Perancangan Pabrik Methylene Chloride Kap 25.000 ton/tahunReaktor 1 (hydrochlorinasi ethanol!Basis Bahan Baku Methanol (kg)Basis Bahan Baku Methanol (kmol)Koponen "ahan "aku R#1Reaksi Pebentukan Methyl ChlorideMol HCl (kmol)MR HCl(kmol/kg)Massa HCl (kg)Mol methanol (kmol)MR Methanol (kg/kmol)Massa methanol (kg)Konversi terhadap methanolSelectivitas terhadap methyl chlorideReaksi Pementukan Methyl chlorideMula!mula (kmol)Bereaksi (kmol)Sisa (kmol)Reaksi Pebentukan $iethyl %ter (Reaksi &aping!Mol methanol (kmol)Konversi terhadap methanolSelektivitas terhadap dimethyl eterPerandingan molar ahan aku (HC"/Methanol#$%&)Reaksi Pementukan Methyl chlorideMula!mula (kmol)Bereaksi (kmol)Sisa (kmol)'asil Reaksi R#1Reaksi Pebentukan Methyl ChlorrideMethanol (kmol)HCl (kmol)methyl chloride (kmol)H'( (kmol)Reaksi Pebentukan $iethyl %terMethanol (kmol))imethyl eter (kmol)(eraca assa di R#1KomponenMethanolHC"Methyl chloride)imethyl eter*otal+eraca massa di ,uenchingKomponenMethanolHClMethyl chloride)imethyl eter)otalkmolkg+eraca massa di dryng to-er $KomponenH'( (kmol)H'(H'(HClMethyl chloride)imethyl eter*otalkmolkg+eraca massa di destilasi $KomponenHClMethyl chloride*otalkmolkgReaktor 2 Chlorinasi ethyl chloride Bahan Baku (kg)Koponen "ahan "aku R#1Reaksi Pebentukan MethyleneChlorideMassa Cl'(kg)MR Cl'(kmol/kg)Mol Cl' (kmol)Massa Methyl chloride (kg)MR Methyl chloride (kg/kmol)Mol Methyl chloride(kmol)Konversi terhadap Methyl chlorideKonversi terhedap methylene chlorideKonversi terhadap chloro.ormH'(H'S(/Perandingan molar ahan aku(Cl'/CH&Cl # 0123)Reaksi 1 Pebentukan Methylene ChlorideReaksi Pementukan Methylene chlorideMula!mula (kmol)Bereaksi (kmol)Sisa (kmol)Reaksi saping 1 pebentukan chloro*orReaksi Pementukan Chloro.ormMula!mula (kmol)Bereaksi (kmol)Sisa (kmol)Reaksi saping 2 pebentukan Carbon tetrachlorideReaksi Pementukan Caron tetrachlorideMula!mula (kmol)Bereaksi (kmol)Sisa (kmol)'asil Reaksi R#2Reaksi pebentukan ethylen chlorideMethyl Chloride (kg)Cl' (kmol)Methylene chloride (kmol)HCl (kmol)Reaksi saping pebentukan chloro*orMethylene chloride (kmol)Cl' (kmol)Chloro.orm (kmol)HCl (kmol)Reaksi saping pebentukan carbon tetrachlorideChloro.orm(kmol)Cl' (kmol)Caron tetrachloride (kmol)HCl (kmol)(eraca assa di R#2KoponenMethyl ChlorideCl'HClMethylene ChlorideChloro.ormCaron tetrachloride)otalkolkg(eraca assa di +uenching #2KoponenMethyl ChlorideHClMethylene ChlorideChloro.ormCaron tetrachloride)otalkolkg(eraca assa asuk gas li+uid separator 1 (,1!KoponenMethyl ChlorideHClMethylene ChlorideChloro.ormCaron tetrachloride)otalKolKg(eraca assa asuk gas li+uid separator 2 (,-!KoponenKoponenMethyl ChlorideHClMethylene ChlorideChloro.ormCaron tetrachloride)otalKolKg(eraca assa asuk