-03]
Quotations ofLORD KELVIN
(Sir William Thomson)
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
BEWARE: Syndrome “the latest version“ software
garbage in garbage out I have one good news and one bad news. The good news is that statistical analysis in now easy to perform. The bad news is that statistical analysis in now easy to perform(Sastroasmoro, 2000)
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
A
C
B
D
[S]
Vo
Vo
[S]
Rule of thumbs:0,1 Km<[S]<10 Km
ITP703 Anda sebagai Ahli Pangan
Perhatikan: "minimal experimental design" yang diperlukan, dll
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
10
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
100
80
60
40
20
00 2 4 6 8 10 t
Storage Time (months)
Obs
reve
d Va
lue
T2T3
T1 < T2 < T3
T1
ITP703 Anda sebagai Ahli Pangan
Perhatikan: "minimal experimental design" yang diperlukan, dll
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
Perhatikan: "Number & frequency of sampling” yang diperlukan
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
T25 T30 T35 T40t
t1 t1 t1 t1 t1t2 t2 t2 t2 t2t3 t3 t3 t3 t3t4 t4 t4 t4 t4Perhatikan:
"Number & frequency of sampling” yang diperlukan
ITP703 Anda sebagai Ahli Pangan
Perhatikan: "minimal experimental design" yang diperlukan, dll
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
Menghasilkan 1 data: k, T25C
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Perhatikan: "Number & frequency of sampling” yang diperlukan
ITP703 Anda sebagai Ahli Pangan
Perhatikan: "minimal experimental design" yang diperlukan, dll
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
Menghasilkan 1 data: k, T25C
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Minimal Experimental Design?
Hati-hati dengan well established model :kinetika, reologi,dll
ITP703 Anda sebagai Ahli Pangan
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
12
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
A B
Linier?
ITP703 Anda sebagai Ahli Pangan
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
13
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
ITP703 Anda sebagai Ahli Pangan
Check!• Theoretical background
• Assumptions
• Your data?– Unit and dimensions
– Mass balance
– Energy balance
– Momentum balance
– ETC
Back to basics: • Understand the “physical, chemical, biological + engineering
phenomena” behind the problem you are facing (“object or problem of your study”)
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected] [email protected]
Case 1.Kinetic of food quality changes during processing and storage- Understanding Shelf Life of Foods
Purwiyatno HariyadiDepartment Food Science & Technology, Faculty of Agricultural TechnologyandSoutheast Asian Food & Agricultural Science & Technology (SEAFAST) Center,
Bogor Agricultural University
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Main References :
Labuza,T. 2007. Lecture Note (http://www.ardilla.umn.edu/tplabuza.html)
Kilcast, D and Subramaniam, P. (Eds). 2000. The stability and shelf-life of food. Woodhead Publishing Limited, Abington Hall, Abington, Cambridge CB1 6AH, England
Hariyadi, P. 2006. Handouts and Modules of Shelf Life Determination (in Bahasa Indonesia). Seafast Center/Department of Food Science and Technology, Faculty of Agriculture Technology, Bogor Agricultural University.
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is Shelf life ?
Everything has a shelf life
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
The period between manufacture and retailpurchase of a food product during which theproduct is of satisfactory quality(IFT; 1974).
What is Shelf life ?
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
The time during which the food product will :1. remain safe;2. be certain to retain desired sensory, chemical, physical
and microbiological characteristics;3. comply with any label declaration of nutritional data,
when stored under the recommended conditions. (IFST Guidelines, 1993)
What is Shelf life ?
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Shelf-life as the period during which a food productmaintains its microbiological safety and suitability at a specified storage temperature and, where appropriate, specified storage and handling conditions (Codex Alimentarius, CAC/RCP-46; 1999) .
What is Shelf life ?
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Open Dating?Yahoo/Google ?
Open shelf-life dating
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Open dating is the use of dates(means the use of legible terms such as a day, month, and year; NOT a code, or a symbol) on a can or package of food that gives the consumer (including distributors, wholeseller or retailers) an indication of when the food was packaged or by when it should be sold or used.
Open shelf-life dating
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Open shelf-life dating
Why?
1. Encourages better handling practices by wholesalers, retailers, andconsumers by expediting the sale or use of food near the end of shelf life.
2. Increase consumer confidence in the freshness of food purchased.
3. Better handling practices attributed toopen dating could minimize nutrient loss.
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Can be expressed as :
1. date of pack or manufacture,2. pull date or sell-by date,3. best-if-used-by date,4. expiration date or use-by date, or5. combination of two of the above.
Open shelf-life dating
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Expressed as Expiration date
• Date that indicates that before that date food products is still in “satisfactory quality” or “desired” condition” (provided that product stored under the recommended conditions)
• END of shelf life
Open shelf-life dating
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Expressed as Expiration date
Open shelf-life dating
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
20
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Expressed as Expiration date
Open shelf-life dating
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “satisfactory quality“ ?What is “desired” ?
