GEOKIMIA 2

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    BUMI TEMPAT KITA

    BERPIJAK

    BENTUK DAN STRUKTUR BUMI

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    BUMI DAN ALAM SEMESTA

    Bumi adalah salah satu unit cakrawaladari sistem tata surya kita, yang terdapat

    matahari, planet, dan satelit

    Dalam mempelajari geokimiapengenalan kandungan dan komposisi

    bumi sangat penting

    Bertambahnya kedalaman berubah sifatfisik dan kimianya

    Faktor Tekanan dan Temperatur sangat

    menentukan komposisi bumi bagian

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    Bumi kita tersusun oleh tiga bagian

    besar mantel, inti luar dan inti bagiandalam

    Kerak samudra berbeda secara

    komposisi juga berat jenisnya dengansamudra

    Kerak samudra bersifat basalatis dan

    bersifat SIMA Kerak benua bersifat granitis dan

    bersifat SIAL

    Mantel kaya akan besi, Aluminium,

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    Struktur Bumi

    Nama Sifat Kimia Sifat Fisik

    Atmosfir O2,H2O,CO2,

    N2

    Gas

    Biosfer H2O, bahanOrganik

    Cairan, Padatan

    Hidrosfe

    r

    Air tawar, Air

    Asin

    Cairan, Padatan

    Kerak Batuan Silikat Padatan

    Mantel Bahan Silikat, >

    Olivin, Piroksin

    Padat

    Teras Campuran besi Cairan, Padatan

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    STRUKTUR BUMI, RINGWORD,1975KEDALAMAN NAMA BAGIAN SUSUNAN BATUAN

    20-25 km

    dibawah kerak

    Benua

    Kerak bumi Bataun beku,

    sedimen, metamorf

    10-12 km

    dibawah kerak

    Samudra

    Kerak bumi Bataun beku, sedimen,

    metamorf

    400 km Selubung atas Eklogit dan Peridotit

    Kaya Fe,Mg,Ca, Na,

    Silikat Al

    400-1000 km Jalur peralihan Silikat besi padat, Mg,Ca, Al, Oksida besi

    1000-2900 km Selubung bawah Oksida besi padat,

    Mg,SiO2

    2900-5100 km Inti luar Besi sedikit silikat

    5100-6371 km Inti dalam Besi padat

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    MOHO - ~40km

    Wiechert-

    Gutenberg

    discontinuity

    CRUST

    CORE

    3 Major Zones, 2 Transitions

    Earths Chemical Differentiation

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    Mantle Composition

    Oxides Mantle Crust

    SiO2 45 60

    MgO 37 4

    FeO 8 4

    Al2O3 3 15

    CaO 3 6

    Na2O 0.5 3Cr2O3 0.4 0.01

    MnO 0.2 0.1

    TiO2 0.1 1

    Mantle makes up >2/3 of earths

    mass

    Composition approximated by

    pyrolite, an invention ofRingwoods to explain the way

    these waves move through the

    mantle.

    SiO2 45%

    MgO 30-40%FeO 8-13%

    Al2O3 3%

    CaO 3%

    High Mn, Cr, Ti

    Mantle versus crust

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    MAGMATIC DIFFERENTIATION

    Differentiation processes affect all major rock types. Wide variety of specificreactions happen as igneous, metamorphic, and sedimentary rocks form,change, transport ions, and decompose which result in geochemicaldifferentiation.

    How does Magma composition change?

    Hot material in different parts of the mantle?

    Melts some rocks into itinteracts with surrounding material (PartialMelting)

    Fractional crystallizationcrystals form and get separated form

    source.

    Why earths crust has widely varyingchemistry?

    Liqu id

    MagmaFractional crystallization

    Residual melt

    Crystal l ized

    rock

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    Plate Tectonics - Igneous Genesis

    1. Mid-ocean Ridges2. Intracontinental Rifts

    3. Island Arcs

    4. Active Continental

    Margins

    5. Back-arc Basins

    6. Ocean Island Basalts7. Miscellaneous Intra-

    Continental Activity

    kimberlites,

    carbonatites,

    anorthosites,

    etc.

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    Trace elements and partition coefficients

    Definition: a trace elementis an element present at concentration too low tosignificantly affect the phase relations; hence it is a passive agent in the

    processes determined by the major and minor elements. In particular thebehavior of the trace element does not depend on its own concentration(Henrys Law).

    To use trace elements, we need to know how they are distributed, orpartitioned, among phases. Most often this is expressed by looking at theratio of concentration in a solid phase to concentration in the liquid phase,thepartition coefficient

    Dimineral/melt

    i mineral

    i melt

    Di f j

    j

    Dij /melt

    When several minerals are present in the rock, then we can find the bulkpartition coefficientby a suitable weighted average of mineral partition

    coefficients:

    If the bulk partition coefficient < 1, the trace element is termed

    incompatible.If the bulk partition coefficient > 1, the trace element is compatible

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    Nuclear reactions

    determine element

    abundance

    Is the earth

    homogeneousthough?

    Is the solar system??

    Is the universe???