gas li+uid separator - (,5!KoponenMethyl ChlorideHClMethylene ChlorideChloro.ormCaron tetrachloride)otalKolKgKoponen Masuk#keluar Kondensor keseluruhanKoponenMethyl ChlorideHClMethylene ChlorideChloro.ormCaron tetrachloride)otalkolkg(eraca Massa $estilasi 1KoponenMethyl ChlorideHClMethylene ChlorideChloro.ormCaron tetrachloride)otalkolkg(eraca Massa $estilasi 2KoponenMethyl ChlorideMethylene ChlorideChloro.ormCaron tetrachloride)otalkolkg(eraca Massa $estilasi -KoponenMethylene ChlorideChloro.ormCaron tetrachloride)otalkolkgPerancangan Pabrik Methylene Chloride Kap 25.000 ton/tahunReaktor 1 (hydrochlorinasi ethanol!$1000&$%'300HCl Methanol/ &/$%4442 &$%'300HCl (kg)/1''/%3&20HC" &45$13'0%6&&& !HCl (kmol)HC" &45/$%4442 !/$%4442&4%3000$3'0%6&&&&$%'300&'%0000$000%000076%3577%65Reaksi Pebentukan $iethyl %ter (Reaksi &aping!0%3&0&76%350%'5H'(H'(Kol kgReaksi Pebentukan Methyl Chlorride0%3&0& $4%7200$0%7/20 &77%34/2&0%2$72 $133$%&//'&0%2$72 33'%73//Reaksi Pebentukan $iethyl %ter0%/466 $3%00000%0&06 $%/$370%0&06 0%33/$Masuk R!$kmol kg&$%'300 $1000%00000%06&3 0%06&3/$%4442 $13'0%6&&&! !! !.-.0001 2/520.0112Masuk 8uenching !$ 9liran 2'kmol kg0%/466 $3%0000&0%6&&7 333%0$02$0%7/20 &77%34/2&0%2$72 $133$%&//'0%0&06 $%/$37.-.0001 2/522.--51112.5202-/2--.2522Masuk )ryng to-er !$(kg)9liran 6'kmol kg2%/0$& $&&%''&0'%$67/ 27%7$'7&0%2$72 $133$%&//'0%0&06 $%/$37! !,0.-,11 1/.15.2011,2.-,112/,-2.0110Masuk )estilasi !$(kg)9liran 6'kmol kg'%$67/ 27%7$'7&0%2$72 $33$%&//'-2.0001 11-1.25.2-2.000111-1.25.2Reaktor 2 Chlorinasi ethyl chlorideCl' dan CH&ClCl'CH&Cl& /Cl' kmol kg''%722& $14&$%&66/:mpurities (HCl)Kmol Kg0%''/4 6%$727$14&$%&66/2$%0000''%722&$13/2%$&6&30%3000&0%4&4/3'%305&2%005$3%6&05Reaksi saping 2 pebentukan Carbon tetrachloridekmol kgReaksi pebentukan ethylen chloride$/%33'& 2&/%67034%67&' /67%/$4&$4%06/$ $1&42%$/72$4%06/$ 362%020'Reaksi saping pebentukan chloro*or$0%$&&0 64$%&0/'0%7/'$ 44%66433%73$$ 2$$%$37&3%73$$ '$2%'$40Reaksi saping pebentukan carbon tetrachloride3%007$ 376%36'60%0000 0%00000%7/'$ $/3%02220%7/'$ &/%&63&Masuk 3liran 11 (kol!3liran 10kol kg''%722& $14&$%&66/0%''/4 6%$727! !! !! !2-.2010 1/1-0.521-5-.2-2--/121..2,1Masuk9liran ''kmol kg$/%33'& 2&/%6703'&%'0$7 6/4%647/$0%$&&0 64$%&0/'3%007$ 376%36'60%7/'$ $/3%02225-.2-2- -/121..2,15-.2-2--/121..2,1(eraca assa asuk gas li+uid separator 1 (,1!Masuk9liran &6kmol kg$/%33'& 2&/%6703'&%'0$7 6/4%647/$0%$&&0 64$%&0/'3%007$ 376%36'60%7/'$ $/3%02225-.2-2- -/121..2,15-.2-2--/121..2,1(eraca assa asuk gas li+uid separator 2 (,-!Masuk9liran /'kmol kg$$%7$'0 40$%3360''%3/2' 6''%72&$&%3/23 &0$%3&&6$%0000 $$7%30$20%$''2 $6%70&3-0.1205 1/21,.,100-0.12051/21,.,100(eraca assa asuk gas li+uid separator - (,5!Masuk9liran /&kmol kg6%2'60 //0%24'6'$%2006 27'%02630%42'4 32%$4200%07$0 $0%627/0%0044 $%0''$-1.1000 1/-01.0002-1.10001/-01.0002Koponen Masuk#keluar Kondensor keseluruhanMasuk3liran -2kol kg$/%33'& 2&/%6703'&%'0$7 6/4%647/$0%$&&0 64$%&0/'3%007$ 376%36'60%7/'$ $/3%02225-.2-2- -/121..2,15-.2-2--/121..2,1Masuk3liran 51kol kg6%77&2 /3/%$6'4'%3/&4 7'%6/'2$0%$&&0 64$%&0/'3%007$ 376%36'60%7/'$ $/3%02222..1215 2/151.00002..12152/151.0000Masuk3liran 11kol kg0%00$2 0%064$$0%$&&0 64$%&0/'3%007$ 376%36'60%7/'$ $/3%022211.0252 1/105.050211.02521/105.0502Masuk3liran 100kol kg0%000/ 0%0'773%0062 376%3&720%7/'$ $/3%02225.0511 .,-.1,.,5.0511.,-.1,.,Perhitungan impuritiesMethanol (5)H'( (5)Massa methanol ; H'(Massa H'( (kg)Mol H'( (kmol)Methanol (kg)$100$%30'&MethanolH'( $1000%0000 $%30'&Methanol(kmol)MethanolH'( &$%'300 0%06&3HC"&$%'300 /$%4442&0%2$72 &0%2$720%3&0& $0%7/20CH&(H ;0%3&0&0%04$40%/466

Keluar R!$kmol kg0%/466 $3%0000&0%6&&7 33&%37$7$0%7/20 &77%34/2&0%2$72 $133$%&//'0%0&06 $%/$37.-.0001 2/520.0112Masuk 8uenching !$ 9liran 2&kmol kg! !&7%3'7$ 2$$%3'&'! !! !! !-0.5201 .11.52-2112.5202-/2--.2522Masuk )ryng to-er !$(kg)9liran 6&kmol kg'CH&(H $%/60& '4%4//4! !! !! !4%3'3' 4&7%/20&2.0055 111.11,0,2.-,112/,-2.0110Keluar )estilasi !$ (kg)9liran 7& (top)kmol kg'%$67/ 27%7$'70%06&& /%'0372.2.2. 2,.1120-2.000111-1.25.2:mpurities Bahan Baku R!'Cl'Cl'77%305Methyl chloride (CH&Cl)(kmol)kmol kg&0%4&4/ $13/2%$&6&:mpuritiesKmol kg! !Cl'&0%4&4/ ''%722&$4%06/$ $4%06/$$/%33'& 4%67&'CH'Cl' ; Cl'$4%06/$ 4%67&'3%73$$ 3%73$$$0%$&&0 0%7/'$CHCl&; Cl'3%73$$ 0%7/'$0%7/'$ 0%7/'$3%007$ 0%0000000CH&Cl ;Masuk 3liran 11 (kol!3liran 1,kol kg&0%4&4/ $13/2%$&6&! !! !!!!-0.1-1, 1/5,..1-2-5-.2-2--/121..2,1Keluar 9liran &6kmol kg$/%33'& 2&/%6703'&%'0$7 6/4%647/$0%$&&0 64$%&0/'3%007$ 376%36'60%7/'$ $/3%02225-.2-2- -/121..2,15-.2-2--/121..2,1Keluar 9liran /'kmol kg$$%7$'0 40$%3360''%3/2' 6''%72&$&%3/23 &0$%3&&6$%0000 $$7%30$20%$''2 $6%70&3-0.1205 1/21,.,1005-.2-2--/121..2,1Keluar 9liran /&kmol kg6%2'60 //0%24'6'$%2006 27'%02630%42'4 32%$4200%07$0 $0%627/0%0044 $%0''$-1.1000 1/-01.0002-0.12051/21,.,100Keluar 9liran 44kmol kg3%3364 '60%2027'0%436& 23/%0'420%0000 0%0000! !! !21.2112 1/0-,..-,1-1.10001/-01.0002Keluar"otto&eparator 1kol kg'%4/0' $&&%&&'40%43/2 '&%674/4%3633 337%220//%0070 /27%06$$0%6$7& $'4%$2/&1,..022 1/-22.25,.2..12152/151.00005-.2-2--/121..2,1Keluaraliran 11 (botto!kol kg0%00$2 0%064$! !$0%$&&0 64$%&0/'3%007$ 376%36'60%7/'$ $/3%022211.0252 1/105.05022..12152/151.0000Keluar3liran 100 ("otto!kol kg! !0%000/ 0%0'773%0062 376%3&720%7/'$ $/3%02225.0511 .,-.1,.,11.02521/105.0502Keluar3liran 102 ("otto!kol kg! !0%000$ 0%002&0%7/$7 $/3%0/260.0,10 1,5.05515.0511.,-.1,.,77%6350%$35$00$%30'&$%30'&0%06&3$ata "erat Molekul KomponenHCl