Except in situations in which microbiological safety is an issue, the definition of shelf-life is related to the positioning of the product in themarket in terms of quality and customer perceptions of that quality.
END of SHELF LIFE?
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected] [email protected]
END of SHELF LIFE?
• What is specific quality properties ?• What is “desired” quality? What is “satisfactory quality”? • Who determined “desired”/”satisfactory quality”? • At what condition food product is not in ”satisfactory
quality” condition?
• How “satisfactory quality” changes during distribution, storage, display ???
• Kinetic of quality changes
What is “critical factor” for customer perceptions of quality ?
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “critical factor” for customer perceptions of quality ?
Kilcast, D and Subramaniam, P.
(Eds). 2000.
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
22
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “critical factor” for customer perceptions of quality ?
Kilcast, D and Subramaniam, P.
(Eds). 2000.
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “critical factor” for customer perceptions of quality ?
Kilcast, D and Subramaniam, P.
(Eds). 2000.
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
23
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “critical factor” for customer perceptions of quality ?
Kilcast, D and Subramaniam, P.
(Eds). 2000.
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “critical factor” for customer perceptions of quality ?
“critical Factor”
Whichone?
a. (Micro)biological factors : bacteria, mold, yeast
b. Chemical factors : vit C., thiamin, riboflavin, etc
c. Nutritional factors : protein, fats, digestion quality, etc
d. Fucntionality factors : enzyme activity, probiotic acitivity,antioxidant activity, etc
e. Physical factors: Viscosity, texture, color, emulsion stability, etc
f. Organoleptic factor : Appearance quality, odor, taste, etc
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “critical factor” for customer perceptions of quality ?
“critical Factor”
Whichone?
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
FACTORS INFLUENCING SHELF-LIFE OF FOODSA. intrinsic (properties of the final product) :
• Water activity (aw) (available water).• pH value and total acidity; type of acid.• Available oxygen.• Nutrients.• Natural microflora and surviving microbiological
counts.• Natural biochemistry of the product formulation
(enzymes, chemical reactants).• Use of preservatives in product formulation (e.g.
salt).
What is “critical factor” for customer perceptions of quality ?
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
What is “critical factor” for customer perceptions of quality ?
FACTORS INFLUENCING SHELF-LIFE OF FOODSB. Extrinsic factors (factors the final product encounters as it moves through the food chain) :
• Time–temperature profile during processing.• Temperature.• Relative humidity (RH).• Exposure to light (UV and IR).• Environmental microbial counts.• Composition of atmosphere within packaging.• Subsequent heat treatment (e.g.
Reheating/cooking before consumption).• Consumer handling.
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
• Experiments & Analysis
• Emperical Analysis
SHELF LIFE
Informations needed :• Quality critical factor(s)?• Value of critical factor(s)
• Maximum value (quality at the factory gate)
• Minimum value of critical factor(s) : minimum quality at the end of shelf-life
• Kinetic parameters for quality changes (Ea, Q10)
PRINCIPLES OF SHELF LIFE DETERMINATION
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Measure either loss of A, desirable quality marker, or production of B, undesirable quality marker
A = qualityt = time
k = rate constantn = reaction order
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
A B-dA/dt = kAn
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Zero order (n=0) quality changes -dA/dt = kAn
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Zero order (n=0) quality changes-dA/dt = kz or A = A0 - kz t
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
If Qs is quality level at the end of shelf life, thenAs= A0 - kz ts
orts = (A0-As)/ kz
at whichts is shelf life of the product
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
Zero order (n=0) quality changes-dA/dt = kz or A = A0 - kz t
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Just Illustration:
Ao = 100 units at time zeroA = 60 units at 20 weeksWhat is kz if quality change follow zero order ?
Remember, kz is a slope ∆Y/∆X= (100-60)/(20-0)= 40/20 = 2 units per day
Thus 2 units per day x 20 days is loss of 40 units (with 60 units of quality left)
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
Zero order (n=0) quality changes-dA/dt = kz or At = A0 - kz t
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
100
80
60
40
20
00 2 4 6 8 10
Storage Time (months)
Qua
lity
Val
ue
Firts order (n=1) kinetic of quality changes-dA/dt = kA1 -dA/dt = kfA
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
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ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Firts order (n=1) kinetic of quality changes-dA/dt = kA1 -dA/dt = kfA
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
or ln (A/A0) = - kt
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Firts order (n=1) kinetic of quality changes-dA/dt = k A1
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
or ln (A/A0) = - kft
Sudut Pandang Rekayasa Proses Pangan dalam Menjelaskan Fenomena Dasar Ilmu Pangan”
ITP703 – Ilmu Pangan LanjutPurwiyatno [email protected]
30
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Firts order (n=1) kinetic of quality changes-dA/dt = k A1
PRINCIPLES OF SHELF LIFE DETERMINATION
KINETIC OF QUALITY CHANGES
or log (A/A0) = - (kf/2.3)t
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If As is A at the end of shelf life, thenln (As/A0) = - kfts
Or ts = [ln(A0/As)]/kf
Or t1/2 = 0,693/ kf
At which ts is shelf life of product
PRINCIPLES OF SHELF LIFE DETERMINATION
Firts order (n=1) kinetic of quality changes-dA/dt = kA or ln (A/A0) = - kft
KINETIC OF QUALITY CHANGES
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Just Illustration :
Ao = 100 units at time zeroA = 60 units at 20 weeksWhat is kf if quality changes follows first order?Remember slope is ∆Y/∆X but on Ln scale so
= (Ln( 60/100))/(20-0) = 0.51/20= 0.02554 day-1
A= Aoe-kft A= 100 x e-0.02554x20 = 100 x e-0.511 = 60
PRINCIPLES OF SHELF LIFE DETERMINATION
Firts order (n=1) kinetic of quality changes-dA/dt = kA or ln (A/A0) = - kft
KINETIC OF QUALITY CHANGES
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Examples of kinetic of quality change of slecetd product during storage/processing
Zero Order• Overall quality of frozen food
• Non-enzimatic browning
First Order• Vitamin loss/degradation
• Mikcorbial inactivation
• Oxidatif deterioration of color
• Thermal degradation of texture
PRINCIPLES OF SHELF LIFE DETERMINATION
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Quality degradation during storage : Difference between zero and first order kinetics
Zero or First Order Kinetics?
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Quality degradation during storage : Difference between zero and first order kinetics
Zero or First Order Kinetics?
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Quality degradation during storage : Difference between zero and first order kinetics
Zero or First Order Kinetics?
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Quality degradation during storage : Difference between zero and first order kinetics
Zero or First Order Kinetics?
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Quality degradation during storage : Difference between zero and first order kinetics
Zero or First Order Kinetics?
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Quality degradation during storage : Difference between zero and first order kinetics
xx
Zone of data thatmay distinguishbetween zero andfirst orfer kinetics
Zero or First Order Kinetics?
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Quality degradation during storage : Difference between zero and first order kinetics
Zero or First Order Kinetics?
To be able to distinguish easily wwther quality changes is following zero or first order; perform experiment until the extent of quality loss is more than 50%
Published values
(27.7oC)
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Recommendation (Labuza, T. 2007)
• If few data points with time and• End Quality level is less than 50%
change from initial
Then KISS : Use zero order
Zero or First Order Kinetics?
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Case 2: Predicting Shelf life of Food by Accelerated Shelf-life Testing (ASLT) method Using Arrhenius model
Purwiyatno HariyadiDepartment Food Science & Technology, Faculty of Agricultural TechnologyandSoutheast Asian Food & Agricultural Science & Technology (SEAFAST) Center,
Bogor Agricultural University
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Main References :
Labuza,T. 2007. Lecture Note (http://www.ardilla.umn.edu/tplabuza.html)
Kilcast, D and Subramaniam, P. (Eds). 2000. The stability and shelf-life of food. Woodhead Publishing Limited, Abington Hall, Abington, Cambridge CB1 6AH, England
Hariyadi, P. 2006. Handouts and Modules of Shelf Life Determination (in Bahasa Indonesia). Seafast Center/Department of Food Science and Technology, Faculty of Agriculture Technology, Bogor Agricultural University.
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Accelerated Shelf Life TestArrhenius Method
Principles : accelerate rate of quality loss by increasing temperature of storage
Quality loss -dA/dt = kAn
Rate constant (k) depends on Temperature :
k = k0.exp-Ea/RT
k = rate constantk0 = frequency factor (NOT as function of T)Ea = Activation EnergyT = Absolute Temperature (K)R = Gas constant; 1,986 kal/mol (8.314 J/mol.K)
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Valeu of k as affected by temperature (T) Arrhenius Plot
k
(1/T)
TR
aE
eokk-
=
Accelerated Shelf Life TestArrhenius Method
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Slope- Ea/R
Ln k = Ln ko - (Ea/R)(1/T)
Ln k
(1/T)
Arrhenius Plot
Ln ko
Accelerated Shelf Life TestArrhenius Method
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Example : Carbohydrate at amorphous condition may undergoes crystalization at low temperature.
Know your product WELL!
Retrogradation• Texture hardening• Release of water• Bread staling
Accelerated Shelf Life TestArrhenius Method
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• Rate of “bread staling” incease as temperature of storage decrease (4°C - 40°C)
• Maximum “staling” rate : 4°C.
Example : Carbohydrate at amorphous condition may undergoes crystalization at low temperature.
Know your product WELL!
Accelerated Shelf Life TestArrhenius Method
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• Arrhenius anomali. Effect of temperature on “bread staling”
• Negative Ea Ea" = - 9 kcal/mol..
3.2 3.3 3.4 3.5 3.6
1/T x 103
Ln (
stal
ing
rate
)
Accelerated Shelf Life TestArrhenius Method
Know your product WELL!
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100
80
60
40
20
0
0 2 4 6 8 10
Storage Time (months)
Val
ue o
f Qua
lity
Mar
ker
T1
T2T3
T1 < T2 < T3
Number & frequency of sampling !
Accelerated Shelf Life TestArrhenius Method -- in Practices
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Do experiment and measurement of quality loss –at least- at 3 different temperatures of storage Statistical problems
• Can’t do predictions with one temperature
Accelerated Shelf Life TestArrhenius Method -- in Practices (1a)
ln k
1/T
?
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Do experiment and measurement of quality loss –at least- at 3 different temperatures of storage Statistical problems
• Can’t do predictions with one temperature• Two points always give a straight line
Accelerated Shelf Life TestArrhenius Method -- in Practices (1a)
ln k
1/T
ITP703 - Ilmu Pangan LanjutPurwiyatno [email protected]
Do experiment and measurement of quality loss –at least- at 3 different temperatures of storage Statistical problems
• Can’t do predictions with one temperature• Two points always give a straight line• Three points give poor statistics
Accelerated Shelf Life TestArrhenius Method -- in Practices (1a)
ln k
1/T
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• Choose temperature of storage higher that normal T of storage
• Temperature od storage will not cause changes in mechanism of quality loss
• Again; know your product WELL hub Arrhenius:
A
B
ln k
1/T
RangeOf
StorageTemp
Range of ASLT
Temperature
Maximum ASLT
Temperature
Accelerated Shelf Life TestArrhenius Method -- in Practices (1b)
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Type of Product Temperature of ASLT (°C)
Control Temperature
(°C)Canned foods 30, 35, 40, 45 4
Dried foods 30, 35, 40, 45 -18
Chilled Products 5, 10, 15, 20 0
Frozen products -5, -10, -15 < -40
So, which three (3) different temperatures of storage? Know your product WELL
Accelerated Shelf Life TestArrhenius Method -- in Practices (2)
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Accelerated Shelf Life TestArrhenius Method -- in Practices (3a)
• Frequency of sampling Know your product WELL
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Shelf life at 5oC= 12 months
If Q10=2 ASLT (at 25oC) : 3 months
If Q10=3 ASLT (at 25oC) : 1.3 months
If Q10=4 ASLT (at 25oC) : 23 days
Number of samples? Statistical problems• Can’t do predictions with one temperature• Two points always give a straight line• Three points give poor statistics
Accelerated Shelf Life TestArrhenius Method -- in Practices (3a)
• Frequency of sampling Know your product WELL
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Value of k at normal storage condition May be predicted/calculated using Arrhenius Equation :
k = ko.exp-Ea/RT
ln k = ln ko – Ea/R (1/T)
Ta(normal T of storage)
Ln k
1/TZone of experiment -
accelerated
T1 T2 T3
And, extrapolatevalue of k at normal T of storage:
Accelerated Shelf Life TestArrhenius Method -- in Practices (4)
k1k2
k3
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Determinn As (quality value at end of shelf life).• Standard of identity, SNI, etc• Sensory properties
Shelf life may be predicted using :
ts = (A0-As)/kz; if quality changes follow zero order kineticsts = [ln(A0/As)]/kf; if quality changes follow first order kinetics
Accelerated Shelf Life TestArrhenius Method -- in Practices (5)
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Accelerated Shelf Life TestArrhenius Method -- in Practices (6)
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Accelerated Shelf Life TestArrhenius Method -- in Practices (7)
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Accelerated Shelf Life TestArrheniusMethod --in Practices (8)
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Accelerated Shelf Life TestArrhenius Method -- in Practices (9)
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Accelerated Shelf Life TestArrhenius Method -- in Practices (10)
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Accelerated Shelf Life TestArrhenius Method -- in Practices (11)
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Accelerated Shelf Life TestArrhenius Method -- in Practices (12)
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Degree of losses of selected vitamin predicted using Arrhenius model as compared to its actual losses
Losses (%) after 6 months of storage , 20oC, RH 75%
Vitamin Predicted by Result ofArrhenius Model Analysis
Vitamin C(ascorbic acid) 24,0 23,0
Vitamin A 15,0 10,0
Folic Acid 8,1 7,4
Vitamin B12 9,2 7,7
Accelerated Shelf Life TestArrhenius Method -- in Practices (13)
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Thank youterimakasih